DEQ-CFW_00062421

6 DuPont Fluoroproducts
11111 NC Highw
Fayetteville,
Fayetteville, NC
oUPONT® VJW
APR r a
DuPont Fluoroproducts
tij
APR 18 20 March 29, 2006
N.C. Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
DISCHARGE MONITORING REPORT — February 2006
Attached is E. I. DuPont de Nemours & Company, Inc., Fayetteville Works Discharge
Monitoring Report for the month of February 2006.
If you have any questions, please contact Robert Geddie at [phone].
RJG: sns
Attachment
cc: Ken Cook - ENGR, Old Hickory
R. J. Geddie - FW
M. E. Johnson - FW
G. G. Santiago- FW
File: F-1-3-4
E. I. du Pont de Nemours and Company
FL-4 Rev.3/2000
DEQ-CFW 00062421

y.. M-1.
DEQ-CFW 00062422

NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 001 MONTH Feb. YEAR 2006
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. geoffie GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Environmental Labor ory (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Ray Beard / Robert J. Geddie
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES DIV. OF WATER QUALITY X �}� +E' /J
z":4
DENR (SIGNATURE OF OPE4fOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27699-1617 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
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DEM Form MR-1 (12/93)
DEQ-CFW 00062423

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements L�J
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements L�
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
NC Hwy 87 South, Fayetteville, NC, 28306 [phone] October 31, 2006
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
W092
Zinc
Chlorine
00082
Color (ADM[)
00625
Total Kjeldhal
01027
Cadmium
01105
Aluminum
Nitrogen
00095
Conductivity
00630
Nitrates/Nitdtes
01032
Hexavalent Chromium
01147
Total Selenium
71880 Formaldehyde
00300
Dissolved Oxygen
01034
Chromium
31616
Fecal Coliform
71900 Mercury
00310
BOD5
00665
Total Phosphorous
32730
Total Phenolics
81551 Xylene
00340
COD
00720
Cyanide
01037
Total Cobalt
34235
Benzene
00400
pH
00745
Total Sulfide
01042
Copper
34481
Toluene
00530
Total Suspended
00927
Total Magnesium
38260
MBAS
Residue
00929
Total Sodium
01045
Iron
39516
PCB's
00545
Settleable Matter
00940
Total Chloride
01051
Lead
50050
Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
DEQ-CFW 00062424

<y
Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 03/01/06
Facility: DUPONT � NPDES#: NC0003573 Pipe#: 002 County: BLADEN
Laboratory Performing Test: MERITECH LABS, INC.
� Comments: Asterisk (*) denotes
X eT
--g-ignature-ot Operato kn Responsible Charge missing organism
i X sY f '
Signature o La or r. Supervisor * PASSED: -4.33% Reduction
Work Order: Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
forth Carolina Cerioaapnnia
Chronic Pass/Fail Reproduction Toxicity Test
:ONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced 11181181201191181201201181 0118120119
Adult (L)ive (D)ead JIL IL IL IL IL IL IL IL 1* IL IL IL
effluent %: 3.3%
'REATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced 11181211181221201201181181 0119122121
Adult (L)ive (D)ead IIL IL IL IL IL IL IL IL 1* IL IL IL
Chronic Test Results
Calculated t = -1.449
Tabular t = 2.528
% Reduction = -4.33
% Mortality
Avg.Reprod.
0.00
18.91
Control
Control
0.00
19.73
Treatment 2
Treatment 2
Control CV
4.992% PASS FAIL
% control orgs X
producing 3rd
brood Check One
100%
1st sample 1st sample 2nd sample Complete This For Either Test
PH Test Start Date: 02/22/06
Control 7.96 7.93 7.91 7.96 7.91 7.84 Collection (Start) Date
Sample 1: 02/20/06 Sample 2: 02/23/06
Treatment 2 7.90 7.86 7.82 7.97 7.90 8.00 Sample Type/Duration 2nd
1st P/F
s s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X 24 hrs L A A
r d r d r d- U M M
t t t Sample 2 X 24 hrs T P P
1st sample 1st sample 2nd sample
D.O. Hardness (mg/1) 46 ........ .........
Control 7.85 7.68 7.90 7.52 E79
7.72
Spec. Cond.(µmhos) 176 315 418
Treatment 2 7.85 7.70 7.87 7.65 7.82
Chlorine (mg/1) ,....... 0.13 <0.1
LC50/Acute Toxicity Test Sample temp. at receipt(°C) 0.2 0.3
(Mortality expressed as %, combining replicates)
%
%
%
%
%
's
Note: Please
Concentration Complete This
Section Also
Mortality
start/end start/end
1'C50 = % Method of Determination
95% Con i ence Limits Moving Average _ Probit _
% -- % Spearman Karber _ Other
Organism Tested: Ceriodaphnia dubia Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
Control
High
Conc.
nH D.O.
DEQ-CFW 00062425

