WQ0041666_Application_20240522

Phone [phone] ~ Fax [phone]
755 Yadkinville Rd ~ Mocksville, NC 27028
April 17, 2024
Division of Water Resources
Water Quality Permitting Section
Non-Discharge Permitting Unit
1617 Mail Services Center
Raleigh, NC 27699-1617
RE: Permit Modification – WQ0041666

To Whom it May Concern:

EMA Resources is submitting the included permit modification for the EMA Resources
Inc. – DCAR Permit WQ0041666. We are asking to have the City of Durham – Brown
WTP Facilities’ dry tons increased from 1500 to 2500. During 2023, we land applied
more than anticipated and this increase should account for any increases in production. A
check for $348.00 is being mailed today along with the submission confirmation.

If you have any questions concerning this modification, please contact Brent Collins –
Director of Technical Services

Respectfully,

Brent Collins
Director of Technical Services
[e-mail]
[phone]
Phone [phone] ~ Fax [phone]
755 Yadkinville Road ~ Mocksville, NC 27028
Permit Modification
For
EMA Resources Inc. - WQ0041666
Distribution of Residual Solids
(503 Exempt)
Prepared By:
EMA Resources Inc.
755 Yadkinville Road
Mocksville, NC 27028
336-751-1441

April 17th, 2024
Table of Contents
Current Permit
DCAR Form
RSC Form
Operation and Maintenance Plan
Vicinity Maps
Program Information
Marketability Statement
Label for Residuals
Process Flow
Quantitative Justification
Analytical Data
March 10, 2022
ERIK BLANKENSHIP PRESIDENT
EMA RESOURCES, INC.
755YADKINVILLE ROAD
MOCKSVILLE, NORTH CAROLINA 27028
Subject: Permit No. WQ0041666
EMA Resources Class A
Residuals Program
Attachment A Certification
Davie County
Dear Mr. Blankenship:
In accordance with your permit major modification request received December 22, 2021, we are
forwarding herewith a modified Attachment A certified March 10, 2022, to EMA Resources, Inc. for the
subject residuals management program.
Modifications to the subject Attachment are as follows: Addition of the Wade G. Brown WTP
(NC0332010 P01) as an approved residuals source with a permitted dry tonnage of 1,500 dry tons per
year (DT/yr).
The modified Attachment A shall be effective from the date of certification until January 31, 2027
(i.e., expiration date of the current permit), shall void Attachment A of Permit No. WQ0041666 issued July
16, 2020 that was previously certified on March 25, 2021, and shall be subject to the conditions and
limitations as specified therein, as well as those specified in the above-referenced permit. Please replace
Attachment A of Permit No. WQ0041666 that was certified on March 25, 2021 with the modified
Attachment A.Please note that the Permittee shall submit a renewal application no later than August
4, 2026.
If any parts, requirements or limitations contained in this certification are unacceptable, the
Permittee has the right to request an adjudicatory hearing upon written request within 30 days following
receipt of this permit. This request shall be in the form of a written petition, conforming to Chapter 150B
of the North Carolina General Statutes, and filed with the Office of Administrative Hearings at 6714 Mail
Service Center, Raleigh, NC 27699-6714. Otherwise, this certification shall be final and binding.
If you need any additional information concerning this matter, please contact Erick Saunders at
[phone] or [e-mail].
Sincerely,
S. Daniel Smith, Director
Division of Water Resources
Mr. Erik Blankenship
March 10, 2022
Page 2 of 2
cc: Durham County Health Department (Electronic Copy)
Raleigh Regional Office, Water Quality Regional Operations Section (Electronic Copy)
Winston-Salem Regional Office, Water Quality Regional Operations Section (Electronic Copy)
Brent Collins EMA Resources, Inc. (Electronic Copy)
Laserfiche File (Electronic Copy)
Digital Permit Archive (Electronic Copy)
WQ0041666 Version 1.0 Shell Version 200201 Page 1 of 10
NORTH CAROLINA
ENVIRONMENTAL MANAGEMENT COMMISSION
DEPARTMENT OF ENVIRONMENTAL QUALITY
RALEIGH
DISTRIBUTION OF CLASS A RESIDUALS PERMIT
_____________________________________________________________________________________
In accordance with the provisions of Article 21 of Chapter 143, General Statutes of North Carolina as
amended, and other applicable Laws, Rules, and Regulations
PERMISSION IS HEREBY GRANTED TO
EMA Resources, Inc.
Davie County
FOR THE
operation of a residuals management program for EMA Resources, Inc. and consisting of the distribution
of Class A residuals generated by the approved facility listed in Attachment A, with no discharge of wastes
to surface waters, pursuant to the application received May 5, 2020, and in conformity with other supporting
data subsequently filed and approved by the Department of Environmental Quality and considered a part
of this permit. The disposal of residuals is regulated under Title 40 Code of Federal Regulations Part 503.
This permit does not exempt the Permittee from complying with Federal Regulation 40 CFR Part 503.
This permit shall be effective from the date of issuance through January 31, 2027, and shall be subject to
the following conditions and limitations:
I. SCHEDULES
1. The Permittee shall request renewal of this permit on Division-approved forms no later than August 4,
2026. [15A NCAC 02T .0105(b), 02T .0109]
II. PERFORMANCE STANDARDS
1. The Permittee shall maintain and operate the subject residuals management program so there is no
discharge to surface waters, nor any contravention of groundwater or surface water standards. In the
event the residuals management program fails to perform satisfactorily, including the creation of
nuisance conditions due to improper operation and maintenance, the Permittee shall immediately cease
distributing residuals, take immediate corrective actions, and contact the Winston-Salem Regional
Office supervisor. [15A NCAC 02T .0108(b)(1)(A)]
2. This permit shall not relieve the Permittee of their responsibility for damages to groundwater or surface
water resulting from the operation of this residuals management program. [15A NCAC 02T
.0108(b)(1)(A)]
3. Only residuals generated by the facility listed in Attachment A are approved for distribution in
accordance with this permit. [15A NCAC 02T .1101]
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4. Pollutant concentrations in distributed residuals shall not exceed the following Ceiling Concentrations
or Monthly Average Concentrations, on a dry weight basis:
Parameter Ceiling Concentration Monthly Average
Concentration
(mg/kg) (mg/kg)
Arsenic 75 41
Cadmium 85 39
Copper 4,300 1,500
Lead 840 300
Mercury 57 17
Molybdenum 75 N/A
Nickel 420 420
Selenium 100 100
Zinc 7,500 2,800
[15A NCAC 02T .1105(a), 02T .1105(c)]
5. Class A biological residuals shall meet the pathogen reduction requirements in 15A NCAC 02T
.1106(a). Exemptions to this requirement shall be specified in Attachment A. [15A NCAC 02T
.1106(a), 02T .1106(d)]
6. Class A biological residuals shall meet one of the vector attraction reduction alternatives in 15A NCAC
02T .1107(a). Exemptions to this requirement shall be specified in Attachment A. [15A NCAC 02T
.1107(a), 02T .1107(c)]
7. The facilities and sites herein were permitted per the following setbacks:
a. Setbacks for Class A land application sites are as follows (all distances in feet):
Liquid
Residuals
Cake
Residuals 1
i. Each private or public water supply source: 100 100
ii. Surface waters such as intermittent and perennial streams, perennial
waterbodies, and wetlands:100 25
iii. Surface water diversions such as ephemeral streams, waterways, and
ditches:25 0
iv. Groundwater lowering ditches where the bottom of the ditch
intersects the SHWT:25 0
v. Each well with exception of monitoring wells: 100 100
vi. Bedrock outcrops: 25 0
1
solids by weight and can be stacked without flowing, as well as can be handled, transported
and spread as a solid (e.g., using a backhoe, front end loader, slinger spreader, broadcast
spreader or other equipment designed for handling solid materials) without leaving any
significant liquid fraction behind.
[15A NCAC 02T .1108(b)]
WQ0041666 Version 1.0 Shell Version 200201 Page 3 of 10
8. Residuals and other sources of Plant Available Nitrogen (PAN) shall not be applied in exceedance of
agronomic rates. Appropriate agronomic rates shall be calculated using expected nitrogen requirements
based on the determined Realistic Yield Expectations (RYE) using any of the following methods:
a.re-approved site specific historical data for specific crop or soil types by calculating
the mean of the best three yields of the last five consecutive crop harvests for each field.
b. North Carolina Historical Data for specific crop and soil types as provided by North Carolina State
University Department of Soil Science (http://nutrients.soil.ncsu.edu/yields/index.php ). A copy
shall be kept on file and reprinted every five years in accordance with Condition IV.6.
c. If the RYE cannot be determined using methods (a) or (b) above, the Permittee may use the RYE
and appropriate nutrient application rates reported in any of the following documents:
i.Crop management plan as outlined by the local Cooperative Extension Office, the North
Carolina Department of Agriculture and Consumer Services, the Natural Resource
Conservation Service, or other agronomist.
ii.Waste Utilization Plan as outlined by the Senate Bill 1217 Interagency Group - Guidance
Document: Chapter 1
(http://www.ncagr.gov/SWC/tech/documents/9th_Guidance_Doc_100109.pdf).
iii.Certified Nutrient Management Plan as outlined by the Natural Resources Conservation
Services (NRCS). These plans must meet the USDA-NRCS 590 Nutrient Management
Standards (ftp://ftp-fc.sc.egov.usda.gov/NHQ/practice-standards/standards/590.pdf).
d. If the RYE and appropriate nutrient application rates cannot be determined, the Permittee shall
contact the Division to determine necessary action.
[15A NCAC 02T .1109(a)(1)(K)]
9. Prior to distributing Class A residuals that have a sodium adsorption ratio (SAR) of 10 or higher, the
Permittee shall obtain and implement recommendations from at least one of the following: the local
Cooperative Extension Office; the Department of Agriculture and Consumer Services; the Natural
Resource Conservation Service; a North Carolina Licensed Soil Scientist; or an agronomist. The
recommendations shall address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a
mechanism for maintaining site integrity and conditions conducive to crop growth. The Permittee shall
maintain written records of these recommendations and details of their implementation. The Permittee
shall notify third-party entities of the effects of a high SAR content residuals on their receiving sites.
[15A NCAC 02T .0108(b)(1)(A)]
WQ0041666 Version 1.0 Shell Version 200201 Page 4 of 10
III. OPERATION AND MAINTENANCE REQUIREMENTS
1. The Permittee shall operate and maintainthe residuals management program as a non-discharge system.
[15A NCAC 02T .1100]
2. The Permittee shall maintain a Division-approved Operation and Maintenance Plan that shall include:
a. Description of the program, and associated facilities and equipment, in sufficient detail to show
what operations are necessary for the program to function and by whom the functions are to be
conducted;
b. Description of anticipated maintenance of facilities and equipment associated with the program;
c. Include provisions for safety measures, including restriction of access to sites and equipment;
d. Spill control provisions:
i. Response to upsets and bypasses including control, containment, and remediation; and
ii. Contact information for plant personnel, emergency responders, and regulatory agencies;
e. Detailed inspection procedures:
i. Names or titles of personnel responsible for conducting inspections;
ii. Frequency and location of inspections, and procedures to assure that the selected locations and
inspection frequency are representative of the residuals management program; and
iii. Description of record keeping and actions to be taken by the inspector in the event that
noncompliance is observed;
f. Detailed sampling and monitoring procedures:
i. Names or titles of personnel responsible for conducting sampling and monitoring;
ii. Description of monitoring procedures including parameters to be monitored; and
iii. Sampling frequency and procedures to assure that representative samples are collected.
Fluctuation in temperature, flow, and other operating conditions can affect the quality of the
residuals gathered during a particular sampling event. The sampling plan shall account for any
foreseen fluctuations in residuals quality and indicate the most limiting times for residuals to
meet pathogen and vector attraction reduction requirements.
[15A NCAC 02T .1110(a)]
3.
classification of the residuals management program, the Permittee shall designate and employ a
certified operator in responsible charge (ORC), and one or more certified operators as back-up ORCs.
The ORC or their back-up shall visit the facilities in accordance with 15A NCAC 08G 0204 and shall
comply with all other requirement in 15A NCAC 08G 0204. [15A NCAC 02T .0117, 08G .0204]
4. The Permittee shall ensure that a copy of this permit and the Division-approved Operation and
Maintenance Plan is available when land applying bulk Class A residuals. [15A NCAC 02T .1110(b)]
5. The Permittee shall ensure that spill control provisions are available when transporting or land applying
bulk Class A residuals. [15A NCAC 02T .1110(a)(4)]
6. Class A residuals may be staged at the land application site for up to 30 days for biological residuals
and 60 days for non-biological residuals. Class A residuals shall be stored or staged in a manner to
prevent runoff of leachate and other wastewaters generated. [15A NCAC 02T .1110(c), 02T .1110(d)]
7. Adequate measures shall be taken to prevent wind erosion and runoff from the bulk Class A residual
land application sites. [15A NCAC 02T .0108(b)(1)(A)]
WQ0041666 Version 1.0 Shell Version 200201 Page 5 of 10
8. Bulk Class A residuals shall not be land applied under the following conditions:
a. If the residuals are likely to adversely affect a threatened or endangered species listed under section
4 of the Endangered Species Act or its designated critical habitat;
b. If the application causes nuisance conditions;
c. If the land fails to assimilate the bulk residuals or the application causes the contravention of surface
water or groundwater standards;
d. If the land is flooded, frozen, or snow-covered, or is otherwise in a condition such that runoff of
the residuals would occur;
e. Within the 100-year flood elevation, unless the residuals are injected or incorporated within a 24-
hour period following a residuals land application event;
f. During precipitation events, or within 24 hours following a rainfall event of 0.5 inches or greater
in a 24-hour period;
g. If the slope of the land is greater than 10% when liquid residuals are surface applied, or if the slope
of the land is greater than 18% when liquid residuals are injected or incorporated;
h. If the land does not have an established vegetative cover crop unless the land is a Division-approved
no-till site, or the residuals are injected, or incorporated within a 24-hour period following the
application of residuals;
i. If the vertical separation of the seasonal high water table and the depth of residuals application is
less than one foot;
j. If the vertical separation of the depth to bedrock and the depth of residuals application is less than
one foot;
k. If the application exceeds agronomic rates; or
l. If the land application sites are located within a WS-I watershed pursuant to 15A NCAC 02B .0212
or within the Critical Area of a WS-II pursuant to Sub-Item (4)(g) of Rule 15A NCAC 02B .0212,
or within the Critical Area of a WS-III or WS-IV watershed pursuant to Sub-Item (4)(h) of Rules
15A NCAC 02B .0215, and .0216.
[15A NCAC 02T .1109(a)(1), 02T .1109(b)]
9. The Permittee shall notify all third-party entities receiving bulk Class A residuals that land application
activities occurring on the third-
.1108(b) and 02T .1109(a)(1) (i.e., Conditions II.7.a. and III.8., respectively). [15A NCAC 02T
.1103(a)(4), 02T .1103(a)(5)]
10. Bagged or other container Class A residuals shall have an affixed label or an information sheet provided
to the person receiving theClass A residuals. The label or information sheet shall contain the following:
a. The name and address of the person who prepared the residuals;
b. A statement that residual land application is prohibited except in accordance with the instructions
on the label or information sheet;
c. A statement that the residuals shall be applied at agronomic rates and recommended rates for its
intended use.
[15A NCAC 02T .1109(c)]
11. The Permittee shall not distribute bulk Class A residuals to any person or entity known to be applying
residuals contrary to the conditions of this permit. The Permittee shall report to the Winston-Salem
Regional Office any person or entity known to be applying residuals contrary to the conditions of this
