WQ0000800_Final Permit_19960815

State of North Carolina
Department of Environs; OM,
"-health and Natural Resp-ulrc.es
Division of Water Quality
James B. Hunt, Jr., Governor
Jonathan B. Howes, Secretary. -
A. Preston Howard, Jr., P.E,, Dire oe`
Keith Johnson, President
United Piece Dye Works, L.P.
125 Dye Plant Road
Edenton, North Carolina 27932
Dear Mr. Johnson:
August 15, 1996
Subject: Permit No. WQ0000800
United Piece Dye Works, L.P.
Land Application of Wastewater Residuals
Chowan County
In accordance with your renewal request received on June 3, 1996, we are forwarding herewith
Permit No. WQ0000800, dated August 15, 1996, to the United Piece Dye Works, L.P. for the operation
of a wastewater residuals land application program.
After reviewing the annual land application report submitted by United Piece Dye Works, L.P. it
has come to the Division's attention that the permittee may not be applying its wastes at agronomic rates.
The report shows the surface application of waste on fields in January and February when the cover crop
is soybeans. Soybeans are planted approximately in June and harvested after October. Other instances
show the application of wastes on conn in September through December. Corn is not planted until
approximately April and harvested in July. Under normal circumstances, the Division recommends the
application of wastes no greater than thirty days in advance of the cover crop being planted. By applying
the wastes thirty days in advance of planting the cover crop, the full benefit of the residuals will be utilizied
by the crop. The Division encourages the continued beneficial reuse of the residuals produced by this
facility. Failure to land apply the residuals in accordance with the subject permit may subject the United
Piece Dye Works, L.P. to appropriate enforcement actions.
Please be advised of Condition No. 119 which states, "Surface applied residuals will be plowed or
disced within twenty-four (24) hours after application on lands with no cover crop established."
Please be advised of Condition No. 11 17 which states, "The Division is concerned about the high
Sodium Adsorption Ratio (SAR) found in the residuals being land applied. Appropriate measures,
including the application of gypsum to balance the ratio if necessary, shall be undertaken to ensure that the
land application sites are not damaged. In accordance with the submitted agronomist report, a sodium
(Na) loading of less than 180 pounds per acre per year shall be maintained on all land application sites."
This permit shall be effective from the date of issuance until July 31, 2001, shall void Permit No.
WQ0000800 issued January 3, 1992, and shall be subject to the conditions and limitations as specified
therein. Please pay particular attention to the monitoring and reporting requirements contained in this
permit. Failure to establish an adequate system for collecting and maintaining the required operational
information will result in future compliance problems.
If any parts, requirements, or limitations contained in this permit are unacceptable, you have the
right to request an adjudicatory hearing upon written request within thirty (30) days following receipt of
this permit. This request must be in the form of a written petition, conforming to Chapter 150B of North
Carolina General Statutes, and filed with the Office of Administrative Hearings, P.O. Drawer 27447,
Raleigh, NC 27611-7447. Unless such demands are made this permit shall be final and binding.
P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone [phone] FAX [phone]
An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper

If you need additional information concerning this matter, please contact Mr. Michael D. Allen at
[phone] extension 547.
Sincerely,
IC,
A. Prestooward, Jr., t.E.
cc: Chowan County Health Department
Law Engineering
Washington Regional Office, Water Quality Section
Washington Regional Office, Groundwater Section
Bob Cheek, Groundwater Section, Central Office
Training and Certification Unit (no revised rating)
Facilities Assessment Unit

NORTH CAROLINA
ENVIRONMENTAL MANAGEMENT COMMISSION
DEPARTMENT OF ENVIRONMENT, HEALTH AND NATURAL RESOURCES
RALEIGH
RESIDUALS LAND APPLICATION PERMIT
In accordance with the provisions of Article 21 of Chapter 143, General Statutes of North Carolina as
amended, and other applicable Laws, Rules, and Regulations
PERMISSION IS HEREBY GRANTED TO THE
United Piece Dye Works, L.P.
Chowan County
I ESI M
operation of a wastewater residuals land application program consisting of the application of 400.0 dry
tons per year of residuals from the sources listed in Condition 11 5, to approximately 47.3 acres of land in
Chowan County with no discharge of wastes to the surface waters, pursuant to the renewal request
received on Tune 3, 1996, and in conformity with the project plan, specifications, and other supporting
data subsequently filed and approved by the Department of Environment, Health and Natural Resources
and considered a part of this permit.
This permit shall be effective from the date of issuance until July 31, 2001, shall void Permit No.
WQ0000800 issued January 3, 1992, and shall be subject to the following specified conditions and
limitations:
I. PERFORMANCE STANDARDS
1. This permit shall become voidable if the soils fail to adequately assimilate the wastes and
may be rescinded unless the sites are maintained and operated in a manner which will
protect the assigned water quality standards of the surface waters and ground waters.
2. The land application program shall be effectively maintained and.operated as a non -
discharge system to prevent the discharge of any wastes resulting from the operation of this
program.
3. The issuance of this permit shall not relieve the Permittee of the responsibility for damages
to surface or groundwaters resulting from the operation of this program.
4. In the event that the land application program is not operated satisfactorily, including the
creation of nuisance conditions, the Permittee shall cease applying residuals to the sites and
take any immediate corrective actions as may be required by the Division.

