NC0024333__Modification_20240805

.ea14STATEo,
ROY COOPER
''?, I)
Governor
ELIZABETH S.BISER . •
�sr awM,,..}'
Secretory _ ,,,- r
RICHARD E.ROGERS,JR. NORTH CAROLINA
Director Environmental Quality
August 05, 2024
City of Monroe
Attn: Scott Clark, Director of Water Resources
PO Box 69
Monroe, NC 28111
Subject: Permit Renewal
Application No. NC0024333
Monroe WWTP
Union County
Dear Applicant:
The Water Quality Permitting Section acknowledges the August 5, 2024, receipt of your permit modification application
and supporting documentation. Your application will be assigned to a permit writer within the Section's NPDES WW
permitting branch. Per G.S. 150E-3 your current permit does not expire until permit decision on the application is made.
Continuation of the current permit is contingent on timely and sufficient application for renewal of the current permit. The
permit writer will contact you if additional information is required to complete your permit renewal. Please respond in a
timely manner to requests for additional information necessary to allow a complete review of the application and renewal
of the permit.
Information regarding the status of your renewal application can be found online using the Department of Environmental
Quality's Environmental Application Tracker at:
https://www.deq.nc.gov/permits-rules/environmental-application-tracker
If you have any additional questions about the permit, please contact the primary reviewer of the application using the
links available within the Application Tracker.
Sincere),:lii:
Wren edford
Administrative Assistant
Water Quality Permitting Section
ec: WQPS Laserfiche File w/application
.DE �p North Carolina Department of Environmental Quality I Division of Water Resourres
704 66 vllk Rrgional Office 610 East Cmtrr Avmue.Suite 301 Mooresvilk.North Carolina 28115
6'�' 704.bb3.Ib99

Hazen
RECEIVED
AUG 0 2 2024
July 31, 2024
NCDEQ/DWR/NPDES
To: North Carolina Department of Environmental Quality
Division of Water Resources
1617 Mail Service Center
Raleigh,NC, 27699-1617
Attention: Mr. Mike Montebello
Job: 32138-020: Monroe WWTP Expansion to 13.4 mgd
We Are Herewith i Under Separate Cover Sent By: Blue Printer Hold for Pickup
Sending You: Reports H I Tracings Prints : Hand Delivered Mail
Shop Drawings H Specifications X Other X UPS FedEx
No. Date I Descri.tion
1 7/31/2024 Check for Major Modification Fee of$1,387
2 7/31/2024 Monroe Wastewater Treatment Plant NPDES Permit Major Modification Application
(NC0024333)—3 copies
3 7/31/2024 Monroe Wastewater Treatment Plant NPDES Permit Major Modification Application
(NC0024333)—USB Drive
Remarks:
Transmitted: Copies to:
At Your Request
1.7 For Your Information
LE For Your Comments
Z For Your Approval Very truly yours,
El For Distribution Hazen and Sawyer
❑Revise and Resubmit
H Other File. By: Mary E. Sadler, PE
Hazen and Sawyer•9101 Southern Pine Blvd, Suite 250 •Charlotte, NC 28273•704.357.3150

Monroe
City of
Water Resources monroenc.org • 704-282-4601 • PO Box 69,Monroe,NC 28111
July 29, 2024 PECEIVEO
Mr. Mike Montebello mIG 0 2 2024
Water Quality Permitting Section,NPDES
Division of Water Resources WR�NppES
North Carolina Department of Environmental Quality CpEQID
1617 Mail Service Center Raleigh,NC,27699-1617
Re: NPDES Permit Renewal and Major Modification Application(NC0024333)
City of Monroe Wastewater Treatment Plant
City of Monroe,North Carolina
Dear Mr.Montebello:
The City of Monroe is permitted to discharge 10.4 million gallons per day(mgd)of treated effluent from the
City of Monroe Wastewater Treatment Plant(WWTP)to Richardson Creek in the Yadkin Pee Dee River
basin per North Carolina National Pollutant Discharge Elimination System(NPDES)Permit NC0024333.
This NPDES permit is scheduled to expire on January 31,2025. The current NPDES permit contains
effluent flow limits for 10.4 and 12.4 mgd.
The enclosed application is for the renewal of this permit and a major modification request for expansion of
the City's WWTP from 10.4 mgd to 15.4 mgd. In accordance with the requirements of federal(40 CFR 122)
and state(15A NCAC 2H .0105(3))regulations,we are submitting three signed copies and one electronic
file of the completed application package and associated attachments and figures. The application package
includes the following information:
• Application fee of$1,387
• Tab A: Application EPA Form 2A
• Tab B: EPA Form 2A Additional Information(Site Plans,Process Narrative,Topographic Map,
and Process Flow Diagrams)
• Tab C: Residuals Management Plan
• Tab D: Summary of First Species Effluent Toxicity Testing,2021 to 2024
• Tab E: Annual Priority Pollutant Analysis Results,2021 to 2024
• Tab F: Second Species Effluent Toxicity Testing(fourth test pending)
• Tab G: Engineering Alternatives Analysis with Speculative Limits Letter
Major Modification Request for an Expansion to 15.4 mgd
We request an expansion of our Monroe WWTP from 10.4 to 15.4 mgd. This expansion is necessary to meet
the economic development needs in the City's service area over the 20-year planning period(e.g.,2045)and
accommodate additional wastewater flow from Union County. We currently have a contract with Union
County to treat up to 2.65 mgd of domestic wastewater flow. We are currently in discussions with the County
to provide additional wastewater capacity.

The City has prepared an Engineering Alternatives Analysis(EAA)to support a WWTP expansion from 10.4
to 15.4 mgd. An interim expansion from 10.4 to 13.4 mgd is necessary to phase infrastructure costs of the
proposed expansion over the planning period. An EAA was prepared in accordance with Division of Water
Resources(DWR)Engineering Alternatives Analysis Guidance dated January 2024 and is located in Tab G of
this application.
Effluent disposal at the existing outfall to Richardson Creek was identified as the preferred project alternative.
No additional land will be required for this project alternative as all modifications will be restricted to plant
property. This alternative has been selected by the City to be the most technically feasible,the most
economical,and protective of receiving stream water quality. The City received speculative limits from DWR
in 2021 for the proposed expansion. DWR determined that assimilative capacity was available for a surface
water discharge of 15.4 mgd at the existing Monroe WWTP outfall. The speculative limits letter is located in
Tab G Attachment C of this application.
The City commissioned a Preliminary Engineering Report(PER)in 2022 that evaluated the WWTP
expansion options.The PER recommended a new parallel treatment facility located outside the current fence
line but within the WWTP property boundary. Previous expansion projects maximized the available site
footprint within the existing fence line. Additionally,portions of the existing facility infrastructure are
60 years old,which exceeds useful service life.The new parallel treatment facility will be sized for future
expansions to 24 mgd. It is anticipated that the existing WWTP will eventually be decommissioned as the
parallel treatment facility is constructed in phases.
Due to hydraulic constraints,a new Outfall 002 will be required for the parallel treatment facility. The
proposed Outfall 002 is 1,400 feet downstream of existing Outfall 001 and is within the Monroe WWTP
property boundary. We anticipate NPDES compliance for 10.4 mgd at the existing Outfall 001 and a separate
compliance Outfall 002 for the 3 mgd parallel treatment facility.
Second Species Toxicity Testing
At the time of this application submittal,a fourth second species toxicity testing event is not completed. The
fourth second species test is scheduled to be completed in September 2024. The second species toxicity tests
will be forwarded to the Division of Water Resources(DWR)along with revisions to Part E of EPA Form 2A
to include this fourth test result.
Monitoring Reduction Frequency
The City has prepared a monitoring frequency reduction analysis in accordance with DWR's guidance
document,Reduction of Monitoring Frequencies in NPDES Permits for Exceptionally Performing Facilities
(October 2012). Per the DWR guidance,the following criteria has been met by the City of Monroe:
• The WWTP has not had any civil penalty assessments in the past three years for permit
limit violations for either biochemical oxygen demand (BOD),total suspended solids
(TSS),ammonia,or fecal coliform.
• Monroe WWTP employees have not been convicted of any criminal violations of the Clean
Water Act(CWA).
• The City is not currently under a Special Order of Consent(SOC).

• The Monroe WWTP is not on EPA's Quarterly Noncompliance Report for BOD, TSS,
ammonia,or fecal coliform.
Table 1 provides a summary of DMR data from June 2021 through May 2024 that supports a reduction in the
monitoring frequency for BOD, TSS,ammonia,and fecal coliform.The three-year arithmetic mean of
effluent data is less than 50 percent of the monthly permit limit for all parameters. Less than 15 of the daily
effluent samples are over 200 percent of the monthly average permit limit for BOD,TSS,and ammonia and
less than 20 of the daily effluent samples are over 200 percent of the weekly average permit limit for fecal
coliform.Our WWTP meets the requirements to be categorized as an Exceptionally Performing Facility per
DWR guidance and is eligible for a reduction in the monitoring frequency of all four parameters.
Table 1: Summary of Reduction of Monitoring Frequency Reduction Analysis
Fecal
Approval Criteria 1.2 BOD5 TSS Ammonia Coliform
3-year average 2.86 mg/L 2.29 mg/L 0.004 mg/L 2.0/ 100 mL
7.3 mg/L 1.0 mg/L
Monthly Average (summer) 30 mg/L (summer) 400/ 100 mL
Permit Limit 14.5 mg/L 2.0 mg/L
(winter) (winter)
7.5 mg/L
Weekly Average (summer) 45 mg/L 3 mg/L 276/ 100 mL
Permit Limit 15.0 mg/L
(winter)
Percent of permit limit 39% 7.6% < 1 (summer) 0.5%
Number of daily
samples over 200%of 1 (summer) 7 0(summer)
monthly average permit 6(winter) 0(winter)
limit
Number of daily
samples over 200%of
weekly average permit _-- ---- ---- 0
limit
Non-monthly average
violations between 0(summer) 0 0 1
6/1/2023 through 0(winter)
5/31/2024
Data in compliance
with DWR Guidance Yes Yes Yes Yes
for Monitoring
Frequency Reduction?
Per Division of Water Resources Guidance Regarding the Reduction of Monitoring Frequencies in
NPDES Permits for Exceptionally Performing Facilities dated October 2012.
2 Analysis is representative of data from June 2021 through May 2024.
Mercury Minimization
The City prepared a Mercury Minimization Plan(MMP)in January 2022. Per our Plan,the City has
continued to comply with the Dental Amalgam Rule. We also distribute Industrial Waste Surveys to
prospective industries and evaluate discharges prior to issuing Industrial Use Permits. The City also continues
to collect Long Term Monitoring Plan(LTMP)data on the influent and effluent to track mercury discharges
in our WWTP effluent.

If you have any questions regarding any of the NPDES permit renewal application materials,please contact
me at(704)282-4624 or [e-mail].
Sincerely,
' CI'
Scott Clark
Director of Water Resources
Attachments
cc: Amy Cook, PE,City of Monroe
Kyle Edwards,City of Monroe
Mike Parker,PE,Hazen and Sawyer
Mary Sadler,PE,Hazen and Sawyer
L 1

City of Monroe
Monroe Wastewater Treatment Plant
NPDES Permit No. NC0024333
Outfall 002
Table of Contents
Tab A. EPA Form 2A
Tab B. EPA Form 2A Additional Information
a. Topographic Map
i. Figure 2.3
b. Site Map(Facility Site Plan)
i. 10.4 mgd Site Plan
ii. 13.4 mgd Site Plan
iii. 15.4 mgd Site Plan
c. Process Narrative (Attachment 1)
d. Process Flow Diagram
i. Figure 2.4.A(10.4 mgd)
ii. Figure 2.4.B (13.4 mgd)
iii. Figure 2.4.0 (15.4 mgd)
Tab C. Residuals Management Plan
Tab D. Summary of First Species Effluent Toxicity Testing,2021 to 2024
Tab E. Annual Priority Pollutant Analysis Results, 2021 to 2024
Tab F. Second Species Toxicity Testing Results, 2021 to 2024
Tab G. Engineering Alternatives Analysis with Speculative Limits Letter

Tab A

United States Office of Water EPA Form 3510-2A
Environmental Protection Agency Washington,D.C. Revised March 2019
Water Permits Division
►EPA Application Form 2A
New and Existing Publicly
Owned Treatment Works
NPDES Permitting Program
Note: Complete this form if your facility is a new or existing publicly owned treatment works.

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
Form U.S.Environmental Protection Agency
2A &EPA Application for NPDES Permit to Discharge Wastewater
NPDES NEW AND EXISTING PUBLICLY OWNED TREATMENT WORKS
SECTION 1.BASIC APPLICATION INFORMATION FOR ALL APPLICANTS(40 CFR 122.21(j)(1)and(9))
1.1 Facility name
City of Monroe WWTP
Mailing address(street or P.O.box)
PO Box 69
City or town State ZIP code
o Monroe North Carolina 28111-0069
Contact name(first and last) Title Phone number Email address
Scott E.Clark Director of Water Resources [phone] [e-mail]
Location address(street,route number,or other specific identifier) ❑Same as mailing address
775 Treeway Drive
LL -
City or town State ZIP code
Monroe North Carolina 28110
1.2 Is this application for a facility that has yet to commence discharge?
❑ Yes 4 See instructions on data submission ❑ No
requirements for new dischargers.
1.3 Is applicant different from entity listed under Item 1.1 above?
O Yes 0 No 5 SKIP to Item 1.4.
Applicant name
Applicant address(street or P.O.box)
0
8City or town State ZIP code
03 Contact name(first and last) Title Phone number Email address
n.
a
1.4 Is the applicant the facility's owner,operator,or both?(Check only one response.)
❑ Owner ❑ Operator E Both
1.5 To which entity should the NPDES permitting authority send correspondence?(Check only one response.)
❑ Facility El Applicant
❑ Facility and applicant
(they are one and the same)
1.6 Indicate below any existing environmental permits.(Check all that apply and print or type the corresponding permit
number for each.)
Existing Environmental Permits
❑r NPDES(discharges to surface ❑ RCRA(hazardous waste) ❑ UIC(underground injection
water) control)
NC0024333
o ❑ PSD(air emissions) ❑ Nonattainment program(CAA) ❑ NESHAPs(CM)
rn
y ❑ Ocean dumping(MPRSA) ❑ Dredge or fill(CWA Section 0 Other(specify)
w 404)
i NCG110022,WQ0001346,W
EPA Form 3510-2A(Revised 3-19) Page 1

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
1.7 Provide the collection system information requested below for the treatment works.
Municipality Population Collection System Type
Served Served (indicate percentage) Ownership Status
35,894 100 %separate sanitary sewer EI Own ❑ Maintain
lo Monroe 0 %combined storm and sanitary sewer ❑ Own 0 Maintain
d ❑ Unknown 0 Own ❑ Maintain
U)
e 4,055 100 %separate sanitary sewer 0 Own 0 Maintain
o Wingate(Unionfis 0 %combined storm and sanitary sewer 0 Own 0 Maintain
County) ❑ Unknown 0 Own 0 Maintain
a100 %separate sanitary sewer 0 Own 0 Maintain
Marshville 2,537 0 %combined storm and sanitary sewer ❑ Own 0 Maintain
R (Union County) 0 Unknown ❑ Own ❑ Maintain
E %separate sanitary sewer 0 Own 0 Maintain
N %combined storm and sanitary sewer 0 Own 0 Maintain
c 0 Unknown 0 Own 0 Maintain
`—' Total
d Population 42,486
ci Served
Separate Sanitary Sewer System Combined Storm and
Sanitary Sewer
Total percentage of each type of 100 % 0 %
sewer line(in miles)
a' 1.8 Is the treatment works located in Indian Country?
c
o ❑ Yes ❑s No
0
c 1.9 Does the facility discharge to a receiving water that flows through Indian Country?
co
c ❑ Yes ❑o No
1.10 Provide design and actual flow rates in the designated spaces. Design Flow Rate
10.4 mgd
= Annual Average Flow Rates(Actual)
Two Years Ago Last Year This Year
c
cu
CO_ 5.83 mgd 6.41 mgd 7.04 mgd
t" Maximum Daily Flow Rates(Actual)
ca Two Years Ago Last Year This Year
17.68 mgd 19.23 mgd 22.97 mgd 1
u, 1.11 Provide the total number of effluent discharge points to waters of the United States by type.
o Total Number of Effluent Discharge Points by Type 1
a Constructed
Combined Sewer
Treated Effluent Untreated Effluent Overflows Bypasses Emergency
_c .a Overflows
0
U)
0 1(+1 proposed)
EPA Form 3510-2A(Revised 3-19) Page 2

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
Outfalls Other Than to Waters of the United States
1.12 Does the POTW discharge wastewater to basins,ponds,or other surface impoundments that do not have outlets for
discharge to waters of the United States?
❑ Yes ❑✓ No 4 SKIP to Item 1.14.
1.13 Provide the location of each surface impoundment and associated discharge information in the table below.
Surface Impoundment Location and Discharge Data
Average Daily Volume Continuous or Intermittent
Location Discharged to Surface
Impoundment (check one)
O Continuous
gpd 0 Intermittent
❑ Continuous
gpd ❑ Intermittent
❑ Continuous
gpd ❑ Intermittent
-0
2 1.14 Is wastewater applied to land?
m 0 Yes 0 No 4 SKIP to Item 1.16.
c 1.15 Provide the land application site and discharge data requested below.
y Land Application Site and Discharge Data
o Continuous or
`o Location Size Average Daily Volume Intermittent
rn Applied (check one)
s ❑ Continuous
oacres gpd ❑ Intermittent
s acres gp
❑ Continuous
d
❑ Intermittent
--aa ❑ Continuous
a acres gpd 0 Intermittent
to
1.16 Is effluent transported to another facility for treatment prior to discharge?
o ❑ Yes ❑✓ No 4 SKIP to Item 1.21.
1.17 Describe the means by which the effluent is transported(e.g.,tank truck,pipe).
1.18 Is the effluent transported by a party other than the applicant?
❑ Yes ❑ No 4 SKIP to Item 1.20.
1.19 Provide information on the transporter below.
Transporter Data
Entity name Mailing address(street or P.O.box)
City or town State ZIP code
Contact name(first and last) Title
Phone number Email address
EPA Form 3510-2A(Revised 3-19) Page 3

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
1.20 In the table below,indicate the name,address,contact information,NPDES number,and average daily flow rate of the
receiving facility.
Receiving Facility Data
zf Facility name Mailing address(street or P.O.box)
City or town State ZIP code
0
U
Contact name(first and last) Title
0
0
Phone number Email address
0a NPDES number of receiving facility(if any) ❑None Average daily flow rate mgd
0 1.21 Is the wastewater disposed of in a manner other than those already mentioned in Items 1.14 through 1.21 that do not
have outlets to waters of the United States(e.g.,underground percolation,underground injection)?
rn
❑ Yes ❑ No 4 SKIP to Item 1.23.
obelow onthese otherdisposal Provide information in the table dis osal methods.
Information on Other Disposal Methods
o Disposal Location of Size of Annual Average Continuous or Intermittent
Method Disposal Site Disposal Site Daily Discharge (check one)
Description Volume
acresgpd ❑ Continuous
❑ Intermittent
❑ Continuous
acres gpd 0 Intermittent
0 Continuous
acres gpd 0 Intermittent
1.23 Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(n)?(Check all that apply.
y Consult with your NPDES permitting authority to determine what information needs to be submitted and when.)
0-
❑ Discharges into marine waters(CWA ❑ Water quality related effluent limitation(CWA Section
Section 301(h)) 302(b)(2))
❑✓ Not applicable
1.24 Are any operational or maintenance aspects(related to wastewater treatment and effluent quality)of the treatment works
the responsibility of a contractor?
❑ Yes ❑ No+SKIP to Section 2.
1.25 Provide location and contact information for each contractor in addition to a description of the contractors operational
and maintenance responsibilities.
Contractor Information
Contractor 1 _ Contractor 2 Contractor 3
0
Contractor name
(company name)
Mailing address
(street or P.O.box)
City,state,and ZIP
code
oContact name(first and
last)
Phone number
Email address
Operational and
maintenance
responsibilities of
contractor
EPA Form 3510-2A(Revised 3-19) Page 4

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
SECTION 2.ADDITIONAL INFORMATION(40 CFR 122.21(j)(1)and (2))
o Outfalls to Waters of the United States
Cr 2.1 Does the treatment works have a design flow greater than or equal to 0.1 mgd?
rn
o EYes ❑ No 4 SKIP to Section 3.
c 2.2 Provide the treatment works'current average daily volume of inflow Average Daily Volume of Inflow and Infiltration
"17; and infiltration.
1,668,389 gpd
c Indicate the steps the facility is taking to minimize inflow and infiltration.
B
m Visual inspections,Smoke testing,TV inspections, Flow monitoring data, Prioritizing repairs,Point repairs,Manhole
3 Rehabilitation,Pipe bursting and replacement of aging collection system piping.
0
w
c
2.3 Have you attached a topographic map to this application that contains all the required information?(See instructions for
RI O. specific requirements.)
o
n' EYes ElNo
E 2.4 Have you attached a process flow diagram or schematic to this application that contains all the required information?
3 to (See instructions for specific requirements.)
rn
a ❑✓ Yes ❑ No
2.5 Are improvements to the facility scheduled?
✓❑ Yes ❑ No 4 SKIP to Section 3.
= Briefly list and describe the scheduled improvements.
0
'� 1 Expansion to 13.4 MGD(improvements to influent pumping,new facilities include:screenings facility,alkalinity feed,
c one(1)BNR basin,three(3)aeration blowers,two(2)final clarifiers, RAS pump station,two(2)disk filters,two(2)utt
E
Gl
2. Expansion to 15.4 MGD(+one(1)fine screen,+one(1)BNR basin,+one(1)blower,improvements to disk filtration,U
E li
0
u, 3.
o
c
d
0 4.
U)
R 2.6 Provide scheduled or actual dates of completion for improvements.
c Scheduled or Actual Dates of Completion for Improvements
°' Affected Attainment of
E Scheduled Begin End Begin
> Outfalls Operational
2 Improvement Construction Construction Discharge
p, (list outfall Level
E (from above) (MM/DD/YYYY) (MM/DD/YYYY) (MM/DD/YYYY)
number) (MM/DD/YYYY)
1. 001,002(New) 10/01/2025 10/01/2028 10/01/2028 10/01/2028
13
a>
v 2. 001,002 10/01/2035 10/01/2037 10/01/2037 10/01/2037
3.
4.
2.7 Have appropriate permits/clearances concerning other federal/state requirements been obtained?Briefly explain your
response.
ElYes ❑ No ❑ None required or applicable
Explanation:
Appropriate permits and clearances will be obtained during construction and prior to discharge into the receiving stream.
EPA Form 3510-2A(Revised 3-19) Page 5

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
SECTION 3.INFORMATION ON EFFLUENT DISCHARGES(40 CFR 122.21(j)(3)to(5))
3.1 Provide the following information for each outfall.(Attach additional sheets if you have more than three outfalls.)
Outfall Number ooi Outfall Number 002 Outfall Number
State North Carolina North Carolina(Proposed)
County Union Union(Proposed)
O City or town Monroe,NC Monroe,NC(Proposed)
0
Distance from shore o ft. o ft. ft.
d Depth below surface 0 ft. o ft. ft.
0
Average daily flow rate 6.989 mgd Proposed mgd mgd
Latitude 34° 59' 47" N 34° 59' 54" N
Longitude 80 29' 29" W 80` 29' 15" W ° "
3.2 Do any of the outfalls described under Item 3.1 have seasonal or periodic discharges?
c ❑ Yes El No-?t SKIP to Item 3.4.
3.3 If so,provide the following information for each applicable outfall.
y Outfall Number Outfall Number Outfall Number
n Number of times per year
discharge occurs
et_ Average duration of each
o discharge(specify units)
Average flow of each mgd mgd mgd
discharge
Months in which discharge
occurs
3.4 Are any of the outfalls listed under Item 3.1 equipped with a diffuser?
❑ Yes 0 No 4 SKIP to Item 3.6.
3.5 Briefly describe the diffuser type at each applicable outfall.
Outfall Number Outfall Number Outfall Number
Does the treatment works discharge or plan to discharge wastewater to waters of the United States from one or more
m = 3.6 discharge points?
3 w 0 Yes ❑ No+SKIP to Section 6.
EPA Form 3510-2A(Revised 3-19) Page 6

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
3.7 Provide the receiving water and related information(if known)for each outfall.
Outfall Number ow Outfall Number °°2 Outfall Number
Receiving water name Richardson Creek Richardson Creek(Proposed)
Name of watershed,river, Yadkin—Pee Dee Yadkin—Pee Dee(Proposed)
g or stream system
a U.S.Soil Conservation
y Service 14-digit watershed 03040105070020 03040105070020(Proposed)
o code
g Name of state 3 management/river basin Yadkin—Pee Dee Yadkin—Pee Dee(Proposed)
U.S.Geological Survey
0 8-digit hydrologic 03040105 03040105(Proposed)
o
co cataloging unit code
Critical low flow(acute) 0.433 cfs 0.433 cfs cfs
Critical low flow(chronic) 0.433 cfs 0.433 cfs cfs
Total hardness at critical mg/L of mg/L of mg/L of
low flow NA CaCO3 NA CaCO3 CaCO3
3.8 Provide the following information describing the treatment provided for discharges from each outfall.
Outfall Number 001 Outfall Number N2 Outfall Number
Highest Level of 0 Primary 0 Primary ❑ Primary
Treatment(check all that 0 Equivalent to ❑ Equivalent to 0 Equivalent to
apply per outfall) secondary secondary secondary
0 Secondary 0 Secondary 0 Secondary
0 Advanced 0 Advanced 0 Advanced
i ❑ Other(specify) 0 Other(specify) ❑ Other(specify)
c
i, Design Removal Rates by 001 002(Proposed Outfall)
0 Outfall
2 BOD5 or CBOD5 98.71 % 98.71
e
m
ITSS 98.55 % 98.55 %
0 Not applicable 0 Not applicable 0 Not applicable 1
Phosphorus % % %
0 Not applicable 0 Not applicable 0 Not applicable
Nitrogen %
Other(specify) 0 Not applicable ❑Not applicable ❑Not applicable
Ammonia 99.98 % 99.98 %
EPA Form 3510-2A(Revised 3-19) Page 7
1
I

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
3.9 Describe the type of disinfection used for the effluent from each outfall in the table below. If disinfection varies by
season,describe below.
Chlorination(001)and UV(002)
as
0
Outfall Number 001 Outfall Number 002 Outfall Number
0
a Disinfection type UV(Proposed)
Chlorination
Seasons used All
ll
co
Dechlorination used? ❑ Not applicable El Not applicable ❑ Not applicable
0 Yes ❑ Yes ❑ Yes
❑ No 0 No El No
3.10 Have you completed monitoring for all Table A parameters and attached the results to the application package?
O Yes ❑ No
3.11 Have you conducted any WET tests during the 4.5 years prior to the date of the application on any of the facility's
discharges or on any receiving water near the discharge points?
❑✓ Yes El No 4 SKIP to Item 3.13.
3.12 Indicate the number of acute and chronic WET tests conducted since the last permit reissuance of the facility's
discharges by outfall number or of the receiving water near the discharge points.
Outfall Number 001 Outfall Number 002 Outfall Number
Acute Chronic Acute Chronic Acute Chronic
Number of tests of discharge
water 3 13 Proposed OProposed Ot
Number of tests of receiving
water
3.13 Does the treatment works have a design flow greater than or equal to 0.1 mgd?
ElYes ❑ No+ SKIP to Item 3.16.
0 3.14 Does the POTW use chlorine for disinfection,use chlorine elsewhere in the treatment process,or otherwise have
reasonable potential to discharge chlorine in its effluent?
❑✓ Yes 4 Complete Table B,including chlorine. ❑ No 4 Complete Table B,omitting chlorine.
3.15 Have you completed monitoring for all applicable Table B pollutants and attached the results to this application
package?
w ❑✓ Yes El No
3.16 Does one or more of the following conditions apply?
• The facility has a design flow greater than or equal to 1 mgd.
• The POTW has an approved pretreatment program or is required to develop such a program.
• The NPDES permitting authority has informed the POTW that it must sample for the parameters in Table C,must
sample other additional parameters(Table D),or submit the results of WET tests for acute or chronic toxicity for
each of its discharge outfalls(Table E).
Yes 4 Complete Tables C,D,and E as
❑ applicable. ElNo 4 SKIP to Section 4.
3.17 Have you completed monitoring for all applicable Table C pollutants and attached the results to this application
package?
❑✓ Yes ❑ No
3.18 Have you completed monitoring for all applicable Table D pollutants required by your NPDES permitting authority and
attached the results to this application package?
ID Yes No additional sampling required by NPDES
permitting authority.
EPA Form 3510-2A(Revised 3-19) Page 8

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
3.19 Has the POTW conducted either(1)minimum of four quarterly WET tests for one year preceding this permit application
or(2)at least four annual WET tests in the past 4.5 years?
No 4 Complete tests and Table E and SKIP to
E Yes ❑ Item 3.26.
3.20 Have you previously submitted the results of the above tests to your NPDES permitting authority?
❑ Yes ❑ No 4 Provide results in Table E and SKIP to
Item 3.26.
3.21 Indicate the dates the data were submitted to your NPDES permitting authority and provide a summary of the results.
Date(s)Submitted Summary of Results
(MM/DD/YYYY)
Test results have been submitted through e-permitting.
All WET test results have been provided with this NPDES Major
= Modification Request.Table E has been filled out and a summary of 1st
Species Toxicity Tests have been included with this package.
co 3.22 Regardless of how you provided your WET testing data to the NPDES permitting authority,did any of the tests result in
toxicity?
❑ Yes ❑✓ No 3 SKIP to Item 3.26.
tu3.23 Describe the cause(s)of the toxicity:
c
a,
w
3.24 Has the treatment works conducted a toxicity reduction evaluation?
❑ Yes ❑✓ No 3 SKIP to Item 3.26.
3.25 Provide details of any toxicity reduction evaluations conducted.
3.26 Have you completed Table E for all applicable outfalls and attached the results to the application package?
❑✓ ❑
Not applicable because previously submitted
Yes
information to the NPDES •ermittin• authorit .
SECTION 4. INDUSTRIAL DISCHARGES AND HAZARDOUS WASTES(40 CFR 122.21(j)(6)and(7))
4.1 Does the POTW receive discharges from SIUs or NSCIUs?
✓❑ Yes ❑ No 4 SKIP to Item 4.7.
4.2 Indicate the number of SIUs and NSCIUs that discharge to the POTW.
Number of SIUs Number of NSCIUs
13 0
.12 4.3 Does the POTW have an approved pretreatment program?
_ © Yes ❑ No
g 4.4 Have you submitted either of the following to the NPDES permitting authority that contains information substantially
identical to that required in Table F: (1)a pretreatment program annual report submitted within one year of the
E application or(2)a pretreatment program?
co
❑ Yes ❑ No 4 SKIP to Item 4.6.
w 4.5 Identify the title and date of the annual report or pretreatment program referenced in Item 4.4.SKIP to Item 4.7.
11) City of Monroe Pretreatment Annual Report 02/29/2024
a
c
4.6 Have you completed and attached Table F to this application package?
❑✓ Yes ❑ No
EPA Form 3510-2A(Revised 3-19) Page 9

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
4.7 Does the POTW receive,or has it been notified that it will receive,by truck,rail,or dedicated pipe,any wastes that are
regulated as RCRA hazardous wastes pursuant to 40 CFR 261?
❑ Yes ❑ No 4 SKIP to Item 4.9.
4.8 If yes,provide the following information:
Annual
Hazardous Waste Waste Transport Method Amount of Units
Number (check all that apply) Waste
Received
❑ Truck ❑ Rail
❑ Dedicated pipe ❑ Other(specify)
.c
U '
❑ Truck ❑ Rail
Dedicated pipe Other(specify)
a
N ❑ Truck ❑ Rail
❑ Dedicated pipe ❑ Other(specify)
d
4.9 Does the POTW receive,or has it been notified that it will receive,wastewaters that originate from remedial activities,
including those undertaken pursuant to CERCLA and Sections 3004(7)or 3008(h)of RCRA?
0 Yes ❑ No Ht SKIP to Section 5.
3 4.10 Does the POTW receive(or expect to receive)less than 15 kilograms per month of non-acute hazardous wastes as
specified in 40 CFR 261.30(d)and 261.33(e)?
❑r Yes 4 SKIP to Section 5. ❑ No
4.11 Have you reported the following information in an attachment to this application:identification and description of the
site(s)or facility(ies)at which the wastewater originates;the identities of the wastewater's hazardous constituents;and
the extent of treatment,if any,the wastewater receives or will receive before entering the POTW?
❑ Yes ❑ No
SECTION 5.COMBINED SEWER OVERFLOWS(40 CFR 122.21(j)(8))
5.1 Does the treatment works have a combined sewer system?
❑ Yes ElNo 3SKIP to Section 6.
Of
5.2 Have you attached a CSO system map to this application?(See instructions for map requirements.)
e ❑
16 a Yes ❑ No
5.3 Have you attached a CSO system diagram to this application?(See instructions for diagram requirements.)
co
❑ Yes ❑ No
EPA Form 3510-2A(Revised 3-19) Page 10

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
5.4 For each CSO outfall,provide the following information.(Attach additional sheets as necessary.)
CSO Outfall Number CSO Outfall Number CSO Outfall Number
City or town
0
t State and ZIP code
c.)
o County
al
= Latitude °
0
0 °
c o Longitude °
Distance from shore ft. ft. ft.
Depth below surface ft. ft. ft.
5.5 Did the POTW monitor any of the following items in the past year for its CSO outfalls?
CSO Outfall Number CSO Outfall Number CSO Outfall Number
Rainfall ❑ Yes 0 No ❑ Yes 0 No ❑ Yes ❑ No
al
c
o CSO flow volume ❑ Yes 0 No 0 Yes 0 No ❑ Yes ❑ No
CSO pollutant 0 Yes 0 No 0 Yes 0 No 0 Yes 0 No
0 concentrations
y
a Receiving water quality 0 Yes 0 No 0 Yes 0 No 0 Yes ❑ No
CSO frequency 0 Yes 0 No 0 Yes 0 No 0 Yes 0 No
Number of storm events 0 Yes ❑ No ❑ Yes ❑No 0 Yes ❑ No
5.6 Provide the following information for each of your CSO outfalls.
CSO Outfall Number CSO Outfall Number CSO Outfall Number
w Number of CSO events in
>-
the past year events events events
W
R
Average duration per hours hours hours
c event ❑Actual or 0 Estimated 0 Actual or 0 Estimated 0 Actual or 0 Estimated
> million gallons million gallons million gallons
o Average volume per event
0 0 Actual or 0 Estimated 0 Actual or 0 Estimated 0 Actual or 0 Estimated
Minimum rainfall causing inches of rainfall inches of rainfall inches of rainfall
a CSO event in last year 0 Actual or 0 Estimated 0 Actual or 0 Estimated 0 Actual or 0 Estimated
EPA Form 3510-2A(Revised 3-19) Page 11

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
5.7 I Provide the information in the table below for each of your CSO outfalls.
CSO Outfall Number CSO Outfall Number CSO Outfall Number
Receiving water name
Name of watershed/
stream system
U.S.Soil Conservation ❑Unknown 0 Unknown 0 Unknown
Service 14-digit
rn watershed code
(if known)
m Name of state
re management/river basin
0
U) U.S.Geological Survey 0 Unknown 0 Unknown 0 Unknown
8-Digit Hydrologic Unit
Code(if known)
Description of known
water quality impacts on
receiving stream by CSO
(see instructions for
exam sles
SECTION 6.CHECKLIST AND CERTIFICATION STATEMENT(40 CFR 122.22(a)and(d))
6.1 In Column 1 below,mark the sections of Form 2A that you have completed and are submitting with your application.For
each section,specify in Column 2 any attachments that you are enclosing to alert the permitting authority.Note that not
all applicants are required to provide attachments.
Column 1 Column 2
❑ Section 1: Basic Application ❑ w/variance request(s) ❑ wl additional attachments
Information for All Applicants
❑ Section 2:Additional 0 wl topographic map El w/process flow diagram
Information ❑ w/additional attachments
w/Table A El wl Table D
❑ Section 3:Information on ❑ w/Table B ❑
Effluent Discharges w/Table E
❑ wl Table C ❑ w/additional attachments
Section 4: Industrial ❑ w/SIU and NSCIU attachments ❑ w/Table F
_ 0 Discharges and Hazardous ❑
Wastes ✓ w/additional attachments
.71
❑ Section 5:Combined Sewer ❑ wl CSO map El w/additional attachments
:E* Overflows
❑ w/CSO system diagram
a Section 6:Checklist and ❑
Certification Statement w/attachments
N
6.2 Certification Statement
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in
accordance with a system designed to assure that qualified personnel properly gather and evaluate the information
submitted.Based on my inquiry of the person or persons who manage the system. or those persons directly responsible
for gathering the information, the information submitted is,to the best of my knowledge and belief, true,accurate,and
complete.I am aware that there are significant penalties for submitting false information,including the possibility of fine
and imprisonment for knowing violations.
Name(print or type first and last name) Official title
Scott E.Clark Water Resources Director
Signature Date signed
/� Chit 7-2 9-Z02.y
EPA Form 3510-2A(Revised 3-19) Page 12

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP 001 OMB No.2040-0004
TABLE A. EFFLUENT PARAMETERS FOR ALL POTWS
Maximum Daily Discharge Average Daily Discharge Analytical ML or MDL
Pollutant Value Units Value Units Number of Methods (include units)
Sam*les
Biochemical oxygen demand
CI ML
i BOD5 or❑CBOD5 167 mg/I 2.86 mg/I 739 SM 5210 B 2 0 MDL
resort one
0 ML
Fecal coliform 70 cfu 2.00 cfu 742 SM 9222 D 2 l7 MDL
Design flow rate 22.97 MGD 6.425 MGD 1096
pH(minimum) 6.0 su
pH(maximum) 7.5 su
Temperature(winter) 23 C 17.9 C 297
Temperature(summer) 27 C 23.07 C 423
0 ML
Total suspended solids(TSS) 223 mg/I 2.29 mg/I 741 SM 2540 D 2.5 0 MDL
1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2A(Revised 3-19) Page 13

This page intentionally left blank.

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP 001 OMB No.2040-0004
TABLE B. EFFLUENT PARAMETERS FOR ALL POTWS WITH A FLOW EQUAL TO OR GREATER THAN 0.1 MGD
Maximum Daily Discharge Average Daily Discharge Analytical ML or MDL
Value Units Value Units
Pollutant Number of Method', (include units)
_ Samples
o ML
Ammonia(as N) 1.9 mg/I 0.004 mg/I 741 4500 NH3 C 1 2 MDL
Chlorine 0 ML
(total residual,TRC)2 <10 ug/I <10 ug/I 742 4500 CLG 10 E MDL
0 ML
Dissolved oxygen 9.73 mg/I 7.16 mg/I 742 10360LD0 NA 0 MDL
0 ML
Nitrate/nitrite 41 mg/I 29.36 mg/I 42 353.2 0.4/0.5 2 MDL
0 ML
Kjeldahl nitrogen 2.3 mg/I 0.97 mg/I 49 EPA 351.2 0.1/0.5 2 MDL
0 ML
Oil and grease 8.2 mg/I 0.19 mg/I 47 EPA 1664 B 4.8/5.1 2 MDL
0 ML
Phosphorus 5.5 mg/I 3.38 mg/I 48 EPA 365.1 0.05/0.5 2 MDL
0 ML
Total dissolved solids 530 mg/I 430.33 mg/I 3 2540C-20 25 2 MDL
1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR chapter I,subchapter N or O.See instructions and 40 CFR 122.21(e)(3).
2 Facilities that do not use chlorine for disinfection,do not use chlorine elsewhere in the treatment process,and have no reasonable potential to discharge chlorine in their effluent are not
required to report data for chlorine.
EPA Form 3510-2A(Revised 3-19) Page 15

This page intentionally left blank.

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP 001 OMB No.2040-0004
TABLE C. EFFLUENT PARAMETERS FOR SELECTED POTWS
Maximum Daily Discharge Average Daily Discharge Analytical ML or MDL
Pollutant Number of Method' (include units)
Value Units Value Units Samples
Metals,Cyanide,and Total Phenols
Hardness(as CaCO3) 313 mg/I 142.69 mg/I 62 2430C/200.7 52/10 mg/I ❑❑O ML
MDL
Antimony,total recoverable <5 ug/I <5 ug/I 3 200.7/200.8 1/5 ug/I l0 ML
MDL
Arsenic,total recoverable <2 ug/I <2 ug/I 14 200.8 2 ug/I ML
0 MDL
EI Beryllium,total recoverable <1 ug/I <1 ug/I 4 200.7/200.8 1 ug/I ML
0 MDL
Cadmium,total recoverable <0.5 ug/I <0.5 ug/I 14 200.8 .2/0.5 ug/I 0 ML
0 MDL
Chromium,total recoverable 4.9 ug/I 0.41 ug/I 14 200.7/200.8 1/5 ug/I 0 ML
❑MDL
ML
Copper,total recoverable 9 ug/I 5.97 ug/I 68 200.7/200.8 1/2/5 ug/I 0 MDL
Lead,total recoverable <2 ug/I <2 ug/I 14 200.8 1/2 ug/I O ML
0 MDL
2 ML
Mercury,total recoverable 3.69 ng/I 0.88 ng/I 14 1631E 0.5 ng/I ❑MDL
Nickel,total recoverable 9.8 ug/I 6.50 ug/I 14 200.7/200.8 1/2/5 ug/I 0 ML
❑MDL
Selenium,total recoverable <5 ug/I <5 ug/I 14 200.8 2/5 ug/I 0 ML
❑MDL
Silver,total recoverable <1 ug/I <1 ug/I 66 200.8 /0.5/1 ug/I 0 ML
MDL
Thallium,total recoverable <10 ug/I <10 ug/I 4 200.7/200.8 ./2/10 ug/I 0 ML
MDL
Zinc,total recoverable 107 ug/I 68.27 ug/1 68 200.7/200.8 10 ug/I 0 ML
0 MDL
Cyanide 18 ug/I 0.64 ug/I 723 335.4/4500-CN 4/10 ug/I O M
❑MDL
Total phenolic compounds 0.016 mg/I 0.0078 mg/I 4 420.4 5/.02 mg/I 0 ML
❑MDL
Volatile Organic Compounds
2 ML
Acrolein <5 ug/I <5 ug/I 3 624.1 5 ug/I 0 MDL
Acrylonitrile <5 ug/I <5 ug/I 3 624.1 5 ug/I ML
0 MDL
Benzene <1 ug/1 <1 ug/I 4 624.1 1 ug/I 0 ML
❑MDL
2 ML
Bromoform <2 ug/I <2 ug/I 4 624.1 1/2 ug/I 0 MDL
EPA Form 3510-2A(Revised 3-19) Page 17

m D
> co
T N r
' O CD CD CD CD W N 7 N 7' Cj S 7" 7' O m m
c.' N C) N S �G [1 d a N d a �_ O _� 0 O O Q C) D
cr. .., :-. 7 0 IV `G `< Cr n c) C) — C) C) O O_ 0 O O O O
m 0 7• 7- 7- 7- o o CD a 0 = m 0 CD
N 7- � O O_ N a9 a- 0 N O 0 0 N O O Q O CD 5- Q_ j CD T o
O O O C) C'f 0 3 7 O O O n O O O 3 ,5 a) O N f_ 0 =;
a a 0 7- a a CD o CD o- co co 3 < CD 3 7 c) o C O�
< CD CD ,< o O CD CD -00 -0 `G O w y 0 7• O (D C� rn A
n N N CD O j N C7D fD CD 5`i c
G' CD m C° CD 7 CD CD 5- v 3 a)i CD ... v w 33
i CD `G 7 CD O D CD
0
cD 7 CD CD CD D
CD CD
m
T
0
73
N C Z
A A A A A A A A A A A A A A ALr1CDA A A A IN cn13
NJ NJ I--' NJ NJ NJ NJ NJ I--• NJ NJ NJ N NJ NJ N lM U) NJ ~ 0
O NJ NJ X rn Z m3 m CD 3 -I on
m A 3.
ID O w
m -0 W 3
O o-
O -I co
0 �
C C C C C C C C C C C C C C C C C C C C C C C CO
0O 00 00 00 00 00 CA 00 00 00 00 00 CYO 00 OO 00 00 00 C10 00 Ocl'S 00 7
(")
0
'-' TI
3
0
A A A A A A A A A A A A A A A • cc-, A A • A A m
N N N. NJ NJ NJ NJ NJ 1--• NJ NJ NJ NJ NJ NJ V Co h r NJ N NJ NJ C 0 Z
W LA W CD CDC 3
G CD
CD I
C
CD
0
C C 00Cpp C C C C ppCpp C C C C ppCp ppCp CC C C C C C ppCpp C co
\ \ \ 0-0 \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ \ 3
y
O
Cn
S 0
Co C
CC co
CD 0
0
r c
Z 3
CO
A A A A A A A A A A A A A AA A A W A A A A ,� A
CD -11
Cn O
m. j
CJ) a) Cr) Cr) al 01 a) 01 CT CJ) CJ) CJ) a, O) al CJ) CT 01 01 01 01 01 CD y
NJ N NJ NJ NJ NJ N NJ NJ N NJ N NJ N NJ NJ NJ NJ NJ NJ NJ NJ
A A A A A A A A A A A A A A A A A A A A A A •„.
i-+ I-. i--' i-+ F' F' i--' F F F F N+ F' ' ' ' I-) N C F' i--' I-+ r F' i-' 0 n
m
T
0
1-, I-' F' 1- I-' F' 1-+ I--' N I-, I- I� I� I-, I� I-, ^
03
NJ NJ I--‘ N J NJ NJ NJ NJ Fs NJ NJ NJ NJ NJ NJ NJ NJU-i NJ NJ NJ NJ = �'S 3 D
C C C C C C C C C C C C C C C C C C C C C C C r co,
00 00 \ �' oG\ \ 00 \ 00 \ 00 \ \ 00 00 00 00 00 00 00 00 00 00 CD
is
❑©❑© ❑© ❑© ❑©❑© ❑© ❑© ❑©❑©❑©❑© ❑© ❑©❑© ❑©❑© ❑©❑© ©©❑© ❑© =. C A W
co 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 3 r 'o
CO 0 r 0 r 0 r 0 r 0 r 0 r 0 r O r Or' 0 r 0 r- 0' Or Or' 0' 0' 0r0' 0' 0 0m0' ocn
r r r r r r r r r r r r r r r r r r r r r r C
EO m

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP 001 0MB No.2040-0004
TABLE C. EFFLUENT PARAMETERS FOR SELECTED POTWS
Maximum Daily Discharge Average Daily Discharge Analytical ML or MDL
Pollutant Number of Method1 (include units)
Value Units Value Units Samples
ID ML
Trichloroethylene <2 ug/I <2 ug/I 4 624.1 1/2 ug/I ❑MDL
ID ML
Vinyl chloride <2 ug/I <2 ug/I 4 624.1 1/2 ug/I ❑MDL
Acid-Extractable Compounds
ML
p-chloro-m-cresol <5 ug/I <5 ug/I 2 625.1 4.5/5 ug/I ❑❑MDL
2-chlorophenol <5 ug/I <5 ug/I 4 625.1 4.5/5 ug/I O ML
❑MDL
2,4-dichlorophenol <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I O ML
❑MDL
ID
2,4-dimethylphenol <10 ug/I <10 ug/I 4 625.1 3.1/10 ug/I ML
❑MDL
4,6-dinitro-o-cresol <10 ug/I <10 ug/I 4 625.1 3.1/10 ug/I O M
❑MDL
2,4-dinitrophenol <50 ug/I <50 ug/I 4 625.1 3.5/50 ug/I El ML
0 MDL
ID ML
2-nitrophenol <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I ❑MDL
4-nitrophenol <10 ug/I <10 ug/I 4 625.1 3.1/10 ug/I ID ML
❑MDL
Pentachlorophenol <10 ug/I <10 ug/I 4 625.1 3.1/10 ug/I O ML
❑MDL
E ML
Phenol <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I ❑MDL
ID ML
2,4,6-trichlorophenol <10 ug/I <10 ug/I 4 625.1 3.1/10 ug/I ❑MDL
Base-Neutral Compounds
Acenaphthene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I O ML
❑MDL
ID ML
Acenaphthylene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I ❑MDL
O ML
Anthracene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 MDL
Benzidine <50 ug/I <50 ug/I 2 625.1 8/50 ug/I CI ML
❑MDL
Benzo(a)anthracene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I O ML
❑MDL
Benzo(a)pyrene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I O ML
0 MDL
3,4-benzofluoranthene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I ID ML
❑MDL
EPA Form 3510-2A(Revised 3-19) Page 19

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP 001 0MB No.2040-0004
TABLE C. EFFLUENT PARAMETERS FOR SELECTED POTWS
Maximum Daily Discharge Average Daily Discharge Analytical ML or MDL
Pollutant Number of Method', (include units)
Value Units Value Units Samples
Benzo(ghi)perylene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I D ML
❑MIX
Benzo(k)fluoranthene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 ML
❑MDL
O ML
Bis(2-chloroethoxy)methane <10 ug/I <10 ug/I 4 625.1 3.1/10 ug/I ❑MDL
CI ML
Bis(2-chloroethyl)ether <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 MDL
Bis 2-chloroiso ro I ether <5 ug/I <5 u I 4 625.1 l0 ML
( p py) g/ /4.5/5 ug/I ❑MDL
CI ML
Bis(2-ethylhexyl)phthalate <8 ug/I <8 ug/I 4 625.1 .5/5/8 ug/I ❑MDL
4-bromophenyl phenyl ether <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 ML
❑MDL _
0 ML
Butyl benzyl phthalate <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 MDL
2-chloronaphthalene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I ML
0 MDL
4-chlorophenyl phenyl ether <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I O M
❑MDL
Chrysene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 MMDL
di-n-butyl phthalate <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I ❑MMDL 1
di-n-octyl phthalate <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 ML
❑MDL
Dibenzo(a,h)anthracene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 ML
❑MDL
1,2-dichlorobenzene <10 ug/I <10 ug/I 4 625.1 L/2/10 ug/I l0 ML
MDL
1,3-dichlorobenzene <10 ug/I <10 ug/I 4 625.1 L/2/10 ug/I CI ML
0 MDL
1,4-dichlorobenzene <10 ug/I <10 ug/I 4 625.1 L/2/10 ug/I 0 ML
❑MDL
3,3-dichlorobenzidine <10 ug/I <10 ug/I 4 625.1 3.1/10 ug/I 0 ML
❑MDL
Diethyl phthalate <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I O ML
❑MDL
Dimethyl phthalate <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I l0 ML
MDL
2,4-dinitrotoluene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I l0 ML
_ ❑MDL
0 ML
2,6-dinitrotoluene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 MDL
EPA Form 3510-2A(Revised 3-19) Page 20

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP 001 OMB No.2040-0004
TABLE C. EFFLUENT PARAMETERS FOR SELECTED POTWS
Maximum Daily Discharge Average Daily Discharge Analytical ML or MDL
Pollutant Number of Method1 (include units)
Value Units Value Units Samples
1,2-diphenylhydrazine <5 ug/I <5 ug/I 2 625.1 1.6/5 ug/I 0 ML
❑MDL _
Fluoranthene <5 ug/1 <5 ug/I 4 625.1 /4.5/5 ug/I O ML
❑MDL
0 ML
Fluorene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 MDL
2 ML
Hexachlorobenzene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 MDL
2 ML
Hexachlorobutadiene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 MDL
Hexachlorocyclo-pentadiene <10 ug/I <10 ug/I 4 625.1 3.1/10 ug/I 0 MDL
Hexachloroethane <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I CI ML
0 MDL
Indeno(1,2,3-cd)pyrene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I O ML
0 MDL
Isophorone <10 ug/I <10 ug/I 4 625.1 3.1/10 ug/I 0 ML
❑MDL
Naphthalene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 ML
0 MDL
Nitrobenzene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I El ML
O MDL
N-nitrosodi-n-propylamine <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I O ML
CI MDL
N-nitrosodimethylamine <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 ML
_ coon
EHML
N-nitrosodiphenylamine <10 ug/I <10 ug/I 4 625.1 3.1/10 ug/I ❑MDL
Phenanthrene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I ML
_ 0 MDL Pyrene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I ML
0 MDL
1,2,4-trichlorobenzene <5 ug/I <5 ug/I 4 625.1 /4.5/5 ug/I 0 ML
0 MDL
1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or
required under 40 CFR Chapter I,Subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2A(Revised 3-19) Page 21

This page intentionally left blank.

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
TABLE D.ADDITIONAL POLLUTANTS AS REQUIRED BY NPDES PERMITTING AUTHORITY
Maximum Daily Discharge Average Daily Dischar e
Pollutant Analytical ML or MDL
(list) Value Units Value Units Number of Method1 (include units)
Samples
ElNo additional sampling is required by NPDES permitting authority.
❑ML
❑MDL
❑ML
❑MDL
0 ML
❑MDL
❑ML
0 MDL
0 ML
❑MDL
❑ML
❑MDL
❑ML
❑MDL
❑ML
❑MDL
0 ML
❑MDL
❑ML
0 MDL
❑ML
❑MDL
❑ML
❑MDL
❑ML
0 MDL
❑ML
❑MDL
❑ML
❑MDL
❑ML
❑MDL
❑ML
❑MDL
1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required
under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3).
EPA Form 3510-2A(Revised 3-19) Page 23

This page intentionally left blank.

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP 001 OMB No.2040-0004
TABLE E. EFFLUENT MONITORING FOR WHOLE EFFLUENT TOXICITY
The table provides response space for one whole effluent toxicity sample.Copy the table to report additional test results.
Test Information
Test Number 1 Test Number 2 Test Number 3
Test species Pimephales promelas Pimephales promelas Pimephales promelas
Age at initiation of test In-house culture,<24-hr In-house culture,<24-hr In-house culture,<24-hr
Outfall number o01 o01 001
Date sample collected 03/01/2021 09/12/2022 03/04/2024
Date test started 03/02/2021 09/13/2022 03/05/2024
Duration 7 days(terminated 3/9/21) 7 days(terminated 9/20/22) 7 days(terminated 3/12/24)
Toxicity Test Methods
Test method number EPA 1000.0 EPA 1000.0 EPA 1000.0
Manual title EPA-821-R-02-013 EPA-821-R-02-013 EPA-821-R-02-013
Edition number and year of publication 4th edition,October 2002 4th edition,October 2002 4th edition,October 2002
Page number(s)
Sample Type
Check one: ❑ Grab ❑ Grab ❑ Grab
❑r 24-hour composite Cl 24-hour composite CI 24-hour composite
Sample Location
Check one: ❑ Before Disinfection ❑ Before Disinfection ❑ Before disinfection
❑After Disinfection ❑After Disinfection ❑After disinfection
r❑ After Dechlorination ❑✓ After Dechlorination CI After dechlorination
Point In Treatment Process
Describe the point in the treatment process Final effluent Final effluent Final effluent
at which the sample was collected for each
test.
Toxicity Type
Indicate for each test whether the test was ❑Acute ❑Acute ❑Acute
performed to asses acute or chronic toxicity,
or both.(Check one response.) ❑`' Chronic ❑:' Chronic ❑r Chronic
❑ Both ❑ Both ❑ Both
EPA Form 3510-2A(Revised 3-19) Page 25

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP 001 OMB No.2040-0004
TABLE E. EFFLUENT MONITORING FOR WHOLE EFFLUENT TOXICITY
The table provides response space for one whole effluent toxicity sample.Copy the table to report additional test results.
Test Number 1 Test Number 2 Test Number 3
Test Type
Indicate the type of test performed.(Check one ❑ Static ❑ Static 0 Static
response.)
❑r Static-renewal [ Static-renewal ❑r Static-renewal
❑ Flow-through ❑ Flow-through ❑ Flow-through
Source of Dilution Water
Indicate the source of dilution water.(Check ❑✓ Laboratory water 0 Laboratory water ❑r Laboratory water
one response.)
❑ Receiving water _ ❑ Receiving water ElReceiving water
If laboratory water,specify type. moderately hard synthetic water moderately hard synthetic water moderately hard synthetic water
If receiving water,specify source. NA NA NA
Type of Dilution Water
Indicate the type of dilution water.If salt El Fresh water 0 Fresh water ✓❑ Fresh water
water,specify"natural'or type of artificial
sea salts or brine used. ❑ Salt water(specify) ElSalt water(specify) ❑ Salt water(specify)
Percentage Effluent Used
Specify the percentage effluent used for all 45%,67.5%,90%,95%,100% 45%,67.5%,90%,95%,100% 45%,67.5%,90%,95%,100%
concentrations in the test series.
Control(0%effluent/100%dilution water) Control(0%effluent/100%dilution water) Control(0%effluent/100%dilution water)
NA NA NA
Parameters Tested
Check the parameters tested. ®pH ❑ Ammonia ® pH ❑ Ammonia ® pH ❑ Ammonia
❑ Salinity ® Dissolved oxygen ❑ Salinity 0 Dissolved oxygen ❑ Salinity ® Dissolved oxygen
® Temperature ® Temperature ® Temperature
Acute Test Results
Percent survival in 100%effluent NA % NA % NA %
LCso NA NA NA
95%confidence interval NA % NA % NA
Control percent survival NA % NA % NA
EPA Form 3510-2A(Revised 3-19) Page 26

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP 001 OMB No.2040-0004
TABLE E. EFFLUENT MONITORING FOR WHOLE EFFLUENT TOXICITY
The table provides response space for one whole effluent toxicity sample.Copy the table to report additional test results.
Test Number 1 Test Number 2 Test Number 3
Acute Test Results Continued
Other(describe) NA NA NA
Chronic Test Results
NOEC 100 % 100 % 100 %
IC25 >100 % >100 % >100 %
Control percent survival 100 % 100 % 100 %
Other(describe) NA NA NA
Quality ControUQuality Assurance
Is reference toxicant data available? El Yes 0 No 0 Yes 0 No 0 Yes 0 No
Was reference toxicant test within
acceptable bounds? 0 Yes 0 No 0 Yes ❑ No 0 Yes ❑ No
What date was reference toxicant test run 03/02/2021 09/13/2022 03/05/2024
(MM/DD/YYYY)?
Other(describe) 3-day sample collection 3-day sample collection 3-day sample collection
EPA Form 3510-2A(Revised 3-19) Page 27

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP 001 0M8 No.2040-0004
TABLE E.EFFLUENT MONITORING FOR WHOLE EFFLUENT TOXICITY
The table provides response space for one whole effluent toxicity sample.Copy the table to report additional test results.
Test Information
Test Number 4 Test Number Test Number
Test species To be provided September 2024
Age at initiation of test To be provided September 2024
Outfall number To be provided September 2024
Date sample collected
Date test started
Duration To be provided September 2024
Toxicity Test Methods
Test method number To be provided September 2024
Manual title To be provided September 2024
Edition number and year of publication To be provided September 2024
Page number(s) To be provided September 2024
Sample Type
Check one: ❑ Grab ❑ Grab 0 Grab
❑ 24-hour composite 0 24-hour composite ❑ 24-hour composite
Sample Location
Check one: 0 Before Disinfection 0 Before Disinfection 0 Before disinfection
O After Disinfection 0 After Disinfection ❑After disinfection
O After Dechlorination ❑ After Dechlorination ❑ After dechlorination
Point In Treatment Process
Describe the point in the treatment process To be provided September 2024
at which the sample was collected for each
test.
Toxicity Type
Indicate for each test whether the test was 0 Acute 0 Acute 0 Acute
performed to asses acute or chronic toxicity,
Or both.(Check one response.) ❑Chronic ❑ Chronic El Chronic
O Both 0 Both ❑ Both
EPA Form 3510-2A(Revised 3-19) Page 25

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP 001 OMB No.2040-0004
TABLE E. EFFLUENT MONITORING FOR WHOLE EFFLUENT TOXICITY
The table provides response space for one whole effluent toxicity sample.Copy the table to report additional test results.
Test Number 4 Test Number Test Number
Test Type
Indicate the type of test performed.(Check one ❑ Static 0 Static ❑ Static
response.)
❑Static-renewal ❑Static-renewal ❑ Static-renewal
❑ Flow-through ❑ Flow-through ❑ Flow-through
Source of Dilution Water
Indicate the source of dilution water.(Check ❑ Laboratory water 0 Laboratory water ❑ Laboratory water
one response.)
❑ Receiving water ❑ Receiving water ❑ Receiving water
If laboratory water,specify type.
If receiving water,specify source.
Type of Dilution Water
Indicate the type of dilution water.If salt ❑ Fresh water ❑ Fresh water ❑ Fresh water
water,specify"natural"or type of artificial
sea salts or brine used. ❑ Salt water(specify) ❑ Salt water(specify) ElSalt water(specify)
Percentage Effluent Used
Specify the percentage effluent used for all
To be provided September 2024
concentrations in the test series.
To be provided September 2024
To be provided September 2024
Parameters Tested
Check the parameters tested. ❑pH ❑ Ammonia ❑ pH 0 Ammonia ❑ pH 0 Ammonia
❑ Salinity ❑ Dissolved oxygen ❑ Salinity ❑ Dissolved oxygen ❑ Salinity ❑ Dissolved oxygen
❑ Temperature ❑ Temperature ❑ Temperature
Acute Test Results
Percent survival in 100%effluent
LC5o
95%confidence interval % % %
Control percent survival
EPA Form 3510-2A(Revised 3-19) Page 26

EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP 001 OMB No.2040-0004
TABLE E. EFFLUENT MONITORING FOR WHOLE EFFLUENT TOXICITY
The table provides response space for one whole effluent toxicity sample.Copy the table to report additional test results.
Test Number 4 Test Number Test Number
Acute Test Results Continued
Other(describe) To be provided September 2024
Chronic Test Results
NOEC
IC25 % %
Control percent survival
Other(describe) To be provided September 2024
Quality Control/Quality Assurance
Is reference toxicant data available? 0 Yes 0 No 0 Yes 0 No ❑ Yes 0 No
Was reference toxicant test within ❑ Yes 0 No 0 Yes ❑ No 0 Yes 0 No
acceptable bounds?
What date was reference toxicant test run
(MM/DD/YYYY)?
Other(describe) To be provided September 2024
EPA Form 3510-2A(Revised 3-19) Page 27

This page intentionally left blank.