permit. [15A NCAC 02T .0108(b)(1)(A)]
WQ0041666 Version 1.0 Shell Version 200201 Page 6 of 10
IV. MONITORING AND REPORTING REQUIREMENTS
1. The Permittee shall conduct and report any Division required monitoring necessary to evaluate this
[15A NCAC 02T .0108(c)]
2. The residuals from each source generating facility shall be analyzed to demonstrate they are non-
hazardous under the Resource Conservation and Recovery Act (RCRA). Residuals that test or are
classified as a hazardous or toxic waste under 40 CFR Part 261 shall not be land applied. The analyses
(i.e., corrosivity, ignitability, reactivity, and toxicity characteristic leaching procedure (TCLP)) shall be
performed at the frequency specified in Attachment A, and the Permittee shall maintain these results
for five years. Any exemptions from the requirements in this condition shall be specified in Attachment
A.The TCLP analysis shall include the following parameters, and the Federal regulatory level (mg/L)
is in parentheses:
Arsenic (5.0) 1,4-Dichlorobenzene (7.5) Nitrobenzene (2.0)
Barium (100.0) 1,2-Dichloroethane (0.5) Pentachlorophenol (100.0)
Benzene (0.5) 1,1-Dichloroethylene (0.7) Pyridine (5.0)
Cadmium (1.0) 2,4-Dinitrotoluene (0.13) Selenium (1.0)
Carbon tetrachloride (0.5) Endrin (0.02) Silver (5.0)
Chlordane (0.03)Heptachlor (and its epoxide)
(0.008)Tetrachloroethylene (0.7)
Chlorobenzene (100.0) Hexachlorobenzene (0.13) Toxaphene (0.5)
Chloroform (6.0) Hexachlorobutadiene (0.5) Trichloroethylene (0.5)
Chromium (5.0) Hexachloroethane (3.0) 2,4,5-Trichlorophenol (400.0)
m-Cresol (200.0) Lead (5.0) 2,4,6-Trichlorophenol (2.0)
o-Cresol (200.0) Lindane (0.4) 2,4,5-TP (Silvex) (1.0)
p-Cresol (200.0) Mercury (0.2) Vinyl chloride (0.2)
Cresol (200.0) Methoxychlor (10.0)
2,4-D (10.0) Methyl ethyl ketone (200.0)
Once the residuals have been monitored for two years at the frequency specified in Attachment A, the
Permittee may submit a permit modification request to reduce the frequency of this monitoring
requirement. In no case shall the monitoring frequency be less than once per permit cycle.
[15A NCAC 13A .0102(b), 02T .1101, 02T .1105]
WQ0041666 Version 1.0 Shell Version 200201 Page 7 of 10
3. The residuals from each source generating facility shall be analyzed at the frequency specified in
Attachment A, and the Permittee shall maintain the results for a minimum of five years. Each analysis
shall include the following parameters:
Aluminum Mercury Potassium
Ammonia-Nitrogen Molybdenum Selenium
Arsenic Nickel Sodium
Cadmium Nitrate-Nitrite Nitrogen
Sodium Adsorption Ratio
(SAR)
Calcium Percent Total Solids TKN
Copper pH Zinc
Lead Phosphorus
Magnesium Plant Available Nitrogen
(by calculation)
[15A NCAC 02T .1101]
4. Residuals shall be monitored for compliance with pathogen and vector attraction reduction
requirements at the frequency specified in Attachment A. The monitoring results shall specify the
stabilization process utilized, and demonstrate compliance with the Class A pathogen reduction
requirements in 15A NCAC 02T .1106(a), and one vector attraction reduction requirement in 15A
NCAC 02T .1107(a) shall be met. Any exemptions from the requirements in this condition shall be
specified in Attachment A. [15A NCAC 02T .1106(a), 02T .1107(a), 02T .1111(c)]
5. Representative samples of residuals that are prepared for distribution shall be collected and analyzed.
[15A NCAC 02T .1111(a)]
6. The Permittee shall maintain records for all bulk Class A residual distribution events. These records
shall include the following:
a. Residuals source (as listed in Attachment A);
b. Date of distribution;
c. Name and address of residuals recipient;
d. Volume of residuals distributed to each recipient; and
e. Intended use of residuals.
[15A NCAC 02T .0108(c)]
7. One hard copy and one electronic copy of an annual report shall be submitted on or before March 1
st.
The annual report shall meet the requirements described in the Instructions for Residuals Application
Annual Reporting Forms. Instructions for reporting and annual report forms are available at
http://deq.nc.gov/about/divisions/water-resources/water-resources-permits/wastewater-branch/non-
discharge-permitting-unit/reporting-forms, or can be obtained by contacting the Non-Discharge Branch
directly. The annual report shall be submitted to the following address:
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
[15A NCAC 02T .1111(d)]
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8.Noncompliance Notification
The Permittee shall report to the Winston-Salem Regional Office, telephone number [phone],
within 24 hours of first knowledge of the:
a. Any process unit failure (e.g., mechanical, electrical, etc.) rendering the facility incapable of
adequate residual treatment.
b. Any failure resulting in a discharge to surface waters.
c. Any time self-monitoring indicates the program has gone out of compliance with its permit
limitations.
d. Distribution of residuals abnormal in quantity or characteristic.
e. Any discharge from a vehicle or piping system transporting residuals.
Response personnel at telephone number [phone], [phone], or [phone]. All
noncompliance notifications shall file a written report to the Winston-Salem Regional Office within
five days of first knowledge of the occurrence, and this report shall outline the actions proposed or
taken to ensure the problem does not recur. [15A NCAC 02T .0108(b)(1)(A)]
V. INSPECTIONS
1. The Permittee shall perform inspections and maintenance to ensure proper operation of the
storage and distribution facilities. [15A NCAC 02T .1110(f)]
2. The Permittee shall inspect the residuals processing, storage, and transport facilities to
prevent malfunctions, facility deterioration, and operator errors that may result in discharges of wastes
to the environment, threats to human health, or public nuisances. The Permittee shall maintain an
inspection log that includes the date and time of inspection, observations made, and maintenance,
repairs, or corrective actions taken. The Permittee shall maintain this inspection log for a period of five
years from the date of inspection, and this log shall be made available to the Division upon request.
[15A NCAC 02T .0108(b)(1)(A), 02T .1110(f)]
3. Division authorized representatives may, upon presentation of credentials, enter and inspect any
property, premises, or place related to the distribution sites or facilities permitted herein at any
reasonable time for determining compliance with this permit. Division authorized representatives may
inspect or copy records maintained under the terms and conditions of this permit, and may collect
groundwater, surface water, or leachate samples. [G.S. 143-215.3(a)(2)]
WQ0041666 Version 1.0 Shell Version 200201 Page 9 of 10
VI. GENERAL CONDITIONS
1. Failure to comply with the conditions and limitations contained herein may subject the Permittee to a
Division enforcement action. [G.S. 143-215.6A, 143-215.6B, 143-215.6C]
2. This permit is effective only with respect to the nature and volume of wastes described in the permit
application, and Division-approved plans and specifications. [G.S. 143-215.1(d)]
3. Unless specifically requested and approved in this permit, there are no variances to administrative codes
or general statutes governing the construction or operation of the facilities permitted herein. [15A
NCAC 02T .0105(n)]
4. The issuance of this permit does not exempt the Permittee from complying with all statutes, rules,
regulations, or ordinances that other jurisdictional government agencies (e.g., local, state, and federal)
may require. [15A NCAC 02T .0105(c)(6)]
5. If the permitted residuals program change ownership, or the Permittee changes their name, the
Permittee shall submit a permit modification request on Division-approved forms. The Permittee shall
comply with all terms and conditions of this permit until the permit is transferred to the successor-
owner. [G.S. 143-215.1(d3)]
6. This permit is subject to revocation or modification upon 60-day notice from the Division Director, in
whole or part for:
a. violation of any terms or conditions of this permit or Administrative Code Title 15A Subchapter
02T;
b. obtaining a permit by misrepresentation or failure to disclose all relevant facts;
c.
i.
to be kept;
ii. to have access to any permit required documents and records;
iii. to inspect any monitoring equipment or method as required in this permit; or
iv. to sample any pollutants;
d.
e. a Division determination that the conditions of this permit are in conflict with North Carolina
Administrative Code or General Statutes.
[15A NCAC 02T .0110]
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7. Unless the Division Director grants a variance, expansion of the facilities permitted herein shall not
occur if any of the following apply:
a. The Permittee or any parent, subsidiary, or other affiliate of the Permittee has been convicted of
environmental crimes under G.S. 143-215.6B, or under Federal law that would otherwise be
prosecuted under G.S. 143-215.6B, and all appeals of this conviction have been abandoned or
exhausted.
b. The Permittee or any parent, subsidiary, or other affiliate of the Permittee has previously abandoned
a wastewater treatment facility without properly closing the facility.
c. The Permittee or any parent, subsidiary, or other affiliate of the Permittee has not paid a civil
penalty, and all appeals of this penalty have been abandoned or exhausted.
d. The Permittee or any parent, subsidiary, or other affiliate of the Permittee is currently not compliant
with any compliance schedule in a permit, settlement agreement, or order.
e. The Permittee or any parent, subsidiary, or other affiliate of the Permittee has not paid an annual
fee.
[15A NCAC 02T .0120(b), 02T .0120(d)]
8. This permit shall not be renewed if the Permittee or any affiliation has not paid the required annual fee.
[15A NCAC 02T .0120(c)]
Permit issued this the 16th day of July 2020
NORTH CAROLINA ENVIRONMENTAL MANAGEMENT COMMISSION
____________________________________________
S. Daniel Smith, Director
Division of Water Resources
By Authority of the Environmental Management Commission
Permit Number WQ0041666
March 25, 2021
ERIK BLANKENSHIP PRESIDENT
EMA RESOURCES, INC.
755 YADKINVILLE ROAD
MOCKSVILLE, NORTH CAROLINA 27028
Subject: Permit No. WQ0041666
EMA Resources DCAR
Attachment A Certification
Davie County
Dear Mr. Blankenship:
In accordance with your permit major modification request received February 25, 2021, we are
forwarding herewith a modified Attachment A certified March 25, 2021, to EMA Resources, Inc. for the
subject residuals management program.
Modifications to the subject Attachment are as follows: Addition of the John J. Kime WTP (Permit
No. NC0087866) as a residuals source, with an approved dry tonnage of 1,035 dry tons/yr (DT/yr).
The modified Attachment A shall be effective from the date of certification until January 1,
2027 (i.e., expiration date of the current permit), shall void Attachment A of Permit No. WQ0041666
issued July 16, 2020, and shall be subject to the conditions and limitations as specified therein, as well as
those specified in the above-referenced permit. Please replace Attachment A of Permit No. WQ0041666
that was issued July 16, 2020 with the modified Attachment A. Please note that the Permittee shall
submit a renewal application no later than August 4, 2026.
If any parts, requirements or limitations contained in this certification are unacceptable, the
Permittee has the right to request an adjudicatory hearing upon written request within 30 days following
receipt of this permit. This request shall be in the form of a written petition, conforming to Chapter 150B
of the North Carolina General Statutes, and filed with the Office of Administrative Hearings at 6714 Mail
Service Center, Raleigh, NC 27699-6714. Otherwise, this certification shall be final and binding.
If you need any additional information concerning this matter, please contact Erick Saunders at
[phone] or [e-mail].
Sincerely,
S. Daniel Smith, Director
Division of Water Resources
cc: Davie County Health Department (Electronic Copy)
Randolph County Health Department (Electronic Copy)
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State of North Carolina
Department of Environmental Quality
Division of Water Resources
15A NCAC 02T .1100 – DISTRIBUTION OF CLASS A RESIDUALS
FORM: DCAR 06-16
FORM: DCAR 06-16 Page 1 of 3
I. APPLICANT INFORMATION:
1. Applicant's name: EMA Resources Inc.
Applicant type: Individual Corporation General Partnership Privately-Owned Public Utility
Federal State Municipal County
Signature authority’s name per 15A NCAC 02T .0106: Erik Blankenship Title: President
Applicant’s mailing address: 755 Yadkinville Rd
City: Mocksville State: NC Zip: 27028-
Telephone number: [phone] Email Address: [e-mail]
2. Consultant’s name: License Number (for P.E.):
Affiliation: On Staff Retained (Firm: )
Consultant’s mailing address:
City: State: Zip: -
Telephone number: ( ) - Email Address:
3. Fee submitted: $348 (See Instruction B)
II. PERMIT INFORMATION:
1. Application is for (check all that apply):new, modified, renewed permit
2. If this application is being submitted to renew or modify an existing permit, provide the following:
Permit number: WQ0041666
Date of most-recently issued permit: 11/15/2022
Date of most-recently certified Attachment A (if different than the permit): 11/15/2022
III. FACILITY INFORMATION:
1. Name of residuals processing facility: Wade G. Brown WTP
City: Durham State: NC Zip: 27701
Coordinates: Latitude: 36 05 29 Longitude: 78 52 21
Datum:NAD83 Level of accuracy:nearest second
Method of measurement: GPS
County where facility is located: Durham
2. Facility contact (person familiar with residuals preparation):
Name: Tom Lucas Title: WTP ORC
Mailing address: 101 City Hall Plaza
City: Durham State: NC Zip: 27701
Telephone number: [phone] E-mail address: [e-mail]
FORM: DCAR 06-16 Page 2 of 3
3. Is the residual process facility also the generator? Yes; No
If No, please specify delivery frequency and quantity of residual to be processed: ______
4. Length of residuals storage at facility: Source Specific days (Note: the Division requires minimum 30 days storage in units that
are separate from treatment system, i.e. not in clarifiers, aeration basins, etc.)
IV. RESIDUALS QUALITY INFORMATION:
1. Specify how these residuals will be distributed:
sold or given away in bags or other containers; lawn (bulk); home garden (bulk);
other (explain); Residuals will be land applied by EMA Resources Inc. at agronomic rates
Note: Bulk residuals shall mean residuals that are transported and not sold or giving away in a bag or other receptacles with a
load capacity of one metric ton or less.
2.Complete the following if residuals are to be mixed with other materials:
Type of Materials Amounts to be added
per 1.0 dry ton of residuals (dry ton)
3. Approximate amounts of the residuals received and processed at the facility: 2500 dry tons per year.
4. Approximate amounts of the final product (processed residuals) to be distributed: 2500 dry tons per year.
5. Provide a description of the onsite storage management plan for the treated residuals (including estimated average and
maximum storage times prior to distribution): Source Specific
6. Does the facility have a stormwater management plan? Yes; No
Explain whether the treatment and storage areas are under roof or how stormwater runoff will be handled: Source Specific
V. RESIDUALS SOURCE INFORMATION: (Required for all new, renewed, or modified residuals source)
Complete and submit the attached Residuals Source Certification and all associated documentation.
RSC 06-16.doc
FORM: DCAR 06-16 Page 3 of 3
Professional Engineer's Certification: (Application Involving New or Changes to Treatment or Storage Units)
I, , attest that this application for
has been reviewed by me and is accurate and complete to the best of my knowledge. I further attest that to the best of my knowledge
the proposed design has been prepared in accordance with the applicable regulations. Although certain portions of this submittal package
may have been developed by other professionals, inclusion of these materials under my signature and seal signifies that I have reviewed
this material and have judged it to be consistent with the proposed design.
North Carolina Professional Engineer's Seal, Signature, and Date:
Applicant's Certification:
The applicant or any affiliate has not been convicted of an environmental crime, has not abandoned a wastewater facility without proper
closure, does not have an outstanding civil penalty where all appeals have been exhausted or abandoned, are compliant with any active
compliance schedule, and do not have any overdue annual fees under Rule 15A NCAC 02T .0105.
Yes No, Explain;
I, Erik Blankenship President
(Signature Authority’s Name – PLEASE PRINT) (Title)
attest that this application for EMA Resources Inc.
(Facility Name)