5. Some of the buffers specified below may not have been included in previous permits for
this land application operation. However, any sites or fields that are included in this
permit, but were approved with different applicable buffers shall be reflagged to comply
with the below buffers. The following buffer zones shall be maintained:
a) 400 feet from residences or places of public assembly under separate ownership for
surface application method; however, the buffer zone requirement may be reduced to a
minimum of 100 feet upon written consent -of the owner and approval from the
appropriate DEM regional office,
b) 200 feet from residences or places of public assembly under separate ownership for
subsurface residual injection method; however, the buffer zone requirement may be
reduced to a minimum of 100 feet upon written consent of the owner and the
appropriate DEM regional office,
c) 100 feet from any public or private water supply source, waters classified as SA or SB,
and any Class I or Class II impounded reservoir used as a source of drinking water for
both methods,
d) 100 feet from any streams classified as WS or B, any other stream, canal, marsh or
coastal waters and any other lake or impoundment for surface application,
e) 50 feet from any streams classified as WS or B, any other stream, canal, marsh or
coastal waters and any other lake or impoundment for subsurface application,
f) 100 feet from property lines for both surface and subsurface application methods;
g) 50 feet from public right of ways for both application methods,
h) 10 feet from upslope interceptor drains and surface water diversions for both
application methods,
i) 25 feet from downslope interceptor drains, surface water diversions, groundwater
drainage systems and surface drainage ditches for both application methods.
6. A copy of this permit shall be maintained at the land application site when residuals are
being applied during the life of this permit. A spill prevention and control plan shall be
maintained in all residuals transport and application vehicles.
7. Specific residual application area boundaries shall be clearly marked on each site prior to
and during application.
8. No residuals at any time shall be stored at any application site, unless approval has been
requested and obtained from the Division of Water Quality.
9. Maximum slope for residual application shall be 10% for surface application and 1 S% for
subsurface applications.
II. OPERATION AND MAINTENANCE REQUIREMENTS
1. The facilities and application sites shall be properly maintained and operated at all times.
2. A suitable vegetative cover, as listed in condition 11 4, shall be maintained in accordance
with the crop management plan outlined by the local Extension Office of the Department of
Agriculture, or the Soil Conservation Service, or other agronomist, and approved by this
Division.
3. An acceptable pH must be maintained in the soil, residual and lime mixture, greater than
6.0, on all land application sites to insure optimum yield for the crop(s) specified below.
The agronomist shall provide information on the pH best suited for the specified crop and
the soil type.

4. The application rates shall not exceed the following for the specified crops:
Crop PAN f lb./acre/ r.
Alfalfa
200
Bermuda Grass (Hay, Pasture)
220
Blue Grass
120
Corn (Grain)
160
Corn (Silage)
200
Cotton
70
Fescue
250
Forest (Hardwood & Softwood)
75
Milo
100
Small Grain (Wheat, barley, oats)
100
Sorghum, Sudex (Pasture)
180
Sorghum, Sudex (Silage)
220
Soybeans
200
Timothy, Orchard, & Rye Grass
200
5. No residuals other than the following are hereby approved for land application in
accordance with this permit:
Permit Volume
Source _ County Number (drytons/,
United Piece Dye Works, L.P. Chowan NCO003867 400.0
b. The Iifetime heavy metal loadings shall not exceed the following for the corresponding
Cation Exchange Capacities (CEC):
Lifetime Loadings (lbs/acre)
Parameter
CEC < 5
CEC 5 - 15
CEC > 15
Lead
500
1000
2000
Zinc
250
500
1000
Copper
125
250
500
Nickel
125
250
500
Cadmium
4.5
9
18
7. Upon classification of the facility by the Certification Commission, the Permittee shall
employ a certified land application/residuals operator to be in responsible charge (ORC) of
the land application program. The operator must hold a certificate of the type classification
assigned to the land application program by the Certification Commission. The Permittee
must also employ a certified back-up operator of the appropriate type to comply with the
conditions of Title 15A NCAC 8A, .0202.
8. Adequate procedures shall be provided to prevent surface runoff from carrying any
disposed or stored residuals into any surface waters.
9. Surface applied residuals will be plowed or disced within twenty-four (24) hours after
application on lands with no cover crop established.
10. For areas that are prone to flooding or within the 100 -year flood elevation, residuals may
be applied only during periods of dry weather. The residuals must be incorporated into the
soil within twenty-four (24) hours after application.
3

11. Appropriate measures must be taken to control public access to the land application sites
during active site use and for the 12 -month period following the last residual application
event. Such controls may include the posting of signs indicating the activities being
conducted at each site.
12. Adequate provisions shall be taken to prevent wind erosion and surface runoff from
conveying pollutants from the residuals application area onto the adjacent property or into
any surface waters.
13. Residuals shall not be applied in inclement weather or until 24 hours following a rainfall
event of 112 -inch or greater in 24 hours. Any emergency residuals disposal measures must
first be approved by the Division of Water Quality.
14. Residuals shall not be applied to any land application site that is flooded, frozen or snow-
covered.
15. Residuals shall not be applied at rates greater than agronomic rates, unless authorized by
the Division.
16. Animals shall not be grazed on an application site for 30 days after residuals application.
Application sites that are to be used for grazing shall have fencing that will be used to
prevent access after each application.
17. The Division is concerned about the high Sodium Adsorption Ratio (SAR) found in the
residuals being land applied. Appropriate measures, including the application of gypsum to
balance the ratio if necessary, shall be undertaken to ensure that the land application sites
are not damaged. In accordance with the submitted agronomist report, a sodium (Na)
loading of less than 180 pounds per acre per year shall be maintained on all land application
sites.
III. MONITORING AND REPORTING REQUIREMENTS
1. Any monitoring (including groundwater, surface water, residuals, soil, or plant tissue
analyses) deemed necessary by the Division of Water Quality to insure protection of the
environment will be established and an acceptable sampling and reporting schedule shall be
followed.
2. Proper records shall be maintained by the Permittee tracking all application activities.
These records shall include, but are not necessarily limited to the following information:
a. source of residuals
b. date of residual application
c. location of residual application (site, field, or zone #)
d . method of application
e. weather conditions (sunny, cloudy, raining, etc.)
f. soil conditions
g. type of crop or crops to be grown on field
h. volume of residuals applied in gallons/acre, dry tons/acre or kilograms/hectare
i. annual and cumulative totals of dry tons/acre of residuals, annual and cumulative
pounds/acre of each heavy metal (which shall include, but not be limited to cadmium,
copper, lead, nickel, and zinc), annual pounds/acre of plant available nitrogen (PAN),
annual pounds/acre of sodium, annual pounds/acre of soil amendment (i.e. gypsum),
and annual pounds/acre of phosphorus applied to each field.
4

