NC0025402_Permit renewal application_20090430

/
J
E C E D E
APR 2 1 2009
April 30, 2009
Re:
Dear Ms. Sprinkle,
Sincerely,
Cc:
Town of Enfield • P.O. Box 699 • Enfield. North Carolina 27823 • [phone] • FAX [phone] • Website: www.enfieldnc.org
L
Enclosed for your review is the NPDES Permit renewal package for the Enfield
Wastewater Treatment plant. Our existing permit expires on October 31, 2009. We are
requesting the Division to renew our NPDES Permit. There have been no changes at
the facility since the issuance of the last permit. Please note the results for one priority
pollutant analysis (schedule in August 2009) have not been received. An amended
application will be sent as soon as the results are received.
If you have any questions concerning the information provided, please feel free to give
me a call.
James Pittman
Gary Stainback
Town of Enfield WWTP
NPDES Permit No. NC0025402
Town of Enfield
Bobby Davis
Town Administrator
Ms. Dina Sprinkle
NO DENR/Water Quality/Point Source Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
"Enfield
‘North Carolina
T ou n ded in 17 4 0
fj
DENR - WATER QUALITY
SURFACE WATER PROTECTION SECTION
lER:PERMIT ACTU
BASIC APPLICATION INFORMATION
PART A. BASIC APPLICATION INFORMATION FOR ALL APPLICANTS:
All treatment works must complete questions A.1 through A.8 of this Basic Application Information Packet
Facility Information.A.1.
Facility Name Enfield WWTP
Mailing Address PO Box 699
Enfield, NC 27823
Contact Person Bobby Davis
Title Town Administrator
Telephone Number [phone]
Facility Address 18270 Highway 301 North
(not P.O. Box)Enfield, NC 27823
Applicant Information. If the applicant is different from the above, provide the following:A.2.
Applicant Name Town of Enfield
Mailing Address PO Box 699
Enfield. NC 27823
Contact Person Bobby Davis
Title Town Administrator
Telephone Number [phone]
Is the applicant the owner or operator (or both) of the treatment works?
□ operatorowner
Indicate whether correspondence regarding this permit should be directed to the facility or the applicant.
□ facility applicant
A.3.
PSDNPDESNC0025402
WQ0008Q15OtherUIC
OtherRCRA
A.4.
Type of Collection System OwnershipPopulation ServedName
Town of Enfield2349SanitaryEnfield
Total population served 2349
FACILITY NAME AND PERMIT NUMBER:
RIVER BASIN:PERMIT ACTION REQUESTED:
Page 2 of 21EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.
RIVER BASIN:
Tar Pamlico
FACILITY name and permit
Enfield WWTP, NC0025402
K^toUESTED?
Renewal
Collection System Information. Provide information on municipalities and areas served by the facility. Provide the name and population of each
entity and, if known, provide information on the type of collection system (combined vs. separate) and its ownership (municipal, private, etc.).
Existing Environmental Permits. Provide the permit number of any existing environmental permits that have been issued to the treatment works
(include state-issued permits).
Tar PamlicoEnfield WWTP, NC0025402 Renewal 1A.5.Indian Country.
Is the treatment works located in Indian Country?a.
Yes 0 No
b.
Yes 0 No
A.6.
Design flow ratel.O mgda.
This YearLast YearTwo Years Ago
b.Annual average daily flow rate 0.411 0.5290.569
0.841Maximum daily flow rate 0.7060.982c.
A.7.
%100
Combined storm and sanitary sewer %
A.8.Discharges and Other Disposal Methods.
0 Yes NoDoes the treatment works discharge effluent to waters of the U.S.?a.
If yes, list how many of each of the following types of discharge points the treatment works uses:
i.Discharges of treated effluent 1
ii.Discharges of untreated or partially treated effluent
iii.Combined sewer overflow points
iv.Constructed emergency overflows (prior to the headworks)
Otherv.
b.
0 No
If yes, provide the following for each surface impoundment:
Location:
mgd
Yes 0 NoDoes the treatment works land-apply treated wastewater?c.
If yes, provide the following for each land application site:
Location:
Number of acres:
mgd
intermittent?Is land application
d.
0 No Yes
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.Page 3 of 21
Annual average daily volume applied to site:
continuous or
Annual average daily volume discharge to surface impoundment(s)
Is discharge continuous or intermittent?
Does the treatment works discharge to a receiving water that is either in Indian Country or that is upstream from (and eventually flows
through) Indian Country?
Does the treatment works discharge or transport treated or untreated wastewater to another
treatment works?
0 Separate sanitary sewer
Flow. Indicate the design flow rate of the treatment plant (i.e., the wastewater flow rate that the plant was built to handle). Also provide the
average daily flow rate and maximum daily flow rate for each of the last three years. Each year's data must be based on a 12-month time period
with the 12th month of “this year" occurring no more than three months prior to this application submittal.
Does the treatment works discharge effluent to basins, ponds, or other surface impoundments
that do not have outlets for discharge to waters of the U.S.? Yes
Collection System. Indicate the type(s) of collection system(s) used by the treatment plant. Check all that apply. Also estimate the percent
contribution (by miles) of each.
N/A
If transport is by a party other than the applicant, provide:
Transporter Name
Mailing Address
Contact Person
Title
Telephone Number (
For each treatment works that receives this discharge, provide the following:
Name
Mailing Address
Contact Person
Title
Telephone Number L 1
If known, provide the NPDES permit number of the treatment works that receives this discharge
mgdProvide the average daily flow rate from the treatment works into the receiving facility.
e.
(3 No□ Yes
If yes, provide the following for each disposal method:
Description of method (including location and size of site(s) if applicable):
□ intermittent?Is disposal through this method or
Page 4 of 21EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.
If yes, describe the mean(s) by which the wastewater from the treatment works is discharged or transported to the other treatment works
(e.g., tank truck, pipe).
Does the treatment works discharge or dispose of its wastewater in a manner not included
in A.8. through A.8.d above (e.g., underground percolation, well injection):
Annual daily volume disposed by this method:
□ continuous
RIVER BASIN:
Tar Pamlico
FACILin NAME ANU FERMI I
Enfield WWTP, NC0025402
PERMITACTI^^QUESTEDr
Renewal
1WASTEWATER DISCHARGES:
A.9. Description of Outfall.
Outfall number 001a.
Locationb.
ft.Distance from shore (if applicable)c.
ft.Depth below surface (if applicable)d.
mgdAverage daily flow ratee.
□ Yes 0 No (gotoA.O.g.)Does this outfall have either an intermittent or a periodic discharge?f.
If yes, provide the following information:
Number f times per year discharge occurs:
Average duration of each discharge:
mgdAverage flow per discharge:
Months in which discharge occurs:
0 No□ YesIs outfall equipped with a diffuser?9-
A.10. Description of Receiving Waters.
Name of receiving water Fishing Creeka.
Name of watershed (if known)N/Ab.
N/AUnited States Soil Conservation Service 14-digit watershed code (if known):
Name of State Management/River Basin (if known): Tar Pamlicoc.
N/AUnited States Geological Survey 8-digit hydrologic cataloging unit code (if known):
Critical low flow of receiving stream (if applicable)d.
cfschronicN/AcfsacuteN/A
mg/l of CaCOaTotal hardness of receiving stream at critical low flow (if applicable):N/Ae.
Page 5 of 21ERA Form 3510-2A (Rev. 1-99). Replaces ERA forms 7550-6 & 7550-22.
PERMIT ACTION REQUESTED:
Renewal
R BASIN:
Tar Pamlico
FACILITY NAME AND PERMIT NUMBER:
Enfield WWTP, NC0025402
Enfield_______________
(City or town, if applicable)
Halifax
(County)
NC
(State)
36oO9’O2’’
(Latitude)
27823
(Zip Code)
77°41'17"
(Longitude)
If you answered “Yes” to question A.8.a, complete questions A.9 through A.12 once for each outfall (including bypass points) through
which effluent is discharged. Do not include information on combined sewer overflows in this section. If you answered “No” to question
A.8.a, go to Part B, “Additional Application Information for Applicants with a Design Flow Greater than or Equal to 0.1 mgd.”
PERMIT ACTI01
A.11. Description of Treatment
a.
Describe:
b.
Design BODS removal or Design CBOD5 removal 95 %
Design SS removal 91 %
Design P removal N/A %
Design N removal N/A %
Other %
What type of disinfection is used for the effluent from this outfall? If disinfection varies by season, please describe:c.
Chlorine
If disinfection is by chlorination is dechlorination used for this outfall? Yes No
Does the treatment plant have post aeration? Yes S No
Outfall number:001
MAXIMUM DAILY VALUE AVERAGE DAILY VALUEPARAMETER
Value Units Value Units Number of Samples
6.3 s.u.
7.14 s.u.
Flow Rate 0.841 MGD 0.529 MGD 366
Temperature (Winter)20.0 Degrees 15.5 Degrees 126.5
Temperature (Summer)27.0 22.4 Degrees 126.5
AVERAGE DAILY DISCHARGE
POLLUTANT ML/MDL
Cone.Units Cone.Units
CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS
BODS 8.6 Mg/I 3.6 Mg/I 159 SM5210B 2.0 mg/l
CBOD5
FECAL COLIFORM 1895.3 #/100ml 307.3 #/100ml 171 SM9222D
TOTAL SUSPENDED SOLIDS (TSS)25.5 Mg/I 9.5 Mg/I 159 SM2540D 1.0 mg/l
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.Page 6 of 21
pH (Minimum)
pH (Maximum)
END OF PART A.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
What level of treatment are provided? Check all that apply.
Primary 0 Secondary
Number of
Samples
ANALYTICAL
METHOD
RIVER BASIN:
Tar Pamlico
1.0
CFU/100ML
BIOCHEMICAL OXYGEN
DEMAND (Report one)
Advanced other.
Indicate the following removal rates (as applicable):
___________________________Degrees
* For pH please report a minimum and a maximum daily value
MAXIMUM DAILY
DISCHARGE
ZTiO^fcoUESTED?
Renewal
FACILITY NAME AND PERMIT nWEER:
Enfield WWTP, NC0025402
A.12. Effluent Testing Information. All Applicants that discharge to waters of the US must provide effluent testing data for the following
parameters. Provide the indicated effluent testing required by the permitting authority for each outfall through which effluent is
discharged. Do not include information on combined sewer overflows in this section. All information reported must be based on data
'tected through analysis conducted using 40 CFR Part 136 methods. In addition, this data must comply with QA/QC requirements of
40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. At a
minimum, effluent testing data must be based on at least three samples and must be no more than four and one-half years apart.
BASIC APPLICATION INFORMATION
PART B.

topographic map of the area extending at least one mile beyond facility property boundaries.
e.
f.
B.3.
B.4.
United WaterName:
Mailing Address:
B.5.
a.
b.
Page 7 of 21EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.
Telephone Number:
Responsibilities of Contractor.
PERMIT ACTION REQUESTED:
Renewal
R BASIN:
Tar Pamlico
FACILITY NAME AND PERMIT NUMBER:
Enfield WWTP, NC0025402
Indicate whether the planned improvements or implementation schedule are required by local, State, or Federal agencies.
Yes No
c.
d. Wells, springs, other surface water bodies.
ADDITIONAL APPLICATION INFORMATION FOR APPLICANTS WITH A DESIGN FLOW GREATER THAN OR
EQUAL TO 0.1 MGD (100,000 gallons per day).
All applicants with a design flow rate > 0.1 mgd must answer questions B.1 through B.6. All others go to Part C (Certification).-----------------------
B.1. Inflow and Infiltration. Estimate the average number of gallons per day that flow into the treatment works from inflow and/or infiltration.
N/A gpd
Briefly explain any steps underway or planned to minimize inflow and infiltration.
Operation/Maintenance Performed by Contractor(s).
Are any operational or maintenance aspects (related to wastewater treatment and effluent quality) of the treatment works the responsibility of a
contractor? El Yes No
If yes. list the name, address, telephone number, and status of each contractor and describe the contractor’s responsibilities (attach additional
pages if necessary).
B-2'
area.) See Attached
a. The area surrounding the treatment plant, including all unit processes.
b The major pipes or other structures through which wastewater enters the treatment works and the pipes or other structures through which
treated wastewater is discharged from the treatment plant. Include outfalls from bypass piping, if applicable.
Each well where wastewater from the treatment plant is injected underground.