has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that the Division of Water Resources
may not conduct a technical review of this program and approval does not constitute a variance to any rules or statutes unless specifically
granted in the permit. Further, any discharge of residuals to surface waters or the land will result in an immediate enforcement action,
which may include civil penalties, injunctive relief, and/or criminal prosecution. I will make no claim against the Division of Water
Resources should a condition of this permit be violated. I also understand that if all required parts of this application are not completed
and that if all required supporting information and attachments are not included, this application package will be returned to me as
incomplete.
Note: In accordance with North Carolina General Statutes §143-215.6A and §143-215.6B, any person who knowingly makes any false
statement, representation, or certification in any application shall be guilty of a Class 2 misdemeanor, which may include a fine not to
exceed $10,000 as well as civil penalties up to $25,000 per violation.

Signature: Date:
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.

State of North Carolina
Department of Environmental Quality
Division of Water Resources
RESIDUALS SOURCE CERTIFICATION
FORM: RSC 06-16
FORM: RSC 06-16 Page 1 of 5
I. RESIDUALS SOURCE-GENERATING FACILITY INFORMATION (See Instruction B.):
1. Facility Name: City of Durham – Brown WTP
2. Facility permit holder is: Federal, State, Local Government, or Private.
Facility permit issued by:Div. of Water Resources, Div. of Environmental Health,
or Other (explain: ).
3. Facility contact person and title: Tom Lucas – WTP ORC
Complete mailing address: 101 City Hall Plaza
City: Durham State: NC Zip: 27701-
Telephone number: [phone] E-mail address: [e-mail]
4. Facility physical address: 7297 Adams Fard Rd
City: Durham State: NC Zip: 27712-
Coordinates: Latitude: 36 05 29 Longitude: 78 52 21
Datum: NAD83 Level of accuracy: nearest second
Method of measurement: MAP
5. Purpose of the facility:
treatment of municipal wastewater,treatment of 100% domestic wastewater,
treatment of potable water,treatment of 100% industrial wastewater,
treatment of industrial wastewater mixed with domestic wastewater,
(approximate percentages: % industrial and % domestic)
other (explain: ).
6. Does the facility have an approved pretreatment program: Yes No
7. Facility permitted/design flow: 30 MGD and facility average daily flow: 27.3 (both WTPs) MGD
8. Average amount of residuals being generated at this facility 2200 dry tons per year.
9. Specify the following regarding treatment and storage volumes available at the facility:
Type and volume of residuals treatment: Water treatment process
Type and volume of residuals storage (i.e., outside of residuals treatment units): Approximately ½ acre covered storage pad
II. RESIDUALS QUALITY INFORMATION (See Instruction C.):
1. Specify if residuals are regulated under:
40 CFR Part 503 or 40 CFR Part 257.
Note: Only residuals that are generated during domestic/municipal wastewater treatment processes are regulated under 40
CFR Part 503, otherwise, the residuals are regulated under 40 CFR Part 257.
2. Specify if residuals are defined under 15A NCAC 02T.1102(6)as:
Biological Non-Biological
FORM: RSC 06-16 Page 2 of 5

Note: Biological residuals are residuals that have been generated during the treatment of domestic wastewater, animal
processing wastewater, or the biological treatment of industrial wastewater (biological treatment is a system that utilizes
biological processes including lagoons, activated sludge systems, extended aeration systems, and fixed film systems).
3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non-hazardous under
RCRA: (Note - this item does not have to be completed for facilities that are less than 0.5 MGD in design flow that treat
100% non-municipal, domestic wastewater only)
a. Are the residuals listed in 40 CFR §261.31-§261.33: yes no.
If yes, list the number(s):
b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21-
261.24: yes no.
Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as well
as those for corrosivity, ignitability, and reactivity:
Laboratory: Pace Analytical and Date of analysis: 1/10/24
Passed corrosivity test: yes no. pH: s.u. (2 < pH < 12.5)
Passed ignitability test:yes no. Flashpoint: >170 oF (> 140oF)
Passed reactivity test: yes no. HCN: 0.478 mg/kg (<250) & H2S: <75 mg/kg (<500)
TCLP Parameter Limit
(mg/l)
Result
(mg/l)
TCLP Parameter Limit
(mg/l)
Result
(mg/l)
Arsenic 5.0 ND Hexachlorobenzene 0.13 ND
Barium 100.0 0.474 Hexachloro-1,3-Butadiene 0.5 ND
Benzene 0.5 ND Hexachloroethane 3.0 ND
Cadmium 1.0 ND Lead 5.0 ND
Carbon Tetrachloride 0.5 ND Lindane 0.4 ND
Chlordane 0.03 ND Mercury 0.2 ND
Chlorobenzene 100.0 ND Methoxychlor 10.0 ND
Chloroform 6.0 ND Methyl Ethyl Ketone 200.0 ND
Chromium 5.0 ND Nitrobenzene 2.0 ND
m-Cresol 200.0 ND Pentachlorophenol 100.0 ND
o-Cresol 200.0 ND Pyridine 5.0 ND
p-Cresol 200.0 ND Selenium 1.0 ND
Cresol 200.0 ND Silver 5.0 ND
2,4-D 10.0 ND Tetrachloroethylene 0.7 ND
1,4-Dichlorobenzene 7.5 ND Toxaphene 0.5 ND
1,2-Dichloroethane 0.5 ND Trichloroethylene 0.5 ND
1,1-Dichloroethylene 0.7 ND 2,4,5-Trichlorophenol 400.0 ND
2,4-Dinitrotoluene 0.13 ND 2,4,6-Trichlorophenol 2.0 ND
Endrin 0.02 ND 2,4,5-TP (Silvex) 1.0 ND
Heptachlor and its Hydroxide 0.008 ND Vinyl Chloride 0.2 ND
FORM: RSC 06-16 Page 3 of 5

4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not violate
the ceiling concentrations for metals regulated under 15A NCAC 02T .1105.
a.For Distribution/Land Application:Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: Waypoint Analytical and Date of analysis: 03/04/2024
Parameter Ceiling
Concentration Limits
(ClassA & ClassB)

(mg/kg)
Monthly Average
Concentration Limits
(Class A Only)

(mg/kg)
Result

(mg/kg)
Arsenic 75 41 6.16
Cadmium 85 39 5.91
Copper 4,300 1,500 216
Lead 840 300 <4.93
Mercury 57 17 <0.112
Molybdenum 75 n/a 6.26
Nickel 420 420 30.1
Selenium 100 100 <8.62
Zinc 7,500 2,800 68
b. For Surface Disposal Unit (landfill): Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: and Date of analysis:
Distance from Disposal
Unit to Boundary to
Closest Property Line
(meters, check one)
Arsenic

(mg/kg)
Chromium

(mg/kg)
Nickel

(mg/kg)
> 0 but < 25 30 200 210
34 220 240
39 260 270
46 300 320
53 360 390
62 450 420
Result (mg/kg)
FORM: RSC 06-16 Page 4 of 5

5.Nutrient/Micronutrient Determination:Complete the following:
a. Total solids: 20.3 %.
b. Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following nutrient and
micronutrient parameters:
Laboratory: Waypoint Analytical and Date of analysis: 03/04/2024
Parameter Result
(mg/kg)
Aluminum 20700
Ammonia-Nitrogen 626
Calcium <956
Magnesium 460
Nitrate-Nitrite Nitrogen 49.1
pH (Standard Unit) 5.2
Phosphorus 1110
Potassium 380
Sodium <320
Total Kjeldahl Nitrogen 7140
c. Using the results listed in Item II. 5b. above, calculate the sodium adsorption ration (SAR): 0.96
[Note: If residuals contain SAR of 10 or higher, the applicant shall obtain recommendations from the local Cooperative
Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, a
North Carolina Licensed Soil Scientist, or an agronomist, prior to land application of residuals. The recommendations shall
address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a mechanism for maintaining site integrity and
conditions conducive to crop growth].
d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: 10 %. This rate
is a (check one): default value, or actually established.
If the residuals are not generated from the treatment of municipal or domestic wastewater, explain or provide technical
justification as to why the selected default value is appropriate to be applied to these residuals:
e. Calculate the PAN for the residuals (i.e., on a dry weight basis) and fill the results in the following table:
Application Method First (1st) Year PAN

(mg/kg)
Five-Year
Maximum Adjusted PAN
(mg/kg)
Surface 1,014 1,404
Injection/Incorporation 1,327 1,717
6. Other Pollutants Determination: Specify whether or not there are any other pollutants of concern in the residuals and provide
the results of the latest analyses:
FORM: RSC 06-16 Page 5 of 5

