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HomeMy WebLinkAboutWI0600068_UndergroundInjectionEventReport_20240812 AXOM AECOM 919.854.6200 tel 701 Corporate Center Drive,Suite 475 919.854.6259 fax Raleigh,North Carolina27607 May 22, 2015 Mr. Al Chapman North Carolina Department of Environment and Natural Resources Division of Waste Management, Superfund Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Subject: Report on Underground Injection Event, Smittys Cleaners 3060 Owen Drive Fayetteville, Cumberland County, North Carolina AECOM Project No. 60321176.G03 DSCA Site ID 26-0003 Dear Mr. Chapman, AECOM Technical Services of North Carolina, Inc. completed the attached Underground Injection Report for the above referenced site on behalf of the North Carolina Dry-Cleaning Solvent Cleanup Act Program. The report text and Analytical Data Tables with associated attachments are enclosed to document the injection and subsequent monitoring. If you have any questions or need additional information, please contact Brian Ray at (919) 239-7179. Sincerely yours, Matt Allen, P.G. Brian A. Ray Project Manager Program Manager 1 AC'OM Environment Submitted to Submitted by NCDENR Division of Waste AECOM Management Raleigh, NC 1646 Mail Service Center 60342855 Raleigh, North Carolina 27699 Report on Underground Injection Event (WI0600068 ) Smitty's Cleaners (DSCA Site ID 26-0003) 3060 Owen Drive Fayetteville, Cumberland County, North Carolina AECOM Environment Submitted to Submitted by NCDENR Division of Waste AECOM Management Raleigh, NC 1646 Mail Service Center 60342855 Raleigh, North Carolina 27699 on Report Underground Injection Event (WI0600068) `ea. Prepared By Bethany Donovan ®eeeO�'(H C�4l�p SEAL ' - Z041 Ra4iewed Matt Allen, P.G. 0 C. P oeeo Revi By Brian Ray Smitty's Cleaners (DSCA Site ID 26-0003) 3060 Owen Drive Fayetteville, Cumberland County, North Carolina AECOM Environment i Table of Contents 1 Introduction.........................................................................................................................................................................1-1 2 Pilot Groundwater Monitoring Well Installation...............................................................................................................2-1 3 Pilot Injection and Monitoring Program Summary...........................................................................................................3-1 3.1 Injection Locations........................................................................................................................................................3-1 3.2 Injection Procedure ......................................................................................................................................................3-1 3.3 Injection Performance Monitoring.................................................................................................................................3-1 3.4 Sampling and Analysis Procedures..............................................................................................................................3-1 4 Performance Results..........................................................................................................................................................4-1 4.1 Groundwater Elevation Data........................................................................................................................................4-1 4.2 Groundwater Volatile Organic Compound Results.......................................................................................................4-1 4.3 Secondary Effects (Geochemical Parameters).............................................................................................................4-1 5 Summary..............................................................................................................................................................................5-1 6 References...........................................................................................................................................................................6-1 List of Appendices Appendix A. Underground Injection Control Permit Appendix B. Monitoring Well Construction Record/Lithology Appendix C. Contractor's Injection Report Appendix D. Groundwater Collection Records Appendix E. Laboratory Analytical Reports Appendix F. Historical Chlorinated Volatile Organic Compounds 60342855 May 2015 AECOM Environment i List of Tables Table 3-1. Summary of Geochemical Data Table 4-1. Summary of Groundwater Elevation Table 4-2. Summary of Volatile Organic Compound Concentrations in Groundwater Table 4-3. Summary of Field Parameters List of Figures Figure 1 1. Site Location Map Figure 1 2. Site Map Figure 3 1. Injection Location Map Figure 4-1. Groundwater Potentiometric Surface—November 2014 Figure 4-2. Groundwater PCE Isoconcentration Map—January 2015 Figure 4-3. Historical PCE Concentrations in Selected Monitoring Wells 60342855 May 2015 AECOM Environment ii List of Acronyms AECOM AECOM North Carolina, Inc. bls below land surface CVOC chlorinated volatile organic compound DCE dichloroethene DNAPL dense non-aqueous phase liquid DO dissolved oxygen DSCA Dry-cleaning Solvent Cleanup Act EPA United States Environmental Protection Agency ESTCP Environmental Security Technology Certification Program ISCO In situ chemical oxidation NCDENR North Carolina Department of Environment and Natural Resources ORP oxidation-reduction potential PCE tetrachloroethene Redox-Tech Redox-Tech, LLC Site Smitty's Cleaners(DSCA ID#26-0003)dry cleaning facility located at 3060 Owen Drive, Fayetteville, Cumberland County, North Carolina 28306 TCE trichloroethylene TOC total organic carbon VOCs volatile organic compounds 60342855 May 2015 AECOM Environment 1-1 1 Introduction AECOM Technical Services of North Carolina, Inc. (AECOM)is submitting this report on behalf of the North Carolina Department of Environment and Natural Resources (NCDENR) Dry-cleaning Solvent Cleanup Act(DSCA) Program in accordance with the requirements listed in Part VII (5)of Injection Permit W10600068 for injection of potassium permanganate at the Smitty's Cleaners(DSCA ID#26-0003)dry cleaning facility located at 3060 Owen Drive, Fayetteville, Cumberland County, North Carolina 28306(the Site). The Site location map and site map are shown on Figure 1-1 and Figure 1-2. This report describes results as of January 2015 of injection activities that occurred at the Site between November 3 and November 5, 2014. The injection permit was originally procured by Cardno ATC in February 2011. Cardno ATC requested a permit renewal in a letter to the NCDENR Division of Water Resources dated January 31, 2014 and a renewed permit was subsequently granted with the same permit number. The renewed permit is included in this report as Appendix A. Results from the permanganate injection event are summarized below. 60342855 May 2015 AECOM Environment 2-1 2 Pilot Groundwater Monitoring Well Installation Prior to initiation of the pilot test, one pilot injection monitoring well (IMW-1)was installed at the Site to monitor subsurface conditions during the pilot study. IMW-1 was installed using hollow stem auger methods to 24 feet below land surface(bls) and completed with a ten-foot section of 0.010-inch slot,1.5-inch diameter polyvinyl chloride prepack screen. The bottom of the well was set approximately 2 feet into the shallow subsurface clay layer identified beneath the Site in order to intercept the highest concentrations of chlorinated volatile organic compounds(CVOCs)in groundwater. The well was completed with an expandable locking plug and a steel flush mount manhole set in a concrete pad. A monitoring well construction log with lithology is included as Appendix B. The well location is depicted on Figure 1-2. 60342855 May 2015 AECOM Environment 3-1 3 Pilot Injection and Monitoring Program Summary 3.1 Injection Locations Nine injection locations(IP-1 through IP-9)were selected for the injection based on the objectives of treating the area in the vicinity of well MW-33 (location of the highest historical tetrachloroethene[PCE]concentration at the Site)and IMW-1,which was installed specifically to monitor this injection event. Approximate injection locations were located by AECOM personnel at the Site by hand measuring from known points and are shown on Figure 3-1. Injection points IP-1, IP-2, IP-3, and IP-7 were located inside(the middle dry-cleaning room)the on-site building and the remaining injection points were within an uncovered courtyard space in the building complex. 3.2 Injection Procedure The potassium permanganate injection event included the injection of approximately 600 pounds of potassium permanganate as 810 gallons of slurry. The injections were conducted by Redox-Tech, LLC(Redox-Tech)under the supervision of AECOM between November 3 and 5, 2014. Redox-Tech injected the oxidant solution at 9 locations in 90-gallon batches at an average flow rate of 4 to 7 gallons per minute via direct-push injection rods at depths from 17.5 to 22.5 feet bls. Each batch of injection fluid was mixed on-site by dissolving granular potassium permanganate in water obtained from an on-site spigot supplied by the Fayetteville public works commission. The potassium permanganate was manufactured by Carus Chemical Corporation, and a Certificate of Analysis is provided as part of the Contractor's Injection Report in Appendix C. A"bottom-up" injection technique was used to inject through bottom-out, direct-push rods. During injection, no water table mounding or daylighting was observed. Additionally,the formation did not provide any significant back pressure during the injection. Boreholes were abandoned using hydrated bentonite after completing each injection. Injection rates, pressures, and volumes are summarized in the Contractor's Injection Report included as Appendix C. 3.3 Injection Performance Monitoring To evaluate the effectiveness of the injection activities,the following monitoring wells were part of the performance monitoring program: MW-2, MW-3R, MW-5, MW-33, and IMW-1. A baseline groundwater sampling event was conducted on each of the above wells, except IMW-1, on October 21, 2014 in order to establish pre-injection groundwater volatile organic compound (VOC)concentrations. Groundwater sampling data collected from IMW-1 on September 5, 2014, immediately after it was installed, was considered the baseline data for this monitoring well. AECOM conducted performance sampling events on the following dates: — November 13, 2014 (one week post-injection) — November 21, 2014 (two weeks post-injection) — November 26, 2014 (three weeks post-injection) — December 5, 2014 (four weeks post-injection) — December 18, 2014 (six weeks post-injection) — December 29, 2014 (eight weeks post-injection) — January 15, 2015(ten weeks post-injection) 3.4 Sampling and Analysis Procedures Prior to groundwater sampling,water levels in each of the referenced wells were gauged with an electronic water level meter. Additionally, each well was purged using low-flow sample techniques with a peristaltic pump. During the purging process, water quality parameters including pH, oxidation-reduction potential (ORP), temperature, specific conductivity, and dissolved 60342855 May 2015 AECOM Environment 3-2 oxygen (DO)were recorded at each monitoring well. These parameters were measured using a YSI Model 556 multi- parameter meter and a flow-through cell. Purging continued until water quality parameters stabilized. The groundwater collection records are included in Appendix D. Additionally, groundwater color was observed during purging and sampling and noted on the collection records. Purple coloration typically indicates that strong permanganate concentrations are present; light pink coloration indicates that trace permanganate concentrations are present; brown coloration indicates that permanganate has mostly oxidized to manganese dioxide. No qualitative correlation to oxidant concentration was made to the observation of gray or turbid groundwater. Post Injection monitoring events for VOCs were conducted during the week two,week three, week four,week seven, and month two sampling trips in accordance with the injection permit. If purple or light-pink color was present in the sample at the time of sampling, indicating the presence of unreacted oxidant, the sample was quenched by reacting permanganate with excess sodium thiosulfate in pre-charged sample vials before analyzing for VOCs. Quenching was necessary to stop the reaction of permanganate with VOCs at the time of sampling and to prevent malfunction of analytical instrumentation components that are incompatible with permanganate. VOCs were analyzed by United States Environmental Protection Agency(EPA) Method 8260B. Groundwater geochemistry samples were collected from IMW-1 during multiple sampling events and from MW-2 during the baseline sampling event. Samples from IMW-1 and MW-2 were submitted for the analysis of total organic carbon (TOC) by EPA Method 9060, chloride by EPA Method 9056, and manganese, potassium, sodium by EPA Method 6010 at ESC Lab Sciences. Additionally, dehalorespiring bacteria were analyzed at various times throughout the performance monitoring period by Microbial Insights, Inc. Geochemical data are summarized on Table 3-1. 60342855 May 2015 AECOM Environment 4-1 4 Performance Results 4.1 Groundwater Elevation Data The groundwater potentiometric surface for November 2014 is included as Figure 4-1. Depth to groundwater during each monitoring event is summarized in Table 4-1. The potentiometric surface shown in Figure 4-1 indicates that groundwater flow gradients have both east and west components in the injection area. Due to the high permeability of the surficial sands at the site, little change was noted in groundwater elevations after the injection event. Groundwater elevations returned to baseline conditions almost immediately after injection and any variation in groundwater elevation during the post injection monitoring is likely a response to regional groundwater fluctuations. 4.2 Groundwater Volatile Organic Compound Results Baseline PCE concentrations in groundwater at IMW-1 collected on September 5, 2014 were higher than historical PCE concentrations detected on or off-site to date. The baseline sampling event for the remaining wells was conducted on October 21, 2014(13 days before injection). Data were received a few days prior to the permanganate injection on November 3, 2014. Based on laboratory analytical data,VOC concentrations in most of the on-site wells were higher by one to two orders of magnitude compared to the previous sampling event in May 2012. This significant increase was suggestive of a recent release of VOCs and is currently being investigated. PCE,trichloroethylene(TCE), and cis-1,2-dichloroethylene (DCE)were detected at concentrations above laboratory reporting limits during the performance monitoring period. Additionally, xylenes, carbon tetrachloride, 1,1-dichloroethane, methylene chloride, bromodichloromethane, chlorodibromomethane, chloroform, acetone, and methyl ethyl ketone were detected during the monitoring period. A summary of the detected VOCs is included in the attached Assessment Data Tables. Historical VOC concentrations are summarized in Table 4-2. Figure 4-2 is a PCE isoconcentration map of the injection site showing the PCE concentrations from post injection monitoring during December 5, 2014 and January 15, 2015. Figure 4-3 summarizes concentrations of PCE during the performance monitoring period. Laboratory data for the baseline and performance monitoring events are included as Appendix E. Figure 4-3 shows that the permanganate injection event was effective at reducing concentrations of PCE within the injection area (MW-33 and IMW-1)as of the January 15, 2015 sampling event. Limited production of daughter products, TCE, and cis- 1,2-DCE was observed. Trends in VOC concentrations after the injection in MW-33 and IMW-1 indicate oxidation of PCE and limited production of TCE and cis-1,2-DCE. Oxidizing conditions in the aquifer were maintained for approximately one month. VOCs concentrations decreased significantly during the injection monitoring period, but rebounded to levels slightly below baseline conditions. Trend plots for historical CVOC concentrations in monitoring wells in the injection area are included as Appendix F. 4.3 Secondary Effects (Geochemical Parameters) Field water quality parameters, pH, DO, ORP, and specific conductivity were measured at each well during performance monitoring events. A summary of the groundwater field parameters as well as groundwater color can be found in Table 4-3. Groundwater geochemical data indicate that the radius of influence of the injection was approximately 10 feet or less at most locations. After the pilot injection, pH increased in the surrounding monitoring wells. A significant increase in pH occurred at IMW-1 and MW-33 initially after injection and then began to decrease as the chemical oxidation process moved toward completion. There was only a slight increase in pH in MW-2 and MW-5 due to their distance from the injection area. After the injection, a decrease in DO was observed in monitoring wells MW-33 and IMW-1. As expected with an injection of a highly ionic solution like potassium permanganate, the specific conductivity of IMW-1 increased considerably. By the middle of the second month of performance monitoring the specific conductivity had decreased; however, it had not returned to baseline levels during the last sampling event on January 15, 2015. 60342855 May 2015 AECOM Environment 4-2 The ORP of groundwater from monitoring wells MW-33 and IMW-1 changed significantly after the injection. An initial increase was observed in IMW-1 before the permanganate reaction moved toward completion and the ORP began to return to baseline levels. The ORP in MW-33 continued to increase slightly over the performance monitoring period, possibly indicating the continued reaction of permanganate in the subsurface around the well. Groundwater color was also observed and recorded during the performance monitoring period. A purple color was almost immediately evident in IMW-1 and remained for approximately 22 days. A brown color was present at MW-33 during the first post-injection sampling event which is indicative of oxidized permanganate. Additionally, geochemical data including TOC, chloride, manganese, potassium, and sodium were collected at monitoring wells IMW-1 and MW-2 at various times during the performance monitoring period. The groundwater geochemistry at IMW-1 was affected by the permanganate injection due to its close proximity to the injection points. Geochemical data collected at monitoring well IMW-1 indicate an increase in potassium and manganese due to the injection of potassium permanganate. Elevated concentrations of potassium, manganese, and chloride remained for approximately six weeks during the monitoring period. The geochemistry of groundwater near MW-2 was not affected. Geochemical data are summarized on Table 3-1. 60342855 May 2015 AECOM Environment 5-1 5 Summary The pilot injection event involved the injection of 600 pounds of potassium permanganate(a total of 810 gallons of solution). Two months after the injection, concentrations of PCE decreased at MW-33 and IMW-1. The permanganate injection resulted in a general increase in the oxidizing potential and thus decreased PCE concentrations in the aquifer in the vicinity of the injection points. During the first sampling event after injection, a purple color was visible in groundwater at IMW-1 and a brown color was visible in MW-33 indicating the presence of potassium permanganate and oxidized potassium permanage, respectively. A significant increase in pH occurred at MW-33 and IMW-1 after injection, which decreased steadily the two months following injection. Generally, conductivity increased and DO decreased, as expected after oxidant injection. However, there were no significant changes in the geochemistry or field parameters at the surrounding monitoring wells (MW- 2, MW-3R, and MW-5) indicating the radius of influence was limited to a small area surrounding the injection. As stated previously,the significant increase in CVOC concentrations in each of the performance monitoring wells except MW- 1 during the baseline sampling event, suggests that there was a secondary release of CVOCs onsite prior to the pilot injections. After the injection and subsequent decrease in CVOC concentrations, rebound of PCE occurred in late November 2014. The rebound of PCE concentrations to concentrations in excess of 30 milligrams per liter indicates that repetitive injections would be necessary to complete source zone reduction. The high concentrations of CVOCs at this site(i.e. greater than 1 percent of the solubility)suggest the possible presence of residual dense non-aqueous phase liquid (DNAPL). Groundwater in the source area prior to injections was approximately 24 percent of the solubility for PCE. However, to date, DNAPL has not been identified at the site. In situ chemical oxidation (ISCO)treatments are generally not recommended for soils and groundwater that are heavily impacted by contamination due to high costs due to repeated dosing requirements. Free phase product is less amenable to ISCO than dissolved phase concentrations of CVOCs(Environmental Security Technology Certification Program [ESTCP], 2010);therefore, it is recommended that other technologies be evaluated to treat source area CVOCs. 60342855 May 2015 AECOM Environment 6-1 6 References ESTCP, 2010. Cost and Performance Report: Remediation of DNAPL Through Sequential In Situ Chemical Oxidation and Bioaugmentation. ER-200116. June 2010. 60342855 May 2015 AECOM Environment Tables 60342855 May 2015 Table 3-1 Summary of Geochemical Data Smitty's Cleaners (26-0003) 3060 Owen Drive, Fayetteville, NC MW-2 10/21/2014 1.30 6.30 0.10 3.20 9.70 10/21/2014 2.80 4.80 0.04 2.40 7.60 11/13/2014 41.00 54.00 75.00 610.00 11.00 IMW-1 12/18/2014 NA 37.00 3.00 280.00 9.10 12/29/2014 NA 11.00 0.09 140.00 7.70 1/15/2015 NA 9.10 2.00 110.00 7.50 Notes: TOC-Total Organic Carbon mg/L-milligrams per liter Ng/L-micrograms per liter AECOM Table 4-1 Summary of Groundwater Elevation Smitty's Cleaners (26-0003) 3060 Owen Drive, Fayetteville, NC MW1 178.85 178.55 NM NM NM NM NM NM MW2 177.97 NM NM NM 177.58 NM NM NM MW3R 178.74 NM NM NM 178.33 NM NM NM MW5 178.75 NM NM NM 178.71 NM NM NM MW33 178.28 177.83 178.1 177.78 Dry 177.9 178.54 179.00 I M W 1 178.65 1 178.29 1 178.18 1 178.40 178.35 178.03 1 178.99 1 179.00 Notes: Groundwater elevation shown in feet above mean sea leve NM-Water level not measured during sampling event AECOM Table 4-2 Summary of Volatile Organic Compound Concentrations in Groundwater Smitty's Cleaners (26-0003) 3060 Owen Drive, Fayetteville, NC MW-1 02/24/06 0.0157 <0.001 <0.001 09/13/07 0.045 <0.001 <0.001 08/05/08 0.036 <0.005 <0.005 04/24/09 0.013 <0.001 <0.001 07/07/09 0.0048 <0.0028 <0.005 10/14/09 0.0019 <0.001 <0.001 01/26/10 0.0007J <0.0028 <0.005 04/14/11 0.0011 <0.0028 <0.005 05/29/12 0.0007 <0.0028 <0.005 11/13/14 0.0014 <0.001 <0.001 MW-2 02/23/06 4.6 <0.100 <0.100 09/13/07 9.4 <0.050 <0.050 08/05/08 2.1 0.0022J 0.0013J 04/22/09 1.8 0.0019 0.0041 07/07/09 1.1 <0.014 0.0036J 10/13/09 0.530 0.0016 0.0072 01/26/10 0.420 0.00191 0.0084 04/14/11 0.170 0.00077J 0.00111 05/29/12 0.240 <0.0028 0.0012J 10/21/14 3.9 0.0053 0.00044 12/05/14 9.3 0.011 <0.025 MW-3R 11/08/06 0.079 <0.002 <0.001 08/05/08 0.130 <0.005 <0.005 04/23/09 0.460 0.0012 0.0017 07/07/09 0.280 0.00075J 0.00092J 10/13/09 0.200 0.00053J 0.00088J 01/26/10 0.150 0.0011 0.0048J 04/14/11 0.130 <0.0028 0.00077J 05/29/12 <0.0007 <0.0028 0.005 10/21/14 0.55 0.0017 <0.001 12/05/14 1.2 0.0023 <0.005 MW-5 11/10/06 0.063 <0.002 <0.001 09/13/07 0.040 <0.001 <0.001 08/05/08 0.010 <0.005 <0.005 04/24/09 0.022 <0.001 <0.001 07/07/09 0.020 <0.0028 <0.005 10/13/09 0.063 <0.001 <0.001 01/26/10 0.021 <0.0028 <0.005 04/14/11 0.021 <0.0028 <0.005 05/30/12 0.042 <0.0028 <0.005 10/21/14 14 0.24 0.19 12/05/14 14 0.11 <0.10 MW-33 6/13/12 0.027 <0.0028 <0.005 10/21/14 48 0.046 <0.05 11/13/14 16 0.021 0.0051 11/21/14 20 0.0099 0.0023 11/26/14 26 <0.50 <0.5 12/18/14 24 <0.025 <0.025 12/29/14 32 0.025 0.0074 1/15/15 34 <0.20 <0.20 IMW-1 10/21/14 18 <0.20 <0.025 11/13/14 0.0018 <0.001 <0.001 11/21/14 0.00056 J <0.001 <0.001 11/26/14 1.9 <0.001 <0.001 12/5/14 9.5 0.0044 0.00092 12/18/14 16 0.011 0.0024 12/29/14 13 0.015 0.0035 1/15/15 13 <0.10 <0.10 Note: mg/L-milligrams per liter Bold values are above laboratory detection limits AECOM Table 4-3 Summary of Field Parameters Smitty's Cleaners (26-0003) 3060 Owen Drive, Fayetteville, NC Sample Date Specific 10� (PS/cm) Field Measurement MW-1 04/24/09 4.03 293.9 5.17 161 NA 07/07/09 5.44 192.6 5.26 141 NA 10/14/09 5.84 140.7 4.93 95 NA 04/14/11 6.39 210.4 4.68 177 NA 11/13/14 6.63 123.9 5.03 210 clear MW-2 4/22/2009 3.13 205.2 5.27 146 NA 7/7/2009 4.12 139.9 5.32 138 NA 10/13/2009 3.76 98.1 5.32 226 NA 4/14/2011 5.04 197.3 5.44 149 NA 10/21/2014 4.19 128.2 5.75 138 clear 12/5/2014 2.81 101.2 5.97 130 clear MW-3R 4/23/09 Dry Dry Dry Dry NA 7/7/09 Dry Dry Dry Dry NA 10/13/09 Dry Dry Dry Dry NA 1/26/10 Dry Dry Dry Dry NA 4/14/11 Dry Dry Dry Dry NA 10/21/2014 5.59 151 5.75 174 clear 12/5/2014 Dry Dry Dry Dry NA MW-5 4/24/09 5.56 280.2 5.67 75 NA 7/7/09 3.65 82.5 5.54 56 NA 10/13/09 1.81 84.9 4.88 116 NA 4/14/11 6.52 192.8 4.66 65 NA 5/30/12 5.43 165.1 5.89 54 NA 10/21/14 4.1 232 5.09 52 clear 12/5/14 4.82 266.5 5.15 50 clear MW-33 10/21/2014 4.89 128.20 5.59 153 clear 11/13/2014 4.10 213.80 6.04 159 brown 11/21/2014 4.33 133.70 5.63 167 clear 11/26/2014 2.73 129.00 6.36 147 clear 12/5/2014 Dry Dry Dry Dry Dry 12/18/2014 3.01 137.00 6.13 142 clear 12/29/2014 3.47 167.20 6.01 153 clear 1/15/2015 2.74 273.90 5.46 170 clear IMW1 10/21/2014 2.89 66.60 6.22 125 clear 11/13/2014 1.24 677.80 6.70 1832 purple 11/21/2014 0.55 686.30 6.81 1851 purple 11/26/2014 1.07 705.30 6.77 1787 purple 12/5/2014 0.38 550.20 6.67 1508 pink 12/18/2014 1.27 255.10 6.41 590 clear 12/29/2014 1.36 226.90 6.50 588 clear 1/15/2015 1.26 212.60 6.33 426 clear -d Notes: DO-Dissolved Oxygen Dry-Well went dry during pumping mg/L-milligrams per liter my-millivolt NA-Not analyzed during sampling event ORP-Oxygen Reduction Potential pS/cm-microsiemens per centimeter AECOM AECOM Environment Figures 60342855 May 2015 i ^•:•,, PVC,/ • `pp����r+ J`. .. -y � All y wi LE r fA �r • x- mot► "- :,��:�'r •' �'' , . ���.� l, WA � JIB �1 �1'.�'� r C:�i® \ e• e 0 A =. =•• .• • - •- .• Location • • • • �� • 111 • • • •1 1 111 111 N m O r z LEGEND: i ¢ —--— PROPERTY BOUNDARY MONITORING WELL ABANDONED MONITORING WELL OWEN pR\VE MW-3 0 a-Oi •/• •/• MW-3R m o •/' /• FORMER DRY MOTORCYCLE •/• CLEANING ROOM ' y /' SHOP /''/• FORMER PCE AMERIGRANITE ./ MACHINE 2 ' E ` FORMER PCE 02 • MACHINE 1 a O MW-2�1 k 2 ` MW-5 COURTYARD MW-33 IMW-1 FORMER PCE MACHINE 3 I a Q w , W MIDDLE DRY I N w ` CLEANING • ROOM FORMER i LL • VARSOL o ` MACHINE I SMITTY'S N • CLEANERS z Z U U � #MW-4 w W m � I U (n , w M W ` BOILER 9 M0 ROOM o o> • C Lo o� MW 1 c o 04 04 S • •/' • •�-o ai ol .I co o '/• / fn co ow ` •�• �� oU • /'•/• •/• / rn 6z c0•/' W 't �Zn '/ /• ti w �•'/• ./•• ./� ti� Q U N co a_ '/,,/• ❑ ./••/•• � J Z O ga V aN •/' U L) 1"=30' •/. H p N m ai ./• �O M 0 JLL U^)� � 0- V! r x m O M Q LEGEND: d i PROPERTY BOUNDARY MONITORING WELL 9 INJECTION POINT 0 a Q FORMER DRY MOTORCYCLE CLEANING ROOM SHOP U L U U AMERIGRANITE m N 0 E FORMER PCE �o MACHINE 2 �N U� ail FORMER PCE z MACHINE 10 IP-1 9 IP-4 Z o e 0 COURTYARD V O 0 J w MW-5 19 9 IP-5 9 IP-8 ZO � H (D IP-7 9 IP-9 W 9 -O-IMW-1 Z M W-33 — 9 IP-6 N IP-3 0 9 FORMER PCE z MACHINE 3 Z) 0 U Q K m 7 U U) ui MIDDLE DRY o w CLEANING 9 U ROOM O �} M Lo 0 o� o 0 o N N � o �# f9 l Q a v co J� co r cc G c O o0 FORMER 0w co ai �z VARSOL W U J� MACHINE Q > co coo J'C z CD �Q 5 0 10 N a O O L) 1"=10" H o a) a) N� co T'o �o M L JLL x r m O � z LEGEND: h i ¢ ^ ■1 3 —--— PROPERTY BOUNDARY MONITORING WELL p pFtNE N OWE -�• p LL ABANDONED MONITORING WELL ^ MW_3 o a 178.74 GROUNDWATER ELEVATION(FT.MSL) —178.5— GROUNDWATER POTENTIOMETRIC CONTOUR ••/ (FT.MSL)(DASHED WHERE INFERRED) ' /•' ` GROUNDWATER FLOW DIRECTION /•'/• MW-3R 1 s •/' 178.74 U / /�• FORMER DRY •/' ' CLEANING ROOM -/ MOTORCYCLE y /' SHOP coo I /'•/, FORMER PCE AMERIGRANITE ` Lu w�' -/ I MACHINE 2 ' U ma ` I w ' FORMER PCE ' O C) 7 ' MACHINE 1 0I aLL ' COURTYARD U 2 M W-5 MW-2 2 \ 178.75 M W-33 IMW-1 177.971 2 w 178.64 178.28 W 2 CD o ` FORMER PCE z ` MACHINE 3 w 0 N w , I 0 ` ` ' Z m W 01 MIDDLE DRY I Q W a CLEANING , a uj O ROOM FORMER W Z VARSOL I Q o ` MACHINE N SMITTY'S CLEANERS I z 0 I , o I a ` #MW-4 of w m � ` I U u w ` M ? w ` BOILER 0 ROOM o m I ch Lo > ` O O o 179.14 , 04 N Co FL Jai •� . Co O ono ,/ •/• / v� fn Co oz ` /� /•' A to4/ W U Lu Co zo Z(r J p Z cfl a V o 1. aq.N ,/' O .) 1"=30' •/, ~o m ai .�• �O M 0 JLL U^)� � 0- V! N x ' m � � z LEGEND: i a —--— PROPERTY BOUNDARY MONITORING WELL / EN VIP ., { ABANDONED MONITORING WELL / OW MW-3 •/ o �a/' ■ a 9.3 PCE ISOCONCENTRATION (mg/L) —0.7— GROUNDWATER PCE ISOCONCENTRATION / / / /•'/ ■ CONTOUR(mg/L)(DASHED WHERE INFERRED) PCE TETRACHLOROETHYLENE 1010 / •/'' ' 0 mg/L MILLIGRAMS PER LITER •' / ■ NS NOT SAMPLED / / 1.2 FORMER DRY 1.2 0 NOTES / LEANING ROOD / 1.GROUNDWATER SAMPLES COLLECTED ON ✓/.•�j® ' DECEMBER 5,2014 AND JANUARY 15,2015 / MOTORCYCLE ' FORMER PCE AMERIGRANITE SHOP d E /• MACHINE 2 / FORMER PCE z MACHINE 1 ` 1 I 0 �� ♦ I MW 5 COURTYARD M , 1 I o , I I 14 34 13W-1 9.3 I , W 34 U a \ I ` FORMER PCE ■ / Z CD U I MACHINE 3 20 / / / U O < S2 Q MIDDLE DRY I / W z w ` CLEANING a 0 ` ` ` ROOM FORMER / • ` VARSOL I e Lu F- o ` ` MACHINE e SMI / p � ♦ ` I Z CLEANERS e ` 7 / / ` 0 0 ./ NS MW-4 0 / 0000- /I In ® ® / ®, 0.007 Z , BOILER / c� e U ROOM ` 9) 10.0007 ' M Lo > o o MW-1 I o 0 0.0014 1 c N NIA ♦ ./'• ` ' •_'• / to04 co �o ♦ ,/ rnz ♦ /' ' C CD w / 0L�z 0 U ♦ i ♦ '/• co W 0 oa- tw- oa / 11, 15 0 30 •/ 2 fn a)a� ' 3: .5; Z N N \ . = N c ' 1"=30' ,• H C:) a) a) JLL x M O � m z LEGEND: 11/8/06 0.079 a —--— PROPERTY BOUNDARY 8/5108 0.130 4/23/09 0.460 MONITORING WELL OWEN pR��E 717/09 0.280 /•' ABANDONED MONITORING WELL MW-3 10/13/09 0.200 2 a PCE TETRACHLOROETHYLENE 1/26/10 0.150 ' mg/L MILLIGRAMS PER LITER 4114/11 0.130 5/29/12 <0.0007 ' WELL ID /.•/• 10/21/14 0.55 ' s MW-3R 12/5/14 1.20 ' 9/5/2014 24 ./• ' U 10/21/2014 18 •/ FORMER DRY SAMPLE DATE PCE CONCENTRATION . ./ CLEANING ROOM ' ° (mg/L) / / MOTORCYCLE y •/' SHOP 0 �o •/•,/' FORMER PCE AMERIGRANITE • MACHINE 2 ' Z z ` 2 �0 FORMER PCE ' O MACHINE 1 0 I Z J aw ` COURTYARD MW-2 W U M W-5 Q IMW-1 0 ; MW-33 2/23106 4.60 O ` 9/13/07 9.40 Z Z LL FORMER PCE U • 1v1o/os 0.063 MACHINE 3 I V p ' 8/5/08 2.10 It 9/13/07 0.040 4/22/09 1.80 Z II.- 8/5/08 0.010 9/5/2014 24 , 7/7/09 1.10 Z Mi 4/24/09 0.022 MIDDLE DRY 10/21/2014 18 I 10/13/09 0.53 W O a 7/7/09 0.020 CLEANING 11/13/2014 0.0018 1126/10 0.42 V w ` 6113/12 0.027 ' d 10/13/09 0.063 ROOM FORMER 11/21/2014 0.00056J ' 4/14/11 0.17 J W • 10/21/14 48 I LL ` 1/26/10 0.021 VARSOL 11/26/2014 1.90 Q ~ 11/13/14 16 5/29/12 0.24 U V 0 4/14/11 0.021 11/13/14 20 MACHINE 12/5/2014 9.50 10/21/14 3.90 Lu c=i 11/26/14 26 12/18/2014 16.00 I 0 � 5/30/12 0.042 12/5/14 9.30 W w ` 10/21/14 14 e 12/18/14 24 12/29/2014 13.00 07 N • 12/5/14 14 12/29/14 32 1/15/2015 13.00 2 ' SMITTY'S 1115115 34 I Z ` CLEANERS ' 0 U � I #MW-4 w m � I U w cM z ` iw p ` BOILER ROOM o �n M > • Lo MW-1 I p o 04 ' 04 co FL 2/24/06 0.0157 ; ��.��� U 0 J o 0.045 i ZI /.• 8/5/08 0.036 G c o �o ` ,/'• 4l24/09 0.013 •/.�/ / y O o z •• / •/• 7/7/09 0.0048 ,/' W o • /•' 10/14/09 0.0019 ,/" Q Z t N w w •• 1/26110 0.0007J j W.>_ p M O oa 4zo /14/11 0.0011 ❑ •/.•/•• V� z oQ 5/29/12 0.0007 15 0 30 •/ 2 fn � a O '� • 11/13/14 0.0014 /••/• z �N �0 L) 1 =30' T•o m a�i ./• �O M L JLL U^)� ILL0- V! AECOM Environment Appendix A. Underground Injection Control Permit 60342855 May 2015 i i HCDEENR North Carolina department of Environment and Natural Resources Division at Water Quality Beverly Eaves Perdue Coleen H. Sullins Dee Freeman Governor Director Secretary February 28,2011 Petitioner for DSCA Site 26-0003 =i j.s DSCA Program Mail Service Center 1646 Raleigh,North Carolina 27699-1646 Ref: Issuance of Injection Permit WI0600068 Smitty's Cleaners DSCA Site#26-0003 Injection hi situ Groundwater Remediation Wells (5I) Fayetteville, Cumberland County,North Carolina. Dear Petitioner: In accordance with the application received on December 30,2010, and the supporting data received January 25,2011, we are forwarding permit number WI0600068. This permit is to inject sodium permanganate and potassium permanganate to remediate groundwater contaminated with dry cleaning solvents (tetrachloroethyhene and daughter products) at the facility referenced above. This permit shall be effective from the date of issuance until January 31, 2014, and shall be subject to the conditions and limitations stated therein, including the requirement to submit a final project evaluation as stated in PART VII—MONITORING AND REPORTING REQUIREMENTS. Please read the entire permit to ensure that you are aware of all compliance requirements of the permit. You will need to notify this office by telephone 48 hours prior to initiation of operation of the facility. In order to continue uninterrupted legal use of the injection facility for the stated purpose, you must submit an application to renew the permit 120 days prior to its expiration date. Please contact me at (919) 715-6162 or at david.goodrich@ncdenr.gov if you have any questions about your permit. Best Regards, P11 l David Goodrich Hydrogeologist cc: Art Barnhardt,Fayetteville Regional Office Justin C. Ballard,ATC Associates of North Carolina,PC,2725 East Millbrook Road, Suite 121,Raleigh,NC 27604 Al Chapman,DWM Superfund Section, 1646 Mail Service Center,Raleigh,NC 27699-1646 Fayetteville Public Works Commission,P.O.Box 1089,Fayetteville,NC 28302 Buck Wilson,Cumberland County Health Department,Environmental Health Section, 1235 Ramsey Street, Fayetteville,NC 28301 WI0600068 Permit File AQUIFER PROTECTION SECTION 1636 Mail Service Center,Raleigh,North Carolina 27699-1636 Location:2728 Capital Boulevard,Raleigh,North Carolina 27604 One Phone:919-733-3221\FAX 1:919-715-0588;FAX 2:919-715-6048,Customer Service:1-877-623-6748 NorthCaroliiia Internet:www.ncwaterguality.org A Wtv. An Equal Gpporuni�:1,�ffirmative Aciicn Employe- p. € NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES RALEIGH, NORTH CAROLINA PERMIT FOR THE CONSTRUCTION AND OPERATION OF A WELL FOR INJECTION In accordance with the provisions of Article 7, Chapter 87; Article 21, Chapter 143, and other applicable Laws, Rules, and Regulations PERMISSION IS HEREBY GRANTED TO Petitioner for DSCA Site No. 26-0003 FOR THE CONSTRUCTION AND OPERATION OF 107 TYPE 5I INJECTION WELLS, defined in Title 15A North Carolina Administrative Code 2C .0209(e)(3)(C), to inject Sodium Pemanganate and Potassium Permanganate, for the oxidation of chlorinated dry cleaning solvents which include PCE. These injection wells/points will be located at Smitty's Cleaners Site, 3060 Owen Drive, Fayetteville, Cumberland County, North Carolina, and will be operated in accordance with the application submitted December 29, 2010, and in conformity with the specifications and supporting data submitted January 25, 2011, all of which are filed with the Department of Environment and Natural Resources and are considered a part of this permit. This permit is for Construction and Operation only, and does not waive any provisions of the Water Use Act or any other applicable Laws, Rules, or Regulations. Operation and use of an injection well shall be in compliance with Title 15A North Carolina Administrative Code 2C .0100 and .0200, and any other Laws, Rules, and Regulations pertaining to well construction and use. This permit shall be effective, unless revoked, from the date of its issuance until January 31, 2014, and shall be subject to the specified conditions and limitations set forth in Parts I through X hereof. I Permit issued this the 28th day of February, 2011. LA* Lor Coleen H. Sullins, Director Division of Water Quality By Authority of the Environmental Management Commission. Permit No.WI0600068 PAGE 1 OF 5 ver.Feb.2011 AP/UIC-6 PART I- WELL CONSTRUCTION GENERAL CONDITIONS 1. The Permittee must comply with all conditions of this permit and with the standards and criteria specified in Criteria and Standards Applicable to Injection Wells (15A NCAC 2C .0200). Any noncompliance with conditions of this permit constitutes a violation of the North Carolina Well Construction Act and is grounds for enforcement action as provided for in N.C.G.S. 87-94. 