NC0005363_App A Analytical Data_20160201

Corrective Action Plan Part 2 February 2016
W.H. Weatherspoon Power Plant
APPENDIX A
LABORATORY ANALYTICAL REPORTS
SynTerra
P:\ Duke Energy Progress.1026 \ 109. Weatherspoon Ash Basin GW Assessment Plan \ 20.EG_CAP \ CAP Part
2\ Weatherspoon CAP Part 2 February 2016.docx

DUKE
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
Analytical Laboratory
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
J15120037
WEATHERSPOON -AB GW ASSESSMENT WATER
Mark Taylor, Tim Hunsucker, Brandon Russo, Kathy Webb, John Toepfer
Anne Pifer
Anne Pifer
Phone:
Date:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
12/9/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time Collected By Sample Description
2015037570
Weatherspoon
01 -Dec -15
2:55 PM
JHG
MW -2
2015037581
Weatherspoon
01 -Dec -15
11:05 AM
JHG
MW -3
2015037582
Weatherspoon
01 -Dec -15
1:43 PM
JHG
MW -55D
2015037583
Weatherspoon
01 -Dec -15
1:04 PM
JHG
MW -04
2015037584
Weatherspoon
01 -Dec -15
12:23 PM
JHG
MW -551
2015037585
Weatherspoon
01 -Dec -15
11:40 AM
JHG
MW -05
2015037586
Weatherspoon
01 -Dec -15
3:28 PM
JHG
MW -441
2015037587
Weatherspoon
01 -Dec -15
4:16 PM
JHG
MW -1
2015037588
Weatherspoon
01 -Dec -15
12:53 PM
JHG
MW -081
2015037589
Weatherspoon
01 -Dec -15
11:05 AM
JHG
MW -06
2015037590
Weatherspoon
01 -Dec -15
11:05 AM
JHG
MW -06 DUP
2015037591
Weatherspoon
01 -Dec -15
4:05 PM
JHG
CW -01
2015037592
Weatherspoon
01 -Dec -15
5:55 PM
Filter Blank
2015037593
Weatherspoon
01 -Dec -15
5:55 PM
Equipment Blank
14 Total Samples

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
LU Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
d❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
0 Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
d❑ Chain of Custody
d❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 12/9/2015

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -2
Collection Date: 01 -Dec -15 2:55 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.016 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
5 EPA 300.0
12/02/2015 15:32
INORGANIC IONS BY IC
1 EPA 245.1
12/03/2015 15:13
ACPAYNE
Chloride
5.8
mg/L
0.1
Sulfate
25
mg/L
0.5
MERCURY (COLD VAPOR) IN WATER
1 EPA 200.7
12/02/2015 10:19
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
12/02/2015 10:19
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
FCJORDA
1 EPA 200.7
12/02/2015 11:43
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.042
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.240
mg/L
0.01
Manganese (Mn)
0.019
mg/L
0.005
Strontium (Sr)
0.284
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.041
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.241
mg/L
0.01
Manganese (Mn)
0.020
mg/L
0.005
Strontium (Sr)
0.283
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
51.8
mg/L
0.01
Magnesium (Mg)
1.12
mg/L
0.005
Potassium (K)
1.09
mg/L
0.1
Sodium (Na)
2.87
mg/L
0.05
Sample #: 2015037570
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/04/2015 09:25 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
12/02/2015 15:32
BGN9034
5 EPA 300.0
12/02/2015 15:32
BGN9034
1 EPA 245.1
12/03/2015 15:13
ACPAYNE
1 EPA 245.1
12/03/2015 16:12
ACPAYNE
1 EPA 245.1
12/05/2015 12:31
ACPAYNE
1 EPA 200.7
12/02/2015 10:19
FCJORDA
1 EPA 200.7
12/02/2015 10:19
FCJORDA
1 EPA 200.7
12/02/2015 10:19
FCJORDA
1 EPA 200.7
12/02/2015 10:19
FCJORDA
1 EPA 200.7
12/02/2015 10:19
FCJORDA
1 EPA 200.7
12/02/2015 10:19
FCJORDA
1 EPA 200.7
12/02/2015 10:19
FCJORDA
1 EPA 200.7
12/02/2015 11:43
FCJORDA
1 EPA 200.7
12/02/2015 11:43
FCJORDA
1 EPA 200.7
12/02/2015 11:43
FCJORDA
1 EPA 200.7
12/02/2015 11:43
FCJORDA
1 EPA 200.7
12/02/2015 11:43
FCJORDA
1 EPA 200.7
12/02/2015 11:43
FCJORDA
1 EPA 200.7
12/02/2015 11:43
FCJORDA
1 EPA 200.7
12/02/2015 13:03
FCJORDA
1 EPA 200.7
12/02/2015 13:03
FCJORDA
1 EPA 200.7
12/02/2015 13:03
FCJORDA
1 EPA 200.7
12/02/2015 13:03
FCJORDA

Site: MW -2
Collection Date: 01 -Dec -15 2:55 PM
Analyte
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.038
Barium (Ba)
0.044
Boron (B)
< 0.05
Iron (Fe)
0.597
Manganese (Mn)
0.025
Strontium (Sr)
0.289
Zinc (Zn)
< 0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037570
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/03/2015 09:20
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:20
MHH7131
mg/L
0.05
1
EPA 200.7
12/03/2015 09:20
MHH7131
mg/L
0.01
1
EPA 200.7
12/03/2015 09:20
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:20
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:20
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:20
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 12:31
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 12:31
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 12:31
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 12:31
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 12:31
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 12:31
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 12:31
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 12:31
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 12:31
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 12:31
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 12:31
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/03/2015 12:31
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/03/2015 12:31
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/02/2015 14:31
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
12/02/2015 14:31
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
12/02/2015 14:31
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
12/02/2015 14:31
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
12/02/2015 14:31
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
12/02/2015 14:31
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/02/2015 14:31
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
12/02/2015 14:31
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
12/02/2015 14:31
JAHERMA
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
12/02/2015 14:31
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
12/02/2015 14:31
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/02/2015 14:31
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/02/2015 14:31
JAHERMA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -2
('nllor+inn rlo+o• 01_rlon_9r, 7 -FG DRA
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
0.440
ug/L
0.2
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
< 25
mg/L
25
1
Total Carbon
Sample #:
2015037570
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/03/2015 20:13
MHALL3
EPA 200.8
12/03/2015 20:13
MHALL3
EPA 200.8
12/03/2015 20:13
MHALL3
EPA 200.8
12/03/2015 20:13
MHALL3
EPA 200.8
12/03/2015 20:13
MHALL3
EPA 200.8
12/03/2015 20:13
MHALL3
EPA 200.8
12/03/2015 20:13
MHALL3
EPA 200.8
12/03/2015 20:13
MHALL3
EPA 200.8
12/03/2015 20:13
MHALL3
EPA 200.8
12/03/2015 20:13
MHALL3
EPA 200.8
12/03/2015 20:13
MHALL3
EPA 200.8
12/03/2015 20:13
MHALL3
EPA 200.8
12/03/2015 20:13
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/03/201516:05 CJELLIO
TOC 0.538 mg/L 0.1 1 SM5310C/EPA9060A 12/02/201513:37 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 12/02/2015 10:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -3
Collection Date: 01 -Dec -15 11:05 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.016 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
10
INORGANIC IONS BY IC
12/02/2015 13:09
BGN9034
1
Chloride
20
mg/L
1
Sulfate
44
mg/L
1
MERCURY (COLD VAPOR) IN WATER
12/05/2015 12:38
ACPAYNE
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 200.7
12/02/2015 10:30
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
1
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
12/02/2015 10:30
FCJORDA
1
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.080
mg/L
0.005
Boron (B)
0.463
mg/L
0.05
Iron (Fe)
1.08
mg/L
0.01
Manganese (Mn)
0.046
mg/L
0.005
Strontium (Sr)
0.579
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
12/02/2015 11:54
FCJORDA
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.079
mg/L
0.005
Boron (B)
0.432
mg/L
0.05
Iron (Fe)
1.03
mg/L
0.01
Manganese (Mn)
0.046
mg/L
0.005
Strontium (Sr)
0.577
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
81.7
mg/L
0.01
Magnesium (Mg)
3.02
mg/L
0.005
Potassium (K)
2.23
mg/L
0.1
Sodium (Na)
12.9
mg/L
0.05
Sample #: 2015037581
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/04/2015 09:26 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
12/02/2015 13:09
BGN9034
10
EPA 300.0
12/02/2015 13:09
BGN9034
1
EPA 245.1
12/03/2015 15:15
ACPAYNE
1
EPA 245.1
12/03/2015 16:05
ACPAYNE
1
EPA 245.1
12/05/2015 12:38
ACPAYNE
1
EPA 200.7
12/02/2015 10:30
FCJORDA
1
EPA 200.7
12/02/2015 10:30
FCJORDA
1
EPA 200.7
12/02/2015 10:30
FCJORDA
1
EPA 200.7
12/02/2015 10:30
FCJORDA
1
EPA 200.7
12/02/2015 10:30
FCJORDA
1
EPA 200.7
12/02/2015 10:30
FCJORDA
1
EPA 200.7
12/02/2015 10:30
FCJORDA
1
EPA 200.7
12/02/2015 11:54
FCJORDA
1
EPA 200.7
12/02/2015 11:54
FCJORDA
1
EPA 200.7
12/02/2015 11:54
FCJORDA
1
EPA 200.7
12/02/2015 11:54
FCJORDA
1
EPA 200.7
12/02/2015 11:54
FCJORDA
1
EPA 200.7
12/02/2015 11:54
FCJORDA
1
EPA 200.7
12/02/2015 11:54
FCJORDA
1
EPA 200.7
12/02/2015 13:23
FCJORDA
1
EPA 200.7
12/02/2015 13:23
FCJORDA
1
EPA 200.7
12/02/2015 13:23
FCJORDA
1
EPA 200.7
12/02/2015 13:23
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -3
Collection Date: 01 -Dec -15 11:05 AM
Analyte
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.155
Barium (Ba)
0.081
Boron (B)
0.418
Iron (Fe)
1.54
Manganese (Mn)
0.044
Strontium (Sr)
0.559
Zinc (Zn)
< 0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037581
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/03/2015 09:32
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:32
MHH7131
mg/L
0.05
1
EPA 200.7
12/03/2015 09:32
MHH7131
mg/L
0.01
1
EPA 200.7
12/03/2015 09:32
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:32
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:32
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:32
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:34
MHALL3
Arsenic (As)
4.44
ug/L
1
1
EPA 200.8
12/03/2015 13:34
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:34
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:34
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:34
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:34
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:34
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:34
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:34
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:34
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:34
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/03/2015 13:34
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/03/2015 13:34
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/02/2015 15:13
JAHERMA
Arsenic (As)
4.25
ug/L
1
1
EPA 200.8
12/02/2015 15:13
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:13
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:13
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:13
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:13
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/02/2015 15:13
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:13
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:13
JAHERMA
Nickel (Ni)
1.23
ug/L
1
1
EPA 200.8
12/02/2015 15:13
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:13
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/02/2015 15:13
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/02/2015 15:13
JAHERMA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -3
Collection Date: 01 -Dec -15 11:05 AM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
3.95
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
0.675
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
300
mg/L
25
1
Total Carbon
Sample #:
2015037581
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/03/2015 19:52
MHALL3
EPA 200.8
12/03/2015 19:52
MHALL3
EPA 200.8
12/03/2015 19:52
MHALL3
EPA 200.8
12/03/2015 19:52
MHALL3
EPA 200.8
12/03/2015 19:52
MHALL3
EPA 200.8
12/03/2015 19:52
MHALL3
EPA 200.8
12/03/2015 19:52
MHALL3
EPA 200.8
12/03/2015 19:52
MHALL3
EPA 200.8
12/03/2015 19:52
MHALL3
EPA 200.8
12/03/2015 19:52
MHALL3
EPA 200.8
12/03/2015 19:52
MHALL3
EPA 200.8
12/03/2015 19:52
MHALL3
EPA 200.8
12/03/2015 19:52
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/03/201516:05 CJELLIO
TOC 2.2 mg/L 0.1 1 SM5310C/EPA9060A 12/02/201513:37 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS 8.0 mg/L 5 1 SM2540D 12/02/201510:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -55D
Collection Date: 01 -Dec -15 1:43 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.023 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
1 EPA 300.0
12/02/2015 13:27
INORGANIC IONS BY IC
1 EPA 245.1
12/03/2015 15:17
ACPAYNE
Chloride
3.4
mg/L
0.1
Sulfate
0.36
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
1 EPA 200.7
12/02/2015 10:34
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
12/02/2015 10:34
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
FCJORDA
1 EPA 200.7
12/02/2015 13:27
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.036
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.00
mg/L
0.01
Manganese (Mn)
0.032
mg/L
0.005
Strontium (Sr)
0.230
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
UNDIGESTED METALS BY ICP
12/03/2015 09:36
MHH7131
Calcium (Ca)
44.2
mg/L
0.01
Magnesium (Mg)
1.11
mg/L
0.005
Potassium (K)
1.33
mg/L
0.1
Sodium (Na)
2.82
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.062
mg/L
0.005
Barium (Ba)
0.037
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.37
mg/L
0.01
Manganese (Mn)
0.037
mg/L
0.005
Strontium (Sr)
0.231
mg/L
0.005
Zinc (Zn)
0.015
mg/L
0.005
Sample #: 2015037582
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/04/2015 09:28 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
12/02/2015 13:27
BGN9034
1 EPA 300.0
12/02/2015 13:27
BGN9034
1 EPA 245.1
12/03/2015 15:17
ACPAYNE
1 EPA 245.1
12/03/2015 16:14
ACPAYNE
1 EPA 200.7
12/02/2015 10:34
FCJORDA
1 EPA 200.7
12/02/2015 10:34
FCJORDA
1 EPA 200.7
12/02/2015 10:34
FCJORDA
1 EPA 200.7
12/02/2015 10:34
FCJORDA
1 EPA 200.7
12/02/2015 10:34
FCJORDA
1 EPA 200.7
12/02/2015 10:34
FCJORDA
1 EPA 200.7
12/02/2015 10:34
FCJORDA
1 EPA 200.7
12/02/2015 13:27
FCJORDA
1 EPA 200.7
12/02/2015 13:27
FCJORDA
1 EPA 200.7
12/02/2015 13:27
FCJORDA
1 EPA 200.7
12/02/2015 13:27
FCJORDA
1 EPA 200.7
12/03/2015 09:36
MHH7131
1 EPA 200.7
12/03/2015 09:36
MHH7131
1 EPA 200.7
12/03/2015 09:36
MHH7131
1 EPA 200.7
12/03/2015 09:36
MHH7131
1 EPA 200.7
12/03/2015 09:36
MHH7131
1 EPA 200.7
12/03/2015 09:36
MHH7131
1 EPA 200.7
12/03/2015 09:36
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -55D
Collection Date: 01 -Dec -15 1:43 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP -MS
EPA 200.8
12/03/2015 13:41
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
140
mg/L
25
Total Carbon
TOC
0.753
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
8.0
mg/L
5
1 EPA 200.8
Sample #:
2015037582
1 EPA 200.8
12/03/2015 20:20
Matrix:
GW WW
12/03/2015 20:20
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
12/03/2015 13:41
MHALL3
1
EPA 200.8
12/03/2015 13:41
MHALL3
1
EPA 200.8
12/03/2015 13:41
MHALL3
1
EPA 200.8
12/03/2015 13:41
MHALL3
1
EPA 200.8
12/03/2015 13:41
MHALL3
1
EPA 200.8
12/03/2015 13:41
MHALL3
1
EPA 200.8
12/03/2015 13:41
MHALL3
1
EPA 200.8
12/03/2015 13:41
MHALL3
1
EPA 200.8
12/03/2015 13:41
MHALL3
1
EPA 200.8
12/03/2015 13:41
MHALL3
1
EPA 200.8
12/03/2015 13:41
MHALL3
1
EPA 200.8
12/03/2015 13:41
MHALL3
1
EPA 200.8
12/03/2015 13:41
MHALL3
1 EPA 200.8
12/03/2015 20:20
MHALL3
1 EPA 200.8
12/03/2015 20:20
MHALL3
1 EPA 200.8
12/03/2015 20:20
MHALL3
1 EPA 200.8
12/03/2015 20:20
MHALL3
1 EPA 200.8
12/03/2015 20:20
MHALL3
1 EPA 200.8
12/03/2015 20:20
MHALL3
1 EPA 200.8
12/03/2015 20:20
MHALL3
1 EPA 200.8
12/03/2015 20:20
MHALL3
1 EPA 200.8
12/03/2015 20:20
MHALL3
1 EPA 200.8
12/03/2015 20:20
MHALL3
1 EPA 200.8
12/03/2015 20:20
MHALL3
1 EPA 200.8
12/03/2015 20:20
MHALL3
1 EPA 200.8
12/03/2015 20:20
MHALL3
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 12/03/201516:05 CJELLIO
1 SM5310C/EPA9060A 12/02/201513:37 GHUTCHI
1 SM2540D 12/02/201510:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -04
Collection Date: 01 -Dec -15 1:04 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.047 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
20
INORGANIC IONS BY IC
12/02/2015 13:45
BGN9034
1
Chloride
59
mg/L
2
Sulfate
150
mg/L
2
MERCURY (COLD VAPOR) IN WATER
12/05/2015 12:41
ACPAYNE
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 200.7
12/02/2015 10:38
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
1
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
12/02/2015 10:38
FCJORDA
1
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.080
mg/L
0.005
Boron (B)
1.89
mg/L
0.05
Iron (Fe)
0.057
mg/L
0.01
Manganese (Mn)
0.463
mg/L
0.005
Strontium (Sr)
0.450
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
12/02/2015 11:58
FCJORDA
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.087
mg/L
0.005
Boron (B)
1.99
mg/L
0.05
Iron (Fe)
0.058
mg/L
0.01
Manganese (Mn)
0.470
mg/L
0.005
Strontium (Sr)
0.475
mg/L
0.005
Zinc (Zn)
0.008
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
73.8
mg/L
0.01
Magnesium (Mg)
3.72
mg/L
0.005
Potassium (K)
2.68
mg/L
0.1
Sodium (Na)
59.8
mg/L
0.05
Sample #: 2015037583
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/04/2015 09:29 LSTARL1
Vendor Method V_PACE
20
EPA 300.0
12/02/2015 13:45
BGN9034
20
EPA 300.0
12/02/2015 13:45
BGN9034
1
EPA 245.1
12/03/2015 15:20
ACPAYNE
1
EPA 245.1
12/03/2015 16:16
ACPAYNE
1
EPA 245.1
12/05/2015 12:41
ACPAYNE
1
EPA 200.7
12/02/2015 10:38
FCJORDA
1
EPA 200.7
12/02/2015 10:38
FCJORDA
1
EPA 200.7
12/02/2015 10:38
FCJORDA
1
EPA 200.7
12/02/2015 10:38
FCJORDA
1
EPA 200.7
12/02/2015 10:38
FCJORDA
1
EPA 200.7
12/02/2015 10:38
FCJORDA
1
EPA 200.7
12/02/2015 10:38
FCJORDA
1
EPA 200.7
12/02/2015 11:58
FCJORDA
1
EPA 200.7
12/02/2015 11:58
FCJORDA
1
EPA 200.7
12/02/2015 11:58
FCJORDA
1
EPA 200.7
12/02/2015 11:58
FCJORDA
1
EPA 200.7
12/02/2015 11:58
FCJORDA
1
EPA 200.7
12/02/2015 11:58
FCJORDA
1
EPA 200.7
12/02/2015 11:58
FCJORDA
1
EPA 200.7
12/02/2015 13:30
FCJORDA
1
EPA 200.7
12/02/2015 13:30
FCJORDA
1
EPA 200.7
12/02/2015 13:30
FCJORDA
1
EPA 200.7
12/02/2015 13:30
FCJORDA

