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Home My WebLink AboutNC0003298_Dioxin Monitoring Study_20171222INTERNATIONAL PAPER RIEGELWOOD MILL JOHN L RIEGEL ROAD RIEGELWOOD, NC 28456 December 22, 2017 Certified Mail: 7016 3010 0001 1137 0038 Cyndi Karoly DECEIVED/DENR/M Chief, Water Sciences Section DEC 2 9 2017 NC DEQ Division of Water Quality !later Resources 1621 Mail Service Center Permitting section Raleigh, NC 27699-1621 SUBJECT: Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, NC — 2017 Report NPDES Permit No. NC0003298 Dear Ms. Karoly: Please find enclosed the 2017 annual report for fish tissue dioxin monitoring conducted on the Cape Fear River in the vicinity of International Paper's Riegelwood Mill. If you have questions or need additional information, please call our Environmental Engineer, Kevin Burk, at 910.362.3476. Sincerely, Gary rrow Environmental, Health, Safety & Sustainability Manager Enclosure cc: Morella King, Regional Operations Supervisor NC DEQ — Wilmington Regional Office 127 Cardinal Drive Extension Wilmington, NC 28405 Tom Belnick, NPDES Unit Supervisor NC DEQ Division of Water Quality 1617 Mail Service Center Raleigh, NC 27699-1617 S-\Groups\Environmental\Wastewater\Fish Tissue\2017\Annual Fish Tissue Dioxin Report -2017.docx December 22, 2017 Page 2 of 2 Danny Staley NC DHHS, Division of Public Health 1931 Mail Service Center Raleigh, NC 27699-1931 Tom Tharrington NC DEQ — Wilmington Regional Office 127 Cardinal Drive Extension Wilmington, NC 28405 ehg S•\Groups\Environmental\Wastewater\Fish Tissue\2017\Annual Fish Tissue Dioxin Report -2017.docx RECEIVED/DENlIR/DWR DEC 2 9 2017 Water Resources Permitting Section DIOXIN MONITORING STUDY OF FISH TISSUE FROM THE CAPE FEAR RIVER IN THE VICINITY OF THE INTERNATIONAL PAPER COMPANY MILL AT RIEGELWOOD, NORTH CAROLINA 2017 REPORT Prepared for International Paper Company Riegelwood Mill John L. Riegel Road Riegelwood, North Carolina 28456 Prepared by CZR Incorporated 4709 College Acres Drive, Suite 2 Wilmington, North Carolina 28403 December 2017 l DIOXIN MONITORING STUDY OF FISH TISSUE FROM THE CAPE FEAR RIVER IN THE VICINITY OF THE INTERNATIONAL PAPER COMPANY MILL AT RIEGELWOOD, NORTH CAROLINA TABLE OF CONTENTS Paqe TABLEOF CONTENTS ........................................ .. . ....................................ii LIST OF TABLES - LIST OF FIGURES ........... .............................. ................. ............. .......... LISTOF APPENDICES ........................... .......................................................iii 1.0 INTRODUCTION ........................................ ... ............................ ....... 1 2.0 METHODS ........................ . ............. .................... .............................. 2 2.1 Sampling Stations .... ............................................................ 2 2.2 Species Selection ........ ................ .. .............................. . ......... 8 2.3 Sample Collection Methodology........................................................... 8 2.4 Sample Preparation and Shipment ............. ............................... . 11 2.5 Chemical Analysis................................................................ 12 30 RESULTS AND DISCUSSION................................................................ 13 3.1 Fish Collection ................................................... ................. 13 3.2 Tissue Analyses ...................................................................... 13 REFERENCES........ .................. .......................................................... 22 LIST OF TABLES Table Page 2-1 Water quality parameters measured in Cape Fear River sampling during 2017 fish collections in association with International Paper, Riegelwood, NC.. 7 2-2 Collection dates, techniques, effort, and fish captured in Cape Fear River fish collections during 2017 in association with International Paper, Riegelwood, NC............................. ................... ......................................... ............ 9 3-1 Summary of 2017 fish composites retained from three Cape Fear River stations in the vicinity of the International Paper Company Mill at Riegelwood, NC..............................................................................................15 3-2 Fish composite data for three Cape Fear River stations in the vicinity of the International Paper Company Mill at Riegelwood, NC, collected during 2017.... 19 3-3 Summary of analytical results from fish tissue composites collected in the Cape Fear River near the International Paper Company Mill at Riegelwood, NC, during 2017 ... ...................... .................... . . ..................... ...... 20 3-4 Comparison of dioxin (2,3,7,8-TCDD) concentrations among gamefish and bottom feeder composites from the Cape Fear River from 1992 to 2017 ........ 21 LIST OF FIGURES Figure Page 2-1 Sampling Stations -- Sites of Fish Collection on the Cape Fear River near Riegelwood, NC....................................................................................... 3 2-2 Sampling Station 1 -- Site of Fish Collection on the Cape Fear River near Riegelwood, NC..................................................................................4 2-3 Sampling Station 2 -- Site of Fish Collection on the Cape Fear River near Riegelwood, NC........................................................................ ... 5 2-4 Sampling Station 3 -- Site of Fish Collection on the Cape Fear River near Riegelwood, NC ................................. ........................... .................... 6 LIST OF APPENDICES APPENDIX A: DIOXIN MONITORING STRATEGY APPENDIX B: NORTH CAROLINA SCIENTIFIC COLLECTION PERMITS APPENDIX C: LETTER OF TRANSMITTAL/CHAIN OF CUSTODY APPENDIX D: TOTAL TEQ (WHO TEFS) / SGS LEVEL II ANALYTICAL LAB REPORTS 1.0 INTRODUCTION *- International Paper Company's (International Paper) NPDES permit (No. NC0003298) for the Riegelwood Mill requires the collection and analysis of fish tissue for the presence of dioxins and furans. The mill is located along the Cape Fear River near Riegelwood, Columbus County, North Carolina. The dioxin monitoring program is administered by the North Carolina Division of Water Resources (DWR), formerly the Division of Water Quality. International Paper contracted CZR Incorporated (CZR) to collect fish samples during 2017. To maintain report consistency, the format and style of this report are similar to CZR Incorporated's past monitoring reports (1993 through 2016 Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the Federal Paper Board's Mill at Riegelwood, North Carolina) which were modeled and derived from the September 1992 report (EA Report No. 12347.01) titled "Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of Federal Paper's Riegelwood, North Carolina Mill" prepared by EA Engineering, Science, and Technology, Inc Monitoring protocols were established in September 1990 to comply with the Special Order by Consent (SOC) EMC WQ No. 84-30 AD II effective 12 July 1990. The protocols comply with both the NPDES permit and the SOC. The following sections discuss sampling stations, sample collection techniques, sample preparation, and analytical results. 1 2.0 METHODS 2.1 Sampling Stations Fish collections occurred in the sampling areas established from previous studies (EA Engineering, Science, and Technology, Inc., 1992). Sampling stations were originally selected as required by the NPDES permit and SOC North Carolina's DWR fish tissue dioxin monitoring strategy for the Riegelwood Mill is provided in Appendix A. One station was located upstream of the mill's discharge and the remaining stations were located downstream of the mill (Figure 2-1) Station 1 is approximately 11 miles upstream of Lock & Dam No 1 in the vicinity of Elwell's Ferry (SR 1730). This station is a control site located approximately 20 miles upstream of the mill outfall and separated from the mill by a physical barrier, Lock & Dam No 1 (Figure 2-2). Station 2 is approximately 2 miles downstream of the mill discharge near Green Bank Landing (Figure 2-3). Station 3 is approximately 13 miles downstream of the mill discharge near the confluence of the Cape Fear River and the Black River (Figure 2-4). Generally, fish habitat was sparse and varied among the three sampling stations The available fish habitat consisted of inundated tree roots, aquatic macrophytes, overhanging riparian vegetation, snags, and fallen timber. Physicochemical measurements taken in conjunction with fish collections at each sampling station are found in Table 2-1. 2 STATION 1 ♦Council 11 MAchell W _ 7a SAht_" Frs HNry Bolton 214 Lake %Vaccamaw 9 Late Vvaccamaw State Pam LEGEND SAMPLING STATION SITE OF PAPER MILL SOURCE BASE MAP RETRIEVED FROM DELORME STREET ATLAS USA 2010 Kelly { d21 i z Fear +T er Black o STATION 2 ane. La�.gCrank _Roan lsfand fro i lei egelwood ♦ C11111, aa Fear -� 1 Delco STATION -3 u:,,� ti $2f1fOFt .. .`.� 1 . Sandy Lu"., 41s � ` ®Leland, , , , ._Navas. SAMPLING STATIONS SITES OF FISH COLLECTION ON THE CAPE FEAR RIVER NEAR RIEGELWOOD, NC SCALE: AS SHOWN JAPPROVED BY: DRAWN BY: TW DATE: 11/28/17 FILE: 1340—KEY 0 3 ml 6 m1 CP#1340 4709 COLLEGE ACRES DRIVE ZR OLIN SUITE 2 to SCALE IN FEET INCORPORATED WILMINGTON, NORTELC9R10/39229253 FIGURE 2-1 QMRONYDrtI4 CDNSULT/JffS FAX 910/392-9139 + -7 c Z Z 3; Ira < 1�7 0 L-1 on 73 mn, -74 - LEGEND SAMPLING STATION 1 SITES OF FISH COLLECTION ON THE SAMPLING STATION CAPE FEAR RIVER NEAR RIEGELWOOD, NC SCALE: AS SHOWN APPROVED BY: DRAWN BY: TLJ 0 2,000 4,000 DATE: 12/09/08 FILE: 1340—SPI SOURCE: F SCALE IN FEET 4709 COLLEGE ACRES DRIVE CP#1 340.16 NORTH CAROLINA DEPARTMENT OF TRANSPORTATION, LISGS TOPOGRAPHIC MAP MOSAICS, NC STATEPLANE, ZR VINCO.PORATED SUITE 2 w,LMINGTON, NORTH CAROLINA 28403 TEL 91 FIGURE 2-2 NAD83 FEET, 1:24000-SCALE, IJSGSTopoTile0l8.SlD 9,0/392-9253 �SULT� FAX 0/392-9139 Lti t Loidi#V L ..Aft IF :�7 1 -ft -w K -ykes LEGEND SAMPLING STATION 2 SITES OF FISH COLLECTION ON THE � SAMPLING STATION CAPE FEAR RIVER NEAR RIEGELWOOD,, NC SCALE: AS SHOWN APPROVED BY: DRAWN BY: TLJ 0 2,000 4,000 DATE: 12/09/08 FILE: 1340 -SPI SOURCE: NORTH CAROLINA DEPARTMENT OF TRANSPORTATION, USGS TOPOGRAPHIC MAP MMOSAICS, NC STATEPLANE, NAD83 FEET, 1:24000 -SCALE, USGSTopoTiIe018.SID91 SCALE IN FEET 4709 COLLEGE ACRES DRIVE SUITE 2 TEL 910 2-9253 INCORPORATED Z R WILMINGTON, NORTH CAROLINA 28403 9 91 IL mmsuLT— FAX 0//3392- 39 CP#1 340.16 FIGURE -::3] -kms r;,-::, � 1. � _ •+Q- -_-y _ r. �• -' 'y� _' �- �_ _ .s - \1 `� � - s - _ - y .:..-��. -2- '�'. y ",Y. y "' "�' '�. �.. �� .rte .. .� ' -"_ 4 \i rE.�, - ... y t . �•.1 \ • -ti L 1 �- re W _ 1. � -`! .. r. - W "_:,. ! � '." �„n,_ r w y ~ � -'lr �,! "� � � 1 +,, �• ` .•i�” � .fes -Y. .«J _ _ 'v ��— J \r/, 21 r •i- A _*` r5iL7Jj-C•�o8 .,.. "�. - --�1- _ "� +v. } - .... `W '• a ,,•� ? �,1, g y � M r• � r. � �4 � r f� •� ^S- < _I L_ l � _ st.r. 3-� LEGEND SAMPLING STATION SOURCE: NORTH CAROLINA DEPARTMENT OF TRANSPORTATION, USGS TOPOGRAPHIC MAP MOSAICS, NC STATEPLANE, NAD83 FEFT, 1:24000—SCALE, USGSTopoTile018.SID co y SAMPLING STATION 3 SITES OF FISH COLLECTION ON THE CAPE FEAR RIVER NEAR RIEGELWOOD, NC SCALE: AS SHOWN APPROVED BY: DRAWN BY: TLJ 0 2,000 4,000 DATE: 12/09/08 FILE: 1340—SP1 C P# 1340.1 6 SCALE IN FEET �'"�'�\�_ 4709 COLLEGE ACRES DRIVE 'V ZR SUITE 2 WILMINGTON, NORTH CAROLINA 28403 INCORPORATED TEL 910/392-9253 FIGURE 2-4 crrvlaoHucrrtu CONSULT—S FAX 910/392-9139 Table 2-1. Water quality parameters measured in Cape Fear River sampling during 2017 fish collections in association with International Paper, Riegelwood, NC. Sampling Temp DO Station Date Time (°C) DO% (mg/L) Cond(gS) SpCond(gS) Sahnity(psu) Secchi(m) pH 1 5 -Sept -17 1920 27.5 70.7 5.54 175.8 171.5 0.08 29.25 5.21 1 6 -Sept -17 0805 27.0 69.8 5.60 167.5 161.2 0.07 31.00 5.16 1 7 -Sept -17 0720 26.2 70.8 5.78 156.8 152.4 0.07 39.00 5.74 2 6 -Sept -17 1540 26.9 90.4 7.29 227.3 212.4 0.10 34.00 5.78 2 7 -Sept -17 0955 26.1 70.9 5.74 143.6 140.0 0.06 38.00 5.53 2 26 -Sept -17 0745 25.2 67.4 5.52 151.1 150.3 0.07 40.00 5.64 2 27 -Sept -17 0735 25.4 65.9 5.43 253.6 251.8 0.12 32.00 6.02 2 28 -Sept -17 0805 25.6 60.7 4.90 313.7 307.2 0.15 30.00 5.99 3 25 -Sept -17 1725 25.3 61.0 4.96 167.6 167.0 0.08 28.50 5.72 3 26 -Sept -17 0930 24.6 52.4 4.72 186.2 181.9 0.09 28.50 5.78 3 27 -Sept -17 0830 24.7 52.4 4.36 155.4 156.3 0.07 28.00 5.71 3 28 -Sept -17 0930 25.0 50.1 4.11 163.2 162.8 0.08 25.00 5.71 2.2 Species Selection The goal of the fish collection effort was to obtain four composite samples at each sampling location with each sample consisting of ten individuals of the same species and of similar length and weight. Larger specimens were given preference. Composites at each station were composed of gamefish and bottom feeding species fillets. Target species defined by the NPDES permit and SOC for Riegelwood Mill include: • one composite sample for largemouth bass with sunfish (bluegill, redbreast, etc.) as fallback species; • one composite sample for bluegill with other sunfish (redbreast, redear, etc.) as fallback species; • one composite sample for catfish (order of preference being flathead, channel, blue, and others) or carp; • one composite sample for catfish (order of preference being flathead, channel, blue, or others with fallback species as edible finfish). 2.3 Sample Collection Methodology Various active and passive methods of fish collection were used to obtain target species. Fish were collected under scientific fish collecting Permit Number SECP-707778 (North Carolina Division of Marine Fisheries) and License Number 17-SFC00004 (North Carolina Wildlife Resources Commission) (Appendix B). Gill nets (flounder nets; 5.50 -inch mesh x 20 mesh x 50 or 100 yards and 5.75 -inch mesh x 15 mesh x 50 or 100 yards), trot lines, and hook and line fishing were primarily used to collect fish Descriptions of effort and gear types used are given in Table 2-2. 