7. Pathogen Reduction: Per 15A NCAC 02T.1106, specify how residuals will meet the pathogen reduction requirements:
a.For Distribution/Land Application of Class A or Equivalent:
A fecal coliform density that is demonstrated to be less than 1,000 MPN per gram of total dry solids,
or
A salmonella sp.density that is demonstration to be less than 3 MPN per 4 grams of total dry solids.
AND one of the followings (except for non-biological residuals):
Alternative 1 [15A NCAC 02T.1106(b)(3)(A)] - Time/Temperature Compliance.
Alternative 2 [15A NCAC 02T.1106(b)(3)(B)] - Alkaline Treatment.
Alternative 3 [15A NCAC 02T.1106(b)(3)(C)] - Prior Testing for Enteric Virus/Viable Helminth Ova.
Alternative 4 [15A NCAC 02T.1106(b)(3)(D)] - No Prior Testing for Enteric Virus/Viable Helminth Ova.
Alternative 5 [15A NCAC 02T.1106(b)(3)(E)-(K)] - Process to Further Reduce Pathogens (PFRP).
Specify one:composting,heat drying,heat treatment,
thermophilic aerobic digestion, beta ray irradiation,
gamma ray irradiation, or pasteurization.
b. For Land Application of Class B:
Alternative 1 [15A NCAC 02T.1106(c)(1)] - Fecal Coliform Density Demonstration.
Alternative 2 [15A NCAC 02T.1106(c)(2)] - Process to Significantly Reduce Pathogens (PSRP).
Specify one: aerobic digestion, air drying, anaerobic digestion,
composting, or lime stabilization.
c. For Surface Disposal:
Select One of the Class A or Equivalent Pathogen Reduction Alternatives in Item II. 7a. above.
Select One of the Class B or Equivalent Pathogen Reduction Alternatives in Item II. 7b. above.
Exempt - If Daily Cover Alternative is chosen in Item II.8. below [15A NCAC 02T.1106(a)(2)].
Not Applicable - Non-Biological Residuals with NO Domestic Wastewater Contribution.
8. Vector Attraction Reduction (VAR): Per 15A NCAC 02T.1107, specify how residuals will meet the VAR requirements:
Alternative 1 [15A NCAC 02T.1107(a)(1)] - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion).
Alternative 2 [15A NCAC 02T.1107(a)(2)] - 40-Day Bench Scale Test (Anaerobic Digestion).
Alternative 3 [15A NCAC 02T.1107(a)(3)] - 30-Day Bench Scale Test (Aerobic Digestion).
Alternative 4 [15A NCAC 02T.1107(a)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion).
Alternative 5 [15A NCAC 02T.1107(a)(5)] - 14-Day Aerobic Processes.
Alternative 6 [15A NCAC 02T.1107(a)(6)] - Alkaline Stabilization.
Alternative 7 [15A NCAC 02T.1107(a)(7)] - Drying of Stabilized Residuals.
Alternative 8 [15A NCAC 02T.1107(a)(8)] - Drying of Unstabilized Residuals.
Alternative 9 [15A NCAC 02T.1107(a)(9)] - Injection.
Alternative 10 [15A NCAC 02T.1107(a)(10)] - Incorporation.
Alternative for Surface Disposal Units Only - Soil/Other Material Cover [15A NCAC 02T.1107(b)(2)].
Not Applicable - Non-Biological Residuals with NO Domestic Wastewater Contribution.
Note: For animal processing residuals, only alternatives 9 or 10 may be chosen due to the nuisance conditions that typically occur
when these residuals are applied and left on the land surface.
Standard Operating Procedure and Operation
and Maintenance Plan for Brown WTP Residuals –
EMA Resources Inc. Permit
Land Application Program – WQ0041666

1. Purpose
a. Ensure the requirements of EMA Resources Inc. Permit# WQ0041666 are
met.
2. Personnel
a. The following is a list of personnel in order they are to be contacted when
information needs to be shared.
i. EMA Resources Inc.
1. David Ackley – Project Manager – 419-212-3699
2. Brent Collins – Director of Technical Services – 336-399-3646
3. Roy Whitaker – Director or Marketing – 336-909-1718
4. Mike Collins – Director of Operations – 336-399-6670
ii. City of Durham
1. Tom Lucas – WTP ORC – 919-560-4362 x35267
3. Operational Functions
a. The operational function of this project will involve trucking cake residuals
to agronomic sites. It is going to be spread at agronomic rates that are
determined using the Realistic Yield Expectations (RYE) as outlined in the
permit, the amount of other nutrient sources the landowner and operator
has applied, and the residuals nutrient and metal sample that is current for
that monitoring period. It is going to be spread with a cake applicator that
will use an auger and paddles to spread the material in such a way as to
achieve a consistent spread pattern. The material is going to be land
applied on fields that have a crop growing on them that are going to either
be grazed or cut for animal feed. Application rates will be reduced by 25%
on fields that are primarily used for grazing in accordance with USDA-NRCS
590. Grazed fields will be determined by the farmers and EMA project
managers.
4. Maintenance Schedule
a. EMA Resources Inc. will follow the maintenance schedule as recommended
by the EMA Resources Director of Operations (Mike Collins) for the
equipment necessary to complete the job.
5. Safety Measures
a. City of Durham-Brown WTP and EMA Resources Inc. believe in operating in
a safety conscious manner and all employees participate in safety training
that is designed to help employees recognize safety issues and take steps
to prevent accidents from occurring. In addition, EMA Resources employees
have the authority to stop operations if they think any aspect of the
operation is going to cause environmental or personal harm.
6. Spill Response Plan
a. In the unlikely event of a spill, the following action shall be taken
immediately.
i.Management of Spill Clean-up Activities: The EMA Resources
Project Manager shall take immediate charge and initiate clean-up
activities. EMA Resources labor and equipment is to be utilized. In
the event additional labor and equipment is required, assistance may
be requested from the City of Durham, The NC Department of
Transportation, and other private contractors as necessary.
ii.Halt the Source of the Spill: Such as a ruptured container or
damaged transport unit.
iii.Contain the Spill: Form a barrier. Sufficient quantities of straw shall
be used for such purposes. Earthen barriers may be constructed to
augment the straw bale containment area of the spill. The
Operations Manager or the person in charge on the spill site will
advise the clean-up personnel where to get the straw, lime, and other
items necessary to complete the clean-up operation. ie. local farmers,
farm supply centers, nurseries.
iv.Initial Clean-Up: Employ front-end loaders, vacuum equipment,
sludge application vehicles, and/or local septic tank service to
remove as much of the spilled material as possible. Straw and/or
sand should be scattered in the spill area to soak up the remaining
material. The straw and sand soaked material will be collected and
removed to a disposal area approved by representatives of the state
regulatory agency.
v.Final Clean-Up: Employ rotary brush sweeper if needed and apply
lime to the spill area upon the approval of the clean-up efforts by the
state regulatory representative. If the event occurs on private
property, the clean-up will be completed to the satisfactory of the
property owner and state regulatory representatives. The ultimate
goal will be restore the spill area to its original condition if possible.
vi.Notification: As soon as possible after the spill occurs, the EMA
Resources Project Manager or designee will notify the City of Durham
and the EMA Resources main office. EMA Resources office staff are
then responsible for notifying other key EMA Resources personnel.
vii.Reporting: EMA Resources staff will notify the Raleigh Regional
office of NCDENR by telephone [phone] as soon as possible,
but not more than 24 hours after, or on the next working day
following the occurrence. The EMA Project Manager shall provide a
written report within 48 hours of the spill to the EMA Resources
Director of Technical Services and City of Durham staff. The report
shall list all relative information and actions taken. With the
assistance of EMA Resources personnel, and City of Durham
personnel, a written report will be filed with the Raleigh Regional
office within 5 days of the occurrence. For after-hours reporting, the
Division’s emergency number shall be called to report all incidences
[phone].
7. Inspection Plan
a. Inspection for the land application of residuals will be conducted on a
minimum of a weekly basis at the land application site during land
application activities. The inspection frequency is based on the time frame
that it is going to take to complete the project and the amount of dry tons
to be land applied from this facility. The inspections will consist of
inspecting a current field that is being applied as well as inspecting random
fields that have been completed. Inspections will be conducted by David
Ackley – Project Manager. These inspections will consist of the following:
i. Verifying the application rates for each field that plan on receiving
material.
ii. Checking the calculated loads to ensure the correct amount of
residuals are being land applied.
iii. Ensure that all manned equipment has a copy of the permit and the
operation and maintenance plan.
iv. Ensure that the field has been flagged properly and that all buffers
are being adhered to.
v. Verify that the proper number of samples of the residuals have been
taken and that it meets the criteria for land application.
vi. The records will be kept in the EMA Resources project files in the
main office.
vii. EMA Resources and City of Durham staff will immediately inform the
other party if any of the following conditions are noted.
1. Any occurrence with the distribution program resulting in the
land application of significant amounts of material that is
abnormal in quantity or characteristics.
2. Any failure of the distribution system that results in the release
to surface waters.
3. Any time that self-monitoring indicates that the facility has
gone out of compliance with the permit.
4. Any process failure that results in the system not adequately
treating the residuals.
5. Any spill or discharge from a vehicle or piping system during
residuals transportation.
6. Any release that requires immediate reporting outside normal
business hours shall be called in by EMA Resources staff to
DENR at [phone]. This number is to be called in the
event of a release to surface waters or imminent failure of a
storage system when the event occurs outside of normal
business hours.
8. Sampling and Monitoring Plan
a. Sampling for this project consists of sampling the residuals prior to land
application occurring in order to ensure that the residuals are suitable for
land application.
b. The samples will be collected from the storage pad that holds the residuals
c. David Ackley, Brent Collins, Roy Whitaker or other designee will be
responsible for sample collection for nutrient and metal, TCLP, and soil
samples.
d. Nutrient, metal and TCLP sample aliquots will be collected randomly and
consist of at least 7 individual aliquots mixed together in order to get the
composite sample for these parameters.
e. The residuals will be sampled annually for TCLP including the RCIIs.
f. Metal and nutrient parameters will be collected and analyzed based on the
requested dry ton numbers in the permit application.
9. Environmental Impacts
a. The environmental impacts for residuals may be affected by this procedure.
b. This procedure helps assure that land application is conducted in a safe and
efficient manner while ensuring compliance with the laws and regulations
and to minimize exposure, negative environmental impacts and public
relation concerns.
Sources: Esri, HERE, Garmin, USGS, Intermap, INCREMENT P, NRCan,
Esri Japan, METI, Esri China (Hong Kong), Esri Korea, Esri (Thailand),
NGCC, (c) OpenStreetMap contributors, and the GIS User Community
City of Durham - WTP
EMA Resources Inc.1
WQ0041666
BC
SCALE:
PROJECT NO:
DATE:
DRAWN BY:
FIGURE NO.
12-19-21
1 " = 0.5 miles
±
Property Boundary
World Street Map
Source: Esri, Maxar, GeoEye, Earthstar Geographics, CNES/Airbus DS,
USDA, USGS, AeroGRID, IGN, and the GIS User Community
City of Durham - WTP
EMA Resources Inc.1
WQ0041666
BC
SCALE:
PROJECT NO:
DATE:
DRAWN BY:
FIGURE NO.
12-19-21
1 " = 660 feet
±
Property Boundary

Program Information

1. Provide a narrative explaining the following:
a. How will the materials be handled and transported from where the residuals were
produced to where it will be treated?

The residuals are produced through non-biological water treatment processes at the
Brown WTP. See process flow. Liquid material from the Williams WTP is trucked to the
Brown WTP and comingled before being pressed using their belt filter press. Once the
residuals have been dewatered, they will be stored at the on-site pad. When the residuals
are ready to be land applied, they will be taken to agricultural sites by EMA Resources
and land applied at agronomic rates.

b. How will the residuals be processed/treated?

See Process flow diagram and narrative.

c. Where will the residuals be stored until processing?

The residuals will be stored at their approximately ½ acre covered cake storage pad.

d. How will the final product be distributed?

The residuals will be delivered to local farmers via end dump trailers. Each load will be
off-loaded to a high flotation applicator for application on a receiver site (grassland or
row crop).

Brown WTP Marketability Statement

Residuals will be given to local farmers for crop production. EMA Resources Inc. will land apply the
material for the local farmers who have chosen to receive the product. Cake spreaders will be utilized
to spread the material in a consistent and even manner. The material will be applied to fields that have
a cover crop growing, either grass for hay production, pasture, or row crops. Agronomic rates will be
determined using the Realistic Yield Website through NC State.