Site: MW -04
Collection Date: 01 -Dec -15 1:04 PM
Analyte
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.056
Barium (Ba)
0.079
Boron (B)
1.83
Iron (Fe)
0.163
Manganese (Mn)
0.483
Strontium (Sr)
0.423
Zinc (Zn)
0.006
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037583
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/03/2015 09:40
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:40
MHH7131
mg/L
0.05
1
EPA 200.7
12/03/2015 09:40
MHH7131
mg/L
0.01
1
EPA 200.7
12/03/2015 09:40
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:40
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:40
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:40
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:48
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:48
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:48
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:48
MHALL3
Chromium (Cr)
1.53
ug/L
1
1
EPA 200.8
12/03/2015 13:48
MHALL3
Cobalt (Co)
3.99
ug/L
1
1
EPA 200.8
12/03/2015 13:48
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:48
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:48
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:48
MHALL3
Nickel (Ni)
5.13
ug/L
1
1
EPA 200.8
12/03/2015 13:48
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 13:48
MHALL3
Thallium (TI) Low Level
0.330
ug/L
0.2
1
EPA 200.8
12/03/2015 13:48
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/03/2015 13:48
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/02/2015 15:20
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:20
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:20
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:20
JAHERMA
Chromium (Cr)
1.41
ug/L
1
1
EPA 200.8
12/02/2015 15:20
JAHERMA
Cobalt (Co)
4.09
ug/L
1
1
EPA 200.8
12/02/2015 15:20
JAHERMA
Copper (Cu)
1.11
ug/L
1
1
EPA 200.8
12/02/2015 15:20
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:20
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:20
JAHERMA
Nickel (Ni)
4.49
ug/L
1
1
EPA 200.8
12/02/2015 15:20
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:20
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/02/2015 15:20
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/02/2015 15:20
JAHERMA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -04
Collection Date: 01 -Dec -15 1:04 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
5.35
ug/L
1
1
Cobalt (Co)
6.57
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
4.67
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
0.316
ug/L
0.2
1
Vanadium (V) Low Level
0.374
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
440
mg/L
25
1
Total Carbon
Sample #:
2015037583
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/02/2015 22:49
JAHERMA
EPA 200.8
12/02/2015 22:49
JAHERMA
EPA 200.8
12/02/2015 22:49
JAHERMA
EPA 200.8
12/02/2015 22:49
JAHERMA
EPA 200.8
12/02/2015 22:49
JAHERMA
EPA 200.8
12/02/2015 22:49
JAHERMA
EPA 200.8
12/02/2015 22:49
JAHERMA
EPA 200.8
12/02/2015 22:49
JAHERMA
EPA 200.8
12/02/2015 22:49
JAHERMA
EPA 200.8
12/02/2015 22:49
JAHERMA
EPA 200.8
12/02/2015 22:49
JAHERMA
EPA 200.8
12/02/2015 22:49
JAHERMA
EPA 200.8
12/02/2015 22:49
JAHERMA
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/03/201516:05 CJELLIO
TOC 1.2 mg/L 0.1 1 SM5310C/EPA9060A 12/02/201513:37 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 12/02/2015 10:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -551
Collection Date: 01 -Dec -15 12:23 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
10
INORGANIC IONS BY IC
12/02/2015 14:02
BGN9034
1
Chloride
51
mg/L
1
Sulfate
61
mg/L
1
MERCURY (COLD VAPOR) IN WATER
12/05/2015 12:43
ACPAYNE
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 200.7
12/02/2015 10:42
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
1
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
12/02/2015 10:42
FCJORDA
1
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.069
mg/L
0.005
Boron (B)
0.756
mg/L
0.05
Iron (Fe)
0.542
mg/L
0.01
Manganese (Mn)
0.056
mg/L
0.005
Strontium (Sr)
0.510
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
12/02/2015 12:02
FCJORDA
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.068
mg/L
0.005
Boron (B)
0.748
mg/L
0.05
Iron (Fe)
0.509
mg/L
0.01
Manganese (Mn)
0.055
mg/L
0.005
Strontium (Sr)
0.505
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
91.4
mg/L
0.01
Magnesium (Mg)
2.73
mg/L
0.005
Potassium (K)
1.15
mg/L
0.1
Sodium (Na)
32.1
mg/L
0.05
Sample #: 2015037584
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/04/2015 09:30 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
12/02/2015 14:02
BGN9034
10
EPA 300.0
12/02/2015 14:02
BGN9034
1
EPA 245.1
12/03/2015 14:21
ACPAYNE
1
EPA 245.1
12/03/2015 16:19
ACPAYNE
1
EPA 245.1
12/05/2015 12:43
ACPAYNE
1
EPA 200.7
12/02/2015 10:42
FCJORDA
1
EPA 200.7
12/02/2015 10:42
FCJORDA
1
EPA 200.7
12/02/2015 10:42
FCJORDA
1
EPA 200.7
12/02/2015 10:42
FCJORDA
1
EPA 200.7
12/02/2015 10:42
FCJORDA
1
EPA 200.7
12/02/2015 10:42
FCJORDA
1
EPA 200.7
12/02/2015 10:42
FCJORDA
1
EPA 200.7
12/02/2015 12:02
FCJORDA
1
EPA 200.7
12/02/2015 12:02
FCJORDA
1
EPA 200.7
12/02/2015 12:02
FCJORDA
1
EPA 200.7
12/02/2015 12:02
FCJORDA
1
EPA 200.7
12/02/2015 12:02
FCJORDA
1
EPA 200.7
12/02/2015 12:02
FCJORDA
1
EPA 200.7
12/02/2015 12:02
FCJORDA
1
EPA 200.7
12/02/2015 13:34
FCJORDA
1
EPA 200.7
12/02/2015 13:34
FCJORDA
1
EPA 200.7
12/02/2015 13:34
FCJORDA
1
EPA 200.7
12/02/2015 13:34
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -551
Collection Date: 01 -Dec -15 12:23 PM
Analyte
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.147
Barium (Ba)
0.067
Boron (B)
0.745
Iron (Fe)
0.655
Manganese (Mn)
0.053
Strontium (Sr)
0.499
Zinc (Zn)
< 0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037584
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/03/2015 09:44
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:44
MHH7131
mg/L
0.05
1
EPA 200.7
12/03/2015 09:44
MHH7131
mg/L
0.01
1
EPA 200.7
12/03/2015 09:44
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:44
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:44
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:44
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:30
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:30
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:30
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:30
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:30
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:30
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:30
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:30
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:30
MHALL3
Nickel (Ni)
1.28
ug/L
1
1
EPA 200.8
12/03/2015 14:30
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:30
MHALL3
Thallium (TI) Low Level
0.226
ug/L
0.2
1
EPA 200.8
12/03/2015 14:30
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/03/2015 14:30
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/02/2015 15:27
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:27
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:27
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:27
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:27
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:27
JAHERMA
Copper (Cu)
1.21
ug/L
1
1
EPA 200.8
12/02/2015 15:27
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:27
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:27
JAHERMA
Nickel (Ni)
1.62
ug/L
1
1
EPA 200.8
12/02/2015 15:27
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:27
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/02/2015 15:27
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/02/2015 15:27
JAHERMA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -551
Collection Date: 01 -Dec -15 12:23 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
1.29
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
0.463
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
370
mg/L
25
1
Total Carbon
Sample #:
2015037584
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/03/2015 20:34
MHALL3
EPA 200.8
12/03/2015 20:34
MHALL3
EPA 200.8
12/03/2015 20:34
MHALL3
EPA 200.8
12/03/2015 20:34
MHALL3
EPA 200.8
12/03/2015 20:34
MHALL3
EPA 200.8
12/03/2015 20:34
MHALL3
EPA 200.8
12/03/2015 20:34
MHALL3
EPA 200.8
12/03/2015 20:34
MHALL3
EPA 200.8
12/03/2015 20:34
MHALL3
EPA 200.8
12/03/2015 20:34
MHALL3
EPA 200.8
12/03/2015 20:34
MHALL3
EPA 200.8
12/03/2015 20:34
MHALL3
EPA 200.8
12/03/2015 20:34
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/03/201516:05 CJELLIO
TOC 0.999 mg/L 0.1 1 SM5310C/EPA9060A 12/02/201513:37 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS 8.0 mg/L 5 1 SM2540D 12/02/201510:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -05
Collection Date: 01 -Dec -15 11:40 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.021 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
10
INORGANIC IONS BY IC
12/03/2015 08:01
BGN9034
1
Chloride
8.7
mg/L
0.1
Sulfate
60
mg/L
1
MERCURY (COLD VAPOR) IN WATER
12/05/2015 12:46
ACPAYNE
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 200.7
12/02/2015 10:46
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
1
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
12/02/2015 10:46
FCJORDA
1
Aluminum (AI)
0.059
mg/L
0.005
Barium (Ba)
0.013
mg/L
0.005
Boron (B)
0.093
mg/L
0.05
Iron (Fe)
13.2
mg/L
0.01
Manganese (Mn)
0.027
mg/L
0.005
Strontium (Sr)
0.026
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
12/02/2015 12:06
FCJORDA
Aluminum (AI)
0.062
mg/L
0.005
Barium (Ba)
0.014
mg/L
0.005
Boron (B)
0.093
mg/L
0.05
Iron (Fe)
12.6
mg/L
0.01
Manganese (Mn)
0.027
mg/L
0.005
Strontium (Sr)
0.027
mg/L
0.005
Zinc (Zn)
0.006
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
2.61
mg/L
0.01
Magnesium (Mg)
1.29
mg/L
0.005
Potassium (K)
0.224
mg/L
0.1
Sodium (Na)
14.7
mg/L
0.05
Sample #: 2015037585
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/04/2015 09:31 LSTARL1
Vendor Method V_PACE
1
EPA 300.0
12/03/2015 08:01
BGN9034
10
EPA 300.0
12/03/2015 08:01
BGN9034
1
EPA 245.1
12/03/2015 14:23
ACPAYNE
1
EPA 245.1
12/03/2015 16:21
ACPAYNE
1
EPA 245.1
12/05/2015 12:46
ACPAYNE
1
EPA 200.7
12/02/2015 10:46
FCJORDA
1
EPA 200.7
12/02/2015 10:46
FCJORDA
1
EPA 200.7
12/02/2015 10:46
FCJORDA
1
EPA 200.7
12/02/2015 10:46
FCJORDA
1
EPA 200.7
12/02/2015 10:46
FCJORDA
1
EPA 200.7
12/02/2015 10:46
FCJORDA
1
EPA 200.7
12/02/2015 10:46
FCJORDA
1
EPA 200.7
12/02/2015 12:06
FCJORDA
1
EPA 200.7
12/02/2015 12:06
FCJORDA
1
EPA 200.7
12/02/2015 12:06
FCJORDA
1
EPA 200.7
12/02/2015 12:06
FCJORDA
1
EPA 200.7
12/02/2015 12:06
FCJORDA
1
EPA 200.7
12/02/2015 12:06
FCJORDA
1
EPA 200.7
12/02/2015 12:06
FCJORDA
1
EPA 200.7
12/02/2015 13:38
FCJORDA
1
EPA 200.7
12/02/2015 13:38
FCJORDA
1
EPA 200.7
12/02/2015 13:38
FCJORDA
1
EPA 200.7
12/02/2015 13:38
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -05
Collection Date: 01 -Dec -15 11:40 AM
Analyte
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.368
Barium (Ba)
0.014
Boron (B)
0.096
Iron (Fe)
14.9
Manganese (Mn)
0.026
Strontium (Sr)
0.026
Zinc (Zn)
< 0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037585
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/03/2015 09:48
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:48
MHH7131
mg/L
0.05
1
EPA 200.7
12/03/2015 09:48
MHH7131
mg/L
0.01
1
EPA 200.7
12/03/2015 09:48
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:48
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:48
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:48
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:51
MHALL3
Arsenic (As)
1.06
ug/L
1
1
EPA 200.8
12/03/2015 14:51
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:51
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:51
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:51
MHALL3
Cobalt (Co)
1.58
ug/L
1
1
EPA 200.8
12/03/2015 14:51
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:51
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:51
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:51
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:51
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:51
MHALL3
Thallium (TI) Low Level
0.746
ug/L
0.2
1
EPA 200.8
12/03/2015 14:51
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/03/2015 14:51
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:21
MHALL3
Arsenic (As)
1.12
ug/L
1
1
EPA 200.8
12/03/2015 15:21
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:21
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:21
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:21
MHALL3
Cobalt (Co)
1.72
ug/L
1
1
EPA 200.8
12/03/2015 15:21
MHALL3
Copper (Cu)
1.83
ug/L
1
1
EPA 200.8
12/03/2015 15:21
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:21
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:21
MHALL3
Nickel (Ni)
1.64
ug/L
1
1
EPA 200.8
12/03/2015 15:21
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:21
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/03/2015 15:21
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/03/2015 15:21
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -05
Collection Date: 01 -Dec -15 11:40 AM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
2.41
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
1.25
ug/L
1
1
Cobalt (Co)
1.56
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
3.63
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
71
mg/L
25
1
Total Carbon
Sample #:
2015037585
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/03/2015 20:41
MHALL3
EPA 200.8
12/03/2015 20:41
MHALL3
EPA 200.8
12/03/2015 20:41
MHALL3
EPA 200.8
12/03/2015 20:41
MHALL3
EPA 200.8
12/03/2015 20:41
MHALL3
EPA 200.8
12/03/2015 20:41
MHALL3
EPA 200.8
12/03/2015 20:41
MHALL3
EPA 200.8
12/03/2015 20:41
MHALL3
EPA 200.8
12/03/2015 20:41
MHALL3
EPA 200.8
12/03/2015 20:41
MHALL3
EPA 200.8
12/03/2015 20:41
MHALL3
EPA 200.8
12/03/2015 20:41
MHALL3
EPA 200.8
12/03/2015 20:41
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/03/201516:05 CJELLIO
TOC 1.1 mg/L 0.1 1 SM5310C/EPA9060A 12/02/201513:37 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS 7.0 mg/L 5 1 SM2540D 12/02/201510:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -441
Collection Date: 01 -Dec -15 3:28 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
5 EPA
INORGANIC IONS BY IC
12/02/2015 14:38
BGN9034
1 EPA
Chloride
14
mg/L
0.5
Sulfate
45
mg/L
0.5
MERCURY (COLD VAPOR) IN WATER
12/05/2015 12:48
ACPAYNE
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
200.7
12/02/2015 10:49
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
1 EPA
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
12/02/2015 10:49
FCJORDA
1 EPA
Aluminum (AI)
0.009
mg/L
0.005
Barium (Ba)
0.050
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.455
mg/L
0.01
Manganese (Mn)
0.033
mg/L
0.005
Strontium (Sr)
0.503
mg/L
0.005
Zinc (Zn)
0.013
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
12/02/2015 12:13
FCJORDA
Aluminum (AI)
0.008
mg/L
0.005
Barium (Ba)
0.050
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.419
mg/L
0.01
Manganese (Mn)
0.033
mg/L
0.005
Strontium (Sr)
0.507
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
91.8
mg/L
0.01
Magnesium (Mg)
1.35
mg/L
0.005
Potassium (K)
1.41
mg/L
0.1
Sodium (Na)
4.68
mg/L
0.05
Sample #: 2015037586
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/04/2015 09:32 LSTARL1
Vendor Method V_PACE
5 EPA
300.0
12/02/2015 14:38
BGN9034
5 EPA
300.0
12/02/2015 14:38
BGN9034
1 EPA
245.1
12/03/2015 14:26
ACPAYNE
1 EPA
245.1
12/03/2015 16:24
ACPAYNE
1 EPA
245.1
12/05/2015 12:48
ACPAYNE
1 EPA
200.7
12/02/2015 10:49
FCJORDA
1 EPA
200.7
12/02/2015 10:49
FCJORDA
1 EPA
200.7
12/02/2015 10:49
FCJORDA
1 EPA
200.7
12/02/2015 10:49
FCJORDA
1 EPA
200.7
12/02/2015 10:49
FCJORDA
1 EPA
200.7
12/02/2015 10:49
FCJORDA
1 EPA
200.7
12/02/2015 10:49
FCJORDA
1 EPA
200.7
12/02/2015 12:13
FCJORDA
1 EPA
200.7
12/02/2015 12:13
FCJORDA
1 EPA
200.7
12/02/2015 12:13
FCJORDA
1 EPA
200.7
12/02/2015 12:13
FCJORDA
1 EPA
200.7
12/02/2015 12:13
FCJORDA
1 EPA
200.7
12/02/2015 12:13
FCJORDA
1 EPA
200.7
12/02/2015 12:13
FCJORDA
1 EPA
200.7
12/02/2015 13:42
FCJORDA
1 EPA
200.7
12/02/2015 13:42
FCJORDA
1 EPA
200.7
12/02/2015 13:42
FCJORDA
1 EPA
200.7
12/02/2015 13:42
FCJORDA

