DEQ-CFW_00062448

NPDES PERMIT NO. NC 0003573 DISC
FACILITY NAME DuPont - Fayetteville Works
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J.
CAS
NT 'JAN 9
001 MONTH November YEAR 2005
CLASS 3 COUNTY Bladen
GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Environmental LaboraVy (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES
Mail ORIGINAL and ONE Co
Robert J. Geddle
ATTN: CENTRAL FILES
DIV. OF WATER QUALITY JAW 1 � 4
DENR (SIGNATURE OF OPERATOOWN RESPONSIBLE CHARGE) DAT,:
1617 MAIL SERVICE CENTER ®\N4
BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS '
RALEIGH, NO 27699-1617 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE "
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DEM Form MR4 (12/93) * Holiday
DEQ-CFW 00062448

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken In respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the Information, the information Is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
Including the possibility of fines and imprisonment for knowing violations."
Z' Date �Z19�
NC Hwy 87 South, Fayetteville, NC, 28306-"- [phone] October 31, 2006
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
01092 Zinc
Chlorine
00082
Color (ADMI)
00625
Total Kjeldhal
01027
Cadmium
01105 Aluminum
Nitrogen
00095
Conductivity
00630
Nitrates/Nltrites
01032
Hexavalent Chromium
01147 Total Selenium
71880 Formaldehyde
00300
Dissolved Oxygen
01034
Chromium
31616 Fecal Colfform
71900 Mercury
00310
BOD5
00665
Total Phosphorous
32730 Total Phenolics
81551 Xylene
00340
COD
00720
Cyanide
01037
Total Cobalt
34235 Benzene
00400
pH
00745
Total Sulfide
01042
Copper
34481 Toluene
00530
Total Suspended
00927
Total Magnesium
38260 WAS
Residue
00929
Total Sodium
01045
Iron
39516 PCBs
00545
Settleable Matter
00940
Total Chloride
01051
Lead
50050 Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 681 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated In the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facilely as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D) 30 9 -11-110
DEQ-CFW 00062449

Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 11/23/05
Facility: DUPONT NPDES#: NC0003573 Pipe#: 002 County: BLADEN
Laboratory Performing -�Test: MERITECH LABS, INC.
X �. ./�A� Comments
Signature of L o atory Supervisor I * PASSED: -4.15% Reduction *
Work Order: Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
Chronic Pass/Fail Reproduction Toxicity Test
'-ONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced 1119120120118115119117119119110121120
Adult Wive (D)ead JAL IL IL IL IL IL IL IL IL IL IL IL
affluent %: 3.3%
Chronic Test Results
Calculated t = -0.526
Tabular t = 2.508
Reduction = -4.15
Mortality
Avg.Reprod.
0.00
18.08
Control
Control
0.00
18.83
Treatment 2
Treatment 2
CREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV
16.583%
# Young Produced 18 15 21 23 20 16 21 19 10 24 22,17 % control orgs
producing 3rd
brood
Adult Wive (D) ead L L L L L L L L L L L L 91. 7%
PASS FAIL
X
Check One
1st sample 1st sample 2nd sample Complete This For Either Test
pH Test Start Date: 11/16/05
Control 7.80 7.77 7.78 7.90 7.87 7.90 Collection (Start) Date
Sample 1: 11/14/05 Sample 2: 11/17/05
Treatment 2 7.76 7.78 7.82 7.87 7.87 7.75 Sample Type/Duration 2nd
1st P/F
s s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X 24 hrs L A A
r d r d r d U M M
t t t Sample 2 X 24 hrs T P P
1st sample 1st sample 2nd sample
D.O. Hardness (mg/1) 46 ........ .........
.......... ..........
Control 7.82 7.83 8.05 7.63 M
Spec. Cond.(µmhos) 175 406 422
Treatment 2 7.85 7.95 8.04 7.45
Chlorine (mg/1) ,........0 .11 <0 .1
LC50/Acute Toxicity Test Sample temp. at receipt (°C) ........ 3.2 0.1
(Mortality expressed as t, combining replicates)
96
%
%
%
%
%
%
%
%
Note: Please
Concentration Complete This
Section Also
Mortality
start/end start/end
�C50 = % Method of Determination
95% Con i�c�e Limits Moving Average Probit
% -- % Spearman Karber _ Other -
Control
High
ri,r, n
PH
Organism Tested: Ceriodaphnia dubia Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4..41)
DEQ-CFW 00062450

