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HomeMy WebLinkAboutNC0003468_Other Correspondence_20181015 S V MC* �` thrt DUKE �0! ►� Dan River Combined Cycle ENERGY® Duke Energy Carolinas 864 S Edgewood Road Eden, NC 27288 October 15, 2018 Mr.Jeffrey 0.Poupart North Carolina Department of Environmental Quality 1617 Mail Service Center Raleigh. NC 27699-1617 Subject: Duke Energy Carolinas, LLC Dan River Combined Cycle Station NPDES Permit: NC0003468 Rockingham County Dear Mr. Poupart: On June 18th, 2018, Duke Energy Carolinas, LLC (Duke Energy) provided notification that discharge of interstitial water was commencing at the subject facility. This notification was submitted in accordance with the terms of the facility's NPDES permit. Duke Energy hereby submits notice that a new treatment system is being installed to treat interstitial water for release. We anticipate that the new system will produce effluent similar to the previous supplemental treatment system described in the June 18th letter. The new system will also allow for a higher flow volume to be treated. The new system will be capable of treating 750 gpm (1.08 MGD if used continuous for a 24 hour day). This flow volume is significantly less than the 1.5 MGD used by the Division in permitting and Reasonable Potential Analysis calculations. The purpose of this letter is to provide notification of the planned temporary changes and a description of this additional treatment process for your information and files. Duke Energy plans to begin release of this water on November 1, 2018. This letter serves as both our submittal of plans describing the treatment technologies but also our required notification at least one week prior to commencement of the discharge found in Section A.(4) on page 8 of 22 of our NPDES permit. As you are aware, the historic wastewater treatment system for wastewater flows from Dan River's former coal generating facility consist of sedimentation and neutralization process provided by the two site ash basins. That wastewater treatment system will be temporarily supplemented to include the following additional treatment: • Reaction tank for chemical addition and equalization (oxidation & pH adjustment) • RapidsandTM ballasted flocculating clarifier • Horizontal pressure filter The treated effluent from the expanded wastewater treatment system will be routed to Dan River through temporary piping to the permitted outfall 002 location. Any process wastes flows (such backwash processes) resulting from this additional treatment will be recycled to the ash basin. Sludge will be collected and properly disposed of in the onsite landfill. The vendor selected to provide the temporary units will be providing additional operational support staff for the R :4 °.1.1t,; treatment equipment. SDS sheets for chemicals proposed to be used in the process are attached to this submittal along with a simplified process flow diagram. In accordance with NCGS 143-215(a6) and because all activity is authorized under the facility's existing NPDES permit, no authorization to construct is required to be issued before the temporary systems can be utilized and no NPDES permit modification is necessary. Duke Energy remains committed to safely closing ash basins at all of our North Carolina sites. We look forward to continuing to work with your agency i n a collaborative manner to facilitate this work. If there are any questions, please feel free to contact Joyce Dishmon at Joyce.Dishmon@duke-energy.com or (336) 623-0238.` I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system. or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief true, accurate, and complete I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonmentfor knowing violations. Sincerely, el / ,7 7p744. Michael Lanning GM II-Regulated Stations Dan River Combined Cycle Power Generating Carolinas East Attachments Cc: Julie Gryzb - w/attachments NC DWR 1617 Mail Service Center Raleigh, NC 27699-1617 Sherri Knight- w/attachments WSRO 450 West Hanes Mill Road Winston-Salem.NC 27105 Richard Baker-w/attachments-via email Shannon Langley - w/attachments -via email Dana Newcomb - w/attachments,ORC Joyce Dishmon/Filenet- w/attachments