.,a_, ‘ " >, and drinking water wells that are: 1) within % mile of the property boundaries of the treatment
works, and 2) listed in public record or otherwise known to the applicant.
Any areas where the sewage sludge produced by the treatment works is stored, treated, or disposed. See Attached
If the treatment works receives waste that is classified as hazardous under the Resource Conservation and Recovery Act (RCRA) by truck, rail,
or spedal ?ipe S on the map where the hazardous waste enters the treatment works and where it is treated, stored, and/or d.sposed.
Process Flow Diagram or Schematic. Provide a diagram showing the processes of the treatment plant, including all bypass piping and all
hackuo oower sources or redunancy in the system. Also provide a water balance showing all treatment units, including disinfection (e.g.,
chlorination and dechlorination). The water balance must show daily average flow rates at influent and discharge points and approx.mate daily flow
rates between treatment units. Include a brief narrative description of the diagram. See Attached
PO Box 1279 ______________________
Clemmons, NC 27012----------------------------------------------------------------------------------
[phone]
Operation and Maintenance of VWVTP
Scheduled improvements and Schedules of Implementation. Provide information on any uncompleted implementation schedule or
uncompleted ptens for improvements that will affect the wastewater treatment, effluent quality, or design capacity of the treaty works. f the
treatment works has several different implementation schedules or is planning several improvements, submit separate responses to question B.5
for each. (If none, go to question B.6.) None
List the outfall number (assigned in question A.9) for each outfall that is covered by this implementation schedule.
FACILITY NAME AND PERMIT N ER:
Enfield WWTP, NC0025402
If the answer to B.5.b is “Yes," briefly describe, including new maximum daily inflow rate (if applicable).c.
d.
Schedule Actual Completion
Implementation Stage MM/DD/YYYY MM/DD/YYYY
- Begin Construction I L I
L /- End Construction //
/L I /- Begin Discharge
//- Attain Operational Level /L
□ Yes □ NoHave appropriate permits/clearances concerning other Federal/State requirements been obtained?e.
Describe briefly:
Outfall Number: 001
AVERAGE DAILY DISCHARGE
MUMDLPOLLUTANT
Cone.UnitsCone.Units
0.1 mg/lSM4500WH3FMg/l 1592.31 Mg/l 0.74
2 ug/lSM2540F3.9 Ug/l 16511.8 Ug/l
SM4500G 0 mg/l164Mg/l 7.97 Mg/lDISSOLVED OXYGEN 9.98
SM4500WORGC 1.0 mg/lMg/l 244.86 Mg/l 2.29
0.01 mg/lEPA353.2Mg/l 10.13 Mg/l 0.13
1664A 5.0 mg/l123.5 Mg/l23.5 Mg/lOIL and GREASE
SM4500PE 0.01 mg/l0.35 Mg/l 24PHOSPHORUS (Total)0.74 Mg/l
1.0 mg/l160.11128Mg/l128Mg/l
OTHER
Page 8 of 21EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.
RIVER BASIN:
Tar Pamlico
B.6. EFFLUENT TESTING DATA (GREATER THAN 0.1 MGD ONLY).
Applicants that discharge to waters of the US must provide effluent testing data for the following parameters. Provide the indicated
effluent testing required by the permitting authority for each outfall through which effluent is discharged. Do not include information
on combine sewer overflows in this section. All information reported must be based on data collected through analysis conducted
using 40 CFR Part 136 methods. In addition, this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate
QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. At a minimum effluent testing data must be
based on at least three pollutant scans and must be no more than four and on-half years old.
CHLORINE (TOTAL
RESIDUAL, TRO)
TOTAL KJELDAHL
NITROGEN (TKN)
TOTAL DISSOLVED SOLIDS
(TDS)
NITRATE PLUS NITRITE
NITROGEN
END OF PART B.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
Provide dates imposed by any compliance schedule or any actual dates of completion for the implementation steps listed below, as
applicable. For improvements planned independently of local, State, or Federal agencies, indicate planned or actual completion dates, as
applicable. Indicate dates as accurately as possible.
MAXIMUM DAILY
DISCHARGE
Number of
Samples
ANALYTICAL
METHOD
CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS
AMMONIA (as N)
PERMIT ACTK^feoUESTED?
Renewal
BASIC APPLICATION INFORMATION
PARTC. CERTIFICATION
ALL APPLICANTS MUST COMPLETE THE FOLLOWING CERTIFICATION.
Name and official title
Signature
Telephone number
Date signed
SEND COMPLETED FORMS TO:
27699-1617
Page 9 of 21EPA Form 3510-2A (Rev. 1-99). Replaces ERA forms 7550-6 & 7550-22.
All applicants must complete the Certification Section. Refer to instructions to determine who is an officer for the purposes of this
certification. All applicants must complete all applicable sections of Form 2A, as explained in the Application Overview. Indicate below which
parts of Form 2A you have completed and are submitting. By signing this certification statement applicants confirm that they have reviewed
Form 2A and have completed all sections that apply to the facility for which this application is submitted.
PERMIT ACTION REQUESTED:
Renewal
'ER BASIN:
Tar Pamlico
NCDENR/ DWQ
Attn: NPDESUnit
1617 Mail Service Center
Raleigh, North Carolina
FACILITY NAME AND PERMIT NUMBER:
Enfield WWTP, NC0025402
Bobby Davis TowXAdprfnfetrator
(252)3146
Upon request of the permitting authority, you must submit any other information necessary to assure wastewater treatment practices at the treatment
works or identify appropriate permitting requirements.
Indicate which parts of Form 2A you have completed and are submitting:
E] Basic Application Information packet Supplemental Application Information packet:
El Part D (Expanded Effluent Testing Data)
EJ Part E (Toxicity Testing: Biomonitoring Data)
□ Part F (Industrial User Discharges and RCRA/CERCLA Wastes)
□ Part G (Combined Sewer Systems)
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who
manage the system or those persons directly responsible for gathering the information, the information is, to the best of my knowledge and belief, true,
accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment
for knowing violations.
RIVER BASIN:
Tar PamlicoRenewalEnfield WWTP, NC0025402
SUPPLEMENTAL APPLICATION INFORMATION
PART D. EXPANDED EFFLUENT TESTING DATA
Refer to the directions on the cover page to determine whether this section applies to the treatment works.
AVERAGE DAILY DISCHARGEMAXIMUM DAILY DISCHARGE
ML/MDLPOLLUTANT
Cone.Units Mass UnitsCone.Units Mass Units
METALS (TOTAL RECOVERABLE), CYANIDE, PHENOLS, AND HARDNESS.
ANTIMONY
ARSENIC
BERYLLIUM
CADMIUM
CHROMIUM
COPPER
LEAD
MERCURY
NICKEL
SELENIUM
SILVER
THALLIUM
ZINC
CYANIDE
HARDNESS (as CaCO3)
Use this space (or a separate sheet) to provide information on other metals requested by the permit writer
Page 10 of 21EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.
TOTAL PHENOLIC
COMPOUNDS
Number
of
Samples
ANALYTICAL
METHOD
Effluent Testing: 1.0 mgd and Pretreatment Works. If the treatment works has a design flow greater than or equal to 1.0 mgd or it has (or is required
to have) a pretreatment program, or is otherwise required by the permitting authority to provide the data, then provide effluent testing data for the following
pollutants. Provide the indicated effluent testing information and any other information required by the permitting authority for each outfall through which
effluent is discharged. Do not include information on combined sewer overflows in this section. All information reported must be based on data collected
through analyses conducted using 40 CFR Part 136 methods. In addition, these data must comply with QA/QC requirements of 40 CFR Part 136 and
other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. Indicate in the blank rows provided below
any data you may have on pollutants not specifically listed in this form. At a minimum, effluent testing data must be based on at least three pollutant
scans and must be no more than four and one-half years old. SEE ATTACHED, Please note that a PPA is scheduled for August 2009, will send
when results are received.Outfall number: 001(Complete once for each outfall discharging effluent to waters of the United States.)
PERMfrACTio^feoUESTED?FACILITY NAME AND PERMrFNI^fcRr
R BASIN:PERMIT ACTION REQUESTED:FACILITY NAME AND PERMIT NUMBER:
Tar PamlicoRenewalEnfield WWTP, NC0025402
(Complete once for each outfall discharging effluent to waters of the United States.)Outfall number:
AVERAGE DAILY DISCHARGEMAXIMUM DAILY DISCHARGE
ML/MDLPOLLUTANT
Units Mass UnitsCone.Units Mass Units Cone.
VOLATILE ORGANIC COMPOUNDS
ACROLEIN
ACRYLONITRILE
BENZENE
BROMOFORM
CHLOROBENZENE
CHLOROETHANE
CHLOROFORM
1,1-DICHLOROETHANE
1,2-DICHLOROETHANE
1,2-DICHLOROPROPANE
ETHYLBENZENE
METHYL BROMIDE
METHYL CHLORIDE
METHYLENE CHLORIDE
TOLUENE
Page 11 of 21ERA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.
Number
of
Samples
CHLORODIBROMO­
METHANE
ANALYTICAL
METHOD
CARBON
TETRACHLORIDE
2-CHLOROETHYLVINYL
ETHER
DICHLOROBROMO­
METHANE
TRANS-1.2-DICHLORO-
ETHYLENE
TETRACHLORO­
ETHYLENE
1,1-DICHLORO-
ETHYLENE
1,3-DICHLORO-
PRORYLENE
1,1,2,2-TETRA-
CHLOROETHANE
RIVER BASIN:
Tar PamlicoRenewalEnfield WWTP, NC0025402
(Complete once for each outfall discharging effluent to waters of the United States.)Outfall number: 001
AVERAGE DAILY DISCHARGEMAXIMUM DAILY DISCHARGE
ML/MDLPOLLUTANT
Units Mass UnitsMassUnitsCone.Cone.Units
TRICHLOROETHYLENE
VINYL CHLORIDE
Use this space (or a separate sheet) to provide information on other volatile organic compounds requested by the permit writer
ACID-EXTRACTABLE COMPOUNDS
P-CHLORO-M-CRESOL
2-CHLOROPHENOL
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
4,6-DINITRO-O-CRESOL
2,4-DINITROPHENOL
2-NITROPHENOL
4-NITROPHENOL
PENTACHLOROPHENOL
PHENOL
Use this space (or a separate sheet) to provide information on other acid-extractable compounds requested by the permit writer
BASE-NEUTRAL COMPOUNDS
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZIDINE
BENZO(A)ANTHRACENE
BENZO(A)PYRENE
Page 12 of 21EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.
Number
of
Samples
ANALYTICAL
METHOD
1,1,1-
TRICHLOROETHANE
2,4,6-
TRICHLOROPHENOL
1,1.2-
TRICHLOROETHANE
PERMIT ACTIO^^QUESTEdTFACILITY NAME AND PERMIT N^^R?
PERMIT ACTION REQUESTED:FACILITY NAME AND PERMIT NUMBER:
Tar PamlicoRenewalEnfield WWTP, NC0025402
Outfall number:
MAXIMUM DAILY DISCHARGE
ML/MDLPOLLUTANTUnitsCone.Units MassUnitsCone.Units Mass
BENZO(GHI)PERYLENE
CHRYSENE
DI-N-BUTYL PHTHALATE
DI-N-OCTYL PHTHALATE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
2,4-DINITROTOLUENE
2,6-DINITROTOLUENE
Page 13 of 21EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.
(Complete once for each outfall discharging effluent to waters of the United States.)
AVERAGE DAILY DISCHARGE
Number
of
Samples
BIS (2-CHLOROETHOXY)
METHANE
4-BROMOPHENYL
PHENYL ETHER
BUTYL BENZYL
PHTHALATE
3,3-DICHLORO-
BENZIDINE
ANALYTICAL
METHOD
3,4 BENZO­
FLUORANTHENE
BENZO(K)
FLUORANTHENE
BIS (2-CHLOROETHYL)-
ETHER
BIS (2-CHLOROISO-
PROPYL) ETHER
BIS (2-ETHYLHEXYL)
PHTHALATE
2-CHLORO-
NAPHTHALENE
4-CHLORPHENYL
PHENYL ETHER
DIBENZO(A.H)
ANTHRACENE
1,2-DIPHENYL-
HYDRAZINE
^^ERBASIN?