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03105/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
TABLE F. INDUSTRIAL DISCHARGE INFORMATION
Response space is provided for three SIUs.Copy the table to report information for additional SIUs.
SIU CM-: Sam IU CM-: SIU CM-:
Name of SIU ATI Specialty Materials-Bakers South Operatic ATI Specialty Materials-Monroe ATI Specialty Materials-Bakers Operations
Mailing address(street or P.O.box) 3750 Alloy Way,PO Box 5030 2020 Ashcraft Avenue,PO Box 5030 3412 Goldmine Road,PO Box 5030
City,state,and ZIP code Monroe,NC 28111 Monroe,NC 28111 Monroe,NC 28111
Description of all industrial processes that affect Melt,forge,finishing,etching,EGIA,powder Vacuum induction melting,remelting, Metal,forge,finishing,etch,and heat
or contribute to the discharge. atomization and heat treating processes forging,rolling,finishing,etching and heat treating processes
treating processes
List the principal products and raw materials that Principal Products:Nickel.Cobalt and Principal Products:Nickel.Cobalt and Principal Products:Nickel.Cobalt and
affect or contribute to the SIU's discharge. Titanium Alloys,and specialty steels in billets, Titanium Alloys,and specialty steels in Titanium Alloys,and specialty steels in
bars and shapes billets,bars and shapes billet,bars and shapes
Raw Material:Ni,Co,Cb,Al,Ti,Cu,Fe,C,Si, Raw Material:Ni,Co,Cb,Al,Ti,Cu,Fe,C, Raw Material:Ni,Co,Cb,Al,Ti,Cu,Fe,C,
Cr,Mn,Mo,V,Zr,and Mg Si,Cr,Mn,Mo,V,Zr,and Mg SI,Cr,Mn,Mo,V,Zr,and Mg
Indicate the average daily volume of wastewater
discharged by the SIU. 31,339 gpd 69,043 gpd D gpd
How much of the average daily volume is
attributable to process flow? 22,589 gpd 44,043 gpd a gpd
How much of the average daily volume is
attributable to non-process flow? 8,750 gpd 25,000 gpd 1,625 gpd
Is the SIU subject to local limits?
❑✓ Yes 0 No ❑r Yes ❑ No ❑r Yes 0 No
Is the SIU subject to categorical standards?
El Yes ❑ No ElYes 0 No ❑r Yes ❑ No
EPA Form 3510-2A(Revised 3-19) Page 29

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
TABLE F.INDUSTRIAL DISCHARGE INFORMATION
Response space is provided for three SIUs.Copy the table to report information for additional SIUs.
SIU CM SIU CM-, SIU CM
Under what categories and subcategories is the 40 CFR 471 Subpart C 40 CFR 471 Subpart C 40 CFR 471 Subpart C
SIU subject? 40 CFR 471 Subpart F 40 CFR 471 Subpart F 40 CFR 471 Subpart F
Has the POTW experienced problems(e.g.,
upsets,pass-through interferences)in the past 4.5 ❑ Yes ElNo ❑ Yes ❑r No ❑ Yes ❑r No
years that are attributable to the SIU?
If yes,describe. NA NA NA
EPA Form 3510-2A(Revised 3-19) Page 30

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
TABLE F.INDUSTRIAL DISCHARGE INFORMATION
Response space is provided for three Sills.Copy the table to report information for additional Sills.
SIU CM' SIU CM-: SIU CM-:
Name of SIU Atrium Health-Union Boyd Corporation-Monroe Charlotte Pipe and Foundry Company,Plast
Mailing address(street or P.O.box) 600 Hospital Drive,PO Box 5003 300 Acme Drive 4210 Old Charlotte Highway,PO Box 1339
City,state,and ZIP code Monroe,NC 28111 Monroe,NC 28112 Monroe,NC 28111
Description of all industrial processes that affect Health Care Occupancy/Acute Care/Long Manufacturing decorative trim and PVC compounds for captive use,extrude
or contribute to the discharge. Term Care nameplates,printing,etching,stamping, PVC and CPVC pipe,injection molds PVC,
assembly ABS,CPVC fittings and assemblies
List the principal products and raw materials that Health Care Principal Products:Decorative trim and Principal Products:PVC and CPVC pipes;
affect or contribute to the SIU's discharge. nameplates PVC,ABS,CPVC and ABS fittings
Raw Materials:ABS compound,CPVC
resin,CPVC compound,PVC resin,PVC
compound,calcium carbonate,calcium
Indicate the average daily volume of wastewater
discharged by the SIU. 51,730 gpd 13,550 gpd 63,575 gpd
How much of the average daily volume is
attributable to process flow? 51,730 gpd 11,475 gpd 46,525 gpd
How much of the average daily volume is
attributable to non-process flow? o gpd 2,075 gpd 17,050 gpd
Is the SIU subject to local limits?
❑r Yes 0 No ❑✓ Yes 0 No ❑r Yes 0 No
Is the SIU subject to categorical standards?
❑ Yes r❑ No ❑✓ Yes 0 No 0 Yes ❑r No
EPA Form 3510-2A(Revised 3-19) Page 29

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
TABLE F.INDUSTRIAL DISCHARGE INFORMATIDN
Response space is provided for three SIUs.Copy the table to report information for additional SIUs.
SIU CM- SIU CM': SIU CM-:
Under what categories and subcategories is the NA 40 CFR 433.15 NA
SIU subject?
Has the POTW experienced problems(e.g.,
upsets,pass-through interferences)in the past 4.5 ❑ Yes El No ❑ Yes ElNo 0 Yes 9 No
years that are attributable to the SIU?
If yes,describe. NA NA NA
EPA Form 3510-2A(Revised 3-19) Page 30

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
TABLE F.INDUSTRIAL DISCHARGE INFORMATION
Response space is provided for three SIUs.Copy the table to report information for additional SIUs.
SIU cm-: SIU cM-I SIU cm-:
Name of SIU Glenmark Pharmaceuticals Inc.USA Goulston Technologies,Inc. NC Biogas LLC(facility not constructed or of
Mailing address(street or P.O.box) 4147 Goldmine Road 700 North Johnson St. 325 Acme Drive
City,state,and ZIP code Monroe,NC 28110 Monroe,NC 28110 Monroe,NC 28110
Description of all industrial processes that affect Manufacturing of injectable pharmaceutical Blending of textile lubricants used in the Produce biogas from poultry manure to
or contribute to the discharge. products. processing of natural and man-made be combusted to produce hot water and
fibers power
The facility is operating for
research/development and commercial
manufacturing of products for sale.
List the principal products and raw materials that Principal Products:Ethanol,isopropyl Principal Products:Anti-soiling finishes, Raw Materials:Poultry manure and
affect or contribute to the SIU's discharge. alcohol,methylene chloride water and spin finishes,Anti-static agents, process additives such as citric acid,
generic active pharmaceutical ingredients Lubricating agents. sulfuric,sodium hydroxide,sodium
hypochlorite,ferric chloride,and polymer.
Raw Materials:Ethoxylated esters,
alcohols and phosphates,fatty acid esters,
Indicate the average daily volume of wastewater
discharged by the SIU. 5,585 gpd 13,503 gpd o gpd
How much of the average daily volume is
attributable to process flow? 2,910 gpd 10,303 gpd o gpd
How much of the average daily volume is
attributable to non-process flow? 2,675 gpd 3,200 gpd o gpd
Is the SIU subject to local limits?
El Yes ❑ No El Yes 0 No CI Yes 0 No
Is the SIU subject to categorical standards?
0 Yes 0 No ❑ Yes El No 0 Yes El No
EPA Form 3510-2A(Revised 3-19) Page 29

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
TABLE F.INDUSTRIAL DISCHARGE INFORMATION
Response space is provided for three SIUs.Copy the table to report information for additional SIUs.
SIU CM SIU CM-1 SIU CM-.
Under what categories and subcategories is the 40 CFR 439.47 Subpart D NA NA
SIU subject?
Has the POTW experienced problems(e.g.,
upsets,pass-through interferences)in the past 4.5 D Yes ❑r No ❑ Yes 0 No ❑ Yes ❑r No
years that are attributable to the SIU?
If yes,describe. NA NA NA
EPA Form 3510-2A(Revised 3-19) Page 30

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
TABLE F.INDUSTRIAL DISCHARGE INFORMATION
Response space is provided for three SIUs.Copy the table to report information for additional SIUs.
SIU CM-; SIU CM SIU CM-:
Name of SIU Norton Door Controls ORO Manufacturing Co. Pilgrim's Pride Corporation
Mailing address(street or P.O.box) 3000 Highway 74 East 5000 Stitt Street 5901 West Marshville Blvd
City,state,and ZIP code Monroe,NC 28112 Monroe,NC 28110 Marshville,NC 28103
Description of all industrial processes that affect Machining steel,brass,aluminum and cast Manufacture,fabrication and finishing Chicken slaughter and processing,
or contribute to the discharge. iron,buffing,vibratory de-burring,parts metal products and assembly sanitation
washing,water-base painting,powder
coating
List the principal products and raw materials that Principal Products:Mechanical-hydraulic Principal Products:Military type troop Principal Products:Raw chicken products
affect or contribute to the SIU's discharge. door closures,electronic door operators,and seats and various sheet and tubular metal cut up,deboned,and ice pack
door suspension pivots products
Raw Materials:Live Chickens
Raw Material:Aluminum and iron castings, Raw Material:Steel and aluminum sheet,
steel,hydraulic oil,water based paint, rod,bar and tube
Indicate the average daily volume of wastewater
discharged by the SIU. 5,657 gpd 1,119 gpd 668,051 gpd
How much of the average daily volume is
attributable to process flow? 307 gpd 344 gpd 648,051 gpd
How much of the average daily volume is
attributable to non-process flow? 5,350 gpd 775 gpd 20,000 gpd
Is the SIU subject to local limits?
✓❑ Yes 0 No ❑r Yes 0 No ❑✓ Yes 0 No
Is the SIU subject to categorical standards?
0 Yes 0 No ❑✓ Yes 0 No 0 Yes CI No
EPA Form 3510-2A(Revised 3-19) Page 29

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
TABLE F. INDUSTRIAL DISCHARGE INFORMATION
Response space is provided for three SIUs.Copy the table to report information for additional SIUs.
SIU cm-. SIU CM-. SIU cM-:
Under what categories and subcategories is the 40 CFR 433 NA NA
SIU subject?
Has the POTW experienced problems(e.g.,
upsets,pass-through interferences)in the past 4.5 El Yes El No ❑ Yes El No ❑ Yes 2 No
years that are attributable to the SIU?
If yes,describe. NA NA NA
EPA Form 3510-2A(Revised 3-19) Page 30

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
TABLE F. INDUSTRIAL DISCHARGE INFORMATION
Response space is provided for three SIUs.Copy the table to report information for additional SIUs.
SIU CM- siu..! .A siu NA
Name of SIU Tyson Farms,Inc. NA NA
Mailing address(street or P.O.box) 233 South Secrest Avenue
City,state,and ZIP code
Monroe,NC 28111
Description of all industrial processes that affect Chicken slaughter and processing.Involves
or contribute to the discharge. cut up,debone,packaging,hatching of
chicks,and processing chicken feed.
List the principal products and raw materials that Principal Products:Poultry Products
affect or contribute to the SIU's discharge.
Raw Material:Live Chickens,marination
Indicate the average daily volume of wastewater
discharged by the SIU. 1,730,794 gpd gpd gpd
How much of the average daily volume is
attributable to process flow? 1,705,469 gpd gpd gpd
How much of the average daily volume is
attributable to non-process flow? 25,325 gpd gpd gpd
Is the SIU subject to local limits?
0 Yes ❑ No 0 Yes ❑ No ❑ Yes 0 No
Is the SIU subject to categorical standards?
❑ Yes El No 0 Yes 0 No 0 Yes 0 No
EPA Form 3510-2A(Revised 3-19) Page 29

EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19
110000554873 NC0024333 City of Monroe WWTP OMB No.2040-0004
TABLE F. INDUSTRIAL DISCHARGE INFORMATION
Response space is provided for three SIUs.Copy the table to report information for additional SIUs.
SIU CM- SIU SIU
Under what categories and subcategories is the NA
SIU subject?
Has the POTW experienced problems(e.g.,
upsets,pass-through interferences)in the past 4.5 ❑ Yes ❑r No ❑ Yes ❑ No 0 Yes ❑ No
years that are attributable to the SIU?
If yes,describe.
EPA Form 3510-2A(Revised 3-19) Page 30

Tab B

U 583ft 0 5ft 3
do
,4(7
_ .
#14111 .11 Cb
47,- .ir
0 ,,_ I ...,_
—Per e9;*$
.faaditi
o,
111,40:itN414.44104 o 4 '4Ri014 1 0 0 ' ' ....,4 4\
' Ciir-7K * •i '.
Amor
---------, gpk4 TrAkinimp:- lip
),
1 or
ti 111W ' k Rib.
n c
1 , o
.1,1 0 0 01#4 11 1 \
1 \ Alli r-. op) A ki A..,
`N. a ' !IT 4W
0 .
4' _ /1 .--1 41Fil %
— ' i''`J r y'J Monroe WWTP Parcel
- t , il/Qe,
,,
�. , t
1116 till
St-- ,-- -��/ t 4," V T W EIm St
, , i
__
, i
o �
1 0
illtlig
F !. LJTh
---7.2pr- -
''
� p ��
r) ( D • �� res;on-R�
0v.
• --- r-
-- ,
c,
'` . ,
���/Kn, I vim. . N t
��`,_ .� �583 ' p(� 0 D NN....,..
M•,n • J.?
p\` Cif lS
ou Clu A�� O � .` _pair
n _ O �SJ
a : ,
Latitude: 34 59'47" Longitude: 80 29'29" • D
0
USGS Quadrangle: Wingate, NC mes. O . 3
Subbasin: 03-07-14 :
Stream Classification: 13-17-36-(5) . - Iin-Dai -R.
Receiving Stream: Richardson Creek
,•4
_ ,
NORTH 0 sn N ,NNGGA , Ey�A,, . rces:E ri, 1 'r'Sta e of North Carolina
rf<d: ROLINA •• , 1,T mTom,Gary✓ni,n,Safe.Gr.hh,�eocl chnologies, Inc,METI/NASA,
USGS,EPA-,- U5 Ce. siis Bureau,USDA,USFWS
---/X'
>o r ---
Figure 2.3: NPDES Location Map
F Monroe WWTP NPDES Modification Application
NPDES Permit: NC0024333
City of Monroe, North Carolina
0 0.10.2 0.4 0.6 0.8 Hazen
NEEm Miles Monroe

— __
c,
, , - ._.,47,--- ---.. r„—
,,
s.
i„,„
y
/ EXIS i1NG PIONROE I TFALI �Trr9t ,/
_,,---_ _____...-,-,
---- �_��, t //
FI OW FOUALIZAPON BASIN �� 4O a�
NOT IN/lEW I / �\ 41". ---�
n r. glit,�iY� —q�4' • ,::AI<F sTr1RA(rF AREA - � ✓ / \\ ' ,�r 0
��; � ap� ► � �.��� s:: t'ICFsrt,Rs asw �. A
1I
AP1'[,Lnall,La NO J - �s s� ��
_ 1
i • /SECl7NUARY CL RIFIFR NO , -- �l • . )���
I c 011iE$TER 4�♦� �` + \\
���el ��,vw iv. ' v� '��.�_ I(1(
\ UIC E$TER, , ',, \\ `_ \\
! , \, Eli 04H, � �
ass � 1 I �_r,� � - � � \ ♦ _
Alii
� C(7NTAC1- AERA TIt�N \` ��`\ ` \L.-.� ,� r--
IS
,Ii ., s ,lisitv.TAN BASIN NO AERATION BASIN Nt) I r --� �_ "� -
c lr'
-, \IIIIS,FFF t FN F Ai
r
11% c.RFFNINC Bu i n1N i ' 1 7:4140p
f ,,,
t .....gitiw„, _ mi.6...„ .40:-:------_T-- ,...------_-----_-_,,,,-,---------___ __... - )
-\ ,c ---r\ -/ - mil ,_
r--I5 ------:----. ---- ----5----7--7,it....„....m.H--- -r----\
(c---
\ ' , 10; 411-'7" 7.---` k..
)_/,,,,
,,,,/ 4/„-yr,01_
, ,,,, . ,,- 7/„/"---- ---
Du:iv'fi 4I
I; ,
;,,,-:R ,,)‘ ''
\ \'',, ''''','-'\ T,), \ ,-,''''f-':,\- ----_____v-- ' #
---- 'tlkt4 (--*C-7----///-4*4
.. / ' 7,---; ,y--- / e
_z /,
/, ,,-
,./,/
(`V.. .� ) �`,y, \ .. `-- .S� �-,. 1 I Ij�lll�il1I,/
'I,,,,/ �o,/
\ _\ I „1
l�l
::: ;751
: ,„
_, , /,
,___„,,_,
— /
\ .11i1,,, 1
i ROf ,\,.„\..--,---- ''
c ik
1 I ERT�i.E 0 , /,,, ,,_. ,
\\ a(1,
/I i , j��%
\ ,, _ ,.._
, _ / )Ii :i%' ------,_,.--__,--- -__---=-
S ifi lhi;,))11, lor
/a), Itt" ,
__ I .... i L % --- )
_ �+ ��Lt` �1;41
) I
;(--- , CITY OF MONROE
{�j�� �/��'*��, �ii4it��tyi�� il _� toe NORTH CAROLINA
///ll/ / I l�ri�) /Xb 'rl\T`t -�_i. I 3 � MONROE WWTP: EXISTING 10.4 MGD SITE PLAN

_ ._._ i
,r__,__
_, .
.,y , , _,_ ,
s r -_,
_�}c j EXISTING MONR EOUTFACE`. AR`�r `/ ~-77 ��\
�` �� - / _45,5 REF /��— --: - '.. . .� •FLOW EQUALIZATION BASIN % ��---�— ` `
INOTIN VIEW) a' I 1 >� C w aB5 4u0 h -_ : ___ �� -5- V �.� ._a �
,- 46,5 n i/do�, A,P- -�� G ems* S �®
ELEC BUILDING BELT FILTER PRESS
G %' to 05 �1.� i / �� , �rcr 4'' w F PROPOSED
a�D ;65 )� _��I .h^ir-ARFa ��� ��1 n v� ?s ADDITIONAL
,/ / � .: ,�q0 "��" = �� �^ / �` s�. ' 1 DI 1ES IL:R` Ik, \ ,,8 < "> \\'` OUTFACE
,i'. SECONDARY CLARIFIER NO.1 r WA 1♦%- ar- __ ��� � E jf ��-,,
`I
5 _ t 1\'�' = D!^rS TER 4 ♦ ICI DICES fER, , \\
J d „ /� J 0,V _ � .5�� DICES IER _
�n Leh . ♦� ( DlnesTFR.! s � Ob ) ��
a: coNlAcr � �'� NPW PS
�� ' lit
TAN AERA r10N ��� ��\� � ne � � —
ri
BnsIN Nos AERATION BASIN No (., \� \ I` =� -- CASCADE AERATOR
sQ5 ��� ���BaswN �� k_44111N.s. � EQ CONTROL VAULT �; ..1.
�r �- _ O����,,,�� ■ ���� �� ..____1/ UV FACILITY
,� :, ) FLtwEouALlznrloNBAsr l ELEC BUILDING �,� '
. ) •
SEONDARY'CLARIFIER NQ 2 1 /' .-;�" /,kv/ ,'/
/- �� SECONDARY CL41LE R NO 1• i a �� �- 011(. VA : '
ij / \ \ DING _ ♦ ,� \ BLOWER BUILDING =- �` ��� / FILTERS !� i----:, (---- _.., , f----. .„::::::::.__ --__--- 11P4Pare,,,,.Age_ i _.--- -----__ •---.7.-,--.------------.-----2---,....._-.7---..,-------..,..... .
g20.�� �� —SCREENING BUILDING - 1f f ��— 5'5— : r m y�=-
:/ -
c'\,,_,t • .5-n o ♦.i�,1. < 1 , <3,h4
y
? (rri.-1-,,, 1 •�VI 1 '� !-/
� \;_ �1 // ice
/ >\..)., '..,"
7 SCREENING `fsA �, / lig ig FLOW CONTROL STRUCTURE =,�`� ' ) ''.f A70/ // //�"FACILITY f j: ALKALINITY' O �� RAS PS /� "/
7
l� I. �j,, ,�'l iiiv i 7%(� fit-- �(1, '�� ��
ELEC BUILDING ..... a«1.1 ��
GENERATORiirl ERIAIII / 0�i,j,1( "/1,�, ��
\ ' CLARIFIER ` �,i;l i ((;)(2,\,_� � l - �.. a Ir7r-- � d �1,,%„ I(l;rlir
� ,,,,,
( 11r(p'1 .1 - ELEC BUILDING �, �,,,
Zir �� 111 Q �� WAS PS % ��\��
r % y .k..1 r1---(: iir � ��� ----- INITIAL BLOWERS /.%
���f„;.-...; . *\N,.‘-, , it _ PER I 1��� 11�II1 -- .! - ��9
i, V
1 r 1 / \_,:.___
__?' \ :1 C --- 4111 /it' / ,,,-----
-I i'), k,\ ) \
. , ‘-. ----- ,--.7,---:1 /
It------ 1
�' \ —_ / ..-:, T.%
//)) ) ))).--j
Ili (s\
� �,;, \\�(rye �l �} � % �l', i I-,,;,,- 13.4 MGD EXPANSION
CITY OF MONROE
' LI ������r)�� � 10-5--7:-/
NORTH CAROLINA
li� ///K�i � �� MONROE WWTP: 13.4 MGD SITE PLAN

Tab C

City of Monroe
Monroe Wastewater Treatment Plant
NPDES Permit No. NC0024333
Residuals Management Plan
The Monroe Wastewater Treatment Plant(WWTP) is currently rated at 10.4 mgd. This Major Modification
Application Package requests new tiered effluent flow limits for expansion to 13.4 mgd and 15.4 mgd.
The current solids handling processes at the Monroe WWTP include sludge thickening, aerobic digestion,
dewatering, and cake storage prior to hauling and land application by a third-party contractor on permitted
agricultural farmland. An expansion will require an increase in capacity to treat the additional solids that
will be generated. The City will continue to use sludge thickening and aerobic digestion, coupled with
sludge dewatering, for biosolids management. Digested solids meet Class B requirements.
Two rotary drum screens are utilized for preliminary treatment of influent wastewater. Dewatered
screenings are hauled to a landfill, and this form of residual management of influent screenings will
continue through the subsequent expansion phases to 13.4 and 15.4 mgd respectively.
Sludge Thickening
Five aerobic digesters are used in series for thickening, stabilization, and storage of waste activated
sludge (WAS). WAS is removed from the biological process at a single waste point from the combined
return activated sludge (RAS) manifold. WAS is conveyed to the solids handling and treatment area
through a 12-inch force main. WAS is initially stored in Digesters 3 and 4, each with a volume of
0.25 million gallons (MG).
The expansion to 13.4 mgd will include an additional connection to Digesters 3 and 4 to convey WAS
from the proposed treatment train. Digesters 3 and 4 thicken and aerate the WAS to approximately 3%
solids. This connection will also provide adequate capacity for the 15.4 mgd expansion.
Sludge Digestion
Thickened WAS (TWAS) is then sent to Digester 2, with a volume of 1.15 MG, where it is constantly
mixed and aerated by surface mechanical aerators. The solids are then pumped into Digester 1
(0.49 MG), where aeration by surface mechanical aerators continues, and then to Digester 5 (3.0 MG).
Digester 5 is equipped with positive displacement blowers for mixing and aeration via fine bubble
membrane diffusers. Solids are held and aerated until volatile solids reduction (VSR) is achieved. Lime
may be added to Digesters 1 and 2 to meet the EPA Part 503 Biosolids Rule when VSR cannot be
achieved through aerobic digestion.
Projected digested sludge production is 109,500 gal/day and 124,600 gal/day (thickened to 3%)for
expansions to 13.4 mgd and 15.4 mgd respectively. The combined volume of the existing aerobic
digesters (5.1 MG)will provide 46.9 days of retention time at 13.4 mgd and 38.7 days of retention time at
15.4 mgd. An additional
g a 2.5 MG digester will be included in the 15.4 mgd expansion.
9 g pa slon. The 30-days of
digestion will meet Class B Pathogen Reduction Requirements per EPA Regulations. If the 38% volatile
solids reduction requirement cannot be met, vector attraction reduction may be achieved by adding lime
to the digested sludge to raise the pH to 12 for 2 hours and then maintain the pH above 11.5 for an
Monroe WWTP Residuals Management Plan Page 1 of 2

City of Monroe
Monroe Wastewater Treatment Plant
NPDES Permit No. NC0024333
additional 22 hours.
Sludge Dewaterinq and Land Application
Digested solids can be hauled and land applied as a liquid, or dewatered to cake solids for Class B land
application on agricultural farmland.
For dewatering, digested solids are pumped to one 2.0-meter belt filter press (BFP). The BFP provides
dewatered cake solids of approximately 18% to reduce the volume of material to be hauled and land
applied. The expansion to 13.4 mgd will not include improvements to dewatering. The expansion to
15.4 mgd will include installation of a second BFP to increase the WWTP's dewatering capacity and
provide equipment redundancy.
The existing uncovered sludge drying beds are currently used to store dewatered sludge cake during
times of inclement weather when solids cannot be land applied. The approximate available sludge drying
bed area is 19,200 square feet, which provides approximately 20 days of cake storage for the existing
WWTP sludge production. To increase the stack depth and prevent rainwater from collecting in the drying
beds, the 15.4 mgd expansion project will include a canopy to cover the drying beds.
Monroe WWTP Residuals Management Plan Page 2 of 2

Tab D

Summary of Monroe Wastewater Treatment Plant First Species Toxicity Testing 2021-2024
90%Dilution-Chronic
Toxicity Test Start Date Contract Lab Organism Mortality Location Compliance/Noncomp. Time period pH DO Sample Component Cond C12
Start Finish Start Finish
Environmental Test Start 7.54 7.98 8.10 8.10 Dilution NA NA
Ceriodaphnia
Wednesday,June 9,2021 Testing Solutions, dubia 0% EFF Compliance 1st Renewal 7.40 8.13 8.00 8.10 1st Sample 941 <0.1
Inc. 2nd Renewal 7.96 7.97 7.90 8.20 2nd Sample 922 <0.1
Environmental Test Start 7.34 7.63 8.00 8.00 Dilution NA NA
Ceriodaphnia
Wednesday,September 22,2021 Testing Solutions, dubia 0% EFF Compliance 1st Renewal 7.15 7.76 8.20 8.30 1st Sample 1030 <0.1
Inc. 2nd Renewal 7.71 7.71 8.10 7.90 2nd Sample 985 <0.1
Environmental Test Start 7.08 7.75 8.20 7.80 Dilution NA NA
Wednesday,December 15,2021 Testing Solutions, Ceriodaphnia 0% EFF Compliance 1st Renewal 7.19 7.75 8.10 8.10 1st Sample 921 <0.1
dubia
Inc. 2nd Renewal 7.64 7.77 7.90 8.20 2nd Sample 1110 <0.1
Environmental Test Start 7.33 7.77 8.10 8.00 Dilution NA NA
Ceriodaphnia
Wednesday,March 9,2022 Testing Solutions, 0% EFF Compliance 1st Renewal 6.98 7.70 8.40 7.90 1st Sample 885 <0.1
dubia
Inc. 2nd Renewal 7.63 7.50 7.70 7.90 2nd Sample 571 <0.1
Environmental Test Start 7.26 7.58 7.70 8.00 Dilution NA NA
Wednesday,June 15,2022 Testing Solutions, Ceriodaphnia 0% EFF Compliance 1st Renewal 7.04 7.68 8.00 8.10 1st Sample 857 <0.1
dubia
Inc. 2nd Renewal 7.54 7.57 7.90 7.90 2nd Sample 1070 <0.1
Environmental Test Start 6.62 7.21 8.20 7.80 Dilution NA NA
Ceriodaphnia
Wednesday,September 14,2022 Testing Solutions, 0% EFF Compliance 1st Renewal 6.66 7.52 8.00 8.00 1st Sample 763 <0.1
dubia
Inc. 2nd Renewal 7.21 7.35 8.00 8.00 2nd Sample 967 <0.1
Environmental Test Start 6.72 7.42 7.90 7.50 Dilution NA NA
Wednesday,December 14,2022 Testing Solutions, Ceriodaphnia 0% EFF Compliance 1st Renewal 6.53 7.54 8.00 8.10 1st Sample 848 <0.1
dubia
Inc. 2nd Renewal 7.47 7.48 7.90 8.00 2nd Sample 930 <0.1
Environmental Test Start 7.21 7.77 7.70 7.80 Dilution NA NA
Ceriodaphnia
Wednesday,March 15,2023 Testing Solutions, 0% EFF Compliance 1st Renewal 6.90 7.76 8.00 8.00 1st Sample 661 <0.1
dubia
Inc. 2nd Renewal 7.57 7.75 8.00 8.10 2nd Sample 878 <0.1
Environmental Ceriodaphnia Test Start 7.26 7.46 7.90 7.90 Dilution NA NA
Wednesday,June 14,2023 Testing Solutions, 0% EFF Compliance 1st Renewal 6.76 7.46 7.80 8.00 1st Sample 635 <0.1
dubia
Inc. 2nd Renewal 7.39 7.38 8.00 7.60 2nd Sample 880 <0.1
Environmental Test Start 7.14 7.49 7.70 7.90 Dilution NA NA
Ceriodaphnia
Wednesday,September 13,2023 Testing Solutions, 0% EFF Compliance 1st Renewal 6.84 7.33 7.70 8.00 1st Sample 520 <0.1
dubia
Inc. 2nd Renewal 7.31 7.35 7.80 8.00 2nd Sample 804 <0.1
Environmental Test Start 6.94 7.30 7.70 7.60 Dilution NA NA
Ceriodaphnia
Wednesday,December 6,2023 Testing Solutions, 0% EFF Compliance 1st Renewal 6.77 7.30 8.00 8.10 1st Sample 786 <0.1
dubia
Inc. 2nd Renewal 7.25 7.33 8.00 7.70 2nd Sample 944 <0.1
Environmental Test Start 6.92 7.39 8.00 7.80 Dilution NA NA
Wednesday,March 6,2024 Testing Solutions, Ceriodaphnia 0% EFF Compliance 1st Renewal 6.88 7.52 8.00 8.10 1st Sample 475 <0.1
dubia
Inc 2nd Renewal 7.39 7.33 8.10 7.90 2nd Sample 526 <0.1

Tab E

eAn aIicaI ® 1
Report of Analysis
City of Monroe
PO Box 69
Monroe, NC 28111
Attention: Kevin Keesler
Project Name: EFF PPA
Lot Number:WC03110
Date Completed:03/16/2021
Revision Date: 03/18/2021
03/19/2021 1:13 PM
Approved and released by:
Project Manager I: Hannah K. Lucas
A/ ,►
,-....... _ AM 1
ANSI National Accredilallon Board
,' ACCREDITED
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety,without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel: [phone] Fax: [phone] www.pacelabs.com

PACE ANALYTICAL SERVICES, LLC
SC DHEC No:32010001 NELAC No:E87653 NC DENR No:329 NC Field Parameters No:5639
Case Narrative
City of Monroe
Lot Number: WC03110
This Report of Analysis contains the analytical result(s)for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TN I) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
If you have any questions regarding this report please contact the Pace Project Manager listed on the
cover page.
This report supersedes and replaces any prior reports issued under this lot number. Sample -004 was
analyzed neat for volatiles.
Volatiles
Sample-004 was diluted 10X due to the laborartory error; however, all results were ND. The sample was
re-analyzed neat outside of the 14-day holding time. Both sets of data are included.
Pace Analytical Services,LLC(formerly Shealy Environmetal Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172(803)791-9700 Fax[phone] www.pacelabs.com
cc

PACE ANALYTICAL SERVICES, LLC
Sample Summary
City of Monroe
Lot Number: WC03110
Sample Number Sample ID Matrix Date Sampled Date Received
001 EFF PPA Aqueous 03/02/2021 1008 03/03/2021
002 EFF PPA Aqueous 03/02/2021 0916 03/03/2021
003 EFF PPA Aqueous 03/02/2021 0917 03/03/2021
004 EFF PPA Aqueous 03/02/2021 0920 03/03/2021
005 EFF PPA Aqueous 03/02/2021 0919 03/03/2021
006 PPA EFF Aqueous 03/02/2021 0925 03/03/2021
007 PPA EFF Dup Aqueous 03/02/2021 0927 03/03/2021
008 Field Blank Aqueous 03/02/2021 0923 03/03/2021
(8 samples)
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

PACE ANALYTICAL SERVICES, LLC
Detection Summary
City of Monroe
Lot Number: WC03110
ample Sample ID Matrix Parameter Method Result Q Units Page
001 EFF PPA Aqueous Ammonia-N (gas 350.1 0.77 mg/L 6
001 EFF PPA Aqueous Hardness(total) SM 2340C- 130 mg/L 6
001 EFF PPA Aqueous Nitrate-Nitrite-N 353.2 13 mg/L 6
001 EFF PPA Aqueous Phosphorus 365.1 1.7 mg/L 6
001 EFF PPA Aqueous TDS SM 2540C- 340 mg/L 6
001 EFF PPA Aqueous Copper 200.8 3.9 ug/L 6
001 EFF PPA Aqueous Nickel 200.8 4.6 ug/L 6
001 EFF PPA Aqueous Zinc 200.8 49 ug/L 6
002 EFF PPA Aqueous HEM (oil and grease) 1664B 6.5 mg/L 7
004 EFF PPA Aqueous Bromodichloromethane 624.1 3.0 H ug/L 10
004 EFF PPA Aqueous Chloroform 624.1 2.5 H ug/L 10
004 EFF PPA Aqueous Dibromochloromethane 624.1 2.0 H ug/L 10
(12 detections)
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......A ..c GC

Description:EFF PPA Matrix:Aqueous
Date Sampled:03/02/2021 1008
Date Received:03/03/2021
Inorganic non-metals
---- Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
350.1 (Ammonia-N )350.1 1 03/08/2021 1426 KFE 84977
1 (Hardness(to)SM 2340C-2011 1 03/09/2021 1751 AAB 85287
1 (Nitrate-Nitr)353.2 15 03/11/2021 2116 AAB 85602
1 (Phosphorus)365.1 1 03/11/2021 1331 DMA 85402
1 (TDS)SM 2540C-2011 1 03/04/2021 1108 MSG 84661
1 351.4 (TKN)351.2 1 03/05/2021 1110 DMA 03/04/2021 1748 84715
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Ammonia-N (gas diffusion) 350.1 0.77 0.10 mg/L 1
Hardness(total) SM 2340C-2011 130 10 mg/L 1
Nitrate-Nitrite-N 353.2 13 0.30 mg/L 1
Phosphorus 7723-14-0 365.1 1.7 0.050 mg/L 1
TDS SM 2540C-2011 340 25 mg/L 1
TKN 351.2 ND 0.25 mg/L 1
ICP-MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 200.2 200.8 1 03/05/2021 2049 BNW 03/05/2021 0304 84622
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Antimony 7440-36-0 200.8 ND 5.0 ug/L 1
Arsenic 7440-38-2 200.8 ND 2.0 ug/L 1
Beryllium 7440-41-7 200.8 ND 1.0 ug/L 1
^--'mium 7440-43-9 200.8 ND 0.50 ug/L 1
mium 7440-47-3 200.8 ND 5.0 ug/L 1
Copper 7440-50-8 200.8 3.9 2.0 ug/L 1
Lead 7439-92-1 200.8 ND 2.0 ug/L 1
Nickel 7440-02-0 200.8 4.6 2.0 ug/L 1
Selenium 7782-49-2 200.8 ND 5.0 ug/L 1
Silver 7440-22-4 200.8 ND 1.0 ug/L 1
Thallium 7440-28-0 200.8 ND 2.0 ug/L 1
Zinc 7440-66-6 200.8 49 10 ug/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
F nalytical Services,LLC (formerly Shealy Environmental Services,Inc.)
ntage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Description:EFF PPA Matrix:Aqueous
Date Sampled:03/02/2021 0916
Date Received:03/03/2021
Inorganic non-metals
— Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
(HEM (oil and)1664B 1 03/10/2021 1938 SMA 85328
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
HEM(oil and grease) 1664B 6.5 5.0 mg/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
F talytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1 itage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
-C GG

Description:EFF PPA Matrix:Aqueous
Date Sampled:03/02/2021 0917
Date Received:03/03/2021
Inorganic non-metals
- Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
10-204-00-1-X (Cyanide-To)SM 4500-CN E- 1 03/08/2021 1730 KFE 03/08/2021 1515 85000
1 (Phenolics)420.4 1 03/05/2021 1255 DMA 84783
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Cyanide-Total 57-12-5 SM 4500-CN E-2 ND 0.010 mg/L 1
Phenolics 420.4 ND 0.0050 mg/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
F nalytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1__ itage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Description:EFF PPA Matrix:Aqueous
Date Sampled:03/02/2021 0920
Date Received:03/03/2021
Volatile Organic Compounds by GC/MS
Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
624.1 624.1 10 03/04/20210107 DJG 84612
2 624.1 624.1 1 03/17/20212308 DJG 86052
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Acrolein 107-02-8 624.1 ND 50 ug/L 1
Acrylonitrile 107-13-1 624.1 ND 50 ug/L 1
Benzene 71-43-2 624.1 ND 10 ug/L 1
Bromodichloromethane 75-27-4 624.1 ND 10 ug/L 1
Bromoform 75-25-2 624.1 ND 10 ug/L 1
Bromomethane(Methyl bromide) 74-83-9 624.1 ND 20 ug/L 1
' Carbon tetrachloride 56-23-5 624.1 ND 10 ug/L 1
Chlorobenzene 108-90-7 624.1 ND 10 ug/L 1
Chloroethane 75-00-3 624.1 ND 20 ug/L 1
2-Chloroethylvinylether 110-75-8 624.1 ND 50 ug/L 1
Chloroform 67-66-3 624.1 ND 10 ug/L 1
Chloromethane(Methyl chloride) 74-87-3 624.1 ND 20 ug/L 1
Dibromochloromethane 124-48-1 624.1 ND 10 ug/L 1
1,2-Dichlorobenzene 95-50-1 624.1 ND 10 ug/L 1
1,3-Dichlorobenzene 541-73-1 624.1 ND 10 ug/L 1
1,4-Dichlorobenzene 106-46-7 624.1 ND 10 ug/L 1
Dichlorodifluoromethane 75-71-8 624.1 ND 20 ug/L 1
1,1-Dichloroethane 75-34-3 624.1 ND 10 ug/L 1
1,2-Dichloroethane 107-06-2 624.1 ND 10 ug/L 1
1,1-Dichloroethene 75-35-4 624.1 ND 10 ug/L 1
,-i -12-Dichloroethene 156-59-2 624.1 ND 10 ug/L 1
-1,2-Dichloroethene 156-60-5 624.1 ND 10 ug/L 1
vichloropropane 78-87-5 624.1 ND 10 ug/L 1
cis-1,3-Dichloropropene 10061-01-5 624.1 ND 10 ug/L 1
trans-1,3-Dichloropropene 10061-02-6 624.1 ND 10 ug/L 1
Ethylbenzene 100-41-4 624.1 ND 10 ug/L 1
Methylene chloride 75-09-2 624.1 ND 10 ug/L 1
1,1,2,2-Tetrachloroethane 79-34-5 624.1 ND 10 ug/L 1
Tetrachloroethene 127-18-4 624.1 ND 10 ug/L 1
Toluene 108-88-3 624.1 ND 10 ug/L 1
1,2,4-Trichlorobenzene 120-82-1 624.1 ND 10 ug/L 1
1,1,1-Trichloroethane 71-55-6 624.1 ND 10 ug/L 1
1,1,2-Trichloroethane 79-00-5 624.1 ND 10 ug/L 1
Trichloroethene 79-01-6 624.1 ND 10 ug/L 1
Trichlorofluoromethane 75-69-4 624.1 ND 10 ug/L 1
Vinyl chloride 75-01-4 624.1 ND 10 ug/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
F ialytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1__ _itage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
n..,--v,.vcc

Description:EFF PPA Matrix:Aqueous
Date Sampled:03/02/2021 0920
Date Received:03/03/2021
Run 1 Acceptance Run 2 Acceptance
Surrogate Q %Recovery Limits Q %Recovery Limits
ofluorobenzene 93 70-130 H 96 70-130
,,L,ichloroethane-d4 93 70-130 H 95 70-130
Toluene-d8 99 70-130 H 93 70-130
Volatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 624.1 624.1 10 03/04/20210107 DJG 84612
2 624.1 624.1 1 03/17/20212308 DJG 86052
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Acrolein 107-02-8 624.1 ND H 5.0 ug/L 2
Acrylonitrile 107-13-1 624.1 ND H 5.0 ug/L 2
Benzene 71-43-2 624.1 ND H 1.0 ug/L 2
Bromodichloromethane 75-27-4 624.1 3.0 H 1.0 ug/L 2
Bromoform 75-25-2 624.1 ND H 1.0 ug/L 2
Bromomethane(Methyl bromide) 74-83-9 624.1 ND H 2.0 ug/L 2
Carbon tetrachloride 56-23-5 624.1 ND H 1.0 ug/L 2
Chlorobenzene 108-90-7 624.1 ND H 1.0 ug/L 2
Chloroethane 75-00-3 624.1 ND H 2.0 ug/L 2
2-Chloroethylvinylether 110-75-8 624.1 ND H 5.0 ug/L 2
Chloroform 67-66-3 624.1 2.5 H 1.0 ug/L 2
Chloromethane(Methyl chloride) 74-87-3 624.1 ND H 2.0 ug/L 2
Dibromochloromethane 124-48-1 624.1 2.0 H 1.0 ug/L 2
1,2-Dichlorobenzene 95-50-1 624.1 ND H 1.0 ug/L 2
1,3-Dichlorobenzene 541-73-1 624.1 ND H 1.0 ug/L 2
A A ^ichlorobenzene 106-46-7 624.1 ND H 1.0 ug/L 2
Drodifluoromethane 75-71-8 624.1 ND H 2.0 ug/L 2
1,t-uichloroethane 75-34-3 624.1 ND H 1.0 ug/L 2
1,2-Dichloroethane 107-06-2 624.1 ND H 1.0 ug/L 2
1,1-Dichloroethene 75-35-4 624.1 ND H 1.0 ug/L 2
cis-1,2-Dichloroethene 156-59-2 624.1 ND H 1.0 ug/L 2
trans-1,2-Dichloroethene 156-60-5 624.1 ND H 1.0 ug/L 2
1,2-Dichloropropane 78-87-5 624.1 ND H 1.0 ug/L 2
cis-1,3-Dichloropropene 10061-01-5 624.1 ND H 1.0 ug/L 2
trans-1,3-Dichloropropene 10061-02-6 624.1 ND H 1.0 ug/L 2
Ethylbenzene 100-41-4 624.1 ND H 1.0 ug/L 2
Methylene chloride 75-09-2 624.1 ND H 1.0 ug/L 2
1,1,2,2-Tetrachloroethane 79-34-5 624.1 ND H 1.0 ug/L 2
Tetrachloroethene 127-18-4 624.1 ND H 1.0 ug/L 2
Toluene 108-88-3 624.1 ND H 1.0 ug/L 2
1,2,4-Trichlorobenzene 120-82-1 624.1 ND H 1.0 ug/L 2
1,1,1-Trichloroethane 71-55-6 624.1 ND H 1.0 ug/L 2
1,1,2-Trichloroethane 79-00-5 624.1 ND H 1.0 ug/L 2
Trichloroethene 79-01-6 624.1 ND H 1.0 ug/L 2
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
F talytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1__ __.stage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Description:EFF PPA Matrix:Aqueous
Date Sampled:03/02/2021 0920
Date Received:03/03/2021
Volatile Organic Compounds by GC/MS
- Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
624.1 624.1 10 03/04/20210107 DJG 84612
2 624.1 624.1 1 03/17/20212308 DJG 86052
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Trichlorofluoromethane 75-69-4 624.1 ND H 1.0 ug/L 2
Vinyl chloride 75-01-4 624.1 ND H 1.0 ug/L 2
Run 1 Acceptance Run 2 Acceptance
Surrogate Q %Recovery Limits Q %Recovery Limits
Bromofluorobenzene 93 70-130 H 96 70-130
1,2-Dichloroethane-d4 93 70-130 H 95 70-130
Toluene-d8 99 70-130 H 93 70-130
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
F talytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1__ -_.stage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..,.,, in,.eee

Description:EFF PPA Matrix:Aqueous
Date Sampled:03/02/2021 0919
Date Received:03/03/2021
Semivolatile Organic Compounds by GC/MS
- Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
625.1 625.1 1 03/13/2021 2200 SCD 03/05/2021 1812 84833
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Acenaphthene 83-32-9 625.1 ND 1.6 ug/L 1
Acenaphthylene 208-96-8 625.1 ND 1.6 ug/L 1
Anthracene 120-12-7 625.1 ND 1.6 ug/L 1
Benzidine 92-87-5 625.1 ND 8.0 ug/L 1
Benzo(a)anthracene 56-55-3 625.1 ND 1.6 ug/L 1
Benzo(a)pyrene 50-32-8 625.1 ND 1.6 ug/L 1
Benzo(b)fluoranthene 205-99-2 625.1 ND 1.6 ug/L 1
Benzo(g,h,i)perylene 191-24-2 625.1 ND 1.6 ug/L 1
Benzo(k)fluoranthene 207-08-9 625.1 ND 1.6 ug/L 1
4-Bromophenyl phenyl ether 101-55-3 625.1 ND 1.6 ug/L 1
Butyl benzyl phthalate 85-68-7 625.1 ND 1.6 ug/L 1
bis(2-Chloro-1-methylethyl)ether 108-60-1 625.1 ND 1.6 ug/L 1
4-Chloro-3-methyl phenol 59-50-7 625.1 ND 1.6 ug/L 1
bis(2-Chloroethoxy)methane 111-91-1 625.1 ND 1.6 ug/L 1
bis(2-Chloroethyl)ether 111-44-4 625.1 ND 1.6 ug/L 1
2-Chloronaphthalene 91-58-7 625.1 ND 1.6 ug/L 1
2-Chlorophenol 95-57-8 625.1 ND 1.6 ug/L 1
4-Chlorophenyl phenyl ether 7005-72-3 625.1 ND 1.6 ug/L 1
Chrysene 218-01-9 625.1 ND 1.6 ug/L 1
Dibenzo(a,h)anthracene 53-70-3 625.1 ND 1.6 ug/L 1
3,3'-Dichlorobenzidine 91-94-1 625.1 ND 8.0 ug/L 1
9 A-nichlorophenol 120-83-2 625.1 ND 1.6 ug/L 1
ylphthalate 84-66-2 625.1 ND 1.6 ug/L 1
uiuiiethyl phthalate 131-11-3 625.1 ND 1.6 ug/L 1
2,4-Dimethylphenol 105-67-9 625.1 ND 1.6 ug/L 1
Di-n-butyl phthalate 84-74-2 625.1 ND 1.6 ug/L 1
4,6-Dinitro-2-methylphenol 534-52-1 625.1 ND 8.0 ug/L 1
2,4-Dinitrophenol 51-28-5 625.1 ND 8.0 ug/L 1
2,4-Dinitrotoluene 121-14-2 625.1 ND 3.2 ug/L 1
2,6-Dinitrotoluene 606-20-2 625.1 ND 3.2 ug/L 1
Di-n-octylphthalate 117-84-0 625.1 ND 1.6 ug/L 1
1,2-Diphenylhydrazine(as azobenzene) 103-33-3 625.1 ND 1.6 ug/L 1
bis(2-Ethylhexyl)phthalate 117-81-7 625.1 ND 8.0 ug/L 1
Fluoranthene 206-44-0 625.1 ND 1.6 ug/L 1
Fluorene 86-73-7 625.1 ND 1.6 ug/L 1
Hexachlorobenzene 118-74-1 625.1 ND 1.6 ug/L 1
Hexachlorobutadiene 87-68-3 625.1 ND 1.6 ug/L 1
Hexachlorocyclopentadiene 77-47-4 625.1 ND 8.0 ug/L 1
Hexachloroethane 67-72-1 625.1 ND 1.6 ug/L 1
Indeno(1,2,3-c,d)pyrene 193-39-5 625.1 ND 1.6 ug/L 1
LOQ=Limit of Quantitation 8=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
F lalytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1__ ._.itage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
o...... 11 ..c CC

Description:EFF PPA Matrix:Aqueous
Date Sampled:03/02/2021 0919
Date Received:03/03/2021
Semivolatile Organic Compounds by GC/MS
Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
625.1 625.1 1 03/13/2021 2200 SCD 03/05/2021 1812 84833
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Isophorone 78-59-1 625.1 ND 1.6 ug/L 1
Naphthalene 91-20-3 625.1 ND 1.6 ug/L 1
Nitrobenzene 98-95-3 625.1 ND 1.6 ug/L 1
2-Nitrophenol 88-75-5 625.1 ND 3.2 ug/L 1
4-Nitrophenol 100-02-7 625.1 ND 8.0 ug/L 1
N-Nitrosodimethylamine 62-75-9 625.1 ND 1.6 ug/L 1
N-Nitrosodi-n-propylamine 621-64-7 625.1 ND 1.6 ug/L 1
N-Nitrosodiphenylamine(Diphenylamine) 86-30-6 625.1 ND 1.6 ug/L 1
Pentachlorophenol 87-86-5 625.1 ND 8.0 ug/L 1
Phenanthrene 85-01-8 625.1 ND 1.6 ug/L 1
Phenol 108-95-2 625.1 ND 1.6 ug/L 1
Pyrene 129-00-0 625.1 ND 1.6 ug/L 1
1,2,4-Trichlorobenzene 120-82-1 625.1 ND 1.6 ug/L 1
2,4,6-Trichlorophenol 88-06-2 625.1 ND 1.6 ug/L 1
Run 1 Acceptance
Surrogate Q %Recovery Limits
2-Fluorobiphenyl 69 37-129
2-Fluorophenol 29 24-127
Nitrobenzene-d5 64 38-127
Phenol-d5 40 28-128
Terphenyl-d14 74 10-148
" ' Tribromophenol 95 41-144
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
F lalytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1__ ._.itage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D...... 11..c CC

Description:PPA EFF Matrix:Aqueous
Date Sampled:03/02/2021 0925
Date Received:03/03/2021
Mercury (CVAFS)
Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1631E 1 03/05/2021 0628 JMH 03/04/2021 0834 84613
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury(CVAFS) 7439-97-6 1631E ND 0.500 ng/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
F ialytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1__ __.stage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D.-- 1 Z ..0 GG

Description:PPA EFF Dup Matrix: Aqueous
Date Sampled:03/02/2021 0927
Date Received:03/03/2021
Mercury (CVAFS)
Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1631E 1 03/05/2021 0644 JMH 03/04/2021 0834 84613
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury(CVAFS) 7439-97-6 1631E ND 0.500 ng/L 1
LOG=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
I nalytical Services,LLC (formerly Shealy Environmental Services,Inc.)
-_ntage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
n.. .. in ,.eee

Description:Field Blank Matrix:Aqueous
Date Sampled:03/02/2021 0923
Date Received:03/03/2021
Mercury (CVAFS)
— Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1631E 1 03/05/2021 0650 JMH 03/04/2021 0834 84613
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury(CVAFS) 7439-97-6 1631E ND 0.500 ng/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40%
H=Out of holding time W=Reported on wet weight basis
f nalytical Services,LLC (formerly Shealy Environmental Services,Inc.)
__ _ntage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D...... 1 G-FCC

QC Summary
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..,.,. 14,.C G Q

Inorganic non-metals - MB
Sample ID: WQ84661-001 Matrix: Aqueous
Batch:84661
Analytical Method:SM 2540C-2011
rarameter Result Q Dil LOQ Units Analysis Date
TDS ND 1 25 mg/L 03/04/2021 1108
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria *=RPD is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Inorganic non-metals - LCS
Sample ID: WQ84661-002 Matrix: Aqueous
Batch:84661
Analytical Method:SM 2540C-2011
Spike
Amount Result %Rec
rarameter (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date
TDS 1500 1500 1 98 90-110 03/04/2021 1108
LOQ=Limit of Quantitation ND=Not detected at or above the Lao N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..— 1 a-f CC

Inorganic non-metals - MB
Sample ID: WQ84715-001 Matrix: Aqueous
Batch:84715 Prep Method: 351.4
Analytical Method: 351.2 Prep Date: 03/04/2021 1748
rarameter Result Q Dil LOQ Units Analysis Date
TKN ND 1 0.10 mg/L 03/05/2021 1018
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..,.,. 1 n,.f cc

Inorganic non-metals - LCS
Sample ID: WQ84715-002 Matrix: Aqueous
Batch:84715 Prep Method: 351.4
Analytical Method:351.2 Prep Date: 03/04/2021 1748
Spike
Amount Result %Rec
rarameter (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date
TKN 2.0 2.0 1 99 90-110 03/05/2021 1018
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
n..,.,.111

Inorganic non-metals - MB
Sample ID: WQ84783-001 Matrix: Aqueous
Batch:84783
Analytical Method:420.4
. ameter Result Q Oil LOQ Units Analysis Date
Phenolics ND 1 0.0050 mg/L 03/05/2021 1059
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
*=RSD is out of criteria +=RPD is out of criteria
Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Inorganic non-metals - LCS
Sample ID: WQ84783-002 Matrix: Aqueous
Batch:84783
Analytical Method:420.4
Spike
Amount Result %Rec
rarameter (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date
Phenolics 0.050 0.050 1 99 90-110 03/05/2021 1103
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Inorganic non-metals - MS
Sample ID: WC03110-003MS Matrix: Aqueous
Batch:84783
Analytical Method:420.4
Sample Spike
Amount Amount Result %Rec
r-arameter (mg/L) (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date
Phenolics ND 0.050 0.050 1 101 90-110 03/05/2021 1300
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Nose: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..--1/ ..F CC

Inorganic non-metals - MSD
Sample ID: WC03110-003MD Matrix: Aqueous
Batch:84783
Analytical Method:420.4
Sample Spike
i Amount Amount Result %Rec %RPD
rarameter (mg/L) (mg/L) (mg/L) Q Dil %Rec % RPD Limit Limit Analysis Date
Phenolics ND 0.050 0.051 1 103 2.1 90-110 20 03/05/2021 1305
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Inorganic non-metals - MB
Sample ID: WQ84977-001 Matrix: Aqueous
Batch:84977 Prep Method: 350.1
Analytical Method:350.1
rdrameter Result Q Dil LOQ Units Analysis Date
Ammonia-N (gas diffusion) ND 1 0.10 mg/L 03/08/2021 1414
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
'vote: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......'7G..F GC

Inorganic non-metals - LCS
Sample ID: WQ84977-002 Matrix: Aqueous
Batch:84977 Prep Method: 350.1
Analytical Method:350.1
Spike
Amount Result %Rec
rat dmeter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Ammonia-N (gas diffusion) 2.5 2.6 1 103 90-110 03/08/2021 1416
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..--'IC-F CC
1

Inorganic non-metals - MB
Sample ID: WQ85000-001 Matrix: Aqueous
Batch:85000 Prep Method: 10-204-00-1-X
Analytical Method:SM 4500-CN E-2011 Prep Date: 03/08/2021 1515
r-arameter Result Q DiI LOQ Units Analysis Date
Cyanide-Total ND 1 0.010 mg/L 03/08/2021 1702
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
nose: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......'1-7..f CG

Inorganic non-metals - LCS
Sample ID: WQ85000-002 Matrix: Aqueous
Batch:85000 Prep Method: 10-204-00-1-X
Analytical Method:SM 4500-CN E-2011 Prep Date: 03/08/2021 1515
Spike
Amount Result %Rec
rarameter (mg/L) (mg/L) Q Di! %Rec Limit Analysis Date
Cyanide-Total 0.10 0.092 1 92 90-110 03/08/2021 1703
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......'1 V..G G G

Inorganic non-metals - MB
Sample ID: WQ85287-001 Matrix: Aqueous
Batch:85287
Analytical Method:SM 2340C-2011
-arameter Result Q Dil LOQ Units Analysis Date
Hardness(total) ND 1 10 mg/L 03/09/2021 1751
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
now: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D.,..,.111,,c cG

Inorganic non-metals - LCS
Sample ID: WQ85287-002 Matrix: Aqueous
Batch:85287
Analytical Method:SM 2340C-2011
-- Spike
Amount Result %Rec
..ameter (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date
Hardness(total) 100 100 1 100 90-110 03/09/2021 1751
LOQ=Limit of Quantitauon ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D....,.1(1-FCC

Inorganic non-metals - MB
Sample ID: WQ85402-001 Matrix: Aqueous
Batch:85402
Analytical Method:365.1
_._meter Result Q Dil LOQ Units Analysis Date
Phosphorus ND 1 0.050 mg/L 03/11/2021 1237
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D....,, ]1 ..0 CC

Inorganic non-metals - LCS
Sample ID: WQ85402-002 Matrix: Aqueous
Batch:85402
Analytical Method: 365.1
Spike
Amount Result % Rec
. .....meter (mg/L) (mg/L) Q Di! %Rec Limit Analysis Date
Phosphorus 1.0 0.99 1 99 90-110 03/11/2021 1240
LOCI=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
V.Q.C. Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Inorganic non-metals - MB
Sample ID: WQ85602-001 Matrix: Aqueous
Batch:85602
Analytical Method:353.2
. .ameter Result Q Dil LOQ Units Analysis Date
Nitrate-Nitrite-N ND 1 0.020 mg/L 03/11/2021 2028
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..--Z 1-{•C C

Inorganic non-metals - LCS
Sample ID: WQ85602-002 Matrix: Aqueous
Batch:85602
Analytical Method:353.2
Spike
Amount Result %Rec
. ...ameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate-Nitrite-N 0.80 0.78 1 98 90-110 03/11/2021 2029
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......ZA ,.0 CC

Inorganic non-metals - MB
Sample ID: WQ85328-001 Matrix: Aqueous
Batch:85328
Analytical Method: 1664B
o,ameter Result Q Dil LOQ Units Analysis Date
HEM(oil and grease) ND 1 5.0 mg/L 03/10/2021 1938
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria *=RPD is out of criteria
hose: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..--14-f GC

Inorganic non-metals - LCS
Sample ID: WQ85328-002 Matrix: Aqueous
Batch:85328
Analytical Method: 1664B
Spike
Amount Result %Rec
r-aremeter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
HEM (oil and grease) 40 35 1 88 78-114 03/10/2021 1938
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ84612-001 Matrix: Aqueous
Batch:84612 Prep Method: 624.1
Analytical Method: 624.1
-a.ameter Result Q Dil LOQ Units Analysis Date
Acrolein ND 1 5.0 ug/L 03/03/2021 1947
Acrylonitrile ND 1 5.0 ug/L 03/03/2021 1947
Benzene ND 1 1.0 ug/L 03/03/2021 1947
Bromodichloromethane ND 1 1.0 ug/L 03/03/2021 1947
Bromoform ND 1 1.0 ug/L 03/03/2021 1947
Bromomethane(Methyl bromide) ND 1 2.0 ug/L 03/03/2021 1947
Carbon tetrachloride ND 1 1.0 ug/L 03/03/2021 1947
Chlorobenzene ND 1 1.0 ug/L 03/03/2021 1947
Chloroethane ND 1 2.0 ug/L 03/03/2021 1947
2-Chloroethylvinylether ND 1 5.0 ug/L 03/03/2021 1947
Chloroform ND 1 1.0 ug/L 03/03/2021 1947
Chloromethane(Methyl chloride) ND 1 2.0 ug/L 03/03/2021 1947
Dibromochloromethane ND 1 1.0 ug/L 03/03/2021 1947
1,2-Dichlorobenzene ND 1 1.0 ug/L 03/03/2021 1947
1,3-Dichlorobenzene ND 1 1.0 ug/L 03/03/2021 1947
1,4-Dichlorobenzene ND 1 1.0 ug/L 03/03/2021 1947
Dichlorodifluoromethane ND 1 2.0 ug/L 03/03/2021 1947
1,1-Dichloroethane ND 1 1.0 ug/L 03/03/2021 1947
1,2-Dichloroethane ND 1 1.0 ug/L 03/03/2021 1947
1,1-Dichloroethene ND 1 1.0 ug/L 03/03/2021 1947
cis-1,2-Dichloroethene ND 1 1.0 ug/L 03/03/2021 1947
trans-1,2-Dichloroethene ND 1 1.0 ug/L 03/03/2021 1947
1,2-Dichloropropane ND 1 1.0 ug/L 03/03/2021 1947
' 1,3-Dichloropropene ND 1 1.0 ug/L 03/03/2021 1947
s-1,3-Dichloropropene ND 1 1.0 ug/L 03/03/2021 1947
Ethylbenzene ND 1 1.0 ug/L 03/03/2021 1947
Methylene chloride ND 1 1.0 ug/L 03/03/2021 1947
1,1,2,2-Tetrachloroethane ND 1 1.0 ug/L 03/03/2021 1947
Tetrachloroethene ND 1 1.0 ug/L 03/03/2021 1947
Toluene ND 1 1.0 ug/L 03/03/2021 1947
1,2,4-Trichlorobenzene ND 1 1.0 ug/L 03/03/2021 1947
1,1,1-Trichloroethane ND 1 1.0 ug/L 03/03/2021 1947
1,1,2-Trichloroethane ND 1 1.0 ug/L 03/03/2021 1947
Trichloroethene ND 1 1.0 ug/L 03/03/2021 1947
Trichlorofluoromethane ND 1 1.0 ug/L 03/03/2021 1947
Vinyl chloride ND 1 1.0 ug/L 03/03/2021 1947
Acceptance
Surrogate Q %Rec Limit
Bromofluorobenzene 100 70-130
1,2-Dichloroethane-d4 96 70-130
Toluene-d8 99 70-130
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of critera
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
mute: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......21,.0 CC