Duke Energy Carolinas, LLC NPDES Permit NC0003468 Dan River Combined Cycle Station Interstitial Water Treatment Flow Chart Mobile SECONDARY Interstitial Water — Reaction/Feed BASIN tank 0 -0 opt�o�a� Undertow--- Ballasted PRIMARY }nterst�t�a}Water Blo�,down Flocculating Clarifier BASIN eac kH'ash Pressure Filter Outfall 002 to Dan River 4 � • ATS Y ,:.. ALPINE TECHNICAL SERVICES Yk,PSk':':iY Material Safety Data Sheet ATS-AE-150 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY Product name. ATS-AE-150 Company: Alpine Technical Services 601 Nest 6825 South Midvale. UT 84047 Telephone: 801-255-5336 Telefax: 801-255-0486 Emergency telephone number. Chem-1 el 800-255-3924 Product Use Processing aid for industrial applications 2 HAZARDS IDENTIFICATION Appearance and Odor I orm: Viscous liquid Color: Milky Odor: Aliphatic Emeraencv Overview. Spills produce extremely slippery surfaces 3 COMPOSITIONIINFORMATION ON INGREDIENTS Identification Anionic water-soluble polymer in emulsion 4 FIRST AID MEASURES Inhalation:No hazards which require special first aid measures. Skin contact: Nash off immediately with soap and plenty of water. In case of persistent skin irritation,consult a physician Eye contact- Rinse thoroughly with plenty of water. also under the eyelids. In case of persistent eye irritation.consult a physician Ingestion. The product is not considered toxic based on studies on laboratory animals. Alpine Technical Services, 601 West 6825 South, Midvale, Utah 84047-1047 April 18,2011 • a 6 sEivi 5 FIRE-FIGHTING MEASURES Suitable extinguishing media. Water Water spray Foam.Carbon dioxide(CO2). Dry powder. Precautions: Spills produce extremely slippery surfaces. Special protective equipment for firelighters: No special protective equipment required Flash point• Does not flash. Autoignition temperature: Does not ignite 6.ACCIDENTAL RELEASE MEASURES Personal precautions. No special precautions required. knvnonmental precautions: Do not contaminate water. Methods for cleaning up • Do not Ilush with water Dam up Soak up with inert absorbent material. IF liquid has been spilt in laige quantities clean up promptly by scoop or ti acuum. Keep in suitable and closed containers for disposal After cleaning.flush away traces with water. 7.HANDLING AND STORAGE I kindling Safe handling advice: Avoid contact with skin and eyes. When prepanng the woiking solution ensuie there is adequate ventilation When using do not smoke. Storage Keep in a dry cool place(0-30°C). Freciing will affect the physical condition and may damage the material 8 EXPOSURE CONTROLS/PERSONAL PROTECTION I:ngincering measures Use local exhaust if misting occurs.Natural ventilation is adequate in absence of mists. Personal protective equipment: Respiratory protection: In case of insufficient ventilation wear suitable respiratory equipment. I land protection. Rubber gloves. Eye protection: Safety glasses with side-shields. Do not wear contact lenses where this product is used. Skin and body protection. Chemical resistant apron or protective suit if splashing or repeated contact with solution is likely. Alpine Technical Services, 601 West 6825 South, Midvale, Utah 84047-1047 April 18,2011 ATS ALPINE Hygiene measures Wash hands and face before breaks and immediately after handling the product Handle in accordance with good industrial hygiene and safety pi actice Alpine Technical Services, 601 West 6825 South, Midvale, Utah 84047-1047 April 18,2011 NIC SERVICES v 9.PHYSICAL AND CHEMICAL PROPERTIES Poria Viscous liquid Color. Milky Odor. Aliphatic p11 : 6- 8@5c/I Melting point/range Not applicable Flash point: Does not flash Autoignition tempeiature Does not ignite Appiox bulk density• 1.05 Wates solubility: Sec"Technical Bulletin I 0 STABILITY AND REACTIVITY Stability: Stable l laiaidons polymerisation docs not occur. Materials to avoid. Oxidizing agents may cause exothermic reactions. 