3. A representative annual soils analysis (Standard Soil Fertility Analysis) shall be conducted
on each site receiving residuals in the respective calendar year and the results maintained on
file by the Permittee for a minimum of five years.
The Standard Soil Fertility Analysis shall include, but is not necessarily limited to, the
following parameters:
Acidity
Calcium
Copper
Magnesium
Base Saturation (by calculation)
Cation Exchange Capacity
Manganese Potassium
Percent Humic Matter Sodium
pH Zinc
Phosphorus
The Standard Soil Fertility Analysis (see above) and an analysis for the following
pollutants shall be conducted once prior to permit renewal on soils from each site which has
received residuals during the permit cycle.
Cadmium Lead Nickel
4. A residuals analysis will be conducted quarterly from the date of permit issuance by the
Permittee and the results maintained on file by the Permittee for a minimum of five years.
If land application occurs at a frequency less than quarterly, a residuals analysis will be
required for each instance of land application. The residuals analysis shall include but is
not necessarily limited to the following parameters:
Cadmium
Nitrate -Nitrite Nitrogen
Copper
% Total Solids
Lead
pH
Nickel
Phosphorus
Zinc
Plant Available Nitrogen (by calculation)
Aluminum
Potassium
Ammonia -Nitrogen
Sodium
Calcium
TKN
Magnesium
After the residuals have been monitored for two years at the above frequency, the Permittee
may submit a request to the Division for a permit modification for the reduction of the
frequency of monitoring for pollutant concentrations and for the pathogen density
requirements, but in no case shall the frequency of monitoring be less than once per year
when residuals are applied to the land.
5. A Toxicity Characteristics Leaching Procedure (TCLP) analysis shall be conducted by the
Permittee annually. The TCLP analysis shall include the following parameters (please note
the regulatory level in mg/L in parentheses):
Arsenic (5.0)
Benzene (0.5)
Carbon tetrachloride (0.5)
Chlorobenzene (100.0)
Chromium (5.0)
m -Cresol (200.0)
Cresol (200.0)
1,4 -Dichlorobenzene (7.5)
1,1-Dichloroethylene (0.7)
Endrin (0.02)
(continued on next page)
Barium (100.0)
Cadmium (1.0)
Chlordane (0.03)
Chloroform (6.0)
o -Cresol (200.0)
p -Cresol (200.0)
2,4-D (10.0)
1,2-Dichloroethane (0.5)
2,4-Dinitrotoluene (0.13)
Heptachlor (and its hydroxide) (0.008)

Hexachlorobenzene (0.13)
Hexachloroethane (3.0)
Lindane (0.4)
Methoxychlor (10.0)
Nitrobenzene (2.0)
Pyridine (5.0)
Silver (5.0)
Toxaphene (0.5)
2,4,5 -Trichlorophenol (400.0)
2,4,5 -TP (Silvex) (1.0)
Hexachioro-1,3-butadiene (0.5)
Lead (5.0)
Mercury (0.2)
Methyl ethyl ketone (200.0)
Pentachlorophenol (100.0)
Selenium (1.0)
Tetrachloroethylene (0.7)
Trichloroethylene (0.5)
2,4,6 -Trichlorophenol (2.0)
Vinyl chloride (0.2)
6. Three copies of all required monitoring and reporting requirements as specified in
conditions 111 1, 111 2, 1113, 1114, and 1115, shall be submitted annually on or before
March 1 of the following year to the following address:
NC Division of Water Quality
Water Quality Section
Facility Assessment Unit
PO Box 29535
Raleigh, NC 27626-0535
7. Noncompliance Notification:
The Permittee shall report by telephone to the Washington Regional Office, telephone
number [phone], as soon as possible, but in no case more than 24 hours or on the
next working day following the occurrence or first knowledge of the occurrence of any of
the following:
a. Any occurrence with the land application program which results in the land application
of significant amounts of wastes which are abnormal in quantity or characteristic.
b. Any failure of the land application program resulting in a release of material to receiving
waters.
c. Any time that self-monitoring information indicates that the facility has gone out of
compliance with the conditions and limitations of this permit or the parameters on
which the system was designed.
d. Any process unit failure, due to known or unknown reasons, that render the facility
incapable of adequate residual treatment.
e. Any spillage or discharge from a vehicle or piping system transporting residuals to the
application site.
Persons reporting such occurrences by telephone shall also file a written report in letter
form within five (5) days following first knowledge of the occurrence. This report must
outline the actions taken or proposed to be taken to ensure that the problem does not recur.
IV. GROUNDWATER REQUIREMENTS
The six (6) existing monitor wells are to be designated in all future correspondence and on
all GW -59 forms as the three (3) monitor wells at the Parrish Field Site, Site No. 1: Site
No. 1 MW -1, Site No. 1 MW -2, and Site No. 1 MW -3, and the three (3) monitor wells at
the Homefeed Site, Site No. 2: Site No. 2 MW -1 (formerly MW -1 1), Site No. 2 MW -2
(formerly MW -12), and Site No. 2 MW -3 (formerly MW -13).
511