RIVER BASIN:FACILITY NAME AND PERMIT Nl
Tar PamlicoRenewalEnfield WWTP, NC0025402
(Complete once for each outfall discharging effluent to waters of the United States.)Outfall number: 001.
MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE
ML/MDLPOLLUTANT
Units Cone.Units Mass UnitsCone.Units Mass
FLUORANTHENE
FLUORENE
HEXACHLOROBENZENE
HEXACHLOROETHANE
ISOPHORONE
NAPHTHALENE
NITROBENZENE
PHENANTHRENE
PYRENE
Use this space (or a separate sheet) to provide information on other base-neutral compounds requested by the permit writer
Use this space (or a separate sheet) to provide information on other pollutants (e g., pesticides) requested by the permit writer
Page 14 of 21EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.
END OF PART D.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
Number
of
Samples
ANALYTICAL
METHOD
HEXACHLORO­
BUTADIENE
HEXACHLOROCYCLO-
PENTADIENE
INDENO(1,2,3-CD)
PYRENE
N-NITROSODI-N-
PROPYLAMINE
N-NITROSODI-
METHYLAMINE
N-NITROSODI-
PHENYLAMINE
1,2,4-
TRICHLOROBENZENE
PERMIT ACTIO^^QUESTEdT
SUPPLEMENTAL APPLICATION INFORMATION
PART E. TOXICITY TESTING DATA
E.1. Required Tests.
Indicate the number of whole effluent toxicity tests conducted in the past four and one-half years.
chronic acute SEE ATTACHED
E.2.
Test number: Test number: Test number:
Test information.a.
Test Species & test method number
Age at initiation of test
Outfall number
Dates sample collected
Date test started
Duration
b.Give toxicity test methods followed.
Manual title
Edition number and year of publication
Page number(s)
Give the sample collection method(s) used. For multiple grab samples, indicate the number of grab samples used.c.
24-Hour composite
Grab
d. Indicate where the sample was taken in relation to disinfection. (Check all that apply for each.
Before disinfection
After disinfection
After dechlorination
Page 15 of 21EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.
PERMIT ACTION REQUESTED:
Renewal
ER BASIN:
Tar Pamlico
FACILITY NAME AND PERMIT NUMBER:
Enfield WWTP, NC0025402
POTWs meeting one or more of the following criteria must provide the results of whole effluent toxicity tests for acute or chronic toxicity for each of the
facility’s discharge points: 1) POTWs with a design flow rate greater than or equal to 1.0 mgd; 2) POTWs with a pretreatment program (or those that are
required to have one under 40 CFR Part 403); or 3) POTWs required by the permitting authority to submit data for these parameters.
• At a minimum, these results must include quarterly testing for a 12-month period within the past 1 year using multiple species (minimum of two
species), or the results from four tests performed at least annually in the four and one-half years prior to the application, provided the results
show no appreciable toxicity, and testing for acute and/or chronic toxicity, depending on the range of receiving water dilution. Do not include
information on combined sewer overflows in this section. All information reported must be based on data collected through analysis conducted
using 40 CFR Part 136 methods. In addition, this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QA/QC
requirements for standard methods for analytes not addressed by 40 CFR Part 136.
• In addition, submit the results of any other whole effluent toxicity tests from the past four and one-half years. If a whole effluent toxicity test
conducted during the past four and one-half years revealed toxicity, provide any information on the cause of the toxicity or any results of a
toxicity reduction evaluation, if one was conducted.
• If you have already submitted any of the information requested in Part E, you need not submit it again. Rather, provide the information
requested in question E.4 for previously submitted information. If EPA methods were not used, report the reasons for using alternate methods.
If test summaries are available that contain all of the information requested below, they may be submitted in place of Part E.
If no biomonitoring data is required, do not complete Part E. Refer to the Application Overview for directions on which other sections of the form to
complete.
Individual Test Data. Complete the following chart for each whole effluent toxicity test conducted in the last four and one-half years. Allow one
column per test (where each species constitutes a test). Copy this page if more than three tests are being reported.
FACILITY NAME AND PERMIT N1 RIVER BASIN:
Test number:Test number:Test number:
Describe the point in the treatment process at which the sample was collected.e.
Sample was collected:
For each test, include whether the test was intended to assess chronic toxicity, acute toxicity, or bothf.
Chronic toxicity
Acute toxicity
Provide the type of test performed.9-
Static
Static-renewal
Flow-through
Source of dilution water. If laboratory water, specify type; if receiving water, specify source.h.
Laboratory water
Receiving water
Type of dilution water. If salt water, specify “natural" or type of artificial sea salts or brine used.
Fresh water
Salt water
Give the percentage effluent used for all concentrations in the test series.j-
Parameters measured during the test. (State whether parameter meets test method specifications)k.
pH
Salinity
Temperature
Ammonia
Dissolved oxygen
I.Test Results.
Acute:
%%%
LC50
%%%95% C.l.
%%%Control percent survival
Other (describe)
Page 16 of 21EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.
Percent survival in 100%
effluent
^^R?PERMIT ACTIO^^QUESTED?
PERMIT ACTION REQUESTED:FACILITY NAME AND PERMIT NUMBER:
Chronic:
%%%NOEC
%%%IC25
%%%Control percent survival
Other (describe)
m. Quality Control/Quality Assurance.
Is reference toxicant data available?
/II I II
Other (describe)
E.3. Toxicity Reduction Evaluation. Is the treatment works involved in a Toxicity Reduction Evaluation?
Yes No If yes, describe:
/IDate submitted:(MM/DD/YYYY)
Summary of results: (see instructions)
EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.Page 17 of 21
Was reference toxicant test within
acceptable bounds?
E.4. Summary of Submitted Biomonitoring Test Information. If you have submitted biomonitoring test information, or information regarding the
cause of toxicity, within the past four and one-half years, provide the dates the information was submitted to the permitting authority and a summary
of the results.
END OF PART E.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE.
What date was reference toxicant test
run (MM/DD/YYYY)?
^^ER BASIN:
QUESTED:RIVER BASIN:FACILITY NAME AND PERMIT N
SUPPLEMENTAL APPLICATION INFORMATION
PART F. INDUSTRIAL USER DISCHARGES AND RCRA/CERCLA WASTES
Pretreatment program. Does the treatment works have, or is subject ot, an approved pretreatment program?F.1.
0 No Yes
F.2.
Number of non-categorical SIUs. a.
Number of CIUs. b.
SIGNIFICANT INDUSTRIAL USER INFORMATION:
F.3.
Name:
Mailing Address:
Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU’s discharge.F.4.
F.5.
Principal product(s):
Raw material(s):
F.6.
a.
continuous or
b.
intermittent)continuous or ( gpd
Pretreatment Standards. Indicate whether the SIU is subject to the following:F.7.
No YesLocal limitsa.
Yes NoCategorical pretreatment standardsb.
If subject to categorical pretreatment standards, which category and subcategory?
Page 18 of 21EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.
Number of Significant Industrial Users (SIUs) and Categorical Industrial Users (CIUs). Provide the number of each of the following types of
industrial users that discharge to the treatment works.
All treatment works receiving discharges from significant industrial users or which receive RCRA.CERCLA, or other remedial wastes must
complete part F.
GENERAL INFORMATiON: - • ■ ' ~
gpd ( continuous or intermittent)
Non-process wastewater flow rate. Indicate the average daily volume of non-process wastewater flow discharged into the collection system
in gallons per day (gpd) and whether the discharge is continuous or intermittent.
PERMITACTIC^fei
Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages
as necessary.
Principal Product(s) and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU’s
discharge.
Flow Rate.
Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per
day (gpd) and whether the discharge is continuous or intermittent.
Supply the following information for each SIU. If more than one SIU discharges to the treatment works, copy questions F.3 through F.8 and
provide the information requested for each SIU.
R BASIN:PERMIT ACTION REQUESTED:FACILITY NAME AND PERMIT NUMBER:
F.8.
RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL, OR DEDICATED PIPELINE:
RCRA Waste. Does the treatment works receive or has it in the past three years received RCRA hazardous waste by truck, rail or dedicated pipe?F.9.
Yes
Rail Dedicated Pipe Truck
UnitsAmount
F.12. Remediation Waste. Does the treatment works currently (or has it been notified that it will) receive waste from remedial activities?
Yes (complete F.13 through F.15.)No
F.15. Waste Treatment
Is this waste treated (or will be treated) prior to entering the treatment works?a.
Yes No
If yes, describe the treatment (provide information about the removal efficiency):
Is the discharge (or will the discharge be) continuous or intermittent?b.
Continuous Intermittent If intermittent, describe discharge schedule.
Page 19 of 21EPA Form 3510-2A (Rev. 1-99). Replaces EPA forms 7550-6 & 7550-22.
END OF PART F.
REFER TO THE APPLICATION OVERVIEW (PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems (e.g.,
upsets, interference) at the treatment works in the past three years?
Yes No If yes, describe each episode.
F.14. Pollutants. List the hazardous constituents that are received (or are expected to be received). Include data on volume and concentration, if
known. (Attach additional sheets if necessary.)
F.13. Waste Origin. Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates (or is excepted to origniate in
the next five years).
F.11. Waste Description. Give EPA hazardous waste number and amount (volume or mass, specify units).
EPA Hazardous Waste Number
No (go to F.12)
F.10. Waste transport Method by which RCRA waste is received (check all that apply):
CERCLA (SUPERFUND) WASTEWATER, RCRA REMEDIATION/CORRECTIVE ACTION
WASTEWATER, AND OTHER REMEDIAL ACTIVITY WASTEWATER:
Topographic Map
03-03-04
North
Facility
Location
Enfield WWTP
NC0025402
Halifax County
....
' • - ■
Facility Information
36°09’02”N Sub-Basin:
77°41’17” W
C28NW
CNSW
Latitude:
Longitude:
Quad#:
Stream Class:
Receiving Stream: Fishing Creek
Permitted Flow: 1.0 MGD
Station
0
□
XS7
Bricks
/
/
Bricks
t ■ * 1
......... ,^^(IgWTE
^00025402
Plant Schematic
Enfield Wastewater Treatment Plant
Influent
Clarifier Clarifier
/■
_/
(
>
Sludge
Storage
Grit
Removal
Bar
Screen
Sludge Disposal
(Land Application) *
Aeration
Basin
Return
Waste
Sludge
Sludge
Stabilization
Chlorine
Contact
Chamber
Fishing
Creek
Influent
Return
Sludge
Pump
Station
/
Priority Pollutant Analysis
nitoring and Pollutant Seainuali
Parameter
0.01
1
1
1
1
1
1
1
1
1
Page 1Form - DMR- PPA-1
1
1
1
1
1
1
Analytical
Method
Quantitation
Level
Sample
Result
Units of
Measurement
Number of
samples
Month March
Year 2007
Permit No. NC0025402
Outfall 001
Facility Name Enfield WWTP
Date of sampling 3/13/07
Analytical Laboratory TriTest
ORC James Pittman
Phone [phone]
1
1
1
1
1
1
Copper
Lead
Sample
Type
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Grab
Grab
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
200.7
213.2
200.7
200.7
239.2
245.1
200.7
270.2
200.7
279.2
288.1
4500C/E
510A/B
350.1
4500QG
353.2
351.2
365.2
2540C
2340C
4500CL
5520B
204.2
206.2
624
624
624
624
624
624
624
624
624
624
624
624
624
624
0.001
0.001
0.01
0.001
0.005
0.0002
0.01
0.01
0.005
0.01
0.01
0.005
0.002
0.003
0.005
100
’so”
5
"T~
5
5
T”
10
5
5
5
"T"
T"
<0.003
<0.005
1.68
8.4
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
UG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
Ammonia (as N)
Dissolved oxygen
Nitrate/Nitrite_______________
Total Kjeldahl nitrogen
Total Phosphorus
Total dissolved solids
Hardness___________________
Chlorine (total residual, TRC)
Oil and grease
Metals (total recoverable), cyanide and total phenols
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Mercury
Nickel
Selenium
Silver_______________________
Thallium
Zinc
Cyanide
Total phenolic compounds
Volatile organic compounds
Acrolein
Acrylonitrile
Benzene
Bromoform ________________
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
2-chloroethylvinyl ether
Chloroform
Dichlorobromomethane
1,1 -dichloroethane
1,2-dichloroethane
Trans-1,2-dichloroethylene
1
0.622
2
20
<0.002
>0.005
<0.010
<0.010
<0.005
<0.0002
<0.010
<0.002
<0.010
<0.001
0.012
<0.005
<.005
2.26
2.99
0.2
119
31.7
<20
16
<50
<50
<5
<5
TTo
TIo
<5
<5
”77
Ts"
“TT
o.i
0
0.01
1
Page 1 of
Chain of Custody
Sampled By:
Attn: Nadine Blackwell
Fax:
analysis Requeste<
St(’in
V\/W? 77-07
002wwGGrab
iture)Relinquished by (si<
cReceived by (signature)
SanW Description '
•_______________’• ' _____——I—
c
Project Reference:
Project Number:
Purchase Order #:
For Lab Use Only:
Temperatue at receipt:
Report Results To:
HMS/ Enfield WWTP
PO Box 818
Enfield, NO 27813
Priority Pollutant Analysis
03
Bill Results To:
Hydro Management Services
Enfield WWTP
PO Box 1279
Clemmons, NO 27012
5-^0 7
□ .4+2 0
Temp:.