11a/ill-thus decomposition products. [hernial decomposition may produce Carbon oxides(COx). Nitrogen oxides(NOx) Alpine Technical Services, 601 West 6825 South, Midvale, Utah 84047-1047 April 18,2011 • ATS ALPINE TECHNICAL SERVICES 11 TOXICOLOGICAL INFORMATION Acute toxicit), Skin: The product is not expected to he toxic. Oral: LD50/oral/rat>5000 mg/kg. Inhalation. The product is not expected to be toxic by inhalation. Irritation Skin. May cause skin irritation with susceptible persons Eyes: May cause eye in itation with susceptible pet sons Sensitization- The product is not expected to be sensitizing. Chronic toxicity: Prolonged skin contact may deiat the skin and produce dermatitis. 12 ECOLOGICAL INFORMATION Aquatic toxicity 1oxicity to fish: LC50/96 hours> 100 mg/I (OECD 203).Toxicity to daphnia. EC50/48 hours> 100 mg/1(OECD 202). Toxicity to algae 1C50/Scenedesmus subspicatus/72 hours> 100 mpg/I (OECD 201) Environmental fate Persistence and degradability : Not readily biodegradable Hydrolysis- Does not hydrolyse. 13 DISPOSAL CONSIDERATIONS Disposal: In accordance with local, state and federal regulations. Container Rinse empty containers with water and use the rinse water to prepare the working solution.Can he landfilled or incineiated. when in compliance with local, state and federal regulations. 14 TRANSPORT INFORMATION DOT Dot status: Not classified as dangerous in the meaning of DOT regulations Alpine Technical Services, 601 West 6825 South, Midvale, Utah 84047-1047 April 18,2011 KIS 1MDG/l MO Remarks:Not classrlied as dangerous in the meaning of IMO/1MDG regulations. ICAO/IATA Remarks. Not classified as dangerous in the meaning of1CAO/IATA regulations 15 REGULATORY INFORMATION International Inventor res Futopean Union(EINECS/ELINCS) : All components of this product arc eithei listed on the inventory or are exempt from listing USA('TSCA) : All components of this product are eithei listed on the inventory or arc exempt from listing. Canada(DSL) . All components of this product are either listed on the inventory or are exempt from listing. Austialia(AICS) : All components of this product are either listed on the inventory or are exempt from listing. China(IECSC) :All components of this product arc either listed on the inventory or arc exempt from listing Japan (ENCS) All components of this product are either li-zfe�d on the inventory or are exempt from listing Korea(ECL) : All components of this product are either listed on the inventory or are exempt Irum listing Philippines(PICCS) • All components of this product are either listed on the inventory or are exempt from listing Alpine Technical Services, 601 West 6825 South, Midvale, Utah 84047-1047 April 18,2011 -- - - - - - - - --- - - - - - - - - ---- -- -- - - - ATS Pftisio ALPINE TECHNICAL SERVICES 0040.0 16.OTHER INFORMATION NEPA and HMIS Ratints. NFPA I-lealth : 1 1'Ianimabil,t . Instabillt\ • 0 HMIS: I lealth • I Flat nabilit\ • I Ph\sical I lazard. 0 I lie dat t in this\fatenal Data Sheet relates onl} to the speulic matzo tl desr_nated heten,and doe,not',late to use III Combination iS rth an:,other mate:.tl ut in art.ptoses, "I ht,information is based upon technical mlbnnattoa belies ed to he reliable It"subject to tes"ron a,additional Icnov.I dge and.spertenee is seamed "Ilii,mtotmattonba-ed up, t technical information belies ed to be It is subject to tr„,con as additional l.nms ledge and e\penence t,cam:d Alpine Technical Services, 601 West 6825 South, Midvale, Utah 84047-1047 April 18,2011 Alpine Technical Services, 601 West 6825 South, Midvale, Utah 84047-1047 Product#: 138874 From. BRENNTAG MID-SOUTH INC. To: Thursday,October 11,2018 BRENNTAGMM-: SAFETY DATA SHEET 1. Identification Product identifier BRENNFLOC CP 98116 Other means of identification None Recommended use ALL PROPER AND LEGAL PURPOSES Recommended restrictions None known Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Brenntag Mid-South, Inc Address 1405 Highway 136,West Henderson, KY 42420 Telephone 270-830-1222 E-mail Not available. Emergency phone number 800-424-9300 CHEMTREC 2. Hazard(s) identification Physical hazards Not classified. Health hazards Sensitization,skin Category 1 Germ cell mutagenicity Category 1 Carcinogenicity Category 1 Reproductive toxicity Category 1 Aspiration hazard Category 1 Environmental hazards Not classified OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement May be fatal if swallowed and enters airways. May cause an allergic skin reaction May cause genetic