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ84612-002 Matrix: Aqueous
Batch:84612 Prep Method: 624.1
Analytical Method:624.1
Spike
Amount Result % Rec
rarameter (ug/L) (ug/L) Q Dil %Rec Limit Analysis Date
Acrolein 200 220 1 108 60-140 03/03/2021 1900
Acrylonitrile 40 42 1 105 60-140 03/03/2021 1900
Benzene 20 20 1 101 65-135 03/03/2021 1900
Bromodichloromethane 20 21 1 103 65-135 03/03/2021 1900
Bromoform 20 20 1 98 70-130 03/03/2021 1900
Bromomethane(Methyl bromide) 20 19 1 97 15-185 03/03/2021 1900
Carbon tetrachloride 20 19 1 97 70-130 03/03/2021 1900
Chlorobenzene 20 19 1 95 65-135 03/03/2021 1900
Chloroethane 20 18 1 88 40-160 03/03/2021 1900
2-Chloroethylvinylether 20 19 1 93 1-225 03/03/2021 1900
Chloroform 20 19 1 96 70-135 03/03/2021 1900
Chloromethane(Methyl chloride) 20 19 1 96 1-205 03/03/2021 1900
Dibromochloromethane 20 20 1 100 53-149 03/03/2021 1900
1,2-Dichlorobenzene 20 18 1 92 65-135 03/03/2021 1900
1,3-Dichlorobenzene 20 19 1 94 70-130 03/03/2021 1900
1,4-Dichlorobenzene 20 19 1 93 65-135 03/03/2021 1900
Dichlorodifluoromethane 20 16 1 78 60-140 03/03/2021 1900
1,1-Dichloroethane 20 21 1 103 70-130 03/03/2021 1900
1,2-Dichloroethane 20 21 1 104 70-130 03/03/2021 1900
1,1-Dichloroethene 20 17 1 84 50-150 03/03/2021 1900
cis-1,2-Dichloroethene 20 19 1 96 70-130 03/03/2021 1900
trans-1,2-Dichloroethene 20 18 1 91 70-130 03/03/2021 1900
1,2-Dichloropropane 20 20 1 99 35-165 03/03/2021 1900
,3-Dichloropropene 20 21 1 107 25-175 03/03/2021 1900
3-1,3-Dichloropropene 20 22 1 109 50-150 03/03/2021 1900
Ethylbenzene 20 19 1 96 60-140 03/03/2021 1900
Methylene chloride 20 20 1 101 60-140 03/03/2021 1900
1,1,2,2-Tetrachloroethane 20 20 1 102 60-140 03/03/2021 1900
Tetrachloroethene 20 20 1 100 70-130 03/03/2021 1900
Toluene 20 20 1 102 70-130 03/03/2021 1900
1,2,4-Trichlorobenzene 20 23 1 113 60-140 03/03/2021 1900
1,1,1-Trichloroethane 20 20 1 101 70-130 03/03/2021 1900
1,1,2-Trichloroethane 20 20 1 100 70-130 03/03/2021 1900
Trichloroethene 20 21 1 104 65-135 03/03/2021 1900
Trichlorofluoromethane 20 18 1 92 50-150 03/03/2021 1900
Vinyl chloride 20 18 1 90 5-195 03/03/2021 1900
Acceptance
Surrogate Q %Rec Limit
Bromofluorobenzene 100 70-130
1,2-Dichloroethane-d4 93 70-130
Toluene-d8 99 70-130
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) I
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..--1 0.-c CC

Volatile Organic Compounds by GC/MS - MB
Sample ID: WQ86052-001 Matrix: Aqueous
Batch:86052 Prep Method: 624.1
Analytical Method:624.1
I-diameter Result Q Dil LOQ Units Analysis Date
Acrolein ND 1 5.0 ug/L 03/17/2021 2142
Acrylonitrile ND 1 5.0 ug/L 03/17/2021 2142
Benzene ND 1 1.0 ug/L 03/17/2021 2142
Bromodichloromethane ND 1 1.0 ug/L 03/17/2021 2142
Bromoform ND 1 1.0 ug/L 03/17/2021 2142
Bromomethane(Methyl bromide) ND 1 2.0 ug/L 03/17/2021 2142
Carbon tetrachloride ND 1 1.0 ug/L 03/17/2021 2142
Chlorobenzene ND 1 1.0 ug/L 03/17/2021 2142
Chloroethane ND 1 2.0 ug/L 03/17/2021 2142
2-Chloroethylvinylether ND 1 5.0 ug/L 03/17/2021 2142
Chloroform ND 1 1.0 ug/L 03/17/2021 2142
Chloromethane(Methyl chloride) ND 1 2.0 ug/L 03/17/2021 2142
Dibromochloromethane ND 1 1.0 ug/L 03/17/2021 2142
1,2-Dichlorobenzene ND 1 1.0 ug/L 03/17/2021 2142
1,3-Dichlorobenzene ND 1 1.0 ug/L 03/17/2021 2142
1,4-Dichlorobenzene ND 1 1.0 ug/L 03/17/2021 2142
Dichlorodifluoromethane ND 1 2.0 ug/L 03/17/2021 2142
1,1-Dichloroethane ND 1 1.0 ug/L 03/17/2021 2142
1,2-Dichloroethane ND 1 1.0 ug/L 03/17/2021 2142
1,1-Dichloroethene ND 1 1.0 ug/L 03/17/2021 2142
cis-1,2-Dichloroethene ND 1 1.0 ug/L 03/17/2021 2142
trans-1,2-Dichloroethene ND 1 1.0 ug/L 03/17/2021 2142
1,2-Dichloropropane ND 1 1.0 ug/L 03/17/2021 2142
1,3-Dichloropropene ND 1 1.0 ug/L 03/17/2021 2142
s-1,3-Dichloropropene ND 1 1.0 ug/L 03/17/2021 2142
Ethylbenzene ND 1 1.0 ug/L 03/17/2021 2142
Methylene chloride ND 1 1.0 ug/L 03/17/2021 2142
1,1,2,2-Tetrachloroethane ND 1 1.0 ug/L 03/17/2021 2142
Tetrachloroethene ND 1 1.0 ug/L 03/17/2021 2142
Toluene ND 1 1.0 ug/L 03/17/2021 2142
1,2,4-Trichlorobenzene ND 1 1.0 ug/L 03/17/2021 2142
1,1,1-Trichloroethane ND 1 1.0 ug/L 03/17/2021 2142
1,1,2-Trichloroethane ND 1 1.0 ug/L 03/17/2021 2142
Trichloroethene ND 1 1.0 ug/L 03/17/2021 2142
Trichlorofluoromethane ND 1 1.0 ug/L 03/17/2021 2142
Vinyl chloride ND 1 1.0 ug/L 03/17/2021 2142
Acceptance
Surrogate Q %Rec Limit
Bromofluorobenzene 94 70-130
1,2-Dichloroethane-d4 98 70-130
Toluene-d8 92 70-130
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
nose: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
o.,.-,zn..acc

Volatile Organic Compounds by GC/MS - LCS
Sample ID: WQ86052-002 Matrix: Aqueous
Batch:86052 Prep Method: 624.1
Analytical Method:624.1
Spike
Amount Result % Rec
rarameter (ug/L) (ug/L) Q Oil %Rec Limit Analysis Date
Acrolein 200 210 1 107 60-140 03/17/2021 2057
Acrylonitrile 40 39 1 97 60-140 03/17/2021 2057
Benzene 20 21 1 104 65-135 03/17/2021 2057
Bromodichloromethane 20 18 1 92 65-135 03/17/2021 2057
Bromoform 20 17 1 87 70-130 03/17/2021 2057
Bromomethane(Methyl bromide) 20 19 1 96 15-185 03/17/2021 2057
Carbon tetrachloride 20 19 1 97 70-130 03/17/2021 2057
Chlorobenzene 20 19 1 94 65-135 03/17/2021 2057
Chloroethane 20 20 1 98 40-160 03/17/2021 2057
2-Chloroethylvinylether 20 18 1 92 1-225 03/17/2021 2057
Chloroform 20 19 1 94 70-135 03/17/2021 2057
Chloromethane(Methyl chloride) 20 19 1 95 1-205 03/17/2021 2057
Dibromochloromethane 20 18 1 90 53-149 03/17/2021 2057
1,2-Dichlorobenzene 20 18 1 92 65-135 03/17/2021 2057
1,3-Dichlorobenzene 20 19 1 94 70-130 03/17/2021 2057
1,4-Dichlorobenzene 20 18 1 90 65-135 03/17/2021 2057
Dichlorodifluoromethane 20 21 1 103 60-140 03/17/2021 2057
1,1-Dichloroethane 20 20 1 98 70-130 03/17/2021 2057
1,2-Dichloroethane 20 20 1 99 70-130 03/17/2021 2057
1,1-Dichloroethene 20 17 1 84 50-150 03/17/2021 2057
cis-1,2-Dichloroethene 20 19 1 93 70-130 03/17/2021 2057
trans-1,2-Dichloroethene 20 18 1 90 70-130 03/17/2021 2057
1,2-Dichloropropane 20 19 1 97 35-165 03/17/2021 2057
,3-Dichloropropene 20 20 1 98 25-175 03/17/2021 2057
-1,3-Dichloropropene 20 20 1 98 50-150 03/17/2021 2057
Ethylbenzene 20 18 1 89 60-140 03/17/2021 2057
Methylene chloride 20 19 1 97 60-140 03/17/2021 2057
1,1,2,2-Tetrachloroethane 20 17 1 87 60-140 03/17/2021 2057
Tetrachloroethene 20 19 1 93 70-130 03/17/2021 2057
Toluene 20 19 1 94 70-130 03/17/2021 2057
1,2,4-Trichlorobenzene 20 16 1 80 60-140 03/17/2021 2057
1,1,1-Trichloroethane 20 19 1 95 70-130 03/17/2021 2057
1,1,2-Trichloroethane 20 19 1 93 70-130 03/17/2021 2057
Trichloroethene 20 19 1 95 65-135 03/17/2021 2057
Trichlorofluoromethane 20 19 1 97 50-150 03/17/2021 2057
Vinyl chloride 20 19 1 95 5-195 03/17/2021 2057
Acceptance
Surrogate Q %Rec Limit
Bromofluorobenzene 90 70-130
1,2-Dichloroethane-d4 92 70-130
Toluene-d8 91 70-130
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..,.,,nn._F cc

,
Volatile Organic Compounds by GC/MS - LCSD
Sample ID: WQ86052-003 Matrix: Aqueous
Batch:86052 Prep Method: 624.1
Analytical Method:624.1
Spike
Amount Result %Rec %RPD
rdrameter (ug/L) (ug/L) Q Oil %Rec %RPD Limit Limit Analysis Date
Acrolein 200 150 + 1 76 33 60-140 20 03/18/2021 0104
Acrylonitrile 40 27 + 1 68 36 60-140 20 03/18/2021 0104
Benzene 20 20 1 100 3.7 65-135 20 03/18/2021 0104
Bromodichloromethane 20 17 1 86 6.9 65-135 20 03/18/2021 0104
Bromoform 20 12 N,+ 1 59 38 70-130 20 03/18/2021 0104
Bromomethane(Methyl bromide) 20 19 1 93 3.3 15-185 20 03/18/2021 0104
Carbon tetrachloride 20 20 1 101 4.7 70-130 20 03/18/2021 0104
Chlorobenzene 20 19 1 95 0.96 65-135 20 03/18/2021 0104
Chloroethane 20 18 1 90 8.3 40-160 20 03/18/2021 0104
2-Chloroethylvinylether 20 18 1 90 1.8 1-225 20 03/18/2021 0104
Chloroform 20 18 1 92 2.9 70-135 20 03/18/2021 0104
Chloromethane(Methyl chloride) 20 18 1 92 3.8 1-205 20 03/18/2021 0104
Dibromochloromethane 20 15 1 75 18 53-149 20 03/18/2021 0104
1,2-Dichlorobenzene 20 20 1 99 6.8 65-135 20 03/18/2021 0104
1,3-Dichlorobenzene 20 19 1 96 2.0 70-130 20 03/18/2021 0104
1,4-Dichlorobenzene 20 19 1 95 5.7 65-135 20 03/18/2021 0104
Dichlorodifluoromethane 20 21 1 103 0.73 60-140 20 03/18/2021 0104
1,1-Dichloroethane 20 20 1 99 1.2 70-130 20 03/18/2021 0104
1,2-Dichloroethane 20 18 1 92 7.0 70-130 20 03/18/2021 0104
1,1-Dichloroethene 20 18 1 89 5.7 50-150 20 03/18/2021 0104
cis-1,2-Dichloroethene 20 18 1 91 1.4 70-130 20 03/18/2021 0104
trans-1,2-Dichloroethene 20 18 1 88 2.3 70-130 20 03/18/2021 0104
1,2-Dichloropropane 20 19 1 94 3.0 35-165 20 03/18/2021 0104
1,3-Dichloropropene 20 17 1 84 15 25-175 20 03/18/2021 0104
5-1,3-Dichloropropene 20 16 1 81 20 50-150 20 03/18/2021 0104
Ethylbenzene 20 18 1 90 1.3 60-140 20 03/18/2021 0104
Methylene chloride 20 18 1 88 9.9 60-140 20 03/18/2021 0104
1,1,2,2-Tetrachloroethane 20 17 1 83 3.7 60-140 20 03/18/2021 0104
Tetrachloroethene 20 19 1 95 2.0 70-130 20 03/18/2021 0104
Toluene 20 19 1 95 0.51 70-130 20 03/18/2021 0104
1,2,4-Trichlorobenzene 20 20 + 1 98 21 60-140 20 03/18/2021 0104
1,1,1-Trichloroethane 20 20 1 98 3.3 70-130 20 03/18/2021 0104
1,1,2-Trichloroethane 20 17 1 85 8.4 70-130 20 03/18/2021 0104
Trichloroethene 20 19 1 96 0.96 65-135 20 03/18/2021 0104
Trichlorofluoromethane 20 19 1 94 2.5 50-150 20 03/18/2021 0104
Vinyl chloride 20 17 1 87 8.8 5-195 20 03/18/2021 0104
Acceptance
Surrogate Q %Rec Limit
Bromofluorobenzene 97 70-130
1,2-Dichloroethane-d4 86 70-130
Toluene-d8 93 70-130
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPO is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......d 1 ,.0 GC

Semivolatile Organic Compounds by GC/MS - MB
Sample ID: WQ84833-001 Matrix: Aqueous
Batch:84833 Prep Method: 625.1
Analytical Method:625.1 Prep Date: 03/05/2021 1812
rarameter Result Q Dil LOQ Units Analysis Date
Acenaphthene ND 1 1.6 ug/L 03/13/2021 1815
Acenaphthylene ND 1 1.6 ug/L 03/13/2021 1815
Anthracene ND 1 1.6 ug/L 03/13/2021 1815
Benzidine ND 1 8.0 ug/L 03/13/2021 1815
Benzo(a)anthracene ND 1 1.6 ug/L 03/13/2021 1815
Benzo(a)pyrene ND 1 1.6 ug/L 03/13/2021 1815
Benzo(b)fluoranthene ND 1 1.6 ug/L 03/13/2021 1815
Benzo(g,h,i)perylene ND 1 1.6 ug/L 03/13/2021 1815
Benzo(k)fluoranthene ND 1 1.6 ug/L 03/13/2021 1815
4-Bromophenyl phenyl ether ND 1 1.6 ug/L 03/13/2021 1815
Butyl benzyl phthalate ND 1 1.6 ug/L 03/13/2021 1815
bis(2-Chloro-1-methylethyl)ether ND 1 1.6 ug/L 03/13/2021 1815
4-Chloro-3-methyl phenol ND 1 1.6 ug/L 03/13/2021 1815
bis(2-Chloroethoxy)methane ND 1 1.6 ug/L 03/13/2021 1815
bis(2-Chloroethyl)ether ND 1 1.6 ug/L 03/13/2021 1815
2-Chloronaphthalene ND 1 1.6 ug/L 03/13/2021 1815
2-Chlorophenol ND 1 1.6 ug/L 03/13/2021 1815
4-Chlorophenyl phenyl ether ND 1 1.6 ug/L 03/13/2021 1815
Chrysene ND 1 1.6 ug/L 03/13/2021 1815
Dibenzo(a,h)anthracene ND 1 1.6 ug/L 03/13/2021 1815
3,3'-Dichlorobenzidine ND 1 8.0 ug/L 03/13/2021 1815
1 1.6ug/L03/13/2021 1 1 2,4 Dichlorophenol ND 8 5
Diethylphthalate ND 1 1.6 ug/L 03/13/2021 1815
sthyl phthalate ND 1 1.6 ug/L 03/13/2021 1815
Dimethylphenol ND 1 1.6 ug/L 03/13/2021 1815
Di-n-butyl phthalate ND 1 1.6 ug/L 03/13/2021 1815
4,6-Dinitro-2-methylphenol ND 1 8.0 ug/L 03/13/2021 1815
2,4-Dinitrophenol ND 1 8.0 ug/L 03/13/2021 1815
2,4-Dinitrotoluene ND 1 3.2 ug/L 03/13/2021 1815
2,6-Dinitrotoluene ND 1 3.2 ug/L 03/13/2021 1815
Di-n-octylphthalate ND 1 1.6 ug/L 03/13/2021 1815
1,2-Diphenylhydrazine(as azobenzene) ND 1 1.6 ug/L 03/13/2021 1815
bis(2-Ethylhexyl)phthalate ND 1 8.0 ug/L 03/13/2021 1815
i Fluoranthene ND 1 1.6 ug/L 03/13/2021 1815
Fluorene ND 1 1.6 ug/L 03/13/2021 1815
Hexachlorobenzene ND 1 1.6 ug/L 03/13/2021 1815
Hexachlorobutadiene ND 1 1.6 ug/L 03/13/2021 1815
Hexachlorocyclopentadiene ND 1 8.0 ug/L 03/13/2021 1815
Hexachloroethane ND 1 1.6 ug/L 03/13/2021 1815
Indeno(1,2,3-c,d)pyrene ND 1 1.6 ug/L 03/13/2021 1815
Isophorone ND 1 1.6 ug/L 03/13/2021 1815
Naphthalene ND 1 1.6 ug/L 03/13/2021 1815
Nitrobenzene ND 1 1.6 ug/L 03/13/2021 1815
2-Nitrophenol ND 1 3.2 ug/L 03/13/2021 1815
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......Al,.!'GG

Semivolatile Organic Compounds by GC/MS - MB
Sample ID: WQ84833-001 Matrix: Aqueous
Batch:84833 Prep Method: 625.1
Analytical Method: 625.1 Prep Date: 03/05/2021 1812
rarameter Result Q Dil LOQ Units Analysis Date
4-Nitrophenol ND 1 8.0 ug/L 03/13/2021 1815
N-Nitrosodimethylamine ND 1 1.6 ug/L 03/13/2021 1815
N-Nitrosodi-n-propylamine ND 1 1.6 ug/L 03/13/2021 1815
N-Nitrosodiphenylamine(Diphenylamine)ND 1 1.6 ug/L 03/13/2021 1815
Pentachlorophenol ND 1 8.0 ug/L 03/13/2021 1815
Phenanthrene ND 1 1.6 ug/L 03/13/2021 1815
Phenol ND 1 1.6 ug/L 03/13/2021 1815
Pyrene ND 1 1.6 ug/L 03/13/2021 1815
1,2,4-Trichlorobenzene ND 1 1.6 ug/L 03/13/2021 1815
2,4,6-Trichlorophenol ND 1 1.6 ug/L 03/13/2021 1815
Acceptance
Surrogate Q %Rec Limit
2-Fluorobiphenyl 75 37-129
2-Fluorophenol 37 24-127
Nitrobenzene-d5 70 38-127
Phenol-d5 55 28-128
Terphenyl-d14 77 10-148
2,4,6-Tribromophenol 83 41-144
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Semivolatile Organic Compounds by GC/MS - LCS
Sample ID: WQ84833-002 Matrix: Aqueous
Batch:84833 Prep Method: 625.1
Analytical Method:625.1 Prep Date: 03/05/2021 1812
Spike
Amount Result % Rec
rarameter (ug/L) (ug/L) Q Dil %Rec Limit Analysis Date
Acenaphthene 20 16 1 81 47-145 03/13/2021 1840
Acenaphthylene 20 15 1 77 33-145 03/13/2021 1840
Anthracene 20 16 1 80 27-133 03/13/2021 1840
Benzidine 100 11 1 11 1-150 03/13/2021 1840
Benzo(a)anthracene 20 15 1 77 33-143 03/13/2021 1840
Benzo(a)pyrene 20 17 1 84 17-163 03/13/2021 1840
Benzo(b)fluoranthene 20 18 1 92 24-159 03/13/2021 1840
Benzo(g,h,i)perylene 20 17 1 86 1-219 03/13/2021 1840
Benzo(k)fluoranthene 20 18 1 88 11-162 03/13/2021 1840
4-Bromophenyl phenyl ether 20 18 1 91 53-127 03/13/2021 1840
Butyl benzyl phthalate 20 16 1 79 1-152 03/13/2021 1840
bis(2-Chloro-1-methylethyl)ether 20 17 1 84 36-166 03/13/2021 1840
4-Chloro-3-methyl phenol 20 17 1 85 22-147 03/13/2021 1840
bis(2-Chloroethoxy)methane 20 17 1 84 33-184 03/13/2021 1840
bis(2-Chloroethyl)ether 20 18 1 89 12-158 03/13/2021 1840
2-Chloronaphthalene 20 16 1 80 60-120 03/13/2021 1840
2-Chlorophenol 20 13 1 67 23-134 03/13/2021 1840
4-Chlorophenyl phenyl ether 20 17 1 87 25-158 03/13/2021 1840
Chrysene 20 16 1 79 17-168 03/13/2021 1840
Dibenzo(a,h)anthracene 20 19 1 93 1-227 03/13/2021 1840
3,3'-Dichlorobenzidine 20 2.4 1 12 1-262 03/13/2021 1840
2,4-Dichlorophenol 20 15 1 73 39-135 03/13/2021 1840
Diethylphthalate 20 17 1 87 1-120 03/13/2021 1840
ethyl phthalate 20 17 1 84 1-120 03/13/2021 1840
Dimethylphenol 20 16 1 78 32-120 03/13/2021 1840
Di-n-butyl phthalate 20 17 1 84 1-120 03/13/2021 1840
4,6-Dinitro-2-methylphenol 20 23 1 115 1-181 03/13/2021 1840
2,4-Dinitrophenol 40 49 1 122 1-191 03/13/2021 1840
2,4-Dinitrotoluene 20 20 1 102 39-139 03/13/2021 1840
2,6-Dinitrotoluene 20 20 1 102 50-158 03/13/2021 1840
Di-n-octylphthalate 20 18 1 89 4-146 03/13/2021 1840
1,2-Diphenylhydrazine(as azobenzene) 20 14 1 70 1-150 03/13/2021 1840
bis(2-Ethylhexyl)phthalate 20 17 1 83 8-158 03/13/2021 1840
Fluoranthene 20 17 1 84 26-137 03/13/2021 1840
Fluorene 20 16 1 81 59-121 03/13/2021 1840
Hexachlorobenzene 20 18 1 90 1-152 03/13/2021 1840
Hexachlorobutadiene 20 17 1 85 24-120 03/13/2021 1840
Hexachlorocyclopentadiene 100 50 1 50 1-150 03/13/2021 1840
Hexachloroethane 20 16 1 82 40-120 03/13/2021 1840
Indeno(1,2,3-c,d)pyrene 20 16 1 82 1-171 03/13/2021 1840
Isophorone 20 20 1 100 21-196 03/13/2021 1840
Naphthalene 20 16 1 . 81 21-133 03/13/2021 1840
Nitrobenzene 20 18 1 92 35-180 03/13/2021 1840
2-Nitrophenol 20 17 1 87 29-182 03/13/2021 1840
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

i
Semivolatile Organic Compounds by GC/MS - LCS
Sample ID: WQ84833-002 Matrix: Aqueous
Batch:84833 Prep Method: 625.1
Analytical Method:625.1 Prep Date: 03/05/2021 1812
Spike
Amount Result %Rec
rarameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
4-Nitrophenol 40 33 1 83 1-132 03/13/2021 1840
N-Nitrosodimethylamine 20 15 1 74 1-150 03/13/2021 1840
N-Nitrosodi-n-propylamine 20 19 1 94 1-230 03/13/2021 1840
N-Nitrosodiphenylamine(Diphenylamine) 20 10 1 52 1-150 03/13/2021 1840
Pentachlorophenol 40 36 1 90 14-176 03/13/2021 1840
Phenanthrene 20 16 1 80 54-120 03/13/2021 1840
Phenol 20 12 1 59 5-120 03/13/2021 1840
Pyrene 20 15 1 74 52-120 03/13/2021 1840
1,2,4-Trichlorobenzene 20 16 1 80 44-142 03/13/2021 1840
2,4,6-Trichlorophenol 20 16 1 81 37-144 03/13/2021 1840
Acceptance
Surrogate Q %Rec Limit
2-Fluorobiphenyl 76 37-129
2-Fluorophenol 43 24-127
Nitrobenzene-d5 81 38-127
Phenol-d5 59 28-128
Terphenyl-d 14 71 10-148
2,4,6-Tribromophenol 93 41-144
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40
=RSD is out of criteria +=RPD is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......AG-F CC

ICP-MS - MB
Sample ID: WQ84622-001 Matrix: Aqueous
Batch:84622 Prep Method: 200.2
Analytical Method:200.8 Prep Date: 03/05/2021 0304
rarameter Result Q Dil LOQ Units Analysis Date
Antimony ND 1 5.0 ug/L 03/05/2021 1033
Arsenic ND 1 2.0 ug/L 03/05/2021 1033
Beryllium ND 1 1.0 ug/L 03/05/2021 1033
Cadmium ND 1 0.50 ug/L 03/05/2021 1033
Chromium ND 1 5.0 ug/L 03/05/2021 1033
Copper ND 1 2.0 ug/L 03/05/2021 1033
Lead ND 1 2.0 ug/L 03/05/2021 1033
Nickel ND 1 2.0 ug/L 03/05/2021 1033
Selenium ND 1 5.0 ug/L 03/05/2021 1033
Silver ND 1 1.0 ug/L 03/05/2021 1033
Thallium ND 1 2.0 ug/L 03/05/2021 1033
Zinc ND 1 10 ug/L 03/05/2021 1033
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

ICP-MS - LCS
Sample ID: WQ84622-002 Matrix: Aqueous
Batch:84622 Prep Method: 200.2
Analytical Method:200.8 Prep Date: 03/05/2021 0304
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil %Rec Limit Analysis Date
Antimony 100 100 1 102 85-115 03/05/2021 1039
Arsenic 100 95 1 95 85-115 03/05/2021 1039
Beryllium 100 92 1 92 85-115 03/05/2021 1039
Cadmium 100 93 1 93 85-115 03/05/2021 1039
Chromium 100 100 1 100 85-115 03/05/2021 1039
Copper 100 95 1 95 85-115 03/05/2021 1039
Lead 100 93 1 93 85-115 03/05/2021 1039
Nickel 100 93 1 93 85-115 03/05/2021 1039
Selenium 100 90 1 90 85-115 03/05/2021 1039
Silver 100 93 1 93 85-115 03/05/2021 1039
Thallium 100 94 1 94 85-115 03/05/2021 1039
Zinc 100 95 1 95 85-115 03/05/2021 1039 1
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Mercury (CVAFS) - MB
Sample ID: WQ84613-001 Matrix: Aqueous
Batch:84613 Prep Method:
Analytical Method: 1631E Prep Date: 03/04/2021 0834
rarameter Result Q Dil LOQ Units Analysis Date
Mercury(CVAFS) ND 1 0.500 ng/L 03/05/2021 0506
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D.. -AO„e CC

Mercury (CVAFS) - LCS
Sample ID: WQ84613-002 Matrix: Aqueous
Batch:84613 Prep Method:
Analytical Method: 1631E Prep Date: 03/04/2021 0834
Spike
Amount Result %Rec
rarameter (ng/L) (ng/L) Q Dil % Rec Limit Analysis Date
Mercury(CVAFS) 5.00 4.61 1 92 75-125 03/05/2021 0516
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
n..,...nn,.ccc

Mercury (CVAFS) - MS
Sample ID: WC03110-006MS Matrix: Aqueous
Batch:84613 Prep Method:
Analytical Method: 1631E Prep Date: 03/04/2021 0834
Sample Spike
Amount Amount Result %Rec
rarameter (ng/L) (ng/L) (ng/L) Q Dil %Rec Limit Analysis Date
Mercury(CVAFS) ND 5.00 4.87 1 97 71-125 03/05/2021 0633
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Mercury (CVAFS) - MSD
Sample ID: WC03110-006MD Matrix: Aqueous
Batch:84613 Prep Method:
Analytical Method: 1631E Prep Date: 03/04/2021 0834
Sample Spike
Amount Amount Result %Rec % RPD
r-ammeter (ng/L) (ng/L) (ng/L) Q Oil %Rec % RPD Limit Limit Analysis Date
Mercury(CVAFS) ND 5.00 4.91 1 98 0.78 71-125 24 03/05/2021 0639
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......GI -4-GC

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

. 0
< (a
• D
PACE ANALYTICAL SERVICES. LLC
▪ m 0 106 Vantage Point Drive •We COlumbla,SC 29172 N u m bet 5 U 61 1
cn ceiinaly�iCal Telenhocie No.AD3791-9700 Fax No.803-791-9111
O• 2
vtv w.pa.leiabs.com
1
m co
Hari( 'Report to Ranrplar Crate No
Co n Coated ' „o •17,4. (Printed Name)Ty Al.! f;m( 'y
4. C.Ly (l / L' Je�l f
a o ^ _ i i.e..iH,le-np,DO)can be,e x rded.aglow Page
Telephone No.
Actdre�s 01 �.
o Pe)
r'x stag Zip Code Presarval1Ve _"td PeraTaeterg' A , 1 , 1 3 2.
c 3 Final
�� ��•� I _ Nunrlhif Of DoMa�ws
_ 6
1_ � �'/�. g.cf 1 I 1.urpras aHN� P !" f— Cj 1 P J aYarwrt� rya;: ;��
N`- Project 2.NaOH 5.riCI .3 3 if f 1 .}� '•'� •:' _6 ` uuL
Name '� P 'A 3.H SO4 8.Sodium T ii uilair „* ',Z L II i I1I II dl 1,I1II 1 D
�' o P.O.Number • .a r X 11AP)tf:x �+
w��t E r v7 di.. S WC03I10
o . _Number 'i�� 2''' 3i 3Kr CM ci } 1t1 rn
m Sample ID r Descriptor' E
lei i e rl
WW irh' L m Q 1" ]
ICa Akachaarrptemay av ' 0 >==Solid r U 3 6 4-- -2 * _
y Start c
T Remerks/Cooler ID
3_1,-� is%c.� �� lit - z„ r
1! r�,lriah Al � z; V C .�7 • :k x. X 4 .>�� ,. 3,,;:4J,r,.24ti;rt
.,• W start
n 'Filo* G Y..%u. ' A D
^ yi 2-2.1 094, r-
- start r
,,"1 - ' ?t )� cn
fFnloh� ? �1 6)9 r'7 l �'I'I
Start _ - 71
i ia' i
v
0- Firer 3,2 t r Cry��, _ �
f i
o 9tin !
‘)/ Flash 1G it r i l X.
cn
tern Amato Time Required(Prior Ise approve'Lege Wed tor expedited TAT.) Sam eat Die poael (1)r PelurinlurtsISpAetty) PcxiuibleHazardIdentification r
Stardord r Rush(Please Specify) 0 Return:u Client Dsoouel Vr'Lab I r i FA i-He u•d ❑Ftrrrnatle 0 3tdn linter& 17 hriam o Wiliam
-� Date ITicre 1. iiecived Dy Date lime r
1'fiell nqubhed i ampler ( fs`P-) (7
2 Rednculshed b Date Time a.flecuived by Date Time ^� 1
!' „Ceti., — -e 'a/.31—LJ r- -31 _ ''J ` • `— 3/.�/tr !
3.FtellnquIshed n/J ,-.1 f el' Date Tim 3.Hc:.hwd by Date Time
/iiii
fle►ingLiyhed ay Cate lime 4.Lebora.k:y'Re lily e
S r r7-1 111CI
Note:All samples are retained for four weeks from LAB LSE ON Y it i.-
receipt unless other arrangements are made. l;xEived an icalGleCkj s n No n ae?ac1. fiooeparw tTe ,'� •C T41rp.eerrlc 1 n No
DISlyrrnvnoN:WHIM d YELLc W-itar:.Vn to frumnhary Wm 9e npletsl:PANK-r-feblekv.r Copy Document Nanbe. &IF:C wrt e1

8Ce m
< a'
,�d PACE ANALYTICAL SERVICES, LLC
v f n,,,,` iCu; ti'3nteryA Point Drive •West Columbia SC 29172 Number
5- m /___ -race/ll Analytical 'le F.. Shona tdcr. Ei.YJ-791.9/00 Fax.No,803-791-9111
o r '+:v.w_pacelabs.00m
N N 1
r C �+�+� r I CLote Ile,
* � �rclil .Hc�xx1 On SEmFIe• -�-^
c� o li lj -7hP i ) 1 ril/V'9elkte / i•
^I fir Nic-l.r'ram' Contact '• !r°/ [.�e (Printed Rams ! J
Address Telephone No. i 9e
o g Field Parameters(I.e.,pH,temp,DO)con be recorlen bnice
c m ).-r 1� J ,r?c•1 Email ___2-, of .)-
c`` City State I Zip Coda Preservative ,f;4;$ `,�, --1 - NAY-:r ar ihmlainurs
Ti co
n d .r iG''-(-r? .1.. 45.1 r 1 l4tpros, �.UNDO C {� 'crr.:ra T,y^F. P-Rt16G G•O
Alms
1V�
ro m Prefect tr--[ —""[_��__�.. —2.el COH 5.HC f I I - �,Iq ��1
v Name i'T?,(' TT 13 '- SO42 9.Sahli n Ih;�w,`aH -• 3I !t f I� J
N p' JJ �/ --
Project IN.0.Number Matrix ,v_,
W o ',lumber e a : " i OW Dvr >, d1 n i WC03110 m
CD yr R.srmlP ID i Deacnpton iCollectian Collodion . c a * IYW M1' C D
2 iConla-ers la each aamplrr nsty be Date(e) Time • ~ r �sdid Q e. ' r Z
?. � r D
� �_ comoinr+C on Dori u1e.) trri i.�ry) � � �— -
o y terrnik.1;cooler r0 r
P i9- Finish 3 N WICV r"• A
I —1
w Slur Y
PP.9 . :7 )vp• Fir, t3-1,-.?i (,)cra7 wit/ I x '
I
D
r
F1rrn3 .:) NI v • r�, C/)
cu r
•
3 �rc I rn
'inlsh I _-_ I Can s
Turn Around 17na Repeal l(Prlar lab amoral required for expedited TiiT.) Sample thspo,-vl QC Requirements(Specify) Foes ble Heta+d Idemiliontnn r
PeLStardar-d : Rush(Pleosc Epcolry► a Rahn Io flint 4 Ghp.sal b4 lib 11 hnn-Fazard u namable Li i Irrrem C,Pasco ❑Urancnot _ r
1.Relinlu_lied by I Sam et Dab: -lisle 1. Received by /f/ .{/- Date Toe 02.11::Iln:tt•'sned by ++ Ile/ True 2 Rerelv4ac' Date, Tirra -1.+
:). Relinquished b I2. _y,_� ~Dale Tr 9.Receivec by Oa:n um:'
1 /
4.Rellnyul:hed by i?rite True 4.Laboratory(ie ve eo . Ti 7 5
f
Note: All samples are retained for four weeks from LAS LSE ONLY L._,.../
receipt unless other arrangements are made. Received Oil lt (Crndtl Cl Ye P•Fk• ❑lcsPact HiceptTstre. •C Temp Eland E l I.Peto
DSTIW UT7ON:WHJTE 8 Yi9.4.0VAF durn Au Uzi*esAey WI),.aim;+ue!'.).YINN-Heins AP.1rt eV? 1 y,-) 3 t 1 Document isamtber:MFl1A7N r-0!

PACE ANALYTICAL SERVICES, LLC
�r� Samples Receipt Checklist(SRC)(MEd018C-15) Revised:51/79/2020
.' r eArt heal: Issuing Authority:Pace ENV-WOOL page I of 1
Sample Receipt Checklist (SRC)
Clieart: CITY OF` ONR(tr: by JRG2 � '3:1k3i2021 Lot O: H'C.Y37It1
Cooler ins ected :data: +
Mr2ns of receipt © Pace Client I IPS FedEx • Other: ^�
n Yes No I.Were melody sea.s1resent on the cooler?
Ycs No 0N.A1. If custody seals wcrc present were they intact rind unbroken?
pH Strip ID: ?f0-2595 __ Chlorine Strip Ill: 21-3ti tested by:n:u°
receipt %Solid Snap-Cup ID: NA
-sled temperature uponr p R
Original temperature upon rttceipt i Derived(Corrected) pe p
1.5 /:.S .:C I5.! r III -4c NA i'1A °C NA r t4A oC
Method:Eremperaotire Blank( Against Bottles IR Gun ID: 6 IR Gun Correction Factor; tl . °C
ethod of coolant: © Wet Tee LI Ice Packs ❑ D 0 None __
3, If temperature o''any cooler exceeded 6.0CC,was Project Manager Notified?
L
Yes ❑Teo DNA
PM was Noti cd by: phone/email i face-to-face(circle fine).
Ycs 10 No 1=,tNA 4. 15 the.commercial cxeirier's packing slip attached to this form.?
0 Yes -No 5. Were proper custody procedures(relinouished+receivecf)followed?
EiYtNi QNo 6. Were sample IDs listed on the COC?
Yea R No 7. Were sample IDS listed on all la_tnple containers?
Yes No _ 8. Was collection date&Lime listed on the COC1
'12 Yes [TINo 9. Was collection dale it time listed on all sample eronaincrs?
n Y;.s ❑No 10. Did all container label information(?D. dart;,time)agree with the COG?
ri,Yes ifiNo 11. Were tests to be performed listed on the COC7
12. Did all samples arrive in the proper container for such test and/or in good condition
©Yes ❑No, `(unhn ken, lids on,etc.)? _
©Ycs LINu 11.Was adequate sample volume available? _ 1
. Yes ❑No 14.1>were all samples received within IA the holding time or 48 holler,whichever comes firs..?
Ycs [Li No I .Were any salnp.cs conainers missing/excess(circle one)samples Na listed on COC?
DNA❑ 16.For VOA and RSTt-175 samples,were bubbles present:-"pea-size"('h•"or 6mm in diameter)
!❑Yes 1 Nooin ciw of the VOA vials?
d Yes L;No I NA I':. Were all LIRO/metals/nutrient samples received at t;pH of<2?
I Y , LI No LNA 18. Were all cyanide sa3inples received at a pH> 12 and sul&samples received,at a pH>9?.
,� 19. Were a:1 applicable N1-13/1142 1cyanidciphenul+625.1i6G8.? (i':6.Srnr/L)samples free of
V Yr_v ❑No DNA residual chlorine?
Q 20. Were client retnarkshequests(i.e.-equestcc dilutions,MS/MSD desiotta'ions,etc...)
©Yet QNo NA correctly transcribed from the COC. into the comment section in L1MS?
❑Yes lNo, 21. Was the quote number listed on the container label'?If yes.Quote# 141.
il*i
Sample Preservation (Must in completed:enw scny sampie(s)irco~-ec tly preserved or with hcnds xtce.)
ample(s) NA _ were received incorrectly preserved and were adjusted accordingly
it sample rcexivmg with NA mL of circle one:H2SO4,11NO3,HCI, NetOH using SR li NA .
'rime of preservation y-4 . If If more than one preservative is needed,pl_asc note in the:.oinments below.
Sarnple(s) NA wete received with bubbles>6 rem in diameter.
Samples(s) t'c^ _ were received with i'RC>0.5 mg+T.(1:"!t 19 is no)and were
adjusted accordingly in sample receiving with sodium th:osulfute(Na2S2O5)with Shealy tfT N^ .
i
SR barcode labels applies by: 1P3.1Date: mi.:19202i
•
Con,merits:
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.corn
D......GC..F GC

Analytical
Report of Analysis
City of Monroe
PO Box 69
Monroe, NC 28111
Attention: Kevin Keesler
Project Name: EFF PPA
Lot Number:X114079
Date Completed:10/18/2022
10/19/2022 6:15 AM
Approved and released by:
Project Manager II: Edward Barnett
AllAB
ANSI National Accreditation Board
ACCREDITED
TESTING LABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel: [phone] Fax: [phone] www.pacelabs.com

PACE ANALYTICAL SERVICES, LLC
SC DHEC No:32010001 NELAC No:E87653 NC DENR No:329 NC Field Parameters No:5639
Case Narrative
City of Monroe
Lot Number: X114079
This Report of Analysis contains the analytical result(s)for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non-Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 &SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
VOCs
Insufficient sample volume was provided to perform matrix spike/matrix spike duplicate (MS/MSD)for
analytical batch 55153. An LCS/LCSD was run in lieu of an MS/MSD.
The following sample had a pH <2: X114079-004.
Subcontracted Results
Cyanide was subcontracted to Pace Gulf Coast, LA for analysis. The results are included after the Pace
report of analysis.
Pace Analytical Services,LLC(formerly Shealy Environmetal Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172(803)791-9700 Fax[phone] www.pacelabs.com

PACE ANALYTICAL SERVICES, LLC
Sample Summary
City of Monroe
Lot Number: X114079
Sample Number Sample ID Matrix Date Sampled Date Received
001 EFF PPA Aqueous 09/14/2022 1007 09/14/2022
002 EFF PPA Aqueous 09/14/2022 0859 09/14/2022
003 EFF PPA Aqueous 09/14/2022 0858 09/14/2022
004 EFF PPA Aqueous 09/14/2022 0901 09/14/2022
005 EFF PPA Aqueous 09/14/2022 0900 09/14/2022
006 PPA EFF Aqueous 09/14/2022 0906 09/14/2022
007 PPA EFF DUP Aqueous 09/14/2022 0909 09/14/2022
008 FIELD BLANK Aqueous 09/14/2022 0905 09/14/2022
(8 samples)
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......'1-F L 1

PACE ANALYTICAL SERVICES, LLC
Detection Summary
City of Monroe
Lot Number: X114079
,a,,,rle Sample ID Matrix Parameter Method Result Q Units Page
001 EFF PPA Aqueous Hardness(total) SM 2340C- 150 mg/L 5
001 EFF PPA Aqueous Nitrate-Nitrite-N 353.2 37 mg/L 5
001 EFF PPA Aqueous Phosphorus 365.1 4.0 mg/L 5
001 EFF PPA Aqueous TDS SM 2540C- 530 mg/L 5
001 EFF PPA Aqueous Copper 200.8 6.9 ug/L 5
001 EFF PPA Aqueous Nickel 200.8 6.6 ug/L 5
001 EFF PPA Aqueous Zinc 200.8 50 ug/L 5
004 EFF PPA Aqueous Bromodichloromethane 624.1 5.5 ug/L 8
004 EFF PPA Aqueous Chloroform 624.1 6.3 ug/L 8
004 EFF PPA Aqueous Dibromochloromethane 624.1 2.1 ug/L 8
(10 detections)
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D.-,,A ..G 41

Description:EFF PPA Matrix:Aqueous
Date Sampled:09/14/2022 1007
Date Received:09/14/2022
Inorganic non-metals
In Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
350.1 (Ammonia-N )350.1 1 10/03/2022 1331 CMM 55875
1 (Hardness(to)SM 2340C-2011 1 10/12/2022 1145 JJM 56856
1 (Nitrate-Nitr)353.2 50 09/15/2022 1758 KKP 54283
1 (Phosphorus)365.1 5 09/21/2022 2236 DMA 54865
1 (TDS)SM 2540C-2011 1 09/20/2022 1741 CBP 54704
1 351.4 (TKN)351.2 1 10/04/2022 1951 DMA 10/04/2022 1411 55998
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Ammonia-N (gas diffusion) 350.1 ND 0.10 mg/L 2
Hardness(total) SM 2340C-2011 150 10 mg/L 1
Nitrate-Nitrite-N 353.2 37 1.0 mg/L 1
Phosphorus 7723-14-0 365.1 4.0 0.25 mg/L 1
TDS SM 2540C-2011 530 25 mg/L 1
TKN 351.2 ND 0.10 mg/L 1
ICP-MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 200.2 200.8 1 10/03/2022 0007 BNW 09/15/2022 0652 54219
2 200.2 200.8 1 10/05/2022 1908 BNW 09/15/2022 0652 54219
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Antimony 7440-36-0 200.8 ND 5.0 ug/L 1
Arsenic 7440-38-2 200.8 ND 2.0 ug/L 1
fllium 7440-41-7 200.8 ND 1.0 ug/L 1
mium 7440-43-9 200.8 ND 0.50 ug/L 1
Chromium 7440-47-3 200.8 ND 5.0 ug/L 1
Copper 7440-50-8 200.8 6.9 2.0 ug/L 1
Lead 7439-92-1 200.8 ND 2.0 ug/L 1
Nickel 7440-02-0 200.8 6.6 2.0 ug/L 1
Selenium 7782-49-2 200.8 ND 5.0 ug/L 2
Silver 7440-22-4 200.8 ND 1.0 ug/L 1
Thallium 7440-28-0 200.8 ND 2.0 ug/L 1
Zinc 7440-66-6 200.8 50 10 ug/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range Q=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
H=Out of holding time W=Reported on wet weight basis S=MS/MSD failure
F ialytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1,,,, vootage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Description:EFF PPA Matrix:Aqueous
Date Sampled:09/14/2022 0859
Date Received:09/14/2022
Inorganic non-metals
Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
(HEM (oil and) 1664E 1 09/27/2022 1712 CLJ 55414
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
HEM (oil and grease) 1664B ND 5.1 mg/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range Q=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
H=nut of holding time W=Reported on wet weight basis S=MS/MSD failure
P alytical Services,LLC (formerly Shealy Environmental Services,Inc.)
ltio vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Description:EFF PPA Matrix:Aqueous
Date Sampled:09/14/2022 0858
Date Received:09/14/2022
Inorganic non-metals
1 Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
(Phenolics)420.4 1 09/15/2022 1911 DMA 54307
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Phenolics 420.4 ND 0.0050 mg/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range Q=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
N-"..'of holding time W=Reported on wet weight basis S=MS/MSD failure
F ialytical Services,LLC (formerly Shealy Environmental Services,Inc.)
luti vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Description:EFF PPA Matrix:Aqueous
Date Sampled:09/14/2022 0901
Date Received:09/14/2022
Volatile Organic Compounds by GC/MS
n Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
624.1 624.1 1 09/24/20221742 BBW 55153
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Acrolein 107-02-8 624.1 ND 5.0 ug/L 1
' Acrylonitrile 107-13-1 624.1 ND 5.0 ug/L 1
Benzene 71-43-2 624.1 ND 1.0 ug/L 1
Bromodichloromethane 75-27-4 624.1 5.5 1.0 ug/L 1
Bromoform 75-25-2 624.1 ND 1.0 ug/L 1
Bromomethane(Methyl bromide) 74-83-9 624.1 ND 2.0 ug/L 1
Carbon tetrachloride 56-23-5 624.1 ND 1.0 ug/L 1
Chlorobenzene 108-90-7 624.1 ND 1.0 ug/L 1
Chloroethane 75-00-3 624.1 ND 2.0 ug/L 1
2-Chloroethylvinylether 110-75-8 624.1 ND 5.0 ug/L 1
Chloroform 67-66-3 624.1 6.3 1.0 ug/L 1
Chloromethane(Methyl chloride) 74-87-3 624.1 ND 2.0 ug/L 1
Dibromochloromethane 124-48-1 624.1 2.1 1.0 ug/L 1
1,2-Dichlorobenzene 95-50-1 624.1 ND 1.0 ug/L 1
1,3-Dichlorobenzene 541-73-1 624.1 ND 1.0 ug/L 1
1,4-Dichlorobenzene 106-46-7 624.1 ND 1.0 ug/L 1
Dichlorodifluoromethane 75-71-8 624.1 ND 2.0 ug/L 1
1,1-Dichloroethane 75-34-3 624.1 ND 1.0 ug/L 1
1,2-Dichloroethane 107-06-2 624.1 ND 1.0 ug/L 1
1,1-Dichloroethene 75-35-4 624.1 ND 1.0 ug/L 1
cis-1,2-Dichloroethene 156-59-2 624.1 ND 1.0 ug/L 1
-1,2-Dichloroethene 156-60-5 624.1 ND 1.0 ug/L 1
)ichloropropane 78-87-5 624.1 ND 1.0 ug/L 1
cts-1,3-Dichloropropene 10061-01-5 624.1 ND 1.0 ug/L 1
trans-1,3-Dichloropropene 10061-02-6 624.1 ND 1.0 ug/L 1
Ethylbenzene 100-41-4 624.1 ND 1.0 ug/L 1
Methylene chloride 75-09-2 624.1 ND 1.0 ug/L 1
1,1,2,2-Tetrachloroethane 79-34-5 624.1 ND 1.0 ug/L 1
Tetrachloroethene 127-18-4 624.1 ND 1.0 ug/L 1
Toluene 108-88-3 624.1 ND 1.0 ug/L 1
1,2,4-Trichlorobenzene 120-82-1 624.1 ND 1.0 ug/L 1
1,1,1-Trichloroethane 71-55-6 624.1 ND 1.0 ug/L 1
1,1,2-Trichloroethane 79-00-5 624.1 ND 1.0 ug/L 1
Trichloroethene 79-01-6 624.1 ND 1.0 ug/L 1
Trichlorofluoromethane 75-69-4 624.1 ND 1.0 ug/L 1
Vinyl chloride 75-01-4 624.1 ND 1.0 ug/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range 0=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
H=Out of holding time W=Reported on wet weight basis S=MS/MSD failure
P ialytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1,,,, „a,,tage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Description:EFF PPA Matrix:Aqueous
Date Sampled:09/14/2022 0901
Date Received:09/14/2022
Run 1 Acceptance
Rrtrrogate Q %Recovery Limits
omofluorobenzene 96 70-130
t,2-Dichloroethane-d4 96 70-130
Toluene-d8 96 70-130
LOG=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range Q=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
H=Out of holding time W=Reported on wet weight basis S=MS/MSD failure
F talytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1,,,, .a,itage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D„�.,n._c 41

Description:EFF PPA Matrix:Aqueous
Date Sampled:09/14/2022 0900
Date Received:09/14/2022
Semivolatile Organic Compounds by GC/MS
1 Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
625.1 625.1 1 09/22/2022 1024 SCD 09/19/2022 1534 54557
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Acenaphthene 83-32-9 625.1 ND 1.6 ug/L 1
Acenaphthylene 208-96-8 625.1 ND 1.6 ug/L 1
Anthracene 120-12-7 625.1 ND 1.6 ug/L 1
Benzidine 92-87-5 625.1 ND S 8.0 ug/L 1
Benzo(a)anthracene 56-55-3 625.1 ND 1.6 ug/L 1
Benzo(a)pyrene 50-32-8 625.1 ND 1.6 ug/L 1
Benzo(b)fluoranthene 205-99-2 625.1 ND 1.6 ug/L 1
Benzo(g,h,i)perylene 191-24-2 625.1 ND 1.6 ug/L 1
Benzo(k)fluoranthene 207-08-9 625.1 ND 1.6 ug/L 1
4-Bromophenyl phenyl ether 101-55-3 625.1 ND 1.6 ug/L 1
Butyl benzyl phthalate 85-68-7 625.1 ND 1.6 ug/L 1
bis(2-Chloro-1-methylethyl)ether 108-60-1 625.1 ND 1.6 ug/L 1
4-Chloro-3-methyl phenol 59-50-7 625.1 ND 1.6 ug/L 1
bis(2-Chloroethoxy)methane 111-91-1 625.1 ND 1.6 ug/L 1
bis(2-Chloroethyl)ether 111-44-4 625.1 ND 1.6 ug/L 1
2-Chloronaphthalene 91-58-7 625.1 ND 1.6 ug/L 1
2-Chlorophenol 95-57-8 625.1 ND 1.6 ug/L 1
4-Chlorophenyl phenyl ether 7005-72-3 625.1 ND 1.6 ug/L 1
Chrysene 218-01-9 625.1 ND 1.6 ug/L 1
Dibenzo(a,h)anthracene 53-70-3 625.1 ND 1.6 ug/L 1
3,3'-Dichlorobenzidine 91-94-1 625.1 ND 8.0 ug/L 1
"' " -)ichlorophenol 120-83-2 625.1 ND S 1.6 ug/L 1
tylphthalate 84-66-2 625.1 ND 1.6 ug/L 1
Dimethyl phthalate 131-11-3 625.1 ND 1.6 ug/L 1
2,4-Dimethylphenol 105-67-9 625.1 ND 1.6 ug/L 1
Di-n-butyl phthalate 84-74-2 625.1 ND 1.6 ug/L 1
4,6-Dinitro-2-methylphenol 534-52-1 625.1 ND S 8.0 ug/L 1
2,4-Dinitrophenol 51-28-5 625.1 ND S 8.0 ug/L 1
2,4-Dinitrotoluene 121-14-2 625.1 ND 3.2 ug/L 1
2,6-Dinitrotoluene 606-20-2 625.1 ND 3.2 ug/L 1
Di-n-octylphthalate 117-84-0 625.1 ND 1.6 ug/L 1
1,2-Diphenylhydrazine(as azobenzene) 103-33-3 625.1 ND 1.6 ug/L 1
bis(2-Ethylhexyl)phthalate 117-81-7 625.1 ND 8.0 ug/L 1
Fluoranthene 206-44-0 625.1 ND 1.6 ug/L 1
Fluorene 86-73-7 625.1 ND 1.6 ug/L 1
Hexachlorobenzene 118-74-1 625.1 ND 1.6 ug/L 1
Hexachlorobutadiene 87-68-3 625.1 ND 1.6 ug/L 1
Hexachlorocyclopentadiene 77-47-4 625.1 ND S 8.0 ug/L 1
Hexachloroethane 67-72-1 625.1 ND 1.6 ug/L 1
Indeno(1,2,3-c,d)pyrene 193-39-5 625.1 ND 1.6 ug/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range Q=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
14=n..1 of holding time W=Reported on wet weight basis S=MS/MSD failure
P talytical Services,LLC (formerly Shealy Environmental Services,Inc.)
luo vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D...... 1n,.f 41

Description:EFF PPA Matrix:Aqueous
Date Sampled:09/14/2022 0900
Date Received:09/14/2022
Semivolatile Organic Compounds by GC/MS
1 Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
625.1 625.1 1 09/22/2022 1024 SCD 09/19/2022 1534 54557
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Isophorone 78-59-1 625.1 ND 1.6 ug/L 1
Naphthalene 91-20-3 625.1 ND 1.6 ug/L 1
Nitrobenzene 98-95-3 625.1 ND 1.6 ug/L 1
2-Nitrophenol 88-75-5 625.1 ND 3.2 ug/L 1
4-Nitrophenol 100-02-7 625.1 ND S 8.0 ug/L 1
N-Nitrosodimethylamine 62-75-9 625.1 ND 1.6 ug/L 1
N-Nitrosodi-n-propylamine 621-64-7 625.1 ND 1.6 ug/L 1
N-Nitrosodiphenylamine(Diphenylamine) 86-30-6 625.1 ND 1.6 ug/L 1
Pentachlorophenol 87-86-5 625.1 ND S 8.0 ug/L 1
Phenanthrene 85-01-8 625.1 ND 1.6 ug/L 1
Phenol 108-95-2 625.1 ND 1.6 ug/L 1
Pyrene 129-00-0 625.1 ND 1.6 ug/L 1
1,2,4-Trichlorobenzene 120-82-1 625.1 ND 1.6 ug/L 1
2,4,6-Trichlorophenol 88-06-2 625.1 ND S 1.6 ug/L 1
Run 1 Acceptance
Surrogate Q %Recovery Limits
2-Fluorobiphenyl 64 37-129
2-Fluorophenol 70 24-127
Nitrobenzene-d5 82 38-127
Phenol-d5 77 28-128
Terphenyl-d14 72 10-148
i-Tribromophenol 76 41-144
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range Q=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
I'-^.••of holding time W=Reported on wet weight basis S=MS/MSD failure
P lalytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1 Ub vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D...... t 1 ..C 41

Description:PPA EFF Matrix: Aqueous
Date Sampled:09/14/2022 0906
Date Received:09/14/2022
Mercury (CVAFS)
n Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1631E 1 09/27/2022 0247 JMH 09/26/2022 0718 55176
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury(CVAFS) 7439-97-6 1631E ND 0.500 ng/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range Q=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
N=^,i1 of holding time W=Reported on wet weight basis S=MS/MSD failure
P talytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1 uo vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D...... 1'1..f L 1

Description:PPA EFF DUP Matrix:Aqueous
Date Sampled:09/14/2022 0909
Date Received:09/14/2022
Mercury (CVAFS)
n Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1631E 1 09/27/2022 0253 JMH 09/26/2022 0718 55176
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury(CVAFS) 7439-97-6 1631E ND 0.500 ng/L 1
LOG=Limit of Quantitation 8=Detected in the method blank E=Quantitation of compound exceeded the calibration range Q=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
N= of holding time W=Reported on wet weight basis S=MS/MSD failure
F talytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1..vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D....,. 1Z ,.C41

Description:FIELD BLANK Matrix:Aqueous
Date Sampled:09/14/2022 0905
Date Received:09/14/2022
Mercury (CVAFS)
in Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1631E 1 09/27/2022 0258 JMH 09/26/2022 0718 55176
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury(CVAFS) 7439-97-6 1631E ND 0.500 ng/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range 0=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
H=Out of holding time W=Reported on wet weight basis S=MS/MSD failure
F talytical Services,LLC (formerly Shealy Environmental Services,Inc.)
1„u valitage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D...... 1A ..G G1

QC Summary
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D...... 1 Q..!41

Inorganic non-metals - MB
Sample ID: XQ54283-001 Matrix: Aqueous
Batch:54283
Analytical Method:353.2
Parameter Result Q Dil LOQ Units Analysis Date
Nitrate-Nitrite-N ND 1 0.020 mg/L 09/15/2022 1728
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..-- 1 ,.F G1

Inorganic non-metals - LCS
Sample ID: XQ54283-002 Matrix: Aqueous
Batch:54283
Analytical Method: 353.2
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date
Nitrate-Nitrite-N 0.80 0.81 1 101 90-110 09/15/2022 1730
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
o....,, i1,.c4i

Inorganic non-metals - MB
Sample ID: XQ54307-001 Matrix: Aqueous
Batch:54307
Analytical Method:420.4
Parameter Result Q Dil LOQ Units Analysis Date
Phenolics ND 1 0.0050 mg/L 09/15/20221709
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D....,. 1 O-C G 1

Inorganic non-metals - LCS
Sample ID: XQ54307-002 Matrix: Aqueous
Batch:54307
Analytical Method:420.4
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date
Phenolics 0.050 0.054 1 108 90-110 09/15/20221714
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Inorganic non-metals - MB
Sample ID: XQ54704-001 Matrix: Aqueous
Batch:54704
Analytical Method:SM 2540C-2011
Parameter Result Q Dil LOQ Units Analysis Date
TDS ND 1 25 mg/L 09/20/2022 1741
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......1n,.c 41

Inorganic non-metals - LCS
Sample ID: XQ54704-002 Matrix: Aqueous
Batch:54704
Analytical Method:SM 2540C-2011
Spike
Amount Result %Rec
rarameter (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date
TDS 50 54 1 108 90-110 09/20/20221741
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
rime; Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D.,....11 ..0 L 1

Inorganic non-metals - MB
Sample ID: XQ54865-001 Matrix: Aqueous
Batch:54865
Analytical Method:365.1
Parameter Result Q Dil LOQ Units Analysis Date
Phosphorus ND 1 0.050 mg/L 09/21/2022 2147
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Inorganic non-metals - LCS
Sample ID: XQ54865-002 Matrix: Aqueous
Batch:54865
Analytical Method:365.1
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date
Phosphorus 1.0 1.0 1 103 90-110 09/21/2022 2150
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Inorganic non-metals - MB
Sample ID: XQ55875-001 Matrix: Aqueous
Batch:55875 Prep Method: 350.1
Analytical Method:350.1
Parameter Result Q DiI LOQ Units Analysis Date
Ammonia-N(gas diffusion) ND 1 0.10 mg/L 10/03/2022 1321
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..—IA ,.c 41

Inorganic non-metals - LCS
Sample ID: XQ55875-002 Matrix: Aqueous
Batch:55875 Prep Method: 350.1
Analytical Method:350.1
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date
Ammonia-N(gas diffusion) 2.5 2.6 1 104 90-110 10/03/2022 1323
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Inorganic non-metals - MB
Sample ID: XQ55998-001 Matrix: Aqueous
Batch:55998 Prep Method: 351.4
Analytical Method:351.2 Prep Date: 10/04/2022 1411
Parameter Result Q Dil LOQ Units Analysis Date
TKN ND 1 0.10 mg/L 10/04/2022 1935
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Inorganic non-metals - LCS
Sample ID: XQ55998-002 Matrix: Aqueous
Batch:55998 Prep Method: 351.4
Analytical Method:351.2 Prep Date: 10/04/2022 1411
Spike
Amount Result %Rec
Parameter (mg/L) (mg/L) Q Dil %Rec Limit Analysis Date
TKN 2.0 2.0 1 102 90-110 10/04/20221935
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..--1-7-f 41

Inorganic non-metals - MB
Sample ID: XQ56856-001 Matrix: Aqueous
Batch:56856
Analytical Method:SM 2340C-2011
Parameter Result Q Dil LOQ Units Analysis Date
Hardness(total) ND 1 10 mg/L 10/12/2022 0000
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..,.,.'1 Q,.F 41

Inorganic non-metals - LCS
Sample ID: XQ56856-002 Matrix: Aqueous
Batch:56856
Analytical Method:SM 2340C-2011
Spike
Amount Result %Rec
rarameter (mg/L) (mg/L) Q DiI %Rec Limit Analysis Date
Hardness(total) 100 99 1 99 90-110 10/12/2022 1145
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
in—cci

Inorganic non-metals - Duplicate
Sample ID: X114079-001DU Matrix: Aqueous
Batch:56856
Analytical Method: SM 2340C-2011
Sample
Amount Result %RPD
Parameter (mg/L) (mg/L) Q Dil % RPD Limit Analysis Date
Hardness(total) 150 150 1 2 6 20 10/12/2022 1145
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......2 n.. 1

Inorganic non-metals - MB
Sample ID: XQ55414-001 Matrix: Aqueous
Batch:55414
Analytical Method: 1664B
rarameter Result Q Dil LOQ Units Analysis Date
HEM(oil and grease) ND 1 5.0 mg/L 09/27/2022 1712
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......11 ..F 41

