DEQ-CFW_00060449

r Q A
OCT $ "" 2013
EFFLUEN
NPDES PERMIT NO. NC0003573 DISCHARGE NO. 001 MONTH August YEAR 2013
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Jamie R. Lewis GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Laboratory (Lumberton) (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Jamie R. Lewis / Arnold Ray Beard
Mail ORIGINAL and 0:��\ /�
ATTN: CENTRAL FILES �/
DIV. OF WATER QUALITY S E P 2 5 2013
DENR
1617 MAIL SERVICE CENTEFGENjRAL FILES
RALEIGH, NC 27699-1617 DWQ/BOG
(SIGNAT E OF OPERATOR IN RESPONSIBLE CHARGE) OCTATE
BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS C- 7 2013
ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
6
E
> o
«°�N
CL 0
v�
v
E
m
0
w
rn
o
50050
00400
00310
00530
00556
39700
39700
01034
01042
01
-
FLOW
ri,
WU
~
2
G
;�
N
M
w
p
Ww
a
mC
(n W
��
O
F-
W
¢
atf
OJ
�W
w
=N
QUQ W
Wro
�w
w
SNJ
aUa W
Wm
2
_2
U
O
LUYo
aY
o'Ea
J
O
Q
~O
z
F-
O
EFF X
O
J�
Q
p
HRS
HRS
Y/N
MGD
'c
UNITS
Lb/Day
Lb/Day
mg/L
ug/L
Lb/Day
Lb/Day
Lb/Day
Lb/Day
Lb/ -ay'
1
0800
24
B
0.828SEP,n
2
0800
24
Y
1.096
3
0800
24 `1
1 0.979
4
0800
24
1
1 1.006
5
0800
24
Y
1 0.944
30 .
' 7.81
15.7
37.8
6
o800
24
Y
1 0.881
30
7.80
<14.7
<36.7
7 `
0800
24
Y ."
. 0.948 `
29"'
7.86
63.3
<39.5
<5 0
7i.05
0:0004
`<0 04:
0.05'
0.09
0.28
8
o800
24
Y
0.923
9
o800
24
Y
1.055`
10
o800
24
0.899
11
0800
24
0.874.,
12
o800
24
Y
0.746
30
7.82
39.8
24.3
13
0800
24
Y
0.991
30
7.74
23.1
<41.3
14
0800
24
Y
1.007
30
7.79
26.0
<42.0
15
0800
'24
Y
0.943
16
0800
24
Y
1.012
17
0800
24
1.150
18
0800
24
0.962
19
0800
24
Y
1.014
29
7.71
<16.9
52.4
20
o800
24
Y 1
0.871
29
7.73
14.5
40.7
21
0800
24
Y 1
1.144,
28 '
7.77
21.0
<47.7
22
0800
24
Y
0.998
23
0800
24
Y
0.948
24
0800
24
0.947
25
0800
24
0.990
26
0800
24
Y
1.093
28
7.74
<18.2
72.9
27
0800
24 1
Y
1.009 ,`
28
7.69
26.4
124.5
28
0800
24 1
Y
1.230
29
7.05
32.8
158.0
29
0800
24
Y
1.222
30
0800
24
Y
0.978
31
0800
24 °1
1.004
AVERAGE
0.990
29
21.9
42.6
0
0
0.00
0
0.05
0.09
0.28
MAXIMUM
` 1.230
30
7.86
63.3
158.0
<5.0
0
0.00
<0.04
0.05
0.09
0.28
MINIMUM
0.746
28
7.05
14.5
24.3
<5.0
0
0.00
<0.04
0.05
0.09
0.28
Comp. (C) Grab (G)
G
G
C
C
G
G
G
G
G
G
G
Monthly Limit
2.0
182.6
303.1
1
1
0.113
8.36
10.91
12.72
7.90
Daily Limit'
6-9 1484.71
981.51
1
0.5 1
120.85
125.44
1
29.96'
19.65
)FFICE
DEM Form MR-1 (12193)
DEQ-CFW 00060449