2. This permit shall become voidable unless the facility is constructed in accordance with the conditions of this permit, the approved plans and specifications, and other supporting data. 3. This permit is valid only for the performance of the number of subsurface injections described in the application and other supporting data. The performance of additional injections must be approved in advance by the Aquifer Protection Section. 4. Each injection shall be performed and the injection hole immediately backfilled with hydrated bentonite so that water from land surface cannot migrate into the subsurface. PART II -WELL CONSTRUCTION SPECIAL CONDITIONS At least forty-eight (48) hours prior to performing each boring and injection event, the Permittee shall notify the Aquifer Protection Section-Underground Injection Control (UIC) Central Office staff, telephone number (919) 715-715-6162 and the Fayetteville Regional Office Aquifer Protection Section Staff, telephone number (910) 433-3300. PART III - OPERATION AND USE GENERAL CONDITIONS 1. This permit is effective only with respect to the nature, volume of materials, rate of injection, and number of injection events as described in the application and other supporting data. 2. This permit is not transferable without prior notice to, and approval by, the Director of the Division of Water Quality (Director). In the event there is a desire for the facility to change ownership, or there is a name change of the Permittee, a formal permit amendment request must be submitted to the Director, including any supporting materials as may be appropriate, at least 30 days prior to the date of the change. 3. The issuance of this permit shall not relieve the Permittee of the responsibility of complying with any and all statutes, rules, regulations, or ordinances which may be imposed by other local, state, and federal agencies which have jurisdiction. Furthermore, the issuance of this permit does not imply that all regulatory requirements have been met. PART IV - PERFORMANCE STANDARDS 1. The Permittee shall be required to comply with the terms and conditions of this permit even if compliance requires a reduction or elimination of the permitted activity. 2. The issuance of this permit shall not relieve the Permittee of the responsibility for damages to surface or groundwater resulting from the operation of this facility. Pen-nit No. WI0600068 PAGE 2 OF 5 ver-Feb.201 I AP/UIC-6 i PART V- OPERATION AND MAINTENANCE REQUIREMENTS 1. The Permittee must notify the Division and receive prior written approval from the Director of any planned alterations or additions to the permitted procedure, or for any activity not specifically authorized by the permit. 2. At least forty-eight (48) hours prior to the initiation of the operation of the facility for injection, the Permittee must notify by telephone the Aquifer Protection Section-UIC, Central Office staff, telephone number (919) 715-6162. Notification is required so that Division staff can inspect or otherwise review the injection facility and determine if it is in compliance with permit conditions. PART VI -INSPECTIONS 1. Any duly authorized officer, employee, or representative of the Division of Water Quality may, upon presentation of credentials, enter and inspect any property, premises, or place on or related to the injection facility at any reasonable time for the purpose of determining compliance with this permit, may inspect or copy any records that must be maintained under the terms and conditions of this permit, and may obtain samples of groundwater, surface water, or injection fluids. 2. Department representatives shall have reasonable access for purposes of inspection, observation, and sampling associated with injection and any related facilities as provided for in N.C.G.S. 87-90. 3. Provisions shall be made for collecting any necessary and appropriate samples associated with the injection facility activities. PART VII - MONITORING AND REPORTING REQUIREMENTS 1. The proposed monitoring plan included in the application shall be followed. All sample results shall be submitted to the Aquifer Protection Section's Fayetteville Regional Office and the Raleigh Central Office. Any monitoring (including groundwater, surface water, or soil sampling) deemed necessary by the Division of Water Quality to ensure surface and ground water protection, will be established and an acceptable sampling reporting schedule shall be followed. i i 2. The Permittee shall submit an Injection Event Record within 30 days of completing each injection. 3. The Permittee shall produce a final project evaluation within 9 months after completing all injection-related activity associated with this permit or produce a project interim evaluation before submitting a renewal application for this permit. This document shall assess the injection projects findings in a written summary. The final project evaluation shall also contain monitoring well sampling data, contaminant plume maps and potentiometric surface maps. Permit No.WI0600068 PAGE 3 OF 5 ver.Feb.2011 AP/UIC-6 4. The monitoring results and the final project evaluation shall be submitted to: Aquifer Protection Section-UIC Program DENR-Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 and to: Aquifer Protection Section DENR-DWQ Fayetteville Regional Office 225 Green Street Suite 714/ Systel Building Fayetteville,NC 28301-5043 5. The Permittee shall report by telephone, within 48 hours of the occurrence or first knowledge of the occurrence, to the Fayetteville Regional Office, telephone number (910) 433-3300, any of the following: (A)Any occurrence at the injection facility which results in any unusual operating circumstances; (B)Any failure due to known or unknown reasons, that renders the facility incapable of proper injection operations, such as mechanical or electrical failures. 6. Where the Permittee becomes aware of an omission of any relevant facts in a permit application, or of any incorrect information submitted in said application or in any report to the Director, the relevant and correct facts or information shall be promptly submitted to the Director by the Permittee. 7. In the event that the permitted facility fails to perform satisfactorily, the Permittee shall take such immediate action as may be required by the Director. PART VIII - PERMIT RENEWAL In order to continue uninterrupted legal use of the injection facility for the stated purpose, the Permittee must submit an application to renew the permit 120 days prior to its expiration date. PART IX - CHANGE OF WELL STATUS 1. When operations have ceased at the facility and a well will no longer be used for any purpose, the Permittee shall abandon that well in accordance with the procedures specified in 15A NCAC 2C .0214, including but not limited to the following: (A)All casing and screen materials may be removed prior to initiation of abandonment procedures if such removal will not cause or contribute to contamination of the groundwaters. (B)The entire depth of each well shall be sounded before it is sealed to insure freedom from obstructions that may interfere with sealing operations. Permit No.WI0600068 PAGE 4 OF 5 ver.Feb.2011 AP/UIC-6 i (C)The well shall be thoroughly disinfected, prior to sealing, if the Director determines that failure to do so could lead to the contamination of an underground source of drinking water. (D)Drilled wells shall be completely filled with cement grout or bentonite grout, which shall be introduced into the well through a pipe which extends to the bottom of the well and is raised as the well is filled. (E) In the case of gravel-packed wells in which the casing and screens have not been removed, neat-cement, or bentonite grout shall be injected into the well completely filling it from the bottom of the casing to the top. (F) In those cases when, as a result of the injection operations, a subsurface cavity has been created, each well shall be abandoned in such a manner that will prevent the movement of fluids into or between underground sources of drinking water and in accordance with the terms and conditions of the permit. (G)The Permittee shall submit a Well Abandonment Record (Form GW-30) as specified in 15A NCAC 2C .0213(h)(1) within 30 days of completion of abandonment. 2. The written documentation required in Part IX (1) and (2) (G) shall be submitted to: Aquifer Protection Section-UIC Program DENR-Division of Water Quality 1636 Mail Service Center Raleigh,NC 27699-1636 PART X—WORKER PRECAUTIONS DURING APPLICATION 1. Some effects reported to be associated with the product proposed to be used are as follows: eye, skin, nose, throat, and lung irritation. If the product is released into the environment in a way that could result in a suspension of fine solid or liquid particles (e.g., grinding, blending, vigorous shaking or mixing), then proper personal protective equipment should be used. The application process should be reviewed by an industrial hygienist to ensure that the most appropriate personal protective equipment is used. j 2. Persons working with these products should wear goggles or a face shield, gloves, and protective clothing. Face and body protection should be used for anticipated splashes or sprays. 3. Eating, drinking, smoking, handling contact lenses, and applying cosmetics should not be permitted in the application area during or immediately following application. 4. Safety controls should be in place to ensure that the check valve and the pressure delivery systems are working properly. 5. The Material Safety Data Sheets should be followed to prevent incompatible or adverse reactions and injuries. Permit No.WI0600068 PAGE 5 OF 5 ver. Feb.2011 AP/UIC-6 2725 East Millbrook Road CvvATC Suite 121 Raleigh, NC 27604 Tel: 919-871-0999 Fax: 919-871-0335 ATC ASSOCIATES OF NORTH CAROLINA,P.C. www.atcassociates.com Engineering Individual Solutions N.C. Engineering License No. C-1598 January 31, 2014 Mr. Thomas Slusser NCDENR Division of Water Quality Aquifer Protection Section, UIC Program 1636 Mail Service Center Raleigh,North Carolina 27699-1636 RE: Injection Permit WI0600068 Renewal Application Smitty's Cleaners 3060 Owen Drive Fayetteville, Cumberland County,NC DSCA Site Identification#26-0003 Dear Mr. Slusser: Enclosed are two copies of a renewal application for injection permit WI060068 prepared by ATC Associates of North Carolina, P.C. (ATC) under contract to the North Carolina Drycleaning Solvent Cleanup Act (DSCA) Program. The permit covers injection of sodium and potassium permanganate for chemical oxidation of chlorinated solvent compounds at the above referenced site. The work has been postponed to date, but is expected to be implemented in the near future. Per instructions from the UIC Program Staff, ATC understands that for a renewal application submittal of only Sections I and II of the permit application are required. However, ATC has also completed Section III and is including a new site access agreement because the site property owner has changed. If you have questions or require additional information, please do not hesitate to contact us at (919) 871-0999. Sincerely, ATC Associates of North Carolina, P.C. Cw Justin C. Ballard, P.G. Genna K. Olson, P.G. Project Manager Program Manager cc: Al Chapman—NCDENR DSCA Program Attachment: Updated Property Access Agreement North Carolina Department of Environment and Natural Resources APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION In Situ Groundwater Remediation (15A NCAC 02C.0225) I Tracer Injection (15A NCAC 02C.0229) Do not use this form for the following: • in situ remediation,tracer,or aquifer test injection wells permitted by rule(ref. 15A NCAC 02C.0217) • remediation systems that reinject treated contaminated groundwater(ref. 15A NCAC 02T.1600) Application Number(to be completed by DWR): L APPLICATION INFORMATION 1. Project is: []New [] Modification [x] Renewal without modification [] Renewal with modification 2. If this application is being submitted for renewal or modification to an existing permit,provide: existing permit number W10600068 and the issuance date February 28,2011 For renewal without modifications,fill out sections I&H only, sign the certification on the last page of this form, and obtain the property owner's signature to indicate consent(if the applicant is not the owner). For all renewals, submit a status report including monitoring results of all injection activities to date. II. WELL OWNER(generally the responsible party) 1. Name: Joyce W. Smith (Petitioner for DSCA Site#26-0003) 2. Signing Official's Name*: Justin C. Ballard Title: Project Manager * Signing Official must be in accordance with instructions in Part IX on page 5. 3. Mailing address of applicant: DSCA Program,Mail Service Center 1646 City: Raleigh State: NC Zip: 27699 4. Telephone number: 919-707-8368 Email: al.chapmankricdetingov 5. Status (choose one): x Individual Business/Org. Federal State County Municipality III. PROPERTY OWNER(if different than well owner) 1. Name: Mr. Young Bang 2. Physical address: 722 Murray Hill Road City: Fayetteville State: NC Zip: 28303 3. Mailing address: 722 Murray Hill Road City: Fayetteville State: NC Zip: 28303 4. Telephone number: Unknown Email: Unknown IIII. PROJECT CONTACT—Person who can answer technical questions about the proposed injection project. 1. Name: Justin Ballard Title: Project Manager 2. Company: ATC Associates of North Carolina,P.C. 3. Address: 2725 E. Millbrook Rd 4. City: Raleigh State: NC Zip: 27604 5. Telephone number: 919-871-0999 Email: Justin.ballard(a cardno.com Revised 11/19/2013 UIC-51/5T Page 1 of 5 ACCESS AGREEMENT B (Petitioner is NOT the Property Owner) Site Name: Smitty's Cleaners Address: 3058 Owen Drive, Fayetteville, NC County: Cumberland DSCA Site ID No.: 26-0003 Name of Property Owner typed or printed: Mr. Young Bang WHEREAS, Mr. Younq Bang (name of Property Owner, hereinafter: Property Owner) is the owner of a parcel of property located at 3058 Owen Drive, Fayetteville, NC in Cumberland County, North Carolina (Property); and WHEREAS, (the petitioner) is petitioning to the North Carolina Department of Environment and Natural Resources, Division of Waste Management (Division) for certification of the Property into the Dry-Cleaning Solvent Cleanup Act Program (Program) pursuant to the Dry-Cleaning Solvent Cleanup Act of 1997 as amended, Part 6, Article 21A, Chapter 143, N.C.G.S. § 143-215.104A et seq. (DSCA); and WHEREAS, the Petitioner intends to enter into an Agreement for Assessment and Remediation (ARA) with the Division concerning the Dry- Cleaning Solvent contamination on the Property; and WHEREAS, the implementation of the ARA will require that the Division and its independent contractors (contractors) have free and unencumbered access to the Property for the purposes of investigating, assessing and remediating Dry-Cleaning Solvent contamination on and around the Property; and WHEREAS, the parties to this Access Agreement are the Division and Property Owner; NOW THEREFORE, in consideration of the terms and conditions contained in this Access Agreement, and for other good and valuable consideration, the receipt and sufficiency of which are hereby acknowledged, the parties hereto agree as follows: Access Agreement B(March 6,2006) Page 1. Grant of License and Permission, Property Owner hereby grants (a) to the Division a license to access the Property to monitor and enforce the ARA and (b) to the Division's contractor(s) a license to access the Property to undertake all work to be performed at the Property, including, but not limited to, the following purposes: a. Inspecting, sketching and photographing the Property; b. Taking such soil, water and air samples as may be necessary; C. Taking other actions related to the investigation of surface or subsurface conditions, such as installation of monitoring wells or excavation of impacted soil; d. Transportation of equipment onto and around the Property as necessary to accomplish the investigation; e. Taking response actions necessary to mitigate any threat to human health and the environment; f. Remediating dry-cleaning solvent contamination at the Property as needed; and g. Undertaking such other activities as necessary to complete the work to be performed as required or permitted under the ARA. 2. Conditions Precedent. The licenses created in Paragraph 1 shall take effect upon the certification of the Property into the Program and shall remain in effect, unless otherwise terminated pursuant to Paragraph 12 below so long as the Property remains certified under the Program. 3. Observation. Upon the Property Owner's reasonable notice and request, the Property Owner and its consultants shall have the right to observe any activities performed by or on behalf of the Division at the Property. Upon the Property Owner's reasonable notice and request, the Division or its contractors shall allow the Property Owner to split samples of any environmental samples obtained on behalf of the Division. All costs associated with obtaining and analyzing the split samples shall be borne solely by the Property Owner. 4. Interference. The Division and its contractors shall endeavor to perform any activities authorized hereunder at the Property in a manner that minimizes interference with the use of the Property. The Division and its contractors will make reasonable attempts to notify the Property Owner at least 48 hours prior to entering the Property for the purposes stated in Paragraph 1. Access Agreement B(March 6,2006) Page 2 5. Insurance. The Division's contractors have agreed to maintain the insurances as defined in their agreement with the Division, provided however, that the Division shall have no liability for its contractor's failure to maintain such insurance. 6. Site Repair. The Division or its contractors shall remove and shall have the right to remove from the Property all equipment and other materials belonging to the Division or its contractors within a reasonable period of time after the completion of the activities at the Property authorized hereunder. To the extent practicable, the Division's contractors shall restore the Property to the original condition it was in prior to any activities authorized hereunder at the Property, and except as otherwise agreed to by the parties, shall properly abandon any monitoring wells in accordance with any applicable laws and regulations. 7. Protection of Wells and Equipment. The Property Owner shall not damage, remove, pave over or cover any monitoring or remediation wells on the property. The Property Owner also shall not tamper with or affect the operation of assessment or remediation equipment installed on the property by the Division's contractors. 8. Notice. Any notices, reports, or other communications required or permitted under this Access Agreement shall be addressed to the representative for each party as set forth below:. To Property Owner: Mr. Young Bang 722 Murray Hill Road Fayetteville, NC 28303 To the Division: Mr. Al Chapman, L.G. DSCA Program NC Division of Waste Management 1646 Mail Service Center Raleigh, NC 27699-1646 9. Limitations. All obligations of the Division pursuant to this Access Agreement shall be contingent upon the availability of moneys in the North Carolina Dry-Cleaning Solvent Act Fund. 10. Governing Law. This Access Agreement shall be governed by and construed in accordance with the laws of the State of North Carolina, without reference to choice of law principles. 11. Integration Clause. This Access Agreement represents the entire understanding and agreement between the parties hereto and supersedes any Access Agreement B(March 6,2006) Page 3 and all prior agreements, whether written or oral, that may exist between the parties regarding same. No amendment or modification to this Access Agreement or any waiver of any provisions hereof shall be effective unless in writing and signed by both parties. 12. Termination. The licenses created in Paragraph 1 may be terminated upon delivery of reasonable written notice to the Division, which termination shall be effective upon receipt of such notice. However, such termination will also terminate the ARA and cause the forfeiture of liability protection under the DSCA. If no such notice is served and subject to provisions of Paragraph 2 above, the licenses created herein shall remain in effect until such time as all work or activities under the Program have been completed at the Property. The right and obligation set out in the first sentence of Paragraph 6 shall survive the termination of this license. 13. Modification. This Access Agreement may not be amended except in writing by the parties to this Access Agreement. The parties each represent and warrant that this Access Agreement is executed by their duly authorized representatives as of the date accepted and agreed upon below. Accepted and agreed, this day of zso-1FE -- (Si ature of perty Owner) (Signature for the Division) Access Agreement B(March 6,2006) Page 4 AECOM Environment Appendix B. Monitoring Well Construction Record/Lithology 60342855 May 2015 WELL CONSTRUCTION RECORD For Internal Use ONLY: This form can be used for single or multiple wells 1.Well Contractor Information: John Allen 14.WATER ZONES FROM TO DESCRIPTION Well Contractor Name ft. ft. 4196-B ft. ft. NC Well Contractor Certification Number 15.OUTER CASING for multi-cased wells OR LINER if a licable FROM TO DIAMETER THICKNESS MATERIAL Probe Technology, Inc. 0 ft. 14 ft 1.5 i° 1 schd.40 1 PVC Company Name 16.INNER CASING OR TUBING eother at closed-loop) FROM TO DIAMETER THICKNESS MATERIAL 2.Well Construction Permit#: ft. ft. in. List all applicable well permits(i.e.County,State,Variance,Injection,etc) fL ft. in. 3.Well Use(check well use): 17.SCREEN Water Supply Well: FROM TO DIAMETER SLOT SIZE THICKNESS MATERIAL ❑Agricultural ❑Municipal/Public 14 tf 24 tt' 1.5 in. 0.010 schd.40 PVC El Geothermal(Heating/Cooling Supply) El Residential Water Supply(single) fL ft. in. ❑Industrial/Commercial El Residential Water Supply(shared) 18.GROUT FROM TO MATERIAL EMPLACEMENT METHOD&AMOUNT ❑litigation 0 ft. 10 fL portland pour Non-Water Supply Well: 10 IL 12 IL bentonite pour ❑ZMonitoring ❑Recovery Injection Well: fL fL El Aquifer Recharge ❑Groundwater Remediation 19.SAND/GRAVEL PACK(if applicable) El Aquifer Storage and Recovery El Salinity Barrier FROM TO MATERIAL EMPLACEMENT METHOD fL tr. El Aquifer Test ❑Stormwater Drainage 12 24 silica pour ft. fL ❑Experimental Technology ❑Subsidence Control 20.DRILLING LOG attach additional sheets if necessar ❑Geothermal(Closed Loop) ❑Tracer FROM TO DESCRIPTION(color,hardness,soil/rock type,grain size,etc.) El Geothermal(Heating/Cooling Return) ❑Other(explain under#21 Remarks) fL ft fL ft 4.Date Well 9-4-14 s)Completed: Well ID# NW-1 fL ft. 5a.Well Location: ft ft Smitty's Cleaners rL ft Facility/Owner Name Facility ID#(if applicable) fL ft. 3060 Owen Drive, Fayetteville, NC, NC Physical Address,City,and Zip 21.REMARKS Cumberland All wells constructed with 2 feet of sand over the screen, at least 2 county Parcel Identification No.(PIN) feet of bentonite and grout to surface. 5b.Latitude and Longitude in degrees/minutes/seconds or decimal degrees: 22•Certification: (if well field,one lat/long is sufficient) 35 1' 10.3" N 78 53' 48.4" W �- 9-23-14 Signature of Certified Well Contractor Date 6.Is(are)the well(s): ZPermanent or ❑Temporary By signing this form,I hereby certify that the well(s)was(were)constructed in accordance with 15A NCAC 02C.0100 or 15A NCAC 02C.0200 Well Construction Standards and that a 7.Is this a repair to an existing well: ❑Yes or 91No copy of this record has been provided to the well owner. If this is a repair,fill out known well construction information and explain the nature of the repair under#21 remarks section or on the back of this form. 23.Site diagram or additional well details: You may use the back of this page to provide additional well site details or well 8.Number of wells constructed: 1 construction details. You may also attach additional pages if necessary. For multiple injection or non-water supply wells ONLY with the same construction,you can submit one form. SUBMITTAL INSTUCTIONS 9.Total well depth below land surface: 24 (ft.) 24a. For All Wells: Submit this form within 30 days of completion of well For multiple wells list all depths if different(example-3@200'and 2@100') construction to the following: 10.Static water level below top of casing: (ft.) Division of Water Resources,Information Processing Unit, If water level is above casing,use"+" 1617 Mail Service Center,Raleigh,NC 27699-1617 11.Borehole diameter: 3 (in.) 24b.For Iniection Wells ONLY: In addition to sending the form to the address in 24a above, also submit a copy of this form within 30 days of completion of well 12.Well construction method: DPT construction to the following: (i.e.auger,rotary,cable,direct push,etc.) Division of Water Resources,Underground Injection Control Program, FOR WATER SUPPLY WELLS ONLY: 1636 Mail Service Center,Raleigh,NC 27699-1636 13a.Yield m Method of test: 24c.For Water Supply&Injection Wells: (gP ) Also submit one copy of this form within 30 days of completion of 13b.Disinfection type: Amount: well construction to the county health department of the county where constructed. Form GW-1 North Carolina Department of Environment and Natural Resources-Division of Water Resources Revised August 2013 A=COM Att. XX: Well Completion Log Well ID: IMW-1 Project: Smitty's Cleaners Date: 4 Sept 2014 Drilling Contractor: Probe Technologies,Inc. Address 3060 Owen Drive,Fayetteville Logged By: Guy Allard Drill Rig Type:GeoProbe Project#: 60321176 Well Diameter/Material: 1.5"PVC Method: Hollow Stem Auger Geol. Depth DPT Drilling ID Graphic (ft) Recovery Lithology Well Construction Method 0 ----------- Concrete Slab ------------------------ Light tan/orange fine SANDS,dry Grout: .5-10' 5 Light tan/Brown fine and medium unrecorded coarse SANDS,well sorted,dry 1.5"PVC Riser:0-14' 10 2.5'DPT Recovery = c a Bentonite s Seal: 10-12' CD ------ --------------------------- CD gray/white coarse SAND well sorted and moist Filter Pack: 12-24' 15 3'DPT Recovery -------------------------- ------ Dark orange coarse SAND,well sorted 1.5"0.010 and moist PVC Screen: ------ -------------------------— 14-24' Light gray/white coarse SAND,well sorted and saturated -. . -20 4'DPT -------------------------— Recovery Dark gray coarse SANDS,poorly sorted and saturated --------------------------- Dark orange,CLAYEY SAND, saturated ------------------- Black,CLAY, some silts and moist AECOM Remarks: 701 Corporate Center Drive,Suite 475 Northing: DPT=Direct Push Technology Technolo Raleigh,NC 27607 Easting: Phone:(919)854-6200 Fax:(919)854-6200 ft,msl=feet mean sea level;n=number of blows TOC Elevation: AECOM Environment Appendix C. Contractor's Injection Report 60342855 May 2015 REDOX TECH, LLC "Providing Innovative In Situ Soil and Groundwater Treatment" Field Summary Report AECOM - Fayetteville, NC Prepared by Ivan Blackman on 1113012014 Field Contractor Redox Tech, LLC Client AECOM Environment Project Leads Ivan Blackman Project Lead Matt Allen Phone Number 919-678-0140 Phone Number 919-239-7160 Email Address blackman@redox-tech.com Email Address matthew.allen@aecom.com Start Date 11/03/2014 End Date 11/05/2014 Chemicals 600 lbs Potassium Permanganate Total Injection Points 9 injection points Injection depths and intervals with volume of injectate are presented in Table I Total Solution Injected: 810 gals of solution along with 180 gallons of chase water Brief Narrative Redox Tech performed potassium permanganate injection services from November 3-5, 2014, at the Owens Drive site in Fayetteville, NC . Redox personnel included Ernest Hatcher, James Murphy, and Ivan Blackman. Water for this project was transported from nearby on-site spigot using a garden hose to the ChemGrout mixing and pumping unit where potassium permanganate was introduced and mixed and then pumped into each DPT location. The 1.5-inch Geoprobe rods were driven to depth by a track mounted Geoprobe 54LT rig. The specified volume and mass of potassium permanganate are presented in Table 1 and Figure I shows the injection locations. Page I REDOX TECH, LLC "Providing Innovative In Situ Soil and Groundwater Treatment" Injection locations IP-1, 2, 3 and 9 were located inside the building with all other locations were located within an uncovered spaced with the building. IP-9 was moved laterally after it was noted the original location was located over a concrete footer. Table 1. Injection Summary Injection Start InjectionVolume Date Depth (ft) Stop Time Pressure NOTES Point Time (psi) Injected (gal) 11/03/14 IP- 1 22.5 2:25 2:31 25 30 11/03/14 IP- 1 20.5 2:45 2:51 25 30 11/03/14 IP- 1 18.5 2:53 2:59 25 30 +20 gallons of chase water 11/03/14 IP- 2 22.5 3:18 3:22 25 30 11/03/14 IP- 2 20.5 3:24 3:30 25 30 11/03/14 IP- 2 18.5 3:31 3:39 25 30 +20 gallons of chase water 11/04/14 IP- 3 22.5 9:21 9:29 25 30 11/04/14 IP- 3 20.5 9:35 9:41 25 30 11/04/14 IP- 3 18.5 9:48 9:52 25 30 +20 gallons of chase water 11/04/14 IP- 4 22.5 1:18 1:23 25 30 11/04/14 IP- 4 20.5 1:24 1:29 25 30 11/04/14 IP- 4 18.5 1:33 1:40 25 30 +20 gallons of chase water 11/04/14 IP- 5 22.5 1:48 2:53 25 30 11/04/14 IP- 5 20.5 1:56 2:00 25 30 11/04/14 IP- 5 18.5 2:03 2:11 25 30 +20 gallons of chase water 11/04/14 IP- 6 22.5 2:18 2:25 25 - 800 30 rods plugged/rods pulled to next interval 11/04/14 IP- 6 20.5 3:15 3:21 25 30 11/04/14 IP- 6 18.5 3:22 3:29 25 30 +20 gallons of chase water Page 2 REDOX TECH, LLC "Providing Innovative In Situ Soil and Groundwater Treatment" Table 1. Injection Summary Injection Start InjectionVolume Date Depth (ft) Stop Time Pressure NOTES Point Time (Psi) Injected (gal) 11/05/14 IP- 7 22.5 1:55 2:00 25 30 11/05/14 IP- 7 20.5 2:1 2:05 25 30 11/05/14 IP- 7 18.5 2:12 2:25 25 30 +20 gallons of chase water 11/05/14 IP- 8 22.5 9:19 9:24 25 30 11/05/14 IP- 8 20.5 9:25 9:31 25 30 11/05/14 IP- 8 18.5 9:50 10:01 25 30 +20 gallons of chase water 11/05/14 IP- 9 22.5 10:20 10:27 25 30 11/05/14 IP- 9 20.5 10:39 10:46 25 30 11/05/14 IP- 9 18.5 10:58 11:06 25 30 +20 gallons of chase water Total Volume of Solution Injected 810 + 180 gallons of chase water Page 3 REDOX TECH, LLC "Providing Innovative In Situ Soil and Groundwater Treatment" y .• !. .A �c "1 19 ARi 4 NL .,_ NIXON October 3.2014 1:1,128 Outside Budding O (LOms (LO15 0.03 ml TaxParcelPolygons Blue- Band_3 1. ,Tr, 1 .. Red: Band_!! o (Lois (L03 a.0e tm 9.u. Ems, 0401.ae. oora•. -�d E.v.wr U-I?W w Glen-Band —2 .O.ES^lb 09 LGM U904AEAI Ore•W%• g1.A VON SOP l...rK Figure 1. Location Map Page 4 INJECTION EVENT RECORD North Carolina Department of Environment and Natural Resources—Division of Water Resources Permit Number Were any wells abandoned during this injection 1. Permit Information ev t? 6 o ElYes ❑ No Permittee If yes,please provide the following information: Number of Monitoring Wells Facility Name 3� Number of Injection Wells q Facility Address Please include a copy of the GW-30 for each well abandoned. 2. Injection Contractor Information 4. Injectant Information , �acix TLcr-r L� Injection Contractor/Company Name ``S� Injectant Type Street Address 24i v Qi ace �)r Concentration 31.3161 kgL!3 I•. t� 443 kt. City State Zip Code If the injectant is diluted please indicate the source dilution fluid. Area code—Phone number Total Volume Injected 3. Well Information Volume Injected per well o c✓�j Number of wells used for injection 5. Injection History Well names jp—x — / I7_ 9 Injection date(s) Were any new wells installed during this injection Injection number(e.g. 3 of 5) eve [ Yes ❑ No Is this the last injection at this site? ❑ Yes ❑ No G AS c,(� If yes,please provide the following information: Number of Monitoring Wells I DO HEREBY CERTIFY THAT ALL THE INFORMATION ON THIS FORM IS CORRECT TO Number of Injection Wells '� THE BEST OF MY KNOWLEDGE AND THAT THE INJECTION WAS PERFORMED WITHIN THE Type of Well Installed(Check applicable type): STANDARDS LAID OUT IN THE PERMIT. ❑ Bored ❑ Drilled Direct-Push ❑ Hand-Augured ❑ Other(specify) SIGNATURE OF INJECTION CONTRACTOR DATE Please include a copy of the GW-I form for each well installed. PRINT N E OF PERSON PERFORMING THE INJECTION Submit the original of this form to the Division of Water Resources within 30 days of injection. Form UIC-IER Attn:UIC Program, 1636 Mail Service Center,Raleigh,NC 27699-1636,Phone No.919-807-6464 Rev. 8/5/2013 WELL CONSTRUCTION RECORD For Inlernul Use ONLY: This form can be used for single or multiple wells 1.Welt Contractor Information: 7,00uT:ER fiR - U ��41 e�rrt,� TO DESCRIPTION Well Contractor Name ft.4qrt.NC Well Contractor Certification Number IN fti "bit i ' 1 TO DIAMETER THICKNESS I MATERIAL ft. ft. in. Company Name 16�INNEIMUSINOD BIN(M 11 FROM TO DIAMETER THICKNESS MATERIAL 2.Well Construction Permit#: ft. ft. in. List all applicable well permkr(l.e.County,State,Variance,lryectfon,etc.) ft. ft. In. 3.Well Use(check well use): REE. Water Supply Well: FROM TO DIAMETER SLOTSIZE THICKNESS MATERIAL ❑Agricultural ❑Municipal/Public ❑Geothermat(Heating/Cooling Supply) ❑Residential Water Supply(single) R. «• In. ❑Industrial/Commercial ❑Residential Water Supply(shared) 1 .GRQ FROM TO MATERIAL EMPLACEMENT METHOD&AMOUNT ❑Aril ation ft ft. Non-Water Supply Well: ft. ft. ❑Monitoring ❑Recovery Injection Well: ft. ft. ❑Aquifer Recharge QGroundwater Remediation AND GRA%VWME a Vw1wriffiab FROM TO MATERIAL EMPLACEMENT METHOD ❑Aquifer Storage and Recovery []Salinity Barrier «. ft. ❑Aquifer Test ❑Stormwater Drainage ft. «. OExperimental Technology ❑Subsidence Control a 0:"DRILLI1Vl.;1CQCX uitt cfi'?f8dlti 1il Iih et ❑Geothermal(Closed Loop) ❑Tracer FROM TO DESCRIPTION color,hardness,soittrocktype,grain size etc. ❑Geothertml(HeatingtCooling Return) ❑Other(explain under#21 Remarks ft. «• ft. ft. 4.Date Well(s)Completed: f 1, Well 1D# ft. ft. 5a.Well Location: «. «. L Facility/Owner Name 16 , Facility ID#(ifapplicable) «• «• 3o6d Okte-j OY1Mt - t,0,t�f�U;Lte- &/— ft. «. Physical Address,City,and Zip t 1121:�REMARK County Parcel Identification No.(PIN) 5b.Latitude and Longitude in degreeslininutes/seconds or decimal degrees: 22•Certification: (if well field,one[at/long is sufficient) 7 / N W l 1c_ � Signature of Certified Well Contractor Date 6.Is(are)the well(s): ❑Permanent or OTemporary By signing this form,I hereby certtfy that the ovil(s)was(were)constructed in accordance with 15A NCAC 01C.0100 or 13A NCAC 02C.0200 Well Construction Standards and that a 7.Is this a repair to an existing well: ❑Yes or 0No copy of this record has been provided to the well owner. Ifthis B a repair,fill out known well construction Information and explain the nature of the repair under#21 remarks section or on the back ofthis form. 23.Site diagram or additional well details: c� You may use the back of this page to provide additional well site details or well 8.Number of ivells constructed: ! construction details. You may also attach additional pages if necessary. For multiple infection or non-water supply wells ONLY with the same construction,yyou can submit one form. SUBMITTAL INSTUCTIONS f 9.Total well depth below land surface: Z 2 (ft.) 24a. For All Wells: Submit this form within 30 days of completion of well For multiple w llr list all depths ifili ferew(example-3Q200'and 2@1001 construction to the following: 10.Static water level below top of casing: (ft.) Division of Water Resources,Information Processing Unit, lfwater level u above casing,use"+" 1617 Mail Service Center,Raleigh,NC 27699-1617 11.Borehole diameter: f' Z= (in.) 24b.For Injection Wells ONLY: In addition to sending the form to the address in _ 24a above, also subunit a copy of this form within 30 days of completion of well 12.Well construction method: / construction to the following: (i.e.auger,rotary,cable,direct push,etc.) Division of Water Resources,Underground Injection Control Program, FOR WATER SUPPLY WELLS ONLY: 1636 Mail Service Center,Raleigh,NC 27699-1636 13s.Yield(gpm) Method of test 24c.For Water Supply&Injection Wells: Also submit one copy of this form within 30 days of completion of 13b.Disinfection type: Amount: well construction to the county health department of the county where constructed. Form OW-1 North Carolina Department of Environment and Natural Resources-Division of Water Resources Revised August 2013 WELL ABANDONMENT RECORD For Internal Use ONLY: This form can be used for single or multiple wells 1.Well Contractor Information: WELL ABANDONMENT DETAILS 4^-( li.L-A-C-Ae-A-IL A-V-( 7s.Number of wells being abandoned: Well Contractor Name(or well owner personally abandoning well on his/her property) For multiple injection or non-water supply wells ONLY with the same ie 0/7 i Z construction/abandonment,you can submit one form. .