Inorganic non-metals - LCS
Sample ID: XQ55414-002 Matrix: Aqueous
Batch:55414
Analytical Method: 1664B
Spike
Amount Result %Rec
Parameter (mg/L) (mglL) Q Dil %Rec Limit Analysis Date
HEM (oil and grease) 40 38 1 95 78-114 09/27/2022 1712
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Volatile Organic Compounds by GC/MS - MB
Sample ID: XQ55153-001 Matrix: Aqueous
Batch:55153 Prep Method: 624.1
Analytical Method:624.1
rarameter Result Q Dil LOQ Units Analysis Date
Acrolein ND 1 5.0 ug/L 09/24/2022 1438
Acrylonitrile ND 1 5.0 ug/L 09/24/2022 1438
Benzene ND 1 1.0 ug/L 09/24/2022 1438
Bromodichloromethane ND 1 1.0 ug/L 09/24/2022 1438
' Bromoform ND 1 1.0 ug/L 09/24/2022 1438
Bromomethane(Methyl bromide) ND 1 2.0 ug/L 09/24/2022 1438
Carbon tetrachloride ND 1 1.0 ug/L 09/24/2022 1438
Chlorobenzene ND 1 1.0 ug/L 09/24/2022 1438
Chloroethane ND 1 2.0 ug/L 09/24/2022 1438
2-Chloroethylvinylether ND 1 5.0 ug/L 09/24/2022 1438
Chloroform ND 1 1.0 ug/L 09/24/2022 1438
Chloromethane(Methyl chloride) ND 1 2.0 ug/L 09/24/2022 1438
Dibromochloromethane ND 1 1.0 ug/L 09/24/2022 1438
1,2-Dichlorobenzene ND 1 1.0 ug/L 09/24/2022 1438
1,3-Dichlorobenzene ND 1 1.0 ug/L 09/24/2022 1438
1,4-Dichlorobenzene ND 1 1.0 ug/L 09/24/2022 1438
Dichlorodifluoromethane ND 1 2.0 ug/L 09/24/2022 1438
1,1-Dichloroethane ND 1 1.0 ug/L 09/24/2022 1438
1,2-Dichloroethane ND 1 1.0 ug/L 09/24/2022 1438
1,1-Dichloroethene ND 1 1.0 ug/L 09/24/2022 1438
cis-1,2-Dichloroethene ND 1 1.0 ug/L 09/24/2022 1438
trans-1,2-Dichloroethene ND 1 1.0 ug/L 09/24/2022 1438
1,2-Dichloropropane ND 1 1.0 ug/L 09/24/2022 1438
1,3-Dichloropropene ND 1 1.0 ug/L 09/24/2022 1438
s-1,3-Dichloropropene ND 1 1.0 ug/L 09/24/2022 1438
Ethylbenzene ND 1 1.0 ug/L 09/24/2022 1438
Methylene chloride ND 1 1.0 ug/L 09/24/2022 1438
1,1,2,2-Tetrachloroethane ND 1 1.0 ug/L 09/24/2022 1438
Tetrachloroethene ND 1 1.0 ug/L 09/24/2022 1438
Toluene ND 1 1.0 ug/L 09/24/2022 1438
1,2,4-Trichlorobenzene ND 1 1.0 ug/L 09/24/2022 1438
1,1,1-Trichloroethane ND 1 1.0 ug/L 09/24/2022 1438
1,1,2-Trichloroethane ND 1 1.0 ug/L 09/24/2022 1438
Trichloroethene ND 1 1.0 ug/L 09/24/2022 1438
Trichlorofluoromethane ND 1 1.0 ug/L 09/24/2022 1438
Vinyl chloride ND 1 1.0 ug/L 09/24/2022 1438
Acceptance
Surrogate Q %Rec Limit
Bromofluorobenzene 97 70-130
1,2-Dichloroethane-d4 96 70-130
Toluene-d8 97 70-130
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......]7 ..{'41

Volatile Organic Compounds by GC/MS - LCS
Sample ID: XQ55153-002 Matrix: Aqueous
Batch:55153 Prep Method: 624.1
Analytical Method:624.1
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Oil %Rec Limit Analysis Date
Acrolein 200 190 1 93 60-140 09/24/2022 1329
Acrylonitrile 40 35 1 86 60-140 09/24/2022 1329
Benzene 20 17 1 87 65-135 09/24/2022 1329
Bromodichloromethane 20 18 1 90 65-135 09/24/2022 1329
Bromoform 20 18 1 88 70-130 09/24/2022 1329
Bromomethane(Methyl bromide) 20 16 1 81 15-185 09/24/2022 1329
Carbon tetrachloride 20 18 1 89 70-130 09/24/2022 1329
Chlorobenzene 20 17 1 87 65-135 09/24/2022 1329
Chloroethane 20 17 1 83 40-160 09/24/2022 1329
2-Chloroethylvinylether 20 20 1 100 1-225 09/24/2022 1329
Chloroform 20 19 1 93 70-135 09/24/2022 1329
Chloromethane(Methyl chloride) 20 17 1 86 1-205 09/24/2022 1329
Dibromochloromethane 20 18 1 88 53-149 09/24/2022 1329
1,2-Dichlorobenzene 20 17 1 87 65-135 09/24/2022 1329
1,3-Dichlorobenzene 20 17 1 86 70-130 09/24/2022 1329
1,4-Dichlorobenzene 20 16 1 80 65-135 09/24/2022 1329
Dichlorodifluoromethane 20 15 1 74 60-140 09/24/2022 1329
1,1-Dichloroethane 20 18 1 92 70-130 09/24/2022 1329
1,2-Dichloroethane 20 18 1 92 70-130 09/24/2022 1329
1,1-Dichloroethene 20 17 1 85 50-150 09/24/2022 1329
cis-1,2-Dichloroethene 20 19 1 93 70-130 09/24/2022 1329
trans-1,2-Dichloroethene 20 17 1 86 70-130 09/24/2022 1329
1,2-Dichloropropane 20 20 1 99 35-165 09/24/2022 1329
1,3-Dichloropropene 20 19 1 97 25-175 09/24/2022 1329
s-1,3-Dichloropropene 20 19 1 95 50-150 09/24/2022 1329
Ethylbenzene 20 17 1 87 60-140 09/24/2022 1329
Methylene chloride 20 16 1 82 60-140 09/24/2022 1329
1,1,2,2-Tetrachloroethane 20 18 1 92 60-140 09/24/2022 1329
Tetrachloroethene 20 17 1 87 70-130 09/24/2022 1329
Toluene 20 18 1 89 70-130 09/24/2022 1329
1,2,4-Trichlorobenzene 20 16 1 79 60-140 09/24/2022 1329
1,1,1-Trichloroethane 20 18 1 90 70-130 09/24/2022 1329
1,1,2-Trichloroethane 20 17 1 84 70-130 09/24/2022 1329
Trichloroethene 20 17 1 87 65-135 09/24/2022 1329
Trichlorofluoromethane 20 19 1 93 50-150 09/24/2022 1329
Vinyl chloride 20 18 1 91 5-195 09/24/2022 1329
Acceptance
Surrogate Q %Rec Limit
Bromofluorobenzene 98 70-130
1,2-Dichloroethane-d4 93 70-130 i
Toluene-d8 92 70-130
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..,...2A ..f 41

Volatile Organic Compounds by GC/MS - LCSD
Sample ID: XQ55153-003 Matrix: Aqueous
Batch:55153 Prep Method: 624.1
Analytical Method:624.1
Spike
Amount Result %Rec %RPD
Parameter (ug/L) (ug/L) Q Dil %Rec %RPD Limit Limit Analysis Date
Acrolein 200 200 1 98 4.7 60-140 20 09/24/2022 1352
Acrylonitrile 40 38 1 94 8.5 60-140 20 09/24/2022 1352
Benzene 20 19 1 94 7.0 65-135 20 09/24/2022 1352
Bromodichloromethane 20 19 1 97 7.1 65-135 20 09/24/2022 1352
Bromoform 20 19 1 94 6.5 70-130 20 09/24/2022 1352
Bromomethane(Methyl bromide) 20 19 1 93 14 15-185 20 09/24/2022 1352
Carbon tetrachloride 20 19 1 96 7.5 70-130 20 09/24/2022 1352
Chlorobenzene 20 19 1 96 10 65-135 20 09/24/2022 1352
Chloroethane 20 17 1 85 2.0 40-160 20 09/24/2022 1352
2-Chloroethylvinylether 20 21 1 107 6.9 1-225 20 09/24/2022 1352
Chloroform 20 19 1 97 4.6 70-135 20 09/24/2022 1352
Chloromethane(Methyl chloride) 20 19 1 94 8.9 1-205 20 09/24/2022 1352
Dibromochloromethane 20 19 1 96 9.3 53-149 20 09/24/2022 1352
1,2-Dichlorobenzene 20 19 1 97 11 65-135 20 09/24/2022 1352
1,3-Dichlorobenzene 20 19 1 93 7.3 70-130 20 09/24/2022 1352
1,4-Dichlorobenzene 20 18 1 89 10 65-135 20 09/24/2022 1352
Dichlorodifluoromethane 20 14 1 70 5.4 60-140 20 09/24/2022 1352
1,1-Dichloroethane 20 20 1 100 8.4 70-130 20 09/24/2022 1352
1,2-Dichloroethane 20 20 1 100 8.3 70-130 20 09/24/2022 1352
i 1,1-Dichloroethene 20 18 1 89 4.9 50-150 20 09/24/2022 1352
cis-1,2-Dichloroethene 20 20 1 100 7.9 70-130 20 09/24/2022 1352
trans-1,2-Dichloroethene 20 19 1 93 7.2 70-130 20 09/24/2022 1352
1,2-Dichloropropane 20 21 1 105 5.7 35-165 20 09/24/2022 1352
1,3-Dichloropropene 20 21 1 103 5.7 25-175 20 09/24/2022 1352
s-1,3-Dichloropropene 20 20 1 101 6.9 50-150 20 09/24/2022 1352
Ethylbenzene 20 19 1 94 7.9 60-140 20 09/24/2022 1352
Methylene chloride 20 16 1 82 0.018 60-140 20 09/24/2022 1352
1,1,2,2-Tetrachloroethane 20 20 1 102 10 60-140 20 09/24/2022 1352
Tetrachloroethene 20 19 1 95 9.0 70-130 20 09/24/2022 1352
Toluene 20 19 1 97 8.0 70-130 20 09/24/2022 1352
1,2,4-Trichlorobenzene 20 17 1 87 9.3 60-140 20 09/24/2022 1352
1,1,1-Trichloroethane 20 19 1 95 4.8 70-130 20 09/24/2022 1352
1,1,2-Trichloroethane 20 19 1 94 11 70-130 20 09/24/2022 1352
Trichloroethene 20 19 1 93 7.0 65-135 20 09/24/2022 1352
Trichlorofluoromethane 20 16 1 82 13 50-150 20 09/24/2022 1352
Vinyl chloride 20 18 1 90 1.4 5-195 20 09/24/2022 1352
Acceptance
Surrogate Q %Rec Limit
Bromofluorobenzene 96 70-130
1,2-Dichloroethane-d4 93 70-130
Toluene-d8 93 70-130
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D....,.'2 C,.G 41

Semivolatile Organic Compounds by GC/MS - MB
Sample ID: XQ54557-001 Matrix: Aqueous
Batch:54557 Prep Method: 625.1
Analytical Method:625.1 Prep Date: 09/19/2022 1534
Parameter Result Q Oil LOQ Units Analysis Date
Acenaphthene ND 1 1.6 ug/L 09/22/2022 0131
Acenaphthylene ND 1 1.6 ug/L 09/22/2022 0131
Anthracene ND 1 1.6 ug/L 09/22/2022 0131
Benzidine ND 1 8.0 ug/L 09/22/2022 0131
Benzo(a)anthracene ND 1 1.6 ug/L 09/22/2022 0131
Benzo(a)pyrene ND 1 1.6 ug/L 09/22/2022 0131
Benzo(b)fluoranthene ND 1 1.6 ug/L 09/22/2022 0131
Benzo(g,h,i)perylene ND 1 1.6 ug/L 09/22/2022 0131
Benzo(k)fluoranthene ND 1 1.6 ug/L 09/22/2022 0131
4-Bromophenyl phenyl ether ND 1 1.6 ug/L 09/22/2022 0131
Butyl benzyl phthalate ND 1 1.6 ug/L 09/22/2022 0131
bis(2-Chloro-1-methylethyl)ether ND 1 1.6 ug/L 09/22/2022 0131
4-Chloro-3-methyl phenol ND 1 1.6 ug/L 09/22/2022 0131
bis(2-Chloroethoxy)methane ND 1 1.6 ug/L 09/22/2022 0131
bis(2-Chloroethyl)ether ND 1 1.6 ug/L 09/22/2022 0131
2-Chloronaphthalene ND 1 1.6 ug/L 09/22/2022 0131
2-Chlorophenol ND 1 1.6 ug/L 09/22/2022 0131
4-Chlorophenyl phenyl ether ND 1 1.6 ug/L 09/22/2022 0131
Chrysene ND 1 1.6 ug/L 09/22/2022 0131
Dibenzo(a,h)anthracene ND 1 1.6 ug/L 09/22/2022 0131
3,3'-Dichlorobenzidine ND 1 8.0 ug/L 09/22/2022 0131
2,4-Dichlorophenol ND 1 1.6 ug/L 09/22/2022 0131
Diethylphthalate ND 1 1.6 ug/L 09/22/2022 0131
ethyl phthalate ND 1 1.6 ug/L 09/22/2022 0131
Dimethylphenol ND 1 1.6 ug/L 09/22/2022 0131
Di-n-butyl phthalate ND 1 1.6 ug/L 09/22/2022 0131
4,6-Dinitro-2-methylphenol ND 1 8.0 ug/L 09/22/2022 0131
2,4-Dinitrophenol ND 1 8.0 ug/L 09/22/2022 0131
2,4-Dinitrotoluene ND 1 3.2 ug/L 09/22/2022 0131
2,6-Dinitrotoluene ND 1 3.2 ug/L 09/22/2022 0131
Di-n-octylphthalate ND 1 1.6 ug/L 09/22/2022 0131
1,2-Diphenylhydrazine(as azobenzene) ND 1 1.6 ug/L 09/22/2022 0131
bis(2-Ethylhexyl)phthalate ND 1 8.0 ug/L 09/22/2022 0131
Fluoranthene ND 1 1.6 ug/L 09/22/2022 0131
Fluorene ND 1 1.6 ug/L 09/22/2022 0131
Hexachlorobenzene ND 1 1.6 ug/L 09/22/2022 0131
Hexachlorobutadiene ND 1 1.6 ug/L 09/22/2022 0131
Hexachlorocyclopentadiene ND 1 8.0 ug/L 09/22/2022 0131
Hexachloroethane ND 1 1.6 ug/L 09/22/2022 0131
Indeno(1,2,3-c,d)pyrene ND 1 1.6 ug/L 09/22/2022 0131
Isophorone ND 1 1.6 ug/L 09/22/2022 0131
Naphthalene ND 1 1.6 ug/L 09/22/2022 0131
Nitrobenzene ND 1 1.6 ug/L 09/22/2022 0131
2-Nitrophenol ND 1 3.2 ug/L 09/22/2022 0131
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) I
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D.,....14,.F AI

Semivolatile Organic Compounds by GC/MS - MB
Sample ID: XQ54557-001 Matrix: Aqueous
Batch:54557 Prep Method: 625.1
Analytical Method:625.1 Prep Date: 09/19/2022 1534
rarameter Result Q Dil LOQ Units Analysis Date
i 4-Nitrophenol ND 1 8.0 ug/L 09/22/2022 0131
N-Nitrosodimethylamine ND 1 1.6 ug/L 09/22/2022 0131
N-Nitrosodi-n-propylamine ND 1 1.6 ug/L 09/22/2022 0131
N-Nitrosodiphenylamine(Diphenylamine)ND 1 1.6 ug/L 09/22/2022 0131
Pentachlorophenol ND 1 8.0 ug/L 09/22/2022 0131
Phenanthrene ND 1 1.6 ug/L 09/22/2022 0131
Phenol ND 1 1.6 ug/L 09/22/2022 0131
Pyrene ND 1 1.6 ug/L 09/22/2022 0131
1,2,4-Trichlorobenzene ND 1 1.6 ug/L 09/22/2022 0131
2,4,6-Trichlorophenol ND 1 1.6 ug/L 09/22/2022 0131
Acceptance
Surrogate Q %Rec Limit
2-Fluorobiphenyl 77 37-129
2-Fluorophenol 57 24-127
Nitrobenzene-d5 103 38-127
Phenol-d5 77 28-128
Terphenyl-d14 86 10-148
2,4,6-Tribromophenol 80 41-144
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria *=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Semivolatile Organic Compounds by GC/MS - LCS
Sample ID: XQ54557-002 Matrix: Aqueous
Batch:54557 Prep Method: 625.1
Analytical Method:625.1 Prep Date: 09/19/2022 1534
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil %Rec Limit Analysis Date
Acenaphthene 20 16 1 78 47-145 09/22/2022 0155
Acenaphthylene 20 15 1 77 33-145 09/22/2022 0155
Anthracene 20 16 1 78 27-133 09/22/2022 0155
Benzidine 100 12 1 12 1-150 09/22/2022 0155
Benzo(a)anthracene 20 16 1 78 33-143 09/22/2022 0155
Benzo(a)pyrene 20 15 1 75 17-163 09/22/2022 0155
Benzo(b)fluoranthene 20 17 1 83 24-159 09/22/2022 0155
Benzo(g,h,i)perylene 20 17 1 83 1-219 09/22/2022 0155
Benzo(k)fluoranthene 20 17 1 84 11-162 09/22/2022 0155
4-Bromophenyl phenyl ether 20 15 1 76 53-127 09/22/2022 0155
Butyl benzyl phthalate 20 21 1 103 1-152 09/22/2022 0155
bis(2-Chloro-1-methylethyl)ether 20 29 1 143 36-166 09/22/2022 0155
4-Chloro-3-methyl phenol 20 18 1 89 22-147 09/22/2022 0155
bis(2-Chloroethoxy)methane 20 20 1 100 33-184 09/22/2022 0155
bis(2-Chloroethyl)ether 20 25 1 127 12-158 09/22/2022 0155
2-Chloronaphthalene 20 15 1 74 60-120 09/22/2022 0155
2-Chlorophenol 20 14 1 70 23-134 09/22/2022 0155
4-Chlorophenyl phenyl ether 20 15 1 73 25-158 09/22/2022 0155
Chrysene 20 16 1 79 17-168 09/22/2022 0155
Dibenzo(a,h)anthracene 20 17 1 84 1-227 09/22/2022 0155
3,3'-Dichlorobenzidine 20 9.2 1 46 1-262 09/22/2022 0155
2,4-Dichlorophenol 20 13 1 65 39-135 09/22/2022 0155
Diethylphthalate 20 18 1 92 1-120 09/22/2022 0155
ethyl phthalate 20 17 1 86 1-120 09/22/2022 0155
_,. Dimethylphenol 20 15 1 74 32-120 09/22/2022 0155
Di-n-butyl phthalate 20 19 1 97 1-120 09/22/2022 0155
4,6-Dinitro-2-methylphenol 20 16 1 81 1-181 09/22/2022 0155
2,4-Dinitrophenol 40 28 1 69 1-191 09/22/2022 0155
2,4-Dinitrotoluene 20 16 1 81 39-139 09/22/2022 0155
2,6-Dinitrotoluene 20 16 1 79 50-158 09/22/2022 0155
Di-n-octylphthalate 20 21 1 106 4-146 09/22/2022 0155
1,2-Diphenylhydrazine(as azobenzene) 20 23 1 117 1-150 09/22/2022 0155
bis(2-Ethylhexyl)phthalate 20 21 1 107 8-158 09/22/2022 0155
Fluoranthene 20 15 1 76 26-137 09/22/2022 0155
Fluorene 20 15 1 75 59-121 09/22/2022 0155
Hexachlorobenzene 20 14 1 71 1-152 09/22/2022 0155
Hexachlorobutadiene 20 10 1 52 24-120 09/22/2022 0155
Hexachlorocyclopentadiene 100 31 1 31 1-150 09/22/2022 0155
Hexachloroethane 20 15 1 73 40-120 09/22/2022 0155
Indeno(1,2,3-c,d)pyrene 20 16 1 78 1-171 09/22/2022 0155
Isophorone 20 20 1 101 21-196 09/22/2022 0155
Naphthalene 20 14 1 71 21-133 09/22/2022 0155
Nitrobenzene 20 18 1 91 35-180 09/22/2022 0155
2-Nitrophenol 20 15 1 74 29-182 09/22/2022 0155
LOQ=Limit of Quantitalion ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) I
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Semivolatile Organic Compounds by GC/MS - LCS
Sample ID: XQ54557-002 Matrix: Aqueous
Batch:54557 Prep Method: 625.1
Analytical Method:625.1 Prep Date: 09/19/2022 1534
Spike
Amount Result %Rec
Parameter (ugiL) (ug/L) Q DII %Rec Limit Analysis Date
4-Nitrophenol 40 43 1 107 1-132 09/22/2022 0155
N-Nitrosodimethylamine 20 22 1 110 1-150 09/22/2022 0155
N-Nitrosodi-n-propylamine 20 25 1 126 1-230 09/22/2022 0155
N-Nitrosodiphenylamine(Diphenylamine) 20 16 1 78 1-150 09/22/2022 0155
Pentachlorophenol 40 30 1 75 14-176 09/22/2022 0155
Phenanthrene 20 16 1 78 54-120 09/22/2022 0155
Phenol 20 17 1 83 5-120 09/22/2022 0155
Pyrene 20 16 1 80 52-120 09/22/2022 0155
1,2,4-Trichlorobenzene 20 11 1 54 44-142 09/22/2022 0155
2,4,6-Trichlorophenol 20 15 1 76 37-144 09/22/2022 0155
Surrogate Q %Rec Acceptance Limit
2-Fluorobiphenyl 67 37-129
2-Fluorophenol 49 24-127
Nitrobenzene-d5 85 38-127
Phenol-d5 71 28-128
Terphenyl-d14 75 10-148
2,4,6-Tribromophenol 73 41-144
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

Semivolatile Organic Compounds by GC/MS - MS
Sample ID: X114079-005MS Matrix: Aqueous
Batch:54557 Prep Method: 625.1
Analytical Method:625.1 Prep Date: 09/19/2022 1534
Sample Spike
Amount Amount Result %Rec
Parameter (ug/L) (ug/L) (ug/L) Q Dil %Rec Limit Analysis Date
Acenaphthene ND 40 31 1 78 47-145 09/22/2022 1112
Acenaphthylene ND 40 32 1 79 33-145 09/22/2022 1112
Anthracene ND 40 31 1 76 27-133 09/22/2022 1112
Benzidine ND 200 ND N 1 0.00 1-150 09/22/2022 1112
Benzo(a)anthracene ND 40 30 1 76 33-143 09/22/2022 1112
Benzo(a)pyrene ND 40 29 1 72 17-163 09/22/2022 1112
Benzo(b)fluoranthene ND 40 32 1 80 24-159 09/22/2022 1112
Benzo(g,h,i)perylene ND 40 26 1 65 1-219 09/22/2022 1112
Benzo(k)fluoranthene ND 40 31 1 78 11-162 09/22/2022 1112
4-Bromophenyl phenyl ether ND 40 32 1 79 53-127 09/22/2022 1112
Butyl benzyl phthalate ND 40 42 1 104 1-152 09/22/2022 1112
bis(2-Chloro-1-methylethyl)ether ND 40 50 1 126 36-166 09/22/2022 1112
4-Chloro-3-methyl phenol ND 40 35 1 88 22-147 09/22/2022 1112
bis(2-Chloroethoxy)methane ND 40 38 1 95 33-184 09/22/2022 1112
bis(2-Chloroethyl)ether ND 40 44 1 109 12-158 09/22/2022 1112
2-Chloronaphthalene ND 40 30 1 76 60-120 09/22/2022 1112
2-Chlorophenol ND 40 28 1 70 23-134 09/22/2022 1112
4-Chlorophenyl phenyl ether ND 40 30 1 74 25-158 09/22/2022 1112
Chrysene ND 40 31 1 79 17-168 09/22/2022 1112
Dibenzo(a,h)anthracene ND 40 29 1 71 1-227 09/22/2022 1112
3,3'-Dichlorobenzidine ND 40 22 1 56 1-262 09/22/2022 1112
2,4-Dichlorophenol ND 40 27 1 68 39-135 09/22/2022 1112
Diethylphthalate ND 40 38 1 94 1-120 09/22/2022 1112
'ethyl phthalate ND 40 35 1 88 1-120 09/22/2022 1112
_,. Dimethylphenol ND 40 36 1 90 32-120 09/22/2022 1112
Di-n-butyl phthalate ND 40 40 1 101 1-120 09/22/2022 1112
4,6-Dinitro-2-methylphenol ND 40 22 1 54 1-181 09/22/2022 1112
2,4-Dinitrophenol ND 80 32 1 40 1-191 09/22/2022 1112
2,4-Dinitrotoluene ND 40 34 1 85 39-139 09/22/2022 1112
2,6-Dinitrotoluene ND 40 32 1 80 50-158 09/22/2022 1112
Di-n-octylphthalate ND 40 35 1 88 4-146 09/22/2022 1112
1,2-Diphenylhydrazine(as azobenzene) ND 40 44 1 111 1-150 09/22/2022 1112
bis(2-Ethylhexyl)phthalate ND 40 36 1 91 8-158 09/22/2022 1112
Fluoranthene ND 40 31 1 77 26-137 09/22/2022 1112
Fluorene ND 40 30 1 76 59-121 09/22/2022 1112
Hexachlorobenzene ND 40 30 1 75 1-152 09/22/2022 1112
Hexachlorobutadiene ND 40 23 1 59 24-120 09/22/2022 1112
Hexachlorocyclopentadiene ND 200 54 1 27 1-150 09/22/2022 1112
Hexachloroethane ND 40 29 1 73 40-120 09/22/2022 1112
Indeno(1,2,3-c,d)pyrene ND 40 27 1 67 1-171 09/22/2022 1112
Isophorone ND 40 38 1 95 21-196 09/22/2022 1112
Naphthalene ND 40 29 1 72 21-133 09/22/2022 1112
Nitrobenzene ND 40 36 1 90 35-180 09/22/2022 1112
2-Nitrophenol ND 40 30 1 76 29-182 09/22/2022 1112
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria *=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
o.... nn..c�i

Semivolatile Organic Compounds by GC/MS - MS
Sample ID: X114079-005MS Matrix: Aqueous
Batch:54557 Prep Method: 625.1
Analytical Method:625.1 Prep Date: 09/19/2022 1534
Sample Spike
Amount Amount Result %Rec
Parameter (ug/L) (ug/L) (ug/L) Q Dil %Rec Limit Analysis Date
4-Nitrophenol ND 80 83 1 103 1-132 09/22/2022 1112
N-Nitrosodimethylamine ND 40 45 1 112 1-150 09/22/2022 1112
N-Nitrosodi-n-propylamine ND 40 45 1 112 1-230 09/22/2022 1112
N-Nitrosodiphenylamine(Diphenylamine) ND 40 37 1 92 1-150 09/22/2022 1112
Pentachlorophenol ND 80 63 1 79 14-176 09/22/2022 1112
Phenanthrene ND 40 32 1 81 54-120 09/22/2022 1112
Phenol ND 40 33 1 84 5-120 09/22/2022 1112
Pyrene ND 40 33 1 82 52-120 09/22/2022 1112
1,2,4-Trichlorobenzene ND 40 25 1 61 44-142 09/22/2022 1112
2,4,6-Trichlorophenol ND 40 30 1 75 37-144 09/22/2022 1112
Surrogate Q %Rec Acceptance
Limit
2-Fluorobiphenyl 70 37-129
2-Fluorophenol 55 24-127
Nitrobenzene-d5 87 38-127
Phenol-d5 74 28-128
Terphenyl-d14 77 10-148
2,4,6-Tribromophenol 76 41-144
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D.,....A 1 ,.0 4 1

Semivolatile Organic Compounds by GC/MS - MSD
Sample ID: X114079-005MD Matrix: Aqueous
Batch:54557 Prep Method: 625.1
Analytical Method:625.1 Prep Date: 09/19/2022 1534
Sample Spike
Amount Amount Result %Rec %RPD
Parameter (ug/L) (ug/L) (ug/L) Q Oil %Rec %RPD Limit Limit Analysis Date
Acenaphthene ND 40 32 1 80 3.1 47-145 48 09/22/2022 1201
Acenaphthylene ND 40 32 1 81 2.5 33-145 74 09/22/2022 1201
Anthracene ND 40 32 1 81 6.3 27-133 66 09/22/2022 1201
Benzidine ND 200 26 + 1 13 200 1-150 40 09/22/2022 1201
Benzo(a)anthracene ND 40 33 1 82 7.6 33-143 53 09/22/2022 1201
Benzo(a)pyrene ND 40 32 1 79 10 17-163 72 09/22/2022 1201
Benzo(b)fluoranthene ND 40 37 1 93 14 24-159 71 09/22/2022 1201
Benzo(g,h,i)perylene ND 40 22 1 54 19 1-219 97 09/22/2022 1201
Benzo(k)fluoranthene ND 40 36 1 89 14 11-162 63 09/22/2022 1201
4-Bromophenyl phenyl ether ND 40 32 1 80 1.2 53-127 43 09/22/2022 1201
Butyl benzyl phthalate ND 40 44 1 111 6.2 1-152 60 09/22/2022 1201
bis(2-Chloro-1-methylethyl)ether ND 40 55 1 136 8.1 36-166 76 09/22/2022 1201
4-Chloro-3-methyl phenol ND 40 22 1 54 48 22-147 73 09/22/2022 1201
bis(2-Chloroethoxy)methane ND 40 41 1 103 8.1 33-184 54 09/22/2022 1201
bis(2-Chloroethyl)ether ND 40 49 1 122 11 12-158 108 09/22/2022 1201
2-Chloronaphthalene ND 40 30 1 74 2.3 60-120 24 09/22/2022 1201
2-Chlorophenol ND 40 15 + 1 37 62 23-134 61 09/22/2022 1201
4-Chlorophenyl phenyl ether ND 40 31 1 77 4.0 25-158 61 09/22/2022 1201
Chrysene ND 40 33 1 83 5.8 17-168 87 09/22/2022 1201
Dibenzo(a,h)anthracene ND 40 25 1 63 13 1-227 126 09/22/2022 1201
3,3'-Dichlorobenzidine ND 40 35 1 88 45 1-262 108 09/22/2022 1201
2,4-Dichlorophenol ND 40 10 N,+ 1 26 90 39-135 50 09/22/2022 1201
Diethylphthalate ND 40 39 1 98 3.6 1-120 100 09/22/2022 1201
ethyl phthalate ND 40 36 1 89 1.8 1-120 183 09/22/2022 1201
Dimethylphenol ND 40 27 1 67 29 32-120 58 09/22/2022 1201
Di-n-butyl phthalate ND 40 42 1 104 3.2 1-120 47 09/22/2022 1201
4,6-Dinitro-2-methylphenol ND 40 ND N 1 0.00 200 1-181 203 09/22/2022 1201
2,4-Dinitrophenol ND 80 ND N,+ 1 0.00 200 1-191 132 09/22/2022 1201
2,4-Dinitrotoluene ND 40 33 1 83 1.7 39-139 42 09/22/2022 1201
2,6-Dinitrotoluene ND 40 32 1 80 0.47 50-158 48 09/22/2022 1201
Di-n-octylphthalate ND 40 43 1 107 20 4-146 69 09/22/2022 1201
1,2-Diphenylhydrazine(as azobenzene) ND 40 42 1 105 5.2 1-150 40 09/22/2022 1201
bis(2-Ethylhexyl)phthalate ND 40 41 1 103 12 8-158 82 09/22/2022 1201
Fluoranthene ND 40 32 1 81 4.9 26-137 66 09/22/2022 1201
Fluorene ND 40 31 1 79 3.1 59-121 38 09/22/2022 1201
Hexachlorobenzene ND 40 31 1 77 3.6 1-152 55 09/22/2022 1201
Hexachlorobutadiene ND 40 25 1 63 7.8 24-120 62 09/22/2022 1201
Hexachlorocyclopentadiene ND 200 ND N,+ 1 0.00 200 1-150 40 09/22/2022 1201
Hexachloroethane ND 40 29 1 72 1.3 40-120 52 09/22/2022 1201
Indeno(1,2,3-c,d)pyrene ND 40 24 1 60 12 1-171 99 09/22/2022 1201
Isophorone ND 40 39 1 99 3.4 21-196 93 09/22/2022 1201
Naphthalene ND 40 32 1 79 10 21-133 65 09/22/2022 1201
Nitrobenzene ND 40 37 1 92 1.3 35-180 62 09/22/2022 1201
2-Nitrophenol ND 40 16 + 1 41 60 29-182 55 09/22/2022 1201
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......Al,.F 41

Semivolatile Organic Compounds by GC/MS - MSD
Sample ID: X114079-005MD Matrix: Aqueous
Batch:54557 Prep Method: 625.1
Analytical Method:625.1 Prep Date: 09/19/2022 1534
Sample Spike
Amount Amount Result %Rec %RPD
Parameter (ug/L) (ug/L) (ug/L) Q Dil %Rec %RPD Limit Limit Analysis Date
4-Nitrophenol ND 80 ND N,+ 1 0.00 200 1-132 131 09/22/2022 1201
N-Nitrosodimethylamine ND 40 0.98 + 1 2.5 190 1-150 50 09/22/2022 1201
N-Nitrosodi-n-propylamine ND 40 48 1 121 7.3 1-230 87 09/22/2022 1201
N-Nitrosodiphenylamine(Diphenylamine) ND 40 37 1 92 0.61 1-150 40 09/22/2022 1201
Pentachlorophenol ND 80 ND N,+ 1 0.00 200 14-176 86 09/22/2022 1201
Phenanthrene ND 40 34 1 84 3.8 54-120 39 09/22/2022 1201
Phenol ND 40 15 + 1 38 74 5-120 64 09/22/2022 1201
Pyrene ND 40 34 1 85 3.9 52-120 49 09/22/2022 1201
1,2,4-Trichlorobenzene ND 40 25 1 63 2.7 44-142 50 09/22/2022 1201
2,4,6-Trichlorophenol ND 40 11 N,+ 1 27 93 37-144 58 09/22/2022 1201
Surrogate Q %Rec Acceptance
Limit
2-Fluorobiphenyl 68 37-129
2-Fluorophenol 34 24-127
Nitrobenzene-d5 88 38-127
Phenol-d5 36 28-128
Terphen yl-d 14 79 10-148
2,4,6-Tribromophenol N 38 41-144
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......A 2 -,f 41

r
ICP-MS - MB
Sample ID: XQ54219-001 Matrix: Aqueous
Batch:54219 Prep Method: 200.2
Analytical Method:200.8 Prep Date: 09/15/2022 0652
Parameter Result Q Dil LOQ Units Analysis Date
Antimony ND 1 5.0 ug/L 10/02/2022 2051
Arsenic ND 1 2.0 ug/L 10/02/2022 2051
Beryllium ND 1 1.0 ug/L 10/02/2022 2051
Cadmium ND 1 0.50 ug/L 10/02/2022 2051
Chromium ND 1 5.0 ug/L 10/02/2022 2051
Copper ND 1 2.0 ug/L 10/02/2022 2051
Lead ND 1 2.0 ug/L 10/02/2022 2051
Nickel ND 1 2.0 ug/L 10/02/2022 2051
Selenium ND 1 5.0 ug/L 10/02/2022 2051
Silver ND 1 1.0 ug/L 10/02/2022 2051
Thallium ND 1 2.0 ug/L 10/02/2022 2051
Zinc ND 1 10 ug/L 10/02/2022 2051
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D..,...AA ..0 41

ICP-MS - LCS
Sample ID: XQ54219-002 Matrix: Aqueous
Batch:54219 Prep Method: 200.2
Analytical Method:200.8 Prep Date: 09/15/2022 0652
Spike
Amount Result %Rec
Parameter (ug/L) (ug/L) Q Dil %Rec Limit Analysis Date
Antimony 100 89 1 89 85-115 10/04/20221113
Arsenic 100 88 1 88 85-115 10/02/2022 2140
Beryllium 100 87 1 87 85-115 10/04/20221113
Cadmium 100 85 1 85 85-115 10/02/2022 2140
Chromium 100 92 1 92 85-115 10/02/2022 2140
Copper 100 100 1 101 85-115 10/02/2022 2140
Lead 100 93 1 93 85-115 10/02/2022 2140
Nickel 100 96 1 96 85-115 10/02/2022 2140
Selenium 100 86 1 86 85-115 10/03/20221014
Silver 100 89 1 89 85-115 10/02/2022 2140
Thallium 100 92 1 92 85-115 10/04/20221113
Zinc 100 85 1 85 85-115 10/03/20221014
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
•=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......AG..G 4 1

Mercury (CVAFS) - MB
Sample ID: XQ55176-001 Matrix: Aqueous
Batch:55176 Prep Method:
Analytical Method: 1631E Prep Date: 09/26/2022 0718
Parameter Result Q Dil LOQ Units Analysis Date
Mercury(CVAFS) ND 1 0.500 ng/L 09/27/2022 0225
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
A ,.F 41

Mercury (CVAFS) - LCS
Sample ID: XQ55176-002 Matrix: Aqueous
Batch:55176 Prep Method:
Analytical Method: 1631E Prep Date: 09/26/2022 0718
Spike
Amount Result %Rec
Parameter (ng/L) (ng/L) Q DII %Rec Limit Analysis Date
Mercury(CVAFS) 5.00 5.05 1 101 75-125 09/27/2022 0236
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......A'7—C 41

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com

oa,
o c,
< fD
RACE ANALYTICAL SERVICES, LLC
108 Vantage Point Drive• Weal Coluinbfe,SC 291.42
o m (.9ace Ana/y icaI Telephone No, 903•191-97oo Fax No.303-741•-9111 Number 6 .5 5 j 5
5' CD
e w wwoabelabs.com
_
alert Report to i J .
CD N Sampler —
_ W\GACQr- Contact !.e_v.A kt(.Sitf- ;Printed Name) j� Qunte No.
Address 1 „,_ &C f et
Telephone-No. _
n° Po Box hoc( Email Field Parameters Cie,pH.temp,DO)Gan be recorded below Page i
3 i Cr.' sow Zip Cede 'Presantat�ve P I i i ' I - 1 1'urrt�erotContalners a Mor1E 0 e. lit-' 3 P l� 1,thpre;. 4.IINQ3 P J�
G. & cortenet Type Fd'lala Wks)
n m Project 2.Nit-- 5..-ICI P P ._--
3 �, Ll 1 s a 5 r I3raaR,r.:ve Ira9Fe, D
up rn
Name E-Fv- PPfl 5.112604 5.:43urn ?ti0.xlkie
ject
3 Nronber -�RU.Number - r 2 ct t Matrix .0) ^ L �, Il1I Ili Ii III 1 0
ram,o g Semple IU 1 Description ,a S f,�V t1Y! , + .� -� rn
m Peacoats tor each aerr Collection CollectionLI y!y!F'd ? -F M v' X114079
ca
,,rrr rr"�he u11e 5 lime C7' Q
as rOmbined,M one Fait t) +{ �m7) v S S.Sp10 Q Q ETU Z
m
io cs C H Z t `�, f.. Z iJ V
o smdn_ -22 icsaq a �, ;coaarlo D
O N
d Flni9trC'�_' �� �{_1C1`1 1M X )( X )( ) M4 ' jN,,, S4, A31 D7 r
x
o �19rr —__ 2nr Jii A C,ife C2�c ct,,.pi,' —I
I n/ n
v Flrtistl{'Zj t7 ,l
e 1
I
D
rO Start r
r
�'"' -ILI Nw x ( rn
73
uh t I'TI
h� •
cu
m FFnisi�-1 lL cJc of
11
0 Start W
AI
cn
Amarorxto Tl`me✓Required{Prier lab spproud requirrat'ar re:pedlT te1 TAT.) Sample 0ls)U;el Q I —
Requirements(Specify) Passito H;eard Identification r
Standard 0 Resit{Huse£en PT) ❑RUIIJfP�1 Client �CIIE{10�5I C f t.MV _ .E tier Hez rd n Ft)amble C`Slab Irntett 0 Po Son Unk•erne r
1"`�
1 Hclinquieted by I,Sampler Dnt Tnii, 1.Received& Cate
_ IKEr+v�rt4 .�4� `�'I��2� I is vil+,a �=!�2 �- ,Term1 l
2.Fielilyul:-Ytati by (/r�____� K! lime ? Ftweived �4
'! Date
L 1ZIS I. �` ?/Y 2L rme
3.RetinquiBttrxi ny OM Triri' 3.Fiecixafid by Date
Time .
4,Rellrlqulshed by 'p .___„.— .
-`te
.u f c L� 1 Z 4. t:arelo Rsoeivea Y De.:e Tut e
Noire:All samples are retained for four weeks from LAO USE •I 7—
receipt unless other arrangements are made. Fe 1 o t kin tCrtedtj L4vee r Nc lee pant I Ranker p 1 .
• --- apt air f; . Temp.btu'.,. i Y! U No
UYSiiiHUTION:V1H1T7 8 FFIi0W-Renm,to tabi-a!a;rw:hS:,rroers,s7 N'MC{wlQ 4udCarly

,
OD0�
m D
PACE ANALYTICAL SERVICES, LLC
v d ace/WA/Veal
Vurttage Point Drive• west Columbia,SC 29172
o- Telephone No.8)3-791.9700 Fax No.803-791-0111 Number
v CD
fD y Client a^ourl W
r- C.. Sampler r�L�Src{'
P . 'Y ci. ap C ie_ Co•lec! even Kt L-C it r n f lau i<ND.Name; 1�onAt'Fl, �f t�'CA Ack1re.sa (� Teleylacra NO.o I'�) } l I,c1 Email Parameters(i.e.,pH,tamp,DO;can ber rde d relax Page
5 a 9t31e lip Cole Preservative �— --
13 cn CN1CO4. AIC .ten 1 1.l ern. 4.HNC.' Numberd%onrainar3
n m Project 2.N2LiN 7.HCI G.
caCui.-pge p-mac ti.&r.rj
t
` tiart19^' -I Preservative;U_u ucdc•In IPhti D
F 8.H2904 6.Solon.Tliimulfate ��jjr� f( t
NJ Nulaoer F.O.Number is PiOjeCt
} _up rn
IING+IlIW1U�9i�1
Matrix Vt n
wSample ID 1 De5cr1pli0n oi ';dlect'on cnllexlo r B 1tii, fat' f'" C irn XI 14479 m
m y (COnt.'Iry r€for each serve taw La �aru(sj � Tf�1e to MN� NW '� D
m c rnb'ned ou LOU Pine.) �-y I J_"nld tPl en
2 _ �Vr/al Ind try) J pr IeP Z
o 2 star. i
rn Remarks CGC!er ID r
d it7 P FF finish 9.(y c clb -�
x —
scan -
? 7 p
p { F f1 Fnishc��N 0 Cijr W �/ 0
Elie
i.,./ I-
1' r p. .�,iQ k Finish c�.(�y CC-Pc
{ S I\I v.,./ Cn
m
h'IaA ••��
0, /
0 Firm
m
iv . r i
Start •
.— - n
Cn
9nnh i
rn
i I
Tam Ary rrd rime Requital(t mar lab anyway relauhgd pnr axFt3hKJ rap Sam pin a?is r
P p CC Requirements(Smelly POsaitale 1-lAud!dertin:A on
X Standard n Hush(?'earse 5pacryi ❑Return In Cllrnt .11eDiegosail by Lab =Wm-Hazard r Flarrnabe :Sl h aitant r
1.P.ellnq.fshed by I Sampler Paiso� a l'rtlrlcwn
'aR ,�,� f DM tTkne '1.Rscaieed by
f Jct.{s� L+, 1 2 2- Date Tme
C\- t. ` t (S C q-}tj - jt (5
2. Relinquished by .f/J, 1i rl ' /� 1.L iTime�1� 2.Fa�eh:ed by �S�! Dater ` , 2}Li-7)-
Time
- / I u
a 3erinqushed b ' sq / f� 3.Ra a ad t v / Ail
7/ 4 V 7, V TiI I`ld Dace Time
—
r. PCifnquished ny Date Time 4. L \ratory Recarve i by Cate rirnc
Note:All samples are retained for four weeks from LAB USE( ,1I Y� uu
receipt unless Other arrangements arc made. !Poetised or lce iced; Na ❑foe Par±. RC Tern ✓"ttrl/
- _ i PI P� °C Tarp Elsie Y i iN) l
D7s7!fI141IrnON:WflfTl:i YET�olveFrett"to rtbvrrkyp se sar tn10.l:P7n7e-FrsadoGislydGon, Sr 1 �} 1'1 1t�Wlib
��•/i\C O' \121 V�f Y ocv'1,d•v Murnirar L4DY JNI-C;7
V1 1 p�

PACE ANALYTICAL SERVICES, LLC
Dc# T'rtlr FNV-FRM-WCOL-0255 v)2_Samples Receipt Checklist(SRC)
Effective Date;2/2/202z
Sample Receipt Checklist (SRC)
chew: City afDiorax Cooler inspected Mate. %NR r 19 14/2°22 Lot#: XT14079
Means o receipt a `'ace ,C. iebt J uP5 FiniEx Other:
I i___ Yes F4,No I.VJece cu tudy seals present on the;o kr'
Yes No J7[NA 2.If c tutudy seals were present,wilt t112 rota�t and unbroken?
72-1677
pH Strip ID: ID: 21?539
P _Chlorine Ship Tested bti-1CDRw
Original temperature upon receipt/Derived(Cccrected)temperature upon Ieccipr %Solid Snap-Cup ID: NA
2.6 ;la nC 24.2 /21.2 'C NA f N A oC NA /NA vc
Method:WiTtinperattne 13Iat1k ri *ainst Bottles TR Gun B7: 8 ER.Gun Correction Factor: o IC
Method of coolant: Z t.kict Ice [I Ice PrtcF:a E Dry Ice 0 None
©Yes El No DNA 3. Were all coolers received at ar below 6.0°C?If no,was Piojectct Ma ificd?
_ PM was Notified by.phone;email/face-to-face(click one).
Yes a..�No DNA 4. Is the commercial courier's jacking slip attached to this font?
Sill Yes �Na 3. Were proper custody procedures(relinquisherVrec eived)followed?
!I`Yas __ Na 6 Were sample IDs listed on the COC and all sample containers?
f Yes No 7. Was collection date&time listed on the COC amid all sample containers? •
�/ Yesr � 8.Did all container label information(ID,date,time)agree with die COC?
I Yes 9No
No r9.
9.Were tests to be pied listed on the COC? I
IZIYes r 10.Did all satnpkes arrive in;he proper containers for each test and/or in good condition
1J (unbroken,lids on.etc,)?
'Yes p lipNo t T-Was adequate saunlle volume available?
./ Yes No 12.Were all samples received within the holding time or 48 hours.whichever conies fuss?
DYes []No 13.Were all samples containers accounted for?(No inissing/excess)
I '
Were VOA.8015C and RSI(-175 sanspls4 free of bubbles `pea-size"(.A'or 6mm in
/e QNo DNA
diameter)in any of the VOA vials?
7Yes No NA 15.Were all DRUhneailsi'nnirient samples received at a pH of<27
y/ Yes f No ®NA 16. Were afilyanide sauipks received at a prl> 12 and sulfide samples received at a pH>9?
Lizi
Yes []No EJNA 17 Were all applicabfc Nnn,rr yaniddplicno11625.1/6 3 (<O.51ngft.)samples free of
residual sine?
t:I11
Yes aNc DNA 18.Was the quote number listed on the container label?If yes.Quote i/
Sample Preservation (Must be completed fur ia.iy sample(s)inccrreetlypre er eed or with hea;hpacc,) o
Saniph.'(s) NA
were received incorrectly preserved and were adjusted aCCOIC1111 y
saniile receiving with NA toil,of circle one:II2SO4.HNO3.NCI NaOH using SR a' NA
rote ofpreservation NA . limn than one preservative is needed,please note in the contents below.
Sample(s) +I - were received with bubbles>6 rrtru in ditunetet
Sa❑iples(s) NA were received with TRC'>0_5 ing/L.(If#19 is no)and were
adjusted according,'iu sample receiving with sodium tlrsosttlatc CNa O with UnNa
crewszS i Te ID:
Comments:
QuaitraK tp:56360 Pacee Analytical Services,LLC Page 1 of 1
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
D......41 ..C41

LELAP Certificate Number: 01955
A2LA Accredited(DoD ELAP-QSM 5.4) Certificate Number: 6429.01
ace Analytical
ANALYTICAL RESULTS
PERFORMED BY
Pace Analytical Gulf Coast
7979 Innovation Park Dr.
Baton Rouge, LA 70820
[phone]
Report Date 09/20/2022
Report # 222091684
11111111111111111111
Project X114079
Samples Collected 9/14/22
Deliver To Additional Recipients
Edward Barnett Jenna Holliday, Pace Analytical
Pace Analytical
106 Vantage Point Dr
Columbia, SC 29223
803.509.8398
11001,
ACCREDITED
CERT#6429.01
Pace Gulf Coast Report#:222091684 ,019/20/2022 15:17 Page 1 of 10

Report#: 222091684
aceAnalytrcal
Project ID: X114079 Report Date: 09/20/2022
Laboratory Endorsement
Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized
agencies.The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this
retention period the samples will be disposed in accordance with Pace Gulf Coast's Standard Operating Procedures.
Common Abbreviations that may be Utilized in this Report
ND Indicates the result was Not Detected at the specified reporting limit
NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030
DO Indicates the result was Diluted Out
MI Indicates the result was subject to Matrix Interference
TNTC Indicates the result was Too Numerous To Count
SUBC Indicates the analysis was Sub-Contracted
FLD Indicates the analysis was performed in the Field
DL Detection Limit
LOD Limit of Detection
LOQ Limit of Quantitation
RE Re-analysis
CF HPLC or GC Confirmation
00:01 Reported as a time equivalent to 12:00 AM
Reporting Flags that may be Utilized in this Report
J or I Indicates the result is between the MDL and LOQ
J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria
U Indicates the compound was analyzed for but not detected
B or V Indicates the analyte was detected in the associated Method Blank
Q Indicates a non-compliant QC Result(See Q Flag Application Report)
* Indicates a non-compliant or not applicable QC recovery or RPD—see narrative
E Organics-The result is estimated because it exceeded the instrument calibration range
E Metals-%diference for the serial dilution is> 10%
L Reporting Limits adjusted to meet risk-based limit.
P RPD between primary and confirmation result is greater than 40
DL Diluted analysis—when appended to Client Sample ID
Sample receipt at Pace Gulf Coast is documented through the attached chain of custody. In accordance with NELAC,this report shall be
reproduced only in full and with the written permission of Pace Gulf Coast.The results contained within this report relate only to the samples
reported.The documented results are presented within this report.
This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof.The results
contained within this report are intended for the use of the client.Any unauthorized use of the information contained in this report is prohibited.
I certify that this data package is in compliance with The NELAC Institute(TNI)Standard 2009 and terms and conditions of the contract and
Statement of Work both technically and for completeness,for other than the conditions in the case narrative. Release of the data contained in this
hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee,
as verified by the following signature.
Estimated uncertainty of measurement is available upon request.This report is in compliance with the DOD QSM as specified in the contract if
applicable.
Authorized Signature
Pace Gulf Coast Report 222091684
Pace Gulf Coast Report#:222091684 0A/20/2022 15:17 Page 2 of 10

• Report#: 222091684
Project ID: X114079 Report Date: 09/20/2022
Certifications
Certification Certification Number
A2LA Accredited (DoD ELAP-QSM 5.4) 6429.01
Alabama 01955
Arkansas 88-0655
Colorado 01955
Delaware 01955
Florida E87854
Georgia 01955
Hawaii 01955
Idaho 01955
Illinois 200048
Indiana 01955
Kansas E-10354
Kentucky 95
Louisiana 01955
Maryland 01955
Massachusetts 01955
Michigan 01955
Mississippi 01955
Missouri 01955
Montana N/A
Nebraska 01955
New Mexico 01955
North Carolina 618
North Dakota R-195
Oklahoma 9403
South Carolina 73006001
South Dakota 01955
Tennessee 01955
Texas T104704178
Vermont 01955
Virginia 460215
Washington C929
USDA Soil Permit P330-16-00234
Pace Gulf Coast Report#:222091684 09/20/2022 15:17 Page 3 of 10

Report#: 222091684
ceMahmcaI
Project ID: XI14079 Report Date: 09/20/2022
Case Narrative
Client: Pace Analytical Services Report: 222091684
Pace Analytical Gulf Coast received and analyzed the sample(s)listed
on the Report Sample Summary page of this report. Receipt of the sample(s)is documented
by the attached chain of custody.This applies only to the sample(s)listed in this report.
No sample integrity or quality control exceptions were identified unless noted below.
No anomalies were found for the analyzed sample(s).
Pace Gulf Coast Report#:222091684 <009/20/2022 15:17 Page 4 of 10

Report#: 222091684
eAnaMicaI
Project ID: X114079 Report Date: 09/20/2022
Sample Summary
Lab ID Client ID Matrix Collect Date Receive Date
22209168401 EFF PPA Water 9/14/22 08:58 9/16/22 09:19
Pace Gulf Coast Report#:222091684 <029/20/2022 15:17 Page 5 of 10

Report#: 222091684
eArelyfical
Project ID: X114079 Report Date: 09/20/2022
Detect Summary
Results and Detection Limits are adjusted for dilution and moisture when applicable
EPA 335.4
Lab ID Client ID Parameter Units Result Dil. %Moist
22209168401 EFF PPA Cyanide mg/L 0.010 1 NA
Pace Gulf Coast Report#:222091684 <09/20/2022 15:17 Page 6 of 10

• Report#: 222091684
Project ID: X114079 Report Date: 09/20/2022
Sample Results
EFF PPA Collect Date 09/14/2022 08:58 Lab ID 22209168401
Receive Date 09/16/2022 09:19 Matrix Water
EPA 335.4
Prep Date Prep Batch Prep Method Dilution Run Date Run Batch Analyst %Moisture
09/19/22 09:15 749989 Cyanide Prep 1 09/20/22 11:35 750091 SLL2 NA
CAS# Parameter Result LOQ Units
57-12-5 Cyanide 0.010 0 (04') mg/L
Pace Gulf Coast Report#:222091684 09/20/2022 15:17 Page 7 of 10

Report#: 222091684
Project ID: XI14079 Report Date: 09/20/2022
General Chemistry QC Summary
Analytical Batch Client ID MB749989 LCS749989 LCSH1749989
750091 Lab ID 2397048 2397049 2397051
Prep Batch Sample Type MB LCS LCSHI
749989 Prep Date 09/19/22 09:15 09/19/22 09:15 09/19/22 09:15
Prep Method Analysis Date 09/20/22 10:50 09/20/22 10:52 09/20/22 10:57
Cyanide Prep Matrix Water Water Water
EPA 335.4 Units mg/L Spike Result %F2 Control Spike Result %R Control
Result LOQ Added Limits%R Added Limits%R
Cyanide 57-12-5 ND 0.0040 0.020 0.021 103 80-120 0.10 0.10 102 80-120
Analytical Batch Client ID EFF PPA 2396669MS 2396669MSD
750091 Lab ID 22209168401 2397074 2397075
Prep Batch Sample Type SAMPLE MS MSD
749989 Prep Date 09/19/2022 09:15 09/19/22 09:15 09/19/22 09:15
Prep Method Analysis Date 09/20/2022 11:35 09/20/22 11:37 09/20/22 11:43
Cyanide Prep Matrix Water Water Water
EPA 335.4 Units mg/L Spike Result °AR Control Spike Result %R RPD RPD
Result LOQ Added Limits%R Added Limit
Cyanide 57-12-5 0.010 0.0040 0.10 0.098 87 80-120 0.10 0.098 88 0 20
Pace Gulf Coast Report#:222091684 CO19/20/2022 15:17 Page 8 of 10

Client ID: 4367-Pace Analytical Services
sDG: 222091684
PM: RWe
Chain of Custody /7 I CeAnalytical
1
Workorder: X114079 Workorder Name: X114079 Owner Received Date: 9/14/2022 Results Requested By: 9/27/2022
Report To: Subcontract To: Requested Analysis
Edward T. Barnett Project#X114079
Pace Analytical
106 Vantage Point Drive Pace Gulf Coast
Columbia SC,29223 7979 Innovation Park Drive,
803-509-8398 Baton Rouge, LA 70820 :n
[e-mail] Preserved containers gl..
Sample Collect u
u,
Item Sample ID Type Date/Time Lab ID Matrix_ r LAB USE ONLY
1 EFF PPA grab 09/14/22 @ 0858 X114079-003 _ Aqueous x j
2
3
4
5
6 I
7
8
9
10
Transfers Released By Date/Time Reveived By Date/Time Comments
1 .0ic�c_F•��`-'"'�� (1.1‹..?_) liDD
2 FQ€:4-f)
61"1t/'00- C ••ii I}QJAMCakft2 ct-iirggcull
3 I 1Dto allifil c Li%) D. -IQ-
Cooler Temperature on Receipt °C Custody Seal Y or N Received on Ice Y or N Sample Intact Y or N
***In order to maintain client confidentiality,location/name of the sampling site,sampler's name and signature may not be provided on this COC
This chain of custody is considered complete as is since this information is available in the owner laboratory.
Friday,June 17,2016 11:01:34 AM FMT-ALL-C-002rev.00 24March2009 Page 1 of 1
Pace Gulf Ci eport#:222091684 I 2022 15:17 e 9 of 10
Paue 60 of„,

aceAnalytical SAMPLE RECEIVING CHECKLIST OHHM II II
k 2 2 2 0 9 1 6 8 4
SAMPLE DELIVERY GROUP 222091684 CHECKLIST YES NO
Client PM RWe Transport Method
4367 Pace Analytical Services FH rX Samples received with proper thermal preservation? Iv
Radioactivity is <1600 cpm? If no, record cpm value in notes section. :i 7
Profile Number Received By COC relinquished and complete (including samplelDs, collect times, and sampler)? •e 7
296533 Farkins, Brennan
All containers received in good condition and within hold time? 1.el 7
Line Item(s) Receive Date(s) All sample labels and containers received match the chain of custody? j.il
2-Cyanide 09/16/22
Preservative added to any containers? I v1
If received, was headspace for VOC water containers < 6mm?
Samples collected in containers provided by Pace Gulf Coast?
COOLERS DISCREPANCIES LAB PRESERVATIONS
Airbill Thermometer ID: E42 Temp°C ' Nbne Nbne
166334679426 0.2
NOTES
Revision 1.6 Page 1 of 1
Pace Gulf G eport#:222091684 I 2022 15:17 e 10 of 10
Pape 61 of 0.

