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HomeMy WebLinkAboutNC0003468_6. DRSS CAP Part 2_Appx C_FINAL_20160210This page intentionally left blank UNC CHARLOTTE Addendum to Soil Sorption Evaluation Dan River Steam Station Rockingham County, NC Prepared for: HDR Engineering, Inc. Hydropower Services 440 S. Church St, Suite 1000 Charlotte, NC 28202 Investigators: William G. Langley, Ph.D., P.E. Dongwook Kim, Ph.D. UNC Charlotte / Lee College of Engineering Department of Civil and Environmental Engineering EPIC Building 3252 9201 University City Blvd. Charlotte, NC 28223 February 2, 2016 This page intentionally left blank TABLE OF CONTENTS 1 Background.........................................................................................................................1 2 Results................................................................................................................................1 3 Comments and Recommendations..................................................................................... 1 4 References......................................................................................................................... 3 TABLES Table 1. Antimony Table 2. Arsenic Table 3 Boron Table 4 Cadmium Table 5 Cobalt Table 6 Molybdenum Table 7 Selenium Table 8 Thallium Table 9 Vanadium FIGURES (See Tables 1-9 for figure numbers) Background This addendum provides three sorption isotherm equations for batch data analyzed and initially reported in the Soil Sorption Evaluation for Dan River Steam Station (Langley and Oza 2015). The isotherm model equations are: Linear: S = KdC Linear with So > 0: S = KdC + So Freundlich: S = KfC'm where S is the constituent concentration on soil (ug/g), Kd is the linear sorption coefficient (ml/g), C is the constituent concentration in water (ug/1), So is the soil concentration at C = 0, n is the unitless Freundlich exponent, and Kf is the Freundlich constant (I'/nug('-'/n)/g). The parameters Kd, So, Kf, and n are estimated using linear regressions on the sorption data. The parameter So represents that portion of constituent concentration on the soil that is sorbed irreversibly. 2 Results Results are provided in Tables 1 through 8 by constituent and sample. The results include parameter estimates and indicators of the goodness -of -fit of the resulting model equations to the sorption data. 3 Comments and Recommendations In addition to the general comments and qualifiers offered in the Results and Table 16 of the original report, the following comments and recommendations are provided. For the fate and transport model, the range of sorption estimates (maximum and minimum) should be used as the upper and lower limits for selecting a calibrated value that is consistent with measured constituents. For a specific constituent and sample, the isotherm model with the minimum chi-square value best represents the lab data in its arithmetic form. Linear isotherms with So < 0 are considered not applicable because they imply negative soil concentrations (S) as constituent concentration (C) approaches zero. For linear isotherms with So > 0, the y-intercept So is assumed to represent irreversible sorption as opposed to previous exposure to the constituent in the field which is manifested as a negative -sloping or irregular isotherm as would have been noted in the original report. Freundlich isotherms with n < 1 are considered not applicable because they are not concave downward (Freundlich 1924). For constituents not considered for Dan River, sorption values may be transferable from other sites with similar geochemical settings, or may be estimated using site -specific data from the Comprehensive Site Assessment in a geochemical model. 2 4 References Freundlich H. 1924. The Elements of Colloidal Chemistry, translated by George Barger. Dutton and Company Publishers: New York, NY, pp. 58-61. Langley, W.G. and Oz, Shubhashini. Soil Sorption Evaluation for Dan River Steam Station, UNC-Charlotte, October 2015. Ho, Yuh-Shan, Wen-Ta Chiu, and Chung -Chi Wang. "Regression analysis for the sorption isotherms of basic dyes on sugarcane dust." Bioresource technology 96.11 (2005): 1285-1291. Matott, L. Shawn, IsoFit Documentation and User's Guide Version 1.2, State University of New York at Buffalo Department of Civil, Structural and Environmental Engineering Version 1.2, updated 01 /18/07. 3 Table 1 Antimony Well ID No. data points Linear Isotherm, S,, = 0 Linear isotherm, So > 0 Freundlich isotherm Fig. Nos. Trial A Trial B Trial A Trial B Trial A Trial B Trial A Trial B Kd 2 R 2 Kd 2 R 2 Kd So 2 R 2 Kd Sa 2 R 2 K, 1/n 2 R 2 K, 1/n 2 R 2 1/g - Ng/g 1/g - Ng/g 1/g Ng/g - ug/g 1/g Ng/g - Ng/g (c) - - Ng/g (c) - Ng/g AB - 30 BR (32-34) 3 3 0.940 0.961 1.597 1.140 0.958 1.822 0.754 1.133 0.968 0.251 0.917 1.110 0.950 0.389 1.672 0.716 0.934 0.199 1.870 0.719 0.857 0.397 1,2 AB - 30 BR (43-44) 5 5 0.210 0.977 2.257 0.195 0.960 3.566 0.183 0.619 0.997 0.036 0.165 0.767 0.989 0.146 0.625 0.647 0.987 0.088 0.667 0.630 0.999 0.006 3,4 AB - 105 L 5 5 0.072 1 0.997 0.084 0.068 0.996 0.057 0.072 1 0.001 0.992 1 0.084 (d) 0.081 0.964 0.977 0.089 (e) 5,6 AS - 2D 5 5 0.028 0.989 0.138 0.038 0.907 1 1.122 (d) (d) 0.034 1 0.943 0.960 0.176 (e) 7,8 AS - 1 OD 5 5 0.031 0.971 0.631 0.037 0.977 0.685 0.029 0.227 1 0.926 1 0.261 0.032 0.430 1 0.977 1 0.124 0.107 0.715 0.936 0.382 0.118 0.740 0.961 0.118 9,10 GWA-10 5 5 0.014 0.973 0.195 0.015 0.970 0.212 (d) (d) 0.014 0.979 0.935 0.214 (e) 11,12 GWA - 5BR 5 5 0.046 0.988 0.302 0.045 0.992 0.381 1 0.045 0.074 0.969 0.209 0.041 0.237 0.988 0.063 0.103 0.796 0.959 0.292 0.119 0.763 0.980 0.141 13,14 GWA -4D 5 5 0.187 0.937 4.355 0.190 0.938 4.568 0.155 0.865 0.962 0.483 0.157 0.876 0.968 0.399 0.652 0.643 0.979 0.140 0.678 0.637 0.992 0.060 15,16 GWA - 11 D 5 5 0.136 1 0.948 1 5.709 0.123 0.934 5.689 0.113 0.839 0.987 0.160 0.101 0.895 0.973 0.306 0.652 0.568 1 0.998 1 0.017 0.586 0.595 0.999 0.009 17,18 GWA - 12D 5 5 0.024 0.997 0.107 0.025 1 0.996 0.083 0.023 0.078 0.992 0.057 0.025 0.061 0.987 0.054 1 0.048 1 0.843 1 0.971 0.092 0.044 0.873 0.984 0.075 19,20 GWA - 1 S 5 5 0.772 0.990 0.279 0.824 0.994 0.224 0.734 0.235 0.984 0.250 0.805 0.104 0.988 0.218 1 (e) (e) 21,22 GWA - 3S 1 5 5 0.117 0.973 1.616 0.103 0.968 1 1.962 0.101 0.607 1 0.988 0.115 1 0.088 1 0.647 0.987 0.129 1 0.359 1 0.698 