w rf
90 9- Nvr
DEQ-CFW 00062451

EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 002 MONTH November YEAR 2005
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Environmental Laboratory (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddie
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF WATER QUALITY
DENR
1617 MAIL SERVICE CENTER
RALEIGH, NC 27699-1617
X F'�'✓4
(SIGNATURE OF OPERA IN RESPONSIBLE CHARGE)
BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
DATE
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13.612
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12
0800
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12.799
14
0800
24
B
12.614
19
7.8
16
0800
24
Y
12.947
21
7.7
........................
18
0800
24
Y
11.688
18
7.7
20
0800
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11.948
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22
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12.269
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26
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12.212
17
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:..........................
30
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24
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12.381
16
7.5
............
....
AVERAGE
12.480
18
531
<0.1
0.51
<2.0
102.0
a.�c1�.t
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.
MINIMUM
8.777
15
7.1
95
<0.1
0.51
<2.0
102.0
Monthly Limit
Daily Limit
6-9
7917
DEM Form MR-1(12/93) * Holiday
DEQ-CFW 00062452

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements LJ
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements L,J
Noncompliant
If the facility Is noncompliant, please comment on corrective actions being taken In respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the Information, the information Is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
Including the possibility of fines and imprisonment for knowing violations."
Hudson -
L-
Date
NC Hwy 87 South, Fayetteville, NC, 28306' [phone] October 31, 2006
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
01092 Zinc
Chlorine
00082
Color (ADMI)
00625
Total igeldhal
01027
Cadmium
01105 Aluminum
Nitrogen
00095
Conductivity
00630
Nftrates/Nftrftes
01032
Hexavalent Chromium
01147 Total Selenium
71880 Formaldehyde
00300
Dissolved Oxygen
01034
Chromium
31616 Fecal Colifonn
71900 Mercury
00310
BOD5
00865
Total Phosphorous
32730 Total Phenolics
81551 Xylene
00340
COD
00720
Cyanide
01037
Total Cobalt
34235 Benzene
00400
pH
00745
Total Sulfide
01042
Copper
34481 Toluene
00530
Total Suspended
00927
Total Magnesium
38260 WAS
Residue
00929
Total Sodium
01045
Iron
39516 PCB's
00545
Settleable Matter
00940
Total Chloride
01051
Lead
50050 Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
*" If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
^0 9
DEQ-CFW 00062453

EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 006 MONTH November YEAR 2005
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddle GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Environmental Laboratory (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddie
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF WATER QUALITY
DENR
1617 MAIL SERVICE CENTER
RALEIGH, NC 27699-1617
X po-rp
(SIGNATURE OF
/JZO
IN RESPONSIBLE CHARGE) DATE
BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
e:oe
INJiii
n : e e
_
m_m
��$g
o ICf �Y•la.l'
.
1 1 •
_®___________�
67;lIFTe'6Nlaillt
• "
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DEQ-CFW 00062454

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision In accordance with a system designed to assure that qualified personnel properly gather and evaluate
the Information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the Information, the information Is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
Including the possibility of fines a
NC Hwy 87 South, Fayetteville, NC, 28306 (910) 6784400 October 31, 2006
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 ON & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADMI)
00626
Total lgeldhai
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032 Hexavalent Chromium
01034 Chromium
01037
Total Cobalt
01042
Copper
01045
Iron
01051
Lead
01092
01105
01147
31616
32730
34235
34481
38260
39516
50050
Zinc
Aluminum
Total Selenium
Fecal Colifomt
Total Phenolics
Benzene
Toluene
WAS
PCB's
Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facirdy's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
no ,�Er
DEQ-CFW 00062455

al I PON� DuPont Fluoroproducts
u ® 22828 NC Highway 87 W
Fayetteville, NC 28306-7332
December 16, 2005
N.C. Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
DISCHARGE MONITORING REPORT — November 2005
Attached is E. I. DuPont de Nemours & Company, Inc., Fayetteville Works Discharge
Monitoring Report for the month of November 2005.
If you have any questions, please contact Robert Geddie at [phone].
RJG: nef
Attachment
cc: Ken Cook - ENGR, Old Hickory
R. J. Geddie - FW
M. E. Johnson - FW
G. G. Santiago- FW
.File: F-1-3-4
El. du Pont de Nemours and Company
DEQ-CFW 00062456

90 9- W'dIr
DEQ-CFW-00062457