9800 Kiney Ave. Suite 100
Huntersville,NC 28078078
[phone]
July 20, 2023
Kevin Keesler
City of Monroe
PO Box 69
Monroe, NC 28111
RE: Project: EFF PPA-Revised Report
Pace Project No.: 92672544
Dear Kevin Keesler:
Enclosed are the analytical results for sample(s)received by the laboratory on June 14, 2023. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
•Pace Analytical Services-Asheville
•Pace Analytical Services-Charlotte
Revision 1 -This report was reissued July 11, 2023. Per client request, data for the following compounds on sample 001
has been posted under 200.8 and removed from 200.7: As, Cd, Pb, Se, and Ag.
Revision 2-This report was reissued July 20, 2023. Hardness result has been reported.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Ariel S Fitzgerald for
Tyriek Hooks
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 1 of 30

(Face
[phone]
CERTIFICATIONS
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
Pace Analytical Services Charlotte
South Carolina Laboratory ID:99006 South Carolina Certification#:99006001
9800 Kincey Ave.Ste 100, Huntersville, NC 28078 South Carolina Drinking Water Cert.#:99006003
North Carolina Drinking Water Certification#:37706 Florida/NELAP Certification#: E87627
North Carolina Field Services Certification#:5342 Kentucky UST Certification#:84
North Carolina Wastewater Certification#: 12 Louisiana DoH Drinking Water#: LA029
South Carolina Laboratory ID:99006 VirginiaNELAP Certification#:460221
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville,NC 28804 South Carolina Laboratory ID:99030
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
North Carolina Drinking Water Certification#:37712 VirginiaNELAP Certification#:460222
North Carolina Wastewater Certification#:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 2 of 30

9800 Kincey Ave. Suite100
Huntersville,NC 28078078
{i!V [phone]
SAMPLE ANALYTE COUNT
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92672544001 EFF PPA COMP EPA 200.7 Rev 4.4 1994 DBB1 9 PASI-A
EPA 200.8 Rev 5.4 1994 KRL 5 PASI-A
SM 2540C-2015 MAB2 1 PASI-A
EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A
EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 353.2 Rev 2.0 1993 EGC 1 PASI-A
EPA 365.1 Rev 2.0 1993 ZJP 1 PASI-A
92672544002 EFF PPA GRAB EPA 1664E REL 1 PASI-C
EPA 625.1 PKS 58 PASI-C
EPA 624.1 SAS 34 PASI-C
EPA 420.4 Rev 1.0 1993 KDF1 1 PASI-A
SM 4500-CN-E-2011 EGC 1 PASI-A
PASI-A=Pace Analytical Services-Asheville
PASI-C=Pace Analytical Services-Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 3 of 30

(-Vace
[phone]
ANALYTICAL RESULTS
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
Sample: EFF PPA COMP Lab ID: 92672544001 Collected: 06/13/23 10:12 Received: 06/14/23 10:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services-Asheville
Antimony ND ug/L 5.0 1 06/15/23 15:12 06/19/23 12:53 7440-36-0
Beryllium ND ug/L 1.0 1 06/15/23 15:12 06/19/23 12:53 7440-41-7
Boron 211 ug/L 50.0 1 06/15/23 15:12 06/19/23 12:53 7440-42-8
Chromium ND ug/L 5.0 1 06/15/23 15:12 06/19/23 12:53 7440-47-3
Copper 5.4 ug/L 5.0 1 06/15/23 15:12 06/19/23 12:53 7440-50-8
Nickel 7.8 ug/L 5.0 1 06/15/23 15:12 06/19/23 12:53 7440-02-0
Thallium ND ug/L 10.0 1 06/15/23 15:12 06/19/23 12:53 7440-28-0
Hardness,Total(SM 2340B) 112000 ug/L 662 1 06/15/23 15:12 06/19/23 12:53
Zinc 78.6 ug/L 10.0 1 06/15/23 15:12 06/19/23 12:53 7440-66-6
200.8 MET ICPMS Analytical Method:EPA 200.8 Rev 5.4 1994 Preparation Method: EPA 200.8 Rev 5.4 1994
Pace Analytical Services-Asheville
Arsenic ND ug/L 1.0 1 07/03/23 16:03 07/04/23 00:22 7440-38-2
Cadmium ND ug/L 0.20 1 07/03/23 16:03 07/04/23 00:22 7440-43-9
Lead ND ug/L 1.0 1 07/03/23 16:03 07/04/23 00:22 7439-92-1
Selenium ND ug/L 2.0 1 07/03/23 16:03 07/04/23 00:22 7782-49-2
Silver ND ug/L 0.40 1 07/03/23 16:03 07/04/23 00:22 7440-22-4
IOC Total Dissolved Solids Analytical Method:SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 447 mg/L 25.0 1 06/16/23 13:26
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 06/28/23 10:38 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Kjeldahl,Total 2.1 mg/L 0.50 1 06/22/23 16:39 06/23/23 05:12 7727-37-9
353.2 Nitrogen,NO2/NO3 pres. Analytical Method: EPA 353.2 Rev 2.0 1993
1 Pace Analytical Services-Asheville
Nitrogen,NO2 plus NO3 25.8 mg/L 0.40 10 06/24/23 13:41
365.1 Phosphorus,Total Analytical Method:EPA 365.1 Rev 2.0 1993 Preparation Method:EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 4.1 mg/L 0.050 1 06/22/23 12:38 06/22/23 15:19 7723-14-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 30

9800 Kincey Ave. Suite 100
acp Huntersville,NC 28078
(,�( �,J [phone]
ANALYTICAL RESULTS
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
Sample: EFF PPA GRAB Lab ID: 92672544002 Collected: 06/13/23 09:17 Received: 06/14/23 10:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 16648
Pace Analytical Services-Charlotte
Oil and Grease ND mg/L 4.8 1 06/20/23 13:15
625 RVE Analytical Method: EPA 625.1 Preparation Method:EPA 625.1
Pace Analytical Services-Charlotte
Acenaphthene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 83-32-9
Acenaphthylene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 208-96-8
Anthracene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 120-12-7
Benzo(a)anthracene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 56-55-3
Benzo(a)pyrene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 50-32-8
Benzo(b)fluoranthene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 205-99-2
Benzo(g,h,i)perylene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 191-24-2
Benzo(k)fluoranthene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 207-08-9
4-Bromophenylphenyl ether ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 101-55-3
Butylbenzylphthalate ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 85-68-7
4-Chloro-3-methylphenol ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 59-50-7
bis(2-Chloroethoxy)methane ND ug/L 9.1 1 06/15/23 10:19 06/16/23 21:15 111-91-1
k (2-Chloroethyl)ether ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 111-44-4
Thloronaphthalene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 91-58-7
, hlorophenol ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 95-57-8
4-Chlorophenylphenyl ether ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 7005-72-3
Chrysene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 218-01-9
Dibenz(a,h)anthracene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 53-70-3
3,3'-Dichlorobenzidine ND ug/L 9.1 1 06/15/23 10:19 06/16/23 21:15 91-94-1 IL
2,4-Dichlorophenol ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 120-83-2
Diethylphthalate ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 84-66-2 L1
2,4-Dimethylphenol ND ug/L 9.1 1 06/15/23 10:19 06/16/23 21:15 105-67-9
Dimethylphthalate ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 131-11-3
Di-n-butylphthalate ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 9.1 1 06/15/23 10:19 06/16/23 21:15 534-52-1
2,4-Dinitrophenol ND ug/L 45.5 1 06/15/23 10:19 06/16/23 21:15 51-28-5
2,4-Dinitrotoluene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 121-14-2
2,6-Dinitrotoluene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 606-20-2
Di-n-octylphthalate ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 117-84-0
bis(2-Ethylhexyl)phthalate ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 117-81-7
Fluoranthene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 206-44-0
Fluorene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 86-73-7
Hexachloro-1,3-butadiene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 87-68-3
Hexachlorobenzene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 118-74-1
Hexachlorocyclopentadiene ND ug/L 9.1 1 06/15/23 10:19 06/16/23 21:15 77-47-4
Hexachloroethane ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 193-39-5
Isophorone ND ug/L 9.1 1 06/15/23 10:19 06/16/23 21:15 78-59-1
Naphthalene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 91-20-3
Nitrobenzene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 98-95-3
2-Nitrophenol ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 88-75-5
litrophenol ND ug/L 9.1 1 06/15/23 10:19 06/16/23 21:15 100-02-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 30

(- Face' Huntersville,NC 28078
[phone]
ANALYTICAL RESULTS
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
Sample: EFF PPA GRAB Lab ID: 92672544002 Collected: 06/13/23 09:17 Received: 06/14/23 10:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
625 RVE Analytical Method:EPA 625.1 Preparation Method:EPA 625.1
Pace Analytical Services-Charlotte
N-Nitrosodimethylamine ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 621-64-7
N-Nitrosodiphenylamine ND ug/L 9.1 1 06/15/23 10:19 06/16/23 21:15 86-30-6
2,2'-Oxybis(1-chloropropane) ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 108-60-1
Pentachlorophenol ND ug/L 9.1 1 06/15/23 10:19 06/16/23 21:15 87-86-5
Phenanthrene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 85-01-8
Phenol ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 108-95-2
Pyrene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 129-00-0
1,2,4-Trichlorobenzene ND ug/L 4.5 1 06/15/23 10:19 06/16/23 21:15 120-82-1
2,4,6-Trichlorophenol ND ug/L 9.1 1 06/15/23 10:19 06/16/23 21:15 88-06-2
Surrogates
Nitrobenzene-d5(S) 61 % 10-120 1 06/15/23 10:19 06/16/23 21:15 4165-60-0
2-Fluorobiphenyl(S) 62 % 15-120 1 06/15/23 10:19 06/16/23 21:15 321-60-8
Terphenyl-d14(S) 77 % 11-131 1 06/15/23 10:19 06/16/23 21:15 1718-51-0
Phenol-d6(S) 38 % 10-120 1 06/15/23 10:19 06/16/23 21:15 13127-88-3
2-Fluorophenol(S) 45 % 10-120 1 06/15/23 10:19 06/16/23 21:15 367-12-4
2,4,6-Tribromophenol(S) 71 % 10-137 1 06/15/23 10:19 06/16/23 21:15 118-79-6
4 Volatile Organics Analytical Method: EPA 624.1
Pace Analytical Services-Charlotte
Benzene ND ug/L 1.0 1 06/23/23 17:07 71-43-2
Bromodichloromethane 4.2 ug/L 2.0 1 06/23/23 17:07 75-27-4
Bromoform ND ug/L 2.0 1 06/23/23 17:07 75-25-2
Bromomethane ND ug/L 2.0 1 06/23/23 17:07 74-83-9
Carbon tetrachloride ND ug/L 2.0 1 06/23/23 17:07 56-23-5 M1
Chlorobenzene ND ug/L 2.0 1 06/23/23 17:07 108-90-7
Chloroethane ND ug/L 2.0 1 06/23/23 17:07 75-00-3
Chloroform 5.6 ug/L 2.0 1 06/23/23 17:07 67-66-3
Chloromethane ND ug/L 2.0 1 06/23/23 17:07 74-87-3
Dibromochloromethane ND ug/L 2.0 1 06/23/23 17:07 124-48-1
1,2-Dichlorobenzene ND ug/L 2.0 1 06/23/23 17:07 95-50-1
1,3-Dichlorobenzene ND ug/L 2.0 1 06/23/23 17:07 541-73-1
1,4-Dichlorobenzene ND ug/L 2.0 1 06/23/23 17:07 106-46-7
1,1-Dichloroethane ND ug/L 2.0 1 06/23/23 17:07 75-34-3
1,2-Dichloroethane ND ug/L 2.0 1 06/23/23 17:07 107-06-2
1,1-Dichloroethene ND ug/L 2.0 1 06/23/23 17:07 75-35-4
cis-1,2-Dichloroethene ND ug/L 2.0 1 06/23/23 17:07 156-59-2
trans-1,2-Dichloroethene ND ug/L 2.0 1 06/23/23 17:07 156-60-5
1,2-Dichloropropane ND ug/L 2.0 1 06/23/23 17:07 78-87-5
cis-1,3-Dichloropropene ND ug/L 2.0 1 06/23/23 17:07 10061-01-5
trans-1,3-Dichloropropene ND ug/L 2.0 1 06/23/23 17:07 10061-02-6
Ethylbenzene ND ug/L 1.0 1 06/23/23 17:07 100-41-4
Methylene Chloride ND ug/L 2.0 1 06/23/23 17:07 75-09-2
1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 06/23/23 17:07 79-34-5
Tetrachloroethene ND ug/L 2.0 1 06/23/23 17:07 127-18-4
uene ND ug/L 1.0 1 06/23/23 17:07 108-88-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 30

gace-
9800 Kincey Ave. Suite 100
Huntersville,NC 28078
[phone]
ANALYTICAL RESULTS
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
Sample: EFF PPA GRAB Lab ID: 92672544002 Collected: 06/13/23 09:17 Received: 06/14/23 10:30 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method: EPA 624.1
Pace Analytical Services-Charlotte
1,1,1-Trichloroethane ND ug/L 2.0 1 06/23/23 17:07 71-55-6
1,1,2-Trichloroethane ND ug/L 2.0 1 06/23/23 17:07 79-00-5
Trichloroethene ND ug/L 2.0 1 06/23/23 17:07 79-01-6
Trichlorofluoromethane ND ug/L 2.0 1 06/23/23 17:07 75-69-4
Vinyl chloride ND ug/L 2.0 1 06/23/23 17:07 75-01-4
Surrogates
4-Bromofluorobenzene(S) 103 % 70-130 1 06/23/23 17:07 460-00-4
Toluene-d8(S) 104 % 70-130 1 06/23/23 17:07 2037-26-5
1,2-Dichloroethane-d4(S) 116 % 70-130 1 06/23/23 17:07 17060-07-0
420.4 Phenolics,Total Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services-Asheville
Phenolics,Total Recoverable ND mg/L 0.020 1 06/26/23 10:40 06/27/23 09:04 64743-03-9
4500CNE Cyanide,Total Analytical Method:SM 4500-CN-E-2011 Preparation Method:SM 4500-CN-E-2011
Pace Analytical Services-Asheville
r""anide ND mg/L 0.010 1 06/21/23 10:36 06/21/23 16:32 57-12-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 30

a/'�/� 9800 Kincey Ave. Suite 100
/ _G Huntersville,NC 28078
V [phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
QC Batch: 781694 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664E Analysis Description: 1664 HEM,Oil and Grease
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92672544002
METHOD BLANK: 4055337 Matrix: Water
Associated Lab Samples: 92672544002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 06/20/23 13:15
LABORATORY CONTROL SAMPLE: 4055338
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 40 36.0 90 78-114
MATRIX SPIKE SAMPLE: 4055339
92671906001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
I and Grease mg/L ND 38.5 33.8 85 78-114
SAMPLE DUPLICATE: 4055340
92672404001 Dup
Parameter Units Result Result RPD Qualifiers
Oil and Grease mg/L ND ND
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 30

1
Fce [phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
QC Batch: 780811 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92672544001
METHOD BLANK: 4050719 Matrix: Water
Associated Lab Samples: 92672544001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Antimony ug/L ND 5.0 06/19/23 12:27
Beryllium ug/L ND 1.0 06/19/23 12:27
Boron ug/L ND 50.0 06/19/23 12:27
Chromium ug/L ND 5.0 06/19/23 12:27
Copper ug/L ND 5.0 06/19/23 12:27
Nickel ug/L ND 5.0 06/19/23 12:27
Thallium ug/L ND 10.0 06/19/23 12:27
Zinc ug/L ND 10.0 06/19/23 12:27
LABORATORY CONTROL SAMPLE: 4050720
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
itimony ug/L 500 492 98 85-115
Beryllium ug/L 500 497 99 85-115
Boron ug/L 500 498 100 85-115
Chromium ug/L 500 502 100 85-115
Copper ug/L 500 492 98 85-115
Nickel ug/L 500 498 100 85-115
Thallium ug/L 500 495 99 85-115
Zinc ug/L 500 491 98 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4050721 4050722
MS MSD
92672544001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Antimony ug/L ND 500 500 507 511 101 102 70-130 1
Beryllium ug/L ND 500 500 510 513 102 103 70-130 0
Boron ug/L 211 500 500 724 727 103 103 70-130 0
Chromium ug/L ND 500 500 503 506 100 101 70-130 1
Copper ug/L 5.4 500 500 516 517 102 102 70-130 0
Nickel ug/L 7.8 500 500 505 507 99 100 70-130 0
Thallium ug/L ND 500 500 488 494 98 99 70-130 1
Zinc ug/L 78.6 500 500 567 569 98 98 70-130 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 30

(/!Jlace [phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
QC Batch: 784549 Analysis Method: EPA 200.8 Rev 5.4 1994
QC Batch Method: EPA 200.8 Rev 5.4 1994 Analysis Description: 200.8 MET
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92672544001
METHOD BLANK: 4068982 Matrix: Water
Associated Lab Samples: 92672544001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Arsenic ug/L ND 1.0 07/04/23 00:07
Cadmium ug/L ND 0.20 07/04/23 00:07
Lead ug/L ND 1.0 07/04/23 00:07
Selenium ug/L ND 2.0 07/04/23 00:07
Silver ug/L ND 0.40 07/04/23 00:07
LABORATORY CONTROL SAMPLE: 4068983
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Arsenic ug/L 50 49.3 99 85-115
Cadmium ug/L 50 49.5 99 85-115
ad ug/L 50 49.0 98 85-115
lenium ug/L 50 49.8 100 85-115
Silver ug/L 25 24.8 99 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4068984 4068985
MS MSD
92672544001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Arsenic ug/L ND 50 50 50.5 50.7 100 100 70-130 0
Cadmium ug/L ND 50 50 48.3 48.0 97 96 70-130 1
Lead ug/L ND 50 50 49.6 49.3 99 98 70-130 1
Selenium ug/L ND 50 50 50.3 49.3 100 98 70-130 2
Silver ug/L ND 25 25 24.1 24.0 96 96 70-130 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 30

(j,(�G•w we, 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
QC Batch: 782662 Analysis Method: EPA 624.1
QC Batch Method: EPA 624.1 Analysis Description: 624 MSV
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92672544002
METHOD BLANK: 4059850 Matrix: Water
Associated Lab Samples: 92672544002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1-Trichloroethane ug/L ND 2.0 06/23/23 10:57
1,1,2,2-Tetrachloroethane ug/L ND 2.0 06/23/23 10:57
1,1,2-Trichloroethane ug/L ND 2.0 06/23/23 10:57
1,1-Dichloroethane ug/L ND 2.0 06/23/23 10:57
1,1-Dichloroethene ug/L ND 2.0 06/23/23 10:57
1,2-Dichlorobenzene ug/L ND 2.0 06/23/23 10:57
1,2-Dichloroethane ug/L ND 2.0 06/23/23 10:57
1,2-Dichloropropane ug/L ND 2.0 06/23/23 10:57
1,3-Dichlorobenzene ug/L ND 2.0 06/23/23 10:57
1,4-Dichlorobenzene ug/L ND 2.0 06/23/23 10:57
Benzene ug/L ND 1.0 06/23/23 10:57
Bromodichloromethane ug/L ND 2.0 06/23/23 10:57
Q•)moform ug/L ND 2.0 06/23/23 10:57
)momethane ug/L ND 2.0 06/23/23 10:57
.arbon tetrachloride ug/L ND 2.0 06/23/23 10:57
Chlorobenzene ug/L ND 2.0 06/23/23 10:57
Chloroethane ug/L ND 2.0 06/23/23 10:57
Chloroform ug/L ND 2.0 06/23/23 10:57
Chloromethane ug/L ND 2.0 06/23/23 10:57
cis-1,2-Dichloroethene ug/L ND 2.0 06/23/23 10:57
cis-1,3-Dichloropropene ug/L ND 2.0 06/23/23 10:57
Dibromochloromethane ug/L ND 2.0 06/23/23 10:57
Ethylbenzene ug/L ND 1.0 06/23/23 10:57
Methylene Chloride ug/L ND 2.0 06/23/23 10:57
Tetrachloroethene ug/L ND 2.0 06/23/23 10:57
Toluene ug/L ND 1.0 06/23/23 10:57
trans-1,2-Dichloroethene ug/L ND 2.0 06/23/23 10:57
trans-1,3-Dichloropropene ug/L ND 2.0 06/23/23 10:57
Trichloroethene ug/L ND 2.0 06/23/23 10:57
Trichlorofluoromethane ug/L ND 2.0 06/23/23 10:57
Vinyl chloride ug/L ND 2.0 06/23/23 10:57
1,2-Dichloroethane-d4(S) % 115 70-130 06/23/23 10:57
4-Bromofluorobenzene(S) % 102 70-130 06/23/23 10:57
Toluene-d8(S) % 103 70-130 06/23/23 10:57
LABORATORY CONTROL SAMPLE: 4059851
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,1,1-Trichloroethane ug/L 20 25.8 129 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 30

_ /Flace 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
LABORATORY CONTROL SAMPLE: 4059851
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,1,2,2-Tetrachloroethane ug/L 20 21.9 110 70-130
1,1,2-Trichloroethane ug/L 20 22.9 114 70-130
1,1-Dichloroethane ug/L 20 23.0 115 70-130
1,1-Dichloroethene ug/L 20 24.1 121 70-130
1,2-Dichlorobenzene ug/L 20 22.6 113 70-130
1,2-Dichloroethane ug/L 20 25.4 127 70-130
1,2-Dichloropropane ug/L 20 24.0 120 70-130
1,3-Dichlorobenzene ug/L 20 22.4 112 70-130
1,4-Dichlorobenzene ug/L 20 22.5 113 70-130
Benzene ug/L 20 23.1 115 70-130
Bromodichloromethane ug/L 20 23.8 119 70-130
Bromoform ug/L 20 21.6 108 70-130
Bromomethane ug/L 20 17.8 89 45-151
Carbon tetrachloride ug/L 20 25.5 127 70-130
Chlorobenzene ug/L 20 22.5 113 70-130
Chloroethane ug/L 20 21.5 108 40-152
Chloroform ug/L 20 22.9 115 70-130
Chloromethane ug/L 20 21.1 105 58-130
cis-1,2-Dichloroethene ug/L 20 24.7 123 70-130
-1,3-Dichloropropene ug/L 20 23.3 117 70-130
)romochloromethane ug/L 20 22.9 115 70-130
Ethylbenzene ug/L 20 22.6 113 70-130
Methylene Chloride ug/L 20 24.9 125 66-130
Tetrachloroethene ug/L 20 23.0 115 70-130
Toluene ug/L 20 21.9 110 70-130
trans-1,2-Dichloroethene ug/L 20 24.3 121 70-130
trans-1,3-Dichloropropene ug/L 20 23.5 118 70-130
Trichloroethene ug/L 20 23.2 116 70-130
Trichlorofluoromethane ug/L 20 24.6 123 62-130
Vinyl chloride ug/L 20 18.9 94 62-130
1,2-Dichloroethane-d4(S) % 118 70-130
4-Bromofluorobenzene(S) % 100 70-130
Toluene-d8(S) % 101 70-130
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4059852 4059853
MS MSD
92672544002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,1,1-Trichloroethane ug/L ND 20 20 27.3 23.6 136 118 70-150 15
1,1,2,2-Tetrachloroethane ug/L ND 20 20 25.2 22.6 126 113 69-142 11
1,1,2-Trichloroethane ug/L ND 20 20 24.7 22.9 123 115 70-138 7
1,1-Dichloroethane ug/L ND 20 20 25.6 21.8 128 109 70-150 16
1,1-Dichloroethene ug/L ND 20 20 26.6 23.6 133 118 70-156 12
1,2-Dichlorobenzene ug/L ND 20 20 25.0 23.0 125 115 70-141 8
1,2-Dichloroethane ug/L ND 20 20 25.1 23.5 125 118 69-143 6
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 30

9800 KinceyAve. Suite 100
-(wila�Q Huntersville,NC 28078
(�( v [phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4059852 4059853
MS MSD
92672544002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,2-Dichloropropane ug/L ND 20 20 25.7 24.6 128 123 70-156 4
1,3-Dichlorobenzene ug/L ND 20 20 26.2 23.6 131 118 70-143 10
1,4-Dichlorobenzene ug/L ND 20 20 25.8 23.4 129 117 70-142 10
Benzene ug/L ND 20 20 24.5 22.5 122 112 70-142 9
Bromodichloromethane ug/L 4.2 20 20 31.5 29.4 137 126 70-139 7
Bromoform ug/L ND 20 20 26.9 23.9 135 120 64-140 12
Bromomethane ug/L ND 20 20 16.0 14.8 80 74 28-192 8
Carbon tetrachloride ug/L ND 20 20 30.0 27.5 150 138 70-140 9 M1
Chlorobenzene ug/L ND 20 20 25.9 24.1 129 121 70-141 7
Chloroethane ug/L ND 20 20 23.1 19.3 115 97 58-191 18
Chloroform ug/L 5.6 20 20 33.0 27.6 137 110 70-138 18
Chloromethane ug/L ND 20 20 18.8 16.9 94 85 43-162 11
cis-1,2-Dichloroethene ug/L ND 20 20 25.3 22.6 127 113 70-143 11
cis-1,3-Dichloropropene ug/L ND 20 20 25.9 23.7 130 119 68-151 9
Dibromochloromethane ug/L ND 20 20 29.7 26.5 142 126 70-144 11
Ethylbenzene ug/L ND 20 20 25.8 24.3 129 121 70-143 6
Methylene Chloride ug/L ND 20 20 24.9 22.4 124 112 70-144 11
Tetrachloroethene ug/L ND 20 20 26.1 24.6 131 123 70-143 6
uene ug/L ND 20 20 24.1 22.7 121 114 69-144 6
ns-1,2-Dichloroethene ug/L ND 20 20 25.9 23.3 129 116 70-151 11
trans-1,3-Dichloropropene ug/L ND 20 20 25.7 24.4 129 122 70-139 5
Trichloroethene ug/L ND 20 20 25.6 24.0 128 120 70-142 6
Trichlorofluoromethane ug/L ND 20 20 24.6 22.5 123 112 62-146 9
Vinyl chloride ug/L ND 20 20 17.9 16.4 89 82 61-162 8
1,2-Dichloroethane-d4(S) % 108 103 70-130
4-Bromofluorobenzene(S) % 98 98 70-130
Toluene-d8(S) % 100 103 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 30

/'�/'�^ 9800 Kincey Ave. Suite 100
/// _G Huntersville,NC 28078
fir!V [phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
QC Batch: 780807 Analysis Method: EPA 625.1
QC Batch Method: EPA 625.1 Analysis Description: 625 MSS
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92672544002
METHOD BLANK: 4050693 Matrix: Water
Associated Lab Samples: 92672544002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,2,4-Trichlorobenzene ug/L ND 5.0 06/16/23 17:01
2,2'-Oxybis(1-chloropropane) ug/L ND 5.0 06/16/23 17:01
2,4,6-Trichlorophenol ug/L ND 10.0 06/16/23 17:01
2,4-Dichlorophenol ug/L ND 5.0 06/16/23 17:01
2,4-Dimethylphenol ug/L ND 10.0 06/16/23 17:01
2,4-Dinitrophenol ug/L ND 50.0 06/16/23 17:01
2,4-Dinitrotoluene ug/L ND 5.0 06/16/23 17:01
2,6-Dinitrotoluene ug/L ND 5.0 06/16/23 17:01
2-Chloronaphthalene ug/L ND 5.0 06/16/23 17:01
2-Chlorophenol ug/L ND 5.0 06/16/23 17:01
2-Nitrophenol ug/L ND 5.0 06/16/23 17:01
3,3'-Dichlorobenzidine ug/L ND 10.0 06/16/23 17:01 IL
A 5-Dinitro-2-methylphenol ug/L ND 10.0 06/16/23 17:01
3romophenylphenyl ether ug/L ND 5.0 06/16/23 17:01
hloro-3-methylphenol ug/L ND 5.0 06/16/23 17:01
4-Chlorophenylphenyl ether ug/L ND 5.0 06/16/23 17:01
4-Nitrophenol ug/L ND 10.0 06/16/23 17:01
Acenaphthene ug/L ND 5.0 06/16/23 17:01
Acenaphthylene ug/L ND 5.0 06/16/23 17:01
Anthracene ug/L ND 5.0 06/16/23 17:01
Benzo(a)anthracene ug/L ND 5.0 06/16/23 17:01
Benzo(a)pyrene ug/L ND 5.0 06/16/23 17:01
Benzo(b)fluoranthene ug/L ND 5.0 06/16/23 17:01
Benzo(g,h,i)perylene ug/L ND 5.0 06/16/23 17:01
Benzo(k)fluoranthene ug/L ND 5.0 06/16/23 17:01
bis(2-Chloroethoxy)methane ug/L ND 10.0 06/16/23 17:01
bis(2-Chloroethyl)ether ug/L ND 5.0 06/16/23 17:01
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 06/16/23 17:01
Butylbenzylphthalate ug/L ND 5.0 06/16/23 17:01
Chrysene ug/L ND 5.0 06/16/23 17:01
Di-n-butylphthalate ug/L ND 5.0 06/16/23 17:01
Di-n-octylphthalate ug/L ND 5.0 06/16/23 17:01
Dibenz(a,h)anthracene ug/L ND 5.0 06/16/23 17:01
I Diethylphthalate ug/L ND 5.0 06/16/23 17:01
Dimethylphthalate ug/L ND 5.0 06/16/23 17:01
Fluoranthene ug/L ND 5.0 06/16/23 17:01
Fluorene ug/L ND 5.0 06/16/23 17:01
Hexachloro-1,3-butadiene ug/L ND 5.0 06/16/23 17:01
Hexachlorobenzene ug/L ND 5.0 06/16/23 17:01
Hexachlorocyclopentadiene ug/L ND 10.0 06/16/23 17:01
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 14 of 30

- win/'�^ 9800 Kincey Ave. Suite 100
/�/ G Huntersville,NC 28078
���!!!V [phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
METHOD BLANK: 4050693 Matrix: Water
Associated Lab Samples: 92672544002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Hexachloroethane ug/L ND 5.0 06/16/23 17:01
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 06/16/23 17:01
Isophorone ug/L ND 10.0 06/16/23 17:01
N-Nitroso-di-n-propylamine ug/L ND 5.0 06/16/23 17:01
N-Nitrosodimethylamine ug/L ND 5.0 06/16/23 17:01
N-Nitrosodiphenylamine ug/L ND 10.0 06/16/23 17:01
Naphthalene ug/L ND 5.0 06/16/23 17:01
Nitrobenzene ug/L ND 5.0 06/16/23 17:01
Pentachlorophenol ug/L ND 10.0 06/16/23 17:01
Phenanthrene ug/L ND 5.0 06/16/23 17:01
Phenol ug/L ND 5.0 06/16/23 17:01
Pyrene ug/L ND 5.0 06/16/23 17:01
2,4,6-Tribromophenol(S) % 113 10-137 06/16/23 17:01
2-Fluorobiphenyl(S) % 79 15-120 06/16/23 17:01
2-Fluorophenol(S) % 74 10-120 06/16/23 17:01
Nitrobenzene-d5(S) % 91 10-120 06/16/23 17:01
Phenol-d6(S) % 62 10-120 06/16/23 17:01
Tarphenyl-d14(S) % 118 11-131 06/16/23 17:01
LABORATORY CONTROL SAMPLE: 4050694
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,2,4-Trichlorobenzene ug/L 50 39.8 80 44-142
2,2'-Oxybis(1-chloropropane) ug/L 50 44.7 89 36-166
2,4,6-Trichlorophenol ug/L 50 53.1 106 37-144
2,4-Dichlorophenol ug/L 50 54.0 108 1-191
2,4-Dimethylphenol ug/L 50 52.6 105 32-119
2,4-Dinitrophenol ug/L 250 319 128 1-181
2,4-Dinitrotoluene ug/L 50 61.0 122 39-139
2,6-Dinitrotoluene ug/L 50 58.1 116 50-158
2-Chloronaphthalene ug/L 50 49.0 98 60-118
2-Chlorophenol ug/L 50 50.0 100 23-134
2-Nitrophenol ug/L 50 56.1 112 29-182
3,3'-Dichlorobenzidine ug/L 100 69.1 69 1-262 IL
4,6-Dinitro-2-methylphenol ug/L 100 126 126 1-181
4-Bromophenylphenyl ether ug/L 50 52.2 104 53-127
4-Chloro-3-methylphenol ug/L 100 109 109 22-147
4-Chlorophenylphenyl ether ug/L 50 52.0 104 25-158
4-Nitrophenol ug/L 250 177 71 1-132
Acenaphthene ug/L 50 51.9 104 47-145
Acenaphthylene ug/L 50 52.4 105 33-145
Anthracene ug/L 50 50.7 101 1-166
Benzo(a)anthracene ug/L 50 54.9 110 33-143
Benzo(a)pyrene ug/L 50 55.8 112 17-163
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 15 of 30

ace • 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
LABORATORY CONTROL SAMPLE: 4050694
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Benzo(b)fluoranthene ug/L 50 58.9 118 24-159
Benzo(g,h,i)perylene ug/L 50 69.9 140 1-219
Benzo(k)fluoranthene ug/L 50 60.1 120 11-162
bis(2-Chloroethoxy)methane ug/L 50 51.5 103 33-184
bis(2-Chloroethyl)ether ug/L 50 50.6 101 12-158
bis(2-Ethylhexyl)phthalate ug/L 50 60.7 121 8-158
Butylbenzylphthalate ug/L 50 61.9 124 1-152
Chrysene ug/L 50 57.7 115 17-168
Di-n-butylphthalate ug/L 50 59.1 118 1-118
Di-n-octylphthalate ug/L 50 62.2 124 4-146
Dibenz(a,h)anthracene ug/L 50 69.6 139 1-227
Diethylphthalate ug/L 50 58.3 117 1-114 L1
Dimethylphthalate ug/L 50 54.4 109 1-112
Fluoranthene ug/L 50 58.7 117 26-137
Fluorene ug/L 50 56.9 114 59-121
Hexachloro-1,3-butadiene ug/L 50 30.9 62 24-116
Hexachlorobenzene ug/L 50 54.6 109 1-152
Hexachlorocyclopentadiene ug/L 50 36.2 72 25-150
Hexachloroethane ug/L 50 26.7 53 40-113
leno(1,2,3-cd)pyrene ug/L 50 69.1 138 1-171
:phorone ug/L 50 52.1 104 21-196
N-Nitroso-di-n-propylamine ug/L 50 51.8 104 1-230
N-Nitrosodimethylamine ug/L 50 40.6 81 25-150
N-Nitrosodiphenylamine ug/L 50 47.8 96 25-150
Naphthalene ug/L 50 43.0 86 21-133
Nitrobenzene ug/L 50 48.4 97 35-180
Pentachlorophenol ug/L 100 121 121 14-176
Phenanthrene ug/L 50 57.1 114 54-120
Phenol ug/L 50 33.3 67 5-112
Pyrene ug/L 50 56.3 113 52-115
2,4,6-Tribromophenol(S) % 118 10-137
2-Fluorobiphenyl(S) % 91 15-120
2-Fluorophenol(S) % 75 10-120
Nitrobenzene-d5(S) % 101 10-120
Phenol-d6(S) % 61 10-120
Terphenyl-d14(S) % 113 11-131
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4050695 4050696
MS MSD
92668974001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,2,4-Trichlorobenzene ug/L ND 100 100 80.4 64.7 80 65 44-142 22
2,2'-Oxybis(1-chloropropane) ug/L ND 100 100 92.8 87.5 93 88 36-166 6
2,4,6-Trichlorophenol ug/L ND 100 100 114 116 114 116 37-144 2
2,4-Dichlorophenol ug/L ND 100 100 110 111 110 111 1-191 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 16 of 30

ace 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4050695 4050696
MS MSD
92668974001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
2,4-Dimethylphenol ug/L ND 100 100 111 115 111 115 32-119 3
2,4-Dinitrophenol ug/L ND 500 500 712 698 142 140 1-181 2
2,4-Dinitrotoluene ug/L ND 100 100 130 128 130 128 39-139 1
2,6-Dinitrotoluene ug/L ND 100 100 124 123 124 123 50-158 1
2-Chloronaphthalene ug/L ND 100 100 106 94.9 106 95 60-118 11
2-Chlorophenol ug/L ND 100 100 104 102 104 102 23-134 2
2-Nitrophenol ug/L ND 100 100 116 120 116 120 29-182 3
3,3'-Dichlorobenzidine ug/L ND 200 200 202 181 101 91 1-262 11 IL
4,6-Dinitro-2-methylphenol ug/L ND 200 200 273 266 137 133 1-181 3
4-Bromophenylphenyl ether ug/L ND 100 100 103 107 103 107 53-127 4
4-Chloro-3-methylphenol ug/L ND 200 200 210 215 105 107 22-147 2
4-Chlorophenylphenyl ether ug/L ND 100 100 109 108 109 108 25-158 1
4-Nitrophenol ug/L ND 500 500 410 388 82 78 1-132 5
Acenaphthene ug/L ND 100 100 109 105 109 105 47-145 3
Acenaphthylene ug/L ND 100 100 109 104 109 104 33-145 4
Anthracene ug/L ND 100 100 107 108 107 108 1-166 0
Benzo(a)anthracene ug/L ND 100 100 111 122 111 122 33-143 9
Benzo(a)pyrene ug/L ND 100 100 121 118 121 118 17-163 2
nzo(b)fluoranthene ug/L ND 100 100 123 122 123 122 24-159 1
nzo(g,h,i)perylene ug/L ND 100 100 145 146 145 146 1-219 1
Benzo(k)fluoranthene ug/L ND 100 100 125 123 125 123 11-162 2
bis(2-Chloroethoxy)methane ug/L ND 100 100 102 101 102 101 33-184 1
bis(2-Chloroethyl)ether ug/L ND 100 100 103 101 103 101 12-158 2
bis(2-Ethylhexyl)phthalate ug/L ND 100 100 129 130 127 128 8-158 1
Butylbenzylphthalate ug/L ND 100 100 119 126 119 126 1-152 5
Chrysene ug/L ND 100 100 116 121 116 121 17-168 4
Di-n-butylphthalate ug/L ND 100 100 122 124 122 124 1-118 1 M1
Di-n-octylphthalate ug/L ND 100 100 130 132 130 132 4-146 2
Dibenz(a,h)anthracene ug/L ND 100 100 143 146 143 146 1-227 2
Diethylphthalate ug/L ND 100 100 122 121 122 121 1-114 2 MO
Dimethylphthalate ug/L ND 100 100 114 115 114 115 1-112 1 M1
Fluoranthene ug/L ND 100 100 122 127 122 127 26-137 3
Fluorene ug/L ND 100 100 120 114 120 114 59-121 5
Hexachloro-1,3-butadiene ug/L ND 100 100 67.5 55.7 68 56 24-116 19
Hexachlorobenzene ug/L ND 100 100 110 112 110 112 1-152 2
Hexachlorocyclopentadiene ug/L ND 100 100 74.8 62.5 75 63 25-150 18
Hexachloroethane ug/L ND 100 100 67.2 57.6 67 58 40-113 15
Indeno(1,2,3-cd)pyrene ug/L ND 100 100 141 140 141 140 1-171 1
Isophorone ug/L ND 100 100 103 103 103 103 21-196 0
N-Nitroso-di-n-propylamine ug/L ND 100 100 104 103 104 103 1-230 1
N-Nitrosodimethylamine ug/L ND 100 100 84.2 81.0 84 81 25-150 4
N-Nitrosodiphenylamine ug/L ND 100 100 91.0 103 91 103 25-150 13
Naphthalene ug/L ND 100 100 88.1 75.8 88 76 21-133 15
Nitrobenzene ug/L ND 100 100 97.4 95.4 97 95 35-180 2
Pentachlorophenol ug/L ND 200 200 256 268 128 134 14-176 5
Phenanthrene ug/L ND 100 100 114 115 114 115 54-120 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 17 of 30

gace [phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4050695 4050696
MS MSD
92668974001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenol ug/L ND 100 100 67.9 67.1 68 67 5-112 1
Pyrene ug/L ND 100 100 114 120 114 120 52-115 5 M1
2,4,6-Tribromophenol(S) % 115 117 10-137
2-Fluorobiphenyl(S) % 94 90 15-120
2-Fluorophenol(S) % 73 69 10-120
Nitrobenzene-d5(S) % 94 94 10-120
Phenol-d6(S) % 59 56 10-120
Terphenyl-d14(S) % 109 108 11-131
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 18 of 30

(tFace
[phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
QC Batch: 781025 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92672544001
METHOD BLANK: 4051824 Matrix: Water
Associated Lab Samples: 92672544001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 06/16/23 13:23
LABORATORY CONTROL SAMPLE: 4051825
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 266 106 90-110
SAMPLE DUPLICATE: 4051826
92672494001 Dup
Parameter Units Result Result RPD Qualifiers
tal Dissolved Solids mg/L 71.0 69.0 3
SAMPLE DUPLICATE: 4051827
92672765002 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 212 220 4
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 19 of 30

(41ace- 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
QC Batch: 783189 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92672544001
METHOD BLANK: 4061983 Matrix: Water
Associated Lab Samples: 92672544001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 06/28/23 10:11
LABORATORY CONTROL SAMPLE: 4061984
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 5.1 103 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4061985 4061986
MS MSD
92672413001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
...rogen,Ammonia mg/L 38.1 5 5 43.1 43.2 101 102 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4061987 4061988
MS MSD
92672413002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 0.19 5 5 5.3 5.3 103 103 90-110 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 20 of 30

gac [phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
QC Batch: 782328 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92672544001
METHOD BLANK: 4058184 Matrix: Water
Associated Lab Samples: 92672544001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Kjeldahl,Total mg/L ND 0.50 06/23/23 05:05
LABORATORY CONTROL SAMPLE: 4058185
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Kjeldahl,Total mg/L 10 10.5 105 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4058186 4058187
MS MSD
92672639001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
....rogen,Kjeldahl,Total mg/L 23.7 10 10 31.1 31.2 75 75 90-110 0 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 21 of 30

(1ace
[phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
QC Batch: 782827 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate+Nitrite,preserved
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92672544001
METHOD BLANK: 4060772 Matrix: Water
Associated Lab Samples: 92672544001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, NO2 plus NO3 mg/L ND 0.040 06/24/23 13:11
LABORATORY CONTROL SAMPLE: 4060773
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen, NO2 plus NO3 mg/L 2.5 2.5 100 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4060774 4060775
MS MSD
92672261004 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
..:rogen,NO2 plus NO3 mg/L 1.3 2.5 2.5 3.9 3.9 105 104 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4060776 4060777
MS MSD
92672261005 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,NO2 plus NO3 mg/L 2.3 2.5 2.5 4.9 4.8 102 101 90-110 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 22 of 30

-/'�/'c/'� 9800 Kincey Ave. Suite 100
/J/ /�+ Huntersville,NC 28078
(�(�,/�J [phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
QC Batch: 782223 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus,Total
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92672544001
METHOD BLANK: 4057644 Matrix: Water
Associated Lab Samples: 92672544001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 06/22/23 15:07
LABORATORY CONTROL SAMPLE: 4057645
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4057646 4057647
MS MSD
92672302001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
oosphorus mg/L 1.5 2.5 2.5 4.1 4.1 101 103 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4057648 4057649
MS MSD
92672413001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 41.4 2.5 2.5 44.2 43.0 113 64 90-110 3 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 23 of 30

(/ Face
[phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
QC Batch: 782928 Analysis Method: EPA 420.4 Rev 1.0 1993
QC Batch Method: EPA 420.4 Rev 1.0 1993 Analysis Description: 420.4 Phenolics
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92672544002
METHOD BLANK: 4060978 Matrix: Water
Associated Lab Samples: 92672544002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phenolics,Total Recoverable mg/L ND 0.020 06/27/23 08:45
LABORATORY CONTROL SAMPLE: 4060979
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phenolics,Total Recoverable mg/L 0.05 0.051 102 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4060980 4060981
MS MSD
92671942002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
"enolics,Total Recoverable mg/L 0.037 0.05 0.05 0.070 0.063 66 51 90-110 11 M1,R1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4060982 4060983
MS MSD
92672006003 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenolics,Total Recoverable mg/L 0.067 0.05 0.05 0.082 0.074 29 14 90-110 9 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 24 of 30

9800 Kincey Ave. Suite100
Huntersville,NC 28078078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
QC Batch: 781564 Analysis Method: SM 4500-CN-E-2011
QC Batch Method: SM 4500-CN-E-2011 Analysis Description: 4500CNE Cyanide,Total
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92672544002
METHOD BLANK: 4054737 Matrix: Water
Associated Lab Samples: 92672544002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Cyanide mg/L ND 0.010 06/21/23 16:17
LABORATORY CONTROL SAMPLE: 4054738
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Cyanide mg/L 0.1 0.091 91 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4054739 4054740
MS MSD
92673016001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
,snide mg/L ND 0.1 0.1 0.10 0.049 94 43 80-120 69 M1,R1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4054741 4054742
MS MSD
92673017001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Cyanide mg/L ND 0.1 0.1 0.029 0.10 26 97 80-120 110 M1,R1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 25 of 30

9800 Kincey Ave. Suite 100
Huntersville,NC 28078
[phone]
QUALIFIERS
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as
"Total"may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
ANALYTE QUALIFIERS
IL This analyte exceeded secondary source verification criteria low for the initial calibration.The reported results should be
considered an estimated value.
L1 Analyte recovery in the laboratory control sample(LCS)was above QC limits. Results for this analyte in associated
samples may be biased high.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 26 of 30

gace- 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: EFF PPA-Revised Report
Pace Project No.: 92672544
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92672544002 EFF PPA GRAB EPA 1664E 781694
92672544001 EFF PPA COMP EPA 200.7 Rev 4.4 1994 780811 EPA 200.7 Rev 4.4 1994 780864
92672544001 EFF PPA COMP EPA 200.8 Rev 5.4 1994 784549 EPA 200.8 Rev 5.4 1994 784584
92672544002 EFF PPA GRAB EPA 625.1 780807 EPA 625.1 781183
92672544002 EFF PPA GRAB EPA 624.1 782662
92672544001 EFF PPA COMP SM 2540C-2015 781025
92672544001 EFF PPA COMP EPA 350.1 Rev 2.0 1993 783189
92672544001 EFF PPA COMP EPA 351.2 Rev 2.0 1993 782328 EPA 351.2 Rev 2.0 1993 782522
92672544001 EFF PPA COMP EPA 353.2 Rev 2.0 1993 782827
92672544001 EFF PPA COMP EPA 365.1 Rev 2.0 1993 782223 EPA 365.1 Rev 2.0 1993 782382
92672544002 EFF PPA GRAB EPA 420.4 Rev 1.0 1993 782928 EPA 420.4 Rev 1.0 1993 782990
92672544002 EFF PPA GRAB SM 4500-CN-E-2011 781564 SM 4500-CN-E-2011 781984
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:07/20/2023 02:12 PM without the written consent of Pace Analytical Services,LLC. Page 27 of 30

• �• v-r r•nr-rrvrl r-VVVJ VVG JQlfif./IC 1+U11UILIUt1 upon mecelpt
ti-gace -
Effective Date: 11/14/2022
Laboratory receiving samples:
Asheville❑ Eden❑ Greenwood ❑ Huntersville Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑
Sample Condition Client Name: wO# ° 92672544
Upon Receipt -• Project 6
C(47 of A('Y'
❑F d Ex ❑UPS ❑LISPS
Courier: ['Client Hill I III II I III I I III
❑Commercial [Pace ❑Other:
/ 92672544
Custody Seal Present? ❑Yes No Seals Intact? Oyes 'No
iDate/Initials Person Examining Contents: `� 6���j�/
Packing Material: ❑Bubble Wrap LJBubble Bags ❑None ❑ Other Biological Tissue zen?
Thermometer: Dyes ❑No N/A
❑IR Gun ID: 9L`�-70 Type of Ice: EiWet ❑Blue Done
cQ9f Correction Factor:
Cooler Temp: Add/Subtract(°C) ()et, Temp should be above freezing to 6°C
C . ❑Samples out of temp criteria.Samples on ice,cooling process
Cooler Temp Corrected(° / (/ has begun
USDA Regulated Soil( N/A,water sample)
Did samples originate in a quarantine zone within the United States:CA,NY,or SC Did samples originate from a foreign source(internationally,
(check maps)?Dyes ONo including Hawaii and Puerto Rico)?Oyes ONo
Comments/Discrepancy:
Chain of Custody Present? fJY s ONo ON/A 1.
Samples Arrived within Hold Time? Yes ❑ ON/A 2.
_ — Short Hold Tlmr Analytic(<77 hr)�_._ QYes— ON/A
Rush Turn Around Time Requested? Oyes No ON/A 4.
Sufficient Volume? ies ONo ON/A 5.
Correct Containers Used? es ONo ON/A 6.
-Pace Containers Used? es ONo ON/A
Containers Intact? Yes ONo ON/A 7.
• [hes QNO 1711/A �.
Sample Labels Match COC? \ 6��,'Yes ONo ON/A 9.
-Includes Date/Time/ID/Analysis Matrix:
SIT
Headspace in VOA Vials(>5-6mm)? ❑Yes IJE�o ON/A 10.
Trip Blank Present? Oyes �N ON/A 11.
Trip Blank Custody Seals Present? Oyes dNo ON/A
COMMENTS/SAMPLE DISCREPANCY Field Data Required? Dyes ONo
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date:
Page 28 of 30
Qualtrax ID: 69614 p,,,o 1 esf

;'dace
Effective Date: 11/14/2022
WO# : 92672544
*Check mark top half of box if pH and/or dechlorination is verified and Project PM: TIH Due Date: 06/28/23
within the acceptance range for preservation samples. CLIENT: 92—Ci tyofMen
Exceptions:VOA,Coliform,TOC,Oil and Grease,DRO/8015(water)DOC,LLHg
**Bottom half of box is to list number of bottles
***Check all unpreserved Nitrates for chlorine
v
Z U U U Ze
z z z z _ a a a O1 z _ A
Z N .....
Z N Q Z 9 — ¢ Z ,a ip M
N d al V v ^ C Gj N v V 2 Z t, 1 1 Q1 T Q
Z i_ i'_ a, V a. N N Z v x a ¢ v Y a < g e z a
C Z 1a a 2 a !?• 2 v i n z 2 a o z Z O aa, 2
a a n E. O p u s A v a a a p v ` 8 v Z a i u v N a, 3 d
7 7 . C N z
z O C lJ n O N_ O 2 rN Y O 0. C. N M = C c a
L.
_ N Z v o I74 c a > a a'
? ° 7
u u u 7 u u u t y S Z U c m .41 �
N N - U.73 N N •"• N d al a W 2 4✓ = Z 3 _ 5 Y u u .0 n a7
a a a _� —° n °a. m E E E E Q Q ¢ a ;,, v _� E E a
J J J 10. J J CL E < Q J Q J <
> > > O a. n vl in a J v1 Q
E E E ;, E E E E « o`, v E E J J J J .J J —• J J
N o 8 = ,n o ,n ,n = = o _« o E E E E E E !� E E E E E E
rl Vl ri N ,Ny .N-1 3 rl e-1 N ..y ..�i 4 �f Vi rN1 ry 'A 2 N
E 7r Pn 74 71 Yt m W m LL 7 S
o m a v ' •. '+ m vi m ate. m '4; C en N. -. a Cl T. tO v6 tO
Ill m m m m m m m m 3 �' a a a �' �'
kjk.likk
O Y 7 N ut m >1h .
-
.........."...
3 14 1 liggilglinimi. iiim 0000111111
I ilk
Ilkh,,,,k1.
, 5 g 141‘11 a
2 .61111111111211:111111111 --kilti iiii
78 .1111111441 to Rqk
9 hi h„„ii,,, 3
II
to ......... h
NN
11 gqgg
12
g ggg k
pH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot#
adjusted added
—
Note: Whenever there is a discrepancy affecting North Carolina compliance samples,a copy of this form will be sent to the North Carolina DENR Certification Office(i.e.
Out of hold,incorrect preservative,out of temp,incorrect containers.
Page 29 of 30
Qualtrax ID:69614 Pane 9 of 7

0
co
0
cn
Pace Analytical Services, LLC
/� 9800 Kince Ave. Suite 100 a
YBCe Chain of Custody Record Huntersv.11e, NC 28078 Number
Telephone No. [phone]
Project Manager:Tyreik Hooks
Client Report to Contact Telephone No./Fax No./Email
City of Monroe WWTP(pretreatment) Kevin Keesler 704-282-4632/[e-mail]
Address Sampler's Signature
775 Treeway Drive Analysis(Attach List if more space is needed) Page
City State Zip Code x Lry ;. Bal---"--
Monroe N.C. 28110 Printed Name 1 of--±2
Project Name
EFF PPA Kenneth Bartlett
Project Number C-
���j Matrix No.of Containers ty Z �
t'�3 .n o Preseryati�n Type_ " 0
0 v U
Sample ID/Description 0 E o a m Q a c Z (? c m G T :^ Remarks/Cooler
(Containers for each sample Start End " ° 3 ' a o r-, = r^ N ^ To'-
'� �] ( (.�t�
may be combined on one line) Date/Time Date/Time o Z° D _ I I a Z Z I 2 I 6 0._ rZU -7ZS ! /
EFF PPA !id h0/3 G/3 lo.2 x x x x I /
EFF PPA /,_z :„3 /3 x x x x all
EFF PPA 4 1or3 %r hill. x x , x x C"L/
EFF PPA /i, k:r3 b/
L /7 l012- x x x x C)41
r
,'\-.`-:\s- Ph, N; ea/
EFF PPA 17.3 1 c,;y 1 s,�,fA3,�t, 1, ,
x x x S►,, s, i- •?-' Cd,
1/0/3
x CC. C(A
_I . _
EFFPPA 4//7C5111 x 1 x x Q. •1_,_
EFFPPA 1
/3Cf 0 x j x , j x c'kZ_
EFF PPA "i cfiri A > LIcci,Z,
EFF PPA �//3 0121 X >C
EFF PPA ‘67 v`1Iy :'( x ei: L
Illi Possible Hazard Identification
Non-Hazard Flammable Skin Irritant Noe:All samples are retained for six weeks from re:eipt unless other
© ❑ ❑ Sample Disposal by Lab
❑Poison ❑Unknown arrangements are made
'Relinquished By: _�� 'Date ITime f J 3Q
lia,Yo✓I.- ! p
Q' l/ 6,4/45 1 /3z

--1
u..9.0.....ncey ve 100
9800 Kincey Ave. Suite 100
a�e Huntersville,NC 28078
[phone]
March 26, 2024
Kevin Keesler
City of Monroe
PO Box 69
Monroe, NC 28111
RE: Project: EFF PPA
Pace Project No.: 92717151
Dear Kevin Keesler:
Enclosed are the analytical results for sample(s)received by the laboratory on March 06, 2024. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
•Pace Analytical Services-Asheville
•Pace Analytical Services-Charlotte
•Pace Analytical Services-Ormond Beach
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
kfg
Tyriek Hooks
[e-mail]
704-977-0947
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 1 of 51

9800 Kincey Ave. Suite 100
ace Huntersville,NC 28078
[phone]
CERTIFICATIONS
Project: EFF PPA
Pace Project No.: 92717151
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach,FL 32174 Mississippi Certification: FL NELAC Reciprocity
Alaska DEC-CS/UST/LUST Missouri Certification#:236
Alabama Certification#:41320 Montana Certification#:Cert 0074
California Certification#3096 Nebraska Certification: NE-OS-28-14
Colorado Certification:FL NELAC Reciprocity New Hampshire Certification#:2958
Connecticut Certification#:PH-0216 New Jersey Certification#:FL022
Delaware Certification: FL NELAC Reciprocity New York Certification#: 11608
DoD-ANAB#:ADE-3199 North Carolina Environmental Certificate#:667
Florida Certification#:E83079 North Carolina Certification#: 12710
Georgia Certification#:955 North Dakota Certification#: R-216
Guam Certification: FL NELAC Reciprocity Ohio DEP 87780
Hawaii Certification:FL NELAC Reciprocity Oklahoma Certification#:D9947
Illinois Certification#:200068 Pennsylvania Certification#:68-00547
Indiana Certification:FL NELAC Reciprocity Puerto Rico Certification#: FLO1264
Kansas Certification#:E-10383 South Carolina Certification:#96042001
Kentucky Certification#:90050 Tennessee Certification#:TN02974
Louisiana Certification#: FL NELAC Reciprocity Texas Certification:FL NELAC Reciprocity
Louisiana Environmental Certificate#:05007 US Virgin Islands Certification: FL NELAC Reciprocity
Maine Certification#:FL01264 Virginia Environmental Certification#:460165
Maryland Certification:#346 West Virginia Certification#:9962C
Massachusetts Certification#:M-FL1264 Wisconsin Certification#:399079670
Michigan Certification#:9911 Wyoming(EPA Region 8): FL NELAC Reciprocity
ce Analytical Services Charlotte
South Carolina Laboratory ID:99006 South Carolina Certification#:99006001
9800 Kincey Ave.Ste 100,Huntersville,NC 28078 South Carolina Drinking Water Cert.#:99006003
North Carolina Drinking Water Certification#:37706 Florida/NELAP Certification#: E87627
North Carolina Field Services Certification#:5342 Kentucky UST Certification#:84
North Carolina Wastewater Certification#: 12 Louisiana DoH Drinking Water#:LA029
South Carolina Laboratory ID:99006 VirginiaNELAP Certification#:460221
Pace Analytical Services Asheville
2225 Riverside Drive,Asheville,NC 28804 South Carolina Laboratory ID:99030
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
North Carolina Drinking Water Certification#:37712 VirginiaNELAP Certification#:460222
North Carolina Wastewater Certification#:40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 2 of 51

/'� 9800 Kincey Ave. Suite 100
irk V V Huntersville,NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: EFF PPA
Pace Project No.: 92717151
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92717151001 EFF PPA EPA 200.7 AME 1 PASI-O
EPA 200.8 LEC 12 PASI-O
SM 2540C-2015 RVS 1 PASI-A
EPA 350.1 Rev 2.0 1993 ARJ 1 PASI-A
EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A
EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A
EPA 365.1 Rev 2.0 1993 ZJP 1 PASI-A
EPA 420.4 Rev 1.0 1993 ARJ 1 PASI-A
92717151002 EFF PPA EPA 1664B YY 1 PASI-C
EPA 625.1 PKS 60 PASI-C
EPA 624.1 SAS 37 PASI-C
92717151005 EFF PPA EPA 625.1 PKS 58 PASI-C
PASI-A=Pace Analytical Services-Asheville
PASI-C=Pace Analytical Services-Charlotte
PASI-O=Pace Analytical Services-Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,LLC. Page 3 of 51

9800 Kincey Ave. Suite 100
a V(/'_�e Huntersville,NC 28078
[phone]
' ANALYTICAL RESULTS
Project: EFF PPA
Pace Project No.: 92717151
Sample: EFF PPA Lab ID: 92717151001 Collected: 03/05/24 10:13 Received: 03/06/24 11:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method: EPA 200.7
Pace Analytical Services-Ormond Beach
Tot Hardness asCaCO3(SM 2340B 83800 ug/L 3310 1 03/12/24 09:39 03/13/24 00:41
200.8 MET ICPMS Analytical Method:EPA 200.8 Preparation Method:EPA 200.8
Pace Analytical Services-Ormond Beach
Antimony ND ug/L 1.0 1 03/11/24 04:41 03/11/24 20:00 7440-36-0
Arsenic ND ug/L 1.0 1 03/11/24 04:41 03/11/24 20:00 7440-38-2
Beryllium ND ug/L 0.10 1 03/11/24 04:41 03/11/24 20:00 7440-41-7
Cadmium ND ug/L 0.10 1 03/11/24 04:41 03/11/24 20:00 7440-43-9
Chromium ND ug/L 1.0 1 03/11/24 04:41 03/11/24 20:00 7440-47-3
Copper 6.5 ug/L 1.0 1 03/11/24 04:41 03/11/24 20:00 7440-50-8
Lead ND ug/L 1.0 1 03/11/24 04:41 03/11/24 20:00 7439-92-1
Nickel 6.6 ug/L 1.0 1 03/11/24 04:41 03/11/24 20:00 7440-02-0
Selenium ND ug/L 2.0 1 03/11/24 04:41 03/11/24 20:00 7782-49-2
Silver ND ug/L 0.50 1 03/11/24 04:41 03/11/24 20:00 7440-22-4
Thallium ND ug/L 1.0 1 03/11/24 04:41 03/11/24 20:00 7440-28-0
Zinc 72.1 ug/L 10.0 1 03/11/24 04:41 03/11/24 20:00 7440-66-6
-140C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services-Asheville
Total Dissolved Solids 314 mg/L 25.0 1 03/07/24 06:08
350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Ammonia ND mg/L 0.10 1 03/20/24 10:23 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen,Kjeldahl,Total 2.0 mg/L 0.50 1 03/13/24 19:30 03/14/24 06:57 7727-37-9
353.2 Nitrogen, NO2/NO3 pres. Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services-Asheville
Nitrogen, NO2 plus NO3 16.8 mg/L 0.24 6 03/21/24 11:41
365.1 Phosphorus,Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method:EPA 365.1 Rev 2.0 1993
Pace Analytical Services-Asheville
Phosphorus 1.6 mg/L 0.050 1 03/19/24 13:55 03/20/24 11:08 7723-14-0
420.4 Phenolics,Total Analytical Method: EPA 420.4 Rev 1.0 1993 Preparation Method: EPA 420.4 Rev 1.0 1993
Pace Analytical Services-Asheville
Phenolics,Total Recoverable 0.016 mg/L 0.0050 1 03/21/24 10:13 03/22/24 10:24 64743-03-9 P4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 4 of 51

9800 Kincey Ave. Suite 100
( Jace Huntersville,NC 28078
[phone]
ANALYTICAL RESULTS
Project: EFF PPA
Pace Project No.: 92717151
Sample: EFF PPA Lab ID: 92717151002 Collected: 03/05/24 10:55 Received: 03/06/24 11:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method: EPA 1664B
Pace Analytical Services-Charlotte
Oil and Grease ND mg/L 4.8 1 03/15/24 10:28
625 RVE Analytical Method:EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services-Charlotte
Acenaphthene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 83-32-9
Acenaphthylene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 208-96-8
Anthracene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 120-12-7
Benzidine ND ug/L 50.0 1 03/08/24 09:26 03/11/24 22:36 92-87-5
Benzo(a)anthracene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 56-55-3
Benzo(a)pyrene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 50-32-8
Benzo(b)fluoranthene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 205-99-2
Benzo(g,h,i)perylene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 191-24-2
Benzo(k)fluoranthene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 207-08-9
4-Bromophenylphenyl ether ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 101-55-3
Butylbenzylphthalate ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 85-68-7
4-Chloro-3-methylphenol ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 59-50-7
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 03/08/24 09:26 03/11/24 22:36 111-91-1
s(2-Chloroethyl)ether ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 111-44-4
•Chloronaphthalene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 91-58-7
2-Chlorophenol ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 95-57-8
4-Chlorophenylphenyl ether ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 7005-72-3
Chrysene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 218-01-9
Dibenz(a,h)anthracene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 53-70-3
3,3'-Dichlorobenzidine ND ug/L 10.0 1 03/08/24 09:26 03/11/24 22:36 91-94-1
2,4-Dichlorophenol ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 120-83-2
Diethylphthalate ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 03/08/24 09:26 03/11/24 22:36 105-67-9
Dimethylphthalate ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 131-11-3
Di-n-butylphthalate ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 03/08/24 09:26 03/11/24 22:36 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 03/08/24 09:26 03/11/24 22:36 51-28-5
2,4-Dinitrotoluene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 121-14-2
2,6-Dinitrotoluene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 606-20-2
Di-n-octylphthalate ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 117-84-0
1,2-Diphenylhydrazine ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 122-66-7
bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 117-81-7
Fluoranthene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 206-44-0
Fluorene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 86-73-7
Hexachloro-1,3-butadiene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 87-68-3
Hexachlorobenzene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 03/08/24 09:26 03/11/24 22:36 77-47-4
Hexachloroethane ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 193-39-5
Isophorone ND ug/L 10.0 1 03/08/24 09:26 03/11/24 22:36 78-59-1
Naphthalene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 91-20-3
"''robenzene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 98-95-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 5 of 51

gace '
9800 Kincey Ave. Suite 100
Huntersville,NC 28078
[phone]
ANALYTICAL RESULTS
Project: EFF PPA
Pace Project No.: 92717151
Sample: EFF PPA Lab ID: 92717151002 Collected: 03/05/24 10:55 Received: 03/06/24 11:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
625 RVE Analytical Method:EPA 625.1 Preparation Method:EPA 625.1
Pace Analytical Services-Charlotte
2-Nitrophenol ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 88-75-5
4-Nitrophenol ND ug/L 10.0 1 03/08/24 09:26 03/11/24 22:36 100-02-7
N-Nitrosodimethylamine ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 03/08/24 09:26 03/11/24 22:36 86-30-6
2,2'-Oxybis(1-chloropropane) ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 108-60-1
Pentachlorophenol ND ug/L 10.0 1 03/08/24 09:26 03/11/24 22:36 87-86-5
Phenanthrene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 85-01-8
Phenol ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 108-95-2
Pyrene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 129-00-0
1,2,4-Trichlorobenzene ND ug/L 5.0 1 03/08/24 09:26 03/11/24 22:36 120-82-1
2,4,6-Trichlorophenol ND ug/L 10.0 1 03/08/24 09:26 03/11/24 22:36 88-06-2
Surrogates
Nitrobenzene-d5(S) 52 % 10-120 1 03/08/24 09:26 03/11/24 22:36 4165-60-0
2-Fluorobiphenyl(S) 50 % 15-120 1 03/08/24 09:26 03/11/24 22:36 321-60-8
Terphenyl-d14(S) 76 % 11-131 1 03/08/24 09:26 03/11/24 22:36 1718-51-0
Phenol-d6(S) 23 % 10-120 1 03/08/24 09:26 03/11/24 22:36 13127-88-3
Fluorophenol(S) 39 % 10-120 1 03/08/24 09:26 03/11/24 22:36 367-12-4
1,6-Tribromophenol(S) 61 % 10-137 1 03/08/24 09:26 03/11/24 22:36 118-79-6
624 Volatile Organics Analytical Method: EPA 624.1
Pace Analytical Services-Charlotte
Acrolein ND ug/L 5.0 1 03/14/24 16:39 107-02-8
Acrylonitrile ND ug/L 5.0 1 03/14/24 16:39 107-13-1
Benzene ND ug/L 1.0 1 03/14/24 16:39 71-43-2
Bromodichloromethane 2.2 ug/L 2.0 1 03/14/24 16:39 75-27-4
Bromoform ND ug/L 2.0 1 03/14/24 16:39 75-25-2
Bromomethane ND ug/L 2.0 1 03/14/24 16:39 74-83-9
Carbon tetrachloride ND ug/L 2.0 1 03/14/24 16:39 56-23-5
Chlorobenzene ND ug/L 2.0 1 03/14/24 16:39 108-90-7
Chloroethane ND ug/L 2.0 1 03/14/24 16:39 75-00-3
2-Chloroethylvinyl ether ND ug/L 5.0 1 03/14/24 16:39 110-75-8
Chloroform ND ug/L 2.0 1 03/14/24 16:39 67-66-3
Chloromethane ND ug/L 2.0 1 03/14/24 16:39 74-87-3
Dibromochloromethane ND ug/L 2.0 1 03/14/24 16:39 124-48-1
1,2-Dichlorobenzene ND ug/L 2.0 1 03/14/24 16:39 95-50-1
1,3-Dichlorobenzene ND ug/L 2.0 1 03/14/24 16:39 541-73-1
1,4-Dichlorobenzene ND ug/L 2.0 1 03/14/24 16:39 106-46-7
1,1-Dichloroethane ND ug/L 2.0 1 03/14/24 16:39 75-34-3
1,2-Dichloroethane ND ug/L 2.0 1 03/14/24 16:39 107-06-2
1,1-Dichloroethene ND ug/L 2.0 1 03/14/24 16:39 75-35-4
cis-1,2-Dichloroethene ND ug/L 2.0 1 03/14/24 16:39 156-59-2
trans-1,2-Dichloroethene ND ug/L 2.0 1 03/14/24 16:39 156-60-5
1,2-Dichloropropane ND ug/L 2.0 1 03/14/24 16:39 78-87-5
cis-1,3-Dichloropropene ND ug/L 2.0 1 03/14/24 16:39 10061-01-5
r:nns-1,3-Dichloropropene ND ug/L 2.0 1 03/14/24 16:39 10061-02-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 6 of 51