1 0.990 0.048 0.357 0.675 1 0.989 0.046 1 23,24 Linear So=O Linear SpO Freundlich Kd Kd So K, 1/n Maximum 1.140 0.917 1.133 1.870 0.979 Minimum 0.014 0.023 0.001 0.014 0.568 Median 0.087 0.101 0.607 0.357 0.716 Notes a. Coefficient of determination (R2)indicates goodness of fit of individual isotherm to its linear regression (Ho et al. 2005). b. Minimum chi-square (X2) indicates best fit of three isotherms in arithmetic form (Ho et al. 2005, Ng et al. 2002). c. units: llvn)pg(1-1m)/g d. Not applicable for So<0 or Kd<0 from linear regression. e. Not applicable for (1/n)>1 or Kf<0 from Freundlich regression (Matott 2007). f. For all C<MDL (method detection limit), estimate a minimum Kd using C = MDL at lowest soil -to -solution ratio. g. Isotherm data not available. Table 2 Arsenic No. data points Linear Isotherm, So = 0 Linear isotherm, So > 0 Freundlich isotherm Trial A Trial B Trial A Trial B Trial A Trial B Well ID Trial A Trial B Kd z R z Kd z R z Kd So z R z Kd So z R z Kr 1 /n 2 R z Kr 1 /n z R z Fig. Nos. 1/g - Ng/g 1/g - Ng/g 1/g ug/9 ug/g 1/g ug/g ug/g (c) Ng/g (c) ug/g AB - 30 BR (32-34) 3 3 2.919 0.973 0.649 2.778 0.981 0.496 (d) (d) (e) (e) 25,26 AB - 30 BR (43-44) 3 3 2.031 0.997 0.096 2.088 0.997 0.109 1 (d) (d) (e) (e) 27,28 AB - 105 L 3 3 1.957 0.999 0.058 1.853 0.998 0.050 (d) (d) (e) I (e) 29,30 AS - 2D 5 5 0.478 0.995 0.240 0.527 0.996 0.353 0.448 0.349 0.997 0.049 0.498 0.302 0.998 0.063 0.640 0.895 0.999 0.011 0.738 0.853 0.976 0.097 31,32 AS - 1 OD 5 5 0.539 0.999 0.058 0.570 0.998 0.071 0.529 0.101 0.999 0.020 0.549 0.200 0.999 0.021 0.630 0.924 0.994 0.040 0.662 0.943 0.999 0.008 33,34 GWA - 10 5 5 0.082 0.976 0.878 0.084 0.979 0.840 0.072 0.599 0.982 0.209 0.073 0.584 0.986 0.066 0.179 0.828 0.989 0.089 0.184 0.823 0.990 0.066 35,36 GWA - 5BR 5 5 0.548 0.993 0.265 0.522 0.979 1 0.933 0.515 0.331 0.993 0.122 0.468 0.599 0.982 0.295 0.689 0.917 0.986 0.079 0.811 0.848 1 0.987 0.145 37,38 GWA -4D 5 5 1.007 0.966 1.161 1.062 0.957 1 1.342 (d) (d) (e) (e) 39,40 GWA - 11 D 3 3 1.817 0.999 1 0.039 1.701 0.996 0.107 1.813 0.014 0.996 0.040 1.614 0.313 0.990 0.088 (e) 1.792 0.980 0.978 0.085 41,42 GWA - 12D 4 5 0.724 0.982 0.866 0.669 0.961 1.711 0.635 0.752 0.991 0.129 0.624 0.377 0.905 1.203 1.170 0.802 0.994 0.039 0.973 0.762 0.617 1.542 43,44 GWA - 1 S 3 3 1.810 0.999 0.863 1.775 1.000 0.798 (d) (d) (e) (e) 45,46 GWA - 3S 5 4 1.339 0.993 0.348 1.513 0.997 0.132 1 (d) (d) (e) (e) 47,48 Linear So=O Linear So>O Freundlich Kd Kd So Kf 1/n Maximum 2.919 1.813 0.752 1.792 0.980 Minimum 0.082 0.072 0.014 0.179 0.762 Median 1.200 0.522 0.340 0.689 0.853 Notes a. Coefficient of determination (R2) indicates goodness of fit of individual isotherm to its linear regression (Ho et al. 2005). b. Minimum chi-square (X2) indicates best fit of three isotherms in arithmetic form (Ho et al. 2005). c. units: h'/")Ng('-'/")/g d. Not applicable for So<0 or Kd<0 from linear regression. e. Not applicable for (1/n)>1 or Kf<0 from Freundlich regression (Matott 2007). f. For all C<MDL (method detection limit), estimate a minimum Kd using C = MDL at lowest soil -to -solution ratio. ci. Isotherm data not available. Table 3 Boron No. data points Linear Isotherm, So = 0 Linear isotherm, So > 0 Freundlich isotherm Trial A Trial B Trial A Trial B Trial A Trial B Well ID Trial A Trial B Kd z R z Kd z R z Kd So z R z Kd So z R z K, 1 /n 2 R z Kr 1 /n z R z Fig. Nos. 1/g - Ng/g 1/g - Ng/g 1/g ug/g ug/g 1/g ug/g I - ug/g (c) Ng/g (c) ug/g AB - 30 BR (32-34) 5 5 0.002 0.920 0.281 0.002 0.982 0.062 (d) (d) (e) (e) 49,50 AB - 30 BR (43-44) 5 5 0.001 0.949 0.117 0.002 0.943 0.172 1 (d) (d) (e) (e) 51,52 AB - 105 L 5 4 0.000 0.971 3.592 0.001 0.714 0.598 (d) (d) (e) (e) 53,54 AS - 2D 5 5 0.001 0.986 0.550 0.002 0.773 0.885 (d) (d) (e) (e) 55,56 AS - 1 OD 5 5 0.002 0.633 2.472 0.002 0.808 0.945 (d) (d) (e) (e) 57,58 GWA - 10 5 5 0.004 0.990 0.061 0.004 0.993 0.034 (d) (d) (e) (e) 59,60 GWA - 5BR 5 5 0.002 0.885 0.393 0.001 0.928 1 0.168 (d) 0.001 0.271 1 0.053 0.160 (e) 0.030 0.458 1 0.081 0.164 61,62 GWA-4D 5 5 0.0004 0.843 0.166 0.0004 1.000 1 1.164 (d) (d) (e) (e) 63,64 GWA - 11 D 5 5 0.001 1 1.000 0.301 0.001 0.999 0.635 (d) 0.000 0.225 1.000 0.463 (e) 0.034 0.423 1.000 0.450 65,66 GWA-12D 5 3 0.003 0.995 1 0.025 0.003 0.999 0.002 0.002 0.201 1 0.981 0.003 0.002 0.075 0.993 0.001 0.011 0.745 1 0.985 0.003 0.005 0.881 0.992 0.001 67,68 GWA - 1 S 5 5 0.002 0.962 0.156 0.002 0.983 0.064 (d) (d) (e) (e) 69,70 GWA - 3S 1 5 5 0.002 0.995 0.024 0.003 0.918 0.405 1 (d) (d) 1 0.003 0.993 1 0.904 0.024 (e) 71,72 Linear So=O Linear So>O Freundlich Kd Kd So Kf 1/n Maximum 0.004 0.002 0.271 0.034 0.993 Minimum 0.0004 0.0005 0.075 0.003 0.423 Median 0.002 0.001 0.213 0.011 0.745 Notes a. Coefficient of determination (R2) indicates goodness of fit of individual isotherm to its linear regression (Ho et al. 2005). b. Minimum chi-square (X2) indicates best fit of three isotherms in arithmetic form (Ho et al. 2005). c. units: h'/")Ng('-'/")/g d. Not applicable for So<0 or Kd<0 from linear regression. e. Not applicable for (1/n)>1 or Kf<0 from Freundlich regression (Matott 2007). f. For all C<MDL (method detection limit), estimate a minimum Kd using C = MDL at lowest soil -to -solution ratio. ci. Isotherm data not available. Table 4 Cadium No. data points Linear Isotherm, So = 0 Linear isotherm, So > 0 Freundlich isotherm Trial A Trial B Trial A Trial B Trial A Trial B Well ID Trial A Trial B Kd z R z Kd z R z Kd So z R z Kd So z R z Kr 1 /n 2 R z Kr 1 /n z R z Fig. Nos. 1/g - Ng/g 1/g ug/g 1/g ug/9 ug/g 1/g ug/g ug/g (c) Ng/g (c) ug/g AB - 30 BR (32-34) 5 5 0.209 0.998 0.064 0.201 (f) (d) (d) (e) (e) 73,74 AB - 30 BR (43-44) 5 5 0.505 0.934 1.057 0.537 0.988 0.319 (d) (d) (e) (e) 75,76 AB - 105 L 1 1 5.869 (f) 5.869 (f) (f) (f) (f) (f) 77,78 5 5 1.049 0.832 2.3 0.970 (d) (d) (e) (e)AS-2D 79,80 AS-1OD 5 5 0.456 0.842 1 1.986 0.539 0.911 1 1.038 (d) (d) (e) (e) 81,82 GWA - 10 1 1 5.869 (f) 5.869 (f) (f) (f) M (f) 83,84 GWA-5BR 5 5 0.747 0.960 0.778 0.870 0.988 0.367 (d) (d) (e) (e) 85,86 GWA-4D 5 5 0.206 0.963 0.687 0.216 0.965 0.727 (d) (d) (e) (e) 87,88 GWA - 11 D 5 5 0.317 0.969 0.634 0.310 0.983 0.421 (d) (d) (e) (e) 89,90 GWA-12D 1 1 5.869 (f) 5.869 (f) (f) (f) (f) (f) 91,92 GWA - 1 S 5 5 0.167 0.958 0.789 0.171 0.958 0.693 (d) (d) (e) (e) 93,94 GWA - 3S 1 5 5 0.560 0.991 1 0.242 0.583 0.980 