■: ■T.ipp:
Composite
oTTER-oTSST
6701 Conference Drive, Raleigh, NC 27607
ph: [phone] fax: [phone]
NCWW Cert #67, NCDW Cert # 37731
ReceivaZy (signature) /"’xZZ
Received toy (signature) / ,Time
■ /z
Time
Tritest W.O. 0702-01435
[Zzfstandard Report Delivery
□ Rush Report Delivery (w/ surcharge)
Note: Rush projects are subject to prior approval by Lab
Requested Due Date:
Attn: Tony Gorham
Phone: [phone]
Lead, Antimony, Arsenic, Beryllium, Cadmium, Chromium, Copper,
Mercury Nickel, Selenium, Silver, Thallium, Zinc, Ammonia, Total
Kjeldahl Nitrogen, Nitrate-Nitrite, Total Nitrogen Calculation, Total
Phosphorus, Total Dissolved Solids, Metals Prep,
TOTAL HARDNESS (WW), Calcium, Magnesium, Total Hardness
Calculation ______
Cyanide, Oil & Grease, Phenols w/chloroform extr., Volatiles by 8260B,
8270 (A&B/N), Extraction, 8270 Waters
'Stan Date Stop Date
Startjrime
3-^ 7
Sm t
001
Date _ ~ _ Time A3-13'07 \ /'t? • 7^
Date
Relinqui^ci by (signature^/
l^linquisheT'by (^igrfatur^^ (

/latnx^
Page 5 of 5
Laboratory Report
Work Order #: 0702-01435
QualifierResultsMethodTest Performed
Reviewed by:
for Tritest, Inc?
Phenanthrene
Phenol
Pyrene
Pyridine
1.2.4- Trichlorobenzene
2.4.5- Trichlorophenol
2.4.6- Trichlorophenol
Extraction, 8270 Waters
Sample ID
Grab
EPA8270C
EPA 8270C
EPA8270C
EPA8270C
EPA8270C
EPA 8270C
EPA 8270C
EPA 3510
Time Sampled
9:50
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<20 ug/L
<10 ug/L
DONE
Sample Type
Grab
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
Analyzed
Date Time
Condition
4 +/- 2 deg CNo.
002
o
o
TOoTEST
6701 Conference Drive
Raleigh, NC 27607
Date Sampled
3/13/2007
Matrix
WW
NC/WW Cert. #: 067
NC/DW Cert. #: 37731Telephone: [phone]
Fax: [phone]
-v
Page 4 of 5
Laboratory Report
Work Order#: 0702-01435
QualifierResultsMethodTest Performed
No.
002
Telephone: [phone]
Fax: [phone]
Sample ID
Grab
EPA8270C
ERA 8270C
ERA 8270C
ERA8270C
EPA8270C
EPA8270C
ERA8270C
EPA8270C
EPA8270C
EPA8270C
EPA8270C
EPA8270C
EPA8270C
EPA8270C
ERA 8270C
EPA8270C
EPA8270C
ERA 8270C
EPA8270C
ERA 8270C
ERA8270C
ERA 8270C
ERA 8270C
ERA 8270C
EPA8270C
ERA 82700
ERA 8270C
ERA8270C
ERA 8270C
EPA8270C
EPA8270C
ERA 82700
EPA8270C
EPA8270C
ERA 82700
EPA8270C
ERA 82700
EPA8270C
EPA8270C
EPA8270C
ERA 8270C
EPA8270C
EPA8270C
ERA8270C
Time Sampled
9:50
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<20 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<50 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<50 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<20 ug/L
<10 ug/L
<10 ug/L
<20 ug/L
<20 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<30 ug/L
Sample Type
Grab
NC/WW Cert. #: 067
NC/DW Cert. #: 37731
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
Analyzed
Date Time
2-Chloronaphthalene
4-Chloro-3-methylphenol
2-Chlorophenol
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
Dibenzofuran
Di-n-butyl phthalate
3,3’-Dichlorobenzidine
1.2- Dichlorobenzene
1.3- Dichlorobenzene
1.4- Dichlorobenzene- -
2.4- Dichlorophenol
Diethyl phthalate
2.4- Dimethylphenol
Dimethyl phthalate
2.4- Dinitrophenol
2.4- Oinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
Isophorone
2-Methyl-4,6-dinitrophenol
1- Methylnaphthalene
2- Methylnaphthalene
2- Methylphenol
3- & 4-Methylphenol
Naphthalene
2- Nitroaniline
3- Nitroaniline
4- Nitroaniline
Nitrobenzene
2-Nitrophenol-
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitrosodiphenylamine
N-Nitrosodi-n-propylamine
Pentach lorophenol
6701 Conference Drive
Raleigh, NC 27607
Date Sampled
3/13/2007
Condition
4 +/- 2 deg C
Matrix
WW
1%8TEST
Page 3 of 5
Laboratory Report
Work Order #: 0702-01435
QualifierResultsMethodTest Performed
Sample ID
Grab
6701 Conference Drive
Raleigh, NC 27607
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA 8260B
EPA8260B
EPA8260B
EPA8260B
EPA 8260B
EPA8260B
EPA 8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8270C
EPA 8270C
EPA8270C
EPA 8270C
EPA8270C
EPA8270C
EPA 8270C
EPA 8270C
EPA8270C
EPA 8270C
EPA 8270C
EPA8270C
EPA8270C
EPA 8270C
EPA8270C
EPA8270C
EPA8270C
EPA 8270C
EPA8270C
EPA8270C
EPA8270C
EPA8270C
EPA8270C
Time Sampled
9:50
<50 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<10 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<15 ug/L
<5 ug/L
<10 ug/L
<50 ug/L
<10 ug/L
<5 ug/L
<5 ug/L
<100 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<20 ug/L
<20 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<50 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<20 ug/L
Sample Type
Grab
NC/WW Cert. #: 067
NC/DW Cert. #: 37731
Condition
4 +/- 2 deg C
No.
002
Date Sampled
3/13/2007
Matrix
WW .
Telephone: [phone]
Fax: [phone]
MIBK (4-Methyl-2-pentanone)
n-Propylbenzene
Styrene
1.1.1.2- Tetrachloroethane
1.1.2.2- Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1.1.1- Trichloroethane
1.1.2- Trichloroethane
Trichloroethene
Trichlorofluoromethane
1.2.3- Trichloropropane
1.2.4- Trimethylbenzene
1.3.5- Trimethylbenzene
Vinyl acetate
Vinyl chloride
o-Xylene
m- & p-Xylene
trans-1,4-Dichloro-2-butene
lodomethane
8270 (A&B/N)
Acenaphthene
Acenaphthylene
Acetophenone
2-Acety I a m i n of I u o re n e
4-Aminobiphenyl
Aniline
Anthracene
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Benzo(g,h,i)perylene
Benzoic acid
Benzyl alcohol
Benzyl butyl phthalate
Bis(2-chloroethyl)ether
Bis(2-chloroethoxy)methane
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-Bromophenyl phenyl ether
Carbazole
4-Chloroaniline
o
TOSTEST
Analyzed
Date Time
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
4/2/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
3/19/07 8:00
Page 2 of 5
Laboratory Report
Work Order #: 0702-01435
QualifierResultsMethodTest Performed
No.
002
Acrolein
Acrylonitrile
Benzene
Bromodichloromethane
Bromobenzene
Bromochloromethane
Bromoform
Bromomethane
sec-Butylbenzene
tert-Butylbenzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Dibromochloromethane
1.2- Dibromo-3-chloropropane
1.2- Dibromoethane
Dibromomethane
1.2- Dichlorobenzene
1.3- Dichlorobenzene
1.4- Dichlorobenzene
Dichlorodifluoromethane
1.1- Dichloroethane
1.2- Dichloroethane
1.1- Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1.2- Dichloropropane
1.3- Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
Isopropylbenzene
p-lsopropyltoluene
Methylene chloride
Methyl ethyl ketone (MEK)
Sample ID
Grab
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA 8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA 8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA 8260B
EPA8260B
EPA 8260B
EPA8260B
EPA8260B
EPA 8260B
Time Sampled
9:50
Sample Type
Grab
NC/WW Cert. #: 067
NC/DWCert#: 37731
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
3/14/07 7:12
Analyzed
Date Time
Condition
4 +/- 2 deg C
Telephone: [phone]
Fax: [phone]
6701 Conference Drive
Raleigh, NC 27607
Date Sampled
3/13/2007
<50 ug/L
<50 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<10 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<10 ug/L
<10 ug/L
<5 ug/L
<10 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<25 ug/L
<5 ug/L
<10 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<50 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<50 ug/L
Matrix
WW
o
l^STEST
i
Page 1 of 5
Laboratory Report
0702-01435Work Order #:
EN5540
QualifierResultsMethodTest Performed
QualifierResultsMethodTest Performed
<50 ug/L
No.
001
Cyanide
Oil & Grease
Phenols w/chloroform extr.
Volatiles by 8260B
Acetone
Sample ID
Composite
Sample ID
Grab
ERA 200.8
ERA 200.8
ERA 200.8
ERA 200.8
ERA 200.8
ERA 200.8
ERA 200.8
ERA 245.1
ERA 200.8
ERA 200.8
ERA 200.8
ERA 200.8
ERA 200.8
ERA 350.1
ERA 351.2
ERA 353.2
CALCULATION
ERA 365.4
ERA 160.1.
ERA 200.8
ERA 200.8
CALC.
ERA 335.2/335.3
EPA1664A
SM 510 A-B
EPA 8260B
ERA 8260B
Time Sampled
9:50
9.40 mg/L
1.98 mg/L
31.7 mg/L
Report Date:
Date Received:
NC/WW Cert. #: 067
NC/DW Cert. #: 37731
Sample Type
Composite
Sample Type
Grab
4/16/2007
3/13/2007
Analyzed
Date Time
Analyzed
Date Time
8:00
9:00
7:12
7:12
Lead
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Ammonia
Total Kjeldahl Nitrogen
Nitrate-Nitrite
Total Nitrogen Calculation
Total Phosphorus
Total Dissolved Solids
TOTAL HARDNESS (WW)
Calcium
Magnesium
Total Hardness Calculation
- Prepared for —
Tony Gorham
HMS/ Enfield WWTP
PO Box 818
Enfield, NC 27813
6701 Conference Drive
Raleigh, NC 27607
Date Sampled
3/13/2007
Date Sampled
3/13/2007
Time Sampled
9:45
<0.005 mg/L
<0.003 mg/L
<0.005 mg/L
<0.002 mg/L
>0.005 mg/L
<0.010 mg/L
<0.010 mg/L
<0.2 ug/L
<0.010 mg/L
<0.002 mg/L
<0.010 mg/L
<0.001 mg/L
0.012 mg/L
1.68 mg/L as N
2.99 mg/L
2.26 mg/L as N
5.25 mg/L
0.20 mg/L
119 mg/L
<0.005 mg/L
16.0 mg/L
<0.005# mg/L
Cust. Code:
Cust. P.O.#:
Matrix
WW
Matrix
WW
Condition
4 +/- 2 deg C
Condition
4 +/- 2 deg CNo.
