DEQ-CFW_00062789

aU PONTR
DuPont Fluoroproducts
MEMO CRO
APR 2 2 20011
N.C. Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
DuPont Fluoroproducts /
22828 NC Highway 87 W
Fayetteville, NC 28306-7332
March 18, 2004
DISCHARGE MONITORING REPORT — February 2004
Attached is E. I. DuPont de Nemours & Company, Inc., Fayetteville Works Discharge
Monitoring Report for the month of February 2004.
If you have any questions, please contact Robert Geddie at [phone].
RJG: smw
Attachment
cc: Ken Cook - ENGR, Old Hickory
R. J. Geddie - FW
M. E. Johnson - FW
R. F. Shaul - FW
File: F-1-3-4
E. I. du Pont de Namours and Company
FL-4 Rev. 312000
DEQ-CFW 00062789

EFFLUENT
4NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 001 MONTH February —2004
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Biladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddle GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) Simalabs (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddle
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF ENVIRONMENTAL MANAGEMENT
DENR
P.O BOX 2905
RALEIGH, NC 27626-0635
x /C
(SIGNATURE OF
RESPONSIBLE CHARGE)
BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
-91140110j,
DATE
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DEIII Form MR-! (12193)
DEQ-CFW-00062790

o Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken In respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the Information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
Including the possibility of fines and imprisonment for knowing violations."
Hudson - Site Mar
lee (Please print or
NC Hwv 87
678-1400
rX i'/o
October
PARAMETER CODES
00010 Temperature 00556 OR & Grease 00951 Total Fluoride 01067 Nfdcel 50080 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonla Nitrogen
01092 Zinc
Chlorine
00082
Color (ADMI)
00625
Total Igeldhal
01027
Cadmium
01105 Aluminum
Nitrogen
00095
Conductivity
00630
Nltrat"itrites
01032
Hexavalent Chromium
01147 Total Selenium
71880 Formaldehyde
00300
Dissolved Oxygen
01034
Chromium
31616 Fecal Coliform
71900 Mercury
00310
BOD5
00665
Total Phosphorous
32730 Total Phenolics
81551 Xylene
00340
COD
00720
Cyanide
01037
Total Cobalt
34235 Benzene
00400
pH
00745
Total Sulfide
01042
Copper
34481 Toluene
00530
Total Suspended
00927
Total Magnesium
38260 WAS
Residue
00929
Total Sodium
01045
Iron
39516 PCB's
00545
Settleable Matter
00940
Total Chloride
01051
Lead
50050 Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal ooliforrn is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC•8A .0202 (b) (5) (B).
" " If signed by other than the premittee, delegation of signatory authority must: be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
DEQ-CFW 00062791

11
Pace Analytical Services, Inc.
,Analytical ® Ashe Riverside Drive
Asheville, NC 28804
www.pac �491@t Toxicity Report AT-1 Form Chronic Pass/Fail and Acute l-C�(�one: 828.254.7176
fax:828.252,4618
Date 3\1\04
Dupont NPDES#NC 000 Pipe # 002
County Bladen
ory Performing Test PACE Analcal Services Inc. g�
fJ, X ,� �/ - AW ARTaments
tank Sum=147.50
Sig re of Operator in Res p. Charge 1-Tailed Critical=109.00
r
Samples Not Aerated Unless Otherwise Noted
Environmental Sciences Branch Chronic Test Results
IVIAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR Calculated t
1621 Mail Service Center °
Raleigh, North Carolina 27699-1621 Tabular t
North Carolina CerlodaphnJa Chronic Pass/Fail Reproduction ToxicHyTest % Reduction 0.44
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
% Mortality Avg. Reprod.
# Young Produced 17 22 26 23 23 26 25 21 28 10 24 29 Control Control
Adult L Ive Dead L L L L L L L L L L L L. o.00 22.e0
Treatment 2 Treatment 2
Effluent% 3.3 0.0 22.70
rnntmi ry
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 22.6 PASS FAIL
# Young Produced 8 20 24 25 21 22 1 23 23 28 26 26 26 %-trol or msUk
produc(ng 3rd broodAdult (L)ive (D)ead L L L LL L L L L L L L 91.7 one
Complete This For Either Test Test start Date:
1st 1st 2nd 2\18\04
pH Control 7.0 7.2 7.2 7.1 1 7.2 7.5 collection start Data
Treatment 6.8 7.0 7.3 7.4 7.1 7.2 Sample 1 2\16\04 Sample 2 2\19\04
S E S E S E Samnel Twe/Duration
t n t n t n �6'
a d a d a d Grab Comp. Duration
1
r r r Sample 1 °x
t t t X 24hr
� O
1st 1st 2nd Sample X 24hr m
D.O Control 8.2 8.0 8.1 7.9 7.8 ]76
Hardness (mg/I) 43
Treatment 8.1 7.7 7.4 7.4 7.9 spec. Cond. (umhos) 140 Oat epe
Chlorine (mrtA) <0.1 <0.1
LCW/Acute Toxicity Test Sample temp. at recelot (Cl 0.1 0.5
(Mortallty expressed as % . combinina replicates)
% % % % % % % % %
Concentration Note: Please
% % % % % % % % % Complete This
Mortality Section also
LC50= %
Method of Determination
95% Confidence
Moving Avg. Probst
% - %
Spearman Other
Organism Tested: CerfOda hale dubla ITest
Duration Hours):
Asheville Certification_iDs
NC Wastewater
40
NC Drinking Water
37712
SC Environmental
99030
FL NELAP
E87648
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
1N AC00q A2
a s
start/end start/end
Control
High
Conc.
pH ,
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627
DEQ-CFW 00062792

