DEQ-CFW_00063146

P &J3
EFFLUENT WAY q �g
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 001 MONTH March YAF��°001
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) Simalabs (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddie / Kenneth M. Hall
Mail ORIGINAL and ONE COPY to: d
ATTN: CENTRAL FILES
DIV. OF ENVIRONMENTAL MANAGEMENT
DENR (SIGNATURE OF OPERATO IN RESPONSIBLE CHARGE)
A
DATE
P.O BOX 29635 BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27626-0635 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEI iE
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DEQ-CFW 00063146

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
All monitoring data and sampling frequencies do NOT meet permit requirements
Compliant
0
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
The Outfall 001 samples for March 2. 3. 9, and 10 that were submitted to Simalabs International laboratory for BOD5
were held longer than the 48-hour maximum hold time, thereby invalidating those samples. The cause of this error
was due to a misunderstanding by the Simalab analvst with regard to the BODE hold time requirement. who has
subsequently been Instructed on these requlrements. The BOD5 results for those samples were:
03/02/01 = "estimated 123 mg/V: 03/03/01 =145 mg/L: 03/09/01 = 5.7 ma/L: and 03/10/01 = 5.3 mg/L.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Barry L. Hudson - Site Manager
Permittee (Please print or tvpe)
NC ft 87 South, Fayetteville, NC, 28306 (910) 6784400 May 31, 2001
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease W951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080 Color (Pt -Co) 00610 Ammonia Nitrogen
00082 Color (ADMI) 00625 Total lgeldhal
Nitrogen
00095 Conductivity 00630 Nitrates/Nitrites
00300 Dissolved Oxygen
00310 BOD5 00665 Total Phosphorous
00340 COD 00720 Cyanide
00400 pH 00745 Total Sulfide
00530 Total Suspended 00927 Total Magnesium
Residue 00929 Total Sodium
00545 Settleable Matter 00940 Total Chloride
01027 Cadmium
01032 Hexavaient Chromium
01034 Chromium
01037
Total Cobalt
01042
Copper
01045
Iron
01051
Lead
01092
01105
01147
31616
32730
34235
34481
38260
39516
50050
Zinc
Aluminum
Total Selenium
Fecal Coliform
Total Phenolics
Benzene
Toluene
MBAS
PCB's
Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC BA .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A 0506
%b) (2) (D) D ��vw, 1-0
ru+AY 0 2 2001
CENTRAL FILES
DEQ-CFW 00063147

EFFLUENT MAY 0 9 2001
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 001 MONTH March YEAR 2001
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddle GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) Burlington Research, Inc. (2) Burlington Research
CHECK BOX IF ORC HAS CHANGED ® PERSON(S) COLLECTING SAMPLES Robert J. Geddle / K. Mark Hall
Mail ORIGINAL and ONE COPY to: D'
ATTN: CENTRAL FILES
DIV. OF ENVIONMENTAL MANAGEMENT X
DEHNR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
P.O BOX 29535 BY THIS SIGNITURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27626-0535 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
DEM Form MR -I (IWR9) ; . NF = No flow at Outfall 001 at the sample time.
DEQ-CFW 00063148