8 Kel Table 2-2 Collection dates, techniques, effort, and fish captured in Cape Fear River fish collections during 2017 in association with International Paper, Riegelwood, NC See Figures 1 through 3 for site/station locations. Sampling Station Date Gear Level of Effort Catch 1 5 September 2017 Hook & Line 1 50 hour 18 bluegill 1 6 September 2017 Hook & Line 125 hour 1 largemouth bass (released), 6 bluegill (4 released) Trot line 2 lines — 50 hooks 2 blue catfish Gill net 8 nets overnight — 400 yards 13 blue catfish, 4 flathead catfish, 4 common carp 1 7 September 2017 Gill net 4 nets overnight — 100 yards 5 blue catfish, 2 flathead catfish, 1 common carp 2 6 September 2017 Hook & line 2 25 hour 9 bluegill 2 7 September 2017 Hook & line 1 50 hour 6 bluegill Trot line 2 lines — 50 hooks 1 channel catfish Gill net 4 nets overnight — 200 yards 4 blue catfish, 6 common carp, 2 flathead catfish 2 26 September 2017 Hook & line 150 hour 3 bluegill Trot line 2 lines — 50 hooks 1 blue catfish Gill net 3 nets overnight — 200 yards 2 blue catfish 2 27 September 2017 Hook & Line 0.50 hour 2 bluegill Trot line 2 line — 50 hooks 3 blue catfish (1 released) Gill net 3 nets overnight — 200 yards 6 blue catfish 2 28 September 2017 Gill net 3 nets overnight — 150 yards 3 blue catfish, 3 common carp Trot line 1 line — 25 hooks I channel catfish (released) Table 2-2. (Concluded) Sampling Station Date Gear Level of Effort Catch 3 25 September 2017 Hook & line 125 hour 11 bluegill 3 26 September 2017 Hook & line 100 hour 11 bluegill Trot line 2 lines — 50 hooks 5 blue catfish Gill net 4 nets overnight — 200 yards 3 blue catfish, 3 common carp 3 27 September 2017 Trot line 3 lines — 75 hooks 0 fish Gill net 4 nets overnight — 200 yards 1 blue catfish 3 28 September 2017 Trot line 2 lines — 50 hooks 3 blue catfish Gill net 4 nets overnight — 250 yards 1 flathead catfish, 1 blue catfish 0 24 Sample Preparation and Shipment Collected fish were descaled or skinned, filleted, and preserved by CZR. SGS Environmental Services (5500 Business Drive, Wilmington, North Carolina 28405) was responsible for final sample preparation (i.e., homogenization) and chemical analysis. To prevent cross -contamination between stations and composites, all equipment used to handle fish (excluding nets) was solvent rinsed with pesticide -grade acetone and hexane and when applicable, wrapped with aluminum foil (e.g., measuring boards and scale pans) which was changed between composites Fish from different stations were held in separate coolers and disposable latex gloves were worn and frequently changed when handling fish during each phase of sample preparation As fish were collected, they were placed on wet ice until processing. Fish were filleted with knives on cutting boards wrapped with aluminum foil (dull side up). Cutting board wraps were changed and fillet knives were solvent rinsed between composites. Fillet samples consisted of flesh from both sides of each specimen, including the skin (for gamefish) but not the scales. Catfish and carp specimens were skinned. Samples were wrapped in aluminum foil (dull side toward the fish) to shield it from light and were labeled with sample location, species, and date of collection. All labeled samples making up a single composite were placed in individual plastic "zip -lock" bags, then all composite sample bags were sealed inside a larger bag for each station Samples were frozen to await delivery to the laboratory for analysis. On 24 October 2017, the frozen samples were hand -delivered to SGS Environmental Services in Wilmington, North Carolina, in coolers packed with ice. A copy of the letter of transmittal/chain of custody that accompanied samples is included in Appendix C. 11 2.5 Chemical Analysis SGS Environmental Services performed the chemical extraction and analyses in accordance with EPA Method 1613B using high-resolution chromatography/high-resolution mass spectrometry for detecting the presence of 2,3,7,8- tetrachlorodibenzo-p-dioxin (TCDD) and 2,3,7,8-tetrachlorodibenzofuran (TCDF). Additionally, analyses of all 17 of the dioxin and furan congeners that are substituted with chlorine at the 2,3,7, and 8 positions were performed. All summary results were reported as 2,3,7,8-TCDD, 2,3,7,8-TCDF; and dioxin toxicity equivalents (TEQs). TEQs were calculated using 17 of the 2,3,7,8 -chlorine substituted dioxin and furan congeners using the 2005 World Health Organization (WHO) toxicity equivalent factors (TEFs) for mammals (Total TEQ WHO TEFs) (Van den Berg et al , 2006). Congener concentrations reported as non -detect were entered as zero in the calculation of all TEQ values. Congeners reported as estimated maximum possible concentrations (EMPC) were not included in calculations of total TEQs. Total extractable lipid content was also determined for each composite sample. A composite sample of blue catfish from Station 1 was designated for duplicate laboratory analysis. A quantity sufficient for re -extraction of each composite sample (where available) was retained and will be held frozen for a period of 30 days at the lab following the analysis. Duplicate samples will be held at CZR for three months following the completion of this report. 12 3.0 RESULTS AND DISCUSSION 3.1 Fish Collection A summary description of the 2017 fish composites is found in Table 3-1. Gamefish and bottom feeder target species were collected from each of the three stations. Gamefish or water -column feeding species submitted for analysis included bluegill (Lepomis macrochirus) from Stations 1, 2, and 3 Bottom feeder species submitted for analysis included blue catfish (Ictalurus furcatus) from Stations 1, 2, and 3. Sample composites with calculated average total fish lengths and weights are found in Table 3-2. 3.2 Tissue Analyses Dioxin (TCDD) concentrations (all reported in parts per trillion — ppt) in 2017 were detected in 5 of 13 composite samples, none exceeding 0.44 ppt which was found in blue catfish composite number 2 (composite of 10 individuals) at reference Station 1 (Table 3-3) Other concentrations of dioxin detected from Station 1 were 0 29 ppt found in blue catfish composite number 1 (composite of 10 individuals), and an estimated maximum possible concentration of 0 22 ppt found in the duplicate sample of fillets submitted from composite number 1. Dioxin concentrations of 0.17 ppt and 0 25 ppt were detected from Station 2 in blue catfish composite numbers 5 (composite of 8 individuals) and 6 (composite of 10 individuals), respectively. No dioxin concentrations were detected from Station 3. Furan (TCDF) concentrations (all reported in parts per trillion — ppt) in 2017 were detected in 3 of 13 composite samples, none exceeding 0.38 ppt which was also found in blue catfish composite number 2 (composite of 10 individuals), located at reference Station 1 (Table 3-3). The only other concentrations detected were 0.29 ppt found in blue catfish composite number 1 (composite of 10 individuals), located at Station 1 and an estimated maximum possible concentration of 0.27 ppt found in the duplicate sample of fillets submitted from composite number 1. Furan concentrations were not detected from either Station 2 or Station 3. `9l All analytical results for fish tissue composites collected and submitted during 2017 are summarized in Table 3-3 Percent lipid contents ranged from 0.3 (bluegill at both Stations 1 and 3) to 7.6 (blue catfish from Station 1). Reported TEQs for 2,3,7,8-TCDD/F only are all below 0.50 ppt. Data for individual congeners (Total TEQ, WHO TEFs) and laboratory data reports provided by SGS Environmental Services are included in Appendix D. Total TEQ values for all 17 congeners (using WHO TEFs) in 2017 ranged from 0 00 ppt in all bluegill composites submitted from Stations 1, 2, and 3 to 1.34 ppt in blue catfish composite number 2 at Station 1 (Table 3-3). Total TEQ values for all fish composite samples collected and submitted in 2017 are well below the state advisory level of 4.00 ppt (NCDENR 2013). Furthermore, all blue catfish composites submitted from downstream of the Riegelwood Mill at Stations 2 and 3 had lower total TEQs than control Station 1. Average dioxin concentrations (TCDD) from game and bottom feeding fish in the vicinity of the Riegelwood Mill have remained low during the course of annual sampling periods over the last twenty-six years and do not display any increasing trends in TCDD concentration (Table 3-4). 14 Table 3-1 Summary of 2017 fish composites retained from three Cape Fear River stations in the vicinity of the International Paper Company Mill at Riegelwood, North Carolina Station Composite Species Length Weight (g) Fillet A (g) Ka 1 1 Blue catfish 446 900 150 1 01 1 1 Blue catfish 550 1,800 185 1 08 1 1 Blue catfish 565 1,850 270 1 03 1 1 Blue catfish 584 2,100 310 1 05 1 1 Blue catfish 610 2,250 200 099 1 1 Blue catfish 618 2,600 430 1 10 1 1 Blue catfish 622 2,650 350 1 10 1 1 Blue catfish 596 2,800 300 1 32 1 1 Blue catfish 665 2,900 430 099 1 1 Blue catfish 679 3,200 500 1 02 1 2 Blue catfish 644 3,300 450 124 1 2 Blue catfish 670 3,300 495 1 10 1 2 Blue catfish 668 3,500 500 1.17 1 2 Blue catfish 674 3,500 550 1 14 1 2 Blue catfish 703 3,500 475 1 01 1 2 Blue catfish 686 3,900 550 1 21 1 2 Blue catfish 722 4,050 545 1 08 1 2 Blue catfish 683 4,100 625 1 29 1 2 Blue catfish 751 5,400 820 1 27 1 2 Blue catfish 729 6,000 850 1 55 1 3 Bluegill 150 75 10 222 1 3 Bluegill 157 75 10 194 1 3 Bluegill 156 80 10 211 1 3 Bluegill 156 85 10 224 1 3 Bluegill 158 85 10 2.16 1 3 Bluegill 162 85 10 200 1 3 Bluegill 162 85 10 200 1 3 Bluegill 166 90 10 197 1 3 Bluegill 160 95 10 2.32 1 3 Bluegill 171 100 15 2.00 1 4 Bluegill 165 105 15 234 1 4 Bluegill 169 110 15 228 1 4 Bluegill 173 110 10 212 1 4 Bluegill 174 110 15 209 1 4 Bluegill 178 110 15 1 95 1 4 Bluegill 188 115 15 173 1 4 Bluegill 177 125 15 2.25 1 4 Bluegill 178 140 15 248 1 4 Bluegill 180 140 15 240 1 4 Bluegill 197 170 15 222 15 Table 3-1 (continued) Station Composite Species Length Weight (g) Fillet A (g) Ka 1 - Common carp 516 2,100 245 1 53 1 - Common carp 543 2,200 270 1 37 1 - Common carp 565 2,350 325 1 30 1 - Common carp 567 2,400 325 1 32 1 - Common carp 602 2,600 310 1 19 1 - Flathead catfish 447 800 90 0.90 1 - Flathead catfish 580 2,000 225 1 03 1 - Flathead catfish 602 2,400 260 1 10 1 - Flathead catfish 611 2,500 295 1 10 1 - Flathead catfish 616 2,300 250 098 1 - Flathead catfish 648 2,700 315 099 2 5 Blue catfish 529 1,200 185 081 2 5 Blue catfish 558 1,500 185 086 2 5 Blue catfish 553 1,700 200 1 01 2 5 Blue catfish 590 1,900 310 093 2 5 Blue catfish 617 1,900 260 081 2 5 Blue catfish 598 2,000 290 094 2 5 Blue catfish 598 2,400 340 1 12 2 5 Blue catfish 630 2,400 320 0.96 2 6 Blue catfish 640 2,750 410 1 05 2 6 Blue catfish 651 2,850 440 1 03 2 6 Blue catfish 638 3,100 400 1 19 2 6 Blue catfish 657 3,200 450 1 13 2 6 Blue catfish 716 3,200 350 087 2 6 Blue catfish 672 3,700 500 1 22 2 6 Blue catfish 703 3,800 490 1 09 2 6 Blue catfish 724 3,800 460 1 00 2 6 Blue catfish 697 3,850 540 1 14 2 6 Blue catfish 691 4,000 610 1 21 2 7 Bluegill 150 60 10 178 2 7 Bluegill 152 68 10 194 2 7 Bluegill 164 75 15 170 2 7 Bluegill 159 80 10 199 2 7 Bluegill 167 85 20 183 2 7 Bluegill 151 90 15 261 2 7 Bluegill 160 90 10 220 2 7 Bluegill 163 90 10 208 2 7 Bluegill 167 90 15 193 2 7 Bluegill 168 105 15 221 2 8 Bluegill 174 110 15 2.09 2 8 Bluegill 185 110 10 174 2 8 Bluegill 190 123 10 179 2 8 Bluegill 178 125 20 222 2 8 Bluegill 186 130 10 202 16 L� 66 L 0 6 86 OL L Ilmenl9 L L £ L L Z U £6 t,9 L Ili6anle L L £ t,L Z M L6 Z9L IIi6anl8 LL £ 68 L O L 98 99L IIi6enl8 LL £ L8 L O L 9L 69L I1i6enl9 LL £ £6 L 9 69 £9L Ili6anl9 LL £ V6 L OL 89 M IIi6anl8 LL £ 86 L 9 89 L9L 11i6an18 LL £ 98 L O L 99 ZS L Ili6an18 L L £ OL L OL Z9 t,9 L IIi6anl9 L L £ 8 L L 099 006'£ Z69 4sipeo onl8 OL £ 9L L Oct, 008'£ Z69 4slReo anl8 OL £ 660 OLt, 009'£ 80L 4sg}eo anl8 OL £ V6 0 9t,t, OO L'£ L69 4speo enl9 OL £ £0 L 0££ OOVZ 9L9 4sipeo anl9 0 L £ £6 0 9LZ 00 L'Z 0 L9 4speo 9nl8 0 L £ 980 OZ£ 090'Z £Z9 4sipeo anl8 0 L £ 00 L OL£ OLO'Z 989 4s!}4eo anl8 6 £ 960 00£ 006'L 989 4s!geo anl8 6 £ L60 08L On"L 8£9 4s!4eo an18 6 £ 990 09L On' L 9Z9 4speo anl8 6 £ L8 0 09L 09Z' L £Z9 4sipeo ante 6 £ L9 0 08L 098 0£9 gsi}}eo onl8 6 £ , Z6 0 00£ 099'£ 9£L 4si}teo pea4;elj - Z L6 0 99L 008'Z 099 4sPeo pea4}el=l - Z OZ L 0t,£ 090'£ ££9 djeo uowwoo - Z , L£ L 09£ 090'£ 909 djeo uowwoo - Z L£ L 0££ 000'£ ZL9 djeo uowwoo - Z Z9 L Ot,Z 000'£ OL9 djeo uowwoo - Z 9Z L 09£ 009'Z Z69 djeo uowwoo - Z £t, L 08Z 099'Z £99 dieo uowwoo - Z 8Z L 99Z OOZ'Z 999 djeo uowwoo - Z ZZ L 9ZZ 008' L 8Z9 djeo uowwoo - Z 80 L ON 099' L 9£9 djeo uowwoC) - Z 9L 0 Ot,L 008 £Lt, 4spm leuuego - Z 9LZ OZ 9L L LOZ Ili6an18 8 Z Et, Z OZ 9L L 66L IIi6anl9 8 Z t,6 L OZ 09L ZOZ II!6an18 8 Z £L Z 9L 9£L 99L II!6an18 8 Z t,8 L 9L 0£ L Z6 L 11i6an18 8 Z e� (6) V 40111d (6) 44618M (ww) saloadg a;lsodwoo uol;e;g -(penw}uoo) L -E alge I Table 3-1 (concluded) Station Composite Species Length Weight (g) Fillet A (g) Ka 3 12 Bluegill 173 90 15 174 3 12 Bluegill 172 105 20 206 3 12 Bluegill 181 105 10 1 77 3 12 Bluegill 172 112 15 220 3 12 Bluegill 172 115 15 2.26 3 12 Bluegill 185 113 15 1 78 3 12 Bluegill 184 123 10 1 97 3 12 Bluegill 197 172 20 225 3 12 Bluegill 217 185 30 181 3 12 Bluegill 220 250 40 235 3 - Bluegill 147 58 5 183 3 - Bluegill 149 59 5 178 3 - Common carp 560 2,200 230 1 25 3 - Common carp 578 2,600 290 1 35 3 - Common carp 640 3,900 490 1.49 3 - Flathead catfish 588 2,100 240 1 03 aFulton-type condition factor - (weight(g)/length(mm)3)*100000 im Table 3-2 Fish composite data for three Cape Fear River stations in the vicinity of the International Paper Company Mill at Riegelwood, North Carolina, collected during 2017 " CompositeNumber a in Average Average Average Station number Type Species composite length weight (g) _ (mm) weight (g) 1 1 B Blue catfish 10 5935 2,3050 3125 b 1 2 B Blue catfish 10 6930 4,0550 5860 1 3 G Bluegill 10 1598 855 105 -- 1 4 G Bluegill 10 1779 1235 145 2 5 B Blue catfish 8 5841 1,8750 261 3 2 6 B Blue catfish 10 6789 3,4250 4650 2 7 G Bluegill 10 1601 833 130 2 8 G Bluegill 10 1886 1373 157 3 9 B Blue catfish 6 5477 1,4517 2150 3 10 B Blue catfish 7 661 6 2,9786 4029 3 11 G Bluegill 10 1582 774 90 3 12 G Bluegill 10 1873 1370 190 aB = Bottom feeder, G = Gamefish/water-column feeder bReplicate samples submitted `Ull Table 3-3. Summary of analytical results from fish tissue composites collected in the Cape Fear River near the International Paper Company Mill at Riegelwood, North Carolina, during 2017. Detailed case narratives of the laboratory results are found in Appendix D. Notes a f 5% statistical variability. b Includes Estimated Maximum Possible Concentrations due to ion ratio failure. C Toxic Equivalent (Total TEQ WHO TEFs) excludes Estimated Maximum Possible Concentrations per EPA Method 1613B. d Not detected. e Analyte not displayed on table was detected, but Total TEQ (WHO TEFs) remains less than 0 00 ppt. f Duplicate sample. 9 Estimated Maximum Possible Concentration. 2,3,7,8-TCDD (ppt) 2,3,7,8-TCDF (ppt) 2,3,7,8- TCDD/F Total TEQ Percent Percent Percent WHO TEQ WHO TEFs Station Species Composite (#) lipid Concentration recoverya Concentration recoverya (ppt)b (ppt)e 1 Blue catfish (1) 5.0 0.29 86.6 029 866 0.32 0.88 1 Blue catfish (2) 7.6 044 84.0 038 80 1 0.48 1.34 1 Bluegill (3) 0.3 ND 91 8 ND 80.0 0.00 0 00e 1 Bluegill (4) 0.7 ND 87.9 ND 82.5 0.00 0.00 1 Blue catfish (13)f 5 3 0 229 83 8 0.27 54.3 0.25 0.73 2 Blue catfish (5) 2 8 0 17 84 2 ND 79.1 0.17 0.32 2 Blue catfish (6) 3 4 025 87.2 ND 74.9 0.25 0.83 0 2 Bluegill (7) 12 ND 85.0 NDd 71.6 000 000 2 Bluegill (8) 1.2 NDd 88.4 ND' 75.7 0.00 0.00 3 Blue catfish (9) 0.6 NDd 999 ND' 83.2 0.00 0.22 3 Blue catfish (10) 2.2 ND 917 ND 75.6 000 0 13 3 Bluegill (11) 0 3 ND 93.7 ND 79.0 000 000 3 Bluegill (12) 0 4 ND 767 ND 610 0.00 0.00 Notes a f 5% statistical variability. b Includes Estimated Maximum Possible Concentrations due to ion ratio failure. C Toxic Equivalent (Total TEQ WHO TEFs) excludes Estimated Maximum Possible Concentrations per EPA Method 1613B. d Not detected. e Analyte not displayed on table was detected, but Total TEQ (WHO TEFs) remains less than 0 00 ppt. f Duplicate sample. 9 Estimated Maximum Possible Concentration. Table 3-4 Comparison of dioxin (2,3,7,8-TCDD) concentrations among gamefish and bottom feeder composites from the Cape Fear River from 1992 to 2017 2,3,7,8-TCDD average concentration (ppt) Station 1 Station 2 Station 3 Year Gamefish Bottom feeder Gamefish Bottom feeder Gamefish Bottom feeder 1992 009 015 038 209 035 115 1993 0 09a 016 0 17b 0.59 033 038 1994 008 ND 032 02 0.22 042 1995 ND ND ND 021 b ND ND 1996 ND ND ND 037 b ND 012 1997 ND 0 17b 0 20a 025 a ND 006 b 1998 ND ND ND ND ND 031 1999 ND 005 b 008b 0 17b ND 0.31b 2000 ND ND` 0 18b ND 009 b ND 2001 ND ND` 0 11b 0 19b 0 11b 008 b 2002 ND 026 b ND 029 b ND ND 2003 ND ND ND 005 b ND 063 N 2004 ND 025 b ND 014 026 01 j 2005 023 0.34' 012 043 020 026 a 2006 0.07b 022 a ND 0 24a ND 0.36' 2007 ND 033 a ND 0 15' ND 007 b 2008 ND 042 a ND 0.11 ND 0 33" 2009 042 070 032 113 056 b 0 49 2010 ND 030 b ND 029 b 0 14b 0 12b 2011 ND 0.10b ND 042 ND ND 2012 ND 0 18b ND 052 a ND 0 11b 2013 ND 0.11b ND 0.18a ND 0.19' 2014 ND 012 ND 0 09a ND 007 b 2015 001 b 0.12a 0.01b 0 10a ND 02 a 2016 ND 0.10 ND ND ND 0 03b 2017 ND 037 ND 021 ND ND *1992 data were obtained from EA Report No. 12347 01 (EA Engineering, Science, and Technology, Inc., 1992) ND = Not detected, detection limits were not used in calculating average concentrations of 2,3,7,8-TCDD aValues represent average of dioxin concentrations and estimated concentrations bValues represent average of estimated concentrations `Estimated concentration found in replicate. REFERENCES CZR Incorporated. 