DEQ-CFW_00062532

f
4wo
DuPont Fluoroproducts
N.C. Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
DuPont Fluoroproducts
22828 NC Highway 87 W
Fayetteville, NC 28306'-7332
v
March 21, 2005
DISCHARGE MONITORING REPORT — February 2005
Attached is E. I. DuPont de Nemours & Company, Inc., Fayetteville Works Discharge
Monitoring Report for the month of February 2005.
If you have any questions, please contact Robert Geddie at [phone].
RJG: smw
Attachment
cc: Ken Cook - ENGR, Old Hickory
R. J. Geddie - FW
M. E. Johnson - FW
R. F. Shaul - FW
File: F-1-3-4
L I. du Ponl de Wnioms and Company
DEQ-CFW 00062532

CCSZ9000 AA=10-030
T MES
MAR 24 05

r V
EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. MONTH February YEAR 2005
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddi GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Environmental Laboratory (2) Pace Analytical
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddie
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF WATER QUALITY X
DENR (SIGNATURE OF OPERAMR IN RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27699-1617 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
d
FLOW
w
x
oN`
EFF X
f- N
O
w W
w
.p
2,
o
°
_�
a,
INF �
?
=
N
a o
X
w
v
p
a o
15
o
W
V W
°
a
O
y W
eO
ei
z
W
d
o
J W
go
CL
HRS
HRS
Y/N
MGD
-C
UNITS
Lb/Day
Lb/Day
mg/L
P/F
ug/L
#! $1
i 3
7...
�a3 ......
::� i1�
a� ..
:::'::::::::::::::::::::::::::::::;::::::::':::::::::::::::::::::::::':::::::::::::::::::::.:::::�::::::
........
.......
.......
.......
.......
. .
2
o800
24
Y
0.922
13
7.6
63.8
96.1
1.7
4
0800
24
Y
0.703
6
0800
24
0.774
:�:
�oaoo :°:2A�:::�#17�?l8€:�:�
€€�'is7•..,d4.........3�9
...........
.......
.......
.......
.......
.......
... .
8
10800
24 1
Y
0.686
18
7.7
41.2
105.8
LLL
10
0800
24
Y
0.828
Pass
12
0800
24
0.720
14
osoo
24
Y
0,846
18
7.7
33.2
98.8
5iseoo:
`2#1rb9197:7:..�'f...........5�
:.g.
... ........
.......
.......
.......
.......
...........
.
'
16
0800
24
B
0.811
19
7.7
33.1
175.9
18
0800
24
B
0.819
1ii3k12A
E
..�,.. �....................................
.......
.......
.......
.......
20
0800
24
0.803
2210800
24 1
Y
0.874
19
7.6
69.2
109.3
�3:iisoa:2�f:#��,2��
��Q�
��7���
EMI::'
..14..........
�: ��:�`:;����
3..>.. .........
.......
��'•�
.......
����:�����`:��:�������:
.......
.......
.............
. .
��������'
24
0800
24
Y
0.895
25beoo:
€:2'
.................#l.......................................
.......
.......
.......
.....
.......
........
....
....
....
..... .
26
0800
24
0.894
A:ckk
i
2
...#1,...12..................................................
.......
.......
.......
..... .
2810800
24
Y
0.920
15
7.4
38.4
191.8
9.uI3
...............
.......................................
.
30
osoo
24
...............
.................................
.......
..
AVERAGE
0.828
17
47.3
150.2
1.7
Pass
as:.:...............................................•..................
.....................................
.
MINIMUM
0.609
13
7.4
27.9
55.9
1.7
Pass
Corn :: C Gfab: C,.::::::::::::::::::::::::::::r.:::::::::::G::::::::::::G::::::::::::G•;:;:::::�:::::::::::
G:::::::::::::::::::..:.:.:::.:.:.:..:.:.:.:.:.:.:..:.:.:.:•:•:.:::.:.:.:.:.::.:.:.:•:.:..:.:.:.:.:.:.::.:.:.:.:.:
Monthly Limit
2.0
191.3
317.8
PASS
DEM Form MR4 (12/93)
DEQ-CFW 00062534

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements tobe made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
a�
NC Hwy 87 South, Fayetteville, NC, 28306 [phone] October 31, 2006
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADMI)
00625
Total lgeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032 Hexavalent Chromium
01034 Chromium
01037 Total Cobalt
01042 Copper
01045 Iron
01051 Lead
01092
01105
01147
31616
32730
34235
34481
38260
39516
50050
Zinc
Aluminum
Total Selenium
Fecal Coliform
Total Phenolics
Benzene
Toluene
MBAS
PCB's
Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
so 12 8VW
DEQ-CFW 00062535