1 0.434 1 (d) (d) (e) (e) 95,96 Linear So=O Linear So>O Freundlich Kd Kd So Kf 1/n Maximum 5.869 Minimum 0.167 Median 0.549 Notes a. Coefficient of determination (R2) indicates goodness of fit of individual isotherm to its linear regression (Ho et al. 2005). b. Minimum chi-square (X2) indicates best fit of three isotherms in arithmetic form (Ho et al. 2005). c. units: h'/")Ng('-'/n)/g d. Not applicable for So<0 or Kd<0 from linear regression. e. Not applicable for (1/n)>1 or Kf<0 from Freundlich regression (Matott 2007). f. For all C<MDL (method detection limit), estimate a minimum Kd using C = MDL at lowest soil -to -solution ratio. ci. Isotherm data not available. Table 5 Cobalt No. data points Linear Isotherm, So = 0 Linear isotherm, So > 0 Freundlich isotherm Trial A Trial B Trial A Trial B Trial A Trial B Well ID Trial A Trial B Kd z R z Kd z R z Kd So z R z Kd So z R z Kr 1 /n 2 R z Kr 1 /n z R z Fig. Nos. 1/g - Ng/g 1/g - ug/g 1/g ug/9 ug/g 1/g ug/g ug/g (c) Ng/g (c) ug/g AB - 30 BR (32-34) 5 5 0.365 0.937 4.774 0.430 0.892 2.816 (f) (d) (e) (e) 97,98 AB - 30 BR (43-44) 5 5 0.592 0.561 11.380 0.706 0.604 9.631 0.496 0.510 1 0.029 11.350 (d) (e) (e) 99,100 AB- 105 L 2 2 4.666 0.971 0.452 4.965 0.954 0.684 (d) (d) (e) (e) 101,102 AS - 2D 2 3 3.325 1.000 0.0004 3.271 0.939 1.228 (d) (d) (e) (e) 103,104 AS-1OD 5 5 1.262 0.892 6.509 1.368 0.702 10.363 (d) (d) (e) (e) 105,106 GWA - 10 2 2 3.415 1.000 0.001 3.568 0.999 0.013 (d) (d) (e) (e) 107,108 GWA-5BR 4 5 2.613 0.872 2.710 2.378 0.728 6.107 (d) (d) (e) (e) 109,110 GWA-4D 5 5 0.268 0.476 15.999 0.285 0.518 13.270 (d) (d) (e) (e) 111,112 GWA - 11 D 5 5 0.748 0.932 1 1.981 0.717 0.908 2.501 (d) (d) (e) (e) 113,114 GWA-12D 1 1 8.396 (f) 8.396 (f) (f) (f) (f) (f) 115,116 GWA - 1 S 1 5 5 0.558 0.711 6.463 0.496 0.569 11.455 (d) (d) (e) (e) 117,118 GWA - 3S 1 5 5 1.370 0.926 1.647 1.334 0.969 0.993 (d) (d) (e) (e) 119,120 Linear So=O Linear So>O Freundlich Kd Kd So Kf 1/n Maximum 8.396 Minimum 0.268 Median 1.351 Notes a. Coefficient of determination (R2)indicates goodness of fit of individual isotherm to its linear regression (Ho et al. 2005). b. Minimum chi-square (X2) indicates best fit of three isotherms in arithmetic form (Ho et al. 2005). c. units: h'/")Ng('-'/")/g d. Not applicable for So<0 or Kd<0 from linear regression. e. Not applicable for (1/n)>1 or Kf<0 from Freundlich regression (Matott 2007). f. For all C<MDL (method detection limit), estimate a minimum Kd using C = MDL at lowest soil -to -solution ratio. ci. Isotherm data not available. Table 6 Molybdenum No. data points Linear Isotherm, So = 0 Linear isotherm, So > 0 Freundlich isotherm Trial A Trial B Trial A Trial B Trial A Trial B Well ID Trial A Trial B Kd z R z Kd z R z Kd So z R z Kd So z R z Kr 1 /n 2 R z Kr 1 /n z R z Fig. Nos. 1/g Ng/g I/g Ng/g 1/g ug/9 ug/g 1/g hg/g I - ug/g (c) I - Ng/g (c) I - ug/g AB - 30 BR (32-34) 1 1 (f) (f) (f) (f) (f) (f) 121,122 AB - 30 BR (43-44) 4 4 0.352 0.937 5.329 0.384 0.923 7.234 1 0.293 1.132 0.967 0.385 0.316 1.215 0.955 0.557 1.064 0.662 0.978 0.130 1.169 0.661 0.947 0.309 123,124 AB - 105 L 5 5 0.009 0.914 1.553 0.009 0.903 1.654 0.006 0.754 0.916 0.103 0.005 0.777 0.887 0.136 0.116 0.540 0.982 0.032 0.114 0.535 0.933 0.071 125,126 AS - 2D 5 5 0.007 0.809 3.940 0.009 0.925 1.819 0.003 0.941 0.731 0.167 0.006 0.738 0.975 0.038 0.251 0.357 0.909 0.073 0.139 0.508 0.999 0.002 127,128 AS-1OD 5 5 0.057 0.896 11.748 0.056 0.878 14.479 0.044 1.218 0.946 0.533 0.043 1.293 0.936 0.644 0.564 0.505 0.986 0.075 0.601 0.498 0.993 0.059 129,130 GWA - 10 0 0 (g) (g) (g) (g) (g) (g) GWA-5BR 5 5 0.013 0.886 4.384 0.012 0.871 5.636 0.008 0.926 0.936 0.131 0.007 0.952 0.948 0.116 0.232 0.465 0.994 0.015 0.267 0.424 0.984 0.025 131,132 GWA-4D 3 3 1.510 0.997 0.090 1.551 0.980 0.807 1.407 0.456 0.999 0.013 1.329 0.991 1 0.972 0.275 1.777 0.902 0.999 0.003 2.094 0.832 0.935 0.247 133,134 GWA - 11 D 2 2 2.467 0.987 0.444 2.465 0.987 0.446 (d) (d) (e) (e) 135,136 GWA - 12D 5 4 0.004 0.825 2.164 0.004 0.822 1.872 0.001 0.812 0.611 0.056 0.001 0.860 0.325 0.084 0.306 0.237 0.806 0.033 0.354 0.205 0.598 0.059 137,138 GWA-1S 2 2 5.106 0.958 0.651 5.368 0.940 0.896 (d) (d) (e) (e) 139,140 GWA-3S 3 3 0.442 0.927 8.645 0.531 0.933 6.702 0.329 1.903 1 0.978 1.538 0.400 1.847 1 0.977 1.570 1.814 1 0.519 1 0.996 0.733 1 1.849 0.551 1 0.991 0.802 141,142 Linear So=O Linear So>O Freundlich Kd Kd So Kf 1/n Maximum 5.368 1.407 1.903 2.094 0.902 Minimum 0.004 0.001 0.456 0.114 0.205 Median 0.204 0.026 0.946 0.459 0.514 Notes a. Coefficient of determination (R2)indicates goodness of fit of individual isotherm to its linear regression (Ho et al. 2005). b. Minimum chi-square (X2) indicates best fit of three isotherms in arithmetic form (Ho et al. 2005). c. units: h11")N9(1-'/")/g d. Not applicable for So<0 or Kd<0 from linear regression. e. Not applicable for (1/n)>1 or Kf<0 from Freundlich regression (Matott 2007). f. For all C<MDL (method detection limit), estimate a minimum Kd using C = MDL at lowest soil -to -solution ratio. ci. Isotherm data not available. Table 7 Selenium No. data points Linear Isotherm, So = 0 Linear isotherm, So > 0 Freundlich isotherm Trial A Trial B Trial A Trial B Trial A Trial B Well ID Trial A Trial B Kd z R z Kd z R z Kd So z R z Kd So z R z Kr 1 /n 2 R z Kr 1 /n z R z Fig. Nos. 1/g - Ng/g 1/g - ug/g 1/g ug/9 ug/g 1/g ug/g ug/g (c) Ng/g (c) ug/g AB - 30 BR (32-34) 2 2 7.981 0.871 2.474 7.348 0.928 1.411 (d) (d) (e) (e) 143,144 AB - 30 BR (43-44) 5 5 1.239 0.976 1.132 1.324 0.985 0.932 1 (d) (d) (e) (e) 145,146 AB - 105 L 5 5 0.180 0.999 0.049 0.176 0.999 0.056 (d) 0.175 0.030 0.998 0.060 (e) I (e) 147,148 AS - 2D 5 5 0.115 0.983 1.274 0.125 0.986 1.256 0.102 0.827 0.993 0.148 0.111 0.776 0.996 0.093 0.282 0.797 0.997 0.025 0.312 0.782 0.990 0.043 149,150 AS-1OD 5 5 0.260 0.991 0.548 0.268 0.988 0.604 0.243 0.512 0.988 0.217 0.247 0.614 0.988 0.247 0.410 0.869 0.981 0.173 0.406 0.893 0.991 0.135 151,152 GWA - 10 5 5 0.058 0.960 1.803 0.060 0.966 1.577 0.049 0.964 0.956 0.610 0.051 0.903 0.964 0.375 0.137 0.838 0.954 0.420 0.136 0.844 0.951 0.375 153,154 GWA-5BR 5 5 0.135 0.985 0.881 0.121 0.976 1.847 0.121 0.722 0.989 0.215 0.106 0.945 0.989 0.231 0.265 0.843 0.988 0.093 0.325 0.775 0.993 0.061 155,156 GWA-4D 5 5 1.067 0.806 6.164 1.165 0.820 5.797 (d) (d) (e) (e) 157,158 GWA-11D 3 3 3.042 0.993 1 2.223 