DEQ-CFW_00062920

EFFLUENT lam'
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 0 MONTH
FACILITY NAME . DuPont -Fayetteville Works CLASS 3
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie GRADE
CERTIFIED LABORATORIES (1) Simalabs (2)
CHECK BOX IF OFiC HAS CHANGED PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES ! k
DIV. OF ENVIRONMENTAL MANAGEMENT X
DENR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE)
P.0 BOX 29535 BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27626-0535 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
November YEAR 2002
COUNTY Bladen
4 PHONE [phone]
Robert J. Geddie
/,? -/, �"'-d2-
DATE
LLJ
U
u
O
o
E
m
O
O
50050
00010
00400
00310
00530
00556
TG3PB
2
FLOW
w
N
cc
H
3-
a
04
N
In
wW
w
o
wacn
F
FO
aE
C7
0
O
x
1.0
0co
r
U
EFF X
J
HRS
I HRS
Y/N
MGD
'C
UNITS
Lb/Day
Lb/Day
mg/L
P/F
mg/L
1
08001
24
Y
0.824
21
7.5
2
0800
24
0.888
3
08001
24
0.865
4
08001
24
Y
0.904
21
7.5
65.6
73.1
5
08001
24
Y
0.885
21
7.4
79.7
81.2
6
08001
24
Y
1 0.911
22
7.4
80.5
58.5
<1
<5
7
08001
24
Y
0.666
8
08001
24
Y
0.727
9
08001
24
0.749
10
08001
24
0.792
11
08001
24 1
Y
0.788
23
7.4
140.6*
40.7
12
o800
24 1
Y
0.796
23
7.5
141.4*
92.9
13
o800
24
Y
0.720
20
7.6
127.3*
61.3
<5
14
08001
24
Y
1.002
15
08001
24
B
0.682
16
o800
24
0.861
17
08001
24
0.813
18
08001
24
B
0.719
19
7.8
124.7*
118.1
19
08001
24
Y
0.856
19
7.8
463.3
99.9
20
08001
24
Y
0.834
19
7.8
484.51
170.3
Pass
<5
21
woo 1
24
Y
0.752
22
08001
24
Y
0.773
23
o800
24
0.770
24
o800
24
0.955
25
osoo
24
Y
0.490
23
7.6
211.3
29.4
26
o800
24
Y
0.799
24
7.5
379.9
82.0
27
o800
24
Y
0.826
24
7.3
484.9
130.9
<5
28
o8o0
24
*'
0.657
29
o800l
24
'*
0.675
30
woo 1
24
0.877
31
08001
24
AVERAGE
0.795
21
232.01
86.5
0
Pass
0
MAXIMUM
1.002
24
7.8
484.91
170.3
<1
Pass
MINIMUM
0.490
19
7.3
65.6
29.4
<1
Pass
qc
Comp. (C) Grab (G)
G
G
C
C
G
C
Monthly Limit
2.0
191.3
317.8
PASS
Daily Limit
6-9
508.2
1030
N/D
DEM Form MR -I (12/93) ** Holiday * Estimated Value
DEQ-CFW 00062920

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements 0
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
The Outfall 001 BOD-5 monthiv average for November 2002 was 232.0 Ib/dav versus the permit limit of 191.3 Ib/day.
It Is believed that the cause of the excessive BOD-5 discharge was frpm.a change In the supplier of a raw
r
material, which resulted In a microbial slime formation in both the manufacturing area using the raw material
and In the central wastewater treatment plant (WWTP). Indications are that the slime coated the WWTP microbes
which prevented their contact with and biodegradation of the normal BOD-5 wastewaters. Use of that new raw
material has been curtailed. and the WWTP has subseauentiv returned to normal.
4 certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
22828 NC Hwy 87
Permittee Address
00010
Temperature
00076
Turbidity
00080
Color (Pt -Co)
00082
Color (ADMI)
00095
Conductivity
00300
Dissolved Oxygen
00310
BOD5
00340
COD
00400
pH
00530
Total Suspended
Residue
00545
Settleable Matter
00556
00600
00610
00625
00630
Barry L. Hudson - Site N
Permittee (Please print or
Phone Number
PARAMETER CODES
Oil & Grease 00951 Total Fluoride
Total Nitrogen 01002 Total Arsenic
Ammonia Nitrogen
Total 1geldhal
Nitrogen
Nitrates/Nitrites
00665
Total Phosphorous
00720
Cyanide
00745
Total Sulfide
00927
Total Magnesium
00929
Total Sodium
00940
Total Chloride
01027 Cadmium
01032
Hexavalent Chromium
01034
Chromium
01037
Total Cobalt
01042
Copper
01045
Iron
01051
Lead
C�7s
Date
111
, 2001
Exp. Date
01067 Nickel 50060 Total
01077 Silver Residual
01092 Zinc Chlorine
01105 Aluminum
01147
31616
32730
34235
34481
38260
39516
50050
Total Selenium
Fecal Coliform
Total Phenolics
Benzene
Toluene
MBAS
PCB's
now
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assistance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
" ORC must visit facility and document visitation ,of facility as required per'15A NCAC 8A .0202 (b) (5) (B).
**If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D) iJ E U j j Z6102
DEQ-CFW 00062921

Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 12/02/02
Facility: DUPONT- NPDES#: NC0003573 Pipe#: 002 County: BLADEN
Laboratory Performing Test: SIMALABS INTERNATIONAL
X �� /j�� -, Comments:
SiMty of Opdfat r in Responsible Charge
x ��
Signature of Laboratory Supervisor * PASSED: -7.14% Reduction
Work Order: B0211047008A Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
lortn carotin ueriouapnm n -
Chronic Pass/Fail Reproduction Toxicity Test Chronic Test Results
Calculated t = -1.318
Tabular t = 2.508
:ONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 % Reduction = -7.14
% Mortality Avg.Reprod.
# Young Produced 19 19 22 20121121 19 18120126 22 21
0.00 21.00
Control Control
Adult Wive Mead L L L L L L L L L IL L L
0.00 22.50
Treatment 2 Treatment 2
affluent %: 3.3%
REATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV
11.664% PASS FAIL
# Young Produced 21 21 16127121 23 21122123 27 20 24 % control orgs LChecL
producing 3rd
brood
Adult Wive (D)ead L L L L L L L L L L L L 100%
1st sample 1st sample 2nd sample Complete This For Either Test
pH Test Start Date: 11/20/02
Control 7.49 7.60 7.b2 7.92 8.04 7.89 Collection (Start) Date
Sample 1: 11/18/02 Sable 2: 11/21/02
Treatment 2 7.78 7.65 7.64 7.94 7.96 7.91 Sample Type/Duration 2nd
1st P/F
s s s Grab Corp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X 24 hrs L A A
r d r d r d U M M
t t t Sample 2 X 24 hrs T P P
1st sample 1st sample 2nd sample
D.O. Hardness(mg/ U 41 is <<>
Control 8.6 8.4 8.6 8.7 8.6 8.9
Spec. Cond.(µmhos) 84 530 529
Treatment 2 8.7 8.7 8.5 8.8 8.8 8.1
Chlorine(mg/ U .n/a n/a
LC50/Acute Toxicity Test Sample temp. at receipt(°C) 3.1 1.4
(Mortality expressed as %, combining replicates)
Concentration
Mortality
start/end
LC50 = %
Method of Determination
95% Confidence Limits
Moving Average _ Probit _
% -- %
Spearman Kerber _ Other _
PH
Organism Tested: Ceriodaphnia dubia Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
Note: Please
Complete This
Section Also
start/end
Control
High
Cone.
D.O.
JAN 2 2 2003
i
DEQ-CFW 00062922

EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 002 MONTH November YEAR 2002
FACILITY NAME - DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddle GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) Simalabs (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddle
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF ENVIRONMENTAL MANAGEMENT Xr ,Y` ALr
DENR (SIGNATURE OF: OPE OR IN RESPONSIBLE CHARGE) DATE
P.0 BOX 29535 BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27626.0535 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
. 11.1
111 1
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DEM Form MR -I (12/93) ** Holiday
DEQ-CFW 00062924

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements^J
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
- Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
print or
of
Date
NC Hwy 87 South, Fayetteville, NC, 28306 [phone] May 31, 2001
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076
Turbidity
00600
Total Nitrogen
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADMI)
00625
Total Kjoldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitdtes
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01002 Total Arsenic 01077 Silver Residual
01092 Zinc Chlorine
01027 Cadmium 01105 Aluminum
01032 Hexavalent Chromium 01147 Total Selenium 71880 Formaldehyde
01034 Chromium 31616 Fecal Coliform 71900 Mercury
32730 Total Phenolics 81551 Xylene
01037 Total Cobalt
01042 Copper
01045 Iron
01051 Lead
34235 Benzene
34481 Toluene
38260 MBAS
39516 PCBs
50050 Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data A
. ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
•' If signed by other than the premittee, delegation o[-signatory a #"9rity must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D) .
DEQ-CFW 00062925

EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 006 MONTH November YEAR 2002
FACILITY NAME - DuPont -Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddle GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) Simalabs (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddle
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV.OF ENVIRONMENTAL MANAGEMENT X
DENR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
P.0 BOX 29535 BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27626-0535 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
.IL.I
11, 11
11 1
1111111111111111
IIIIIIIIIIIIII,
IIIIIIIII-IIIIIIIIIIIIII,
IIIIIIIIIIIIII,
IIIIIIII_
---
333
'
333
DEQ-CFW 00062926

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements `—�1
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Barry Hudson - Site Manager
Permittee (Please print or typeb ,
"O-
Date
NC Hwy 87 South, Fayetteville, NC, 28306 V [phone] May 31, 2001
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080 Color (Pt -Co) 00610 Ammonia Nitrogen
00082
Color (ADM[)
00625
Total KJeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032 Hexavalent Chromium
01034 Chromium
01037 Total Cobalt
01042 Copper
01045 Iron
01051 Lead
01092
01105
01147
31616
32730
34235
34481
38260
39516
50050
Zinc
Aluminum
Total Seleplum
Fecal Collforrn
Total Phenolics
Benzene
Toluene
WAS
PCB's
Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
" If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D) L, r n` d
DEQ-CFW 00062927

P
aUPONT
DuPont Fluoroproducts
2 2 2003
N.C. Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
DuPont Fluoroproducts
22828 NC Highway 87 W
Fayetteville, NC 28306-7332
December 18, 2002
DISCHARGE MONITORING REPORT — November 2002
Attached is E. I. DuPont de Nemours & Company, Inc., Fayetteville Works Discharge
Monitoring Report for the month of November 2002.
If you have any questions, please contact Robert Geddie at [phone].
RJG: smw
Attachment
cc: Ken Cook - ENGR, Old Hickory
R. J. Geddie - FW
A. L. Tolentino- FW
M. E. Johnson - FW
M. Hagn - FW
File: F-1-3-4
E. I. du Pont de Nemours and Company
FL-4 Rev. 3/2000
DEQ-CFW 00062928

DEQ-CFW-00062929