9800 Kincey Ave. Suite 100
ace Huntersville,NC 28078
[phone]
ANALYTICAL RESULTS
Project: EFF PPA
Pace Project No.: 92717151
Sample: EFF PPA Lab ID: 92717151002 Collected: 03/05/24 10:55 Received: 03/06/24 11:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method: EPA 624.1
Pace Analytical Services-Charlotte
Ethylbenzene ND ug/L 1.0 1 03/14/24 16:39 100-41-4
Methylene Chloride ND ug/L 2.0 1 03/14/24 16:39 75-09-2
1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 03/14/24 16:39 79-34-5
Tetrachloroethene ND ug/L 2.0 1 03/14/24 16:39 127-18-4
Toluene ND ug/L 1.0 1 03/14/24 16:39 108-88-3
1,1,1-Trichloroethane ND ug/L 2.0 1 03/14/24 16:39 71-55-6
1,1,2-Trichloroethane ND ug/L 2.0 1 03/14/24 16:39 79-00-5
Trchloroethene ND ug/L 2.0 1 03/14/24 16:39 79-01-6
Trichlorofluoromethane ND ug/L 2.0 1 03/14/24 16:39 75-69-4
Vinyl chloride ND ug/L 2.0 1 03/14/24 16:39 75-01-4
Surrogates
4-Bromofluorobenzene(S) 97 % 70-130 1 03/14/24 16:39 460-00-4
Toluene-d8(S) 100 % 70-130 1 03/14/24 16:39 2037-26-5
1,2-Dichloroethane-d4(S) 102 % 70-130 1 03/14/24 16:39 17060-07-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 7 of 51

9800 Kincey Ave. Suite 100
ace Huntersville,NC 28078
[phone]
ANALYTICAL RESULTS
Project: EFF PPA
Pace Project No.: 92717151
Sample: EFF PPA Lab ID: 92717151005 Collected: 03/05/24 10:52 Received: 03/06/24 11:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
625 RVE Analytical Method:EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services-Charlotte
Acenaphthene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 83-32-9
Acenaphthylene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 208-96-8
Anthracene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 120-12-7
Benzo(a)anthracene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 56-55-3
Benzo(a)pyrene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 50-32-8
Benzo(b)fluoranthene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 205-99-2
Benzo(g,h,i)perylene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 191-24-2
Benzo(k)fluoranthene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 207-08-9
4-Bromophenylphenyl ether ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 101-55-3
Butylbenzylphthalate ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 85-68-7
4-Chloro-3-methylphenol ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 59-50-7
bis(2-Chloroethoxy)methane ND ug/L 10.0 1 03/12/24 10:28 03/13/24 14:19 111-91-1
bis(2-Chloroethyl)ether ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 111-44-4
2-Chloronaphthalene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 91-58-7
2-Chlorophenol ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 95-57-8
4-Chlorophenylphenyl ether ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 7005-72-3
Chrysene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 218-01-9
)enz(a,h)anthracene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 53-70-3
l-Dichlorobenzidine ND ug/L 10.0 1 03/12/24 10:28 03/13/24 14:19 91-94-1
2,4-Dichlorophenol ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 120-83-2
Diethylphthalate ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 03/12/24 10:28 03/13/24 14:19 105-67-9
Dimethylphthalate ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 131-11-3
Di-n-butylphthalate ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 84-74-2 L1
4,6-Dinitro-2-methylphenol ND ug/L 10.0 1 03/12/24 10:28 03/13/24 14:19 534-52-1
2,4-Dinitrophenol ND ug/L 50.0 1 03/12/24 10:28 03/13/24 14:19 51-28-5
2,4-Dinitrotoluene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 121-14-2
2,6-Dinitrotoluene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 606-20-2
Di-n-octylphthalate ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 117-84-0
bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 117-81-7
Fluoranthene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 206-44-0
Fluorene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 86-73-7
Hexachloro-1,3-butadiene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 87-68-3
Hexachlorobenzene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 03/12/24 10:28 03/13/24 14:19 77-47-4
Hexachloroethane ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 193-39-5
Isophorone ND ug/L 10.0 1 03/12/24 10:28 03/13/24 14:19 78-59-1
Naphthalene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 91-20-3
Nitrobenzene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 98-95-3
2-Nitrophenol ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 88-75-5
4-Nitrophenol ND ug/L 10.0 1 03/12/24 10:28 03/13/24 14:19 100-02-7
N-Nitrosodimethylamine ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.0 1 03/12/24 10:28 03/13/24 14:19 86-30-6
1'3'3.-Oxybis(1-chloropropane) ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 108-60-1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 8 of 51

7
9800 Kincey Ave. Suite 100
ace Huntersville,NC 28078
[phone]
ANALYTICAL RESULTS
Project: EFF PPA
Pace Project No.: 92717151
Sample: EFF PPA Lab ID: 92717151005 Collected: 03/05/24 10:52 Received: 03/06/24 11:50 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
625 RVE Analytical Method:EPA 625.1 Preparation Method: EPA 625.1
Pace Analytical Services-Charlotte
Pentachlorophenol ND ug/L 10.0 1 03/12/24 10:28 03/13/24 14:19 87-86-5
Phenanthrene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 85-01-8
Phenol ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 108-95-2
Pyrene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 129-00-0
1,2,4-Trichlorobenzene ND ug/L 5.0 1 03/12/24 10:28 03/13/24 14:19 120-82-1
2,4,6-Trichlorophenol ND ug/L 10.0 1 03/12/24 10:28 03/13/24 14:19 88-06-2
Surrogates
Nitrobenzene-d5(S) 61 % 10-120 1 03/12/24 10:28 03/13/24 14:19 4165-60-0
2-Fluorobiphenyl(S) 63 % 15-120 1 03/12/24 10:28 03/13/24 14:19 321-60-8
Terphenyl-d14(S) 98 % 11-131 1 03/12/24 10:28 03/13/24 14:19 1718-51-0
Phenol-d6(S) 27 % 10-120 1 03/12/24 10:28 03/13/24 14:19 13127-88-3
2-Fluorophenol(S) 51 % 10-120 1 03/12/24 10:28 03/13/24 14:19 367-12-4
2,4,6-Tribromophenol(S) 70 % 10-137 1 03/12/24 10:28 03/13/24 14:19 118-79-6
REPORT OF LABORA
TORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 9 of 51

9800 Kincey Ave. Suite 100 ,
Ce Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
QC Batch: 839237 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664E Analysis Description: 1664 HEM,Oil and Grease
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92717151002
METHOD BLANK: 4335101 Matrix: Water
Associated Lab Samples: 92717151002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 03/15/24 10:24
LABORATORY CONTROL SAMPLE: 4335102
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 40 32.2 80 78-114
MATRIX SPIKE SAMPLE: 4335103
92718292002 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
it and Grease mg/L 14.2 39.6 46.2 81 78-114
SAMPLE DUPLICATE: 4335104
92718402002 Dup
Parameter Units Result Result RPD Qualifiers
Oil and Grease mg/L 5.0 5.0 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 10 of 51

9800 Kincey Ave. Suite 100
(Face Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
QC Batch: 995695 Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services-Ormond Beach
Associated Lab Samples: 92717151001
METHOD BLANK: 5473667 Matrix: Water
Associated Lab Samples: 92717151001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Tot Hardness asCaCO3(SM 2340B ug/L ND 3310 03/12/24 23:12
LABORATORY CONTROL SAMPLE: 5473668
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Tot Hardness asCaCO3(SM 2340B ug/L 82700 85000 103 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 5473669 5473670
MS MSD
35865176001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
of Hardness asCaCO3(SM ug/L 109000 82700 82700 191000 192000 99 100 70-130 1
2340E
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 5473671 5473672
MS MSD
35865868001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Tot Hardness asCaCO3(SM ug/L 20.8 82700 82700 105000 103000 102 99 70-130 2
2340E mg/L
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 51

9800 Kincey Ave. Suite 100
ace Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
QC Batch: 995418 Analysis Method: EPA 200.8
QC Batch Method: EPA 200.8 Analysis Description: 200.8 MET
Laboratory: Pace Analytical Services-Ormond Beach
Associated Lab Samples: 92717151001
METHOD BLANK: 5472079 Matrix: Water
Associated Lab Samples: 92717151001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Antimony ug/L ND 1.0 03/11/24 19:03
Arsenic ug/L ND 1.0 03/11/24 19:03
Beryllium ug/L ND 0.10 03/11/24 19:03
Cadmium ug/L ND 0.10 03/11/24 19:03
Chromium ug/L ND 1.0 03/11/24 19:03
Copper ug/L ND 1.0 03/11/24 19:03
Lead ug/L ND 1.0 03/11/24 19:03
Nickel ug/L ND 1.0 03/11/24 19:03
Selenium ug/L ND 2.0 03/11/24 19:03 1
Silver ug/L ND 0.50 03/11/24 19:03
Thallium ug/L ND 1.0 03/11/24 19:03
Zinc ug/L ND 10.0 03/11/24 19:03
_.BBORATORY CONTROL SAMPLE: 5472080
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Antimony ug/L 50 51.8 104 85-115
Arsenic ug/L 50 51.5 103 85-115
Beryllium ug/L 5 5.1 102 85-115
Cadmium ug/L 5 5.5 110 85-115
Chromium ug/L 50 52.8 106 85-115
Copper ug/L 50 51.4 103 85-115
Lead ug/L 50 49.8 100 85-115
Nickel ug/L 50 51.1 102 85-115
Selenium ug/L 50 54.2 108 85-115
Silver ug/L 5 5.4 107 85-115
Thallium ug/L 50 50.3 101 85-115
Zinc ug/L 250 256 103 85-115
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 5472081 5472082
MS MSD
35865185001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Antimony ug/L 0.0018 50 50 52.4 52.7 101 102 70-130 1
mg/L
Arsenic ug/L 0.0024 50 50 50.6 50.5 96 96 70-130 0
mg/L
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 12 of 51

9800 Kincey Ave. Suite 100
gace v Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 5472081 5472082
MS MSD
35865185001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Beryllium ug/L 0.00003 5 5 5.0 5.0 99 100 70-130 1
3U
mg/L
Cadmium ug/L 0.00016 5 5 5.0 5.2 97 100 70-130 3
mg/L
Chromium ug/L 0.0011 50 50 49.8 49.7 98 97 70-130 0
mg/L
Copper ug/L 0.0035 50 50 52.7 53.7 98 100 70-130 2
mg/L
Lead ug/L 0.00029 50 50 47.3 46.6 94 93 70-130 1
J mg/L
Nickel ug/L 0.0014 50 50 47.9 47.9 93 93 70-130 0
mg/L
Selenium ug/L 0.00055 50 50 43.7 44.6 86 88 70-130 2
J mg/L
Silver ug/L 0.00002 5 5 5.0 5.1 100 101 70-130 2
8U
mg/L
Thallium ug/L 0.00018 50 50 47.9 47.6 95 95 70-130 1
J mg/L
Zinc ug/L 0.035 250 250 272 271 95 94 70-130 0
mg/L
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 5472083 5472084
MS MSD
92717487002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Antimony ug/L ND 50 50 52.1 51.3 104 102 70-130 2
Arsenic ug/L ND 50 50 52.2 51.6 104 103 70-130 1
Beryllium ug/L ND 5 5 5.2 5.2 104 103 70-130 1
Cadmium ug/L ND 5 5 5.2 5.3 103 106 70-130 3
Chromium ug/L 0.0015 50 50 54.8 54.6 107 106 70-130 0
mg/L
Copper ug/L 0.0039 50 50 55.6 55.3 103 103 70-130 0
mg/L
Lead ug/L ND 50 50 51.7 51.2 102 101 70-130 1
Nickel ug/L ND 50 50 52.7 51.6 104 102 70-130 2
Selenium ug/L ND 50 50 53.6 53.0 107 106 70-130 1
Silver ug/L ND 5 5 5.3 5.4 106 107 70-130 1
Thallium ug/L ND 50 50 50.9 50.3 102 101 70-130 1
Zinc ug/L 0.085 250 250 347 342 105 103 70-130 1
mg/L
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 13 of 51

9800 Kincey Ave. Suite 100
lace Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
QC Batch: 838980 Analysis Method: EPA 624.1
QC Batch Method: EPA 624.1 Analysis Description: 624 MSV
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92717151002
METHOD BLANK: 4333711 Matrix: Water
Associated Lab Samples: 92717151002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1-Trichloroethane ug/L ND 2.0 03/14/24 11:19
1,1,2,2-Tetrachloroethane ug/L ND 2.0 03/14/24 11:19
1,1,2-Trichloroethane ug/L ND 2.0 03/14/24 11:19
1,1-Dichloroethane ug/L ND 2.0 03/14/24 11:19
1,1-Dichloroethene ug/L ND 2.0 03/14/24 11:19
1,2-Dichlorobenzene ug/L ND 2.0 03/14/24 11:19
1,2-Dichloroethane ug/L ND 2.0 03/14/24 11:19
1,2-Dichloropropane ug/L ND 2.0 03/14/24 11:19
1,3-Dichlorobenzene ug/L ND 2.0 03/14/24 11:19
1,4-Dichlorobenzene ug/L ND 2.0 03/14/24 11:19
2-Chloroethylvinyl ether ug/L ND 5.0 03/14/24 11:19
Acrolein ug/L ND 5.0 03/14/24 11:19
Acrylonitrile ug/L ND 5.0 03/14/24 11:19
enzene ug/L ND 1.0 03/14/24 11:19
romodichloromethane ug/L ND 2.0 03/14/24 11:19
Bromoform ug/L ND 2.0 03/14/24 11:19
Bromomethane ug/L ND 2.0 03/14/24 11:19
Carbon tetrachloride ug/L ND 2.0 03/14/24 11:19
Chlorobenzene ug/L ND 2.0 03/14/24 11:19
Chloroethane ug/L ND 2.0 03/14/24 11:19
Chloroform ug/L ND 2.0 03/14/24 11:19
Chloromethane ug/L ND 2.0 03/14/24 11:19
cis-1,2-Dichloroethene ug/L ND 2.0 03/14/24 11:19
cis-1,3-Dichloropropene ug/L ND 2.0 03/14/24 11:19
Dibromochloromethane ug/L ND 2.0 03/14/24 11:19
Ethylbenzene ug/L ND 1.0 03/14/24 11:19
Methylene Chloride ug/L ND 2.0 03/14/24 11:19
Tetrachloroethene ug/L ND 2.0 03/14/24 11:19
Toluene ug/L ND 1.0 03/14/24 11:19
trans-1,2-Dichloroethene ug/L ND 2.0 03/14/24 11:19
trans-1,3-Dichloropropene ug/L ND 2.0 03/14/24 11:19
Trchloroethene ug/L ND 2.0 03/14/24 11:19
Trichlorofluoromethane ug/L ND 2.0 03/14/24 11:19
Vinyl chloride ug/L ND 2.0 03/14/24 11:19
1,2-Dichloroethane-d4(S) % 103 70-130 03/14/24 11:19
4-Bromofluorobenzene(S) % 97 70-130 03/14/24 11:19
Toluene-d8(S) % 99 70-130 03/14/24 11:19
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 14 of 51

9800 Kincey Ave. Suite 100
(-Pace, Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
LABORATORY CONTROL SAMPLE: 4333712
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,1,1-Trichloroethane ug/L 20 18.6 93 70-130
1,1,2,2-Tetrachloroethane ug/L 20 19.3 97 70-130
1,1,2-Trichloroethane ug/L 20 19.6 98 70-130
1,1-Dichloroethane ug/L 20 18.0 90 70-130
1,1-Dichloroethene ug/L 20 17.7 88 69-131
1,2-Dichlorobenzene ug/L 20 21.8 109 70-130
1,2-Dichloroethane ug/L 20 19.4 97 70-130
1,2-Dichloropropane ug/L 20 19.1 96 70-130
1,3-Dichlorobenzene ug/L 20 21.1 105 70-130
1,4-Dichlorobenzene ug/L 20 21.7 109 70-130
2-Chloroethylvinyl ether ug/L 40 32.1 80 64-133
Acrolein ug/L 100 87.3 87 60-140
Acrylonitrile ug/L 100 87.7 88 70-130
Benzene ug/L 20 19.6 98 65-135
Bromodichloromethane ug/L 20 19.4 97 70-130
Bromoform ug/L 20 19.1 96 70-130
Bromomethane ug/L 20 16.0 80 41-148
Carbon tetrachloride ug/L 20 19.2 96 70-130
Chlorobenzene ug/L 20 20.3 101 70-130
"hloroethane ug/L 20 19.4 97 41-157
hloroform ug/L 20 16.2 81 70-130
t,hloromethane ug/L 20 18.6 93 59-141
cis-1,2-Dichloroethene ug/L 20 18.6 93 70-130
cis-1,3-Dichloropropene ug/L 20 19.4 97 70-130
Dibromochloromethane ug/L 20 20.3 101 70-130
Ethylbenzene ug/L 20 20.6 103 70-130
Methylene Chloride ug/L 20 16.6 83 62-130
Tetrachloroethene ug/L 20 19.7 98 70-130
Toluene ug/L 20 19.4 97 70-130
trans-1,2-Dichloroethene ug/L 20 18.8 94 70-130
trans-1,3-Dichloropropene ug/L 20 19.4 97 70-130
Trichloroethene ug/L 20 20.9 105 70-130
Trichlorofluoromethane ug/L 20 16.8 84 57-130
Vinyl chloride ug/L 20 19.8 99 66-140
1,2-Dichloroethane-d4(S) % 100 70-130
4-Bromofluorobenzene(S) % 98 70-130
Toluene-d8(S) % 98 70-130
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4333713 4333714
MS MSD
92718691002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,1,1-Trichloroethane ug/L ND 20 20 21.9 21.3 109 107 70-150 2
1,1,2,2-Tetrachloroethane ug/L ND 20 20 20.8 19.9 104 99 66-144 4
1,1,2-Trichloroethane ug/L ND 20 20 29.0 21.2 145 106 70-142 31 M1,R1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 15 of 51

(41ac
9800 Kincey Ave. Suite 100
e Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4333713 4333714
MS MSD
92718691002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,1-Dichloroethane ug/L ND 20 20 18.3 20.8 92 104 67-150 13
1,1-Dichloroethene ug/L ND 20 20 19.1 20.8 96 104 64-162 8
1,2-Dichlorobenzene ug/L ND 20 20 24.5 23.5 122 117 70-142 4
1,2-Dichloroethane ug/L ND 20 20 22.9 21.7 114 108 58-145 6
1,2-Dichloropropane ug/L ND 20 20 24.0 22.2 120 111 70-144 8
1,3-Dichlorobenzene ug/L ND 20 20 24.7 22.7 123 114 70-142 8
1,4-Dichlorobenzene ug/L ND 20 20 24.6 23.7 123 119 70-140 4
2-Chloroethylvinyl ether ug/L ND 40 40 49.9 36.5 125 91 10-211 31
Acrolein ug/L ND 100 100 ND ND 1 1 40-160 M1
Acrylonitrile ug/L ND 100 100 83.5 97.2 84 97 59-155 15
Benzene ug/L ND 20 20 22.2 21.4 111 107 70-142 3
Bromodichloromethane ug/L ND 20 20 24.2 22.0 121 110 70-139 10
Bromoform ug/L ND 20 20 21.4 20.4 107 102 64-140 5
Bromomethane ug/L ND 20 20 23.2 20.3 116 101 28-192 14
Carbon tetrachloride ug/L ND 20 20 24.3 22.8 121 114 70-140 6
Chlorobenzene ug/L ND 20 20 23.8 23.0 119 115 70-141 3
Chloroethane ug/L ND 20 20 27.4 21.1 137 105 58-191 26
Chloroform ug/L ND 20 20 22.3 21.0 102 96 70-138 6
"'iloromethane ug/L ND 20 20 27.5 21.0 137 105 43-162 27
;-1,2-Dichloroethene ug/L ND 20 20 19.1 21.1 96 106 70-143 10
cis-1,3-Dichloropropene ug/L ND 20 20 28.6 22.0 143 110 68-151 26
Dibromochloromethane ug/L ND 20 20 22.7 21.8 113 109 70-144 4
Ethylbenzene ug/L ND 20 20 24.4 23.7 122 119 70-143 3
Methylene Chloride ug/L ND 20 20 15.7 18.4 78 92 70-144 16
Tetrachloroethene ug/L ND 20 20 22.5 23.0 112 115 70-143 2
Toluene ug/L ND 20 20 30.7 23.1 151 113 69-144 28 M1,R1
trans-1,2-Dichloroethene ug/L ND 20 20 19.5 21.1 97 105 70-151 8
trans-1,3-Dichloropropene ug/L ND 20 20 28.3 21.4 141 107 70-139 28 M1
Trichloroethene ug/L ND 20 20 25.6 23.8 128 119 70-142 7
Trichlorofluoromethane ug/L ND 20 20 19.6 21.1 98 105 62-146 7
Vinyl chloride ug/L ND 20 20 31.4 23.8 157 119 61-162 28
1,2-Dichloroethane-d4(S) % 98 99 70-130
4-Bromofluorobenzene(S) % 97 99 70-130
Toluene-d8(S) % 126 99 70-130
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 16 of 51

9800 Kincey Ave. Suite 100
( ace Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
QC Batch: 837578 Analysis Method: EPA 625.1
QC Batch Method: EPA 625.1 Analysis Description: 625 MSS
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92717151002
METHOD BLANK: 4327101 Matrix: Water
Associated Lab Samples: 92717151002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,2,4-Trichlorobenzene ug/L ND 5.0 03/08/24 12:22
1,2-Diphenylhydrazine ug/L ND 5.0 03/08/24 12:22
2,2'-Oxybis(1-chloropropane) ug/L ND 5.0 03/08/24 12:22
2,4,6-Trichlorophenol ug/L ND 10.0 03/08/24 12:22
2,4-Dichlorophenol ug/L ND 5.0 03/08/24 12:22
2,4-Dimethylphenol ug/L ND 10.0 03/08/24 12:22
2,4-Dinitrophenol ug/L ND 50.0 03/08/24 12:22
2,4-Dinitrotoluene ug/L ND 5.0 03/08/24 12:22
2,6-Dinitrotoluene ug/L ND 5.0 03/08/24 12:22
2-Chloronaphthalene ug/L ND 5.0 03/08/24 12:22
2-Chlorophenol ug/L ND 5.0 03/08/24 12:22
2-Nitrophenol ug/L ND 5.0 03/08/24 12:22
3,3'-Dichlorobenzidine ug/L ND 10.0 03/08/24 12:22
,6-Dinitro-2-methylphenol ug/L ND 10.0 03/08/24 12:22
-Bromophenylphenyl ether ug/L ND 5.0 03/08/24 12:22
4-Chloro-3-methylphenol ug/L ND 5.0 03/08/24 12:22
4-Chlorophenylphenyl ether ug/L ND 5.0 03/08/24 12:22
4-Nitrophenol ug/L ND 10.0 03/08/24 12:22
Acenaphthene ug/L ND 5.0 03/08/24 12:22
Acenaphthylene ug/L ND 5.0 03/08/24 12:22
Anthracene ug/L ND 5.0 03/08/24 12:22
Benzidine ug/L ND 50.0 03/08/24 12:22
Benzo(a)anthracene ug/L ND 5.0 03/08/24 12:22
Benzo(a)pyrene ug/L ND 5.0 03/08/24 12:22
Benzo(b)fluoranthene ug/L ND 5.0 03/08/24 12:22
Benzo(g,h,i)perylene ug/L ND 5.0 03/08/24 12:22
Benzo(k)fluoranthene ug/L ND 5.0 03/08/24 12:22
bis(2-Chloroethoxy)methane ug/L ND 10.0 03/08/24 12:22
bis(2-Chloroethyl)ether ug/L ND 5.0 03/08/24 12:22
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 03/08/24 12:22
Butylbenzylphthalate ug/L ND 5.0 03/08/24 12:22
Chrysene ug/L ND 5.0 03/08/24 12:22
Di-n-butylphthalate ug/L ND 5.0 03/08/24 12:22
Di-n-octylphthalate ug/L ND 5.0 03/08/24 12:22
Dibenz(a,h)anthracene ug/L ND 5.0 03/08/24 12:22
Diethylphthalate ug/L ND 5.0 03/08/24 12:22
Dimethylphthalate ug/L ND 5.0 03/08/24 12:22
Fluoranthene ug/L ND 5.0 03/08/24 12:22
Fluorene ug/L ND 5.0 03/08/24 12:22
Hexachloro-1,3-butadiene ug/L ND 5.0 03/08/24 12:22
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 17 of 51

9800 Kincey Ave. Suite 100
gac e Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
METHOD BLANK: 4327101 Matrix: Water 1
Associated Lab Samples: 92717151002 1
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Hexachlorobenzene ug/L ND 5.0 03/08/24 12:22
Hexachlorocyclopentadiene ug/L ND 10.0 03/08/24 12:22
Hexachloroethane ug/L ND 5.0 03/08/24 12:22
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 03/08/24 12:22
Isophorone ug/L ND 10.0 03/08/24 12:22
N-Nitroso-di-n-propylamine ug/L ND 5.0 03/08/24 12:22
N-Nitrosodimethylamine ug/L ND 5.0 03/08/24 12:22
N-Nitrosodiphenylamine ug/L ND 10.0 03/08/24 12:22
Naphthalene ug/L ND 5.0 03/08/24 12:22
Nitrobenzene ug/L ND 5.0 03/08/24 12:22
Pentachlorophenol ug/L ND 10.0 03/08/24 12:22
Phenanthrene ug/L ND 5.0 03/08/24 12:22
Phenol ug/L ND 5.0 03/08/24 12:22
Pyrene ug/L ND 5.0 03/08/24 12:22
2,4,6-Tribromophenol(S) % 82 10-137 03/08/24 12:22
2-Fluorobiphenyl(S) % 80 15-120 03/08/24 12:22
2-Fluorophenol(S) % 64 10-120 03/08/24 12:22
Nitrobenzene-d5(S) % 82 10-120 03/08/24 12:22
ienol-d6(S) % 45 10-120 03/08/24 12:22
rphenyl-d14(S) % 96 11-131 03/08/24 12:22
LABORATORY CONTROL SAMPLE: 4327102
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,2,4-Trichlorobenzene ug/L 50 25.8 52 44-142
1,2-Diphenylhydrazine ug/L 50 31.9 64 25-150
2,2'-Oxybis(1-chloropropane) ug/L 50 30.8 62 36-166
2,4,6-Trichlorophenol ug/L 50 35.3 71 37-144
2,4-Dichlorophenol ug/L 50 33.7 67 1-191
2,4-Dimethylphenol ug/L 50 35.6 71 32-119
2,4-Dinitrophenol ug/L 250 184 74 1-181
2,4-Dinitrotoluene ug/L 50 34.7 69 39-139
2,6-Dinitrotoluene ug/L 50 33.9 68 50-158
2-Chloronaphthalene ug/L 50 31.5 63 60-118
2-Chlorophenol ug/L 50 33.5 67 23-134
2-Nitrophenol ug/L 50 35.2 70 29-182
3,3'-Dichlorobenzidine ug/L 100 65.0 65 1-262
4,6-Dinitro-2-methylphenol ug/L 100 79.3 79 1-181
4-Bromophenylphenyl ether ug/L 50 36.3 73 53-127
4-Chloro-3-methylphenol ug/L 100 66.2 66 22-147
4-Chlorophenylphenyl ether ug/L 50 35.0 70 25-158
4-Nitrophenol ug/L 250 86.2 34 1-132
Acenaphthene ug/L 50 33.1 66 47-145
Acenaphthylene ug/L 50 33.6 67 33-145
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 18 of 51

ace. 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
LABORATORY CONTROL SAMPLE: 4327102
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Anthracene ug/L 50 32.8 66 1-166
Benzidine ug/L 100 ND 13 10-130
Benzo(a)anthracene ug/L 50 34.9 70 33-143
Benzo(a)pyrene ug/L 50 36.4 73 17-163
Benzo(b)fluoranthene ug/L 50 38.2 76 24-159
Benzo(g,h,i)perylene ug/L 50 34.4 69 1-219
Benzo(k)fluoranthene ug/L 50 37.8 76 11-162
bis(2-Chloroethoxy)methane ug/L 50 34.8 70 33-184
bis(2-Chloroethyl)ether ug/L 50 34.3 69 12-158
bis(2-Ethylhexyl)phthalate ug/L 50 37.4 75 8-158
Butylbenzylphthalate ug/L 50 38.1 76 1-152
Chrysene ug/L 50 34.4 69 17-168
Di-n-butylphthalate ug/L 50 35.3 71 1-118
Di-n-octylphthalate ug/L 50 38.0 76 4-146
Dibenz(a,h)anthracene ug/L 50 35.2 70 1-227
Diethylphthalate ug/L 50 33.6 67 1-114
Dimethylphthalate ug/L 50 33.0 66 1-112
Fluoranthene ug/L 50 34.0 68 26-137
Fluorene ug/L 50 34.5 69 59-121
"exachloro-1,3-butadiene ug/L 50 25.1 50 24-116
exachlorobenzene ug/L 50 32.4 65 1-152
nexachlorocyclopentadiene ug/L 50 30.6 61 25-150
Hexachloroethane ug/L 50 21.3 43 40-113
Indeno(1,2,3-cd)pyrene ug/L 50 34.2 68 1-171
Isophorone ug/L 50 33.3 67 21-196
N-Nitroso-di-n-propylamine ug/L 50 31.9 64 1-230
N-Nitrosodimethylamine ug/L 50 29.2 58 25-150
N-Nitrosodiphenylamine ug/L 50 34.3 69 25-150
Naphthalene ug/L 50 27.8 56 21-133
Nitrobenzene ug/L 50 32.2 64 35-180
Pentachlorophenol ug/L 100 67.9 68 14-176
Phenanthrene ug/L 50 32.8 66 54-120
Phenol ug/L 50 20.9 42 5-112
Pyrene ug/L 50 36.4 73 52-115
2,4,6-Tribromophenol(S) % 74 10-137
2-Fluorobiphenyl(S) % 74 15-120
2-Fluorophenol(S) % 58 10-120
Nitrobenzene-d5(S) % 77 10-120
Phenol-d6(S) % 42 10-120
Terphenyl-d14(S) % 81 11-131
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 19 of 51

9800 Kincey Ave. Suite 100
aVr a Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4327103 4327104
MS MSD
92717030001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,2,4-Trichlorobenzene ug/L ND 100 100 76.3 70.9 76 71 44-142 7
1,2-Diphenylhydrazine ug/L ND 100 100 80.3 73.9 80 74 25-150 8
2,2'-Oxybis(1-chloropropane) ug/L ND 100 100 79.5 75.7 79 76 36-166 5
2,4,6-Trichlorophenol ug/L ND 100 100 78.2 9.7J 78 10 37-144 M1
2,4-Dichlorophenol ug/L ND 100 100 77.2 33.8 77 34 1-191 78 R1
2,4-Dimethylphenol ug/L ND 100 100 87.1 78.8 87 79 32-119 10
2,4-Dinitrophenol ug/L ND 500 500 334 ND 67 0 1-181 M1
2,4-Dinitrotoluene ug/L ND 100 100 77.6 70.6 78 71 39-139 9
2,6-Dinitrotoluene ug/L ND 100 100 80.4 77.3 80 77 50-158 4
2-Chloronaphthalene ug/L ND 100 100 81.2 75.7 81 76 60-118 7
2-Chlorophenol ug/L ND 100 100 79.4 44.4 79 44 23-134 57 R1
2-Nitrophenol ug/L ND 100 100 84.5 30.6 84 31 29-182 94 R1
3,3'-Dichlorobenzidine ug/L ND 200 200 151 141 76 70 1-262 8
4,6-Dinitro-2-methylphenol ug/L ND 200 200 157 ND 79 0 1-181 M1
4-Bromophenylphenyl ether ug/L ND 100 100 91.0 80.9 91 81 53-127 12
4-Chloro-3-methylphenol ug/L ND 200 200 152 121 76 60 22-147 23
4-Chlorophenylphenyl ether ug/L ND 100 100 82.9 77.3 83 77 25-158 7
4-Nitrophenol ug/L ND 500 500 165 ND 33 0 1-132 M1
" enaphthene ug/L ND 100 100 82.3 78.1 82 78 47-145 5
enaphthylene ug/L ND 100 100 83.6 79.4 84 79 33-145 5
Hnthracene ug/L ND 100 100 80.4 75.5 80 75 1-166 6
Benzidine ug/L ND 200 200 37.4J 94.5J 19 47 10-130
Benzo(a)anthracene ug/L ND 100 100 81.2 75.6 81 76 33-143 7
Benzo(a)pyrene ug/L ND 100 100 83.0 77.4 83 77 17-163 7
Benzo(b)fluoranthene ug/L ND 100 100 85.7 80.1 86 80 24-159 7
Benzo(g,h,i)perylene ug/L ND 100 100 95.2 85.5 95 86 1-219 11
Benzo(k)fluoranthene ug/L ND 100 100 79.8 76.9 80 77 11-162 4
bis(2-Chloroethoxy)methane ug/L ND 100 100 85.7 77.3 86 77 33-184 10
bis(2-Chloroethyl)ether ug/L ND 100 100 85.3 82.6 85 83 12-158 3
bis(2-Ethylhexyl)phthalate ug/L ND 100 100 87.7 81.9 88 82 8-158 7
Butylbenzylphthalate ug/L ND 100 100 89.3 81.6 89 82 1-152 9
Chrysene ug/L ND 100 100 80.7 74.8 81 75 17-168 8
Di-n-butylphthalate ug/L ND 100 100 80.9 75.5 81 75 1-118 7
Di-n-octylphthalate ug/L ND 100 100 91.7 81.6 92 82 4-146 12
Dibenz(a,h)anthracene ug/L ND 100 100 91.1 81.1 91 81 1-227 12
Diethylphthalate ug/L ND 100 100 77.2 73.1 77 73 1-114 6
Dimethylphthalate ug/L ND 100 100 77.1 75.0 77 75 1-112 3
Fluoranthene ug/L ND 100 100 75.0 70.9 75 71 26-137 6
Fluorene ug/L ND 100 100 80.4 75.7 80 76 59-121 6
Hexachloro-1,3-butadiene ug/L ND 100 100 76.7 73.8 77 74 24-116 4
Hexachlorobenzene ug/L ND 100 100 83.1 77.6 83 78 1-152 7
Hexachlorocyclopentadiene ug/L ND 100 100 83.6 77.7 84 78 25-150 7
Hexachloroethane ug/L ND 100 100 67.6 64.7 68 65 40-113 4
Indeno(1,2,3-cd)pyrene ug/L ND 100 100 88.5 79.8 88 80 1-171 10
Isophorone ug/L ND 100 100 82.1 74.9 82 75 21-196 9
N-Nitroso-di-n-propylamine ug/L ND 100 100 78.6 73.8 79 74 1-230 6
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 20 of 51

4/ ace [phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4327103 4327104
MS MSD
92717030001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
N-Nitrosodimethylamine ug/L ND 100 100 68.0 65.2 68 65 25-150 4
N-Nitrosodiphenylamine ug/L ND 100 100 86.4 78.6 86 79 25-150 9
Naphthalene ug/L ND 100 100 81.6 75.5 82 76 21-133 8
Nitrobenzene ug/L ND 100 100 79.0 73.4 79 73 35-180 7
Pentachlorophenol ug/L ND 200 200 133 ND 66 0 14-176 M1
Phenanthrene ug/L ND 100 100 80.0 74.5 80 74 54-120 7
Phenol ug/L ND 100 100 51.7 38.7 52 39 5-112 29
Pyrene ug/L ND 100 100 89.3 82.5 89 82 52-115 8
2,4,6-Tribromophenol(S) % 94 16 10-137
2-Fluorobiphenyl(S) % 105 84 15-120
2-Fluorophenol(S) % 80 22 10-120
Nitrobenzene-d5(S) % 107 83 10-120
Phenol-d6(S) % 60 39 10-120
Terphenyl-d14(S) % 115 89 11-131
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 21 of 51

(Face
[phone]
QUALITY CONTROL DATA
' Project: EFF PPA
Pace Project No.: 92717151
QC Batch: 838342 Analysis Method: EPA 625.1
QC Batch Method: EPA 625.1 Analysis Description: 625 MSS
Laboratory: Pace Analytical Services-Charlotte
Associated Lab Samples: 92717151005
METHOD BLANK: 4330407 Matrix: Water
Associated Lab Samples: 92717151005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,2,4-Trichlorobenzene ug/L ND 5.0 03/13/24 10:45
2,2'-Oxybis(1-chloropropane) ug/L ND 5.0 03/13/24 10:45
2,4,6-Trichlorophenol ug/L ND 10.0 03/13/24 10:45
2,4-Dichlorophenol ug/L ND 5.0 03/13/24 10:45
2,4-Dimethylphenol ug/L ND 10.0 03/13/24 10:45
2,4-Dinitrophenol ug/L ND 50.0 03/13/24 10:45
2,4-Dinitrotoluene ug/L ND 5.0 03/13/24 10:45
2,6-Dinitrotoluene ug/L ND 5.0 03/13/24 10:45
2-Chloronaphthalene ug/L ND 5.0 03/13/24 10:45
2-Chlorophenol ug/L ND 5.0 03/13/24 10:45
2-Nitrophenol ug/L ND 5.0 03/13/24 10:45
3,3'-Dichlorobenzidine ug/L ND 10.0 03/13/24 10:45
4.6-Dinitro-2-methylphenol ug/L ND 10.0 03/13/24 10:45
3romophenylphenyl ether ug/L ND 5.0 03/13/24 10:45
::hloro-3-methylphenol ug/L ND 5.0 03/13/24 10:45
4-Chlorophenylphenyl ether ug/L ND 5.0 03/13/24 10:45
4-Nitrophenol ug/L ND 10.0 03/13/24 10:45
Acenaphthene ug/L ND 5.0 03/13/24 10:45
Acenaphthylene ug/L ND 5.0 03/13/24 10:45
Anthracene ug/L ND 5.0 03/13/24 10:45
Benzo(a)anthracene ug/L ND 5.0 03/13/24 10:45
Benzo(a)pyrene ug/L ND 5.0 03/13/24 10:45
Benzo(b)fluoranthene ug/L ND 5.0 03/13/24 10:45
Benzo(g,h,i)perylene ug/L ND 5.0 03/13/24 10:45
Benzo(k)fluoranthene ug/L ND 5.0 03/13/24 10:45
bis(2-Chloroethoxy)methane ug/L ND 10.0 03/13/24 10:45
bis(2-Chloroethyl)ether ug/L ND 5.0 03/13/24 10:45
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 03/13/24 10:45
Butylbenzylphthalate ug/L ND 5.0 03/13/24 10:45
Chrysene ug/L ND 5.0 03/13/24 10:45
Di-n-butylphthalate ug/L ND 5.0 03/13/24 10:45
Di-n-octylphthalate ug/L ND 5.0 03/13/24 10:45
Dibenz(a,h)anthracene ug/L ND 5.0 03/13/24 10:45
Diethylphthalate ug/L ND 5.0 03/13/24 10:45
Dimethylphthalate ug/L ND 5.0 03/13/24 10:45
Fluoranthene ug/L ND 5.0 03/13/24 10:45
Fluorene ug/L ND 5.0 03/13/24 10:45
Hexachloro-1,3-butadiene ug/L ND 5.0 03/13/24 10:45
Hexachlorobenzene ug/L ND 5.0 03/13/24 10:45
Hexachlorocyclopentadiene ug/L ND 10.0 03/13/24 10:45
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 22 of 51
1

( ace [phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
METHOD BLANK: 4330407 Matrix: Water
Associated Lab Samples: 92717151005
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Hexachloroethane ug/L ND 5.0 03/13/24 10:45
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 03/13/24 10:45
Isophorone ug/L ND 10.0 03/13/24 10:45
N-Nitroso-di-n-propylamine ug/L ND 5.0 03/13/24 10:45
N-Nitrosodimethylamine ug/L ND 5.0 03/13/24 10:45
N-Nitrosodiphenylamine ug/L ND 10.0 03/13/24 10:45
Naphthalene ug/L ND 5.0 03/13/24 10:45
Nitrobenzene ug/L ND 5.0 03/13/24 10:45
Pentachlorophenol ug/L ND 10.0 03/13/24 10:45
Phenanthrene ug/L ND 5.0 03/13/24 10:45
Phenol ug/L ND 5.0 03/13/24 10:45
Pyrene ug/L ND 5.0 03/13/24 10:45
2,4,6-Tribromophenol(S) % 96 10-137 03/13/24 10:45
2-Fluorobiphenyl(S) % 86 15-120 03/13/24 10:45
2-Fluorophenol(S) % 89 10-120 03/13/24 10:45
Nitrobenzene-d5(S) % 88 10-120 03/13/24 10:45
Phenol-d6(S) % 68 10-120 03/13/24 10:45
Terphenyl-d14(S) % 115 11-131 03/13/24 10:45
LABORATORY CONTROL SAMPLE: 4330408
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,2,4-Trichlorobenzene ug/L 50 33.9 68 44-142
2,2'-Oxybis(1-chloropropane) ug/L 50 35.1 70 36-166
2,4,6-Trichlorophenol ug/L 50 45.5 91 37-144
2,4-Dichlorophenol ug/L 50 37.2 74 1-191
2,4-Dimethylphenol ug/L 50 40.0 80 32-119
2,4-Dinitrophenol ug/L 250 313 125 1-181
2,4-Dinitrotoluene ug/L 50 55.2 110 39-139
2,6-Dinitrotoluene ug/L 50 47.0 94 50-158
2-Chloronaphthalene ug/L 50 38.9 78 60-118
2-Chlorophenol ug/L 50 40.6 81 23-134
2-Nitrophenol ug/L 50 43.5 87 29-182
3,3'-Dichlorobenzidine ug/L 100 106 106 1-262
4,6-Dinitro-2-methylphenol ug/L 100 130 130 1-181
4-Bromophenylphenyl ether ug/L 50 50.1 100 53-127
4-Chloro-3-methylphenol ug/L 100 80.6 81 22-147 1
4-Chlorophenylphenyl ether ug/L 50 43.0 86 25-158
4-Nitrophenol ug/L 250 182 73 1-132
Acenaphthene ug/L 50 40.6 81 47-145
Acenaphthylene ug/L 50 41.4 83 33-145
Anthracene ug/L 50 53.3 107 1-166
Benzo(a)anthracene ug/L 50 57.7 115 33-143
Benzo(a)pyrene ug/L 50 60.6 121 17-163
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 23 of 51

(_ Face`l 9800 Kincey Ave. Suite 100
Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
LABORATORY CONTROL SAMPLE: 4330408
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Benzo(b)fluoranthene ug/L 50 60.6 121 24-159
Benzo(g,h,i)perylene ug/L 50 56.5 113 1-219
Benzo(k)fluoranthene ug/L 50 58.9 118 11-162
bis(2-Chloroethoxy)methane ug/L 50 36.9 74 33-184
bis(2-Chloroethyl)ether ug/L 50 37.1 74 12-158
bis(2-Ethylhexyl)phthalate ug/L 50 69.5 139 8-158
Butylbenzylphthalate ug/L 50 67.2 134 1-152
Chrysene ug/L 50 55.2 110 17-168
Di-n-butylphthalate ug/L 50 64.4 129 1-118 L1
Di-n-octylphthalate ug/L 50 70.4 141 4-146
Dibenz(a,h)anthracene ug/L 50 57.7 115 1-227
Diethylphthalate ug/L 50 50.2 100 1-114
Dimethylphthalate ug/L 50 45.0 90 1-112
Fluoranthene ug/L 50 57.5 115 26-137
Fluorene ug/L 50 43.5 87 59-121
Hexachloro-1,3-butadiene ug/L 50 31.2 62 24-116
Hexachlorobenzene ug/L 50 48.2 96 1-152
Hexachlorocyclopentadiene ug/L 50 37.0 74 25-150
Hexachloroethane ug/L 50 27.9 56 40-113
' ieno(1,2,3-cd)pyrene ug/L 50 56.0 112 1-171
iphorone ug/L 50 35.2 70 21-196
Iv-Nitroso-di-n-propylamine ug/L 50 37.5 75 1-230
N-Nitrosodimethylamine ug/L 50 30.3 61 25-150
N-Nitrosodiphenylamine ug/L 50 53.4 107 25-150
Naphthalene ug/L 50 36.2 72 21-133
Nitrobenzene ug/L 50 36.2 72 35-180
Pentachlorophenol ug/L 100 131 131 14-176
Phenanthrene ug/L 50 51.8 104 54-120
Phenol ug/L 50 26.3 53 5-112
Pyrene ug/L 50 57.5 115 52-115
2,4,6-Tribromophenol(S) % 105 10-137
2-Fluorobiphenyl(S) % 74 15-120
2-Fluorophenol(S) % 57 10-120
Nitrobenzene-d5(S) % 73 10-120
Phenol-d6(S) % 41 10-120
Terphenyl-d14(S) % 113 11-131
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4330409 4330410
MS MSD
92699837012 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
1,2,4-Trichlorobenzene ug/L ND 50 50 29.9 25.9 60 52 44-142 14
2,2'-Oxybis(1-chloropropane) ug/L ND 50 50 32.9 33.7 66 67 36-166 2
2,4,6-Trichlorophenol ug/L ND 50 50 40.7 40.0 81 80 37-144 2
2,4-Dichlorophenol ug/L ND 50 50 37.3 38.3 75 77 1-191 3
Results presented on this page are in the units indicated by the"Units'column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 24 of 51

gacff 9800 Kincey Ave. Suite 100 Hunte y Ave. Su to 078
100
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4330409 4330410
MS MSD
92699837012 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
2,4-Dimethylphenol ug/L ND 50 50 39.3 40.3 79 81 32-119 3
2,4-Dinitrophenol ug/L ND 250 250 252 247 101 99 1-181 2
2,4-Dinitrotoluene ug/L ND 50 50 44.1 43.3 88 87 39-139 2
2,6-Dinitrotoluene ug/L ND 50 50 37.9 36.7 76 73 50-158 3
2-Chloronaphthalene ug/L ND 50 50 36.2 35.6 72 71 60-118 2
2-Chlorophenol ug/L ND 50 50 42.0 44.5 84 89 23-134 6
2-Nitrophenol ug/L ND 50 50 43.8 45.0 88 90 29-182 3
3,3'-Dichlorobenzidine ug/L ND 100 100 80.5 70.2 81 70 1-262 14
4,6-Dinitro-2-methylphenol ug/L ND 100 100 112 107 112 107 1-181 4
4-Bromophenylphenyl ether ug/L ND 50 50 39.5 37.6 79 75 53-127 5
4-Chloro-3-methylphenol ug/L ND 100 100 72.1 72.2 72 72 22-147 0
4-Chlorophenylphenyl ether ug/L ND 50 50 35.5 34.7 71 69 25-158 2
4-Nitrophenol ug/L ND 250 250 215 194 86 78 1-132 10
Acenaphthene ug/L ND 50 50 36.5 35.4 73 71 47-145 3
Acenaphthylene ug/L ND 50 50 37.3 36.4 75 73 33-145 2
Anthracene ug/L ND 50 50 43.9 41.5 88 83 1-166 6
Benzo(a)anthracene ug/L ND 50 50 49.1 45.3 98 91 33-143 8
Benzo(a)pyrene ug/L ND 50 50 49.8 46.0 100 92 17-163 8
D nzo(b)fluoranthene ug/L ND 50 50 50.0 46.1 100 92 24-159 8
mzo(g,h,i)perylene ug/L ND 50 50 44.8 41.3 90 83 1-219 8
uenzo(k)fluoranthene ug/L ND 50 50 47.2 45.7 94 91 11-162 3
bis(2-Chloroethoxy)methane ug/L ND 50 50 34.9 36.6 70 73 33-184 5
bis(2-Chloroethyl)ether ug/L ND 50 50 34.4 36.7 69 73 12-158 7
bis(2-Ethylhexyl)phthalate ug/L ND 50 50 56.8 51.8 114 104 8-158 9
Butylbenzylphthalate ug/L ND 50 50 57.6 51.5 115 103 1-152 11
Chrysene ug/L ND 50 50 47.2 43.0 94 86 17-168 9
Di-n-butylphthalate ug/L ND 50 50 51.7 47.7 103 95 1-118 8
Di-n-octylphthalate ug/L ND 50 50 58.6 53.7 117 107 4-146 9
Dibenz(a,h)anthracene ug/L ND 50 50 46.1 42.6 92 85 1-227 8
Diethylphthalate ug/L ND 50 50 40.4 39.1 81 78 1-114 3
Dimethylphthalate ug/L ND 50 50 36.6 35.4 73 71 1-112 3
Fluoranthene ug/L ND 50 50 47.4 44.0 95 88 26-137 8
Fluorene ug/L ND 50 50 36.0 34.7 72 69 59-121 3
Hexachloro-1,3-butadiene ug/L ND 50 50 26.2 20.8 52 42 24-116 23
Hexachlorobenzene ug/L ND 50 50 39.0 37.4 78 75 1-152 4
Hexachlorocyclopentadiene ug/L ND 50 50 31.8 29.2 64 58 25-150 8
Hexachloroethane ug/L ND 50 50 23.5 19.7 47 39 40-113 18 M1
Indeno(1,2,3-cd)pyrene ug/L ND 50 50 45.6 41.7 91 83 1-171 9
Isophorone ug/L ND 50 50 34.2 34.6 68 69 21-196 1
N-Nitroso-di-n-propylamine ug/L ND 50 50 35.9 37.8 72 76 1-230 5
N-Nitrosodimethylamine ug/L ND 50 50 29.8 30.4 60 61 25-150 2
N-Nitrosodiphenylamine ug/L ND 50 50 42.3 40.2 85 80 25-150 5
Naphthalene ug/L ND 50 50 33.6 30.7 67 61 21-133 9
Nitrobenzene ug/L ND 50 50 34.2 35.2 68 70 35-180 3
Pentachlorophenol ug/L ND 100 100 109 100 109 100 14-176 9
Phenanthrene ug/L ND 50 50 43.0 41.0 86 82 54-120 5
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 25 of 51

9800 Kincey Ave. Suite 100
Huntersville,NC 28078
�!V [phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4330409 4330410
MS MSD
92699837012 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenol ug/L ND 50 50 33.4 33.9 67 68 5-112 1
Pyrene ug/L ND 50 50 50.7 46.1 101 92 52-115 9
2,4,6-Tribromophenol(S) % 90 82 10-137
2-Fluorobiphenyl(S) % 71 69 15-120
2-Fluorophenol(S) % 71 72 10-120
Nitrobenzene-d5(S) % 71 74 10-120
Phenol-d6(S) % 59 59 10-120
Terphenyl-d14(S) % 100 90 11-131
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 26 of 51

(/-'Pace
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
QC Batch: 837229 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92717151001
METHOD BLANK: 4325216 Matrix: Water
Associated Lab Samples: 92717151001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 03/07/24 06:03
LABORATORY CONTROL SAMPLE: 4325217
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 250 100 90-110
SAMPLE DUPLICATE: 4328889
92717230001 Dup
Parameter Units Result Result RPD Qualifiers
:al Dissolved Solids mg/L 11000 10500 5
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 27 of 51

(t1P(ace
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
QC Batch: 840095 Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92717151001
METHOD BLANK: 4339117 Matrix: Water
Associated Lab Samples: 92717151001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 03/20/24 10:04
LABORATORY CONTROL SAMPLE: 4339118
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 5.0 100 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4339119 4339120
MS MSD
92717665001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
rogen,Ammonia mg/L 10.8 5 5 16.2 16.2 108 107 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4339121 4339122
MS MSD
92718686001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Ammonia mg/L 30.9 5 5 35.8 35.7 97 96 90-110 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 28 of 51

(/Face [phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
QC Batch: 838690 Analysis Method: EPA 351.2 Rev 2.0 1993
QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92717151001
METHOD BLANK: 4332040 Matrix: Water
Associated Lab Samples: 92717151001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Kjeldahl,Total mg/L ND 0.50 03/14/24 06:25
LABORATORY CONTROL SAMPLE: 4332041
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Kjeldahl,Total mg/L 10 10.1 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4332042 4332043
MS MSD
92717850001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
:rogen,Kjeldahl,Total mg/L 0.87 10 10 11.5 11.5 107 106 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4332044 4332045
MS MSD
92717850002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen,Kjeldahl,Total mg/L ND 10 10 11.3 11.0 108 105 90-110 3
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 29 of 51

9800 Kincey Ave. Suite 100
gace- Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
QC Batch: 840273 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate+Nitrite,preserved
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92717151001
METHOD BLANK: 4340138 Matrix: Water
Associated Lab Samples: 92717151001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,NO2 plus NO3 mg/L ND 0.040 03/21/24 11:00
LABORATORY CONTROL SAMPLE: 4340139
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 2.5 2.4 98 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4340140 4340141
MS MSD
92717691001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
itrogen,NO2 plus NO3 mg/L 0.65 2.5 2.5 3.1 3.1 97 96 90-110 0
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4340142 4340143
MS MSD
92718189001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Nitrogen, NO2 plus NO3 mg/L 4.1 2.5 2.5 6.7 6.6 105 102 90-110 1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 30 of 51

Kincey Ave. Suite 100
(_ ace 9800 Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
QC Batch: 839768 Analysis Method: EPA 365.1 Rev 2.0 1993
QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus,Total
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92717151001
METHOD BLANK: 4337634 Matrix: Water
Associated Lab Samples: 92717151001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 03/20/24 11:06
LABORATORY CONTROL SAMPLE: 4337635
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.5 100 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4337636 4337637
MS MSD
92717151001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
hosphorus mg/L 1.6 2.5 2.5 3.9 3.9 90 91 90-110 1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4337638 4337639
MS MSD
92717623001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phosphorus mg/L 6.0 2.5 2.5 8.6 8.5 103 102 90-110 0
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 31 of 51

9800 Kincey Ave. Suite 100
(Vace ' Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA
Project: EFF PPA
Pace Project No.: 92717151
QC Batch: 840659 Analysis Method: EPA 420.4 Rev 1.0 1993
QC Batch Method: EPA 420.4 Rev 1.0 1993 Analysis Description: 420.4 Phenolics
Laboratory: Pace Analytical Services-Asheville
Associated Lab Samples: 92717151001
METHOD BLANK: 4342038 Matrix: Water
Associated Lab Samples: 92717151001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phenolics,Total Recoverable mg/L ND 0.0050 03/22/24 10:22
LABORATORY CONTROL SAMPLE: 4342039
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phenolics,Total Recoverable mg/L 0.05 0.045 90 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4342040 4342041
MS MSD
92717760001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
ienolics,Total Recoverable mg/L 0.016 0.05 0.05 0.054 0.068 76 104 90-110 23 M1,R1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 4342042 4342043
MS MSD
92717929002 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD Qual
Phenolics,Total Recoverable mg/L 0.014 0.05 0.05 0.058 0.055 87 82 90-110 4 M1
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 32 of 51

9800 Kincey Ave. Suite 100
ace Huntersville,NC 28078
[phone]
QUALIFIERS
Project: EFF PPA
Pace Project No.: 92717151
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot.
ND-Not Detected at or above adjusted reporting limit.
TNTC-Too Numerous To Count
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL-Practical Quantitation Limit.
RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S-Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as
"Total"may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
ANALYTE QUALIFIERS
L1 Analyte recovery in the laboratory control sample(LCS)was above QC limits. Results for this analyte in associated
samples may be biased high.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
P4 Sample field preservation does not meet EPA or method recommendations for this analysis.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 33 of 51

9800 Kincey Ave. Suite 100
(/7Face Huntersville,NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: EFF PPA
Pace Project No.: 92717151
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92717151002 EFF PPA EPA 1664E 839237
92717151001 EFF PPA EPA 200.7 995695 EPA 200.7 995798
92717151001 EFF PPA EPA 200.8 995418 EPA 200.8 995434
92717151002 EFF PPA EPA 625.1 837578 EPA 625.1 837654
92717151005 EFF PPA EPA 625.1 838342 EPA 625.1 838428
92717151002 EFF PPA EPA 624.1 838980
92717151001 EFF PPA SM 2540C-2015 837229
92717151001 EFF PPA EPA 350.1 Rev 2.0 1993 840095
92717151001 EFF PPA EPA 351.2 Rev 2.0 1993 838690 EPA 351.2 Rev 2.0 1993 838871
92717151001 EFF PPA EPA 353.2 Rev 2.0 1993 840273
92717151001 EFF PPA EPA 365.1 Rev 2.0 1993 839768 EPA 365.1 Rev 2.0 1993 840121
92717151001 EFF PPA EPA 420.4 Rev 1.0 1993 840659 EPA 420.4 Rev 1.0 1993 840743
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:03/26/2024 05:29 PM without the written consent of Pace Analytical Services,LLC. Page 34 of 51
1

I WW1-,
Effective Date: 11/29/2023 4:16:30 PM
Laboratory receiving samples:
Asheville❑ Eden❑ Greenwood❑ Huntersville Raleigh❑ Mechanicsville❑ Atlanta( v..----- -^
ample Condition Client Name: WO# es 92717151
ii, Upon Receipt r / E r /v,i f
A ,Q-e Project#:
Courier. ❑Fed Ex ❑UPS/ _, IIII
❑ Commercial ( ace El Other:
❑Client II I III III III III I I II
,ter 92717151
Custody Seal Present? El Yes ..0 No Seals Intact? ❑Yes D No ,Z1 N/A _
Date/Initials Person Examining Contents: (./'?12 60•
Packing Material: ICJ Bubble Wrap 0 Bubble Bags ❑None 0 Other Biological Tissue Frozen?
Thermometer: ❑Yes ❑No /15-N/A
�R Gun ID: C'3 T 0-7 Type of Ice: $Wet 0 Blue ❑None
7 I 0 /_ Correction Factor.
Cooler Temp: j c' Add/Subtract('C) C Temp should be above freezing to 6'C
0 Samples out of temp criteria.Samples on ice,cooling process
Cooler Temp Corrected ): • \ 1 r(L has begun
USDA Regulated Satf"IN/A,water sample)
Did samples originate inkquarantine zone within the United States:CA,NY,or SC Did samples originate from a foreign source(internationally,
(check maps)?CI Ye /`n''No including Hawaii and Puerto Rico)?❑Yes
Comments/Discrepancy:
Chain of Custody Present? es 0 No 3 N/A 1.
Samples Arrived within Hold Time? ;(es 0 No ❑N/A 2.
Short Hold Time Analysis(<72 hr.)? ❑Yes )21110 ❑N/A 3.
Rush Turn Around Time Requested? ❑yes O4 o ❑N/A 4.
Sufficient Volume? .Yes ❑No ❑N/A S.
Correct Containers Used? ,D'Pes ❑No ON/A 6.
-Pace Containers Used? fes ❑No ❑N/A
Containers Intact? , Yes 0 No ❑N/A 7.
Dissolved analysis:Samples Field Filtered? ❑yes ❑No yN/A 8.
Sample Labels Match COC? yes 0 No ❑N/A 9.
-Includes Date/Time/ID/Analysis Matrix:
Headspace in VOA Vials(>5-6mm)? ❑Yes 'LJ No ❑N/A 10.
Trip Blank Present? ❑yes "o ❑N/A 11.
Trip Blank Custody Seals Present? ❑Yes 0 No --6-N/A
COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes 0 No
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date:
Qualtrax ID: 69614 Paae 1 of 2
Page 35 of 51