2.838 0.986 2.241 3.030 0.035 0.975 2.260 2.635 0.635 0.960 2.781 (e) 3.033 0.959 0.881 2.437 159,160 GWA-12D 5 5 0.055 0.973 1.935 0.050 0.952 2.811 0.047 0.941 0.990 0.130 0.043 0.741 0.906 1.133 0.215 0.722 0.999 0.005 0.226 0.661 0.742 1.442 161,162 GWA-1S 2 2 4.753 1.000 0.002 5.436 0.995 0.120 (d) (d) (e) (e) 163,164 GWA - 3S 1 5 4 1.313 0.990 0.559 1.553 0.998 1 0.052 1.234 0.485 1 0.985 0.404 1.550 0.014 1 0.996 0.048 1.469 0.978 1 0.962 0.392 (e) 165,166 Linear So=O Linear So>O Freundlich Kd Kd So Kf 1/n Maximum 7.981 3.030 0.964 3.033 0.978 Minimum 0.050 0.043 0.014 0.136 0.661 Median 0.668 0.121 0.722 0.297 0.840 Notes a. Coefficient of determination (R2)indicates goodness of fit of individual isotherm to its linear regression (Ho et al. 2005). b. Minimum chi-square (X2) indicates best fit of three isotherms in arithmetic form (Ho et al. 2005). c. units: h'/")Ng('-'/")/g d. Not applicable for So<0 or Kd<0 from linear regression. e. Not applicable for (1/n)>1 or Kf<0 from Freundlich regression (Matott 2007). f. For all C<MDL (method detection limit), estimate a minimum Kd using C = MDL at lowest soil -to -solution ratio. ci. Isotherm data not available. Table 8 Thallium Well ID No. data points Linear Isotherm, S,, = 0 Linear isotherm, So > 0 Freundlich isotherm Fig. Nos. Trial A Trial B Trial A Trial B Trial A Trial B Trial A Trial B Kd 2 R 2 Kd 2 R 2 Kd So 2 R 2 Kd Sa 2 R 2 K, 1/n 2 R 2 K, 1/n 2 R 2 1/g - Ng/g 1/g - Ng/g 1/g Ng/g - ug/g 1/g Ng/g - Ng/g (c) - - Ng/g (c) - - Ng/g AB - 30 BR (32-34) 5 5 0.576 0.990 0.639 0.585 0.988 1.062 0.531 0.643 0.992 0.174 0.530 0.778 0.995 0.128 0.849 0.870 0.995 0.068 0.980 0.823 0.997 0.020 167,168 AB - 30 BR (43-44) 3 3 3.391 0.961 1.021 3.554 0.986 0.518 (d) (d) (e) (e) 169,170 AB- 105 L 3 3 4.383 0.922 2.051 4.581 0.944 1.615 (d) (d) (e) (e) 171,172 AS - 2D 2 2 7.783 0.905 1.861 7.232 0.943 1.163 (d) (d) (e) (e) 173,174 AS - 1 OD 3 2 1.534 0.743 6.189 1.809 0.945 4.802 0.945 2.806 1 0.218 5.397 1.221 3.531 1 1.000 0.000 2.598 0.627 1 0.536 5.404 4.752 0.475 1 1.000 0.000 175,176 GWA - 10 5 5 0.718 0.939 2.351 0.726 0.938 2.461 (d) (d) (e) (e) 177,178 GWA - 5BR 2 2 7.756 0.907 1.818 7.603 0.919 1.596 (d) (d) (e) (e) 179,180 GWA -4D 5 5 0.379 0.989 0.431 0.382 0.996 0.281 (d) (d) (e) (e) 181,182 GWA - 11 D 4 4 1.100 0.986 1 0.902 1.069 0.978 1.602 0.979 0.972 1 0.990 0.186 0.930 1.184 1 0.988 0.247 1.641 0.834 1 0.994 0.068 1.784 0.791 1 0.987 0.098 183,184 GWA - 12D 2 2 5.038 0.999 0.018 4.960 1.000 0.009 (d) (d) (e) (e) 185,186 GWA - 1 S 5 5 0.547 1.000 0.063 0.551 0.998 0.179 0.534 0.177 1.000 0.003 0.527 0.346 0.999 0.015 0.656 0.929 0.999 0.019 0.722 0.901 1 0.997 0.015 187,188 GWA - 3S 1 3 3 2.183 0.968 2.053 2.908 0.990 0.479 1 1.818 1.595 0.954 0.627 2.764 0.443 0.969 0.425 1 3.147 0.779 0.866 0.642 (e) 189,190 Linear So=O Linear SpO Freundlich Kd Kd So K, 1/n Maximum 7.783 2.764 3.531 4.752 0.929 Minimum 0.379 0.527 0.177 0.656 0.475 Median 1.996 0.937 0.875 1.641 0.823 Notes a. Coefficient of determination (R2)indicates goodness of fit of individual isotherm to its linear regression (Ho et al. 2005). b. Minimum chi-square (X2) indicates best fit of three isotherms in arithmetic form (Ho et al. 2005). c. units: llvn)pg(1-1m)/g d. Not applicable for So<0 or Kd<0 from linear regression. e. Not applicable for (1/n)>1 or Kf<0 from Freundlich regression (Matott 2007). f. For all C<MDL (method detection limit), estimate a minimum Kd using C = MDL at lowest soil -to -solution ratio. g. Isotherm data not available. Table 9 Vanadium Well ID No. data points Linear Isotherm, S,, = 0 Linear isotherm, So > 0 Freundlich isotherm Fig. Nos. Trial A Trial B Trial A Trial B Trial A Trial B Trial A Trial B Ka 2 R 2 Kd 2 R 2 Kd So 2 R 2 Kd S. 2 R 2 K, 1/n 2 R 2 K, 1/n 2 R 2 1/g Ng/g 1/g Ng/g 1/g Ng/g ug/g 1/g Ng/g Ng/g (c) Ng/g (c) Ng/g AB - 30 BR (32-34) 1 1 (f) (f) (f) (f) (f) (f) 191,192 AB - 30 BR (43-44) 2 2 2.301 0.929 0.437 2.189 0.950 0.319 (d) (d) (e) (e) 193,194 AB - 105 L 5 5 0.583 0.971 0.559 0.546 0.972 0.528 0.561 0.089 1 0.938 1 0.527 0.518 0.126 0.943 0.476 (e) (e) 195,196 AS - 2D 5 4 0.409 0.999 0.014 0.437 0.997 0.043 (d) 0.420 0.100 0.994 0.032 (e) (e) 197,198 AS - 1 OD 5 5 0.467 0.994 0.126 0.463 0.969 0.526 (d) (d) (e) (e) 199,200 GWA - 10 5 5 0.065 0.974 0.441 0.067 0.977 0.420 0.056 0.279 0.981 0.083 0.058 0.271 0.987 0.022 0.141 0.797 0.993 0.027 0.142 1 0.799 1 0.991 0.022 201,202 GWA - 5BR 5 5 0.429 1 0.972 0.565 0.383 0.979 0.349 0.409 0.111 0.941 0.468 0.359 0.151 0.960 0.303 0.465 0.934 0.786 0.519 (e) 203,204 GWA -4D 1 1 3.664 (f) 3.664 (f) (f) (f) (f) (f) 205,206 GWA - 11 D 1 1 3.664 (f) 3.664 (f) (f) (f) (f) (f) 207,208 GWA - 12D 5 5 0.425 0.997 1 0.045 0.342 0.866 1 1.185 0.414 0.060 1 0.994 0.048 (d) 1 0.390 1 0.777 1 0.514 1.868 209,210 GWA - 1 S 1 1 3.664 (f) 3.664 (f) (f) (f) (f) (f) 211,212 2 2 1.979 0.977 0.1 2.295 0.930 213,214GWA-3S Linear So=O Linear So>0 Freundlich Kd Kd So K, 1/n Maximum 3.664 0.561 0.279 0.465 0.934 Minimum 0.065 0.056 0.060 0.141 0.777 Median 0.565 0.411 0.118 0.266 0.798 Notes a. Coefficient of determination (R2)indicates goodness of fit of individual isotherm to its linear regression (Ho et al. 2005). b. Minimum chi-square (X2) indicates best fit of three isotherms in arithmetic form (Ho et al. 2005). c. units: llvn)pg(1-1m)/g d. Not applicable for So<0 or Kd<0 from linear regression. e. Not applicable for (1/n)>1 or Kf<0 from Freundlich regression (Matott 2007). f. For all C<MDL (method detection limit), estimate a minimum Kd using C = MDL at lowest soil -to -solution ratio. g. Isotherm data not available. 