defects May cause cancer. May damage fertility or the unborn child Precautionary statement Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood,Avoid breathing mist or vapor Contaminated work clothing must not be allowed out of the workplace Wear protective gloves/protective clothing/eye protection/face protection. Response If swallowed. Immediately call a poison center/doctor Do NOT induce vomiting If on skin. Wash with plenty of water If exposed or concerned. Get medical advice/attention If skin irritation or rash occurs' Get medical advice/attention Wash contaminated clothing before reuse Storage Store locked up Disposal Dispose of contents/container in accordance with local/regional/national/international regulations Hazard(s)not otherwise Combustible classified (HNOC) Supplemental information 64 8%of the mixture consists of component(s)of unknown acute oral toxicity 64 8%of the mixture consists of component(s)of unknown acute dermal toxicity, 99.9%of the mixture consists of component(s)of unknown acute inhalation toxicity. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number TRADE SECRET' Proprietary* 25 Material name BRENNFLOC CP 98116 sos us 138874 Version#.02 Revision date'10-11-2018 Issue date-02-22-2018 1 /8 'roduct#: 138874 From BRENNTAG MID-SOUTH INC. To. Thursday, October 11, 2018 Chemical name Common name and synonyms CAS number % TRADE SECRET' Proprietary* 0 1 Other components below reportable levels 74 9 'Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret 4. First-aid measures Inhalation Move to fresh air Call a physician if symptoms develop or persist Skin contact Remove contaminated clothing immediately and wash skin with soap and water In case of eczema or other skin disorders Seek medical attention and take along these instructions Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Most important Aspiration may cause pulmonary edema and pneumonitis May cause an allergic skin reaction symptoms/effects,acute and Dermatitis Rash delayed Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation medical attention and special Symptoms may be delayed treatment needed General information IF exposed or concerned. Get medical advice/attention If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves Show this safety data sheet to the doctor in attendance.Wash contaminated clothing before reuse. 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Powder. Dry chemicals. Carbon dioxide (CO2) Unsuitable extinguishing Do not use water jet as an extinguisher,as this will spread the fire. media Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire fighting Cool containers exposed to heat with water spray and remove container, if no risk is involved equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Combustible No unusual fire or explosion hazards noted 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak Wear protective equipment and appropriate protective equipment and clothing during clean-up Avoid breathing mist or vapor. Do emergency procedures not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation Local authorities should be advised if significant spillages cannot be contained For personal protection, see section 8 of the SDS Methods and materials for Use water spray to reduce vapors or divert vapor cloud drift. Prevent entry into waterways,sewer, containment and cleaning up basements or confined areas Large Spills Stop the flow of material, if this is without risk. Dike the spilled material,where this is possible Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water Small Spills:Wipe up with absorbent material(e.g cloth, fleece) Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. Put material in suitable,covered, labeled containers. For waste disposal, see section 13 of the SDS. For waste disposal, see section 13 of the SDS Environmental precautions Avoid discharge into drains,water courses or onto the ground Material name BRENNFLOC CP 98116 sos us 138874 Version#:02 Revision date 10-11-2018 Issue date:02-22-2018 2/8 • Product#: 138874 From: BRENNTAG MED-SOUTH INC To• Thursday, October 11,2018 • 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.Avoid breathing mist or vapor.Avoid