DEQ-CFW_00060547

QW.
N.C. Division of Water Quality
Attn: Central Files
1617 Mail Service Center
Raleigh, NC 27699-1617
DuPont Fluoroproducts
ft-. 22828 NC 87 Highway West
r // Fayetteville, NC 28306-7332
JUG. 0 6
RECEIVELD
AUG - S 2012
DENR-FAYETTEVILLE REGIONAL OFFICE
DISCHARGE MONITORING REPORT — May 2012
June 21, 2012
ON
P\_ 9l �o
Attached is E. I. DuPont de Nemours & Company, Inc., Fayetteville Works Discharge
Monitoring Report for the month of May 2012.
If you have any questions, please contact Jamie R. Lewis at [phone].
JRL: bao
Attachment
cc: Ken Cook - ENGR, Old Hickory
J. R. Lewis - FW
File: F-1-3-4
E.I. du Pont de Nemours and Company
DEQ-CFW 00060547

t
EFFLUENT L� T M v9
NPDES PERMIT NO. NC0003573 DISCHARGE NO. 001 MONTH JU W9 2017EAR 2012
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Jamie R. Lewis GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Laboratory (Lumberton) (2)
CHECK BOX IF ORC HAS CHANGg PERSON(S) "� COLLECTING SAMPLES Jamie R. Lewis / Arnold Ray Beard
E, � t s I;
Mail ORIGINAL and ONE COP t . �-" nn
ATTN: CENTRAL FILES 1 , _ <
DIV. OF WATER QUALITY ��� 2U X�
DENR CENTRAL Fit � : DATE
(SIGNAT RE OF OPERATOR IN RESPONSIBLE CHARGE)
1617 MAIL SERVICE CENTER DWQ/BOC BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27699-1617 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
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Lb/Day
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1
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25:;:8.17
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25
8.19
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1.003
27
8.24
23.4
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1.050
27'
8.28
34 2
170 8
10
0800
24
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0.955
11
0800
24
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0950
12
0800
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0.949
13
0800
24
0.900 j
14
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24
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1.062
26
8.05
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119.6
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0800
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8,02
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0800
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0.958
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0800
24
Y
0.900
19
0800
24
0.916
20
0800
24
0.850
21
0800
24
Y
0.866
25'
1.15
23.1
53 4
22
0800
24
Y
0.858
26
7.79
16.5
53.0
23
0800
24'
Y
0.911 "
26
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31 9
24
0800
24
Y
0.658
25
0800
24,
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0800
24
0.917
27
0800
24
0.931 '
28
0800
24
0.950
26.1
129.1
29
0800
24
Y
1.156
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8.24
60.7
122.4
30
0800
24
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0.926
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24.7
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Y
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27'>
8.23
AVERAGE
0.918
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MAXIMUM
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28
8.28
60:7
170.8
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MINIMUM
0.658
25
7.75
16.5
31.9
Comp. (C) Grab (G)
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C
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Monthly. Limit
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DEM Form MR-1 (12/93)
*Holiday
DEQ-CFW 00060548

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Ellis H.
6_,?/-2-21jZ--
n
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332 [phone] v October 31, 2016
Permittee Address Phone Number Permit Exp. Date
00010
Temperature
00076
Turbidity
00080
Color (Pt -Co)
00082
Color (ADMI)
00095 Conductivity
00300 Dissolved Oxygen
00310 BOD5
00340 COD
00400 pH
00530 Total Suspended
Residue
00545 Settleable Matter
00556
00600
00610
00625
00630
PARAMETER CODES
Oil & Grease 00951 Total Fluoride
Total Nitrogen 01002 Total Arsenic
Ammonia Nitrogen
Total Kjeldhal
Nitrogen
Nitrates/Nitrites
00665
Total Phosphorous
00720
Cyanide
00745
Total Sulfide
00927
Total Magnesium
00929
Total Sodium
00940
Total Chloride
01027 Cadmium
01032 Hexavalent Chromium
01034 Chromium
01037 Total Cobalt
01042 Copper
01045 Iron
01051 Lead
01067 Nickel
01077 Silver
01092 Zinc
01105 Aluminum
01147 Total Selenium
31616 Fecal Coliform
32730 Total Phenolics
34235 Benzene
34481 Toluene
38260 MBAS
39516 PCB's
50050 Flow
50060 Total
Residual
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
" ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
"` If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
DEQ-CFW 00060549