2. The six (6) existing monitor wells, Site No. 1 MW -1, Site No. 1 MW -2, Site No. 1 MW -
3, Site No. 2 MW -1 (formerly MW -11, Site No. 2 MW -2 (formerly MW -12), and Site
No. 2 MW -3 (formerly MW -13), shall be sampled every March, July, and November, for
the following parameters:
Nitrate (NO3) Total Dissolved Solids
pH Total Organic Carbon
Total Ammonia Water Levels
Volatile Organic Compounds - In November only by Method 6230D below:
Method 6230D (Capillary - Column), "Standard Methods For The Examination of
Water and Wastewater", 17th ed., 1989
The measurement of water levels must be made prior to sampling for the remaining
parameters. The depth to water in each well shall be measured from the surveyed point on
the top of the casing.
The measuring points (top of well casing) of all monitoring wells shall be surveyed to
provide the relative elevation of the measuring point for each monitoring well.
If TOC concentrations greater than 10 mg/1 are detected in any downgradient monitoring
well, additional sampling and analysis must be conducted to identify the individual
constituents comprising this TOC concentration. If the TOC concentration as measured in
the background monitor well exceeds 10 mg/l, this concentration will be taken to represent
the naturally occurring TOC concentration. Any exceedances of this naturally occurring
TOC concentration in the downgradient wells shall be subject to the additional sampling
and analysis as described above.
If any volatile organic compounds are detected by Method 6230D, then the Washington
Regional Office Groundwater Supervisor, telephone number [phone] must be
contacted immediately for further instructions regarding any additional follow-up analyses
required. The results of all initial and follow-up analyses must be submitted
simultaneously.
The results of the sampling and analysis must be received on Form GW -59 (Groundwater
Quality Monitoring: Compliance Report Form) by the Groundwater Section, Permits and
Compliance Unit, P.O. Box 29578 Raleigh, N.C. 27626-0578 on or before the last
working day of the month following the sampling month.
3. Any groundwater quality monitoring, as deemed necessary by the Division, shall be
provided.
4. The COMPLIANCE BOUNDARY for the disposal system is specified by regulations in
15A NCAC 2L, Groundwater Classifications -and Standards. The Compliance Boundary is
for the disposal system constructed after December 31, 1983 is established at either (1) 250
feet from the waste disposal area, or (2) 50 feet within the property boundary, whichever is
closest to the waste disposal area. An exceedance of Groundwater Quality Standards at or
beyond the Compliance Boundary is subject to immediate remediation action in addition to
the penalty provisions applicable under General Statute 143-215.6A(a)(1).
In accordance with 15A NCAC 2L, a REVIEW BOUNDARY is established around the
disposal systems midway between the Compliance Boundary and the perimeter of the
waste disposal area. Any exceedance of standards at the Review Boundary shall require
remediation action on the part of the permittee.
7

V. INSPECTIONS
The Permittee or his designee shall inspect the residuals storage, transport, and application
facilities to prevent malfunctions and deterioration, operator errors and discharges which
may cause or lead to the release of wastes to the environment, a threat to human health, or a
nuisance. The Permittee shall maintain an inspection log or summary including at least the
date and time of inspection, observations made, and any maintenance, repairs, or corrective
actions taken by the Permittee. This log of inspections shall be maintained by the Permittee
for a period of five years from the date of the inspection and shall be made available to the
Division of Water Quality or other permitting authority, upon request.
2. Any duly authorized officer, employee, or representative of the Division of Water Quality
may, upon presentation of credentials, enter and inspect any property, premises or place on
or related to the application site or facility at any reasonable time for the purpose of
determining compliance with this permit; may inspect or copy any records that must be kept
under the terms and conditions of this permit; and may obtain samples of groundwater,
surface water, or leachate.
V1. GENERAL CONDITIONS
I . This permit shall become voidable unless the land application activities are carried out in
accordance with the conditions of this permit, the supporting materials, and in the manner
approved by this Division.
2. This permit is effective only with respect to the nature and volume of wastes described in
the application and other supporting data.
3. This permit is not automatically transferable. In the event that there is a desire for the
facilities to change ownership or a name change of the Permittee, a formal permit request
must be submitted to the Division of Water Quality accompanied by an application fee,
documentation from the parties involved, and other supporting materials as may be
appropriate. The approval of this request will be considered on its merits and may or may
not be approved.
4. The following are approved sites for residuals application (see attached map(s)):
Application Area [acres]
Site No. Owner/Lessee (excluding buffer
Plant United Piece Dye Works, L.P. 8.0
Homefeed United Piece Dye Works, L.P. 16.0
Parrish A United Piece Dye Works, L.P. 7.5
Parrish B United Piece Dye Works, L.P. 7.8
Parrish C United Piece Dye Works, L.P. 8.0
TOTAL AVAILABLE ACRES 47.3
5. Failure to abide by the conditions and limitations contained in this permit may subject the
Permittee to an enforcement action by the Division. of Water Quality in accordance with
North Carolina General Statute 143-215.6(a) to 143-215.6(c).
6. The annual administering and compliance fee must be paid by the Permittee within thirty
(30) days after being billed by the Division. Failure to pay the fee accordingly may cause
the Division to initiate action to revoke this permit as specified by 15 NCAC 2H .0205
(c)(4).