contact with eyes, skin, and clothing Avoid prolonged or repeated contact with skin Avoid prolonged exposure Pregnant or breastfeeding women must not handle this product Should be handled in closed systems,if possible. Use only in well-ventilated areas Wear appropriate personal protective equipment Wash hands thoroughly after handling. Observe good industrial hygiene practices Conditions for safe storage, Store locked up Keep away from heat and sources of ignition. Store in original tightly closed including any incompatibilities container Store away from incompatible materials(see Section 10 of the SDS). Store away from incompatible materials(see Section 10 of the SDS) 8. Exposure controls/personal protection Occupational exposure limits US.OSHA Table Z-1 Limits for Air Contaminants(29 CFR 1910.1000) Components Type Value TRADE SECRET PEL 0.3 mg/m3 US.ACGIH Threshold Limit Values Components Type Value Form TRADE SECRET TWA 0.03 mg/m3 Inhalable fraction and vapor. US.NIOSH: Pocket Guide to Chemical Hazards Components Type Value TRADE SECRET TWA 0.03 mg/m3 Biological limit values No biological exposure limits noted for the ingredient(s) Exposure guidelines US-California OELs: Skin designation TRADE SECRET(CAS Proprietary) Can be absorbed through the skin US-Minnesota Haz Subs:Skin designation applies TRADE SECRET(CAS Proprietary) Skin designation applies US-Tennessee OELs:Skin designation TRADE SECRET(CAS Proprietary) Can be absorbed through the skin. US ACGIH Threshold Limit Values:Skin designation TRADE SECRET(CAS Proprietary) Can be absorbed through the skin US NIOSH Pocket Guide to Chemical Hazards: Skin designation TRADE SECRET(CAS Proprietary) Can be absorbed through the skin US.OSHA Table Z-1 Limits for Air Contaminants(29 CFR 1910.1000) TRADE SECRET(CAS Proprietary) Can be absorbed through the skin Appropriate engineering Good general ventilation(typically 10 air changes per hour)should be used.Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits If exposure limits have not been established,maintain airborne levels to an acceptable level Individual protection measures,such as personal protective equipment The following are recommendations for Personnel Protective Equipment(PPE).The employer/user of this product must perform a Hazard Assessment of the workplace according to OSHA regulations 29 CFR 1910 132 to determine the appropriate PPE for use while performing any task involving potential exposure to this product Eye/face protection Chemical respirator with organic vapor cartridge and full facepiece Skin protection Hand protection Wear appropriate chemical resistant gloves Suitable gloves can be recommended by the glove supplier. Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Respiratory protection Chemical respirator with organic vapor cartridge and full facepiece. Thermal hazards Wear appropriate thermal protective clothing,when necessary. General hygiene Observe any medical surveillance requirements Always observe good personal hygiene considerations measures,such as washing after handling the material and before eating, drinking,and/or smoking Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace Material name BRENNFLOC CP 98116 sos us 138874 Version#:02 Revision date:10-11-2018 Issue date.02-22-2018 3/8 'roduct#• 138874 From. BRENNTAG MID-SOUTH INC To Thursday,October 11,2018 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color MILKY Odor ALIPHATIC Odor threshold Not available pH Not available Melting point/freezing point 41 °F (5 °C) Initial boiling point and boiling 212 47°F (100 26°C)estimated range Flash point Not available Evaporation rate Not available Flammability(solid,gas) Not applicable. Upper/lower flammability or explosive limits Flammability limit-lower Not available (%) Flammability limit-upper Not available (%) Explosive limit-lower(%) Not available Explosive limit-upper(%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density Not available. Solubility(ies) Solubility(water) Not available Partition coefficient Not available (n-octanol/water) Auto-ignition temperature Not available Decomposition temperature Not available. Viscosity Not available Other information Density 8 18 lbs/gal Explosive