EFFLUENT
NPDES PERMIT NO. NC0003573 DISCHARGE NO. 002 MONTH May YEAR 2012
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Jamie R. Lewis GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Laboratory (Lumberton) (2)
CHECK BOX IF ORC HAS CHANGED L PERSON(S) COLLECTING SAMPLES Jamie R. Lewis / Arnold Ray Beard
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF WATER QUALITY X �7
DENR (SIGNAT RE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
RALEIGH, NC 27699-1617 ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
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25:
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18.902
25
7.55
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17.350
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18.049
26
7.86
5
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18.539
6
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24
17.989
7
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24-
Y
17533
26
7.81
8
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24
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18.085
27
7.30
3.4
27.3
0.83
2.51
9
0800
24
Y
18.943
27:
1.55
10
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24
Y
15.950
26
7.64
11
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24
Y
15951
28:
769
12
0800
24
15.950
13
0800
24
15.951
14
o800
24
Y
17.599
26
7.77
15
1610800
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24
24
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Y
17:019
15.510
26
26
7.35
7.40
0.180
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24
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26`
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1 18.494
25
7.25
19
0800
24
17.993
20
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24
17.408
21
0800
24
Y
17.198
26,'
752
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22
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24
Y
17.567
26
7.60
23
osoo
24
Y
19.535
25
7.35
24
osoo
24
Y
18.934
26
7.41
25
0800
24
Y
22.411
26:
7.50
26
0800
24
17.734
27
0800
24
19.448
28
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20.535
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- 21586
28.
7.70
30
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24
Y
24.253
27
7.15
31
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24
Y
19.993
28
736
AVERAGE
18.442
26
3.4
27.3
17.4
0.1801
0.83
2.51
P
MAXIMUM
24.253
281
7.89
3.4
2"
717;4F
0 180
0.83
2.51
P
MINIMUM
15.510
25
7.15
3.4
27.3
17.4
0.180
0.83
2.51
P
Comp. (C) Grab (G)
G
G'
C
C
G
G
C
C
C
Monthly Limit
Daily Limit
DEM Form MR -I (12193) *Holiday
Flow was estimated due to equipment malfunction 5/10 - 5/13,
DEQ-CFW 00060550

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Ellis H. McGauohv - Plant M,haner
Pe ittee (Please print or ty
Signature of mittee* \ j Date
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332 [phone] October 31, 2016
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADMI)
00625
Total Kjeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01092 Zinc
01027 Cadmium 01105 Aluminum
01032
Hexavalent Chromium
01147 Total Selenium
01034
Chromium
31616 Fecal Coliform
32730 Total Phenolics
01037
Total Cobalt
34235 Benzene
01042
Copper
34481 Toluene
38260 MBAS
01045
Iron
39516 PCB's
01051
Lead
50050 Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
_Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
DEQ-CFW 00060551

r Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50
Date: 05/31/12
Facility: DUPONT FAYETTEVILLE WORKS NPDES#: NC0003573 Pipe#: 002 County: BLADEN
L:Si4ga?tnur�len
ory Perf ming Test: MERITECH LABS, INC.
2a��� Comments: dilution water batch 11
X'
o Operator in./%" ponsi a arge also used: hard-44, cond-193
x
Signature of La oratory SLtOrvisor k PASSED: 9.84% Reduction
Work Order: Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
7orth Carolina cerioaapnnia
Chronic Pass/Fail Reproduction Toxicity Test
;ONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced 1121120121123119124123118125118113119
Adult (L)ive (D)ead JIL IL IL IL IL IL IL IL IL IL IL IL
affluent 3.396
'REATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced 1116120115120117121121116119117116122
Adult (L)ive (D)ead IIL IL IL IL IL IL IL IL IL IL IL IL
Chronic Test Results
Calculated t = 1.697
Tabular t = 2.508
Reduction = 9.84
Mortality
Avg.Reprod.
0.00
20.33
Control
Control
0.00
18.33
Treatment 2
Treatment 2
Control CV
16.153%- PASS FAIL
t control orgs X
producing 3rd
brood Check One
100%
1st sample 1st sample 2nd sample Complete This For Either Test
PH Test Start Date: 05/23/12
Control 8.14 7.99 8.06 8.15 8.19 8.04 Collection (Start) Date
Sample 1: 05/21/12 Sample 2: 05/23/12
Treatment 2 8.13 8.01 8.08 8.15 8.19 8.03 Sample Type/Duration 2nd
1st P/F
s s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X 24 hrs L A A
r d r d r d U M M
t t t Sample 2 X 24 hrs T P P
1st sample 1st sample 2nd sample
D.O. Hardness (mg/1) 48 ........ .........
Control 7.74 7.34 7.71 7.29 7.77 7.27 .
Spec. Cond.(pmhos) 192 472 423
Treatment 2 7.69 7.33 7.60 7.36 7.74 7.24
Chlorine (mg/1) ........ 0.12 0.14
LC50/Acute Toxicity Test Sample temp. at receipt(°C) .,...... 0.3 0.7
(Mortality expressed as %, combining replicates)
96
Note: Please
Concentration Complete This
Section Also
Mortality
start/end start/end
[,C50 = %- Method of Determination
950k Confidence Limits Moving Average _ Probit
%; -- � Spearman Karber _ Other
Control
High
PH
Organism Tested: Ceriodaphnia dubia Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
DEQ-CFW 00060552

NPDES NO: NC0003573 DISCHARGE NO: 002 MONTH: May YEAR: 2012
FACILITY: DuPont - Fayetteville Works COUNTY: Bladen
STREAM: Cape Fear River STREAM: Cape Fear River
LOCATION: DuPont River Pump Station LOCATION: Boat Ramp - 4500 ft below Prospect Hall Landing
UPSTREAM DOWNSTREAM
00010
00400
00310
00610
00530
00094
51521
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prdwlcm
uglL
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DWQ Form MR-3 (Revised 7/2000)
•
•
•
DEQ-CFW 00060553

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements �J
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
22828 NC Hwy 87 W
Permittee Address
Ellis H. McGau h - PI t Mana er
PermittA Ai
ee (P ease print ype)
VP
ignature of Permit
NC, 28306-7332 (910) 678-1 15
Number
October 31, 201i
Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver R 'd 1
00080 Color (Pt -Co) 00610 Ammonia Nitrogen
es i ua
01092 Zinc Chlorine
00082 Color (ADMI) 00625 Total Kjeldhal 01027 Cadmium
01105 Aluminum
Nitrogen
00095 Conductivity 00630 Nitrates/Nitrites 01032 Hexavalent Chromium
01147 Total Selenium 71880 Formaldehyde
00300 Dissolved Oxygen 01034 Chromium
31616 Fecal Coliform 71900 Mercury
00310 BOD5 00665 Total Phosphorous
32730 Total Phenolics 81551 Xylene
00340 COD 00720 Cyanide 01037 Total Cobalt
34235 Benzene
00400 pH 00745 Total Sulfide 01042 Copper
34481 Toluene
00530 Total Suspended 00927 Total Magnesium
38260 MBAS
Residue 00929 Total Sodium 01045 Iron
39516 PCB's
00545 Settleable Matter 00940 Total Chloride 01051 Lead
50050 Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group
at [phone] extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
" If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B
(b)(2)(D)
.0506
DEQ-CFW 00060554