7. The issuance of this permit does not preclude the Permittee from complying with any and
all statutes, rules, regulations, or ordinances which may be imposed by other government
agencies (local, state, and federal) which have jurisdiction.
8. The Permittee, at least six (6) months prior to the expiration of this permit, shall request its
extension. Upon receipt of the request, the Commission will review the adequacy of the
facilities described therein, and if warranted, will extend the permit for such period of time
and under such conditions and limitations as it may deem appropriate.
9. This permit may be modified, or revoked and reissued to incorporate any conditions,
limitations and monitoring requirements the Division of Water Quality deems necessary in
order to adequately protect the environment and public health.
Permit issued this the fifteenth day of August, 1996
NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION
A. Preston ard, Jr., P.E.JDirector
Division of WAter Quality
By Authority of the Environmental Management Commission
Permit Number WQ0000800

State of North Carolina
Department of Environrnapt
and Natural Resource
Division of Water Quality
James B. Hunt, Jr., Governor
Wayne McDevitt, Secretary
A. Preston Howard, Jr., P.E., Wrft,T
Mr. Stephen M. Burns, Vice President
Piece Dye Acquisition Corporation
230 East High Street
Charlottesville, Virginia 22902
Dear Mr. Burns:
February 5, 1998
Subject_: Pc^rrrit No. WQ0000800-_
Piece Dye Acquisition Corporation
.Land ;Application of Wastewater Residuals
Chowan County
In accordance with your application received on January 16, 1998, we are forwarding herewith
Permit No. WQ0000800, dated February 5, 1998, to Piece Dye Acquisition Corporation for the continued
operation of a wastewater residuals land, application program. The only modification being made to this
permit at this time is the tranfer of ownership.from United Piece Dye Works to Piece Dye Acquisition
Corporation.
This permit shall be effective from the date of issuance until July 31, 2001, shall void Permit No.
WQ0000800, issued August 15, 1996, and shall be subject to the conditions and limitations as specified
therein. Please pay particular attention to the monitoring and reporting requirements contained in this
permit. Failure to establish an adequate system for collecting and maintaining the required operational
information will result in future compliance problems.
If any parts, requirements, or limitations contained in this permit are unacceptable, you have the
right to request an adjudicatory hearing upon written request within thirty (30) days following receipt of
this permit. This request must be in the form of a written petition, conforming to Chapter 150B of North
Carolina General Statutes, and filed with the Office of Administrative Hearings, P.O. Drawer 27447,
Raleigh, NC 27611-7447. Unless such demands are made this permit shall be final and binding.
If you need additional information concerning this matter, please contact Rick Moore at (919) 733-
5083 extension 527. 9
f
Sincer
Preston Howard, Jr., P.E.
cc: Chowan County Health Department
Mr. Ernest S. Knighton, CEO, United Piece Dye Works
Washington Regional Office, Water Quality Section
Washington Regional Office, Groundwater Section
Bob Cheek, Groundwater Section, Central Office
Technical Assistance and Certification Unit (no revised rating)
Non -Discharge Compliance/Enforcement Unit
P.O. Box 29535, Raleigh, North Carolina 27626-0535 Telephone [phone] FAX [phone]
An Equal Opportunity Affirmative Action Employer 50% recycled/ 10% post -consumer paper

NORTH CAROLINA
ENVIRONMENTAL MANAGEMENT COMMISSION
DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES
RALEIGH
RESIDUALS LAND APPLICATION PERMIT
In accordance with the provisions of Article 21 of Chapter 143, General Statutes of North Carolina as
amended, and other applicable Laws, Rules, and Regulations
Piece Dye Acquisition Corporation
Chowan County
FOR THE
operation of a wastewater residuals land application program consisting of the application of 400.0 dry
tons per year of residuals from the sources listed in Condition 115, to approximately 47.3 acres of land in
Chowan County with no discharge of wastes to the surface waters, pursuant to the name change request
received on January 16, 1998, and in conformity with the project plan, specifications, and other
supporting data subsequently filed and approved by the Department of Environment and Natural
Resources and considered a part of this permit.
This permit shall be effective from the date of issuance until July 31, 2001, shall void Permit No.
WQ0000800, issued August 15, 1996, and shall be subject to the following specified conditions and
Iimitations:
I. PERFORMANCE STANDARDS
1. This permit shall become voidable if the soils fail to adequately assimilate the wastes and
may be rescinded unless the sites are maintained and operated in a manner which will
protect the assigned water quality standards of the surface waters and ground waters.
2. The land application program shall be effectively maintained and operated as anon -
discharge system to prevent the discharge of any wastes resulting from the operation of this
program.
3. The issuance of this permit shall not relieve the Permittee of the responsibility for damages
to surface or groundwaters resulting from the operation of this program.
4. In the event that the land application program is not operated satisfactorily, including the
creation of nuisance conditions, the Permittee shall cease applying residuals to the sites and
take any immediate corrective actions as may be required by the Division.

5- Some of the buffers specified below may not have been included in previous permits for
this land application operation. However, any sites or fields that are included in this
permit, but were approved with different applicable buffers shall be reflagged to comply
with the below buffers. The following buffer zones shall be maintained:
a) 400 feet from residences or places of public assembly under separate, ownership for
surface application method; however, the buffer zone requirement may be reduced to a
minimum of 100 feet upon written consent of the owner and approval from the
appropriate DEM regional office,
b) 200 feet from residences or places of public assembly under separate ownership for
subsurface residual injection method; however, the buffer zone requirement may be
reduced to a minimum of 100 feet upon written consent of the owner and the
appropriate DEM regional office,
c) 100 feet from any public or private water supply source, waters classified as SA or SB,
and any Class I or Class II impounded reservoir used as a source of drinking water for
both methods,
d) 100 feet from any streams classified as WS or B, any other stream, canal, marsh or
coastal waters and any other lake or impoundment for surface application,
e) 50 feet from any streams classified as WS or B, any other stream, canal, marsh or
coastal waters and any other lake or impoundment for subsurface application,
f) 100 feet from property lines for both surface and subsurface application methods;
g) 50 feet from public right of ways for both application methods, .
h) 10 feet from upslope interceptor drains and surface water diversions for both
application methods,
i) 25 feet from downslope interceptor drains, surface water diversions, groundwater
drainage systems and surface drainage ditches for both application methods.
6. A copy of this permit shall be maintained at the land application site when residuals are
being applied during the life of this permit. A spill prevention and control plan shall be
maintained in all residuals transport and application vehicles.
7. Specific residual application area boundaries shall be clearly marked on each site prior to
and during application.
8. No residuals at any time shall be stored at any application site, unless approval has been
requested and obtained from the Division of Water Quality.
9. Maximum slope for residual application shall be 10% for surface application and 18% for
subsurface applications.
II. OPERATION AND MAINTENANCE REQUIREMENTS
1. . The facilities and application sites shall be properly maintained and operated at all times.
2. A suitable vegetative cover, as listed in condition 1114, shall be maintained in accordance
with the crop management plan outlined by the local Extension Office of the Department of
Agriculture, or the Soil Conservation Service, or other agronomist, and approved by this
Division.
3. An acceptable pH must be maintained in the soil, residual and lime mixture, greater than
6.0, on all land application sites to insure optimum yield for the crop(s) specified below.
The agronomist shall provide information on the pH best suited for the specified crop and
the soil type.