1993. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of Federal Paper Board's Mill at Riegelwood, North Carolina. CZR Incorporated 1994. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of Federal Paper Board's Mill at Riegelwood, North Carolina. CZR Incorporated 1995. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of Federal Paper Board's Mill at Riegelwood, North Carolina. CZR Incorporated. 1996 Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated. 1997. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina CZR Incorporated. 1998 Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated. 1999. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated. 2000. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated 2001. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated. 2002 Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated. 2003. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated. 2004 Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated. 2005. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. 22 CZR Incorporated. 2006 Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated. 2007. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated 2008. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina CZR Incorporated 2009. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated. 2010. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated. 2011. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina CZR Incorporated. 2012 Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated 2013. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated. 2014. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated. 2015 Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. CZR Incorporated. 2016. Dioxin Monitoring Study of Fish Tissue from the Cape Fear River in the Vicinity of the International Paper Company Mill at Riegelwood, North Carolina. EA Engineering, Science, and Technology, Inc. 1992. Dioxin Monitoring Study of Fish Tissue from the Vicinity of Federal Paper Board Company's Riegelwood Mill. Prepared for Federal Paper Board Company, Inc., EA Engineering, Science, and Technology, Inc, Smyrna, Georgia. Report No. 12347.01. 23 National Council for Air and Stream Improvement (NCASI). 1991. A critical review of the literature on the bioaccumulation of 2,3,7,8-tetrachlorodibenzo-p-dioxin and furan in fish NCASI Tech. Bull. No 610. NCDENR. 2013. Standard Operating Procedures Fish Tissue Assessments North Carolina Department of Environmental and Natural Resources Division of Water Resources, Environmental Sciences Section, Intensive Survey Branch. Version 1.2. Taylor, K., and K. M. Rudo. 1990. Risk Assessment of Dioxin Contaminated Fish Division of Epidemiology, NC Department of Environment, Health, and Natural Resources. Raleigh, North Carolina Van den Berg, M. et al. 1998. Toxic Equivalency Factors (TEFs) for PCBs, PCDDs, PCDFs for Humans and Wildlife. Environmental Health Perspectives 106: 775-792. Van den Berg, M. et al. 2006. The 2005 World Health Organization Reevaluation of Human and Mammalian Toxic Equivalency Factors for Dioxins and Dioxin -Like Compounds. Toxicological Sciences 93(2): 223-241. 24 DIOXIN MONITORING STRATEGY Monitoring Strategy for International Paper Company at Riegelwood, North Carolina Composite Sample Guidance All fish samples will be composited to maximize the number of sampled individuals and the potential of sampling contaminated fish. Composite samples will consist of single species, ideally represented by a maximum of ten individual fish. Composites will be prepared by combining fillet fish tissue from similar sized individual fish, with a preference for larger fish. Individual length and weight (metric) will be recorded for each fish and the average weight and length for composites will be calculated. Whole fish tissue analysis is not required. Fillets will be prepared by leaving skin on and removing scales for most species, with the exception of catfish which will be skinned. Individual fish will be identified to species. A sufficient quantity of each (un -extracted) composite sample will be retained and archived (frozen) for a period of three months following submission of the final report. Sample Collections Total laboratory samples to be analyzed = 13 (12 samples and one duplicate) Sampling Site 1 - Cape Fear River in the vicinity of SR 1730 Bladen County Four composite samples will be analyzed for dioxin at this station: -one composite sample for largemouth bass with sunfish as fallback species, -one composite sample for bluegill with other sunfish as fallback species (redbreast, redear, etc.), -one composite sample for catfish (flatheads, channels, blue, other) or carp, -one composite sample for catfish (flatheads, channels, blue, other) with other edible flnfish as fallback species. Sampling Site 2 - Cape Fear River in the vicinity of Bryant Mill Creek Four composite samples will be analyzed for dioxin at this station: -one composite sample for largemouth bass with sunfish as fallback species, -one composite sample for bluegill with other sunfish as fallback species (redbreast, redear, etc.), -one composite sample for catfish (flatheads, channels, blue, other) or carp, -one composite sample for catfish (flatheads, channels, blue, other) with other edible finfish as fallback species. Sampling Site 3 - Cape Fear River in the vicinity of confluence with Black River A-1 Four composite samples will be analyzed for dioxin at this station: -one composite sample for largemouth bass with sunfish as fallback species, -one composite sample for bluegill with other sunfish as fallback species (redbreast, redear, etc.), -one composite sample for catfish (flatheads, channels, blue, other) or carp, -one composite sample for catfish (flatheads, channels, blue, other) with other edible finfish as fallback species. Laboratory Analysis and Reporting Procedures Samples will be analyzed for Dioxin and Furans in accordance with analytical protocols set out in Appendix C of USEPA/Paper Industry Cooperative Dioxin Screening Study (EPA 440/1-88-025, March 1988) or other equivalent analytical protocol approved by EPA. Analysis will include the determination of concentrations of 2,3,7,8 TCDD and 2,3,7,8 TCDF. Dioxin analysis will be performed using high resolution Mass Spectrometry as required by EPA Methods 624, 625, 8290, 1613 or other approved methods. Required Analysis of Dioxins and Furans Matrix Compound Quantitative Limits Fish 2,3,7,8 TCDD 1 part per trillion Fish 2,3,7,8 TCDF 1 part per trillion Results will be reported in ppt with a minimum quantitative limit of 1 ppt. Where the compound is detected at concentrations less than the minimum quantitative limit, an estimate of the concentration will be given. If a compound is not detected it will be so noted. Reports A monitoring report will be submitted that will include: -sampling locations shown on copies of topographical maps (1:2400); -analytical methods and procedures with name of laboratory, -individual specimen description (species, length, weight, condition); -composite descriptions (species, average length, average weight); -All results will be reported as 2,3,7,8 TCDD and 2,3,7,8 TCDF in parts per trillion (ppt). A-2 APPENDIX B NORTH CAROLINA SCIENTIFIC COLLECTION PERMITS Scientific Fish Collecting License AUTHORITY �uN STATUTES ' 113-261,113-262. & 113-272 4 usourls "'�'"�' North Carolina Wildlife Resources Commission Division of Inland Fisheries Phone: (888) 248-6834 MSC 1721 Fax, (919) 707-0028 Raleigh, NC 27699-1721 PERMITTEE/UCENSEEn PERMIT NUMBER {1�J!/ D 17tiSFC00004 SAMUEL COOPER EFFECTIVE EXPIRES CZR, INC 4709 COLLEGE ACRES DR STE 2 APR 2 Q 2017 01/13/2017 12131/2017 WILMINGTON, NC 28403 CZR Incorporated Wilmington, NC Conditions and Authorizations: Print Date, 04/14/2017 The above licensee is authorized to collect the species/organisms by the sampling methods as listed below without restriction to season, size, or creel limits unless otherwise specified under Special Conditions These species/organisms may be collected In the River Basins/Counties listed below Sampling in Collection -Sensitive Waters is not authorized under this license unless specified under Special Conditions or allowed through a Commission -issued Endangered Species Permit. For a current list of Collection -Sensitive Waters, see www,ncwildlife.org/Licensing/fishcollection aspx. The take or possession of federally or state listed endangered, threatened, or special concern species is not authorized under this license except in conjunction with a valid Endangered Species Permit. The licensee is required to comply with all requirements and laws specified by the U.S. Fish and Wildlife Service and National Marine Fisheries Service as they pertain to federal ly-I isted species. For a current list of federally or state listed endangered, threatened, or special concern species, see www_ncwildlife.org/Licensing/fishcollection aspx. SPECIES/ORGANISMS: Amblyopsidae; Amiidae; Anguillidae; Aphredoderidae; Atherinopsidee, Catostomidae, Centrarchidae; Clupeidae; Cottidae; Cyprinidae, Elassomatidae; Esocidne; Fundulidae; Ictaluridae; Lepisosteidae, Moronidae; Percidae; Petromyzontidae, Poeciliidae, Salmonidae, Umbridae RIVER BASINS/COUNTIES: CAPE FEAR - Bladen, Brunswick, Columbus, Pender ROANOKE - Bertie, Martin, Washington TAR-PAMLICO - Beaufort SAMPLING METHOD: Electrofishing, Boat; Net, Dip, Net, Fyke, Net, Gill; Seines; Traps; Trawls, Hook and Line ASSISTANTS: SHERRY BANNER, JULIA BERGER, RANDALL PULLEY, LORRIE LALIBERTE BOSWELL, NICHOLAS TUDOR, AMANDA JOHNSON, ZACH GILSTRAP, MATTHEW MICHEL, BENJAMIN BRINK, TOM FUCIGNA, MARK WESTENDORFF, ERIC MOTE, CHAD COLEY SPECIAL CONDITIONS: This permit/license is non -transferable and expires at midnight on the above specified expiration date. ISSUED BY G�^Vt�V ✓ TITLE Chief 97-SFC000D4 NORIN Endangered Species Permit AUTHORITY CAMkA STATUTES f GS 113-331 -113-337 asou�aA "W�t�� North Carolina Wildlife Resources Commission RULES License Section 15A NCAC 101.0001 -.0006 Phone: (888) 248-6834 1707 Mall Service Center Fax: (919) 707-0292 Raleigh, NC 27699-1700 PERMITTEE/LICENSEE PERMIT NUMBER SAMUEL COOPER D E C E i' 17-ES00022 EFFECTIVE EXPIRES CZR, INC 0 4709 COLLEGE ACRES DR STE 2 l APR Z 0 017 01/0112017 12/31/2017 WILMINGTON, NC 28403 COUNTY DISTRICT CZR Incorporated Type of Permit: Possession, Survey, Take Species Authorized: - Fish, Freshwater Location Where Authorized Activity May Be Conducted: STATEWIDE Conditions and Authorizations: Authorization is for State -listed Species Only Print Date, 04/14/2017 Authorized for incidental take of state -listed fish species while conducting fish collection activities as a designated agent of the NC Wildlife Resources Commission. All mortalities must be reported to this office (919)-707-0050 within twenty-four (24) hours; a written report describing the mortality event must be submitted within._ five (5) work days to Division of Wildlife Managenient/Permils, 1722 Mail Service Center, Raleigh, NC 27699-1722, and all mortalities must be Included in the annual report. All activities must be supervised by the permittee, or by an authorized subpermittee as designated by the permit holder All individuals conducting activities under this permit must carry a copy of this permit and a letter of authorization from the permittee while engaged in permitted activities. All specimens field under the authority of this permit must be retained in the possession of the permittee unless lawfully transferred, released, or destroyed Issuance of this permit does not constitute permission to conduct these activities on any public or private lands, such permission must be obtained separately from the appropriate landowner or land manager before beginning these authorized activities. This permit, neither directly nor by Implication, grants right of trespass. The validity of this permit Is conditioned upon compliance with all applicable local, slate, and federal law A requested amendment to this permit must be submitted in writing when requesting any changes to the permit Failure to meet any of the conditions specified herein may constitute just cause for revocation of the permit or denial of renewal. An annual report is due at the time of renewal to be eligible for renewal The report must be submitted through the online reporting system (httpsJ/ncpaws org/RAPSReporting)_ Failure to submit the report may result in the license not being renewed. This permit/license is non -transferable and expires at midnight on the above specified expiration date. ISSUED BY. 440'."_ � TITLE Permits Supervisor 17-ES00022 North Carolina Division of Marine Fisheries Proof of Purchase RENEW : Scientific or Educational Collection Permit: Permit Number 707778 Permit Number : 707778 NC Residency: Sales Outlet: DMF Morehead City Office Permit Year : 2017 Qualifying Product: Terminal Number: MLHENSLEY Effective Datdrime : 01/01/1017 00.00 Fee : 0.00 Expiration Dstdrime : 12/31/2017 23.59 Status- Active Issue Datell Ime : 12/0812016 14.26 Status Date: 12/08/2016 Permit Holder : 730069 CZR, INC. Business Type: Physical Address : 4709 COLLEGE ACRES DRIVE, Mailing Address : SUITE 2, WILMINGTON, NC, 28403 United States County : New Hanover County: Race.' Eyes : Weight: Gender: Date of Birth : Hair: HeIght : ft. Inches Home Phone: (910) 799-3825 Primary Residence: NC Prior Names : Business Phone: (910) 392-9253 Secondary Residence Fax : (910) 392-9139 Ids : E -Mail : scaoper@e2x-me.com Business Agent: 730085 COOPER, SAMUEL Physical Address : 5425 ANDOVER ROAD, Matting Address WILMINGTON, NC, 28403 United States County : New Hanover County Race : Caucasian Eyes : Brown Weight : 160 Gender: Male Date of Birth 03/1211963 Hair: Brown Height: 5 M 10 Inches Home Phone: (910) 799-3825 Primary Residence: NC Prior Names : Business Phone: (910) 392-9253 Secondary Residence Fax : (910) 392-9139 Ids ; E -M211 : SCOOPER@czr-mc.com Contact Information Contact Person Contact Person DOB Contact Person Telephone # SAMUEL COOPER 03/12/1963 (910) 799-3825 Purpose of Collection NResearch Teuebing Specimens Educational Display (Aquariums) X Other (specify) SECTION 401 WQC MONITORING & DIOXIN SCANS Collectors Partici antld Name DOB Contact Phone JULIA YL BERGER 02/02/1951 (910) 392-9253 SHERRY BANNER 07/21/1943 (910) 392-9253 LORRIE LALIBERTE BOSWELL 06/29/1981 (910) 392-9253 RANDALL PULLEY 02/02/1978 (910) 392-9253 GEORGE H. CARROLL 06/03/1953 (919) 772-8548 CHELSEA MCDOUGALL 07/03/1987 (910) 392-9253 NICHOLAS TUDOR 06/23/1989 (910) 392-9253 AMANDA JOHNSON 05/02/1986 (910) 392-9253 ZACH GH,STRAP 10/07/1986 (910) 392-9253 SAM COOPER 03/12/1963 (910) 392-9253 MATTHEW J. MICHAEL 01/21/1982 (910) 392.9253 DAVID P. CONZONIERI 11/29/1992 (919) 7724548 CHAD R. COLEY 07/24/1969 (919) 772-8548 MITCHELL A- MORTON 10/10/1974 (919) 772-8548 MATTHEW MICHEL 01/21/1981 (910) 392-9253 BENJAMIN BRINK 02/14/1990 (910) 392-9253 MARK WESTENDORFF 09/24/1964 (910) 392-9253 ERIC MOTE 01/05/1993 (910) 392-9253 DMF Morehead City OIEcc, 3441 Arendell St, PO Box 769, Moichead City NC , 28557-0769 MICHELLE 11ENSLE Panted : 12/801016 Page North Carolina Division of Marine Fisheries Proof of Purchase RENEW : Scientific or Educational Collection Permit: Permit Number 707778 Permit Number: 707778 NC Residency: Sales Outlet : DMF Morehead City Office Permit Year.