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HomeMy WebLinkAboutWQ0004972_Monitoring - 07-2024_20240830 (3)Monitoring Report Submittal Permit Number#* Name of Facility:* Month:* July Report Information Type * GW-59 WQ0004972 Forest Lake RV Park WWTP Year:* 2024 Upload Document* GW-59 MW Reports for July 2024.pdf PDF Only 2.89 M B Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59). Confirmation Email Address: * agrenier@greenerehssolutions.com Name of Submitter: * Amanda Grenier Signature: Date of submittal: 8/30/2024 This will be filled in automatically Initial Review Reviewer: Wanda.Gerald Is the project number correct?* WQ0004972 Is the monitoring report accepted?* Yes No Regional Office* Winston-Salem Reviewer: _anonymous Review Date: 9/17/2024 Docusign Envelope ID: 9EDCDCEA-6FA3-4BAF-AD82-56E3FDA54B3A SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 10/31/2027 Facility Name: Forest Lake RV WWTP Non -Discharge WQ0004972 UIC Permit Name (if different): NPDES Other Facility Address: 192 Thousand Trails Dr. TYPE OF PERMITTED OPERATION BEING MONITORED Advance NC 27006 County Davie ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: Contact Person: Amanda Grenier Telephone#: 919-356-6509 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Forest Lake RV Spray Irrigation Field No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): 1 Date sample collected: 7/9/2024 FIELD ANALYSES: WAS Well Depth: 90.7 ft. Well Diameter: 2 in. pH 00400: 5.96 units Temp. 000lo: 19.1 °C DRY at Depth to Water Level 82546: 67.6 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 63 µMhos time of sampling, Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: 4.5 gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: ❑ YES ❑■ NO and field acidified: ❑ YES ❑■ NO LABORATORY INFORMATION Date sample analyzed: 7/9/2024 Laboratory Name: Pace Analytical Certification No. 12 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOz) as N 00615 mg/L Pb - Lead olo51 ug/L Coliform: MF Fecal 31616 16 /100mL Nitrate (NO3) as N 00620 0.15 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.05 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al -Aluminum oilo5 mg/L pH (Lab) 00403 6.0 units Ba - Barium 01007 ug/L TOC 00680 2.3 mg/L Ca - Calcium 00916 mg/L Chloride 0094o 2.2 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia oo6lo <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mn - Manganese olo55 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% George Gudgeon, Sr. Vice President Permittee (or Authorized Agent) Name and Title - Please print or type 8/29/2024 GW-59 Rev.06-07-2018 Docusign Envelope ID: 9EDCDCEA-6FA3-4BAF-AD82-56E3FDA54B3A SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 10/31/2027 Facility Name: Forest Lake RV WWTP Non -Discharge WQ0004972 UIC Permit Name (if different): NPDES Other Facility Address: 192 Thousand Trails Dr. TYPE OF PERMITTED OPERATION BEING MONITORED Advance NC 27006 County Davie ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: Contact Person: Amanda Grenier Telephone#: 919-356-6509 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Forest Lake RV Spray Irrigation Field No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): 2 Date sample collected: 7/9/2024 FIELD ANALYSES: WAS Well Depth: 46 ft. Well Diameter: 2 in. pH 00400: 5.69 units Temp. 000lo: 18.7 oC DRY at Depth to Water Level 82546:38.5 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 51.7 µMhos time of sampling, Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: 3.5 gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: ❑ YES ❑■ NO and field acidified: ❑ YES ❑■ NO LABORATORY INFORMATION Date sample analyzed: 7/9/2024 Laboratory Name: Pace Analytical Certification No. 12 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOz) as N 00615 mg/L Pb - Lead olo51 ug/L Coliform: MF Fecal 31616 1.0 /100mL Nitrate (NO3) as N 00620 0.44 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.062 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al -Aluminum oilo5 