DEQ-CFW_00062353

U
�000,3s73
4M.
OCT 23 2006
QENR-FAYE'f1�l.�E RC014PiA►.O�ICE
N.C. Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
DuPont Fluoroproducts
Fayetteville Works Plant
22828 NC Highway 87 West
Fayetteville, NC 28306-7332
1
September 27, 2006
DISCHARGE MONITORING REPORT — August 2006
Attached is E. I. DuPont de Nemours & Company, Inc., Fayetteville Works Discharge
Monitoring Report for the month of August 2006.
If you have any questions, please contact Robert Geddie at [phone].
RJG: sns
Attachment
cc: Ken Cook - ENGR, Old Hickory
R. J. Geddie -,FW
M. E. Johnson - FW
G. G. Santiago- FW
File: F-1-3-4
E.I. du Pont de Nemours and Company
DEQ-CFW 00062353

DEQ-CFW 00062354

S
EF NT
NPDES PERMIT NO. NC 0003573 DISCHARGE O. 001 MONTH Aug. YEAR 2006
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J.?Odle GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Laboratory (Lumberto (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddie / Ray Beard
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF ENVIRONMENTAL MANAGEMENT
DENR
P.O BOX 29535
RALEIGH. NC 27626-0535
DEM Form MR-1 (12/93)
X xe�- d • /. kllll '-
(SIGNATURE OF OPE OR IN RESPONSIBLE CHARGE)
BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
/�1,--;7 / eZ
DATE
DEQ-CFW 00062355

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Barry Hudson - Site Manager
Permittee (Please print or typ )
of
NC Hwy 87 South, Fayetteville, NC, 28306 [phone] October 31, 2006
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
01092 Zinc
Chlorine
00082
Color (ADMI)
00625
Total Kjeldhal
01027
Cadmium
01105 Aluminum
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
01032
Hexavalent Chromium
01147 Total Selenium
71880 Formaldehyde
00300
Dissolved Oxygen
01034
Chromium
31616 Fecal Coliform
71900 Mercury
00310
BOD5
00665
Total Phosphorous
32730 Total Phenolics
81551 Xylene
00340
COD
00720
Cyanide
01037
Total Cobalt
34235 Benzene
00400
pH
00745
Total Sulfide
01042
Copper
34481 Toluene
00530
Total Suspended
00927
Total Magnesium
38260 MBAS
Residue
00929
Total Sodium
01045
Iron
39516 PCB's
00545
Settleable Matter
00940
Total Chloride
01051
Lead
50050 Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b)(2)(D)
nn
�D G— � J
DEQ-CFW 00062356

4M.DuPontFluoroproducts
Fayetteville Works Plant
22828 NC Highway 87 West
Fayetteville, NC 28306-7332
September 27, 2006
Environmental Sciences Branch
Division of Water Quality
NC-DENR.
1621 Mail Service Center
Raleigh, NC 27699-1621
EFFLUENT CHRONIC TOXICITY REPORT — August 2006
Attached is E. I. DuPont de Nemours & Company, Inc., Fayetteville Works Effluent
Chronic Toxicity Report for August 2006.
If you have any questions, please contact Robert Geddie at [phone].
RJG:sns
Attachment
E.I. du Pont de Nemours and Company
DEQ-CFW 00062357

DEQ-CFW 00062358

Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 09/20/06
Facility: DUPONT NPDES#: NC0003573 Pipe#: 002 County: BLADEN
Laboratory Performing Test: MERITECH LABS, INC.
X
eot?� j Comments:
Signature o erat in Respo siTTle Charge
X r�� F
Signature of La oratory Supervisor * PASSED: -3.18% Reduction
Work Order: Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
Chronic Pass/Fail Reproduction Toxicity Test
2ONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced 1124129115128125119123125124121126124
Adult (L)ive (D)ead IIL IL IL IL IL IL IL IL IL IL IL IL
affluent %: 3.3%
Chronic Test Results
Calculated t = -0.595
Tabular t = 2.508
96 Reduction = -3.18
% Mortality
Avg.Reprod.
0.00
23.58
Control
Control
0.00
24.33
Treatment 2
Treatment 2
CREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV
_ 16.21896
# Young Produced 26 28 22 24 23 23 22 23 27 27 23 24 % control orgs
producing 3rd
brood
Adult (L)ive (D)ead L L L L L L L L L L L L 91.7%
PASS FAIL
X
Check One
1st sample lst sample 2nd sample Complete This For Either Test
pH Test Start Date: 08/16/06
Control 7.98 8.03 8.04 8.00 8.04 8.24 Collection (Start) Date
Sample 1: 08/14/06 Sample 2: 08/17/06
Treatment 2 8.07 8.02 8.05 8.02 8.05 7.96 Sample Type/Duration 2nd
1st P/F
s s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X 24 hrs L A A.
r d r d r d U M M
t t t Sample 2 X 24 hrs T P P
1st sample 1st sample 2nd sample .........,
D.O. Hardness (mg/1) 46
Control 7.98 7.69 8.00 7.78 8.20 7.85
Spec. Cond.(µmhos) 173 238 248
Treatment 2 7.95 7.65 8.10 7.81 7.88 7.76
Chlorine (mg/1) .,,,,,,, <0 .1 0.13
LC50/Acute Toxicity Test Sample temp. at receipt (°C) ,,,.,.,, 0.8 0.5
(Mortality expressed as %, combining replicates)
%
%s
°s
%
%
%
%
%
°s
%
%
%
%
P6
%
%
%
%
%
Note: Please
Concentration Complete This
LSection Also
Mortality
start/end start/end
.jC50 = % Method of Determination
95% Con i ence Limits Moving Average Probit
% -- % Spearman Karber ! Other
Organism Tested: Ceriodaphnia dubia Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
Control
High
pH ----- D.O.
DEQ-CFW 00062359

SO �- K;0
DEQ-CFW 00062360

EFFLUENT
NPDES PERMIT NO. NC 0003573 DISCHARGE NO. 002
FACILITY NAME DuPont - Fayetteville Works
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie
CERTIFIED LABORATORIES (1) TBL Laboratory (Lumberton)
CLASS
(2)
MONTH Aug. YEAR 2006
3 COUNTY Bladen
GRADE 4 PHONE [phone]
CHECK BOX IF ORC HAS CHANGED
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF ENVIRONMENTAL MANAGEMENT
DENR
P.O BOX 29535
RALEIGH, NC 27626-0535
PERSON(S) COLLECTING SAMPLES Robert J. Geddie / Ray Beard
>� //
X /CCQQ,T
(SIGNATURE OF OPE TOR IN RESPONSIBLE CHARGE) DATE
BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
o
NA
0
d
E
0
N
O
o
50050
00010
00400
00951
00655
00600
00310
00340
FLOW
�"
W
^
FC
°7O
w
LL.
a
¢
oa
O
z
0
�
_0
o
0
N
p
ca
UW
EFF X
INF
i~
Q
0
HRS
HRS
Y/N
MGD
'c
UNITS
Lb/Day
mg/L
mg/L
mg/L
mg/L
31
7.3
2
osoo
24
Y
17.641
im
am—
ME
ME
mi
WE
4
osoo
24
B
18.418
34
7.4
6
osoo
24
18.184EMMMM
ME
-
_
8
osoo
24
B
18.774
31
7.5
1140
17.703
30
7.5
_-
10
osoo
24
B
E
12
osoo
24
16.408
tr=:
-
OM—
MEN
14
osoo
24
Y
16.226
30
7.4
s-,
30
7.6
16
osoo
24
Y
16.560
EMMMERM-
7.8
-WIN-F
sm
18
osoo
24
Y
16.651
28
4_
20
osoo
24
17.128
24
uz
22
Y
17.335
30
7.3
1337
7o800
17.487
30
7.4
24
24
Y
Mf
_
26
osoo
24
16.283
M M
7.5
28
osoo
24
Y
16.400
31
osoo
24
B
16.684
30
7.6
30
30
1068
1.62
1.90
0.0
80.0
AVERAGE
17.132
6.9 359
1.90
<2.0
80.0
MINIMUM
15.860
28
1.62
WIN
Monthly Limit
-�5
-
DEM Form MR-1 (12193)
DEQ-CFW 00062361

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements C�
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Barry Hudson - Site Man
Permittee (Please print or
Signature of
2S/0
Date
v
NC Hwy 87 South, Fayetteville, NC, 28306 [phone] October 31, 2006
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00082
Color (ADM[)
00095
Conductivity
00300
Dissolved Oxygen
00310
BOD5
00340
COD
00400
pH
00530
Total Suspended
Residue
00545
Settleable Matter
00610 Ammonia Nitrogen
00625 Total Kieldhal
Nitrogen
00630 Nitrates/Nitrites
00665
Total Phosphorous
00720
Cyanide
00745
Total Sulfide
00927
Total Magnesium
00929
Total Sodium
00940
Total Chloride
01027 Cadmium
01032 Hexavalent Chromium
01034 Chromium
01037 Total Cobalt
01042 Copper
01045 Iron
01051 Lead
01092 Zinc
01105 Aluminum
01147 Total Selenium
31616 Fecal Coliform
32730 Total Phenolics
34235 Benzene
34481 Toluene
38260 MBAS
39516 PCB's
50050 Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
9110 G _ 1
DEQ-CFW 00062362

EFFLUENT
NPDES PERMIT NO. INC 0003573 DISCHARGE NO. 006 MONTH Aug. YEAR 2006
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Laboratory (Lumberton) (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddie / Ray Beard
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF ENVIRONMENTAL MANAGEMENT X
DENR (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
P.O BOX 29535 BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27626-0535 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
DEM Form MR -I (12/93)
DEQ-CFW 00062363

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements C�
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Barry Hudson - Site Manager
Permittee (Please print or type)
of
NC Hwy 87 South, Fayetteville, NC, 28306 [phone] October 31, 2006
Permittee Address Phone Number Permit Exp. Date
00010 Temperature
00076 Turbidity
00080 Color (Pt -Co)
00082 Color (ADM[)
00095
Conductivity
00300
Dissolved Oxygen
00310
BOD5
00340
COD
00400
pH
00530
Total Suspended
Residue
00545
Settleable Matter
00556
00600
00610
00625
00630
PARAMETER CODES
Oil & Grease 00951 Total Fluoride
Total Nitrogen 01002 Total Arsenic
Ammonia Nitrogen
Total Kjeldhal
Nitrogen
Nitrates/Nitrites
00665
Total Phosphorous
00720
Cyanide
00745
Total Sulfide
00927
Total Magnesium
00929
Total Sodium
00940
Total Chloride
01027 Cadmium
01032 Hexavalent Chromium
01034 Chromium
01037 Total Cobalt
01042 Copper
01045 Iron
01051 Lead
01067 Nickel
01077 Silver
01092 Zinc
01105 Aluminum
01147 Total Selenium
31616 Fecal Coliform
32730 Total Phenolics
34235 Benzene
34481 Toluene
38260 MBAS
39516 PCBs
50050 Flow
50060 Total
Residual
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
Q
DEQ-CFW 00062364