DEQ-CFW_00060665

01
KNvu
EFFL ENT
NPDES PERMIT NO. NC0003573 DISCHARGE NO. 001 MONTH February YEAR MA�O 1
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Jamie R. Lewis GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Laboratory (Lumberton) (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Jamie Lewis / Ray Beard / Russell Rotan
Mail ORIGINAL and ONE c`
�C; E I l0 '�
y
ATTN: CENTRAL FILES,{,'_
tea.
DIV. OF WATER QUALITY MAR 2 2 2011 X
DENR (SIGNA URE OF OPERATOR IN RESPONSIBLE CHARGE) DATE d
t� (' BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS a �' 4
1617 MAIL SERVICE CENTE�R)I`(8?�3IlOi i �rOC�SSlfiiCi � _-
RALEIGH, NC 27699-1617 Ilv R0
n A,� e.
v
2
FLOW
W
A
R 0
2 011
RY
o
A
EFF X
�y
o
ww
0Oz
Iw.
8
d
U)
INF
fQ
a
$
u°i o
Ix
o
= N
Q
❑
Q o
o
F
p
W J
a.LU
ut
O
7 y
NioWC
(9
'd
t-
g
QUQ z
�N
v
w
O
�
m
a
or
xm
w
O
O
a~
❑
F
FO
O
v
x
HRS
HRS
Y/N
MGD
'C
UNITS
Lb/Day
Lb/Day
mg/L
P/F
ug/L
1
0806
24
Y
0.437
15
7.73
UZI
9.1
2
0800
24
Y
0.682
15
7.90
15.4
15.4
3
osoo
24
Y
0.683
4
o800
24
Y
0.935
5
osoo
24
0.896
6
10800
24
0.887
7
0800'
24 1
i B
0.850
10
7.70
;125.5
46.8
8
0800
24 1
B
0.759
17
7.80
33.5
40.5
9
0800
L 24
Y
0.816
16
8.00
24.5
64.0
10
o800
24
Y
0.782
11
0800
24
Y
0.937
12
0800
24
0.844
13
0800
24
0.912
14
0800
24
Y
0.876
17
7.87
21.2
48.2
15L
0800
24
Y
0.887
18
7.91
16.3
L 49.6
16
0800
24
Y
0.825
17
7.90
17.9
31.0
<5.0
PASS
17
0800
24
Y
0.807
18
osoo
24
Y
0.820
19
0800
24
0.908
20.0800
24
0.851
2110800
24
Y
0.977
18
7.81 1131.0,
66.2
2210800
24 1
Y
1.037
20
7.99
32.9
72.6
23
0800
24
Y
0.870
20
7.92
33.4
111.7
2410800
24
Y
1.008
2510800
24
Y
0.797
26
osoo
24
0.885
27
0800
24
0:999
28
080
224
Y
0.974
22
7.76
30.1
60.9
i29
o800
24
30
0800
24
MINIMUM 0.437 10 7.70 1 10.2 9.1 <5.0 1 PASS
Comp. `C) Grab (G) G G I
C C G I C
Monthly Limit 2.0 1 191.3 1317.81 1 PASS
Daily Limit 6-9 508.2 1 1030 1 0.5
DEM Form MR-I.(12193)
DEQ-CFW 00060665

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements t=J
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332 [phone] October 31, 2011
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADMI)
00625
Total Kjeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032
Hexavalent Chromium
01034
Chromium
01037
Total Cobalt
01042
Copper
01045
Iron
01051
Lead
01092 Zinc
01105 Aluminum
01147 Total Selenium
31616 Fecal Coliform
32730 Total Phenolics
34235 Benzene
34481 Toluene
38260 MBAS
39516 PCB's
50050 Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal conform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
DEQ-CFW 00060666

Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 02/24/11
Facility: DUPONT FAYETTEVILLE WORKS NPDES#: NC0003573 Pipe#: 002 County: BLADEN
Laboratory P forming est: MERITECH LABS, INC.
Comments: second batch dilution
X `
Signature of Operator i�esn.,ble rge water: hard - 46, cond - 185
X
Signature of Laboratory Supervisor * PASSED: -2.45% Reduction
Work Order: Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
forth Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test
�ONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced 1121118121117118121117121124121123123
Adult (L)ive (D)ead III
,. IL IL IL IL IL IL IL IL IL IL IL
affluent %-: 3.3%-
CREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV
11.714 0
# Young Produced 22122120 17 21121121 23 17 21 22 24 % control orgs
producing 3rd
brood
Adult Wive (D) ead L L L L L IL IL L L L L L I
100&
Chronic Test Results
Calculated t = -0.543
Tabular t = 2.508
Reduction = -2.45
Mortality
Avg.Reprod.
0.00
20.42
Control
Control
0.00
20.92
Treatment 2
Treatment 2
PASS FAIL
X
Check 'bne
1st sample 1st sample 2nd sample Complete This For Either Test
pH - Test Start Date: 02/16/11
Control 8.11 8.24 8.25 8.23 E28�.08 Collection (Start) Date
Sample 1: 02/14/11 Sample 2: 02/16/11
Treatment 2 8.09 8.19 8.23 8.08 8.10 Sample Type/Duration 2nd
1st P/F
s s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X 24.2 hrs L A A
r d r d r d U M M
t t t Sample 2 X 24.3 hrs T P P
1st sample 1st sample 2nd-sample
D.O. Hardness (mg/1) 44 ........ .........
Control 7.53 7.46 7.66 7.54 7.67 7.60
Spec. Cond.(pmhos) 178 588 ' 671
Treatment 2 7.49 7.40 7.60 7.35 7.62 7.39
Chlorine (mg/1) ........ 0.24 0.18
LC50/Acute Toxicity Test Sample temp. at receipt(°C) ........ 0.4 0.2
(Mortality expressed as %-, combining replicates) 71
%
g
%
g
I %
%-
o
-
Note: Please
Concentration Complete This
Section Also
Mortality
start/end start/end
:,C50 = %- Method of Determination
95% Con i ence Limits Moving Average Probit
-- o Spearman Karber - Other
Control
High
r'nn r
pH
Organism Tested: Ceriodaphnia dubia Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
DEQ-CFW 00060667

EFFLUENT
NPDES PERMIT NO. NC0003573 DISCHARGE NO. 002 MONTH February YEAR 2011
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Jamie R. Lewis GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Laboratory (Lumberton) (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Jamie Lewis / Ray Beard / Russell Rotan
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES DIV. OF WATER QUALITY X CYYUti 344-
11
DENR (SIGNA)(IRE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS -
RALEIGH, NC 27699-1617
d
FLOW
w
w
c
Y
A
EFFX
�y
w
p-d
o
pQ
O
Fw-
i 2
E
w
INF
�QQ' 2
_
4 p
F
� V
N
o
Q
a o
i=
o`
W
a
O a
H=
Z
uJ z
�'
O
J Lu
W
LL
a U
ca
0
0'
Q
G
~
a
O
O
IRS
HRS
Y/N
MGD
`C
UNITS
Lb/Day
mg/L
V/L
ug/L
mg/L
mg/L
1
10800
24 1
Y
7.761
11
7.31
2
10800
24
Y
7.407
14
7.62
451
3
o800
24 i,Y
8.164
13
7.46
4
0800
24
Y
7.925
12
7.39
5
0800
24
8:068
6
o800
24
7.797
7
0800
24
B
9.224
14
7.30
8
10800
24
B
8.965
15
7.40
0.251
.1.72
<2.0
25.6
.
9
10800
24
Y
8.886
14
7.49
3869
0 077
_
1010800
24
Y
8.918
13 -
7.38
11
0e00
24
Y
8:645
1 13
7.45
12
0800
24
9.144
13
0800`
24
9144
14
0800
24
Y
9.144
14
7.49
15
0800
24
Y
10.882
13
7.49
16
0800
24
Y
6.878
13
7.55
1474
17
0800
24
Y
8:805
14
7.50
18
0800
24
Y
8.308
14
7.43
19
0800
24
8.530
20
0800
24
8.809
21
0800
24
Y
8.381
14
7.52
2210800
24
Y
8.763
16
7.40
2310800
24
Y
9.000
16
7.15
345
24
0800
24
Y
8.796
16
7.29
25
0800
24
Y
9052
17
7.50
26
0800
24
8.383
27
0800
24
9076
28
0800
24
Y
9.024
19 1
7.45
29
0800
24
30
0800
24
31
0800
24
AVERAGE
8.639
14
1535
0.251
'1.72
0.077
0.0
25.60
MAXIMUM
10.882
19
7.62
3869
0.2511
1-.72
0 077
<2.0
26.60
MINIMUM
6.878
11
7.15
345
0.251
1.72
0.077
<2.0
25.60
omp. (C),Grab (G)',
G
G
G
C
C
G
C
C
Monthly Limit
Daily Limit
6-9
7917
DEM Form MR-1 (12/93)
DEQ-CFW 00060668