mg/L pH (Lab) 00403 5.9 units Ba - Barium 01007 ug/L TOC 00680 <1 mg/L Ca - Calcium 00916 mg/L Chloride 0094o 2.9 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia oo6lo <0.10 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mn - Manganese olo55 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% George Gudgeon, Sr. Vice President Permittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.06-07-2018 Docusign Envelope ID: 9EDCDCEA-6FA3-4BAF-AD82-56E3FDA54B3A SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 10/31/2027 Facility Name: Forest Lake RV WWTP Non -Discharge WQ0004972 UIC Permit Name (if different): NPDES Other Facility Address: 192 Thousand Trails Dr. TYPE OF PERMITTED OPERATION BEING MONITORED Advance NC 27006 County Davie ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: Contact Person: Amanda Grenier Telephone#: 919-356-6509 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Forest Lake RV Spray Irrigation Field No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): 3 Date sample collected: 7/9/2024 FIELD ANALYSES: WAS Well Depth: 20.3 ft. Well Diameter: 2 in. pH 00400: 4.72 units Temp. 000lo: 19.4 oC DRY at Depth to Water Level 82546: 11.7 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 233 µMhos time of sampling, Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: 3 gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: ❑ YES ❑■ NO and field acidified: —]YES ❑■ NO LABORATORY INFORMATION Date sample analyzed: 7/9/2024 Laboratory Name: Pace Analytical Certification No. 12 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOz) as N 00615 mg/L Pb - Lead olo51 ug/L Coliform: MF Fecal 31616 580 /100mL Nitrate (NO3) as N 00620 16.6 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.15 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al -Aluminum oilo5 mg/L pH (Lab) 00403 4.8 units Ba - Barium 01007 ug/L TOC 00680 <1 mg/L Ca - Calcium 00916 mg/L Chloride 0094o 29.0 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia oo6lo <0.1 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mn - Manganese olo55 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% George Gudgeon, Sr. Vice President Permittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.06-07-2018 Docusign Envelope ID: 9EDCDCEA-6FA3-4BAF-AD82-56E3FDA54B3A SUBMIT FORM ON YELLOW PAPER ONLY • • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 10/31/2027 Facility Name: Forest Lake RV WWTP Non -Discharge WQ0004972 UIC Permit Name (if different): NPDES Other Facility Address: 192 Thousand Trails Dr. TYPE OF PERMITTED OPERATION BEING MONITORED Advance NC 27006 County Davie ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: Contact Person: Amanda Grenier Telephone#: 919-356-6509 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Forest Lake RV Spray Irrigation Field No. of wells to be sampled: 4 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): 4 Date sample collected: 7/9/2024 FIELD ANALYSES: WAS Well Depth: 39 ft. Well Diameter: 2 in. pH 00400: 5.58 units Temp. 000lo: 18.1 °C DRY at Depth to Water Level 82546: 29.2 ft. below measuring point Screened Interval: ft. to ft. Spec. Cond. 00094: 154.3 µMhos time of sampling, Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: 1.5 gallons Appearance Clear here:❑ Samples for metals were collected unfiltered: ❑ YES ❑■ NO and field acidified: —]YES ❑■ NO LABORATORY INFORMATION Date sample analyzed: 7/9/2024 Laboratory Name: Pace Analytical Certification No. 12 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NOz) as N 00615 mg/L Pb - Lead olo51 ug/L Coliform: MF Fecal 31616 <1 /100mL Nitrate (NO3) as N 00620 7.3 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.12 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 mg/L Al -Aluminum oilo5 mg/L pH (Lab) 00403 5.6 units Ba - Barium 01007 ug/L TOC 00680 <1 mg/L Ca - Calcium 00916 mg/L Chloride 00940 11.2 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia oo6lo <0.1 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3as N; Ammonia Nitrogen, Total) Mn - Manganese olo55 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% George Gudgeon, Sr. Vice President Permittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.06-07-2018 Docusign Envelope ID: 9EDCy'A DCEA- 3� SBA iAD8, b�6�E3�FDA�5�4B3AqL-�,� �FORM Permit # WQ0004972 (Submit one each monitoring period with GW 59 forms,) 1 Enter date monitoring results were due. (8/30/24 ) Will this monitoring report (GW-59 and GW-59A) YES NO be submitted after the established due date? X 2 Was any required information missing on the GW-59 report forms? YES NO IF the answer to question I or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. X 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Office for guidance. X 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: MW #2 field pH was 5.7, lab pH 5.9. MW #3 field pH was 4.7, lab pH 4.8 and nitrate was 16.6 mg/ I. MW #4 field pH was 5.6, lab pH 5.6. X 5 For the constituents identified in question 4 above, have standards been exceeded previously for the YES NO same constituent(s) in the same well(s) in the last two years? If the answer to question 5 is "NO", skip to section 8. If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years). Yes, DEQ is aware and have expressed concerns about the well. 2 more test wells were sampled and the results were sent to DEQ. X 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly located, contact the Regional Office. X 7 Is the permittee implementing previously approved actions required by the Division involving this YES NO groundwater quality problem? If the answer to question 7 is "YES", describe those actions in the space provided below. If the answer to question 7 is "NO", contact the Regional Office within 90 days, an evaluation may be required to determine the impact the waste disposal system is havinq at the review and compliance boundaries surroundinq this facility. Failure to do so may subject the permittee to a Notice of Violation, fines, and/or penalties. 2 more test wells were dug and sampled. The results were submitted to DEQ for review. X 8 The person completing this portion (GIN--59A) of the monitoring report should sign below and submit this form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form. I hereby acknowledge that the above information was evaluated and the information ''submitted in this report (Compliance Report GW-59A) is true and complete to the best of my knowledge. 8/29/24 Signature of Permittee (or Authorized Agent) Date GW-59A 12/8/2003 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 July 24, 2024 Amanda D. Grenier Greener EHS Solutions 21 Selby Ct. Holly Springs, NC 27540 RE: Project: Forest Lake- MW's July Pace Project No.: 92740754 Dear Amanda Grenier: Enclosed are the analytical results for sample(s) received by the laboratory on July 09, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com 704-977-0942 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 23 ace Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Forest Lake- MW's July Pace Project No.: 92740754 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification M 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification M 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification M E87627 Kentucky UST Certification M 84 Louisiana DoH Drinking Water #: LA029 Virginia/VELAP Certification M 460221 South Carolina Laboratory ID: 99030 South Carolina Certification M 99030001 Virginia/VELAP Certification M 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 23 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Forest Lake- MW's July 92740754 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92740754001 MW #1 SM 9222D-2015 CHC 1 PASI-C EPA 9040C SMS 1 PASI-A EPA 350.1 Rev 2.0 1993 NCF 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 Zip 1 PASI-A SM 4500-CI-E-2011 Zip 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92740754002 MW #2 SM 9222D-2015 CHC 1 PASI-C EPA 9040C SMS 1 PASI-A EPA 350.1 Rev 2.0 1993 NCF 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 