4. The application rates shall not exceed the following for the specified crops:
Cro PAN lb./acre/ r.
Alfalfa
200
Bermuda Grass (Hay, Pasture)
220
Blue Grass
120
Corn (Grain)
160
Corn (Silage)
200
Cotton
70
Fescue
250
Forest (Hardwood & Softwood)
75
Milo
100
Small Grain (Wheat, barley, oats)
100
Sorghum, Sudex (Pasture)
180
Sorghum, Sudex (Silage)
220
Soybeans
200
Timothy, Orchard, & Rye Grass
200
5. No residuals other than the following are hereby approved for land application in
accordance with this permit:
Permit
Volume
Source County
Number
(dry tons/year)
Piece Dye Acquisition Corporation Chowan
NC0003867
400.0
6. The lifetime heavy metal loadings shall not exceed the following for the corresponding
Cation Exchange Capacities (CEC):
Lifetime Loadings (lbs/acre)
Parameter CEC < 5
CEC 5 - 15
CEC > 15
Lead 500
1000
2000
Zinc 250
500
1000
Copper 125
250
500
Nickel 1.25
250
500
Cadmium 4.5
9
18
7. Upon classification of the facility by the Certification Commission, the Permittee shall
employ a certified land application/residuals operator to be in responsible charge (ORC) of
the land application program. The operator must hold a certificate of the type classification
assigned to the land application program by the Certification Commission. The Permittee
must also employ a certified back-up operator of the appropriate type to comply with.the
conditions of Title 15A NCAC 8A, .0202.
8. Adequate procedures shall be provided to prevent surface runoff from carrying any
disposed or stored residuals into any surface waters.
9. Surface applied residuals will be plowed or disced within twenty-four (24) hours after
application on lands with no cover crop established.
10. For areas that are prone to flooding or within the 100 -year flood elevation, residuals may
be applied only during periods of dry weather. The residuals must be incorporated into the
soil within twenty-four (24) hours after application.

11. Appropriate measures must be taken to control public access to the land application sites
during active site use and for the 12 -month period following the last residual application
event. Such controls may include the posting of signs indicating the activities being
conducted at each site.
12. Adequate provisions shall be taken to prevent wind erosion and surface runoff from
conveying pollutants from the residuals application area onto the adjacent property or into
any surface waters.
13. Residuals shall not be applied in inclement weather or until 24 hours following a rainfall
event of 1/2 -inch or greater in 24 hours. Any emergency residuals disposal measures must
first be approved by the Division of Water Quality.
14. Residuals shall not be applied to any land application site that is flooded, frozen or snow-
covered.
15. Residuals shall not be applied at rates greater than agronomic rates, unless authorized by
the Division.
16. Animals shall not be grazed on an application site for 30 days after residuals application.
Application sites that are to be used for grazing shall have fencing that will be used to
prevent access after each application.
17. The Division is concerned about the high Sodium Adsorption Ratio (SAR) found in the
residuals being land applied. Appropriate measures, including the application of gypsum to
balance the ratio if necessary, shall be undertaken to ensure that the land application sites
are not damaged. In accordance with the submitted agronomist report, a sodium (Na)
loading of less than 180 pounds per acre per year shall be maintained on all land application
sites.
III. MONITORING AND REPORTING REQUIREMENTS
Any monitoring (including groundwater, surface water, residuals, soil, or plant tissue
analyses) deemed necessary by the Division of Water Quality to insure protection of the
environment will be established and an acceptable sampling and reporting schedule shall be
followed.
2. Proper records shall be maintained by the Permittee tracking all application activities.
These records shall include, but are not necessarily limited to the following information:
a. source of residuals
b . date of residual application
c. location of residual application (site, field, or zone #)
d. method of application
e. weather conditions (sunny, cloudy, raining, etc.)
f. soil conditions
g . type of crop or crops to be grown on field
h. volume of residuals applied in gallons/acre, dry tons/acre or kilograms/hectare
i. annual and cumulative totals of dry tons/acre of residuals, annual and cumulative
pounds/acre of each heavy metal (which shall include, but not be limited to cadmium,
copper, lead, nickel, and zinc), annual pounds/acre of plant available nitrogen (PAN),
annual pounds/acre of sodium, annual poundslacre of soil amendment (i.e. gypsum),
and annual pounds/acre of phosphorus applied to each field.
4