� NC Well Contractor Certification Number 7b.Approximate volume of water remaining in well(s): (gal.) e-c-P FOR WATER SUPPLY WELLS ONLY: Company Name 7c.Type of disinfectant used: 2.Well Construction Permit#: List all applicable well permits Q.e.County,State,Variance,b jection,etc.)iil known 7d.Amount of disinfectant used: 3.Well use(check well use): Water Supply Well: 77e.Sealing materials used(check all that apply)- ❑Agricultural ❑Municipal/Public Sd Neat Cement Grout entonite Chips or Pellets ❑Geothennal(Heating/Cooling Supply) ❑Residential Water Supply(single) ❑Sand Cement Grout ❑Dry Clay ❑Industrial/Commercial ❑Residengal Water Supply(shared) ❑Concrete Grout ❑Drill Cuttings ❑Irri ation ❑Specialty Grout ❑Gravel Non-Water Supply Well: ❑ Bentonite Slurry ❑Other(explain under 7g) OMonitoring ❑Recovery Injection Well: � 7L For each material selected above,provide amount of materials used: ❑Aquifer Recharge lJGroundwater Remediation 1�/k de ❑Aquifer Storage and Recovery ❑Salinity Barrier � l ❑Aquifer Test ❑StormwaterDrainage ❑Experimental Technology ❑Subsidence Control 7g,Provide a brief description of the abandonment procedure: ❑Geothermal(Closed Loop) ❑Tracer / w / 6- ❑Geothermal Heatin Coolin Return) ❑Other ex lain under 7 �/ !j] (]� G� Cer�)ol�aC Q �hCL. U�L �Y t 11]ft+q� 4.Date well(s)abandoned: ! zo_.� 5a.Well location: Facility/OwncrName Facility IDA(ifapplicable) 8.Certification Physical Address,City,and Zip Signature of Certified Well Contractor or Well Owner D06 By signing this form, 1 hereby certify that the wells)was(were) abandoned in County Parcel Identification No.(PIN) accordance with 1 SA NCAC 02C.0100 or 2C.0200 Well Construction Standards and that a copy of this record has been provided to the well owner. 5b.Latitude and longitude in degrees/minutes/seconds or decimal degrees: (if well field,one laulong is autliciem) 9.Site diagram or additional well details: You may use the back of this page to provide additional well site details or well N ---- W abandonment details. You may also attach additional pages if necessary. CONSTRUCTION DETAILS OF WELLS)BEING ABANDONED SUBMITTAL INSTRUCTIONS Attach well construction record(s)if available. For multiple injection or non-water supply wells ONLY with the same construction/abandonment,you can submit one form. 10a.For All Wells: Submit this form within 30 days of completion of well 6a.Well ID#: abandonment to the following: Division of Water Resources,Information Processing Unit, )6b.Total well depth: Z . ft 1617 Mail Service Center,Raleigh,NC 27699-1617 ( 10b.For Iniection Wells: In addition to sending the form to the address in 10a above,also submit one copy of this form within 30 days of completion of well 6c.Borehole diameter: (in.) abandonment to the following: 6d,Water level below ground surface: (ft) Division of Water Resources,Underground Injection Control Program, 1636 Mail Service Center,Raleigh,NC 27699-1636 6e.Outer casing length(i[known): —(ft.) 10c.For Water Suonly&Iniection Wells: In addition to sending the form to the address(es) above, also submit one copy of this form within 30 days of completion of well abandonment to the county health department of the county 6f.Inner casing/tubing length(if known): (ft) where abandoned. 6g.Screen length Of known): (ft.) Form GW-30 North Carolina Department of Environment and Natural Resources-Division of Water Resources Revised August 2013 AECOM Environment Appendix D. Groundwater Collection Records 60342855 May 2015 com Well ID, �W_ Low Flow Ground Water Sample Collection Record Client: Smitty's Cleaners DSCA 26-0003 Date: 10/21/2014 Time: Start I'215 am/pm Project No: 60321176.E02 Finish am/pm Site Location: Fayetteville, NC Weather: `s Collector(s): A.C. Whichard 1. WATER LEVEL DATA: (measured from Top of Casing) a.Total Well Length aN.23_ c. Length of Water Column b. Water Table Depth l ff.35 d. Calculated System Volume 3.(a 3` Casing Diameter/Material 2 )R-VC 2. WELL PURGE DATA a. Purge Method: Peristaltic &KBIadder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10% - Specific Conductance ± 10% - ORP ± 10% - pH ± 10% - Dissolved Oxygen ±10% - Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number YSI pro plus 95--�!-t 1 ¢656, Volume Time Purged Temp. pH Spec.Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) ('c) (mS/cm) (mg/L) (mV) (NTU) (ml/min) (feet) .1225 'A__:ZRS.(.956.1S 9(. _ _ .5$ _ -4I. 1 � — 295o 18.gs, 23�6 3 u6,4cl a.24 �2�— /,2x GG.G — 2-00 1 Es.y5 Clear (Iss �t _ .—J��.6� 6.�so IRSFS 1.95 63•a 2as� / fs.y C1taf — (:z40 S ¢5.65 6.2}_ 114 _ 2.2-4 Sg,� _ !2_09S /$._ys _I Clear I�tys —. SG� 6.�6 _ 119 ,�.sG _ 59. 6 , - — �� /tf. y5 _, Cle«.r _,20.6k G.29f _ 12S_ 2.-+6 _ 6 -1.9 — — 2QSq_f GO-chr• :�55 C6 29S,10 4,111 _ 1'Xy__ 2, 85 145,5 — 129696 Clear ,IGG. — 2Qsc25 vS ._I C/Cur d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ ❑ le Not Required Has required turbidity been reached ❑ ❑ WK Have parameters stabilized 4[ r ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Reg. Time 271n10- I V0A Z. H eL -526 1300 2 W rL I H G e— TUc. 12 5 L- I iVON E 16, t s�btbw+� I Al"ofi ,,L N�. Ncn'E 17 Li c f 120 a Comments: Signaturl'-:�� Date 10/21/2014 �0116com WeIIID:MW Low Flow Ground Water Sample Collection Record Client: Smitty's Cleaners DSCA 26-0003 Date: 10/21/2014 Time: Start 0910 am/pm Project No: 60321176.E02 Finish am/pm Site Location: Fayetteville, NC Weather: 'S Collector(s): A.C. Whichard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length 4,5 95 c. Length of Water Column b. Water Table Depth /9,,gro d. Calculated System Volume 4 3 Casing Diameter/Material 1 pre T 2. WELL PURGE DATA a. Purge Method: Peristaltic &KBIadder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10% - Specific Conductance ±10% -ORP ± 10 % - pH ±10% - Dissolved Oxygen ± 10% - Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number y�� F+tgs�,QSs6 Volume Time Purged Temp. pH Spec.Cond. DO ORE Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) (°%) (MS/cm) (mg/L) (mV) (NTU) (mi/min) (feet) 09y5r _ 1.-+5 I.21,2q S.Fs3 13,-I 3.Lf-6 ItS.ti -- 1109f — C_Ie0,r 0952S �..25 .ZI.Fst S.81 1 b{, 3.4g 1 t2.S l — (9so — ,_-leas 0955 Z.1+5 ;Z2.21-1 s.'Ra. 111 3,%l 17-2,4 t095 — I e—le-(xr I"Qf 3. Is .22.4a s.61 1` -4 W,1s 1.201,9 I m�d Cle.oar 140s 3.:? s )2.55 S,lsgS 13I W.t IL as.v - 119SSS — C tto..r 10195 4.2-5 122.89. 5 SS = °ra,/ 9 /2U, a I d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ ❑ 4!r Not Required Has required turbidity been reached ❑ ❑ WK Have parameters stabilized .;K ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Reg. Time mow. VOA 2 H CL fs2(no m W/O 2-SO r^L I H CL TOL )2SmL I A)Wr= Chlor;rle 5 ► #&a AlUA/S 08A�417N 3 Comments: Signature: Date 10/21/2014 e 1WM WellID:rn�'�R Low Flow Ground Water Sample Collection Record Client: Smitty's Cleaners DSCA 26-0003 Date: 10/21/2014 Time: Start 193s am/pm Project No: 60321176.E02 Finish am/pm Site Location: Fayetteville, NC Weather: Collector(s): A.C. Whichard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length 2 ( c. Length of Water Column ?i•Lf b. Water Table Depth d. Calculated System Volume Casing Diameter/Material 2. WELL PURGE DATA a. Purge Method: Peristaltic &KBIadder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10 % - Specific Conductance ± 10% -ORP ± 10% - pH ± 10 % - Dissolved Oxygen ± 10% - Drawdown < 0.3' c. Field Testing Equipment used: Make Model Serial Number YSI pro plus ¢S}t+ 10Z_f6SG Volume Time Purged Temp. PH Spec.Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) (°%) (Inn ICM) (mg/L) (mv) (NTU) (ml/min) (feet) Ip*5 ),ZS �a.c,�gt s.�S 1��-/ _ 5. 59 _1 iSl.� — lCDfd — clee,,r d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ ❑ 1,?f__;/ Not Reciuired Has required turbidity been reached El El `E Have parameters stabilized .W" ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Reg. Time m w-3l_ v'orl, 2 H<<. Comments: Aa�Z G%leti-t Uru 1 d re -c rtirGr akn Signature: Date 10/21/2014 e com Well ID:M. w_S Low Flow Ground Water Sample Collection Record Client: Smitty's Cleaners DSCA 26-0003 Date: 10/21/2014 Time: Start 1100 am/pm Project No: 60321176.E02 Finish am/pm Site Location: Fayetteville, NC Weather: Collector(s): A.C. Whichard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length ,1�V c. Length of Water Column y Qf b. Water Table Depth .Q d. Calculated System Volume . G 3�' Casing Diameter/Material 1""*,pve- 2. WELL PURGE DATA a. Purge Method: Peristaltic ladder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10% - Specific Conductance ± 10% - ORP ± 10% - pH ± 10% - Dissolved Oxygen ± 10% - Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number YSI pro plus fS�-r+ S�ZQ�Str Volume Time Pursed Temp. pH Spec.Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) Vc) (mSfcm) (mg/L) (mV) (NTU) (ml/min) (feet) I110 1.25 _ I2V 91 1-1.9-4 591 4.2-- 21S.) — 109.S C.Ica� 11115 1.*5 _�4.9: .5.01 S.,k 41./A 27-7. 5 — . (565S — C.ltar 1 I LO 2.L5 _� s.22- S.Oq 52 4.06 229.9S 14S o -� -' Cleoir 112.5- 2..;L 5_ ,-Zs.Is S.0 572. 3.9 9 -A C) — l 0 9$ 35Z 3.2 S 25.I(, s���_. 5 a. �.iQS _z 3�,QS - 100 d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ ❑ Not Reauired Has required turbidity been reached ❑ ❑ [ Have parameters stabilized Z ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Reg. Time M w- S VoA Comments: Signature: Date 10/21/2014 =COM WeIIID:rnw,33 Low Flow Ground Water Sample Collection Record Client: Smitty's Cleaners DSCA 26-0003 Date: 10/21/2014 Time: Start //yS am/pm Project No: 60321176.E02 Finish am/pm Site Location: Fayetteville, NC Weather: Sns;de Collector(s): A.C. Whichard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length I c. Length of Water Column b. Water Table Depth 1'+,t?c� d. Calculated System Volume l . Casing Diameter/Material Z 2. WELL PURGE DATA a. Purge Method: Peristaltic ladder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10% - Specific Conductance ± 10% - ORP ±10% - pH ±10 % - Dissolved Oxygen ± 10% - Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number YSI pro plus ►oZe9 S4r Volume Time Purcied Temp. PH Spec.Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) Vc) (ms/e;iil) (mg/L) (mV) (N T U) (ml/min) (feet) 11595 1 AI.93 G.05 1(01 N.9)z 219.9S — (S*s 1$•is Gleo r 1155 I . S 11,59 4.0y_ 10 4,3-4- AID,s — f logs l er. 25 _ C ie•a.r 4,950 014 I(o9S q,JZ;Z Als,q — f fIkZ Ifs. S C.(eo r 119S5 A-5 A1.39 (,.Oy 1 214.y ' � Hags 15s.zs _ Cleaj IZ 4g1 _ _ 12t,35 •�6�/ 159 4, /0 _ 113.g (09f 2S Cfea e- d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ ❑ 4!r Not Required Has required turbidity been reached ❑ ❑ Have parameters stabilized .�K ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Reg. Time MN-3 3 yui4 2 ¢/GL f3Z� 3 /gig` Comments: Signature: Date 10/21/2014 d com Well ID:mw , Low Flow Ground Water Sample Collection Record Client: b SC_A 2 6 -Z0Sd Date: Time: Start 102-10 am/pm Project No: Finish am/pm Site Location: f JI ; I Icy t_ Weather: IJ L'1 Collector(s): A.C. Whichard/ - 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length a�.- c. Length of Water Column 3.3 b. Water Table Depth /6. '/ d. Calculated System Volume 516 Casing Diameter/Material //"R V c= 2. WELL PURGE DATA a. Purge Method: Peristaltic ladder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10% - Specific Conductance ± 10% -ORP ± 10% - pH ± 10% - Dissolved Oxygen ± 10% - Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number YSI pro plus QSyL 2,y6074&- Volume Time Purged Temp. PH Spec.Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) (°c) (ms/cm) (mg/L) (mV) (NTU) (ml/min) (feet) 4 3 t i 2 sus 9f — C I.e o,-r 141y¢S 3 22.Ys 4.2V 2,09 G .2Tr_ S 2.IF — 12¢lQ! � — C (ear /,dyS Z _l22.3S 6.3Sd 210 G .32- /0 5-cz S �22.(.3 S QS3 11gj (o.44 12,L,6__ 29SO z2.49 S03 210 G.G3 I 7_00— 1 d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ El � Not Required Has required turbidity been reached � ❑ ❑ Have parameters stabilized 47� ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Req. Time 'e""-/ BOA' NG $2rogS //�cTS Comments: Date Sig u � r Well ID:TMW- J ecom I Low Flow Ground Water Sample Collection Record Client: Srn;-F1uS OCe►4 2G-OSQ�1j� Date: //-,13 -)if Time: Start /)2S am/pm Project No: r'itS 211 6 Finish am/pm Site Location: Ile kte Weather: C l S Collector(s): A.C. Whichard/T. Adham 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length k 2 c. Length of Water Column b. Water Table Depth d. Calculated System Volume 3,q ` Casing Diameter/Material 2. WELL PURGE DATA a. Purge Method: Peristaltic ladder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ±10% - Specific Conductance ± 10 % -ORP ± 10% - pH ±10% - Dissolved Oxygen ± 10% - Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number YSI pro plus 0YL.2-Y(. (- Volume Time Purged Temp. 2H Spec.Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) (°C) (MS/cm) (mg/L) (MV) (NTU) (ml/min) (feet) 1135 _ 11- 2�5,u G.s� 232.3 t,�s�s 699,2 I — Zftlszs , ifs. srQS --��rpl� 11NQS 3 2�1.2� 6.r:G I922 /•ti2 raf5'S.4 .24150 _.[/ff.fs�d JI`f$ �/ 2RS.29 (e •� 4 �br�/3 /. 3l (o 4,9 Z¢s� --��fr �� _ .Purple �1 s�- s 2�•32 G•�- -��3� /,Z� �.�s.5t _�zQs�s �/fr.Fnes _.�� Pie d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ ❑ 42f Not Required Has required turbidity been reached 4 ❑ ❑ Have parameters stabilized .Z, ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Reg. Time =t r- -t W Ar 2 Hr c VoC- 115 S Comments: Signature: �f - �� Date //J3/Y )/),7Al � com Well ID: Low Flow Ground Water Sample Collection Record Client: Sr,,;}4�5 li�scA 26- Qt� 23 Date: //-/3-/Y Time: Start am/pm Project No: QS 3 2 I I" Finish am/pm Site Location: 'Faun+4 Weather: Collector(s): A.C. W hichard/ 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length /9.ff3 c. Length of Water Column I S63 b. Water Table Depth f�d d. Calculated System Volume 3 L Casing Diameter/Material 2. WELL PURGE DATA a. Purge Method: Peristaltic ladder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10% - Specific Conductance ±10 % -ORP ± 10% - pH ± 10% - Dissolved Oxygen ± 10% - Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number YSI pro plus 96 yL y6 9sA Volume Time Purged Temp. PH Spec.Cond. DO ORP Turbidi Flow Rate Drawdown Color/Odor (24hr) (Liters) (ram) (MS/cm) (mglL) (mV) (NTU) (ml/min) (feet) 795.-,.* 5,59 /S3 N _ /ZSs _ 2 41_ D d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ ❑ i2f Not Required Has required turbidity been reached �K ❑ ❑ Have parameters stabilized .;?'� ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Reg. Time raw -373 VUPr 2_ -NCL o'Uc /Zpis Comments: A- C C4 Signature: Date ElEr fWM Well ID: Trr�w-1 Low Flow Ground Water Sample Collection Record Client: Smittys DSCA 26-0003 Date: 11/21/2014 Time: Start 0$y6-- am/pm Project No: 60321176.E01 Finish am/pm Site Location: Fayetteville, NC Weather: Collector(s): A.C. Whichard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length 2 4 2 c. Length of Water Column S.L// b. Water Table Depth /ff_ ,cd rX d. Calculated System Volume 3.3ly 4- Casing Diameter/Material 2. WELL PURGE DATA a. Purge Method: Peristaltic ladder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10% - Specific Conductance ± 10% - ORP ± 10% - pH ± 10% - Dissolved Oxygen ± 10% - Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number YS I Volume Time Purged Tema. PH Spec.Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) (0c) (mskm) (mg/L) (MV)_ (iv i U) (n l/min) (feet) _ 1603 Z9(0 15.f6l i u✓p/c Z,06 i /5, s/� s l£s,9 �,$1 _2vs'!'l. .�1 6 9G .4f — 2!9(Z _I O(Z p9<s b 1C,5 6,uo ir57 .(Do 6kt,3 _ - g5X _lip. Sao c�s�---Al,-oA-e �53s is It. tz �',$ i /�5/ __• -6�G. 3 - ZSaf�_� /�.s� s P��p,/� d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ El � Not Required Has required turbidity been reached � ❑ ❑ Have parameters stabilized 4;alll ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Reg. Time VOA 2 HCL VOCs F?S Comments: Signature: — �G - - Date 11/21/2014 e�Com WellID:Inw_33 Low Flow Ground Water Sample Collection Record Client: Smittys DSCA 26-0003 Date: 11/21/2014 Time: Start am/pm Project No: 60321176.E01 Finish am/pm Site Location: Fayetteville, NC Weather: Collector(s): A.C. Whichard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length 9, 2s,3 c. Length of Water Column (.3 b. Water Table Depth &.53 d. Calculated System Volume Casing Diameter/Material 2 2. WELL PURGE DATA a. Purge Method: Peristaltic &KBIadder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10% - Specific Conductance ± 10% -ORP ± 10% - pH ± 10% - Dissolved Oxygen ±10% - Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number YSI ��(�IS6GSSKGz Volume Time Purged Temp. pH Spec.Cond. DO ORE Turbidity Flow Rate Drawdown Color/Odor (24nr) (LiWis) (`C) (MS;crir) (mg/L) (mV) (N T U) (mUmin) (Wet) 3.A.3 /�� �1.j3_ -/33. 120X 1 19r� L'/ec. d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑�/ El � Not Required Has required turbidity been reached h ❑ ❑ Have parameters stabilized 4�r ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Req. Time M r.J-32 VOA 2 HCL VOCs 11356 Comments_ - Signature. , Date 11/21/2014 �UcomWell I D:�--- Low Flow Ground Water Sample Collection Record Client: Smittys Cleaners DSCA 26-0003 Date: 11/26/2014 Time: Start ar pm Project No: 60321176 Finish am/pm Site Location: Fayetteville ,NC Weather: Ats"F Collector(s): A.C. Whichard/Bethanay Meier 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length y.2.3 c. Length of Water Column 5.3v 5 b. Water Table Depth d. Calculated System Volume 3 , 32 L Casing Diameter/Material 2 v C- 2. WELL PURGE DATA a. Purge Method: Serperistaltic (ladder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10 % - Specific Conductance ± 10% -ORP ± 10% - pH ± 10% - Dissolved Oxygen ± 10% - Drawdown <Off c. Field Testing Equipment used: Make Model Serial Number YSI pro plus /!j (�6 2s 11 Volume Time Purged Temp. pH Spec.Cond. DO ORE Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters)_. (°C) (mS/cm) (mg/L) (mV) (NTU) (ml/min) (feet) M5 -. 1 Q.3 4.3 I*-01 1 .3 to � IDO (9.2-5 purp/c12•(0 6.-4y 1-43.5 _) .)1-�.=104. �-10, S too _� 1 (.95 _f_pc� ee 0q+5 1 a.VO (0�'5 (-4-(0 3 1.13 10• s ._ — o v _. 19.�0 , p pit 0gsD - - a.S _12• Cl u.4(0 114:';FI I .0 — too 19.00 puepIC 0951 3•D —13 .1 ju.zml 1101 1.0-4 .409.9 — /Do 111r — Lepte d. Acceptance Criteria Pass/Fail Yes No N/ If No or N/A explain here: Has required volume been removed ❑ ❑ Not Required Has required turbidity been reached ❑ ❑ Have parameters stabilized .;'' ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Reg. Time �� w•1 VOA 2 HCL VOCs /S6QS�d Comments: - Signature: Date 11/26/2014 ASCOM I Well I D:mW_33 Low Flow Ground Water Sample Collection Record Client: Smittys Cleaners DSCA 26-0003 Date: 11/26/2014 Time: Start 94,5- am/pm Project No: 60321176 Finish am/pm Site Location: Fayetteville ,NC Weather: c.;,. S Collector(s): A.C. Whichard/Bethanay Meier 1. WATER LEVEL DATA: (measured from Top of Casing) a.Total Well Length lgg3 c. Length of Water Column /, Z3 b. Water Table Depth d. Calculated System Volume .-?S7— Casing Diameter/Material Z eyc 2. WELL PURGE DATA a. Purge Method: Peristaltic ladder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10% - Specific Conductance ± 10% - ORP ± 10% - pH ± 10% - Dissolved Oxygen ±10% - Drawdown <Off c. Field Testing Equipment used: Make Model Serial Number YSI pro plus 13.E (00 1 ts'4- Volume Time Purged Temp. pH Spec.Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) (°C) (MS/CM) (mg/L) (mV) (NTU) (ml/min) _ (feet) of57'd . 5 19.E �,3fA /4�.3 �• q3 12q _ - I QS / 9,03 CMr. d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ ❑ e / Not Required Has required turbidity been reached El ElQ Have parameters stabilized 4;?", ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Req. Time rrr�„� 33 VOA 2 HCL VOCs /0,70 Comments: Signature: Date 11/26/2014 eL=_com I Well ID: m,,,� Low Flow Ground Water Sample Collection Record Client: - =Tf-4, , r,;,N�.lz,,,_ Date: 5 r.) Time: Start -&-) Crrgpm Project No: (,c LW)(,, Finish Oi,;;S am/pm Site Location: �,rr+r, ri oij�� 0.,f-0:; Weather Conds: e fy T Collector(s): 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length c. Length of Water Column I^t.�,I (a-b) Casing Diameter/Material b. Water Table Depth ,�: , , d. Calculated System Volume(see back) y, 7 L, 2. WELL PURGE DATA a. Purge Method: f)ef .. P,(M p b. Acceptance Criteria defined (see workplan) -Temperature 3% -D.O. 10% - pH + 1.0 unit - ORP ± 10mV -Sp. Cond. 3% -Drawdown <Off c. Field Testing Equipment used: Make Model Serial Number � S5(, lily itiv Volume Time Removed Temp. pH Spec'Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) (°%,) (NS/cm) (mg/L) (mV) (NTU) mi%min ee Z 4--9 i,4 7 9,11c .I P11 — n 4* 5•a C^.2 c'c Lam' L -- 24r d. Acceptance criteria pass/fail Yes No N/A (continued on back) Has required volume been removed ❑ [it Has required turbidity been reached ❑ ❑ Have parameters stabilized ❑ ❑ If no or N/A - Explain below. 3. SAMPLE COLLECTION: Method: P' " P��rrP Sample ID Container Type No. of Containers Preservation Analysis Req. Time I >.... CX�yS Comments IN Signature ('nlAd4 Date A_COM Well ID: , Low Flow Ground Water Sample Collection Record Client: Smitty's Cleaners Date: 12/5/2014 Time: Start L71 IT ropm Project No: 60321176 Finish Cnf-t< am/pm Site Location: 3060 Owen Drive,Fayetteville,NC Weather Conds: Overcatts,50's Collector(s): Guy Allard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length 2o,5 c. Length of Water Column 2- H u (a-b) Casing Diameter/Material 01 b. Water Table Depth 16,a2-, d. Calculated System Volume(see back) C) •1U\ 2. WELL PURGE DATA a. Purge Method: Per, p i,,LAp b. Acceptance Criteria defined (see workplan) -Temperature 3% -D.O. 10% - pH + 1.0 unit -ORP ± 10mV - Sp. Cond. 3% -Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number SSG I(X-t Ott ielr tti�w„•y� Kt`l�7c ' stir Volume Time Removed Temp. pH Spec. Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) K) (µslcm) (m l) (mV) (N T U) ml/min ee d. Acceptance criteria pass/fail Yes No N/A (continued on back) Has required volume been removed ❑ ❑ Has required turbidity been reached ❑ ❑ Have parameters stabilized ❑ ❑ If no or N/A- Explain below. (17el loc.) f`eG6lrLW, 3. SAMPLE COLLECTION: Method: Sample ID Container Type No. of Containers Preservation Analysis Req. Time Im l c'- ,(: "ko w L t)It� t. `1 1(( %-_ i l tiff C)14S (MV'-3 Ift 1 t ' rfi— Comments Signature6u—,� Date A_COM Well ID: Low Flow Ground Water Sample Collection Record Client: 6ti=(, C t„ Aw Date: 1� hi-:,:G Time: Start lh;y /pm Project No: Finish Site Location: D,o)tu, Weather Conds: (u\A Collector(s): 1. WATER LEVEL DATA: (measured from Top of Casing) a.Total Well Length ' I c. Length of Water Column (a-b) Casing Diameter/Material b. Water Table Depth 1 -'10 d. Calculated System Volume(see back) 2. WELL PURGE DATA a. Purge Method: b. Acceptance Criteria defined (see workplan) -Temperature 3% -D.O. 10% - pH + 1.0 unit - ORP ± 10mV - Sp. Cond. 3% -Drawdown <Off c. Field Testing Equipment used: Make Model Serial Number Volume - Time Removed Temp. pH Spec. Cond. DO ORP Turbiditv Flow Rate Drawdown Color/Odor 24hr (Liters) (1c) (µs/cm) (m /L.) (mv (NTu) ml/min ee t'7. si 5z 5, 11 10.,t a--.L4 41, { Lltiv - d. Acceptance criteria pass/fail Yes No N/ (continued on back) Has required volume been removed ❑ ❑ Has required turbidity been reached El ❑ Have parameters stabilized ] ❑ ❑ If no or N/A - Explain below. 3. SAMPLE COLLECTION: Method: Qo r Puw� Sample ID Container Type No. of Containers Preservation Analysis Req. Time nAw 4OD Comments vl Signature Date Y) L a=Com Well ID: —G, Low Flow Ground Water Sample Collection Record Client: `�VL� i f4i� Date: � 1)sc- % -'1 Time: Start $17 m Project No: ((-C)=; 7 G. Finish ytic) Cawpm Site Location: Weather Conds: r1 jz h „��J Collector(s): 6 • r441 ,no 1. WATER LEVEL DATA: (measured from Top of Casing) a.Total Well Length q5 c. Length of Water Column 55 (a-b) Casing Diameter/Material b. Water Table Depth 31 •L11 d. Calculated System Volume(see back) 2. WELL PURGE DATA a. Purge Method: yp r0- Vw, V,(3 b. Acceptance Criteria defined (see workplan) -Temperature 3% -D.O. 10% - pH + 1.0 unit -ORP ± 10mV - Sp. Cond. 3% -Drawdown <Off c. Field Testing Equipment used: Make Model Serial Number T 1?5r ESL iu3 .;c ,L 6 c Volume , Time Removed Temp. pH _Spec. Cond. DO ORP Turbiditv Flow Rate Drawdown Color/Odor (24hr) (L#ers) (°C) (µs cm) (mg/L) (mV) (N T u) ml/min ee ,4 r c — ,(a C —ti 41 ;3-zs- C 1 U`v ,`��� 7 L tr 3 #"d. Acceptance criteria pass/fail Yes No N/A (continued on back) Has required volume been removed ❑ [q Has required turbidity been reached ❑ ❑ Have parameters stabilized E ❑ ❑ If no or N/A- Explain below. 3. SAMPLE COLLECTION: Method: Sample ID Container Type No. of Containers Preservation Analysis Req. Time Comments Signature Date �j ��, c 1 A—COM Well Low Flow Ground Water Sample Collection Record Client: Smitty's Cleaners Date: 12/5/2014 Time: Start am/ Project No: 60321176 Finish am/pm Site Location: 3060 Owen Drive,Fayetteville,NC Weather Conds: Overcatts,50's Collector(s): Guy Allard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length c. Length of Water Column 1 1`5 (a-b) Casing Diameter/Material b. Water Table Depth ?,6,'- d. Calculated System Volume(see back) j tA(0 2. WELL PURGE DATA a. Purge Method: eLIAYJi ra eu m f— b. Acceptance Criteria defined (see workplan) -Temperature 3% -D.O. 10% - pH + 1.0 unit - ORP ± 10mV -Sp. Cond. 3% -Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number ,esr SSG, rd 'Li[36 1S£( Volume Time Removed Temp. PH Spec. Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) (=C) (Ps/cm) (m /L) (mV) (NTU) ml/min ee 2047 5. r .24 pc�- apoo, 2mo 71 S" .(a k,CGb �, S` r) 21 1 '7210 Z 22.s2 0 Z b ,? 2o.eq A/ + d. Acceptance criteria pass/fail Yes No N/A (continued on back) Has required volume been removed ❑ ❑ N Has required turbidity been reached ❑ ❑ S] Have parameters stabilized ® ❑ ❑ If no or N/A- Explain below. '• 3. SAMPLE COLLECTION: Method: f'?�Wkp, 9k_jMr Sample ID Container Type No. of Containers Preservation Analysis Req. Time Y;i�• r r L ,, / N( C-- /,., C tit Comments Signature J Date AC0MWell ID: �_ Low Flow Ground Water Sample Collection Record Client: Smitty's Cleaners Date: 12/5/2014 Time: Start I d5 am/cm) Project No: 60321176 Finish t•73U a pm. Site Location: 3060 Owen Drive,Fayetteville,NC Weather Conds: Overcatts,50's Collector(s): Guy Allard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length c. Length of Water Column (a-b) Casing Diameter/Material b. Water Table Depth d. Calculated System Volume(see back) 2. WELL PURGE DATA a. Purge Method: Pee,, PLA±IQ b. Acceptance Criteria defined (see workplan) -Temperature 3% -D.O. 10% - pH + 1.0 unit - ORP ± 10mV - Sp. Cond. 3% -Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number C t clb cif Ha4�JVU� 1`Ir yrY,Y�'� ✓-1 t�i 3�i Volume Time Removed Temp. pH Spec. Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) (1c) (µsicm) (m /L) (mV) NTU ml/min ee &fv"l SI ` Z (so .O pror, ur` 43 1 ,y (V,0--1 b_ 1-7 U t 17�?57 .'15 O Z 4-- d. Acceptance criteria pass/fail Yes No N/A (continued on back) Has required volume been removed ❑ ❑ Has required turbidity been reached ❑ ❑ Have parameters stabilized '� ❑ ❑ If no or N/A- Explain below. 3. SAMPLE COLLECTION: Method: (- Sample ID Container Type No. of Containers Preservation Analysis Req. Time Comments Signature Date 20c 2oiV no PCOMWell ID: hnw.33 Low Flow Ground Water Sample Collection Record Client: Smittys DSCA 26-0003 Date: 12/18/2014 Time: Start 1219am/pm Project No: 60321176.E02 Finish am/pm Site Location: Fayetteville NC Weather: Collector(s): A.C. Whichard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length 4l .$3 c. Length of Water Column b. Water Table Depth 1 g,:7 3 d. Calculated System Volume G'}` Casing Diameter/Material 2p ye 2. WELL PURGE DATA a. Purge Method: Peristaltic &KBIadder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ±10% -Specific Conductance ±10% - ORP ± 10% - pH ± 10% - Dissolved Oxygen ± 10% - Drawdown <Off c. Field Testing Equipment used: Make Model Serial Number YSI pro plus (Z XH 0 96e-/,4f- Volume Time Purged Temp. nHH Spec.Cond. DO ORE Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) (°C) (ms/cm) (mg/L) (MV) (NTU) (ml/min) (feet) /vi.J- 3.01_ - U d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed �❑ ❑ 42!f Not Reauired Has required turbidity been reached A` ❑ Have parameters stabilized q;?" ❑ r 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Reg. Time Mw_.?3 VOA 2 HCL 8260B Comments: k Signature: Date 12/18/2014 MOW Well ID Low Flow Ground Water Sample Collection Record Client: Smittys DSCA 26-0003 Date: 12/18/2014 Time: Start ��rtTam/pm Project No: 60321176.E02 Finish am/pm Site Location: Fayetteville NC Weather: (210, --.2, Collector(s): A.C. Whichard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length Ay,23 c. Length of Water Column b. Water Table Depth 1S. d. Calculated System Volume /,�� Casing Diameter/Material 2. WELL PURGE DATA a. Purge Method: Peristaltic ladder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10% - Specific Conductance ±10% -ORP ± 10% - pH ± 10% - Dissolved Oxygen ± 10% - Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number YSI pro plus 9(2 4407 Oc A f} Volume Time Purged Tema. PH Spec.Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) (°c) (mSlcm) (mg/L) (mV) (NTU) (ml/min) (feet) 12-44(Z t 2 07 G :vQ1 s $ 1 . 6 3 _.z G 3. z 2 Sn 1 q.13 r2Ys 3 �1�-,$ G .y(_ S�S�f 1 , 3si 59.E Zy�gs 14.13 �_elea� IS-- ITS _ Y 1 .9 4.y2 5� �s 1 . �l _,2 5s.2 .__ ep 50 1 CV 13 � C lees r 12 55 _ S ` __ yi _ 54Q� I. 2-4- 25S . 1 ZOO 1 9._f'S C1eAr d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ ❑ Not Required Has required turbidity been reached ❑ Have parameters stabilized ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Reg. Time VOA 2 HCL 8260B j 3QfG1 Comment Signature: Date 12/18/2014 !"=Co I Well ID:,,:��_ 171 Low Flow Ground Water Sample Collection Record Client: smittys flSCA ak_M3 Date: 12/29/2014 Time: Start am/pm Project No: Go S21\ Finish am/pm Site Location.- Weather: ° ( 5 Collector(s): A.C. Whichard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length 23 c. Length of Water Column 6. 2Z b. Water Table Depth 16 / d. Calculated System Volume 3.15Lf Casing Diameter/Material /. sP✓c 2. WELL PURGE DATA a. Purge Method: Peristaltic ladder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10 % - Specific Conductance ± 10 % - ORP ± 10% - pH ± 10% - Dissolved Oxygen ± 10% - Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number YSI pro plus -S S 1p;?S Volume Time Purged Temp. pH Spec.Cond. DO ORE Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) Vc) (MS/CM) (mg/L) (mV) (NTU) (ml/min) (feet) 6. 21 1-/74/ 2,73 2.491 q - 2-0 le, 3 S Clear ///g( oZ l*,9 6.3y 5/5` /.Fsy ACy3.: - 2-(Af6 1A.35 Uecr 1//S 3 g-.fd G.e// SS/ /.G/ ,23G,G/ -' 29591 /,&35 C-Iec�r //;Lo `/ 1�.q G.y(o 5-3-6 1.37 23 2,2 — lop /1ff 3S ea,r zs s I� -4 G,yq 5_S 4 1,35r z 2 Sr,(Z — ZOO i!rd-i 357 C_[ea�— /74 6.50 TVV /•36 2-241 Z.0 /Ar, 55 C;le�c/ i I d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ ❑ 4!r Not Required Has required turbidity been reached RK ❑ ❑ Have parameters stabilized 47' ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Reg. Time f'r 2 He e- yo i s / 12S.n t /1 A)E e-kk ory ! Comments: gTg a ure: e — Date 12/29/2014 �L=Com WeIIID:mW-33 Low Flow Ground Water Sample Collection Record Client: smittys VSCA 26-QlS6Gl3 Date: 12/29/2014 Time: Start am/pm Project No: 6 M3 a i%-4iG.C gl 2_ Finish am/pm Site Location: a t}t ,(It N C Weather: Collector(s): A.C. Whichard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length /9. Ss3 c. Length of Water Column / b. Water Table Depth &09 d. Calculated System Volume .( Casing Diameter/Material 2. WELL PURGE DATA T a. Purge Method: Peristaltic [Bladder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10% - Specific Conductance ± 10% - ORP ± 10% - pH ± 10% - Dissolved Oxygen ± 10% - Drawdown <Off c. Field Testing Equipment used: Make Model Serial Number YSI pro plus I3S 100 t ts� Volume Time Purcied Temp. PH Spec. Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) (°c) (MS/CM) (mg/L) (mV) (NTU) (ml/min) (feet) /034;25 /.0 /*'0_5 6,95( /S3 3. Yq- /61"2- — /S0 cirg Clcwdx ' d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ ❑ 4!r Not Required Has required turbidity been reached 4 ❑ ❑ Have parameters stabilized .[;?"' ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Reg. Time Vaf!- e Uo'� /2�4; Comments: SigngtureL_ ------- Date 12/29/2014 �Com 1WelIID: W- 3 Low Flow Ground Water Sample Collection Record Client: Smittys Cleaners DSCA 26-0003 Date: 1/ /2015 Time: Start 955- am/pm Project No: 60321176.E02 Finish am/pm Site Location: Fayetteville, NC Weather: 1 i�5 i L Collector(s): A.C. W hichard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length (q.$_'S c. Length of Water Column b. Water Table Depth 63 d. Calculated System Volume • p � y (0 0 Casing Diameter/Material 2. WELL PURGE DATA a. Purge Method: RrPeristaltic ladder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ± 10% - Specific Conductance ± 10% - ORP ± 10% - pH ± 10 % - Dissolved Oxygen ± 10% - Drawdown <0.3' c. Field Testing Equipment used: Make Model Serial Number YSI 556 Volume Time Purged PH Spec.Cond. DO ORE Turbidity Flow Rate Drawdown Color/Odor (24hr) (Liters) (°C) (MS/CM) (mg/L) (mV) (NTU) (ml/min) (feet) ►005- _ 1-4.10 115--5-6 l-4 Z.�51 2�4.� IDS I}.9 X _.Clan E� 1960 1 -7,q9 lQ�is 3,_zt S -9A I7V a.-77_ AU.3 Ifs 2-43, 9 - t(opr 1-4.59 d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ ❑ 4!r Not Required Has required turbidity been reached ❑ ElW/ Have parameters stabilized .W ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No. of Containers Preservation Analysis Req. Time VOA 2 HCL VOCs Comments: Signature: Date 1/ '(2015 �Com Well ID:�mW _ I Low Flow Ground Water Sample Collection Record Client: Smittys Cleaners DSCA 26-0003 Date: _U"/2Q4& Time: Start 102,5 am/pm Project No: 60321176.E02 /—/S/S Finish am/pm Site Location: Fayetteville, NC Weather: CI ASS Collector(s): A.C. Whichard 1. WATER LEVEL DATA: (measured from Top of Casing) a. Total Well Length ;ty.�J& c. Length of Water Column .�.� b. Water Table Depth /[S,o o d. Calculated System Volume 3.�'l Casing Diameter/Material 2. WELL PURGE DATA ii�rt� a. Purge Method: Peristaltic ladder ❑ Monsoon b. Acceptance Criteria Defined (see workplan) -Temperature ±10% - Specific Conductance ± 10% - rawdown <OffRP ±10 - pH ±10% - Dissolved Oxygen ± 10% - Dra C. Field Testing Equipment used: Make Model _— Serial Number YSI 556 /aF:- 10:1,101 Volume Time Purged Temp. RH Spec. Cond. DO ORP Turbidity Flow Rate Drawdown Color/Odo r (24hr) (Liters) ("C) (mS/cm) (mg/L) (mV) (NTU) (ml/min) (feet) /S�5 G.2Z_ /� 3S /ls.2 �-lea. / y� 3 )IS. G,26 _M-a-V — /.23 2►9.(� __ = 2A�S?1 —25 `l cj L.33 y,'Z,� /, :t(o :!12,� ,_ 26�5S7J _ Ils.A',�_ Cleo r d. Acceptance Criteria Pass/Fail Yes No N/A If No or N/A explain here: Has required volume been removed ❑ ❑ 4?f Not Required Has required turbidity been reached ❑ ❑ Have parameters stabilized Z ❑ ❑ 3. SAMPLE COLLECTION: Method: Grab Sample ID Container Type No of Containers Preservation Analysis Reg. Time 1mw p VOA 2 HCL VOCs - 54f iments: G Date 1/14/2015 tur - /—/S/.S AECOM Environment Appendix E. Laboratory Analytical Reports 60342855 May 2015 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 l.