Site: MW -441
Collection Date: 01 -Dec -15 3:28 PM
Analyte
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.042
Barium (Ba)
0.050
Boron (B)
< 0.05
Iron (Fe)
0.469
Manganese (Mn)
0.032
Strontium (Sr)
0.499
Zinc (Zn)
< 0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037586
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/03/2015 09:52
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:52
MHH7131
mg/L
0.05
1
EPA 200.7
12/03/2015 09:52
MHH7131
mg/L
0.01
1
EPA 200.7
12/03/2015 09:52
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:52
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:52
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:52
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:58
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:58
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:58
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:58
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:58
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:58
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:58
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:58
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:58
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:58
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 14:58
MHALL3
Thallium (TI) Low Level
0.278
ug/L
0.2
1
EPA 200.8
12/03/2015 14:58
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/03/2015 14:58
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/02/2015 15:34
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:34
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:34
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:34
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:34
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:34
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/02/2015 15:34
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:34
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:34
JAHERMA
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:34
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:34
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/02/2015 15:34
JAHERMA
Vanadium (V) Low Level
0.424
ug/L
0.3
1
EPA 200.8
12/02/2015 15:34
JAHERMA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -441
Collection Date: 01 -Dec -15 3:28 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
0.446
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
290
mg/L
25
1
Total Carbon
Sample #:
2015037586
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/03/2015 20:48
MHALL3
EPA 200.8
12/03/2015 20:48
MHALL3
EPA 200.8
12/03/2015 20:48
MHALL3
EPA 200.8
12/03/2015 20:48
MHALL3
EPA 200.8
12/03/2015 20:48
MHALL3
EPA 200.8
12/03/2015 20:48
MHALL3
EPA 200.8
12/03/2015 20:48
MHALL3
EPA 200.8
12/03/2015 20:48
MHALL3
EPA 200.8
12/03/2015 20:48
MHALL3
EPA 200.8
12/03/2015 20:48
MHALL3
EPA 200.8
12/03/2015 20:48
MHALL3
EPA 200.8
12/03/2015 20:48
MHALL3
EPA 200.8
12/03/2015 20:48
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/03/201516:05 CJELLIO
TOC 1.8 mg/L 0.1 1 SM5310C/EPA9060A 12/02/201513:37 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS 6.0 mg/L 5 1 SM2540D 12/02/201510:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -1
Collection Date: 01 -Dec -15 4:16 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 1.1 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
1 EPA
INORGANIC IONS BY IC
12/02/2015 14:56
BGN9034
1 EPA
Chloride
2.4
mg/L
0.1
Sulfate
5.6
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
12/05/2015 12:50
ACPAYNE
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
200.7
12/02/2015 10:53
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
1 EPA
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
12/02/2015 10:53
FCJORDA
1 EPA
Aluminum (AI)
0.191
mg/L
0.005
Barium (Ba)
0.009
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.009
mg/L
0.005
Strontium (Sr)
0.009
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
12/02/2015 12:17
FCJORDA
Aluminum (AI)
0.197
mg/L
0.005
Barium (Ba)
0.009
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
0.009
mg/L
0.005
Strontium (Sr)
0.009
mg/L
0.005
Zinc (Zn)
0.007
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
1.01
mg/L
0.01
Magnesium (Mg)
1.23
mg/L
0.005
Potassium (K)
1.13
mg/L
0.1
Sodium (Na)
1.44
mg/L
0.05
Sample #: 2015037587
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/04/2015 09:34 LSTARL1
Vendor Method V_PACE
1 EPA
300.0
12/02/2015 14:56
BGN9034
1 EPA
300.0
12/02/2015 14:56
BGN9034
1 EPA
245.1
12/03/2015 14:28
ACPAYNE
1 EPA
245.1
12/03/2015 16:26
ACPAYNE
1 EPA
245.1
12/05/2015 12:50
ACPAYNE
1 EPA
200.7
12/02/2015 10:53
FCJORDA
1 EPA
200.7
12/02/2015 10:53
FCJORDA
1 EPA
200.7
12/02/2015 10:53
FCJORDA
1 EPA
200.7
12/02/2015 10:53
FCJORDA
1 EPA
200.7
12/02/2015 10:53
FCJORDA
1 EPA
200.7
12/02/2015 10:53
FCJORDA
1 EPA
200.7
12/02/2015 10:53
FCJORDA
1 EPA
200.7
12/02/2015 12:17
FCJORDA
1 EPA
200.7
12/02/2015 12:17
FCJORDA
1 EPA
200.7
12/02/2015 12:17
FCJORDA
1 EPA
200.7
12/02/2015 12:17
FCJORDA
1 EPA
200.7
12/02/2015 12:17
FCJORDA
1 EPA
200.7
12/02/2015 12:17
FCJORDA
1 EPA
200.7
12/02/2015 12:17
FCJORDA
1 EPA
200.7
12/02/2015 13:46
FCJORDA
1 EPA
200.7
12/02/2015 13:46
FCJORDA
1 EPA
200.7
12/02/2015 13:46
FCJORDA
1 EPA
200.7
12/02/2015 13:46
FCJORDA

Site: MW -1
Collection Date: 01 -Dec -15 4:16 PM
Analyte
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.208
Barium (Ba)
0.010
Boron (B)
< 0.05
Iron (Fe)
0.066
Manganese (Mn)
0.008
Strontium (Sr)
0.008
Zinc (Zn)
< 0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037587
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/03/2015 09:57
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:57
MHH7131
mg/L
0.05
1
EPA 200.7
12/03/2015 09:57
MHH7131
mg/L
0.01
1
EPA 200.7
12/03/2015 09:57
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:57
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:57
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 09:57
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:05
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:05
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:05
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:05
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:05
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:05
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:05
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:05
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:05
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:05
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:05
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/03/2015 15:05
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/03/2015 15:05
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/02/2015 15:41
JAHERMA
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:41
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:41
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:41
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:41
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:41
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/02/2015 15:41
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:41
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:41
JAHERMA
Nickel (Ni)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:41
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:41
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/02/2015 15:41
JAHERMA
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/02/2015 15:41
JAHERMA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -1
Collection Date: 01 -Dec -15 4:16 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
< 25
mg/L
25
1
Total Carbon
Sample #:
2015037587
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/03/2015 20:55
MHALL3
EPA 200.8
12/03/2015 20:55
MHALL3
EPA 200.8
12/03/2015 20:55
MHALL3
EPA 200.8
12/03/2015 20:55
MHALL3
EPA 200.8
12/03/2015 20:55
MHALL3
EPA 200.8
12/03/2015 20:55
MHALL3
EPA 200.8
12/03/2015 20:55
MHALL3
EPA 200.8
12/03/2015 20:55
MHALL3
EPA 200.8
12/03/2015 20:55
MHALL3
EPA 200.8
12/03/2015 20:55
MHALL3
EPA 200.8
12/03/2015 20:55
MHALL3
EPA 200.8
12/03/2015 20:55
MHALL3
EPA 200.8
12/03/2015 20:55
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/03/201516:05 CJELLIO
TOC 0.489 mg/L 0.1 1 SM5310C/EPA9060A 12/02/201513:37 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 12/02/2015 10:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -081
Collection Date: 01 -Dec -15 12:53 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.018 mg-N/L M2 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
50
INORGANIC IONS BY IC
12/02/2015 15:50
BGN9034
1
Chloride
46
mg/L
1
Sulfate
310
mg/L
5
MERCURY (COLD VAPOR) IN WATER
12/05/2015 12:53
ACPAYNE
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 200.7
12/02/2015 10:57
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
1
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
12/02/2015 10:57
FCJORDA
1
Aluminum (AI)
0.045
mg/L
0.005
Barium (Ba)
0.040
mg/L
0.005
Boron (B)
1.07
mg/L
0.05
Iron (Fe)
1.23
mg/L
0.01
Manganese (Mn)
0.138
mg/L
0.005
Strontium (Sr)
1.20
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
12/02/2015 12:21
FCJORDA
Aluminum (AI)
0.047
mg/L
0.005
Barium (Ba)
0.041
mg/L
0.005
Boron (B)
1.08
mg/L
0.05
Iron (Fe)
1.22
mg/L
0.01
Manganese (Mn)
0.140
mg/L
0.005
Strontium (Sr)
1.21
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
95.4
mg/L
0.01
Magnesium (Mg)
9.28
mg/L
0.005
Potassium (K)
12.5
mg/L
0.1
Sodium (Na)
43.8
mg/L
0.05
Sample #: 2015037588
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/04/2015 09:41 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
12/02/2015 15:50
BGN9034
50
EPA 300.0
12/02/2015 15:50
BGN9034
1
EPA 245.1
12/03/2015 14:30
ACPAYNE
1
EPA 245.1
12/03/2015 16:38
ACPAYNE
1
EPA 245.1
12/05/2015 12:53
ACPAYNE
1
EPA 200.7
12/02/2015 10:57
FCJORDA
1
EPA 200.7
12/02/2015 10:57
FCJORDA
1
EPA 200.7
12/02/2015 10:57
FCJORDA
1
EPA 200.7
12/02/2015 10:57
FCJORDA
1
EPA 200.7
12/02/2015 10:57
FCJORDA
1
EPA 200.7
12/02/2015 10:57
FCJORDA
1
EPA 200.7
12/02/2015 10:57
FCJORDA
1
EPA 200.7
12/02/2015 12:21
FCJORDA
1
EPA 200.7
12/02/2015 12:21
FCJORDA
1
EPA 200.7
12/02/2015 12:21
FCJORDA
1
EPA 200.7
12/02/2015 12:21
FCJORDA
1
EPA 200.7
12/02/2015 12:21
FCJORDA
1
EPA 200.7
12/02/2015 12:21
FCJORDA
1
EPA 200.7
12/02/2015 12:21
FCJORDA
1
EPA 200.7
12/02/2015 13:50
FCJORDA
1
EPA 200.7
12/02/2015 13:50
FCJORDA
1
EPA 200.7
12/02/2015 13:50
FCJORDA
1
EPA 200.7
12/02/2015 13:50
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -081
Collection Date: 01 -Dec -15 12:53 PM
Analyte
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.133
Barium (Ba)
0.040
Boron (B)
1.07
Iron (Fe)
1.29
Manganese (Mn)
0.136
Strontium (Sr)
1.16
Zinc (Zn)
< 0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037588
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/03/2015 10:01
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:01
MHH7131
mg/L
0.05
1
EPA 200.7
12/03/2015 10:01
MHH7131
mg/L
0.01
1
EPA 200.7
12/03/2015 10:01
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:01
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:01
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:01
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:12
MHALL3
Arsenic (As)
10.0
ug/L
1
1
EPA 200.8
12/03/2015 15:12
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:12
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:12
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:12
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:12
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:12
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:12
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:12
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:12
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:12
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/03/2015 15:12
MHALL3
Vanadium (V) Low Level
3.12
ug/L
0.3
1
EPA 200.8
12/03/2015 15:12
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/02/2015 15:48
JAHERMA
Arsenic (As)
10.8
ug/L
1
1
EPA 200.8
12/02/2015 15:48
JAHERMA
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:48
JAHERMA
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:48
JAHERMA
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:48
JAHERMA
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:48
JAHERMA
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/02/2015 15:48
JAHERMA
Lead (Pb)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:48
JAHERMA
Molybdenum (Mo)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:48
JAHERMA
Nickel (Ni)
1.45
ug/L
1
1
EPA 200.8
12/02/2015 15:48
JAHERMA
Selenium (Se)
<1
ug/L
1
1
EPA 200.8
12/02/2015 15:48
JAHERMA
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/02/2015 15:48
JAHERMA
Vanadium (V) Low Level
3.06
ug/L
0.3
1
EPA 200.8
12/02/2015 15:48
JAHERMA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -081
Collection Date: 01 -Dec -15 12:53 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
10.7
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
1.06
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
1.25
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
3.44
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
540
mg/L
25
1
Total Carbon
Sample #:
2015037588
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/03/2015 21:02
MHALL3
EPA 200.8
12/03/2015 21:02
MHALL3
EPA 200.8
12/03/2015 21:02
MHALL3
EPA 200.8
12/03/2015 21:02
MHALL3
EPA 200.8
12/03/2015 21:02
MHALL3
EPA 200.8
12/03/2015 21:02
MHALL3
EPA 200.8
12/03/2015 21:02
MHALL3
EPA 200.8
12/03/2015 21:02
MHALL3
EPA 200.8
12/03/2015 21:02
MHALL3
EPA 200.8
12/03/2015 21:02
MHALL3
EPA 200.8
12/03/2015 21:02
MHALL3
EPA 200.8
12/03/2015 21:02
MHALL3
EPA 200.8
12/03/2015 21:02
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/03/201516:05 CJELLIO
TOC 0.567 mg/L 0.1 1 SM5310C/EPA9060A 12/02/201513:37 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 12/02/2015 10:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -06
Collection Date: 01 -Dec -15 11:05 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.023 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
50
INORGANIC IONS BY IC
12/03/2015 09:12
BGN9034
1
Chloride
44
mg/L
1
Sulfate
270
mg/L
5
MERCURY (COLD VAPOR) IN WATER
12/05/2015 12:55
ACPAYNE
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 200.7
12/02/2015 11:01
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
1
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
12/02/2015 11:01
FCJORDA
1
Aluminum (AI)
0.099
mg/L
0.005
Barium (Ba)
0.115
mg/L
0.005
Boron (B)
0.609
mg/L
0.05
Iron (Fe)
4.20
mg/L
0.01
Manganese (Mn)
0.165
mg/L
0.005
Strontium (Sr)
1.54
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
12/02/2015 12:24
FCJORDA
Aluminum (AI)
0.106
mg/L
0.005
Barium (Ba)
0.116
mg/L
0.005
Boron (B)
0.633
mg/L
0.05
Iron (Fe)
3.81
mg/L
0.01
Manganese (Mn)
0.176
mg/L
0.005
Strontium (Sr)
1.55
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
93.2
mg/L
0.01
Magnesium (Mg)
8.82
mg/L
0.005
Potassium (K)
9.66
mg/L
0.1
Sodium (Na)
36.2
mg/L
0.05
Sample #: 2015037589
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/04/2015 09:44 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
12/03/2015 09:12
BGN9034
50
EPA 300.0
12/03/2015 09:12
BGN9034
1
EPA 245.1
12/04/2015 11:26
ACPAYNE
1
EPA 245.1
12/03/2015 16:28
ACPAYNE
1
EPA 245.1
12/05/2015 12:55
ACPAYNE
1
EPA 200.7
12/02/2015 11:01
FCJORDA
1
EPA 200.7
12/02/2015 11:01
FCJORDA
1
EPA 200.7
12/02/2015 11:01
FCJORDA
1
EPA 200.7
12/02/2015 11:01
FCJORDA
1
EPA 200.7
12/02/2015 11:01
FCJORDA
1
EPA 200.7
12/02/2015 11:01
FCJORDA
1
EPA 200.7
12/02/2015 11:01
FCJORDA
1
EPA 200.7
12/02/2015 12:24
FCJORDA
1
EPA 200.7
12/02/2015 12:24
FCJORDA
1
EPA 200.7
12/02/2015 12:24
FCJORDA
1
EPA 200.7
12/02/2015 12:24
FCJORDA
1
EPA 200.7
12/02/2015 12:24
FCJORDA
1
EPA 200.7
12/02/2015 12:24
FCJORDA
1
EPA 200.7
12/02/2015 12:24
FCJORDA
1
EPA 200.7
12/02/2015 13:54
FCJORDA
1
EPA 200.7
12/02/2015 13:54
FCJORDA
1
EPA 200.7
12/02/2015 13:54
FCJORDA
1
EPA 200.7
12/02/2015 13:54
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -06
Collection Date: 01 -Dec -15 11:05 AM
Analyte
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.106
Barium (Ba)
0.117
Boron (B)
0.616
Iron (Fe)
4.36
Manganese (Mn)
0.217
Strontium (Sr)
1.45
Zinc (Zn)
< 0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037589
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/03/2015 10:05
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:05
MHH7131
mg/L
0.05
1
EPA 200.7
12/03/2015 10:05
MHH7131
mg/L
0.01
1
EPA 200.7
12/03/2015 10:05
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:05
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:05
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:05
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:19
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:19
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:19
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:19
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:19
MHALL3
Cobalt (Co)
1.23
ug/L
1
1
EPA 200.8
12/03/2015 15:19
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:19
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:19
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:19
MHALL3
Nickel (Ni)
1.62
ug/L
1
1
EPA 200.8
12/03/2015 15:19
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:19
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/03/2015 15:19
MHALL3
Vanadium (V) Low Level
0.324
ug/L
0.3
1
EPA 200.8
12/03/2015 15:19
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:28
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:28
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:28
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:28
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:28
MHALL3
Cobalt (Co)
1.42
ug/L
1
1
EPA 200.8
12/03/2015 15:28
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:28
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:28
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:28
MHALL3
Nickel (Ni)
1.82
ug/L
1
1
EPA 200.8
12/03/2015 15:28
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:28
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/03/2015 15:28
MHALL3
Vanadium (V) Low Level
0.344
ug/L
0.3
1
EPA 200.8
12/03/2015 15:28
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -06
Collection Date: 01 -Dec -15 11:05 AM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
1.34
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
1.55
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
0.560
ug/L
0.2
1
Vanadium (V) Low Level
0.410
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
510
mg/L
25
1
Total Carbon
Sample #:
2015037589
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/04/2015 13:15
MHALL3
EPA 200.8
12/04/2015 13:15
MHALL3
EPA 200.8
12/04/2015 13:15
MHALL3
EPA 200.8
12/04/2015 13:15
MHALL3
EPA 200.8
12/04/2015 13:15
MHALL3
EPA 200.8
12/04/2015 13:15
MHALL3
EPA 200.8
12/04/2015 13:15
MHALL3
EPA 200.8
12/04/2015 13:15
MHALL3
EPA 200.8
12/04/2015 13:15
MHALL3
EPA 200.8
12/04/2015 13:15
MHALL3
EPA 200.8
12/04/2015 13:15
MHALL3
EPA 200.8
12/04/2015 13:15
MHALL3
EPA 200.8
12/04/2015 13:15
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/03/201516:05 CJELLIO
TOC 3.7 mg/L 0.1 1 SM5310C/EPA9060A 12/02/201513:37 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 12/02/2015 10:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -06 DUP
Collection Date: 01 -Dec -15 11:05 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.033 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
50
INORGANIC IONS BY IC
12/03/2015 09:30
BGN9034
1
Chloride
44
mg/L
1
Sulfate
280
mg/L
5
MERCURY (COLD VAPOR) IN WATER
12/05/2015 12:57
ACPAYNE
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 200.7
12/02/2015 11:12
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
1
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
12/02/2015 11:12
FCJORDA
1
Aluminum (AI)
0.109
mg/L
0.005
Barium (Ba)
0.116
mg/L
0.005
Boron (B)
0.640
mg/L
0.05
Iron (Fe)
3.84
mg/L
0.01
Manganese (Mn)
0.187
mg/L
0.005
Strontium (Sr)
1.55
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
12/02/2015 12:28
FCJORDA
Aluminum (AI)
0.100
mg/L
0.005
Barium (Ba)
0.115
mg/L
0.005
Boron (B)
0.615
mg/L
0.05
Iron (Fe)
4.16
mg/L
0.01
Manganese (Mn)
0.163
mg/L
0.005
Strontium (Sr)
1.53
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
94.3
mg/L
0.01
Magnesium (Mg)
8.85
mg/L
0.005
Potassium (K)
10.0
mg/L
0.1
Sodium (Na)
36.7
mg/L
0.05
Sample #: 2015037590
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/04/2015 09:46 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
12/03/2015 09:30
BGN9034
50
EPA 300.0
12/03/2015 09:30
BGN9034
1
EPA 245.1
12/04/2015 11:21
ACPAYNE
1
EPA 245.1
12/03/2015 16:31
ACPAYNE
1
EPA 245.1
12/05/2015 12:57
ACPAYNE
1
EPA 200.7
12/02/2015 11:12
FCJORDA
1
EPA 200.7
12/02/2015 11:12
FCJORDA
1
EPA 200.7
12/02/2015 11:12
FCJORDA
1
EPA 200.7
12/02/2015 11:12
FCJORDA
1
EPA 200.7
12/02/2015 11:12
FCJORDA
1
EPA 200.7
12/02/2015 11:12
FCJORDA
1
EPA 200.7
12/02/2015 11:12
FCJORDA
1
EPA 200.7
12/02/2015 12:28
FCJORDA
1
EPA 200.7
12/02/2015 12:28
FCJORDA
1
EPA 200.7
12/02/2015 12:28
FCJORDA
1
EPA 200.7
12/02/2015 12:28
FCJORDA
1
EPA 200.7
12/02/2015 12:28
FCJORDA
1
EPA 200.7
12/02/2015 12:28
FCJORDA
1
EPA 200.7
12/02/2015 12:28
FCJORDA
1
EPA 200.7
12/02/2015 14:05
FCJORDA
1
EPA 200.7
12/02/2015 14:05
FCJORDA
1
EPA 200.7
12/02/2015 14:05
FCJORDA
1
EPA 200.7
12/02/2015 14:05
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -06 DUP
Collection Date: 01 -Dec -15 11:05 AM
Analyte
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.112
Barium (Ba)
0.117
Boron (B)
0.636
Iron (Fe)
4.42
Manganese (Mn)
0.190
Strontium (Sr)
1.50
Zinc (Zn)
< 0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037590
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/03/2015 10:17
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:17
MHH7131
mg/L
0.05
1
EPA 200.7
12/03/2015 10:17
MHH7131
mg/L
0.01
1
EPA 200.7
12/03/2015 10:17
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:17
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:17
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:17
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:26
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:26
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:26
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:26
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:26
MHALL3
Cobalt (Co)
1.38
ug/L
1
1
EPA 200.8
12/03/2015 15:26
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:26
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:26
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:26
MHALL3
Nickel (Ni)
1.61
ug/L
1
1
EPA 200.8
12/03/2015 15:26
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:26
MHALL3
Thallium (TI) Low Level
0.231
ug/L
0.2
1
EPA 200.8
12/03/2015 15:26
MHALL3
Vanadium (V) Low Level
0.430
ug/L
0.3
1
EPA 200.8
12/03/2015 15:26
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:35
MHALL3
Arsenic (As)
1.05
ug/L
1
1
EPA 200.8
12/03/2015 15:35
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:35
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:35
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:35
MHALL3
Cobalt (Co)
1.27
ug/L
1
1
EPA 200.8
12/03/2015 15:35
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:35
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:35
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:35
MHALL3
Nickel (Ni)
1.77
ug/L
1
1
EPA 200.8
12/03/2015 15:35
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:35
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/03/2015 15:35
MHALL3
Vanadium (V) Low Level
0.358
ug/L
0.3
1
EPA 200.8
12/03/2015 15:35
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: MW -06 DUP
Collection Date: 01 -Dec -15 11:05 AM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
1.21
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
1.02
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
0.206
ug/L
0.2
1
Vanadium (V) Low Level
0.342
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
530
mg/L
25
1
Total Carbon
Sample #:
2015037590
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/04/2015 13:21
MHALL3
EPA 200.8
12/04/2015 13:21
MHALL3
EPA 200.8
12/04/2015 13:21
MHALL3
EPA 200.8
12/04/2015 13:21
MHALL3
EPA 200.8
12/04/2015 13:21
MHALL3
EPA 200.8
12/04/2015 13:21
MHALL3
EPA 200.8
12/04/2015 13:21
MHALL3
EPA 200.8
12/04/2015 13:21
MHALL3
EPA 200.8
12/04/2015 13:21
MHALL3
EPA 200.8
12/04/2015 13:21
MHALL3
EPA 200.8
12/04/2015 13:21
MHALL3
EPA 200.8
12/04/2015 13:21
MHALL3
EPA 200.8
12/04/2015 13:21
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/03/201516:05 CJELLIO
TOC 3.7 mg/L 0.1 1 SM5310C/EPA9060A 12/02/201513:37 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 12/02/2015 10:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: CW -01
Collection Date: 01 -Dec -15 4:05 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.014 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
5 EPA 300.0
12/02/2015 20:36
INORGANIC IONS BY IC
1 EPA 245.1
12/04/2015 11:24
ACPAYNE
Chloride
4.6
mg/L
0.1
Sulfate
16
mg/L
0.5
MERCURY (COLD VAPOR) IN WATER
1 EPA 200.7
12/02/2015 11:24
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
12/02/2015 11:24
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
FCJORDA
1 EPA 200.7
12/02/2015 12:40
Aluminum (AI)
0.028
mg/L
0.005
Barium (Ba)
0.038
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.02
mg/L
0.01
Manganese (Mn)
0.038
mg/L
0.005
Strontium (Sr)
0.112
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (AI)
0.027
mg/L
0.005
Barium (Ba)
0.037
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.05
mg/L
0.01
Manganese (Mn)
0.039
mg/L
0.005
Strontium (Sr)
0.113
mg/L
0.005
Zinc (Zn)
0.013
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
20.6
mg/L
0.01
Magnesium (Mg)
0.813
mg/L
0.005
Potassium (K)
0.888
mg/L
0.1
Sodium (Na)
4.00
mg/L
0.05
Sample #: 2015037591
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/04/2015 09:47 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
12/02/2015 20:36
BGN9034
5 EPA 300.0
12/02/2015 20:36
BGN9034
1 EPA 245.1
12/04/2015 11:24
ACPAYNE
1 EPA 245.1
12/03/2015 16:47
ACPAYNE
1 EPA 245.1
12/05/2015 13:28
ACPAYNE
1 EPA 200.7
12/02/2015 11:24
FCJORDA
1 EPA 200.7
12/02/2015 11:24
FCJORDA
1 EPA 200.7
12/02/2015 11:24
FCJORDA
1 EPA 200.7
12/02/2015 11:24
FCJORDA
1 EPA 200.7
12/02/2015 11:24
FCJORDA
1 EPA 200.7
12/02/2015 11:24
FCJORDA
1 EPA 200.7
12/02/2015 11:24
FCJORDA
1 EPA 200.7
12/02/2015 12:40
FCJORDA
1 EPA 200.7
12/02/2015 12:40
FCJORDA
1 EPA 200.7
12/02/2015 12:40
FCJORDA
1 EPA 200.7
12/02/2015 12:40
FCJORDA
1 EPA 200.7
12/02/2015 12:40
FCJORDA
1 EPA 200.7
12/02/2015 12:40
FCJORDA
1 EPA 200.7
12/02/2015 12:40
FCJORDA
1 EPA 200.7
12/02/2015 14:09
FCJORDA
1 EPA 200.7
12/02/2015 14:09
FCJORDA
1 EPA 200.7
12/02/2015 14:09
FCJORDA
1 EPA 200.7
12/02/2015 14:09
FCJORDA