DEQ-CFW 00062426

EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 002 MONTH Feb. YEAR 2006
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Environmental Laboratory (2)
CHECK BOX IF ORC HAS CHANGED L PERSON(S) COLLECTING SAMPLES Ray Beard / Robert J. Geddie
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF WATER QUALITY X
DENR (SIGNATURE OF OIStRATOR IN RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27699-1617 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
50050
00010
00400
00951
00665
00500
00310
00340
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mg/L
mg/L
mg/L
mg/L
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14.144
15
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14.288
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14.208
20
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14.210
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7
28
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24
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14.096
15
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s
100:I
IBM
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24
AVERAGE
14.065
14
1999
0.801
1.44
8.8
41.5
1-1
MCiiu>l1A
14 363
16
7 8
188
i3 8ti1=
:
ENE
8
415:
MINIMUM
13.726
12
7.0
1290
0.801
1.44
8.8
41.5
C
C
,
Monthly Limit
Dail Limit
6-9
7917
DEM Form MR -I (12193) * See Back Page
DEQ-CFW 00062427

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements Q
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements 0
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
The February 2006 Outfall 002 samples for the analysis of Total Nitrogen and Total Phosphorous were inadvertently
not submitted per the normal site procedure When this error was discovered, the commercial laboratory was asked
to locate retained Outtall 002 samples and perform the Nitrogen and Phosphorous analyses. The only retained
system to augment the existing sampling procedure
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Barry Hudson - Site Manager
Peemittee (Please print or typq) /
re of
NC Hwy 87 South, Fayetteville, NC, 28306 V [phone] October 31, 2006
Permittee Address Phone Number Permit Exp. Date
00010 Temperature
00076 Turbidity
00080 Color (Pt -Co)
00082 Color (ADM[)
00095 Conductivity
00300 Dissolved Oxygen
00310 BOD5
00340 COD
00400 pH
00530 Total Suspended
Residue
00545 Settleable Matter
00556
00600
00610
00625
00630
PARAMETER CODES
Oil & Grease 00951 Total Fluoride
Total Nitrogen 01002 Total Arsenic
Ammonia Nitrogen
Total Kjeldhal
Nitrogen
Nitrates/Nitrites
00665
Total Phosphorous
00720
Cyanide
00745
Total Sulfide
00927
Total Magnesium
00929
Total Sodium
00940
Total Chloride
01027 Cadmium
01032
Hexavalent Chromium
01034
Chromium
01037
Total Cobalt
01042
Copper
01045
Iron
01051
Lead
01067 Nickel
01077 Silver
01092 Zinc
01105 Aluminum
01147 Total Selenium
31616 Fecal Coliform
32730 Total Phenolics
34235 Benzene
34481 Toluene
38260 WAS
39516 PCB's
50050 Flow
50060 Total
Residual
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xyiene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone] extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
"ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 213.0506
(b) (2) (D) 0
DEQ-CFW 00062428

EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. _ 006 MONTH Feb. _ YEAR 2006
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Environmental Laboratory (2)
CHECK BOX IF ORC HAS CHANGED F71 PERSON(S) COLLECTING SAMPLES Ray Beard / Robert J. Geddie
Mail ORIGINAL and ONE COPY to: /
ATTN: CENTRAL FILES X ?0 / 1 t 2/3v �v N
DIV. OF WATER QUALITY
DENR (SIGNATURE OFOPERATOR IN RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH. NC 27699-1617 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
•• 1
111111111111111111�11111-11111111_IIIIIIIIIIIIIIIIII,I-IIIIIII_
11111FTOTO-Izfmit'll
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er®
IIII ISOM,
0
DEQ-CFW 00062429

rJim
Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements L�
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
NC Hwy 87 South, Fayetteville, NC, 28306 u [phone] October 31, 2006
Peemittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
01092
Zinc
Chlorine
00082
Color (ADMI)
00625
Total Kjeldhal
01027
Cadmium
01105
Aluminum
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
01032
Hexavalent Chromium
01147
Total Selenium
71880 Formaldehyde
00300
Dissolved Oxygen
01034
Chromium
31616
Fecal Coliform
71900 Mercury
00310
BOD5
00665
Total Phosphorous
32730
Total Phenolics
81551 Xylene
00340
COD
00720
Cyanide
01037
Total Cobalt
34235
Benzene
00400
pH
00745
Total Sulfide
01042
Copper
34481
Toluene
00530
Total Suspended
00927
Total Magnesium
38260
MBAS
Residue
00929
Total Sodium
01045
Iron
39516
PCB's
00545
Settleable Matter
00940
Total Chloride
01051
Lead
50050
Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
o
DEQ-CFW 00062430