002
Telephone: [phone]
Fax: [phone]
0
o
TWTEST
Project No.: 03
Project ID: Priority Pollutant Analysis
3/14/07 10:50
3/15/07
3/20/07
3/14/07
3/14/07
3/22/07 9:32
3/22/07 9:32
3/22/07 9:32
3/22/07 9:32
3/22/07 9:32
3/22/07 9:32
3/22/07 9:32
3/19/07 9:25
3/22/07 9:32
3/22/07 9:32
3/22/07 9:32
3/22/07 9:32
3/22/07 9:32
3/15/07 10:57
3/19/07 9:52
3/16/07 10:50
3/16/07 10:50
3/21/07 9:08
3/14/07 15:30
0:00
3/27/07 9:57
3/27/07 9:57
3/27/07 9:57
Initoring and Pollutant Sea,inual'
Parameter
1
1
1
1
1
1
1
1
1
1
1
1
1
1
ame
bate7Sigs^fu:
Page 3Form - DMR- PPA-1
1
1
1
1
1
1
1
1
Grab
Sample
Type
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
625
62?
625
62?
625
625
62?
62?
625
62?
625
625
625
625
62?
625
62?
62?
625
62?
625
62?
625
625
62?
62?
62?
62?
625
10
I?
I?
T?
io
io
To
2?
To
T?
T?
io
T?
T?
To
io
io
T?
io
To
To
To
T?
20
To
20
To
To
20
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
1
1
1
T
i
i
i
Base-neutral compounds (cont.)
Chrysene
Di-n-butyl phthalate
Di-n-octyl phthalate
Dibenzo(a,h)anthracene
1.2- dichlorobenzene
1.3- dichlorobenzene
1.4- dichlorobenzene
3.3- dichlorobenzidine
Diethyl phthalate
Dimethyl phthalate
2.4- dinitro toluene________________
2,6-dinitrotoluene________________
1,2-diphenylhydrazine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclo-pentadiene
Hexachloroethane
Indeno(l ,2,3-cd)pyrene___________
Isophorone
Naphthalene
Nitrobenzene
N-nitrosodi-n-propylamine
N-nitrosodimethylamine
N-nitrosodiphenylamine
Phenanthrene
Pyrene
1,2,4,-trichlorobenzene
<10
<10
<10
<10
<?
<10
<10
TTo
<10
TTo
TTo
TTo
<To
<10
<10
<10
TTo
<10
TTo
<10
TTo
<10
<10
<10
<10
TTo
<10
<10
TTo
Permit No. NC0025402
Outfall 001_____________
4-chlorophenyl phenyl ether 625
Analytical
Method
<10
Sample
Result
UG/L
Units of
Measurement
10
Quantitation
Level
I certify under penalty of law that this document and all attachments were prepared under my direction
and supervision in accordance with a system to design to assure that qualified perdonnel properly
gather and evaluat the information submitted. Based on my inquiry of the person or persons that
manage the system, or those persons directly responsibel for gathering the information, the
information submitted is , to the best of my knowledge and belief, true, accurate and complete. I am
aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations.
Month March
Year 2007
1
Number of
samples
Gary ^b»H^back ( f
AutfrorizedJRepre skntati/e
Parameter
Page 2Form - DMR- PPA-1
Permit No. NC0025402
Outfall 001
Analytical
Method
Quantitation
Level
Sample
Result
Units-of
Measurement
Number of
samples
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
Grab
nnual Monitoring and Polluta^^Scz
624
624
624
624
624
624
624
624
624
624
624
624
624
624
625
625
625
625
625
625
625
625
625
625
625
625
625
625
625
625
625
625
625
625
625
625
625
625
625
625
625
10
10
10
50
10
10
10
10
10
10
10
10
20
10
10
10
20
10
10
10
50
fo
10
10
50
10
To
5
5
T
5
10
10
10
5
TF
5
To
5
5
10
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
1
1
1
T
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
<20
<10
<10
<10
<50
Tso
<10
<10
<30
Flo
<10
<10
<10
<10
<50
<10
<LQ
FTo
FTo
<10
FTo
<10
Tio
<10
TTo
<10
<io
<5
<5 "<r
<5
<10
TTo
<5 "<r
<5
<5
Ts"
<5
<5
<10
Sample
Type
Volatile organic compounds (Cont.)
1.1- dichloroethylene__________
1.2- dichloropropane
1.3- dichloropropylene________
Ethylbenzene
Methyl bromide______________
Methyl chloride _____________
Methylene chloride
1,1,2,2-tetrachloroethane
Tetrachloroethylene
Toluene ________________
1.1.1- trichloroethane_________
1.1.2- trichloroethane
Trichloroethylene____________
Vinyl chloride________________
Acid-extractable compounds
P-chloro-m-creso
2-chlorophenol______________
2.4- dichlorophenol___________
2.4- dimethylphenol__________
4.6- dinitro-o-cresol
2.4- dinitrophenol____________
2-nitrophenol_______________
4-nitrophenol________________
Pentachlorophenol
Phenol ____________________
2.4.6- trichlorophenol_________
Base-neutral compounds
Acenaphthene
Acenaphthylene_____________
Anthracene ______________
Benzidine ________________
Benzo (a) anthracene__________
Benzo(a)pyrene______________
3,4 benzofluoranthene
Benzo(ghi)perylene___________
Benzo(k)fluoranthene________
Bis (2-chloroethoxy) methane
Bis (2-chloroethyl) ether_____ _
Bis (2-chloroisopropyl) ether
Bis (2-ethylhexyl) phthalate
4-bromophenyl phenyl ether
Butyl benzyl phthalate
2-chloronaphthalene
Month March
Year 2007
SAMPLE PRESERVATION CHECK-IN SHEET
WO#:
Time:
GC L'PSUSMFEDXCD
Preservative
Analysis Requested
Container Chlorine OTHERH2SO4HNO3NaOHThioNoneHCL
(F?/G Thio OTHERH2SO4NaOHNoneHCL
I
''H2SO-Thio OTHERI /G HN03 NaOHNoneHCL
Thio OTHER:/g F /G H23O4 HN03 NaOHNoneHCL
Thio OTHERC/G F /G Pos / neg H2SO4 HN03 NaOHHCLon<
<\aOH ) ThioC/Pos / neg None HCL H2SO4 HN03
Pos / n ;g NaOH ThioC/P//None HCL HN03
OTHERThioC/G P/Pos / ng HN03 NaOHNoneHCL
^HCIC4P2SO4 OTHERNaOHThioC/G P / 3 None HN03
C/H2SO4 HN03 NaOHP/G None HCL
OTHERPos / neg H2SO4 HN03 NaOHC/G P/G None HCL
Thio OTHERPos / neg H2SO4 HN03 NaOHC/G P/G None HCL
Thio OTHERPos / neg H2SO4 HN03 NaOHC/G P/G None HCL
OTHERNaOHThioC/G P/G Pos / neg H2SO4 HN03NoneHCL
OTHERThioC/G P/G Pos / neg H2SO4 HN03 NaOHNoneHCL
OTHERHN03NaOHThioC/G P/G Pos / neg HCL H2SO4None
Thio OTHERHN03NaOHC/G P/G Pos / neg HCL H2SO4None
Thio OTHERPos / neg H2SO4 HN03 NaOHC/G P/G None HCL
OTHERHN03NaOHThioC/G P/G Pos / neg HCL H2SO4None
Thio OTHERH2SO4HN03NaOHC/G P/G Pos / neg HCLNone
Thio OTHERHN03NaOHC/G P/G Pos/neg H2SO4NoneHCL
COMMENTS:
^7^6
6
Sample
Type
Comp/
Grab
Sample
No.
Checked in by:
Date:
Temp:
Route:
^TSr^
OTHER
Thi^Tm^T)
Thio
Po^/ne^
Pos / n^g
Pos / neg
3~t
ITS
Pos / ne g
Pos / geg
q/G
(€/G
C/G
O
Ijtr/J'iTEST
Parameter
10.060.1350.1
1845000G0
10.13353.2 0.01
10.881351.2
10.15365.4 0.01
11281160.1
1360.622CACL
1
1Grab
1
1
1
1
1Chromium
1
1
1
1
1
1Silver
1Thallium
1Zinc
1
1Grab
1Grab
1Grab
1Grab
1BromoformGrab
1Carbon tetrachloride Grab
1GrabChlorobenzene
1ChlorodibromomethaneGrab
1Grab
1Grab
1Grab
1GrabDichlorobromomethane
1Grab
1Grab
1Grab
Page 1Form - DMR- PPA-1
Facility Name Enfield WWTP
Date of sampling 4/15/08
Analytical Laboratory TriTest
Permit No. NC0025402
Outfall 001
Sample
Type
Analytical
Method
Quantitation
Level
Sample
Result
Units of
Measurement
Month April
Year 2008
Number of
samples
ORC James Pittman
Phone [phone]
Annu^^Ionitoring and Pollutant Scan
1,1 -dichloroethane
1,2-dichloroethane
Trans-1,2-dichloroethylene
Ammonia (as N)
Dissolved oxygen
Nitrate/Nitrite
Total Kjeldahl nitrogen
Total Phosphorus
Total dissolved solids
Hardness
Chlorine (total residual, TRC)
Oil and grease
Metals (total recoverable), cyanide and total phenols
Antimony
Arsenic
Acrylonitrile
Benzene
Chloroethane
2-chloroethylvinyl ether
Chloroform
Beryllium
Cadmium
Copper
Lead
Mercury
Nickel
Selenium
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Grab
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Composite
Grab
200.8
200.8
200.8
200.8
239.2
245.1
200.8
200.8
200.8
200.8
200.8
335.2/335.3
510A/B
4500CL
1664A
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
200.8
200.8
0.001
0.001
0.01
0.001
0.005
0.0002
0.01
0.01
0.005
0.01
0.01
0.005
0.002
0.003
0.005
2
20
<0.003
<0.005
<5
<5
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
MG/L
UG/L
MG/L
Cyanide
Total phenolic compounds
Volatile organic compounds
Acrolein 100
“so"
5
5
T"
5
5
10
T"
“s”
5
5
T"
5
<0.002
<0.005
<0.010
<0.010
<0.005
<0.0002
<0.010
<0.002
<0.010
<0.001
0.016
<0.005
27.1
<20
23.5
<50
<50
<5
<5
<5
<5
<5
<10
<10
8.09
<5
<5
Annual Monitoring and Pollutj Scan
Parameter
1Grab
1Grab
1Grab
1Grab
110Grab
1Grab
1Grab
1Grab
1Grab
1<5Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1
1
1Grab
1Grab
1Grab
1Grab
1GrabBenzidine
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
Page 2Form - DMR- PPA-1
Grab
Grab
Sample
Type
Analytical
Method
Quantitation
Level
Sample
Result
Units of
Measurement
Number of
samples
Month April
Year 2008
Permit No. NC00254
Outfall 001
Volatile organic compounds (Cont.)
1.1 -dichloroethylene
1.2- dichloropropane
1.3- dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Methylene chloride
1.1.2.2- tetrachloroethane
Tetrachloroethylene
Toluene
1.1.1 -trichloroethane
1.1.2- trichloroethane
Trichloroethylene
Vinyl chloride
Acid-extractable compounds
P-chloro-m-creso
2-chlorophenol
2.4- dichlorophenol
2.4- dimethylphenol
4.6- dinitro-o-cresol
2.4- dinitrophenol
2-nitrophenol
4-nitrophenol
Pentachlorophenol
Phenol
2.4.6- trichlorophenol
Base-neutral compounds
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
3,4 benzofluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Bis (2-chloroethoxy) methane
Bis (2-chloroethyl) ether
Bis (2-chloroisopropyl) ether
Bis (2-ethylhexyl) phthalate
4-bromophenyl phenyl ether
Butyl benzyl phthalate
2-chloronaphthalene
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
10
10
To
50
10
10
10
10
To
10
To
10
20
10
10
To
20
10
To
10
50
50
To
10
50
10
10
10
10
v
TT
10
5
5
To
5
5
s’
5
<10
<10
<10
Tso
<10
<10
<10
<10
TTo
TTo
<10
<10
<10
<10
<10
<10
<5
<5
<5
<5
TTo
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
<20
<10
<10
<10
<50
<50
<10
<10
Tso
<10
TTo
<10
<5
<5
<5
<5
<5
<10
4-chlorophenyl phenyl ether
Parameter
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
110Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
1Grab
ck
tative.a:tepresi
' Sfgnatur^
Page 3Form - DMR- PPA-1
Date
Permit No. NC0025402
Outfall 001
8270C
Analytical
Method
10
Quantitation
Level
<10
Sample
Result
UG/L
Units of
Measurement
1
Number of
samples
Month April
Year 2008
Annul^^Ionitoring and Pollutant Scan
Base-neutral compounds (cont.)