3. A representative annual soils analysis (Standard Soil Fertility Analysis) shall be conducted
on each site receiving residuals in the respective calendar year and the results maintained on
file by the Permittee for a minimum of five years.
The Standard Soil Fertility Analysis shall include, but is not necessarily limited to, the
following parameters:
Acidity
Calcium
Copper
Magnesium
Base Saturation (by calculation)
Cation Exchange Capacity
Manganese Potassium
Percent Humic Matter Sodium
pH Zinc
Phosphorus
The Standard Soil Fertility Analysis (see above) and an analysis for the following
pollutants shall be conducted once prior to permit renewal on soils from each site which has
received residuals during the permit cycle.
Cadmium Lead Nickel
4. A residuals analysis will be conducted quarterly from the date of permit issuance by the
Permittee and the results maintained on file by the Permittee for a minimum of five years.
If land application occurs at a frequency less than quarterly, a residuals analysis will be
required for each instance of land application. The residuals analysis shall include but is
not necessarily limited to the following parameters:
Cadmium
Nitrate -Nitrite Nitrogen
Copper
% Total Solids
Lead
pH
Nickel
Phosphorus
Zinc
Plant Available Nitrogen (by calculation)
Aluminum
Potassium
Ammonia -Nitrogen
Sodium
Calcium
TKN
Magnesium
After the residuals have been monitored for two years at the above frequency, the Permittee
may submit a request to the Division for a permit modification for the reduction of the
frequency of monitoring for pollutant concentrations and for the pathogen density
requirements, but in no case shall the frequency of monitoring be less than once per year
when residuals are applied to the land.
5. A Toxicity Characteristics Leaching Procedure (TCLP) analysis shall be conducted by the
Permittee annually. The TCLP analysis shall include the following parameters (please note
the regulatory level in mgfL in parentheses): -
Arsenic (5.0)
Benzene (0.5)
Carbon tetrachloride (0.5)
Chlorobenzene (100.0)
Chromium (5.0)
m -Cresol (200.0)
Cresol (200.0)
1,4 -Dichlorobenzene (7.5)
1,1-Dichloroethylene (0.7)
Endrin (0.02)
(continued on next page)
Barium (100.0)
Cadmium (1.0)
Chlordane (0.03)
Chloroform (6.0)
o -Cresol (200.0)
p -Cresol (200.0)
2,4-D (10.0)
1,2-Dichloroethane (0.5)
2,4-Dinitrotoluene (0.13)
Heptachlor (and its hydroxide) (0.008)

Hexachlorobenzene (0.13)
Hexachloroethane (3.0)
Lindane (0.4)
Methoxychlor (10.0)
Nitrobenzene (2.0)
Pyridine (5.0)
Silver (5.0)
Toxaphene (0.5)
2,4,5 -Trichlorophenol (400.0)
2,4,5 -TP (Silvex) (1.0)
Hexachloro-1,3-butadiene (0.5)
Lead (5.0)
Mercury (0.2)
Methyl ethyl ketone (200.0)
Pentachlorophenol (100.0)
Selenium (1.0)
Tetrachloroethylene (0.7)
Trichloroethylene (0.5)
2,4,6 -Trichlorophenol (2.0)
Vinyl chloride (0.2)
6. Three copies of all required monitoring and reporting requirements as specified in
conditions III 1, III 2, 111 3, 111 4, and III 5, shall be submitted annually on or before
March 1 of the following year to the following address:
NC Division of Water Quality
Water Quality Section
Facility Assessment Unit
PO Box 29535
Raleigh, NC 27626-0535
7. Noncompliance Notification:
The Permittee shall report by telephone to the Washington Regional Office, telephone
number [phone], as soon as possible, but in no case more than 24 hours or on the
next working day following the occurrence or first knowledge of the occurrence of any of
the following:
a. Any occurrence with the land application program which results in the land application
of significant amounts of wastes which are abnormal in quantity or characteristic.
b . Any failure of the land application program resulting in a release of material to receiving
waters.
c. Anytime that self-monitoring information indicates that the facility has gone out of
compliance with the conditions and limitations of this permit or the parameters on
which the system was designed.
d. Any process unit failure, due to known or unknown reasons, that render the facility
incapable of adequate residual treatment.
e. Any spillage or discharge from a vehicle or piping system transporting residuals to the
application site.
Persons reporting such occurrences by telephone shall also file a written report in letter
form within five (5) days following first knowledge of the occurrence. This report must
outline the actions taken or proposed to be taken to ensure that the problem does not recur.
IV. GROUNDWATER REQUIREMENTS
The six (6) existing monitor wells are to be designated in all future correspondence and on
all GW -59 forms as the three (3) monitor wells at the Parrish Field Site, Site No, 1. Site
No. 1 MW -1, Site No, 1 MW -2, and Site No. 1 MW -3, and the three (3) monitor wells at
the Homefeed Site, Site No. 2: Site No. 2 MW -1 (formerly MW -11), Site No. 2 MW -2
(formerly MW -12), and Site No. 2 MW -3 (formerly MW -13).

2. The six (6) existing monitor wells, Site No. 1 MWA, Site No. 1 MW -2, Site No. 1 MW -
3, Site No. 2 MW -1 (formerly 1\4W-11, Site No. 2 MW -2 (formerly MW -12), and Site
No. 2 MW -3 (formerly MW -13), shall be sampled every March, July, and November, for
the following parameters:
Nitrate (NO3) Total Dissolved Solids
pH Total Organic Carbon
Total Ammonia Water Levels
Volatile Organic Compounds - In November only by Method 6230D below:
Method 6230D (Capillary - Column), "Standard Methods For The Examination of
Water and Wastewater", 17th ed., 1989
The measurement of water levels must be made prior to sampling for the remaining
parameters. The depth to water in each well shall be measured from the surveyed point on
the top of the casing.
The measuring points (top of well casing) of all monitoring wells shall be surveyed to
provide the relative elevation of the measuring point for each monitoring well.
If TOC concentrations greater than 10 mg/l are detected in any downgradient monitoring
well, additional sampling and analysis must be conducted to identify the individual
constituents comprising this TOC concentration. If the TOC concentration as measured in
the background monitor well exceeds 10 mg/l, this concentration will be taken to represent
the naturally occurring TOC concentration. Any exceedances of this naturally occurring
TOC concentration in the downgradient wells shall be subject to the additional sampling
and analysis as described above.
If any volatile organic compounds are detected by Method 6230D, then the Washington
Regional Office Groundwater Supervisor, telephone number [phone] must be
contacted immediately for further instructions regarding any additional follow-up analyses
required. The results of all initial and follow-up analyses must be submitted
simultaneously.
The results of the sampling and analysis must be received on Form GW -59 (Groundwater
Quality Monitoring: Compliance Report Form) by the Groundwater Section, Permits and
Compliance Unit, P.O. Box 29578 Raleigh, N.C. 27626-0578 on or before the last
working day of the month following the sampling month.
3. Any groundwater quality monitoring, as deemed necessary by the Division, shall be
provided.
4. The COMPLIANCE BOUNDARY for the disposal system is specified by regulations in
15A NCAC 2L, Groundwater Classifications and Standards. The Compliance Boundary is
for the disposal system constructed after December 31, 1983 is established at either (1) 250
feet from the waste disposal area, or (2) 50 feet within the property boundary, whichever is
closest to the waste disposal area. An exceedance of Groundwater Quality Standards at or
beyond the Compliance Boundary is subject to immediate remediation action in addition to
the penalty provisions applicable under.General Statute 143-215.6A(a)(1).
In accordance with 15A NCAC 2L, a REVIEW BOUNDARY is established around the
disposal systems midway between the Compliance Boundary and the perimeter of the
waste disposal area. Any exceedance of standards at the Review Boundary shall require
remediation action on the part of the permittee.