- 2017 Qualifying Product : Terminal Number: MLHENSLEY Effective Datef ime : 01/01/2017 00.00 Fee : 0.00 Expiration DateflTme : 12/31/2017 23.59 Status : Active Issue Date/Time : 12/08/2016 14.26 Status Date: 12/08/2016 Restriction Intbrmation Restriction Type : Gear Code : Species Group: Water Body : RESTRICT TO Gear Quantity: Species Quantity • Gear Units : Species Size - Time • Species Units: Start Time: End Tune: Comments. GEARS OR METHODS: ELECTROFiSHING; GILL NETS; FYKE NETS; TROT LINES; TRAWL; IIOOK AND LINE; FISH TRAPS Restriction Type : Gear Code: Species Group, Water Body: RESTRICTTO Gear Quantity. Species Quantity: Gear Units : Species Size . Time • Species Units: Start Time: End Time: Comments: SPECIES: ALL EXCEPT THOSE LISTED AS ENDANGERED OR THREATENED. Restriction Type: Gear Code : Species Group • Water Body : RESTRICT TO Gear Quantity . Species Quantity: 0200000000-ALBEMAR LE SOUND Gear Units. Species Size - Time Species Units : Start Time* said Time Comments, Restriction Type Gear Code: Species Group : Water Body . RESTRICT TO Gear Quantity: Species Quantity Gear Units ' Species Size : Time. Species Units: Start Time: End Time - Comments: WATER BODY: CAPE FEAR RIVER, SOUTH CREEK TRIBUTARIES, DUCK, PORTER, DURHAM CREEKS, ALBEMARL_ E SOUND, CHOWAN & ROANOKE RIVERS WELCH CREEK Restriction Type: Gear Code : Species Group • Water Body : RESTRICT TO Gear Quantity • Species Quantity ' 0535301000 -SCOTT CREEK Gear Units • Species Size : Time: Species Units: Start Time- End Time- ime•Comments•Restriction Comments- RestrictionType; Gear Code. Species Group: Water Body : RESTRICT TO Gear Quantity: Species Quantity: 0528070201 -BAILEY CREEK Gear Units : Species Size Time. Species Units., Start Time End Time Comments: Restriction Type. Gear Code. Species Group : Water Body : RESTRTCTTO Gear Quantity : Species Quantity: 0528370000 -SOUTH CREEK Gear Units : Species Size. Time Species Units : Start Time: End Time: Comments: Restriction Type: _ Geer Code : - Species Group : Water Body ' RESTRICTTO Gear Quantity : Species Quantity : 0528370100-TOOLEY CREEK Gear Units: Species Size Time: Species units: Start Time: End Time: Comments - Restriction Type . Gear Code: Species Group: Water Body . RESTRICT TO Gear Quantity Species Quantity : 0528360000 -HUDDLES GUT Gear Units ' Species Size. Time. species units: Start Time: End Time: Comments• DMF Morehead City Office, 3441 Arendell St., PO Box 769. Morehead City NC .28557-0769 MICHELLE HENSLE Printed : 12182016 page - North Carolina Division of Marine Fisheries Proof of Purchase RENEW : Scientific or Educational Collection Permit : Permit Number 707778 Permit Number : 707778 NC Residency ¢ Sales Outlet : DMF Morehead City Office Permit Year: 2017 Qualifying Product: Terminal Number: MLHENSLEY Effective Date/Time : 01!01/2017 00.00 Fee : 000 Explration Date/Time : 12/31/201723-59 Status : Active Issue Date/Time : 12/08/2016 14.26 Status Date: 12/08/2016 Restriction e : car e : species Uroup : Water gody : RESTRICT TO Gear Quantity - Species Quantity : 0528370300 -JACKS CREEK Gear Units : Species Size: Time • Species Units , Start Time, End Time: Comments: Restriction Type. Gear Code- Species Group. Water Body: RESTRICT TO Gear Quantity Species Quantity : 0528370201-DRINKWA TER CREEK Gear Units: Species Size: Time ; Species Units: Start Time: End Time: Comments: Rextriction Type: Gcar Codc : Species Group . Water Body RESTRICT TO Gear Quantity : Species Quantity : 0528370200-JACORS CREEK Gear Units Species Size Time: Species Units Start Time. End Time: Comments - Restriction Type : Gear Code : Species Group Water Body - RESTRICT TO Gcar Quantity : Species Quantity : 0528350400 -PORTER CREEK Gear Units - Species Size: Time: Species Units : StartTime: End Time: Comments: Restriction Type : Gear Code Species Group : Water Body - RESTRICT TO Gear Quantity : Species Quantity: 0528063302 -SCOTT CREEK Gear Units : Species Size: Time. Species Units Start Time. End Time: Comments, Restriction Type : Gear Code Species Group Water -Body: RESTRICT TO Gear Quantity . Species Quantity: 0528370900 -LITTLE CREEK Gear Units : Species Size: Time, Species Units - Strut Time: End Time: Comments: Restriction Type: Gear Code : Species Group. Water Body : RESTRICT TO Gear Quantity Species Quantity : 0528410101 -DUCK CREEK Gear Units : Species Size: Time. Species Units: Start Time, End Time: Comments: Restriction Type : Gear Code : Species Group: Water Body: RESTRICT TO Gear Quantity Species Quantity: 0205010000 -MUDDY CREEK Gear Units . Species Size: Time • Species Units: Start Time: End Time. Comments Restriction Type ; Gear Code • Species Group : Water Body RESTRICTTO Gear Quantity, : Species Quantity ; 0208000000-CHOWAN RIVER Gear Units : Species Size: Time Species Units : Start Time: F.nd Time: Comments: DMF Morehead City Olree, 3441 Arendell SL, PO Box 769, Morehead City NC, 28$57.0769 NUCHELLE HENSLE Printed 12/82016 Page: North Carolina Division of Marine Fisheries Proof of Purchase RENEW: Scientific or Educational Collection Permit : Permit Number 707778 Permit Number : 707778 NC Residency: Sales Outlet: DMF Morehead City Office Permit Year: 2017 Qualifying Product : Terminal Number : MLHENSLEY Effective Daterrime : 01/01/2017 00:00 Fee : 000 Expiration DawMme : 12/31/201723-59 Status: Active Issue Dste/Time : 12108/2016 14:26 Status Date : 12/08/2016 RestrictionType Gear Code : 9pecies Group: Water Body RESTRICT• TO Gear quantity : Species Quantity. 0528000000-FAMLICO RIVER Gear Units: Species Size Time: Species Units Start Time. End Tune: Comments. Restriction Type: Gear Code: Species Group Water Body RESTRICTTO Gear Quantity : Species Quantity : 0528010000 -LONG CREEK Gear Units : Species Size., Time: Species Units . Start Time- End Time - Comments: Restriction Type: Gear Code: Species Group : Water Body - RESTRiCT TO Gear Quantity . Species Quantity: 0528350000-DURIIAhl CREEK Gcar Units : Species Size Tune,: Species Units. Start Time. End Time: Comments: Restriction Tyw : Gear Code : Species Group: Water Body. RESTRICT TO Gear Quantity . Species Quantity,. Gear Units Species Size : Time-, Species Units: Start Time End Time: Cotmnenti: UNNAMED TRIBUTARIES TO DURHAM CREEK, BEAUFORT COUNTY, NC Restriction Type: Gear Code • Species Group : Water Body: RESTRICT TO Gear Quantity - Species Quantity . 0210020000AVELCH CREEK Gear Units: Species Size: Time: Species Units Start Time: End Time. Comments: Restriction Type . Gcar Code: Species Group: Water Body RESTRICT TO Gear Quantity : Species Quantity : 0210000000-ROANOKE RIVER Gear Units . Species Size: Time: Species Units : Start Time: End Time: Comments: Restriction Type: Gear Code: Species Group : Water Body: RESTRICT TO Gear Quantity : Species Quantity 1900000000 -CAPE FEAR RIVER Gear Units: Species Size - Time : Species Units Start Iime: End Time• Comments• Restriction Type: Gear Code• SpeciesGroup: Water l3ody- RESTRICT TO Gear Quantity : Species Quantity: 1201020204-NVHITEHU RST CREEK Gear Units: Species Size Time: Species Units Start Time. End Time: Comments, DMF Motehead City Once, 3441 Arendell SL. PO Box 769. Morelteod City NC, 28557-0769 MICHELLE HENSLE Printed' 12BR016 Poge: North Carolina Division of Marine Fisheries Proof of Purchase RENEW: Scientific or Educational Collection Permit: Permit Number 707778 Permit Number : 707778 NC Residency : Sales Outlet : DMF Morehead City Office Permit Year: 2017 Qualifying Product: Terminal Number: MLHENSLEY Effective Date/Time : 01/01/2017 00:00 Fee : 0.00 Expiration Date/Tlmc:12/31/201723:59 Status: Activc Issue Date/Time ; 12/082016 14:26 Status Date: 12/18/2016 Request To Sell? Authorized to Sell? Issued By; Issued Date: DMF Morehead City Office, 3441 Arendcil SL, PO Box 769, Maroheod City NC., 28557-0769 MICHELLE MSLE Printed . 12/8/2016 Page: APPENDIX C LETTER OF TRANSMITTAL/CHAIN OF CUSTODY C�g 4709 COLLEGE ACRES DRIVE ZR SUITE 2 ` INCORPORATED WILMINGTON, NORTH CAROLINA 28403-1725 ENVIRONMENTAL CONSULTANTS TEL 910-392-9253 CHAIN OF CUSTODY FAX 910.392-9139 czrwilm@czr-Inc.com TO: SGS Environmental Services FROM: Randall L. Pulley Attn: Amy Boehm CZR Incorporated, Suite 2 5500 Business Drive 4709 College Acres Drive Wilmington, NC 28405 Wilmington, NC 28403 rpulley cr czr-inc.com DATE: 24 October 2017 RE: International Paper Company, Inc., 2017 Annual Fish Project (IP PO# 11337550 to SGS) TESTS: Analysis of fish tissues for percent lipid (extraction) and 2, 3, 7, 8 TCDD (Dioxin), 2, 3, 7, 8, TCDF (Furan) with full screen of congeners (Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans) via EPA Method 1613B. ENCLOSED ITEMS: Thirteen (13) frozen composite fish tissue (fillets) samples, each fillet wrapped in aluminum foil (dull side toward fish) and enclosed in labeled "zip -lock" plastic bags. Composites are identified below. COMMENTS: - Send one digital version and two hard copies of the report to Randy Pulley/CZR at the above address. We also request permission to include the report as an appendix to CZR's report summarizing the 2017 collection efforts and results. - Forward the invoice to International Paper -Riegelwood, Shared Services, P.O. Box 792, Milford, OH 45150 - A detailed fish composite data table is also enclosed. lRelin ished by: eceived by: g � oa- 2 dJ7 1,530 Date/time D a �1230 Date/time CZR CP# 1340.25 2151 Alternate Al South • SUITE 2000 • JUPITER, FLORIDA 33477-3902 TEL 561-747-7455 • FAX 561-747-7576 • czrinc@czr-inc.com • www.CZRINC.com ti SAMPLE ID # Composite # Site Species (number of fish fillets) I 1 Blue Catfish (10 "A" fillets) 2 1 Blue Catfish (10 "A" fillets) — 2 bags 3 1 Bluegill (10 "A" fillets) 4 1 Bluegill (10 "A" fillets) 5 2 Blue Catfish (8 "A' fillets) 6 2 Blue Catfish (10 "A" fillets) 7 2 Bluegill (10 "A" fillets) g 2 Bluegill (10 "A" fillets) 9 3 Blue Catfish (6 "A" fillets) 10 3 Blue Catfish (7 "A" fillets) 11 3 Bluegill (10 "A" fillets) 12 3 Bluegill (10 "A" fillets) 13 1 Blue Catfish —replicate #1 (10 "B" fillets) COMMENTS: - Send one digital version and two hard copies of the report to Randy Pulley/CZR at the above address. We also request permission to include the report as an appendix to CZR's report summarizing the 2017 collection efforts and results. - Forward the invoice to International Paper -Riegelwood, Shared Services, P.O. Box 792, Milford, OH 45150 - A detailed fish composite data table is also enclosed. lRelin ished by: eceived by: g � oa- 2 dJ7 1,530 Date/time D a �1230 Date/time CZR CP# 1340.25 2151 Alternate Al South • SUITE 2000 • JUPITER, FLORIDA 33477-3902 TEL 561-747-7455 • FAX 561-747-7576 • czrinc@czr-inc.com • www.CZRINC.com ti APPENDIX D TOTAL TEQ (WHO TEFS) / SGS LEVEL II ANALYTICAL LAB REPORTS I it Table D1 Congener data (pg/g and TEF TEQ) by sample analyzed for 2017 study See Figure 2-1 for sampling station locations in the Cape Fear River Values for TEFs are WHO mammalian factors from Van den Berg et al , 2006 Composite 1 2 3 4 5 6 7 8 9 Station Species WHO- Lab TEF SGS SGS SGS SGS SGS SGS SGS SGS SGS Units pg/g TEQ pg/g TEQ pg/g TEQ pglg TEQ pg/g TEQ pg/g TEQ pg/g TEQ pg/g TEQ pg/g TEQ TCDD 2,3,7,8-TCDD 1 0 029 029 044 044 ND(0 09) 000 ND(0 09) 000 0 17 017 025 025 ND(0 08) 000 ND(0 10) 000 ND(0 06) 000 PeCDD 1,2,3,7,8-PeCDD 10 035 035 053 053 ND(0 12) 000 ND(0 12) 000 EMPC(0 16) 0 16 041 041 ND(0 11) 000 ND(0 12) 000 016 016 HxCDD 1,2,3,4,7,8-HxCDD 01 ND(0 10) 000 EMPC(0 32) 003 ND(0 11) 000 ND(0 09) 000 024 002 ND(0 13) 000 ND(0 10) 000 ND(0 10) 000 EMPC(0 09) 001 1,2,3,6,7,8-HxCDD 01 083 008 139 014 ND(0 l 1) 000 ND(0 08) 000 062 006 093 009 ND(0 09) 000 ND(0 10) 000 027 003 1,2,3,7,8,9-HxCDD 01 EMPC(0 48) 005 EMPC(0 70) 007 ND(0 12) 000 ND(0 09) 000 041 004 EMPC(0 40) 004 ND(0 09) 000 ND(0 10) 000 024 002 HpCDD 1,2,3,4,6,7,8-HpCDD 001 369 004 491 005 EMPC(0 27) 000 ND(0 12) 000 220 002 253 003 ND(0 13) 000 ND(0 14) 000 083 001 OCDD 00003 1830 001 2550 001 284 000 ND(0 28) 000 1060 000 903 000 ND(0 35) 000 ND(0 38) 000 EMPC(2 66) 000 TCDF 2,3,7,8-TCDF 01 029 003 038 0 04 ND(0 08) 000 ND(0 08) 000 ND(0 11) 000 ND(0 09) 000 ND(0 08) 000 ND(0 08) 000 ND(0 04) 000 PeCDF 1,2,3,7,8-PeCDF 003 ND(0 08) 000 0 13 000 ND(0 07) 000 ND(0 06) 000 ND(0 07) 000 ND(0 08) 000 ND(0 06) 000 ND(0 08) 000 ND(0 03) 000 2,3,4,7,8-PeCDF 03 032 010 041 012 ND(0 09) 000 ND(0 08) 000 ND(0 08) 000 0 18 005 ND(0 07) 000 ND(0 11) 000 EMPC(0 05) 002 HxCDF 1,2,3,4,7,8-HxCDF 01 ND(0 09) 000 Oil 001 ND(0 07) 000 ND(0 05) 000 ND(0 08) 000 ND(0 06) 000 ND(0 07) 000 ND(0 13) 000 EMPC(0 05) 001 1,2,3,6,7,8-HxCDF 01 ND(0 09) 000 EMPC(0 11) 001 ND(0 07) 000 ND(0 06) 000 ND(0 07) 000 ND(0 06) 000 ND(0 06) 000 ND(0 12) 000 ND(0 04) 000 1,2,3,7,8,9-HxCDF 0 1 ND(0 10) 000 ND(0 08) 000 ND(0 07) 000 ND(0 06) 000 ND(0 08) 000 ND(0 07) 000 ND(0 07) 000 ND(0 14) 000 ND(0 04) 000 2,3,4,6,7,8-HxCDF 0 1 ND(0 12) 000 ND(0 09) 000 ND(0 09) 000 ND(0 07) 000 ND(0 10) 000 ND(0 07) 000 ND(0 08) 000 ND(0 16) 000 ND(0 05) 000 HpCDF 1,2,3,4,6,7,8-HpCDF 001 ND(0 15) 000 028 000 EMPC(0 51) 001 ND(0 08) 000 ND(0 10) 000 ND(0 09) 000 ND(0 06) 000 ND(0 12) 000 008 000 1,2,3,4,7,8,9-HpCDF 001 ND(0 21) 000 ND(0 15) 000 ND(0 12) 000 ND(0 11) 000 ND(0 14) 000 ND(0 11) 000 ND(0 08) 000 ND(0 14) 000 ND(0 05) 000 OCDF 00003 ND(0 33) 000 ND(0 30) 000 091 000 ND(0 34) 000 ND(0 28) 000 ND(0 29) 000 ND(0 27) 000 ND(0 32) 000 ND(0 14) 000 TOTAL TEQ (EMPC - 0) 088 134 000 000 032 083 000 000 022 TOTAL TEQ (EMPC = EMPC) 093 146 001 000 048 087 000 000 024 Legend/Notes (BC) blue catfish, (BG) bluegill, ND(Detection Limit) indicates compound not detected, EMPC(Estimated Maximum Possible Concentration) indicates estimated maximum value due to ion ratio failure, Total TEQs exclude Estimated Maximum possible Concentrations per EPA Method 1613B Table D1 (concluded) Composite 10 11 12 13 Location BC BG BG i BC -replicate Species WHO_ SGS _ SGS SGS SGS Lab TEF Units pg/g TEQ pg/g TEQ pg/g TEQ pg/g TEQ TCDD 2,3,7,8-TCDD 1 0 ND(0 15) 000 ND(O 07) 000 ND(0 07) 000 EMPC(0 22) 022 PeCDD 1,2,3,7,8-PeCDD 1 0 ND(O 11) 000 ND(0 09) 000 ND(0 10) 000 041 041 HxCDD 1,2,3,4,7,8-HxCDD 01 ND(0 10) 000 ND(0 08) 000 ND(O 08) 000 EMPC(O 25) 003 1,2,3,6,7,8-HxCDD 01 059 006 ND(0 09) 000 ND(0 08) 000 100 010 1,2,3,7,8,9-HxCDD 01 044 004 ND(0 09) 000 ND(O 08) 000 061 006 HpCDD 1,2,3,4,6,7,8-HpCDD 001 1 98 002 ND(O 08) 000 NU(U 11) 000 414 004 OCDD 00003 779 000 ND(0 28) 000 ND(O 27) 000 2070 001 TCDF 2,3,7,8-TCDF 01 ND(O 09) 000 ND(O 06) 000 ND(0 09) 000 027 003 PeCDF 1,2,3,7,8-PeCDF 003 ND(0 06) 000 ND(O 05) 000 ND(O 05) 000 EMPC(O 06) 000 2,3,4,7,8-PeCDF 03 ND(0 08) 000 ND(0 05) 000 ND(0 06) 000 028 008 HxCDF 1,2,3,4,7,8-HxCDF 01 ND(O 08) 000 ND(0 05) 000 ND(0 06) 000 ND(O 07) 000 1,2,3,6,7,8-HxCDF 01 ND(O 07) 000 ND(0 05) 000 ND(0 06) 000 ND(O 06) 000 1,2,3,7,8,9-HxCDF 01 ND(O 08) 000 ND(0 06) 000 ND(0 06) 000 ND(O 06) 000 2,3,4,6,7,8-HxCDF 0 1 ND(0 10) 000 ND(0 07) 000 ND(0 08) 000 ND(0 08) 000 HpCDF 1,2,3,4,6,7,8-HpCDF 001 ND(O 09) 000 ND(O 07) 000 ND(0 06) 000 016 000 1,2,3,4,7,8,9-HpCDF 001 ND(0 12) 000 ND(O 10) 000 ND(O 10) 000 ND(0 07) 000 OCDF 00003 ND(0 32) 000 ND(0 21) 000 ND(0 28) 000 ND(0 19) 000 TOTAL TEQ (EMPC - 0) 0 13 000 000 073 TOTAL TEQ (EMPC - EMPC) 013 000 000 097 Legend/Notes (BC) blue catfish, (BG) bluegill, ND(Detecnon Limit) indicates compound not detected, EMPC(Estimated Maximum Possible Concentration) indicates estimated maximum value due to ion ratio failure, Total TEQs exclude Estimated Maximum possible Concentrations per EPA Method 1613B SGS It, This