•A 0 S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 Mr. Matthew Allen AECOM 701 Corporate Center Drive, Suite 475 Raleigh, NC 27607 Report Summary Tuesday November 11, 2014 Report Number: L729209 Samples Received: 10/23/14 Client Project: 60321176.E02 Description: Smitty Cleaners The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Entire Report Reviewed By: Terrie Fudg ESC resentative Laboratory Certification Numbers A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197, FL - E87487, GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016, NC - ENV375/DW21704/BI0041, ND - R-140. NJ - TN002, NJ NELAP - TN002, SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612, MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1, TX - T104704245-11-3, OK - 9915, PA - 68-02979, IA Lab #364, EPA - TNO02 Accreditation is only applicable to the test methods specified on each scope of accreditation held by ESC Lab Sciences. This report may not be reproduced, except in full, without written approval from ESC Lab Sciences. Where applicable, sampling conducted by ESC is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. Page 1 of 13 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 11, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L729209-01 Date Received October 23, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-2 Project # 60321176.E02 Collected By A.C. Whichard Collection Date 10/21/14 10:10 Parameter Result MDL RDL Units Qualifier Method Date Dil. Chloride 6.3 0.052 1.0 mg/l 9056MOD 10/30/14 1 TOC (Total Organic Carbon) 1.3 0.10 1.0 mg/l 9060A 11/10/14 1 Manganese 0.097 0.0012 0.010 mg/1 6010C 10/24/14 1 Potassium 3.2 0.10 1.0 mg/l 6010C 10/24/14 1 Sodium 9.7 0.099 1.0 mg/1 6010C 10/24/14 1 Volatile Organics Acetone U 0.010 0.050 mg/l 8260B 10/26/14 1 Acrolein U 0.0089 0.050 mg/1 8260B 10/26/14 1 Acrylonitrile U 0.0019 0.010 mg/l 8260B 10/26/14 1 Benzene U 0.00033 0.0010 mg/1 8260B 10/26/14 1 Bromobenzene U 0.00035 0.0010 mg/1 8260B 10/26/14 1 Bromodichloromethane U 0.00038 0.0010 mg/l 8260B 10/26/14 1 Bromoform U 0.00047 0.0010 mg/1 8260B 10/26/14 1 Bromomethane U 0.00087 0.0050 mg/1 8260B 10/26/14 1 n-Butylbenzene U 0.00036 0.0010 mg/1 8260B 10/26/14 1 sec-Butylbenzene U 0.00036 0.0010 mg/1 8260B 10/26/14 1 tert-Butylbenzene U 0.00040 0.0010 mg/1 8260B 10/26/14 1 Carbon tetrachloride U 0.00038 0.0010 mg/1 8260B 10/26/14 1 Chlorobenzene U 0.00035 0.0010 mg/1 8260B 10/26/14 1 Chlorodibromomethane U 0.00033 0.0010 mg/l 8260B 10/26/14 1 Chloroethane U 0.00045 0.0050 mg/l 8260B 10/26/14 1 2-Chloroethyl vinyl ether U 0.0030 0.050 mg/1 J6J3 8260B 10/26/14 1 Chloroform 0.00096 0.00032 0.0050 mg/l J 8260B 10/26/14 1 Chloromethane U 0.00028 0.0025 mg/1 8260B 10/26/14 1 2-Chlorotoluene U 0.00038 0.0010 mg/1 8260B 10/26/14 1 4-Chlorotoluene U 0.00035 0.0010 mg/1 8260B 10/26/14 1 1,2-Dibromo-3-Chloropropane U 0.0013 0.0050 mg/1 8260B 10/26/14 1 1,2-Dibromoethane U 0.00038 0.0010 mg/1 8260B 10/26/14 1 Dibromomethane U 0.00035 0.0010 mg/1 8260B 10/26/14 1 1,2-Dichlorobenzene U 0.00035 0.0010 mg/1 8260B 10/26/14 1 1,3-Dichlorobenzene U 0.00022 0.0010 mg/1 8260B 10/26/14 1 1,4-Dichlorobenzene U 0.00027 0.0010 mg/1 8260B 10/26/14 1 Dichlorodifluoromethane U 0.00055 0.0050 mg/1 8260B 10/26/14 1 1,1-Dichloroethane U 0.00026 0.0010 mg/1 8260B 10/26/14 1 1,2-Dichloroethane U 0.00036 0.0010 mg/1 8260B 10/26/14 1 1,1-Dichloroethene U 0.00040 0.0010 mg/l 8260B 10/26/14 1 cis-1,2-Dichloroethene 0.00044 0.00026 0.0010 mg/1 J 8260B 10/26/14 1 trans-1,2-Dichloroethene U 0.00040 0.0010 mg/l 8260B 10/26/14 1 1,2-Dichloropropane U 0.00031 0.0010 mg/1 8260B 10/26/14 1 1,1-Dichloropropene U 0.00035 0.0010 mg/l 8260B 10/26/14 1 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/11/14 14:21 Printed: 11/11/14 14:22 Page 2 of 13 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 11, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L729209-01 Date Received October 23, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-2 Project # 60321176.E02 Collected By A.C. Whichard Collection Date 10/21/14 10:10 Parameter Result MDL RDL Units Qualifier Method Date Dil. 1,3-Dichloropropane U 0.00037 0.0010 mg/l 8260B 10/26/14 1 cis-1,3-Dichloropropene U 0.00042 0.0010 mg/1 8260B 10/26/14 1 trans-1,3-Dichloropropene U 0.00042 0.0010 mg/l 8260B 10/26/14 1 2,2-Dichloropropane U 0.00032 0.0010 mg/l 8260B 10/26/14 1 Di-isopropyl ether U 0.00032 0.0010 mg/1 8260B 10/26/14 1 Ethylbenzene U 0.00038 0.0010 mg/l 8260B 10/26/14 1 Hexachloro-1,3-butadiene U 0.00026 0.0010 mg/1 8260B 10/26/14 1 Isopropylbenzene U 0.00033 0.0010 mg/l 8260B 10/26/14 1 p-Isopropyltoluene U 0.00035 0.0010 mg/1 8260B 10/26/14 1 2-Butanone (MEK) 0.0048 0.0039 0.010 mg/1 J 8260B 10/26/14 1 Methylene Chloride U 0.0010 0.0050 mg/1 8260B 10/26/14 1 4-Methyl-2-pentanone (MIBK) U 0.0021 0.010 mg/1 8260B 10/26/14 1 Methyl tert-butyl ether U 0.00037 0.0010 mg/1 8260B 10/26/14 1 Naphthalene U 0.0010 0.0050 mg/1 8260B 10/26/14 1 n-Propylbenzene U 0.00035 0.0010 mg/l 8260B 10/26/14 1 Styrene U 0.00031 0.0010 mg/1 8260B 10/26/14 1 1,1,1,2-Tetrachloroethane U 0.00038 0.0010 mg/1 8260B 10/26/14 1 1,1,2,2-Tetrachloroethane U 0.00058 0.0010 mg/1 8260B 10/26/14 1 1,1,2-Trichlorotrifluoroethane U 0.00030 0.0010 mg/1 8260B 10/26/14 1 Tetrachloroethene 3.9 0.074 0.20 mg/1 8260B 10/29/14 200 Toluene U 0.00078 0.0050 mg/1 8260B 10/26/14 1 1,2,3-Trichlorobenzene U 0.00023 0.0010 mg/1 8260B 10/26/14 1 1,2,4-Trichlorobenzene U 0.00021 0.0010 mg/l 8260B 10/26/14 1 1,1,1-Trichloroethane U 0.00032 0.0010 mg/l 8260B 10/26/14 1 1,1,2-Trichloroethane U 0.00038 0.0010 mg/1 8260B 10/26/14 1 Trichloroethene 0.0053 0.00040 0.0010 mg/l 8260B 10/26/14 1 Trichlorofluoromethane U 0.0012 0.0050 mg/1 J4 8260B 10/26/14 1 1,2,3-Trichloropropane U 0.00081 0.0025 mg/1 8260B 10/26/14 1 1,2,4-Trimethylbenzene U 0.00037 0.0010 mg/1 8260B 10/26/14 1 1,2,3-Trimethylbenzene U 0.00032 0.0010 mg/1 8260B 10/26/14 1 1,3,5-Trimethylbenzene U 0.00039 0.0010 mg/1 8260B 10/26/14 1 Vinyl chloride U 0.00026 0.0010 mg/1 8260B 10/26/14 1 Xylenes, Total U 0.0011 0.0030 mg/1 8260B 10/26/14 1 Surrogate Recovery Toluene-d8 105. o Rec. 8260B 10/26/14 1 Dibromofluoromethane 116. % Rec. 8260B 10/26/14 1 4-Bromofluorobenzene 95.2 o Rec. 8260B 10/26/14 1 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/11/14 14:21 Printed: 11/11/14 14:22 Page 3 of 13 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 11, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L729209-02 Date Received October 23, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-3R Project # 60321176.E02 Collected By A.C. Whichard Collection Date 10/21/14 13:30 Parameter Result MDL RDL Units Qualifier Method Date Dil. Volatile Organics Acetone U 0.010 0.050 mg/1 8260B 10/26/14 1 Acrolein U 0.0089 0.050 mg/l 8260B 10/26/14 1 Acrylonitrile U 0.0019 0.010 mg/l 8260B 10/26/14 1 Benzene U 0.00033 0.0010 mg/1 8260B 10/26/14 1 Bromobenzene U 0.00035 0.0010 mg/l 8260B 10/26/14 1 Bromodichloromethane U 0.00038 0.0010 mg/1 8260B 10/26/14 1 Bromoform U 0.00047 0.0010 mg/l 8260B 10/26/14 1 Bromomethane U 0.00087 0.0050 mg/1 8260B 10/26/14 1 n-Butylbenzene U 0.00036 0.0010 mg/1 8260B 10/26/14 1 sec-Butylbenzene U 0.00036 0.0010 mg/1 8260B 10/26/14 1 tert-Butylbenzene U 0.00040 0.0010 mg/1 8260B 10/26/14 1 Carbon tetrachloride U 0.00038 0.0010 mg/1 8260B 10/26/14 1 Chlorobenzene U 0.00035 0.0010 mg/1 8260B 10/26/14 1 Chlorodibromomethane U 0.00033 0.0010 mg/l 8260B 10/26/14 1 Chloroethane U 0.00045 0.0050 mg/1 8260B 10/26/14 1 2-Chloroethyl vinyl ether U 0.0030 0.050 mg/1 8260B 10/26/14 1 Chloroform 0.0011 0.00032 0.0050 mg/1 J 8260B 10/26/14 1 Chloromethane U 0.00028 0.0025 mg/1 8260B 10/26/14 1 2-Chlorotoluene U 0.00038 0.0010 mg/1 8260B 10/26/14 1 4-Chlorotoluene U 0.00035 0.0010 mg/1 8260B 10/26/14 1 1,2-Dibromo-3-Chloropropane U 0.0013 0.0050 mg/1 8260B 10/26/14 1 1,2-Dibromoethane U 0.00038 0.0010 mg/l 8260B 10/26/14 1 Dibromomethane U 0.00035 0.0010 mg/l 8260B 10/26/14 1 1,2-Dichlorobenzene U 0.00035 0.0010 mg/1 8260B 10/26/14 1 1,3-Dichlorobenzene U 0.00022 0.0010 mg/l 8260B 10/26/14 1 1,4-Dichlorobenzene U 0.00027 0.0010 mg/1 8260B 10/26/14 1 Dichlorodifluoromethane U 0.00055 0.0050 mg/1 8260B 10/26/14 1 1,1-Dichloroethane U 0.00026 0.0010 mg/1 8260B 10/26/14 1 1,2-Dichloroethane U 0.00036 0.0010 mg/1 8260B 10/26/14 1 1,1-Dichloroethene U 0.00040 0.0010 mg/1 8260B 10/26/14 1 cis-1,2-Dichloroethene U 0.00026 0.0010 mg/1 8260B 10/26/14 1 trans-1,2-Dichloroethene U 0.00040 0.0010 mg/1 8260B 10/26/14 1 1,2-Dichloropropane U 0.00031 0.0010 mg/1 8260B 10/26/14 1 1,1-Dichloropropene U 0.00035 0.0010 mg/1 8260B 10/26/14 1 1,3-Dichloropropane U 0.00037 0.0010 mg/1 8260B 10/26/14 1 cis-1,3-Dichloropropene U 0.00042 0.0010 mg/1 8260B 10/26/14 1 trans-1,3-Dichloropropene U 0.00042 0.0010 mg/1 8260B 10/26/14 1 2,2-Dichloropropane U 0.00032 0.0010 mg/l 8260B 10/26/14 1 Di-isopropyl ether U 0.00032 0.0010 mg/1 8260B 10/26/14 1 Ethylbenzene U 0.00038 0.0010 mg/l 8260B 10/26/14 1 Hexachloro-1,3-butadiene U 0.00026 0.0010 mg/1 8260B 10/26/14 1 Isopropylbenzene U 0.00033 0.0010 mg/l 8260B 10/26/14 1 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/11/14 14:21 Printed: 11/11/14 14:22 Page 4 of 13 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 11, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L729209-02 Date Received October 23, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-3R Project # 60321176.E02 Collected By A.C. Whichard Collection Date 10/21/14 13:30 Parameter Result MDL RDL Units Qualifier Method Date Dil. p-Isopropyltoluene U 0.00035 0.0010 mg/l 8260B 10/26/14 1 2-Butanone (MEK) 0.0068 0.0039 0.010 mg/1 J 8260B 10/26/14 1 Methylene Chloride U 0.0010 0.0050 mg/l 8260B 10/26/14 1 4-Methyl-2-pentanone (MIBK) U 0.0021 0.010 mg/l 8260B 10/26/14 1 Methyl tert-butyl ether U 0.00037 0.0010 mg/1 8260B 10/26/14 1 Naphthalene U 0.0010 0.0050 mg/l 8260B 10/26/14 1 n-Propylbenzene U 0.00035 0.0010 mg/1 8260B 10/26/14 1 Styrene U 0.00031 0.0010 mg/l 8260B 10/26/14 1 1,1,1,2-Tetrachloroethane U 0.00038 0.0010 mg/1 8260B 10/26/14 1 1,1,2,2-Tetrachloroethane U 0.00058 0.0010 mg/1 8260B 10/26/14 1 1,1,2-Trichlorotrifluoroethane U 0.00030 0.0010 mg/1 8260B 10/26/14 1 Tetrachloroethene 0.55 0.0074 0.020 mg/1 8260B 10/29/14 20 Toluene U 0.00078 0.0050 mg/1 8260B 10/26/14 1 1,2,3-Trichlorobenzene U 0.00023 0.0010 mg/1 8260B 10/26/14 1 1,2,4-Trichlorobenzene U 0.00021 0.0010 mg/l 8260B 10/26/14 1 1,1,1-Trichloroethane U 0.00032 0.0010 mg/1 8260B 10/26/14 1 1,1,2-Trichloroethane U 0.00038 0.0010 mg/1 8260B 10/26/14 1 Trichloroethene 0.0017 0.00040 0.0010 mg/1 8260B 10/26/14 1 Trichlorofluoromethane U 0.0012 0.0050 mg/1 J4 8260B 10/26/14 1 1,2,3-Trichloropropane U 0.00081 0.0025 mg/1 8260B 10/26/14 1 1,2,4-Trimethylbenzene U 0.00037 0.0010 mg/1 8260B 10/26/14 1 1,2,3-Trimethylbenzene U 0.00032 0.0010 mg/1 8260B 10/26/14 1 1,3,5-Trimethylbenzene U 0.00039 0.0010 mg/l 8260B 10/26/14 1 Vinyl chloride U 0.00026 0.0010 mg/l 8260B 10/26/14 1 Xylenes, Total U 0.0011 0.0030 mg/1 8260B 10/26/14 1 Surrogate Recovery Toluene-d8 103. % Rec. 8260B 10/26/14 1 Dibromofluoromethane ill. % Rec. 8260B 10/26/14 1 4-Bromofluorobenzene 98.9 % Rec. 8260B 10/26/14 1 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/11/14 14:21 Printed: 11/11/14 14:22 Page 5 of 13 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 11, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L729209-03 Date Received October 23, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-5 Project # 60321176.E02 Collected By A.C. Whichard Collection Date 10/21/14 11:30 Parameter Result MDL RDL Units Qualifier Method Date Dil. Volatile Organics Acetone U 0.10 0.50 mg/1 8260B 10/26/14 10 Acrolein U 0.089 0.50 mg/l 8260B 10/26/14 10 Acrylonitrile U 0.019 0.10 mg/l 8260B 10/26/14 10 Benzene U 0.0033 0.010 mg/1 8260B 10/26/14 10 Bromobenzene U 0.0035 0.010 mg/l 8260B 10/26/14 10 Bromodichloromethane U 0.0038 0.010 mg/1 8260B 10/26/14 10 Bromoform U 0.0047 0.010 mg/l 8260B 10/26/14 10 Bromomethane U 0.0087 0.050 mg/1 8260B 10/26/14 10 n-Butylbenzene U 0.0036 0.010 mg/1 8260B 10/26/14 10 sec-Butylbenzene U 0.0036 0.010 mg/1 8260B 10/26/14 10 tert-Butylbenzene U 0.0040 0.010 mg/1 8260B 10/26/14 10 Carbon tetrachloride U 0.0038 0.010 mg/1 8260B 10/26/14 10 Chlorobenzene U 0.0035 0.010 mg/1 8260B 10/26/14 10 Chlorodibromomethane U 0.0033 0.010 mg/l 8260B 10/26/14 10 Chloroethane U 0.0045 0.050 mg/1 8260B 10/26/14 10 2-Chloroethyl vinyl ether U 0.030 0.50 mg/1 8260B 10/26/14 10 Chloroform U 0.0032 0.050 mg/1 8260B 10/26/14 10 Chloromethane U 0.0028 0.025 mg/1 8260B 10/26/14 10 2-Chlorotoluene U 0.0038 0.010 mg/1 8260B 10/26/14 10 4-Chlorotoluene U 0.0035 0.010 mg/1 8260B 10/26/14 10 1,2-Dibromo-3-Chloropropane U 0.013 0.050 mg/1 8260B 10/26/14 10 1,2-Dibromoethane U 0.0038 0.010 mg/l 8260B 10/26/14 10 Dibromomethane U 0.0035 0.010 mg/l 8260B 10/26/14 10 1,2-Dichlorobenzene U 0.0035 0.010 mg/1 8260B 10/26/14 10 1,3-Dichlorobenzene U 0.0022 0.010 mg/l 8260B 10/26/14 10 1,4-Dichlorobenzene U 0.0027 0.010 mg/1 8260B 10/26/14 10 Dichlorodifluoromethane U 0.0055 0.050 mg/1 8260B 10/26/14 10 1,1-Dichloroethane U 0.0026 0.010 mg/1 8260B 10/26/14 10 1,2-Dichloroethane U 0.0036 0.010 mg/1 8260B 10/26/14 10 1,1-Dichloroethene U 0.0040 0.010 mg/1 8260B 10/26/14 10 cis-1,2-Dichloroethene 0.19 0.0026 0.010 mg/1 8260B 10/26/14 10 trans-1,2-Dichloroethene U 0.0040 0.010 mg/1 8260B 10/26/14 10 1,2-Dichloropropane U 0.0031 0.010 mg/1 8260B 10/26/14 10 1,1-Dichloropropene U 0.0035 0.010 mg/1 8260B 10/26/14 10 1,3-Dichloropropane U 0.0037 0.010 mg/1 8260B 10/26/14 10 cis-1,3-Dichloropropene U 0.0042 0.010 mg/1 8260B 10/26/14 10 trans-1,3-Dichloropropene U 0.0042 0.010 mg/1 8260B 10/26/14 10 2,2-Dichloropropane U 0.0032 0.010 mg/l 8260B 10/26/14 10 Di-isopropyl ether U 0.0032 0.010 mg/1 8260B 10/26/14 10 Ethylbenzene U 0.0038 0.010 mg/l 8260B 10/26/14 10 Hexachloro-1,3-butadiene U 0.0026 0.010 mg/1 8260B 10/26/14 10 Isopropylbenzene U 0.0033 0.010 mg/l 8260B 10/26/14 10 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/11/14 14:21 Printed: 11/11/14 14:22 Page 6 of 13 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 11, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L729209-03 Date Received October 23, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-5 Project # 60321176.E02 Collected By A.C. Whichard Collection Date 10/21/14 11:30 Parameter Result MDL RDL Units Qualifier Method Date Dil. p-Isopropyltoluene U 0.0035 0.010 mg/l 8260B 10/26/14 10 2-Butanone (MEK) 0.097 0.039 0.10 mg/1 J 8260B 10/26/14 10 Methylene Chloride U 0.010 0.050 mg/l 8260B 10/26/14 10 4-Methyl-2-pentanone (MIBK) U 0.021 0.10 mg/l 8260B 10/26/14 10 Methyl tert-butyl ether U 0.0037 0.010 mg/1 8260B 10/26/14 10 Naphthalene U 0.010 0.050 mg/l 8260B 10/26/14 10 n-Propylbenzene U 0.0035 0.010 mg/1 8260B 10/26/14 10 Styrene U 0.0031 0.010 mg/l 8260B 10/26/14 10 1,1,1,2-Tetrachloroethane U 0.0038 0.010 mg/1 8260B 10/26/14 10 1,1,2,2-Tetrachloroethane U 0.0058 0.010 mg/1 8260B 10/26/14 10 1,1,2-Trichlorotrifluoroethane U 0.0030 0.010 mg/1 8260B 10/26/14 10 Tetrachloroethene 14. 0.37 1.0 mg/1 8260B 10/29/14 1000 Toluene U 0.0078 0.050 mg/1 8260B 10/26/14 10 1,2,3-Trichlorobenzene U 0.0023 0.010 mg/1 8260B 10/26/14 10 1,2,4-Trichlorobenzene U 0.0021 0.010 mg/l 8260B 10/26/14 10 1,1,1-Trichloroethane U 0.0032 0.010 mg/1 8260B 10/26/14 10 1,1,2-Trichloroethane U 0.0038 0.010 mg/1 8260B 10/26/14 10 Trichloroethene 0.24 0.0040 0.010 mg/1 8260B 10/26/14 10 Trichlorofluoromethane U 0.012 0.050 mg/1 J4 8260B 10/26/14 10 1,2,3-Trichloropropane U 0.0081 0.025 mg/1 8260B 10/26/14 10 1,2,4-Trimethylbenzene U 0.0037 0.010 mg/1 8260B 10/26/14 10 1,2,3-Trimethylbenzene U 0.0032 0.010 mg/1 8260B 10/26/14 10 1,3,5-Trimethylbenzene U 0.0039 0.010 mg/l 8260B 10/26/14 10 Vinyl chloride U 0.0026 0.010 mg/l 8260B 10/26/14 10 Xylenes, Total 0.017 0.011 0.030 mg/1 J 8260B 10/26/14 10 Surrogate Recovery Toluene-d8 106. % Rec. 8260B 10/26/14 10 Dibromofluoromethane 108. % Rec. 8260B 10/26/14 10 4-Bromofluorobenzene 97.8 % Rec. 8260B 10/26/14 10 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/11/14 14:21 Printed: 11/11/14 14:22 Page 7 of 13 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 11, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L729209-04 Date Received October 23, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-33 Project # 60321176.E02 Collected By A.C. Whichard Collection Date 10/21/14 12:10 Parameter Result MDL RDL Units Qualifier Method Date Dil. Volatile Organics Acetone U 0.50 2.5 mg/1 8260B 10/26/14 50 Acrolein U 0.44 2.5 mg/l 8260B 10/26/14 50 Acrylonitrile U 0.094 0.50 mg/l 8260B 10/26/14 50 Benzene U 0.016 0.050 mg/1 8260B 10/26/14 50 Bromobenzene U 0.018 0.050 mg/l 8260B 10/26/14 50 Bromodichloromethane U 0.019 0.050 mg/1 8260B 10/26/14 50 Bromoform U 0.023 0.050 mg/l 8260B 10/26/14 50 Bromomethane U 0.043 0.25 mg/1 8260B 10/26/14 50 n-Butylbenzene U 0.018 0.050 mg/1 8260B 10/26/14 50 sec-Butylbenzene U 0.018 0.050 mg/1 8260B 10/26/14 50 tert-Butylbenzene U 0.020 0.050 mg/1 8260B 10/26/14 50 Carbon tetrachloride U 0.019 0.050 mg/1 8260B 10/26/14 50 Chlorobenzene U 0.017 0.050 mg/1 8260B 10/26/14 50 Chlorodibromomethane U 0.016 0.050 mg/l 8260B 10/26/14 50 Chloroethane U 0.023 0.25 mg/1 8260B 10/26/14 50 2-Chloroethyl vinyl ether U 0.15 2.5 mg/1 8260B 10/26/14 50 Chloroform U 0.016 0.25 mg/1 8260B 10/26/14 50 Chloromethane U 0.014 0.13 mg/1 8260B 10/26/14 50 2-Chlorotoluene U 0.019 0.050 mg/1 8260B 10/26/14 50 4-Chlorotoluene U 0.018 0.050 mg/1 8260B 10/26/14 50 1,2-Dibromo-3-Chloropropane U 0.066 0.25 mg/1 8260B 10/26/14 50 1,2-Dibromoethane U 0.019 0.050 mg/l 8260B 10/26/14 50 Dibromomethane U 0.017 0.050 mg/l 8260B 10/26/14 50 1,2-Dichlorobenzene U 0.017 0.050 mg/1 8260B 10/26/14 50 1,3-Dichlorobenzene U 0.011 0.050 mg/l 8260B 10/26/14 50 1,4-Dichlorobenzene U 0.014 0.050 mg/1 8260B 10/26/14 50 Dichlorodifluoromethane U 0.028 0.25 mg/1 8260B 10/26/14 50 1,1-Dichloroethane U 0.013 0.050 mg/1 8260B 10/26/14 50 1,2-Dichloroethane U 0.018 0.050 mg/1 8260B 10/26/14 50 1,1-Dichloroethene U 0.020 0.050 mg/1 8260B 10/26/14 50 cis-1,2-Dichloroethene U 0.013 0.050 mg/1 8260B 10/26/14 50 trans-1,2-Dichloroethene U 0.020 0.050 mg/1 8260B 10/26/14 50 1,2-Dichloropropane U 0.015 0.050 mg/1 8260B 10/26/14 50 1,1-Dichloropropene U 0.018 0.050 mg/1 8260B 10/26/14 50 1,3-Dichloropropane U 0.018 0.050 mg/1 8260B 10/26/14 50 cis-1,3-Dichloropropene U 0.021 0.050 mg/1 8260B 10/26/14 50 trans-1,3-Dichloropropene U 0.021 0.050 mg/1 8260B 10/26/14 50 2,2-Dichloropropane U 0.016 0.050 mg/l 8260B 10/26/14 50 Di-isopropyl ether U 0.016 0.050 mg/1 8260B 10/26/14 50 Ethylbenzene U 0.019 0.050 mg/l 8260B 10/26/14 50 Hexachloro-1,3-butadiene U 0.013 0.050 mg/1 8260B 10/26/14 50 Isopropylbenzene U 0.016 0.050 mg/l 8260B 10/26/14 50 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/11/14 14:21 Printed: 11/11/14 14:22 Page 8 of 13 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 11, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L729209-04 Date Received October 23, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-33 Project # 60321176.E02 Collected By A.C. Whichard Collection Date 10/21/14 12:10 Parameter Result MDL RDL Units Qualifier Method Date Dil. p-Isopropyltoluene U 0.018 0.050 mg/l 8260B 10/26/14 50 2-Butanone (MEK) 0.55 0.20 0.50 mg/1 8260B 10/26/14 50 Methylene Chloride U 0.050 0.25 mg/l 8260B 10/26/14 50 4-Methyl-2-pentanone (MIBK) U 0.11 0.50 mg/l 8260B 10/26/14 50 Methyl tert-butyl ether U 0.018 0.050 mg/1 8260B 10/26/14 50 Naphthalene U 0.050 0.25 mg/l 8260B 10/26/14 50 n-Propylbenzene U 0.017 0.050 mg/1 8260B 10/26/14 50 Styrene U 0.015 0.050 mg/l 8260B 10/26/14 50 1,1,1,2-Tetrachloroethane U 0.019 0.050 mg/1 8260B 10/26/14 50 1,1,2,2-Tetrachloroethane U 0.029 0.050 mg/1 8260B 10/26/14 50 1,1,2-Trichlorotrifluoroethane U 0.015 0.050 mg/1 8260B 10/26/14 50 Tetrachloroethene 48. 1.9 5.0 mg/1 8260B 10/29/14 5000 Toluene U 0.039 0.25 mg/1 8260B 10/26/14 50 1,2,3-Trichlorobenzene U 0.012 0.050 mg/1 8260B 10/26/14 50 1,2,4-Trichlorobenzene U 0.011 0.050 mg/l 8260B 10/26/14 50 1,1,1-Trichloroethane U 0.016 0.050 mg/1 8260B 10/26/14 50 1,1,2-Trichloroethane U 0.019 0.050 mg/1 8260B 10/26/14 50 Trichloroethene 0.046 0.020 0.050 mg/1 J 8260B 10/26/14 50 Trichlorofluoromethane U 0.060 0.25 mg/1 J4 8260B 10/26/14 50 1,2,3-Trichloropropane U 0.040 0.13 mg/1 8260B 10/26/14 50 1,2,4-Trimethylbenzene U 0.019 0.050 mg/1 8260B 10/26/14 50 1,2,3-Trimethylbenzene U 0.016 0.050 mg/1 8260B 10/26/14 50 1,3,5-Trimethylbenzene U 0.019 0.050 mg/l 8260B 10/26/14 50 Vinyl chloride U 0.013 0.050 mg/l 8260B 10/26/14 50 Xylenes, Total 0.086 0.053 0.15 mg/1 J 8260B 10/26/14 50 Surrogate Recovery Toluene-d8 106. % Rec. 8260B 10/26/14 50 Dibromofluoromethane 112. % Rec. 8260B 10/26/14 50 4-Bromofluorobenzene 96.3 % Rec. 8260B 10/26/14 50 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/11/14 14:21 Printed: 11/11/14 14:22 Page 9 of 13 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 11, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L729209-05 Date Received October 23, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID IMW-1 Project # 60321176.E02 Collected By A.C. Whichard Collection Date 10/21/14 13:00 Parameter Result MDL RDL Units Qualifier Method Date Dil. Chloride 4.8 0.052 1.0 mg/l 9056MOD 10/30/14 1 TOC (Total Organic Carbon) 2.8 0.10 1.0 mg/l 9060A 11/10/14 1 Manganese 0.039 0.0012 0.010 mg/1 6010C 10/24/14 1 Potassium 2.4 0.10 1.0 mg/l 6010C 10/24/14 1 Sodium 7.6 0.099 1.0 mg/1 6010C 10/24/14 1 Volatile Organics Acetone U 0.25 1.3 mg/l 8260B 10/26/14 25 Acrolein U 0.22 1.3 mg/1 8260B 10/26/14 25 Acrylonitrile U 0.047 0.25 mg/l 8260B 10/26/14 25 Benzene U 0.0083 0.025 mg/1 8260B 10/26/14 25 Bromobenzene U 0.0088 0.025 mg/1 8260B 10/26/14 25 Bromodichloromethane U 0.0095 0.025 mg/l 8260B 10/26/14 25 Bromoform U 0.012 0.025 mg/1 8260B 10/26/14 25 Bromomethane U 0.022 0.13 mg/1 8260B 10/26/14 25 n-Butylbenzene U 0.0090 0.025 mg/1 8260B 10/26/14 25 sec-Butylbenzene U 0.0091 0.025 mg/1 8260B 10/26/14 25 tert-Butylbenzene U 0.010 0.025 mg/1 8260B 10/26/14 25 Carbon tetrachloride U 0.0095 0.025 mg/1 8260B 10/26/14 25 Chlorobenzene U 0.0087 0.025 mg/1 8260B 10/26/14 25 Chlorodibromomethane U 0.0082 0.025 mg/l 8260B 10/26/14 25 Chloroethane U 0.011 0.13 mg/l 8260B 10/26/14 25 2-Chloroethyl vinyl ether U 0.075 1.3 mg/1 8260B 10/26/14 25 Chloroform U 0.0081 0.13 mg/l 8260B 10/26/14 25 Chloromethane U 0.0069 0.063 mg/1 8260B 10/26/14 25 2-Chlorotoluene U 0.0094 0.025 mg/1 8260B 10/26/14 25 4-Chlorotoluene U 0.0088 0.025 mg/1 8260B 10/26/14 25 1,2-Dibromo-3-Chloropropane U 0.033 0.13 mg/1 8260B 10/26/14 25 1,2-Dibromoethane U 0.0095 0.025 mg/1 8260B 10/26/14 25 Dibromomethane U 0.0086 0.025 mg/1 8260B 10/26/14 25 1,2-Dichlorobenzene U 0.0087 0.025 mg/1 8260B 10/26/14 25 1,3-Dichlorobenzene U 0.0055 0.025 mg/1 8260B 10/26/14 25 1,4-Dichlorobenzene U 0.0068 0.025 mg/1 8260B 10/26/14 25 Dichlorodifluoromethane U 0.014 0.13 mg/1 8260B 10/26/14 25 1,1-Dichloroethane U 0.0065 0.025 mg/1 8260B 10/26/14 25 1,2-Dichloroethane U 0.0090 0.025 mg/1 8260B 10/26/14 25 1,1-Dichloroethene U 0.010 0.025 mg/l 8260B 10/26/14 25 cis-1,2-Dichloroethene U 0.0065 0.025 mg/1 8260B 10/26/14 25 trans-1,2-Dichloroethene U 0.0099 0.025 mg/l 8260B 10/26/14 25 1,2-Dichloropropane U 0.0076 0.025 mg/1 8260B 10/26/14 25 1,1-Dichloropropene U 0.0088 0.025 mg/l 8260B 10/26/14 25 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/11/14 14:21 Printed: 11/11/14 14:22 Page 10 of 13 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 11, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L729209-05 Date Received October 23, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID IMW-1 Project # 60321176.E02 Collected By A.C. Whichard Collection Date 10/21/14 13:00 Parameter Result MDL RDL Units Qualifier Method Date Dil. 1,3-Dichloropropane U 0.0092 0.025 mg/l 8260B 10/26/14 25 cis-1,3-Dichloropropene U 0.010 0.025 mg/1 8260B 10/26/14 25 trans-1,3-Dichloropropene U 0.010 0.025 mg/l 8260B 10/26/14 25 2,2-Dichloropropane U 0.0080 0.025 mg/l 8260B 10/26/14 25 Di-isopropyl ether U 0.0080 0.025 mg/1 8260B 10/26/14 25 Ethylbenzene U 0.0096 0.025 mg/l 8260B 10/26/14 25 Hexachloro-1,3-butadiene U 0.0064 0.025 mg/1 8260B 10/26/14 25 Isopropylbenzene U 0.0082 0.025 mg/l 8260B 10/26/14 25 p-Isopropyltoluene U 0.0088 0.025 mg/1 8260B 10/26/14 25 2-Butanone (MEK) 0.37 0.098 0.25 mg/1 8260B 10/26/14 25 Methylene Chloride U 0.025 0.13 mg/1 8260B 10/26/14 25 4-Methyl-2-pentanone (MIBK) U 0.054 0.25 mg/1 8260B 10/26/14 25 Methyl tert-butyl ether U 0.0092 0.025 mg/1 8260B 10/26/14 25 Naphthalene U 0.025 0.13 mg/1 8260B 10/26/14 25 n-Propylbenzene U 0.0087 0.025 mg/l 8260B 10/26/14 25 Styrene U 0.0077 0.025 mg/1 8260B 10/26/14 25 1,1,1,2-Tetrachloroethane U 0.0096 0.025 mg/1 8260B 10/26/14 25 1,1,2,2-Tetrachloroethane U 0.015 0.025 mg/1 8260B 10/26/14 25 1,1,2-Trichlorotrifluoroethane U 0.0076 0.025 mg/1 8260B 10/26/14 25 Tetrachloroethene 18. 0.37 1.0 mg/1 8260B 10/29/14 1000 Toluene U 0.020 0.13 mg/1 8260B 10/26/14 25 1,2,3-Trichlorobenzene U 0.0058 0.025 mg/1 8260B 10/26/14 25 1,2,4-Trichlorobenzene U 0.0054 0.025 mg/l 8260B 10/26/14 25 1,1,1-Trichloroethane U 0.0080 0.025 mg/l 8260B 10/26/14 25 1,1,2-Trichloroethane U 0.0096 0.025 mg/1 8260B 10/26/14 25 Trichloroethene 0.028 0.010 0.025 mg/l 8260B 10/26/14 25 Trichlorofluoromethane U 0.030 0.13 mg/1 J4 8260B 10/26/14 25 1,2,3-Trichloropropane U 0.020 0.063 mg/1 8260B 10/26/14 25 1,2,4-Trimethylbenzene U 0.0093 0.025 mg/1 8260B 10/26/14 25 1,2,3-Trimethylbenzene U 0.0080 0.025 mg/1 8260B 10/26/14 25 1,3,5-Trimethylbenzene U 0.0097 0.025 mg/1 8260B 10/26/14 25 Vinyl chloride U 0.0065 0.025 mg/1 8260B 10/26/14 25 Xylenes, Total 0.044 0.026 0.075 mg/1 J 8260B 10/26/14 25 Surrogate Recovery Toluene-d8 105. o Rec. 8260B 10/26/14 25 Dibromofluoromethane 110. % Rec. 8260B 10/26/14 25 4-Bromofluorobenzene 101. o Rec. 8260B 10/26/14 25 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/11/14 14:21 Printed: 11/11/14 14:22 Page 11 of 13 Attachment A List of Analytes with QC Qualifiers Sample Work Sample Run Number Group Type Analyte ID Qualifier L729209-01 WG750459 SAMP 2-Chloroethyl vinyl ether R3000479 J6J3 WG750459 SAMP Chloroform R3000479 J WG750459 SAMP cis-1,2-Dichloroethene R3000479 J WG750459 SAMP 2-Butanone (MEK) R3000479 J WG750459 SAMP Trichlorofluoromethane R3000479 J4 L729209-02 WG750459 SAMP Chloroform R3000479 J WG750459 SAMP 2-Butanone (MEK) R3000479 J WG750459 SAMP Trichlorofluoromethane R3000479 J4 L729209-03 WG750459 SAMP 2-Butanone (MEK) R3000479 J WG750459 SAMP Trichlorofluoromethane R3000479 J4 WG750459 SAMP Xylenes, Total R3000479 J L729209-04 WG750459 SAMP Trichloroethene R3000479 J WG750459 SAMP Trichlorofluoromethane R3000479 J4 WG750459 SAMP Xylenes, Total R3000479 J L729209-05 WG750459 SAMP Trichlorofluoromethane R3000479 J4 WG750459 SAMP Xylenes, Total R3000479 J Page 12 of 13 Attachment B Explanation of QC Qualifier Codes Qualifier Meaning J (EPA) - Estimated value below the lowest calibration point. Confidence correlates with concentration. J3 The associated batch QC was outside the established quality control range for precision. J4 The associated batch QC was outside the established quality control range for accuracy. J6 The sample matrix interfered with the ability to make any accurate determination; spike value is low Qualifier Report Information ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical results. Each qualifier is designated in the qualifier explanation as either EPA or ESC. Data qualifiers are intended to provide the ESC client with more detailed information concerning the potential bias of reported data. Because of the wide range of constituents and variety of matrices incorporated by most EPA methods,it is common for some compounds to fall outside of established ranges. These exceptions are evaluated and all reported data is valid and useable "unless qualified as 'R' (Rejected) ." Definitions Accuracy - The relationship of the observed value of a known sample to the true value of a known sample. Represented by percent recovery and relevant to samples such as: control samples, matrix spike recoveries, surrogate recoveries, etc. Precision - The agreement between a set of samples or between duplicate samples. Relates to how close together the results are and is represented by Relative Percent Differrence. Surrogate - Organic compounds that are similar in chemical composition, extraction, and chromotography to analytes of interest. The surrogates are used to determine the probable response of the group of analytes that are chem- ically related to the surrogate compound. Surrogates are added to the sample and carried through all stages of preparation and analyses. TIC - Tentatively Identified Compound: Compounds detected in samples that are not target compounds, internal standards, system monitoring compounds, or surrogates. Page 13 of 13 Summary of Remarks For Samples Printed 11/11/14 at 14:22:27 TSR Signing Reports: 064 R5 - Desired TAT this account is for only dry-cleaning sites in NC. . .EDD is required on all projects. EDD is required for this client. . .report in mg/l only Sample: L729209-01 Account: ENSRDSCA Received: 10/23/14 09:00 Due Date: 10/31/14 00:00 RPT Date: 11/11/14 14:21 Sample: L729209-02 Account: ENSRDSCA Received: 10/23/14 09:00 Due Date: 10/31/14 00:00 RPT Date: 11/11/14 14:21 Sample: L729209-03 Account: ENSRDSCA Received: 10/23/14 09:00 Due Date: 10/31/14 00:00 RPT Date: 11/11/14 14:21 Sample: L729209-04 Account: ENSRDSCA Received: 10/23/14 09:00 Due Date: 10/31/14 00:00 RPT Date: 11/11/14 14:21 Sample: L729209-05 Account: ENSRDSCA Received: 10/23/14 09:00 Due Date: 10/31/14 00:00 RPT Date: 11/11/14 14:21 l Cowpa-,y Name/Address Billing Information- Analysis/Container/Preservative C7vin of Custody Page_of AECOM quote tt: ENSRNC102913S 701 Corporate Center Drive *ESC Suite 475 U L•A•8 to c E s Raleigh , NC 27607 = 3 tmss Lb.—Ad 0 Qi Report tc, Email To: yt Mn•.nt a,rc TN 37121 1tn l�aeCOm.Com 0 V Phowfils-7sh-sass 0. a 1 Phone 000-767-sas9 >. Project City/State r,.67s-7sasas3 0_ Smltty's Cleaners Collected: = v Description; v � Q Phone: 919-872-6600 Client Project so Lab Project a E w = L S 1 '- r0 aar z H249 Fax: (,a��7.1 }�•ERS'11- O ?AIn z Lli d T _ Collected by(print): Site/facility ID a P.O.9x M UJ 0 Accinum.ENSRDSCA Template: Collected by(signs ure) Date Results Needed to _ to !lush? (lab MUST Be Notified) j O u7 Prelogin; Same Day _.- ...200% _. r141 H7 Next Day ............._.... �..100% od TSR: Email?_No ZVfes j X n0 � � Immediate _Two Day ....................... ..SO% No. ic - 0001lr: Packed on ice N_ y _Three Dar _..._....25X FAX? V40 _Yes of A 04 — Y O U O Shipped Via: Sample ID Comp/Grab Matrix• Depth Date Time kntrs( Q L U aem 7Cal,mmsnt y,mple tl hah o ryll�J-7- Ca W 1 -21-1 157 x )C X X c. L4) .S &rctb rnw- 33 rA G w J -LI-►y X "� Tvnw- 1 �rW I -2i-r /3 _ S X X X I •Matrix- SS-Soil GW Groundwater WW-WasteWater OW-Drinking Water OT-Other pH Temp Remarks: Flow _ Other Hold 0 Relinquish Date Time Receiv (Stgna ure) Samples returned via: ❑UPS Condition: (lab use o ,-�p ❑FedEx ❑Courier Relinquished by (Signature) Date: Time: Received by:ISigna;ure) Temp: •C Bottles Received: yr L4 GV COC Seal Intact: _Y _N _NA Relinquished by (Signature) Date: Time: Re wed f ab b, (Signature) Oate: Time: pH Checked: NCF: 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 l.•A 0 S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 Mr. Matthew Allen AECOM 701 Corporate Center Drive, Suite 475 Raleigh, NC 27607 Report Summary Monday November 24, 2014 Report Number: L733918 Samples Received: 11/15/14 Client Project: 60321176 Description: Smitty Cleaners The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Entire Report Reviewed By: Terrie Fudg ESC resentative Laboratory Certification Numbers A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197, FL - E87487, GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016, NC - ENV375/DW21704/BI0041, ND - R-140. NJ - TN002, NJ NELAP - TN002, SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612, MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1, TX - T104704245-11-3, OK - 9915, PA - 68-02979, IA Lab #364, EPA - TNO02 Accreditation is only applicable to the test methods specified on each scope of accreditation held by ESC Lab Sciences. This report may not be reproduced, except in full, without written approval from ESC Lab Sciences. Where applicable, sampling conducted by ESC is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. Page 1 of 9 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 24, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L733918-01 Date Received November 15, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID IMW-1 Project # 60321176 Collected By A.C. Whichard Collection Date 11/13/14 11:55 Parameter Result MDL RDL Units Qualifier Method Date Dil. Chloride 54. 0.052 1.0 mg/l 9056MOD 11/24/14 1 TOC (Total Organic Carbon) 41. 2.0 20. mg/l 9060A 11/22/14 20 Manganese 75. 0.060 0.50 mg/1 6010C 11/24/14 50 Potassium 610 1.0 10. mg/l 6010C 11/20/14 10 Sodium 11. 0.099 1.0 mg/1 6010C 11/20/14 1 Volatile Organics Acetone 1.5 0.10 0.50 mg/l 8260B 11/23/14 10 Acrolein U 0.0089 0.050 mg/1 8260B 11/22/14 1 Acrylonitrile U 0.0019 0.010 mg/l 8260B 11/22/14 1 Benzene U 0.00033 0.0010 mg/1 8260B 11/22/14 1 Bromobenzene U 0.00035 0.0010 mg/1 8260B 11/22/14 1 Bromodichloromethane 0.00078 0.00038 0.0010 mg/l J 8260B 11/22/14 1 Bromoform 0.018 0.00047 0.0010 mg/1 8260B 11/22/14 1 Bromomethane U 0.00087 0.0050 mg/1 8260B 11/22/14 1 n-Butylbenzene U 0.00036 0.0010 mg/1 8260B 11/22/14 1 sec-Butylbenzene U 0.00036 0.0010 mg/1 8260B 11/22/14 1 tert-Butylbenzene U 0.00040 0.0010 mg/1 8260B 11/22/14 1 Carbon tetrachloride U 0.00038 0.0010 mg/1 8260B 11/22/14 1 Chlorobenzene U 0.00035 0.0010 mg/1 8260B 11/22/14 1 Chlorodibromomethane 0.00090 0.00033 0.0010 mg/l J 8260B 11/22/14 1 Chloroethane U 0.00045 0.0050 mg/l 8260B 11/22/14 1 2-Chloroethyl vinyl ether U 0.0030 0.050 mg/1 8260B 11/22/14 1 Chloroform 0.0016 0.00032 0.0050 mg/l J 8260B 11/22/14 1 Chloromethane U 0.00028 0.0025 mg/1 8260B 11/22/14 1 2-Chlorotoluene U 0.00038 0.0010 mg/1 8260B 11/22/14 1 4-Chlorotoluene U 0.00035 0.0010 mg/1 8260B 11/22/14 1 1,2-Dibromo-3-Chloropropane U 0.0013 0.0050 mg/1 8260B 11/22/14 1 1,2-Dibromoethane U 0.00038 0.0010 mg/1 8260B 11/22/14 1 Dibromomethane U 0.00035 0.0010 mg/1 8260B 11/22/14 1 1,2-Dichlorobenzene U 0.00035 0.0010 mg/1 8260B 11/22/14 1 1,3-Dichlorobenzene U 0.00022 0.0010 mg/1 8260B 11/22/14 1 1,4-Dichlorobenzene U 0.00027 0.0010 mg/1 8260B 11/22/14 1 Dichlorodifluoromethane U 0.00055 0.0050 mg/1 8260B 11/22/14 1 1,1-Dichloroethane U 0.00026 0.0010 mg/1 8260B 11/22/14 1 1,2-Dichloroethane U 0.00036 0.0010 mg/1 8260B 11/22/14 1 1,1-Dichloroethene U 0.00040 0.0010 mg/l 8260B 11/22/14 1 cis-1,2-Dichloroethene U 0.00026 0.0010 mg/1 8260B 11/22/14 1 trans-1,2-Dichloroethene U 0.00040 0.0010 mg/l 8260B 11/22/14 1 1,2-Dichloropropane U 0.00031 0.0010 mg/1 8260B 11/22/14 1 1,1-Dichloropropene U 0.00035 0.0010 mg/l 8260B 11/22/14 1 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/24/14 15:43 Printed: 11/24/14 15:44 Page 2 of 9 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 24, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L733918-01 Date Received November 15, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID IMW-1 Project # 60321176 Collected By A.C. Whichard Collection Date 11/13/14 11:55 Parameter Result MDL RDL Units Qualifier Method Date Dil. 1,3-Dichloropropane U 0.00037 0.0010 mg/l 8260B 11/22/14 1 cis-1,3-Dichloropropene U 0.00042 0.0010 mg/1 8260B 11/22/14 1 trans-1,3-Dichloropropene U 0.00042 0.0010 mg/l 8260B 11/22/14 1 2,2-Dichloropropane U 0.00032 0.0010 mg/l 8260B 11/22/14 1 Di-isopropyl ether U 0.00032 0.0010 mg/1 8260B 11/22/14 1 Ethylbenzene U 0.00038 0.0010 mg/l 8260B 11/22/14 1 Hexachloro-1,3-butadiene U 0.00026 0.0010 mg/1 8260B 11/22/14 1 Isopropylbenzene U 0.00033 0.0010 mg/l 8260B 11/22/14 1 p-Isopropyltoluene U 0.00035 0.0010 mg/1 8260B 11/22/14 1 2-Butanone (MEK) 0.038 0.0039 0.010 mg/1 8260B 11/22/14 1 Methylene Chloride U 0.0010 0.0050 mg/1 8260B 11/22/14 1 4-Methyl-2-pentanone (MIBK) U 0.0021 0.010 mg/1 8260B 11/22/14 1 Methyl tert-butyl ether U 0.00037 0.0010 mg/1 8260B 11/22/14 1 Naphthalene U 0.0010 0.0050 mg/1 8260B 11/22/14 1 n-Propylbenzene U 0.00035 0.0010 mg/l 8260B 11/22/14 1 Styrene U 0.00031 0.0010 mg/1 8260B 11/22/14 1 1,1,1,2-Tetrachloroethane U 0.00038 0.0010 mg/1 8260B 11/22/14 1 1,1,2,2-Tetrachloroethane U 0.00058 0.0010 mg/1 8260B 11/22/14 1 1,1,2-Trichlorotrifluoroethane U 0.00030 0.0010 mg/1 8260B 11/22/14 1 Tetrachloroethene 0.0018 0.00037 0.0010 mg/1 8260B 11/22/14 1 Toluene U 0.00078 0.0050 mg/1 8260B 11/22/14 1 1,2,3-Trichlorobenzene U 0.00023 0.0010 mg/1 8260B 11/22/14 1 1,2,4-Trichlorobenzene U 0.00021 0.0010 mg/l 8260B 11/22/14 1 1,1,1-Trichloroethane U 0.00032 0.0010 mg/l 8260B 11/22/14 1 1,1,2-Trichloroethane 0.00047 0.00038 0.0010 mg/1 J 8260B 11/22/14 1 Trichloroethene U 0.00040 0.0010 mg/l 8260B 11/22/14 1 Trichlorofluoromethane U 0.0012 0.0050 mg/1 8260B 11/22/14 1 1,2,3-Trichloropropane U 0.00081 0.0025 mg/1 8260B 11/22/14 1 1,2,4-Trimethylbenzene U 0.00037 0.0010 mg/1 8260B 11/22/14 1 1,2,3-Trimethylbenzene U 0.00032 0.0010 mg/1 8260B 11/22/14 1 1,3,5-Trimethylbenzene U 0.00039 0.0010 mg/1 8260B 11/22/14 1 Vinyl chloride U 0.00026 0.0010 mg/1 8260B 11/22/14 1 Xylenes, Total U 0.0011 0.0030 mg/1 8260B 11/22/14 1 Surrogate Recovery Toluene-d8 102. o Rec. 8260B 11/22/14 1 Dibromofluoromethane 104. % Rec. 8260B 11/22/14 1 4-Bromofluorobenzene 97.1 o Rec. 8260B 11/22/14 1 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/24/14 15:43 Printed: 11/24/14 15:44 Page 3 of 9 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 24, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L733918-02 Date Received November 15, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-33 Project # 60321176 Collected By A.C. Whichard Collection Date 11/13/14 12:45 Parameter Result MDL RDL Units Qualifier Method Date Dil. Volatile Organics Acetone 0.11 0.10 0.50 mg/1 J 8260B 11/22/14 10 Acrolein U 0.089 0.50 mg/l 8260B 11/22/14 10 Acrylonitrile U 0.019 0.10 mg/l 8260B 11/22/14 10 Benzene U 0.0033 0.010 mg/1 8260B 11/22/14 10 Bromobenzene U 0.0035 0.010 mg/l 8260B 11/22/14 10 Bromodichloromethane U 0.0038 0.010 mg/1 8260B 11/22/14 10 Bromoform U 0.0047 0.010 mg/l 8260B 11/22/14 10 Bromomethane U 0.0087 0.050 mg/1 8260B 11/22/14 10 n-Butylbenzene U 0.0036 0.010 mg/1 8260B 11/22/14 10 sec-Butylbenzene U 0.0036 0.010 mg/1 8260B 11/22/14 10 tert-Butylbenzene U 0.0040 0.010 mg/1 8260B 11/22/14 10 Carbon tetrachloride U 0.0038 0.010 mg/1 8260B 11/22/14 10 Chlorobenzene U 0.0035 0.010 mg/1 8260B 11/22/14 10 Chlorodibromomethane U 0.0033 0.010 mg/l 8260B 11/22/14 10 Chloroethane U 0.0045 0.050 mg/1 8260B 11/22/14 10 2-Chloroethyl vinyl ether U 0.030 0.50 mg/1 8260B 11/22/14 10 Chloroform U 0.0032 0.050 mg/1 8260B 11/22/14 10 Chloromethane U 0.0028 0.025 mg/1 8260B 11/22/14 10 2-Chlorotoluene U 0.0038 0.010 mg/1 8260B 11/22/14 10 4-Chlorotoluene U 0.0035 0.010 mg/1 8260B 11/22/14 10 1,2-Dibromo-3-Chloropropane U 0.013 0.050 mg/1 8260B 11/22/14 10 1,2-Dibromoethane U 0.0038 0.010 mg/l 8260B 11/22/14 10 Dibromomethane U 0.0035 0.010 mg/l 8260B 11/22/14 10 1,2-Dichlorobenzene U 0.0035 0.010 mg/1 8260B 11/22/14 10 1,3-Dichlorobenzene U 0.0022 0.010 mg/l 8260B 11/22/14 10 1,4-Dichlorobenzene U 0.0027 0.010 mg/1 8260B 11/22/14 10 Dichlorodifluoromethane U 0.0055 0.050 mg/1 8260B 11/22/14 10 1,1-Dichloroethane 0.0047 0.0026 0.010 mg/1 J 8260B 11/22/14 10 1,2-Dichloroethane U 0.0036 0.010 mg/1 8260B 11/22/14 10 1,1-Dichloroethene U 0.0040 0.010 mg/1 8260B 11/22/14 10 cis-1,2-Dichloroethene 0.0051 0.0026 0.010 mg/1 J 8260B 11/22/14 10 trans-1,2-Dichloroethene U 0.0040 0.010 mg/1 8260B 11/22/14 10 1,2-Dichloropropane U 0.0031 0.010 mg/1 8260B 11/22/14 10 1,1-Dichloropropene U 0.0035 0.010 mg/1 8260B 11/22/14 10 1,3-Dichloropropane U 0.0037 0.010 mg/1 8260B 11/22/14 10 cis-1,3-Dichloropropene U 0.0042 0.010 mg/1 8260B 11/22/14 10 trans-1,3-Dichloropropene U 0.0042 0.010 mg/1 8260B 11/22/14 10 2,2-Dichloropropane U 0.0032 0.010 mg/l 8260B 11/22/14 10 Di-isopropyl ether U 0.0032 0.010 mg/1 8260B 11/22/14 10 Ethylbenzene U 0.0038 0.010 mg/l 8260B 11/22/14 10 Hexachloro-1,3-butadiene U 0.0026 0.010 mg/1 8260B 11/22/14 10 Isopropylbenzene U 0.0033 0.010 mg/l 8260B 11/22/14 10 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/24/14 15:43 Printed: 11/24/14 15:44 Page 4 of 9 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 24, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L733918-02 Date Received November 15, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-33 Project # 60321176 Collected By A.C. Whichard Collection Date 11/13/14 12:45 Parameter Result MDL RDL Units Qualifier Method Date Dil. p-Isopropyltoluene U 0.0035 0.010 mg/l 8260B 11/22/14 10 2-Butanone (MEK) U 0.039 0.10 mg/1 8260B 11/22/14 10 Methylene Chloride U 0.010 0.050 mg/l 8260B 11/22/14 10 4-Methyl-2-pentanone (MIBK) U 0.021 0.10 mg/l 8260B 11/22/14 10 Methyl tert-butyl ether U 0.0037 0.010 mg/1 8260B 11/22/14 10 Naphthalene U 0.010 0.050 mg/l 8260B 11/22/14 10 n-Propylbenzene U 0.0035 0.010 mg/1 8260B 11/22/14 10 Styrene U 0.0031 0.010 mg/l 8260B 11/22/14 10 1,1,1,2-Tetrachloroethane U 0.0038 0.010 mg/1 8260B 11/22/14 10 1,1,2,2-Tetrachloroethane U 0.0058 0.010 mg/1 8260B 11/22/14 10 1,1,2-Trichlorotrifluoroethane U 0.0030 0.010 mg/1 8260B 11/22/14 10 Tetrachloroethene 16. 