. yam•, a`S
a
Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Ellis H. McGaugh - Plant M4pager
Per ittee (Please print or'65
ty
ignature o Permi ee D to
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332 [phone] October 31, 2016
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080 Color (Pt -Co)
00082 Color (ADM[)
00095
Conductivity
00300
Dissolved Oxygen
00310
BOD5
00340
COD
00400
pH
00530
Total Suspended
Residue
00545
Settleable Matter
00610 Ammonia Nitrogen
00625 Total Kjeldhal
Nitrogen
00630 Nitrates/Nitrites
00665
Total Phosphorous
00720
Cyanide
00745
Total Sulfide
00927
Total Magnesium
00929
Total Sodium
00940
Total Chloride
01027 Cadmium
01032 Hexavalent Chromium
01034 Chromium
01037 Total Cobalt
01042 Copper
01045 Iron
01051 Lead
01092 Zinc
01105 Aluminum
01147 Total Selenium
31616
Fecal Coliform
32730
Total Phenolics
34235
Benzene
34481
Toluene
38260
MBAS
39516
PCB's
50050 Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B)
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
DEQ-CFW 00060450

EFFLUENT OCT 3 - 2013
NPDES PERMIT NO. NC0003573 DISCHARGE NO. 002 MONTH August YEAR 2013
FACILITY NAME DuPont - Fayetteville Works CLASS 3 COUNTY Bladen
OPERATOR IN RESPONSIBLE CHARGE (ORC) Jamie R. Lewis GRADE 4 PHONE [phone]
CERTIFIED LABORATORIES (1) TBL Laboratory (Lumberton) (2)
CHECK BOX IF ORC HAS CHANGED PERSON(S) COLLECTING SAMPLES Jamie R. Lewis / Arnold Ray Beard
Mail ORIGINAL and ONE COPY to:
ATTN: CENTRAL FILES
DIV. OF WATER QUALITY
DENR
1617 MAIL SERVICE CENTER
RALEIGH, NC 27699-1617
X
(SIGNAT E OF OPERATOR IN RESPONSIBLE CHARGE)
BY THIS SIGNATURE, I CERTIFY THAT THE REPORT IS
ACCURATE AND COMPLETE TO THE BEST OF MY KNOWLEDGE
DATE
p
e
i= o
4disov
N
0
u-,Lu
o
d
o`
0Q.
o
0
ce
o
50060
00010
00400
00310
00340
00951
51521
00665
1 00600
TGP36
FLOW
i
~�
IIJQ
aW
Wv
~
L
0
N
p
o
U
U.dW
0
ZOaZP
LL
x¢
0
o
o
oC7
a
m
x
n
apV
ozINf
_wX
v
0
P
EFF X
JW
¢�
0
HRS
HRS
Y/N
MGD
*C
UNITS
mg/L
mg/L
mg/L
ug/L
mg/L
mg/L
P/F
1
0800
24
B
19.937 '
31
7.45
2
0800
24
Y
20.720
31
7.39
3
0800
24
20.664
4
0800
24
20.597
5
0800
24
Y
. 19.003 ,
31
7.20
6
0800
24
Y
1 17.933
31
7.11
<2.0
<30.0
0.69
1.75
7 .
0800
24
, Y'-
`•20.269
30
7.39
8
0800
24
Y
20.415
29
7.35
9
0800
24
Y
21.830
29 `
7.31
10
0800
24
23.681
11
0800
24
19.998
12
0800
24
Y
21.607
32
7.29
P
13
0800
24
Y
24.255
32
7.20
14
0800
24
Y
23.057
31
7.19
0.034
15
0800
24 '
Y
23.606
30
7.22
16
0800
24
Y
23.085
30
7.31
17
0800
24
24.721
18
0800
24
20.887
19'
0800
24.
Y
19.220
29
7.10
20
0800
24
Y
14.260
29
7.22
21
0800
.24
Y '
' 21.366
28 ,
7.30
22
0800
24
Y
21.256
28
7.27
23
o800
24 `
Y
19.670
29
7.29
24
0800
24
22.441
25
0800
24
15.550
26
0800
24
Y
17.415
28
7.30
27
0800
24 :
Y
15.281"
28 ':
7.29
28
0800
24
Y
18.491
29
7.48
10.0
29
0800
24
Y
17.571 `
29
7.45
30
0800
24
Y
16.556
29
7.40
31
0800
24
17.415
AVERAGE
20.089
30
0.0
0.0
10.0
0.034
0.69
1.75
P
MAXIMUM
24.721
32
7.48
<2
<30
10.0
0.034
0.69
1.75
P
MINIMUM
14.260
28
7.10
<2
<30
10.0
0.034
0.69
1.75
P
Comp. (C) Grab (G)
G
G
G
C
G
G
C
C
C
Monthly Limit
Daily Limit
6-9
DEM Form MR-1 (12/93)
DEQ-CFW 00060451