report is approved by Amy Boehm Senior Project Manager FINAL LAB REPORT 2017 Annual Fish Project B1447 08 -Nov -2017 CZR, Inc. Sam Cooper 4709 College Acre Drive Suite 2 Wilmington, NC 28403 Phone.9103929253 Email czrwilm@czr-inc.com 131447 pagod9Gifr4Aonmental Services 5500 Business Drive Wilmington, NC 28405 +1 910 350 1903 1 +1 866 846 8290 www sgs corn Member of the SGS Group (SGS SA) r � I - __ _S _ _ - (When applicable, see QC Annotations for details) Client Project 2017 Annual Fish Project SGS Project # B1447 Analytical Protocol(s) 1613B No Samples Submitted 13 Additional QC Sample(s) 0 No Laboratory Method Blanks 1 No OPRs /Batch CS3 2 Date Received 24 -Oct -17 Condition Received Good Temperature upon Receipt (°C) -5 5, -11 8, -4 8 Extraction within Holding Time Yes Analysis within Holding Time Yes Page 2 of 6 B1447 page 2 of 44 SGS 1 Please see Appendices attached for data qualifier/attribute and lab identifier descriptions which maybe contained in the project Page 3 of 6 B1447 page 3 of 44 1i i B The analyte was found in the method blank, at a concentration that was at least 10% of the concentration in the sample C Two or more congeners co -elute In EDDs, C denotes the lowest IUPAC congener in a co -elution group and additional co-eluters for the group are shown with the number of the lowest IUPAC co-eluter E The reported concentration exceeds the calibration range (upper point of the calibration curve) and is an estimated value EMPC Represents an Estimated Maximum Possible Concentration EMPCs arise in cases where the signal/noise ratio is not sufficient for peak identification (the determined ion -abundance ratio is outside the allowed theoretical range), or where there is a co -eluting interference H/h If the standard recovery is below the method or SOP specified value "H" is assigned If the obtained value is less than half the specified value "h" is assigned J Indicates that an analyte has a concentration below the reporting limit (lowest point of the calibration curve) and is an estimated value ND Indicates a non -detect NR or R Indicates a value that is not reportable PR Due to interference, the associates congener is poorly resolved QI Indicates the presence of a quantitative interference SI Denotes "Single Ion Mode" and is utilized for PCBs where the secondary ion trace has a significantly elevated noise level due to background PFK Responses for such peaks are calculated using an EMPC approach based solely on the primary ion area(s) and may be considered estimates U The analyte was not detected The estimated detection limit (EDL) may be reported for this analyte V The labeled standard recovery was found to be outside of the method control limits Page 4 of 6 B1447 page 4 of 44 _SGS J The reported result is an estimate The value is less than the minimum calibration level but greater than the estimated detection limit (EDL) U The analyte was not detected in the sample at the estimated detection limit (EDL) E The reported concentration is an estimate The value exceeds the upper calibration range (upper point of the calibration curve) D Dilution Data Result was obtained from the analysis of a dilution B Analyte found in the sample and associated method blank C Co -eluting congener Cxx Co -elutes with the indicated congener, data is reported under the lowest IUPAC congener 'Xx' denotes the IUPAC number with the lowest numerical designated congener NR Analyte is not reportable because of problems in sample preparation or analysis V Labeled standard recovery is not within method control limits X Results from re-injection/repeat/second-column analysis EMPC Estimated maximum possible concentration Indicates that a peak is identified but did not meet the method specified ion -abundance ratio AR Indicates use of the archived portion of the sample extract CU Indicates a sample that required additional clean-up prior to MS infection/processing D Indicates a dilution of the sample extract The number that follows the "D" indicates the dilution factor DE Indicates a dilution performed with the addition of ES (extraction standard) solution DUP Designation for a duplicate sample MS Designation for a matrix spike MSD Designation for a matrix spike duplicate RJ Indicates a reinfection of the sample extract S Indicates a sample split The number that follows the "S" indicates the split factor Page 5 of 6 131447 page 5 of 44 SGS Arkansas 88-0682 California (FLAP) 2914 CLIA 34D1013708 Connecticut PH -0258 USDA Soil Permit P330-14-00135 DoD 272601 Florida (Pr,mary NELAP) E87634 ISO 17025/IEC 272601 Louisiana 04115 Maine #2014020 Massachusetts M-NC919 Minnesota (Primary NELAP For Method 23) Lab #037-999-459 Cert #981125 New Jersey NC100 New York 11685 North Carolina DEQ 481 North Dakota R-197 Oregon NC200002 Pennsylvania 68-03675 South Carolina Lab #99029 Cert #99029002 Texas T104704260-13-5 US Coast Guard 16714/159 317/SGS Virginia Lab #460214 Cert #8171 Washington C913 West Virginia 293 Rev 22 -Jan -2016 Page 6 of 6 B1447 page 6 of 44 B1447 - TEQ Project ID: 2017 Annual Fish Project Sample Summary,I Method 16136 P _ _ _ Part 1 _ — -,I Method Comp 1 Comp 2 Comp 3 Comp 4 Comp 5 Comp 6 Comp 7 Comp 8 Comp 9 Comp 10 Comp 11 Comp 12 omp Analyte Blank 152 Site 1 Blue Site 1 Blue Site 1 Site 1 Site 2 Blue Site 2 Blue Site 2 Site 2 Site 3 Blue Site 3 Blue Site 3 Site 3 Site 1 Blue Catfish 61447 Catfish Catfish Bluegill Bluegill Catfish Catfish Bluegill Bluegill Catfish Catfish Bluegill BluegillReplicate - 62 g/g Pg/9 g/g Pg'9 Pg/g Pg/g Pg/g P '9 gig Pg/g Pg/9 gig PgI g/9 2,3,7,8-TCDD (0 0851) 0 286 0 437 (0 0931) (0 0945) 0 171 0 247 (0 0801) (0 0972) (0 0556) (0 153) (0 0688) (0 0732) 10 215] 1,2,3,7,8-PeCDD (0 108) 0 347 0 531 (0 116) (0 115) [0 163] 0 411 (0 109) (0 121) 0 155 (0 114) (0 0893) (0 1) 0 408 1,2,3,4,7,8-HxCDD (0 0866) (0 102) [0 3231 (0 109) (0 0901) 0 236 (0 128) (0 098) (0 103) [0 0866] (0 0979) (0 0842) (0 0817) [0 2541 1,2,3,6,7,8-HxCDD (0 0815) 0 828 1 39 (0 106) (0 0821) 0 624 0 926 (0 0933) (0 0951) 0 268 0 587 (0 0859) (0 0778) 0 997 1,2,3,7,8,9-HxcoD (0 0874) [0 4791 [0 6951 (0 117) (0 0914) 0 409 103951 (0 094) (0 104) 0 241 0 443 (0 0908) (0 078) 0 613 1,2,3,4,6,7,8-HpCDD (0 128) 369 491 [0 2681 (0 116) 22 253 (0 131) (0 136) 0 828 1 98 (0 08) (0 112) 414 OCDD (0 295) 183 255 284 (0 283) 106 903 (0 349) (0 375) [2 661 779 (0 284) (0 269) 207 2,3,7,8-TCDF (0 0659) 0 285 0 377 (0 0779) (0 0817) (0 112) (0 0936) (0 0751) (0 0754) (0 0384) (0 0905) (0 0561) (0 0913) 0 271 1,2,3,7,8-PeCDF (0 0464) (0 075) 013 (0 0692) (0 0645) (0 067) (0 0754) (0 0593) (0 083) (0 0329) (0 0635) (0 0457) (0 0506) [0 0613] 2,3,4,7,8-PeCDF (0 0588) 0 323 0 414 (0 0856) (0 0841) (0 0849) 0 183 (0 0723) (0 109) [0 05141 (0 082) (0 0533) (0 0578) 0 276 1,2,3,4,7,8-HxCDF (0 0539) (0 0861) 0 112 (0 0686) (0 0548) (0 077) (0 0646) (0 0656) (0 13) [0 04591 (0 077) (0 0483) (0 0588) (0 0669) 1,2,3,6,7,8-HxCDF (0 0514) (0 0857) [0 109] (0 0651) (0 0551) (0 0714) (0 0633) (0 0648) (0 122) (0 0397) (0 0702) (0 0537) (0 0615) (0 0622) 2,3,4,6,7,8-HxCDF (0 0566) (0 0957) (0 0788) (0 0711) (0 0601) (0 0809) (0 0669) (0 0676) (0 138) (0 0436) (0 0837) (0 0577) (0 0631) (0 0647) 1,2,3,7,8,9-HxCDF (0 0678) (0 122) (0 0914) (0 0872) (0 0705) (0 101) (0 0735) (0 0758) (0 155) (0 0547) (0 0973) (0 068) (0 0759) (0 0767) 1,2,3,4,6,7,8-HpCDF (0 0678) (0 151) 0 278 [0 51 ] (0 0835) (0 0997) (0 0857) (0 0615) (0 116) 00833 (0 0898) (0 0723) (0 0621) 0 159 1,2,3,4,7,8,9-HpCDF (0 0947) (0 209) (0 149) (0 122) (0 114) (0 139) (0 11) (0 0806) (0 138) (0 0502) (0 121) (0 102) (0 0991) (0 0699) OCDF (0 294) (0 327) (0 299) 0 808 (0 344) (0 279) (0 294) (0 269) (0 317) (0 143) (0 322) (0 211) (0 278) (0 186) WHO -2005 TEQ (ND=O, EMPC=O) 0 0 884 134 00011 0 0 323 0 834 0 0 0 215 0 125 0 0 0 728 WHO -2005 TEQ (ND=O, EMPC=EMPC) 0 0 932 146 000888 0 0 485 0 873 0 0 0 244 0 125 0 0 0 971 WH0-2005 TEQ (ND=DU2, EMPC=O) 0 135 0 912 1 35 0.155 016 036 086 014 0 175 0 252 0 299 0 116 0 127 0 742 WHO -2005 TEQ (ND=DL/2, EMPC=EMPC) 0 135 0 959 147 0 163 016 0 522 09 014 0 175 0 282 0.299 0 116 0 127 0 985 WHO -2005 TEQ (ND=DL, EMPC=EMPC) 027 0 987 147 0 317 0 299 066 0 927 0 279 035 0 319 0 472 0 233 0 254 0 999 Checkcode 593-496-WQ 930 -914 -DSC 216-991-YW 623-441-SFL 220 -674 -CHH 518-023-XFH 164-822-XCB 137-923-YJH 410-480-BXX 483-695-RGW 119-971-YMZ 645-856-GGZ 393 -541 -HTB 309-118-FZT Lab ID MB1 15382 -DF -SDS 8144] 15262 DF 001 B1117_15262 DF 002 8-7-15282 DF 003 B— 1528] DF 001 81411 15362 DF_Oo5 81447_15263 DF 008 8-7- 5262 DF -007 B1N]_15282 DF 008 81147 1526] DF 008 —7-2 DF 010 —7-15262_DF_011 B-7_15262_DF 012 81447 15262 -DF 019 () _ D81447 page 7 of 44 [ ] = EMPC B1447 - TEQ Project ID: 2017 Annual Fish Project Sample Summary Method 1613B SMIL Part 2 - ---- MethodComp Comp Comp Comp Comps Comp Comp Comp Comp Comp10 Comp11 Comp12 omp Analyte Blank 152 Site 1 Blue Site 1 Blue Site 1 Site 1 Site 2 Blue Site 2 Blue Site 2 Site 2 Site 3 Blue Site 3 Blue Site 3 Site 3 Site 1 Blue Catfish - 81447 Catfish Catfish Bluegill Bluegill Catfish Catfish Bluegill Bluegill Catfish Catfish Bluegill Bluegill 62 Replicate P9�9 g/9 /g Pg/g Pg/9 gig P /g Pg/9 PgIg g/ Pg/9 PgIg Pg/g Totals TCDDs 0 0 661 0 966 0 0 0 171 0 478 0 0 0 0 0 0 0 315 PeCDDs 0 0 347 0 531 0 0 0 0 411 0 0 0 155 0 0 0 0 408 HxCDDs 0 0 828 1 39 0 0 127 0 926 0 0 0 508 1 03 0 0 161 HpCDDs 0 369 491 0 0 22 253 0 U 0 828 1 98 0 0 414 OCDD 0 183 255 284 0 106 903 0 0 0 779 U 0 207 TCDFs 0 0 593 0 905 0 0 0 0 0 0 0 0 0 0 0 271 PeCDFs 0 0 323 0 834 0 0 0 0 183 0 0 0 0 0 0 045 HxCDFs 0 0 0 556 0 0 0 0 0 0 00734 0 0 0 032 HpCDFs 0 0 0 278 0 0 0 0 0 0 00833 0 0 0 0 159 OCDF 0 0 0 0 808 0 0 0 0 0 0 0 0 0 0 Total PCDDIFs (ND=O, EMPC=O) 0 24.7 368 3.65 0 142 13.6 0 0 1 65 108 0 0 283 Total PCDD/Ps (ND=O, EMPC=EMPC) 0 25.5 378 443 0 146 141 0 0 165 449 108 0 0 301 Total PCDD/Fs (2378-X ND=DL, EMPC=EMPC) 173 1 267 384 1 562 189 157 151 1 85 258 1 495 123 155 169 306 Total 2378s (ND=O, EMPC=O) 0 24 34 3.65 0 14.2 13.3 0 0 1.57 108 0 0 275 Total 2378s (ND=O 6, EMPC=O) 0 865 24.7 346 436 0.943 14.9 13.9 0 923 1.21 1 96 116 0 775 0 845 27.9 Total 2378s (ND=1, EMPC=O) 1.73 254 35 5.07 189 166 145 1 85 241 235 123 166 169 282 Total 23789 (ND=O, EMPC=1) 0 24.5 352 443 0 144 137 0 0 441 108 0 0 281 Total 2378s (ND=O 5, EMPC=1) 0 865 251 355 5.02 0 943 149 142 0 923 121 4.64 116 0.775 0 845 283 Total 2378s (ND -1, EMPC=1) 173 1 258 1 358 1 5.62 1 1.89 15.5 14.8 1 185 1 241 1 487 1 123 165 1 1.69 28.6 Checkcode 593496-WQ 930 -914 -DSC 216-991-YW 623-441-SFL 220 -674 -CHH 518-023-XFH 164-822-XCB 137-923-YJH 410-480-BXX 483-695-RGW 119-971-YMZ 645-856-GGZ 393 -541 -HTB I 309-118-FZT Lab ID MBI I5262_DFSDS 8-7-1— DF 001 B-7 15262 DFO02 5-7 15-2 DF OOO 0--15203_DF 004 8-7-15262DF 005 Bt %15262_DF ONB —7 1526] DF D07 B1i07_15262 DF 008 BI"7 1 2_DF o09 B-7 15262 DF_D10 8-71-2 DF Oil B1M]_15 LDF 012 B-7_1— DF 013 Total 2378s = Sum of 17 2378 -substituted PCDDIPCDF congeners (SARA 313) 0 _ %1447 page 8 of 44 [ ] = EMPC B1447 - TEQ Project ID: 2017 Annual Fish Project Sample Summary Method 16136 Part 3Method Comp 1 Comp 2 Comp 3 Comp 4 Comp 5 Comp 6 Comp 7 Comp 8 Comp 9 Comp 10 Comp'll 1 Cop 1 m 2 Analyte Blank 81Bla 152 Site 1 Blue Site 1 Blue Site 1 Site 1 Site 2 Blue Site 2 Blue Site 2 Site 2 Site 3 Blue Site 3 Blue Site 3 Site 3 Site 1 Blue Catfish - Catfish Catfish Bluegill Bluegill Catfish Catfish Bluegill Bluegill Catfish Catfish Bluegill Bluegill 62 Replicate P9/9 PAP9�9 P9�9 P9�9 P9�9 P9�9 P9�9 Pg/9 PA PA P9/9 P9/9 P9/9 Other PCDD/Fs (ND=O, EMPC=O) Other TCDD 0 0 375 0 529 0 0 0 0 231 0 0 0 0 0 0 0 315 Other PeCDD 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Other HxCDD 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Other HpCDD 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Other TCDF 0 0 309 0 528 0 0 0 0 0 0 0 0 0 0 0 Other PeCDF 0 0 029 0 0 0 0 0 0 0 0 0 0 0 174 Other HxCDF 0 0 0 444 0 0 0 0 0 0 00734 0 0 0 032 Other HpCDF 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Other PCDD/Fs (ND=O, EMPC=EMPC) Other TCDD 0 0 375 0 529 0 0 0 177 0 231 0 0 0 0 0 0 0 315 Other PeCDD 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Other HxCDD 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Other HpCDD 0 0 0 639 0 0 0 0 0 0 0 0 0 0 0 375 Other TCDF 0 0 309 0 703 0 0 0 0 0 0 0 0 0 0 0 669 Other PeCDF 0 0 029 0 0 0 0 0 0 0 0 0 0 0 333 Other HxCDF 0 0 289 0 444 0 0 0 0 124 0 0 165 00734 0 0 0 032 Other HpCDF 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Checkcode 593-496-WQ 930 -914 -DSC 216-991-YW 623-441-SFL 220 -674 -CHH 518-023-XFH 164-822-XCB 137-923-YJH 410-480-BXX 483-695-RGW 119-971-YMZ 645-856-GGZ 393 -541 -HTB 309-118-FZT Lab ID MB1_1516Z DF SDS B1H]_15362 DF 001 BiN]_1'-12 DF_0-2 81111 15203 DF 009 B1Hi_15262_DF 001 8111] 15162 DF_005 B11C3 15382_DF_006 Bt14i 16383 DF 003 B1H7_15363 DF 000 B1N3 15303 DF 009 8141] 15363_DF_O10 BMT 15203 -DF 011 Bt 15363_DF 013 B1N]_15]6ZDF_Ot) () = C81447 page 9 of 44 [ ] = EMPC B1447 - TEQ Project ID: 2017 Annual Fish Project Sample Summary Method 1613B Part 5 (DLs) Method Comp 1 Comp 2 Comp 3 Comp 4 Comp 5 Comp 6 Comp 7 Comp 8 Comp 9 Comp 10 Comp 11 Comp 12 omp Analyte Blank Site 1 Blue Site 1 Blue Site 1 Site 1 Site 2 Blue Site 2 Blue Site 2 Site 2 Site 3 Blue Site 3 Blue Site 3 Site 3 Site 1 Blue B1447_752 Catfish Catfish Bluegill Bluegill Catfish Catfish Bluegill Bluegill Catfish Catfish Bluegill Bluegill Catfish - 62 Replicate '9 /9 P9/9 Pg'g P9I9 Pg/9 Pg/g P9/9 /9 9/9 9/9 P9/9 PA 9/ 2,3,7,8-TCDD 00851 00986 0 107 00931 00945 0 187 00935 00801 00972 00556 0 153 00688 00732 00635 1,2,3,7,8-PeCDD 0 108 0 178 0 121 0 116 0 115 0 145 0 126 0 109 0 121 00445 0 114 00893 01 00743 1,2,3,4,7,8-HXGDD 00866 0 102 0 125 0 109 00901 0 114 0 128 0 098 0 103 00458 00979 00842 00817 00587 1,2,3,6,7,8-HxCDD 00815 00971 0 127 0 106 00821 0 108 0 122 00933 00951 00472 00986 00859 00778 00576 1,2,3,7,8,9-HxCDD 00874 0 106 0 128 0 117 00914 U 12 0 125 0,094 0 104 00507 0 101 00908 0 078 00602 1,2,3,4,6,7,8-HpCDD 0 128 0206 0 186 015 0 116 0 214 017 0 131 0 136 U 0703 0 148 0.08 0 112 0 126 OCDD 0 295 0 536 0 314 0 343 0 283 0 497 031 0 349 0 375 0201 0 445 0 284 0 269 0 18 2,3,7,8-TCDF 00659 00965 0 112 00779 00817 0 112 00936 00751 00754 00384 00905 00561 00913 0 103 1,2,3,7,8-PeCDF 00464 0 075 00795 00692 00645 0 067 00754 00593 0 083 00329 00635 00457 00506 00379 2,3,4,7,8-PeCDF 00588 00889 00949 00856 00841 00849 0 093 00723 0 109 00325 0 082 00533 00578 00444 1,2,3,4,7,8-HxCDF 00539 00861 00705 00686 00548 0 077 00646 00656 013 00391 0 077 00483 00588 00669 1,2,3,6,7,8-HxCDF 00514 00857 00743 00651 00551 00714 00633 00648 0 122 00397 00702 00537 00615 00622 2,3,4,6,7,8-HxCDF 00566 00957 00788 00711 00601 00809 00669 00676 0 138 00436 00837 00577 00631 00647 1,2,3,7,8,9-HxCDF 00678 0 122 00914 00872 00705 0 101 00735 00758 0 155 00547 00973 0 068 00759 00767 1,2,3,4,6,7,8-HpCDF 00678 0 151 0 103 00803 00835 00997 00857 00615 0 116 00371 00898 00723 00621 00544 1,2,3,4,7,8,9-HpCDF 00947 0209 0 149 0 122 0 114 0 139 Oil 00806 0 138 00502 0 121 0 102 00991 00699 ACDF 0 294 0 327 0 299 0 336 0 344 0 279 0 294 0 269 0 317 0 143 0 322 0 211 0 278 0 186 Total TCDD 00851 00986 0 107 00931 00945 0 187 00935 00801 00972 00556 0 153 00688 00732 00635 Total PeCDD 0 108 0 178 0 121 0 116 0 115 0 145 0 126 0 109 0 121 00445 0 114 00893 01 00743 Total HxCDD 00849 0 102 0 127 Oil 00876 0 114 0 124 00947 01 00478 00991 00868 00789 00587 Total HpCDD 0 128 0206 0 186 015 0 116 0 214 017 0 131 0 136 00703 0 148 008 0 112 0 126 Total TCDF 00659 00965 0 112 00779 0 0817 0 112 00936 00751 00754 00384 00905 00561 00913 0 103 Total PeCDF 00519 00812 00864 00765 00732 0 075 00833 0 065 00948 00327 00717 00491 00539 0 041 Total HxCDF 00569 00959 00782 00723 00596 00817 00668 00682 0 135 00436 00812 00563 00645 00671 Total HpCDF 008 0 177 0 124 1 00987 1 00978 1 0 118 00973 1 00703 1 0 126 1 00431 0 104 0 086 00787 0 0619 Checkcode 593-496-WQ 930 -914 -DSC 216-991-YW 623-441-SFL 220 -674 -CHH 518-023-XFH 164-822-XCB 137-923-YJH 410-480-BXX 483-695-RGW 119-971-YMZ 645-856-GGZ 393 -541 -HTB 309-118-FZT Lab ID MBI-16MDF SDS B11"7 15]63 DF_ODI -7 16282 DF 003 B1"7 15282 OF - 003 Bt"7 15381 DF 001 81"7 15263 DF 005 B -71 -2 -DF -ON B1"7 1526t_DF - -7 15]62 DF 000 B1"715263 DF O00 8-7-1- DF 010 -715262 DF 011 61"7.16262 DF 012 D- 15M3 DF 013 11= D81447 page 10 of 44 [ ] = EMPC 1.6 1.4 1.2 1 1 1a WHO-2005-TEO Project ID: 2017 Annual Fish Project B1447 ■ ND=O; EMPC=O ■ ND=O; EMPC=EMPC ND=DL/2; EMPC=O ■ ND=DL/2; EMPC=EMPC ■ ND=DL; EMPC=EMPC m 0.8 CL 0.6 0.4 0.2 0 - ---- --- _ --- -- - -- — ---------- --- ,— -- - - -- - - -- — ---- — - _..