Site: CW -01
Collection Date: 01 -Dec -15 4:05 PM
Analyte
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.228
Barium (Ba)
0.040
Boron (B)
< 0.05
Iron (Fe)
1.62
Manganese (Mn)
0.038
Strontium (Sr)
0.119
Zinc (Zn)
< 0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037591
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/03/2015 10:29
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:29
MHH7131
mg/L
0.05
1
EPA 200.7
12/03/2015 10:29
MHH7131
mg/L
0.01
1
EPA 200.7
12/03/2015 10:29
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:29
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:29
MHH7131
mg/L
0.005
1
EPA 200.7
12/03/2015 10:29
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 17:18
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 17:18
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 17:18
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 17:18
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 17:18
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 17:18
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 17:18
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 17:18
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 17:18
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 17:18
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 17:18
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/03/2015 17:18
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/03/2015 17:18
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:43
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:43
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:43
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:43
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:43
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:43
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:43
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:43
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:43
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:43
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 15:43
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/03/2015 15:43
MHALL3
Vanadium (V) Low Level
0.402
ug/L
0.3
1
EPA 200.8
12/03/2015 15:43
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: CW -01
Collection Date: 01 -Dec -15 4:05 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
0.513
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
83
mg/L
25
1
Total Carbon
Sample #:
2015037591
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/04/2015 13:26
MHALL3
EPA 200.8
12/04/2015 13:26
MHALL3
EPA 200.8
12/04/2015 13:26
MHALL3
EPA 200.8
12/04/2015 13:26
MHALL3
EPA 200.8
12/04/2015 13:26
MHALL3
EPA 200.8
12/04/2015 13:26
MHALL3
EPA 200.8
12/04/2015 13:26
MHALL3
EPA 200.8
12/04/2015 13:26
MHALL3
EPA 200.8
12/04/2015 13:26
MHALL3
EPA 200.8
12/04/2015 13:26
MHALL3
EPA 200.8
12/04/2015 13:26
MHALL3
EPA 200.8
12/04/2015 13:26
MHALL3
EPA 200.8
12/04/2015 13:26
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/03/201516:05 CJELLIO
TOC 1.6 mg/L 1 10 SM5310C/EPA9060A 12/02/201513:37 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 12/02/2015 10:37 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: Filter Blank
Collection Date: 01 -Dec -15 5:55 PM
Analyte
Result
Units Qualifiers
RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 245.1
12/03/2015 16:45
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1
EPA 200.7
12/02/2015 11:28
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
1
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015037592
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
12/03/2015 16:45
ACPAYNE
1
EPA 200.7
12/02/2015 11:28
FCJORDA
1
EPA 200.7
12/02/2015 11:28
FCJORDA
1
EPA 200.7
12/02/2015 11:28
FCJORDA
1
EPA 200.7
12/02/2015 11:28
FCJORDA
1
EPA 200.7
12/02/2015 11:28
FCJORDA
1
EPA 200.7
12/02/2015 11:28
FCJORDA
1
EPA 200.7
12/02/2015 11:28
FCJORDA
1
EPA 200.8
12/03/2015 15:33
MHALL3
1
EPA 200.8
12/03/2015 15:33
MHALL3
1
EPA 200.8
12/03/2015 15:33
MHALL3
1
EPA 200.8
12/03/2015 15:33
MHALL3
1
EPA 200.8
12/03/2015 15:33
MHALL3
1
EPA 200.8
12/03/2015 15:33
MHALL3
1
EPA 200.8
12/03/2015 15:33
MHALL3
1
EPA 200.8
12/03/2015 15:33
MHALL3
1
EPA 200.8
12/03/2015 15:33
MHALL3
1
EPA 200.8
12/03/2015 15:33
MHALL3
1
EPA 200.8
12/03/2015 15:33
MHALL3
1
EPA 200.8
12/03/2015 15:33
MHALL3
1
EPA 200.8
12/03/2015 15:33
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: Equipment Blank
Collection Date: 01 -Dec -15 5:55 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
1 EPA 353.2
12/04/2015 09:48
INORGANIC IONS BY IC
Vendor Method
V_PACE
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
1 EPA 200.7
12/02/2015 14:21
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
12/02/2015 14:21
FCJORDA
1 EPA 200.7
Calcium (Ca)
< 0.01
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
1 EPA 200.7
12/03/2015 10:33
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015037593
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
12/04/2015 09:48
LSTARL1
Vendor Method
V_PACE
1 EPA 300.0
12/02/2015 10:28
BGN9034
1 EPA 300.0
12/02/2015 10:28
BGN9034
1 EPA 245.1
12/03/2015 14:33
ACPAYNE
1 EPA 200.7
12/02/2015 14:21
FCJORDA
1 EPA 200.7
12/02/2015 14:21
FCJORDA
1 EPA 200.7
12/02/2015 14:21
FCJORDA
1 EPA 200.7
12/02/2015 14:21
FCJORDA
1 EPA 200.7
12/03/2015 10:33
MHH7131
1 EPA 200.7
12/03/2015 10:33
MHH7131
1 EPA 200.7
12/03/2015 10:33
MHH7131
1 EPA 200.7
12/03/2015 10:33
MHH7131
1 EPA 200.7
12/03/2015 10:33
MHH7131
1 EPA 200.7
12/03/2015 10:33
MHH7131
1 EPA 200.7
12/03/2015 10:33
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120037
Site: Equipment Blank
Sample #: 2015037593
Collection Date: 01 -Dec -15 5:55 PM
Matrix: GW
WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
12/03/2015 21:09
MHALL3
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
12/03/2015 21:09
MHALL3
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
12/03/2015 21:09
MHALL3
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
12/03/2015 21:09
MHALL3
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
12/03/2015 21:09
MHALL3
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
12/03/2015 21:09
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 21:09
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 21:09
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 21:09
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 21:09
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/03/2015 21:09
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/03/2015 21:09
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/03/2015 21:09
MHALL3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
< 25
mg/L
25
1
SM2540C
12/03/2015 16:05
CJELLIO
Total Carbon
TOC
0.611
mg/L
0.1
1
SM5310C/EPA9060A
12/02/201513:37
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
1
SM2540D
12/02/2015 10:37
CJELLIO
Qualifiers:
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
-- Additional Information --
M2 - Sample 2015037588 EPA 353.2 : MS/MSD recovery below control limits at 80%.