properties Not explosive Oxidizing properties Not oxidizing Percent volatile 35 1 %estimated Specific gravity 0.98 VOC 0 05 %estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use,storage and transport. Chemical stability Material is stable under normal conditions Possibility of hazardous No dangerous reaction known under conditions of normal use. reactions Conditions to avoid Contact with incompatible materials Incompatible materials Strong oxidizing agents Hazardous decomposition Toxic gas. products 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Material name BRENNFLOC CP 98116 sos us 138874 Version#.02 Revision date-10-11-2018 Issue date_02-22-2018 4/8 Product#. 138874 From: BRENNTAG MID-SOUTH INC To. Thursday, October 11,2018 Skin contact May cause an allergic skin reaction. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia Symptoms related to the Aspiration may cause pulmonary edema and pneumonitis May cause an allergic skin reaction physical,chemical and Dermatitis. Rash. toxicological characteristics Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation Serious eye damage/eye Direct contact with eyes may cause temporary irritation irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization May cause an allergic skin reaction Germ cell mutagenicity May cause genetic defects Carcinogenicity May cause cancer. IARC Monographs.Overall Evaluation of Carcinogenicity TRADE SECRET(CAS Proprietary) 2A Probably carcinogenic to humans OSHA Specifically Regulated Substances(29 CFR 1910.1001-1052) Not regulated, US.National Toxicology Program(NTP) Report on Carcinogens TRADE SECRET(CAS Proprietary) Reasonably Anticipated to be a Human Carcinogen. Reproductive toxicity May damage fertility or the unborn child Specific target organ toxicity- Not classified single exposure Specific target organ toxicity- Not classified. repeated exposure Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous However,this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Test Results TRADE SECRET Aquatic Fish LC50 Fathead minnow(Pimephales promelas) 77-160 mg/I,96 hours Rainbow trout,donaldson trout 2.9 mg/I,96 hours (Oncorhynchus mykiss) Persistence and degradability No data is available on the degradability of any ingredients in the mixture. Bioaccumulative potential Partition coefficient n-octanol/water(log Kow) TRADE SECRET -0.67 Mobility in soil No data available. Other adverse effects No other adverse environmental effects(e.g.ozone depletion, photochemical ozone creation potential,endocrine disruption, global warming potential) are expected from this component 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations Local disposal regulations Dispose in accordance with all applicable regulations Hazardous waste code The waste code should be assigned in discussion between the user,the producer and the waste disposal company. Material name.BRENNFLOC CP 98116 sos us 138874 Version#:02 Revision date.10-11-2018 Issue date.02-22-2018 5/8 rocluct#. 138874 From. BRENNTAG MTD-SOUTH INC. To: Thursday,October 11,2018 • Waste from residues/unused Dispose of in accordance with local regulations Empty containers or liners may retain some products product residues This material and its container must be disposed of in a safe manner(see Disposal instructions). Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is emptied Empty containers should be taken to an approved waste handling site for recycling or disposal 14. Transport information DOT Not regulated as dangerous goods. Transport information on packaging may be different from that listed Transportation information on packaging may be different from that listed. IATA Not regulated as dangerous goods. IMDG UN number UN3082 UN proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N 0 S (TRADE SECRET), MARINE POLLUTANT Transport hazard class(es) Class 9 Subsidiary risk - Packing group II I Environmental hazards Marine pollutant Yes EmS F-A, S-F Special precautions for user Read safety instructions, SDS and emergency procedures before handling IMDG \ ,i Marine pollutant General information IMDG Regulated Marine Pollutant 15. Regulatory information US federal regulations This product is