0.37 1.0 mg/1 8260B 11/23/14 1000 Toluene U 0.0078 0.050 mg/1 8260B 11/22/14 10 1,2,3-Trichlorobenzene U 0.0023 0.010 mg/1 8260B 11/22/14 10 1,2,4-Trichlorobenzene U 0.0021 0.010 mg/l 8260B 11/22/14 10 1,1,1-Trichloroethane 0.031 0.0032 0.010 mg/1 8260B 11/22/14 10 1,1,2-Trichloroethane U 0.0038 0.010 mg/1 8260B 11/22/14 10 Trichloroethene 0.021 0.0040 0.010 mg/1 8260B 11/22/14 10 Trichlorofluoromethane U 0.012 0.050 mg/1 8260B 11/22/14 10 1,2,3-Trichloropropane U 0.0081 0.025 mg/1 8260B 11/22/14 10 1,2,4-Trimethylbenzene U 0.0037 0.010 mg/1 8260B 11/22/14 10 1,2,3-Trimethylbenzene U 0.0032 0.010 mg/1 8260B 11/22/14 10 1,3,5-Trimethylbenzene U 0.0039 0.010 mg/l 8260B 11/22/14 10 Vinyl chloride U 0.0026 0.010 mg/l 8260B 11/22/14 10 Xylenes, Total U 0.011 0.030 mg/1 8260B 11/22/14 10 Surrogate Recovery Toluene-d8 104. % Rec. 8260B 11/22/14 10 Dibromofluoromethane 102. % Rec. 8260B 11/22/14 10 4-Bromofluorobenzene 103. % Rec. 8260B 11/22/14 10 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/24/14 15:43 Printed: 11/24/14 15:44 Page 5 of 9 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 24, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L733918-03 Date Received November 15, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-1 Project # 60321176 Collected By A.C. Whichard Collection Date 11/13/14 11:00 Parameter Result MDL RDL Units Qualifier Method Date Dil. Volatile Organics Acetone U 0.010 0.050 mg/1 8260B 11/22/14 1 Acrolein U 0.0089 0.050 mg/l 8260B 11/22/14 1 Acrylonitrile U 0.0019 0.010 mg/l 8260B 11/22/14 1 Benzene U 0.00033 0.0010 mg/1 8260B 11/22/14 1 Bromobenzene U 0.00035 0.0010 mg/l 8260B 11/22/14 1 Bromodichloromethane U 0.00038 0.0010 mg/1 8260B 11/22/14 1 Bromoform U 0.00047 0.0010 mg/l 8260B 11/22/14 1 Bromomethane U 0.00087 0.0050 mg/1 8260B 11/22/14 1 n-Butylbenzene U 0.00036 0.0010 mg/1 8260B 11/22/14 1 sec-Butylbenzene U 0.00036 0.0010 mg/1 8260B 11/22/14 1 tert-Butylbenzene U 0.00040 0.0010 mg/1 8260B 11/22/14 1 Carbon tetrachloride U 0.00038 0.0010 mg/1 8260B 11/22/14 1 Chlorobenzene U 0.00035 0.0010 mg/1 8260B 11/22/14 1 Chlorodibromomethane U 0.00033 0.0010 mg/l 8260B 11/22/14 1 Chloroethane U 0.00045 0.0050 mg/1 8260B 11/22/14 1 2-Chloroethyl vinyl ether U 0.0030 0.050 mg/1 8260B 11/22/14 1 Chloroform U 0.00032 0.0050 mg/1 8260B 11/22/14 1 Chloromethane U 0.00028 0.0025 mg/1 8260B 11/22/14 1 2-Chlorotoluene U 0.00038 0.0010 mg/1 8260B 11/22/14 1 4-Chlorotoluene U 0.00035 0.0010 mg/1 8260B 11/22/14 1 1,2-Dibromo-3-Chloropropane U 0.0013 0.0050 mg/1 8260B 11/22/14 1 1,2-Dibromoethane U 0.00038 0.0010 mg/l 8260B 11/22/14 1 Dibromomethane U 0.00035 0.0010 mg/l 8260B 11/22/14 1 1,2-Dichlorobenzene U 0.00035 0.0010 mg/1 8260B 11/22/14 1 1,3-Dichlorobenzene U 0.00022 0.0010 mg/l 8260B 11/22/14 1 1,4-Dichlorobenzene U 0.00027 0.0010 mg/1 8260B 11/22/14 1 Dichlorodifluoromethane U 0.00055 0.0050 mg/1 8260B 11/22/14 1 1,1-Dichloroethane U 0.00026 0.0010 mg/1 8260B 11/22/14 1 1,2-Dichloroethane U 0.00036 0.0010 mg/1 8260B 11/22/14 1 1,1-Dichloroethene U 0.00040 0.0010 mg/1 8260B 11/22/14 1 cis-1,2-Dichloroethene U 0.00026 0.0010 mg/1 8260B 11/22/14 1 trans-1,2-Dichloroethene U 0.00040 0.0010 mg/1 8260B 11/22/14 1 1,2-Dichloropropane U 0.00031 0.0010 mg/1 8260B 11/22/14 1 1,1-Dichloropropene U 0.00035 0.0010 mg/1 8260B 11/22/14 1 1,3-Dichloropropane U 0.00037 0.0010 mg/1 8260B 11/22/14 1 cis-1,3-Dichloropropene U 0.00042 0.0010 mg/1 8260B 11/22/14 1 trans-1,3-Dichloropropene U 0.00042 0.0010 mg/1 8260B 11/22/14 1 2,2-Dichloropropane U 0.00032 0.0010 mg/l 8260B 11/22/14 1 Di-isopropyl ether U 0.00032 0.0010 mg/1 8260B 11/22/14 1 Ethylbenzene U 0.00038 0.0010 mg/l 8260B 11/22/14 1 Hexachloro-1,3-butadiene U 0.00026 0.0010 mg/1 8260B 11/22/14 1 Isopropylbenzene U 0.00033 0.0010 mg/l 8260B 11/22/14 1 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/24/14 15:43 Printed: 11/24/14 15:44 Page 6 of 9 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen November 24, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L733918-03 Date Received November 15, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-1 Project # 60321176 Collected By A.C. Whichard Collection Date 11/13/14 11:00 Parameter Result MDL RDL Units Qualifier Method Date Dil. p-Isopropyltoluene U 0.00035 0.0010 mg/l 8260B 11/22/14 1 2-Butanone (MEK) U 0.0039 0.010 mg/1 8260B 11/22/14 1 Methylene Chloride U 0.0010 0.0050 mg/l 8260B 11/22/14 1 4-Methyl-2-pentanone (MIBK) U 0.0021 0.010 mg/l 8260B 11/22/14 1 Methyl tert-butyl ether U 0.00037 0.0010 mg/1 8260B 11/22/14 1 Naphthalene U 0.0010 0.0050 mg/l 8260B 11/22/14 1 n-Propylbenzene U 0.00035 0.0010 mg/1 8260B 11/22/14 1 Styrene U 0.00031 0.0010 mg/l 8260B 11/22/14 1 1,1,1,2-Tetrachloroethane U 0.00038 0.0010 mg/1 8260B 11/22/14 1 1,1,2,2-Tetrachloroethane U 0.00058 0.0010 mg/1 8260B 11/22/14 1 1,1,2-Trichlorotrifluoroethane U 0.00030 0.0010 mg/1 8260B 11/22/14 1 Tetrachloroethene 0.0014 0.00037 0.0010 mg/1 8260B 11/23/14 1 Toluene U 0.00078 0.0050 mg/1 8260B 11/22/14 1 1,2,3-Trichlorobenzene U 0.00023 0.0010 mg/1 8260B 11/22/14 1 1,2,4-Trichlorobenzene U 0.00021 0.0010 mg/l 8260B 11/22/14 1 1,1,1-Trichloroethane U 0.00032 0.0010 mg/1 8260B 11/22/14 1 1,1,2-Trichloroethane U 0.00038 0.0010 mg/1 8260B 11/22/14 1 Trichloroethene U 0.00040 0.0010 mg/1 8260B 11/22/14 1 Trichlorofluoromethane U 0.0012 0.0050 mg/1 8260B 11/22/14 1 1,2,3-Trichloropropane U 0.00081 0.0025 mg/1 8260B 11/22/14 1 1,2,4-Trimethylbenzene U 0.00037 0.0010 mg/1 8260B 11/22/14 1 1,2,3-Trimethylbenzene U 0.00032 0.0010 mg/1 8260B 11/22/14 1 1,3,5-Trimethylbenzene U 0.00039 0.0010 mg/l 8260B 11/22/14 1 Vinyl chloride U 0.00026 0.0010 mg/l 8260B 11/22/14 1 Xylenes, Total U 0.0011 0.0030 mg/1 8260B 11/22/14 1 Surrogate Recovery Toluene-d8 103. % Rec. 8260B 11/22/14 1 Dibromofluoromethane 106. % Rec. 8260B 11/22/14 1 4-Bromofluorobenzene 91.5 % Rec. 8260B 11/22/14 1 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 11/24/14 15:43 Printed: 11/24/14 15:44 Page 7 of 9 Attachment A List of Analytes with QC Qualifiers Sample Work Sample Run Number Group Type Analyte ID Qualifier L733918-01 WG755388 SAMP Bromodichloromethane R3006036 J WG755388 SAMP Chlorodibromomethane R3006036 J WG755388 SAMP Chloroform R3006036 J WG755388 SAMP 1,1,2-Trichloroethane R3006036 J L733918-02 WG755388 SAMP Acetone R3006036 J WG755388 SAMP 1,1-Dichloroethane R3006036 J WG755388 SAMP cis-1,2-Dichloroethene R3006036 J Page 8 of 9 Attachment B Explanation of QC Qualifier Codes Qualifier Meaning J (EPA) - Estimated value below the lowest calibration point. Confidence correlates with concentration. Qualifier Report Information ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical results. Each qualifier is designated in the qualifier explanation as either EPA or ESC. Data qualifiers are intended to provide the ESC client with more detailed information concerning the potential bias of reported data. Because of the wide range of constituents and variety of matrices incorporated by most EPA methods,it is common for some compounds to fall outside of established ranges. These exceptions are evaluated and all reported data is valid and useable "unless qualified as 'R' (Rejected) ." Definitions Accuracy - The relationship of the observed value of a known sample to the true value of a known sample. Represented by percent recovery and relevant to samples such as: control samples, matrix spike recoveries, surrogate recoveries, etc. Precision - The agreement between a set of samples or between duplicate samples. Relates to how close together the results are and is represented by Relative Percent Differrence. Surrogate - Organic compounds that are similar in chemical composition, extraction, and chromotography to analytes of interest. The surrogates are used to determine the probable response of the group of analytes that are chem- ically related to the surrogate compound. Surrogates are added to the sample and carried through all stages of preparation and analyses. TIC - Tentatively Identified Compound: Compounds detected in samples that are not target compounds, internal standards, system monitoring compounds, or surrogates. Page 9 of 9 Summary of Remarks For Samples Printed 11/24/14 at 15:44:09 TSR Signing Reports: 064 R5 - Desired TAT this account is for only dry-cleaning sites in NC. . .EDD is required on all projects. EDD is required for this client. . .report in mg/l only Sample: L733918-01 Account: ENSRDSCA Received: 11/15/14 07:00 Due Date: 11/24/14 00:00 RPT Date: 11/24/14 15:43 Sample: L733918-02 Account: ENSRDSCA Received: 11/15/14 07:00 Due Date: 11/24/14 00:00 RPT Date: 11/24/14 15:43 Sample: L733918-03 Account: ENSRDSCA Received: 11/15/14 07:00 Due Date: 11/24/14 00:00 RPT Date: 11/24/14 15:43 Billing Information: MA-.IyIIservative Chain of Custody Vase_�— CornpanV Name/Address: AECOM quote st: ENSRNC102913S *ESCI 701 Corporate Center Drive „ e N•C•It•e Suite 475 Raleigh , NC 2760T ((< «arr C_0t7D651,1W, I 1 p, p Mwwa lu1,H,TN 77177 Report to; f mail To: ►Pone 61s-7Sa sm @aecom.corTpton.SOD767-Sa59P all �yt G.1 AC [a. 61S 744 SIIS9Project T7 City/State „ ti}"1� i �7 Q Smitty's Cleaners Collected; !� ? V Ca / 33 l�� Description rp ` Client Project a Lab Project a 0. d x D250 Phone: 919$72-6600 60321176 0 m o W Fax; _ _ 0) z a s,te/Farirty to a PO if a I A u1 Fete_ENSRDSCA i Collected by(print►: pl fl = �, Gt/ti 26-0003 O C3 Col eCted by(signature Rush? (tab MUST Be Notified) Date ResuRs Ne ed mo d 200% 57 I1 _� N fE0 zSame Day.._..._... - —Next oar 100% Email?—NO-I—Ues 00 I x rA ah Cooler Immediately, —Tw Day . So% No. a ___2S% FAX? OY+kcl _Yes of (AV I Y Shipped Via: Packed on Ice N rQt 2 = Cntrs O 0 L MmlCo.N.ro.n+�t s,rovieo(i.6 onN1 Sample ID Comp/Grab Matrix• Depth Date Time > r V oL //3-/ I i - -- - pH — Temp— •Matrix: SS-Soil GW-Groundwater WW Waste Water DW-Drinking Water OT-Other _ _ Other Flow Hold N -- Remarks- lab use only) Samples returned via: ❑UPS Condition: l Relinquishe Date. Time: R (Signaure) A cC 3 (� � ❑FedEx ❑Courier ❑_ __ r�1J ���/ Bottles Received: ReGnqulshed by (Signature) Date: Time Received by (Signature) Temp: -C C� `3 14 COC Seal Intact\V _N -_NA Time: pH Checked: NCF: 1 C Date: Time Received for lab :(Slgnaturt) Date: ,v Reim by (Signature) �, j' p - - �� G II ( ' I ► I S) 1 j 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 l.•A 0 S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 Mr. Matthew Allen AECOM 701 Corporate Center Drive, Suite 475 Raleigh, NC 27607 Report Summary Friday December 05, 2014 Report Number: L735625 Samples Received: 11/25/14 Client Project: 60321176.F02 Description: Smitty Cleaners The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Entire Report Reviewed By: Terrie Fudg ESC resentative Laboratory Certification Numbers A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197, FL - E87487, GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016, NC - ENV375/DW21704/BI0041, ND - R-140. NJ - TN002, NJ NELAP - TN002, SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612, MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1, TX - T104704245-11-3, OK - 9915, PA - 68-02979, IA Lab #364, EPA - TNO02 Accreditation is only applicable to the test methods specified on each scope of accreditation held by ESC Lab Sciences. This report may not be reproduced, except in full, without written approval from ESC Lab Sciences. Where applicable, sampling conducted by ESC is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. Page 1 of 7 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 05, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L735625-01 Date Received November 25, 2014 Description Smitty Cleaners Site ID 26-003 Sample ID IMW-1 Project # 60321176.F02 Collected By A.C. Whichard Collection Date 11/21/14 09:35 Parameter Result MDL RDL Units Qualifier Method Date Dil. Volatile Organics Acetone 1.2 0.10 0.50 mg/1 8260B 12/01/14 10 Acrolein U 0.0089 0.050 mg/l 8260B 12/05/14 1 Acrylonitrile U 0.0019 0.010 mg/l 8260B 12/05/14 1 Benzene U 0.00033 0.0010 mg/1 8260B 12/05/14 1 Bromobenzene U 0.00035 0.0010 mg/l 8260B 12/05/14 1 Bromodichloromethane 0.00080 0.00038 0.0010 mg/1 J 8260B 12/05/14 1 Bromomethane U 0.00087 0.0050 mg/l 8260B 12/05/14 1 n-Butylbenzene U 0.00036 0.0010 mg/1 8260B 12/05/14 1 sec-Butylbenzene U 0.00036 0.0010 mg/1 8260B 12/05/14 1 tert-Butylbenzene U 0.00040 0.0010 mg/1 8260B 12/05/14 1 Carbon tetrachloride U 0.00038 0.0010 mg/1 8260B 12/05/14 1 Chlorobenzene U 0.00035 0.0010 mg/1 8260B 12/05/14 1 Chlorodibromomethane 0.0010 0.00033 0.0010 mg/1 8260B 12/05/14 1 Chloroethane U 0.00045 0.0050 mg/l 8260B 12/05/14 1 2-Chloroethyl vinyl ether U 0.0030 0.050 mg/1 8260B 12/05/14 1 Chloroform 0.0016 0.00032 0.0050 mg/1 J 8260B 12/05/14 1 Chloromethane U 0.00028 0.0025 mg/1 8260B 12/05/14 1 2-Chlorotoluene U 0.00038 0.0010 mg/1 8260B 12/05/14 1 4-Chlorotoluene U 0.00035 0.0010 mg/1 8260B 12/05/14 1 1,2-Dibromo-3-Chloropropane U 0.0013 0.0050 mg/1 8260B 12/05/14 1 1,2-Dibromoethane U 0.00038 0.0010 mg/1 8260B 12/05/14 1 Dibromomethane U 0.00035 0.0010 mg/l 8260B 12/05/14 1 1,2-Dichlorobenzene U 0.00035 0.0010 mg/l 8260B 12/05/14 1 1,3-Dichlorobenzene U 0.00022 0.0010 mg/1 8260B 12/05/14 1 1,4-Dichlorobenzene U 0.00027 0.0010 mg/l 8260B 12/05/14 1 Dichlorodifluoromethane U 0.00055 0.0050 mg/1 8260B 12/05/14 1 1,1-Dichloroethane U 0.00026 0.0010 mg/1 8260B 12/05/14 1 1,2-Dichloroethane U 0.00036 0.0010 mg/1 8260B 12/05/14 1 1,1-Dichloroethene U 0.00040 0.0010 mg/1 8260B 12/05/14 1 cis-1,2-Dichloroethene U 0.00026 0.0010 mg/1 8260B 12/05/14 1 trans-1,2-Dichloroethene U 0.00040 0.0010 mg/1 8260B 12/05/14 1 1,2-Dichloropropane U 0.00031 0.0010 mg/1 8260B 12/05/14 1 1,1-Dichloropropene U 0.00035 0.0010 mg/1 8260B 12/05/14 1 1,3-Dichloropropane U 0.00037 0.0010 mg/1 8260B 12/05/14 1 cis-1,3-Dichloropropene U 0.00042 0.0010 mg/1 8260B 12/05/14 1 trans-1,3-Dichloropropene U 0.00042 0.0010 mg/1 8260B 12/05/14 1 2,2-Dichloropropane U 0.00032 0.0010 mg/1 8260B 12/05/14 1 Di-isopropyl ether U 0.00032 0.0010 mg/l 8260B 12/05/14 1 Ethylbenzene U 0.00038 0.0010 mg/1 8260B 12/05/14 1 Hexachloro-1,3-butadiene U 0.00026 0.0010 mg/l 8260B 12/05/14 1 Isopropylbenzene U 0.00033 0.0010 mg/1 8260B 12/05/14 1 p-Isopropyltoluene U 0.00035 0.0010 mg/l 8260B 12/05/14 1 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 12/05/14 11:38 Printed: 12/05/14 11:38 Page 2 of 7 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 05, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L735625-01 Date Received November 25, 2014 Description Smitty Cleaners Site ID 26-003 Sample ID IMW-1 Project # 60321176.F02 Collected By A.C. Whichard Collection Date 11/21/14 09:35 Parameter Result MDL RDL Units Qualifier Method Date Dil. 2-Butanone (MEK) 0.030 0.0039 0.010 mg/l 8260B 12/05/14 1 Methylene Chloride U 0.0010 0.0050 mg/1 8260B 12/05/14 1 4-Methyl-2-pentanone (MIBK) U 0.0021 0.010 mg/l 8260B 12/05/14 1 Methyl tert-butyl ether U 0.00037 0.0010 mg/l 8260B 12/05/14 1 Naphthalene U 0.0010 0.0050 mg/1 8260B 12/05/14 1 n-Propylbenzene U 0.00035 0.0010 mg/l 8260B 12/05/14 1 Styrene U 0.00031 0.0010 mg/1 8260B 12/05/14 1 1,1,1,2-Tetrachloroethane U 0.00038 0.0010 mg/l 8260B 12/05/14 1 1,1,2,2-Tetrachloroethane U 0.00013 0.0010 mg/1 8260B 12/05/14 1 1,1,2-Trichlorotrifluoroethane U 0.00030 0.0010 mg/1 8260B 12/05/14 1 Tetrachloroethene 0.00056 0.00037 0.0010 mg/1 J 8260B 12/05/14 1 Toluene U 0.00078 0.0050 mg/1 8260B 12/05/14 1 1,2,3-Trichlorobenzene U 0.00023 0.0010 mg/1 8260B 12/05/14 1 1,2,4-Trichlorobenzene U 0.00021 0.0010 mg/1 8260B 12/05/14 1 1,1,1-Trichloroethane U 0.00032 0.0010 mg/l 8260B 12/05/14 1 1,1,2-Trichloroethane 0.00049 0.00038 0.0010 mg/1 J 8260B 12/05/14 1 Trichloroethene U 0.00040 0.0010 mg/1 8260B 12/05/14 1 Trichlorofluoromethane U 0.0012 0.0050 mg/1 8260B 12/05/14 1 1,2,3-Trichloropropane U 0.00081 0.0025 mg/1 8260B 12/05/14 1 1,2,4-Trimethylbenzene U 0.00037 0.0010 mg/1 8260B 12/05/14 1 1,2,3-Trimethylbenzene U 0.00032 0.0010 mg/1 8260B 12/05/14 1 1,3,5-Trimethylbenzene U 0.00039 0.0010 mg/1 8260B 12/05/14 1 Vinyl chloride U 0.00026 0.0010 mg/l 8260B 12/05/14 1 Xylenes, Total U 0.0011 0.0030 mg/l 8260B 12/05/14 1 Surrogate Recovery Toluene-d8 101. % Rec. 8260B 12/01/14 1 Dibromofluoromethane 100. % Rec. 8260B 12/01/14 1 4-Bromofluorobenzene 97.3 % Rec. 8260B 12/01/14 1 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 12/05/14 11:38 Printed: 12/05/14 11:38 Page 3 of 7 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 05, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L735625-02 Date Received November 25, 2014 Description Smitty's Cleaners Site ID 26-003 Sample ID MW-33 Project # 60321176.F02 Collected By A.C. Whichard Collection Date 11/21/14 11:00 Parameter Result MDL RDL Units Qualifier Method Date Dil. Volatile Organics Acetone U 0.010 0.050 mg/1 ** 8260B 12/01/14 1 Acrolein U 0.0089 0.050 mg/l 8260B 12/01/14 1 Acrylonitrile U 0.0019 0.010 mg/l 8260B 12/01/14 1 Benzene U 0.00033 0.0010 mg/1 8260B 12/01/14 1 Bromobenzene U 0.00035 0.0010 mg/l 8260B 12/01/14 1 Bromodichloromethane U 0.00038 0.0010 mg/1 8260B 12/01/14 1 Bromoform U 0.00047 0.0010 mg/l 8260B 12/01/14 1 Bromomethane U 0.00087 0.0050 mg/1 J4 8260B 12/01/14 1 n-Butylbenzene U 0.00036 0.0010 mg/1 8260B 12/01/14 1 sec-Butylbenzene U 0.00036 0.0010 mg/1 8260B 12/01/14 1 tert-Butylbenzene U 0.00040 0.0010 mg/1 8260B 12/01/14 1 Carbon tetrachloride 0.0012 0.00038 0.0010 mg/1 8260B 12/01/14 1 Chlorobenzene U 0.00035 0.0010 mg/1 8260B 12/01/14 1 Chlorodibromomethane U 0.00033 0.0010 mg/l 8260B 12/01/14 1 Chloroethane U 0.00045 0.0050 mg/1 8260B 12/01/14 1 2-Chloroethyl vinyl ether U 0.0030 0.050 mg/1 8260B 12/01/14 1 Chloroform 0.00092 0.00032 0.0050 mg/1 J 8260B 12/01/14 1 Chloromethane U 0.00028 0.0025 mg/1 8260B 12/01/14 1 2-Chlorotoluene U 0.00038 0.0010 mg/1 8260B 12/01/14 1 4-Chlorotoluene U 0.00035 0.0010 mg/1 8260B 12/01/14 1 1,2-Dibromo-3-Chloropropane U 0.0013 0.0050 mg/1 8260B 12/01/14 1 1,2-Dibromoethane U 0.00038 0.0010 mg/l 8260B 12/01/14 1 Dibromomethane U 0.00035 0.0010 mg/l 8260B 12/01/14 1 1,2-Dichlorobenzene U 0.00035 0.0010 mg/1 8260B 12/01/14 1 1,3-Dichlorobenzene U 0.00022 0.0010 mg/l 8260B 12/01/14 1 1,4-Dichlorobenzene U 0.00027 0.0010 mg/1 8260B 12/01/14 1 Dichlorodifluoromethane U 0.00055 0.0050 mg/1 8260B 12/01/14 1 1,1-Dichloroethane 0.0015 0.00026 0.0010 mg/1 8260B 12/01/14 1 1,2-Dichloroethane U 0.00036 0.0010 mg/1 8260B 12/01/14 1 1,1-Dichloroethene U 0.00040 0.0010 mg/1 8260B 12/01/14 1 cis-1,2-Dichloroethene 0.0023 0.00026 0.0010 mg/1 8260B 12/01/14 1 trans-1,2-Dichloroethene U 0.00040 0.0010 mg/1 8260B 12/01/14 1 1,2-Dichloropropane U 0.00031 0.0010 mg/1 8260B 12/01/14 1 1,1-Dichloropropene U 0.00035 0.0010 mg/1 8260B 12/01/14 1 1,3-Dichloropropane U 0.00037 0.0010 mg/1 8260B 12/01/14 1 cis-1,3-Dichloropropene U 0.00042 0.0010 mg/1 8260B 12/01/14 1 trans-1,3-Dichloropropene U 0.00042 0.0010 mg/1 8260B 12/01/14 1 2,2-Dichloropropane U 0.00032 0.0010 mg/l 8260B 12/01/14 1 Di-isopropyl ether U 0.00032 0.0010 mg/1 8260B 12/01/14 1 Ethylbenzene U 0.00038 0.0010 mg/l 8260B 12/01/14 1 Hexachloro-1,3-butadiene U 0.00026 0.0010 mg/1 8260B 12/01/14 1 Isopropylbenzene U 0.00033 0.0010 mg/l 8260B 12/01/14 1 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 12/05/14 11:38 Printed: 12/05/14 11:38 Page 4 of 7 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 05, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L735625-02 Date Received November 25, 2014 Description Smitty's Cleaners Site ID 26-003 Sample ID MW-33 Project # 60321176.F02 Collected By A.C. Whichard Collection Date 11/21/14 11:00 Parameter Result MDL RDL Units Qualifier Method Date Dil. p-Isopropyltoluene U 0.00035 0.0010 mg/l 8260B 12/01/14 1 2-Butanone (MEK) U 0.0039 0.010 mg/1 8260B 12/01/14 1 Methylene Chloride U 0.0010 0.0050 mg/l 8260B 12/01/14 1 4-Methyl-2-pentanone (MIBK) U 0.0021 0.010 mg/l 8260B 12/01/14 1 Methyl tert-butyl ether U 0.00037 0.0010 mg/1 8260B 12/01/14 1 Naphthalene U 0.0010 0.0050 mg/l 8260B 12/01/14 1 n-Propylbenzene U 0.00035 0.0010 mg/1 8260B 12/01/14 1 Styrene U 0.00031 0.0010 mg/l 8260B 12/01/14 1 1,1,1,2-Tetrachloroethane U 0.00038 0.0010 mg/1 8260B 12/01/14 1 1,1,2,2-Tetrachloroethane 0.00031 0.00013 0.0010 mg/1 J 8260B 12/01/14 1 1,1,2-Trichlorotrifluoroethane U 0.00030 0.0010 mg/1 8260B 12/01/14 1 Tetrachloroethene 20. 0.093 0.25 mg/1 8260B 12/05/14 250 Toluene U 0.00078 0.0050 mg/1 8260B 12/01/14 1 1,2,3-Trichlorobenzene U 0.00023 0.0010 mg/1 8260B 12/01/14 1 1,2,4-Trichlorobenzene U 0.00021 0.0010 mg/l 8260B 12/01/14 1 1,1,1-Trichloroethane 0.0094 0.00032 0.0010 mg/1 8260B 12/01/14 1 1,1,2-Trichloroethane 0.0010 0.00038 0.0010 mg/1 8260B 12/01/14 1 Trichloroethene 0.0099 0.00040 0.0010 mg/1 8260B 12/01/14 1 Trichlorofluoromethane U 0.0012 0.0050 mg/1 8260B 12/01/14 1 1,2,3-Trichloropropane U 0.00081 0.0025 mg/1 8260B 12/01/14 1 1,2,4-Trimethylbenzene U 0.00037 0.0010 mg/1 8260B 12/01/14 1 1,2,3-Trimethylbenzene U 0.00032 0.0010 mg/1 8260B 12/01/14 1 1,3,5-Trimethylbenzene U 0.00039 0.0010 mg/l 8260B 12/01/14 1 Vinyl chloride U 0.00026 0.0010 mg/l 8260B 12/01/14 1 Xylenes, Total U 0.0011 0.0030 mg/1 8260B 12/01/14 1 Surrogate Recovery Toluene-d8 99.5 % Rec. 8260B 12/01/14 1 Dibromofluoromethane 99.3 % Rec. 8260B 12/01/14 1 4-Bromofluorobenzene 100. % Rec. 8260B 12/01/14 1 U = ND (Not Detected) MDL = Minimum Detection Limit = LOD = TRRP SDL RDL = Reported Detection Limit = LOQ = PQL = EQL = TRRP MQL Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 12/05/14 11:38 Printed: 12/05/14 11:38 Page 5 of 7 Attachment A List of Analytes with QC Qualifiers Sample Work Sample Run Number Group Type Analyte ID Qualifier L735625-01 WG758150 SAMP Bromodichloromethane R3008307 J WG758150 SAMP Chloroform R3008307 J WG758150 SAMP Tetrachloroethene R3008307 J WG758150 SAMP 1,1,2-Trichloroethane R3008307 J L735625-02 WG757143 SAMP Acetone R3008130 ** WG757143 SAMP Bromomethane R3008130 J4 WG757143 SAMP Chloroform R3008130 J WG757143 SAMP 1,1,2,2-Tetrachloroethane R3008130 J Page 6 of 7 Attachment B Explanation of QC Qualifier Codes Qualifier Meaning J (EPA) - Estimated value below the lowest calibration point. Confidence correlates with concentration. J4 The associated batch QC was outside the established quality control range for accuracy. Qualifier Report Information ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical results. Each qualifier is designated in the qualifier explanation as either EPA or ESC. Data qualifiers are intended to provide the ESC client with more detailed information concerning the potential bias of reported data. Because of the wide range of constituents and variety of matrices incorporated by most EPA methods,it is common for some compounds to fall outside of established ranges. These exceptions are evaluated and all reported data is valid and useable "unless qualified as 'R' (Rejected) ." Definitions Accuracy - The relationship of the observed value of a known sample to the true value of a known sample. Represented by percent recovery and relevant to samples such as: control samples, matrix spike recoveries, surrogate recoveries, etc. Precision - The agreement between a set of samples or between duplicate samples. Relates to how close together the results are and is represented by Relative Percent Differrence. Surrogate - Organic compounds that are similar in chemical composition, extraction, and chromotography to analytes of interest. The surrogates are used to determine the probable response of the group of analytes that are chem- ically related to the surrogate compound. Surrogates are added to the sample and carried through all stages of preparation and analyses. TIC - Tentatively Identified Compound: Compounds detected in samples that are not target compounds, internal standards, system monitoring compounds, or surrogates. Page 7 of 7 Summary of Remarks For Samples Printed 12/05/14 at 11:38:42 TSR Signing Reports: 064 R5 - Desired TAT this account is for only dry-cleaning sites in NC. . .EDD is required on all projects. EDD is required for this client. . .report in mg/l only Sample: L735625-01 Account: ENSRDSCA Received: 11/25/14 07:45 Due Date: 12/04/14 00:00 RPT Date: 12/05/14 11:38 Sample: L735625-02 Account: ENSRDSCA Received: 11/25/14 07:45 Due Date: 12/04/14 00:00 RPT Date: 12/05/14 11:38 Mill Company Name/Address Billing Information: --� Analysis/Container/Preservative Chain of custody 1`39�_ or AECOM quote#: ENSRIJC101913S 701 Corporate Center Drive *ESC' Suite 475 A l3 E r, E sl Raleigh , NC 27607 12065 L.W—.Ad Report t0- rTail TO' Mart luL,t,se-sax TN 31112 Matt Allen Inathew.allen@aecom.com ►AoM MOM:a I 0P767-St59 1 Project Description: jGty/State — aa:6ts-7sases9- O_ Smitty,s Cleaners collected- Phone 919-872-6600 client Project LN G N Lab Protect R I V to � G173 Fax: Collected by(print) Site/Faciltty ID# — PO M _J I Atctnum:EN$RDSCA 26-003 _ Template: C signature): Date Results Need,d m Rush? (Lab MUST Be Notified) o Prelogin: Same Day ..... ...._.200% cD ' - N TSR: _ . .-..100% [mail?_No _yes co Next Day.._....... . Immediately —Two Day......-.. -. .-.. __` FAX? No Yes I X Cooler: Packed on Ice N r —Three Day-...... ._........ 2sx — — O Shipped Via: Sample ID Comp/GrabI , -__L_L Matrix' Depth Date I ?.me > a.m lcnnunw t s.rpl.a pair o.1V1 M — II-z�_II{ 35- 2 r� _ 1 t I •Matrix: SS-Sod GW-Groundwater WW-'W'astrwater DW Drinking Water OT-Other— _ pH Temp Remarks: I Flow Other Mold N un ed by:(Signature Date: Time: Recei (sig*e) —Samples returned via ❑UPS Condition: (lab use only) 0 FedEx ❑Courier Relinquished by:(Signature) Date: Ti Rec wed by:(Signat�re; Tem 'C Bottles Recehed: I p' � .}l"f �2 I V COC Seal Intact: " Y _N _NA Reli by:lSignature) Date' Time: Recei for lab by rS�gn u Date: Time: H Checked: NCF: _ 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 l.•A 0 S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 Mr. Matthew Allen AECOM 701 Corporate Center Drive, Suite 475 Raleigh, NC 27607 Report Summary Wednesday December 03, 2014 Report Number: L735715 Samples Received: 11/25/14 Client Project: 60321176 .F0 Description: Smitty Cleaners The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Entire Report Reviewed By: Terrie Fudg ESC resentative Laboratory Certification Numbers A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197, FL - E87487, GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016, NC - ENV375/DW21704/BI0041, ND - R-140. NJ - TN002, NJ NELAP - TN002, SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612, MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1, TX - T104704245-11-3, OK - 9915, PA - 68-02979, IA Lab #364, EPA - TNO02 Accreditation is only applicable to the test methods specified on each scope of accreditation held by ESC Lab Sciences. This report may not be reproduced, except in full, without written approval from ESC Lab Sciences. Where applicable, sampling conducted by ESC is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. Page 1 of 2 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 03, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L735715-01 Date Received November 25, 2014 Description Smitty Cleaners Site ID DSC 26-0003 Sample ID IA-01-11212014 Project # 60321176.F0 Collected By A.C. Whichard Collection Date 11/21/14 16:15 Parameter Cas# Mol Wght RDL1 RDL2 ppbv ug/m3 Method Date Dil. Volatile Organics - TO-15 SIM Benzene 71-43-2 78.1 0.020 0.064 0.32 1.0 TO-15 12/02/14 1 Carbon tetrachloride 56-23-5 154 0.020 0.13 0.072 0.45 TO-15 12/02/14 1 Chloroethane 75-00-3 64.5 0.040 0.11 < 0.040 < 0.11 TO-15 12/02/14 1 Chloroform 67-66-3 119 0.020 0.097 < 0.020 < 0.097 TO-15 12/02/14 1 Chloromethane 74-87-3 50.5 0.030 0.062 0.60 1.2 TO-15 12/02/14 1 1,2-Dibromoethane 106-93-4 188 0.020 0.15 < 0.020 < 0.15 TO-15 12/02/14 1 1,4-Dichlorobenzene 106-46-7 147 0.020 0.12 < 0.020 < 0.12 TO-15 12/02/14 1 1,1-Dichloroethane 75-34-3 98 0.020 0.080 < 0.020 < 0.080 TO-15 12/02/14 1 1,1-Dichloroethene 75-35-4 96.9 0.020 0.079 < 0.020 < 0.079 TO-15 12/02/14 1 cis-1,2-Dichloroethene 156-59-2 96.9 0.020 0.079 0.12 0.48 TO-15 12/02/14 1 trans-1,2-Dichloroethene 156-60-5 96.9 0.020 0.079 < 0.020 < 0.079 TO-15 12/02/14 1 1,2-Dichloropropane 78-87-5 113 0.030 0.14 < 0.030 < 0.14 TO-15 12/02/14 1 cis-1,3-Dichloropropene 10061-01-5 111 0.020 0.091 < 0.020 < 0.091 TO-15 12/02/14 1 trans-1,3-Dichloropropene 10061-02-6 111 0.030 0.14 < 0.030 < 0.14 TO-15 12/02/14 1 Ethylbenzene 100-41-4 106 0.030 0.13 0.24 1.0 TO-15 12/02/14 1 1,1,2,2-Tetrachloroethane 79-34-5 168 0.020 0.14 < 0.020 < 0.14 TO-15 12/02/14 1 Tetrachloroethylene 127-18-4 166 0.80 5.4 32. 220 TO-15 12/02/14 40 1,1,1-Trichloroethane 71-55-6 133 0.020 0.11 < 0.020 < 0.11 TO-15 12/02/14 1 1,1,2-Trichloroethane 79-00-5 133 0.030 0.16 < 0.030 < 0.16 TO-15 12/02/14 1 Trichloroethylene 79-01-6 131 0.020 0.11 0.87 4.7 TO-15 12/02/14 1 Vinyl chloride 75-01-4 62.5 0.020 0.051 < 0.020 < 0.051 TO-15 12/02/14 1 Vinyl acetate 108-05-4 86.1 0.020 0.070 < 0.020 < 0.070 TO-15 12/02/14 1 1,4-Bromofluorobenzene 460-00-4 95.5 o Rec. TO-15 12/02/14 1 RDL1 = ppbv , RDL2 = ug/m3 Note: Units are based on (STP) - Standard Temperature and Pressure The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 12/03/14 10:46 Printed: 12/03/14 13:35 Page 2 of 2 E�it ii i ip,I�r�•-,i .�- Analysis/Container/Preservative Chair of Custody Page_of f,ECOM Inc - Raleigh NC Attn:Matt Allen '*E P.O. Box 5604 701 Corporate Center Drive,Suite 47S Glen Allen,VA 23058-5604 Raleigh, NC 27607 j SC- 12065 Lebanon rid nWanS)ulie6 TN 17122 Report to E a l To, matthew.allen@aecom.com� Pnona:615 758 SaSa ' Mr. Matthew Allen Fao61B-5859 n ■t �• ❑h. Project City/State Description Smitty Cleaners Collected. L# C7 1715 Client Project# Lab Project# Phone.919 872 6600 60321176.F0 ENSRDSCA-SMIM Tz L009 Fax: Collected by[print): Site/Facility ID# P.O.# Acctnum:ENSRDSCA DSC 26-0003 E Template797661 I A.c. Collec Rush? (lab MUST Be Notified) Date R suits N eded Prelogin:P48631S 200% /4/�Q c r / G Same D ....... __._ ... TSR: Terrie Fudge, �_next Day....._. ....... ....._...-100% Email? No X_Yes IDS: Immediately _Two Day ...................._.......SO% ?�No Yes No. Three Day FAX r Packed on ice N_ Y_ _ 25% — — cf Ln Shipped via:FedEX Ground 1V5 6P.em�[OnlaPlin]rit San01v x pah onlpl Sample ID Comp/Grab Matrix' Depth Date Time 6 � — :1 �li 2 6r r Air //- —I'- 1 X I Matrix: SS-Soil GW Groundwater wW-wastewater DW-Drinking Water OT•Other_ PH Temp_ Remarks: C � y y y y y � Zz Flow Other_ Hold# 1 CondlUon: (lab use only) Relinquished b Oate: ;Tir-ne: Received by (Signature) Samples returned via ❑UPS Q� /4/ FedEx ❑Courier ❑-C Bottles jieceived Relinquished by (Signature) Date: Received by ISignatu'e) Temp: J COC Seal Intact: _Y _N `NA Relinquished by:(Slgnat Date: Time: Rec ivtd for by: '( mature) Date: Time: pH Checked: NCF: 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 l.•A 0 S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 Mr. Matthew Allen AECOM 701 Corporate Center Drive, Suite 475 Raleigh, NC 27607 Report Summary Wednesday December 10, 2014 Report Number: L736445 Samples Received: 12/02/14 Client Project: 60321176 Description: Smitty Cleaners The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Entire Report Reviewed By: Terrie Fudg ESC resentative Laboratory Certification Numbers A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197, FL - E87487, GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016, NC - ENV375/DW21704/BI0041, ND - R-140. NJ - TN002, NJ NELAP - TN002, SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612, MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1, TX - T104704245-11-3, OK - 9915, PA - 68-02979, IA Lab #364, EPA - TNO02 Accreditation is only applicable to the test methods specified on each scope of accreditation held by ESC Lab Sciences. This report may not be reproduced, except in full, without written approval from ESC Lab Sciences. Where applicable, sampling conducted by ESC is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. Page 1 of 7 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 10, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L736445-01 Date Received December 02, 2014 Description Smitty Cleaners Site ID DSCA 26-0003 Sample ID MW-33 Project # 60321176 Collected By A.C. Whichard Collection Date 11/26/14 10:30 Parameter Result Det. Limit Units Method Date Dil. Volatile Organics Acetone BDL 25. mg/1 8260B 12/09/14 500 Acrolein BDL 25. mg/l 8260B 12/09/14 500 Acrylonitrile BDL 5.0 mg/l 8260B 12/09/14 500 Benzene BDL 0.50 mg/1 8260B 12/09/14 500 Bromobenzene BDL 0.50 mg/l 8260B 12/09/14 500 Bromodichloromethane BDL 0.50 mg/1 8260B 12/09/14 500 Bromoform BDL 0.50 mg/l 8260B 12/09/14 500 Bromomethane BDL 2.5 mg/1 8260B 12/09/14 500 n-Butylbenzene BDL 0.50 mg/1 8260B 12/09/14 500 sec-Butylbenzene BDL 0.50 mg/1 8260B 12/09/14 500 tert-Butylbenzene BDL 0.50 mg/1 8260B 12/09/14 500 Carbon tetrachloride BDL 0.50 mg/1 8260B 12/09/14 500 Chlorobenzene BDL 0.50 mg/1 8260B 12/09/14 500 Chlorodibromomethane BDL 0.50 mg/l 8260B 12/09/14 500 Chloroethane BDL 2.5 mg/1 8260B 12/09/14 500 2-Chloroethyl vinyl ether BDL 25. mg/1 8260B 12/09/14 500 Chloroform BDL 2.5 mg/1 8260B 12/09/14 500 Chloromethane BDL 1.3 mg/1 8260B 12/09/14 500 2-Chlorotoluene BDL 0.50 mg/1 8260B 12/09/14 500 4-Chlorotoluene BDL 0.50 mg/1 8260B 12/09/14 500 1,2-Dibromo-3-Chloropropane BDL 2.5 mg/1 8260B 12/09/14 500 1,2-Dibromoethane BDL 0.50 mg/l 8260B 12/09/14 500 Dibromomethane BDL 0.50 mg/l 8260B 12/09/14 500 1,2-Dichlorobenzene BDL 0.50 mg/1 8260B 12/09/14 500 1,3-Dichlorobenzene BDL 0.50 mg/l 8260B 12/09/14 500 1,4-Dichlorobenzene BDL 0.50 mg/1 8260B 12/09/14 500 Dichlorodifluoromethane BDL 2.5 mg/1 8260B 12/09/14 500 1,1-Dichloroethane BDL 0.50 mg/1 8260B 12/09/14 500 1,2-Dichloroethane BDL 0.50 mg/1 8260B 12/09/14 500 1,1-Dichloroethene BDL 0.50 mg/1 8260B 12/09/14 500 cis-1,2-Dichloroethene BDL 0.50 mg/1 8260B 12/09/14 500 trans-1,2-Dichloroethene BDL 0.50 mg/1 8260B 12/09/14 500 1,2-Dichloropropane 0.76 0.50 mg/1 8260B 12/09/14 500 1,1-Dichloropropene BDL 0.50 mg/1 8260B 12/09/14 500 1,3-Dichloropropane BDL 0.50 mg/1 8260B 12/09/14 500 cis-1,3-Dichloropropene BDL 0.50 mg/1 8260B 12/09/14 500 trans-1,3-Dichloropropene BDL 0.50 mg/1 8260B 12/09/14 500 2,2-Dichloropropane BDL 0.50 mg/1 8260B 12/09/14 500 Di-isopropyl ether BDL 0.50 mg/1 8260B 12/09/14 500 Ethylbenzene BDL 0.50 mg/l 8260B 12/09/14 500 Hexachloro-1,3-butadiene BDL 0.50 mg/1 8260B 12/09/14 500 Isopropylbenzene BDL 0.50 mg/l 8260B 12/09/14 500 p-Isopropyltoluene BDL 0.50 mg/1 8260B 12/09/14 500 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Page 2 of 7 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 10, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L736445-01 Date Received December 02, 2014 Description Smitty Cleaners Site ID DSCA 26-0003 Sample ID MW-33 Project # 60321176 Collected By A.C. Whichard Collection Date 11/26/14 10:30 Parameter Result Det. Limit Units Method Date Dil. 2-Butanone (MEK) BDL 5.0 mg/l 8260B 12/09/14 500 Methylene Chloride BDL 2.5 mg/1 8260B 12/09/14 500 4-Methyl-2-pentanone (MIBK) BDL 5.0 mg/l 8260B 12/09/14 500 Methyl tert-butyl ether BDL 0.50 mg/l 8260B 12/09/14 500 Naphthalene BDL 2.5 mg/1 8260B 12/09/14 500 n-Propylbenzene BDL 0.50 mg/l 8260B 12/09/14 500 Styrene BDL 0.50 mg/1 8260B 12/09/14 500 1,1,1,2-Tetrachloroethane BDL 0.50 mg/l 8260B 12/09/14 500 1,1,2,2-Tetrachloroethane BDL 0.50 mg/1 8260B 12/09/14 500 1,1,2-Trichlorotrifluoroethane BDL 0.50 mg/1 8260B 12/09/14 500 Tetrachloroethene 26. 