V. INSPECTIONS
1. The Permittee or his designee shall inspect the residuals storage, transport, and application
facilities to prevent malfunctions and deterioration; operator errors and discharges which
may cause or lead to the release of wastes to the environment, a threat to human health, or a
nuisance. The Permittee shall maintain an inspection log or summary including at least the
date and time of inspection, observations made, and any maintenance, repairs, or corrective
actions taken by the Permittee. This log of inspections shall be maintained by the Permittee
for a period of five years from the date of the inspection and shall be made available to the
Division of Water Quality or other permitting authority, upon request.
2. Any duly authorized officer, employee, or representative of the Division of Water Quality
may, upon presentation of credentials, enter and inspect any property, premises or place on
or related to the application site or facility at any reasonable time for the purpose of
determining compliance with this permit; may inspect or copy any records that must be kept
under the terms and conditions of this permit; and may obtain samples of groundwater,
surface water, or leachate.
V I . GENERAL CONDITIONS
1. This permit shall become voidable unless the land application activities are carried out in
accordance with the conditions of this permit, the supporting materials, and in the manner
approved by this Division.
2. This permit is effective only with respect to the nature and volume of wastes described in
the application and other supporting data.
3. This permit is not automatically transferable. In the event that there is a desire for the
facilities to change ownership or a name change .of the Permittee, a formal permit request
must be submitted to the Division of Water Quality accompanied by an application fee,
documentation from the parties involved, and other supporting materials as may be
appropriate. The approval of this request will be considered on its merits and may or may
not be approved.
4. The following are approved sites for residuals application (see attached map(s)):
Application Area [acres]
Site No. Owner/Lessee (excluding buffers)_
Plant
Piece Dye Acquisition Corporation
8.0
Hornefeed
Piece Dye Acquisition Corporation
16.0
Parrish A
Piece Dye Acquisition Corporation
7.5
Parrish B
Piece Dye Acquisition Corporation
7.8
Parrish C
Piece Dye Acquisition Corporation
8.0
TOTAL AVAILABLE ACRES
47.3
5. Failure to abide by the conditions and limitations contained in this permit may subject the
Permittee to an enforcement action by the Division of Water Quality in accordance with
North Carolina General Statute 143-215.6(x) to 143-215.6(c).
6, The annual administering and compliance fee must be paid by the Permittee within thirty
(30) days after being billed by the Division. Failure to pay the fee accordingly may cause
the Division to initiate action to revoke this permit as specified by 15 NCAC 2H .0205
(c)(4).

7. The issuance of this permit does not preclude the Permittee from complying with any and
all statutes, rules, regulations, or ordinances which may be imposed by other government
agencies (local, state, and federal) which have jurisdiction.
8. The Permittee, at least six (6) months prior to the expiration of this permit, shall request its
extension. Upon receipt of the request, the Commission will review the adequacy of the
facilities described therein, and if warranted, will extend the permit for such:period of time
and under such conditions and limitations as it may deem appropriate.
9. This permit may be modified, or revoked and reissued to incorporate any conditions,
limitations and monitoring requirements the Division of Water Quality deems necessary in
order to adequately protect the environment and public health.
Permit issued this the fifth day of February, 1998.
NORTH LINA EN NMEN AL MANAGEMENT COMMISSION
-'A. Preston Howard, Jr., P.E., Director
' Division of Water Quality
By Authority of the Environmental Management Commission
Permit Number WQ0000800
VJ

I�
f o 0
O
f i Ql
I' y tiny • s I' ,;` l�':` ':��,' ti _ -.� -
it
it
lrnt
rN
#� t 'I ! i I f ' f . I `�.' ,. f -� I � ..� ` f '""t. •� � Y, L ,11�� � : 1;;�
N.
It
1.
%a a t a / / � tli 1 ,� _ �'' c s ,• n/r• r
-.� `/� / �` 'I •� •r.r j' r� o` .0 r ! ���'�r0r�r� =-ti '' .ilk
�. �� •.9 � I �..:r• � \ 1,rr ! u rJlills r .. .r,-
It
cu
/.;�� a I�,�! 1 i Zo - � °` � ,.�' � ' f { . � ,•.-- ice/ ,;' —�-�!
.s-• �J l/'l �- ♦/ter' ,' J' � f'`�" ��/ ' ' I !�• • U ijh~u-`�
.i � JAI' f IE ��•� , X � � _•� r •� ` .._. �' � � 1l1\ �2, ^{
0
� f L