EMA Resources Inc.
Land Application Permit WQ0041666
Label for Land Application
The residuals that are land applied are produced at the Brown WTP at: 1615 Infinity Road, Durham, NC
27712. Mr. Tom Lucas, Brown Water Treatment ORC is the preparer of the residuals and responsible for
the plant operations.
The residuals from the Brown WTP will be land applied at agronomic rates based on the Realistic Yield
Expectation rate for the fields and crops to be grown. The WTP residuals will not be applied to frozen,
snow covered or flooded fields. The fields will be flagged with the following buffers to help prevent
runoff from the applied fields.
Cake Residuals
Each private or public water supply source:
100
Surface waters such as intermittent and perennial streams, perennial
waterbodies, and wetlands:

25
Surface water diversions such as ephemeral streams, waterways, and
ditches:

0
Groundwater lowering ditches where the bottom of the ditch intersects
the SHWT:

0
Each well with exception of monitoring wells:
100
Bedrock outcrops:
0
Residuals produced by the Brown WTP will be applied to agricultural fields in bulk and will be land
applied according to this label as well as following all permit conditions listed in the land application
permit WQ0041666.
Adequate procedures will be followed to prevent surface runoff from carrying any disposed or stored
residuals into any surface waters.
BROWN WTP RESIDUALS FLOW PROCESS SCHEMATIC 2021 Cake Storage Shed
Ir
to
f
Backwash Clarifiers Thickened Solids Belt Press Gravity Thickeners
Holding Tanks I Dewatering
t zi
Backwash
Eq Tanks
Settled
Solids Tanks

BROWN WTP RESIDUALS FLOW PROCESS SCHEMATIC 2021
Backwash from Backwash Backwash Clarified Water goes
Filters ► Equalization ► Clarifiers back to Terminal
Basins Reservoir
ty
Lea
�t
y�o
Sludge from Thickened Thickened
Settled Solids Gravity
Sedimentation Basins ------- 0. Thickeners ► Solids Holding Sludge from
Basins Tanks Williams
Belt Press
Dewatering
Filtrate goes to
Sanitary Sewer ~
Filtrate goes to
Filtrate EQ
Tanks
Pressed Cake
goes to the
Cake Storage
Shed
Cake is either
► Land Applied or
Landfilled

Quantitative Justification for Residuals Production Rate
Facility:
City of Durham – Brown WTP
Requested Permitted Rate:
2500 dry tons/year
Justification:
We are requesting a permitted dry tonnage rate of 2500 dry tons of water plant
residuals. This number is based on past data and an expected increase in their
production. In 2023, EMA Resources land applied 2,247 which was higher than our
currently permitted amount. This number includes the contributions from the Williams
WTP material that is comingled and pressed at the Brown WTP.
Waypoint,
ANALYTICAL
3/20/2024
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 24-066-0042
Client Project Description: Brown WTP
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanafytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 3/6/2024 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—' symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
r
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 10

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2025
Arkansas
State Program
88-0650
02/07/2025
California
State Program
2904
06/30/2024
Florida
State Program
- NELAP
E871157
06/30/2024
Georgia
State Program
C044
11/14/2025
Georgia
State Program
04015
06/30/2024
Illinois
State Program
- NELAP
200078
10/31/2024
Kentucky
State Program
80215
06/30/2024
Kentucky
State Program
KY90047
12/31/2024
Louisiana
State Program
- NELAP
LA037
12/31/2024
Louisiana
State Program
- NELAP
04015
06/30/2024
Mississippi
State Program
MS
11/14/2025
North Carolina
State Program
47701
07/31/2024
North Carolina
State Program
415
12/31/2024
Pennsylvania
State Program
- NELAP
68-03195
05/31/2024
South Carolina
State Program
84002
06/30/2024
Tennessee
State Program
02027
11/14/2025
Texas
State Program
- NELAP
T104704180
09/30/2024
Virginia
State Program
00106
06/30/2024
Virginia
State Program
- NELAP
460181
09/14/2024
Page 1 of 1 00001/24-066-0042
Page 2 of 10

Waypoint 27(2) 90 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 24-066-0042
Client Project Description: Brown WTP
Lab No Client Sample ID Matrix Date Collected
85737 Brown WTP Solids 03/04/2024 12:15
Date Received
03/06/2024
Page 3 of 10

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Brown WTP
Lab Report Number: 24-066-0042
Date: 3/20/2024
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Block Digestion and FIA Method 4500NORGD-2011
Analyte: Total Kjeldahl Nitrogen
QC Batch No: 1-737601 /L737301
Matrix spike recovery outside of control limits. Acceptable LCS recovery indicates the system was in control, but
the reported result could be affected by matrix interference.
Metals Analysis Method 6010D
Sample 85735 (North Durham)
Analyte: Aluminum
QC Batch No: 1-737815/1-737486
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 85737 (Brown WTP)
Analyte: Aluminum
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Arsenic
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Calcium
QC Batch No: 1-737815/1-737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Cadmium
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Chromium
QC Batch No: 1-737815/1-737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Copper
QC Batch No: 1-737815/1-737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85735 (North Durham)
Analyte: Iron
Page 4 of 10

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
QC Batch No: L737815/L737486
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 85737 (Brown WTP)
Analyte: Iron
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Potassium
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85735 (North Durham)
Analyte: Potassium
QC Batch No: L737956/L737486
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 85737 (Brown WTP)
Analyte: Magnesium
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Manganese
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Molybdenum
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Sodium
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Nickel
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85735 (North Durham)
Analyte: Phosphorus
QC Batch No: L737815/L737486
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 85737 (Brown WTP)
Page 5 of 10

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 1 Fax [phone]
www.waypointanalytical.com
Analyte: Phosphorus
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Lead
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Sulfur
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Selenium
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Sample 85737 (Brown WTP)
Analyte: Zinc
QC Batch No: L737815/L737486
This analyte was analyzed at a dilution due to IEC interference/matrix interference.
Page 6 of 10

Waypointo
ANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
Project Brown WTP
Information :
2790 Whitten Road, Memphis, TN 38133
Main 901,213,2400 0 Fax [phone]
www.waypointanalytical.com
Report Date : 03/20/2024
nnReceived : 03/06/2024
(-
Connie Cook
Report Number : 24-066-0042
REPOR T OF A NA L YSIS
Project
Manager
Lab No : 85737
Matrix:
Solids
Sample ID : Brown WTP
Sampled:
3/4/2024
12:15
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
79.7
%
0.010
0.010
1
03/07/2414:10
CAH
SW-DRYWT
Ammonia Nitrogen
626
mg/Kg - dry
78.8
493
1
03/19/24 15:40
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
49.1
mg/Kg - dry
23.9
25.3
1
03/18/24 11:05
JRZ
4500NO3F-2016
Organic N
6500
mg/Kg - dry
936
1760
1
03/08/24 13:26
CALCULATION
pH
5.2
s.u.
1
03/08/2416:00
CNB
9045D
Total Solids
20.3
%
0.010
0.010
1
03/07/24 14:10
CAH
254OG-2011
Total Kjeldahl Nitrogen
7140
mg/Kg - dry
1760
1
03/08/24 13:26
ANH 4500NORGD-2011
Phosphorus
1110
mg/Kg - dry
69.0
123
5
03/11/24 12:39
BKN
6010D
Aluminum
20700
mg/Kg - dry
115
123
5
03/11/24 12:39
BKN
6010D
Arsenic
6.16 J
mg/Kg - dry
6.16
12.3
5
03/11/24 12:39
BKN
6010D
Cadmium
5.91
mg/Kg - dry
1.23
2.46
5
03/11/24 12:39
BKN
6010D
Calcium
<956
mg/Kg - dry
956
1230
5
03/11/24 12:39
BKN
6010D
Chromium
21.0
mg/Kg - dry
6.16
6.16
5
03/11/24 12:39
BKN
6010D
Copper
216
mg/Kg - dry
7.39
12.3
5
03/11/24 12:39
BKN
6010D
Iron
345000
mg/Kg - dry
421
493
10
03/11/24 12:23
BKN
6010D
Lead
<4.93
mg/Kg - dry
4.93
7.39
5
03/11/24 12:39
BKN
6010D
Magnesium
460
mg/Kg - dry
64.0
123
5
03/11/24 12:39
BKN
6010D
Manganese
2630
mg/Kg - dry
8.62
12.3
5
03/11/24 12:39
BKN
6010D
Mercury
<0.112
mg/Kg - dry
0.112
0.931
1
03/13/24 12:32
FDS
7471A
Molybdenum
6.26
mg/Kg - dry
3.69
6.16
5
03/11/24 12:39
BKN
6010D
Nickel
30.1
mg/Kg - dry
3.69
6.16
5
03/11/24 12:39
BKN
6010D
Potassium
380
mg/Kg - dry
153
246
5
03/11/24 12:39
BKN
6010D
Selenium
<8.62
mg/Kg - dry
8.62
12.3
5
03/11/24 12:39
BKN
6010D
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 7 of 10

Waypointo
ANALYTICAL
46245
EMA Resources Inc Project Brown WTP
Mr. Brent Collins
755 Yadkinville Rd Information
Mocksville , NC 27028
Report Number : 24-066-0042
Lab No : 85737
Sample ID : Brown WTP
Test
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
REPORT OFANAL YSIS
Results Units MDL
Report Date : 03/20/2024
Received : 03/06/2024
C- Ce�
Connie Cook
Project Manager
Matrix: Solids
Sampled: 3/4/ 2024 12.15
MQL DF Date / Time By Analytical
Analyzed Method
Sodium
<320
mg/Kg - dry
320
616
5
03/11/24 12:39 BKN
6010D
Zinc
68.0
mg/Kg - dry
20.9
30.8
5
03/11/24 12:39 BKN
6010D
Sulfur
3870
mg/Kg - dry
128
246
5
03/11/24 12:39 BKN
6010D
Sodium Absorption Ratio
<0.01
Ratio
0.01
0.01
5
03/11/24 12:39
CALCULATION
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
J Estimated value
Page 8 of 10

•
WayPAo�nt,.(2) 2790 n 901.2 Road, Memphis, TN 39133
21.2440
Main 9D1.213.2401] * Fax [phone]
NALYTICAL www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 24-066-0042
Shipping Method
Fed Ex 0 US Postal 0 Lab 0 Other: I
0 UPS 0 Client 0 Courier Thermometer ID: IT137
Shipping container/cooler uncompromised? 0 Yes 0 No
Number of coolers/boxes received I '
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample label(s)?
Yes
0 No
COC properly completed
Yes
0 No
Samples in proper containers?
Yes
0 No
Sample containers intact?
Yes
0 No
Sufficient sample volume for indicated test(s)?
Yes
0 No
All samples received within holding time?
Yes
0 No
Cooler temperature in compliance?
Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Yes
0 No
Samples were considered acceptable as cooling
process had begun.
Water - Sample containers properly preserved
0 Yes
0 No
0 N/A
Water - VOA vials free of headspace
0 Yes
0 No
0 N/A
Trip Blanks received with VOAs
0 Yes
0 No
0 N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
N/A
F_ High concentration container (48 hr)
F_ Low concentration Encore samplers (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low conc pre -weighed
vials (Sod Bis -14 d)
Special precautions or instructions included?
0 Yes
No
Comments:
Signature: ICarleen Qualls Date & Time: 103/06/2024 10:00:41
Page 9 of 10

Client Name/Address
EMA Resources Inc
755 Yadkinvilte Rd
Mocksville, NC 27028
Project Description
Project Number
Client Project Manager/Contact
Brent Collins
ProjeWSite Location (City/State)
Sc,ow^ w rP
Project Manager Phone ft
336-399-3646
Billing Information
Account #46245
HRUSH —Additional charges apply
Special Detection Limits)
Date Results Needed
Project Manager Email
t)[e-mail]
For Laboratory Use Only
Met of Shi ment
Fed Ex ups �us?s
Courier Client Drop Off
Other
Purchase Order Number
&cal-i^ w rP
'm
z
V)
d
o
U
Waypoint
a
_
ANALYTICAL
c
F'
CD
-
2790 Whitten Road
`�
°��'
rn
Q
D
Ll"'
SSemphis, 7'N 38133 Unless noted, all containers
(901) 213•2400 per Table II of 40 CFR Part
x
m
2
I0
Q
r y
Lj
136.
Date Time Sample Identification
E
z
Re
uired Analti$is / Preservative
3J� 17:! 5 brown lAI TP
I
���
C
✓
I/
►�
✓
✓
1:2 J
11t11111111111111111111111111111El I D1111111I1111111I11 It fl�2024� _
LMA Resc+urces Inc 10 00--23
Grown WTP
Matrix Key
WW —Wastewater GW—Groundwater
DW — Drinking Water S—Soil /Solid O — Oil
p - Product M - Misc
Site/Facility ID #
A Cool < 10C Na25203IMicro Only)
8 Cool-6C
C H2504 pH,2
D Nane Required
E NaOH pk�10
F HNO3 pHc2
G HCL PW2
H H3PO4 pHsZ
1 Cool — 6C NAZ5203
Comments/Notes
Meta1s:A1.As, Ca,Cd,Cr,Cu , Fe, Pb
Mn,Mg,Mo, Hg,Nf,Se, Na,P,S, K,Zn
For Lahoratory Use Only Sampled by (Name — Print) Client Remarks/Comments
Ice CLab Comments Seals !I J Sludge Samples - Report Dry Weight
Seals ��
�N
y Relinquished (SIGNATURE Date Time Received by: (SIGNATURE) Date Time
Blan Cooler mp Relinquished by: [SIGNATURE) Date Time Received by: [SIGNATURE) Date Time
Relin uished b ' q y: [SIGNATURE) Date Time rc�ive ySIGNATURE) r2 �Datte�] Ti e
�� I jf LS/ rS �

I
Pace Analytical
ANALYTICAL REPORT
January 24, 2024
EMA Resources
Sample Delivery Group
Samples Received:
Project Number:
Description:
Report To:
L1695669
01/11/2024
Sludge
Mr. Brent Collins
755 Yadkinville Road
Mocksville, NC 27028
Entire Report Reviewed By
zez:9��"
Reagan Johnson
Project Manager
r
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval ofthe laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1695669 01/24/24 09:55 1 of 21

TABLE OF CONTENTS
Cp: Cover Page
Tc: Table of Contents
Ss: Sample Summary
Cn: Case Narrative
Sr: Sample Results
BROWN WTP L1695669-01
Qc: Quality Control Summary
Wet Chemistry by Method 9012 B
Wet Chemistry by Method 9034-9030B
Wet Chemistry by Method 9045D
Wet Chemistry by Method D93/1010A
Mercury by Method 7470A
Metals (ICP) by Method 6010D
Volatile Organic Compounds (GC/MS) by Method 8260D
Chlorinated Acid Herbicides (GC) by Method 8151A
Pesticides (GC) by Method 8081B
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
GI: Glossary of Terms
Al: Accreditations & Locations
Sc: Sample Chain of Custody
1
2
3
4
5
5
7
7
8
9
10
11
12
13
15
16
17
19
20
21
FP1
FSS
FCn]
FSr
FqC
FG1
gAl
9
Sc
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1695669 01/24/24 09:55 2 of 21

SAMPLE SUMMARY
BROWN WTP L1695669-01 Waste
Method
Preparation by Method 1311
Preparation by Method 1311
Wet Chemistry by Method 9012 B
Wet Chemistry by Method 9034-9030B
Wet Chemistry by Method 9045D
Wet Chemistry by Method D93/1010A
Mercury by Method 7470A
Metals (ICP) by Method 6010D
Volatile Organic Compounds (GC/MS) by Method 8260D
Chlorinated Acid Herbicides (GC) by Method 8151A
Pesticides (GC) by Method 8081B
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
Collected by
Brent Collins
Batch
Dilution Preparation
date/time
WG2207860
T1 01/19/2412:41
WG2208021
1 01/17/2413:40
WG2206160
1 01/12/2413:14
WG2205204
1 01/14/24 09:47
WG2206462
1 01/13/24 09:47
WG2208644
1 01/18/2415:15
WG2209772
1 01/20/2410:55
WG2209813
1 01/21/2410:14
WG2208740
1 01/18/2415:11
WG2209661
1 01/21/24 07:50
WG2209670
1 01/21/24 09:44
WG2209666
1 01/21/24 09:43
Collected date/time Received date/time
01/10/2410:00 01/11/24 09:00
Analysis Analyst Location
date/time
01/19/2412:41
BTP
Mt. Juliet, TN
01/17/2413:40
BTP
Mt. Juliet, TN
01/12/2417:08
UNP
Mt. Juliet, TN
01/14/2410:17
DMA
Mt. Juliet, TN
01/13/2411:50
KRB
Mt. Juliet, TN
01/18/2415:15
ARV
Mt. Juliet, TN
01/20/2415:26
AKB
Mt. Juliet, TN
01/21/2413:58
DJS
Mt. Juliet, TN
01/18/2415:11
JCP
Mt. Juliet, TN
01/21/2419:26
AMM
Mt. Juliet, TN
01/21/2417:49
NWH
Mt. Juliet, TN
01/23/2419:27
JRM
Mt. Juliet, TN
FP1
z
Tc
4
Cn
FSr
FqC
FG1
gAl
9
Sc
ACCOUNT: PROJECT: S DG: DATE/TIME:
EMA Resources L1695669 01/24/24 09:55
PAGE:
3 of 21

CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the FP1
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples IT C
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FSS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data.
FSr
� MC
FG
Reagan Johnson Rl
Project Manager
E
Project Narrative
All Reactive Cyanide results reported in the attached report were determined as totals using method 9012 B.
All Reactive Sulfide results reported in the attached report were determined as totals using method 9034-9030B.
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1695669 01/24/24 09:55 4 of 21

BROWN WTP
SAMPLE RESULTS - 01
Collected date/time:
01/10/24 10:00
L1695669
Preparation by Method 1311
Result
Qualifier Prep
Batch
Analyte
date / time
TCLP Extraction
1/19/202412:41:30 PM
WG2207860
TCLP ZHE Extraction
-
1/17/20241:40:13 PM
WG2208021
Initial pH
6.47
1/19/202412:41:30 PM
WG2207860
Final pH
4.97
1/19/202412:41:30 PM
WG2207860
Wet Chemistry by Method 9012 B
Result Qualifier
RDL
Analyte
mg/kg
mg/kg
Reactive Cyanide
0.478 J6
0.250
Wet Chemistry by
Method 9034-9030B
Result Qualifier
RDL
Analyte
mg/kg
mg/kg
Reactive Sulfide
ND
75.0
Wet Chemistry by Method 9045D
Dilution Analysis
date / time
1 01/12/202417:08
Batch
WG2206160
Dilution Analysis Batch
date / time
1 01/14/202410:17 WG2205204
Result Qualifier
Dilution
Analysis
Batch
Analyte su
date / time
Corrosivity by pH 6.06 T8
1
01/13/202411:50
WG2206462
Sample Narrative:
L1695669-01 WG2206462: 6.06 at 20.7C
Wet Chemistry by Method D93/1010A
Result Qualifier
Dilution
Analysis
Batch
Analyte Deg. F
date / time
Ignitability DNIat170
1
01/18/202415:15
WG2208644
Mercury by Method 7470A
Result Qualifier
RDL
Limit
Dilution Analysis
Batch
Analyte mg/I
mg/I
mg/I
date/time
Mercury ND
0.0100
0.20
1 01/20/202415:26
WG2209772
Metals (ICP) by Method 6010D
Result Qualifier
RDL
Limit
Dilution Analysis
Batch
Analyte mg/I
mg/I
mg/I
date/time
Arsenic ND
0.100
5
1 01/21/202413:58
WG2209813
Barium 0.474
0.100
100
1 01/21/202413:58
WG2209813
Cadmium ND
0.100
1
1 01/21/202413:58
WG2209813
Chromium ND
0.100
5
1 01/21/202413:58
WG2209813
Lead ND
0.100
5
1 01/21/202413:58
WG2209813
Selenium ND
0.100
1
1 01/21/202413:58
WG2209813
Silver ND
0.100
5
1 01/21/202413:58
WG2209813
Volatile Organic Compounds (GC/MS) by Method
8260D
Result Qualifier
RDL
Limit
Dilution Analysis
Batch
Analyte mg/I
mg/I
mg/I
date/time
Benzene ND
0.0500
0.50
1 01/18/202415:11
WG2208740
Carbon tetrachloride ND
0.0500
0.50
1 01/18/202415:11
WG2208740
Chlorobenzene ND
0.0500
100
1 01/18/202415:11
WG2208740
Chloroform ND
0.250
6
1 01/18/202415:11
WG2208740
1,2-Dichloroethane ND
0.0500
0.50
1 01/18/202415:11
WG2208740
ACCOUNT:
PROJECT:
5 DG:
DATE/TIME: PAGE:
EMA Resources
L1695669
01/24/24 09:55 5 of 21

BROWN WTP
SAMPLE RESULTS
- 01
Collected date/time: 01/10/24 10:00
L1695669
Volatile Organic Compounds (GC/MS) by Method 8260D
Result
Qualifier RDL
Limit
Dilution
Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
1,1-Dichloroethene
ND
0.0500
0.70
1
01/18/202415:11
WG2208740
2-Butanone (MEK)
ND
0.500
200
1
01/18/202415:11
WG2208740
Tetrachloroethene
ND
0.0500
0.70
1
01/18/202415:11
WG2208740
Trichloroethene
ND
0.0500
0.50
1
01/18/202415:11
WG2208740
Vinyl chloride
ND
0.0500
0.20
1
01/18/202415:11
WG2208740
(S) Toluene-d8
84.4
80.0-120
011181202415:11
WG2208740
(S) 4-Bromofluorobenzene
86.8
77.0-126
011181202415:11
WG2208740
(S)1,2-Dich/oroethane-d4
81.5
70.0-130
011181202415:11
WG2208740
Chlorinated Acid Herbicides (GC) by
Method 8151A
Result
Qualifier RDL
Limit
Dilution
Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
2,4,5-TP (Silvex)
ND
0.00200
1
01/21/202419:26
WG2209661
2,4-D
ND
0.00200
1
01/21/202419:26
WG2209661
(S) 2,4-Dichlorophenyl Acetic Acid
80.0
14.0-158
011211202419:26
WG2209661
Pesticides (GC) by Method 8081B
Result
Qualifier RDL
Limit
Dilution
Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
Chlordane
ND
0.00500
0.03
1
01/21/202417:49
WG2209670
Endrin
ND
0.00500
0.02
1
01/21/202417:49
WG2209670
Heptachlor
ND
0.00500
0.0080
1
01/21/202417:49
WG2209670
Heptachlor epoxide
ND
0.00500
0.0080
1
01/21/202417:49
WG2209670
Lindane
ND
0.00500
0.40
1
01/21/202417:49
WG2209670
Methoxychlor
ND
0.00500
10
1
01/21/202417:49
WG2209670
Toxaphene
ND
0.0100
0.50
1
01/21/202417:49
WG2209670
(S) Decochlorobipheny/
56.7
10.0-128
01/21/202417.49
WG2209670
(S) Tetrochloro-m-xylene
68.6
10.0-127
011211202417.49
WG2209670
Semi Volatile Organic Compounds
(GC/MS) by Method 8270E
Result
Qualifier RDL
Limit
Dilution
Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
1,4-Dichlorobenzene
ND
0.100
7.50
1
01/23/202419:27
WG2209666
2,4-Dinitrotoluene
ND
0.100
0.13
1
01/23/202419:27
WG2209666
Hexachlorobenzene
ND
0.100
0.13
1
01/23/202419:27
WG2209666
Hexachloro-1,3-butadiene
ND
0.100
0.50
1
01/23/202419:27
WG2209666
Hexachloroethane
ND
0.100
3
1
01/23/202419:27
WG2209666
Nitrobenzene
ND
0.100
2
1
01/23/202419:27
WG2209666
Pyridine
ND
0.100
5
1
01/23/202419:27
WG2209666
3&4-Methyl Phenol
ND
0.100
400
1
01/23/202419:27
WG2209666
2-Methylphenol
ND
0.100
200
1
01/23/202419:27
WG2209666
Pentachlorophenol
ND
0.100
100
1
01/23/202419:27
WG2209666
2,4,5-Trichlorophenol
ND
0.100
400
1
01/23/202419:27
WG2209666
2,4,6-Trichlorophenol
ND
0.100
2
1
01/23/202419:27
WG2209666
(S) 2-Fluoropheno/
22.3
10.0-120
01/23/202419:27
WG2209666
(S) Phenol-d5
15.0
10.0-120
011231202419:27
WG2209666
(S) Nitrobenzene-d5
62.0
10.0-127
011231202419:27
WG2209666
(S) 2-Fluorobiphenyl
60.2
10.0-130
011231202419:27
WG2209666
(S)2,4,6-Tribromopheno/
38.4
10.0-155
01/23/202419:27
WG2209666
(S) p-Terphenyl-d14
52.3
10.0-128
011231202419:27
WG2209666
ACCOUNT:
PROJECT:
S DG:
DATE/TIME: PAGE:
EMA Resources
L1695669
01/24/24 09:55 6 of 21

WG2206160
Wet Chemistry by Method 9012 B
Method Blank (MB)
(MB) R4022621-1 01/12/2416:58
MB Result
Analyte mg/kg
Reactive Cyanide U
MB Qualifier MB MDL MB RDL
mg/kg mg/kg
0.0390 0.250
L1695669-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1695669-01 01/12/2417:08 • (DUP) R4022621-3 01/12/2417:09
Original Result DUP Result Dilution DUP RPD
Analyte mg/kg mg/kg %
Reactive Cyanide 0.478 0.475 1 0.699
Laboratory Control Sample (LCS)
QUALITY CONTROL SUMMARY
L1695669-01
DUP Qualifier DUP RPD
Limits
o�
20
(LCS) R4022621-6 01/12/2417:27
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/kg mg/kg % %
Reactive Cyanide 2.50 2.35 94.0 85.0-115
L1695669-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1695669-01 01/12/2417:08 • (MS) R4022621-4 01/12/2417:11 • (MSD) R4022621-5 01/12/2417:15
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
Analyte mg/kg mg/kg mg/kg mg/kg % % % %
Reactive Cyanide 1.67 0.478 1.60 1.59 67.5 66.7 1 75.0-125 J6 J6 0.854
Sample Narrative:
MS: Matrix spike failure due to matrix interference.
MSD: Matrix spike failure due to matrix interference.
RPD Limits
o�
20
Rp
FTC]
FSS
Fn]
Fr
FGI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1695669 01/24/24 09:55 7 of 21