Zip 1 PASI-A SM 4500-CI-E-2011 Zip 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92740754003 MW #3 SM 9222D-2015 KDF 1 PASI-C EPA 9040C SMS 1 PASI-A EPA 350.1 Rev 2.0 1993 NCF 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 Zip 1 PASI-A SM 4500-CI-E-2011 Zip 1 PASI-A SM 531OB-2014 MJP 1 PASI-A 92740754004 MW #4 SM 9222D-2015 CHC 1 PASI-C EPA 9040C SMS 1 PASI-A EPA 350.1 Rev 2.0 1993 NCF 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 Zip 1 PASI-A SM 4500-CI-E-2011 Zip 1 PASI-A SM 531OB-2014 MJP 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 23 ANALYTICAL RESULTS Project: Forest Lake- MW's July Pace Project No.: 92740754 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW #1 Lab ID: 92740754001 Collected: 07/09/24 08:35 Received: 07/09/24 15:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Charlotte Fecal Coliforms 16.0 CFU/100 mL 1.0 1 07/09/24 16:06 07/10/24 14:09 9040 pH Analytical Method: EPA 9040C Pace Analytical Services -Asheville pH at 25 Degrees C 6.0 Std. Units 0.10 1 07/19/24 15:08 H3 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 07/18/24 16:31 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 0.15 mg/L 0.020 1 07/10/24 01:40 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus ND mg/L 0.050 1 07/18/2412:56 07/19/2412:03 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 2.2 mg/L 1.0 1 07/17/2410:38 16887-00-6 5310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon 2.3 mg/L 1.0 1 07/21/24 18:38 7440-44-0 Date: 07/24/2024 12:55 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 23 ANALYTICAL RESULTS Project: Forest Lake- MW's July Pace Project No.: 92740754 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW #2 Lab ID: 92740754002 Collected: 07/09/24 09:30 Received: 07/09/24 15:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Charlotte Fecal Coliforms 1.0 CFU/100 mL 1.0 1 07/09/24 16:06 07/10/24 14:09 9040 pH Analytical Method: EPA 9040C Pace Analytical Services -Asheville pH at 25 Degrees C 5.9 Std. Units 0.10 1 07/19/24 15:15 H3 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 07/18/24 16:51 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 0.44 mg/L 0.020 1 07/10/24 01:42 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.062 mg/L 0.050 1 07/18/2412:56 07/19/2412:05 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 2.9 mg/L 1.0 1 07/17/2410:39 16887-00-6 5310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 07/21/24 19:30 7440-44-0 Date: 07/24/2024 12:55 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 23 ANALYTICAL RESULTS Project: Forest Lake- MW's July Pace Project No.: 92740754 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW #3 Lab ID: 92740754003 Collected: 07/09/24 10:30 Received: 07/09/24 15:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Charlotte Fecal Coliforms 580 CFU/100 mL 1.0 1 07/09/24 17:48 07/10/24 15:48 9040 pH Analytical Method: EPA 9040C Pace Analytical Services -Asheville pH at 25 Degrees C 4.8 Std. Units 0.10 1 07/19/24 14:13 H3 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 07/18/24 16:53 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 16.6 mg/L 0.10 5 07/11/24 00:45 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.15 mg/L 0.050 1 07/18/2412:56 07/19/2412:06 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 29.0 mg/L 1.0 1 07/22/2411:24 16887-00-6 5310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 07/21/24 19:47 7440-44-0 Date: 07/24/2024 12:55 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 23 ANALYTICAL RESULTS Project: Forest Lake- MW's July Pace Project No.: 92740754 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW #4 Lab ID: 92740754004 Collected: 07/09/24 09:55 Received: 07/09/24 15:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Charlotte Fecal Coliforms ND CFU/100 mL 1.0 1 07/09/24 16:06 07/10/24 14:09 9040 pH Analytical Method: EPA 9040C Pace Analytical Services -Asheville pH at 25 Degrees C 5.6 Std. Units 0.10 1 07/19/24 14:03 H3 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia ND mg/L 0.10 1 07/18/24 16:35 7664-41-7 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 7.3 mg/L 0.10 5 07/10/24 01:59 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 0.12 mg/L 0.050 1 07/18/2412:56 07/19/2412:11 7723-14-0 4500 Chloride Analytical Method: SM 4500-CI-E-2011 Pace Analytical Services -Asheville Chloride 11.2 mg/L 1.0 1 07/22/2411:26 16887-00-6 5310B TOC Analytical Method: SM 531OB-2014 Pace Analytical Services -Asheville Total Organic Carbon ND mg/L 1.0 1 07/21/24 20:07 7440-44-0 Date: 07/24/2024 12:55 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 23 QUALITY CONTROL DATA Project: Forest Lake- MW's July Pace Project No.: 92740754 QC Batch: 867115 Analysis Method: SM 9222D-2015 QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) - CHT Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92740754001, 92740754002, 92740754004 METHOD BLANK: 4469324 Matrix: Water Associated Lab Samples: 92740754001, 92740754002, 92740754004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 07/10/24 14:09 SAMPLE DUPLICATE: 4469325 Parameter Fecal Coliforms 92740754002 Dup Units Result Result RPD Qualifiers CFU/100 mL 1.0 ND Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/24/2024 12:55 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 23 QUALITY CONTROL DATA Project: Forest Lake- MW's July Pace Project No.: 92740754 QC Batch: 867617 Analysis Method: SM 9222D-2015 QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) - CHT Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92740754003 METHOD BLANK: 4472176 Matrix: Water Associated Lab Samples: 92740754003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Fecal Coliforms CFU/100 mL ND 1.0 07/10/24 15:48 SAMPLE DUPLICATE: 4472177 Parameter Fecal Coliforms 92740630001 Dup Units Result Result RPD Qualifiers CFU/100 mL 5.0 10.0 67 D6 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/24/2024 12:55 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 23 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Forest Lake- MW's July Pace Project No.: 92740754 QC Batch: 869360 Analysis Method: EPA 9040C QC Batch Method: EPA 9040C Analysis Description: 9040 pH Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92740754003, 92740754004 SAMPLE DUPLICATE: 4480888 92741795001 Dup Parameter Units Result Result RPD Qualifiers pH at 25 Degrees C Std. Units 8.2 8.2 0 H3 SAMPLE DUPLICATE: 4480889 92741795002 Dup Parameter Units Result Result RPD Qualifiers pH at 25 Degrees C Std. Units 8.2 8.2 0 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/24/2024 12:55 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 23 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Forest Lake- MW's July Pace Project No.: 92740754 QC Batch: 869545 Analysis Method: EPA 9040C QC Batch Method: EPA 9040C Analysis Description: 9040 pH Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92740754001, 92740754002 SAMPLE DUPLICATE: 4481569 92740754001 Dup Parameter Units Result Result RPD Qualifiers pH at 25 Degrees C Std. Units 6.0 6.0 0 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/24/2024 12:55 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 23 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Forest Lake- MW's July Pace Project No.: 92740754 QC Batch: 869256 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92740754001, 92740754002, 92740754003, 92740754004 METHOD BLANK: 4480143 Matrix: Water Associated Lab Samples: 92740754001, 92740754002, 92740754003, 92740754004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Ammonia mg/L ND 0.10 07/18/24 15:52 LABORATORY CONTROL SAMPLE: 4480144 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Ammonia mg/L 5 5.1 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4480145 4480146 MS MSD 92740483002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 15.1 5 5 16.5 14.9 29 -3 90-110 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4480147 4480148 MS MSD 92742485001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 0.50 5 5 5.6 5.7 103 103 