0.50 mg/1 8260B 12/09/14 500 Toluene BDL 2.5 mg/1 8260B 12/09/14 500 1,2,3-Trichlorobenzene BDL 0.50 mg/1 8260B 12/09/14 500 1,2,4-Trichlorobenzene BDL 0.50 mg/1 8260B 12/09/14 500 1,1,1-Trichloroethane BDL 0.50 mg/l 8260B 12/09/14 500 1,1,2-Trichloroethane BDL 0.50 mg/1 8260B 12/09/14 500 Trichloroethene BDL 0.50 mg/1 8260B 12/09/14 500 Trichlorofluoromethane BDL 2.5 mg/1 8260B 12/09/14 500 1,2,3-Trichloropropane BDL 1.3 mg/1 8260B 12/09/14 500 1,2,4-Trimethylbenzene BDL 0.50 mg/1 8260B 12/09/14 500 1,2,3-Trimethylbenzene BDL 0.50 mg/1 8260B 12/09/14 500 1,3,5-Trimethylbenzene BDL 0.50 mg/1 8260B 12/09/14 500 Vinyl chloride BDL 0.50 mg/l 8260B 12/09/14 500 Xylenes, Total BDL 1.5 mg/l 8260B 12/09/14 500 Surrogate Recovery Toluene-d8 103. % Rec. 8260B 12/09/14 500 Dibromofluoromethane 107. % Rec. 8260B 12/09/14 500 4-Bromofluorobenzene 109. % Rec. 8260B 12/09/14 500 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 12/09/14 10:10 Revised: 12/10/14 17:41 Page 3 of 7 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 10, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L736445-02 Date Received December 02, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID IMW-1 Project # 60321176 Collected By A.C. Whichard Collection Date 11/26/14 10:00 Parameter Result Det. Limit Units Method Date Dil. Volatile Organics Acetone BDL 2.5 mg/1 8260B 12/03/14 50 Acrolein BDL 0.050 mg/l 8260B 12/03/14 1 Acrylonitrile BDL 0.010 mg/l 8260B 12/03/14 1 Benzene BDL 0.0010 mg/1 8260B 12/03/14 1 Bromobenzene BDL 0.0010 mg/l 8260B 12/03/14 1 Bromodichloromethane BDL 0.0010 mg/1 8260B 12/03/14 1 Bromoform BDL 0.0010 mg/l 8260B 12/03/14 1 Bromomethane BDL 0.0050 mg/1 8260B 12/03/14 1 n-Butylbenzene BDL 0.0010 mg/1 8260B 12/03/14 1 sec-Butylbenzene BDL 0.0010 mg/1 8260B 12/03/14 1 tert-Butylbenzene BDL 0.0010 mg/1 8260B 12/03/14 1 Carbon tetrachloride BDL 0.0010 mg/1 8260B 12/03/14 1 Chlorobenzene BDL 0.0010 mg/1 8260B 12/03/14 1 Chlorodibromomethane BDL 0.0010 mg/l 8260B 12/03/14 1 Chloroethane BDL 0.0050 mg/1 8260B 12/03/14 1 2-Chloroethyl vinyl ether BDL 0.050 mg/1 8260B 12/03/14 1 Chloroform BDL 0.0050 mg/1 8260B 12/03/14 1 Chloromethane BDL 0.0025 mg/1 8260B 12/03/14 1 2-Chlorotoluene BDL 0.0010 mg/1 8260B 12/03/14 1 4-Chlorotoluene BDL 0.0010 mg/1 8260B 12/03/14 1 1,2-Dibromo-3-Chloropropane BDL 0.0050 mg/1 8260B 12/03/14 1 1,2-Dibromoethane BDL 0.0010 mg/l 8260B 12/03/14 1 Dibromomethane BDL 0.0010 mg/l 8260B 12/03/14 1 1,2-Dichlorobenzene BDL 0.0010 mg/1 8260B 12/03/14 1 1,3-Dichlorobenzene BDL 0.0010 mg/l 8260B 12/03/14 1 1,4-Dichlorobenzene BDL 0.0010 mg/1 8260B 12/03/14 1 Dichlorodifluoromethane BDL 0.0050 mg/1 8260B 12/03/14 1 1,1-Dichloroethane BDL 0.0010 mg/1 8260B 12/03/14 1 1,2-Dichloroethane BDL 0.0010 mg/1 8260B 12/03/14 1 1,1-Dichloroethene BDL 0.0010 mg/1 8260B 12/03/14 1 cis-1,2-Dichloroethene BDL 0.0010 mg/1 8260B 12/03/14 1 trans-1,2-Dichloroethene BDL 0.0010 mg/1 8260B 12/03/14 1 1,2-Dichloropropane BDL 0.0010 mg/1 8260B 12/03/14 1 1,1-Dichloropropene BDL 0.0010 mg/1 8260B 12/03/14 1 1,3-Dichloropropane BDL 0.0010 mg/1 8260B 12/03/14 1 cis-1,3-Dichloropropene BDL 0.0010 mg/1 8260B 12/03/14 1 trans-1,3-Dichloropropene BDL 0.0010 mg/1 8260B 12/03/14 1 2,2-Dichloropropane BDL 0.0010 mg/1 8260B 12/03/14 1 Di-isopropyl ether BDL 0.0010 mg/1 8260B 12/03/14 1 Ethylbenzene BDL 0.0010 mg/l 8260B 12/03/14 1 Hexachloro-1,3-butadiene BDL 0.0010 mg/1 8260B 12/03/14 1 Isopropylbenzene BDL 0.0010 mg/l 8260B 12/03/14 1 p-Isopropyltoluene BDL 0.0010 mg/1 8260B 12/03/14 1 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Page 4 of 7 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 10, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L736445-02 Date Received December 02, 2014 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID IMW-1 Project # 60321176 Collected By A.C. Whichard Collection Date 11/26/14 10:00 Parameter Result Det. Limit Units Method Date Dil. 2-Butanone (MEK) 0.020 0.010 mg/l 8260B 12/03/14 1 Methylene Chloride BDL 0.0050 mg/1 8260B 12/03/14 1 4-Methyl-2-pentanone (MIBK) BDL 0.010 mg/l 8260B 12/03/14 1 Methyl tert-butyl ether BDL 0.0010 mg/l 8260B 12/03/14 1 Naphthalene BDL 0.0050 mg/1 8260B 12/03/14 1 n-Propylbenzene BDL 0.0010 mg/l 8260B 12/03/14 1 Styrene BDL 0.0010 mg/1 8260B 12/03/14 1 1,1,1,2-Tetrachloroethane BDL 0.0010 mg/l 8260B 12/03/14 1 1,1,2,2-Tetrachloroethane BDL 0.0010 mg/1 8260B 12/03/14 1 Tetrachloroethene 1.9 0.050 mg/1 8260B 12/03/14 50 Toluene BDL 0.0050 mg/1 8260B 12/03/14 1 1,2,3-Trichlorobenzene BDL 0.0010 mg/1 8260B 12/03/14 1 1,2,4-Trichlorobenzene BDL 0.0010 mg/1 8260B 12/03/14 1 1,1,1-Trichloroethane BDL 0.0010 mg/1 8260B 12/03/14 1 1,1,2-Trichloroethane BDL 0.0010 mg/l 8260B 12/03/14 1 Trichloroethene BDL 0.0010 mg/1 8260B 12/03/14 1 Trichlorofluoromethane BDL 0.0050 mg/1 8260B 12/03/14 1 1,2,3-Trichloropropane BDL 0.0025 mg/1 8260B 12/03/14 1 1,2,4-Trimethylbenzene BDL 0.0010 mg/1 8260B 12/03/14 1 1,3,5-Trimethylbenzene BDL 0.0010 mg/1 8260B 12/03/14 1 Vinyl chloride BDL 0.0010 mg/1 8260B 12/03/14 1 Xylenes, Total BDL 0.0030 mg/1 8260B 12/03/14 1 Surrogate Recovery Toluene-d8 101. % Rec. 8260B 12/03/14 1 Dibromofluoromethane 99.4 % Rec. 8260B 12/03/14 1 a,a,a-Trifluorotoluene 101. % Rec. 8260B 12/03/14 1 4-Bromofluorobenzene 95.8 % Rec. 8260B 12/03/14 1 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 12/09/14 10:10 Revised: 12/10/14 17:41 Page 5 of 7 Attachment A List of Analytes with QC Qualifiers Sample Work Sample Run Number Group Type Analyte ID Qualifier L736445-02 WG757408 SAMP 2,2-Dichloropropane R3007940 J3 WG757408 SAMP Methyl tert-butyl ether R3007940 J3 Page 6 of 7 Attachment B Explanation of QC Qualifier Codes Qualifier Meaning J3 The associated batch QC was outside the established quality control range for precision. Qualifier Report Information ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical results. Each qualifier is designated in the qualifier explanation as either EPA or ESC. Data qualifiers are intended to provide the ESC client with more detailed information concerning the potential bias of reported data. Because of the wide range of constituents and variety of matrices incorporated by most EPA methods,it is common for some compounds to fall outside of established ranges. These exceptions are evaluated and all reported data is valid and useable "unless qualified as 'R' (Rejected) ." Definitions Accuracy - The relationship of the observed value of a known sample to the true value of a known sample. Represented by percent recovery and relevant to samples such as: control samples, matrix spike recoveries, surrogate recoveries, etc. Precision - The agreement between a set of samples or between duplicate samples. Relates to how close together the results are and is represented by Relative Percent Differrence. Surrogate - Organic compounds that are similar in chemical composition, extraction, and chromotography to analytes of interest. The surrogates are used to determine the probable response of the group of analytes that are chem- ically related to the surrogate compound. Surrogates are added to the sample and carried through all stages of preparation and analyses. TIC - Tentatively Identified Compound: Compounds detected in samples that are not target compounds, internal standards, system monitoring compounds, or surrogates. Page 7 of 7 Summary of Remarks For Samples Printed 12/10/14 at 17:41:42 TSR Signing Reports: 064 R5 - Desired TAT this account is for only dry-cleaning sites in NC. . .EDD is required on all projects. EDD is required for this client. . .report in mg/l only Sample: L736445-01 Account: ENSRDSCA Received: 12/02/14 09:00 Due Date: 12/10/14 00:00 RPT Date: 12/09/14 10:10 Sample: L736445-02 Account: ENSRDSCA Received: 12/02/14 09:00 Due Date: 12/10/14 00:00 RPT Date: 12/09/14 10:10 vials are unpreserved - hold time expires 12/03 - JCR - "8 drops of Thiosulfate added to sample to inert the K Permanganate" 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 l.•A 0 S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 Mr. Matthew Allen AECOM 701 Corporate Center Drive, Suite 475 Raleigh, NC 27607 Report Summary Thursday December 18, 2014 Report Number: L738346 Samples Received: 12/11/14 Client Project: 60321176 Description: Smitty Cleaners The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Entire Report Reviewed By: Terrie Fudg ESC resentative Laboratory Certification Numbers A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197, FL - E87487, GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016, NC - ENV375/DW21704/BI0041, ND - R-140. NJ - TN002, NJ NELAP - TN002, SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612, MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1, TX - T104704245-11-3, OK - 9915, PA - 68-02979, IA Lab #364, EPA - TNO02 Accreditation is only applicable to the test methods specified on each scope of accreditation held by ESC Lab Sciences. This report may not be reproduced, except in full, without written approval from ESC Lab Sciences. Where applicable, sampling conducted by ESC is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. Page 1 of 15 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 18, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L738346-01 Date Received December 11, 2014 Description Smitty Cleaners Site ID 26-003 Sample ID MW-2 Project # 60321176 Collected By Guy Allard Collection Date 12/05/14 06:35 Parameter Result Det. Limit Units Method Date Dil. Volatile Organics Acetone BDL 1.3 mg/1 8260B 12/14/14 25 Acrolein BDL 1.3 mg/l 8260B 12/14/14 25 Acrylonitrile BDL 0.25 mg/l 8260B 12/14/14 25 Benzene BDL 0.025 mg/1 8260B 12/14/14 25 Bromobenzene BDL 0.025 mg/l 8260B 12/14/14 25 Bromodichloromethane BDL 0.025 mg/1 8260B 12/14/14 25 Bromoform BDL 0.025 mg/l 8260B 12/14/14 25 Bromomethane BDL 0.13 mg/1 8260B 12/14/14 25 n-Butylbenzene BDL 0.025 mg/1 8260B 12/14/14 25 sec-Butylbenzene BDL 0.025 mg/1 8260B 12/14/14 25 tert-Butylbenzene BDL 0.025 mg/1 8260B 12/14/14 25 Carbon tetrachloride BDL 0.025 mg/1 8260B 12/14/14 25 Chlorobenzene BDL 0.025 mg/1 8260B 12/14/14 25 Chlorodibromomethane BDL 0.025 mg/l 8260B 12/14/14 25 Chloroethane BDL 0.13 mg/1 8260B 12/14/14 25 2-Chloroethyl vinyl ether BDL 1.3 mg/1 8260B 12/14/14 25 Chloroform BDL 0.13 mg/1 8260B 12/14/14 25 Chloromethane BDL 0.063 mg/1 8260B 12/14/14 25 2-Chlorotoluene BDL 0.025 mg/1 8260B 12/14/14 25 4-Chlorotoluene BDL 0.025 mg/1 8260B 12/14/14 25 1,2-Dibromo-3-Chloropropane BDL 0.13 mg/1 8260B 12/14/14 25 1,2-Dibromoethane BDL 0.025 mg/l 8260B 12/14/14 25 Dibromomethane BDL 0.025 mg/l 8260B 12/14/14 25 1,2-Dichlorobenzene BDL 0.025 mg/1 8260B 12/14/14 25 1,3-Dichlorobenzene BDL 0.025 mg/l 8260B 12/14/14 25 1,4-Dichlorobenzene BDL 0.025 mg/1 8260B 12/14/14 25 Dichlorodifluoromethane BDL 0.13 mg/1 8260B 12/14/14 25 1,1-Dichloroethane BDL 0.025 mg/1 8260B 12/14/14 25 1,2-Dichloroethane BDL 0.025 mg/1 8260B 12/14/14 25 1,1-Dichloroethene BDL 0.025 mg/1 8260B 12/14/14 25 cis-1,2-Dichloroethene BDL 0.025 mg/1 8260B 12/14/14 25 trans-1,2-Dichloroethene BDL 0.025 mg/1 8260B 12/14/14 25 1,2-Dichloropropane BDL 0.025 mg/1 8260B 12/14/14 25 1,1-Dichloropropene BDL 0.025 mg/1 8260B 12/14/14 25 1,3-Dichloropropane BDL 0.025 mg/1 8260B 12/14/14 25 cis-1,3-Dichloropropene BDL 0.025 mg/1 8260B 12/14/14 25 trans-1,3-Dichloropropene BDL 0.025 mg/1 8260B 12/14/14 25 2,2-Dichloropropane BDL 0.025 mg/1 8260B 12/14/14 25 Di-isopropyl ether BDL 0.025 mg/1 8260B 12/14/14 25 Ethylbenzene BDL 0.025 mg/l 8260B 12/14/14 25 Hexachloro-1,3-butadiene BDL 0.025 mg/1 8260B 12/14/14 25 Isopropylbenzene BDL 0.025 mg/l 8260B 12/14/14 25 p-Isopropyltoluene BDL 0.025 mg/1 8260B 12/14/14 25 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Page 2 of 15 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 18, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L738346-01 Date Received December 11, 2014 Description Smitty Cleaners Site ID 26-003 Sample ID MW-2 Project # 60321176 Collected By Guy Allard Collection Date 12/05/14 06:35 Parameter Result Det. Limit Units Method Date Dil. 2-Butanone (MEK) BDL 0.25 mg/l 8260B 12/14/14 25 Methylene Chloride BDL 0.13 mg/1 8260B 12/14/14 25 4-Methyl-2-pentanone (MIBK) BDL 0.25 mg/l 8260B 12/14/14 25 Methyl tert-butyl ether BDL 0.025 mg/l 8260B 12/14/14 25 Naphthalene BDL 0.13 mg/1 8260B 12/14/14 25 n-Propylbenzene BDL 0.025 mg/l 8260B 12/14/14 25 Styrene BDL 0.025 mg/1 8260B 12/14/14 25 1,1,1,2-Tetrachloroethane BDL 0.025 mg/l 8260B 12/14/14 25 1,1,2,2-Tetrachloroethane BDL 0.025 mg/1 8260B 12/14/14 25 1,1,2-Trichlorotrifluoroethane BDL 0.025 mg/1 8260B 12/14/14 25 Tetrachloroethene 9.3 0.25 mg/1 8260B 12/18/14 250 Toluene BDL 0.13 mg/1 8260B 12/14/14 25 1,2,3-Trichlorobenzene BDL 0.025 mg/1 8260B 12/14/14 25 1,2,4-Trichlorobenzene BDL 0.025 mg/1 8260B 12/14/14 25 1,1,1-Trichloroethane BDL 0.025 mg/l 8260B 12/14/14 25 1,1,2-Trichloroethane BDL 0.025 mg/1 8260B 12/14/14 25 Trichloroethene 0.011 0.025 mg/1 8260B 12/14/14 25 Trichlorofluoromethane BDL 0.13 mg/1 8260B 12/14/14 25 1,2,3-Trichloropropane BDL 0.063 mg/1 8260B 12/14/14 25 1,2,4-Trimethylbenzene BDL 0.025 mg/1 8260B 12/14/14 25 1,2,3-Trimethylbenzene BDL 0.025 mg/1 8260B 12/14/14 25 1,3,5-Trimethylbenzene BDL 0.025 mg/1 8260B 12/14/14 25 Vinyl chloride BDL 0.025 mg/l 8260B 12/14/14 25 Xylenes, Total BDL 0.075 mg/l 8260B 12/14/14 25 Surrogate Recovery Toluene-d8 102. % Rec. 8260B 12/14/14 25 Dibromofluoromethane 89.0 % Rec. 8260B 12/14/14 25 4-Bromofluorobenzene 102. % Rec. 8260B 12/14/14 25 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 12/18/14 15:24 Printed: 12/18/14 15:58 Page 3 of 15 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 18, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L738346-02 Date Received December 11, 2014 Description Smitty's Cleaners Site ID 26-003 Sample ID MW-3R Project # 60321176 Collected By Guy Allard Collection Date 12/05/14 07:45 Parameter Result Det. Limit Units Method Date Dil. Volatile Organics Acetone BDL 0.25 mg/1 8260B 12/14/14 5 Acrolein BDL 0.25 mg/l 8260B 12/14/14 5 Acrylonitrile BDL 0.050 mg/l 8260B 12/14/14 5 Benzene BDL 0.0050 mg/1 8260B 12/14/14 5 Bromobenzene BDL 0.0050 mg/l 8260B 12/14/14 5 Bromodichloromethane BDL 0.0050 mg/1 8260B 12/14/14 5 Bromoform BDL 0.0050 mg/l 8260B 12/14/14 5 Bromomethane BDL 0.025 mg/1 8260B 12/14/14 5 n-Butylbenzene BDL 0.0050 mg/1 8260B 12/14/14 5 sec-Butylbenzene BDL 0.0050 mg/1 8260B 12/14/14 5 tert-Butylbenzene BDL 0.0050 mg/1 8260B 12/14/14 5 Carbon tetrachloride BDL 0.0050 mg/1 8260B 12/14/14 5 Chlorobenzene BDL 0.0050 mg/1 8260B 12/14/14 5 Chlorodibromomethane BDL 0.0050 mg/l 8260B 12/14/14 5 Chloroethane BDL 0.025 mg/1 8260B 12/14/14 5 2-Chloroethyl vinyl ether BDL 0.25 mg/1 8260B 12/14/14 5 Chloroform BDL 0.025 mg/1 8260B 12/14/14 5 Chloromethane BDL 0.013 mg/1 8260B 12/14/14 5 2-Chlorotoluene BDL 0.0050 mg/1 8260B 12/14/14 5 4-Chlorotoluene BDL 0.0050 mg/1 8260B 12/14/14 5 1,2-Dibromo-3-Chloropropane BDL 0.025 mg/1 8260B 12/14/14 5 1,2-Dibromoethane BDL 0.0050 mg/l 8260B 12/14/14 5 Dibromomethane BDL 0.0050 mg/l 8260B 12/14/14 5 1,2-Dichlorobenzene BDL 0.0050 mg/1 8260B 12/14/14 5 1,3-Dichlorobenzene BDL 0.0050 mg/l 8260B 12/14/14 5 1,4-Dichlorobenzene BDL 0.0050 mg/1 8260B 12/14/14 5 Dichlorodifluoromethane BDL 0.025 mg/1 8260B 12/14/14 5 1,1-Dichloroethane BDL 0.0050 mg/1 8260B 12/14/14 5 1,2-Dichloroethane BDL 0.0050 mg/1 8260B 12/14/14 5 1,1-Dichloroethene BDL 0.0050 mg/1 8260B 12/14/14 5 cis-1,2-Dichloroethene BDL 0.0050 mg/1 8260B 12/14/14 5 trans-1,2-Dichloroethene BDL 0.0050 mg/1 8260B 12/14/14 5 1,2-Dichloropropane BDL 0.0050 mg/1 8260B 12/14/14 5 1,1-Dichloropropene BDL 0.0050 mg/1 8260B 12/14/14 5 1,3-Dichloropropane BDL 0.0050 mg/1 8260B 12/14/14 5 cis-1,3-Dichloropropene BDL 0.0050 mg/1 8260B 12/14/14 5 trans-1,3-Dichloropropene BDL 0.0050 mg/1 8260B 12/14/14 5 2,2-Dichloropropane BDL 0.0050 mg/1 8260B 12/14/14 5 Di-isopropyl ether BDL 0.0050 mg/1 8260B 12/14/14 5 Ethylbenzene BDL 0.0050 mg/l 8260B 12/14/14 5 Hexachloro-1,3-butadiene BDL 0.0050 mg/1 8260B 12/14/14 5 Isopropylbenzene BDL 0.0050 mg/l 8260B 12/14/14 5 p-Isopropyltoluene BDL 0.0050 mg/1 8260B 12/14/14 5 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Page 4 of 15 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 18, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L738346-02 Date Received December 11, 2014 Description Smitty's Cleaners Site ID 26-003 Sample ID MW-3R Project # 60321176 Collected By Guy Allard Collection Date 12/05/14 07:45 Parameter Result Det. Limit Units Method Date Dil. 2-Butanone (MEK) BDL 0.050 mg/l 8260B 12/14/14 5 Methylene Chloride BDL 0.025 mg/1 8260B 12/14/14 5 4-Methyl-2-pentanone (MIBK) BDL 0.050 mg/l 8260B 12/14/14 5 Methyl tert-butyl ether BDL 0.0050 mg/l 8260B 12/14/14 5 Naphthalene BDL 0.025 mg/1 8260B 12/14/14 5 n-Propylbenzene BDL 0.0050 mg/l 8260B 12/14/14 5 Styrene BDL 0.0050 mg/1 8260B 12/14/14 5 1,1,1,2-Tetrachloroethane BDL 0.0050 mg/l 8260B 12/14/14 5 1,1,2,2-Tetrachloroethane BDL 0.0050 mg/1 8260B 12/14/14 5 1,1,2-Trichlorotrifluoroethane BDL 0.0050 mg/1 8260B 12/14/14 5 Tetrachloroethene 1.2 0.050 mg/1 8260B 12/18/14 50 Toluene BDL 0.025 mg/1 8260B 12/14/14 5 1,2,3-Trichlorobenzene BDL 0.0050 mg/1 8260B 12/14/14 5 1,2,4-Trichlorobenzene BDL 0.0050 mg/1 8260B 12/14/14 5 1,1,1-Trichloroethane BDL 0.0050 mg/l 8260B 12/14/14 5 1,1,2-Trichloroethane BDL 0.0050 mg/1 8260B 12/14/14 5 Trichloroethene 0.0023 0.0050 mg/1 8260B 12/14/14 5 Trichlorofluoromethane BDL 0.025 mg/1 8260B 12/14/14 5 1,2,3-Trichloropropane BDL 0.013 mg/1 8260B 12/14/14 5 1,2,4-Trimethylbenzene BDL 0.0050 mg/1 8260B 12/14/14 5 1,2,3-Trimethylbenzene BDL 0.0050 mg/1 8260B 12/14/14 5 1,3,5-Trimethylbenzene BDL 0.0050 mg/1 8260B 12/14/14 5 Vinyl chloride BDL 0.0050 mg/l 8260B 12/14/14 5 Xylenes, Total BDL 0.015 mg/l 8260B 12/14/14 5 Surrogate Recovery Toluene-d8 103. % Rec. 8260B 12/14/14 5 Dibromofluoromethane 85.0 % Rec. 8260B 12/14/14 5 4-Bromofluorobenzene 104. % Rec. 8260B 12/14/14 5 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 12/18/14 15:24 Printed: 12/18/14 15:58 Page 5 of 15 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 18, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L738346-03 Date Received December 11, 2014 Description Smitty's Cleaners Site ID 26-003 Sample ID MW-5 Project # 60321176 Collected By Guy Allard Collection Date 12/05/14 11:00 Parameter Result Det. Limit Units Method Date Dil. Volatile Organics Acetone BDL 5.0 mg/1 8260B 12/14/14 100 Acrolein BDL 5.0 mg/l 8260B 12/14/14 100 Acrylonitrile BDL 1.0 mg/l 8260B 12/14/14 100 Benzene BDL 0.10 mg/1 8260B 12/14/14 100 Bromobenzene BDL 0.10 mg/l 8260B 12/14/14 100 Bromodichloromethane BDL 0.10 mg/1 8260B 12/14/14 100 Bromoform BDL 0.10 mg/l 8260B 12/14/14 100 Bromomethane BDL 0.50 mg/1 8260B 12/14/14 100 n-Butylbenzene BDL 0.10 mg/1 8260B 12/14/14 100 sec-Butylbenzene BDL 0.10 mg/1 8260B 12/14/14 100 tert-Butylbenzene BDL 0.10 mg/1 8260B 12/14/14 100 Carbon tetrachloride BDL 0.10 mg/1 8260B 12/14/14 100 Chlorobenzene BDL 0.10 mg/1 8260B 12/14/14 100 Chlorodibromomethane BDL 0.10 mg/l 8260B 12/14/14 100 Chloroethane BDL 0.50 mg/1 8260B 12/14/14 100 2-Chloroethyl vinyl ether BDL 5.0 mg/1 8260B 12/14/14 100 Chloroform BDL 0.50 mg/1 8260B 12/14/14 100 Chloromethane BDL 0.25 mg/1 8260B 12/14/14 100 2-Chlorotoluene BDL 0.10 mg/1 8260B 12/14/14 100 4-Chlorotoluene BDL 0.10 mg/1 8260B 12/14/14 100 1,2-Dibromo-3-Chloropropane BDL 0.50 mg/1 8260B 12/14/14 100 1,2-Dibromoethane BDL 0.10 mg/l 8260B 12/14/14 100 Dibromomethane BDL 0.10 mg/l 8260B 12/14/14 100 1,2-Dichlorobenzene BDL 0.10 mg/1 8260B 12/14/14 100 1,3-Dichlorobenzene BDL 0.10 mg/l 8260B 12/14/14 100 1,4-Dichlorobenzene BDL 0.10 mg/1 8260B 12/14/14 100 Dichlorodifluoromethane BDL 0.50 mg/1 8260B 12/14/14 100 1,1-Dichloroethane BDL 0.10 mg/1 8260B 12/14/14 100 1,2-Dichloroethane BDL 0.10 mg/1 8260B 12/14/14 100 1,1-Dichloroethene BDL 0.10 mg/1 8260B 12/14/14 100 cis-1,2-Dichloroethene BDL 0.10 mg/1 8260B 12/14/14 100 trans-1,2-Dichloroethene BDL 0.10 mg/1 8260B 12/14/14 100 1,2-Dichloropropane BDL 0.10 mg/1 8260B 12/14/14 100 1,1-Dichloropropene BDL 0.10 mg/1 8260B 12/14/14 100 1,3-Dichloropropane BDL 0.10 mg/1 8260B 12/14/14 100 cis-1,3-Dichloropropene BDL 0.10 mg/1 8260B 12/14/14 100 trans-1,3-Dichloropropene BDL 0.10 mg/1 8260B 12/14/14 100 2,2-Dichloropropane BDL 0.10 mg/1 8260B 12/14/14 100 Di-isopropyl ether BDL 0.10 mg/1 8260B 12/14/14 100 Ethylbenzene BDL 0.10 mg/l 8260B 12/14/14 100 Hexachloro-1,3-butadiene BDL 0.10 mg/1 8260B 12/14/14 100 Isopropylbenzene BDL 0.10 mg/l 8260B 12/14/14 100 p-Isopropyltoluene BDL 0.10 mg/1 8260B 12/14/14 100 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Page 6 of 15 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 18, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L738346-03 Date Received December 11, 2014 Description Smitty's Cleaners Site ID 26-003 Sample ID MW-5 Project # 60321176 Collected By Guy Allard Collection Date 12/05/14 11:00 Parameter Result Det. Limit Units Method Date Dil. 2-Butanone (MEK) BDL 1.0 mg/l 8260B 12/14/14 100 Methylene Chloride BDL 0.50 mg/1 8260B 12/14/14 100 4-Methyl-2-pentanone (MIBK) BDL 1.0 mg/l 8260B 12/14/14 100 Methyl tert-butyl ether BDL 0.10 mg/l 8260B 12/14/14 100 Naphthalene BDL 0.50 mg/1 8260B 12/14/14 100 n-Propylbenzene BDL 0.10 mg/l 8260B 12/14/14 100 Styrene BDL 0.10 mg/1 8260B 12/14/14 100 1,1,1,2-Tetrachloroethane BDL 0.10 mg/l 8260B 12/14/14 100 1,1,2,2-Tetrachloroethane BDL 0.10 mg/1 8260B 12/14/14 100 1,1,2-Trichlorotrifluoroethane BDL 0.10 mg/1 8260B 12/14/14 100 Tetrachloroethene 14. 0.10 mg/1 8260B 12/14/14 100 Toluene BDL 0.50 mg/1 8260B 12/14/14 100 1,2,3-Trichlorobenzene BDL 0.10 mg/1 8260B 12/14/14 100 1,2,4-Trichlorobenzene BDL 0.10 mg/1 8260B 12/14/14 100 1,1,1-Trichloroethane BDL 0.10 mg/l 8260B 12/14/14 100 1,1,2-Trichloroethane BDL 0.10 mg/1 8260B 12/14/14 100 Trichloroethene 0.11 0.10 mg/1 8260B 12/14/14 100 Trichlorofluoromethane BDL 0.50 mg/1 8260B 12/14/14 100 1,2,3-Trichloropropane BDL 0.25 mg/1 8260B 12/14/14 100 1,2,4-Trimethylbenzene BDL 0.10 mg/1 8260B 12/14/14 100 1,2,3-Trimethylbenzene BDL 0.10 mg/1 8260B 12/14/14 100 1,3,5-Trimethylbenzene BDL 0.10 mg/1 8260B 12/14/14 100 Vinyl chloride BDL 0.10 mg/l 8260B 12/14/14 100 Xylenes, Total BDL 0.30 mg/l 8260B 12/14/14 100 Surrogate Recovery Toluene-d8 103. % Rec. 8260B 12/14/14 100 Dibromofluoromethane 88.8 % Rec. 8260B 12/14/14 100 4-Bromofluorobenzene 101. % Rec. 8260B 12/14/14 100 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 12/18/14 15:24 Printed: 12/18/14 15:58 Page 7 of 15 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 18, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L738346-04 Date Received December 11, 2014 Description Smitty's Cleaners Site ID 26-003 Sample ID MW-6 Project # 60321176 Collected By Guy Allard Collection Date 12/05/14 09:10 Parameter Result Det. Limit Units Method Date Dil. Volatile Organics Acetone BDL 0.050 mg/1 8260B 12/14/14 1 Acrolein BDL 0.050 mg/l 8260B 12/14/14 1 Acrylonitrile BDL 0.010 mg/l 8260B 12/14/14 1 Benzene BDL 0.0010 mg/1 8260B 12/14/14 1 Bromobenzene BDL 0.0010 mg/l 8260B 12/14/14 1 Bromodichloromethane BDL 0.0010 mg/1 8260B 12/14/14 1 Bromoform BDL 0.0010 mg/l 8260B 12/14/14 1 Bromomethane BDL 0.0050 mg/1 8260B 12/14/14 1 n-Butylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 sec-Butylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 tert-Butylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 Carbon tetrachloride BDL 0.0010 mg/1 8260B 12/14/14 1 Chlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 Chlorodibromomethane BDL 0.0010 mg/l 8260B 12/14/14 1 Chloroethane BDL 0.0050 mg/1 8260B 12/14/14 1 2-Chloroethyl vinyl ether BDL 0.050 mg/1 8260B 12/14/14 1 Chloroform BDL 0.0050 mg/1 8260B 12/14/14 1 Chloromethane BDL 0.0025 mg/1 8260B 12/14/14 1 2-Chlorotoluene BDL 0.0010 mg/1 8260B 12/14/14 1 4-Chlorotoluene BDL 0.0010 mg/1 8260B 12/14/14 1 1,2-Dibromo-3-Chloropropane BDL 0.0050 mg/1 8260B 12/14/14 1 1,2-Dibromoethane BDL 0.0010 mg/l 8260B 12/14/14 1 Dibromomethane BDL 0.0010 mg/l 8260B 12/14/14 1 1,2-Dichlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,3-Dichlorobenzene BDL 0.0010 mg/l 8260B 12/14/14 1 1,4-Dichlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 Dichlorodifluoromethane BDL 0.0050 mg/1 8260B 12/14/14 1 1,1-Dichloroethane BDL 0.0010 mg/1 8260B 12/14/14 1 1,2-Dichloroethane BDL 0.0010 mg/1 8260B 12/14/14 1 1,1-Dichloroethene BDL 0.0010 mg/1 8260B 12/14/14 1 cis-1,2-Dichloroethene BDL 0.0010 mg/1 8260B 12/14/14 1 trans-1,2-Dichloroethene BDL 0.0010 mg/1 8260B 12/14/14 1 1,2-Dichloropropane BDL 0.0010 mg/1 8260B 12/14/14 1 1,1-Dichloropropene BDL 0.0010 mg/1 8260B 12/14/14 1 1,3-Dichloropropane BDL 0.0010 mg/1 8260B 12/14/14 1 cis-1,3-Dichloropropene BDL 0.0010 mg/1 8260B 12/14/14 1 trans-1,3-Dichloropropene BDL 0.0010 mg/1 8260B 12/14/14 1 2,2-Dichloropropane BDL 0.0010 mg/1 8260B 12/14/14 1 Di-isopropyl ether BDL 0.0010 mg/1 8260B 12/14/14 1 Ethylbenzene BDL 0.0010 mg/l 8260B 12/14/14 1 Hexachloro-1,3-butadiene BDL 0.0010 mg/1 8260B 12/14/14 1 Isopropylbenzene BDL 0.0010 mg/l 8260B 12/14/14 1 p-Isopropyltoluene BDL 0.0010 mg/1 8260B 12/14/14 1 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Page 8 of 15 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 18, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L738346-04 Date Received December 11, 2014 Description Smitty's Cleaners Site ID 26-003 Sample ID MW-6 Project # 60321176 Collected By Guy Allard Collection Date 12/05/14 09:10 Parameter Result Det. Limit Units Method Date Dil. 2-Butanone (MEK) BDL 0.010 mg/l 8260B 12/14/14 1 Methylene Chloride BDL 0.0050 mg/1 8260B 12/14/14 1 4-Methyl-2-pentanone (MIBK) BDL 0.010 mg/l 8260B 12/14/14 1 Methyl tert-butyl ether BDL 0.0010 mg/l 8260B 12/14/14 1 Naphthalene BDL 0.0050 mg/1 8260B 12/14/14 1 n-Propylbenzene BDL 0.0010 mg/l 8260B 12/14/14 1 Styrene BDL 0.0010 mg/1 8260B 12/14/14 1 1,1,1,2-Tetrachloroethane BDL 0.0010 mg/l 8260B 12/14/14 1 1,1,2,2-Tetrachloroethane BDL 0.0010 mg/1 8260B 12/14/14 1 1,1,2-Trichlorotrifluoroethane BDL 0.0010 mg/1 8260B 12/14/14 1 Tetrachloroethene 0.11 0.0010 mg/1 8260B 12/14/14 1 Toluene BDL 0.0050 mg/1 8260B 12/14/14 1 1,2,3-Trichlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,2,4-Trichlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,1,1-Trichloroethane BDL 0.0010 mg/l 8260B 12/14/14 1 1,1,2-Trichloroethane BDL 0.0010 mg/1 8260B 12/14/14 1 Trichloroethene BDL 0.0010 mg/1 8260B 12/14/14 1 Trichlorofluoromethane BDL 0.0050 mg/1 8260B 12/14/14 1 1,2,3-Trichloropropane BDL 0.0025 mg/1 8260B 12/14/14 1 1,2,4-Trimethylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,2,3-Trimethylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,3,5-Trimethylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 Vinyl chloride BDL 0.0010 mg/l 8260B 12/14/14 1 Xylenes, Total BDL 0.0030 mg/l 8260B 12/14/14 1 Surrogate Recovery Toluene-d8 103. % Rec. 8260B 12/14/14 1 Dibromofluoromethane 89.1 % Rec. 8260B 12/14/14 1 4-Bromofluorobenzene 100. % Rec. 8260B 12/14/14 1 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 12/18/14 15:24 Printed: 12/18/14 15:58 Page 9 of 15 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 18, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L738346-05 Date Received December 11, 2014 Description Smitty's Cleaners Site ID 26-003 Sample ID MW-10 Project # 60321176 Collected By Guy Allard Collection Date 12/05/14 16:15 Parameter Result Det. Limit Units Method Date Dil. Volatile Organics Acetone BDL 0.050 mg/1 8260B 12/14/14 1 Acrolein BDL 0.050 mg/l 8260B 12/14/14 1 Acrylonitrile BDL 0.010 mg/l 8260B 12/14/14 1 Benzene BDL 0.0010 mg/1 8260B 12/14/14 1 Bromobenzene BDL 0.0010 mg/l 8260B 12/14/14 1 Bromodichloromethane BDL 0.0010 mg/1 8260B 12/14/14 1 Bromoform BDL 0.0010 mg/l 8260B 12/14/14 1 Bromomethane BDL 0.0050 mg/1 8260B 12/14/14 1 n-Butylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 sec-Butylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 tert-Butylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 Carbon tetrachloride BDL 0.0010 mg/1 8260B 12/14/14 1 Chlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 Chlorodibromomethane BDL 0.0010 mg/l 8260B 12/14/14 1 Chloroethane BDL 0.0050 mg/1 8260B 12/14/14 1 2-Chloroethyl vinyl ether BDL 0.050 mg/1 8260B 12/14/14 1 Chloroform BDL 0.0050 mg/1 8260B 12/14/14 1 Chloromethane BDL 0.0025 mg/1 8260B 12/14/14 1 2-Chlorotoluene BDL 0.0010 mg/1 8260B 12/14/14 1 4-Chlorotoluene BDL 0.0010 mg/1 8260B 12/14/14 1 1,2-Dibromo-3-Chloropropane BDL 0.0050 mg/1 8260B 12/14/14 1 1,2-Dibromoethane BDL 0.0010 mg/l 8260B 12/14/14 1 Dibromomethane BDL 0.0010 mg/l 8260B 12/14/14 1 1,2-Dichlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,3-Dichlorobenzene BDL 0.0010 mg/l 8260B 12/14/14 1 1,4-Dichlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 Dichlorodifluoromethane BDL 0.0050 mg/1 8260B 12/14/14 1 1,1-Dichloroethane BDL 0.0010 mg/1 8260B 12/14/14 1 1,2-Dichloroethane BDL 0.0010 mg/1 8260B 12/14/14 1 1,1-Dichloroethene BDL 0.0010 mg/1 8260B 12/14/14 1 cis-1,2-Dichloroethene BDL 0.0010 mg/1 8260B 12/14/14 1 trans-1,2-Dichloroethene BDL 0.0010 mg/1 8260B 12/14/14 1 1,2-Dichloropropane BDL 0.0010 mg/1 8260B 12/14/14 1 1,1-Dichloropropene BDL 0.0010 mg/1 8260B 12/14/14 1 1,3-Dichloropropane BDL 0.0010 mg/1 8260B 12/14/14 1 cis-1,3-Dichloropropene BDL 0.0010 mg/1 8260B 12/14/14 1 trans-1,3-Dichloropropene BDL 0.0010 mg/1 8260B 12/14/14 1 2,2-Dichloropropane BDL 0.0010 mg/1 8260B 12/14/14 1 Di-isopropyl ether BDL 0.0010 mg/1 8260B 12/14/14 1 Ethylbenzene BDL 0.0010 mg/l 8260B 12/14/14 1 Hexachloro-1,3-butadiene BDL 0.0010 mg/1 8260B 12/14/14 1 Isopropylbenzene BDL 0.0010 mg/l 8260B 12/14/14 1 p-Isopropyltoluene BDL 0.0010 mg/1 8260B 12/14/14 1 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Page 10 of 15 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 18, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L738346-05 Date Received December 11, 2014 Description Smitty's Cleaners Site ID 26-003 Sample ID MW-10 Project # 60321176 Collected By Guy Allard Collection Date 12/05/14 16:15 Parameter Result Det. Limit Units Method Date Dil. 2-Butanone (MEK) BDL 0.010 mg/l 8260B 12/14/14 1 Methylene Chloride BDL 0.0050 mg/1 8260B 12/14/14 1 4-Methyl-2-pentanone (MIBK) BDL 0.010 mg/l 8260B 12/14/14 1 Methyl tert-butyl ether BDL 0.0010 mg/l 8260B 12/14/14 1 Naphthalene BDL 0.0050 mg/1 8260B 12/14/14 1 n-Propylbenzene BDL 0.0010 mg/l 8260B 12/14/14 1 Styrene BDL 0.0010 mg/1 8260B 12/14/14 1 1,1,1,2-Tetrachloroethane BDL 0.0010 mg/l 8260B 12/14/14 1 1,1,2,2-Tetrachloroethane BDL 0.0010 mg/1 8260B 12/14/14 1 1,1,2-Trichlorotrifluoroethane BDL 0.0010 mg/1 8260B 12/14/14 1 Tetrachloroethene 0.00065 0.0010 mg/1 8260B 12/14/14 1 Toluene BDL 0.0050 mg/1 8260B 12/14/14 1 1,2,3-Trichlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,2,4-Trichlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,1,1-Trichloroethane BDL 0.0010 mg/l 8260B 12/14/14 1 1,1,2-Trichloroethane BDL 0.0010 mg/1 8260B 12/14/14 1 Trichloroethene BDL 0.0010 mg/1 8260B 12/14/14 1 Trichlorofluoromethane BDL 0.0050 mg/1 8260B 12/14/14 1 1,2,3-Trichloropropane BDL 0.0025 mg/1 8260B 12/14/14 1 1,2,4-Trimethylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,2,3-Trimethylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,3,5-Trimethylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 Vinyl chloride BDL 0.0010 mg/l 8260B 12/14/14 1 Xylenes, Total BDL 0.0030 mg/l 8260B 12/14/14 1 Surrogate Recovery Toluene-d8 103. % Rec. 8260B 12/14/14 1 Dibromofluoromethane 89.3 % Rec. 8260B 12/14/14 1 4-Bromofluorobenzene 99.7 % Rec. 8260B 12/14/14 1 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 12/18/14 15:24 Printed: 12/18/14 15:58 Page 11 of 15 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 18, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L738346-06 Date Received December 11, 2014 Description Smitty's Cleaners Site ID 26-003 Sample ID IMW-1 Project # 60321176 Collected By Guy Allard Collection Date 12/05/14 17:30 Parameter Result Det. Limit Units Method Date Dil. Volatile Organics Acetone 0.57 0.050 mg/1 8260B 12/14/14 1 Acrolein BDL 0.050 mg/l 8260B 12/14/14 1 Acrylonitrile BDL 0.010 mg/l 8260B 12/14/14 1 Benzene BDL 0.0010 mg/1 8260B 12/14/14 1 Bromobenzene BDL 0.0010 mg/l 8260B 12/14/14 1 Bromodichloromethane 0.00060 0.0010 mg/1 8260B 12/14/14 1 Bromoform BDL 0.0010 mg/l 8260B 12/14/14 1 Bromomethane BDL 0.0050 mg/1 8260B 12/14/14 1 n-Butylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 sec-Butylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 tert-Butylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 Carbon tetrachloride BDL 0.0010 mg/1 8260B 12/14/14 1 Chlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 Chlorodibromomethane 0.00083 0.0010 mg/l 8260B 12/14/14 1 Chloroethane BDL 0.0050 mg/1 8260B 12/14/14 1 2-Chloroethyl vinyl ether BDL 0.050 mg/1 8260B 12/14/14 1 Chloroform 0.0014 0.0050 mg/1 8260B 12/14/14 1 Chloromethane BDL 0.0025 mg/1 8260B 12/14/14 1 2-Chlorotoluene BDL 0.0010 mg/1 8260B 12/14/14 1 4-Chlorotoluene BDL 0.0010 mg/1 8260B 12/14/14 1 1,2-Dibromo-3-Chloropropane BDL 0.0050 mg/1 8260B 12/14/14 1 1,2-Dibromoethane BDL 0.0010 mg/l 8260B 12/14/14 1 Dibromomethane BDL 0.0010 mg/l 8260B 12/14/14 1 1,2-Dichlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,3-Dichlorobenzene BDL 0.0010 mg/l 8260B 12/14/14 1 1,4-Dichlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 Dichlorodifluoromethane BDL 0.0050 mg/1 8260B 12/14/14 1 1,1-Dichloroethane BDL 0.0010 mg/1 8260B 12/14/14 1 1,2-Dichloroethane BDL 0.0010 mg/1 8260B 12/14/14 1 1,1-Dichloroethene BDL 0.0010 mg/1 8260B 12/14/14 1 cis-1,2-Dichloroethene 0.00092 0.0010 mg/1 8260B 12/14/14 1 trans-1,2-Dichloroethene BDL 0.0010 mg/1 8260B 12/14/14 1 1,2-Dichloropropane BDL 0.0010 mg/1 8260B 12/14/14 1 1,1-Dichloropropene BDL 0.0010 mg/1 8260B 12/14/14 1 1,3-Dichloropropane BDL 0.0010 mg/1 8260B 12/14/14 1 cis-1,3-Dichloropropene BDL 0.0010 mg/1 8260B 12/14/14 1 trans-1,3-Dichloropropene BDL 0.0010 mg/1 8260B 12/14/14 1 2,2-Dichloropropane BDL 0.0010 mg/1 8260B 12/14/14 1 Di-isopropyl ether BDL 0.0010 mg/1 8260B 12/14/14 1 Ethylbenzene BDL 0.0010 mg/l 8260B 12/14/14 1 Hexachloro-1,3-butadiene BDL 0.0010 mg/1 8260B 12/14/14 1 Isopropylbenzene BDL 0.0010 mg/l 8260B 12/14/14 1 p-Isopropyltoluene BDL 0.0010 mg/1 8260B 12/14/14 1 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Page 12 of 15 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen December 18, 2014 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L738346-06 Date Received December 11, 2014 Description Smitty's Cleaners Site ID 26-003 Sample ID IMW-1 Project # 60321176 Collected By Guy Allard Collection Date 12/05/14 17:30 Parameter Result Det. Limit Units Method Date Dil. 2-Butanone (MEK) 0.0094 0.010 mg/l 8260B 12/14/14 1 Methylene Chloride BDL 0.0050 mg/1 8260B 12/14/14 1 4-Methyl-2-pentanone (MIBK) BDL 0.010 mg/l 8260B 12/14/14 1 Methyl tert-butyl ether BDL 0.0010 mg/l 8260B 12/14/14 1 Naphthalene BDL 0.0050 mg/1 8260B 12/14/14 1 n-Propylbenzene BDL 0.0010 mg/l 8260B 12/14/14 1 Styrene BDL 0.0010 mg/1 8260B 12/14/14 1 1,1,1,2-Tetrachloroethane BDL 0.0010 mg/l 8260B 12/14/14 1 1,1,2,2-Tetrachloroethane BDL 0.0010 mg/1 8260B 12/14/14 1 1,1,2-Trichlorotrifluoroethane BDL 0.0010 mg/1 8260B 12/14/14 1 Tetrachloroethene 9.5 0.10 mg/1 8260B 12/18/14 100 Toluene BDL 0.0050 mg/1 8260B 12/14/14 1 1,2,3-Trichlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,2,4-Trichlorobenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,1,1-Trichloroethane BDL 0.0010 mg/l 8260B 12/14/14 1 1,1,2-Trichloroethane BDL 0.0010 mg/1 8260B 12/14/14 1 Trichloroethene 0.0044 0.0010 mg/1 8260B 12/14/14 1 Trichlorofluoromethane BDL 0.0050 mg/1 8260B 12/14/14 1 1,2,3-Trichloropropane BDL 0.0025 mg/1 8260B 12/14/14 1 1,2,4-Trimethylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,2,3-Trimethylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 1,3,5-Trimethylbenzene BDL 0.0010 mg/1 8260B 12/14/14 1 Vinyl chloride BDL 0.0010 mg/l 8260B 12/14/14 1 Xylenes, Total BDL 0.0030 mg/l 8260B 12/14/14 1 Surrogate Recovery Toluene-d8 103. % Rec. 8260B 12/14/14 1 Dibromofluoromethane 90.2 % Rec. 8260B 12/14/14 1 4-Bromofluorobenzene 99.9 % Rec. 8260B 12/14/14 1 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 12/18/14 15:24 Printed: 12/18/14 15:59 Page 13 of 15 Attachment A List of Analytes with QC Qualifiers Sample Work Sample Run Number Group Type Analyte ID Qualifier L738346-01 WG759523 SAMP Trichloroethene R3010457 J L738346-02 WG759523 SAMP Trichloroethene R3010457 J L738346-05 WG759523 SAMP Tetrachloroethene R3010457 J L738346-06 WG759523 SAMP Bromodichloromethane R3010457 J WG759523 SAMP Chlorodibromomethane R3010457 J WG759523 SAMP Chloroform R3010457 J WG759523 SAMP cis-1,2-Dichloroethene R3010457 J WG759523 SAMP 2-Butanone (MEK) R3010457 J Page 14 of 15 Attachment B Explanation of QC Qualifier Codes Qualifier Meaning J (EPA) - Estimated value below the lowest calibration point. Confidence correlates with concentration. Qualifier Report Information ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical results. Each qualifier is designated in the qualifier explanation as either EPA or ESC. Data qualifiers are intended to provide the ESC client with more detailed information concerning the potential bias of reported data. Because of the wide range of constituents and variety of matrices incorporated by most EPA methods,it is common for some compounds to fall outside of established ranges. These exceptions are evaluated and all reported data is valid and useable "unless qualified as 'R' (Rejected) ." Definitions Accuracy - The relationship of the observed value of a known sample to the true value of a known sample. Represented by percent recovery and relevant to samples such as: control samples, matrix spike recoveries, surrogate recoveries, etc. Precision - The agreement between a set of samples or between duplicate samples. Relates to how close together the results are and is represented by Relative Percent Differrence. Surrogate - Organic compounds that are similar in chemical composition, extraction, and chromotography to analytes of interest. The surrogates are used to determine the probable response of the group of analytes that are chem- ically related to the surrogate compound. Surrogates are added to the sample and carried through all stages of preparation and analyses. TIC - Tentatively Identified Compound: Compounds detected in samples that are not target compounds, internal standards, system monitoring compounds, or surrogates. Page 15 of 15 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 l.