C f.: r O t)0 V 01 V, W W N Re ma
) • r rn r
o �
n
n N / / / { I n 0 v -• N
a c m / // // -/% / 1 __Y ! 8P4U-125 ml Plastic Unpreserved(N/A)(CI-) n o 0 7• ic-
x
p 9 ,'t G ^"'..! 8P3U•250 ml Plastic Unpreserved(N/A) lc., ,. p to
94
CP 7 -+ " BP2U•S00 ml Plastic Unpreserved(N/A) o 0 •0 •n D -
_ 1 _ � o �
% ° 8P1U•1 liter Plastic Unpreserved(N/A) ro x 3 n -,, i
m ` v c H p ry 0
2 " m �— / ,,/ / f , f-- n •
< ro ry jf / / / / ' /' j' ` 8P45 125 ml Plastic H2SO4(pH<2)ICI.) Z o •a A o
c " A / / / �, /� ` 8P3N-250 ml plastic HNO3(pH<2) v 7 a O -0 i
r // 8P42.125 ml Plastrc ZN Acetate&NaOH(>9) Er a- d -. u
13
o /� f// i l ter/ r J � j 8P48.125 mt Plastic Na011(pH 12)fa) o p c
n A -� �^ r______ I ( WGFU-Wide-mouthed Glass jar Unpreserved -' M 3
a = 11
f D i AG1U-1 liter : d Fs-
'Amber Unpreserved(N/A)(Cl.) n 3 5.
., O i m yr / / /i / / /! /� /`1�'` �/ //j AG1H•1 liter Amber HCI(pH c 2J 6 n
v
rp I AG3U•250 mL Amber Unpreserved(N/A)(Cl.)
2o r- / % AG15.1 liter Amber H2SO4(pH<2) -•
EC gao / ,s— �, io.
ar a p / �/ / '/ / j �I,/e /// AG3S•250 ml Amber H2504(pH<2) c)
') 0
r. N' 7 ... / ._ a
0 /
i n 't' I/ / i ,/ / 1 �� DG94-4U ml Amber NH4CI(N/A)(CI•) —
-1 — J i DG9H•40 ml VOA HCI(N/A) O
G
// 3 A Q. VG97-40 mt.VOA Na2S203(N/A)
/ Y ___ _._ --_
``,•••,�„�._.,.. p, a A0 1 VG9 • 0 m VOA Unprrerv.d(a/Al
,j
)n a 0.. -0
t7 -Q
a n— UG9V•40 ml VOA H3PO4 tN/A) r 3
1 O
s _! �_^ I l KP7U-50 nil Plastic Unpreserved(N/A) F. _ 0
P. a I f V/GK •(3 vials per kit)•VPH/Gas kd(N/A) co '��,•�///ri���+
up u cli j I_ I - --- i Il SVS7.125 ml Sterile Plastrc(N/A-lab) C) w`
n.i cD ; ii ! - r 1 V
0 G. a v �� SP2T-250 nil Sterile Plastic(N/A-lab)
—
O `� r J
tii
0. -
3C re
iD / � / / m
_ �
cn
AGOU•100 ml Amber Unpreserved(N/A)(CI-) O
rn O I W
R o VSGU-20 ml Scintillation vials(N/A) N
_ -_� o
Ul _.
" 1 I , -
, ( I ! DG9U-40 ml Amber Unpreserved vials(N/A) j A

pc G { v ca w N " Itemn I + + k
at o !? °' n p o2. c=9
x o ? IIEW1111111
••A or/ BP4U•125 ml Plastic Unpreserved(N/A)(CI-) A 0
a ea
x- 3 -- T 3 -
GU
�� 5 K III
■ BP3U•250 ml.Plastic Unpreserved(N/A) fe± = 0 l
cl af2 A a o rn I Unpreserved(N/A) ,o ° 4
4 v ro m -- H e o • ni m
d BP1U-1 liter Plastic Unpreserved(N/A) r� x 3 -„ co
'001 ' Al 8P45-125 mL Plastic H2SO4(pH<2)(CI-) roZ a o o Cu Cr
d a, Z _ ov x 0
Pli
/ BP3N-250 ml plastic HNO3(pH<2) a co
I91
t9 Ll -, S
3 n v / oopp / BP42-125 ml Plastic ZN Acetate&NaOH{>9) �� Q y N
3
t c O m N /-+
5 . o BP46.125 ml Plastic NaOH(pH>12)(CI-) o• o p < o
o - o O rT• P. a' M
a
WGFU-Wide-mouthed Glass jar Unpreserved al =' 2 o C n N
^e a = — — et r^-9 v, 7 ?' hi
o p H _ O
- a QIII 1 AG1U-1 liter Amber Unpreserved(N/A)(Cl.) 3 7
I
a ,* ' /' ✓� r/ Arig �/ AGIN-1 liter Amber HCI(pH<2J op p
IC
v n
n m 7 AG3U-2S0 mL Amber Unpreserved(N/A)(CI-) z
A x
9 0 0 /// AG15-1 liter Amber H2504(pH<2) on CD
C;
aAWEEl PrAG3S 250 ml Amber H2504(pH c 2)
o N 1 .1�� u r a
tD
DG94-40 ml Amber NHQCI(N/A)(CI•)
�9 a rD
o -� Q ■■ O
, DG9H•40 mL VOA HCI(N/A)
3 Q ` VG9T-40 mL VOA Na25203(N/A) m
a 1-3:, ,+
1. ( 2t
cr a 2 3 , VG9U-40 mL VOA Unpreserved(N/A)
IL
o rp DG9V-40 ml.VOA H3PO4(N/A) f
C o Vf I I '
es KP7U-50 ml Plastic Unpreserved(N/A)
_ -
TI -, 3 V/GK(3 vials per kit)-VPH/Gas kit(N/A)
a
CD
c SPST-12S ml Sterile Plastic(N/A-lab)
N c -.
c
N 0 a -. SP2T-250 ml Sterile Plastic(N/A-lab)
1.
70 Z Z 7ZZZZ/Z:///77 1-----/ Lir/Y &
j `na ✓ !2 / / / / � BD3R-250 ml.Plastic(NH2)2504(9.3.9.7)
m 3 AGOU-100 ml Amber Unpreserved(N/A)(CI.)
w 0
V r., e-
o r ° VSGU-20 mL Scintillation vials(N/A)
cn I a
i9
i DG9U•40 mL Amber Unpreserved vials(N/A)

0
Pace Analytical Services, LLC 00
9800 Kincey Ave. Suite 100
(13
f'ace Chain of Custody Record Huntersville, NC 28078 Number
Telephone No. [phone]
Project Manager:Tyreik Hooks
Client Report to Contact Telephone No./Fax No.TEmail
City of M nrlP WWTP(pratraatmant) Kevin Keesler 704-282-4632/[e-mail]
Address Sampler's Signature _
775 Treeway Drive Analysis(Attach List if more space is needed) Page
City State Zip Code 1
Monroe N.C. 28110 Printed Name
Project Name 1 of 2
EFF PPA Kevin Keesler
Project Number Matrix No.of Containers by coi
Ja o Pr�setyatipn Type. �, m
Sample ID/Description '�(�}y 7;�'- m �•
`+ c� E „ m Q a z z N N Remarks/Cooler
(Containers for each sample Start End '� U 3 i g o a o 0 o z v, v N iD w
maybe combined on one line) I ti c°n o D _ I 1 z Z F- o = i o 2 2 a
Date/Time Date/Time U z z N N H
'-k 3'.
EFF PPA ID 1 t- -j X X x X ,
EFF PPA 3 ..ti 3-.7 x x _ x
lo�t7 0i3 x
EFF PPA tot-1 I ._);3 x x x x
EFF PPA ? '-t -S
t 3 i-7 i o i 3 x x x x
EFF PPA -' '`i 3' S Sb,As,Be,Cd,Cr,Cu,P
10 i-? 1,3 t 5 x x x x b,Ni,Se,Ag,TI,Zn
EFF PPA 3"-' x x x x
/...,i _
EFF PPA 3 •---t '3 -S X x X X
EFF PPA "`' . . . _ _
13 b y X x X X `see attached
EFF PPA j 3 l X x _ X _ X `see attached
EFF PPA 3r-)t3
( X X X X
Possible Hazard Identification Noe: All samples are retained for six weeks from receipt unless other
©Non-Hazard [Flammable Skin Irritant Sample Disposal by Lab
Poison 0 Unknown arrangements are made
Relinquished By: Date Time
(1)(c)ci , `c .,-.ate-g'T / J I 1
Received By: Date Time
/ ., //7. :.1",/ ,
A/hep b i: �y /fiaa ,3/4.-/ ' __ 1,).k- 'i -t ,;1 et [ 3 , 6l•��5

in
0
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
ace Chain of Custody Record Huntersville, NC 28078 Numberii
Telephone No. [phone]
Project Manager:Tyreik Hooks
Client Report to Contact Telephone No./Fax No./Email
City of Monroe WWTP(Pretreatment) Kevin Keesler 704-282-4632/[e-mail]
Address Sam y_ is Signature
775 Treeway Drive V{.meµ--t���S� r
Page
Analysis(Attach List if more space is needed)
City State Zip Code x � 7/�✓ j
Monroe N.C. 28110 Printed Name a D 2 of 2
Project Name )47Ie fi o-/ 1
Eff PPA Kevin Keesler/
Project Number w Matrix No.of Containers by `n
in o Pr�setvatinn Types C
Sample ID/Description E o m
0 o. vrn
(Containers for each sample a 3 c o m x nLE, Remarks/Cooler
(. U u u o c a N O v ,9 CO
may be combined on one line) �� F- o
Date Time U 3 z x x = z = Io
Field Blank 3 .-i- 24 Ioy<J X X ( -�
Eff PPA 3 '7 21 )5 Li t X X .l�`‘•-•
X X
Possible Hazard Identification
©Non-Hazard Flammable � Skin Irritant Sample Disposal by Lab Note: All samples are retained for six weeks from receipt unless other
Poison 11 Unknown arrangements are made
Relinquished By: �/ Date _ Time
Received By: Date Time
/
- /1/49.a41.--' %/zy //so
R� . `y; Q j //4 1/6 zy /3Q3
),cam)5 (� � >( D�,�tt 1 s��

8
aceAnalytical
Report of Analysis
Pace Analytical Services, LLC
9800 Kincey Avenue
Suite 100
Huntersville, NC 28078
Attention: Tyriek Hooks
Project Name: EFF PPA
Project Number: 92717151
Lot Number:ZC08040
Date Completed:03/21/2024
03/22/2024 2:38 PM
Approved and released by:
Project Coordinator 1: Jenna S. Holliday
A1116
ANSI Natrona'Accreditation Board
ACCREDITED
—
112111=1.1-
TESTINGLABORATORY
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC.
Pace Analytical Services, LLC(formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172
Tel: [phone] Fax: [phone] www.pacelabs.com
Page 40 of 51

PACE ANALYTICAL SERVICES, LLC
SC DHEC No:32010001 NELAC No:E87653 NC DENR No:329 NC Field Parameters No:5639
Case Narrative
Pace Analytical Services, LLC
Lot Number: ZC08040
This Report of Analysis contains the analytical result(s)for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI)standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non-Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM
2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011,
Fecal Coliform Colilert-18. If you have any questions regarding this report, please contact the Pace
Project Manager listed on the cover page.
Pace Analytical Services,LLC(formerly Shealy Environmetal Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172(803)791-9700 Fax[phone] www.pacelabs.com
Page 41 of 51

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Pace Analytical Services, LLC
Lot Number: ZC08040
Project Name: EFF PPA
Project Number: 92717151
Sample Number Sample ID Matrix Date Sampled Date Received
001 Field Blank Aqueous 03/05/2024 1040 03/08/2024
002 EFF PPA Aqueous 03/05/2024 1041 03/08/2024
(2 samples)
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 42 of 51

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Pace Analytical Services, LLC
Lot Number: ZC08040
Project Name: EFF PPA
Project Number: 92717151
;ample Sample ID Matrix Parameter Method Result Q Units Page
002 EFF PPA Aqueous Mercury(CVAFS) 1631E 1.64 ng/L 6
(1 detection)
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 43 of 51
D..,...A -C 1'7

Client.Pace Analytical Services, LLC Laboratory ID:ZC08040-001
Description:Field Blank Matrix:Aqueous
Date Sampled:03/05/2024 1040 Project Name:EFF PPA
Date Received:03/08/2024 Project Number:92717151
in Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 03/21/2024 1157 KAJ 03/20/2024 0833 98508
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury(CVAFS) 7439-97-6 1631E ND 0.500 ng/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range 0=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
H=Out of holding time W=Reported on wet weight basis S=MS/MSD failure
1 nalytical Services,LLC (formerly Shealy Environmental Services,Inc.)
..stage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 44 of 51

Client:Pace Analytical Services, LLC Laboratory ID:ZC08040-002
Description:EFF PPA Matrix:Aqueous
Date Sampled:03/05/2024 1041 Project Name:EFF PPA
Date Received:03/08/2024 Project Number:92717151
Jn Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 1631E 1 03/21/2024 1203 KAJ 03/20/2024 0833 98508
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Mercury(CVAFS) 7439-97-6 1631E 1.64 0.500 ng/L 1
LOQ=Limit of Quantitation B=Detected in the method blank E=Quantitation of compound exceeded the calibration range Q=Surrogate failure
ND=Not detected at or above the LOQ N=Recovery is out of criteria P=The RPD between two GC columns exceeds 40% L=LCS/LCSD failure
H=Out of holding time W=Reported on wet weight basis S=MS/MSD failure
nalytical Services,LLC (formerly Shealy Environmental Services,Inc.)
..ntage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 45 of 51
D..,.,.G-C11

QC Summary
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) QC Data for Lot Number:ZC08040
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 46 of 51
1'1

Mercury (CVAFS) - MB
Sample ID: ZQ98508-001 Matrix: Aqueous
Batch:98508 Prep Method:
Analytical Method: 1631E Prep Date: 03/20/2024 0833
Parameter Result Q Dil LOQ Units Analysis Date
Mercury(CVAFS) ND 1 0.500 ng/L 03/21/2024 1103
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) QC Data for Lot Number:ZC08040
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 47 of 51
D,..--O-F/'1

Mercury (CVAFS) - LCS
Sample ID:ZQ98508-002 Matrix: Aqueous
Batch:98508 Prep Method:
Analytical Method: 1631E Prep Date: 03/20/2024 0833
Spike
Amount Result %Rec
rarameter (ng/L) (ng/L) Q Dil %Rec Limit Analysis Date
Mercury(CVAFS) 5.00 4.91 1 98 75-125 03/21/2024 1114
LOQ=Limit of Quantitation ND=Not detected at or above the LOQ N=Recovery is out of criteria
P=The RPD between two GC columns exceeds 40%
=RSD is out of criteria +=RPD is out of criteria
Note: Calculations are performed before rounding to avoid round-off errors in calculated results
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.) QC Data for Lot Number:ZC08040
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 48 of 51
1'1

Chain of Custody
and
Miscellaneous Documents
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.com
Page 49 of 51

od
0) n
< m
> j
41m
1.
Internal Transfer Chain of Custody - f! ��
o z 1111milihlt it ��ului11P1�111I 0 Rush IeM Prlier_^X
I ID Samples Pro Logged into nC'JC Cert. Needed: [xi Yes Li NU
c F Workorder: 9271715'' Workorder Name: 1=FF PPA owner Received Date: 316,2024 Results Requested Bp: 3120[202484.
n r
,
•Report To
Subcontract To kequest.�f Ana!yals
a Tynek Hooka Face.Analytical West Colombia
- Pace Analytical Charlotte 106 YFr,taoe Fcint Drive 'll 1! '���;
d v, 080.2 KinoeyAve. Suite 10u Wiest Columcia,SC 29172 ,1r�
0 Hurteravillu, NC 28016 ?hone(303)79'1-2700 ,Z �8� 4
N Phctx 7c -977-0l�tt
`1 -
_, `p
7,1
w DC Preserved C.oatainera
n
d - T m
m - D
`„° . Sample Castle t t
o m S' Item Sierp441 ID Type Date'TUne I.al ID afatrlx '_Af3 USE ONLY Z
r � x D
C m` I1 ,HELL)DJJJK PS 3 5r2024 10:4C y2717'151003 Wale! 1 - 1
°D 2 SFr rQA PS `r•'Si2t724 1U_41 92-r t'It5100a Water i \________ �— X - r
......
J
m 5 -�--1 cam++,er,w D
pt (Tlrne Racrtved By Date/Tlme r-
Transfers Rele�ed Sy ae
L�� Cn
1 (>.+t4 k ( [• tin", H r J m
m
K .�.-- --s 3'f y !� X
3 Cooler Temperature on Recelpti9 °C I Custody Seal Y or tp Received on Ice Y or
Samples Intact 0 or N I C
."In order to maintain client confidentially lccatiurL11, J 1e of Mc sampling site, sampler's name and signature may not be provided cut this COO document. rn
This chain of c,stody is considered comniete as is since this+information is available in the a►morlabcraloly. m
r
r
n
rltT-ALL anoxre ccr zara�2u Pa pc. 1 of
m I hur9dey,1Aa►ch G7.2D2n 2.15:13 PM
CD
CD
cn
0 ----

PACE ANALYTICAL SERVICES, LLC
dotiC#Title: ENV 1,RM-WOOL-0286 v02_Samples Receipt CheckF.st(SRC)
Effective late:8f 21 2022
Sample Receipt Checklist(SRC)
client. PAc:E cooky rnspectcd 'i&ate: two.w / 03.(0V:-tr3•t 1_cr;r- Tcos<uu - — _
leans of re;:cipi.. N IIINEMIU I♦Other: _ _
IMEN119 N:.,_ 1.Were costa seals .rein`on the coo er?, j
Blinn teen 2. If custody seals were *resent,were th r intact and unbmkcu?
h1-1 Strip ID: t`A Chlorine Snip ID: 14A Tested by:NA __ 1
tee receipt %Solid Snap-Cup pill NA
Oliginal tentpera,ure upon receipt:Derived(Corrected)leamperttt upon IN
•
19.4 i 19.4 :c NA 1 NA oC NA f NA oc NA f NA o[
I• letliod:LTenlperaturc Blank`` urst Bottles IR Gun ID: a IR Gun Collection Factor: a -(-
Method of coolant: n Wet Ice L_,1 [cc Path •�_ Ice None _ _ _ i
3. 1L rutty'''.crc a coolers ry-. at or below 6.0°C?Hilo,was Project Managernot�nl^
QYes ©No DNA PM was Notified by: +,lane!email I face-to-face(circle cute). '
Ai Yes iU No 112M 4. Is the commercial courier's 'tcking slip attached to this Bairn?
sim1INmin 5. Were proper custody procedures(relinstushed'rcccived)followorl?
lMIN h o 6. Were sample Ills listed on the COC and all;purple containers? _
itgraill® 7. Was collection date&time listed on the COC and all sample containers? I
l'I No_8.Did all container label information(ID.date.time)am-cc with the COC? j
ilIMIIt® 9. Were tests to be perfouncd listed on the COC?
10.Did all samples arrive in the proper containers for each test iu dlor in good condition
�'e� s [] To (unbroken-lids on.etc.)? _
i0ta �_ 11.Was adequate s.1 i lc voluane available?
1
` SMIIll No 12.Were all samples received within!n the holding time or 48 hours.whichever wines first'.'
El
Yes [JN•- 13.Were all samples containers accounted for?(No missing/excess)
'Yes x NA 14.Were VOA.8015C and RSK-175 samples free of bubbles>'pca-size"(`/4"or 6mm iti
❑ ❑ © diameter)in any of the VOA vials?
,IMm No INEZ 15.Were all DROY'1uetalshultrient sal es received at a H of<2?
1•112 •No'hal 16.Were all cyanide k% ^ d, k ,•d g �l...i[yhAiL twit I
17•Were a apphcan -N_3t� lcyanidettp teuo1f625. 1608.3(= .5tng1L)samples he:of
I❑Yes DM) ZNA residual chlorite
flirts ©I�o DNA 18.WAS the quote number listed on the container label?If yes.Quote;# i
';Sample Preservation (Must be completed for any sattrple(s)incorrectly preserved or with heads-pa c)
+amplc(s)"" were received incorrectly preserved and were adjusted accordingly
sample receiving with Nil nil.of circle one l t_SO4.HNO3.HO,NaOH using.SR 4 NA —
rime of preservation NA . If more that one presery ttice is needed,please note in the commons below.
5aurpate(s)
NA we a received with bubbles>6 nun in diameter.
i.amp led 5 1 were received with TRC>U.5 mail(If i#14 is no)and werc
. justed accordingly iu sample receiving with sodium thiosul:Pte(Na.S Q1)with Unique ID: wA
•
Comments:
a --- —.----
0ueltrax ID:56360 Paa0 Anatytiral Ser'.ces, sr.."
Page 1 of 1
Pace Analytical Services,LLC (formerly Shealy Environmental Services,Inc.)
106 Vantage Point Drive West Columbia,SC 29172 [phone] Fax[phone] www.pacelabs.corn
Page 51 of 51

r
Tab F

Environmental Testing Solutions, Inc. Invoice
P. O. Box 7565
Asheville, NC 28802 Date Invoice#
Phone # [phone]
3/19/2021 83527
Bill To
Monroe,City of
Mr.Kyle Ketchum
PO Box 69
Monroe,NC 28110
P.O.No. Terms Project
140071 Net 30 Aquatic Toxicity
Quantity Description Rate Amount
1 Pimephales Full Range Chronic 850.00 850.00
dank you for your business.
1
Total $850.00

PO Box 7565
Asheville, NC 28802
Phone: [phone]
Environmental Testing Solutions.Inc. Fax: [phone]
March 17, 2021
Ms. Stephanie Cooke
City of Monroe
775 Treeway Drive
Monroe, NC 28110
ETS Project Number: 15775
Test Start Date: March 02, 2021
Facility Tested: Monroe WWTP
Enclosed are toxicity test results for samples received by Environmental Testing Solutions Inc.
Parameter
Code Test Procedure, Method Number Result (ChV)
THP6C Fathead minnow, Pimephales promelas, Larval Survival and Growth Chronic >100%
EPA-821-R-02-013, Method 1000.0
All toxicity testing results required as part of your permit must be entered on the Effluent Discharge
Monitoring Form (MR-1)for the month in which it was performed, using the parameter code
THP6C. Additionally,the DMR Reporting Form AT-5 must be signed and e-mailed or mailed to the
following address:
ATForms.ATB(a�ncdenr.gov
North Carolina Division of Water Resources
Water Sciences Section/Aquatic Toxicology Branch
1621 Mail Service Center
Raleigh, NC 27699-1621
Please call if you have any questions concerning these results.
Sincerely,
ri Sumner
Laboratory Supervisor
North Carolina Certificate Numbers: Biological Analyses: 037, Drinking Water: 37786,Wastewater: 600
South Carolina Certificate Number: Clean Water Act: 99053-001

' - PO Box 7565
Asheville,NC 28802
Phone: [phone]
Fax: [phone]
Environmental Testing Solution,it>.
Effluent Toxicity Report Form-Chronic Fathead Minnow Multi-Concentration Test Date: March 17,2021
Facility: City of Monroe NPDES#: NC 0024333 Pipe#: 001 County: Union
Monroe WWTP
Laboratory Performing Test: Environmental Testing Solutions,Inc.,Certificate#037 Comments
Signature of Operator in Responsible Charge(ORC):
ORC Phone/E-mail: Project a: 15775
Signature of Laboratory Supervisor: 04,40 tQ.�� Sample 0: 210302.06,210304.07,210306.0E
e-Mail to: ATForms.ATB a(lncdenr.xov /7 Test Organisms: Pimephales promelas
Or Mail Original to:North Carolina Division of Water Resources Supplier
Water Sciences Section/Aquatic Toxicology Branch In-house Culture
1621 Mail Service Center Begin hatch: 03-01-21 1440
Raleigh,NC 27699-1621 End hatch: 03-02-21 0520
Test Start Date: March 02,2021
Replicate number
1 2 3 4
Control Surviving number of larvae 10 10 10 10 Survival(%) 100.0
Organisms Original number of larvae 10 10 10 10 Average wt(mg) 0.829
Weight/original(mg/larvae) 0.843 0.692 0.890 0.889 Average wt/ 0.829
surviving(mg)
%Effluent Surviving number of larvae 10 10 10 10
45% Original number of larvae 10 10 10 10 Survival(%) 100.0
Weight/original(mg/larvae) 0.900 0.817 0.926 0.847 Average wt(mg) 0.873
%Effluent Surviving number of larvae 10 10 10 10
67.5% Original number of larvae 10 10 10 10 Survival(%) 100.0
Weight/original(mg/larvae) 0.880 0.833 0.793 0.843 Average wt(mg) 0.837
%Effluent Surviving number of larvae 10 10 10 10
90% Original number of larvae 10 10 10 10 Survival(%) 100.0
Weight/original(mg/larvae) 0.905 0.949 0.861 0.880 Average wt(mg) 0.899
%Effluent Surviving number of larvae 10 _ 10 10 10
95% Original number of larvae 10 10 10 10 Survival(%) 100.0
Weight/original(mg/larvae) 0.744 0.864 0.970 0.917 Average wt(mg) 0.874
%Effluent Surviving number of larvae 10 10 10 10
100% Original number of larvae 10 10 10 10 Survival(%) 100.0
Weight/original(mg/larvae) 0.861 0.942 0.850 0.838 Average wt(mg) 0.873
Water Quality Data
Day 0 Day 1 Day 2 Day 3 Day 4 Day 5 Day 6
Initial I Final Initial I Final Initial I Final Initial 1 Final Initial I Final Initial I Final Initial I Final
Control
pH(61.): 7.68 7.49 7.56 7.25 7.63 7.33 7.89 7.20 7.54 7.28 7.73 7.47 7.80 7.19
DO(mg/L): 7.8 7.8 7.7 7.6 7.6 7.4 7.6 7.4 7.8 7.3 7.8 7.5 7.7 7.0
Temp.(°C): 24.7 24.4 24.8 24.7 24.7 24.6 24.7 24.5 24.7 24.7 24.8 24.5 24.8 24.6
High Concentration
pH(SU): 7.12 7.37 7.58 7.20 6.88 7.17 7.53 7.23 7.15 7.48 7.71 7.63 7.74 7.41
DO(mg/L): 8.1 7.9 7.9 7.9 8.3 7.1 7.7 7.3 8.0 7.4 7.8 7.5 7.8 7.3
Temp.I°C): 25.0 24.5 25.0 24.9 25.0 24.7 24.9 24.8 25.3 24.7 24.9 24.5 25.0 24.3
Sample Information Sample 1 Sample 2 Sample 3 Control Analyses Survival Growth
Collection start date: 02-28-21 03-02-21 03-04-21 .`'i Normal: Yes Yes
Grab: • rFi Horn.Var. Yes Yes
Composite duration: 24-h 24-h 24-h ._ NOEC: 100% 100%
Alkalinity(mg/L CaCO3): 64 73 89 60,59,58 LOEC: >100% >100%
Hardness(mg/L CaCO3): 110 140 170 87,87,85 ChV: >100% >100%
Conductivity(Nmhos/cm): 464 690 852 302-324 Method: Visual Insp. Dunnett's
Total residual chlorine(mg/I.): <0.10 <0.10 <0.10 , ' 'j`J
Sample Temp.at Receipt(°C): 2.9 1.6 1.0 . Survival Growth
%Effluent Critical Calculated Critical Calculated
45% . . 2.410 -0.954
67.5% . . 2.410 -0.190
90% 2.410 -1.524
95% . . 2.410 -0.981
Overall Analysis: 100% . 2.410 -0.960
Result: PASS LOEC: >100% NOEC: 100% ChV: >100%
DWR Report Form AT-5

Page 1of5
Environmental Testing Solutions.Inc.
Chronic Whole Effluent Toxicity Test (EPA-821-R-02-013, Method 1000.0)
Species: Pimephales promelas
Client: Monroe WWTP County: Union
NPDES#: NC 0024333 Outfall #: 001
Project#: tS'r\S
Dilution preparation:
Dilution prep(%) 45 67.5 90 95 100 Sample was not aerated or treated unless otherwise
Effluent volume(mL) 450 675 900 950 1000 noted on this form. Sample was warmed to 25.0±1.0°C
Diluent volume(mL) 550 325 100 50 0 in a warm water bath and then diluted to the test
Total volume(mL) 1000 1000 1000 1000 1000 concentrations with moderately hard synthetic water
(MHSW).
Test organism information: Test information:
Organism source: In-house culture Randomizing template: U61K '(et.Los
Incubator number
Age: <24-hours old (p C
and shelf location:
Spawn date: n1 m•1\ Artemia CHM number: CHM1149
63-a\-IA I' '4O Drying information for weight determination:
Hatch dates and times: 70 03.0•1.-t\ 0 S1-0 Date/Time in oven:
"Initial oven temperature: un•C
pH(S.U.)=8.1"5 Date/Time out of oven: 01•I4-11 I OCU
Transfer vessel information: 1
Temperature(°C)= 14•,` °Final oven temperature: L 0•C
Average transfer volume(mL): <0.25 mL Total drying time: Z.'-(-HoiAS
'60°C Oven,Thermometer SN:14-98565
Daily feeding and renewal information:
Day Date Morning feeding Afternoon feeding Test initiation,renewal, Sample MHSW
or termination number batch used
Time Analyst Time Analyst Time Analyst used A 0 03-02-21 OS•3o n` 14130 U t1.\� N 1103o2.0(. 01-.5.11A
1 03-03-21 a&3p G 11'S ‘V..- �,
o 1 pd t 10 0 (I` -
2 03-04-21 ae �`00 \ZCO D11,f 1 1"SO 4 it co'.L cif ca-•15.21 C
3 03-05-21 °5�0 17( ll1v {1,t� 10\`1 lit S. 1
4 03-06-21 I
5 oboo 1l3 0 R 0_1 ck {-f Zl(LSUb.6. n-04•tl N
03-07-21 053o N t,�o l l D l ii
6 03-08-21 0530 �(0` 1l q l) (,( 106
/U�
7 03-09-21 J D i(�
t02q (j�
Chemical analyses:
Parameter Reporting Limit Method number Meter Serial number
pH 0.1 S.U. SM 4500-H+B-2011 Accumet AR20 93312452
Dissolved Oxygen(D.O.) 1.0 mg/L SM 4500-0 G-2011 YSI Model S2CE 18D104324 i
Conductivity 14.9 µmhos/cm SM 2510 B-2011 Accumet AR20 93312452 I
Alkalinity 5.0 mg CaCO3/L SM 2320 B-2011 Accumet AR20 93312452
Hardness 5.0 mg CaCO3/L SM 2340 C-2011 Not applicable Not applicable
Chlorine,Total Residual 0.1 mg/L ORION 97-70-1977 Accumet AB250 92349123
Temperature 0.1°C SM 25508-2010 Digital Thermometer 1306646f5
Control information: Acceptance criteria Summary of test endpoints:
%Mortality: CY1- <_20% 7-day LC50(%) 7 1 00 1•
Average weight per initial larvae: v-$ A NOEC(%) 1001
Average weight per surviving larvae: 0-Q'i4 >_0.25mg/larvae LOEC(%) 100 7.
ChV(%) )1 00 7,
ICzs(%) '>I Ob 7.
SOP AT20-Revision 6—Exhibit AT20.3

E-OZlb'1!q!03-9 uo!s!nad-OZIV dOS
:s4uawwoj
-papunoM=M 'pawnlai pue palueaap=pgp 'aJel Ap ensnun=�1
'news Aliensnun = ws 5pis= Tu!ssiw= w 'pall! = 'snSun4=gj'peep=p 'Jeep =a :sapoa luawwop
.OZSIb NS'aauelegoJlaa13 a!lewolnd gZ ugej 2u!sn pawJojiad sluawaJnseaw 11-191a/V1*
(',)loi uo3
-L 1 1 - Lc 0 •s- b
�L8'9 ZS "0 woa1
uo!hnpa.1 (2w)aemei;o aagwnu
3ua»ad le!3!u!gad 342!am a2eaany
-Q4 .0 0 0 0 0 0 0 O 0 .0 :3sAleuy
% v 5 45 .ra g s\ `b
aenuej Jo Jagwnu ie!3!ul/D=
(2w)aen.2el to Jagwnu le!3!u!aad 142!anq
:3sAleuy
4h.8 fib►- 4.44 08.8 1-1-,•8 91•b o'a Oo• , b$ 8 QV 8
v-9=(2w)342!am aenaei=J
$ \t h-S\ SD •
E'11U1- gn'4t 4.5L •U•41- t's.K- Vitt- cvvt Sb•� �4t :3sAleuV
(2w)342!am aemei+ued=e.
• ..c3\ •H� ,� .c3` •4` \ lZ•ry L LO :alea
<I \ 0/l' , cO \r iThl` b0 �o 0� d� :3sAleuy
0J% :apoa Jolo)Aell
(2w)342!am ued=V.
01 0/ O) 0/ 0/ 0/ 0i 0/ 0, Cl / Cll
0 ) 01 O/ 01 01 01 0 ) 41 Qi 0/ 01 01
9
0) 0/ 0 ) 0 / 01 01 QI O) O ) ai 01 0 )
5
0) 0 / 01 0 ) 0) 01 01 0I 01 Q1 01 01
0 / 0/ 0 ) 01 01 0) 01 01 01 0 / 01 01 E
0/ 0 / 0 / 01 a1 01 0 / 0 / 0 / 01 01 01
0/ 0 / 0/ 0 ) 0/ a) 0 / 0 / 01 Qi 0/ 0)
01 OT 0T 0I 0T OT 0T OT 0I OT 0I OT
0
1 N 1 1 H 9 3 3 a J 8 V
%S•L9 %Sb 1Oa1NO3 Aea
amp L/JMoJD pue lonlnUns
TZ-Zo-£0 :aaea d1MM aoJuow :;ua11J
salawoad saloydawld :saiDads
•suopnios 6upsaiiquawuosinu3
S 3o Z aged , , -

Page3of5
Environmental Testing Solutions,Inc.
Species: Pimephales promelas
Client: Monroe WWTP Date: 03-02-21
Survival and Growth Data
Day 90% 95% 100%
M N 0 P Q R S T U V W X
0 10 10 10 10 10 10 10 10 10 10 10 10
1 (0 ID lO ) 0 tD ID tO /D / 0 /0 /0 /p
2 10 (0 m 10 ( 0 10 I ) I0 10 to 10 IC)
3 I0 I0 ID 1p / 0 f0 I0 to ( 0 t b ( 0 /0
4
( 0 / 0 ID Ib / 0 tD ID t0 /0 10 10 (0
5
ID ID ID 10 ID 10 ID ID /() ID /0 /0
6 (0 10 IO IU ID t b 10 )0 /0 IO /0 /O
(� /0 /p 10 / 0 /o /0 Co IO t0 tO ( 0
*A=Pan weight(mg)
Tray color code: j(ov'n M (
Analyst: _ 1Lt7 �'1 �'Q \9, QO h� o` �� �a K �9� fin, a
Date: _ ot.t .2� �{0. �fr� �M' �• \�• \�� �' \ \� \n. \� `�•
*B=Pan+Larvae weight(mg)
Analyst: _ .c "LA-St '04.59 Ti' SO 13.00 1 SI L'I.It 'L4.O1 L't 16 IS.C. 15-V5 12.5E
Date: IS-IA
C=Larvae weight(mg)=B—A
9.0S 9.0 g•(.1 g.gO ''•y`k g.ta-{ 4.10 ct.11 g.tol q.-kz g.So 8.38
Analyst: _
Weight per initial number of larvae(mg)
=C/Initial number of larvae
Cr,
Analyst: _ '
o• o. O 0 p p Q•
Average weight per initial Percent
number of larvae(mg) reduction Q. g q g _g. 7. -5•S 7. 0 g 13 -5. 3 7.
from control
(%)
*Weight measurements performed using Cahn 28 Automatic Electrobalance, SN 41520.
Comment codes: c=clear, d=dead, fg=fungus, k= killed, m = missing,sk=sick, sm =unusually small,
Ig=unusually large, d&r=decanted and returned, w=wounded.
Comments:
SOP AT2O-Revision 6—Exhibit AT20.3

Fnrironmenul Testing Solutions,Inc
Quality Control: Verification of Data Entry,Calculations,and Statistical Analyses
Chronic Whole Effluent Toxicity Test(EPA-821-R-02-013, Method 1000.0)
Species: Pimephales promelas
Facility: Monroe WWTP Entered by.
Kelley Kcmnan
Test start date: March 02,2021 Rcvµwodby:
Project number: 15775 lim Su l,nur
Sample numbers 210302.06,210304.07,210306.06 ,J,J.J`
Concentration(%) Replicate Initial number of Final number of larvae a=Pan weight(mg) B=Pan.larvae Larvae weight(mg) Weight/Surviumg Mean weight/ Coefficient of variation Weight/Initial number Mean survival Mean weight/Initial Coeffklent of variation Percent reduction from
4rvae weight(mg) :-R-A number of larvae Ita.....
Img) Surviving number of ,a.a"r.^+^^r^..^a.' of larvae(mg) Irl number of larvae
Ixl control(x)
larvae(All .ri.,...Ilxl Imel
A 10 10 13.40 21.83 8.43 0.843 0.843 e
Control0.829 11.3 8 10 10 15.62 22.54 6.92 0.692 0.692 100.0 0.829 11.3 Not ap
plicable
C 10 10 14.90 23.80 8.90 0.890 0.890
D 10 10 15.06 23.95 8.89 0.889 0,889
-E 10 10 15.89 24.89 9.00 0.900 0.900
45% F 10 10 15.06 23.23 8.17 0.817 0.873 5.7 0.817 100.0 0.873 5.7 -5.3
o 10 10 13.41 22.67 9,26 0.926 0.926
H 10 10 15.93 24.40 8.47 0.847 0.847
I 10 10 14.32 23.12 8.80 0.880 0.880
67.5% 1 10 30 14.20 22.53 8.33 0.833 0 837 3 0.833
K 10 10 15.67 23.60 7.93 0.793 0.793 100.0 0.837 4.3 -1.1
L 10 V 10 14.21 22.64 8.43 0.843 0.843
M 10 10 15.47 24.52 9.05 0.905 0.905
90% N 10 10 15.10 24.59 9.49 0.949 0.899 4.2 0.949 300.0 0.899 4.2 -8.5
O 10 10 13.63 22.24 8.61 0.861 0.861
P 10 10 15.00 23.80 8.80 0.880 0.880
_ Q 10 10 15.56 23.00 7.44 0.744 0.744
95Y R 10 10 14.89 23.53 8.64 0.864 0.874 11.1 0.864 300.0 0.874 11.1 -5.5
5 10 10 14.68 24.38 9.70 0.970 0.970
T 10 10 14.84 24.01 9.17 0.917 0.917
U 10 10 15.75 24.36 8.61 0.861 0.861
100% V 10 10 15.66 25.08 9,42 0.942 0.942
0.873 5.4 100.0 0.873 5.4 -5.3
W 10 10 14,83 23.33 8.50 0.850 0.850
X 10 10 14.54 22.92 8.38 0.838 0.838
Outfali 001: MSD= Minimum Significant Difference
Dunnett's MSD value: 0.1111 PMSD= Percent Minimum Significant Difference
PMSD: 13.4 PMSD is a measure of test precision.The PMSD is the minimum percent difference between the control and treatment that can be declared statistically significant in a whole effluent toxicity test.
Lower PMSD bound determined by USEPA(10th percentile) =12%.
Upper PMSD bound determined by USEPA(90th percentile)=30%.
Lower and upper PMSD bounds were determined from the 10th and 90th percentile,respectively,of PMSD data from EPA's WET Interlaboratory Variability Study(USEPA,2001a;USEPA,2001b).
USEPA. 2001a,2001b.Final Report Interlaboratory Variability Study of EPA Short-term Chronic and Acute Whole Effluent Toxicity Test Methods,Volumes 1 and 2-Appendix.EPA-821-8.01-004 and EPA-821-8-01-005.US Environmental Protection Agency,Cincinnati,OH.

[meted W.
�I YY eny,
Statistical Analyses
Sumneriirn
Emiwnrnenul Testing Solutions.Inc (1.1)
Larval Fish Growth and Survival Test-7 Day Growth
Start Date: 3/2/2021 Test ID: PpFRCR Sample ID: Monroe
End Date: 3/9/2021 Lab ID: ETS-Envir.Testing Sol. Sample Type: DMR-Discharge Monitoring Report
Sample Date: Protocol: FWCHR-EPA-821-R-02-013 Test Species: PP-Pimephales promelas
Comments:
Conc-% 1 2 3 4
D-Control 0.8430 0.6920 0.8900 0.8890
45 0.9000 0.8170 0.9260 0.8470
67.5 0.8800 0.8330 0.7930 0.8430
90 0.9050 0.9490 0.8610 0.8800
95 0.7440 0.8640 0.9700 0.9170
100 0.8610 0.9420 0.8500 0.8380
Transform:Untransformed 1-Tailed Isotonic
Conc-% Mean N-Mean Mean Min Max CV% N t-Stat Critical MSD Mean N-Mean
D-Control 0.8285 1.0000 0.8285 0.6920 0.8900 11.298 4 0.8639 1.0000
45 0.8725 1.0531 0.8725 0.8170 0.9260 5.673 4 -0.954 2.410 0.1111 0.8639 1.0000
67.5 0.8373 1.0106 0.8373 0.7930 0.8800 4.271 4 -0.190 2.410 0.1111 0.8639 1.0000
90 0.8988 1.0848 0.8988 0.8610 0.9490 4.232 4 -1.524 2.410 0.1111 0.8639 1.0000
95 0.8738 1.0546 0.8738 0.7440 0.9700 11.070 4 -0.981 2.410 0.1111 0.8639 1.0000
100 0.8728 1.0534 0.8728 0.8380 0.9420 5.398 4 -0.960 2.410 0.1111 0.8639 1.0000
Auxiliary Tests Statistic Critical Skew Kurt
Shapiro-Wilk's Test indicates normal distribution(p>0.01) 0.94248 0.884 -0.7357 0.67902
Bartlett's Test indicates equal variances(p=0.39) 5.22981 15.0863
Hypothesis Test(1-tail,0.05) NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df
Dunnett'sTest 100 >100 1 0.11112 0.13412 0.00274 0.00425 0.66885 5,18
Treatments vs D-Control
Linear Interpolation(200 Resamples)
Point % SD 95%CL(Exp) Skew
IC05 >100
IC10 >100
IC15 >100 1.0
IC20 >100
IC25 >100 0.9
IC40 >100 0.7-
IC50 >100
0.6-
0.5-
0
g
i� 0.3-
C
0.2-
0.1-
e..___ o -0 000
-0.1- - -
-0.2
0 50 100 150
Dose
Dose-Response Plot
1.2
1
t 0.8>
3 _ 1-tail,0.05 level
2 of significance
C7 0.6
O
t`0.4
0.2
0
at 8
a
U
d

Page 4 of 5
Environmental Testing Solutions,Inc.
Species: Pimephales promelas Date: 03-02-21
Client: Monroe WWTP
Daily Chemistry:
Temperatures performed at the time of test initiation,renewal or termination by the analyst identified in the Daily Renewal Information table
located on Page 1. Alkalinity,hardness and chlorine(total residual)performed by the analyst identified on the bench sheet specific for each
analysis and transcribed to this bench sheet.
Day
(Analyst identified for each day,performed pH,D.O.and conductivity measurements only.)
0 1 2
Analyst PiT I41, rts rp H I iw Vt..
Concentration Parameter
pH(S.U.) -GE 7-49 --).s(9 i+.25 '- 3 1- 3-3Dissolved oxygen(mg/L) "-B 4-5 -4.7 1-L i.Ai
CONTROL, Conductivity(pmhos/cm) E 3 ZO 316
MHSW Alkalinity(mg CaCO3/L) (00 59
Hardness(mg CaCO3/L) 81 o-L.tt•u ti 81
Temperature(°C) Z4.1 -‘.A.4 M.A.4 -_A-1 -1.`'-1 -\-i.k-b
pH(S.U.) 7.3e 7.1-fz -7• ? /Lid -O(a '}.21
Dissolved oxygen(mg/L) u,� 1.7 q-6 1,e aj,0 /\,q
45% 7
Conductivity(pmhos/cm) 360 H t 3 `4 t/- `t
Temperature(°C) -1.4.c\ AA.1. 'LA•'\ 1-k. A.A. 1-v-l• p
pH(S.U.) �.'30 353 -I.s-7 T-IB ..0l s' 1
Dissolved oxygen(mg/L) I q-e3 -7_d 11--Q 8 0 ri--I
67.5% Conductivity(µmhos/cm) u/ )4 y 5 % 5t,lt 1
Temperature(°C) Z4_Q\ -`-1.Io -AA. 1 - A_c1 - & -14.1
pH(S.U.) 7. <� 1. 3y ?.c7 (4'4q Ip.9%4 1-0`21
90% Dissolved oxygen(mg/L) 1 q,}j ' -6. 1)2, 1 1-,2-
0
Conductivity(pmhos/cm) 4153 s.l eR 0 21-
Temperature(°C) 1..S-0 Z-l.of Zk.q\ Z'1,`.1 Zq- 1 Z-t•1
pH(S.U.) q./S 7.37 '7.sg 1,i1Q tP•92 1,01-
Dissolved oxygen(mg/L) 1 -4_1 3-6 1- 1 es.2. 1--V
95% S/
Conductiyity(pmhos/cm) ti54,:, `7014 (p/9
Temperature(°C) 7AS-0 AA•to AS- Q -1.4.n1 +�12-V\ 14•1
pH(S.U.) -f�/2 7. S7 -1•S� l� (a.80
Dissolved oxygen(mg/L) '1 ,9 '/,C1 --r]1 83 4
Conductivity(pmhos/cm) y6,1 5`13 1090
100% Alkalinity(mg CaCO3/L) Co Li 1 3
Hardness(mg CaCO3/L) I I 0 iy 0
Chlorine(mg/L) LV,1 Q <0.10
Temperature(°C) -LS-0 —IA-5 ZS•0 Zy-ck -IS.0 2'1.1
Initial Final Initial Final Initial Final
SOP AT2O-Revision 6-Exhibit AT20.3

r
Page 5 of 5
Environmental Testing Solutions.Inc.
Species: Pimephales promelas
Client: Monroe WWTP Date: 03-02-21
Day
(Analyst identified for each day,performed pH,D.O.and conductivity measurements only.) I
3 4 5 J 6
Analyst . / 8SL /-(-3 i- !"`-� ,/s f—i s
Concentration Parameter till r`
pH(S.U.) 1•r33 1,a 0 1.54 7-z c -q.l3 7 f 7.8-0 7-r q
Dissolved oxygen(mg/L) 1./6 1.1+ " ,Z y.`l_3 ..t3 ' •c,— •q `7•p
CONTROL, Conductivity(µmhos/cm) 3 O z 305 T 3)I TSZL 7
MHSW Alkalinity(mg CaCO,/L) 5R --_________,
Hardness(mg CaCOr/L) -y.1` 8 S c t�n4i•tt
Temperature('C) /1A..-11,, -I-LA•S �I-NA-1 �1f--\.1 --1-A- b -�J��-�S• -7'IA-�la Z7`•1-to
pH(S.U.) T.JI[� 7�oa0 .3.i 7•3(0 T.5e9 '('7� 3-6,2. 4 Z.c
Dissolved oxygen(mg/L) 1v-} -4,3 �'Q 7.3 '7•8 7.6 '7-'-1 4-.)
45% ,r� ! Y T
Conductivity(µmhos/cm) �•SL, C _l ^1 533 ` (� 5C-)q S sgJ�q
Temperature(°C) �-IA•3 -7 -.'l• ` --t 11..'�AJc\ -LA.)j y�-• \ IA•� •t4..'\ y-IA-L
pH(S.U.) 7r'58 4.a0 .[..Y- 736 -r'�3 7•6-Q -4-(0 -7•
Dissolved oxygen(mg/L) '' -4,3 q . -3 -7_8 3,J- "1-'7 �.Z
67.5°i �S 7 lQ 3 beo grri't
Conductivity(µmhos/cm)
Temperature(°C) /'tl..`,-'�+ y. .Q1- 1 h°)--0 '-�-Q y2`{_ 1 L'A.\ IA.i �l•S
pH(S U.) 1.�Ji T, 6 1.aT 7.Lir �7-��O �.6�i 4.31 *7.31
Dissolved oxygen(mg/L) .•43- -1,3 To -q.3 V e 7-S '�/--7' 4.2
90% � 191 -393 I COY Tj 0
Conductivity(µmhos/cm) _ L �r �t ` Q
Temperature(°C) �.{ '1oA-(a IS.1 AA-1 -`l• \ ZA_1 �.O 1.•.-‘•1
pH(S.U.) 1-.J} `4.ag q,a3 7H, 7.17-o 3.6`-( 4.72 7 Li1
Dissolved oxygen(mg/L) ')--: 1,3 $.O !.y 7-6 �f,cj' 7'Y -7,3
9s°i la 6o 615 e l� i 'tg�-T!3
Conductivity(µmhos/cm) c �A
Temperature(CC) Z-�l. C(± `'k �-S
L. -1-- .-1\ 1_,-V -ta•L Is.0 A..-1-S
pH(S.U.) ' .5.6 -4, 5 1.1g- 3`i8 .:1 I "-c,,3 7•31-i 'I-`11
r 1 7 7 -7
Dissolved oxygen(mg/L) � 7
. •3 I.Z. -,-i 7e 7..5 4.8 .7•3
Conductivity(µmhos/cm) 1+01 VS' g4,Z 9'c-1Z
100% Alkalinity(mg CaCOs/L) 8cA
Hardness(mg CaCOs/L) I,0
Chlorine(mg/L) { p Cl < 0,l0
Z
Temperature(°C) A.Gt A.A.. LS•- ZUI•1 Z`-`\ ZA-S u.0 14.J
' Initial Final Initial Final Initial Final Initial Final
I
SOP AT2O-Revision 6—Exhibit AT20.3
I

r
' `j 3 5 I Depot Street
r
Asheville,NC 28801
Phone: [phone]
Fax: [phone]
_ Environmental Testing Solutions,Inc.
Whole Effluent Toxicity Chain-of-Custody Form
'acility: Monroe WWTP NPDES#: NC0024333 Pipe#: 001 County: Union
Purchase order:
ipecies: Pimephales promelas Effluent dilution: 45,67.5,90,95, 100%
fest type: Chronic Definitive Parameter code: THP6C
Sample information: (to be completed by sample collector)
Composite sample: Sample location: Lff f,j
Start date: 2- 2./-2( Time: 1L - Volume collected for testing: L
End date: ,' Z—(- i Time: Number of containers filled for testing: 3
Number of samples per hour: IOW Method of transport to laboratory: lj ey
Chilled during collection? e_ Comments:
If chilled,specify temperature: 3 t`.
Triple rinse sample container with sample before filling. Completely fill the sample container with no air space.
Pack the sample container completely in ice. The sample must be<6.0°C upon receipt at the laboratory.
S custody: (to be completed by sample collector and facility personnel)
Sample collected by:
StiCciv- ne_ r �(- 2 (
. ('CC2er i (_(,'2I' (O(. -1
font Signal.: Daic and un,
RelinItiCtr-
quished by:
{ Received by:
L (Q( -0
on�� c 3-i ��( 1�'� 05 i-u
I'nnt Sipnalwc Dac and now Pnnt Stgnanwc Dale and umc
Relinquished by: Received by:
Null Signutu: Date and non Ihint Signal.: I)atc and ttm: '
. .... ......... ......_.».__..._... ass,_,,:, .xu..,.__.,,,r_r :“,grwn- . ._.-._.
Sample receipt information: (to be completed by ETS personnel) •
Relinquished to ETS by: Received at ETS by:
(.)3-Oi-la F
i 053 I/C 0.) I� M.3
Print signatwc Dale and.nn 1'nm Signamc Datc and lime
Custody seals intact?: 1=1/11.1 _ Sample temperature upon receipt at ETS(°C): i 1
Yes Nu NM +cJ 4
Samples received in good condition?: _
Y°a No Total residual chlorine upon receipt at ETS: _ I
r[��� I^G dnJU (DPD Presence/Absense Indicator,MDL=0 10 mg/L) V 1 ^1i'"'
Tracking number: '7 e05
Project numberle5)-15 Sample number: I .J b 302.p(o
lments:

F
0 wini ar omp 1
351 Depot Street
Asheville,NC 28801
Phone: [phone]
Fax: [phone]
N.
.„ Environmental Testing Solutions,Inc.
Whole Effluent Toxicity Chain-of-Custody Form
Facility: Monroe WWTP NPDES#: NC0024333 Pipe#: 001 County: Union
Purchase order:
Species: Pimephales promelas Effluent dilution: 45,67.5,90,95, 100%
Test type: Chronic Definitive Parameter code: THP6C
Sample information: (to be completed by sample collector)
Composite sample: Sample location: Ge(W -
Start date: 3-2—24 Time: tOCA Volume collected for testing: 1 t-,
End date: 5 . -Z( Time: IC)()Co Number of containers filled for testing:
Number of samples per hour: PmJ Method of transport to laboratory: , i
Chilled during
collection? �'j Comments:
If chilled,specify temperature: e
Triple rinse sample container with sample before filling. Completely fill the sample container with no air space.
Pack the sample container completely in ice. The sample must be<6.0°C upon receipt at the laboratory.
S custody: (to be completed by sample collector and facility personnel)
Sample collected by:
Me K. Ctt _ lQ
Punt Signature Date and time
Relinquished by: Received by:
r- ridii..e,_--1, flu___ 3-3-2 0 3.o;zi
� lQl- I-eC k. --19
Trent Signature Ihi<and time 1'nnt Sigrmtw. Date and°nn
Relinquished by: Received by:
runt Signature Ihw and OTC Nino Signaue Due and time
Sample receipt information: (to be completed by ETS personnel)
Relinquished to ETS by: Received at ETS by:
03,04 2- Q 3.cal 71
I—icti„—, t of e 1 10
I'nnt Stgnaw.: I hie and time I'mn Sign..: Date and time
Custody seals intact?: _la — — Sample temperature upon receipt at ETS(°C):
Y.s No Not ua ul /. , r
Samples received in good condition?: ' —
Y.s No Total residual chlorine upon receipt at ETS: _ 771
�f _ La J 3 2 Bey ` (DPD Presence/Absense Indicator,MDL=0.10 mg/L) r"'<nt Ab"rt
Tracking number: 1 /4t
Project number:'S Sample number:4lO3O'4•in-
ments:

II
:`> , 'r 351 Depot Street
Asheville,NC 28801
Phone: [phone]
Fax: [phone]
Environmental Testing Solutions,Inc.
Whole Effluent Toxicity Chain-of-Custody Form
Facility: Monroe WWTP NPDES#: NC0024333 Pipe#: 001 County: Union
Purchase order
Species: Pimephales promelas Effluent dilution: 45,67.5,90,95, 100%
Test type: Chronic Definitive Parameter code: THP6C 1
Sample information: (to be completed by sample collector) /f
Composite sample: Sample location: CK (Wilt
Start date: 3 - —Z( Time: 17IQ Volume collected for testing: r3 L.
End date: '' ,— S — Z 1 Time: i Number of containers filled for testing:
per hour:Number of samples
�(0 Method of transport to laboratory: f' i
Chilled during collection? Comments:
If chilled,specify temperature: Q,'g
Triple rinse sample container with sample before filling. Completely fill the sample container with no air space.
Pack the sample container completely in ice. The sample must be<6.0°C upon receipt at the laboratory.
S custody: (to be completed by sample collector and facility personnel)
Sample collected by:
I r C3i 1 {
1'nnt Swum.: Damandtmm
Relinquished by: Received by: l;
Pnm Sigautmc Date and tom Pnnt Stsnanue IAte and nme I
Relinquished by: Received by:
i I
Punt Swann.: Date and limn I'rint Swann.: Date and tom •
neanannaananaaaanannaann
Sample receipt information: (to be completed by ETS personnel)
Relinquished to ETS by: Received at ETS by:
T ` iWI- 14A— IA- I i ir}
Prim Signature Date and tune 14im Signnm. Date and time
Custody seals intact?: 1111 - - Sample temperature upon receipt at ETS(°C):
Y. No NW weal !,i 'C
Samples received in good condition?: " _
Y. No Total residual chlorine upon receipt at ETS: _ =r
�, ( (DPD Presence/Absense Indicator,MDL=0.10 mg/L) It"ent Absent
r
Tracking number: 'v✓� �� {{�� ,�r �.a.--►;.,AA
Project number:1l Sample number:�a 5 Q tJ�_
ments: #Z i40 b,0{0

Pimephales promelas
Chronic Reference Toxicant Control Chart
Environmental Testing Solutions,Inc. Source: In-house Culture
0.9 1 1 1 1 1 1 1 I 1 1 1 1 1 1 1 I 1 1 1 1
Control Limits (± 2 Standard Deviations) -
0.8 - -
• •
•
• •
0.7 - • • -
• • • • •
• • • • •
• • •
U
0.6 - -
tvo
III III I I I I I I I I I I I I I I
' 1.2
(„) I I I 1 I I I I I I I I I I I I I I I I
Warning Limits
1.0 - . ........... ......... .............. . . . ... .. ......... . . ................ .... ..... ..
•
0.8 - ... _ _
•
• •
• • • •
• • • • • • • • • • I • •
0.6 -
I I 1 I 1 I I 1 I I I I I 1 I I l I I I
09.10 10 0$-110y,1L.03�1.01 OtiOA�303��.0�OS.05 p602��sp��-01 D sp.p9.15 1�O6 11AO;LO$010,��Oti p0ti�1
Test date
• 7-day IC25=25%inhibition concentration. An estimation of the potassium chloride concentration
which would cause a 25%reduction in Pimephales growth(calculated using ToxCalc).
Central Tendency(mean logarithmic IC25 converted to anti-logarithmic values)
• Control Limits (mean logarithmic ICZS±2 standard deviations converted to anti-logarithmic values)
Laboratory Warning Limits(mean logarithmic ICZS±2 coefficent of variations converted to anti-logarithmic values)
USEPA Warning Limits (mean logarithmic ICZS±SA.75 converted to anti-logarithmic values,
SA 75=75th percentile of CVs reported nationally by USEPA)
inDyed ma
sm;rw.e N
m Sumner

Environmental Testing Solutions, Inc. Invoice
P. O. Box 7565
\sheville, NC 28802 Date Invoice#
_'hone# [phone]
9/26/2022 92035
Bill To
Monroe,City of
Mr.Kyle Ketchum
PO Box 69
Monroe,NC 28110
P.O.No. Terms Project
140071 Net 30 Aquatic Toxicity
Quantity Description Rate Amount
1 Pimephales promelas Pass Fail Chronic 850.00 850.00
Thank you for your business.
Total $850.00

PO Box 7565
Asheville, NC 28802
__— Phone: [phone]
Environmental Testing Solutions,Inc.
Fax: [phone]
September 25, 2022
Mr. Kyle Ketchum
City of Monroe
775 Treeway Drive
Monroe, NC 28110
ETS Project Number: 17252
Test Start Date: September 13, 2022
Facility Tested: Monroe WWTP
Enclosed are toxicity test results for samples received by Environmental Testing Solutions Inc.
Parameter
Code Test Procedure, Method Number Result (ChV)
Fathead minnow, Pimephales promelas, Larval Survival and Growth Chronic
THP6C >1OU%
EPA-821-R-02-013, Method 1000.0
All toxicity testing results required as part of your permit must be entered on the Effluent Discharge
Monitoring Form (MR-1) for the month in which it was performed, using the parameter code THP6C.
Additionally, the DMR Reporting Form AT-5 must be signed and e-mailed or mailed to the following
address:
ATForms.ATBncdenr.qov
North Carolina Division of Water Resources
Water Sciences Section /Aquatic Toxicology Branch
1621 Mail Service Center
Raleigh, NC 27699-1621
Please call if you have any questions concerning these results.
Sincerely,
Jim S mner
Laboratory Supervisor
North Carolina Certificate Numbers: Biological Analyses: 037, Drinking Water: 37786,Wastewater: 600
South Carolina Certificate Number: Clean Water Act: 99053-001

PO Box 7565
Asheville,NC 28802
Phone: [phone]
Fax: [phone]
Environmental Testing 501.1.15.11w.
Effluent Toxicity Report Form-Chronic Fathead Minnow Multi-Concentration Test Date: September 25,2022
Facility: City of Monroe NPDES#: NC 0024333 Pipe#: 001 County: Union
Monroe WWTP
Laboratory Performing Test: Environmental Testing Solutions,Inc.,Certificate#037 Comments:
Signature of Operator in Responsible Charge(ORC):
ORC Phone/E-mail: Project n: 17252
Signature of Laboratory Supervisor: / Sample 6: 220913.57,220915.07,220917.07
e-Mail to: [e-mail] Test Organisms: Pimephales promelas
Or Mail Original to: North Carolina Division of Water Resources Supplier
Water Sciences Section/Aquatic Toxicology Branch In-house Culture
1621 Mail Service Center Begin hatch: 09-12-22 1455
Raleigh,NC 27699-1621 End hatch: 09-13-22 0500
Test Start Date: September 13,2022
Replicate number
1 2 3 4
Control Surviving number of larvae 10 10 10 10 Survival(%) 100.0
Organisms Original number of larvae 10 10 10 10 Average wt(mg) 0.787
Weight/original(mg/larvae) 0.729 0.772 0.744 0.904 Average wt/ 0.787
surviving(mg)
%Effluent Surviving number of larvae 10 10 9 10 _
45% Original number of larvae 10 10 10 10 Survival(%) 97.5
Weight/original(mg/larvae) 0.896 0.804 0.878 0.906 Average wt(mg) 0.871
%Effluent Surviving number of larvae 10 10 10 10
67.5% Original number of larvae 10 10 10 10 Survival(%) 100.0
Weight/original(mg/larvae) 0.748 0.821 0.827 0.751 Average wt(mg) 0.787
%Effluent Surviving number of larvae 10 10 10 10
1 90% Original number of larvae 10 10 10 10 Survival(%) 100.0
Weight/original(mg/larvae) 0.787 0.750 0.709 0.847 Average wt(mg) 0.773
%Effluent Surviving number of larvae 9 10 10 _ 10
95% Original number of larvae 10 10 10 10 Survival(%) 97.5
Weight/original(mg/larvae) 0.828 0.803 0.900 0.782 Average wt(mg) 0.828
%Effluent Surviving number of larvae 10 10 9 10
100% Original number of larvae 10 10 10 10 Survival(%) 97.5
Weight/original(mg/larvae) 0.756 0.750 0.753 0.772 Average wt(mg) 0.758
Water Quality Data
Day 0 Day 1 Day 2 Day 3 Day 4 Days Day 6
Initial I Final Initial I Final Initial I Final Initial j Final Initial I Final Initial I Final Initial I Final I
Control
pH(SU): 7.20 7.34 7.22 7.22 7.15 7.22 7.19 7.28 7.28 7.34 7.43 7.43 7.35 7.40 I
DO(mg/L): 7.9 7.7 7.7 7.8 7.8 7.8 7.7 7.8 7.7 7.8 7.7 7.6 7.8 7.5
Temp.(C): 24.8 24.6 24.8 24.8 24.8 24.6 24.8 24.6 24.8 24.4 24.8 24.6 24.8 24.6
High Concentration
pH(SU): 6.67 7.25 7.28 7.21 6.49 7.23 7.05 6.93 6.69 7.01 7.28 7.28 7.37 7.18
DO(mg/L): 7.9 7.8 8.1 7.8 8.4 7.7 7.7 7.9 8.0 7.8 7.9 7.6 8.0 7.5
Temp.(°C): 25.0 24.3 25.0 24.7 25.0 24.6 25.0 24.3 25.0 24.6 25.2 24.6 24.6 24.5
Sample Information Sample 1 Sample 2 Sample 3 I Control Analyses Survival Growth
Collection start date: 09-11-22 09•13-22 09-15-22 s R',,i �`: ti Normal: Yes Yes
Grab: . . . Ham.Var. Yes Yes
Composite duration: 24-h 24-h 24-h .. - - NOEC: 100% 100%
Alkalinity(mg/L CaC031: 48 29 39 60-63 LOEC: >100% >100%
Hardness(mg/L CaCO3): 120 150 190 85-87 ChV: >100% >100%
Conductivity(µmhos/cm): 593 832 979 296-323 Method: Visual Insp. Dunnett's
Total residual chlorine(mg/L): <0.10 <0.10 <0.10 MAO
Sample Temp.at Receipt(°C): 1.0 0.3 0.9 = �.c.E Survival Growth
%Effluent Critical Calculated Critical Calculated
45% . . 2.410 -2.256
67.5% . 2.410 0.013
90% . 2.410 0.377
95% . . 2.410 -1.105
Overall Analysis: 100% . . 2.410 0.795
Result: PASS LOEC: >100% NOEC: 100% ChV: >100%
rmmato Dn.nn.e C......AT.0