aceAnaiXical
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December 07, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, INC 28078
[phone]
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 02, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Rodney Wilke, Duke Energy
pie p«FO
l9eORAT��y
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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CERTIFICATIONS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Nebraska Certification: NE -OS -28-14
Alabama Certification #: 41320
Nevada Certification: FL NELAC Reciprocity
Connecticut Certification M PH -0216
New Hampshire Certification M 2958
Delaware Certification: FL NELAC Reciprocity
New York Certification #: 11608
Florida Certification #: E83079
North Carolina Environmental Certificate #: 667
Georgia Certification #: 955
North Carolina Certification #: 12710
Guam Certification: FL NELAC Reciprocity
North Dakota Certification #: R-216
Hawaii Certification: FL NELAC Reciprocity
Oklahoma Certification #: D9947
Illinois Certification #: 200068
Pennsylvania Certification #: 68-00547
Indiana Certification: FL NELAC Reciprocity
Puerto Rico Certification #: FLO1264
Kansas Certification #: E-10383
South Carolina Certification: #96042001
Kentucky Certification #: 90050
Tennessee Certification #: TN02974
Louisiana Certification #: FL NELAC Reciprocity
Texas Certification: FL NELAC Reciprocity
Louisiana Environmental Certificate M 05007
US Virgin Islands Certification: FL NELAC Reciprocity
Maryland Certification: #346
Virginia Environmental Certification #: 460165
Michigan Certification #: 9911
West Virginia Certification #: 9962C
Mississippi Certification: FL NELAC Reciprocity
Wisconsin Certification #: 399079670
Missouri Certification #: 236
Wyoming (EPA Region 8): FL NELAC Reciprocity
Montana Certification #: Cert 0074
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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SAMPLE SUMMARY
Project: J15120037
Pace Project No.: 92278076
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92278076001
2015037570
Water
12/01/1514:55
12/02/1514:15
92278076002
2015037581
Water
12/01/1511:05
12/02/1514:15
92278076003
2015037582
Water
12/01/1513:43
12/02/1514:15
92278076004
2015037583
Water
12/01/1513:04
12/02/1514:15
92278076005
2015037584
Water
12/01/1512:23
12/02/1514:15
92278076006
2015037585
Water
12/01/1511:40
12/02/1514:15
92278076007
2015037586
Water
12/01/1515:28
12/02/1514:15
92278076008
2015037587
Water
12/01/1516:16
12/02/1514:15
92278076009
2015037588
Water
12/01/1512:53
12/02/1514:15
92278076010
2015037589
Water
12/01/1511:05
12/02/1514:15
92278076011
2015037590
Water
12/01/1511:05
12/02/1514:15
92278076012
2015037591
Water
12/01/1516:05
12/02/1514:15
92278076013
2015037593
Water
12/01/1517:55
12/02/1514:15
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 23

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SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
J15120037
92278076
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92278076001
2015037570
EPA 218.7
TK1
1
PASI-0
92278076002
2015037581
EPA 218.7
TK1
1
PASI-0
92278076003
2015037582
EPA 218.7
TK1
1
PASI-0
92278076004
2015037583
EPA 218.7
TK1
1
PASI-0
92278076005
2015037584
EPA 218.7
TK1
1
PASI-0
92278076006
2015037585
EPA 218.7
TK1
1
PASI-0
92278076007
2015037586
EPA 218.7
TK1
1
PASI-0
92278076008
2015037587
EPA 218.7
TK1
1
PASI-0
92278076009
2015037588
EPA 218.7
TK1
1
PASI-0
92278076010
2015037589
EPA 218.7
TK1
1
PASI-0
92278076011
2015037590
EPA 218.7
TK1
1
PASI-0
92278076012
2015037591
EPA 218.7
TK1
1
PASI-0
92278076013
2015037593
EPA 218.7
TK1
1
PASI-0
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc.. Page 4 of 23

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PROJECT NARRATIVE
Project: J15120037
Pace Project No.: 92278076
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: December 07, 2015
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
General Information:
13 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 23

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ANALYTICAL RESULTS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037570 Lab ID: 92278076001 Collected: 12/01/15 14:55 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/04/15 10:33 18540-29-9 M1
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037581 Lab ID: 92278076002 Collected: 12/01/15 11:05 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/04/15 11:12 18540-29-9
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037582 Lab ID: 92278076003 Collected: 12/01/15 13:43 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/04/15 11:25 18540-29-9
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037583 Lab ID: 92278076004 Collected: 12/01/15 13:04 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/04/15 11:38 18540-29-9
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037584 Lab ID: 92278076005 Collected: 12/01/15 12:23 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/04/15 11:51 18540-29-9
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037585 Lab ID: 92278076006 Collected: 12/01/15 11:40 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/04/15 12:04 18540-29-9
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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ANALYTICAL RESULTS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037586 Lab ID: 92278076007 Collected: 12/01/15 15:28 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/04/15 12:17 18540-29-9
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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ANALYTICAL RESULTS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037587 Lab ID: 92278076008 Collected: 12/01/15 16:16 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/04/15 12:30 18540-29-9
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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ANALYTICAL RESULTS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037588 Lab ID: 92278076009 Collected: 12/01/15 12:53 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/04/15 12:43 18540-29-9
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 14 of 23

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ANALYTICAL RESULTS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037589 Lab ID: 92278076010 Collected: 12/01/15 11:05 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/04/15 12:56 18540-29-9
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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ANALYTICAL RESULTS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037590 Lab ID: 92278076011 Collected: 12/01/15 11:05 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/04/15 13:35 18540-29-9
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
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ANALYTICAL RESULTS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037591 Lab ID: 92278076012 Collected: 12/01/15 16:05 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/04/15 14:14 18540-29-9
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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ANALYTICAL RESULTS
Project: J15120037
Pace Project No.: 92278076
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037593 Lab ID: 92278076013 Collected: 12/01/15 17:55 Received: 12/02/15 14:15 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/04/15 14:27 18540-29-9
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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Page 18 of 23

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QUALITY CONTROL DATA
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: J15120037
Pace Project No.: 92278076
QC Batch: WETA/52715
Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7
Analysis Description: Chromium, Hexavalent IC
Associated Lab Samples: 92278076001, 92278076002,
92278076003, 92278076004, 92278076005, 92278076006, 92278076007,
92278076008,92278076009,92278076010,92278076011,92278076012,92278076013
METHOD BLANK: 1410073
Matrix: Water
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Chromium, Hexavalent ug/L
ND 0.030 12/04/15 10:07
LABORATORY CONTROL SAMPLE: 1410074
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Chromium, Hexavalent ug/L
.075 0.074 99 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1410075 1410076
MS MSD
92278076001
Spike Spike MS MSD MS MSD
% Rec
Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits
RPD RPD Qual
Chromium, Hexavalent ug/L ND
.025 .025 .029J ND 117 118
85-115
20 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1410077 1410078
MS MSD
92278076011
Spike Spike MS MSD MS MSD
% Rec
Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits
RPD RPD Qual
Chromium, Hexavalent ug/L ND
.075 .075 0.086 0.073 115 97
85-115
17 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/07/2015 04:05 PM without the written consent of Pace Analytical Services, Inc..
Page 19 of 23

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QUALIFIERS
Project: J15120037
Pace Project No.: 92278076
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15120037
Pace Project No.: 92278076
Lab ID Sample ID QC Batch Method QC Batch
92278076001
2015037570
EPA 218.7
WETA/52715
92278076002
2015037581
EPA 218.7
WETA/52715
92278076003
2015037582
EPA 218.7
WETA/52715
92278076004
2015037583
EPA 218.7
WETA/52715
92278076005
2015037584
EPA 218.7
WETA/52715
92278076006
2015037585
EPA 218.7
WETA/52715
92278076007
2015037586
EPA 218.7
WETA/52715
92278076008
2015037587
EPA 218.7
WETA/52715
92278076009
2015037588
EPA 218.7
WETA/52715
92278076010
2015037589
EPA 218.7
WETA/52715
92278076011
2015037590
EPA 218.7
WETA/52715
92278076012
2015037591
EPA 218.7
WETA/52715
92278076013
2015037593
EPA 218.7
WETA/52715
Date: 12/07/2015 04:05 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Analytical Method
Analytical
Batch
Page 21 of 23

aCMnalydcal n
Document Name: Document Revised: November 11, 1U1b
Sample Condition Upon Roe i t (SCUR) Pae 1 of 2*
Document Number: Issuing Authority:
F-CHR-CS-003-rev.16.1 Pace Huntersville Quality Office
lent Name:- LL /(� Llv * Page 2 of 2 is for Internal Use Only
:ourier: ❑ Fed E)] UPC]USP❑ Clier❑l Com erclo] -ac Other Optional
:ustody Seal on Cooler/Box Present: Elyes ❑ no S als intact: El yes El no Proj. Due Date:
Proj. Name:
lacking Material: E] Bubble Wrap ❑ Bubble Bags None ❑ Other
rhermometer Used: IR Gun 505 Type of Ice: e)e Blue None amptes on ice, cooling process has begun
rte..., r` .��e,.0-- C.r4nr Nn .n�rrpntinn
•
corrected Cooler Temp.: C
remp should be above freezing to 6*C
Biological Tissue is Frozen: Yes No A
Comments:
/ Date and Initials of person examini�}9
contents:
-hain of Custody Present:
Yes ONO
❑NIA
1.
;hain of Custody Filled Out:
Dyes
ONO
IJ NIA
2.
;hain of Custody Relinquished:
es
No
El NIA
3.
7ampler Name & Signature on COC:
DYes
❑No
❑NIA
4.
Samples Arrived within Hold Time:
❑ ems
ONO
❑NIA
5.
Short Hold Time Analysis (<72hr):
❑Yes
El No
El N/A
6.
Rush Turn Around Time Requested:
❑Yes
EINO
❑NIA
7.
Sufficient Volume:
❑Yes
o
❑NIA
S.
/° t, f / 0,A Y
Correct Containers Used:
-Pace Containers Used:
�., e�s ❑No
13Yes No
❑N!A
❑NIA
9.
Containers Intact:
Yes
ONO
1-7 NIA
10.,-
0.-Filtered
Filteredvolume received for Dissolved tests
❑Yes
[]No
Nh<
11.
Sample Labels match COG:
-Includes date/time/ID/Analysis Matrix.
CV ' No
°�'—
❑NIA
12.
All containers needing preservation have been checked.
All containers needing preservation are found to be in
with EPA recommendation.
exceptions: VOA, coliform, TOC, 0&G, WI -DRO (water)
❑Yes
Dyes
❑Yes
C]No
ONO
❑ o
E] NIA
0141compliance
13.
Samples checked for dechlorination:
❑Yes
[]No
EPOA
14.
Headspace in VOA Vials (>6mm):
❑Yes
❑No
P 1A
15.
Trip Blank Present:
Trip Blank Custody Seals Present
Pace Trip Blank Lot # (if purchased):
Dyes
❑Yes
0 N
ONO
PKA
CSMA
1
Client Notification/ Resolution: Field Data Required? Y 1 N
Person Contacted: DatelTime:
Comments/ Resolution:
SCURF Review: M 1 Date: I t2,12 11S
SRF Review: nate:
Note: Wheneverthere is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office (1.e out of hold, incorrect preservative, out of temp,
Incorrect containers)
4➢Otb: 9e^.278076
1111111111111111111111
92278076
Page 22 of 23

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V i oG} G z 9C�,
j Page 23 of 23

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name: AB GW Assessment Water - Weatherspoon
Project Number:J15120037
Lot Number:QL03066
Date Completed: 12/09/2015
Grant Wilton
Project Manager
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Shealy Environmental Services, Inc. Page: 1 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
LAUCRATORY
ACCREDITATION
TNI
CARO*
�yURE}rAU ...l�y,�y
DO
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QL03066
Project Name: AB GW Assessment Water - Weatherspoon
Project Number: J15120037
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QL03066
Project Name: AB GW Assessment Water - Weatherspoon
Project Number: J15120037
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015037570
Aqueous
12/01/20151455
12/03/2015
002
2015037581
Aqueous
12/01/20151105
12/03/2015
003
2015037582
Aqueous
12/01/20151343
12/03/2015
004
2015037583
Aqueous
12/01/20151304
12/03/2015
005
2015037584
Aqueous
12/01/20151223
12/03/2015
006
2015037585
Aqueous
12/01/20151140
12/03/2015
007
2015037586
Aqueous
12/01/20151528
12/03/2015
008
2015037587
Aqueous
12/01/20151616
12/03/2015
009
2015037588
Aqueous
12/01/20151253
12/03/2015
010
2015037589
Aqueous
12/01/20151105
12/03/2015
011
2015037590
Aqueous
12/01/20151105
12/03/2015
012
2015037591
Aqueous
12/01/20151605
12/03/2015
013
2015037593
Aqueous
12/01/20151755
12/03/2015
3 samples
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(31 detections)
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SHEALY ENVIRONMENTAL SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QL03066
Project Name: AB GW Assessment Water
- Weatherspoon
Project Number: J15120037
Sample Sample ID
Matrix
Parameter
Method
Result Q
Units
Page
001
2015037570
Aqueous
Alkalinity
SM 2320B-
110
mg/L
5
001
2015037570
Aqueous
Bicarbonate Alkalinity
SM 2320B-
110
mg/L
5
001
2015037570
Aqueous
Methane
RSK - 175
28
ug/L
6
002
2015037581
Aqueous
Alkalinity
SM 2320B-
180
mg/L
7
002
2015037581
Aqueous
Bicarbonate Alkalinity
SM 23208-
180
mg/L
7
002
2015037581
Aqueous
Methane
RSK - 175
600
ug/L
8
003
2015037582
Aqueous
Alkalinity
SM 2320B-
120
mg/L
9
003
2015037582
Aqueous
Bicarbonate Alkalinity
SM 2320B-
120
mg/L
9
003
2015037582
Aqueous
Methane
RSK - 175
23
ug/L
10
004
2015037583
Aqueous
Alkalinity
SM 2320B-
120
mg/L
11
004
2015037583
Aqueous
Bicarbonate Alkalinity
SM 2320B-
120
mg/L
11
004
2015037583
Aqueous
Methane
RSK - 175
15
ug/L
12
005
2015037584
Aqueous
Alkalinity
SM 2320B-
180
mg/L
13
005
2015037584
Aqueous
Bicarbonate Alkalinity
SM 2320B-
180
mg/L
13
005
2015037584
Aqueous
Methane
RSK - 175
22
ug/L
14
006
2015037585
Aqueous
Methane
RSK - 175
11
ug/L
16
007
2015037586
Aqueous
Alkalinity
SM 2320B-
180
mg/L
17
007
2015037586
Aqueous
Bicarbonate Alkalinity
SM 2320B-
180
mg/L
17
007
2015037586
Aqueous
Methane
RSK - 175
60
ug/L
18
009
2015037588
Aqueous
Alkalinity
SM 2320B-
58
mg/L
21
009
2015037588
Aqueous
Bicarbonate Alkalinity
SM 2320B-
58
mg/L
21
009
2015037588
Aqueous
Methane
RSK - 175
590
ug/L
22
010
2015037589
Aqueous
Alkalinity
SM 2320B-
36
mg/L
23
010
2015037589
Aqueous
Bicarbonate Alkalinity
SM 2320B-
36
mg/L
23
010
2015037589
Aqueous
Methane
RSK - 175
20
ug/L
24
011
2015037590
Aqueous
Alkalinity
SM 2320B-
36
mg/L
25
011
2015037590
Aqueous
Bicarbonate Alkalinity
SM 2320B-
36
mg/L
25
011
2015037590
Aqueous
Methane
RSK - 175
24
ug/L
26
012
2015037591
Aqueous
Alkalinity
SM 2320B-
41
mg/L
27
012
2015037591
Aqueous
Bicarbonate Alkalinity
SM 2320B-
41
mg/L
27
012
2015037591
Aqueous
Methane
RSK - 175
93
ug/L
28
(31 detections)
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QL03066-001
Description: 2015037570 Matrix: Aqueous
Date Sampled: 12/01/2015 1455 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 1920 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 1920 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 1920 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
110
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
110
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID: QL03066-001
Description: 2015037570 Matrix: Aqueous
Date Sampled: 12/01/2015 1455 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1330 JJG 91655
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 28 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 6 of 30
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QL03066-002
Description: 2015037581 Matrix: Aqueous
Date Sampled: 12/01/2015 1105 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 1927 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 1927 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 1927 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 7 of 30
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CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
180
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
180
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 7 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QL03066-002
Description: 2015037581 Matrix: Aqueous
Date Sampled: 12/01/2015 1105 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1430 JJG 91655
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 600 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 8 of 30
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QL03066-003
Description: 2015037582 Matrix: Aqueous
Date Sampled: 12/01/2015 1343 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 1933 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 1933 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 1933 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 9 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
120
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
120
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 9 of 30
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Methane
Client: Duke Energy Laboratory ID: QL03066-003
Description: 2015037582 Matrix: Aqueous
Date Sampled: 12/01/2015 1343 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1447 JJG 91655
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 23 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QL03066-004
Description: 2015037583 Matrix: Aqueous
Date Sampled: 12/01/2015 1304 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 1953 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 1953 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 1953 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 11 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
120
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
120
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 11 of 30
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Methane
Client: Duke Energy Laboratory ID: QL03066-004
Description: 2015037583 Matrix: Aqueous
Date Sampled: 12/01/2015 1304 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1504 JJG 91655
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 15 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 12 of 30
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QL03066-005
Description: 2015037584 Matrix: Aqueous
Date Sampled: 12/01/2015 1223 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 1959 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 1959 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 1959 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 13 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
180
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
180
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 13 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QL03066-005
Description: 2015037584 Matrix: Aqueous
Date Sampled: 12/01/2015 1223 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1530 JJG 91655
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 22 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 14 of 30
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QL03066-006
Description: 2015037585 Matrix: Aqueous
Date Sampled: 12/01/2015 1140 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 2020 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 2020 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 2020 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 15 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
ND
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 15 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QL03066-006
Description: 2015037585 Matrix: Aqueous
Date Sampled: 12/01/2015 1140 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1547 JJG 91655
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 11 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 16 of 30
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QL03066-007
Description: 2015037586 Matrix: Aqueous
Date Sampled: 12/01/2015 1528 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 2027 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 2027 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 2027 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 17 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
180
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
180
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 17 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QL03066-007
Description: 2015037586 Matrix: Aqueous
Date Sampled: 12/01/2015 1528 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1604 JJG 91655
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 60 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 18 of 30
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QL03066-008
Description: 2015037587 Matrix: Aqueous
Date Sampled: 12/01/2015 1616 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 2031 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 2031 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 2031 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 19 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
ND
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 19 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QL03066-008
Description: 2015037587 Matrix: Aqueous
Date Sampled: 12/01/2015 1616 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1641 JJG 91655
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QL03066-009
Description: 2015037588 Matrix: Aqueous
Date Sampled: 12/01/2015 1253 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 2036 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 2036 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 2036 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 21 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
58
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
58
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 21 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QL03066-009
Description: 2015037588 Matrix: Aqueous
Date Sampled: 12/01/2015 1253 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1721 JJG 91655
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 590 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 22 of 30
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Inorganic non-metals
Client: Duke Energy Laboratory ID: QL03066-010
Description: 2015037589 Matrix: Aqueous
Date Sampled: 12/01/2015 1105 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 2041 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 2041 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 2041 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 23 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
36
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
36
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 23 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QL03066-010
Description: 2015037589 Matrix: Aqueous
Date Sampled: 12/01/2015 1105 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1738 JJG 91655
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 20 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 24 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID: QL03066-011
Description: 2015037590 Matrix: Aqueous
Date Sampled: 12/01/2015 1105 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 2046 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 2046 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 2046 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 25 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
36
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
36
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 25 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QL03066-011
Description: 2015037590 Matrix: Aqueous
Date Sampled: 12/01/2015 1105 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1755 JJG 91655
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 24 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 26 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID: QL03066-012
Description: 2015037591 Matrix: Aqueous
Date Sampled: 12/01/2015 1605 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 2104 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 2104 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 2104 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 27 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
41
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
41
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 27 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QL03066-012
Description: 2015037591 Matrix: Aqueous
Date Sampled: 12/01/2015 1605 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1811 JJG 91655
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 93 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 28 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID: QL03066-013
Description: 2015037593 Matrix: Aqueous
Date Sampled: 12/01/2015 1755 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/04/2015 2108 MJI 91396
1 (Bicarbonate ) SM 2320B-2011 1 12/04/2015 2108 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/04/2015 2108 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 29 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
ND
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 29 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID: QL03066-013
Description: 2015037593 Matrix: Aqueous
Date Sampled: 12/01/2015 1755 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J15120037
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 12/08/2015 1828 JJG 91655
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 30 of 30
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03066
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - MB
Sample ID: QQ91396-001 Matrix: Aqueous
Batch:91396
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 12/04/20151828
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03066
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - LCS
Sample ID: QQ91396-002 Matrix: Aqueous
Batch:91396
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 92 1 92 90-110 12/04/20151834
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03066
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - MS
Sample ID: QL03066-005MS Matrix: Aqueous
Batch: 91396
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 180 100 260 1 80 70-130 12/04/2015 2007
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03066
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - MSD
Sample ID: QL03066-005MD Matrix: Aqueous
Batch: 91396
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity 180 100 260 1 83 1.1 70-130 20 12/04/2015 2015
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03066
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - MB
Sample ID: QQ91655-001 Matrix: Aqueous
Batch:91655
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 12/08/2015 1149
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03066
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - LCS
Sample ID: QQ91655-002 Matrix: Aqueous
Batch:91655
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 300 310 1 105 70-130 12/08/20151117
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03066
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - LCSD
Sample ID: QQ91655-003 Matrix: Aqueous
Batch:91655
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 300 320 1 110 4.8 70-130 30 12/08/20151216
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03066
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Chain of Custody
and
Miscellaneous Documents
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