- 1yti6'L L� 0 ePo 6 Qp1 \ve \�e e1 e1 \ve \11e e1 eti 0y y0 L0 Sc 5�ti y0 y0 Sit Sic 30 S0e FQ3 FQA See S�tie FQ 1 FQ6 S��e S��e Q11 Q1ti\�Sr e�roa� G°0Q1 0111 o�Q10 `oF Loi` e\JeLa C� c e1 Q1 Low B1447 page 11 of 44 a 3$' 40 35 X61 30 25 Totals ■Total PCDD/Fs (ND=O; EMPC=O) Project ID: 2017 Annual Fish ProjC(Aal PCDD/Fs (ND=O; EMPC=EMPC) 131447 ■ Total PCDD/Fs (2378-X ND=DL; EMPC=EMPC) � y 1 a 20 15 10 \ y6ti ` aqS 5 M i 0 1yti61 `a�i`5c La`Zr 0\Jeg�\ 6\�eQ��\ `a�C`Sr `ac�`Sr e\oe6�\ 0\oeg�\ ca�i`5�. calf\Sr ap 1 . 0\oe 0\oe \�e1 \`e1 0\oe 0\Je \�e3 `�e3 Q eQ X01 �e1 N. �S aS �eL p1. -1S 9S� $S Ne'h �e� 115 1LS �i�Sr Go�Q65� CoQ CoQ o�Q1p5� `o�Q `o�Q JeCati 81447 page 12 of 44 Mean Recoveries of Extraction Standards (N=14) Project ID: 2017 Annual Fish Project ■ Mean Std. Dev. B1447 100 90 80 70 60 50 40 30 20 10 0 ti e`�F ¢`�Q +`�Q 1 1 1� 1+ I-1 -I y B1447 page 13 of 44 Mean Recoveries of Clean -Up Standards (N=14) Project ID: 2017 Annual Fish Project ■ Mean Std. Dev. B1447 page 14 of 44 .041 4V B1447 page 14 of 44 I ■ ■ n 0 m V O LO N m co CL n a v m M Mr i I I 1 l � l ■ ■ 1 I I I I I 1 3 I I I 1 I ■ ■ I ■ ■I■ ■' ■ i 1 a I I I ■ i I I I I 1 I I I I I 1 3 I I I I I i■ I I� I ■ ■I■ ■' ■ i 1 I I: _ :: I■ i_ __ 1 !■ I 11 11 I■ I I • I ■ I I I I I I I f 1 1 Ir ■ I 1 I■ I m I IF' ■ I 1 1■ I !! f 1 In /--j I 1 I,. 0 N m 0 C CL m W 03 W O v I� ■ I 1 I I 1 I I ! 1 I I I 1 I I I I i I i ■ 1 I 1 I i I 1 I N 0 t co A A J N t0 CD O_ A A W A O_ V •rims,..da f ■ ■ r ' 1 •rims,..da f SM: ■ r- 0 LO C3 co MEN I ■ I Mll- r- 0 LO C3 co m OEM A rl- rt IQ co e r 0 n m m co a Vw u 0 N N 0) c0 Q n V V m Sample ID: Comp 1 Site 1 Blue Catfish Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: 81447 Date Received: 24 -Oct -2017 Project ID: 2017 Annual Fish Project Weight/Volume: 11.40 g Lab Sample ID B1447_15262_DF_001 Date Extracted: 02 -Nov -2017 Date Collected: 07 -Sep -2017 % Lipid: 5.0% QC Batch No: 15262 Date Analyzed: 06 -Nov -2017 Split: - Dilution: - Time Analyzed: 20:54:51 Analyte Conc. (pg/g) DL (pg/g) EMPC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD 0.286 J ES 2378 -TCDD 86.6 12378-PeCDD 0.347 J ES 12378-PeCDD 85.1 123478-HxCDD ND 0.102 ES 123478-HxCDD 89.4 123678-HxCDD 0.828 J ES 123678-HxCDD 94.4 123789-HxCDD EMPC 0.479 J ES 123789-HxCDD 95.3 1234678-HpCDD 3.69 ES 1234678-HpCDD 93.7 OCDD 18.3 ES OCDD 84.8 2378-TCDF 0.285 J ES 2378-TCDF 86.6 12378-PeCDF ND 0.075 ES 12378-PeCDF 107 23478-PeCDF 0.323 J ES 23478-PeCDF 86.7 123478-HxCDF ND 0.0861 ES 123478-HxCDF 94.5 123678-HxCDF ND 0.0857 ES 123678-HxCDF 91.9 234678-HxCDF ND 0.0957 ES 234678-HxCDF 95.5 123789-HxCDF ND 0.122 ES 123789-HxCDF 89.9 1234678-HpCDF ND 0.151 ES 1234678-HpCDF 94.2 1234789-HpCDF ND 0.209 ES 1234789-HpCDF 93.7 OCDF ND 0.327 ES OCDF 82.3 Totals Standard CS Recoveries CS 37CI-2378-TCDD 87 Total TCDD 0.661 0.661 CS 12347-PeCDD 97.1 Total PeCDD 0.347 0.347 CS 12346-PeCDF 89.6 Total HxCDD 0.828 1.31 CS 123469-HxCDF 98.6 Total HpCDD 3.69 3.69 CS 1234689-HpCDF 98.5 Total TCDF 0.593 0.593 Total PeCDF 0.323 0.323 Total HxCDF ND 0.289 Total HpCDF ND 0.177 ND Total PCDD/Fs 24.7 25.5 WHO -2005 TEQs 5500 Business Drive Wilmington, NC 28405, USA TEQ: ND=O TEQ: ND=DU2 0.884 0.912 0.195 0.932 0.959 TEQ: ND=DL 0.939 0.391 0.987 www.us.sgs.com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 930 -914 -DSC SGS North America - DF v0.30 Report Created: 07 -Nov -2017 16:50 Analyst: TF 81447 page 22 of 44 Sample ID: Comp 2 Site 1 Blue Catfish Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: B1447 Date Received: 24 -Oct -2017 Project ID: 2017 Annual Fish Project Weight/Volume: 11.17 g Lab Sample ID B1447_15262_DF_002 Date Extracted: 02 -Nov -2017 Date Collected: 07 -Sep -2017 % Lipid: 7.6% QC Batch No: 15262 Date Analyzed: 06 -Nov -2017 Split: - Dilution: - Time Analyzed: 21:42:15 Analyte Conc. (pg/g) DL (pg/g) EMPC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD 0.437 J ES 2378 -TCDD 84 12378-PeCDD 0.531 J ES 12378-PeCDD 80.1 123478-HxCDD EMPC 0.323 J ES 123478-HxCDD 98.5 123678-HxCDD 1.39 J ES 123678-HxCDD 95.7 123789-HxCDD EMPC 0.695 J ES 123789-HxCDD 100 1234678-HpCDD 4.91 ES 1234678-HpCDD 90.2 OCDD 25.5 ES OCDD 79.8 2378-TCDF 0.377 J ES 2378-TCDF 80.1 12378-PeCDF 0.13 J ES 12378-PeCDF 90 23478-PeCDF 0.414 J ES 23478-PeCDF 73.5 123478-HxCDF 0.112 J ES 123478-HxCDF 96 123678-HxCDF EMPC 0.109 J ES 123678-HxCDF 94.3 234678-HxCDF ND 0.0788 ES 234678-HxCDF 98.9 123789-HxCDF ND 0.0914 ES 123789-HxCDF 98.3 1234678-HpCDF 0.278 J ES 1234678-HpCDF 89.7 1234789-HpCDF ND 0.149 ES 1234789-HpCDF 92.4 OCDF ND 0.299 ES OCDF 78.5 Totals Standard CS Recoveries CS 37CI-2378-TCDD 86.8 Total TCDD 0.966 0.966 CS 12347-PeCDD 89.4 Total PeCDD 0.531 0.531 CS 12346-PeCDF 78.4 Total HxCDD 1.39 2.41 CS 123469-HxCDF 105 Total HpCDD 4.91 5.55 CS 1234689-HpCDF 98.4 Total TCDF 0.905 1.08 Total PeCDF 0.834 0.834 Total HxCDF 0.556 0.665 Total HpCDF 0.278 0.278 Total PCDD/Fs 35.8 37.8 WHO -2005 TEQs 5500 Business Drive SGS Wilmington, NC 28405, USA TEQ: ND=O TEQ: ND=DU2 1.34 1.35 0.172 1.46 1.47 TEQ: ND=DL 1.36 0.344 1.47 www.us.sgs.com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 216-991-YVV SGS North America - DF v0.30 Report Created: 07 -Nov -2017 16:53 Analyst: TF B1447 page 23 of 44 Sample ID: Comp 3 Site 1 Bluegill Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: B1447 Date Received: 24 -Oct -2017 Project ID: 2017 Annual Fish Project Weight/Volume: 11.24 g Lab Sample ID B1447_15262_DF_003 Date Extracted: 02 -Nov -2017 Date Collected: 07 -Sep -2017 % Lipid: 0.3% QC Batch No: 15262 Date Analyzed: 06 -Nov -2017 Split: - Dilution: - Time Analyzed: 22:29:40 Analyte Conc. (pg/g) DL (pg/g) EMPC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD ND 0.0931 ES 2378 -TCDD 91.8 12378-PeCDD ND 0.116 ES 12378-PeCDD 90.2 123478-HxCDD ND 0.109 ES 123478-HxCDD 97.9 123678-HxCDD ND 0.106 ES 123678-HxCDD 105 123789-HxCDD ND 0.117 ES 123789-HxCDD 102 1234678-HpCDD EMPC 0.268 J ES 1234678-HpCDD 94.1 OCDD 2.84 J ES OCDD 95.3 2378-TCDF ND 0.0779 ES 2378-TCDF 80 12378-PeCDF ND 0.0692 ES 12378-PeCDF 102 23478-PeCDF ND 0.0856 ES 23478-PeCDF 82.5 123478-HxCDF ND 0.0686 ES 123478-HxCDF 98.9 123678-HxCDF ND 0.0651 ES 123678-HxCDF 98.3 234678-HxCDF ND 0.0711 ES 234678-HxCDF 98 123789-HxCDF ND 0.0872 ES 123789-HxCDF 103 1234678-HpCDF EMPC 0.51 J ES 1234678-HpCDF 106 1234789-HpCDF ND 0.122 ES 1234789-HpCDF 98.5 OCDF 0.808 J ES OCDF 92.3 Totals Standard CS Recoveries CS 37CI-2378-TCDD 99 Total TCDD ND 0.0931 ND CS 12347-PeCDD 111 Total PeCDD ND 0.116 ND CS 12346-PeCDF 88.7 Total HxCDD ND 0.11 ND CS 123469-HxCDF 109 Total HpCDD ND 0.268 CS 1234689-HpCDF 102 Total TCDF ND 0.0779 ND Total PeCDF ND 0.0765 ND Total HxCDF ND 0.0723 ND Total HpCDF ND 0.51 Total PCDD/Fs 3.65 4.43 WHO -2005 TEQs 5500 Business Drive TEQ: ND=O 0.0011 0.00888 TEQ: ND=DL/2 0.155 0.155 0.163 Wilmington, NC 28405, USA TEQ: ND=DL 0.309 0.31 0.317www.uss --�� 9 s com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 623-441-SFL SGS North America - DF v0.30 Report Created: 07 -Nov -2017 16:53 Analyst: TF 81447 page 24 of 44 Sample ID: Comp 4 Site 1 Bluegill Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: B1447 Date Received: 24 -Oct -2017 Project ID: 2017 Annual Fish Project Weight/Volume: 11.89 g Lab Sample ID B1447_15262_DF_004 Date Extracted: 02 -Nov -2017 Date Collected: 07 -Sep -2017 % Lipid: 0.7% QC Batch No: 15262 Date Analyzed: 06 -Nov -2017 Split: - Dilution: - Time Analyzed: 23:17:05 Analyte Conc. (pg/g) DL (pg/g) EM PC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD ND 0.0945 ES 2378 -TCDD 87.9 12378-PeCDD ND 0.115 ES 12378-PeCDD 79.8 123478-HxCDD ND 0.0901 ES 123478-HxCDD 100 123678-HxCDD ND 0.0821 ES 123678-HxCDD 100 123789-HxCDD ND 0.0914 ES 123789-HxCDD 101 1234678-HpCDD ND 0.116 ES 1234678-HpCDD 99.7 OCDD ND 0.283 ES OCDD 91.1 2378-TCDF ND 0.0817 ES 2378-TCDF 82.5 12378-PeCDF ND 0.0645 ES 12378-PeCDF 90.4 23478-PeCDF ND 0.0841 ES 23478-PeCDF 72.2 123478-HxCDF ND 0.0548 ES 123478-HxCDF 97.7 123678-HxCDF ND 0.0551 ES 123678-HxCDF 99.2 234678-HxCDF ND 0.0601 ES 234678-HxCDF 100 123789-HxCDF ND 0.0705 ES 123789-HxCDF 102 1234678-HpCDF ND 0.0835 ES 1234678-HpCDF 99.1 1234789-HpCDF ND 0.114 ES 1234789-HpCDF 103 OCDF ND 0.344 ES OCDF 86.9 Totals Standard CS Recoveries CS 37CI-2378-TCDD 93.3 Total TCDD ND 0.0945 ND CS 12347-PeCDD 94.3 Total PeCDD ND 0.115 ND CS 12346-PeCDF 80.9 Total HxCDD ND 0.0876 ND CS 123469-HxCDF 113 Total HpCDD ND 0.116 ND CS 1234689-HpCDF 107 Total TCDF ND 0.0817 ND Total PeCDF ND 0.0732 ND Total HxCDF ND 0.0596 ND Total HpCDF ND 0.0978 ND Total PCDD/Fs ND ND WHO -2005 TEQs 5500 Business Drive TEQ: ND=O 0 0 TEQ: ND=DU2 0.15 0.15 0.15 Wilmington, NC 28405, USA TEQ: ND=DL 0.299 0.299 0.299 www.us.sgs.com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 220 -674 -CHH SGS North America - DF v0.30 Report Created: 07 -Nov -2017 16:53 Analyst: TF 81447 page 25 of 44 Sample ID: Comp 5 Site 2 Blue Catfish Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: B1447 Date Received: 24 -Oct -2017 Project ID: 2017 Annual Fish Project Weight/Volume: 10.77 g Lab Sample ID B1447_15262_DF_005 Date Extracted: 02 -Nov -2017 Date Collected: 07 -Sep -2017 % Lipid: 2.8% OC Batch No: 15262 Date Analyzed: 07 -Nov -2017 Split: - Dilution: - Time Analyzed: 0:04:28 Analyte Conc. (pg/g) DL (pg/g) EM PC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD 0.171 J ES 2378 -TCDD 84.2 12378-PeCDD EMPC 0.163 J ES 12378-PeCDD 85.3 123478-HxCDD 0.236 J ES 123478-HxCDD 88.1 123678-HxCDD 0.624 J ES 123678-HxCDD 95.1 123789-HxCDD 0.409 J ES 123789-HxCDD 86.8 1234678-HpCDD 2.2 J ES 1234678-HpCDD 87.3 OCDD 10.6 ES OCDD 85.8 2378-TCDF ND 0.112 ES 2378-TCDF 79.1 12378-PeCDF ND 0.067 ES 12378-PeCDF 100 23478-PeCDF ND 0.0849 ES 23478-PeCDF 80.3 123478-HxCDF ND 0.077 ES 123478-HxCDF 90.2 123678-HxCDF ND 0.0714 ES 123678-HxCDF 90.1 234678-HxCDF ND 0.0809 ES 234678-HxCDF 91.6 123789-HxCDF ND 0.101 ES 123789-HxCDF 91.4 1234678-HpCDF ND 0.0997 ES 1234678-HpCDF 86.4 1234789-HpCDF ND 0.139 ES 1234789-HpCDF 87.7 OCDF ND 0.279 ES OCDF 84.3 Totals Standard CS Recoveries CS 37CI-2378-TCDD 83.8 Total TCDD 0.171 0.348 CS 12347-PeCDD 93.2 Total PeCDD ND 0.163 CS 12346-PeCDF 78 Total HxCDD 1.27 1.27 CS 123469-HxCDF 93.8 Total HpCDD 2.2 2.2 CS 1234689-HpCDF 91.3 Total TCDF ND 0.112 ND Total PeCDF ND 0.075 ND Total HxCDF ND 0.0817 ND Total HpCDF ND 0.118 ND Total PCDD/Fs 14.2 14.6 WHO -2005 TEQs 5500 Business Drive Wilmington, NC 28405, USA SGS TEO: ND=O TEQ: ND=DU2 0.323 0.36 0.221 0.485 0.522 TEQ: ND=DL 0.397 0.443 0.56 www.ussgs.com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 518-023-XFH SGS North America - DF v0.30 Report Created: 07 -Nov -2017 16:53 Analyst: TF B1447 page 26 of 44 Sample ID: Comp 6 Site 2 Blue Catfish Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: B1447 Date Received: 24 -Oct -2017 Project ID: 2017 Annual Fish Project Weight/Volume: 12.35 g Lab Sample ID B1447_15262_DF_006 Date Extracted: 02 -Nov -2017 Date Collected: 07 -Sep -2017 % Lipid: 3.4% OC Batch No: 15262 Date Analyzed: 07 -Nov -2017 Split: - Dilution: - Time Analyzed: 0:52:26 Analyte Conc. (pg/g) DL (pg/g) EMPC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD 0.247 ,1 ES 2378 -TCDD 87.2 12378-PeCDD 0.411 J ES 12378-PeCDD 80.1 123478-HxCDD ND 0.128 ES 123478-HxCDD 88.8 123678-HxCDD 0.926 ,J ES 123678-HxCDD 89.7 123789-HxCDD EMPC 0.395 .J ES 123789-HxCDD 93.2 1234678-HpCDD 2.53 ES 1234678-HpCDD 93.8 OCDD 9.03 ES OCDD 85.7 2378-TCDF ND 0.0936 ES 2378-TCDF 74.9 12378-PeCDF ND 0.0754 ES 12378-PeCDF 87.4 23478-PeCDF 0.183 .1 ES 23478-PeCDF 70.9 123478-HxCDF ND 0.0646 ES 123478-HxCDF 81.9 123678-HxCDF ND 0.0633 ES 123678-HxCDF 82.7 234678-HxCDF ND 0.0669 ES 234678-HxCDF 91.2 123789-HxCDF ND 0.0735 ES 123789-HxCDF 98.7 1234678-HpCDF ND 0.0857 ES 1234678-HpCDF 86.4 1234789-HpCDF ND 0.11 ES 1234789-HpCDF 95.8 OCDF ND 0.294 ES OCDF 83.3 Totals Standard CS Recoveries CS 37GI-2378-TCDD 92.1 Total TCDD 0.478 0.478 CS 12347-PeCDD 90.3 Total PeCDD 0.411 0.411 CS 12346-PeCDF 73.6 Total HxCDD 0.926 1.32 CS 123469-HxCDF 92.4 Total HpCDD 2.53 2.53 CS 1234689-HpCDF 99.6 Total TCDF ND 0.0936 ND Total PeCDF 0.183 0.183 Total HxCDF ND 0.124 Total HpCDF ND 0.0973 ND Total PCDD/Fs 13.6 14.1 WHO -2005 TEQs 5500 Business Drive TEO: ND=O 0.834 0.873 TEQ: ND=DU2 0.86 0.163 0.9 SGS Wilmington, NC 28405, USA TEQ: ND=DL 0.887 0.327 0.927 www.us.sgs.com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 164-822-XCB SGS North America - DF v0.30 Report Created: 07 -Nov -2017 16:54 Analyst: TF B1447 page 27 of 44 Sample ID: Comp 7 Site 2 Bluegill Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: 81447 Date Received: 24 -Oct -2017 Project ID: 2017 Annual Fish Project Weight/Volume: 11.99 g Lab Sample ID B1447_15262_DF_007 Date Extracted: 02 -Nov -2017 Date Collected: 07 -Sep -2017 % Lipid: 1.2% QC Batch No: 15262 Date Analyzed: 07 -Nov -2017 Split: - Dilution: - Time Analyzed: 1:47:51 Analyte Conc. (pg/g) DL (pg/g) EMPC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD ND 0.0801 ES 2378 -TCDD 85 12378-PeCDD ND 0.109 ES 12378-PeCDD 81.9 123478-HxCDD ND 0.098 ES 123478-HxCDD 86.3 123678-HxCDD ND 0.0933 ES 123678-HxCDD 89.8 123789-HxCDD ND 0.094 ES 123789-HxCDD 91.8 1234678-HpCDD ND 0.131 ES 1234678-HpCDD 90.4 OCDD ND 0.349 ES OCDD 84 2378-TCDF ND 0.0751 ES 2378-TCDF 71.6 12378-PeCDF ND 0.0593 ES 12378-PeCDF 91.4 23478-PeCDF ND 0.0723 ES 23478-PeCDF 72.3 123478-HxCDF ND 0.0656 ES 123478-HxCDF 82.5 123678-HxCDF ND 0.0648 ES 123678-HxCDF 80.6 234678-HxCDF ND 0.0676 ES 234678-HxCDF 84.1 123789-HxCDF ND 0.0758 ES 123789-HxCDF 92.7 1234678-HpCDF ND 0.0615 ES 1234678-HpCDF 90 1234789-HpCDF ND 0.0806 ES 1234789-HpCDF 92.7 OCDF ND 0.269 ES OCDF 83.8 Totals Standard CS Recoveries CS 37CI-2378-TCDD 93.4 Total TCDD ND 0.0801 ND CS 12347-PeCDD 102 Total PeCDD ND 0.109 ND CS 12346-PeCDF 79.1 Total HxCDD ND 0.0947 ND CS 123469-HxCDF 94.9 Total HpCDD ND 0.131 ND CS 1234689-HpCDF 102 Total TCDF ND 0.0751 ND Total PeCDF ND 0.065 ND Total HxCDF ND 0.0682 ND Total HpCDF ND 0.0703 ND Total PCDD/Fs ND ND WHO -2005 TEQs 5500 Business Drive TEQ: ND=O 0 0 TEQ: ND=DU2 0.14 0.14 0.14 Wilmington, NC 28405, USA TEQ: ND=DL 0.279 0.279 0.279 www.us.sgs.com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 137-923-YJH SGS North America - DF v0.30 Report Created: 07 -Nov -2017 16:54 Analyst: TF B1447 page 28 of 44 Sample ID: Comp 8 Site 2 Bluegill Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: B1447 Date Received: 24 -Oct -2017 Project ID: 2017 Annual Fish Project Weight/Volume: 11.31 g Lab Sample ID B1447_15262_DF_008 Date Extracted: 02 -Nov -2017 Date Collected: 07 -Sep -2017 % Lipid: 1.2% QC Batch No: 15262 Date Analyzed: 07 -Nov -2017 Split: - Dilution: - Time Analyzed: 2:35:03 Analyte Conc. (pg/g) DL (pg/g) EMPC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD ND 0.0972 ES 2378 -TCDD 88.4 12378-PeCDD ND 0.121 ES 12378-PeCDD 86.9 123478-HxCDD ND 0.103 ES 123478-HxCDD 94.2 123678-HxCDD ND 0.0951 ES 123678-HxCDD 95.5 123789-HxCDD ND 0.104 ES 123789-HxCDD 95.6 1234678-HpCDD ND 0.136 ES 1234678-HpCDD 96.1 OCDD ND 0.375 ES OCDD 89.6 2378-TCDF ND 0.0754 ES 2378-TCDF 75.7 12378-PeCDF ND 0.083 ES 12378-PeCDF 92.4 23478-PeCDF ND 0.109 ES 23478-PeCDF 74.2 123478-HxCDF ND 0.13 ES 123478-HxCDF 92.5 123678-HxCDF ND 0.122 ES 123678-HxCDF 92 234678-HxCDF ND 0.138 ES 234678-HxCDF 93.4 123789-HxCDF ND 0.155 ES 123789-HxCDF 98.4 1234678-HpCDF ND 0.116 ES 1234678-HpCDF 92.9 1234789-HpCDF ND 0.138 ES 1234789-HpCDF 100 OCDF ND 0.317 ES OCDF 87.1 Totals Standard CS Recoveries CS 37CI-2378-TCDD 97.9 Total TCDD ND 0.0972 ND CS 12347-PeCDD 108 Total PeCDD ND 0.121 ND CS 12346-PeCDF 79.4 Total HxCDD ND 0.1 ND CS 123469-HxCDF 105 Total HpCDD ND 0.136 ND CS 1234689-HpCDF 102 Total TCDF ND 0.0754 ND Total PeCDF ND 0.0948 ND Total HxCDF ND 0.165 Total HpCDF ND 0.126 ND Total PCDD/Fs ND 0.165 WHO -2005 TEQs 5500 Business Drive TEQ: ND=O 0 0 TEQ: ND=DU2 0.175 0.175 0.175 Wilmington, NC 28405, USA TEQ: ND=DL 0.35 0.35 0.35 - www.ussgs.com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 410-480-BXX SGS North America - DF v0.30 Report Created: 07 -Nov -2017 16:54 Analyst: TF B1447 page 29 of 44 Sample ID: Comp 9 Site 3 Blue Catfish Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: B1447 Date Received: 24 -Oct -2017 Project ID: 2017 Annual Fish Project Weight/Volume: 11.46 g Lab Sample ID B1447_15262_DF_009 Date Extracted: 02 -Nov -2017 Date Collected: 27 -Sep -2017 % Lipid: 0.6% QC Batch No: 15262 Date Analyzed: 07 -Nov -2017 Split: - Dilution: - Time Analyzed: 3:22:27 Analyte Conc. (pg/g) DL (pg/g) EMPC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD ND 0.0556 ES 2378 -TCDD 99.9 12378-PeCDD 0.155 J ES 12378-PeCDD 93.1 123478-HxCDD EMPC 0.0866 J ES 123478-HxCDD 100 123678-HxCDD 0.268 J ES 123678-HxCDD 94.5 123789-HxCDD 0.241 J ES 123789-HxCDD 90.7 1234678-HpCDD 0.828 J ES 1234678-HpCDD 82.9 OCDD EMPC 2.66 J ES OCDD 69.3 2378-TCDF ND 0.0384 ES 2378-TCDF 83.2 12378-PeCDF ND 0.0329 ES 12378-PeCDF 93.3 23478-PeCDF EMPC 0.0514 J ES 23478-PeCDF 88.7 123478-HxCDF EMPC 0.0459 J ES 123478-HxCDF 90.7 123678-HxCDF ND 0.0397 ES 123678-HxCDF 87.2 234678-HxCDF ND 0.0436 ES 234678-HxCDF 88.4 123789-HxCDF ND 0.0547 ES 123789-HxCDF 81.3 1234678-HpCDF 0.0833 J ES 1234678-HpCDF 79.4 1234789-HpCDF ND 0.0502 ES 1234789-HpCDF 79.3 OCDF ND 0.143 ES OCDF 67.1 Totals Standard CS Recoveries CS 37CI-2378-TCDD 104 Total TCDD ND 0.0556 ND CS 12347-PeCDD 91.7 Total PeCDD 0.155 0.155 CS 12346-PeCDF 95.1 Total HxCDD 0.508 0.595 CS 123469-HxCDF 105 Total HpCDD 0.828 0.828 CS 1234689-HpCDF 87.6 Total TCDF ND 0.0384 ND Total PeCDF ND 0.0514 Total HxCDF 0.0734 0.119 Total HpCDF 0.0833 0.0833 Total PCDD/Fs 1.65 4.49 WHO -2005 TEQs 5500 Business Drive Wilmington, NC 28405, USA TEQ: ND=O TEQ: ND=DL/2 0.215 0.252 0.0742 0.244 0.282 TEQ: ND=DL 0.29 0.148 0.319 - www.us.sgs.com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 483-695-RGW SGS North America - DF v0.30 Report Created: 07 -Nov -2017 16:54 Analyst: TF 81447 page 30 of 44 Sample ID: Comp 10 Site 3 Blue Catfish Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: B1447 Date Received: 24 -Oct -2017 Project ID: 2017 Annual Fish Project Weight/Volume: 10.72 g Lab Sample ID B1447_15262_DF_010 Date Extracted: 02 -Nov -2017 Date Collected: 27 -Sep -2017 % Lipid: 2.2% QC Batch No: 15262 Date Analyzed: 07 -Nov -2017 Split: - Dilution: - Time Analyzed: 6:40:28 Analyte Conc. (pg/g) DL (pg/g) EMPC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD ND 0.153 ES 2378 -TCDD 91.7 12378-PeCDD ND 0.114 ES 12378-PeCDD 86.2 123478-HxCDD ND 0.0979 ES 123478-HxCDD 91.1 123678-HxCDD 0.587 ,J ES 123678-HxCDD 91.5 123789-HxCDD 0.443 .1 ES 123789-HxCDD 89.9 1234678-HpCDD 1.98 .1 ES 1234678-HpCDD 92.4 OCDD 7.79 ES OCDD 84.2 2378-TCDF ND 0.0905 ES 2378-TCDF 75.6 12378-PeCDF ND 0.0635 ES 12378-PeCDF 99 23478-PeCDF ND 0.082 ES 23478-PeCDF 79.5 123478-HxCDF ND 0.077 ES 123478-HxCDF 91.6 123678-HxCDF ND 0.0702 ES 123678-HxCDF 91.1 234678-HxCDF ND 0.0837 ES 234678-HxCDF 92.6 123789-HxCDF ND 0.0973 ES 123789-HxCDF 93.5 1234678-HpCDF ND 0.0898 ES 1234678-HpCDF 91.7 1234789-HpCDF ND 0.121 ES 1234789-HpCDF 94.4 OCDF ND 0.322 ES OCDF 82.2 Totals Standard CS Recoveries CS 37CI-2378-TCDD 94.7 Total TCDD ND 0.153 ND CS 12347-PeCDD 101 Total PeCDD ND 0.114 ND CS 12346-PeCDF 85.8 Total HxCDD 1.03 1.03 CS 123469-HxCDF 98.5 Total HpCDD 1.98 1.98 CS 1234689-HpCDF 96.6 Total TCDF ND 0.0905 ND Total PeCDF ND 0.0717 ND Total HxCDF ND 0.0812 ND Total HpCDF ND 0.104 ND Total PCDD/Fs 10.8 10.8 WHO -2005 TEQs 5500 Business Drive TEQ: ND=O 0.125 0.125 TEQ: ND=DL/2 0.299 0.184 0.299 9 SGS Wilmington, NC 28405, USA TEQ: ND=DL 0.472 0.369 0.472 www.us.sgs.com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 119-971-YMZ SGS North America - DF v0.30 Report Created: 07 -Nov -2017 16:54 Analyst: TF B1447 page 31 of 44 Sample ID: Comp 11 Site 3 Bluegill Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: 81447 Date Received: 24 -Oct -2017 Project ID: 2017 Annual Fish Project Weight/Volume: 11.37 g Lab Sample ID B1447_15262_DF_011 Date Extracted: 02 -Nov -2017 Date Collected: 27 -Sep -2017 % Lipid: 0.3% QC Batch No: 15262 Date Analyzed: 07 -Nov -2017 Split: - Dilution: - Time Analyzed: 7:27:53 Analyte Conc. (pg/g) DL (pg/g) EMPC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD ND 0.0688 ES 2378 -TCDD 93.7 12378-PeCDD ND 0.0893 ES 12378-PeCDD 90.5 123478-HxCDD ND 0.0842 ES 123478-HxCDD 89.9 123678-HxCDD ND 0.0859 ES 123678-HxCDD 87 123789-HxCDD ND 0.0908 ES 123789-HxCDD 81.2 1234678-HpCDD ND 0.08 ES 1234678-HpCDD 83.7 OCDD ND 0.284 ES OCDD 85 2378-TCDF ND 0.0561 ES 2378-TCDF 79 12378-PeCDF ND 0.0457 ES 12378-PeCDF 101 23478-PeCDF ND 0.0533 ES 23478-PeCDF 83.9 123478-HxCDF ND 0.0483 ES 123478-HxCDF 89.1 123678-HxCDF ND 0.0537 ES 123678-HxCDF 84.6 234678-HxCDF ND 0.0577 ES 234678-HxCDF 86.8 123789-HxCDF ND 0.068 ES 123789-HxCDF 83.9 1234678-HpCDF ND 0.0723 ES 1234678-HpCDF 83.6 1234789-HpCDF ND 0.102 ES 1234789-HpCDF 86.1 OCDF ND 0.211 ES OCDF 82.2 Totals Standard CS Recoveries CS 37CI-2378-TCDD 102 Total TCDD ND 0.0688 ND CS 12347-PeCDD 121 Total PeCDD ND 0.0893 ND CS 12346-PeCDF 103 Total HxCDD ND 0.0868 ND CS 123469-HxCDF 103 Total HpCDD ND 0.08 ND CS 1234689-HpCDF 91.9 Total TCDF ND 0.0561 ND Total PeCDF ND 0.0491 ND Total HxCDF ND 0.0563 ND Total HpCDF ND 0.086 ND Total PCDD/Fs ND ND WHO -2005 TEQs 5500 Business Drive Wilmington, NC 28405, USA TEQ: ND=O TEQ: ND=DL/2 0 0.116 0.116 0 0.116 TEQ: ND=DL 0.233 0.233 0.233 - www'us'sgs.com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 645-856-GGZ SGS North America - DF v0.30 Report Created: 07 -Nov -2017 16:55 Analyst: TF B1447 page 32 of 44 Sample ID: Comp 12 Site 3 Bluegill Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: B1447 Date Received: 24 -Oct -2017 Project ID: 2017 Annual Fish Project Weight/Volume: 12.19 g Lab Sample ID B1447_15262_DF_012 Date Extracted: 02 -Nov -2017 Date Collected: 27 -Sep -2017 % Lipid: 0.4% QC Batch No: 15262 Date Analyzed: 07 -Nov -2017 Split: - Dilution: - Time Analyzed: 8:15:18 Analyte Conc. (pg/g) DL (pg/g) EMPC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD ND 0.0732 ES 2378 -TCDD 76.7 12378-PeCDD ND 0.1 ES 12378-PeCDD 76.7 123478-HxCDD ND 0.0817 ES 123478-HxCDD 83.3 123678-HxCDD ND 0.0778 ES 123678-HxCDD 89.2 123789-HxCDD ND 0.078 ES 123789-HxCDD 90.5 1234678-HpCDD ND 0.112 ES 1234678-HpCDD 84.1 OCDD ND 0.269 ES OCDD 79.9 2378-TCDF ND 0.0913 ES 2378-TCDF 61 12378-PeCDF ND 0.0506 ES 12378-PeCDF 81.4 23478-PeCDF ND 0.0578 ES 23478-PeCDF 70.9 123478-HxCDF ND 0.0588 ES 123478-HxCDF 78.5 123678-HxCDF ND 0.0615 ES 123678-HxCDF 79.2 234678-HxCDF ND 0.0631 ES 234678-HxCDF 83 123789-HxCDF ND 0.0759 ES 123789-HxCDF 87.2 1234678-HpCDF ND 0.0621 ES 1234678-HpCDF 86.8 1234789-HpCDF ND 0.0991 ES 1234789-HpCDF 84.1 OCDF ND 0.278 ES OCDF 76 Totals Standard CS Recoveries CS 37CI-2378-TCDD 85.6 Total TCDD ND 0.0732 ND CS 12347-PeCDD 98.7 Total PeCDD ND 0.1 ND CS 12346-PeCDF 75.7 Total HxCDD ND 0.0789 ND CS 123469-HxCDF 93.9 Total HpCDD ND 0.112 ND CS 1234689-HpCDF 92.5 Total TCDF ND 0.0913 ND Total PeCDF ND 0.0539 ND Total HxCDF ND 0.0645 ND Total HpCDF ND 0.0787 ND Total PCDD/Fs ND ND WHO -2005 TEQs 5500 Business Drive SGS Wilmington, NC 28405, USA TEQ: ND=O TEQ: ND=DL/2 0 0.127 0.127 0 0.127 TEQ: ND=DL 0.254 0.254 0.254 www.us.sgs.com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 393 -541 -HTB SGS North America - DF v0.30 Report Created: 07 -Nov -2017 16:55 Analyst: TF B1447 page 33 of 44 Sample ID: Comp 13 Site 1 Blue Catfish - Replicate #1 Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: B1447 Date Received: 24 -Oct -2017 Project ID: 2017 Annual Fish Project Weight/Volume: 12.09 g Lab Sample ID B1447_15262_DF_013 Date Extracted: 02 -Nov -2017 Date Collected: 07 -Sep -2017 % Lipid: 5.3% QC Batch No: 15262 Date Analyzed: 07 -Nov -2017 Split: - Dilution: - Time Analyzed: 9:02:43 Analyte Conc. (pg/g) DL (pg/g) EMPC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD EMPC 0.215 J ES 2378 -TCDD 83.8 12378-PeCDD 0.408 J ES 12378-PeCDD 97.1 123478-HxCDD EMPC 0.254 J ES 123478-HxCDD 94.6 123678-HxCDD 0.997 J ES 123678-HxCDD 96.8 123789-HxCDD 0.613 J ES 123789-HxCDD 97.4 1234678-HpCDD 4.14 ES 1234678-HpCDD 79.5 OCDD 20.7 ES OCDD 77.3 2378-TCDF 0.271 J ES 2378-TCDF 54.3 12378-PeCDF EMPC 0.0613 J ES 12378-PeCDF 103 23478-PeCDF 0.276 J ES 23478-PeCDF 89.5 123478-HxCDF ND 0.0669 ES 123478-HxCDF 89.6 123678-HxCDF ND 0.0622 ES 123678-HxCDF 89 234678-HxCDF ND 0.0647 ES 234678-HxCDF 97.9 123789-HxCDF ND 0.0767 ES 123789-HxCDF 95 1234678-HpCDF 0.159 J ES 1234678-HpCDF 73.8 1234789-HpCDF ND 0.0699 ES 1234789-HpCDF 82.3 OCDF ND 0.186 ES OCDF 73.1 Totals Standard CS Recoveries CS 37CI-2378-TCDD 87.1 Total TCDD 0.315 0.53 CS 12347-PeCDD 120 Total PeCDD 0.408 0.408 CS 12346-PeCDF 98.9 Total HxCDD 1.61 1.86 CS 123469-HxCDF 105 Total HpCDD 4.14 4.52 CS 1234689-HpCDF 81.9 Total TCDF 0.271 0.94 Total PeCDF 0.45 0.67 Total HxCDF 0.32 0.32 Total HpCDF 0.159 0.159 Total PCDD/Fs 28.3 30.1 WHO -2005 TEQs 5500 Business Drive SGS Wilmington, NC 28405, USAs TEQ: ND=O TEQ: ND=DU2 0.728 0.742 0.105 0.971 0.985 TEQ: ND=DL 0.756 0.21 0.999 www.us.s 9 com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 309-118-FZT SGS North America - DF v0.30 Report Created: 07 -Nov -2017 16:55 Analyst: TF 81447 page 34 of 44 Sample ID: Method Blank B1447_15262 Method 1613B Client Data Sample Data Laboratory Data Name: CZR, Inc. Matrix: Tissue Lab Project ID: B1447 Date Received: n/a Project ID: 2017 Annual Fish Project Weight/Volume: 10.00 g Lab Sample ID MB1_15262_DF_SDS Date Extracted: 02 -Nov -2017 Date Collected: n/a % Lipid: n/a QC Batch No: 15262 Date Analyzed: 06 -Nov -2017 Split: Dilution: - Time Analyzed: 20:07:26 Analyte Conc. (pg/g) DL (pg/g) EMPC (pg/g) Qualifiers Standard ES Recoveries Qualifiers 2378 -TCDD ND 0.0851 ES 2378 -TCDD 81.5 12378-PeCDD ND 0.108 ES 12378-PeCDD 89.2 123478-HxCDD ND 0.0866 ES 123478-HxCDD 92.1 123678-HxCDD ND 0.0815 ES 123678-HxCDD 90.5 123789-HxCDD ND 0.0874 ES 123789-HxCDD 95.3 1234678-HpCDD ND 0.128 ES 1234678-HpCDD 90.6 OCDD ND 0.295 ES OCDD 84.7 2378-TCDF ND 0.0659 ES 2378-TCDF 61.4 12378-PeCDF ND 0.0464 ES 12378-PeCDF 94.1 23478-PeCDF ND 0.0588 ES 23478-PeCDF 75.7 123478-HxCDF ND 0.0539 ES 123478-HxCDF 89.9 123678-HxCDF ND 0.0514 ES 123678-HxCDF 90.9 234678-HxCDF ND 0.0566 ES 234678-HxCDF 92.9 123789-HxCDF ND 0.0678 ES 123789-HxCDF 91.6 1234678-HpCDF ND 0.0678 ES 1234678-HpCDF 93.3 1234789-HpCDF ND 0.0947 ES 1234789-HpCDF 91.3 OCDF ND 0.294 ES OCDF 83.3 Totals Standard CS Recoveries CS 37CI-2378-TCDD 92.1 Total TCDD ND 0.0851 ND CS 12347-PeCDD 113 Total PeCDD ND 0.108 ND CS 12346-PeCDF 80.6 Total HxCDD ND 0.0849 ND CS 123469-HxCDF 105 Total HpCDD ND 0.128 ND CS 1234689-HpCDF 95.5 Total TCDF ND 0.0659 ND Total PeCDF ND 0.0519 ND Total HxCDF ND 0.0569 ND Total HpCDF ND 0.08 ND Total PCDD/Fs ND ND WHO -2005 TEQs S 5500 Business Drive Wilmington, NC 28405, USA TEQ: ND=O TEQ: ND=DL/2 0 0.135 0.135 0 0.135 TEQ: ND=DL 0.27 0.27 0.27 _ __ www.us.sgs.com Tel: +1 910 794-1613; Toll -Free 866 846-8290 Checkcode: 593-496-VVQ SGS North America - DF v0.30 Report Created: 08 -Nov -2017 12:01 Analyst: TF B1447 page 35 of 44 METHOD 1613B Lab Name: Initial Calibration: Instrument ID: VER Data Filename Lab ID: PCDD/F ONGOING PRECISION AND RECOVERY (OPR) FORM 8A SGS North America ICAL: MM6 DF 09062018 10OCT2017 MM6 GC Column ID: ZB-5ms 171106V09 Analysis Date: 06-NOV-2017 18:32:48 OPR1_15262_DF Contract -required concentration limits for OPR as specified in Table 6, Method 1613. 10/94 Processed: 07 Nov 2017 16:34 Analyst: TF B1447 page 36 of 44 SPIKE CONC. RANGE NATIVE ANALYTES CONC. FOUND (ng/mL) OK 2,3,7,8-TCDD 10 10.4 6.7 - 15.8 Y 1,2,3,7,8-PeCDD 50 49.1 35 - 71 Y 1,2,3,4,7,8-HxCDD 50 55.1 35 - 82 Y 1,2,3,6,7,8-HxCDD 50 54.8 38 - 67 Y 1,2,3,7,8,9-HxCDD 50 51 32 - 81 Y 1,2,3,4,6,7,8-HpCDD 50 53 35 - 70 Y OCDD 100 109 78 - 144 Y 2,3,7,8-TCDF 10 10.6 7.5 - 15.8 Y 1,2,3,7,8-PeCDF 50 54.1 40 - 67 Y 2,3,4,7,8-PeCDF 50 57 34 - 80 Y 1,2,3,4,7,8-HxCDF 50 54 36 - 67 Y 1,2,3,6,7,8-HxCDF 50 53.4 42 - 65 Y 2,3,4,6,7,8-HxCDF 50 55.6 35 - 78 Y 1,2,3,7,8,9-HxCDF 50 52.1 39 - 65 Y 1,2,3,4,6,7,8-HpCDF 50 54.9 41 - 61 Y 1,2,3,4,7,8,9-HpCDF 50 53.7 39 - 69 Y OCDF 100 108 63 - 170 Y Contract -required concentration limits for OPR as specified in Table 6, Method 1613. 10/94 Processed: 07 Nov 2017 16:34 Analyst: TF B1447 page 36 of 44 METHOD 16138 Lab Name: Initial Calibration: Instrument ID: VER Data Filename Lab ID: PCDD/F ONGOING PRECISION AND RECOVERY (OPR) FORM 8B SGS North America ICAL: MM6 DF 09062018 10OCT2017 MM6 GC Column ID: ZB-5ms 171106V09 Analysis Date: 06-NOV-2017 18:32:48 OPR1 _15262_DF CLEANUP STANDARD 37CI-2,3,7,8-TCDD 40 36.6 12.4 - 76.4 Y Contract -required concentration limits for OPR as specified in Table 6, Method 1613. 10/94 Processed: 07 Nov 2017 16:34 Analyst: TF 131447 page 37 of 44 SPIKE CONC. RANGE LABELED ANALYTES CONC. FOUND (ng/mL) OK 13C -2,3,7,8-TCDD 100 76.3 20 - 175 Y 13C-1,2,3,7,8-PeCDD 100 82.8 21 - 227 Y 13C-1,2,3,4,7,8-HxCDD 100 83.5 21 - 193 Y 13C-1,2,3,6,7,8-HxCDD 100 86.4 25 - 163 Y 13C-1,2,3,7,8,9-HxCDD 100 87.5 26 - 166 Y 13C-1,2,3,4,6,7,8-HpCDD 100 88.7 26 - 166 Y 13C-OCDD 200 164 26 - 397 Y 13C-2,3,7,8-TCDF 100 61.4 22 - 152 Y 13C-1,2,3,7,8-PeCDF 100 91.5 21 - 192 Y 13C-2,3,4,7,8-PeCDF 100 73.5 13 - 328 Y 13C-1,2,3,4,7,8-HxCDF 100 85.5 19 - 202 Y 13C-1,2,3,6,7,8-HxCDF 100 88.5 21 - 159 Y 13C-2,3,4,6,7,8-HxCDF 100 85.4 22 - 176 Y 13C-1,2,3,7,8,9-HxCDF 100 82.9 17 - 205 Y 13C-1,2,3,4,6,7,8-HpCDF 100 91.2 21 - 158 Y 13C-1,2,3,4,7,8,9-HpCDF 100 89.6 20 - 186 Y 13C-OCDF 200 160 26 - 397 Y CLEANUP STANDARD 37CI-2,3,7,8-TCDD 40 36.6 12.4 - 76.4 Y Contract -required concentration limits for OPR as specified in Table 6, Method 1613. 10/94 Processed: 07 Nov 2017 16:34 Analyst: TF 131447 page 37 of 44 METHOD 1613B Lab Name: Initial Calibration: Instrument ID: VER Data Filename: Lab ID: PCDD/F ONGOING PRECISION AND RECOVERY (OPR) FORM 8A SGS North America ICAL: MM6 DF 09062018 10OCT2017 MM6 GC Column ID: ZB-5ms 171106V23 Analysis Date: 07-NOV-2017 05:53:15 OPR1 15262 DF -RJ Contract -required concentration limits for OPR as specified in Table 6, Method 1613. 