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EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 002 MONTH February YEAR 2004
FACILITY NAME DuPont - Fayettkylife Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddle GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) Simalabs (2)
CHECK BOX IF ORC HAS CHANGED I PERSON(S) COLLECTING SAMPLES Robert J. Geddle
Mail ORIGINAL and ONE COPYRENR-
ATTN: CENTRAL FILES
DN. OF ENVIRONMENTAL MANAGEMEAPR 2 2
DENIR
P.O BOX 29M DWI
RALEIGH, NC 27628-0535
(SIGNATURE OF OPEATOR IN RESPONSIBLE CHARGE)
BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
DATE
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DEM Form MR4 (12(93)
DEQ-CFW-00062794

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
All monitoring data and sampling frequencies do NOT meet permit requirements
Compliant
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the Information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Barry Hudson - Site Manager
Permittee (Please print or type)
NC Hwy 87 South, Fayetteville, NC, 28306 [phone] October 31, 2006
Permittee Address Phone Number Permit Exp. Date
-PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nfckel 50080 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nltrogen
00082
Color (ADMI)
00825
Total igeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032 Hexavalent Chromium
01034 Chromium
01037 Total Cobalt
01042 Copper
01045 Iron
01051 Lead
01092 Zinc
01105 Aluminum
01147 Total Selenium
31616 Fecal Cofform
32730 Total Phenolics
34235 Benzene
34481 Toluene
38260 MBAS
39516 PCBs
50050 Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at (919) 73"083, extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
" ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
"" If signed by other than the premittes, delegation of signatory authority must be on file with the state per 15A NCAC 213.0508
(b) (2) (D)
DEQ-CFW 00062795

EFFLUENT
NPDES PERMIT NO. NC 0003673 DISCHARGE NO. Cos — MONTH FebruaryYEAR 20"
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddle GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) Simalabs (2)
CHECK 13OX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Goddle
Mail ORIGINAL and ONE COPY to.
ATTN: CENTRAL FILES
DIV, OF ENVIRONMENTAL MANAGEMENT
DENR
P.O BOX 29536
RALEIGH, NC 27628-0535
(SIGNATURE OF OPERA IN RESPONSIBLE CHARGE)
BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
DATE
DEQ-CFW-00062796

Facility Status: (Please check one of the following).
All monitoring data and sampling frequencies meet permit requirements
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for Improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my Inquiry of the person or persons who manage the system, or those.
persons directly responsible for gathering the information, the information is, to the. best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
Including the possibility of fines and imprisonment for knowing violations."
PARAMETER CODES
00010 Temperature 00556 OR & Grease 00951 Total Fluoride 01067 Nickel 50080 Total
00076 Turbidity 00600 Total Nitrogen 01002 Toal Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00810
Ammonia Nitrogen
01092 Zinc
Chlorine
00082
Color (ADMI)
00825
Total Igeldhal
01027
Cadmium
01105 Aluminum
Nitrogen
00095
Conductivity
00830
Nitrates/Nitrites
01032
Hexavalent Chromium
01147 Total Selenium
71880 Formaldehyde
00300
Dissolved Oxygen
01034
Chromium
31616 Fecal Colfforn
71900 Mercury
00310
BOD5
00665
Total Phosphorous
32730 Total Phenolics
81551 Xyiene
00340
COD
00720
Cyanide
01037
Total Cobalt
34235 Benzene
00400
pH
00745
Total Sulfide
01042
Copper
34481 Toluene
00530
Total Suspended
00927
Total Magnesium
38260 WAS
Residue
00929
Total Sodium
01045
Iron
39516 PCBs
00545
Settleable Matter
00940
Total Chloride
01051
Lead
50050 Flow
Parameter Code assltance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
" ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
"* If signed by other than the premittee, delegation of signatory authority,n ust,be•onAe with the state per 15A NCAC 2B .0506
(b) (2) (D)
DEQ-CFW 00062797