Pace Analytical Services, Inc.
2225 Riverside Drive
Analytical ® Asheville, NC 28804
��ffFF Toxicity Report AT-1 Form Chronic Pass/Fail and Acute LC5�'one: 828.254.7176
www pact?�ddiU i Fax: [phone]
Date 2\28N05
NPDES#NC 0003573 Pipe # 002
County Bladen
,rming Test ACE Anal rtical Services, Inc.
4 }- Comments
��� Rank Sum=163.00
Sign t f Operator in pun ' arge 1-Tailed Critical=109.00
'sionm Larmratory une isnr Samples Not Aerated Unless Otherwise Noted
r Environmental Sciences Branch Chronic Test Results
MAIL ORIGINAL TO: Div. of Water Quality N.C. DENR Calculated t
1621 Mail Service Center
Raleigh, North Carolina 27699-1621 Tabular t
North Carolina Ceriodaohnia Chronic Pass/Fail Reproduction Toxicity Test % Reduction 0.4
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
Mortality Avg. Repro
# Young Produced
24
29
25
21
22
22
26
28
27
23
23 1
26
Control
Control
Adult (L)ive Dead
L
L
L
L
L
L
L
L I
L
L
L
L
o.00
24.70
Treatment 2
Treatment 2
Effluent% 2.3
8.3
24.60
Cnntrnl ry
TREATMENT 2 ORGANISMS
1
2
3
4
5
6
7
8
9
10
11
12
10.4
PASS FAIL
# Young Produced
28
29
27
22
24
27
28
25
26
10
27
%aontrolorganismsX
producing 3rd brood
Adult (L)ive (D)ead
L
L
t22
L
L
L
L
L
L
L
D
LI
100.o
Check one
I
1st list 2nd 'v"' ""'"� "" I " 2\9\05
PH Control 7.2 7.2 7.2 7.4 7.4 7.6 Collection Start Date
Treatment 7.3 7.5 7.0 7.1 1 7.5 7.7 Sampler 2\7\05 Sample 2\10\05
S E S E S E Samuel Tvoe/Duration
t n t n t n v�
a d a d a d Grab Comp. Duration c m e
r r r Sample t o co 9?.(nt t t X I 24hr o 0 9
1st 1st 2nd Sample 2 X 24hr " 1D
D•O Control 7.8 7.7 8.1 7.8 8.0 7.7 Hardness (mg1l) 50
Treatment 7.7 7.6 8.8 8.7 8.8 $,] Spec. Cond. (umhos) 137 376 404
Chlorine (mg/l) <0.1 <0.1
LC50/Acute Toxicity Test Sample temp. at receipt (C) 0.7 1.0
(Mortality exnressed as % . combining reolicatesl
%
%
%
%
%
%
%
%
Concentration [Note: Please
omplete This
Section also
Mortality
LC50= %
Method of Determination
95% Confidence
Moving Avg. Probit
% - %
Spearman Other
Organism Tested: Cerioda hnia dubia
Test Duration Hours):
Asheville Certification IDS
NC Wastewater
40
NC Drinking Water
37712
SC Environmental
99030
FL. NELAP
E87648
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.
N AC°°p
tD
ac_
start/end start/end
Control
High
Conc.
p
Charlotte Certification IN
NC Wastewater 12
NC Drinking Water 37706
Sc 99006
FL NELAP E87627
DEQ-CFW 00062536

L£SZ9000 M=10-034
chat_ FILES
MAR 24 05

EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 002 MONTH February YEAR 2005
FACILITY NAME DuPont -_Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Environmental Laboratory (2) Pace Analytical
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddie
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF WATER QUALITY X
DENR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27699-1617 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
FLOW
Z
>E
w
o
EFF XLu
FC
o
Q
or
a
o
NF ED
¢oF
a W
a
O IL
J
o$
UDO
O
J W
WU
LL
=
0
o
ag
~
a
o
IRAYiI
1:11
mp
1 : 11
m_
mmmm
m
1 : 11
m�
1:11
•
NI11d1
1 : 1 1
�A
1:11
m
1:11
mm����__
1
m
1:11
m©mmmm
m
1:11
�®
®om®
1 , 1
1 I
_______
DEM Form MR -I (12193)
DEQ-CFW 00062538

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to. be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Barry Hudson - Site Manager
Permittee (Please print or type)
3
Signature
Date
NC Hwy 87 South, Fayetteville, NC, 28306 [phone] October 31, 2006
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADMI)
00625
Total Kjeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032 Hexavalent Chromium
01034 Chromium
01037
Total Cobalt
01042
Copper
01045
Iron
01051
Lead
01092 Zinc
01105 Aluminum
01147 Total Selenium
31616 Fecal Coliform
32730 Total Phenolics
34235 Benzene
34481 Toluene
38260 WAS
39516 PCB's
50050 Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 26.0506
(b) (2) (D)
so 1z M
DEQ-CFW 00062539

EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 006 MONTH February YEAR 2005
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Environmental Laboratory (2) Pace Analytical
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddie
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES (�
DIV. OF WATER QUALITY X
DENR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27699-1617 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
v
FLOW
EFF X
Y
E
INF
_
N
or,
°
o
�
°m
oN
o
aq
©
1 :11
�_-ll-llllllllllllllllll,l
F:Ff
Y
ttt
t:tt
F:Ff
N
t to
e:ee
t
v. .
e 1
kng�

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements r
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements C�
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Barry Hudson - Site Manager
Permittee (Please print or type)
Signature of e m e *" Date
INC Hwy 87 South, Fayetteville, NC, 28306 [phone] October 31, 2006
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADMI)
00625
Total Kjeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032
Hexavalent Chromium
01034
Chromium
01037
Total Cobalt
01042
Copper
01045
Iron
01051
Lead
01092
01105
01147
31616
32730
34235
34481
38260
39516
50050
Zinc
Aluminum
Total Selenium
Fecal Coliform
Total Phenolics
Benzene
Toluene
MBAS
PCB's
Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
so h z 8V
DEQ-CFW 00062541