8 7 6 —5 0) °' 4 U) 3 2 1 0 Figure 1 Antimony Isotherms for AB — 30 BR (32-34) 0 1 2 3 4 5 6 7 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich i 0 10 9 8 7 6 5 U) 4 3 2 1 0 Figure 2 Antimony Isotherms for AB — 30 BR (32-34) 0 1 2 3 4 5 6 7 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich !3 s 6 —5 0) 0' 4 CO 3 2 1 0 Figure 3 Antimony Isotherms for AB — 30 BR (43-44) T 0 5 10 15 20 25 30 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich —5 0) 0' 4 CO 3 fir: Figure 4 Antimony Isotherms for AB — 30 BR (43-44) 0 5 10 15 20 25 30 35 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 7 6 5 �4 Cj) 3 2 1 0 Figure 5 Antimony Isotherms for AB — 105 L 0 10 20 30 40 50 60 70 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 4 0) F 3 U) 2 1 Figure 6 Antimony Isotherms for AB — 105 L 0 10 20 30 40 50 60 70 C (ug/1) • Trial - B linear So=O 5 4 �3 U) 2 1 0 Figure 7 Antimony Isotherms for AS — 2D • 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 C (ug/1) • Trial - A linear So=O Freundlich 4 0) °' 3 U) 2 1 M Figure 8 Antimony Isotherms for AS — 2D 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 C (ug/1) • Trial - B linear So=O 5 4 �3 U) 2 1 0 Figure 9 Antimony Isotherms for AS — 1 OD 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 C (ug/1) • Trial -A linear So=O linear So>0 Freundlich 5 4 �3 U) 2 1 0 Figure 10 Antimony Isotherms for AS — 1 OD 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich Figure 11 Antimony Isotherms for GWA— 10 4 3 9 °' 2 U 1 / • 0 0 20 40 60 80 100 120 140 160 180 200 C (ug/1) • Trial - A linear So=O Freundlich 4 3 0) °' 2 U) 1 Figure 12 Antimony Isotherms for GWA— 10 • 0 20 40 60 80 100 120 140 160 180 200 C (ug/1) • Trial - B linear So=O 5 4 �3 U) 2 1 0 Figure 13 Antimony Isotherms for GWA— 5BR • 0 10 20 30 40 50 60 70 80 90 100 110 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 5 4 �3 CO 2 1 0 Figure 14 Antimony Isotherms for GWA— 5BR 0 10 20 30 40 50 60 70 80 90 100 110 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 7 6 5 �4 U 3 2 1 0 Figure 15 Antimony Isotherms for GWA— 4D 0 5 10 15 20 25 30 35 40 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 7 6 5 �4 U 3 2 1 0 Figure 16 Antimony Isotherms for GWA— 4D 0 5 10 15 20 25 30 35 40 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 7 6 5 �4 3 2 1 0 Figure 17 Antimony Isotherms for GWA— 11 D 0 10 20 30 40 50 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich Figure 18 Antimony Isotherms for GWA— 11 D 4 3 _0) °' 2 U) 1 Mul Figure 19 Antimony Isotherms for GWA— 12D 0 20 40 60 80 100 120 140 160 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 3 0) 0' 2 U) 1 Figure 20 Antimony Isotherms for GWA— 12D 0 20 40 60 80 100 120 140 160 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 8 7 6 —5 0) °' 4 U) 3 2 1 0 Figure 21 Antimony Isotherms for GWA — 1 S 0 1 2 3 4 5 6 C (ug/1) 7 8 9 10 • Trial - A linear So=O linear So>O 8 7 6 —5 _0) °' 4 U) 3 2 1 0 Figure 22 Antimony Isotherms for GWA — 1 S 0 1 2 3 4 5 6 7 8 9 C (ug/1) • Trial - A linear So=O linear So>O 7 6 5 �4 U) 3 2 1 0 Figure 23 Antimony Isotherms for GWA— 3S 0 10 20 30 40 50 60 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 7 6 5 �4 U) 3 2 1 0 Figure 24 Antimony Isotherms for GWA— 3S 10 20 30 40 50 60 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 9 8 7 6 °' 5 U 4 3 2 0 Figure 25 Arsenic Isotherms for AB — 30 BR (32-34) 0 1 2 3 C (ug/1) • Trial - A linear SO=O 9 8 7 6 °' 5 C 4 3 2 0 Figure 26 Arsenic Isotherms for AB — 30 BR (32-34) 0 1 2 C (ug/1) • Trial - B linear SO=O 9 8 7 6 5 0) U 4 3 2 X Figure 27 Arsenic Isotherms for AB — 30 BR (43-44) 0 1 2 3 C (ug/1) • Trial - A linear SO=O E 9 8 7 6 °' 5 CO4 3 2 0 Figure 28 Arsenic Isotherms for AB — 30 BR (43-44) 1 2 3 C (ug/1) • Trial - B linear SO=O IH 9 8 7 6 °' 5 U 4 3 2 0 Figure 29 Arsenic Isotherms for AB — 105 L 1 2 3 4 C (ug/1) • Trial - A linear SO=O 5 9 8 7 6 °' 5 0) ­ 4 3 2 0 Figure 30 Arsenic Isotherms for AB — 105 L 0 1 2 3 4 C (ug/1) • Trial - B linear SO=O 5 Figure 31 Arsenic Isotherms for AS — 2D 8 7 6 —5 _0) 0' 4 U) 3 2 1 0 Figure 32 Arsenic Isotherms for AS — 2D 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 C (ug/1) • Trial - B linear SO=O linear SO>0 Freundlich 8 7 6 —5 0) °' 4 3 2 1 0 0 Figure 33 Arsenic Isotherms for AS — 1 OD 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 C (ug/1) • Trial - A linear SO=O linear SO>0 Freundlich 8 7 6 —5 0) °' 4 U) 3 2 1 0 0 Figure 34 Arsenic Isotherms for AS — 1 OD 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 C (ug/1) • Trial - B linear SO=O linear SO>0 Freundlich 7 6 5 �4 U) 3 2 1 0 Figure 35 Arsenic Isotherms for GWA— 10 0 10 20 30 40 50 60 70 80 C (ug/1) • Trial - A linear SO=O linear SO>0 Freundlich .11 7 6 5 �4 U 3 2 1 0 Figure 36 Arsenic Isotherms for GWA— 10 0 10 20 30 40 50 60 70 80 90 C (ug/1) • Trial - B linear SO=O linear SO>0 Freundlich 9 8 7 6 0' 5 U 4 3 2 1 0 Figure 37 Arsenic Isotherms for GWA— 5BR 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 C (ug/1) • Trial - A linear SO=O linear SO>0 Freundlich 9 8 7 6 a' 5 0) U 4 3 2 1 0 Figure 38 Arsenic Isotherms for GWA— 5BR 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 C (ug/1) • Trial - B linear SO=O linear SO>0 Freundlich �1 E:3 �A 0' 5 4 3 2 1 0 Figure 39 Arsenic Isotherms for GWA— 4D 0 1 2 3 4 5 6 7 8 C (ug/1) • Trial - A linear SO=O E 9 8 7 6 °' 5 0) U 4 3 2 1 0 Figure 40 Arsenic Isotherms for GWA — 4D 0 1 2 3 4 5 6 7 8 C (ug/1) • Trial - B linear SO=O 0 Figure 41 Arsenic Isotherms for GWA — 11 D �1 1:1 • 7 6 a' 5 0) � 4 3 • 2 • 1 0 0 1 2 3 4 5 C (ug/1) • Trial - A linear SO=O linear SO>O 9 8 7 6 °' 5 4 3 2 0 Figure 42 Arsenic Isotherms for GWA— 11 D 0 1 2 3 4 C (ug/1) • Trial - B linear SO=O linear SO>0 Freundlich 5 9 8 7 6 °' 5 0) U 4 3 2 1 0 Figure 43 Arsenic Isotherms for GWA— 12D 0 1 2 3 4 5 6 7 8 9 10 11 12 C (ug/1) • Trial - A linear SO=O linear SO>0 Freundlich 8 7 6 —5 0) °' 4 U) 3 2 1 0 Figure 44 Arsenic Isotherms for GWA— 12D 0 1 2 3 4 5 6 7 8 9 10 11 12 C (ug/1) • Trial - B linear SO=O linear SO>0 Freundlich 9 8 7 6 0' 5 0) U 4 3 2 0 Figure 45 Arsenic Isotherms for GWA — 1 S 3 4 5 C (ug/1) s Trial - A linear SO=O 9 8 7 6 4 3 2 0 Figure 46 Arsenic Isotherms for GWA— 1S 0 1 2 3 4 C (ug/1) • Trial - A linear SO=O 5 Figure 47 Arsenic Isotherms for GWA— 3S 7 9 8 7 6 °' S CO4 3 2 0 Figure 48 Arsenic Isotherms for GWA— 3S 0 1 2 3 4 5 6 C (ug/1) • Trial - B linear SO=O 7 1.2 1.0 11 0) °' 0.6 U) 0.4 =IV Figure 49 Boron Isotherms for AB — 30 BR (32-34) • 0 40 80 120 160 200 240 280 320 360 400 440 480 C (ug/1) • Trial - A linear So=O Figure 50 Boron Isotherms for AB — 30 BR (32-34) 1.2 1.0 111: 0) �' 0.6 o WO Figure 51 Boron Isotherms for AB — 30 BR (43-44) 1.0 M -& 0.6 CO 0.4 • • WIA Ml • 0 40 80 120 160 200 240 280 320 360 400 440 480 C (ug/1) • Trial - A linear So=O 0.6 0) U) 0.4 0.2 0.0 Figure 52 Boron Isotherms for AB — 30 BR (43-44) 0 40 80 120 160 200 240 280 320 360 400 440 480 C (ug/1) • Trial - B linear So=O Figure 53 Boron Isotherms for AB — 105 L 1.0 0 0.6 t1>VA ols 0 80 160 240 320 400 480 C (ug/1) • Trial - A linear So=O Figure 54 Boron Isotherms for AB — 105 L 1.0 M: • 0.6 0.4 