Chrysene
Di-n-butyl phthalate
Di-n-octyl phthalate
Dibenzo(a,h)anthracene
1.2- dichlorobenzene
1.3- dichlorobenzene
1.4- dichlorobenzene
3.3- dichlorobenzidine
Diethyl phthalate
Dimethyl phthalate
2.4- dinitrotoluene
2,6-dinitrotoluene
1,2-diphenylhydrazine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclo-pentadiene
Hexachloroethane
lndeno(l ,2,3-cd)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-nitrosodi-n-propylamine
N-nitrosodimethylamine
N-nitrosodiphenylamine
Phenanthrene
Pyrene
1,2,4,-trichlorobenzene
Grab
Sample
Type
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
8270C
10
10
10
10
10
10
Io’
10
10
10
Io
Io
Io’
20
10
20
10
10
20
10
10
10
Io
10
10
10
20
10
<10
<10
<10
<10
<10
Ho
<10
<10
<10
ITo
<10
<10
<10
<20
Ho
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
UG/L
<10
<10
<10
<10
<10
Ho
<10
<10
<10
<10
Ho
<10
<10
<10
I certify under penalty of law that this document and all attachments were prepared under my direction
and supervision in accordance with a system to design to assure that qualified perdonnel properly
gather and evaluat the information submitted. Based on my inquiry of the person or persons that
manage the system, or those persons directly responsibel for gathering the information, the
information submitted is , to the best of my knowledge and belief, true, accurate and complete. I am
aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations.
Gary Stap»
Authorized
Page 1 of 5
Laboratory Report
0804-00760Work Order #:
EN5540
QualifierResultsMethodTest Performed
Qualifier
ResultsMethodned
No.
001
Sample ID
Composite
Project No.: 03
Project ID: Priority Pollutant Analysis
6701 Conference Drive
Raleigh, NC 27607
ERA 200.8
ERA 200.8
ERA 200.8
ERA 200.8
ERA 200.8
ERA 200.8
ERA 200.8
ERA 245.1
ERA 200.8
ERA 200.8
ERA 200.8
ERA 200.8
ERA 200.8
ERA 350.1
ERA 351.2
ERA 353.2
CALCULATION
ERA 365.4
ERA 160.1
ERA 200.8
ERA 200.8
CALC.
ERA 330.5
ERA 335.2/335.3
EPA1664A
SM 510 A-B
EPA8260B
Time Sampled
9:35
Time Sampled
9:37
<0.005 mg/L
23.5 mg/L
27.1 ug/L
Report Date:
Date Received:
Gust. Code:
Cust. P.O.#:
NC/WW Cert. #: 067
NC/DW Cert. #: 37731
Sample Type
Composite
5/20/2008
4/15/2008
Sample Type
Grab
Analyzed
Date Time
Analyzed
Date Time
Lead
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Ammonia
Total Kjeldahl Nitrogen
Nitrate-Nitrite
Total Nitrogen Calculation
Total Phosphorus
Total Dissolved Solids
TOTAL HARDNESS (WW)
Calcium
Magnesium
Total Hardness Calculation
Tot. Resid. Chlorine; Water
Telephone: [phone]
Fax: [phone]
Sample ID
'rab
.©form extr.
. 8260B
Date Sampled
4/15/2008
Date Sampled
4/15/2008
<0.005 mg/L
<0.003 mg/L
<0.005 mg/L
<0.002 mg/L
<0.005 mg/L
<0.010 mg/L
<0.010 mg/L
<0.2 ug/L
<0.010 mg/L
<0.002 mg/L
<0.010 mg/L
<0.001 mg/L
0.016 mg/L
0.06 mg/L as N
0.88 mg/L
0.13 mg/L as N
1.01 mg/L
0.15 mg/L
128 mg/L
10.6 mg/L
2.31 mg/L
36.0 mg/L
0.1 mg/L
Condition
4 +/- 2 deg C
Condition
4 +/- 2 deg C
Matrix
WW
Matrix
WW
o
0TWTEST
4/22/08
4/22/08
4/22/08 9:53
4/21/08 16:35
4/21/08 11:11
4/21/08 11:11
4/21/08 11:11
4/21/08 11:11
4/21/08 11:11
4/21/08 11:11
4/21/08 11:11
4/22/08 13:07
4/21/08 11:11
4/21/08 11:11
4/21/08 11:11
4/21/08 11:11
4/21/08 11:11
4/22/08 11:00
4/18/08 14:50
4/22/08 10:09
4/22/08 10:09
4/17/08 15:00
4/21/08 13:35
0:00
9:53
9:53
- Prepared for —
Nadine Blackwell
Hydro Management Services
Enfield WWTP
P.O. Box 1279
Clemmons, NC 27012
4/16/08 12:30
4/18/08 8:00
5/3/08 10:00
4/17/08 6:47
Page 2 of 5
Laboratory Report
Work Order#: 0804-00760
QualifierResultsMethodTest Performed
No.
002
Acetone
Acrolein
Acrylonitrile
Benzene
Bromodichloromethane
Bromobenzene
Bromochloromethane
Bromoform
Bromomethane
sec-Butylbenzene
tert-Butyl benzene
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Dibromochloromethane
1.2- Dibromo-3-chloropropane
1.2- Dibromoethane
Dibromomethane
1.2- Dichlorobenzene
1.3- Dichlorobenzene
1.4- Dichlorobenzene
Dichlorodifluoromethane
1.1- Dichloroethane
1.2- Dichloroethane
1,1 -Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1.2- Dichloropropane
1.3- Dichloropropane
2,2-Dichloropropane
> 1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
2-Hexanone
Isopropylbenzene
p-lsopropyltoluene
Methylene chloride
Sample ID
Grab
EPA8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA8260B
EPA 8260B
EPA 8260B
EPA 8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA 8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA 8260B
EPA 8260B
EPA8260B
EPA8260B
EPA 8260B
EPA8260B
EPA 8260B
EPA 8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA 8260B
EPA8260B
EPA8260B
EPA8260B
EPA8260B
EPA 8260B
EPA8260B
EPA 8260B
EPA 8260B
EPA8260B
EPA 8260B
Time Sampled
9:37
Sample Type
Grab
NC/WW Cert. #: 067
NC/DW Cert. #: 37731
Analyzed
Date Time
6:47
6:47
Condition
4 +/- 2 deg C
Telephone: [phone]
Fax: [phone]
6701 Conference Drive
Raleigh, NC 27607
Date Sampled
4/15/2008
<50 ug/L
<50 ug/L
<50 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<10 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<10 ug/L
<10 ug/L
8.09 ug/L
<10 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<25 ug/L
<5 ug/L
<10 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<50 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
Matrix
WW
G
SWTEST
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08
4/17/08
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
Page 3 of 5
Laboratory Report
Work Order #: 0804-00760
QualifierResultsMethodTest Performed
No.
002
Sample ID
Grab
Time Sampled
9:37
<50 ug/L
<50 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<10 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<5 ug/L
<15 ug/L
<5 ug/L
<10 ug/L
<50 ug/L
<10 ug/L
<5 ug/L
<5 ug/L
<100 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<20 ug/L
<20 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<50 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
Sample Type
Grab
NC/WW Cert. #: 067
NC/DWCert. #: 37731
6:47
6:47
6:47
6:47
6:47
6:47
6:47
Condition
4 +/- 2 deg C
Telephone: [phone]
Fax: [phone]
6701 Conference Drive
Raleigh, NC 27607
Date Sampled
4/15/2008
Matrix
WW
Methyl ethyl ketone (MEK)
MIBK (4-Methyl-2-pentanone)
n-Propyl benzene
Styrene
1.1.1.2- Tetrachloroethane
1.1.2.2- Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1 -T richloroethane
1.1.2- T richloroethane
Trichloroethene
Trichlorofluoromethane
1.2.3- T richloropropane
1.2.4- Trimethylbenzene
1.3.5- Tri methylbenzene
Vinyl acetate
Vinyl chloride
o-Xylene
m- & p-Xylene
trans-1,4-Dichloro-2-butene
lodomethane
8270 (A&B/N)
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Aniline
Anthracene
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Benzo(g,h,i)perylene
Benzoic acid
Benzyl alcohol
Benzyl butyl phthalate
Bis(2-chloroethyl)ether
Bis(2-chloroethoxy)methane
Bis(2-chloroisopropyl)ether
Bis(2-ethylhexyl)phthalate
4-Bromophenyl phenyl ether
Carbazole
EPA8260B
ERA 8260B
EPA8260B
ERA 8260B
ERA 8260B
EPA8260B
ERA 8260B
ERA8260B
EPA8260B
ERA 8260B
EPA8260B
ERA 8260B
ERA 8260B
ERA 8260B
ERA 8260B
EPA8260B
EPA8260B
ERA 8260B
ERA 8260B
ERA 8260B
EPA8260B
ERA8260B
" ERA 8270C
ERA 8270C
EPA8270C
ERA 8270C
ERA 8270C
EPA8270C
ERA 8270C
ERA 8270C
EPA8270C
ERA 8270C
ERA 8270C
ERA 8270C
ERA 8270C
EPA8270C
EPA8270C
ERA 8270C
ERA 8270C
ERA 8270C
ERA 8270C
ERA 8270C
ERA 8270C
ERA 8270C
0
o
TO8TEST
Analyzed
Date Time
4/17/08
4/17/08
4/17/08
4/17/08
4/17/08
4/17/08
4/17/08
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/17/08 6:47
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
Page 4 of 5
Laboratory Report
0804-00760Work Order#:
QualifierResultsMethodTest Performed
No.
002
4-Chloroaniline
2-Chloronaphthalene
4-Chloro-3-methylphenol
2-Chlorophenol
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
Dibenzofuran
Di-n-butyl phthalate
3,3'-Dichlorobenzidine
1.2- Dichlorobenzene
1.3- Dichlorobenzene
1.4- Dichlorobenzene
2.4- Dichlorophenol
Diethyl phthalate
2.4- Dimethylphenol
Dimethyl phthalate
2.4- Dinitrophenol
2.4- Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
lndeno(1,2,3-c,d)pyrene
Isophorone
2-Methyl-4,6-dinitrophenol
1 -Methylnaphthalene
2-Methylnaphthalene
2- Methylphenol
3- & 4-Methylphenol
Naphthalene
2- Nitroaniline
3- Nitroaniline
4- Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
N-Nitrosodimethylamine
N-Nitrosodiphenylamine
N-Nitrosodi-n-propylamine
Sample ID
Grab
EPA 8270C
EPA 8270C
EPA8270C
EPA 8270C
EPA8270C
EPA 8270C
EPA8270C
EPA 8270C
EPA8270C
EPA 8270C
EPA 8270C
EPA 8270C
EPA 8270C
EPA8270C
EPA 8270C
EPA8270C
EPA8270C
EPA8270C
EPA8270C
EPA8270C
EPA 8270C
EPA 8270C
EPA 8270C
EPA8270C
EPA 8270C
EPA8270C
EPA 8270C
EPA 8270C
EPA 8270C
EPA 8270C
EPA 8270C
EPA8270C
EPA8270C
EPA8270C
EPA 8270C
EPA 8270C
EPA 8270C
EPA 8270C
EPA 8270C
EPA 8270C
EPA8270C
EPA 8270C
EPA8270C
EPA8270C
Time Sampled
9:37
<20 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<20 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<50 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<50 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<20 ug/L
<10 ug/L
<10 ug/L
<20 ug/L
<20 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
Sample Type
Grab
NC/WW Cert. #: 067
NC/DW Cert. #: 37731
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
6701 Conference Drive
Raleigh, NC 27607
Date Sampled
4/15/2008
Matrix
WW
Condition
4 +/- 2 deg C
Telephone: [phone]
Fax: [phone]
o
■Astest
Analyzed
Date Time
Page 5 of 5
Laboratory Report
Work Order #: 0804-00760
QualifierMethodResultsTest Performed
Reviewed by:
No.