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements rI
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
H. McGau h - Plant 4tager
ittee (Plelpe print or tXp
'3/13
of
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332 [phone]- October 31, 2011
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADMI)
00625
Total Kjeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032 Hexavalent Chromium
01034 Chromium
01037 Total Cobalt
01042 Copper
01045 Iron
01051 Lead
01092 Zinc
01105 Aluminum
01147
Total Selenium
31616
Fecal Coliform
32730
Total Phenolics
34235
Benzene
34481
Toluene
38260
MBAS
39516
PCB's
50050
Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B)
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
DEQ-CFW 00060669

NPDES NO: NC0003573 DISCHARGE NO: 002 MONTH: February YEAR: 2011
FACILITY: DuPont - Fayetteville Works COUNTY: Bladen
STREAM: Cape Fear River STREAM: Cape Fear River
LOCATION: DuPont River Pump Station LOCATION: Boat Ramp - 4500 ft below Prospect Hall Landing
UPSTREAM DOWNSTREAM
00010
00400
00310
00610
00530
00094
51521
N
0
Q
C
O .
_O
U
L •N
3
y
0)
C
l:
M
pp
N
N
O
w
7
O
ro
N
4f 4)
C.
M
N
U-13
O t?
F-
~
O
N
IL
U
y
O
Q
o
a
to
HRS
1 °C
units
mg/L
mg/L
I #/100m1
µmnacm'
ug/L
MMEM
DWQ Form MR-3 (Revised 7/2000)
00010
00400
00310
00610
00530
00094
C)
O
Y
C
C
'
E
>
w
�, ..
m
L V
Z•.
>,
V
O
M
N
a d
_ a...
M
4)
E L
O
C
O
o
LL
U
O
�
m
HRS
°C
units
mg/L
mg/L
#/100ml
µmho/cm
DEQ-CFW 00060670

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
�l
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332 [phone] October 31, 2011
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
01092
Zinc
Chlorine
00082
Color (ADMI)
00625
Total Kjeldhal
01027
Cadmium
01105
Aluminum
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
01032
Hexavalent Chromium
01147
Total Selenium
71880 Formaldehyde
00300
Dissolved Oxygen
01034
Chromium
31616
Fecal Coliform
71900 Mercury
00310
BOD5
00665
Total Phosphorous
32730
Total Phenolics
81551 Xylene
00340
COD
00720
Cyanide
01037
Total Cobalt
34235
Benzene
00400
pH
00745
Total Sulfide
01042
Copper
34481
Toluene
00530
Total Suspended
00927
Total Magnesium
38260
MBAS
Residue
00929
Total Sodium
01045
Iron
39516
PCB's
00545
Settleable Matter
00940
Total Chloride
01051
dead
50050
Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
"" If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
DEQ-CFW 00060671

DuPont Fluoroproducts
Fayetteville Works Plant
22828 NC Highway 87 West
Fayetteville, NC 28306
March 15, 2011
N.C. Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
DISCHARGE MONITORING REPORT — February 2011
Attached is E. I. DuPont de Nemours & Company, Inc., Fayetteville Works Discharge
Monitoring Report for the month of February 2011.
If you have any questions, please contact Jamie R. Lewis at [phone].
JRL: j 1p
Attachment
cc: Ken Cook - ENGR, Old Hickory
J. R. Lewis - FW
J. L. Locklear - FW
File: F-1-3-4
E.I. du Pont de Nemours and Company
DEQ-CFW 00060672