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements Q
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
This DMR page is an addendum to the normal Outfall 001 DMR and Includes the monitoring reaulrements set
forth in the letter from Mr. Paul Rawls (NCDENR DWO FRO) dated February 16, 2001. The thermal/alkaline
treatment system was shutdown on March 18, 2001. Therefore, the last HFA-hydrate and trifluoroacetate samples
taken as a requirement of DWQ was at 0600 on March 19, 2001. The entry of "NF" indicates that there was "no flow"
at Outfall 001 at the specified time, so no grab sample could be taken.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Barry L. Hudson - Site Manager
Permittee (Please print or type)
22828 NC Hwy 87 W, Fayetteville, NC, 28306 [phone] May 31,1996
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010
Temperature
00556
Oil & Grease
00951
Total Fluoride
01067 Nickel
50080 Total
00076
Turbidity
00600
Total Nitrogen
01002
Total Arsenic
01077 Silver
Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
01027
Cadmium
01092 Zinc
Chlorine
00082
Color (ADMI)
00625
Total Kjeldhal
01032
Hexavalent Chromium
01105 Aluminum
71880 Formaldehyde
00095
Conductivity
Nitrogen
01034
Chromium
01147 Total Selenium
71900 Mercury
00300
Dissolved Oxygen
00630
Nitrates/N(trites
01037
Total Cobalt
31616 Fecal Coliform
81551 Xylene
00310
BOD5
00665
Total Phosphorous
01042
Copper
32730 Total Phenolics
00340
COD
00720
Cyanide
01045
Iron
34235 Benzene
00400
pH
00745
Total Sulfide
01051
Lead
34481 Toluene
00530
Total Suspended
00927
Total Magnesium
38260 MBAS
Residue
00929
Total Sodium
39516 PCB's
00545
Settleable Matter
00940
Total Chloride
50050 Flow
Parameter Code assistance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
*' If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCA .. '
(b) (2) (D) 1&
RAY 022001
DIV ()I- WA M tAuALiTY
DEQ-CFW 00063149

` EFFLUENT
WAY 0 9 2009
' �
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 002 MONTH March YEAR 2001
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Sladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddle GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) Simalabs (2)
CHECK BOX IF ORC HAS CHANGED � PERSON(S) COLLECTING SAMPLES Robert J. Geddle / Kenneth M. Hall
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF ENVIRONMENTAL MANAGEMENT X
DENR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
P.O BOX 29635 BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27626-0535 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
DEEM Form MR-1(121!3)
DEQ-CFW 00063150

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
NC Hwy 87 South, Fayetteville, NC, 28306 [phone] May 31, 2001
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 OII & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 008W Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080 Color (Pt -Co) 00610 Ammonia Nitrogen
00082 Color (ADMI) 00625 Total ICteldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032
Hexavalent Chromium
01034
Chromium
01037
Total Cobalt
01042
Copper
01045
Iron
01051
Lead
01092 Zinc
01105 Aluminum
01147 Total Selenium
31616
Fecal Coliform
32730
Total Phenolics
34235
Benzene
34481
Toluene
38260
WAS
39516
PCB's
50050
Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the stat 5 11
(b) (2) (D) i0i
MAY 0 2 2001
[)N Vr VVA I CM WAVY
�.,F R A! FILES
DEQ-CFW 00063151

EFFLUENT ��®p a
NPDES PERMIT NO. NC 0003673 DISCHARGE NO. 006 MONTH Mary 0 9 Et 2001
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddle GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) Simalabs ! (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddle / Kenneth M. Hall
Mall ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES L✓` 6/ L ° ' ' 3��
DIV. OF ENVIRONMENTAL MANAGEMENT X
DENR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
P.O BOX 29MS BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27626-0635 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
.11 1
11,11
11 1
������
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!'19'
Ilion
11.1
13MUMEN
ME
1:11
,11
1:11
DEQ-CFW 00063152

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements ®X
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements C�
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"i certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Barry L. Hudson - Site Manager
Permittee (Please print or type)
NC Hwy 87 South, Fayetteville, NC, 28306 [phone] May 31, 2001
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080 Color (Pt -Co) 00610 Ammonia Nitrogen
00082 Color (ADMI) 00625 Total igeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nhdtes
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032 Hexavalent Chromium
01034 Chromium
01037 Total Cobalt
01042 Copper
01045 Iron
01051 Lead
01092
01105
01147
31616
32730
34235
34481
38260
39516
50050
Zinc
Aluminum
Total Selenium
Fecal Coliform
Total Phenolics
Benzene
Toluene
MBAS
PCB's
Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
• ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b )
�f
" If signed by other than the premittee, delegation of signatory authority must be on file with the state pA#p'tA*C'A&ft .0 � 8"
(b) (2) (D) Ui v tw.
CEMft-- FILE6
DEQ-CFW 00063153

Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 04/18/01
(Facility: DUPONT NPDES#: NC0003573 Pipe#: 002 County: BLADEN
Laborat y Performing Test: SIMALABS INTERNATIONAL
' Comments:
X
Signature ofQpe or in Responsible Charge
Signatu a of Labor tort' Supervisor * PASSED: 7.24% Reduction
Mork Order: 1C113-004 Environmental Sciences Branch
MAIL ORIGINAL TO- Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
forth Carolina cerioaspnm a
Chronic Pass/Fait Reproduction Toxicity Test
.ONTROL ORGANISMS
# Young Produced
1 2 3 4 5 6 7 8 9 10 11 -12
34129129131132128132131133128135131
Chronic Test Results
Calculated t = 1.267
Tabular t = 2.624
X Reduction = 7.24
% Mortality Avg.Reprod.
0.00 31.08
Control Control
Adult (L)ive Mead L L L L L IL IL IL L IL IL IL
0.00 28.83
Treatment 2 Treatment 2
Effluent %: 3.3%
REATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV
7.318% PASS FAIL
# Young Produced 37 34 29 28 27 30 32123136 30 22 18 % control orgs X
producing 3rd
brood Chec90ne
Adult (L)ive (D)ead L L L L L L L L L L L L 100%
1st sample let sample 2nd sample Complete This For Either Test
PH Test Start Date: 03/07/01
Control 7.01 7.21 7.10 7.20 F.91 d721 Collection (Start) Date
Sample 1: 03/05/01 Sample 2: 03/08/01
Treatment 2 6.95 7.22 7.16 7.24 Sample Type/Duration 2nd
1st P/F
s s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X 24 hrs L A A
r d r d r d U M M
t t t Sample 2 X 24 hrs T P P
1st sample 1st sample 2nd sample
D.O. Hardness(mg/t) 40
Control mom
Spec. Cond.(pA hos) 95 623 480
Treatment 2
Chlorine(mg/t) : :....: n/a n/a
LC50/Acute Toxicity Test Sample temp. at receipt(*C) :::?:.:;::::::: 3.0 3.0
(Mortality expressed as %. combining replicates)
wwwwwwwwwa
Concentration
Mortality
start/end
LC50 =
95% Confidence Limits
Concentration
Mortality
start/end
LC50 =
95% Confidence Limits
Method of Determination
Movi%g.Average _ Probit _
% -- %
Spearman Kerber _ Other _
PH
Organism Tested: Ceriodephnia dubis Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
Note: Please
Complete This
Section Also
start/end
Control
High
Conc.
D.O.
f,4AY 2 2 2001
Dw
DEQ-CFW 00063154