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/24/2024 12:55 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 23 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Forest Lake- MW's July Pace Project No.: 92740754 QC Batch: 867030 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92740754001, 92740754002, 92740754004 METHOD BLANK: 4469077 Matrix: Water Associated Lab Samples: 92740754001, 92740754002, 92740754004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrogen, Nitrate mg/L ND 0.020 07/10/24 01:17 LABORATORY CONTROL SAMPLE: 4469078 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate mg/L 1.5 1.5 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4469079 4469080 MS MSD 92740417001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 0.35 1.5 1.5 1.9 1.9 105 105 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4469081 4469082 MS MSD 92740453005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L 0.16 1.5 1.5 1.6 1.6 98 97 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/24/2024 12:55 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 23 QUALITY CONTROL DATA Project: Forest Lake- MW's July Pace Project No.: 92740754 QC Batch: 867371 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92740754003 METHOD BLANK: 4471016 Associated Lab Samples: 92740754003 Parameter Units Nitrogen, Nitrate mg/L LABORATORY CONTROL SAMPLE: 4471017 Parameter Units Nitrogen, Nitrate mg/L Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.020 07/10/24 23:53 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 1.5 1.6 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4471020 4471021 MS MSD 92740823010 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L <0.0039 1.5 1.5 1.5 1.5 100 100 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4471030 4471031 MS MSD 92740823007 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L <0.0039 1.5 1.5 1.2 1.2 79 79 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/24/2024 12:55 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 23 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Forest Lake- MW's July Pace Project No.: 92740754 QC Batch: 868849 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92740754001, 92740754002, 92740754003, 92740754004 METHOD BLANK: 4477962 Matrix: Water Associated Lab Samples: 92740754001, 92740754002, 92740754003, 92740754004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Phosphorus mg/L ND 0.050 07/19/2411:41 LABORATORY CONTROL SAMPLE: 4477963 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus mg/L 2.5 2.5 98 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4477964 4477965 MS MSD 92740735022 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 0.19 2.5 2.5 2.6 2.6 97 96 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4477966 4477967 MS MSD 92740737001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 13.0 2.5 2.5 14.6 14.8 61 70 90-110 1 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/24/2024 12:55 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 23 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Forest Lake- MW's July Pace Project No.: 92740754 QC Batch: 868542 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92740754001, 92740754002 METHOD BLANK: 4476488 Matrix: Water Associated Lab Samples: 92740754001, 92740754002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 07/17/2410:07 LABORATORY CONTROL SAMPLE: 4476489 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 20.7 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4476490 4476491 MS MSD 92739646002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 6.2 10 10 17.0 16.9 108 107 90-110 0 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4476492 4476493 MS MSD 92739646003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 8.0 10 10 17.6 18.4 96 104 90-110 4 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/24/2024 12:55 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 23 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Forest Lake- MW's July Pace Project No.: 