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Ellis H. McGaughy - Plant
PeAnittee (Please print or b
of
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332 (910) 6"315 October 31, 2016
Permittee Address Phone Number Permit Exp. Date
PARAMETER CODES
00010 Temperature 00556 Oil & Grease 00951 Total Fluoride 01067 Nickel 50060 Total
00076 Turbidity 00600 Total Nitrogen 01002 Total Arsenic 01077 Silver Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
00082
Color (ADM[)
00625
Total Kjeldhal
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
00300
Dissolved Oxygen
00310
BOD5
00665
Total Phosphorous
00340
COD
00720
Cyanide
00400
pH
00745
Total Sulfide
00530
Total Suspended
00927
Total Magnesium
Residue
00929
Total Sodium
00545
Settleable Matter
00940
Total Chloride
01027 Cadmium
01032
Hexavalent Chromium
01034
Chromium
01037
Total Cobalt
01042
Copper
01045
Iron
01051
Lead
01092 Zinc
01105 Aluminum
01147 Total Selenium
31616 Fecal Coliform
32730 Total Phenolics
34235 Benzene
34481 Toluene
38260 MBAS
39516 PCB's
50050 Flow
Chlorine
71880 Formaldehyde
71900 Mercury
81551 Xylene
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 26.0506
(b) (2) (D)
DEQ-CFW 00060452

w-Ffi„ent mnx;_eity Renort Form - Chronic Pass/Fail and Acute LC50 Date: 08/22/13
Facility: DUPONT FAYETTEVILLE WORKS NPDES#: NC0003573 Pipe#: 002 County: BLADEN
Laboratory Perfprming Test: MERITECH LABS, INC.
#InComments :
ure o
- I * PASSED: 3.33% Reduction *
Work Order: Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
Vorth Carolina Ceriodaphnia
Chronic Pass/Fail Reproduction Toxicity Test
�ONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
# Young Produced
18
23
21
23120120
21
16
22
19
18
19
Adult (L) ive (D) ead
L
IL
L
L
L
L
L
L
L
L
L
L
affluent %: 3.3%
CREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12
## Young Produced
21
20
21
20
19120113
16
20
20
21
21
Adult (L) ive (D) ead
L
L
L
L
L
L
L
L
L
L
L
L
1st sample 1st sample 2nd sample
PH
Control 8.09 7.77 7.87 7.97 8.02 7.87
Treatment 2 7.89 7.7-97.87 7.88 7.90 7.91
s s s
t e t e t e
a n a n a n
r d r d r d
t t t
1st sample 1st sample 2nd sample
D.O.
Control 7.70 7.64 7.84 7.70 7.81 7.44
Treatment 2 7.75 7.61 7.87 7.66 7.99 7.47
LC50/Acute Toxicity Test
(Mortality expressed as combining replicates)
Chronic Test Results
Calculated t = 0.715
Tabular t = 2.508
Reduction = 3.33
Mortality
Avg.Reprod.
0.00
20.00
Control
Control
0.00
19.33
Treatment 2
Treatment 2
Control CV
10.6600 PASS FAIL
control orgs X
producing 3rd
brood Check One
100%
Complete This For Either Test
Test Start Date: 08/14/13
Collection (Start) Date
Sample 1: 08/12/13 Sample 2: 08/14/13
Sample Type/Duration 2nd
1st P/F
Grab Comp. Duration D
I S S
Sample 1 X 24 hrs L A A
U M M
Sample 2 X 24 hrs T P P
Hardness (mg/1) 48 ........ .........
Spec. Cond.(pmhos) 161 370 493
Chlorine (mg/1) ........ <0.1 <0. 1
Sample temp. at receipt(°C) ........ 0.5 0.7
%
%
°
°
%
°
Note: Please
Concentration Complete This
Section Also
Mortality
start/end start/end
LC50 = % Method of Determination
95% Con 1 ence Limits Moving Average _ Probit
-- % Spearman Karber _ Other
Control
High
PH
Organism Tested: Ceriodaphnia dubia Duration(hrs):
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
DEQ-CFW 00060453