002
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
Pyridine
1.2.4- Trichlorobenzene
2.4.5- Trichlorophenol
2.4.6- Trichlorophenol
Extraction, 8270 Waters
Sample ID
Grab
EPA8270C
EPA 8270C
EPA 8270C
EPA 8270C
EPA 8270C
EPA 8270C
EPA8270C
EPA8270C
EPA 3510
Time Sampled
9:37
Sample Type
Grab
NC/WW Cert. #: 067
NC/DW Cert. #: 37731
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
4/15/08 10:00
Condition
4 +/- 2 deg C
Telephone: [phone]
Fax: [phone]
6701 Conference Drive
Raleigh, NC 27607
Date Sampled
4/15/2008
<30 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<10 ug/L
<20 ug/L
<10 ug/L
DONE
Matrix
WW
o
TOTEST
Analyzed
Date Time
Page 1 of 1
Chain of Custody
Bill Results To:
Sampled By:
Attn: Nadine Blackwell
Fax:
001WWCComposite
002WWG
For Lab Use Only:matuj d b'ReciRelini
/ Received by (signature)RelinquL
Received by (signature) 'Relinquished by (signature C
Report Results To:
HMS/ Enfield WWTP
.PO Box 818
’Enfield, NC 27813
0737
Lead, Antimony, Arsenic, Beryllium, Cadmium, Chromium, Copper,
Mercury, Nickel, Selenium, Silver, Thallium, Zinc, Ammonia, Total
Kjeldahl Nitrogen, Nitrate-Nitrite, Total Nitrogen Calculation, Total
Phosphorus, Total Dissolved Solids, Metals Prep,
TOTAL HARDNESS (WW), Calcium, Magnesium, Total Hardness
Calculation, Tot. Resid. Chlorine; Water, Alkali Metals Prep
Cyanide, Oil & Grease, Phenols w/chloroform extr., Volatiles by 8260B,
8270 (A&B/N), Extraction, 8270 Waters
Project Reference:
Project Number:
Purchase Order#:
- 4+2 C
□ Temp:.
Hydro Management Services
Enfield WWTP
PO Box 1279
Clemmons, NC 27012
Priority Pollutant Analysis
03
o
TmTesT
6701 Conference Drive, Raleigh, NC 27607
ph: [phone] fax: [phone]
NCWW Cert #67, NCDW Cert # 37731
‘ Efate Time .—■
7 (^ionatureb^7
Time .j .__r ui i_au use vzmy.
J (femperatue at receipt:
4 ^Grat>
Attn: Tony Gorham
Phone: [phone]
Tritest W.O. # 0804-00760
J^j^Standard Report Delivery
| | Rush Report Delivery (w/ surcharge)
Note: Rush projects are subject to prior approval by Lab
Requested Due Date:
SAMPLE PRESERVATION CHECK-IN SHEET
WO#:
Time:
CD TTS USM FEDX GC UPS
Analysis Requested
Container Chlorine None HCL H2SO4 HNO3 NaOH Thio OTHER
/&/G /Pi/G Pos / ne None HCL H2SO4 NaOH Thio OTHERI
C/G P/G Pos / leg'None HCL HN03 NaOH Thio OTHERI
C/G P G Pos /H2SO4 HN03 NaOH Thio1leg OTHER
Pos / leg ■Noi HCL H2SO4 HN03 NaOH Thio OTHER1
Pos/None HCL H2SO4 HN03ieg ThioIp
C/1 G P Pos / neg None HCL H2SO49 HN03 NaOH Thio OTHER
C G P/G Pos None HCL H2SO4 HN03 NaOH Thiojie i OTHER
tcFcGNone1 H2SO4 HN03 NaOH Thio OTHER
C/1\9 p None HCL H2SO4 HN03 NaOH Thio2_
C/G P/G Pos / neg None HCL H2SO4 HN03 NaOH Thio
C/G P/G Pos / neg None HCL H2SO4 HNO3 NaOH Thio OTHER
C/G P/G Pos/neg None HCL H2SO4 HN03 NaOH Thio OTHER
C/G P/G Pos/neg None HCL H2SO4 HN03 NaOH Thio OTHER
C/G P/G Pos / neg None HCL H2SO4 HN03 NaOH Thio OTHER
C/G P/G Pos/neg None HCL H2SO4 HN03 NaOH Thio OTHER
C/G P/G Pos / neg None HCL H2SO4 HN03 NaOH Thio OTHER
C/G P/G Pos / neg None HCL H2SO4 HN03 NaOH Thio OTHER
C/G P/G Pos / neg None HCL H2SO4 HN03 NaOH Thio OTHER
C/G P/G Pos / neg None HCL H2SO4 HN03 NaOH Thio OTHER
C/G P/G Pos/neg None HCL H2SO4 HN03 NaOH Thio OTHER
COMMENTS:
Pl/ G
\ //•
THE
Sample
Type
Comp/
Grab
Sample
No.
Temp:
Route:
Checked in by:
Date:
o
BTEST
(^fHEJI
OTHER
" P/G
one i HCL7 V V
C^/G
C/f^
Pos
Pos /|^^)
Preservative
Toxicity Tests
Environmental Testing Solutions, Inc.
County: HalifaxPipe#: 001NPDES #: NC- 0025402Facility: Enfield WWTP
is, Infy'/ \Comments:
% Effluent
Surviving number of larvae
Weight/original (mg/larvae)
% Effluent
Surviving number of larvae
Weight/original (mg/larvae)
Water Quality Data
<
Control
Calculated
>14%ChV:14%NOEC:LOEC:>14%
D WO form AT-5 (8/03)
7.19
7.7
25.0
Survival (%)
Average wt (mg)
Survival (%)
Average wt (mg)
Control
Organisms
Survival (%)
Average wt (mg)
Hatch date:
Hatch time:
Survival (%)
Average wt (mg)
Survival (%)
Average wt (mg)
PO Box 7565
Asheville, NC 28802
Phone: [phone]
Fax: [phone]
E-mail: [e-mail]
Control
pH (SU):
DO (mg/L):
Temp. (°C):
pH (SU):
DO (mg/L):
Temp. (°C):
Laboratory Performing Test: Environmental Testingffiluj
Signature of Operator in Responsible Charge:
Signature of Laboratory Supervisor:
Analyses
Normal:
Hom. Var.
NOEC:
LOEC:
ChV:
Method:
Surviving number of larvae
| 7.0% | Original number of larvae
Weight/original (mg/larvae)
Surviving number of larvae
Original number of larvae
Weight/original (mg/larvae)
Surviving number of larvae
Original number of larvae
Weight/original (mgdarvae)
7.42
7,5
24.5
24-h
20
38
248
<0.10
0.3
7.53
7.8
24.8
1
10
10
0.702
10
10
0.684
10
10
0.652
10
10
0.665
10
10
0.646
24-h
28
32
256
<0.10
0.9
7.14
7.2
24.4
7.18
7.2
24.5
Replicate number
2 3
10
10
0.673
10
10
0.642
10
10
0.605
10
10
0.727
10
10
0.663
7.35
7.8
24.9
10
10
0.586
10
10
0.569
10
10
0.597
9
10
0.597
10
10
0.652
7,30
7.6
24.7
7,30
7.6
24.5
33, 34
48, 44
154-165
10
10
0.642
10
10
0.704
10
10
0.670
10
10
0.680
7.33
7.4
24.5
Project:
Samples:
7.43
8.1
24.8
Survival
Critical
5276_______________________
090224.01,090226.01, 090228.02
7,15
7,4
24.3
100.0
0.648
0.648
100.0
0.634
100.0
0.640
100.0
0.660
97.5
0.665
100.0
0.663
7.61
8.5
24.8
7.33
8.4
24.9
Test Organisms
Outside supplier:
I Aquatox, Inc.
7.15
7.2
24.7
7,41
8.3
25.0
02-23-09
1600 ET
7.08
7.0
24 3
6,97
6,7
24.5
% Effluent
| 10.5% | Original number of larvae
7,60
7,9
24.6
High Concentration
7,50
7,7
24.7
7,32
7.5
24.4
7,66
7,9
24.8
10
10
0.665
Sample 2
02-24-09
10
10
0.629
Sample 3
02-26-09
24-h
29
34
253
<0.10
2.1
10
10
0.713
4
10
10
0.632
10
10
0.645
7.32
7.5
24.7
7,30
7.6
24.8
7,36
7.7
24.4
7.53
7.8
24.8
Start date:
02-24-09
Survival
NA
NA
14%
>14%
>14%
Visual Inspec.
7.21
7,7
24.2
End date:
03-03-09
Start time:
1105
Day 6
Initial | Final
7.59
8.1
24.9
% Effluent
I 14% I
Sample 1
02-22-09
% Effluent
3.5%
5.25%
7,0%
10.5%
14%
Day 5
Initial | Final
7.12
7,1
24.4
_____Growth
Critical
2.410
2.410
2.410
2.410
2.410
Growth
Yes
Yes
14%
>14%
>14%
Dunnett's
Calculated
0.449
0.281
-0.530
-0.385
-0.473
End time:
1100
Day 0
Initial | Final
Day 1
Initial | Final
Day 2
Initial | Final
Day 3
Initial | Final
Sample Information
Collection start date:
Grab:
Composite duration:
Alkalinity (mg/L CaCO3):
Hardness (mg/L CaCO3):
Conductivity (pmhos/cm):
Total residual chlorine (mg/L):
Sample Temp, al Receipt (°C):
Survival (%)
Average wt (mg)
Average wt /
surviving (mg)
Date: March 09, 2009
Effluent Aquatic Toxicity Report Form - Chronic Fathead Minnow Multi-Concentration Test
% Effluent
| 5.25% | Original number of larvae
_______ Surviving number of larvae
| 3.5% | Original number of larvae
Weight/original (mg/larvae)
Overall Analysis:
Result: PASS
Day 4
Initial | Final
Mail Original To: North Carolina Department of Environment and Natural Resources
DWQ/ Environmental Sciences Branch
1621 Mail Service Center
Raleigh, NC 27699-1621
■
■A
NPDES #: NC- 0025402
Facility: Enfield WWTP
Comments: |tions, Inc
I
Control
% Effluent
Water Quality Data
Control
Calculated
ChV:14%NOEC:>14%LOEC:
DWQform AT-5 (8/03)
93.5
0.747
100.0
0.795
100.0
0.790
Environmental Testing Solutions. Inc.
Effluent Aquatic Toxicity Report Form
Survival (%)
Average wt (mg)
Survival (%)
Average wt (mg)
Survival (%)
Average wt (mg)
97.5
0.771
100.0
0.796
Hatch date:
Hatch time:
Survival (%)
Average wt (mg)
Average wt /
surviving (mg)
Survival (%)
Average wt (mg)
Survival (%)
Average wt (mg)
3830______________________
080506.03, 080508.03,080510.03
I
I
7.16
8.1
24.7
7.04
8.4
24.8
10
10
0,720
9
10
0.843
7.25
7.9
24.9
10
10
0.754
10
10
0.726
10
10
0.711
Replicate number
2 3
10 ~
10
0.877
7.03
7.6
24.4
10
10
0.757
10
10
0.809
10
10
0.775
10
10
0.883
10
10
0.829
6.96
8.0
24.7
10
10
0.787
10
10
0.647
10
10
0.855
9
10
0.741
10
10
0.755
10
10
0.814
4
10
10
0.843
10
10
0.739
10
10
0.761
10
10
0.841
10
10
0.824
10
10
0.805
7.19
7.8
25.0
7.41
7.8
24.8
Survival
Critical
100.0
0.763
0.763
6.73
6.8
24.2
7.33
8.1
24.7
6.86
7.6
24.5
7.21
7.8
24.8
7,10
7.9
24.8
05-05-08
1600 BT
Calculated
0.279
-0.537
-0.131
-0.545
-0.452
% Effluent Surviving number of larvae
I 7.0% I Original number of larvae
Weight/original (mg'larvae)
% Effluent Surviving number of larvae
110.5% | Original number of larvae
Weight/original (mg'larvae)
7.14
7.7
24.5
7.10
7.8
24.5
24.5-h
22
38
194
<0.10
2.4
7.33
7.7
24.7
24.25-h
29
34
209
<0.10
5.4
6.78
7.6
24.4
7.17
7.8
24.6
25-h
29
32
213
<0.10
5.7
7.11
7.6
24.5
6.98
7.5
24.4
7.40
7.8
24.9
6.93
7.4
24.7
6.91
7.2
24.6
Project:
Samples:
7.15
8.0
24.9
6.89
7.2
24.5
7 13
8.1
24.9
Start time:
1142
7.02
7.5
24.8
6.92
7.4
24.8
% Effluent Surviving number of larvae
| 5.25%^ Original number of larvae
Weight/original (mgdarvae)
Sample 3
05-08-08
% Effluent
3.5%
5.25%
7.0%
10.5%
14%
>14%
Survival
NA
NA
14%
>14%
>14%
Visual Inspec.