10/94 Processed: 07 Nov 2017 16:37 Analyst: TF B1447 page 38 of 44 SPIKE CONC. RANGE NATIVE ANALYTES CONC. FOUND (ng/mL) OK 2,3,7,8-TCDD 10 10.2 6.7 - 15.8 Y 1,2,3,7,8-PeCDD 50 48.5 35 - 71 Y 1,2,3,4,7,8-HxCDD 50 54.4 35 - 82 Y 1,2,3,6,7,8-HxCDD 50 54.6 38 - 67 Y 1,2,3,7,8,9-HxCDD 50 51.1 32 - 81 Y 1,2,3,4,6,7,8-HpCDD 50 51.9 35 - 70 Y OCDD 100 107 78 - 144 Y 2,3,7,8-TCDF 10 10.7 7.5 - 15.8 Y 1,2,3,7,8-PeCDF 50 54.2 40 - 67 Y 2,3,4,7,8-PeCDF 50 53.9 34 - 80 Y 1,2,3,4,7,8-HxCDF 50 51.1 36 - 67 Y 1,2,3,6,7,8-HxCDF 50 52.8 42 - 65 Y 2,3,4,6,7,8-HxCDF 50 53.3 35 - 78 Y 1,2,3,7,8,9-HxCDF 50 51.2 39 - 65 Y 1,2,3,4,6,7,8-HpCDF 50 55.4 41 - 61 Y 1,2,3,4,7,8,9-HpCDF 50 53.6 39 - 69 Y OCDF 100 108 63 - 170 Y Contract -required concentration limits for OPR as specified in Table 6, Method 1613. 10/94 Processed: 07 Nov 2017 16:37 Analyst: TF B1447 page 38 of 44 METHOD 16138 Lab Name: Initial Calibration: Instrument ID: VER Data Filename Lab ID: PCDD/F ONGOING PRECISION AND RECOVERY (OPR) FORM 86 SGS North America ICAL: MM6 DF 09062018 10OCT2017 MM6 GC Column ID: ZB-5ms 171106V23 Analysis Date: 07-NOV-2017 05:53:15 OPR1 15262 DF -RJ CLEANUP STANDARD 37CI-2,3,7,8-TCDD 40 38.8 12.4 - 76.4 Y Contract -required concentration limits for OPR as specified in Table 6, Method 1613. 10/94 Processed: 07 Nov 2017 16:37 Analyst: TF 131447 page 39 of 44 SPIKE CONC. RANGE LABELED ANALYTES CONC. FOUND (ng/mL) OK 13C -2,3,7,8-TCDD 100 79.8 20 - 175 Y 13C-1,2,3,7,8-PeCDD 100 80.7 21 - 227 Y 13C-1,2,3,4,7,8-HxCDD 100 86.2 21 - 193 Y 13C-1,2,3,6,7,8-HxCDD 100 85.3 25 - 163 Y 13C-1,2,3,7,8,9-HxCDD 100 86.5 26 - 166 Y 13C-1,2,3,4,6,7,8-HpCDD 100 87.9 26 - 166 Y 13C-OCDD 200 184 26 - 397 Y 13C-2,3,7,8-TCDF 100 58.6 22 - 152 Y 13C-1,2,3,7,8-PeCDF 100 89.7 21 - 192 Y 13C-2,3,4,7,8-PeCDF 100 71.8 13 - 328 Y 13C-1,2,3,4,7,8-HxCDF 100 83.5 19 - 202 Y 13C-1,2,3,6,7,8-HxCDF 100 83.2 21 - 159 Y 13C-2,3,4,6,7,8-HxCDF 100 86.5 22 - 176 Y 13C-1,2,3,7,8,9-HxCDF 100 86.9 17 - 205 Y 13C-1,2,3,4,6,7,8-HpCDF 100 84.2 21 - 158 Y 13C-1,2,3,4,7,8,9-HpCDF 100 91.5 20 - 186 Y 13C-OCDF 200 175 26 - 397 Y CLEANUP STANDARD 37CI-2,3,7,8-TCDD 40 38.8 12.4 - 76.4 Y Contract -required concentration limits for OPR as specified in Table 6, Method 1613. 10/94 Processed: 07 Nov 2017 16:37 Analyst: TF 131447 page 39 of 44 5500 Business Drive Wilmington, NC 28405 USA Tel: 910 794-1613 Toll Free: 866 846-8190 Fax: 910 794-3919 Sample Receipt Notification Project Manager: Amy Boehm Receipt Date & Time: 24 -Oct -17 at 15:30 AP Project name: B1447 Requested TAT: 21 days Projected due date: 15 -Nov -17 Matrix: Tissue Phone#: 910-794-1613 Email Address: Amv.8oehm sas.com Company Contact: Sam Cooper Company: CZR, Inc. Project Name & Site: 2017 Annual Fish Project Project PO#: Inv. 1P -OH; 11337550 QAAP/Contract #: N/A Requested Analysis: Method 1613B, % lipids Phone#: 9103929253 Email Address: czrwilm@czr-inc.com Client Smp ID AP Smp ID Sample Condition &Notes Quantity Size Sampling Date Sampling Time Received Temp Container # Shipping # Comp 1 Site 1 Blue Catfish B1447_001 Blue Catfish (10 "A" Fillets) 10 Bag 07 -Sep -17 00:00 -4.8 3 N/A Comp 2 Site 1 Blue Catfish B 1447_002 Blue Catfish (10 "A" Fillets) 10 Bag 07 -Sep -17 00:00 -4.8 3 N/A Comp 3 Site 1 Bluegill B1447_003 Bluegill (10 "A" Fillets) 10 Bag 07 -Sep- 17 00:00 -4.8 3 N/A Comp 4 Site 1 Bluegill B1447_004 Bluegill (10 "A" Fillets) 10 Bag 07 -Sep -17 00:00 -4.8 3 N/A Comp 5 Site 2 -Blue Catfish— 447 5 Blue Catfish (8 "A" Fillets) 8 Bag 07 -Sep -17 00:00 -11.8 2 N/A Comp 6 Site 2 Blue Catfish B1447_006 Blue Catfish (10 "A" Fillets) 10 Bag 07 -Sep -17 00:00 -11.8 2 N/A Comp 7 Site 2 Bluegill B1447_007 Bluegill (10 "A" Fillets) 10 Bag 07 -Sep -17 00:00 -11.8 2 N/A Comp 8 Site 2 Bluegill B1447_008 Bluegill (10 "A" Fillets) 10 Bag 07 -Sep -17 00:00 -11.8 2 N/A Comp 9 Site 3 Blue Catfish B1447_009 Blue Catfish (6 "A" Fillets) 6 Bag 27 -Sep -17 00:00 -5.5 1 N/A Comp 10 Site 3 Blue Catfish B 1447_010 Blue Catfish (7 "A" Fillets) 7 Bag 27 -Sep -17 00:00 -5.5 I N/A Comp 11 Site 3 Bluegill B1447_011 Bluegill (10 "A" fillets) 10 Bag 27 -Sep -17 00:00 -5.5 1 N/A Comp 12 Site 3 Bluegill B1447_012 Bluegill (10 "A" Fillets) 10 Bag 27 -Sep -17 00:00 -5.5 1 N/A Comp 13 Site I Blue Catfish - Replicate #1 B 1447_013 Blue Catfish - Replicate (10 "B" Fillets) 10 Bag 07 -Sep -17 00:00 -4.8 3 N/A Preservation Type: Sample Seals: No Any un -extracted sample will be stored for 90 days from reporting date. Additional storage fees may apply for any samples stored longer than 90 days. Notes/Comments: Samples received intact Received hv: Ashlev Owens Logged in bv: Ashley Owens All services are rendered in accordance with the applicable SGS General Conditions of Service accessible via: http://www.sgs.com/terms and conditions.htm QC'ed h : AK 25 Oct 17 B1447 page 40 of 44 SGS North America o° ZR 4709 COLLEGE ACRES DRIVE € SUITE 2 INC ORPO RATED WILMINGTON, NORTH CAROLINA 28403-1725 ENVIRONMENTAL CONSULTANTS TEL 910-392-9253 CHAIN OF CUSTODY FAX 910-392-9139 czrwilm@czr-inc,com TO: SGS Environmental Services FROM: Randall L. Pulley Attn: Amy Boehm CZR Incorporated, Suite 2 5500 Business Drive 4709 College Acres Drive Wilmington, NC 28405 Wilmington, NC 28403 rpulley@czr-inc.com DATE: 24 October 2017 RE: International Paper Company, Inc., 2017 Annual Fish Project (IP PO# 11337550 to SGS) TESTS: Analysis of fish tissues for percent lipid (extraction) and 2, 3, 7, 8 TCDD (Dioxin), 2, 3, 7, 8, TCDF (Furan) with full screen of congeners (Polychlorinated Dibenzodioxins and Polychlorinated Dibenzofurans) via EPA Method 1613B. ENCLOSED ITEMS: Thirteen (13) frozen composite fish tissue (fillets) samples, each fillet wrapped in aluminum foil (dull side toward fish) and enclosed in labeled "zip -lock" plastic bags. Composites are identified below. SAMPLE ID # Composite # Site 1 2 3 4 5 6 8 9 10 11 12 13 Species (number of fish fillets) Blue Catfish (10 "A" fillets) Blue Catfish (10 "A" fillets) — 2 bags Bluegill (10 "A" fillets) Bluegill (10 "A" fillets) Blue Catfish (8 "A" fillets) Blue Catfish (10 "A" fillets) Bluegill (10 "A" fillets) Bluegill (10 "A" fillets) Blue Catfish (6 "A" fillets) Blue Catfish (7 "A" fillets) Bluegill (10 "A" fillets) Bluegill (10 "A" fillets) Blue Catfish — replicate #I (10 `B" fillets) COMMENTS: - Send one digital version and two hard copies of the report to Randy Pulley/CZR at the above address. We also request permission to include the report as an appendix to CZR's report summarizing the 2017 collection efforts and results. - Forward the invoice to International Paper -Riegelwood, Shared Services, P.O. Box 792, Milford, OH 45150 - A detailed fish composite data table is also enclosed. ROMqdished by: QA.4 6XZ'".10 eceived by: a l ocr a, OJ7 1 V Date/time 0 IolaW/-I IS=30 $t"'? .-1'I.g Date/time -4 3 : —q ga CZR CP# 1340.25 B1447 page 41 of 442151 Alternate AIA South • SUITE 2000 • JUPITER, FLORIDA 33477-3902 TEL 561-747-7455 • FAX 561-747-7576 • czrinc@czr-inc.com • www.CZRINC.com pm A 0 A n n n n n 3 3 3 3 3 0 0 0 0 0 n - m W A W N N Xw A A N m N� O o o O T N N N N N N w C V V V V V V V V T F m m m m m m m m ID O m N N N N N N N N - 0 0 0 0 0 0 0 0 V V V V J J V V tp N 1 d a a a a m a a m < n C S I m m m m m m m m m mg n N b N n N m v3v�3 N a T S S S T S? h A T n A_ 0 O � S N 3 A O v T N N ppp N�� N ppN pppppp t,SQ� N � v 17 0 0 D O m ND A � _ � d fp m � r' o o a o 0 o A .J I^ Q• J� O� O� Ol Ol 01 Q� J V N lli \ N N \"Zi\ VI N N N N N N N N N N N N T 01 N V O'� Q1 01 d1 O� O� Q� O� O� N O N\\\ O O O O N 0 N N 0 0 N N 0 0 N 0 0 0 0 a N N 0 0 N\ 0 0 N N 0 0 N 0 N N\\\\\\\ 0 0 0 0 0 0 0 0 0 N N 0 0 N N 0 0 N\\\ 0 0 0 0 N N 0 0 N 0 V V V V V V N H V V N H V V V i-+ V J J J J J f+ J J J J ✓ V !-� r+ V J J V r J J V J V J J r+ J V �+ r+ J V J J r V J N V 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 m m m m m m m m m m W m m m m m m m m m m m m V V \ V V \ \ \ \ V N N N N \ N N` N ` \ \\ N N N N\ -_ N O O O O O 0 0 0 0 0 0 O O O O O O O O O O O O O O O O O O O O 0 0 0 0 0 0 0 0 0 0 V V V V V V V V V V J V V J V V J V V V V V J V 1 1J V V J J J J J J J V J V A .v A ;:I% % a v v v V v 7 a O am a a a a a a a a a a a a a a a a a a a a a a a a a a a a a a 0 nnnnn- 0 1-1-1 0 0 0 0 Fl+ + -1 - + dl- + IT +H- - - m m m m m m m m m 3 3 3 3 3 w ... . °1 °i °: m m m m w m m m m m m m m m m m m m m m c c c c %- n 3 0 3 3 0 0 3 3 0 0 S??? d d m d v c m io c c `o ro io m '� tD c c c c c c c c c c c r0 m c ro on, a y ,n, n n a w M- A n Si J J J 7 J p d 6 D. d t d d W 00. 00. W 00 0➢ W W _ W DD. W pD 00 Oa 00 00 00 A A 00 ,.� d .dn 00 N O� lA '_' J ^ tl� � r^ Oo N N F+ J S S S S S S S S S 0 O _ A V O lO N Y .-. �. -, ^ J 00 w O 1 T J Q� U� A1 T V V N W O� 00 O� �-' N O V V O Oo V W 00 A W �D N r O O� v N 00 O 0, J O i0 ✓ N O� w A ao O A �D 01 N N N N N V8999§ N N N N orN or o� F, o�.�, �O b 00 00 aD o00 J J oTO gNA P P a008 0 WN W W W W o-09W,N 8WN W W W N N N N V A W N N N t0 N N a N O N N F. r. N N N N N O N N 0 0 0 0 0 0 0 0 0 N A O N O �D O N U1 O N N O V O to 0 O O N N O O N" NO W W N N N W OmmO N N N N V 00 J O Q� N O N A N A N A O O 0 O 0 0N 0N 0O� 0 0N 0 08 It N N N N N N w C V V V V V V V V T F m m m m m m m m ID O m N N N N N N N N - 0 0 0 0 0 0 0 0 V V V V J J V V tp N 1 d a a a a m a a m < n C S I m m m m m m m m m mg n N b N n N m v3v�3 N a T S S S T S? h A T n A_ 0 O � S N 3 A O v T N N ppp N�� N ppN pppppp t,SQ� N � v 17 0 0 D O m ND A � _ � d fp m � r' o o a o 0 o A .J I^ Site 2 - 2017 International Paper - Cape Fear River Label foil with "Site 2, Bluegill (1), date caught,'A' or'B"' Date Caught By Date Filleted By Site Put same species from same site in zip -lock by A or!fillet. A Species (N) Total length (mm) Total Weight (g) = raft fillet Fillet A Weight (g) Fillet B Weight (g) 9/27/2017 MW/BB 9/28/2017 RP 2 Blue Catfish (12) 529 1200 185 390 9/7)2017 MW/BB 1 9/7/2017 BB 2 Blue Catfish (1) 558 1500 185 200 9/7/2017 MW/BB. 9/7/2017 B8 2 Blue Catfish (3) 553 1.700 200 160 9/27/2017 MW/BB 9/28/2017 RP 2 Blue Catfish (13) 590 1900 310 280 9/2812017 MW/BB 9/28/2017 RP 2 Biue Catfish ill) 61.7 MCI 260 1 255 9/27/2017 MW/BB 9%28/2017 RP 2 Blue Catfish (11) 598 2000 290 270 612017 MW/BB 9/28/2017 RP 2 Blue Catfish (6)598 2400 340 315 " �..-8/2017 RP 2 " 10) 630 2400 320 350 9/27/2017 MW/88 9/28%2017 R? 2 Blue Catfish (8) 640 275u _ 410.15 9/26/2017 MW/BB 1 9/28/2017 RP 2 Blue Catfish (5) 651 2850 440 400 9/27/2017 MW/BB 9/28/2017 RP 2 Blue Catfish (14) _ - 638 3100 400 370 9/27/2017 MW/BB 9/28/2017 RP 2 Blue Catfish (9) 657 3200 1 450 410 9/7/2017 MW/BB 9/7/2017 RP 2 Blue Catfish (2) 716 3200 i 350 390 9/27/2017 MW/BB 9/28/2017 RP 2 Blue Catfish (7) 672 3700 500 500 9/28/2017 MW/BB 9/28/2017 RP 2 Blue Catfish (15) 703 3800 490 445 9/26/2017 MW/BB 9/27/2017 SC 2 Blue Catfish (18) 724 3800 1 460 440 9/28/2017 9/7/2017 MW/BB MW/BB 9/28/2017 9/7/2017 RP RP 2 2 Blue Catfish (16) Blue Catfish (4) 697 691 3850 4000 540 610 490 540 9/7/2017 MW/BB 9/7/2017 RP 2 Bluegill (10) 150 60 30 30 9/26/2017 MW/BB 9/27/2017 SC 2 Bluegill (17) 152 68 10 10 9/7/2017 MW/BB 9/7/2017 RP 2 Bluegill (13) 164 75 15 15 9/6/2017 MW/BB 9/7/2017 RP 2 Bluegill (6) 159 80 10 10 9/7/2017 MW/BB 9/7/2017 RP 2 Bluegill (14) 167 85 20 15 9/6/2017 MW/BB 9/7/2017 RP 2 Bluegill (8) 151 90 IS 15 9/6/2017 MW/BB 9/7/2017 RP 2 Bluegill (9) 160 90 10 10 9/6/2017 MW/BB 9/7/2017 RP 2 Bluegill (7) 163 1 90 10 10 9/7/2017 MW/BB 9/7/2017 RP 2 Bluegill (15) 167 90 15 15 9/6/2017 MW/BB 9/7/2017 RP 2 Bluegill (3) 168 105 15 10 9/6/2017 MW/BB 9/7/2017 RP 2 Bluegill (2) 174 110 15 10 9/26/2017 MW/BB - 9/27/2017 SC 2 Bluegill (16) 185 110 30 10 9/26/2017 MW/BB 9/27/2017 SC 2 Bluegill (18) 190 123 10 10 9/7/2017 MW/BB 9/7/2017 RP 2 Bluegill(12) 178 125 20 20 9/6/2017 MW/BB 9/7/2017 RP 2 Bluegill (5) 1 186 130 12 10 9/6/2017 MW/BB 9/7/2017 RP 2 Bluegill (1) 192 130 15 15 9/27/2017 MW/BB 9/28/2017 1 RP 2 Bluegill (19) 185 135 15 15 9/7/2017 MW/BB 9/7/2017 RP 2 Bluegill (11) 202 160 20 20 9/27/2017 MW/BB 9/28/2017 RP 2 Biuegill(20) 193 175 20 20 9/6/2017 MW/BB 9/7/2017 RP 2 Bluegill (4) 201 175 20 20 9/7/2017 MW/BB 9/7/2017 BB w 2 Flathead Cat (1) 660 1 2800 .55 190 9/7/2017 MW/BB 9/7/2017 BB 2 Flathead Cat (2) 735 3650 300 240 - 9/7/2017 MW/BB 9/7/2017 RP 2 G Common Carp (6) 528 1800 225 200 9/28/2017 MW/BB 9/28/2017 RP 2 Common Carp (7) 535 1650 200 190 9/28/2017 MW/BB 9/28/2017 RP 2 Common Carp (8) 556 2200 265 210 9/7/2017 MW/BB 9/7/2017 RP 2 Common Carp (5) 563 2550 280 270 9/7/2017 MW/BB 9/7/2017 BB 2 Common Carp (3) 570 3000 240 250 9/7/2017 MW/BB 9/7/2017 RP 2 Common Carp (4) 592 2600 350 320 9/28/2017 MW BB 9/28/2017 RP 2 Common Carp (9) 606 3050 350 350 9/7/2017 MW/BB 9/7/2017 RP 2 Common Carp (2) 612 3000 330 310 9/7/2017 9/28/2017 MW/BB MW 9/7/2017 1 9/28/2017 RP RP 2 2 Common Carp (1) Channel Catfish (1)' 633 473 3050 800 340 340 140 130 Comopsite 6 Site 2Blue Catfish 10 2, 4, 5,7,9,9,14,15, 16, 19 - A fillerts Composite 7 Site 2 Bluegill 10 3, 6, 7, 8, 9, 10, 13, 14, 15, 17 - A fillets Composite 8 Site 2 Bluegill 10 1, 2, 4, 5,11,12,16, 18,19, 20 - A fillets 81447 page 43 of 44 Site 3 - 2017 International Paper - Cape Fear River Label foil with "Site 2, Bluegill (1), date caught,'A' or'B"' Put same species from same site in zip -lock by A or B fillet. A = left fillet Date Caught By: Date Filleted By Site Species (b) Total Length (mm) Total Weight (g) Fillet A Weight (g) Fillet B Weight (g) 9/26J2017 MW/BB 9/27/2017 SC 3 Blue Catfish (7) 523 1250 160 150' 9/26/2017 MW/BB 9/27/2017 SC 3 Blue Catfish (5) 525 1280 160 140 - 9/27/2017 MW/BB 9/28/2017 RP 3 Blue Catfish (9) 530 850 180 190 9/26/2017 MW/BB 9/27/2017 SC 3 Blue Catfish (2) 538 1420 180 170 9/26/2017 MW BB .9/27/2017 SC 3 Blue Catfish 8) 585 2010 310 240 9/26/2017 MW/BB _ 9/27/2017 RP SC 3 3 , Blue Catfish (4) _ 585 i 610 1900 21(10 300 _ iS 270_ Zoo 9/26/2017 MW/88 9/27/2017 SC 3 Blue Catfish (3) 615 _ 2400 330 270 9/28/2017 MW/88 9/28/2017 Rp 3 Blue Catfish (12) 623 2050 320 310 9/28/2017 MW/BB 9/28/2017 RP 3 Blue Catfish (11) 691 3100 445 450 9/26/2017 MW/BB 9/27/2017 SC 3 Blue Catfish (1) 692 3800 430 400 9/26/2017 MW/BB 9/27/2017 SC 3 Blue Catfish (6) 692 3900 550 490 9/28/2017 MW/BB 9/28/2017 RP 3 Blue Catfish (10) 708 3500 470 510 9/25/2017 MW/BB 9/27/2017 SC 1 3 Btuegill (4) 147 58 5 5 9/26/2017 MW/BB 9/27/2017 SC 3 Bluegill (19) 149 59 5 5 9/26/2017 MW/BB 9/27/2017 SC 3 Bluegill (22) 151 68 5 10 9/25/2017 MW/BB 9/27/2017 SC 3 Bluegill (11) 152 6S 10 10 9/26/2017 MW/BB 9/27/2017 Sc 3 Bluegill (18) 152 68 10 10 9/25/2017 MW/BB 9/27/2017 SC 3 Bluegill (9) 153 69 5 30 9/25/2017 MW/BB 9/27/2017 SC 3 Bluegill (6) 154 62 10 10 9/26/2017 MW/BB 9/27/2017 SC 3 Bluegill (21) 1S9 75 10 10 9/25/2017 MW/BB 9/27/2017 SC 1 3 Bluegill (7) 162 91 10 10 9/26/2017 MW/BB 9/27/2017 SC 3 Bluegill J13) 164 93 10 SO 9/25/2017 MW/BB 9/27/2017 SC 3 Bluegill (2) 165 85 10 is 9/26/2017 MW/BB 9/27/2017 SC 3 Bluegill (17) 170 98 10 10 9/25/2017 MW/8B 9/27/2017 SC 3 Bluegill (8) 172 112 15 15 9/2S/2017 MW/BB 9/27/2017 SC 3 Bluegill (10) 172 115 15 15 9/26/2017 MW/BB 9/27/2017 SC 3 Bluegill (20) 172 105 20 20 9/25/2017 MW/BB 9/27/2017 Sc 3 Bluegill (5) 173 90 15 15 9/26/2017 MW/BB 9/27/2017 SC 1 3 Bluegill (15) 181 105 10 10 9/26/2017 MW/BB 9/27/2017 SC 3 Bluegill (12) 184 123 10 10 9/26/2017 MW/BB 9/27/2017 SC 3 Bluegill (14) 185 113 15 15 9/26/2017 MW/BB 9/27/2017 SC 3 Bluegill (16) 197 172 20 20 9/25/2017 MW/BB 9/27/2017 SC 3 Bluegill (1) 217 185 30 25 9/25/2017 MW/B8 9/27/2017 SC 3 Bluegill (3) 220 250 40 40 9/28/2017 MW/BB 9/28/2017 RP 3 Flathead Cat (1) 588 2100 240 210 9/26/2017 MW/88 9/27/2017 SC 3 Common Carp (3) 560 2200 230 280 9/26/2017 MW/BB 9/27/2017 SC 3 Common Carp (1) 578 i 2600 290 350 9/26/2017 MW/BB 9/27/2017 SC 3 Common Carp (2) 640 3900 490 470 Composite 10 Site 3 Blue catfish Composite 11 Site 3 Bluegill Composite 12 Site 3 Bluegill B1447 page 44 of 44 1, 3, 4, 5, 10, 11, 12 - A fillets 2, 6, 7, 9, 11, 13, 17, 18, 22, 21 - A fillets 1. 3, 5, 8, 30, 12, 14, 15. 16, 20 A fillets