• Page 1 of 5
•
Environmental Testing Solutions.Inc.
Chronic Whole Effluent Toxicity Test (EPA-821-R-02-013, Method 1000.0)
Species: Pimephales promelas
Client: Monroe WWTP County: Union
NPDES#: NC 0024333 Outfall #: 001
Project#: 11'LS-1--
Dilution preparation:
Dilution prep(%) 45 67.5 90 95 100 Sample was not aerated or treated unless otherwise
Effluent volume(mL) 450 675 900 950 1000 noted on this form. Sample was warmed to 25.0±1.0°C
Diluent volume(mL) 550 325 100 50 0 in a warm water bath and then diluted to the test
concentrations with moderately hard synthetic water
Total volume(mL) 1000 1000 1000 1000 1000 (MHSW).
Test organism information: Test information:
Organism source: In-house culture Randomizing template: 4)INK
Age: <24-hours old Incubator number .(Y.'1. - `V
and shelf location: cf.
Spawn date: pc{•OS-1.A— Artemia CHM number: CHM1149
O°\-CL-L"L okcA Drying information for weight determination:
Hatch dates and times: TO 0't'rS'"1,'1_ 0 S 00 Date/Time in oven: 0c1.1p•IA-- %OAS
'Initial oven temperature: (pp•L
Transfer vessel information: pH(S.U.)= "%,8.0 Date/Time out of oven: 09.1 1 1. ', 104S
Temperature(°C)= 1.4.0 "Final oven temperature: le •C
Average transfer volume(mL): <0.25 mL Total drying time: -ek-rko.)vt.S
`60°C Oven,Thermometer SN:14-98585'
Daily feeding and renewal information:
Day Date Morning feeding Afternoon feeding Test initiation,renewal, Sample MHSW
or termination number batch used
Time Analyst Time Analyst Time Analyst used
0 09-13-22 USOS A 1IL0 4 oio /` 120`10),61 0b04•1.1.11,
1 09-14-22 dsoo r( 1100 0A3i Xt ``�•� I.
2 09-15-22 cg oo k +- oo In kkso -ticci S .01 o4-o4-11.0
3 09-16-22 OS00 1100 K CPC3b 1 L
4 09-17-22 o ca oQ yk 1-US It_ WA O ').togi`4al oq•►~{•1t A
5 09-18-22 0totO it V100 0` 101ri 1,
6 09-19-22 u
0500 lk i I00 h oISS �t 0�•IS•71 A
7 09-20-22 1 044 ((
Chemical analyses:
Parameter Reporting Limit Method number Meter Serial number
pH 0.1 S.U. SM 4500-H+B-2011 Accumet AR20 93312452
Dissolved Oxygen(D.0.) 1.0 mg/L SM 4500-0 G-2016 YSI Model 52CE 18D104324
Conductivity 14.9 µmhos/cm SM 2510 B-2011 Accumet AR20 93312452
Alkalinity 5.0 mg CaCO3/L SM 2320 B-2011 Accumet AR20 93312452
Hardness 5.0 mg CaCO3/L 5M 2340 C-2011 Not applicable Not applicable
Chlorine,Total Residual 0.1 mg/L ORION 97-70-1977 Accumet AB250 92349123
Temperature 0.1°C SM 2550B-2010 ; Digital Thermometer %low410,6
Control information: Acceptance criteria Summary of test endpoints:
%Mortality: 67. 5 20% 7-day LC50(%) 7)OP?,
Average weight per initial larvae: 0,181 NOEC(%) 1 b0 7
Average weight per surviving larvae: 0.181 >_0.25mg/larvae LOEC(%) }1C07
ChV(%) > nib/.
IC25(%) > IOU 7.
SOP AT2O-Revision 6—Exhibit AT20.3

Page 2 of 5
Environmental Testing Solutions,Inc.
Species: Pimephales promelas
Client: Monroe WWTP Date: 09-13-22
Survival and Growth Data
Day CONTROL 45% 67.5%
A BCDE F G H I 1 K L
0
10 10 10 10 10 10 10 10 10 10 10 10
1
to to to to 10 ID 10 10 IC) 10 to io
2
10 t0 1 0 10 lb t b 10 tD f0 Ip 113 t(�
!p Lo I0 10 ID ID )-C;:.`10 '0 ID ,0 / 0
4
10 10 10 /0 10 10 °I 10 10 10 10 /0
5 10 10 10 ID /0 10 a to l0 to /0 10
6 ID 10 , 0 10 10 lb Cl ID 10 / 0 10 / 0
7 10 to /0 /0 10 q 10 10 (0 10 /0
'A=Pan weight( )
Tray color code:-HU►N\
Analyst: �C IU. (6)q?(9 l5.22 14 10Sb Ila.laO IU.0 13.31 IC1.I(0 I3.$3 128Z
Date: wit -22
B=Pan+Larvae weight(mg)
Analyst: 4C 21 17 22.14 Z219 P 23.52 Zu.S-)23AS 23.u(! tact 223 ID Z6.33
Date: Oq.23.22
C=Larvae weight(mg)=B—A
l.2q 1•44 g.16 g.o" e.i - 1,06 1.48 8•Zt g.Z.i 1.st
Analyst:
Weight per initial number of larvae(mg)
=C/Initial number of larvae
n n n tr tb % % o. n C, ntv
Analyst: 0- t• 0 0• v• 0' 0. 0. 0• O. O• ()-
Average weight per initial Percent
number of larvae(mg) reduction
0. 1g1 O . $-11 — 10.67, p.�lbl O. 1 7.
from
control(%)
*Weight measurements performed using Cahn 28 Automatic Electrobalance, SN 41520.
Comment codes: c=clear, d= dead, fg=fungus, k= killed, m =missing, sk=sick,sm =unusually small,
Ig=unusually large, d&r=decanted and returned, w=wounded.
Comments:
SOP AT2O-Revision 6—Exhibit AT20.3

£'OZ1V 1!q!gx3-9 uo!s!na8-0Z1V dOS
:sluawwo,
.papunoM=M 'pauanlai pue palueaap=i)gp 'a2Je!Ai ensnun=21
'news AI!ensnun= ws 51p!s=)!s'9u!ssiw= w 'pap!_ 'snOunj= 'peap= p 'aeapp=D :sapop luawwo0
'OZS1t NS'aJueiegoJlna13 u!lewolny gZ uge0 2u!sn pawiopad sluawainseaw 1(421am.
(%)
uoihnpai (2w)ame!;o Jagwnu
1ua»ad !e!1!u!Jad 1g2!am aZeiany
.o .O p .0 0 a O ,O v O p A :1sA!euy
e f-Y 41 �4/ N 0�
v p ti� ,C p �`�
a `1 v �o o
aenle!;o Jagwnu!e!1!ui 1 D=
(2w)aenue!;o Jagwnu!ewu!Jad 400m
:1sA!euy
2L L cs't- a5•t_ 95•L Z8'L 0o12 ctir8 811 1.1,'' 100'L Oc•t- L8'L
y-8=(2w)142!am eenaei=J
72. lo0 :a1ea
h0')2 Q16Q1 $O'OZ ZS 1 Z obZZ 2S�Z tJ QZ 019 I Z 0I 12 I±lZ OS IZ IAll :1sA,euy
(2w)141am aenJel+ued=e.
-fl-SO : lea
22 21 t2•2I 83Z1 O ( u•s! SS'n( hb71 g�' 1mG hi 00171 /i :15A!euy
Wnld, lo!oD
Aeu
(2w)l48!am ued=V.
01 6 o, or or or or y or 0r o/ 0/
L
0r b 01 at 01 01 Ot la 01 01 O/ 01 9
0r b 0/ 0/ 0/ O/ 01 la 0/ Cl , 01 01
S
01 b 0/ 0/ 0r 01 0, b 01 01 a) 01
b
01,,'"'M 0 O ) 01 01 01 r of 01 0 ) 01 _ t
0) 01 0) 01 al 01 S11 01 0/ 0/ 01 01
Z
Q 1 Qi Qi 01 O 1 a/ pi 01 01 01 01 0,
I
0T OI 0T 0T 0I OI OT 0I OI OI 0I OI
0
X AA A n 1 S a 0 d 0 N W
%00I %S6 %06 Aea
ntDG ylMoag pun/onlning
ZZ-ET-60 :ale() d1MM aoauo(N :;ua!l)
sn/awoad sa/nydawrd :salads
01•suounios 6upsa1 IMawu0,1nu3
S 40 E aged

•
Enoronmen W Telling Solutions.Inc.
Quality Control: Verification of Data Entry,Calculations,and Statistical Analyses
Chronic Whole Effluent Toxicity Test(EPA-821-R-02-013, Method 1000.0)
Species: Pimephales promelas
Facility: Monroe WWTP Entered by
Mlky Necnan
Itif
Test start date: September 13,2022 w-
Rrflwedby.
Project number: 17252 can Sumner
Sample numbers 220913.07,220915.07,220917.07
at
Concentration(%) Replicate Initial numberol Final number of larvae A=Pan weight(mg) 8=Pan a Larvae larvae weight(mg) Weight/Surviving Mean weight/ Coefficientol variation Weight/Initial number Mean survival Mean weight/ Coefficient of variation Percent reduction from
larvae weight(mg) =B.A nu
mber of larvae(mg) Surviving number of IM•••»wr 0,••"..wr�•,'.. of larvae Ixl Initial number of Irl control(x)
larvae(mg) on t1%) larvae(mg)
A 10 10 14.68 21.97 7.29 0.729 0.729
Control 8 10 10 14.76 22.48 7.72 0.772 0.772
0.78/ 10.1 0.744 100.0 0.787 10.1 Not applicable
C 10 10 15.22 22.66 7.44 0.744
D _ 10 10 14.22 23.26 9.04 0.904 _ 0.904
E 10 10 14.56 23.52 8.96 0.896 0,896
10 10 16.50 24.54 8.04 0.804 0.804
45%
F
G 10 9 14.40 23.16 8.78 0 976 0.895 7.9 97.5 0.871 5.3 -10.6
0.878
H 10 10 14.40 23.46 9.06 0.906 0.906
I 10 10 13.31 20.79 7.48 0.746 0.748
10 10 14.16 22.37 8.21 0.821 0.821
67.5% I
K 10 10 13.83 22.10 8.27 0.827 0.787 5 5 100.0 0.787 5.5 0.1
0.827
L 10 10 12.82 20.33 7.51 0.751 0.751
M 10 10 14.82 22.69 7.87 0.787 0.787
90% N 10 10 14.06 21.56 7.50 0.750 0.750
O 10 10 14.70 21.79 7.09 0.709 0.773 7.6 100.0 0.773 7.6 1.8
0.709
P 10 10 12.63 21.10 8.47 0.847 0.847
a 10 9 13.68 21.96 8.28 0.920 0.828
959, R 10 10 12.94 20.97 8.03 0.803 0.803
5 10 10 14.53 23.53 9.00 0.900 0.851 81 97.5 0.828 6.2 -5.2
0.900
T 10 10 15.08 22.90 7.82 0.782 0.782
U 10 10 13.76 21.32 7.56 0.756 0.756
100% V 10 10 12.58 20.08 7.50 0.750 0.750
W 10 9 13.37 20.90 7.53 0.637 0.779 51 97.5 0.758 1.3 3,7
0.753
X 10 10 13.32 21.04 7.72 0.772 0.772
Outfall 001: MSD= Minimum Significant Difference
Dunnett's MSD value: 0.0895 PMSD= Percent Minimum Significant Difference
PMSD: 11.4 PMSD is a measure of test precision.The PMSD is the minimum percent difference between the control and treatment that can be declared statistically significant in a whole effluent toxicity test.
lower PMSD bound determined by USEPA(10th percentile) =12%.
Upper PMSD bound determined by USEPA(90th percentile)=30%.
Lower and upper PMSD bounds were determined from the 10th and 90th percentile,respectively,of PMSD data from EPA's WET Interlaboratory Variability Study(USEPA,2001a;USEPA,2001b).
USEPA. 2001a,2001b.Final Report: Interlaboratory Variability Study of EPA Short-term Chronic and Acute Whole Effluent Toxicity Test Methods,Volumes 1 and 2-Appendix.EPA-821-8-01-004 and EPA-821-B-01-005.US Environmental Protection Agency,Cincinnati,OH.

Emmen by:
knee K&m.
Statistical Analyses Revnwcdbp
lm Sumner
Environmental Testing Solutions.Inc.
Larval Fish Growth and Survival Test-7 Day Growth
Start Date: 9/13/2022 Test ID: PpFRCR Sample ID: Monroe
End Date: 9/20/2022 Lab ID. ETS-Envir.Testing Sol. Sample Type: DMR-Discharge Monitoring Report
Sample Date: Protocol: FWCHR-EPA-821-R-02-013 Test Species: PP-Pimephales prometas
Comments:
Conc-% 1 2 3 4
D-Control 0.7290 0.7720 0.7440 0.9040
45 0.8960 0.8040 0.8780 0.9060
67.5 0.7480 0.8210 0.8270 0.7510
90 0.7870 0.7500 0.7090 0.8470
95 0.8280 0.8030 0.9000 0.7820
100 0.7560 0.7500 0.7530 0.7720
Transform:Untransformed 1-Tailed Isotonic
Conc-% Mean N-Mean Mean Min Max CV% N t-Stat Critical MSD Mean N-Mean
D-Control 0.7873 1.0000 0.7873 0.7290 0.9040 10.143 4 0.8291 1.0000
45 0.8710 1.1064 0.8710 0.8040 0.9060 5.298 4 -2.256 2.410 0.0895 0.8291 1.0000
67.5 0.7868 0.9994 0.7868 0.7480 0.8270 5.478 4 0.013 2.410 0.0895 0.7961 0.9601
90 0.7733 0.9822 0.7733 0.7090 0.8470 7.577 4 0.377 2.410 0.0895 0.7961 0.9601
95 0.8283 1.0521 0.8283 0.7820 0.9000 6.205 4 -1.105 2.410 0.0895 0.7961 0.9601
100 0.7578 0.9625 0.7578 0.7500 0.7720 1.295 4 0.795 2.410 0.0895 0.7578 0.9139
Auxiliary Tests Statistic Critical Skew Kurt
Shapiro-Wilk's Test indicates normal distribution(p>0.01) 0.95859 0.884 0.68749 0.32034
Bartlett's Test indicates equal variances(p=0.16) 7.9409 15.0863
Hypothesis Test(1-tail,0.06) NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df
Dunnett's Test 100 >100 1 0.08945 0.11363 0.00694 0.00276 0.06758 5,18
Treatments vs D-Control
Linear Interpolation(200 Resamples)
Point % SD 95%CL(Exp) Skew
IC05 96.098
IC10 >100
IC15 >100 1.0
IC20 >100 0.9
IC25 >100 0.8
IC40 >100
IC50 >100 0.7
0.6
0.5
C
a 0.4
ai 0.3
0.2
0.1
0.0•. •-
,07
-01
-0.2
0 50 100 150
Dose%
Dose-Response Plot
1
0.9
0.8 y/ -
0.7= - 1-tail.0.05 level
r of significance
t 0.6
O 0.5
a,
p 0.4
N-
0.3
0.2
0.1
0 ,
73 vy tit b 8
sr
U
O

Page 4 of 5
Environmental Testing Solutions.Inc.
Species: Pimephales promelas Date: 09-13-22
Client: Monroe WWTP
Daily Chemistry:
Temperatures performed at the time of test initiation,renewal or termination by the analyst identified in the Daily Renewal Information table
located on Page 1. Alkalinity,hardness and chlorine(total residual)performed by the analyst identified on the bench sheet specific for each
analysis and transcribed to this bench sheet.
Day
(Analyst identified for each day,performed pH,D.O.and conductivity measurements only.)
0 1 2
Analyst U L--c. ✓V -L-"C l'c tit/ t 4/
Concentration Parameter
pH(S.U.) ?.2v 3.3(-1 722 2Z `4 LS 2Z
Dissolved oxygen(mg/L) 14:9 ' '.1- -)-•1- ,4„..e .e `I,QJ
CONTROL, Conductivity(µmhos/cm) 38C1 323 31-7 l
MHSW Alkalinity(mg CaCO3/L) E..12\ s7 tt'it 19 l
Hardness(mg CaCO,/L) Er-18 S
Temperature(°C) 134. - b -L\{,S -t,A,k IA.k IA-to
pH(S.U.) (12•LIe -30 3-3`Z 7 2<-1 COP(2. C.o.Dissolved oxygen(mg/L) O 0 /'f 9 '--a- Qj,a 1.•)'
45% y5U USCG S32 1
Conductivity(µmhos/cm)
Temperature)°C) Z3-1•& -IA.6 L4.cj 't.`A •k -).`1(.'N Zy•s{
pH(S.U.) .?.so ?.22 co.'7 -P-0
67.5/o Dissolved oxygen(mg/L) '7',: - -M ,+,4 r .,g 0,D 1-
0
Conductivity(µmhos/cm) [�q?' C, 52 2. p p `l ?US--
Temperature
(°C) 1_`4• l 1,k.� 1 t. i -7-1A \ l,,�•'A.`A 1,.•"A
pH(S.U.) (9.�o .4-22. -n2$ T•19 Ly•(20 �.03
90/ Dissolved oxygen(mg/L) "} / r D '�} 1
0
Conductivity(µmhos/cm) S(0/4 5J 81 ?"4S
Temperature 1°C) 1S. 0 -4 .S•0 '1Ss--0 A-`l- .a
Lr-I -y
pH(S.U.) (9.?� �-.2 -2� �.2 _ (Q•SS "4-1c
Dissolved oxygen(mg/L) a0 .6 6,0 1. AD '1-_1-
95%
Conductivity(µmhos/cm) 59(0 00 L.( o02
Temperature(°C) 1.S-Q "NA."( '15.0 'L`k.1 L. -`1 -v-k-6
pH(S.U.) C9•( 7-2. 9.28 -Z( f0•(49 -23
Dissolved oxygen(mg/L) '
! .,44fLI q.a .,q 1-
Conductivity(µmhos/cm) Sri 3 Co 2 ? '32
100% Alkalinity(mg CaCO3/L) "-j Z9
Hardness(mg CaCO3/L) l20 15 0
Chlorine(mg/L) <0.10 40.10
Temperature(°C) 1.5•O Z4. .1 As.0 ' '1 ZS.0 -Lg.
Initial Final Initial Final Initial Final
SOP AT2O-Revision 6—Exhibit AT20.3

Page 5 of 5
Environmental Testing Solutions.Inc.
Species: Pimephales promelas
Client: Monroe WWTP Date: 09-13-22
Day
(Analyst identified for each day,performed pH,D.O.and conductivity measurements only.)
3 4 5 6
Analyst jr. . MC. }Mil, eL Gs, [G iG .t-
Concentration Parameter
pH(S.U.) ' 'la 1*AS 4•A2 1,34 ''i3 -4.1AS -15 7,uW
Dissolved oxygen(mg/L) r "IS 11, 13 --4.'" -1 tQ •I. k -(.5
CONTROL, Conductivity(pmhos/cm) gelz 310 oZgtG 313
MHSW Alkalinity(mg CaCOs/L) ti_z� t.0 tF-Li-
Hardness (0 3
(mg CaCO3/1) ` ,k,�, `' &1 k ``,, \h es
`' (c 1 C ..11
Temperature(°C) ' t.•1•R �.''1.17 1A• 'L .•'1 Z', 4� 1't-b 1_k•s %-t-t.
pH(S.U.) 91 2q 77•l1S 4.05 4,, g "-T3„f-(�, 3) ,�.Uy ••l.{? DA
Dissolved oxygen(mg/l) 1•, YTi .?..t, t Y/� •^Y. -1•S -1.ex V"�_,"�,
Conductivity(pmhos/cm)
45% Sy2 1 o4 1 (Q2S 313
Temperature(°C) Ztk•-1 1..t•4 1..k• \ 1A''S 1.-l• l 1'l•'l Ll4,. 1 0.t.
pH(S.U.) 7-21 1.01 t4. 1a 1,33 "3.3G qua .2G
Dissolved oxygen(mg/L) V 1.9 '3 fJ .1 -4•g —1 x S &•O
°i 67.5 6 cia '20
Conductivity(µm ,Sq �. t-}hos/cm)
Temperature(°C) 7"tot. A.q•A I-!1�.�•q "'y•'S -1,4-• 1 -•�1'9..2_ ^�--IA.1 -14,Lk
pH(S.U.) "Sti/t�V t1.�It0 tF•7� 1.0� �•OS7 ?-2 T'3- Z
Dissolved oxygen(mg/L) ,y 9- -q,C' 7.Q '7,t -4_s -1. fi 0 ,•�j
90% I t
Conductivity(µmhos/cm) 732. `3'15 , 9140 �3-�
Temperature("C) 1S.0 11•1.`l t_S.0 1.4.`l L .O 1'-k'S AA.'-7 l -IA.S
pH(S.U.) 'ot2 c�.q(J larga -7.03 3�S 92@ , 2''? .z3
Dissolved oxygen(mg/L) r)'11- -as/ 3.0 1,3 -1 ,i•p '•\.t.1
°r 95 `30L•f 94 l 9ci9 (D201
Conductivity(pmhos/cm)
Temperature(°C) IS.a 1—`k•S AS•I) 1".,{ 1S.t -1..,-k.5 1.,-t.t. lq•3
pH(S.U.) —4.Oc 10•4%3 (.0.1/9 TOI 4.a8 ?.n 33? (S
Dissolved oxygen(mg/L) l'. "•q QC.Q 4•Y 41 `1•b 8.0 --1.5
Conductivity(pmhos/cm) O'q -1,''1 I 0-10 t 0-40
100% Alkalinity(mg CaCOs/L)
Hardness(mg CaCOs/L) tot U
Chlorine(mg/L) G 0•'0 I
Temperature(°C) A.S•C - ,,II S ZS.O ..A-Lk•b "Is•Z. 2k•1, 1-i'b -11l• S Initial Final Initial Final Initial Final Initial Final
SOP AT2O-Revision 6—Exhibit AT20.3

r i 351 Depot Street
Asheville,NC 28801
Phone: [phone]
Fax: [phone]
Environmental Testing Solutions,Inc.
Whole Effluent Toxicity Chain-of-Custody Form
Facility: Monroe WWTP NPDES#: NC0024333 Pipe#: 001 County: Union
Purchase order:
Species: Pimephales promelas Effluent dilution: 45,67.5,90,95, 100%
Test type: Chronic Definitive Parameter code: THP6C
Sample information: (to be completed by sample collector) cc
Composite sample: Sample location: E c • c„
Start date: CI fa 12 Z Time: I tJO Es Volume collected for testing: I...
End date: 1/(Z/L2 Time: iliete Number of containers filled for testing: 3
Number of samples per hour: {'\O\ ) Method of transport to laboratory: Eect-6
Chilled during collection? Comments:
If chilled,specify temperature: 11 L
Triple rinse sample container with sample before filling. Completely fill the sample container with no air space.
Pack the sample container completely in ice. The sample must be<6.0°C upon receipt at the laboratory.
e custody: (to be completed by sample collector and facility personnel)
Sample collected by:
lug ioOL7
K,(' (ci(AO avuLLW clIELIzz
Pent Signature Date and time
Relinquished by: Received by:
ICA (Of aL) ( �{l�.cozy/ c1�►21 Zz prat„.p DC/ I2.7z
Punt Signature Date and time I Signature Date and time
Relinquished by: Received by:
Print Signature Date and time Print Signature Doe and time
Sample receipt information: (to be completed by ETS personnel)
Relinquished to ETS by: Received at ETS by:
�1�- /'cam S L �� 13 az
Print Signature Date and time Print Signature Date and time
Custody seals intact?: ' M. - Sample temperature upon receipt at ETS(°C):
Yes No Not used j.0 t�
Samples received in good condition?:
Yes No Total residual chlorine upon receipt at ETS:
�j Q(� (DPD Presence/Absense Indicator,MDL=0.10 mg/L) I'r"`mt At'"'
Tracking number: �(7 ( 'I:�'Si)V7°L Project number:il.�c' q A �v!'wiCtiSample number: 3a
..,,rdments:

1 t t • 351 Depot Street
_ 1 Asheville,NC 28801
1 ' Phone: [phone]
.__.. Fax: [phone]
, Environmental Testing Solutions,Inc.
`••
.
Whole Effluent Toxicity Chain-of-Custody Form-
Facility: Monroe WWTP NPDES#: NC0024333 Pipe#: 001 County: Uniooi
Purchase order:
Species: Pintep/Tales pronzelas Effluent dilution: 45,67.5,90,95, 100°/a
Test type: Chronic Definitive Parameter code: THP6C
Sample information: (to be completed by sample collector)Composite sample: Sample location:C Mn V` A--
Start date: Cl /13/ZZ Time: l00° Volume collected for testing: 9L
End date: 01/ , 1 / 'ZZ Time: t 00i Number of containers filled for testing: 5
Number of samples per hour: v VU Method of transport to laboratory: C c J-EX
Chilled during collection? J ) Comments:
If chilled,specify temperature: 3.,2°C..
Triple rinse sample container with sample before filling. Completely fill the sample container with no air space.
Pack the sample container completely in ice. The sample must be<6.(1°C upon receipt at the laboratory.
y
vie custody: (to be completed by sample collector and facility personnel) -
Sample collected by:
Ci
14vvrvin c orrte4 . �y t I�l(�
to ly
Niul Si,00lon: 'Jai and lime
Relinquished by: Received by:
ICA 4 61 d N•2t—
Go^'ttr Roil I PCL .—'
:•iguana. Dale and Om '..
Relinquished by: Received by:
1 4,..o51 )-
Punt SIgnitturc Datu erJ tune Sipn.;un. Da,:o.J inia
Sample receipt information: (to be completed by ETS personnel)
Relinquished to ETS by: Received at ETS by:
I'ini 5Iptat"n •Signawn: 1).,anJ lima
Custody seals intact?: l •-/f" Q Sample temperature upon receipt at ETS(°C): .G
V<, Nn t,ol ra J � 3 I
Samples received in good condition?: FM-1
vc. NJ Total residual chlorine upon receipt at ETS: I
vr/yt! (DPD Prescnce/Absense Iudicmor,MDL-0.10 mg/L) r^"°` ^t"`"'
Tracking number:
tiogQ3S/56 6 Project numbcr J` ' Sample number: aq04(St64 j
Comments:

e TM z
351 Depot Street
Asheville,NC 28801
Phone: [phone]
Fax: [phone]
_ Environmental Testing Solutions,Inc.
Whole Effluent Toxicity Chain-of-Custody Form
Facility: Monroe WWTP NPDES#: NC0024333 Pipe#: 001 County: Union
Purchase order:
Species: Pimephales promelas Effluent dilution: 45,67.5,90,95, 100%
Test type: Chronic Definitive Parameter code: THP6C
Sample information: (to be completed by sample collector) �
Composite same: Sample location: �' Vv�it/ t,
Start date: I I s l 2 Z Time: PO(0 Volume collected for testing: 13 L
End date: CI I )\p I2z Time: 100. Number of containers filled for testing: ti-
Number of samples per hour: -P'lO\A-) Method of transport to laboratory: r-t-4.k r 6 X
Chilled during collection? Comments:
If chilled,specify temperature: 7 4,i
Triple rinse sample container with sample before filling. Completely fill the sample container with no air space.
Pack the sample container completely in ice. The sample must be<6.0°C upon receipt at the laboratory.
custody: (to be completed by sample collector and facility personnel)
Sample collected by:
I 0. cl,4+ el 1101 22-
c a r,1� t-u-4.-4--,- 10)1
Print Signature Date and time
Relinquished by: Received by:
t vttein w..-vi IIt.v a ��'��1.->Q el•I�•�
am ca(l c.Arixivk WI/
Print SIwuuc Date and time Print Sipauure Date and time
Relinquished by: Received by:
F.'— '. 77r.- —'1 [1 .7— ....-'."1
14im Sigrolure Date and lime Pont Signaw. Date and tyre
Sample receipt information: (to be completed by ETS personnel)
Relinquished to ETS by: Received at ETS by:
re 09.►1-u 01.'1.22_
,ort— �L1— vk- c az2
Print Signature Date and time Pnm Signature Date and time
Custody seals intact?: 1110 - - Sample temperature upon receipt at ETS(°C): n /
Yn. No I Not used D /� '
Samples received in good condition?: Ilia —
Yea No Total residual chlorine upon receipt at ETS: _ �'
/j,,p j�`�a l (DPD Presence/Absense Indicator,MDL=0.10 mg/L) Present Absent
number: ( 3s�J `� ,(
Project number:112SL Sample number:d42°C1 7.01'
—.,...ments:

Pimephales promelas
Chronic Reference Toxicant Control Chart
Environmental Testing Solutions,Inc. Source: In-house Culture
0.9 1 1 I 1 1 1 1 1 1 1 1 1 1 1 1 I 1 1 1 1
- Control Limits (± 2 Standard Deviations) -
0.8 - -
- • -
•
• •
0.7 - • • -
• • •• • •
• ••
• • • • • • -
V •
•
0.6 - -
aA
1 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1 1 1 1 1
UN 1.2 ! lilt I 1 1 1 1 r 1 1 1 1 1 1 1 1 I 1
_
al Warning Limits
ri 1.0 -- -
0.8 — _.._.._ _..� ..�.. _
• •
• • • • • _
• • • • • • • • • .. • •
•
0.6 - .. ., .. _..._ ..._.._____ .-„�., ®..__..., -
......-....... .
0.4 - -
1 I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 E
03.01-�a•.06 oAA. 6.0%-O1,13 oa.01 9A11 10.0$110ti.12 01-0105'.of 0%.0 SO-oa O5 05 03-06 01 01 1._01 1.- O.L 0913.L1
Test date
• 7-day ICzs 25%inhibition concentration. An estimation of the potassium chloride concentration
which would cause a 25%reduction in Pimephales growth (calculated using ToxCalc).
Central Tendency(mean logarithmic IC25 converted to anti-logarithmic values)
Control Limits (mean logarithmic IC25±2 standard deviations converted to anti-logarithmic values) 1
Laboratory Warning Limits(mean logarithmic IC25±2 coefficent of variations converted to anti-logarithmic values)
• USEPA Warning Limits (mean logarithmic IC25±SA.75 converted to anti-logarithmic values,
SA 75= 75th percentile of CVs reported nationally by USEPA)
erea me
ne.Kwea ny
m Sumner
at

Environmental Testing Solutions, Inc. Invoice
P. O. Box 7565
Asheville, NC 28802 Date Invoice#
Phone # [phone]
3/18/2024 100196
Bill To
Monroe,City of
Mr. Kyle Ketchum
PO Box 69
Monroe,NC 28110
P.O. No. Terms Project
140071 Net 30 Aquatic Toxicity
Quar tit) Description Rate Amount
I Pimephales Full Range Chronic 925.00 925.00
Thank you for your business.
Total $925.00

PO Box 7565
Asheville, NC 28802
Phone: [phone]
EnwoornentaI Testing Solution,Inc Fax: [phone]
March 15, 2024
Mr. Kyle Ketchum
City of Monroe
775 Treeway Drive
Monroe, NC 28110
ETS Project Number: 19446
Test Start Date: March 05, 2024
Facility Tested: Monroe WWTP
Enclosed are toxicity test results for samples received by Environmental Testing Solutions Inc.
Parame:er
Code Test Procedure, Method Number Result (ChV)
THP6C Fathead minnow, Pimephales promelas, Larval Survival and Growth Chronic )100%
EPA-821-R-02-013, Method 1000.0
All toxicity testing results required as part of your permit must be entered on the Effluent Discharge
Monitoring Form (MR-1) for the month in which it was performed, using the parameter code
THP6C. Additionally, the DMR Reporting Form AT-5 must be signed and e-mailed or mailed to the
following address:
ATForms.ATB(a�deq.nc.gov
North Carolina Division of Water Resources
Water Sciences Section/Aquatic Toxicology Branch
1621 Mail Service Center
Raleigh, NC 27699-1621
Please call if you have any questions concerning these results.
Sincerely,
Jim Sumner
Laboratory Supervisor
North Carolina Certificate Numbers: Biological Analyses: 037, Drinking Water: 37786,Wastewater: 600
South Carolina Certificate Number: Clean Water Act: 99053-001

PO Box 7565
Asheville,NC 28802
Phone. [phone]
Fax: [phone]
Fnwreranantal Twin9 Saluaon.int.
Effluent Toxicity Report Form-Chronic Fathead Minnow Multi-Concentration Test Date: March 15,2024
Facility: City of Monroe NPDES#: NC 0024333 Pipe#: 001 County: Union
Monroe WWTP
Laboratory Performing Test: Environmental Testing Solutions,Inc.,Certificate#037 Comments
Signature of Operator in Responsible Charge(ORC):
ORC Phone/E-mail: Project 4. 19446
Signature of Laboratory Supervisor- / A,4f /, Sample it 240305.06,240307 08,240309.0
1\
e-Mail to: [e-mail] Test Organisms: Pimephales promelas
Or Mail Original to:North Carolina Division of Water Resources supplier
Water Sciences Section/Aquatic Toxicology Branch in-house Culture
1621 Mail Service Center Begin hatch: 03-04-24 1400
Raleigh,NC 27699-1621 End hatch: 03-05-24 0500
Test Start Date: March 05,2024
Replicate number
1 2 3 4
Control Surviving number of larvae 10 10 10 10 Survival(%( 100.0
Organisms Original number of larvae 10 10 10 10 Average wt(mg) 0.974
Weight/original(mg/larvae) 0.770 0.998 1.042 1.086 Average wt/ 0.974
surviving(mg)
%Effluent Surviving number of larvae 10 10 10 10
45% Original number of larvae 10 10 10 10 Survival(%) 100.0
Weight/original(mg/larvae) 1.048 0.873 0.890 0.836 Average wt(mg) 0.912
%Effluent Surviving number of larvae 10 10 10 10
67.S% Original number of larvae 10 10 10 10 Survival(%) 100.0
Weight/original(mg/larvae) 0.930 1.030 1.002 0.988 Average wt(mg) 0.988
%Effluent Surviving number of larvae 10 10 10 10
90% Original number of larvae 10 10 10 10 Survival(%) 100.0
Weight/original(mg/larvae) 0.826 0.879 0.972 0.910 Average wt(mg) 0.897
%Effluent Surviving number of larvae 10 10 10 10
95%J Original number of larvae 10 10 10 10 Survival(%) 100.0
Weight/original(mg/larvae) 1.026 1.065 1.120 0.951 Average wt(mg) 1.041
%Effluent Surviving number of larvae 10 10 10 9
100%J Original number of larvae 10 10 10 10 Survival(%) 97.5
Weight/original(mg/larvae) 0.840 0.852 1.012 0.682 Average wt(mg) 0.847
Water Quality Data
Day 0 Day 1 Day 2 Day 3 Day 4 Day 5 Day 6
Initial [ Final Initial I Final Initial I Final Initial I Final Initial I Final Initial I Final , Initial I Final
Control
pH(SU). 8.13 7.74 7.76 7.65 7.84 7.56 7.84 7.64 7 55 7.60 7.76 7.66 7,87 7.17
DO(mg/L.): 7.6 7.9 7.8 7.8 7.8 7.5 7.8 7.4 7.7 7 4 7.7 7.9 7.9 6 2
Temp.CC). 24.8 24.6 24.8 25.0 24.7 24.6 24.8 24.8 24.8 24.5 24.7 24.7 24-7 24.3
High Concentration
pH(SU): 6.71 7.51 7.37 7.26 6.70 6.89 6.95 7.03 6.72 6.97 7.22 7.08 7.32 6.74
DO(mg/L): 8.0 7.8 8.0 7.9 8.0 7.4 8.0 7.3 7.8 6.9 7 8 7.9 8.1 5.8
Temp.('C). 25.0 24.6 25.0 24.5 249 24 6 25.0 24.8 25.0 24.6 25.0 24.7 24.8 24.5
Sample Information Sample 1 Sample 2 Sample 3 Control Analyses Survival Growth
Collection start date- 03-03-24 03-05-24 03-07-24 _ Normal: Yes Yes
Grab: Hom.Var. Yes Yes
Composite duration: 24.25-h 24-h 24-h NOEC. 100% 100%
Alkalinity(mg/L CaCO3): 21 13 15 60,63,61 LOEC: >100% >100%
Hardness(mg/L CaCO3). 67 97 85 87,89,89 ChV- >100% >100%
Conductivity(µmhos/cm): 343 573 487 293-319 Method' Visual Insp. Dunnett's
Total residual chlorine(mg/L). <0.10 <0.10 <0.10 -
Sample Temp.at Receipt('C). 0.8 1.3 0.3 Survival Growth
%Effluent Critical Calculated Critical Calculated
45% 2.410 0.901
67.5% 2.410 -0.195
90% 2.410 1.118
95% 2.410 -0.963
Overall Analysis: 100% 2.410 1.846
Result: PASS LOEC: >100% NOEC: 100% ChV: >100%
DWR Report Form AT-5

r
Page 1 of 5
Environmental Testing Solutions.Inc.
Chronic Whole Effluent Toxicity Test (EPA-821-R-02-013, Method 1000.0)
Species: Pimephales promelas
Client: Monroe WWTP County: Union
NPDES#: NC 0024333 Outfall #: 001
Project#: 1'tAaly
Dilution preparation:
Dilution prep(%) 45 67.5 90 9 5 100 Sample was not aerated or treated unless otherwise
Effluent volume(mL) 450 675 900 950 1000 noted on this form. Sample was warmed to 25.0±1.0°C
Diluent volume(mL) 550 325 100 50 0 in a warm water bath and then diluted to the test
concentrations with moderately hard synthetic water
Total volume(mL) 1000 1000 1000 1000 1000 (MHSW).
Test organism information: Test information:
Organism source: In-house culture Randomizing template: dilpotz(e-
Incubator number
Age: <24-hours old and shelf location: \ O
Spawn date: 01-11 •t`4 Artemia CHM number: CHM1294
03-04-'A 14 d0 Drying information for weight determination:
Hatch dates and times: "CD �4S L'l 05tld Date/Time in oven: 03s It-'s-4 I No
'Initial oven temperature: lot •(-
Transfer vessel information:
pH(S.U.)= t.1( Date/Time out of oven: 01-».t� IMet
Temperature(°C)= L`{.S "Final oven temperature: V 0 •C
Average transfer volume(ml): <0.25 ml Total drying time: 1A-011.1i1S.
"60°C Oven,Thermometer SN:14-985B5
Doily feeding and renewal information:
Day Date Morning feeding Afternoon feeding Test initiation,renewal, Sample MHSW
or termination number batch used
Time Analyst Time Analyst Time Analyst used
0 03-05-24
OSeS I`ItX) IA 1110 lk 1rto3o15.Ob of If-LA8
1 03-06-24 OSoo (/, 111() K �1..O �'( .L
2 03-07-24 G t�
usao t3�o +ZS9 Z`1cr561_ oQ 01-2d At
3 03-08-24 OSoo ik. !IV,' �1 o' - jr‘
4 03-09-24 Q�
obo4 Iwo k to,-1.. ,SvSrR_n 0-01-1,4,A
5 03-10-24 uboo 1100 11
a'-0 h
6 03-11-24
Ob Uoo {k \10o It o1•LO ,,��1
7 03-12-24 00 a at,t5 i1
Chemical analyses: }�
Parameter Reporting Limit Method number Meter Serial number
pH 0.1 S.U. SM 4500-H+B-2011 Accumet AR20 93312452
Dissolved Oxygen(D.O.) 1.0 mg/L SM 4500-0 G-2016 YSI Model 52CE 18D104324
Conductivity 14.9 µmhos/cm SM 2510 B-2011 Accumet AR20 93312452
Alkalinity 5.0 mg CaCO3/L SM 2320 B-2011 Accumet AR20 93312452
Hardness 5.0 mg CaCO3/L SM 2340 C-2011 y Not applicable Not applicable
Chlorine,Total Residual 0.1 mg/L ORION 97-70-1977 Accumet AB250 92349123
Temperature 0.1°C j SM 2550B-2010 Digital Thermometer S301144_c
Control information: Acceptance criteria Summary of test endpoints:
%Mortality: n7. <20% 7-day LC50(%) 7 I oo--/
Average weight per initial larvae: 197q14 NOEC(%) \0 0 y
Average weight per surviving larvae: 0A14 >_0.25mg/larvae LOEC(%) 100-1
ChV(%) 100-1.
Ica(%) , (0o 7.
SOP AT2O-Revision 6—Exhibit AT20.3

Page 2 of 5
Environmental Testing Solutions.Inc
Species: Pimephales promelas
Client: Monroe WWTP Date: 03-05-24
Survival and Growth Data
Day CONTROL 45% 67.5%
A B C D E F G H I J K L
0 10 10 10 10 10 10 10 10 10 10 10 10
1 (0 (p 10 10 l0 i0 10 I0 (0 10 (0 ( b
2 (0 l0 10 10 ( D 10 10 IO ( 0 10 10 ( 0
3 is 11) 10 10 l0 10 10 ID 10 10 10 CO
a 10 10
10
10 10
tlo (0 ID 10 10 10 10
5 ( 0 10 10 10 10 10 ( 0 10 10 lb )0 1D
6
Ib 10 10 lb (0 10 (0 ID lb (0 10 10
•7
rp to to /0 10 ► 0 (0 ► U / 0 10 / 0 (0
*A=Pan weight(mg)
Tray color code: (...-0101
Analyst: l3L I2..71-12.05 14. 18' 13.g514•S`t II. 93 13•$.2- 14.17- 12.57- 12.90 (5.00(2.r.,?-
Date: O2•1 /.2.'i
*B=Pan+Larvae wei fit(mg)
Analyst: it,`I1 1.1.43S 1.4.60 t ts5L -10-6C t1.12 1.1.S3 t1.11 Z3.2A ZS.61.1-SS
Date: 0'b•►V L`1
11
C=Larvae weight(mg)=B—A
7 1J 4g� 104� 1�.�6 Iv.0 y1 � ,3 9D.9J S36 Q.3� t��° i�D2 q.44,
Analyst: /
. i
Weight per initial number of larvae(mg)
=C/Initial number of larvae I '3 9,6 $9D o.97,0 I �2 O
D.17J p 9'� l 0tJZ l.od� 0,$�3 0 ��� 1.03o 40,
Analyst: 2/0
i
Average weight per initial Percent
number of larvae(mg) reduction 0 9 L1 ' L�
from 0.g12 6 •�I`
control(%)
*Weight measurements performed using Cahn 28 Automatic Electrobalance, SN 41520.
Comment codes: c=clear, d =dead, fg=fungus, k=killed, m =missing,sk=sick, sm =unusually small,
Ig=unusually large, d&r=decanted and returned,w=wounded.
Comments:
SOP AT2O-Revision 6—Exhibit AT20.3

Page 3 of 5
Environmental Testing Solutions,Inc.
Species: Pimephales promelas
Client: Monroe WWTP Date: 03-05-24
Survival and Growth Data
Day 90% 95% 100%
M N 0 P Q R 5 T U V W X
0
10 10 10 10 10 10 10 10 10 10 10 10
1 10 (0 Ip to 10 tD 10 10 ► 0 (0 Ip l0
2 /0 10 t0 It) 10 10 10 ►0 10 ( 0 10 10
3 I0 1p ID 10 10 10 10 ID 10 10 to /0
4 lb ( 0 ID IQ t0 1p 10 10 ID 10 10 ID
5 t0 to ID ID so 10 ID
( 0 /0 ► 0 10 /0
6 (0 ID 10 ( 0 ( 0 ( 0 ( 0 10 10 ( 0 10 1p
so 10 l0 (0 10 ► 0 l0 (0 to 10 ,K
aA=Pan weight(mg)
Tray color code: (...121 d
Analyst: - g‘" II.% 13.29 13.93 II46 14.23 15.23 13./2 15. 05 15.1$ 13. 15 14.08 13•SS
Date: _61 2 •1 1.1Li"
'B=Pan+Larvae weight(mg)
Analyst: - 2- 22.0& T ieS 2015 1-1.41 LS.0 LS.It. 1%15b t3.S? 2V.61 tq.2i0 -my()
Date: _ •14•14
C=Larvae weight(mg)=B-A
9, 2G q�'19 ��� a Io 'a-26 10�S I(.Z9 (1, 1 B.S� 1�12 6
5(40
Analyst:
Weight per initial number of larvae(mg)
=C/Initial number of larvae �.4,2, .S11 0.�7Z o.glo �2� 1.D65 IZ� 0.951 co.352 ) 0/2 068z
I o,
Analyst:
Average weight per initial Percent
number of larvae(mg) reduction [� J
from control �. ! /. I '�� I - 6 S/. .air c- . 1 -
(%)
*Weight measurements performed using Cahn 28 Automatic Electrobalance, SN 41520.
Comment codes: c=clear, d =dead, fg=fungus, k= killed, m = missing, sk=sick,sm = unusually small,
Ig=unusually large, d&r=decanted and returned,w=wounded.
Comments:
SOP AT20-Revision 6-Exhibit AT20.3

Envuonnwnial letting Saluuons,Inc.
Quality Control: Verification of Data Entry,Calculations, and Statistical Analyses
Chronic Whole Effluent Toxicity Test(EPA-821-R-02-013, Method 1000.0)
Species: Pimephales promelas
Facility: Monroe WTP Entered by.
W
Kclky Kcenan
Test start date: March 05,2024 Reviewed by.
Project number: 19446
lint Sumner
Sample numbers 240305.06,240307.08,240309.07
Concentration(X) Replicate Initial number of Final number of larvae A Pan weight ling) B=Pan♦larvae Larvae wei1M(mg) Weight/Surviving Mean weight/ Coefficient of variation Weight/Initial number Mean survival Mean weight/Initial Coefficient of variatwn Percent reduction Irom
brvae weight(mg) =B-A number of larvae(mg) Surviving number of Iw..a*am Pe•e,.,w.a evwr, of larvae(mg) I%1 number of larvae I%I control I%I
larvae Intl =.u....il%1 Imgl
A 10 10 12.77 20.47 7 70 0.770 0.770
B 10 10 12.05 22.03 9.98 0.998 0.998
Control 0.974 14.4 100.0 0.974 14.4 Not applicable
C 10 10 14.18 24.60 10.42 1.042 1.042
D 10 10 _ 13.85 24.71 _ 10.86 1.086 1.086
E 10 10 14.84 25.32 10.48 1.048 1.048
F 10 10 11.93 20.66 8.73 0.873 0.873
45% G 10 10 13.82 22.72 8.90 0.890 0 912 30.3 0.890 300.0 0.932 109 6.4
H 10 10 _ 14.17 22.53 8.36 0.836 0.836
I 10 10 12.57 21.87 9.30 0.930 0.930 -
1 10 10 12.90 23.20 10.30 1.030 1.030
67.SY. X 10 10 15.00 25.02 10.02 1.002 0.988 4.3 1.002 100.0 0.988 43 -1.4
L 10 10 12.67 22.55 9.88 _ 0.988 0.988
M 10 10 11.56 _ 19.82 8.26 0.826 0.826
N 10 10 13.29 22.08 8.79 0.879 0.879
90% O 30 10 13.93 23.65 9,72 0.972 0.897 6.8 0.972
300.0 0.897 6.8 7.9
P 10 10 11.85 20.95 9.10 0.910 0.910
Q 10 10 14.23 24.49 10.26 1.026 1.026
R 10 10 15.23 25.88 10.65 1.065 1.065
95% 1.041 6.8 100.0 1.041 6.8 -6.8
S 10 10 13.92 25.12 11.20 1.120 1.120
T 10 _ 10 15.05 24.56 9.51 0.951 -it 10
U 10 10 15.18 23.58 8.40 0.840 0.840
✓ 10 10 13.15 21.67 8.52 0.852 0.852
100% W 10 10 _ 14.08 24.20 10.12 1.012 0.865 12.3 1.012 97S 0.847 15.9 13.1
X 10 9 13.58 20.40 6.82 0.758 0.682
-
Outfa11001: MOD= Minimum Significant Difference
Dunnett's MSD value: 0.1665 PMSD= Percent Minimum Significant Difference
PMSD: 17.1 PMSD is a measure of test precision. The PMSD is the minimum percent difference between the control and treatment that can be declared statistically significant in a whole effluent toxicity test.
Lower PMSD bound determined by USEPA(10th percentile) =12%.
Upper PMSD bound determined by USEPA(90th percentile)=30%.
Lower and upper PMSD bounds were determined from the 10th and 90th percentile,respectively,of PMSD data from EPA's WET Interlaboratory Variability Study(USEPA,2001a:USEPA,2001b).
USEPA. 2001a,2001b.Final Report. Interlaboratory Variability Study of EPA Short-term Chronic and Acute Whole Effluent Toxicity Test Methods,Volumes 1 and 2-Appendix.EPA-821-B-01-004 and EPA-821-8-01-O0S.US Environmental Protection Agency,Cincinnati,OH

F nii'nl Dy'
Kelley Keenan
Statistical Analyses Restiw-0
Nm Surmmn
Environmental Testing Solutions.Inc.
Larval Fish Growth and Survival Test-7 Day Growth
Start Date 3/5/2024 Test ID PpFRCR Sample ID. Monroe
End Date: 3/12/2024 Lab ID ETS-Envir Testing Sol. Sample Type DMR-Discharge Monitoring Report
Sample Date Protocol: FWCHR-EPA-821-R-02-013 Test Species PP-Pimephales promelas
Comments:
Conc-% 1 2 3 4
D-Control 0 7700 0.9980 1.0420 1.0860
45 1.0480 0.8730 0.8900 0.8360
67.5 0.9300 1.0300 1.0020 0.9880
90 0.8260 0 8790 0.9720 0.9100
95 1.0260 1 0650 1.1200 0.9510
100 0.8400 0.8520 1 0120 0 6820
Transform:Untransformed 1-Tailed Isotonic
Conc-% Mean N-Mean Mean Min Max CV% N t-Stat Critical MSD Mean N-Mean
D-Control 0.9740 1.0000 0.9740 0.7700 1 0860 14.442 4 0.9740 1.0000
45 0.9118 0 9361 0.9118 0.8360 1 0480 10.265 4 0.901 2.410 0.1665 0.9591 0.9847
67.5 0.9875 1.0139 0.9875 0.9300 1.0300 4.266 4 -0.195 2-410 0.1665 0.9591 0.9847
90 0.8968 0.9207 0.8968 0.8260 0.9720 6.801 4 1.118 2.410 0.1665 0.9591 0.9847
95 1 0405 1.0683 1.0405 0.9510 1 1200 6.828 4 -0.963 2.410 0.1665 0.9591 0.9847
100 0.8465 0.8691 0.8465 0.6820 1.0120 15 926 4 1.846 2 410 0.1665 0 8465 0.8691
Auxiliary Tests Statistic Critical Skew Kurt
Shapiro-Wilk's Test indicates normal distribution(p>0.01) 0 97607 0.884 -0 3596 0.56271
Bartlett's Test indicates equal variances(p=0.39) 5.24302 15 0863
Hypothesis Test(1-tail,0.05) NOEC LOEC ChV TU MSDu MSDp MSB MSE F-Prob df
Dunnett's Test 100 >100 1 0 16648 0 17092 0 0199 0 00954 0 11463 5, 18
Treatments vs D-Control
Linear Interpolation(200 Resamples)
Point % SD 95%CL(Exp) Skew
IC05 96 502
IC10 98 664
IC15 >100 1 0
IC20 >100 0.9
IC25 >100
IC40 >100 0.8
IC50 >100 07
06
C
05
n 04
m 03
tY
02
01
0.0• - - ♦
-0.1 -
-0.2 . . . . . . , .
0 50 100 150
Dose
Dose-Response Plot
1.2
r 0 8 - 1-tail,0.05 level
of significance
o -
0 0 6
04
02
0 ,
° v 3 a o
V
a

Page 4 of 5
Environmental Testing Solutions,Inc.
Species: Pimephales promelas Date: 03-05-24
Client: Monroe WWTP
Daily Chemistry:
Temperatures performed at the time of test initiation,renewal or termination by the analyst identified in the Daily Renewal Information table
located on Page 1. Alkalinity,hardness and chlorine(total residual)performed by the analyst identified on the bench sheet specific for each
analysis and transcribed to this bench sheet.
Day
(Analyst identified for each day,performed pH,D.O.and conductivity measurements only.)
0 1 2
Analyst 0a At- 01 6L i St_
Concentration Parameter ,
pH(S.U.) 8.►3 - �.'7.4 7-7Z. 3--G.5 4-I .Se.'
Dissolved oxygen(mg/L) '1.1, •1.tk 1,e 18 3 ' ,5
CONTROL, Conductivity(µmhos/cm) -A3 Oswalt.74' 3/ff 31-;
MHSW Alkalinity(mg CaCOiL) \DC) t,5
Hardness(mg CaCO3/L) R --It 01n W N S R
Temperature(°C) A-1.k AAA, -N.A. h A.S_ 0 •v-t-1 1``l•le
pH(S.U.) -3-.I LP -Co "?- -4.(oQ -.s " t3S 4.tf 3
° Dissolved oxygen(mg/L) -1-t ' 1.g •1.-` _8 /1 9 , 4,5
45/o Conductivity(µmhos/cm) 32(2 34-0 Oil
Temperature 1°C) '1,',ilk1,'- S -1.4 A Z-4.b '1}t.1 Za.`{
pH(S.U.) 4-.02 -4.G I 7•96, -4-i-el?" 42'L 7.2�
Dissolved oxygen(mg/L) 1•La 1.1 -1.4‘ 116 14,c
67.5°/n -333 3S0 LOGI
Conductivity(µmhos/cm)
Temperature(°C) a IA-1 '� -S
I
pH(S.U.) Ca.c-I -4-S 5 4-45 1.3�4- ''.( 7..I l4-
Dissolved oxygen(mg/L) , '1 1-1 8•t) yj,Ql -4-0 ,4
90%
Conductivity(µmhos/cm) 3 tt-{' 36,2 611- "-
Temperature 1°C) $.0 1`{•1 ZS,o Z'{•1 "`A_ 1. "• 1
J
pH(S.U) (t1� r 'Scm-. tit '4.90 I-. 'i.3�I j� OD •° I
Dissolved oxygen mgJtJ 1.1 1.g •o /7 ,s q 1,
95%
Conductivity(µmhos/cm) )lt q 3C t ci
D
Temperature 1°C) is-O 1.`1•1, -1.S.D Z4.1 1a' 1 1 1.�-1 1
pH(S.U.) (.1-i ?' .5I 7_37 7-2-4, (0.10 Ice.71
Dissolved oxygen(mg/L) <3,0 1. Q 6,p . 1 }�� 1-,1
'Cot5).J
Conductivity(µmhos/cm) )4.3 3C % .
100% Alkalinity(mg CaCOiL) '2 t t 1
Hardness(mg CaCOiL) (01 91
Chlorine(mg/L) C 0,/Q `` G 0.10 `
Temperature(°C) )S•0 Z- •b �.0 1. .S 1d-i 14-L
Initial Final Initial Final Initial Final
SOP AT2O-Revision 6-Exhibit AT20.3

Page 5 of 5
EnvlronmentalTesting Solutions,Inc.
promelas
Species: Pimephales romelas
P p
Client: Monroe WWTP Date: 03-05-24
Day
(Analyst identified for each day,performed pH,D.O.and conductivity measurements only.)
3 4 5 6
Analyst ,L •
aw. 1 L or.. aL 8� ✓L.
Concentration Parameter
pH(S.U.) 9.gam. ._... T 1.tt'+'" 1-55 __. 1.ko Itoo 3_��. -.fs'�n ,.. t ..
Dissolved oxygen(mg/L) 1 .�- 1.-1 -4.4 1_,} 1.i -1.l (/,L
CONTROL, Conductivity(µmhos/cm) 31 q 30 y. 3c6 3,160
MHSW Alkalinity(mg CaCOt/L) ......._ Lot „-;
Hardness(mg CaCOt/L) - I ' 4 :---------.Netipii.vili
Temperature(°C) 1.A•f. 1A. i 12-t-g 1.vt-S '\k•1 A4.1 Zq•1 14.3
pH(SU.) 4.4.11 4.'-1'1 4,a1 1.3t• 4. 193 4-.s'' 7.66 4.dS
Dissolved oxygen(rng/L) f)..C1 -1, _ 4.-t. 4 ','} ^1• i 1. Ins
45% 4 7 yr
Conductivity(µmhos/cm) 4,3-4- .. c395 381 ^1 1s1-co •'f �1
Temperature(°C) Z`t•q l.4--5 'NA.c\ /\4•1. �(�'�N•.A-& t %•1 .'t• 1 /�1.4/.6
pH(S.U.) '.. t -4. 1.1 to I-.� to '.9 �'c..r 3 3-C. 2. 7(•C� O
Olssolved oxygen(mg/L) 4.' -:.,3 �...� },O 1-,1' "'t•g 1.i V 1
67.5% 4.8 �a� �a l tt3 I
Conductivity(ymhoz(cm) t' a IAA.
Temperature(°C) 1 .1 1S-1, NS•0 •-t.S 'ly•Q "Lg.1 14.1 IA.to
pH(S.U.) '4-.2$ •I-.A3 1-.0o 1-.11 .4-.4o 3.23 '?..4FCo 0_eA,
Dissolved oxygen(mg � A/L) 1 '. -4-A, t,-`14.'4 1.q g•o .5'."4-
90%
Conductivity(µmhos/cm) 93 q t-}.le) q t�8" �J
Temperature(°C) '‘..1., 1A- t S.0 -1,-1-'1 L .-1 1.�-to 1„,I.1 \'
pH(S U.) qr..1.0 4•,Di U-9 V 444 1-.30 -?-..I '3-3/ 0.11
Dissolved oxygen(mg/L) /3 .4• 4-5 ti4C1 ,,••,,1. D,1- 1•9 €.t }
95% ry 9-2 '� ►"tiff (��
Conductivity(µmhos/cm) 't
Temperature(°C) AS•0 V\- f t_ \S.0 /- -IA-V `S•0 1.'.S 1.A•c i- 1^-�- 1
pH(5,U.) 6-- --�,,s �.t73 (2.}a t[/.,`(t- 1.?' 7, •nag 4-.32. V• --I
Dissolved oxygen(mg/L) V.•� -4, '1.,t, K• 1 1 _�_.__._^9 a _..,._ S.•I .� S.(
Conductivity(µmhos/cm) Cea(,i+ }.I.g' ' T L.f°� 4-9(-t°
ZQQ% Alkalinity(mg CaCOo/L) IS
Hardness(mg CaCO,/L) 8S
Chlorine(mg/L) •, p t. �,�
Temperature CC) Zlt `
•o .4.6 \S.o -1-4.to1.S•0 -1 .g 1.A•C
Initial Final Initial Final Initial Final Initial Final
SOP AT2O-Revislon 6-Exhibit AT20.3

•
351 Depot Street
7,0
Asheville,NC 28801
Phone: [phone]
Fax: [phone]
Environmental Testing Solutions,Inc.
Whole Effluent Toxicity Chain-of-Custody Form
Facility: Monroe WWTP NPDES#: NC0024333 Pipe#: 001 County: Union
Purchase order
Species: Pimephales promelas Effluent dilution: 45,67.5,90,95, 100%
Test type: Chronic Definitive Parameter code: THP6C
Sample information: (to be completed by sample collector)Composite sample: Sample location: E 1 Vein'r
Start date: 3 I G`31 Z_y Time: I Volume collected for testing: L
End date: 3j 1L4 I Z4 Time: Number of containers filled for testing:
Number of samples per hour: Method of transport to laboratory: F ,Cl-Ex
Chilled during collection? Comments:
If chilled,specify temperature: 2..t
Triple rinse sample container with sample before filling. Completely fill the sample container with no air space.
Pack the sample container completely in ice. The sample must be<6.0°C upon receipt at the laboratory.
nple custody: (to be completed by sample collector and facility personnel)
Sample collected by:
i_CUkYen. - /M 3InLjIzit
ct&rrne asL 'r tots
Pom Signature Date and time
Relinquished by: Received by:
Lc ) Itt tiA"- 30 214 034ou.2`4
cu r,(1e S cani t tO �c
Pent Signature Date and time Pont Signature Date and time
Relinquished by: Received by:
Print Signature Date and time Prig Signature Date and time
Sample receipt information: (to be completed by ETS personnel)
Relinquished to ETS by: Received at ETS by:
Fiyct.,„0 03 O.l� ,,/ � o3osz,1
/'t•1,1� ink
Pont Signature Date and tune Print Sipnttuc Data and time
Custody seals intact?: EaC:i 1111 Sample temperature upon receipt at ETS(°C):
Yes No Net used
Samples received in good condition?: I —
Yea No Total residual chlorine upon receipt at ETS: _
(DPD Presence/Absense Indicator,MDL=0.10 mg/L)
Tracking number: COCCI y 23(, Pn em A t
Project number: Iitas Sample number: 1..d'OS•0 to
Comments: