DEQ-CFW_00062188

. s
E r.4 ENT
NPDES PERMIT NO. NC0003573 DISCHARGE NO. 001 MONTH November YEAR 2007
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. QAdie GRADE 4 PHONE (910) 674ftj
CERTIFIED LABORATORIES (1) TBL Laboratory (Lumb on) (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddie / Ray Mild�,,,.
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES DVO '�"
DIV. OF WATER QUALITY (�p X f2/ 4e.,l
DENR .r t8 20� (SIGNATURE OF OPERAT IN RESPONSIBLE CHAR DATE
161E MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
ACCURATE AND COMPLETE
RALEIGH, NC 27699-1617 E TO THE BEST OF4AICI AI-66E,'�
IW.
Q
oY
2
ao
oa
O
o
E
F
o
O
vi
O
U
O
50050
00010
00400
00310
00530
00556
TG3PB
39700
FLOW
UJI
MU)
Q?
W J
C. w
V
1.--
C.
v
cm(n
r�i
O
MI
c
w
in
ww
_aa
�y
fAw
Q
H
<
Ix
U
otf
J_
-
x
F-
u
C
C
U
�w
-Jw
UZ
QQw
X 00
2
EFF X
INF 0
>-LIJ
Q I-
o9
HRS
HRS
Y/N
MGD
*C
UNITS
Lb/Day
Lb/Day
mg/L
P/F
ug/L
1
0800
24
Y
0.000
2
0800
24
Y
0.341
20
7.71
3
0800
24
0.357
<6.0
45.6
7.8
4
0800
24
0.159
<2.7
16.8
5
0800
24
Y
0.178
16
8.12
<3.0
18.6
6
0800
24
Y
0.642
18
8.28
10.7
80.3
7
0800
24
Y
0.346
16
7.61
6.9
25.7
8
0800
24
Y
0.349
9
0800
24
Y
0.535
10
0800
24
0.546
11
0800
24
0.588
12
0800
24
Y
0.626
15
7.21
84.6
28.2
13
0800
24
Y
0.533
17
7.23
88.0
21.8
PASS
14
0800
24
B
0.764
19
7.19
124.9
79.6
15
0800
24
Y
0.690
16
0800
24
Y
0.696
17
0800
24
0.723
18
0800
24
0.740
172.8
148.1
19
0800
24
B
0.721
18
7.46
151.5
83.6
20
0800
24
B
0.673
18
7.47
133.0
46.6
21
0800
24
B
0.690
19
7.45
22
0800
24
**
0.565
**
**
23
0800
24
B
0.542
24
0800
24
0.483
25
0800
24
0.611
26
0800
24
Y
0.669
16
7.40
156.2
128.3
27
0800
24
Y
0.656
19
7.32
118.7
158.7
28
0800
24
Y
0.609
15
7.56
94.0
58.4
29
0800
24
Y
0.655
30
0800
24
Y
0.656
31
0800
24
AVERAGE
0.545
17
81.5
67.2
7.8
PASS
MAXIMUM
0.764
20
8.28
172.8
158.7
7.8
PASS
MINIMUM
0.000
15
7.19
<2.7
16.8
7.8
PASS
Comp. (C) Grab (G)
G
G
C
C
G
C
Monthly Limit
2.0
1
191.31
317.81
1
PASS
Daily Limit
6-9 1508.21
1030 1
1
1
0.5
DEM Form MR -I (12/93)
* Shut Down ** Holiday
DEQ-CFW 00062188

1 6
Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements r
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Karen B. Wrigley - Plant Manager
Permittee (Please print or type)
of
--�?o 07
Date
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332 [phone] October 31, 2011
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
01092
Zinc
Chlorine
00082
Color (ADMI)
00625
Total Kjeldhal
01027
Cadmium
01105
Aluminum
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
01032
Hexavalent Chromium
01147
Total Selenium
71880 Formaldehyde
00300
Dissolved Oxygen
01034
Chromium
31616
Fecal Coliform
71900 Mercury
00310
BOD5
00665
Total Phosphorous
32730
Total Phenolics
81551 Xylene
00340
COD
00720
Cyanide
01037
Total Cobalt
34235
Benzene
00400
pH
00745
Total Sulfide
01042
Copper
34481
Toluene
00530
Total Suspended
00927
Total Magnesium
38260
MBAS
Residue
00929
Total Sodium
01045
Iron
39516
PCB's
00545
Settleable Matter
00940
Total Chloride
01051
Lead
50050
Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D) LQ L Z 030
DEQ-CFW 00062189

Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 11/26/07
Facility: DUPONT
Labora ryperforming Test: MERITECH, INC
X r
Signature ot ffperat.Rr,in esponylbie C
NPDES#: NC0003573 Pipe#: 002 County: BLADEN
Comments: Dilution Water Batch
#626 & 627 Used
X - . --�- v
Signature o a oratory Supervisor * PASSED: 1.21% Reduction
Work Order: Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
forth Carolina Ceriodapnnia
Chronic Pass/Fail Reproduction Toxicity Test
=TROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced 1127128128128129126130128126129126126
Adult (L)ive (D)ead IIL IL IL IL IL IL IL IL IL IL IL IL
'sffluent %: 3.3%
CREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced 1128127126127127132128126127127127125
Adult (L) ive (D) ead L L IL IL IL IL IL JL.JL IL IL IL
Chronic Test Results
Calculated t = 0.525
Tabular t = 2.508
% Reduction = 1.21
% Mortality
Avg.Reprod.
0.00
27.58
Control
Control
0.00
27.25
Treatment 2
Treatment 2
Control CV
4.999% PASS FAIL
% control orgs X
producing 3rd
] E
brood Check One
100%
1st sample 1st sample 2nd sample Complete This For Either Test
pH Test Start Date: 11/14/07
Control 8.13 7.86 8.08 7.96 8.00 7.98 Collection (Start) Date
Sample 1: 11/12/07 Sample 2: 11/15/07
Treatment 2 8.13 8.00 8.08 7.96 8.00 7.98 Sample Type/Duration 2nd
1st P/F
s s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X 24.0 hrs L A A
r d r d r d U M M
t t t Sample 2 X 24.0 hrs T P P
1st sample 1st sample 2nd sample
D.O. Hardness (mg/1) 48 ........ .........
Control 7.60 7.57 8.05 7.70 7.94 7.38
Spec. Cond.(µmhos) 173 232 322
Treatment 2 7.67 7.61 8.00 7.64 7.93 7.25
Chlorine (mg/1) ........ <0 .1 < 0 . 1
LC50/Acute Toxicity Test Sample temp. at receipt(°C) 1.2 1.2
(Mortality expressed as %, combining replicates) P1
Note. ease
Concentration Complete This
Mortality
Section Also
start/end start/end
Method of Determination
95% Con i ence Limits Moving Average _ Probit
% -- % Spearman Karber - Other
Control
High
("nn t-
11
Organism Tested: Ceriodaphnia dubia Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
om
DEQ-CFW 00062190

�6�Z9000 AA=10-030
ocr 27 07
L-,.,

EFFLUENT
NPDES PERMIT NO. NC0003573 DISCHARGE NO. 002 MONTH November YEAR 2007
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Robert J. Geddie GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Laboratory (Lumberton) (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Robert J. Geddie / Ray Beard
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF WATER QUALITY
DENR
1617 MAIL SERVICE CENTER
RALEIGH, NC 27699-1617
(SIGNATURE OF OPERAT RESPONSIBLE CHARGE)
BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
DATE
LU
a
A�
.t�
¢o
O N
C
o`
i=
8
0
w
o
K
o
50050
00010
00400
00951
00665
00600
51521
00310
00340
FLOW
�y
9y
�
M V
~'
=
O.
c
O
LL
�0
Qp
Nx
p 0
a
Z
o
2
Q
o
°tea
��
JO
W Q
W F-
a o
N
y
p
m
o
O
U
EFF X
INF
>-
Q
G
HRS
HRS
Y/N
MGD
C
UNITS
Lb/Day
mg/L
mg/L
ug/L
mg/L
mg/L
1
osoo
24
Y
13.732
18
6.48
44
2
osoo
24
Y
9.262
19
6.48
3
osoo
24
7.863
4
osoo
24
12.654
5
10800
24
Y
10.669
17
6.88
6
osoo
24
Y
11.159
17
7.50
493
0.48
0.99
<2
<100
7
osoo
24
Y
11.620
16
6.99
0.075
8
osoo
24
Y
11.537
16
6.90
9
osoo
24
Y
11.734
17
6.90
10
osoo
24
11.743
11
osoo
24
12.044
12
osoo
24
Y
13.680
16
6.92
13
osoo
24
Y
13.685
17
6.96
347
14
osoo
24
B
13.725
18
7.01
15
osoo
24
Y
14.107
19
7.08
16
osoo
24
Y
14.146
16
7.12
17
osoo
24
14.125
18
osoo
24
14.207
19
osoo
24
B
14.145
18
7.22
1035
20
osoo
24
B
14.046
17
7.23
21
osoo
24
B
13.952
17
7.18
22
osoo
24
**
13.882
**
**
23
osoo
24
B
13.738
17
7.17
24
osoo
24
13.551
25
osoo
24
13.635
26
osoo
24
Y
13.723
16
7.12
27
osoo
24
Y
13.683
17
7.14
639
28
osoo
24
Y
13.471
16
7.16
29
osoo
24
Y
13.706
17
7.21
30
osoo
24
Y
13.592
16
7.07
31
osoo
24
AVERAGE
12.894
17
512
0.48
0.99
0.075
<2
<100
MAXIMUM
14.207
19
7.50
1035
0.48
0.99
0.075
<2
<100
MINIMUM
7.863
16
6.48
44
0.48
0.99
0.075
<2
<100
Comp. (C) Grab (G)
G
G
C
C
C
C
C
C
Monthly Limit
Daily Limit
1
1
6-9 1
7917
DEM Form MR-1 (12/93)
* Shut Down ** Holiday
DEQ-CFW 00062192

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Karen B. Wrigley - Plant Manager
Permittee (Please print or type)
re
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332 [phone] October 31, 2011
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
01092
Zinc
Chlorine
00082
Color (ADMI)
00625
Total Kjeldhal
01027
Cadmium
01105
Aluminum
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
01032
Hexavalent Chromium
01147
Total Selenium
71880 Formaldehyde
00300
Dissolved Oxygen
01034
Chromium
31616
Fecal Coliform
71900 Mercury
00310
BOD5
00665
Total Phosphorous
32730
Total Phenolics
81551 Xylene
00340
COD
00720
Cyanide
01037
Total Cobalt
34235
Benzene
00400
pH
00745
Total Sulfide
01042
Copper
34481
Toluene
00530
Total Suspended
00927
Total Magnesium
38260
MBAS
Residue
00929
Total Sodium
01045
Iron
39516
PCB's
00545
Settleable Matter
00940
Total Chloride
01051
Lead
50050
Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D) L0 LZ J30
DEQ-CFW 00062193

NPDES NO: NC0003573
DISCHARGE NO: 002 MONTH: November YEAR: 2007
FACILITY: DuPont - Fayetteville Works COUNTY: Bladen
STREAM: Cape Fear River STREAM: Cape Fear River
LOCATION: DuPont River Pump Station LOCATION: Boat Ramp - 4500 ft below Prospect Hall Landing
UPSTREAM
-
-
_LLIm
:
DWQ Form MR-3 (Revised 7/2000)
DOWNSTREAM
DEQ-CFW 00062194

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Karen B. Wrigley - Plant Manager
Permittee (Please print or type)
I;;>,
of Permittee"*
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332 [phone] October 31, 2011
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADM[)
00625
Total Kjeldhal
01027
Cadmium
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
01032
Hexavalent Chromium
00300
Dissolved Oxygen
01034
Chromium
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
01037
Total Cobalt
00400
pH
00745
Total Sulfide
01042
Copper
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
01045
Iron
00545
Settleable Matter
00940
Total Chloride
01051
Lead
01092 Zinc Chlorine
01105 Aluminum
01147 Total Selenium
71880 Formaldehyde
31616
Fecal Coliform
71900 Mercury
32730
Total Phenolics
81551 Xylene
34235
Benzene
34481
Toluene
38260
MBAS
39516 PCB's
50050 Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 213 .0506
(b) (2) (D)
LO LZ 330
a= r
DEQ-CFW 00062195

QW.
N.C. Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
DuPont Fluoroproducts
Fayetteville Works Plant
22828 NC Highway 87 West
Fayetteville, NC 28306
December 19, 2007
DISCHARGE MONITORING REPORT — November 2007
Attached is E. I. DuPont de Nemours & Company, Inc., Fayetteville Works Discharge
Monitoring Report for the month of November 2007.
If you have any questions, please contact Robert Geddie at [phone].
RJG: sns
Attachment
cc: Ken Cook - ENGR, Old Hickory
R. J. Geddie - FW
M. E. Johnson - FW
G. G. Santiago- FW
File: F-1-3-4
E.I. du Pont de Nemours and Company
DEQ-CFW 00062196

LO LZ 3-30
DEQ-CFW-00062197