•A 0 S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 Mr. Matthew Allen AECOM 701 Corporate Center Drive, Suite 475 Raleigh, NC 27607 Report Summary Wednesday January 07, 2015 Report Number: L741155 Samples Received: 12/30/14 Client Project: 60321176.E02 Description: Smitty Cleaners The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Entire Report Reviewed By: Terrie Fudg ESC resentative Laboratory Certification Numbers A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197, FL - E87487, GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016, NC - ENV375/DW21704/BI0041, ND - R-140. NJ - TN002, NJ NELAP - TN002, SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612, MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1, TX - T104704245-11-3, OK - 9915, PA - 68-02979, IA Lab #364, EPA - TNO02 Accreditation is only applicable to the test methods specified on each scope of accreditation held by ESC Lab Sciences. This report may not be reproduced, except in full, without written approval from ESC Lab Sciences. Where applicable, sampling conducted by ESC is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. Page 1 of 7 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen January 07, 2015 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L741155-01 Date Received December 30, 2014 Description Smitty Cleaners Site ID DSCA 26-0003 Sample ID IMW-1 Project # 60321176.E02 Collected By A.C. Whichard Collection Date 12/29/14 11:30 Parameter Result Det. Limit Units Qualifier Method Date Dil. Chloride 11000 1000 ug/l 9056MOD O1/05/15 1 Manganese 90. 10. ug/l 6010C 12/30/14 1 Potassium 140000 5000 ug/l V 6010C 12/30/14 5 Sodium 7700 1000 ug/1 6010C 12/30/14 1 Volatile Organics Acetone 110 500 ug/l J 8260B O1/02/15 10 Acrolein BDL 500 ug/1 8260B O1/02/15 10 Acrylonitrile BDL 100 ug/l 8260B O1/02/15 10 Benzene BDL 10. ug/1 8260B O1/02/15 10 Bromobenzene BDL 10. ug/l 8260B O1/02/15 10 Bromodichloromethane BDL 10. ug/1 8260B O1/02/15 10 Bromoform BDL 10. ug/1 8260B O1/02/15 10 Bromomethane BDL 50. ug/l 8260B O1/02/15 10 n-Butylbenzene BDL 10. ug/1 8260B O1/02/15 10 sec-Butylbenzene BDL 10. ug/l 8260B O1/02/15 10 tert-Butylbenzene BDL 10. ug/1 8260B O1/02/15 10 Carbon tetrachloride BDL 10. ug/l 8260B O1/02/15 10 Chlorobenzene BDL 10. ug/1 8260B O1/02/15 10 Chlorodibromomethane BDL 10. ug/l 8260B O1/02/15 10 Chloroethane BDL 50. ug/1 8260B O1/02/15 10 2-Chloroethyl vinyl ether BDL 500 ug/l 8260B O1/02/15 10 Chloroform BDL 50. ug/l 8260B O1/02/15 10 Chloromethane BDL 25. ug/1 8260B O1/02/15 10 2-Chlorotoluene BDL 10. ug/l 8260B O1/02/15 10 4-Chlorotoluene BDL 10. ug/1 8260B O1/02/15 10 1,2-Dibromo-3-Chloropropane BDL 50. ug/l 8260B O1/02/15 10 1,2-Dibromoethane BDL 10. ug/1 8260B O1/02/15 10 Dibromomethane BDL 10. ug/l 8260B O1/02/15 10 1,2-Dichlorobenzene BDL 10. ug/1 8260B O1/02/15 10 1,3-Dichlorobenzene BDL 10. ug/l 8260B O1/02/15 10 1,4-Dichlorobenzene BDL 10. ug/1 8260B O1/02/15 10 Dichlorodifluoromethane BDL 50. ug/l 8260B O1/02/15 10 1,1-Dichloroethane BDL 10. ug/l 8260B O1/02/15 10 1,2-Dichloroethane BDL 10. ug/1 8260B O1/02/15 10 1,1-Dichloroethene BDL 10. ug/l 8260B O1/02/15 10 cis-1,2-Dichloroethene 3.5 10. ug/1 J 8260B O1/02/15 10 trans-1,2-Dichloroethene BDL 10. ug/l 8260B O1/02/15 10 1,2-Dichloropropane BDL 10. ug/1 8260B 01/02/15 10 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Laboratory Certification Numbers: AIHA - 100789, AL - 40660, CA - I-2327, CT- PH-0197, FL - E87487, GA - 923, IN - C-TN-01 KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140, SC - 84004, TN - 2006, VA - 00109, WV - 233 AZ -0612, MN - 047-999-395, NY - 11742, NJ - TN002, WI - 998093910 Page 2 of 7 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen January 07, 2015 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L741155-01 Date Received December 30, 2014 Description Smitty Cleaners Site ID DSCA 26-0003 Sample ID IMW-1 Project # 60321176.E02 Collected By A.C. Whichard Collection Date 12/29/14 11:30 Parameter Result Det. Limit Units Qualifier Method Date Dil. 1,1-Dichloropropene BDL 10. ug/l 8260B O1/02/15 10 1,3-Dichloropropane BDL 10. ug/1 8260B O1/02/15 10 cis-1,3-Dichloropropene BDL 10. ug/l 8260B O1/02/15 10 trans-1,3-Dichloropropene BDL 10. ug/l 8260B O1/02/15 10 2,2-Dichloropropane BDL 10. ug/1 8260B O1/02/15 10 Di-isopropyl ether BDL 10. ug/l 8260B O1/02/15 10 Ethylbenzene BDL 10. ug/1 8260B O1/02/15 10 Hexachloro-1,3-butadiene BDL 10. ug/l 8260B O1/02/15 10 Isopropylbenzene BDL 10. ug/1 8260B O1/02/15 10 p-Isopropyltoluene BDL 10. ug/l 8260B O1/02/15 10 2-Butanone (MEK) BDL 100 ug/1 8260B O1/02/15 10 Methylene Chloride BDL 50. ug/l 8260B O1/02/15 10 4-Methyl-2-pentanone (MIBK) BDL 100 ug/1 8260B O1/02/15 10 Methyl tert-butyl ether BDL 10. ug/1 8260B O1/02/15 10 Naphthalene BDL 50. ug/l 8260B O1/02/15 10 n-Propylbenzene BDL 10. ug/1 8260B O1/02/15 10 Styrene BDL 10. ug/l 8260B O1/02/15 10 1,1,1,2-Tetrachloroethane BDL 10. ug/1 8260B O1/02/15 10 1,1,2,2-Tetrachloroethane BDL 10. ug/l 8260B O1/02/15 10 1,1,2-Trichlorotrifluoroethane BDL 10. ug/1 8260B O1/02/15 10 Tetrachloroethene 13000 1000 ug/l 8260B O1/07/15 1000 Toluene BDL 50. ug/1 8260B O1/02/15 10 1,2,3-Trichlorobenzene BDL 10. ug/l 8260B O1/02/15 10 1,2,4-Trichlorobenzene BDL 10. ug/l 8260B O1/02/15 10 1,1,1-Trichloroethane BDL 10. ug/1 8260B O1/02/15 10 1,1,2-Trichloroethane BDL 10. ug/l 8260B O1/02/15 10 Trichloroethene 15. 10. ug/1 8260B O1/02/15 10 Trichlorofluoromethane BDL 50. ug/l 8260B O1/02/15 10 1,2,3-Trichloropropane BDL 25. ug/1 8260B O1/02/15 10 1,2,4-Trimethylbenzene BDL 10. ug/l 8260B O1/02/15 10 1,2,3-Trimethylbenzene BDL 10. ug/1 8260B O1/02/15 10 1,3,5-Trimethylbenzene BDL 10. ug/l 8260B O1/02/15 10 Vinyl chloride BDL 10. ug/1 8260B O1/02/15 10 Xylenes, Total BDL 30. ug/l 8260B O1/02/15 10 Surrogate Recovery Toluene-d8 109. % Rec. 8260B O1/02/15 10 Dibromofluoromethane 100. % Rec. 8260B O1/02/15 10 4-Bromofluorobenzene 109. % Rec. 8260B O1/02/15 10 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Laboratory Certification Numbers: AIHA - 100789, AL - 40660, CA - I-2327, CT- PH-0197, FL - E87487, GA - 923, IN - C-TN-01 KY - 90010, KYUST - 0016, NC - ENV375,DW21704, ND - R-140, SC - 84004, TN - 2006, VA - 00109, WV - 233 AZ -0612, MN - 047-999-395, NY - 11742, NJ - TN002, WI - 998093910 Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 01/07/15 10:11 Printed: 01/07/15 11:12 Page 3 of 7 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen January 07, 2015 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L741155-02 Date Received December 30, 2014 Description Smitty Cleaners Site ID DSCA 26-0003 Sample ID MW-33 Project # 60321176.E02 Collected By A.C. Whichard Collection Date 12/29/14 12:00 Parameter Result Det. Limit Units Method Date Dil. Volatile Organics Acetone BDL 0.50 mg/1 8260B O1/02/15 10 Acrolein BDL 0.50 mg/l 8260B O1/02/15 10 Acrylonitrile BDL 0.10 mg/l 8260B O1/02/15 10 Benzene BDL 0.010 mg/1 8260B O1/02/15 10 Bromobenzene BDL 0.010 mg/l 8260B O1/02/15 10 Bromodichloromethane BDL 0.010 mg/1 8260B O1/02/15 10 Bromoform BDL 0.010 mg/l 8260B O1/02/15 10 Bromomethane BDL 0.050 mg/1 8260B O1/02/15 10 n-Butylbenzene BDL 0.010 mg/1 8260B O1/02/15 10 sec-Butylbenzene BDL 0.010 mg/1 8260B O1/02/15 10 tert-Butylbenzene BDL 0.010 mg/1 8260B O1/02/15 10 Carbon tetrachloride BDL 0.010 mg/1 8260B O1/02/15 10 Chlorobenzene BDL 0.010 mg/1 8260B O1/02/15 10 Chlorodibromomethane BDL 0.010 mg/l 8260B O1/02/15 10 Chloroethane BDL 0.050 mg/1 8260B O1/02/15 10 2-Chloroethyl vinyl ether BDL 0.50 mg/1 8260B O1/02/15 10 Chloroform 0.0034 0.050 mg/1 8260B O1/02/15 10 Chloromethane BDL 0.025 mg/1 8260B O1/02/15 10 2-Chlorotoluene BDL 0.010 mg/1 8260B O1/02/15 10 4-Chlorotoluene BDL 0.010 mg/1 8260B O1/02/15 10 1,2-Dibromo-3-Chloropropane BDL 0.050 mg/1 8260B O1/02/15 10 1,2-Dibromoethane BDL 0.010 mg/l 8260B O1/02/15 10 Dibromomethane BDL 0.010 mg/l 8260B O1/02/15 10 1,2-Dichlorobenzene BDL 0.010 mg/1 8260B O1/02/15 10 1,3-Dichlorobenzene BDL 0.010 mg/l 8260B O1/02/15 10 1,4-Dichlorobenzene BDL 0.010 mg/1 8260B O1/02/15 10 Dichlorodifluoromethane BDL 0.050 mg/1 8260B O1/02/15 10 1,1-Dichloroethane BDL 0.010 mg/1 8260B O1/02/15 10 1,2-Dichloroethane BDL 0.010 mg/1 8260B O1/02/15 10 1,1-Dichloroethene BDL 0.010 mg/1 8260B O1/02/15 10 cis-1,2-Dichloroethene 0.0074 0.010 mg/1 8260B O1/02/15 10 trans-1,2-Dichloroethene BDL 0.010 mg/1 8260B O1/02/15 10 1,2-Dichloropropane BDL 0.010 mg/1 8260B O1/02/15 10 1,1-Dichloropropene BDL 0.010 mg/1 8260B O1/02/15 10 1,3-Dichloropropane BDL 0.010 mg/1 8260B O1/02/15 10 cis-1,3-Dichloropropene BDL 0.010 mg/1 8260B O1/02/15 10 trans-1,3-Dichloropropene BDL 0.010 mg/1 8260B O1/02/15 10 2,2-Dichloropropane BDL 0.010 mg/l 8260B O1/02/15 10 Di-isopropyl ether BDL 0.010 mg/1 8260B 01/02/15 10 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Page 4 of 7 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen January 07, 2015 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L741155-02 Date Received December 30, 2014 Description Smitty Cleaners Site ID DSCA 26-0003 Sample ID MW-33 Project # 60321176.E02 Collected By A.C. Whichard Collection Date 12/29/14 12:00 Parameter Result Det. Limit Units Method Date Dil. Ethylbenzene BDL 0.010 mg/l 8260B O1/02/15 10 Hexachloro-1,3-butadiene BDL 0.010 mg/1 8260B O1/02/15 10 Isopropylbenzene BDL 0.010 mg/l 8260B O1/02/15 10 p-Isopropyltoluene BDL 0.010 mg/l 8260B O1/02/15 10 2-Butanone (MEK) BDL 0.10 mg/1 8260B O1/02/15 10 Methylene Chloride BDL 0.050 mg/l 8260B O1/02/15 10 4-Methyl-2-pentanone (MIBK) BDL 0.10 mg/1 8260B O1/02/15 10 Methyl tert-butyl ether BDL 0.010 mg/l 8260B O1/02/15 10 Naphthalene BDL 0.050 mg/1 8260B O1/02/15 10 n-Propylbenzene BDL 0.010 mg/1 8260B O1/02/15 10 Styrene BDL 0.010 mg/1 8260B O1/02/15 10 1,1,1,2-Tetrachloroethane BDL 0.010 mg/1 8260B O1/02/15 10 1,1,2,2-Tetrachloroethane BDL 0.010 mg/1 8260B O1/02/15 10 1,1,2-Trichlorotrifluoroethane BDL 0.010 mg/1 8260B O1/02/15 10 Tetrachloroethene 32. 1.0 mg/l 8260B O1/07/15 1000 Toluene BDL 0.050 mg/1 8260B O1/02/15 10 1,2,3-Trichlorobenzene BDL 0.010 mg/1 8260B O1/02/15 10 1,2,4-Trichlorobenzene BDL 0.010 mg/1 8260B O1/02/15 10 1,1,1-Trichloroethane BDL 0.010 mg/1 8260B O1/02/15 10 1,1,2-Trichloroethane BDL 0.010 mg/1 8260B O1/02/15 10 Trichloroethene 0.025 0.010 mg/1 8260B O1/02/15 10 Trichlorofluoromethane BDL 0.050 mg/1 8260B O1/02/15 10 1,2,3-Trichloropropane BDL 0.025 mg/l 8260B O1/02/15 10 1,2,4-Trimethylbenzene BDL 0.010 mg/l 8260B O1/02/15 10 1,2,3-Trimethylbenzene BDL 0.010 mg/1 8260B O1/02/15 10 1,3,5-Trimethylbenzene BDL 0.010 mg/l 8260B O1/02/15 10 Vinyl chloride BDL 0.010 mg/1 8260B O1/02/15 10 Xylenes, Total BDL 0.030 mg/l 8260B O1/02/15 10 Surrogate Recovery Toluene-d8 109. % Rec. 8260B O1/02/15 10 Dibromofluoromethane 100. % Rec. 8260B O1/02/15 10 4-Bromofluorobenzene ill. % Rec. 8260B O1/02/15 10 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 01/07/15 10:11 Printed: 01/07/15 11:12 Page 5 of 7 Attachment A List of Analytes with QC Qualifiers Sample Work Sample Run Number Group Type Analyte ID Qualifier L741155-01 WG762568 SAMP Potassium R3012736 V WG762800 SAMP Acetone R3013043 J WG762800 SAMP cis-1,2-Dichloroethene R3013043 J L741155-02 WG762800 SAMP Chloroform R3013043 J WG762800 SAMP cis-1,2-Dichloroethene R3013043 J Page 6 of 7 Attachment B Explanation of QC Qualifier Codes Qualifier Meaning J (EPA) - Estimated value below the lowest calibration point. Confidence correlates with concentration. V (ESC) - Additional QC Info: The sample concentration is too high to evaluate accurate spike recoveries. Qualifier Report Information ESC utilizes sample and result qualifiers as set forth by the EPA Contract Laboratory Program and as required by most certifying bodies including NELAC. In addition to the EPA qualifiers adopted by ESC, we have implemented ESC qualifiers to provide more information pertaining to our analytical results. Each qualifier is designated in the qualifier explanation as either EPA or ESC. Data qualifiers are intended to provide the ESC client with more detailed information concerning the potential bias of reported data. Because of the wide range of constituents and variety of matrices incorporated by most EPA methods,it is common for some compounds to fall outside of established ranges. These exceptions are evaluated and all reported data is valid and useable "unless qualified as 'R' (Rejected) ." Definitions Accuracy - The relationship of the observed value of a known sample to the true value of a known sample. Represented by percent recovery and relevant to samples such as: control samples, matrix spike recoveries, surrogate recoveries, etc. Precision - The agreement between a set of samples or between duplicate samples. Relates to how close together the results are and is represented by Relative Percent Differrence. Surrogate - Organic compounds that are similar in chemical composition, extraction, and chromotography to analytes of interest. The surrogates are used to determine the probable response of the group of analytes that are chem- ically related to the surrogate compound. Surrogates are added to the sample and carried through all stages of preparation and analyses. TIC - Tentatively Identified Compound: Compounds detected in samples that are not target compounds, internal standards, system monitoring compounds, or surrogates. Page 7 of 7 C ompany Name/Address Billing Information: — Analysis/Container/Preservative Chain of Custody Pat@ . g AECOM quote st: ENSRNC102913S *ESC 701 Corporate Center Drive Suite 475 Raleigh , NC 27607 i - - - mou.1Jeaoonw o> o Report to: Email To �Mountm+Kt TF+an7a PNww 61 S-75a-SlSs Mathew Allen mathew.allen@aecom.com Men+:aa1767-S/S9 >. City/State — Fa.615-tst sae ❑e . Project Smitty's Cleaners Description: Collected QL V l a ✓ 7 Client Project a Lab Protect p d Phone 919-872-6600 0 8031 / T Fax: $6 a 1 a Collected by(pnnt): Site/Facility IU tl f-o a I _ : p Acctnum:ENSRDSCA E C Template: Col na.ur Rush? (Lab MUST Be Notified) Date Results Needed in o g L � PrNo m: e —Same Day__......................200% r-TT CI^ - _, fV � :9 TSR: _Next Day ............-.........._..300% Email?_No,xyes 00 .. Z Immediately _Two Day ......................_..Sox X Cooler: _ .25% FAX? No Yes Igo to � i Packed on Ice N_ Y Three Day ...................._... — — of U I C Y Shipped Vw: � L � Sample ID Comp/Grab Matra O>• Depth Date Time :ntrs U sem/com+mmant Samok+I�o:y1 61 _ I •Matrix: SS-Soil GW-Groundwater WW-WasteWater DW-Drinking Water OT-Other— pH _ Temp Remarks: Flow Other_ Hold M _ _I D Reli 6-6y:ISipnitureM_— Date. Tim�ej: d by:(Signature) :-mples returned wa. ❑UPS` — Conditions ❑ ❑ 1 (lab use only) /5 /7 fedEx Courier ❑ Relinquished by (Signature) Date- Ti Received by:(Signature) Temp: 'C 6oltles Received: .((� _ s S COC Seal Intact: ✓_Y _N _NA Re sh (Signature) _ Late: Time: Received for b to Signature) Date: 'rime: —_ pH Checked: i NCr: 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 l.•A 0 S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 Mr. Matthew Allen AECOM 701 Corporate Center Drive, Suite 475 Raleigh, NC 27607 Report Summary Tuesday January 20, 2015 Report Number: L743794 Samples Received: 01/16/15 Client Project: 60321176 Description: Smitty Cleaners The analytical results in this report are based upon information supplied by you, the client, and are for your exclusive use. If you have any questions regarding this data package, please do not hesitate to call. Entire Report Reviewed By: Terrie Fudg ESC resentative Laboratory Certification Numbers A2LA - 1461-01, AIHA - 100789, AL - 40660, CA - 01157CA, CT - PH-0197, FL - E87487, GA - 923, IN - C-TN-01, KY - 90010, KYUST - 0016, NC - ENV375/DW21704/BI0041, ND - R-140. NJ - TN002, NJ NELAP - TN002, SC - 84004, TN - 2006, VA - 460132, WV - 233, AZ - 0612, MN - 047-999-395, NY - 11742, WI - 998093910, NV - TN000032011-1, TX - T104704245-11-3, OK - 9915, PA - 68-02979, IA Lab #364, EPA - TNO02 Accreditation is only applicable to the test methods specified on each scope of accreditation held by ESC Lab Sciences. This report may not be reproduced, except in full, without written approval from ESC Lab Sciences. Where applicable, sampling conducted by ESC is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. Page 1 of 14 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen January 20, 2015 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L743794-01 Date Received January 16, 2015 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-33 Project # 60321176 Collected By A.C. Whichard Collection Date 01/15/15 10:20 Parameter Result Det. Limit Units Method Date Dil. Volatile Organics Acetone BDL 10. mg/1 8260B O1/17/15 200 Acrolein BDL 10. mg/l 8260B O1/17/15 200 Acrylonitrile BDL 2.0 mg/l 8260B O1/17/15 200 Benzene BDL 0.20 mg/1 8260B O1/17/15 200 Bromobenzene BDL 0.20 mg/l 8260B O1/17/15 200 Bromodichloromethane BDL 0.20 mg/1 8260B O1/17/15 200 Bromoform BDL 0.20 mg/l 8260B O1/17/15 200 Bromomethane BDL 1.0 mg/1 8260B O1/17/15 200 n-Butylbenzene BDL 0.20 mg/1 8260B O1/17/15 200 sec-Butylbenzene BDL 0.20 mg/1 8260B O1/17/15 200 tert-Butylbenzene BDL 0.20 mg/1 8260B O1/17/15 200 Carbon tetrachloride BDL 0.20 mg/1 8260B O1/17/15 200 Chlorobenzene BDL 0.20 mg/1 8260B O1/17/15 200 Chlorodibromomethane BDL 0.20 mg/l 8260B O1/17/15 200 Chloroethane BDL 1.0 mg/1 8260B O1/17/15 200 2-Chloroethyl vinyl ether BDL 10. mg/1 8260B O1/17/15 200 Chloroform BDL 1.0 mg/1 8260B O1/17/15 200 Chloromethane BDL 0.50 mg/1 8260B O1/17/15 200 2-Chlorotoluene BDL 0.20 mg/1 8260B O1/17/15 200 4-Chlorotoluene BDL 0.20 mg/1 8260B O1/17/15 200 1,2-Dibromo-3-Chloropropane BDL 1.0 mg/1 8260B O1/17/15 200 1,2-Dibromoethane BDL 0.20 mg/l 8260B O1/17/15 200 Dibromomethane BDL 0.20 mg/l 8260B O1/17/15 200 1,2-Dichlorobenzene BDL 0.20 mg/1 8260B O1/17/15 200 1,3-Dichlorobenzene BDL 0.20 mg/l 8260B O1/17/15 200 1,4-Dichlorobenzene BDL 0.20 mg/1 8260B O1/17/15 200 Dichlorodifluoromethane BDL 1.0 mg/1 8260B O1/17/15 200 1,1-Dichloroethane BDL 0.20 mg/1 8260B O1/17/15 200 1,2-Dichloroethane BDL 0.20 mg/1 8260B O1/17/15 200 1,1-Dichloroethene BDL 0.20 mg/1 8260B O1/17/15 200 cis-1,2-Dichloroethene BDL 0.20 mg/1 8260B O1/17/15 200 trans-1,2-Dichloroethene BDL 0.20 mg/1 8260B O1/17/15 200 1,2-Dichloropropane BDL 0.20 mg/1 8260B O1/17/15 200 1,1-Dichloropropene BDL 0.20 mg/1 8260B O1/17/15 200 1,3-Dichloropropane BDL 0.20 mg/1 8260B O1/17/15 200 cis-1,3-Dichloropropene BDL 0.20 mg/1 8260B O1/17/15 200 trans-1,3-Dichloropropene BDL 0.20 mg/1 8260B O1/17/15 200 2,2-Dichloropropane BDL 0.20 mg/1 8260B O1/17/15 200 Di-isopropyl ether BDL 0.20 mg/1 8260B 01/17/15 200 Ethylbenzene BDL 0.20 mg/l 8260B O1/17/15 200 Hexachloro-1,3-butadiene BDL 0.20 mg/1 8260B O1/17/15 200 Isopropylbenzene BDL 0.20 mg/l 8260B O1/17/15 200 p-Isopropyltoluene BDL 0.20 mg/1 8260B O1/17/15 200 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Page 2 of 14 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen January 20, 2015 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L743794-01 Date Received January 16, 2015 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID MW-33 Project # 60321176 Collected By A.C. Whichard Collection Date 01/15/15 10:20 Parameter Result Det. Limit Units Method Date Dil. 2-Butanone (MEK) BDL 2.0 mg/l 8260B O1/17/15 200 Methylene Chloride BDL 1.0 mg/1 8260B O1/17/15 200 4-Methyl-2-pentanone (MIBK) BDL 2.0 mg/l 8260B O1/17/15 200 Methyl tert-butyl ether BDL 0.20 mg/l 8260B O1/17/15 200 Naphthalene BDL 1.0 mg/1 8260B O1/17/15 200 n-Propylbenzene BDL 0.20 mg/l 8260B O1/17/15 200 Styrene BDL 0.20 mg/1 8260B O1/17/15 200 1,1,1,2-Tetrachloroethane BDL 0.20 mg/l 8260B O1/17/15 200 1,1,2,2-Tetrachloroethane BDL 0.20 mg/1 8260B O1/17/15 200 1,1,2-Trichlorotrifluoroethane BDL 0.20 mg/1 8260B O1/17/15 200 Tetrachloroethene 34. 0.20 mg/1 8260B O1/17/15 200 Toluene BDL 1.0 mg/1 8260B O1/17/15 200 1,2,3-Trichlorobenzene BDL 0.20 mg/1 8260B O1/17/15 200 1,2,4-Trichlorobenzene BDL 0.20 mg/1 8260B O1/17/15 200 1,1,1-Trichloroethane BDL 0.20 mg/l 8260B O1/17/15 200 1,1,2-Trichloroethane BDL 0.20 mg/1 8260B O1/17/15 200 Trichloroethene BDL 0.20 mg/1 8260B O1/17/15 200 Trichlorofluoromethane BDL 1.0 mg/1 8260B O1/17/15 200 1,2,3-Trichloropropane BDL 0.50 mg/1 8260B O1/17/15 200 1,2,4-Trimethylbenzene BDL 0.20 mg/1 8260B O1/17/15 200 1,2,3-Trimethylbenzene BDL 0.20 mg/1 8260B O1/17/15 200 1,3,5-Trimethylbenzene BDL 0.20 mg/1 8260B O1/17/15 200 Vinyl chloride BDL 0.20 mg/l 8260B O1/17/15 200 Xylenes, Total BDL 0.60 mg/l 8260B O1/17/15 200 Surrogate Recovery Toluene-d8 103. % Rec. 8260B O1/17/15 1 Dibromofluoromethane 99.7 % Rec. 8260B O1/17/15 1 4-Bromofluorobenzene 104. % Rec. 8260B O1/17/15 1 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 01/20/15 10:08 Printed: 01/20/15 10:08 Page 3 of 14 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen January 20, 2015 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L743794-02 Date Received January 16, 2015 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID IMW-1 Project # 60321176 Collected By A.C. Whichard Collection Date 01/15/15 10:45 Parameter Result Det. Limit Units Method Date Dil. Chloride 9.1 1.0 mg/l 9056MOD O1/19/15 1 Magnesium 2.0 1.0 mg/l 6010B O1/18/15 1 Potassium 110 1.0 mg/l 6010B O1/18/15 1 Sodium 7.5 1.0 mg/1 6010B O1/18/15 1 Volatile Organics Acetone BDL 5.0 mg/l 8260B O1/17/15 100 Acrolein BDL 5.0 mg/1 8260B O1/17/15 100 Acrylonitrile BDL 1.0 mg/1 8260B O1/17/15 100 Benzene BDL 0.10 mg/1 8260B O1/17/15 100 Bromobenzene BDL 0.10 mg/1 8260B O1/17/15 100 Bromodichloromethane BDL 0.10 mg/1 8260B O1/17/15 100 Bromoform BDL 0.10 mg/1 8260B O1/17/15 100 Bromomethane BDL 0.50 mg/l 8260B O1/17/15 100 n-Butylbenzene BDL 0.10 mg/1 8260B O1/17/15 100 sec-Butylbenzene BDL 0.10 mg/1 8260B O1/17/15 100 tert-Butylbenzene BDL 0.10 mg/1 8260B O1/17/15 100 Carbon tetrachloride BDL 0.10 mg/1 8260B O1/17/15 100 Chlorobenzene BDL 0.10 mg/1 8260B O1/17/15 100 Chlorodibromomethane BDL 0.10 mg/1 8260B O1/17/15 100 Chloroethane BDL 0.50 mg/1 8260B O1/17/15 100 2-Chloroethyl vinyl ether BDL 5.0 mg/l 8260B O1/17/15 100 Chloroform BDL 0.50 mg/l 8260B O1/17/15 100 Chloromethane BDL 0.25 mg/1 8260B O1/17/15 100 2-Chlorotoluene BDL 0.10 mg/l 8260B O1/17/15 100 4-Chlorotoluene BDL 0.10 mg/1 8260B O1/17/15 100 1,2-Dibromo-3-Chloropropane BDL 0.50 mg/1 8260B O1/17/15 100 1,2-Dibromoethane BDL 0.10 mg/1 8260B O1/17/15 100 Dibromomethane BDL 0.10 mg/1 8260B O1/17/15 100 1,2-Dichlorobenzene BDL 0.10 mg/1 8260B O1/17/15 100 1,3-Dichlorobenzene BDL 0.10 mg/1 8260B O1/17/15 100 1,4-Dichlorobenzene BDL 0.10 mg/1 8260B O1/17/15 100 Dichlorodifluoromethane BDL 0.50 mg/1 8260B O1/17/15 100 1,1-Dichloroethane BDL 0.10 mg/1 8260B O1/17/15 100 1,2-Dichloroethane BDL 0.10 mg/1 8260B O1/17/15 100 1,1-Dichloroethene BDL 0.10 mg/1 8260B O1/17/15 100 cis-1,2-Dichloroethene BDL 0.10 mg/1 8260B O1/17/15 100 trans-1,2-Dichloroethene BDL 0.10 mg/1 8260B O1/17/15 100 1,2-Dichloropropane BDL 0.10 mg/1 8260B 01/17/15 100 1,1-Dichloropropene BDL 0.10 mg/l 8260B O1/17/15 100 1,3-Dichloropropane BDL 0.10 mg/1 8260B O1/17/15 100 cis-1,3-Dichloropropene BDL 0.10 mg/l 8260B O1/17/15 100 trans-1,3-Dichloropropene BDL 0.10 mg/1 8260B O1/17/15 100 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Page 4 of 14 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •AB S•C•fE•N C=E•S Tax I.D. 62-0814289 Est. 1970 REPORT OF ANALYSIS Mr. Matthew Allen January 20, 2015 AECOM 701 Corporate Center Drive, Suite 4 Raleigh, NC 27607 ESC Sample # L743794-02 Date Received January 16, 2015 Description Smitty's Cleaners Site ID DSCA 26-0003 Sample ID IMW-1 Project # 60321176 Collected By A.C. Whichard Collection Date 01/15/15 10:45 Parameter Result Det. Limit Units Method Date Dil. 2,2-Dichloropropane BDL 0.10 mg/l 8260B O1/17/15 100 Di-isopropyl ether BDL 0.10 mg/1 8260B O1/17/15 100 Ethylbenzene BDL 0.10 mg/l 8260B O1/17/15 100 Hexachloro-1,3-butadiene BDL 0.10 mg/l 8260B O1/17/15 100 Isopropylbenzene BDL 0.10 mg/1 8260B O1/17/15 100 p-Isopropyltoluene BDL 0.10 mg/l 8260B O1/17/15 100 2-Butanone (MEK) BDL 1.0 mg/1 8260B O1/17/15 100 Methylene Chloride BDL 0.50 mg/l 8260B O1/17/15 100 4-Methyl-2-pentanone (MIBK) BDL 1.0 mg/1 8260B O1/17/15 100 Methyl tert-butyl ether BDL 0.10 mg/1 8260B O1/17/15 100 Naphthalene BDL 0.50 mg/1 8260B O1/17/15 100 n-Propylbenzene BDL 0.10 mg/1 8260B O1/17/15 100 Styrene BDL 0.10 mg/1 8260B O1/17/15 100 1,1,1,2-Tetrachloroethane BDL 0.10 mg/1 8260B O1/17/15 100 1,1,2,2-Tetrachloroethane BDL 0.10 mg/l 8260B O1/17/15 100 1,1,2-Trichlorotrifluoroethane BDL 0.10 mg/1 8260B O1/17/15 100 Tetrachloroethene 13. 0.10 mg/1 8260B O1/17/15 100 Toluene BDL 0.50 mg/1 8260B O1/17/15 100 1,2,3-Trichlorobenzene BDL 0.10 mg/1 8260B O1/17/15 100 1,2,4-Trichlorobenzene BDL 0.10 mg/1 8260B O1/17/15 100 1,1,1-Trichloroethane BDL 0.10 mg/1 8260B O1/17/15 100 1,1,2-Trichloroethane BDL 0.10 mg/1 8260B O1/17/15 100 Trichloroethene BDL 0.10 mg/l 8260B O1/17/15 100 Trichlorofluoromethane BDL 0.50 mg/l 8260B O1/17/15 100 1,2,3-Trichloropropane BDL 0.25 mg/1 8260B O1/17/15 100 1,2,4-Trimethylbenzene BDL 0.10 mg/l 8260B O1/17/15 100 1,2,3-Trimethylbenzene BDL 0.10 mg/1 8260B O1/17/15 100 1,3,5-Trimethylbenzene BDL 0.10 mg/l 8260B O1/17/15 100 Vinyl chloride BDL 0.10 mg/1 8260B O1/17/15 100 Xylenes, Total BDL 0.30 mg/l 8260B O1/17/15 100 Surrogate Recovery Toluene-d8 99.3 % Rec. 8260B O1/17/15 1 Dibromofluoromethane 95.5 % Rec. 8260B O1/17/15 1 4-Bromofluorobenzene 107. % Rec. 8260B O1/17/15 1 BDL - Below Detection Limit Det. Limit - Practical Quantitation Limit(PQL) Note: The reported analytical results relate only to the sample submitted. This report shall not be reproduced, except in full, without the written approval from ESC. Reported: 01/20/15 10:08 Printed: 01/20/15 10:09 Page 5 of 14 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •A B S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 AECOM Mr. Matthew Allen 701 Corporate Center Drive, Suite 475 Quality Assurance Report Level II Raleigh, NC 27607 January 20, 2015 L743794 Laboratory Blank Analyte Result Units % Rec Limit Batch Date Analyzed Magnesium < 1 mg/l WG765180 01/18/15 15:54 Potassium < 1 mg/l WG765180 01/18/15 15:54 Sodium < 1 mg/l WG765180 01/18/15 15:54 1,1,1,2-Tetrachloroethane < .001 mg/l WG765203 01/17/15 14:15 1,1,1-Trichloroethane < .001 mg/l WG765203 01/17/15 14:15 1,1,2,2-Tetrachloroethane < .001 mg/l WG765203 01/17/15 14:15 1,1,2-Trichloroethane < .001 mg/l WG765203 01/17/15 14:15 1,1,2-Trichlorotrifluoroethane < .001 mg/l WG765203 01/17/15 14:15 1,1-Dichloroethane < .001 mg/l WG765203 01/17/15 14:15 1,1-Dichloroethene < .001 mg/l WG765203 01/17/15 14:15 1,1-Dichloropropene < .001 mg/l WG765203 01/17/15 14:15 1,2,3-Trichlorobenzene < .001 mg/l WG765203 01/17/15 14:15 1,2,3-Trichloropropane < .001 mg/l WG765203 01/17/15 14:15 1,2,3-Trimethylbenzene < .001 mg/l WG765203 01/17/15 14:15 1,2,4-Trichlorobenzene < .001 mg/l WG765203 01/17/15 14:15 1,2,4-Trimethylbenzene < .001 mg/l WG765203 01/17/15 14:15 1,2-Dibromo-3-Chloropropane < .005 mg/l WG765203 01/17/15 14:15 1,2-Dibromoethane < .001 mg/l WG765203 01/17/15 14:15 1,2-Dichlorobenzene < .001 mg/l WG765203 01/17/15 14:15 1,2-Dichloroethane < .001 mg/l WG765203 01/17/15 14:15 1,2-Dichloropropane < .001 mg/l WG765203 01/17/15 14:15 1,3,5-Trimethylbenzene < .001 mg/l WG765203 01/17/15 14:15 1,3-Dichlorobenzene < .001 mg/l WG765203 01/17/15 14:15 1,3-Dichloropropane < .001 mg/l WG765203 01/17/15 14:15 1,4-Dichlorobenzene < .001 mg/l WG765203 01/17/15 14:15 2,2-Dichloropropane < .001 mg/l WG765203 01/17/15 14:15 2-Butanone (MEK) < .01 mg/1 WG765203 01/17/15 14:15 2-Chloroethyl vinyl ether < .05 mg/l WG765203 01/17/15 14:15 2-Chlorotoluene < .001 mg/l WG765203 01/17/15 14:15 4-Chlorotoluene < .001 mg/l WG765203 01/17/15 14:15 4-Methyl-2-pentanone (MIBK) < .01 mg/l WG765203 01/17/15 14:15 Acetone < .05 mg/l WG765203 01/17/15 14:15 Acrolein < .025 mg/l WG765203 01/17/15 14:15 Acrylonitrile < .01 mg/l WG765203 01/17/15 14:15 Benzene < .001 mg/l WG765203 01/17/15 14:15 Bromobenzene < .001 mg/l WG765203 01/17/15 14:15 Bromodichloromethane < .001 mg/l WG765203 01/17/15 14:15 Bromoform < .001 mg/l WG765203 01/17/15 14:15 Bromomethane < .005 mg/l WG765203 01/17/15 14:15 Carbon tetrachloride < .001 mg/l WG765203 01/17/15 14:15 Chlorobenzene < .001 mg/l WG765203 01/17/15 14:15 Chlorodibromomethane < .001 mg/l WG765203 01/17/15 14:15 Chloroethane < .005 mg/l WG765203 01/17/15 14:15 Chloroform < .005 mg/l WG765203 01/17/15 14:15 Chloromethane < .0025 mg/l WG765203 01/17/15 14:15 cis-1,2-Dichloroethene < .001 mg/l WG765203 01/17/15 14:15 cis-1,3-Dichloropropene < .001 mg/l WG765203 01/17/15 14:15 Di-isopropyl ether < .001 mg/l WG765203 01/17/15 14:15 Dibromomethane < .001 mg/l WG765203 01/17/15 14:15 Dichlorodifluoromethane < .005 mg/l WG765203 01/17/15 14:15 Ethylbenzene < .001 mg/l WG765203 01/17/15 14:15 Hexachloro-1,3-butadiene < .001 mg/l WG765203 01/17/15 14:15 Isopropylbenzene < .001 mg/l WG765203 01/17/15 14:15 Methyl tert-butyl ether < .001 mg/l WG765203 01/17/15 14:15 Methylene Chloride < .005 mg/l WG765203 01/17/15 14:15 n-Bttylbenzene < .001 mg/l WG765203 01/17/15 14:15 n-Propylbenzene < .001 mg/l WG765203 01/17/15 14:15 * Performance of this Analyte is outside of established criteria. For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.' Page 6 of 14 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •A B S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 AECOM Mr. Matthew Allen 701 Corporate Center Drive, Suite 475 Quality Assurance Report Level II Raleigh, NC 27607 January 20, 2015 L743794 Laboratory Blank Analyte Result Units % Rec Limit Batch Date Analyzed Naphthalene < .005 mg/1 WG765203 01/17/15 14:15 p-Isopropyltoluene < .001 mg/1 WG765203 01/17/15 14:15 sec-Butylbenzene < .001 mg/1 WG765203 01/17/15 14:15 Styrene < .001 mg/1 WG765203 01/17/15 14:15 tert-Butylbenzene < .001 mg/1 WG765203 01/17/15 14:15 Tetrachloroethene < .001 mg/1 WG765203 01/17/15 14:15 Toluene < .005 mg/1 WG765203 01/17/15 14:15 trans-1,2-Dichloroethene < .001 mg/1 WG765203 01/17/15 14:15 trans-1,3-Dichloropropene < .001 mg/l WG765203 01/17/15 14:15 Trichloroethene < .001 mg/1 WG765203 01/17/15 14:15 Trichlorofluoromethane < .005 mg/1 WG765203 01/17/15 14:15 Vinyl chloride < .001 mg/1 WG765203 01/17/15 14:15 Xylenes, Total < .003 mg/1 WG765203 01/17/15 14:15 4-Bromofluorobenzene % Rec. 99.80 71-126 WG765203 01/17/15 14:15 Dibromofluoromethane % Rec. 95.60 78.3-121 WG765203 01/17/15 14:15 Toluene-d8 % Rec. 100.0 88.5-111 WG765203 01/17/15 14:15 Chloride < 1 mg/1 WG765305 01/19/15 04:38 Duplicate Analyte Units Result Duplicate RPD Limit Ref Samp Batch Chloride mg/1 24.0 20.5 15.0 20 L743445-01 WG765305 Chloride mg/1 9.10 9.10 0.0 20 L743794-02 WG765305 Laboratory Control Sample Analyte Units Known Val Result % Rec Limit Batch Magnesium mg/1 10 10.0 100. 80-120 WG765180 Potassium mg/1 10 10.2 102. 80-120 WG765180 Sodium mg/1 10 10.1 101. 80-120 WG765180 1,1,1,2-Tetrachloroethane mg/1 .025 0.0260 104. 74.2-124 WG765203 1,1,1-Trichloroethane mg/1 .025 0.0246 98.5 73.2-123 WG765203 1,1,2,2-Tetrachloroethane mg/1 .025 0.0245 98.1 70.7-122 WG765203 1,1,2-Trichloroethane mg/1 .025 0.0247 98.7 77.7-118 WG765203 1,1,2-Trichlorotrifluoroethane mg/1 .025 0.0265 106. 67.2-143 WG765203 1,1-Dichloroethane mg/1 .025 0.0239 95.7 70.7-126 WG765203 1,1-Dichloroethene mg/1 .025 0.0255 102. 67.8-129 WG765203 1,1-Dichloropropene mg/1 .025 0.0245 98.0 73.1-125 WG765203 1,2,3-Trichlorobenzene mg/1 .025 0.0252 101. 64.9-135 WG765203 1,2,3-Trichloropropane mg/1 .025 0.0269 107. 71.8-121 WG765203 1,2,3-Trimethylbenzene mg/1 .025 0.0239 95.6 72.3-116 WG765203 1,2,4-Trichlorobenzene mg/1 .025 0.0269 108. 69.7-136 WG765203 1,2,4-Trimethylbenzene mg/1 .025 0.0251 100. 75-123 WG765203 1,2-Dibromo-3-Chloropropane mg/1 .025 0.0242 96.8 65.4-128 WG765203 1,2-Dibromoethane mg/1 .025 0.0271 108. 76.6-121 WG765203 1,2-Dichlorobenzene mg/1 .025 0.0251 101. 78.4-117 WG765203 1,2-Dichloroethane mg/1 .025 0.0243 97.3 68.8-124 WG765203 1,2-Dichloropropane mg/1 .025 0.0236 94.3 76.5-119 WG765203 1,3,5-Trimethylbenzene mg/l .025 0.0252 101. 75.6-124 WG765203 1,3-Dichlorobenzene mg/1 .025 0.0267 107. 70.8-128 WG765203 1,3-Dichloropropane mg/1 .025 0.0247 98.7 77.4-117 WG765203 1,4-Dichlorobenzene mg/1 .025 0.0243 97.2 78.8-115 WG765203 2,2-Dichloropropane mg/1 .025 0.0237 94.7 62.4-133 WG765203 2-Butanone (MEK) mg/1 .125 0.105 84.0 55-149 WG765203 2-Chloroethyl vinyl ether mg/1 .125 0.128 102. 43.8-150 WG765203 * Performance of this Analyte is outside of established criteria. For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.' Page 7 of 14 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •A B S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 AECOM Mr. Matthew Allen 701 Corporate Center Drive, Suite 475 Quality Assurance Report Level II Raleigh, NC 27607 January 20, 2015 L743794 Laboratory Control Sample Analyte Units Known Val Result % Rec Limit Batch 2-Chlorotoluene mg/1 .025 0.0269 108. 