0.2 • • • 0 50 100 150 200 250 300 350 400 450 500 C (ug/1) • Trial - B linear So=O 0.6 U) 0.4 0.2 0.0 Figure 55 Boron Isotherms for AS — 2D • • 0 50 100 150 200 250 300 350 400 450 500 C (ug/1) • Trial - A linear So=O 0.5 0.0 Figure 56 Boron Isotherms for AS — 2D • 0 50 100 150 200 250 300 350 400 450 500 C (ug/1) • Trial - B linear So=O 2.5 2.0 1.5 U) 1.0 0.5 0.0 Figure 57 Boron Isotherms for AS — 1 OD 0 50 100 150 200 250 C (ug/1) • Trial - A linear So=O • • 300 350 400 Figure 58 Boron Isotherms for AS — 1 OD 2.5 2.0 1.5 • 0) CO 1.0 • 0.5 • • • 0 40 80 120 160 200 240 280 320 360 400 440 C (ug/1) • Trial - B linear So=O 2.0 1.5 1.0 CO mew 1js Figure 59 Boron Isotherms for GWA— 10 • 0 40 80 120 160 200 240 280 320 360 400 440 C (ug/1) • Trial - A linear So=O 2.0 1.5 1.0 U) mew 1js Figure 60 Boron Isotherms for GWA— 10 • 0 40 80 120 160 200 240 280 320 360 400 440 C (ug/1) • Trial - B linear So=O Figure 61 Boron Isotherms for GWA— 5BR 1.2 le, 0.6 CO WN] • 0 50 100 150 200 250 300 350 400 450 C (ug/1) • Trial - A linear So=O 0.4 0.2 Figure 62 Boron Isotherms for GWA— 5BR 0 50 100 150 200 250 300 350 400 450 500 C (ug/l) • Trial - B linear So=O linear So>0 Freundlich Figure 63 Boron Isotherms for GWA— 4D 0.5 0.4 0.3 0) U) 0.2 0.1 00 ;SAC • 0 50 100 150 200 250 300 350 400 450 500 C (ug/1) • Trial - A linear So=O 0.7 0.6 0.5 0.4 0.3 0.2 0.1 0.0 Figure 64 Boron Isotherms for GWA— 4D • 0 50 100 150 200 250 300 350 400 450 500 C (ug/1) • Trial - B linear So=O Figure 65 Boron Isotherms for GWA— 11 D 0.5 0.4 a, 0.3 0.2 0.1 0.0 0.5 0.4 0.3 U) 0.2 0.1 0.0 Figure 66 Boron Isotherms for GWA— 11 D 0 100 200 300 400 500 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 1.2 1.0 1)�: 0) °' 0.6 n1 � MOO Figure 67 Boron Isotherms for GWA— 12D 0 50 100 150 200 250 300 350 400 450 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 0.6 0) U) 0.4 0.2 0.0 Figure 68 Boron Isotherms for GWA— 12D 0 50 100 150 200 250 300 350 400 450 500 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich U) 0.5 0.0 Figure 69 Boron Isotherms for GWA — 1 S • 0 50 100 150 200 250 300 350 400 450 C (ug/1) • Trial - A linear So=O U) 0.5 0.0 Figure 70 Boron Isotherms for GWA— 1S Ll ll�W�tlll1 Wi�lzlll �W$=18I8=xll j11I1=Wi] C (ug/1) • Trial - A linear So=O 1.2 1.0 0.6 U) 0.4 M11K Effelue Figure 71 Boron Isotherms for GWA— 3S 0 0 50 100 150 200 250 300 350 400 450 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 2.0 1.8 1.6 1.4 1.2 1311.0 U) 0.8 0.6 0.4 0.2 0.0 Figure 72 Boron Isotherms for GWA— 3S 0 70 140 210 280 350 420 C (ug/1) s Trial - B linear So=O Figure 73 Cadmium Isotherms for AB — 30 BR (32-34) 6 � - 5 4 °' 3 CO 2 1 0 0) 0' 3 2 1 0 Figure 74 Cadmium Isotherms for AB — 30 BR (32-34) 0 4 8 12 16 20 24 C (ug/1) • Trial - B linear So=O 28 4 0) 033 W 1 we] Figure 75 Cadmium Isotherms for AB — 30 BR (43-44) • 0 2 4 6 8 10 C (ug/1) • Trial - A linear So=O n 0) 0' 3 2 1 0 Figure 76 Cadmium Isotherms for AB — 30 BR (43-44) • 0 2 4 6 8 10 C (ug/1) • Trial - B linear So=O Figure 77 Cadmium Isotherms for AB — 105 L 4 0) :03' 3 U) 2 1 Figure 78 Cadmium Isotherms for AB — 105 L 0.0 0.5 1.0 C (ug/1) • Trial - B linear So=O Figure 79 Cadmium Isotherms for AS — 2D 6 5 4 R 3 2 0 • • 0 2 3 4 C (ug/1) • Trial - A linear So=O Figure 80 Cadmium Isotherms for AS — 2D Figure 81 Cadmium Isotherms for AS — 1 OD 6 • 5 4 °' 3 cf) • 2 1 / • 0 0 1 2 3 4 5 6 7 8 9 C (ug/1) • Trial - A linear So=O Figure 82 Cadmium Isotherms for AS — 1 OD [1 4 0) F 3 2 1 MM Figure 83 Cadmium Isotherms for GWA— 10 0.0 0.5 1.0 C (ug/1) • Trial - A linear So=O 4 3 CO 2 1 Mul Figure 84 Cadmium Isotherms for GWA— 10 0.0 0.5 1.0 C (ug/1) • Trial - B linear So=O 6 5 4 0) 0' 3 U) 2 1 mug Figure 85 Cadmium Isotherms for GWA— 5BR 1 2 3 4 5 6 7 8 C (ug/1) • Trial - A linear So=O 6 5 4 0' 3 CO 2 1 Figure 86 Cadmium Isotherms for GWA— 5BR 0 1 2 3 4 5 6 7 8 C (ug/1) • Trial - B linear So=O Figure 87 Cadmium Isotherms for GWA— 4D 12 16 C (ug/1) -A --linear So=O 20 24 0) °' 3 CO 2 1 Mul Figure 88 Cadmium Isotherms for GWA— 4D • 0 4 8 12 16 20 24 C (ug/1) • Trial - B linear So=O 6 5 �4 0) U) 3 2 1 0 Figure 89 Cadmium Isotherms for GWA— 11 D 0 3 6 9 12 15 18 C (ug/1) • Trial - A linear So=O 7 6 5 �4 U) 3 2 1 0 Figure 90 Cadmium Isotherms for GWA— 11 D 3 6 9 12 15 18 C (ug/1) • Trial - B linear So=O 6 5 4 0) °' 3 U) 2 1 ED Figure 91 Cadmium Isotherms for GWA— 12D 0.0 0.5 1.0 C (ug/1) • Trial - A linear So=O In 0) R 3 U) 2 1 MH Figure 92 Cadmium Isotherms for GWA— 12D 0.0 0.5 1.0 C (ug/1) • Trial - B linear So=O 4 0) °' 3 2 1 Figure 93 Cadmium Isotherms for GWA— 1S • 4 8 12 16 20 24 28 C (ug/1) s Trial - A linear So=O 6 5 4 _0) °' 3 U) 2 1 Mul Figure 94 Cadmium Isotherms for GWA— 1S C] 4 8 12 16 20 24 28 C (ug/1) • Trial - A linear So=O i-" 4 0) °' 3 U) 2 1 mug Figure 95 Cadmium Isotherms for GWA— 3S 0 1 2 3 4 5 6 7 8 9 10 C (ug/1) • Trial - A linear So=O 6 5 4 0) EM' 3 U) 2 0 Figure 96 Cadmium Isotherms for GWA— 3S 0 1 2 3 4 5 6 7 8 9 10 C (ug/1) • Trial - B linear So=O 9 8 7 6 a' 5 0) U 4 3 2 1 O Figure 97 Cobalt Isotherms for AB — 30 BR (32-34) • 0 4 8 12 16 20 C (ug/1) • Trial - A linear So=O 9 8 7 6 �' 5 0) 4 3 2 1 0 Figure 98 Cobalt Isotherms for AB — 30 BR (32-34) 11 0 2 4 6 8 10 12 14 16 C (ug/1) • Trial - B linear So=O 01 8 7 6 a' 5 0) 1 W 4 3 2 1 11] Figure 99 Cobalt Isotherms for AB — 30 BR (43-44) 0 1 2 3 4 5 6 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich rA Figure 100 Cobalt Isotherms for AB — 30 BR (43-44) 9 8 • 7 6 5 � 4 3 • 2 • 1 • • 0 0 1 2 3 4 5 6 C (ug/1) • Trial - B linear So=O Figure 101 Cobalt Isotherms for AB — 105 L 9 8 7 6 0' 5 U 4 3 2 1 0 Figure 102 Cobalt Isotherms for AB — 105 L 9 8 7 6 0' 5 0) U 4 3 2 1 0 • 9 8 7 6 5 U 4 3 2 1 0 Figure 103 Cobalt Isotherms for AS — 2D 2 3 C (ug/1) • Trial - A linear So=O linear So>O 9 8 7 6 °' 5 0) M U 4 3 2 0 Figure 104 Cobalt Isotherms for AS — 2D 2 3 C (ug/1) • Trial - B linear So=O 9 8 7 6 °' S 0) M U 4 3 2 1 0 Figure 105 Cobalt Isotherms for AS — 1 OD • 0 1 2 3 4 5 6 C (ug/1) • Trial - A linear So=O 9 8 7 6 4 3 2 0 Figure 106 Cobalt Isotherms for AS — 1 OD 0 1 2 3 4 C (ug/1) • Trial - B linear So=O 9 8 7 6 a' 5 0) U 4 3 2 0 Figure 107 Cobalt Isotherms for GWA— 10 0 1 2 C (ug/1) • Trial - A linear So=O 3 9 8 7 6 C 4 3 2 0 Figure 108 Cobalt Isotherms for GWA— 10 0 1 2 C (ug/1) • Trial - B linear So=O 3 9 8 7 6 5 U 4 3 2 1 0 Figure 109 Cobalt Isotherms for GWA— 5BR • 2 