Growth
Critical
2.410
2.410
2.410
2.410
2.410
Surviving number of larvae
| 14% | Original number of larvae
Weight/original (mg'larvae)
Sample 1
05-04-08
1
10 ~
10
0.545
Sample 2
05-06-08
End date:
05-13-08
Growth
Yes
Yes
14%
>14%
>14%
Dunnett's
31,3!
45,40
147-161
7 :■ .
Test Organisms
Outside supplier:
i Aquatox, Inc.
Control
pH(SU):
DO (mg/L):
Temp. (°C):
High Concentration
pH (SU): '
DO (mg/L):
Temp. (°C):
Analyses
Normal:
Hom. Var.
NOEC:
LOEC:
ChV:
Method:
Sample Information
Collection start date:
Grab:
Composite duration:
Alkalinity (mg/L CaCO3):
Hardness (mg/L CaCOj):
Conductivity (pmhos/cm):
Total residual chlorine (mg/L):
Sample Temp, at Receipt (°C):
Mail Original To
Surviving number of larvae
Organisms Original number of larvae
Weight/ori^nal (mg/larvae)
% Effluent Surviving number of larvae
| 3.5% I Original number of larvae
Weight/original (mg/larvae)
A PO Box 7565
Weville, NC 28802
Phone: [phone]
Fax: [phone]
E-mail: [e-mail]
Date: May 30, 2008
- Chronic Fathead Minnow Multi-Concentration Test
Pipe #: 001 County: Halifax
Overall Analysis:
Result: PASS
End time: |
1113 ]
Day 6
Initial I FinalDay 4
Initial | Final
Day 5
Initial | FinalDay 1
Initial I Final
Dav 3
Initial I Final
Day 2
Initial ] Final
6.93
7.7
24.6
Laboratory Performing Test: Environmental Testing,
Signature of Operator in Responsible Charge: ✓
Signature of Laboratory Supervisor:
: North Carolina Department of Environment and Natural Resources
DWQ/ Environmental Sciences Branch
1621 Mail Service Center
Raleigh, NC 27699-1621
Day 0
Initial | Final
I Start date: I
| 05-06-08 |
NPDES #: NC- 0025402Facility: Enfield WWTP
Comments;
Surviving number of larvae
Weight/original (mg/larvae)
% Effluent
Surviving number of larvae
Weight/original (mg/larvae)
% Effluent
Surviving number of larvae
Weight/original (mg/larvae)
% Effluent
Water Quality Data
Control
Calculated
>14%14%ChV:NOEC:>14%LOEC:Result:
DWQform AT-5 (8/03)
Survival (%)
Average wt (mg)
Survival (%)
Average wt (mg)
Average wt /
surviving (mg)
Survival (%)
Average wt (mg)
Survival (%)
Average wt (mg)
Hatch date:
Hatch time:
% Effluent _____ ___________
| 10,5% | Original number of larvae
Overall Analysis:
PASS
PO Box 7565
Asheville, NC 28802
Phone: [phone]
Fax: [phone]
E-mail: [e-mail]
Analyses
Normal:
Hom. Var.
NOEC:
LOEC:
ChV:
Method:
Survival (%)
Average wt (mg)
Survival (%)
Average wt (mg)
% Effluent _________________
| 5.25% | Original number of larvae
Surviving number of larvae
| 7.0% | Original number of larvae
Weight/original (mg/larvae)
Surviving number of larvae
| 1-1% | Original number of larvae
Weight/original (mg/larvae)
Day 0
Initial | Final
7.07
7,9
24.6
1
9
10
0.650
10
10
0.691
10
10
0.725
10
10
0.730
10
10
0.590
10
10
0.660
Replicate number
2 3
10
10
0.685
10
10
0.644
10
10
0.618
10
10
0.676
10
10
0.629
10
10
0.713
6.97
7,9
24.9
26,25-h
56
42
287
0.163
2.3
10
10
0.576
10
10
0.624
10
10
0.695
10
10
0.762
10
10
0.685
10
10
0.525
32,34
43,42
146-158
4
10
10
0.571
10
10
0.659
9
10
0.636
10
10
0.640
10
10
0.670
10
10
0.668
Day 3
Initial | Final
7,10
7.6
24.6
Survival
Critical
97.5
0.621
0.639
6.74
6.6
24.5
100.0
0.655
6.73
6.9
24.2
100.0
0.702
100.0
0.644
100.0
0.642
7,00
8.0
24.7
Test Organisms
Outside supplier:
Aquatox, Inc.
6.98
7.6
24.6
7,01
8.0
24.9
08-11-08
1600 ET
7,19
7,7
24.7
7.66
7.9
24.9
6.81
7.7
24.3
6.85
7,7
24.2
24.75-h
56
42
288
0.139
5.5
24.75-h
59
42
287
0.147
0.6
7,01
7.5
24.2
6.88
7,5
24.4
7.02
7,7
24.6
6,91
7.4
24.2
7.15
7.7
24.6
7,05
7.9
24.4
6.99
7.6
24.3
Day 4
Initial | Final
7,11
7.7
24.7
Stan date:
08-12-08
Day 5
Initial | Final
7,00
8.1
24.8
Stan time:
1318
6.90
7,5
24.5
7.07
7.8
24.6
End time:
1232
6.95
7,6
24.2
6.86
8.1
24.7
Sample 2
08-12-08
Sample 3
08-14-08
7,04
7.5
24.3
7.01
7.4
24.2
97.5
0.669
End date:
08-19-08
Growth
Yes
Yes
14%
>14%
>14%
Dunnett's
Calculated
-0.882
-1.245
-2.114
-0.597
-0.545
7,01
7.5
24.0
Sample 1
08-10-08
Survival
NA
NA
14%
>14%
>14%
Visual Inspec.
___Growth
Critical
2.410
2.410
2.410
2.410
2.410
Day 6
Initial | Final
Day 1
Initial | Final
%, Effluent
3.5%
5.25%
7,0%
10.5%
14%
Sample Information
Collection start date:
Grab:
Composite duration:
Alkalinity (mg/L CaCO3):
Hardness (mg/L CaCO3):
Conductivity (pmhos/cm):
Total residual chlorine (mg/L):
Sample Temp, at Receipt (°C):
Control
Organisms Original number of larvae
Control
pH (SU):
DO (mg/L):
Temp. (°C):
High Concentration
pH (SU):
DO (mg/L):
Temp. (°C):
Project: 4024 __________________ __
Samples: 080812.03, 080814,02, 080816.02
Surviving number of larvae
| 3.5% | Original number of larvae
Weight/original (mg/larvae)
Laboratory Performing Test: Environmental Testins^oluypps, ff
Signature of Operator in Responsible Charge: . /
Signature of Laboratory Supervisor: u
Mail Original To: North Carolina Department of Environment and Natural Resources
DWQ/Environmental Sciences Branch
1621 Mail Service Center
Raleigh, NC 27699-1621
\-------------------------------------------
KjjjJ Environmental Testing Solutions, Inc. Date: August 25. 2008
Effluent Aquatic Toxicity Report Form - Chronic Fathead Minnow Multi-Concentration Test
Pipe #: 001 County: Halifax
Day 2
Initial I Final
Pipe #: 001Facility: Enfield WWTP
Comments:
II
Mail Original To: North Carolina Department of Environment and Natural Resources I
Control J
% Effluent
■
% Effluent
Surviving number of larvae
Weight/original (mg/larvae)
% Effluent
Water Quality Data
Control
Calculated
>14%ChV:14%>14% NOEC:LOEC:Result:
DWOform AT-5 (8/03)
I
ii
1
DWQ/ Environmental Sciences Branch
1621 Mail Service Center
Raleigh, NC 27699-1621
Survival (%)
Average wt (mg)
Survival (%)
Average wt (mg)
Survival (%)
Average wt (mg)
Survival (%)
Average wt (mg)
Hatch date:
Hatch time:
% Effluent
I 10.5%
Survival (%)
Average wt (mg)
Average wt /
surviving (mg)
Survival (%)
Average wt (mg)
Overall Analysis:
PASS
NPDES #: NC- 0025402
% Effluent
| 7.0% | Original number of larvae
7,13
7,9
24.6
7,00
7.6
24.4
7.18
7.8
24.6
1
10
10
0.629
10
10
0.649
10
10
0.553
10
10
0.590
10
10
0.534
10
10
0.625
24-h
45
40
255
<0.10
1.3
Replicate number
2 3
10
10
0.618
6,78
6.9
24.7
6.77
6.9
24.8
10
10
0.663
10
10
0.619
10
10
0.512
10
10
0.584
10
10
0.628
6.99
7,8
24.9
10
10
0.662
10
10
0.623
10
10
0.724
10
10
0.578
10
10
0.566
10
10
0.617
33,34
44,44
148 - 155
4
10
10
0.639
10
10
0.618
10
10
0.642
10
10
0.637
10
10
0.656
7.20
7,9
24.8
Survival
Critical
100.0
0.637
0.637
100.0
0.638
100.0
0.625
6.87
7.0
24.8
682
6.9
24.7
100.0
0.581
100.0
0.580
100.0
0.632
7,34
8.0
24.9
Test Organisms
Outside supplier:
I Aquatox, Inc.
6,74
6.5
24.4
7,41
8.1
24.7
11-03-08
1600 ET
Surviving number of larvae
| 14% | Original number of larvae
Weight/original (mg/larvae)
Surviving number of larvae
Original number of larvae
Weight/original (mgOarvae)
7.06
7,4
24.5
24-h
29
42
279
<0.10
0.8
7.30
7.7
24.7
7.23
7.5
24.8
7.01
7.4
24.8
6.98
7,3
24.6
7.34
7.6
24.8
6.99
7.5
24.6
7.36
8.0
24.8
7,22
8,2
24.9
Start date:
11-04-08
End cate:
11-11-08
Day 5
Initial | Final
7.23
8.3
24.8
Start time:
1035
6,69
6.8
24.5
7.18
8.2
24.9
6.66
5.4
24.4
7.28
7,7
24.8
Sample 3
11-06-08
25.25-h
36
40
252
<0.10
1.5
6.99
7.7
24.6
Day 4
Initial | Final
Growth
Critical
2.410
2.410
2.410
2.410
2.410
Calculated
-0.041
0.413
1.867
1.875
0.182
End time:
0937
6.75
5.3
24.5
Day 0
Initial | Final
Sample 1
11-02-08
Day 1
Initial | Final
Sample 2
11-04-08
Day 3
Initial | Final
Survival
NA
NA
14%
>14%
>14%
Visual Inspec.
Growth
Yes
Yes
14%
>14%
>14%
Dunnett's
% Effluent
3.5%
5.25%
7.0%
10.5%
14%
10.
10
0.602
PO Box 7565
AWille,NC 28802
Phone: [phone]
Fax: [phone]
E-mail: [e-mail]
Sample Information
Collection start date:
Grab:
Composite duration:
Alkalinity (mg/L CaCO3):
Hardness (mg/L CaCO3):
Conductivity (pmhos/cm):
Total residual chlorine (mg/L):
Sample Temp, at Receipt (°C):
Analyses
Normal:
Hom. Var.
NOEC:
LOEC:
ChV:
Method:
Control
pH (SU):
DO (mg/L):
Temp. (°C):
High Concentration
pH (SU):
DO (mg/L):
Temp. (°C):

Project: 5061___________________________
Samples: 081 104.02,081106.02,081108.10
Date: November 24, 2008
Chronic Fathead Minnow Multi-Concentration Test
County: Halifax
Day 2
Initial | Final
Surviving number of larvae
Organisms Original number of larvae
Weight/original (mg/larvae)
Surviving number of larvae
| 3.5% | Original number of larvae
Weight/original (mg/larvae)
Surviving number of larvae
| 5.25% | Original number of larvae
Weight/original (mg/larvae)
Laboratory Performing Test: Environmental Testing, Signature of Operator in Responsible Charge:
Signature of Laboratory Supervisor: <
Day 6
Initial | Final |
' r/
. Environmental Testing Solutions, Inc.
Effluent Aquatic Toxicity Report Form -