a"Hazardous Chemical"as defined by the OSHA Hazard Communication Standard,29 CFR 1910.1200. TSCA Section 12(b) Export Notification(40 CFR 707, Subpt.D) Not regulated CERCLA Hazardous Substance List(40 CFR 302.4) TRADE SECRET(CAS Proprietary) Listed SARA 304 Emergency release notification TRADE SECRET(CAS Proprietary) 5000 LBS OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. Material name BRENNFLOC CP 98116 sos us 138874 Version#-02 Revision date.10-11-2018 Issue date:02-22-2018 6/8 - - - - - - - - - - - - -- - - - - - - -- - - - - - Product# 138874 From BRENNTAG MID-SOUTH INC. To• Thursday, October 11,2018 Superfund Amendments and Reauthorization Act of 1986 (SARA) SARA 302 Extremely hazardous substance Chemical name CAS number Reportable Threshold Threshold Threshold quantity planning quantity planning quantity, planning quantity, (pounds) (pounds) lower value upper value (pounds) (pounds) TRADE SECRET Proprietary 5000 1000 10000 SARA 311/312 Hazardous Yes chemical Classified hazard Respiratory or skin sensitization categories Germ cell mutagenicity Carcinogenicity Reproductive toxicity Aspiration hazard SARA 313 (TRI reporting) Chemical name CAS number % by wt. TRADE SECRET Proprietary 0 1 Other federal regulations Clean Air Act(CAA)Section 112 Hazardous Air Pollutants(HAPs) List TRADE SECRET(CAS Proprietary) Clean Air Act(CAA)Section 112(r)Accidental Release Prevention (40 CFR 68.130) Not regulated Safe Drinking Water Act Not regulated (SDWA) US state regulations California Proposition 65 A WARNING: This product can expose you to TRADE SECRET,which is known to the State of California to cause cancer and birth defects or other reproductive harm. For more information go to www.P65Warnings ca gov California Proposition 65 -CRT: Listed date/Carcinogenic substance TRADE SECRET(CAS Proprietary) Listed. January 1, 1990 California Proposition 65 -CRT: Listed date/Developmental toxin TRADE SECRET(CAS Proprietary) Listed February 25 2011 California Proposition 65 -CRT: Listed date/Male reproductive toxin TRADE SECRET(CAS Proprietary) Listed February 25, 2011 US.California.Candidate Chemicals List. Safer Consumer Products Regulations(Cal.Code Regs,tit.22,69502.3, subd.(a)) TRADE SECRET(CAS Proprietary) International Inventories Country(s) or region Inventory name On inventory(yes/no)* Australia Australian Inventory of Chemical Substances(AICS) Yes Canada Domestic Substances List(DSL) Yes Canada Non-Domestic Substances List(NDSL) No China Inventory of Existing Chemical Substances in China (IECSC) Yes Europe European Inventory of Existing Commercial Chemical No Substances(EINECS) Europe European List of Notified Chemical Substances(ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List(ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) Taiwan Taiwan Toxic Chemical Substances(TCS) Yes United States& Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes 'A"Yes"indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A"No"indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s) Material name.BRENNFLOC CP 98116 SOS US 138874 Version# 02 Revision date 10-11-2018 Issue date-02-22-2018 7/8 - ------ - -- ----- roduct#. 138874 From BRENNTAG MED-SOUTH INC To. Thursday,October 11, 2018 16. Other information, including date of preparation or last revision Issue date 02-22-2018 Revision date 10-11-2018 Version# 02 H MIS®ratings Health.3* Flammability 0 Physical hazard. 0 NFPA ratings Health.0 Flammability' 0 Instability.0 Disclaimer While Brenntag believes the information contained herein to be accurate, Brenntag makes no representation or warranty,express or implied, regarding, and assumes no liability for,the accuracy or completeness of the information. The Buyer assumes all responsibility for handling, using and/or reselling the Product in accordance with applicable federal,state,and local law This SDS shall not in any way limit or preclude the operation and effect of any of the provisions of Brenntag's terms and conditions of sale Revision information This document has undergone significant changes and should be reviewed in its entirety Material name:BRENNFLOC CP 98116 SOS US 138874 Version#:02 Revision date 10-11-2018 Issue date:02-22-2018 8/8