WG2205204
Wet Chemistry by Method 9034-9030B
Method Blank (MB)
(MB) R4023746-1 01/14/2410:17
MB Result MB Qualifier MB MDL
Analyte mg/kg mg/kg
Reactive Sulfide U 30.0
Laboratory Control Sample (LCS)
MB RDL
mg/kg
75.0
QUALITY CONTROL SUMMARY
L1695669-01
(LCS) R4023746-2 01/14/2410:17
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/kg mg/kg % %
Reactive Sulfide 100 99.9 99.9 53.8-124
L1695070-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1695070-04 01/14/2410:17 • (MS) R4023746-3 01/14/2410:17 • (MSD) R4023746-4 01/14/2410:17
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg mg/kg % % % % %
Reactive Sulfide 100 ND ND ND 59.6 67.4 1 10.0-136
0.000
20
Rp
FTc
FSS
Fn]
Fr
FGI
E
FSC
ACCOUNT: PROJECT: SDG:
EMA Resources L1695669
DATE/TIME:
01/24/24 09:55
PAGE:
8of21

WG2206462
Wet Chemistry by Method 9045D
QUALITY CONTROL SUMMARY
L1695669-01
Laboratory Control Sample (LCS)
(LCS) R4022734-1 01/13/2411:50
Spike Amount LCS Result
Analyte su su
Corrosivity by pH 10.0 10.0
Sample Narrative:
LCS:10 at 20C
LCS Rec. Rec. Limits LCS Qualifier
100 99.0-101
Rp
FTC
FSS
Fn]
Fr
FG
FAI
FSC
ACCOUNT:
EMA Resources
PROJECT: SDG: DATE/TIME: PAGE:
L1695669 01/24/24 09:55 9 of 21

WG2208644
Wet Chemistry by Method D93/1010A
L1695669-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1695669-01 01/18/2415:15 • (DUP) R4024024-3 01/18/2415:15
Original Result DUP Result Dilution DUP RPD
Analyte Deg. F Deg. F %
Ignitability DNI at 170 DNI at 170 1 0.000
QUALITY CONTROL SUMMARY
L1695669-01
DUP Qualifier DUP RPD
Limits
10
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R4024024-1 01/18/2415:15 • (LCSD) R4024024-2 01/18/2415:15
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits
Analyte Deg. F Deg. F Deg. F % % %
Ignitability 126 125 125 98.9 98.9 95.6-104
LCS Qualifier LCSD Qualifier RPD RPD Limits
0.000 10
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1695669 01/24/24 09:55 10 of 21

WG2209772
Mercury by Method 7470A
Method Blank (MB)
(MB) R4024606-1 01/20/2415:21
MB Result
Analyte mg/I
Mercury U
MB Qualifier MB MDL MB RDL
mg/I mg/I
0.00330 0.0100
Laboratory Control Sample (LCS)
QUALITY CONTROL SUMMARY
L1695669-01
(LCS) R4024606-2 01/20/2415:24
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/I mg/I % %
Mercury 0.0300 0.0316 105 80.0-120
L1695669-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1695669-01 01/20/2415:26 • (MS) R4024606-3 01/20/2415:29 • (MSD) R4024606-4 01/20/2415:31
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD
Analyte mg/I mg/I mg/I mg/I % % % %
Mercury 0.0300 ND 0.0310 0.0307 103 102 1 75.0-125
RPD Limits
o�
20
Rp
FTc
FSS
Fn]
Fr
FGI
E
FSC
ACCOUNT: PROJECT:
EMA Resources
SDG:
L1695669
DATE/TIME:
01/24/24 09:55
PAGE:
11 of 21

WG2209813
Metals (ICP) by Method 6010D
Method Blank (MB)
(MB) R4024794-1 01/21/2413:40
MB Result MB Qualifier
Analyte
mg/I
Arsenic
U
Barium
U
Cadmium
U
Chromium
U
Lead
U
Selenium
0.0613 J_
Silver
U
Laboratory Control Sample (LCS)
(1-CS) R4024794-2 01/21/2413:43
Spike Amount
LCS Result
Analyte
mg/I
mg/I
Arsenic
10.0
9.99
Barium
10.0
9.48
Cadmium
10.0
9.56
Chromium
10.0
9.30
Lead
10.0
9.36
Selenium
10.0
10.2
Silver
2.00
1.90
MB MDL
mg/I
0.0330
0.0330
0.0330
0.0330
0.0330
0.0330
0.0330
LCS Rec.
99.9
94.8
95.6
93.0
93.6
102
95.1
QUALITY CONTROL SUMMARY
L1695669-01
MB RDL
mg/I
0.100
0.100
0.100
0.100
0.100
0.100
0.100
Rec. Limits
80.0-120
80.0-120
80.0-120
80.0-120
80.0-120
80.0-120
80.0-120
LCS Qualifier
L1695897-15 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1695897-15 01/21/2413:46 • (MS) R4024794-4 01/21/2413:52 • (MSD) R4024794-5 01/21/2413:55
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
Analyte
mg/I
mg/I
mg/I
mg/I
%
%
%
Arsenic
10.0
ND
10.3
10.4
103
104
1 75.0-125
Barium
10.0
0.572
10.3
10.4
96.9
98.1
1 75.0-125
Cadmium
10.0
ND
9.88
10.0
98.8
100
1 75.0-125
Chromium
10.0
ND
9.49
9.68
94.9
96.8
1 75.0-125
Lead
10.0
ND
9.55
9.69
95.5
96.9
1 75.0-125
Selenium
10.0
ND
10.5
10.7
105
107
1 75.0-125
Silver
2.00
ND
1.96
2.00
97.9
100
1 75.0-125
MS Qualifier MSD Qualifier RPD
RPD Limits
0.968
20
1.18
20
1.29
20
1.97
20
1.44
20
1.70
20
2.26
20
Rp
FTC]
FSS
Fn]
Fr
FGI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1695669 01/24/24 09:55 12 of 21

WG2208740 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1695669-01
Method Blank (MB)
(MB) R4024218-3 01/18/2412:22
MB Result
MB Qualifier
MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
Benzene
U
0.0167
0.0500
Carbon tetrachloride
U
0.0167
0.0500
Chlorobenzene
U
0.0167
0.0500
Chloroform
U
0.0833
0.250
1,2-Dichloroethane
U
0.0167
0.0500
1,1-Dichloroethene
U
0.0167
0.0500
2-Butanone (MEK)
U
0.167
0.500
Tetrachloroethene
U
0.0167
0.0500
Trichloroethene
U
0.0167
0.0500
Vinyl chloride
U
0.0167
0.0500
(S) Toluene-d8
88.1
80.0-120
(S) 4-Bromofluorobenzene
83.1
77.0-126
(S)1,2-Dichloroethane-d4
81.8
70.0-130
Laboratory Control
Sample (LCS) • Laboratory
Control
Sample
Duplicate (LCSD)
(LCS) R4024218-1 01/18/2410:30 • (LCSD) R4024218-2
01/18/2410:49
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
LCS Qualifier LCSD Qualifier RPD
RPD Limits
Analyte
mg/I
mg/I
mg/I
%
%
%
%
%
Benzene
0.250
0.263
0.289
105
116
70.0-123
9.42
20
Carbon tetrachloride
0.250
0.235
0.262
94.0
105
68.0-126
10.9
20
Chlorobenzene
0.250
0.265
0.259
106
104
80.0-121
2.29
20
Chloroform
0.250
0.264
0.271
106
108
73.0-120
2.62
20
1,2-Dichloroethane
0.250
0.260
0.264
104
106
70.0-128
1.53
20
1,1-Dichloroethene
0.250
0.229
0.267
91.6
107
71.0-124
15.3
20
2-Butanone (MEK)
1.25
1.36
1.33
109
106
44.0-160
2.23
20
Tetrachloroethene
0.250
0.247
0.240
98.8
96.0
72.0-132
2.87
20
Trichloroethene
0.250
0.228
0.239
91.2
95.6
78.0-124
4.71
20
Vinyl chloride
0.250
0.241
0.253
96.4
101
67.0-131
4.86
20
(S) Toluene-d8
87.8
82.1
80.0-120
(S) 4-Bromofluorobenzene
92.8
82.0
77.0-126
(S)1,2-Dichloroethane-d4
80.1
81.3
70.0-130
Rp
FTc
FSS
Fn]
Fr
FGI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1695669 01/24/24 09:55 13 of 21

WG2208740
QUALITY
CONTROL
SUMMARY
Volatile Organic Compounds (GC/MS)
by Method 8260D
L1695669-01
L1695669-01 Original Sample
(OS) • Matrix
Spike (MS)
• Matrix Spike Duplicate
(MSD)
Rp
(OS) L1695669-01 01/18/2415:11 • (MS) R4024218-4
01/18/2419:16 • (MSD) R4024218-5 01/18/2419:35
Spike Amount
Original Result
MS Result
MSD Result MS Rec.
MSD Rec. Dilution Rec. Limits MS Qualifier
MSD Qualifier RPD
RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
%
%
%
%
%
F
Benzene 0.250
ND
0.312
0.324
125
130 1
17.0-158
3.77
27
Carbon tetrachloride 0.250
ND
0.291
0.301
116
120 1
23.0-159
3.38
28
FSS
Chlorobenzene 0.250
ND
0.299
0.313
120
125 1
33.0-152
4.58
27
Chloroform 0.250
ND
0.326
0.336
130
134 1
29.0-154
3.02
28
1,2-Dichloroethane 0.250
ND
0.309
0.327
124
131 1
29.0-151
5.66
27
Fn]
1,1-Dichloroethene 0.250
ND
0.285
0.214
114
85.6 1
11.0-160
28.5
29
2-Butanone (MEK) 1.25
ND
1.61
1.62
129
130 1
10.0-160
0.619
32
Fr
Tetrachloroethene 0.250
ND
0.264
0.288
106
115 1
10.0-160
8.70
27
Trichloroethene 0.250
ND
0.275
0.283
110
113 1
10.0-160
2.87
25
Vinyl chloride 0.250
ND
0.271
0.290
108
116 1
10.0-160
6.77
27
(S) Toluene-d8
85.0
86.1
80.0-120
(S) 4-Bromofluorobenzene
89.0
89.1
77.0-126
FGI
(S)1,2-Dichloroethane-d4
83.9
84.7
70.0-130
FAI
FSC
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
EMA Resources
L1695669
01/24/24 09:55
14 of 21

WG2209661
Chlorinated Acid Herbicides (GC)
by Method 8151A
Method Blank (MB)
(MB) R4024883-1 01/21/2415:52
MB Result
MB Qualifier MB MDL
Analyte mg/l
mg/l
2,4,5-TP (Silvex) U
0.000667
2,4-D U
0.000667
(S) 2,4-Dich/oropheny/ Acetic 78.4
Acid
Laboratory Control Sample (LCS)
(LCS) R4024883-2 01/21/2416:03
QUALITY CONTROL SUMMARY
L1695669-01
MB RDL
mg/l
0.00200
0.00200
14.0-158
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/l
mg/1
%
%
2,4,5-TP (Silvex) 0.0500
0.0481
96.2
50.0-125
2,4-D 0.0500
0.0467
93.4
50.0-120
(S) 2,4-Dich/oropheny/ Acetic
79.4
14. 0-158
Acid
L1694991-01 Original Sample (OS)
• Matrix
Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1694991-01 01/21/2418:41 • (MS) R4024883-3
01/21/2418:52 • (MSD) R4024883-4 01/21/2419:04
Spike Amount
Original Result
MS Result
MSD Result MS Rec. MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
Analyte mg/l
mg/l
mg/l
mg/l % %
%
%
%
2,4,5-TP (Silvex) 0.0500
ND
0.0501
0.0496 100 99.2
1 50.0-125
E P 1.00
20
2,4-D 0.0500
ND
0.0470
0.0472 94.0 94.4
1 50.0-120
0.425
20
(S) 2,4-Dich/oropheny/ Acetic
69.2 70.2
14.0-158
Acid
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
EMA Resources
L1695669
01/24/24 09:55
15 of 21

WG2209670
QUALITY
CONTROL
SUMMARY
Pesticides (GC) by Method 8081B
L1695669-01
Method Blank (MB)
Rp(MB)
R4024752-1 01/21/2416:38
MB Result
MB Qualifier
MB MDL
MB RDL
Analyte mg/I
mg/I
mg/I
FTC]
Chlordane U
0.00167
0.00500
Endrin U
0.00167
0.00500
FSS
Heptachlor U
0.00167
0.00500
Heptachlor epoxide U
0.00167
0.00500
Lindane U
0.00167
0.00500
Fn]
Methoxychlor U
0.00167
0.00500
Toxaphene U
0.00333
0.0100
Fr
(S) Decachlorobipheny/ 64.9
10.0-128
(S) Tetrochloro-m-xylene 73.0
10.0-127
Laboratory Control Sample (LCS)
FGI
(LCS) R4024752-2 01/21/2416:47
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
FAI
Analyte mg/I
mg/I
%
%
Endrin 0.0100
0.00836
83.6
57.0-134
0.0100
0.00827
82.7
27.0-132
FSCHeptachlor
Heptachlor epoxide 0.0100
0.00774
77.4
57.0-130
Lindane 0.0100
0.00773
77.3
55.0-129
Methoxychlor 0.0100
0.00904
90.4
54.0-155
(S) Decachlorobipheny/
69.5
10.0-128
(S) Tetrochloro-m-xylene
72.2
10.0-127
L1694886-04 Original Sample
(OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1694886-04 01/21/2416:56 • (MS) R4024752-3 01/21/2417:04
• (MSD) R4024752-4 01/21/2417:13
Spike Amount
Original Result
MS Result
MSD Result MS Rec.
MSD Rec. Dilution Rec. Limits MS Qualifier
MSD Qualifier RPD
RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I %
%
%
%
%
Endrin 0.0100
ND
0.00776
0.00880 77.6
88.0 1
10.0-160
12.6
39
Heptachlor 0.0100
ND
0.00750
0.00880 75.0
88.0 1
16.0-136
16.0
40
Heptachlor epoxide 0.0100
ND
0.00734
0.00824 73.4
82.4 1
10.0-160
11.6
36
Lindane 0.0100
ND
0.00741
0.00834 74.1
83.4 1
14.0-141
11.8
40
Methoxychlor 0.0100
ND
0.00789
0.00859 78.9
85.9 1
10.0-160
8.50
34
(S) Decachlorobipheny/
46.7
59.9
10.0-128
(S) Tetrochloro-m-xylene
64.1
76.1
10.0-127
ACCOUNT:
PROJECT:
SDG:
DATE/TIME:
PAGE:
EMA Resources
L1695669
01/24/24 09:55
16 of 21