3 C (ug/1) • Trial - A linear So=O 9 8 7 °' 5 0) M U 4 3 2 0 Figure 110 Cobalt Isotherms for GWA— 5BR 2 3 C (ug/1) • Trial - B linear So=O Figure 111 Cobalt Isotherms for GWA— 4D 9 8 • 7 6 0' 5 4 3 • 2 • 1 • • 0 0 2 4 6 8 10 12 14 C (ug/1) • Trial - A linear So=O Figure 112 Cobalt Isotherms for GWA— 4D 9 8 • 7 6 °' 5 0) � 4 3 • i; • 1 • • 0 0 2 4 6 8 10 12 C (ug/1) • Trial - B linear So=O 9 8 7 6 4 3 2 1 0 Figure 113 Cobalt Isotherms for GWA— 11 D 0 2 4 6 8 C (ug/1) • Trial - A linear So=O I 10 9 8 7 6 °' 5 U 4 3 2 1 0 Figure 114 Cobalt Isotherms for GWA— 11 D 2 4 6 8 C (ug/1) • Trial - B linear So=O • 10 9 8 7 6 4 3 2 1 0 Figure 115 Cobalt Isotherms for GWA— 12D 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 C (ug/1) • Trial - A linear So=O 9 8 7 6 0' 5 U 4 3 2 1 0 Figure 116 Cobalt Isotherms for GWA— 12D 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 C (ug/1) • Trial - B linear So=O Figure 117 Cobalt Isotherms for GWA— 1S �11 E:1 7 6 °' 5 0) M U 4 3 2 1 • • 0 • 0 1 2 3 4 5 6 7 8 9 C (ug/1) • Trial - A linear So=O Figure 118 Cobalt Isotherms for GWA— 1 S 9 8 • 7 6 0' 5 0) U 4 3 • 2 • 1 • • 0 0 1 2 3 4 5 6 7 8 C (ug/1) • Trial - A linear So=O 9 8 7 6 �' 5 0) U 4 3 2 0 Figure 119 Cobalt Isotherms for GWA— 3S 0 1 2 3 4 5 6 C (ug/1) • Trial - A linear So=O 9 8 7 6 0' 5 � 4 3 2 1 0 Figure 120 Cobalt Isotherms for GWA— 3S • 1 2 3 4 5 6 C (ug/1) • Trial - B linear So=O Figure 121 Molybdenum Isotherms for AB - 30 BR (32-34) 9 8 7 6 0' 5 c 4 3 2 9 8 7 6 a' 5 0) U 4 3 A Figure 122 Molybdenum Isotherms for AB - 30 BR (32-34) 0.0 0.2 0.4 0.6 0.8 1.0 C (ug/1) • Trial - B linear So=O 9 8 7 6 5 0) � 4 3 2 X Figure 123 Molybdenum Isotherms for AB — 30 BR (43-44) 0 5 10 15 20 25 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 9 8 7 6 0' 5 U 4 3 2 0 Figure 124 Molybdenum Isotherms for AB — 30 BR (43-44) 0 5 10 15 20 25 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 0) 0) 3 2 1 0 Figure 125 Molybdenum Isotherms for AB — 105 L 0 60 120 180 240 300 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 0) 3 2 1 0 Figure 126 Molybdenum Isotherms for AB — 105 L 60 120 180 240 300 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich Figure 127 Molybdenum Isotherms for AS — 2D 0 50 100 150 200 250 300 350 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 3.0 2.5 %A 1.5 1.0 tilp M Figure 128 Molybdenum Isotherms for AS — 2D 0 50 100 150 200 250 300 350 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 7 6 5 �4 U 3 2 1 0 Figure 129 Molybdenum Isotherms for AS — 1 OD 0 25 50 75 100 125 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 7 6 5 �4 3 2 1 0 Figure 130 Molybdenum Isotherms for AS — 1 OD 0 25 50 75 100 125 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 3 0) 0' 2 1 NEI Figure 131 Molybdenum Isotherms for GWA— 5BR 0 60 120 180 240 300 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 3 2 0) 0) U) 1 0 Figure 132 Molybdenum Isotherms for GWA— 5BR 60 120 180 240 300 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 9 8 7 6 °' 5 U 4 3 2 1 0 Figure 133 Molybdenum Isotherms for GWA— 4D 0 1 2 3 4 5 6 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 9 8 7 6 °' 5 0) U 4 3 2 1 0 Figure 134 Molybdenum Isotherms for GWA— 4D 0 1 2 3 4 5 6 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 9 8 7 6 °' 5 0) U 4 3 2 0 Figure 135 Molybdenum Isotherms for GWA— 11 D 1 2 3 C (ug/1) • Trial - A linear So=O 4 9 8 7 6 °' 5 0) U 4 3 2 0 Figure 136 Molybdenum Isotherms for GWA— 11 D 1 2 3 C (ug/1) • Trial - B linear So=O 4 CO 0.5 0.0 Figure 137 Molybdenum Isotherms for GWA— 12D 50 100 150 200 250 300 350 400 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 0) 0.5 0.0 Figure 138 Molybdenum Isotherms for GWA— 12D 0 50 100 150 200 250 300 350 400 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 9 8 7 6 °' 5 U 4 3 2 1 0 Figure 139 Molybdenum Isotherms for GWA — 1 S 0.0 0.4 0.8 1.2 C (ug/1) • Trial - A linear So=O • 1.6 9 8 7 6 0' 5 U 4 3 2 1 0 Figure 140 Molybdenum Isotherms for GWA — 1 S • 0 1 1 2 C (ug/1) • Trial - A linear So=O 9 8 7 6 4 3 2 1 0 Figure 141 Molybdenum Isotherms for GWA — 3S 0 5 10 15 20 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 9 8 7 6 °' 5 0) 4 3 2 0 Figure 142 Molybdenum Isotherms for GWA— 3S 5 10 15 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 20 Figure 143 Selenium Isotherms for AB — 30 BR (32-34) ^1) 5 Figure 144 Selenium Isotherms for AB — 30 BR (32-34) 12 6 4 2 0 0.0 0.5 1.0 1.5 C (ug/1) • Trial - B linear So=O 12 10 6 4 Figure 145 Selenium Isotherms for AB — 30 BR (43-44) • 0 1 2 3 4 5 6 7 8 9 C (ug/1) • Trial - A linear So=O 12 10 a' 6 4 Figure 146 Selenium Isotherms for AB — 30 BR (43-44) 0 1 2 3 4 5 6 7 8 9 C (ug/1) • Trial - B linear So=O 11 10 9 8 7 6 U) 5 4 3 2 1 0 Figure 147 Selenium Isotherms for AB — 105 L 0 8 16 24 32 40 48 56 C (ug/1) • Trial -A linear So=O linear So>0 Freundlich 64 11 10 9 8 7 6 U) 5 4 3 2 1 0 Figure 148 Selenium Isotherms for AB — 105 L 0 8 16 24 32 40 48 56 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 64 12 10 8 6 U) 4 2 0 0 Figure 149 Selenium Isotherms for AS — 2D 7 14 21 28 35 42 49 56 63 70 77 84 91 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 12 10 8 6 4 2 0 0 Figure 150 Selenium Isotherms for AS — 2D 7 14 21 28 35 42 49 56 63 70 77 84 91 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 11 10 9 8 7 6 U) 5 4 3 2 1 0 Figure 151 Selenium Isotherms for AS — 1 OD 0 11 22 33 44 C (ug/1) • Trial -A linear So=O linear So>0 Freundlich 11 10 9 8 7 a' 6 0) U) 5 4 3 2 1 0 Figure 152 Selenium Isotherms for AS — 1 OD 0 11 22 33 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich • 44 8 7 6 0' 5 U 4 3 2 1 0 Figure 153 Selenium Isotherms for GWA— 10 • 0 16 32 48 64 80 96 112 128 144 160 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 9 8 7 6 0' 5 U 4 3 2 1 0 0 Figure 154 Selenium Isotherms for GWA— 10 16 32 48 64 80 96 112 128 144 160 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 11 10 9 8 7 6 U) 5 4 3 2 1 0 Figure 155 Selenium Isotherms for GWA— 5BR 0 8 16 24 32 40 48 56 64 72 80 88 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 11 10 9 8 7 6 U) 5 4 3 2 1 0 Figure 156 Selenium Isotherms for GWA— 5BR 0 8 16 24 32 40 48 56 64 72 80 88 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 12 10 r, 6 U) 4 2 0 Figure 157 Selenium Isotherms for GWA— 4D 0 1 2 3 4 5 6 7 8 C (ug/1) • Trial - A linear So=O Figure 158 Selenium