92740754 QC Batch: 869556 Analysis Method: SM 4500-CI-E-2011 QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92740754003, 92740754004 METHOD BLANK: 4481599 Matrix: Water Associated Lab Samples: 92740754003, 92740754004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride mg/L ND 1.0 07/22/2411:21 LABORATORY CONTROL SAMPLE: 4481600 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride mg/L 20 21.0 105 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4481601 4481602 MS MSD 92741604001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chloride mg/L 24.0 10 10 34.1 34.2 101 103 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/24/2024 12:55 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 23 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Forest Lake- MW's July Pace Project No.: 92740754 QC Batch: 869883 Analysis Method: SM 531 OB-2014 QC Batch Method: SM 531 OB-2014 Analysis Description: 5310E TOC Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92740754001, 92740754002, 92740754003, 92740754004 METHOD BLANK: 4483431 Matrix: Water Associated Lab Samples: 92740754001, 92740754002, 92740754003, 92740754004 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Total Organic Carbon mg/L ND 1.0 07/21/24 15:55 LABORATORY CONTROL SAMPLE: 4483432 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Organic Carbon mg/L 25 24.0 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4483433 4483434 MS MSD 92740735022 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 6.9 25 25 31.6 31.1 99 97 90-110 2 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4483435 4483436 MS MSD 92740751001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Total Organic Carbon mg/L 4.3 25 25 27.1 27.4 91 92 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/24/2024 12:55 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 23 Pace Analytical Services, LLC Face9800 Kincey Ave. Suite 100 (-�Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Forest Lake- MW's July Pace Project No.: 92740754 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H3 Sample was received or analysis requested beyond the recognized method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/24/2024 12:55 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 23 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Forest Lake- MW's July 92740754 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92740754001 MW #1 SM 9222D-2015 867115 SM 9222D-2015 867116 92740754002 MW #2 SM 9222D-2015 867115 SM 9222D-2015 867116 92740754003 MW #3 SM 9222D-2015 867617 SM 9222D-2015 867618 92740754004 MW #4 SM 9222D-2015 867115 SM 9222D-2015 867116 92740754001 MW #1 EPA 9040C 869545 92740754002 MW #2 EPA 9040C 869545 92740754003 MW #3 EPA 9040C 869360 92740754004 MW #4 EPA 9040C 869360 92740754001 MW #1 EPA 350.1 Rev 2.0 1993 869256 92740754002 MW #2 EPA 350.1 Rev 2.0 1993 869256 92740754003 MW #3 EPA 350.1 Rev 2.0 1993 869256 92740754004 MW #4 EPA 350.1 Rev 2.0 1993 869256 92740754001 MW #1 EPA 353.2 Rev 2.0 1993 867030 92740754002 MW #2 EPA 353.2 Rev 2.0 1993 867030 92740754003 MW #3 EPA 353.2 Rev 2.0 1993 867371 92740754004 MW #4 EPA 353.2 Rev 2.0 1993 867030 92740754001 MW #1 EPA 365.1 Rev 2.0 1993 868849 EPA 365.1 Rev 2.0 1993 869261 92740754002 MW #2 EPA 365.1 Rev 2.0 1993 868849 EPA 365.1 Rev 2.0 1993 869261 92740754003 MW #3 EPA 365.1 Rev 2.0 1993 868849 EPA 365.1 Rev 2.0 1993 869261 92740754004 MW #4 EPA 365.1 Rev 2.0 1993 868849 EPA 365.1 Rev 2.0 1993 869261 92740754001 MW #1 SM 4500-CI-E-2011 868542 92740754002 MW #2 SM 4500-CI-E-2011 868542 92740754003 MW #3 SM 4500-CI-E-2011 869556 92740754004 MW #4 SM 4500-CI-E-2011 869556 92740754001 MW #1 SM 5310B-2014 869883 92740754002 MW #2 SM 5310B-2014 869883 92740754003 MW #3 SM 5310B-2014 869883 92740754004 MW #4 SM 5310B-2014 869883 Date: 07/24/2024 12:55 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 23 i DC# Title: ENV-FRM-HUN1-0083 v05 Sample Condition Upon Receipt ace Effective Date: 05/24/2024 Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersvi lie � Raleigh❑ Mechanicsville❑ AtlantaF— KernercviliPl-1 SampleClient Name: WO# : 92740754 Upon ; C.