NPDES NO: NC0003573 DISCHARGE NO: 002 MONTH: August YEAR: 2013
FACILITY: DuPont - Fayetteville Works COUNTY: Bladen
STREAM: Cape Fear River STREAM: Cape Fear River
LOCATION: DuPont River Pump Station LOCATION: Boat Ramp - 4500 ft below Prospect Hall Landing
UPSTREAM DOWNSTREAM
j�6
•
u
•
�
DWQ Form MR-3 (Revised 7/2000)
is
ca
Y
U
U
o
T
m
E
00010
00400
00310
00610
00530
00094
w
rn
a w
y
m U
a`)
E
I"-
2
Ca.
)
o
>,
m
v
�
m
a
x
a
a)
>
U
af6i
° E
�j
f6 E
>
o
U
FIRS
°C
units
mg/L
mg/L
#/100mi
µmho/cm
1
2
3'
4
5
6
7
10
11
12
13
14
15,
16
17
18
19
20
21
22
23.
24
25,
26
27
28
29
30
31
Average
Maximum
Minimum
DEQ-CFW 00060454

Facility Status: (Please check one of the following)
All monitoring data and sampling frequencies meet permit requirements 0
Compliant
All monitoring data and sampling frequencies do NOT meet permit requirements
Noncompliant
If the facility is noncompliant, please comment on corrective actions being taken in respect to equipment, operation,
maintenance, etc., and a time table for improvements to be made.
"I certify, under penalty of law, that this document and all attachments were prepared under my direction or
supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate
the information submitted. Based on my inquiry of the person or persons who manage the system, or those
persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief,
true, accurate, and complete. I am aware that there are significant penalties for submitting false information,
including the possibility of fines and imprisonment for knowing violations."
Ellis H. McGau
22828 NC Hwy 87 W, Fayetteville, NC, 28306-7332
(9L1V67$=1315
October 31, 2016
Permittee Address
Phone Number
Permit Exp. Date
PARAMETER CODES
00010
Temperature
00556
Oil & Grease
00951
Total Fluoride
01067 Nickel
50060
Total
00076
Turbidity
00600
Total Nitrogen
01002
Total Arsenic
01077 Silver
Residual
00080
Color (Pt -Co)
00610
Ammonia Nitrogen
01092 Zinc
Chlorine
00082
Color (ADMI)
00625
Total Kjeldhal
01027
Cadmium
01105 Aluminum
Nitrogen
00095
Conductivity
00630
Nitrates/Nitrites
01032
Hexavalent Chromium
01147 Total Selenium
71880
Formaldehyde
00300
Dissolved Oxygen
01034
Chromium
31616 Fecal Coliform
71900
Mercury
00310
BOD5
00665
Total Phosphorous
32730 Total Phenolics
81551
Xylene
00340
COD
00720
Cyanide
01037
Total Cobalt
34235 Benzene
00400
pH
00745
Total Sulfide
01042
Copper
34481 Toluene
00530
Total Suspended
00927
Total Magnesium
38260 MBAS
Residue
00929
Total Sodium
01045
Iron
39516 PCB's
00545
Settleable Matter
00940
Total Chloride
01051
Lead
50050 Flow
Parameter Code assitance may be obtained by calling the Water Quality Compliance Group at [phone], extension 581 or 534
The monthly average for fecal coliform is to be reported as a GEOMETRIC mean. Use only units designated in the reporting
facility's permit for reporting data
* ORC must visit facility and document visitation of facility as required per 15A NCAC 8A .0202 (b) (5) (B).
** If signed by other than the premittee, delegation of signatory authority must be on file with the state per 15A NCAC 2B .0506
(b) (2) (D)
DEQ-CFW 00060455