Isotherms for GWA— 4D 47 Figure 159 Selenium Isotherms for GWA— 11 D 12 10 8 6 4 2 0 • • 0 1 2 3 4 5 C (ug/1) • Trial - A linear So=O linear So>O 12 10 8 0) U 6 4 2 0 Figure 160 Selenium Isotherms for GWA— 11D 0 1 2 3 4 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 5 �01 8 7 6 0' 5 U 4 3 2 1 0 Figure 161 Selenium Isotherms for GWA— 12D 0 17 34 51 68 85 102 119 136 153 170 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich �1 E:3 N A °' 5 0) 4 3 2 1 0 Figure 162 Selenium Isotherms for GWA— 12D 0 20 40 60 80 100 120 140 160 180 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich Figure 163 Selenium Isotherms for GWA— 1S 12 10 8 6 4 2 0 12 10 0) 6 CO 4 2 0 Figure 164 Selenium Isotherms for GWA— 1S 0.0 0.5 1.0 1.5 2.0 C (ug/1) • Trial - A linear So=O 2.5 12 10 r. 6 CO 4 2 0 Figure 165 Selenium Isotherms for GWA— 3S 0 1 2 3 4 5 6 7 8 C (ug/1) 9 10 • Trial - A linear So=O linear So>0 Freundlich Figure 166 Selenium Isotherms for GWA— 3S 12 10 8 6 U) • 4 • 2 • 0 0 1 2 3 4 5 C (ug/1) • Trial - B linear So=O U 6 7 8 linear So>O 12 10 6 U) 4 2 0 Figure 167 Thallium Isotherms for AB — 30 BR (32-34) 0 3 6 9 12 15 18 21 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 12 10 8 6 U) 4 f►i Figure 168 Thallium Isotherms for AB — 30 BR (32-34) 0 3 6 9 12 15 18 21 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich Figure 169 Thallium Isotherms for AB — 30 BR (43-44) 12 10 8 6 U) 4 2 W C (ug/1) s. Trial - A - linear So=O 3 12 10 8 0) 0' 6 U) 4 2 0 Figure 170 Thallium Isotherms for AB — 30 BR (43-44) 1 2 3 C (ug/1) • Trial - B linear So=O • 12 10 6 CO 4 2 0 Figure 171 Thallium Isotherms for AB — 105 L 0 1 2 C (ug/1) • Trial - A linear So=O 3 12 10 0) 6 CO 4 2 0 Figure 172 Thallium Isotherms for AB — 105 L 1 2 3 C (ug/1) • Trial - B linear So=O 12 10 6 U) 4 2 0 Figure 173 Thallium Isotherms for AS — 2D n 0.0 0.5 1.0 1.5 C (ug/1) • Trial - A linear So=O Figure 174 Thallium Isotherms for AS — 2D 47 12 10 _0) :' 6 U) 4 2 0 Figure 175 Thallium Isotherms for AS — 10D 0 1 1 2 3 4 4 5 6 6 7 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 12 10 _0) 0' 6 U) 4 2 0 Figure 176 Thallium Isotherms for AS — 1 OD 0 1 1 2 3 4 4 5 6 6 7 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 12 10 8 6 4 2 0 0 Figure 177 Thallium Isotherms for GWA— 10 C (ug/1) • Trial - A linear So=O • 12 11 10 9 8 a, 7 6 c) 5 4 3 2 1 0 Figure 178 Thallium Isotherms for GWA— 10 0 2 4 6 8 10 12 14 C (ug/1) • Trial - B linear So=O 12 10 6 U) 4 2 0 Figure 179 Thallium Isotherms for GWA— 5BR n 0.0 0.5 1.0 1.5 C (ug/1) • Trial - A linear So=O Figure 180 Thallium Isotherms for GWA— 5BR 12 F---- • 12 F- 10 8 6 U) 4 2 0 Figure 181 Thallium Isotherms for GWA— 4D 0 5 10 15 20 25 30 C (ug/1) • Trial - A linear So=O 12 10 6 CO 4 2 0 Figure 182 Thallium Isotherms for GWA— 4D 5 10 15 20 25 30 C (ug/1) • Trial - B linear So=O 12 10 6 U) 4 2 0 Figure 183 Thallium Isotherms for GWA— 11 D 0 2 4 6 8 10 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 0 12 12 10 8 6 U) 4 2 0 Figure 184 Thallium Isotherms for GWA— 11 D 0 2 4 6 8 10 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich C] 12 12 10 8 6 U) 4 2 0 Figure 185 Thallium Isotherms for GWA— 12D 0 1 2 C (ug/1) • Trial - A linear So=O 3 Figure 186 Thallium Isotherms for GWA— 12D 12 10 6 CO 4 2 0 Figure 187 Thallium Isotherms for GWA— 1S 6 12 18 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 24 12 10 6 CO 4 2 0 Figure 188 Thallium Isotherms for GWA— 1S 6 12 18 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 24 12 10 6 CO 4 2 0 Figure 189 Thallium Isotherms for GWA— 3S 0 1 2 3 4 5 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 0 12 10 E:a _0) °' 6 U) 4 2 0 Figure 190 Thallium Isotherms for GWA— 3S 1 2 3 4 C (ug/1) 5 6 • Trial - B linear So=O linear So>0 Freundlich 4 =' 2 U) Figure 191 Vanadium Isotherms for AB — 30 BR (32-34) 0.0 0.2 0.4 0.6 0.8 1.0 C (ug/1) • Trial - A linear So=O n 3 °' 2 1 I Figure 192 Vanadium Isotherms for AB — 30 BR (32-34) 0 0 C (ug/1) 4.0 3.5 3.0 2.5 2.0 C/) 1.5 1.0 0.5 0.0 Figure 193 Vanadium Isotherms for AB — 30 BR (43-44) 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 C (ug/1) • Trial - A linear So=O Figure 194 Vanadium Isotherms for AB — 30 BR (43-44) 4.0 3.5 3.0 2.5 2.0 1.5 1.0 0.5 0.0 • 4 Figure 195 Vanadium Isotherms for AB — 105 L 4 5 6 7 linear So>0 Figure 196 Vanadium Isotherms for AB — 105 L 4 • 3 °' 2 0 0 1 2 3 4 C (ug/1) 5 6 7 • Trial - B linear So=O linear So>O 3 0) 0' 2 1 Figure 197 Vanadium Isotherms for AS — 2D 1 2 3 4 5 6 7 8 C (ug/1) • Trial - A linear So=O 0 4 3 0) °' 2 U) 1 Nut Figure 198 Vanadium Isotherms for AS — 2D 0 1 2 3 4 5 6 7 8 9 C (ug/1) • Trial - B linear So=O linear So>O Figure 199 Vanadium Isotherms for AS — 1 OD 4 3 0) °' 2 U) 1 MH Figure 200 Vanadium Isotherms for AS — 10D 2 4 6 8 C (ug/1) • Trial - B linear So=O 3 2 U) 1 0 Figure 201 Vanadium Isotherms for GWA— 10 8 16 24 32 40 C (ug/1) • Trial -A linear So=O linear So>0 Freundlich 3 2 0) 0) U) 1 0 Figure 202 Vanadium Isotherms for GWA— 10 8 16 24 32 40 48 C (ug/1) • Trial - B linear So=O linear So>0 Freundlich 4 3 0) 2 CO 1 MUS Figure 203 Vanadium Isotherms for GWA — 5BR 0 1 2 3 4 5 6 7 8 9 C (ug/1) • Trial - A linear So=O linear So>0 Freundlich 10 Figure 204 Vanadium Isotherms for GWA — 5BR Cl 4 3 0) °' 2 1 Mul Figure 205 Vanadium Isotherms for GWA— 4D 0.0 0.2 0.4 0.6 0.8 1.0 C (ug/1) • Trial - A linear So=O 3 0) 0' 2 1 Figure 206 Vanadium Isotherms for GWA— 4D 0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 C (ug/1) • Trial - B linear So=O 4 3 0) °' 2 U) 1 Nut Figure 207 Vanadium Isotherms for GWA— 11D 0.0 0.2 0.4 0.6 0.8 1.0 C (ug/1) • Trial - A linear So=O Figure 208 Vanadium Isotherms for GWA— 11 D E 4 3 2 U) 1 Mul Figure 209 Vanadium Isotherms for GWA— 12D 3 6 9 C (ug/1) • Trial - A linear So=O linear So>O 4 3 0) °' 2 U) 1 M Figure 210 Vanadium Isotherms for GWA— 12D • 3 6 9 C (ug/1) • Trial - B linear So=O Freundlich Figure 211 Vanadium Isotherms for GWA — 1 S 3 rn 0' 2 U) 1 MC 4 3 0) °' 2 U) 1 Figure 212 Vanadium Isotherms for GWA— 1S 0.0 0.2 0.4 0.6 0.8 1.0 C (ug/1) • Trial - A linear So=O 4 3 0) °' 2 U) 1 MC Figure 213 Vanadium Isotherms for GWA— 3S • 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 C (ug/1) • Trial - A linear So=O 4 3 0) °' 2 U) 1 Nut Figure 214 Vanadium Isotherms for GWA— 3S 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 C (ug/1) • Trial - B linear So=O