@SEW 2
MAY 0 2 2001
ul v "f% .AuHLITY
CENTRAL FILES
DEQ-CFW 00063155

Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 04/18/01
Facility: DUPONT NPDES#: NC0003573 Pipe#: 002 County: BLADEN
Laborat�y Perfo frig Test SIMA S INTERNATIONAL
,/ j ` I Comments:
X �(
Signatur of_ r in Responsible Charge
X 'fie
Signs ure of Laboratory Supervisor * PASSED: -4.53% Reduction
Work Order: B0103013904A Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
lorth carotin cerioaapnm a
Chronic Pass/Fail Reproduction Toxicity Test
:ONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced 121123124122124118116124122121126124
Adult (L)ive (D)ead IL IL IL IL IL IL IL IL IL IL IL IL
:ffluent %: 3.3%
'REATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 1
# Young Produced 2712712612312212012212412112312511
Adult (L)ive (D)ead L L L IL IL IL IL IL D IL IL IL
Chronic Test Results
Calculated t = -0.847
Tabular t = 2.508
% Reduction = -4.53
% Mortality Avg.Reprod.
0.00 22.08
Control Control
8.33 23.08
Treatment 2 Treatment 2
Control CV
12.729% PASS FAIL
% control orgs LChecL_
producing 3rd
brood
100%
let sample 1st sample 2nd sample Complete This For Either Test
pH Test Start Date: 03/14/01
Control 7.22 7.24 7.11 7.31 6.T8 7.30 Collection (Start) Date
Sample 1: 03/12/01 Sample 2: 03/15/01
Treatment 2 7.18 7.27 7.15 7.Z5 7.10 7.31 Sample Type/Duration 2nd
1st P/F
s s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X 24 hrs L A A
r d r d r d U M M
t t t Sample 2 X 24 hrs T P P
let sample 1st sample 2nd sample
D.O. Hardness(mg/l) 45 <:
Control 8.3 8.Z 8.4 8.0 8.3 8.6
Spec. Cond.(Wnhos) 98 576 645
Treatment 2
ChLorine(mg/l) ;':::;: n/a n/a
LC50/Acute Toxicity Test jSampLe temp. at receipt(°C) ::......:`. 2.0 3.5
(Mortality expressed as %, combining replicates)
wwwwwwwwww
Note: Please
Concentration Complete This
Section Also
Mortality
start/end start/end
Control
obit _
High
Conc.
pH D.O.
Note: Please
Concentration Complete This
Section Also
Mortality
start/end start/end
Control
obit _
High
Conc.
pH D.O.
LC50 = Z
. .Method of Determination
95% Confidence Limits
Moving Average _ Probit
-- %
Spearman Karber _ Other
Organism Tested::-Cerfodaphnia dubia Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
MAY 2001
D,w Q::::�j
DEQ-CFW 00063156

MAY 0 2 2001
j
Div v, o,-%k L;n %AUALlW
CENTRAL FILES
DEQ-CFW 00063157

DuPont Fluoroproducts
NCDENR Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
Subject: Discharge Monitoring Report —March 2001
NPDES Permit No. NC0003573
Dear Sirs:
DuPont Fluoroproducts
22828 NC Highway 87 W
Fayetteville, NC 28306-7332
April 25, 2001
MAY 2 2001
Enclosed is the DuPont — Fayetteville Works' Discharge Monitoring Report for March 2001.
This report includes an additional DMR page for Outfall 001 to report the special monitored
parameters required by the DWQ Fayetteville Regional Office.
Four daily samples of Outfall 001 submitted for BOD5 analysis to our commercial laboratory
(Simalabs International) were started well after the 48-hour maximum hold time. Those samples
were for March 2 (Sample ID E10302), March 3 (ID E10303), March 9 (ID E10309), and
March 10 (ID E 10310). This exceedance of the maximum hold time invalidates those analytical
results for their use on the Discharge Monitoring Report.
See the attached letter from Simalabs addressing this issue.
If you have any questions regarding this matter, please feel free to call me at [phone].
Michael E. Johnson
Environmental Manager
Enclosures
cc: Mr. Paul Rawls, NCDENR DWQ, Fayetteville Regional Office
Ms. Kitty Kramer, NCDENR DWQ, Fayetteville Regional Office
E. I. du Pont de Nemours and Company FL-4 Rev. 3/2000
DEQ-CFW 00063158

9 aggpf- at.
MAY 0 2 2001
d
UI — lutilctiQUALITY
CENTRAL FILES
DEQ-CFW 00063159

r -
I N T E R N A T 1 0 N A 1.
April 24, 2001
Mr. Michael Johnson
DuPont Fayetteville
22828 NC Hwy 87 West
Fayetteville, NC 28306
Dear Mr. Johnson,
On Monday, March 5, 2001 SIMALABS International picked up DuPont Fayetteville
Works samples labeled E10302, I10302, E10303, and I10303 and carried these samples
back to the lab for BOD 5-day analyses. On Monday, March 12, 2001 SIMALABS
International picked up DuPont Fayetteville Works samples labeled E10309, I10309,
E 10310, and 110310 and carried these samples to the lab for BOD 5-day analyses. BOD
analyses must be started within 48 hours of collection, as required by Standard Methods
for the Examination of Water and Wastes, 18"' Edition. Unfortunately, all eight of these
samples were started outside of the 48-hour hold time. The North Carolina Division of
Water Quality Laboratory Certification Section requires us to qualify these results as
being analyzed outside of the regulatory hold times. Method hold times, particularly for
non -chemically preserved samples should be met to ensure accurate measurements of
parameters, as present when the sample was collected. Samples tested outside of the hold
times may have their validity questioned.
I am very sorry to report this lab error to you. I can assure that this issue was discussed
in length and detail with the laboratory analysts and the problem should not reoccur.
Your business is very important to us and we plan to work hard in the future to ensure
your trust in our testing results.
If I can be of any further assistance to you, please call me in my office at [phone].
:sincerely,
qo7nSledge, II
General Manager
SIMALABS International
WAY ? 2 2001
Fj V
1302 13elIll 0n[ St ITCt, Burlington. NC 27215-6035 TE1...336.570.4661 FAX [phone]
DEQ-CFW 00063160