74.7-122 WG765203 4-Chlorotoluene mg/1 .025 0.0244 97.4 77.5-120 WG765203 4-Methyl-2-pentanone (MIBK) mg/1 .125 0.118 94.7 70.5-133 WG765203 Acetone mg/1 .125 0.0819 65.5 35.6-163 WG765203 Acrolein mg/1 .125 0.115 92.0 10-190 WG765203 Acrylonitrile mg/1 .125 0.118 94.2 55.2-130 WG765203 Benzene mg/1 .025 0.0236 94.5 74.8-121 WG765203 Bromobenzene mg/1 .025 0.0236 94.6 77.5-116 WG765203 Bromodichloromethane mg/l .025 0.0232 92.7 75.1-116 WG765203 Bromoform mg/1 .025 0.0258 103. 67.5-130 WG765203 Bromomethane mg/1 .025 0.0287 115. 49.9-162 WG765203 Carbon tetrachloride mg/1 .025 0.0239 95.6 70.2-123 WG765203 Chlorobenzene mg/1 .025 0.0260 104. 78.1-119 WG765203 Chlorodibromomethane mg/1 .025 0.0241 96.3 74-121 WG765203 Chloroethane mg/1 .025 0.0220 88.0 61.7-135 WG765203 Chloroform mg/1 .025 0.0235 94.0 76-121 WG765203 Chloromethane mg/1 .025 0.0203 81.2 61.5-129 WG765203 cis-1,2-Dichloroethene mg/1 .025 0.0239 95.8 76-119 WG765203 cis-1,3-Dichloropropene mg/1 .025 0.0240 95.8 78.2-120 WG765203 Di-isopropyl ether mg/l .025 0.0225 90.1 65.6-132 WG765203 Dibromomethane mg/1 .025 0.0236 94.4 79.5-118 WG765203 Dichlorodifluoromethane mg/1 .025 0.0223 89.4 54.8-135 WG765203 Ethylbenzene mg/1 .025 0.0260 104. 78.8-122 WG765203 Hexachloro-1,3-butadiene mg/1 .025 0.0251 100. 64.7-129 WG765203 Isopropylbenzene mg/1 .025 0.0252 101. 78.6-132 WG765203 Methyl tert-butyl ether mg/1 .025 0.0247 98.8 71.2-126 WG765203 Methylene Chloride mg/1 .025 0.0228 91.4 70.3-120 WG765203 n-Butylbenzene mg/1 .025 0.0255 102. 76.2-126 WG765203 n-Propylbenzene mg/1 .025 0.0253 101. 78.2-122 WG765203 Naphthalene mg/1 .023 0.0249 99.6 68.4-128 WG765203 p-Isopropyltoluene mg/1 .025 0.0259 104. 74-131 WG765203 sec-Butylbenzene mg/1 .025 0.0253 101. 74.4-127 WG765203 Styrene mg/1 .025 0.0260 104. 80.4-126 WG765203 tert-Butylbenzene mg/1 .025 0.0256 102. 75.3-126 WG765203 Tetrachloroethene mg/1 .025 0.0270 108. 72.6-126 WG765203 Toluene mg/1 .025 0.0233 93.1 79.7-116 WG765203 trans-1,2-Dichloroethene mg/1 .025 0.0232 93.0 72.6-121 WG765203 trans-1,3-Dichloropropene mg/1 .025 0.0229 91.8 74.3-123 WG765203 Trichloroethene mg/1 .025 0.0246 98.2 77.7-118 WG765203 Trichlorofluoromethane mg/1 .025 0.0266 106. 63.5-135 WG765203 Vinyl chloride mg/1 .025 0.0223 89.4 65.9-128 WG765203 Xylenes, Total mg/1 .075 0.0758 101. 78.7-121 WG765203 4-Bromofluorobenzene 104.0 71-126 WG765203 Dibromofluoromethane 101.0 78.3-121 WG765203 Toluene-d8 99.70 88.5-111 WG765203 Chloride mg/1 40 39.1 98.0 90-110 WG765305 Laboratory Control Sample Duplicate Analyte Units Result Ref %Rec Limit RPD Limit Batch Magnesium mg/1 10.0 10.0 100. 80-120 0.0 20 WG765180 Potassium mg/1 10.2 10.2 102. 80-120 0.0 20 WG765180 Sodium mg/1 10.0 10.1 100. 80-120 0.0 20 WG765180 1,1,1,2-Tetrachloroethane mg/1 0.0271 0.0260 108. 74.2-124 4.22 20 WG765203 1,1,1-Trichloroethane mg/1 0.0254 0.0246 102. 73.2-123 3.01 20 WG765203 * Performance of this Analyte is outside of established criteria. For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.' Page 8 of 14 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •A B S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 AECOM Mr. Matthew Allen 701 Corporate Center Drive, Suite 475 Quality Assurance Report Level II Raleigh, NC 27607 January 20, 2015 L743794 Laboratory Control Sample Duplicate Analyte Units Result Ref %Rec Limit RPD Limit Batch 1,1,2,2-Tetrachloroethane mg/1 0.0260 0.0245 104. 70.7-122 5.91 20 WG765203 1,1,2-Trichloroethane mg/1 0.0257 0.0247 103. 77.7-118 4.17 20 WG765203 1,1,2-Trichlorotrifluoroethane mg/1 0.0262 0.0265 105. 67.2-143 1.23 20 WG765203 1,1-Dichloroethane mg/1 0.0248 0.0239 99.0 70.7-126 3.43 20 WG765203 1,1-Dichloroethene mg/1 0.0268 0.0255 107. 67.8-129 4.93 20 WG765203 1,1-Dichloropropene mg/1 0.0251 0.0245 100. 73.1-125 2.51 20 WG765203 1,2,3-Trichlorobenzene mg/1 0.0264 0.0252 106. 64.9-135 4.60 20 WG765203 1,2,3-Trichloropropane mg/1 0.0268 0.0269 107. 71.8-121 0.280 20 WG765203 1,2,3-Trimethylbenzene mg/1 0.0244 0.0239 98.0 72.3-116 2.09 20 WG765203 1,2,4-Trichlorobenzene mg/1 0.0281 0.0269 112. 69.7-136 4.54 20 WG765203 1,2,4-Trimethylbenzene mg/1 0.0262 0.0251 105. 75-123 4.25 20 WG765203 1,2-Dibromo-3-Chloropropane mg/1 0.0251 0.0242 100. 65.4-128 3.55 20 WG765203 1,2-Dibromoethane mg/1 0.0282 0.0271 113. 76.6-121 4.06 20 WG765203 1,2-Dichlorobenzene mg/1 0.0255 0.0251 102. 78.4-117 1.51 20 WG765203 1,2-Dichloroethane mg/1 0.0254 0.0243 102. 68.8-124 4.23 20 WG765203 1,2-Dichloropropane mg/1 0.0250 0.0236 100. 76.5-119 5.88 20 WG765203 1,3,5-Trimethylbenzene mg/1 0.0263 0.0252 105. 75.6-124 4.50 20 WG765203 1,3-Dichlorobenzene mg/1 0.0272 0.0267 109. 70.8-128 1.70 20 WG765203 1,3-Dichloropropane mg/1 0.0262 0.0247 105. 77.4-117 5.87 20 WG765203 1,4-Dichlorobenzene mg/1 0.0251 0.0243 100. 78.8-115 3.05 20 WG765203 2,2-Dichloropropane mg/1 0.0246 0.0237 98.0 62.4-133 3.98 20 WG765203 2-Butanone (MEK) mg/1 0.106 0.105 84.0 55-149 0.680 20 WG765203 2-Chloroethyl vinyl ether mg/1 0.135 0.128 108. 43.8-150 5.24 20 WG765203 2-Chlorotoluene mg/1 0.0278 0.0269 ill. 74.7-122 3.19 20 WG765203 4-Chlorotoluene mg/1 0.0256 0.0244 102. 77.5-120 4.87 20 WG765203 4-Methyl-2-pentanone (MIBK) mg/1 0.129 0.118 103. 70.5-133 8.27 20 WG765203 Acetone mg/1 0.0839 0.0819 67.0 35.6-163 2.35 23.9 WG765203 Acrolein mg/1 0.123 0.115 98.0 10-190 6.72 28.1 WG765203 Acrylonitrile mg/1 0.122 0.118 98.0 55.2-130 3.64 20 WG765203 Benzene mg/1 0.0244 0.0236 97.0 74.8-121 3.06 20 WG765203 Bromobenzene mg/1 0.0248 0.0236 99.0 77.5-116 4.71 20 WG765203 Bromodichloromethane mg/1 0.0247 0.0232 99.0 75.1-116 6.31 20 WG765203 Bromoform mg/1 0.0267 0.0258 107. 67.5-130 3.35 20 WG765203 Bromomethane mg/1 0.0275 0.0287 110. 49.9-162 4.27 20 WG765203 Carbon tetrachloride mg/1 0.0249 0.0239 99.0 70.2-123 3.89 20 WG765203 Chlorobenzene mg/1 0.0270 0.0260 108. 78.1-119 3.73 20 WG765203 Chlorodibromomethane mg/1 0.0263 0.0241 105. 74-121 8.86 20 WG765203 Chloroethane mg/1 0.0214 0.0220 86.0 61.7-135 2.65 20 WG765203 Chloroform mg/1 0.0239 0.0235 96.0 76-121 1.68 20 WG765203 Chloromethane mg/1 0.0218 0.0203 87.0 61.5-129 7.12 20 WG765203 cis-1,2-Dichloroethene mg/1 0.0241 0.0239 96.0 76-119 0.750 20 WG765203 cis-1,3-Dichloropropene mg/1 0.0249 0.0240 100. 78.2-120 3.90 20 WG765203 Di-isopropyl ether mg/1 0.0235 0.0225 94.0 65.6-132 4.21 20 WG765203 Dibromomethane mg/1 0.0250 0.0236 100. 79.5-118 5.69 20 WG765203 Dichlorodifluoromethane mg/1 0.0237 0.0223 95.0 54.8-135 5.80 20 WG765203 Ethylbenzene mg/1 0.0266 0.0260 106. 78.8-122 2.24 20 WG765203 Hexachloro-1,3-butadiene mg/1 0.0270 0.0251 108. 64.7-129 7.30 20 WG765203 Isopropylbenzene mg/1 0.0261 0.0252 104. 78.6-132 3.19 20 WG765203 Methyl tert-butyl ether mg/1 0.0248 0.0247 99.0 71.2-126 0.250 20 WG765203 Methylene Chloride mg/1 0.0235 0.0228 94.0 70.3-120 2.64 20 WG765203 n-Butylbenzene mg/l 0.0261 0.0255 104. 76.2-126 2.18 20 WG765203 n-Propylbenzene mg/1 0.0264 0.0253 106. 78.2-122 4.58 20 WG765203 Naphthalene mg/1 0.0260 0.0249 104. 68.4-128 4.48 20 WG765203 p-Isopropyltoluene mg/1 0.0269 0.0259 108. 74-131 3.67 20 WG765203 sec-Butylbenzene mg/1 0.0262 0.0253 105. 74.4-127 3.56 20 WG765203 Styrene mg/1 0.0269 0.0260 108. 80.4-126 3.37 20 WG765203 tert-Butylbenzene mg/1 0.0263 0.0256 105. 75.3-126 2.90 20 WG765203 Tetrachloroethene mg/1 0.0279 0.0270 112. 72.6-126 3.07 20 WG765203 Toluene mg/1 0.0242 0.0233 97.0 79.7-116 4.07 20 WG765203 * Performance of this Analyte is outside of established criteria. For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.' Page 9 of 14 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •A B S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 AECOM Mr. Matthew Allen 701 Corporate Center Drive, Suite 475 Quality Assurance Report Level II Raleigh, NC 27607 January 20, 2015 L743794 Laboratory Control Sample Duplicate Analyte Units Result Ref %Rec Limit RPD Limit Batch trans-1,2-Dichloroethene mg/1 0.0245 0.0232 98.0 72.6-121 5.23 20 WG765203 trans-1,3-Dichloropropene mg/1 0.0259 0.0229 104. 74.3-123 12.2 20 WG765203 Trichloroethene mg/1 0.0266 0.0246 106. 77.7-118 7.91 20 WG765203 Trichlorofluoromethane mg/1 0.0264 0.0266 106. 63.5-135 0.710 20 WG765203 vinyl chloride mg/1 0.0221 0.0223 88.0 65.9-128 1.24 20 WG765203 Xylenes, Total mg/1 0.0792 0.0758 106. 78.7-121 4.28 20 WG765203 4-Bromofluorobenzene 101.0 71-126 WG765203 Dibromofluoromethane 97.20 78.3-121 WG765203 Toluene-d8 102.0 88.5-111 WG765203 Chloride mg/1 39.3 39.1 98.0 90-110 0.0 20 WG765305 Matrix Spike Analyte Units MS Res Ref Res TV % Rec Limit Ref Samp Batch Magnesium mg/1 106. 98.3 10 77.0 75-125 L743769-01 WG765180 1,1,1,2-Tetrachloroethane mg/1 0.0223 0.0 .025 89.0 64-128 L743799-01 WG765203 1,1,1-Trichloroethane mg/1 0.0212 0.0 .025 85.0 58.7-134 L743799-01 WG765203 1,1,2,2-Tetrachloroethane mg/1 0.0218 0.0 .025 87.0 56-132 L743799-01 WG765203 1,1,2-Trichloroethane mg/1 0.0214 0.0 .025 86.0 66.3-125 L743799-01 WG765203 1,1,2-Trichlorotrifluoroethane mg/1 0.0235 0.0 .025 94.0 54.8-154 L743799-01 WG765203 1,1-Dichloroethane mg/1 0.0215 0.0 .025 86.0 58.5-132 L743799-01 WG765203 1,1-Dichloroethene mg/1 0.0231 0.0 .025 92.0 51.1-140 L743799-01 WG765203 1,1-Dichloropropene mg/1 0.0211 0.0 .025 84.0 57.3-136 L743799-01 WG765203 1,2,3-Trichlorobenzene mg/1 0.0229 0.0 .025 92.0 59.1-138 L743799-01 WG765203 1,2,3-Trichloropropane mg/1 0.0233 0.0 .025 93.0 61.4-128 L743799-01 WG765203 1,2,3-Trimethylbenzene mg/1 0.0210 0.0 .025 84.0 61.3-122 L743799-01 WG765203 1,2,4-Trichlorobenzene mg/1 0.0250 0.0 .025 100. 63.6-143 L743799-01 WG765203 1,2,4-Trimethylbenzene mg/1 0.0218 0.0 .025 87.0 57.4-137 L743799-01 WG765203 1,2-Dibromo-3-Chloropropane mg/1 0.0222 0.0 .025 89.0 57.3-136 L743799-01 WG765203 1,2-Dibromoethane mg/1 0.0236 0.0 .025 94.0 67.1-125 L743799-01 WG765203 1,2-Dichlorobenzene mg/1 0.0226 0.0 .025 90.0 68.2-123 L743799-01 WG765203 1,2-Dichloroethane mg/1 0.0214 0.0 .025 86.0 60-126 L743799-01 WG765203 1,2-Dichloropropane mg/1 0.0215 0.0 .025 86.0 64.2-123 L743799-01 WG765203 1,3,5-Trimethylbenzene mg/1 0.0221 0.0 .025 88.0 63.6-132 L743799-01 WG765203 1,3-Dichlorobenzene mg/1 0.0231 0.0 .025 92.0 63.1-131 L743799-01 WG765203 1,3-Dichloropropane mg/1 0.0220 0.0 .025 88.0 67.9-121 L743799-01 WG765203 1,4-Dichlorobenzene mg/1 0.0217 0.0 .025 87.0 68.6-123 L743799-01 WG765203 2,2-Dichloropropane mg/1 0.0198 0.0 .025 79.0 50.5-144 L743799-01 WG765203 2-Butanone (MEK) mg/1 0.0918 0.0 .125 73.0 22.4-138 L743799-01 WG765203 2-Chloroethyl vinyl ether mg/1 0.0461 0.0 .125 37.0 10-155 L743799-01 WG765203 2-Chlorotoluene mg/1 0.0232 0.0 .025 93.0 63.6-128 L743799-01 WG765203 4-Chlorotoluene mg/1 0.0213 0.0 .025 85.0 65.7-127 L743799-01 WG765203 4-Methyl-2-pentanone (MIBK) mg/1 0.108 0.0 .125 86.0 60.8-140 L743799-01 WG765203 Acetone mg/1 0.155 0.00213 .125 120. 10-130 L743799-01 WG765203 Acrolein mg/1 0.107 0.0 .125 86.0 10-200 L743799-01 WG765203 Acrylonitrile mg/1 0.107 0.0 .125 86.0 49.4-133 L743799-01 WG765203 Benzene mg/1 0.0212 0.0 .025 85.0 54.3-133 L743799-01 WG765203 Bromobenzene mg/1 0.0202 0.0 .025 81.0 63.9-124 L743799-01 WG765203 Bromodichloromethane mg/1 0.0205 0.0 .025 82.0 63.9-121 L743799-01 WG765203 Bromoform mg/1 0.0220 0.0 .025 88.0 59.5-134 L743799-01 WG765203 Bromomethane mg/1 0.0227 0.0 .025 91.0 41.7-155 L743799-01 WG765203 Carbon tetrachloride mg/1 0.0211 0.0 .025 84.0 55.7-134 L743799-01 WG765203 Chlorobenzene mg/1 0.0224 0.0 .025 89.0 67-125 L743799-01 WG765203 Chlorodibromomethane mg/1 0.0214 0.0 .025 86.0 64.3-125 L743799-01 WG765203 Chloroethane mg/1 0.0186 0.0 .025 74.0 51.5-136 L743799-01 WG765203 * Performance of this Analyte is outside of established criteria. For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.' Page 10 of 14 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •A B S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 AECOM Mr. Matthew Allen 701 Corporate Center Drive, Suite 475 Quality Assurance Report Level II Raleigh, NC 27607 January 20, 2015 L743794 Matrix Spike Analyte Units MS Res Ref Res TV % Rec Limit Ref Samp Batch Chloroform mg/l 0.0202 0.0 .025 81.0 63-129 L743799-01 WG765203 Chloromethane mg/l 0.0182 0.0 .025 73.0 42.4-135 L743799-01 WG765203 cis-1,2-Dichloroethene mg/l 0.0207 0.0 .025 83.0 59.2-129 L743799-01 WG765203 cis-1,3-Dichloropropene mg/l 0.0211 0.0 .025 84.0 66.4-125 L743799-01 WG765203 Di-isopropyl ether mg/l 0.0198 0.0 .025 79.0 56.9-136 L743799-01 WG765203 Dibromomethane mg/l 0.0204 0.0 .025 82.0 68.2-124 L743799-01 WG765203 Dichlorodifluoromethane mg/l 0.0198 0.0 .025 79.0 40.6-144 L743799-01 WG765203 Ethylbenzene mg/l 0.0221 0.0 .025 88.0 61.4-133 L743799-01 WG765203 Hexachloro-1,3-butadiene mg/l 0.0230 0.0 .025 92.0 55.1-136 L743799-01 WG765203 Isopropylbenzene mg/l 0.0223 0.0 .025 89.0 66.8-141 L743799-01 WG765203 Methyl tert-butyl ether mg/l 0.0216 0.0 .025 86.0 57.7-134 L743799-01 WG765203 Methylene Chloride mg/l 0.0199 0.0 .025 80.0 58.1-122 L743799-01 WG765203 n-Butylbenzene mg/l 0.0231 0.0 .025 92.0 62.7-140 L743799-01 WG765203 n-Propylbenzene mg/l 0.0224 0.0 .025 90.0 65.9-131 L743799-01 WG765203 Naphthalene mg/l 0.0225 0.0 .025 90.0 58-135 L743799-01 WG765203 p-Isopropyltoluene mg/l 0.0228 0.0 .025 91.0 63.2-139 L743799-01 WG765203 sec-Butylbenzene mg/l 0.0226 0.0 .025 90.0 62.2-136 L743799-01 WG765203 Styrene mg/l 0.0225 0.0 .025 90.0 66.8-133 L743799-01 WG765203 tert-Butylbenzene mg/l 0.0221 0.0 .025 89.0 63.3-134 L743799-01 WG765203 Tetrachloroethene mg/l 0.0237 0.0 .025 95.0 53-139 L743799-01 WG765203 Toluene mg/l 0.0204 0.0 .025 82.0 61.4-130 L743799-01 WG765203 trans-1,2-Dichloroethene mg/l 0.0205 0.0 .025 82.0 56.5-129 L743799-01 WG765203 trans-1,3-Dichloropropene mg/l 0.0207 0.0 .025 83.0 64.1-128 L743799-01 WG765203 Trichloroethene mg/l 0.0221 0.0 .025 88.0 44.1-149 L743799-01 WG765203 Trichlorofluoromethane mg/l 0.0230 0.0 .025 92.0 49.6-145 L743799-01 WG765203 Vinyl chloride mg/l 0.0191 0.0 .025 76.0 47.8-137 L743799-01 WG765203 Xylenes, Total mg/l 0.0672 0.0 .075 90.0 63.3-131 L743799-01 WG765203 4-Bromofluorobenzene 99.90 71-126 WG765203 Dibromofluoromethane 99.50 78.3-121 WG765203 Toluene-d8 101.0 88.5-111 WG765203 Chloride mg/1 63.7 12.6 50 100. 80-120 L744017-04 WG765305 Matrix Spike Duplicate Analyte Units MSD Ref %Rec Limit RPD Limit Ref Samp Batch Magnesium mg/1 106. 106. 74.6* 75-125 0.0 20 L743769-01 WG765180 1,1,1,2-Tetrachloroethane mg/l 0.0165 0.0223 66.1 64-128 29.7* 20 L743799-01 WG765203 1,1,1-Trichloroethane mg/l 0.0160 0.0212 63.8 58.7-134 28.0* 20 L743799-01 WG765203 1,1,2,2-Tetrachloroethane mg/l 0.0168 0.0218 67.4 56-132 25.5* 22.2 L743799-01 WG765203 1,1,2-Trichloroethane mg/l 0.0160 0.0214 64.0* 66.3-125 28.8* 20 L743799-01 WG765203 1,1,2-Trichlorotrifluoroethane mg/1 0.0173 0.0235 69.3 54.8-154 30.1* 22.5 L743799-01 WG765203 1,1-Dichloroethane mg/l 0.0162 0.0215 64.8 58.5-132 28.2* 20 L743799-01 WG765203 1,1-Dichloroethene mg/l 0.0166 0.0231 66.5 51.1-140 32.7* 20.2 L743799-01 WG765203 1,1-Dichloropropene mg/l 0.0161 0.0211 64.3 57.3-136 26.8* 20 L743799-01 WG765203 1,2,3-Trichlorobenzene mg/l 0.0169 0.0229 67.6 59.1-138 30.1* 23.7 L743799-01 WG765203 1,2,3-Trichloropropane mg/l 0.0174 0.0233 69.6 61.4-128 29.2* 22.4 L743799-01 WG765203 1,2,3-Trimethylbenzene mg/l 0.0160 0.0210 63.8 61.3-122 27.3* 20 L743799-01 WG765203 1,2,4-Trichlorobenzene mg/l 0.0183 0.0250 73.2 63.6-143 31.1* 21.9 L743799-01 WG765203 1,2,4-Trimethylbenzene mg/l 0.0164 0.0218 65.6 57.4-137 28.2* 20 L743799-01 WG765203 1,2-Dibromo-3-Chloropropane mg/l 0.0164 0.0222 65.7 57.3-136 29.9* 27 L743799-01 WG765203 1,2-Dibromoethane mg/l 0.0178 0.0236 71.1 67.1-125 28.0* 20 L743799-01 WG765203 1,2-Dichlorobenzene mg/l 0.0166 0.0226 66.6* 68.2-123 30.3* 20 L743799-01 WG765203 1,2-Dichloroethane mg/l 0.0162 0.0214 64.8 60-126 27.5* 20 L743799-01 WG765203 1,2-Dichloropropane mg/l 0.0156 0.0215 62.3* 64.2-123 32.0* 20 L743799-01 WG765203 1,3,5-Trimethylbenzene mg/l 0.0167 0.0221 66.8 63.6-132 27.9* 20.5 L743799-01 WG765203 * Performance of this Analyte is outside of established criteria. For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.' Page 11 of 14 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •A B S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 AECOM Mr. Matthew Allen 701 Corporate Center Drive, Suite 475 Quality Assurance Report Level II Raleigh, NC 27607 January 20, 2015 L743794 Matrix Spike Duplicate Analyte Units MSD Ref oRec Limit RPD Limit Ref Samp Batch 1,3-Dichlorobenzene mg/1 0.0170 0.0231 67.9 63.1-131 30.5* 20 L743799-01 WG765203 1,3-Dichloropropane mg/1 0.0159 0.0220 63.4* 67.9-121 32.5* 20 L743799-01 WG765203 1,4-Dichlorobenzene mg/1 0.0159 0.0217 63.5* 68.6-123 31.0* 20 L743799-01 WG765203 2,2-Dichloropropane mg/1 0.0166 0.0198 66.4 50.5-144 17.5 21.9 L743799-01 WG765203 2-Butanone (MEK) mg/1 0.0715 0.0918 57.2 22.4-138 24.9 27 L743799-01 WG765203 2-Chloroethyl vinyl ether mg/1 0.00580 0.0461 4.64* 10-155 155.* 20 L743799-01 WG765203 2-Chlorotoluene mg/1 0.0175 0.0232 70.0 63.6-128 27.8* 20 L743799-01 WG765203 4-Chlorotoluene mg/1 0.0156 0.0213 62.3* 65.7-127 30.8* 20 L743799-01 WG765203 4-Methyl-2-pentanone (MIBK) mg/1 0.0825 0.108 66.0 60.8-140 26.7* 25.1 L743799-01 WG765203 Acetone mg/1 0.0676 0.155 52.4 10-130 78.8* 27.9 L743799-01 WG765203 Acrolein mg/1 0.0870 0.107 69.6 10-200 21.1 27.7 L743799-01 WG765203 Acrylonitrile mg/1 0.0825 0.107 66.0 49.4-133 26.2* 25.3 L743799-01 WG765203 Benzene mg/1 0.0156 0.0212 62.3 54.3-133 30.5* 20 L743799-01 WG765203 Bromobenzene mg/1 0.0157 0.0202 62.9* 63.9-124 24.8* 20 L743799-01 WG765203 Bromodichloromethane mg/1 0.0153 0.0205 61.3* 63.9-121 28.9* 20 L743799-01 WG765203 Bromoform mg/1 0.0167 0.0220 66.9 59.5-134 27.3* 20.5 L743799-01 WG765203 Bromomethane mg/1 0.0188 0.0227 75.1 41.7-155 19.0 21.9 L743799-01 WG765203 Carbon tetrachloride mg/1 0.0158 0.0211 63.1 55.7-134 28.9* 20 L743799-01 WG765203 Chlorobenzene mg/1 0.0169 0.0224 67.8 67-125 27.6* 20 L743799-01 WG765203 Chlorodibromomethane mg/1 0.0164 0.0214 65.6 64.3-125 26.6* 20.8 L743799-01 WG765203 Chloroethane mg/1 0.0138 0.0186 55.0 51.5-136 29.7 40 L743799-01 WG765203 Chloroform mg/1 0.0154 0.0202 61.4* 63-129 27.3* 20 L743799-01 WG765203 Chloromethane mg/1 0.0136 0.0182 54.2 42.4-135 29.1* 20 L743799-01 WG765203 cis-1,2-Dichloroethene mg/1 0.0156 0.0207 62.2 59.2-129 28.4* 20 L743799-01 WG765203 cis-1,3-Dichloropropene mg/1 0.0149 0.0211 59.8* 66.4-125 34.1* 20 L743799-01 WG765203 Di-isopropyl ether mg/1 0.0151 0.0198 60.3 56.9-136 26.8* 20 L743799-01 WG765203 Dibromomethane mg/1 0.0153 0.0204 61.4* 68.2-124 28.5* 20 L743799-01 WG765203 Dichlorodifluoromethane mg/1 0.0150 0.0198 59.9 40.6-144 27.5* 20.2 L743799-01 WG765203 Ethylbenzene mg/1 0.0169 0.0221 67.7 61.4-133 26.4* 20 L743799-01 WG765203 Hexachloro-1,3-butadiene mg/1 0.0174 0.0230 69.6 55.1-136 27.5* 23.6 L743799-01 WG765203 Isopropylbenzene mg/1 0.0166 0.0223 66.4* 66.8-141 29.2* 20 L743799-01 WG765203 Methyl tert-butyl ether mg/1 0.0164 0.0216 65.6 57.7-134 27.2* 20 L743799-01 WG765203 Methylene Chloride mg/1 0.0153 0.0199 61.0 58.1-122 26.5* 20 L743799-01 WG765203 n-Butylbenzene mg/1 0.0176 0.0231 70.3 62.7-140 27.3* 20.3 L743799-01 WG765203 n-Propylbenzene mg/1 0.0166 0.0224 66.2 65.9-131 30.1* 20 L743799-01 WG765203 Naphthalene mg/1 0.0170 0.0225 68.1 58-135 27.7* 25.5 L743799-01 WG765203 p-Isopropyltoluene mg/1 0.0171 0.0228 68.4 63.2-139 28.6* 20.4 L743799-01 WG765203 sec-Butylbenzene mg/1 0.0165 0.0226 66.1 62.2-136 31.0* 20.3 L743799-01 WG765203 Styrene mg/1 0.0165 0.0225 65.9* 66.8-133 30.9* 20 L743799-01 WG765203 tert-Butylbenzene mg/1 0.0167 0.0221 66.6 63.3-134 28.3* 21 L743799-01 WG765203 Tetrachloroethene mg/1 0.0175 0.0237 70.1 53-139 29.8* 20 L743799-01 WG765203 Toluene mg/1 0.0155 0.0204 61.9 61.4-130 27.5* 20 L743799-01 WG765203 trans-1,2-Dichloroethene mg/1 0.0155 0.0205 61.9 56.5-129 28.0* 20 L743799-01 WG765203 trans-1,3-Dichloropropene mg/1 0.0154 0.0207 61.6* 64.1-128 29.2* 20 L743799-01 WG765203 Trichloroethene mg/1 0.0163 0.0221 65.4 44.1-149 30.0* 20 L743799-01 WG765203 Trichlorofluoromethane mg/1 0.0168 0.0230 67.0 49.6-145 31.3* 21.2 L743799-01 WG765203 vinyl chloride mg/1 0.0145 0.0191 58.0 47.8-137 27.4* 20 L743799-01 WG765203 Xylenes, Total mg/1 0.0505 0.0672 67.3 63.3-131 28.5* 20 L743799-01 WG765203 4-Bromofluorobenzene 100.0 71-126 WG765203 Dibromofluoromethane 99.70 78.3-121 WG765203 Toluene-d8 99.60 88.5-111 WG765203 Chloride mg/1 64.2 63.7 103. 80-120 1.00 20 L744017-04 WG765305 Serial Dilution * Performance of this Analyte is outside of established criteria. For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.' Page 12 of 14 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •A B S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 AECOM Mr. Matthew Allen 701 Corporate Center Drive, Suite 475 Quality Assurance Report Level II Raleigh, NC 27607 January 20, 2015 L743794 Batch number /Run number / Sample number cross reference WG765180: R3015111: L743794-02 WG765203: R3015293: L743794-01 02 WG765305: R3015356: L743794-02 * * Calculations are performed prior to rounding of reported values. * Performance of this Analyte is outside of established criteria. For additional information, please see Attachment A 'List of Analytes with QC Qualifiers.' Page 13 of 14 12065 Lebanon Rd. Mt. Juliet, TN 37122 (615) 758-5858 1-800-767-5859 *ESC Fax (615) 758-5859 •A B S•C•f E•N C,E•S Tax I.D. 62-0814289 Est. 1970 AECOM Mr. Matthew Allen 701 Corporate Center Drive, Suite 475 Quality Assurance Report Level II Raleigh, NC 27607 January 20, 2015 L743794 The data package includes a summary of the analytic results of the quality control samples required by the SW-846 or CWA methods. The quality control samples include a method blank, a laboratory control sample, and the matrix spike/matrix spike duplicate analysis. If a target parameter is outside the method limits, every sample that is effected is flagged with the appropriate qualifier in Appendix B of the analytic report. Method Blank - an aliquot of reagent water carried through the entire analytic process. The method blank results indicate if any possible contamination exposure during the sample handling, digestion or extraction process, and analysis. Concentrations of target analytes above the reporting limit in the method blank are qualified with the "B" qualifier. Laboratory Control Sample - is a sample of known concentration that is carried through the digestion/extraction and analysis process. The percent recovery, expressed as a percentage of the theoretical concentration, has statistical control limits indicating that the analytic process is "in control". If a target analyte is outside the control limits for the laboratory control sample or any other control sample, the parameter is flagged with a "J4" qualifier for all effected samples. Matrix Spike and Matrix Spike Duplicate - is two aliquots of an environmental sample that is spiked with known concentrations of target analytes. The percent recovery of the target analytes also has statistical control limits. If any recoveries that are outside the method control limits, the sample that was selected for matrix spike/matrix spike duplicate analysis is flagged with either a "J5" or a "J6". The relative percent difference (%RPD) between the matrix spike and the matrix spike duplicate recoveries is all calculated. If the RPD is above the method limit, the effected samples are flagged with a "J3" qualifier. Page 14 of 14 dCompany Name/Address: Billing Information Anatysis/Container/Preservative Chain of Cutto ly Pale_Of �*ESC AECOM I Quote s;<: — 701 Corporate Center Drive �ENSRNC102913S f Suite 475 Raleigh , NC 27607 L A is s c i e N c-E-s Report to Email To- Matt Allen mathew.allen@aecom.com 1T065labet,T fl1 t. , 4ruunt luae4 TN i71T1 r+h.-61S-7M Sa3a projectCity/State j ►+bye e00-767aessDescri tion-Smltt�/�S Cleaners ` ��P Collected: N i>v L t M e Client Project ELPhone: 919-872-6600 I Lab Project M LL# G?t7/f -CV o z Fax: l9 3 2 I I w W C005 Collected by(Vint): Site/Facility ID# P-0.0 13 IL f C. - 0 0 Acctnum:ENSRDSCA Collect sign c: Rush? (Lab MUST Be Notified) Date Results Needed m E o Template: O U) N Same Dry 20^ to cV .. Prelogin: Neal Day .. 100% N Email? No es 1 00 Z TSR: Immediately Two Da — 1 Packed on Ice N` Y�� _Three Day_.. FAX?)�No _Yes I No. >� 0{ ' rn 'o Y Cooler. LL U Sample 10 Comp/Grab Matrix• Depth Date Time r_ntrs O t p7 Shipped Via: U � fb.n/CoaainwM ,an,�i.ri4o only) iv I 7 'X_ x iPL i 1 4 I -T I •Matrix: SS-Sod GW Groundwater WW-wastewater DW-Dunking Water OT-Other pH Temp_ (j 2 T Remarks: Flow _ Other Hold Y Relinqui Si natur Oate: Time: 1 Rece (Signab. el r !� Samples rrturned via: ❑UPS Condition: ({ab use oi4i 2 x ❑Courier ❑_ (� J Relinquished by (�df(Signature) Date: Time: Rece ved by:(Signature) . / Tem C /Sp: 4 ties Received: �^ I OC Seal Intact: Y _N NA Reh (Signature) Date- Time: Rec ' rlab ure) Date: Time: PH Checked: NCF: ceArraJyticaJ' MicroseepslPace Analytical Energy Services,LLC 220 William Pitt Way Pittsburgh,PA 15238 Phone:(412)826-5245 micrascegs: ' Fax:(412)828-3433 February 4, 2015 Matt Allen AECOM 701 Corporate Center Dr Suite 475 Raleigh, NC 27607 RE: SMITTY'S CLEANERS 160321176 Microseeps Workorder: 14306 Dear Matt Allen: Enclosed are the analytical results for sample(s) received by the laboratory on Thursday, December 11,2014. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. i Sincerely, Robbin Robl 02/04/2015 rrobl@microseeps.com (?. ; y- Is i Customer Service Representative i Enclosures i As a valued client we would appreciate your comments on our service. Please email info@microseeps.com. Total Number of Pages Report ID: 14306-621091 Page 1 of 10 CERTIFICATE OF ANALYSIS U`1'1Ct y This report shall not be reproduced,except in full, without the written consent of MicroseepslPace Analytical Energy Services,LLC. l r `s , caAna4 tica!" i Client: AECOM PACE Analytical CSIA Center 701 Corporate Center Drive,Suite.475 220 William Pitt Way Rafeigh, NC 27607 Pittsburgh, PA 15238 Tel: 919.239,7160 Tel:412.826.5245 Report to: Matthew Allen Report by: Dr. Yi Wang. Project: Smitty's Cleaners Director;CSIA Center of Excellence Project# 60321176 Cell:609.721.2843 Email: matthew.allen@_aecom.com Email:yi.wang @ zymaxusa.com i , REPORT OF FORENSICS ISOTOPIC ANALYTICAL RESULTS Date Received: 12/11/2014 Date Reported:2/3/2015 Samples from AECOM for 813C(96o PDB)and 837CI{ SMOG) isotope ratios of dissolved chlorinated solvents Pace CSIA Ellen#'s 8.ample ID 5 C `` 6 C Z. 'CI S, 01; ....Lab ID pescription TCE: PCE TC5 PCE 14306=1 MW-2 -32.89 -28.21 -2.45 -0.10 14306-2 MW-5 -25,39 -28.71 -0.47 -0.09 14306-3 MW-6 0- -27.65 u- "0.20 14306-4 MW-10 U- J-28.19 u- U- 14306-5 MW-3R -28.83 -27.58 u- -0.02 JJarget analyte produced a low peak signal and the result is considered usable to+2u but not the standard t 0.5%o u-Either there was no peak corresponding to the target analyte or that such a peak dd not produce a reliable CSIA result TCE:trichloroethene PCE:tetrachloroethene Method:Compound Specific Isotope Analysis for 13C and'H by GC-IRMS,for 37C1 by GC-qMS . :S3C.. SaCI S7CI Quality Control STDs::TOE :. .PCE TCE. : .'PCE Qc-1.:-zip 87 2a: o..... .:a46 o oz QC-2 =26 93 30~<2 �0.18 -0,78T. Mean -26.90 29.4'I 0.14 0;38. Analytical Precision (ICY) 0.04 I.-Go.: 045. 0:57 C Pace CSIA Forensic Isotope Services Product or Dissolved Organics:Chlorinated Solvents,Oil,Extract,Fraction and Kerogen 3D-CSIA of 130,31GI,and`H for POE,TOE,DOE,MTBE,BTEX,PAHs,Pesticides,Alkanes,Gasoline and 011;Bulk TIC.2H,"'0,'4S,and 14N Gas Sample :Gas Composition and 2D-CSIA of t3C and ZH of C1 to C5;13c of Co2;14C of C1 and Coe;34S of.HA;16N and i80 of N20 gas Water and Dissolved Inorganics 2H.)4 and 160;348 and"10 of dissolved sulfate;348 of dissolved HiS 15N and 1 0.of dissolved Nitrate;.16N of Ammonia;13C of dissolved C%and CarbonatelBicarbonale Soil and Minerals 'yO,'s0,.'ON,1148,UK 14C of carbonate or organics Post-Analysis Forensic Isotope Data Interpretation CHAIN-OF-CUSTODY 1 Analytical Request Document �,ems 220 William Pitt Way The Chain-of Custody is a LEGAL DOCUMENT.All relevant fields must be completed accurately. Z .f"itceAnalyfical. Pittsburgh,PA'15238 mww.pacelabs.aora 412-825-5245 !.s C.f Page: ^� of 'Section A Micraseeps Section B Section C Required Client Informatlon: Required Project Tnformatiom Invoice information', �"] Company: Report To: Attention: �j 45- 99 Addrp„cs: CcpyTo: Company Name: REGULATORY AGENCY Address: NPDES i GROUNDWATER ; DRINKING WATER Email To'. Purchase Order No Pace Quote UST RCRA OTHER . _ Refarehcje P ona: F. Project Nams:[, Pace Project site.Location O }.L J�l�l�'TT`; .L"`JkW Mane9er. - Reclt;@sted DyeDat SAT: PioJeCGNur,A U ,,,a r Pace Profile#: STATE: ..mi .l7a4 C✓ erjuested Analysis Filtered(YIN) a section.D Matrix Codes LLCOLLEC��I� - RequiradCrtanllnforM0cn MATRIX OOCE, o Preservatives O 7+ it Drinking Water DW ;, ci pAL Water WT 0 COMPo$rre coNwosrm w Z Wastewater WW m START sNorclue w Product P > 3 t solusolid SL N O U rl) t SAMPLE 1D Oilpa l O " 4 Z z (A-X:0-9 1,3 Air AR p u <'Y m L7 Sample los MUST BE UNIQUE 'tissue 7S O � �- � Z � 'N It � Other OT X of 0 y U n Q lS ,it CL Q 4 ¢ -O c Z Ca Cn Q � '" Q ./1 m g vi DATE TIME DATE TIME y X = r + ,. Pave.Project No:l Lab I.D. 2 L W IN r wz � 3 LJ" t.(;Z� 4 ALo—o � 5 '� ^ s l7 6 7 8. 9 1Q 11 12 - ADDMONAL COMMENTS- RFLINQUISHED syiAEFILIAT 11 ,DATE TIME CEPTEO BY;lAFFfLIAT1ON DATE.. TIME- SAMPLE CONAfF'IONS Y041 /J )L SAMPLER NAME AND SIGNATURE U a a o ^ . C m� o U� � y Z C?I`ifali� 4� PRINT Name of SAMPLER: E m a a ~ w v . ram -SIGNATURE ofSAMPLER: DA7ESignod d V Co(MMPDDIYY): 'Important Note:Bysigning this form you ara accepling Pace's NET 30 daybaymeni renn5 end,agmaing-to late charges of 1.5%-par month for sny invoices not paid within-30 days. F-ALL-0-020rAV.07.1 5-May-2007 Cooler Receipt. Form ecfi- 'Lab Work Order: Client Name: Pro j .A. Shipping/Container information (circle appropriate response) Courier: UFeZExUPS L15P5 Client Other: Air bill Preset Ye Nu�J Tracking Number: Z f -�/b Custody Seal on Cooler/Box Present: Yes {vo Seals Intact:: Yes No Cooler/Box Packing Material: Bubble Wrap Ab.sorben Foamy Other Type of Ice:j We Blue. None Ice Intact: Yes Melted \1 Cooler Temperature: oc- 9 Kadiation Screened: Ye No Chain of Custody Reese t: Ye No Comments: 13. Laboratory Assignment/Log-in(check appropriate response) _ I YES NO N/A Comment Reference non-Conformam Chain of Custody properly filled out / .f t Chain of Custody relinquished Sampler Name&Signature on COC Containers intact Were.samples in separate bags Sample container labels match COC Sample name/date and time collected Sufficient volume provided Microseeps containers used Are containers properly preserved for,the requested testing? L/ (as labeled) If an unknown preservation state,.were containers checked? If Yes,see Ph form. Exception: VOA`s coliform Was volume for dissolved testing field filtered,as noted on the COC? Was volume received in a preserved container? Comments- Cooler contents examinedjreceived by: Date:' f / project Manager. Review: RL Date. ESi t t Document Name:Sample Condition Upon Document Revised:April 04,201.$ ,� .. Recei t SCtJR Pa a 1.of 2 ��aceAnalytical Issuing.Authorities: Document No.: i F-RAi-CS-007-rev.02 Faee Asheville QUEIIK Office i Client Name: Where Received: Huntersyllle [ Asheville 0 Eden Raleigh Courier(Circle).:- Fed Ex ISPS LISPS Client Commercial Pace .other Custody Seat on.CoolerfBox Present: 0 yes ( no Seals Intact: Pryes no Packing Material: :E] Bubble Wrap (� Bubyle,8ag�;�} None Other_ �� �- Samples on Ice,cooling ptocess has begun Circle Thermometer Used.IR Gun 5 :122065387T V of Ice: et Blue None [J iR Gun Backtkp-SIt3t 6"r Date,and Witlais of person examintng 'temp Correction Factor: Add,tf ubtract O t� C co t is/Pre at Corrected Cooler Temp.: �t ".. C Biological Tissue.is.Frgaen: Yes NoEA) check. Temp should be above freeAng"to 6°C Caminents r 'Chain-of custody Present: yes C]No DWA 1:.- - - - Ghain•of Custody-Filled Out: Yes ONO CINIA 2. Chairs of Custody Relinquished Yes .DNo ONIA 3. Sampler Name&Signature on COCt Yes DNo ❑NJA �: Samples Arrived within}told Time: Yes ONO OwA.5.. Short Hold Time Anal la".(<72hr: lyss A 140 DN,A $: Rush Turn Aroun.ci Tirrie Requested: Dyes No C1NIA•7; Sufficient Volume: Yes DNo ONIa S. Correct Containers Used: as ONa." C1NlA 9. -Peoe.Contalners used: es` (7NO ©NiA Containers intact: 4es DNo EIWA 10. Filtered volume.recelved for Dissolved tests Dyes ©Nb NIA 11. Sample Labels match COC: 1Ye p4o` ON/A 12. includes"dateltimellD/Analysis_ Matrix: A containers needing preeWatkm have been checked. I�+lee []No ONtA '13. M"Containers needing preservation are found to be In l4" DNo ©i ilA compliance with EPA-moommendation. exceptions; VOA, CoVoim,TOG,Ow.WWRO(water) Yes ❑No Samples checked.fordechlodnatlon: yes DNo ©NIA 14. TIWA 1 Heads ace in VOA Vials >omm Yes DNo ' Trip Blank Present: Oyes DNo gNIA 16. Trip Blank Custody Seats Present UYss DNO AllA Pace Trip Blank Lot# If urchased: Hold Data Roauired? y ! N client Notification/Resolutions Person Contacted:- Date/Time- Comments!ResOJLAO:X Place label here SCURF-ISRF pate:E�:: Review:: OR Note: Whenever there is A discrepancy affecting North Carolina oompflanoe" ndwrm samples,a,copy of thls Hawrite protect number form will be sent to the North Carolina DEHNR Certification-Office i.I.e out of hold,Incorrect presenvalive,out of temp, (if label avajest Incorrect containers) Docu-nont Name:Sample Condition Upon Document Revised:April 04,20.13 ° Receipt SCUR Pa e 21 Z *1 weAna Document No.: Fical Issuing Authorities: s��a lF F-RAL-CS-001-rev.02 Pace Asheville Quality Office Sample Bottle Codes 41 n,. Q Nt 2 U3 d Z I° � I— in Z l U LL. CV �- t� cri 0) M M <L to N Item# m m M m CO, m ca m Q Q Q ¢ ¢ o > > o > > U) �n E Client Sample INS) Sate le Dlscre ane ( pH Adjustment Log for Preserved,.Sam des Samp(e!D Type of pH uponon Time PrQsarvation AmRurst of Lot#of Preservative receipt Adjusted Preservative added Presen+ati4e Battle Code Key 125 ml Plastic Unp:BP4U 1 Liter Amber Unp:AG1 U 40 ml VOA H2SO4:DG9S 250 ml Plastic unp: BP3U 1 Llter Amber HCt:AGIH .5035.K1t:VOAK 500 ml plastic Unp:'BP2U 500 ml Amber Unp:AG2U VPH/Gas Kit:VtGK 1 Liter Plastic Unp: f3PIU 1 Liter Amber H2SO4:AG IS 125 ml Sterile Plastic:SP5T 250 ml Plastic-H2SO4:BP3S 250 mi Amber H2SO4;AMS 250 ml Sterile Plastic:SP2T 250 ml Plastic HNO3:BP3N 250 ml Amber NH4CL:AGM 250 1 250 ml Plastic ZN Acetate:BP3Z 40 ml VOA HCh DG9H 250 ml Plastic NaOH:SP30 40 ml VOA Na2S203:VG9T Wide mouthed glass jar unp:WGFU 40 ml VOA Unp:VG9U AECOM Environment Appendix F. Historical Chlorinated Volatile Organic Compounds 60342855 May 2015 10 M W-2 9 KMn04 Injection Nov 3-5, 2014 8 7 6 awn E c 0 5 L Y V C u 4 3 2 — --$--PCE 1 — fTCE cis-1,2-DCE 0 I� o�� 00� o�� o�0i otio oy'L �,y3 oyo� oti� ti ti ti Date 1.4 MW-3R �PCE fTCE KMn04 Injection November 3-5, 2014 12 cis-1,2-DCE 1.0 J t 0.8 C 0 i-� f4 L it C w c 0.6 — 0 v 0.4 0.2 h\�00�o� o\�o�o� ��ow �\��o� 001tio �\��titi �\���ti� A`ti o�ti� ti ti ti Date 16 tPCE MW-5 fTCE KMn04 Injection 14 Ar—cis-1,2-DCE Nov 3-5, 2014 12 10 J UCA C C O m 8 4+ C GJ u c O u 6 4 2 0 tio��o\oo �\���o� ��o\o� titi���\moo °\��titi w\���ti� Date 30 IMW-1 --4o--PCE KMn04 Injection fTCE Nov 3-5, 2014 cis-1,2-DCE 25 20 J �Q E C O 15 L u c O U 10 5 0 N, ti� ti� ti� N, ti� ti� ti� ti� ti� 1; ti tih til ,ti0 ,LO ,ti0 ,LO ,LO ,LO ,LO ,ti0 ,LO ,LO ,ti0 ,ti0 ,y0 ,y0 ,LO ,LO �\�o� ���\ tio���\ tio���\ titi�y�\ titi���\ titi���\ titi���\ tiro\ ti�yo\ ti��o\ Date 60 --+--PCE MW-33 KMn04 Injection fTCE Nov 3-5, 2014 cis-1,2-DCE 50 40 J E C 0 m 30 41 C v V C O V 20 10 0 Date About AECOM With nearly 100,000 employees—including architects, engineers,designers,planners,scientists and management and construction services professionals —serving clients in more than 150 countries around the world following the acquisition of URS,AECOM is a premier,fully integrated infrastructure and support services firm.AECOM is ranked as the#1 engineering design firm by revenue in Engineering News-Record magazine's annual industry rankings.The company is a leader in all of the key markets that it serves,including transportation,facilities,environmental,energy,oil and gas,water,high-rise buildings and government. AECOM provides a blend of global reach,local knowledge,innovation and technical excellence in delivering solutions that create,enhance and sustain the world's built,natural and social environments.A Fortune 500 company,AECOM companies,including URS Corporation and Hunt Construction Group,had revenue of approximately$19.5 billion during the 12 months ended Sept.30,2014.More information on AECOM and its services can be found at www.aecom.com. AECOM 701 Corporate Center Drive,Suite 475 Raleigh,North Carolina 27607 T: +1.919.854.6200 F: +1.919.854.6259