WG2209666
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
QUALITY CONTROL SUMMARY
L1695669-01
Method Blank (MB)
(MB) R4025523-2 01/23/2414:15
MB Result
Analyte
mg/I
1,4-Dichlorobenzene
U
2,4-Dinitrotoluene
U
Hexachlorobenzene
U
Hexachloro-1,3-butadiene
U
Hexachloroethane
U
Nitrobenzene
U
Pyridine
U
3&4-Methyl Phenol
U
2-Methylphenol
U
Pentachlorophenol
U
2,4,5-Trichlorophenol
U
2,4,6-Trichlorophenol
U
(S) 2-Fluoropheno/
47.6
(S) Phenol-d5
31.1
(S) Nitrobenzene-d5
78.9
(S) 2-Fluorobiphenyl
73.8
(S) 2,4,6-Tribromopheno/
52.5
(S) p-Terphenyl-d14
70.1
MB Qualifier MB MDL
mg/I
0.0333
0.0333
0.0333
0.0333
0.0333
0.0333
0.0333
0.0333
0.0333
0.0333
0.0333
0.0333
Laboratory Control Sample (LCS)
(LCS) R4025523-1 01/23/2413:52
Spike Amount
LCS Result
Analyte
mg/I
mg/I
1,4-Dichlorobenzene
0.500
0.311
2,4-Dinitrotoluene
0.500
0.381
Hexachlorobenzene
0.500
0.321
Hexachloro-1,3-butadiene
0.500
0.313
Hexachloroethane
0.500
0.300
Nitrobenzene
0.500
0.356
Pyridine
0.500
0.0698
3&4-Methyl Phenol
0.500
0.270
2-Methylphenol
0.500
0.255
Pentachlorophenol
0.500
0.224
2,4,5-Trichlorophenol
0.500
0.345
2,4,6-Trichlorophenol
0.500
0.356
(S) 2-Fluorophenol
(S) Phenol-d5
(S) Nitrobenzene-d5
LCS Rec
62.2
76.2
64.2
62.6
60.0
71.2
14.0
54.0
51.0
44.8
69.0
71.2
45.2
31.4
65.4
MB RDL
mg/I
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
0.100
10.0-120
10.0-120
10.0-127
10.0-130
10.0-155
10.0-128
Rec. Limits
18.0-120
49.0-124
44.0-120
19.0-120
15.0-120
27.0-120
10.0-120
31.0-120
28.0-120
23.0-120
44.0-120
42.0-120
10.0-120
10.0-120
10.0-127
LCS Qualifier
Rp
FTC]
FSS
Fn]
Fr
FGI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1695669 01/24/24 09:55 17 of 21

WG2209666
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
Laboratory Control Sample (LCS)
(LCS) R4025523-1 01/23/2413:52
Spike Amount LCS Result LCS Rec.
Analyte _ mg/1 mg/1 %
(S) 2-Fluorobiphenyl
(S) 2,4, 6-Tribromophenol
(S) p-Terphenyl-d14
/ /.
60.5
56.8
QUALITY CONTROL SUMMARY
L1695669-01
Rec. Limits
10.0-130
10.0-155
10.0-128
LCS Qualifier
L1695570-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1695570-02 01/23/2414:37 • (MS) R4025523-3 01/23/2414:59 • (MSD) R4025523-4 01/23/2415:21
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
Analyte
mg/I
mg/I
mg/I
mg/I
%
%
%
1,4-Dichlorobenzene
0.500
ND
0.301
0.329
60.2
65.8
1 17.0-120
2,4-Dinitrotoluene
0.500
ND
0.385
0.419
77.0
83.8
1 39.0-125
Hexachlorobenzene
0.500
ND
0.336
0.342
67.2
68.4
1 35.0-122
Hexachloro-1,3-butadiene
0.500
ND
0.344
0.358
68.8
71.6
1 12.0-120
Hexachloroethane
0.500
ND
0.309
0.325
61.8
65.0
1 10.0-120
Nitrobenzene
0.500
ND
0.390
0.420
78.0
84.0
1 12.0-120
Pyridine
0.500
ND
ND
ND
11.1
16.9
1 10.0-120
3&4-Methyl Phenol
0.500
ND
0.279
0.200
55.8
40.0
1 10.0-120
2-Methylphenol
0.500
ND
0.257
0.192
51.4
38.4
1 10.0-120
Pentachlorophenol
0.500
ND
0.219
0.210
43.8
42.0
1 10.0-128
2,4,5-Trichlorophenol
0.500
ND
0.366
0.326
73.2
65.2
1 33.0-120
2,4,6-Trichlorophenol
0.500
ND
0.366
0.322
73.2
64.4
1 26.0-120
(S) 2-Fluorophenol
43.2
29.1
10.0-120
(S) Phenol-d5
28.5
19.5
10.0-120
(S) Nitrobenzene-d5
73.3
80.0
10.0-127
(S) 2-Fluorobiphenyl
67.9
75.7
10.0-130
(S) 2,4,6- Tribromophenol
60.0
54.0
10.0-155
(S) p-Terphenyl-d14
57.9
57.4
10.0-128
MS Qualifier MSD Qualifier RPD
RPD Limits
8.89
40
8.46
25
1.77
24
3.99
34
5.05
40
7.41
30
J3 41.2
37
33.0
36
29.0
30
4.20
37
11.6
31
12.8
31
Rp
FTc
FSS
Fn]
Fr
FGI
FAI
FSC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1695669 01/24/24 09:55 18 of 21

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and if you have additional questions please contact your project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
MDL Method Detection Limit.
ND Not detected at the Reporting Limit (or MDL where applicable).
RDL Reported Detection Limit.
Rec. Recovery.
RPD Relative Percent Difference.
SDG Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
(S) Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U Not detected at the Reporting Limit (or MDL where applicable).
Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
Dilution standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section of the report includes the results of the laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the
samples from the time of collection until delivery to the laboratory for analysis.
This section of your report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
J3
J6
T8
Description
The analyte concentration exceeds the upper limit of the calibration range of the instrument established by the initial
calibration (ICAL).
The identification of the analyte is acceptable; the reported value is an estimate.
The associated batch QC was outside the established quality control range for precision.
The sample matrix interfered with the ability to make any accurate determination; spike value is low.
RPD between the primary and confirmatory analysis exceeded 40%.
Sample(s) received past/too close to holding time expiration.
FP1
z
Tc
FSS
4
Cn
I
Sr
RC
SAI
MC
ACCOUNT:
EMA Resources
PROJECT: SDG: DATE/TIME: PAGE:
L1695669 01/24/24 09:55 19 of 21

ACCREDITATIONS & LOCATIONS
Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama
40660
Nebraska _
Alaska
17-026
Nevada _
Arizona
AZ0612
New Hampshire
Arkansas
88-0469
New Jersey—NELAP
California
2932
New Mexico'
Colorado
TN00003
New York _
Connecticut
PH-0197
North Carolina
Florida
E87487
North Carolina'
Georgia
NELAP
North Carolina'
Georgia
923
_North Dakota
Idaho
TN00003
Ohio—VAP
Illinois
200008
Oklahoma
Indiana
C-TN-01
Oregon _
Iowa
364
Pennsylvania
Kansas
E-10277
Rhode Island
Kentucky16
KY90010
South Carolina
Kentucky 2
16
South Dakota
Louisiana
A130792
Tennessee' 4
Louisiana
LA018
Texas
Maine
TN00003
Texas'
Maryland
324
Utah
Massachusetts
M-TNO03
Vermont
Michigan
9958
Virginia
Minnesota
047-999-395
Washington
Mississippi
TN00003
West Virginia
Missouri
340
Wisconsin
Montana
CERT0086
Wyoming
A21-A— ISO 17025
1461.01
AIHA-LAP,LLC EMLAP
A21-A — ISO 17025'
1461.02
DOD
Canada
1461.01
USDA
EPA—Crypto
TN00003
NE-OS-15-05
TN000032021-1
2975
TNO02
TN00003
— 11742
Env375
DW21704
41
_ R-140
CL0069
' Drinking Water 2 Underground Storage Tanks s Aquatic Toxicity ° Chemical/Microbiological 'Mold 'Wastewater n/a Accreditation not applicable
*Not all certifications held by the laboratory are applicable to the results reported in the attached report.
*Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
9915
TN200002
68-02979
LA000356
84004002
n/a
2006
T104704245-20-18
LABO152
TN000032021-11
VT2006
233
998093910
A2LA
100789
1461.01
P330-15-00234
FP1
2
Tc
FSS
4
Cn
FSr
Fqc
FGI
9
qc
ACCOUNT: PROJECT: S DG: DATE/TIME: PAGE:
EMA Resources L1695669 01/24/24 09:55 20 of 21

mpany Name/Address:
EMA Resources
755 Yadkinville Road
Mocksville, NC 27028
keport to:
Mr, Brent Collins
Project Description:
Sludge
Phone: [phone]
Billing Information.
Mr. Brent Collins Pres
755 Yadkinville Road Chk
Mocksville, NC 27028
EmaiI To:
[e-mail];roy.whitak
(ICity/State j / Please Circle:
I Collected: �/ n0/1� J PT MT CT ET
)
Client Project # Lab Project #
Collet It dd by (print): f Site/Facility ID # P.O. #
Collected by (signature): Rush. L
� (ab MUST Be Notified) Quote #
Same Day _ Five Day
Next Day 5 Day (Rad Only) Date Results
Immediately Two Day _ 10 Day (Rad Only)
Packed on Ice N _ Y _ Three Day
Sample ID Comp/Grab I Matrix * Depth I Date
rvw•, t..l TP SSI 3 /�iv Zy
Ln
41
tfi
O
Z
�
+r
U
!ded
No.
t?
of
1.4
Time Cntrs
qV1
Q- 0V
2—
V
v
1 Chain of Custody Page _ of
�ace,
r EOPLE ADVANCING SCIENCE
MT JULIET, TN
12055 Lebanon Rd Mount Juliet, TN 37122 -
Submnting a sample via this chain of custody
constitutes acknowledgment and acceptance of the
Pace Terms and Conditions found at, -
https//info.pacelabs.com/hubts/pas-standard-
terms.pdf
'SDG #
H132
Acctnum: EMARES
Template:T11413
PreloRin: P1046917
PM: 923 -Rea an Johnson
PB:
shipped via: FedEX Ground
Remarks Sample # (lab only)
* Matrix:
lemarks:
Sam le R cei t check)
I
SS - Soil AIR - Air F - Filter
pH Temp
COC seal Present/Intact : __ aP Y _N
GW Groundwater B- Bioassa y
Flow Other
COC signed/Accurate: .'Y _
not*-les arrive intact: _✓Y
N
N
WW - WasteWater
Correct bottles used: /Y/
N
DW - Drinking Water
m
Samples returned via:
Tracking #
Z i `�
sufficient volume sent: �Y _N
If Applicable
OT -Other w
U?S FedEx _ Courier
js
VOA Zero Headspace Y
N
Relinquished b : (Signature)
_ _
Date:
Time:
,.
Received by (Signature)
Trip Blank Received: Yes N
Preservation.Corre_ct/Checked_ --Y --N
RAD Screen <0.5 mR/hr : zY
HCL/MeoH
_N
TRR
_
Relinquished by : (Signature)
Date:
Time:
Received by: (Signature)
l
Temp:1.14 °C Bottles Received:
If preservation required by Login: Date/Time
2--
Relinquished by : (Signature)
Date:
Time:
Received for lab b, ` (Signature)
..
Date: Time:
Hold:
Conditio

EMA Resources Permit Modification -
WQ0041666
Final Audit Report 2024-04-17
Created: 2024-04-17
By: Brent Collins([e-mail])
Status: Signed
Transaction ID: CBJCHBCAABAAc01PXZ6nxeFz7PF1XY-OgRgs_ij15f2Y
"EMA Resources Permit Modification - WQ0041666" History
Document created by Brent Collins([e-mail])
2024-04-17 - 12:59:32 PM GMT- IP address: 206.85.202.26
CP. Document emailed to Erik Blankenship ([e-mail]) for signature
2024-04-17 - 12:59:49 PM GMT
Email viewed by Erik Blankenship ([e-mail])
2024-04-17 - 1:20:57 PM GMT- IP address: 206.85.202.92
&0 Document e-signed by Erik Blankenship ([e-mail])
Signature Date: 2024-04-17 - 1:21:49 PM GMT - Time Source: server- IP address: 206.85.202.92
Q Agreement completed.
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