,f
illotil i1
MAY 0 2 2001
U
ON yr omm1 di QUALITY
CENTRAL FILES
DEQ-CFW 00063161

DuPont Fluoroproducts
NCDENR Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
APR 3 0 2001
W
Subject: Discharge Monitoring Report — March 2001
NPDES Permit No. NC0003573
Dear Sirs:
DuPont Fluoroproducts
22828 NC Highway 87 W
Fayetteville, NC 28306-7332
April 25, 2001
Enclosed is the DuPont — Fayetteville Works' Discharge Monitoring Report for March 2001.
This report includes an additional DMR page for Outfall 001 to report the special monitored
parameters required by the DWQ Fayetteville Regional Office.
Four daily samples of Outfall 001 submitted for BOD5 analysis to our commercial laboratory
(Simalabs International) were started well after the 48-hour maximum hold time. Those samples
were for March 2 (Sample ID E10302), March 3 (ID E10303), March 9 (ID E10309), and
March 10 (ID E 10310). This exceedance of the maximum hold time invalidates those analytical
results for their use on the Discharge Monitoring Report.
See the attached letter from Simalabs addressing this issue.
If you have any questions regarding this matter, please feel free to call me at [phone].
Michael E. Johnson
Environmental Manager
Enclosures
cc: Mr. Paul Rawls, NCDENR DWQ, Fayetteville Regional Office
Ms. Kitty Kramer, NCDENR DWQ, Fayetteville Regional Office
E. I. du Pont de Nemours and Company FLA Rev. 3/2000
DEQ-CFW 00063162

A
April 24, 2001
Mr. Michael Johnson
DuPont Fayetteville
22828 NC Hwy 87 West
Fayetteville, NC 28306
Dear Mr. Johnson,
On Monday, March 5, 2001 SIMALABS International picked up DuPont Fayetteville
Works samples labeled El0302,110302, El0303, and 110303 and carried these samples
back to the lab for BOD 5-day analyses. On Monday, March 12, 2001 SIMALABS
International picked up DuPont Fayetteville Works samples labeled E10309,110309,
E10310, and I10310 and carried these samples to the lab for BOD 5-day analyses. BOD
analyses must be started within 48 hours of collection, as required by Standard Methods
for the Examination of Water and Wastes, 186' Edition. Unfortunately, all eight of these
samples were started outside of the 48-hour hold time. The North Carolina Division of
Water Quality Laboratory Certification Section requires us to qualify these results as
being analyzed outside of the regulatory hold times. Method hold times, particularly for
non -chemically preserved samples should be met to ensure accurate measurements of
parameters, as present when the sample was collected. Samples tested outside of the hold
times may have their validity questioned.
I am very sorry to report this lab error to you. I can assure that this issue was discussed
in length and detail with the laboratory analysts and the problem should not reoccur.
Your business is very important to us and we plan to work hard in the future to ensure
your trust in our testing results.
If I can be of any further assistance to you, please call me in my office at [phone].
Sincerely,
d�� X. -21
o B. Sledge, III
General Manager
SIMALABS International
1 302 lie Imont Street, Burling tun, NC 27215-6935 TFL.336.570.4661 FAX [phone]
DEQ-CFW 00063163

EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 001 MONTH March YEAR 2002001
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddle GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) Simalabs (2)
CHECK BOX IF ORC HAS CHANGED C� PERSON(S) COLLECTING SAMPLES Robert J. Geddle I Kenneth M. Hall
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF ENVIRONMENTAL MANAGEMENT
DENR
P.O BOX 29535
13AI Fire Nr 27A2&0535
DEM Form MR -I (12193)
(SIGNATURE OF OPERATOFMN RESPONSIBLE CHARGE)
BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
DATE
DEQ-CFW 00063164

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements 0
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
The Outfall 001 samples for March 2, 3, 9, and 10 that were submitted to Simalabs International laboratory for BODE
were held longer than the 48-hour maximum hold time, thereby Invalidating those samples. The cause of this error
was due to a misunderstanding by the Simalab analyst with regard to the BODS hold time requirement, who has
_subsequently been Instructed on these requirements. The BODE results for those samples were:
03/02/01 = "estimated 123 ma/L": 03/03/01 =145 mo/L! 03/02/01 = 5.7 me/L! and 02/10/01 = 5.2 mn/L-
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Barry L. Hudson - Site Manager
Permittee (Please print or type)
NC Hwy 87 South, Fayetteville, NC, 28306 (910) 6784400 May 31, 2001
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 006W Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADMI)
00625
Total Igeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BODS
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032 Hexavalent Chromium
01034 Chrorrdum
01037 Total Cobalt
01042 Copper
01045 Iron
01051 Lead
01092
01105
01147
31616
32730
34235
34481
38260
39516
50050
Zinc
Aluminum
Total Selenium
Fecal Coliform
Total Phenolics
Benzene
Toluene
MBAS
PCB's
Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
DEQ-CFW 00063165

EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 001 MONTH March YEAR 2001
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) Burlington Research, Inc. (2) Burlington Research
CHECK BOX IF ORC HAS CHANGED ® PERSON(S) COLLECTING SAMPLES Robert J. Geddle / K. Mark Hall
Mail ORIGINAL and ONE COPY to:ATTN: CENTRAL FILES 0' (��ZDIV. OF ENVIRONMENTAL MANAGEMENT X G��h�✓" LA�' - T / -
DEHNR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
RO BOX 29635 BY THIS SIGNITURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27626-0535 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
DEM Form MR -I (12/93) NF = No flow at Outfall 001 at the sample time.
DEQ-CFW 00063166

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements �J
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
This DMR page is an addendum to the normal Outfall 001 DMR and includes the monitoring requirements set
forth in the letter from Mr. Paul Rawls (NCDENR DWO FRO) dated February 16. 2001. The thermal/alkaline
treatment system was shutdown on March 18, 2001. Therefore, the last HFA-hydrate and trifluoroacetate samples
taken as a requirement of DWO was at 0600 on March 19, 2001. The entry of "NF" Indicates that there was "no flow"
at Outfall 001 at the specified time, so no arab sample could be taken.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information Is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
22828 NC Hwy 87 W, Fayetteville, NC, 28306
[phone]
May 31,1996
Permittee Address
Phone Number
Permit Exp. Date
PARAMETER CODES
00010
Temperature
00556
Oil & Grease
00951
Total Fluoride
01067 Nickel
50060 Total
00076
Turbidity
00600
Total Nitrogen
01002
Total Arsenic
01077 Silver
`' Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
01027
Cadmium
01092 Zinc
Chlorine
00082
Color (ADMI)
00625
Total ICeldhal
01032
Hexavalent Chromium
01105 Aluminum
71880 Formaldehyde
00095
Conductivity
Nitrogen
01034
Chromium
01147 Total Selenium
71900 Mercury
00300
Dissolved Oxygen
00630
NitratesJN(trites
01037
Total Cobalt
31616 Fecal Coliform
81551 Xylans
00310
BOD5
00665
Total Phosphorous
01042
Copper
32730 Total Phenolics
00340
COD
00720
Cyanide
01045
Iron
34235 Benzene
00400
pH
00745
Total Sulfide
01051
Lead
34481 Toluene
00530
Total Suspended
00927
Total Magnesium
38260 MBAS
Residue
00929
Total Sodium
39516 PCBs
00545
Settleable Matter
00940
Total Chloride
50050 Flow
Parameter Code assistance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 634
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean.. Use only units designated in the reporting
facility's permit for reporting data
` ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 213 .0506
(b) (2) (D)
DEQ-CFW 00063167

EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 002 MONTH March YEAR 2001
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddle GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) Simalabs (2)
CHECK BOX IF ORC HAS CHANGED � PERSON(S) COLLECTING SAMPLES Robert J. Geddle / Kenneth M. Nall
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES � � s �l � , � /v /
DN. OF ENVIRONMENTAL MANAGEMENT X
DENR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
P.0 BOX 29535 BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27626.0535 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
DEM Form MR -I (12193)
DEQ-CFW 00063168

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for Improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the Information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the Information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
87
y L Hudson - Site N
iittee (Please print or
�`1
ature of a ittee"
28306
678-1400
Phone
2001
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01087 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADMI)
W625
Total igeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
asshance may be obtained
i ne montniy average for fecal coliform is to
facility's permit for reporting data
01027 Cadmium
01032
Hexavalent Chromium
01034
Chromium
01037
Total Cobalt
01042
Copper
01045
Iron
01051
Lead
as a Lit:umhTHIC mean.
01092
01105
01147
31616
32730
34235
34481
38260
39516
50050
on
Zinc
Aluminum
Total Selenium
Fecal Coliform
Total Phenolics
Benzene
Toluene
WAS
PCB's
Flaw
ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
**If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 28.0506
(b) (2) (D)
r,
DEQ-CFW 00063169

EFFLUENT
NPDES PERMIT NO. NC 0003673 DISCHARGE NO. 006 MONTH March YEAR 2001
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie GRADE 4 PHONE (910) 67&1219
CERTIFIED LABORATORIES (1) Simalabs (2)
CHECK BOX IF OFIC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddie / Kenneth M. Hall
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF ENVIRONMENTAL MANAGEMENT
DENR
P.O BOX 29535
aei Gir.N Nr 77A2&0535
X -01 — I ���±
0
(SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
�/3l0
DATE
.\
DE-CFW_00063170

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements =X
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"1 certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Barry L Hudson -Site Manager
Permittee (Please print or type)
NC Hwy 87 South, Fayetteville, NC, 28308 [phone] May 31, 2001
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00800 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADMI)
00625
Total lgeldhal
Nitrogen
00095
Conductivity
006W
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00885
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032
Hexavalent Chromium
01034
Chromium
01037
Total Cobalt
01042
Copper
01045
Iron
01051
lead
01092
01105
01147
31616
32730
34235
34481
38280
39516
50050
Zinc
Aluminum
Total Selenium
Fecal Coliform
Total Phenolics
Benzene
Toluene
MBAS
PCB's
Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone]. extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
" ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202- (b) (5) (B).
'" If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 213 .0506
(b) (2) (D)
DEQ-CFW 00063171

Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 04/18/01
Facility: DUPONT NPOES#: N00003573 Pipe#: 002 County: BLADEN
Laborat Perfo ing Test. SINALAAJBS INTERNATIONAL
Y 77 Q I
Comments:
Signatur''e of Laborbtory Supervisor I * PASSED: 7.24% Reduction * I
Work Order: 1C113-004 Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
Chronic Pass/Fail Reproduction Toxicity Test
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced 134129129131132128132131133128135131
Adult (L)ive Mead IL IL IL IL IL IL IL IL IL IL IL IL
9ffluent %: 3.3%
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 1
# Young Produced 137134129128127130132123136130122
Adult Wive Mead IL IL IL IL IL IL IL IL IL IL IL IL
Chronic Test Results
Calculated t - 1.267
Tabular t - 2.624
% Reduction - 7.24
% Mortality Avg.Reprod.
0.00 31.08
Control Control
0.00 28.83
Treatment 2 Treatment 2
Control CV
7.318% PASS FAIL
X control orgs X
producing 3rd
brood Check90ne
100X
let sample let sample 2nd sample Complete This For Either Test
PH Test Start Date: 03/07/01
Control 7.01 7.21 7.10 7.Z0 6.95 7.20 Collection (Start) Date
Sample 1: 03/05/01 Sample 2: 03/08/01
Treatment 2 6.95 7.22 7.16 7.24 7.18 7.19 Sample Type/Duration
1st
s s s Grab Comp. Duration D
t e t e t e I S
a n a n a n Sample 1 X 24 hrs L A
r d r d r d U M
t t t Sample 2 X 24 hrs T P
1st sample 1st sample 2nd sample
D.O. Hardness(mg/l) 40
Control
Spec. Cord.(1whos) 95 623
Treatment 2 8.8 8.8 8.6 8.4 8.5 8.3
Chlorine(mg/l) ;?: n/a
LC50/Acute Toxicity Test Sample temp. at receipt(°C) ::::::::;t.:::; 3.0
(Mortality expressed as %, combining replicates)
x
x
x
x
x
x
x
x
x
x
x
%I
x
x
x
%I
x
%I
x
x
obit
Note: Please
Concentration Complete This
Section Also
Mortality
start/end start/end
Control
_
_ High
Conc.
PH D.O.
LC50 = %
Method of Determine
95% Confidence Limits
Moving Average _ Pr
Organism Tested: Ceriodaphnia dubia Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
2nd
P/F
S
A
M
P
480
We
3.0
DEQ-CFW 00063172

s y
J
Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 04/18/01
Facility: DUPONT NPDESt: M00003573 Pipet: 002 County: BLADEM
Labors' tyjr/7ei n ` Test ASt 4vS INTERNATIONAL Comments:
I Signd'ture of Laboratory Supervisor I * PASSED: -4.53% Reduction * I
Work Order: B0103013904A Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
Chronic Pass/Fail Reproduction Toxicity Test
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
t Young Produced 121123124122124118116124122121126124
Adult (L)ive (D)ead L IL IL IL IL IL IL IL IL JJL IL.
affluent X: 3.3%
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 1
t Young Produced 127127126123122120122124121123125
Adult Wive (D)ead IL IL IL IL IL IL IL IL ID IL IL IL
Chronic Test Results
Calculated t = -0.847
Tabular t = 2.508
X Reduction = -4.53
X Mortality Avg.Reprod.
0.00 22.08
Control Control
8.33 23.08
Treatment 2 Treatment 2
Control CV
12.729% PASS FAIL
% control orgs ECheck
producing 3rd,00Xbrood One
1st sample 1st sample 2nd sample Complete This For Either Test
PH Test Start Date: 03/14/01
Control T.22 7.24 T.11 7.31 6.78 7.30 Collection (Start) Date
Sample 1: 03/12/01 Sample 2: 03/15/01
Treatment 2 7.18 7.27 7.15 T.25 T.10 7.31 Sample Type/Duration 2nd
1st P/F
s s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X 24 hrs L A A
r d r d r d U M M
t t t Sample 2 X 24 hrs T P P
1st sample 1st sample 2nd sample
D.O. Hardness(mg/l) 45 Control :2 :`::>
8.3 8.2 8.4 8.0 8.3 8.6
Spec. Cond.(gmhos) 98 576 645
Treatment 2
Chlorine(mg/1) ::.:.:.:_:.: n/a n/a
LC50/Acute Toxicity Test Sample temp. at receipt(°C) :::;:;.;.;.;. 2.0 3.5
(Mortality expressed as X, combining replicates)
x
x
x
x
X
x
x%
x%
x
X%
x
x
X
x%
x%
Note: Please
Concentration Complete This
Section Also
Mortality
start/end start/end
LC50 = %
Method of Determination
9S% Confidence Limits
Moving Average _ Pr
obit
Organism Tested: Ceriadephnia dubia Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
DEQ-CFW 00063173