-i��I'A Y :PLC 0 I��-�10��Project #: � Courier: [:]Fed -Ex [-]UPS ❑USPS ❑Client ❑ Commercial Pace❑Other: 92740754 I Custody Seal Present? Dyes No Seals Intact? Yes ❑No [-]N/A Date/Initials Person Examining Contents-/y / Packing Material: ❑Bubble Wrap []Bubble Bags ❑None ❑ Other Biological Tissue Frozen? Thermometer: / []Yes ❑NOO/ N/A ❑ IR Gun ID: ` ICI G Type of Ice: I/ IWet yp 7_ ❑Blue ❑None Correction Factor - Cooler Temp: Add/Subtract ("C) Temp should be above freezing to I 6'C �� ❑Samples out of temp criteria. Samples on ice, cooling process Cooler Temp Corrected (°C): . -, 5 has begun USDA Regulated Soil (❑ N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC Did samoles originate from n fnreinn anurre (internatinnally jcheck maps)? UYes UNo including Hawaii and Puerto Rico)? ❑Yes ❑No Comments/Discrepancy: Chain of Custody Present? EfYes ❑No (—]N/A I I. Samples Arrived within Hold Time? Yes ❑No ❑N/A 2. Short Hold Time Analysis (<72 hr.)? ❑Yes 2�o ❑N/A 3. Rush Turn Around Time Requested? [--]Yes No []N/A 4. Sufficient Volume? Ayes [:]No ❑N/A 5. Correct Containers Used? 10yes ❑No ❑N/A 6. -Pace Containers Used? ]yes ❑No ❑N/A 7. Containers Intact? Qr]Yes [—]No (—]N/A Dissolved analysis: Samples Field Filtered? ❑Yes dNo [:]N/A 8. 9. Sample Labels Match COC? Dyes ❑No ❑N/A -Includes Date/Time/ID/Analysis Matrix: W1 Headspace in VOA Vials (>5-6mm)? ❑Yes ❑No El N/A 110. Trip Blank Present? ❑Yes [:]No N/A 11. Trip Blank Custody Seals Present? ❑Yes [:]No CJN/A COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Lot ID of split containers: Date/Time: Date: Date: Field Data Required? ❑Yes [:]No Qualtrax ID: 69614 Page 1 of 2 Page 21 of 23 Vace DC#_Title: ENV-FRM-HUN1-0083 v05_Sample Condition Upon Receipt Effective Date: 05/24/2024 'Check mark top half of box if pH and/or dechlorination is verified and within the WO# 92740754 acceptance range for preservation samples. Project # PM: MWB Due Date: 07/24/24 Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg CLIENT • 92-Greener —Bottom half of box is to list number of bottles "'Check all unpreserved Nitrates for chlorine Laboratory Receiving Location: Asheville ❑ Eden❑ Greenwood ❑ Huntersville [f Raleigh[] Mechanicsville[] Atlanta[—] Kernersville❑ Client 6re,� t Profile/(Circle one)3 (33o7Z Notes — V Q a a a t7 ' — 0 d n J L v = a z- _ 'a Q Q c V 2 ? Q o n 7 - a 7 - n - u c 7 O ti O S o ? x m R 5 u c 8EE y v_ �EE n J E v z O a v S Q ? n n Z N n a m'i c > '^ 1 _ d Z S! J Y o ? c 7 MEE v EE 'a 8 3 E A of E E E v d u d i ¢ — a E < E rn a >> E o E a >> e 0 a E 0 a ea E .ii E vi ICA o: f a Q $ > Si o > d 0 7 _ m a a m a m — a m a m o m i m V Q i7 Q Q l7 Q V a i? D to > > x > cc Am A5 5K7 I J� CIS /i 3 4NN\ \N, 6 �'N 9 i 10 N. I; \N\\\ 11 ', 1 12 \NN\ N\N N I pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted 11 Time preservation adjusted Amount of Preservative added Lot # Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Qualtrax ID: 69614 Page 2 of 2 Page 22 of 23 rr z 3 C C z c I(C C IJ 4 C a o ,n c 2v, n — — 01 n m_ c m 3 — C Q i (i A o a — _ v a fD N = % D o .. O a r xN ��o Cl — m _ _ v C to v D m .°1•. 3 a _a � 3 F ` — 3 v. cn � o io n 0 < D C CL a a e_ — Z n an o f O v a N z d T < w v0 o n V ) S n c Nj ry •G 7 A < J V o N o c 9 c a o o 0 0 a m 3 D n 0 b A _ m n - u > n n N v n n 0 O n f '— o 'o a ,� \ d a — m -° l o u - `• i 3^ °6 i A v N �D 3 In 01 Q V n za ea n v o o 3 o a w D ° w r ^ ? Fir_ n p 7 ,0 3 C N < < < v f 3 3 ° 3 o. n a z z .y N o N 0 ti n O! ° o O v a 2 o— n o a M — n 9 - - - O � t f d r V 3 W) u v J 0 � \ -1 n r1 n A c A N — z fD — o _ 3 n o � Ammonia/ T. Phos 3 u Chloride/ pH ❑� �'�, �lirA 0 v a' Fecal Coliform MF Nitrate a �• o kJ . •'{, fir: r •f❑ 1. 0 0 o 3 3 3 D fJ �J UJ W CJs- n TOC N . A o D m 0. c C y p N u 2 O (�' N 7 Z { R _ a 0 D � a 1 _ n N X O c o 0 : m 0 A v Lab Use Onl a 43 3 o r X — 3 A °° N� Lp� 3 A — 0 CD a r _ a 3 v a s $ j - ° z c 2 — O N Id-id+ed for — — — Pa e 23 of 23 g amble.