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SHEALY ENVIRONMENTAL SERVICES, INC.
Skdt Eaxlron m and Smirt�q, liar.
Mcumord Numbt4.: biatm]6C. W
Sample Receipt Checklist (SRC)
Cticnt: rZy Cooler inspected bydate:`�*�.a.^�•-,.?is Lot #:
Pale L of ]
ruptaces dame_ 13W23A 5
.Effecive Dow MIA
l4eans of receipt: SESI L) (:lient ❑ UPS ❑ FedEx ❑ other
Yep EJ I No
i. Wcrc CUE dy seals (Mrnl tan the coulta?
Yes Ej I Na El I NA
2_ If custody seals here present, vtnere they intact and unbTokcrm?
pH strip H): C1 strip ID-.__.. _
Cooler ]Dffiri?i l t / iure upon 5ivc G'Deriv�ed (c�arrected) temperature opaai receipt: �r
/I.Q,! L� �'4.. f 1 ,` I I 45r
Mdhoda ❑ 'Temperature B nk 2rAgainsi Baffles Ili Gun IIS IR Gula Ccefection Faclor,0— 0 12C:
Method ofcoolwt: et ice ❑ Blue Ince ❑ ory Ice ❑ N(me
Yes ❑ No ❑ Ns
3. if tempemturc of any coolmr cxceedcd 6,0'C, yr Project Mamiger notified? FM
notified by SRC, phone, note (circle one), other:
(For coolers received via commercial courier, PMs arc to be notim
i:mmediatclv,)
Yes _ o EJ 1 A Z
4_ is the cm=ercial courier's packing slip attachM to thio F4ir,n?
Yrs _ No
5_ Were proper cusrutidy° procedures (relin uish.edn=0iVCd) follcwcd?
ycs LNU ^I N,.k Pr
54 Were sam le>s re"quished by client to conunercial courier?
cs N0
6, Were sample ins listed cin the COC -9
Yes FA Ko ❑
?, )AVc same lc Llys IiBA cru all mwple wMaitiera?
Yes b:io-
d. Was c( lection date cit tirnc listed on the coc')
Yes I'cr
9_ Was colleotiondate & time listed on all sa Ic ontaincrs?
y€s leo.
10, Did all [:omrr4miner label i�7f= niatior3 ID, dark tutae) agree with the C ?
Yes 1Z K'0 °]
11. Were tests to be perfLwmW ]3sted on the COC;
Yes o ❑
1 ?. Did all qaWks arriv+c in the er containers for each test'.
Y" 0
13_ Did all cornainers arrive in goad cmidifion unbrol un. lids on. ctG.)?
Yvs N07
14, Was s u4te ymple %,olume available?
Yes ❑ No
15. W ac all sumplca] reoeived within `fix tha holding tiaue or 48 hours, whichever
Mines fust?
ycki ❑ Nu
16. Were any Samples containers misrdng?
YcmL No
1.7_ Were there any excess sam lcs not lived can COC ?
Ycg El I No NA El
1 S. Were bubbles present -";Rea 6mm in diarm cw in an )'OA vialary
}des, ❑ No 0 NA
19, -Were. all metals; O&Glll2M?nutricw mrinpics mvv,6 ved A a pH of 'r
Yes ❑ No ❑ NA
20, NVmrc ell cya side an&or sulfide sain les r€ceivcd ata pH rt 12?
Yes E] 1`a o E] NA
2.1. Weres all applicable Nil3KXN{cy w iddphenol (<01mg1) samples frm -of
residual clslmrrine?
Yes U leo NART
21 Werc collcrlion tern ermttures documented on the CUC ibr NC ba i -o
Yea ❑ ITU ❑ NAIL
`?, Werc client r=larks reiuests (i.e. rexuesced ditutims, MS/MSD k5ignatio ,
&c.. - . mrrectly transmi bed from the COC ixatr} the coranwmE w -mon in LI_MS .
Yes N0
24_ -Was the quote ri mminber used takes from the a mtain mer lah-21''
Semple Preservatimmn
(T umi. becompleted for any sample(s) i>ioorre-Uly preSff%resd or with headspacc,)
sarnple(s) _were reAved incwrectly preserved and were adjuatod
accordinoy in Maple recei Mig wmlh (H�8 i4, HNO3, iiC1, NaOH) using SR #
sample(s)
were receivod with bubbles >6 mm in diameter,
sample(s).
were n:Lvived with TRC ; -0.2 inp (If #j i No
SC Orinkirmg W atcr F'i-jecl Sainple(s) pH--crificd to bo -J2 by Bate. _
sample(s) urue sot rmm:ivesl at rt PH qf �-2 and were 30justed acQardi ly U%inx SR4
sample lie a liedb
: S=S,, Verified by-- Dale,
cpmnlcu :
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

�C'��I�E�Cit• _
EIer neat One Inc.
6319-D Carolina Beach Rd.
@4 Hming$on, SIC 28412
Phone: [phone]
Fax: [phone]
[e-mail]
26261-1
REPORT OF ANALYSES
< 0.1 mg/L 1
Duke Energy
December 9, 2015
1455
Laboratory Services
Client Project Name AB GW Assessment water Phase 3 (wells)
< 0.1 mg/L 1
Weatherspoon
12/01/15
13339 Hagers Ferry Road Bld.
MG03A Client Project Number J15120037
MW -55D Sulfide
Huntersville, NC 28078
PO Number
12/01/15
Sample Matrix GW WW
Sample Type Grab Date Received
12/03/2015
Date Analyzed 12/04/2015
Method SM 4500 S2_ D Time Received
1325
Delivered by Courier
Received by
LLB
eOne ID Duke Energy ID
Parameter Result Unit Dil DL Date
Time
1223
Sampled
Sampled
26261-1
MW -2 Sulfide
< 0.1 mg/L 1
0.1
12/01/15
1455
26261-2
MW -3 Sulfide
< 0.1 mg/L 1
0.1
12/01/15
1105
26261-3
MW -55D Sulfide
< 0.1 mg/L 1
0.1
12/01/15
1343
26261-4*
MW -04 Sulfide
< 0.2 mg/L 2
0.1
12/01/15
1304
26261-5*
MW -551 Sulfide
< 0.2 mg/L 2
0.1
12/01/15
1223
26261-6
MW -05 Sulfide
< 0.1 mg/L 1
0.1
12/01/15
1140
26261-7
MW -441 Sulfide
< 0.1 mg/L 1
0.1
12/01/15
1528
26261-8
MW -1 Sulfide
< 0.1 mg/L 1
0.1
12/01/15
1616
*Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Ken ocmirh, Laboratory Director
Page 1 of 2
26261 Duke Report Packet Compiled by-ln:z
NC Certifications:
DW 37788 and DWQ DENR 604

Element One Onc.
6319-D Carolina Beach Rd.
WOmington, VAC 28412
Phone: [phone]
Fax: [phone]
e1 Vab w@e1 Vab.comra
26261-9
REPORT OF ANALYSES
Sulfide
0.434
Duke Energy
December 9, 2015
0.1
12/01/15
Laboratory Services
Client Project Name AB GW Assessment
water Phase
3 (wells)
< 0.1
Weatherspoon
1
0.1
13339 Hagers Ferry Road Bld.
MG03A Client Project Number J15120037
26261-11
MW -06 Dup
Huntersville, NC 28078
PO Number
mg/L
1
Sample Matrix GW WW
Sample Type Grab
Date Received
12/03/2015
Date Analyzed 12/04/2015
Method SM 4500 S2- D
Time Received
1325
Delivered by Courier
0.1
Received by
LLB
eOne ID Duke Energy ID
Parameter Result Unit Dil
DL Date
Time
mg/L
1
Sampled
Sampled
26261-9
MW -081
Sulfide
0.434
mg/L
1
0.1
12/01/15
1253
26261-10
MW -06
Sulfide
< 0.1
mg/L
1
0.1
12/01/15
1105
26261-11
MW -06 Dup
Sulfide
< 0.1
mg/L
1
0.1
12/01/15
1105
26261-12
CW -01
Sulfide
0.467
mg/L
1
0.1
12/01/15
1605
26261-13
Equipment Blank
Sulfide
< 0.1
mg/L
1
0.1
12/01/15
1755
Page 2 of 2
NC Certifications: DW 37788 and DWQ DENR 604

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elementOne SAMPLE SUBMISSION FORM Lab ID 26261
Report TAT 7 Days Analysis Due Date 12.07.15
Hold Time Expiration 12.08.15 @ 1105 Report Due Date 12.14.15
Client: Duke Energy Date Rec: 12.03.15
LIMS No J15120037 Time Rec: 1325
Project ID Weathers oon Rec By LLB
H >9 Ye =No= Tem <_ 6°C No Ref. Method:
If No, Record I If No, Record SM4500 S2 D
. dmpiG mummuimun at %.ouection inrormation
Lab ID Client ID
Collection Date
Collection Time
Analysis Requested
1 MW -2
12.01.15
1455
-5111 fide
2 MW -3
12 01 15
1105
ulfi
3.._ MW -5 5 D _
12.01 15
1343
_
4 MW -04
_
12.01.15
1304
5 MW -551
12.01.15
1223
6 MW -05
_ ....
12.01.15
1140ul
ifif e
7 MW -441
12.01.15
1528
�ulfid2
2.01.15
1616_
9 MW -08112.01.15
...12.01.15
1253
e
10 MW -06
- _-
1105......
11 MW -06 Dup
12.01.15
1105
12 CW -01
12 01.151605
13 Equipment Blank
12.01.15 __.. __._.1755_
__.. ... __--
ulfide
NOTE for SulfideI The MS/MSD spike should approximate 2 to 3 times the sample concentration. If no sulfide detected
at 100 pg/L spike the sample to render the final spike concentration at - 500 pg/L
SS Page 1 f 1 Prep By / Date l 1 H 15
SS by Labeled By / Date 4 E is - 3 . t 5-
12/4/2015
12/4/2015 1:28:20 PM ID Verification By /Date L4r— I X L(,(�

METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT gM
1.000
CLIENT: Duke
SPK LEVELLuM
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
XY
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17.10
KAM / DAM
------
0
STD 0.600--- -
ABS 0'°°
0.000 ��
0.094 0.400
0.240 0300
0.200
0.443 0.100 ----
0.633 0000
0.00 2.00 4.00 6.00
0.826 i X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
_0 0.626
6
800 1000
10.00
X
10
10
Y
-
-'S0
12.00
Slope
0.082116484
Correlation
0.999009688
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810 1
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26260-1
0.007
-0.2996
10
10
10
<
26260-1 SPK
0.319
3.6534
10
10
10
0.365
73%
5.0
26260-2
0.167
1.7276
10
10
10
0.173
26260-2 DUP
0.154
1.5629
10
10
10
0.156'' '
10%
26260-2 SPK
0.563
6.7448
10
10
10
0.674
104%
5.0
26260-3
0.041
0.1312
10
10
10
< 0.1
26260-3 SPK
0.447
5.2751
10
10
10
0.528
106%
5.0
26260-4
0.001
-0.3756
10
10
10
< OA -
26260 -4 SPK
0.417
4.8950
10
10
10
0.490
98%
5.0
26260-5
0.001
-0.3756
10
10
10
<
26260-5 SPK
0.313
3.5774
10
10
10
0.358
72%
5.0
26260-6
0.007
-0.2996
10
10
10
<
26260-6 SPK
0.187
1.9810
10
10
10
0.198
40%
5.0
26260-7
2.350
29.3857
10
10
10
2.939
26260-7 SPK
2.454
30.7034
10
10
10
3.070
26%
5.0
26260-8
0.003
-0.3503
10
10
10
<
26260-8 SPK
0.307
3.5014
10
10
10
0.350
70%
5.0
26260-9
0.000
0.0000
10
10
10
26260-9 SPK
0.466
5.5158
10
10
10
0.552
110%
5.0
#VALUE!
Blank
0.000
0.0000
10
10
10
<
QC
0.458 1
5.4145 1
10
10
10
0.541
108%
0
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 1 of 16

METHOD:
SM 4555 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVEL (ug)
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
ug STD
SOLUTION
0.00
1.00
2.50
500
7.50
10.00
26260 / 261 / 262 ! 266 / 267 / 268
12/04/15 Na2S•91-12O Lot #
8:00 40721
17:10
KAM / DAM
0.
STD o.eoo
ABS 0700
0�
0.000
0.094 0.400
0.240 0300
0.200 .240
0.443 0.+.
0.633 00°°.� z.W 4.00 6.00
0.826
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
e
s 13
- - -
3.00 low
10.00
X
10
10
Y
--500
�'.50
12100
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26260-10
0.000
0.0000
10
10
10
<_0.1
26260-10 SPK
0.447
5.2751
10
10
10
0.528
106%
5.0
26261-1
0.013
-0.2236
10
10
10
26261-1 DUP
0.001
-0.3756
10
10
10
< 0.1
N/A
26261-1 SPK
0.435
5.1231
10
10
10
0.512
102%
5.0
26261-2
0.002
-0.3629
10
10
10
< 0.1
26261-2 SPK
0.408
4.7810
10
10
10
0.478
96%
5.0
26261-3
0.004
-0.3376
10
10
10
< 0.1
26261-3 SPK
0.436
5.1358
10
10
10
0.514
103%
5.0
26261-4
0.000
0.0000
10
10
10
<
26261-4 SPK
0.337
3.8814
10
10
10
0.388
78%
5.0
26261-5
0.003
-0.3503
10
10
10
<
26261-5 SPK
0.338
3.8941
10
10
10
0.389
78%
5.0
26261-6
0.003
-0.3503
10
10
10
< 0.1
26261-6 SPK
0.433
5.0977
10
10
10
0.510
102%
5.0
26261-7
0.013
-0.2236
10
10
10
< 0.1
26261-7 SPK
0.407
4.7683
10
10
10
0.477
95%
5.0
26261-8
0.000
0.0000
10
10
10
'50.1
26261-8 SPK
0.450
5.3131
10
10
10
0.531
106%
5.0
Blank
0.000
0.0000
10
10
10 1
<
QC
0.459
5.4272
10
10 1
10 1
0.543
109%
5.0
Submitted for QA/QC- Date: 12/07/15
By: (Print) IKAM
/ DAM
(sign):
Page 2 of 16
/ ��

METHOD:
SM 4500 S2- U
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT (u
1.000
CLIENT: Duke
SPK LEVELLucjl
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y
x.eox T-
5TD aeon
ABS 0.700
0.000 0.600
0001
0.094 0.400
0.240 0.200 .240
0.443
0.633 0.1x0.00 2.00 401 e.0o
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
One
-
011 low
10.00
X
10
10
Y
---°�
-'�
12.00
_
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26261-9
0.373
4.3376
10 1
10
10
26261-9 SPK
0.773
9.4055
10
10
10
0.941
101%
5.0
26261-10
0.003
-0.3503
10
10
10
26261-10 SPK
0.442
5.2118
10
10
10
0.521
104%
5.0
26261-11
0.003
-0.3503
10
10
10
0.1
26261-11 DUP
0.004
-0.3376
10
10
10
< 0.1
N/A
26261-11 SPK
0.440
5.1864
10
10
10
0.519
104%
5.0
26261-12
0.399
4.6670
10
10
10
'0.467:
26261-12 SPK
0.802
9.7729
10
10
10
0.977
102%
5.0
26261-13
0.001
-0.3756
10
10
10
<Q.1:
26261-13 SPK
0.443
5.2244
10
10
10
0.522
104%
5.0
26262-1
0.004
-0.3376
10
10
10
26262-1 SPK
0.399
4.6670
10
10
10
0.467
93%
5.0
26262-2
0.000
0.0000
10
10
10
' 0.'1
26262-2 SPK
0.375
4.3629
10
10
10
0.436
87%
5.0
26262-3
0.179
1.8796
10
10
10
7777ER
26262-3 SPK
0.604
7.2643
10
10
10
0.726
108%
5.0
26262-4
0.004
-0.3376
10
10
10
<
26262-4 SPK
0.358
4.1475
10
10
10
0.415
83%
5.0
Blank
0.000
0.0000 1
10
10
10
<
QC
0.458
5.4145 1
10
10
10
0.541
108%
5.0
Submitted for QA/QC- Date:12/07/15
By: (Print)
KAM / DAM
(sign): , ,
Page 3 of 16

METHOD:
SM 4555 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT (u
1.000
CLIENT: Duke
SPK LEVEL u
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM /DAM
Y
STD 0.000 --
ABS 0700 -
0.000 0.800
V500 -
0.094 + 0.400
0.240 1 0� --
0.200
0.443 alm -
0.633 0000
0.00 2.00 4.00 8.00
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD-44-3
QC Std Lot: SD-44-4
STD ABSORPTION
0. B
8.00 1000
10.00
X
10
10
Y
4�
-+-250
-'�
taco
12.00
_
Slope
0.082116484
Correlation
0.999009688
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26262-5
0.023
-0.0969
10
10
10
< 0.1
26262-5 SPK
0.443
5.2244
10
10
10
0.522
104%
5.0
26262-6
0.000
0.0000
10
10
10
`0.1
26262-6 SPK
0.376
4.3756
10
10
10
0.438
88%
5.0
26262-7
0.178
1.8669
10
10
10
0.187
26262-7 SPK
0.572
6.8588
10
10
10
0.686
100%
5.0
26262-8
0.000
0.0000
10
10
10
< 0.11
26262-8 DUP
0.000
0.0000
10
10
10
< 0.1
N/A
26262-8 SPK
0.375
4.3629
10
10
10
0.436
87%
5.0
26262-9
0.009
-0.2742
10
10
10
<
26262-9 SPK
0.120
1.1321
10
10
10
0.113
23%
5.0
26262-10
0.011
-0.2489
10
10
10
< 0.1
26262-10 SPK
0.400
4.6796
10
10
10
0.468
94%
5.0
26262-11
0.010
-0.2616
10
10
10
< Q.
26262-11 SPK
0.419
4.9204
10
10
10
0.492
98%
5.0
26262-12
0.393
4.5910
10
10
10
0.459,
26262-12 SPK
0.809
9.8616
10
10
10
0.986
105%
5.0
26262-13
0.882
10.7865
10
10
10
1.079
26262-13 SPK
1.221 1
15.0815
10
10
10
1.508
86%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.459
5.4272
10
10 1
10
0.543 1
109%
5
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 4 of 16 1

METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVEL (uM
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot#
8:00 40721
17:10
KAM / DAM
Y
STD
ABS °'°°
0.000 °. --- - - -
0.094 °^°° __-
0.240 °.200 --- ---- - 2<° �.
0.443--
0.633 0."
0.00 2.00 4.00 600
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
0.826
3°�
B00 low 12.00
10.00
X
10
10
Y
�,�
_ _ z�
�'�
_
Slope
0.082116484
Correlation 0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74/0
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26262-14
0.490
5.8199
10
10
10
0.582
26262-14 SPK
0.932
11.4200
10
10
10
1.142
112%
5.0
26262-15
0.001
-0.3756
10
10
10
< 0.1
26262-15 SPK
0.380
4.4262
10
10
10
0.443
89%
5.0
26262-16
0.000
0.0000
10
10
10
< 0.1
26262-16 SPK
0.432
5.0851
10
10
10
0.509
102%
5.0
26262-17
0.070
0.4986
10
10
10
< 0.1
26262-17 SPK
0.432
5.0851
10
10
10
0.509
102%
5.0
26262-18
0.077
0.5873
10
10
10
< 0.1
26262-18 DUP
0.077
0.5873
10
10
10
< 0.1
N/A
26262-18 SPK
0.428
5.0344
10
10
10
0.503
101 1G
5.0
26262-19
0.070
0.4986
10
10
10
<,0.1
26262-19 SPK
0.480
5.6932
10
10
10
0.569
114%
5.0
26262-20
0.725
8.7973
10
10
10
0.880
26262-20 SPK
1.046
12.8643
10
10
10
1.286
81%
5.0
26262-21
0.027
-0.0462
10
10
10
i} 111
26262-21 SPK
0.385
4.4896
10
10
10
0.449
90%
5.0
26262-22
0.063
0.4099
10
10
10
<
26262-22 SPK
0.489
5.8073
10
10
10
0.581
116%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.459
5.4272
10
10
10
0.543
109%
5
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 5 of 16 9

METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
u /mL
DETECTION LIMIT (ug)
1,000
CLIENT: Duke
SPK LEVEL(ug)
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y
STD 0800
ABS 0.00
0.600
0.000 0.500
0.094 °
00 --_- _- za0
0.240 - --0.2
0.443 0.100 - fi - - - - - --
0.633 °0.00 2.00 4.00 6.00
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
IQC Std Lot: SD -44-4
ISTID ABSORPTION
'6 3
-� -
6.00 low 12.00
10.00
X
10
10
Y
25°
11,1111-1
1
Slope
0.082116484
Correlation 0.999009688
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26262-23
0.012
-0.2362
10 1
10
10
<0.1
26262-23 SPK
0.414
4.8570
10
10
10
0.486
97%
5.0
26262-24
0.003
-0.3503
10
10
10
<
26262-24 SPK
0.343
3.9575
10
10
10
0.396
79%
5.0
26262-25
0.350
4.0462
10
10
10
0.405
26262-25 SPK
0.752
9.1394
10 1
10
10
0.914
102%
5.0
26262-26
0.004
-0.3376
10
10
10
< 0.1
26262-26 SPK
0.440
5.1864
10
10
10
0.519
104%
5.0
26260-1
0.004
-0.3376
10
10
5
< 0.2
26260-1 SPK
0.366
4.2489
10
10
5
0.850
85%
5.0
26260-5
0.011
-0.2489
10
10
5
<0.2'- .
26260-5 SPK
0.368
4.2742
10
10
5
0.855
85%
5.0
26260-6
0.002
-0.3629
10
10
5
<
26260-6 SPK
0.295
3.3493
10
10
5
0.670
67%
5.0
26260-7
1.378
17.0707
10
10
5
3.414
26260-7 SPK
1.646
20.4662
10
10
5
4.093
68%
5.0
26260-8
0.003
-0.3503
10
10
5
<
26260-8 SPK
0.345
3.9828
10
10
5
0.797
80%
5.0
26261-4
0.000
0.0000
10
10
5777777,
��9' r "e 0.2
26261-4 SPK
0.381
4.4389
10
10
5
0.888
89%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.459
5.4272
10
10 1
10
0.543
109%
0
Submitted for QA/QC- Date:12/07/15
By: (Print) I
KAM / DAM
(sign):
Page 6 of 16
��2%c

METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT (u
1.000
CLIENT:
Duke
SPK LEVEL (uM
5
Lab ID#
26260 / 261 / 262 / 266 /
12/04/15
8:00
17:10
KAM / DAM
Y
267 / 268
Na2S•9H2O Lot #
40721
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD-44-3
QC Std Lot: SD-44-4
STD ABSORPTION
10.00
X
10
10
Y
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
STD
°600-A
992
0700
ABS
0.600
-000
0.00
1.00
2.50
5.00
7.50
10.00
0.000
600
2.50
0.094 ° 400
° 300
0.240
0.200
T X044
0.443
0.633
0.826
0.00
2.00
4.00
6.00
X
6.00
1000 12.00
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26261-5
0.000
0.0000
10
10
5
< 0.2
26261-5 SPK
0.402
4.7050
10
10
5
0.941
94%
5.0
26262-4
0.005
-0.3249
10
10
5
< 0.2
26262-4 SPK
0.374
4.3502
10
10
5
0.870
87%
5.0
26262-9
0.003
-0.3503
10
10
5
<
26262-9 SPK
0.249
2.7665
10
10
5
0.553
55%
5.0
26262-13
0.525
1 6.2634
10
10
5
1.25
26262-13 SPK
0.888
10.8625
10
10
5
2.173
92%
5.0
26262-20
0.377
4.3882
10
10
5
0.878
26262-20 SPK
0.757
9.2028
10
10
5
1.841
96%
5.0
26262-22
0.035
0.0552
10
10
5
< 0.2
26262-22 SPK
0.458 1
5.4145
10
10
5
1.083
108%
5.0
26262-24
0.006
-0.3123
10
10
5
< 0.2
26262-24 SPK
0.387
4.5149
10
10
5
0.903
90%
5.0
26260-6
0.005
-0.3249
10
10
2
<
26260-6 SPK
0.347
4.0081
10
10
2
2.004
80%
5.0
26260-7
0.671
8.1132
10
10
2
4.057
26260-7 SPK
1.000
12.2815
10
10
2
6.141
83%
5.0
26260-8
0.005
-0.3249
10
10
2
< 0.5
26260-8 SPK
0.405
4.7430
10
10
2
2.371
95%
5.0
Blank
0.000 1
0.0000
10
10
10
<
QC 1
0.460 1
5.4398
10
10
10
0.544
109%
5.0
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign): ice.
i
Page 7 of 16

METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT (u
1.000
CLIENT: Duke
SPK LEVELLuM
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
SAMPLE
I.D.
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y o.�
STD
ABS °'°°
0.600
0.000 0
0.094 0.d00 ,as
0.240 0,2W .240
0.443 i 0.100 - -
0.633 000°O.W 2.00 4.00 fico
0.826 i X
Slope
SAMP ug PER ALI in mL PREP ALI in mL
ABS ALIQUOT ANALYZED VOL in mL TAKEN
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
3
eoo low
0.082116484 Correlation
RESULTS % RPD
ug/mL % SPK REC
10.00
X
10
10
Y
--aw
12.00
0.999009688
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26262-9
0.002
-0.3629
10
10
2
< 0.5 III
26262-9 SPK
0.377
4.3882
10
10
2
2.194
88%
5.0
26260-6
0.012
-0.2362
10
10
1
<,1,0 ,
26260-6 SPK
0.386
4.5023
10
10
1
4.502
90%
5.0
26260-7
0.343
3.9575
10
10
1
3.96.1.
26260-7 SPK
0.733
8.8987
10
10
1
8.899
99%
5.0
26266-1
0.005
-0.3249
10
10
10
< 0.1
26266-1 SPK
0.431
5.0724
10
10
10
0.507
101%
5.0
26266-2
0.002
-0.3629
10
10
10
<
26266-2 DUP
0.001
-0.3756
10
10
10
<
N/A
26266-2 SPK
0.347
4.0081
10
10
10
0.401
80%
5.0
26266-3
0.003
-0.3503
10
10
10
<
26266-3 SPK
0.224
2.4498
10
10
10
0.245
49%
5.0
26266-4
0.000
0.0000
10
10
10
26266-4 SPK
0.404
4.7303
10
10
10
0.473
95%
5.0
26266-5
0.180
1.8923
10
10
10
0.189
26266-5 SPK
0.563
6.7448
10
10
10
0.674
97%
5.0
26266-6
0.000
0.0000
10
10
10
< 0.1
26266-6 SPK
0.431
5.0724
10
10
10
0.507
101%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.460
5.4398
10
10
10
0.544
1099/.
5.0
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 8 of 16 c

METHOD:
SM 4500 S2- 1)
ELEMENT ASSAY:
Sulfide
CLIENT:
Duke
Lab ID#
26260 / 261 / 262 / 266 / 267 1268
Date:
12/04/15
Time Analysis Begun
8:00
Time Analysis Ended
17:10
Analyst:
X
KAM / DAM _
Y
ug STD
STD
SOLUTION
ABS
o. 6
0.00
0.000
1.00
0.094
2.50
0.240
5.00
0.443
750
0 633
ELEMENT ONE
Wave Length 664 - -.- "'" "'
SPK LEVEL Luca
MAX ALIQUOT
Na2S•9H2O Lot # STANDARD conc(ppm)
40721 Cal Std Lot: SD -4,
STD
O.e00
o.eoo
Slope
0.082116484
o. 6
0.700
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
0.600
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
.6 13
0.000
0.500
10
10
10
<
"
0.400
Std. B. 1.00
0.097
443
10
10
0.300
<
84.07%
1.0
Std. B. 2.50
0.236
0.200
10
240
10
0.260
104.07%
0.1w
Std. B. 5.00
0.454
5.3638
10
10
0.000
- -
107.28%
5.0
Std. B. 7.50
0.638
0.00 2.00 4.00 6.00 6.00 1000
10.00 0.826 X
1.000
5
10.00
X
10
10
SOU
00
Page 9 of 16 ���!�
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26266-7
0.004
-0.3376
10
10
10
<0
26266-7 SPK
0.347
4.0081
10
10
10
0.401
80%
5.0
26266-8
0.000
0.0000
10
10
10
<
26266-8 SPK
0.331
3.8054
10
10
10
0.381
76%
5.0
26266-9
0.003
-0.3503
10
10
10
26266-9 SPK
0.368
4.2742
10
10
10
0.427
85%
5.0
26266-10
0.001
-0.3756
10
10
10`,
e. < 0.1"'
26266-10 SPK
0.405
4.7430
10
10
10
0.474
95%
5.0
26266-11
0.105
0.9421
10
10
10
<
26266-11 DUP
0.099
0.8660
10
10
10
<
N/A
26266-11 SPK
0.488
5.7946
10
10
10
0.579
116%
5.0
26266-12
0.406
4.7557
10
10
10
0.476
26266-12 SPK
0.696
8.4299
10
10
10
0.843
73%
5.0
26266-13
0.000
0.0000
10
10
10 _777777;T7,
26266-13 SPK
0.387
4.5149
10
10
10
0.451
90%
5.0
26266-14
0.000
0.0000
10
10
10
< 0.1
26266-14 SPK
0.365
4.2362
10
10
10
0.424
85%
5.0
26266-15
0.000
0.0000
10
10
10
<0A,
26266-15 SPK
0.441
5.1991
10
10
10
0.520
104%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.440
5.1864
10
10
10
0.519
1040/(
, .0
Submitted for QA/QC-
Date: 12/07/15
By: (Print)
KAM
/ DAM
(sign):
Page 9 of 16 ���!�

METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT (ugj
1.000
CLIENT: Duke
SPK LEVEL (ug)
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y a.�
STD 0.
ABS 0700
0.000 0600
y
0.094 0d00
0.240 0300
0.200 .240
0.443 0100
0.633 I o"000m 2.00 4.00 6.0o
0.826 j X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD-44-3
IQC Std Lot: SD-44-4
JSTD ABSORPTION
0'
eoo low
10.00
X
10
10
Y
12.00
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26266-16
0.031 1
0.0045
10
10
10
< 0.1
26266-16 SPK
0.387 1
4.5149
10
10
10
0.451
90%
5.0
26266-17
0.010
-0.2616
10
10
10
< 0.1
26266-17 SPK
0.408
4.7810
10
10
10
0.478
96%
5.0
26266-18
0.000
0.0000
10
10
10
< 0.1
26266-18 SPK
0.433
5.0977
10
10
10
0.510
102%
5.0
26266-19
0.011 1
-0.2489
10
10
10
< 0.1
26266-19 SPK
0.431
5.0724
10
10
10
0.507
101%
5.0
26266-20
0.001
-0.3756
10
10
10
< 0.1
26266-20 SPK
0.426
5.0091
10
10
10
0.501
100%
5.0
26266-21
0.000
0.0000
10
10
10
< 0.1
26266-21 DUP
0.000
0.0000
10
10
10
< 0.1
N/A
26266-21 SPK
0.417 1
4.8950
10
10
10
0.490
98%
5.0
26266-22
0.000
0.0000
10
10
10
< 0.1
26266-22 SPK
0.418
4.9077
10
10
10
0.491
98%
5.0
26267-1
0.000
0.0000
10
10
10
< 0.1
26267-1 SPK
0.418
4.9077
10
10
10
0.491
98%
5.0
26267-2
0.077
0.5873
10
10
10
<
26267-2 SPK
0.498
5.9213
10
10
10
0.592
118%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.438
5.1611
10
10
10
0.516
103%
50
Submitted for QA/QC- Date:12/07/15
By: (Print)
KAM / DAM
(sign): w'
Page 10 of 16
c

METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVELLugj
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y
STD o
ABS 0.700
osao
0.000 osoo --
0.094 I 0400 `"9
0.240 1
0.443
0.633 I o.000 2.00 aoo 6.00
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
0.840
13
-
a.00 low
10.00
X
10
10
Y
--no
-500
uoo
Slope
0.082116484
Correlation
0.999009688
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26267-3
0.033
0.0298
10
10
10
<
26267-3 SPK
0.114
1.0561
10
10
10
0.106
21%
5.0
26267-4
0.005
-0.3249
10
10
10
< 0.1
26267-4 SPK
0.392
4.5783
10 1
10
10
0.458
92%
5.0
26267-5
0.002
-0.3629
10
10
10
< 0.1
26267-5 SPK
0.401
4.6923
10
10
10
0.469
94%
5.0
26267-6
0.010
-0.2616
10
10
10
< 0.1
26267-6 SPK
0.438
5.1611
10
10
10
0.516
103%
5.0
26267-7
0.002
-0.3629
10
10
10
< 0.1
26267-7 SPK
0.451
5.3258
10
10
10
0.533
107%
5.0
26267-8
0.068
0.4733
10
10
10
<
26267-8 SPK
0.493
5.8579
10
10
10
0.586
117%
5.0
26267-9
0.000
0.0000
10
10
10
< 0.1
26267-9 DUP
0.000
0.0000
10
10
10
< 0.1
N/A
26267-9 SPK
0.424
4.9837
10
10
10
0.498
100%
5.0
26267-10
0.260
2.9059
10
10
10
0.291
26267-10 SPK
0.649
7.8344
10
10
10
0.783
99%
5.0
26267-11
0.074
0.5493
10
10
10
i. < 0.1
26267-11 SPK
0.457
5.4018
10
10
10
0.540
108%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.442
5.2118
10
10
10
0.521
104%
.0
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 11 of 16//i%��
G

METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVELLug)
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y
0.000
STD --
ABS 070°
0.000 0.e --------
0.500
0.094 i 0..00
0.240 1111 0.000 -
o2ao
0.443750 0.633 + 000am 2.00 4.00 6.00
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
13
800 ,0.00
10.00
X
10
10
Y
o�
iz.W
Slope
0.082116484
Correlation
0.999009688
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74/0
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26267-12
0.009
-0.2742
10
10
10
;z< 0.1, ,.
26267-12 SPK
0.431
5.0724
10
10
10
0.507
101%
5.0
26267-13
0.001
-0.3756
10
10
10
26267-13 SPK
0.403
4.7177
10
10
10
0.472
94%
5.0
26267-14
0.022
-0.1095
10
10
10
<
26267-14 SPK
0.133
1.2968
10
10
10
0.130
26%
5.0
26268-1
0.075
0.5620
10
10
10
0.1
26268-1 SPK
0.450
5.3131
10
10
10
0.531
106%
5.0
26268-2
0.074
0.5493
10
10
10
<
26268-2 SPK
0.201
2.1584
10
10
10
0.216
43%
5.0
26268-3
0.017
-0.1729
10
10
10
< 0.1
26268-3 SPK
0.447
5.2751
10
10
10
0.528
106%
5.0
26268-4
0.000
0.0000
10
10
10
<
26268-4 SPK
0.303
3.4507
10
10
10
0.345
69%
5.0
26268-5
0.024
-0.0842
10
10
10
< 0.1
26268-5 DUP
0.010
-0.2616
10
10
10
< 0.1
N/A
26268-5 SPK
0.389
4.5403
10
10
10
0.454
91%
5.0
26268-6
0.013
-0.2236
10
10
10
< 0.1
26268-6 SPK
0.104
0.9294
10
10
10
<
19%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.442
5.2118
10
10
10
0.521
104%
5.0
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
�-
Page 12 of 16 4�/��

METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT (u
1.000
CLIENT: Duke
SPK LEVEL (uq)
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H20 Lot #
8:00 40721
17:10
KAM / DAM
Y
STD 0. o
ABS 0.700
0.000
0.094 0400
0.240 OMO
0.443 0.00
0.633 °'0°01 200 400 6.00
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD-44-3
QC Std Lot: SD-44-4
STD ABSORPTION
0M
6.w low
10.00
X
10
10
Y
T ,000
1200
SAMPLE SAMP ug PER
1. D. ABS ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Slope
ALI in mL
TAKEN
0.082116484
RESULTS
ug/mL
Correlation
% RPD
% SPK REC
0.999009688
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26268-7
0.149
1.4995
10
10
10
0.150'
26268-7 SPK
0.565
6.7702
10
10
10
0.677
105%
5.0
26268-8
0.070
0.4986
10
10
10
<
26268-8 SPK
0.489
5.8073
10
10
10
0.581
116%
5.0
26268-9
0.001
-0.3756
10
10
10
< 0.1
26268-9 SPK
0.434
5.1104
10
10
10
0.511
102%
5.0
26268-10
0.000
0.0000
10
10
10
< 0.1
26268-10 SPK
0.421
4.9457
10
10
10
0.495
99%
5.0
26268-11
0.001
-0.3756
10
10
10
<
26268-11 SPK
0.341
3.9321
10
10
10
0.393
79%
5.0
26268-12
0.030
-0.0082
10
10
10
< 0.1
26268-12 SPK
0.463
5.4778
10
1 10
10
0.548
110%
5.0
26268-13
0.024
-0.0842
10
10
10
< 0.1
26268-13 SPK
0.451
5.3258
10
10
10
0.533
107%
5.0
26268-14
0.000
0.0000
10
10
10
< 0.1
26268-14 SPK
0.442
5.2118
10
10
10
0.521
104%
5.0
26266-2
0.000
0.0000
10
10
5
< 0.2
26266-2 DUP
0.013
-0.2236
10
10
5
< 0.2
N/A
26266-2 SPK
0.385
4.4896
10
10
5
0.898
90%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.441
5.1991
10
10
10
0.520
104%
50
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 13of 1616

M TJ-i0D : SM 4500 S2- D
ELEMENT ASSAY: Sulfide
CLIENT: Duke
Lab ID# 26260 / 261 / 262 / 266 / 267
Date: 12/04/15
Time Analysis Begun 8:00
Time Analysis Ended 17:10
Analyst: KAM / DAM
X Y
ug STD
STD
0.700
SOLUTION
ABS
Slope
0.00
0.000
Y
0.400
1.00
0.094
-
2.50
0.240
o.,m
5.00
0.443
SPIKE
LEVEL
7.50
0.633
0.0000
10.00 0.826
ELEMENT ONE
Wave Length 664 "" "" i "- "Olvel 1
SPK LEVEL u
MAX ALIQUOT
Na2S•9H2O Lot # STANDARD conc(ppm)
40721 Cal Std Lot: SD -4,
ABSORPTION
0.800
o.e00
.e'ze
0.700
0. o
Slope
0.so0
Correlation
Y
0.400
443
0.300
-
0200
Z
o.,m
--
0.om
SPIKE
LEVEL
0.00
2.00 4.00 800 Bm inm ,.
L
1.000
5
10.00
X
10
10
Page 14 of 16
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26266-3
0.022
-0.1095
10
10
5
< 0.2:' `
26266-3 SPK
0.398
4.6543
10
10
5
0.931
93%
5.0
26266-7
0.000
0.0000
10
10
5
<
26266-7 SPK
0.361
4.1855
10
10
5
0.837
84%
5.0
26266-8
0.008
-0.2869
10
10
5
<
26266-8 SPK
0.358
4.1475
10
10
5
0.830
83%
5.0
26266-11
0.049
0.2325
10
10
5
< 0.2
26266-11 DUP
0.049
0.2325
10
10
5
< 0.2
N/A
26266-11 SPK
0.445
5.2498
10
10
5
1.050
105%
5.0
26266-12
0.225
2.4624
10
10
5
0.492
26266-12 SPK
0.599
7.2009
10 1
10
5
1.440
95%
5.0
26267-2
0.037
0.0805
10
10
5
26267-2 SPK
0.464
5.4905
10
10
5
1.098
110%
5.0
26267-3
0.014
-0.2109
10
10
5
<
26267-3 SPK
0.148
1.4869
10
10
5
0.297
30%
5.0
26267-8
0.040
0.1185
10
10
5
< 01'
26267-8 SPK
0.447
5.2751
10
10
5
1.055
106%
5.0
26267-14
0.013
-0.2236
10
10
5
< 0.1
26267-14 SPK
0.243
2.6905
10
10
5
0.538
54%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.442
5.2118
10
10
10
0.521
104%
.0
Submitted for QA/QC-
Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 14 of 16

METHOD:
SM 4500 S2-
E
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVELLu
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10 00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y 0�6
STD 0, am
ABS 0J00 -
0.600 --.-
0.000 0500 -
Y -
0.094 lifll
360
0.240 0
0.2oo
0.443
0.633 00°0.00 z.ao 4.00 6.00
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
63
a.00 10.00
10.00
X
10
10
Y
a6
I W
0
-'S6
12.00
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER ALI in mL
ALIQUOT ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26268-2
0.007
-0.2996
10
10
5
<
26268-2 SPK
0.290
3.2860
10
10
5
0.657
66%
5.0
26268-4
0.000
0.0000
10
10
5
< 0.2
26268-4 SPK
0.368
4.2742
10
10
5
0.855
85%
5.0
26268-6
0.006
-0.3123
10
10
5
<
26268-6 SPK
0.193
2.0570
10
10
5
0.411
41%
5.0
26268-8
0.037
0.0805
10
10
5
�° < 0.2
26268-8 SPK
0.453
5.3511
10 1
10
5
1.070
107%
5.0
26268-11
0.004
-0.3376
10
10
5
-<'0.2'
26268-11 SPK
0.372
4.3249
10
10
5
0.865
86%
5.0
26266-7
0.001
-0.3756
10
10
2
26266-7 SPK
0.384
4.4769
10
10
2
2.238
90%
5.0
26266-8
0.006
-0.3123
10
10
2
26266-8 SPK
0.375
4.3629
10
10
2
2.181
87%
5.0
26267-3
0.004
-0.3376
10
10
2
<
26267-3 SPK
0.297
3.3747
10
10
2
1.687
67%
5.0
26267-14
0.005
-0.3249
10
10
2
<
26267-14 SPK
0.357
4.1348
10
10
2
2.067
83%
5.0
26268-2
0.020
-0.1349
10
10
2
<
26268-2 SPK
0.225
2.4624
10
10
2
1.231
49%
5.0
Blank
0.000
0.0000
10
10 1
10
<
QC
0.443
5.2244
10
10
10
0.522
104%
5.
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 15 of 16

METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVELLugj
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM /DAM
Y 0.�
STD 0.600
ABS 0.700 -
0.600 -- - _--
0.000 0600 -- -
0.094 °.'°°
0300
0.240 1 0.300 -- _ 4. ._
0.443 j O.mo - -- ---
0.633 0.a00 m 3.00 4.00 000
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
6
3
8.00 10,00
10.00
X
10
10
Y
--- a�
2W
�,Ooo
12,00
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26268-6
0.003
-0.3503
10
10
2
<
26268-6 SPK
0.324
3.7167
10
10
2
1.858
74%
5.0
26267-3
0.001
-0.3756
10
10
1
<
26267-3 SPK
0.347
4.0081
10
10
1
4.008
80%
5.0
26267-14
0.002
-0.3629
10
10
1
< 1.0 ".
26267-14 SPK
0.375
4.3629
10
10
1
4.363
87%
5.0
26268-2
0.011
-0.2489
10
10
1
<
26268-2 SPK
0.320
3.6661
10
10
1
3.666
73%
5.0
26268-6
0.001
-0.3756
10
10
1
< 1.0
26268-6 SPK
0.370
4.2995
10
10
1
4.300
86%
5.0
26267-3
0.000
0.0000
10
10
0.5
<2.6��,
26267-3 SPK
0.390
4.5529
10
10
0.5
9.106
91%
5.0
26268-2
0.008
-0.2869
10
10
0.5
<
26268-2 SPK
0.331
3.8054
10
10
0.5
7.611
76%
5.0
26268-2
0.009
-0.2742
10
10
0.25
". < 4,0
26268-2 SPK
0.378
4.4009
10
10
0.25
17.604
88%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.443
5.2244
10
10
10
0.522
104%
5.0
Submitted for QA/QC- Date: 12/07/15
By: (Print)
K:AM / DAM
(sign):
U
Page 16 of 16
C

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EDD

DUKE Analytical Laboratory Page 1 of 134
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments:
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
J15120075
WEATHERSPOON - AB GW ASSESSMENT WATER
Mark Taylor, Tim Hunsucker, Brandon Russo, Kathy Webb, John Toepfer
Anne Pifer
Pit 0-1- mr
axx
Anne Pifer
Phone:
Date:
Please contact the Program Manager (Anne Pifer) with any questions regarding this report.
Data Flags & Calculations:
12/17/2015
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Sample ID Plant/Station
Collection
Date and Time Collected By
Sample Description
2015037769
Weatherspoon
02 -Dec -15
4:25 PM
illegible
BW -2S
2015037770
Weatherspoon
02 -Dec -15
1:40 PM
illegible
BW -21
2015037771
Weatherspoon
02 -Dec -15
2:10 PM
illegible
MW -07
2015037772
Weatherspoon
02 -Dec -15
9:40 AM
illegible
MW-44SA
2015037773
Weatherspoon
02 -Dec -15
12:03 PM
illegible
MW -491
2015037774
Weatherspoon
02 -Dec -15
11:05 AM
illegible
BW -1
2015037775
Weatherspoon
02 -Dec -15
12:40 PM
illegible
BW -03S
2015037776
Weatherspoon
02 -Dec -15
3:40 PM
illegible
BW -031
2015037777
Weatherspoon
02 -Dec -15
9:55 AM
illegible
CW -2
2015037778
Weatherspoon
02 -Dec -15
11:11 AM
illegible
CW -3
2015037779
Weatherspoon
02 -Dec -15
12:32 PM
illegible
MW -411
2015037780
Weatherspoon
02 -Dec -15
1:47 PM
illegible
BW -31D
2015037781
Weatherspoon
02 -Dec -15
1:47 PM
illegible
BW -31D DUP
2015037782
Weatherspoon
02 -Dec -15
6:00 PM
illegible
Filter Blank
2015037783
Weatherspoon
02 -Dec -15
6:00 PM
illegible
Equipment Blank
15 Total Samples
Page 2 of 134

Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes V] No
All laboratory QA/QC requirements are acceptable.❑ Yes ❑ No
Report Sections Included:
L� Job Summary Report
❑ Sample Identification
❑ Technical Validation of Data Package
❑ Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
Page 3 of 134
OV Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑ Chain of Custody
❑ Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 12/11/2015

Certificate of Laboratory Analysis Page 4 of 134
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -2S
Collection Date: 02 -Dec -15 4:25 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
1 EPA 300.0
12/03/2015 20:03
INORGANIC IONS BY IC
1 EPA 245.1
12/04/2015 11:19
ACPAYNE
Chloride
7.2
mg/L
0.1
Sulfate
7.5
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
1 EPA 200.7
12/04/2015 12:23
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
12/04/2015 12:23
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
FCJORDA
1 EPA 200.7
12/04/2015 14:30
Aluminum (AI)
0.245
mg/L
0.005
Barium (Ba)
0.027
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.04
mg/L
0.01
Manganese (Mn)
0.014
mg/L
0.005
Strontium (Sr)
0.017
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (AI)
0.226
mg/L
0.005
Barium (Ba)
0.027
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.987
mg/L
0.01
Manganese (Mn)
0.014
mg/L
0.005
Strontium (Sr)
0.017
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
2.79
mg/L
0.01
Magnesium (Mg)
0.559
mg/L
0.005
Potassium (K)
0.568
mg/L
0.1
Sodium (Na)
4.34
mg/L
0.05
Sample #: 2015037769
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/08/2015 08:45 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
12/03/2015 20:03
BGN9034
1 EPA 300.0
12/03/2015 20:03
BGN9034
1 EPA 245.1
12/04/2015 11:19
ACPAYNE
1 EPA 245.1
12/05/2015 13:46
ACPAYNE
1 EPA 245.1
12/08/2015 17:16
TLINN
1 EPA 200.7
12/04/2015 12:23
FCJORDA
1 EPA 200.7
12/04/2015 12:23
FCJORDA
1 EPA 200.7
12/04/2015 12:23
FCJORDA
1 EPA 200.7
12/04/2015 12:23
FCJORDA
1 EPA 200.7
12/04/2015 12:23
FCJORDA
1 EPA 200.7
12/04/2015 12:23
FCJORDA
1 EPA 200.7
12/04/2015 12:23
FCJORDA
1 EPA 200.7
12/04/2015 14:30
FCJORDA
1 EPA 200.7
12/04/2015 14:30
FCJORDA
1 EPA 200.7
12/04/2015 14:30
FCJORDA
1 EPA 200.7
12/04/2015 14:30
FCJORDA
1 EPA 200.7
12/04/2015 14:30
FCJORDA
1 EPA 200.7
12/04/2015 14:30
FCJORDA
1 EPA 200.7
12/04/2015 14:30
FCJORDA
1 EPA 200.7
12/06/2015 13:42
FCJORDA
1 EPA 200.7
12/06/2015 13:42
FCJORDA
1 EPA 200.7
12/06/2015 13:42
FCJORDA
1 EPA 200.7
12/06/2015 13:42
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -2S
Collection Date: 02 -Dec -15 4:25 PM
Analyte Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
2.05
Barium (Ba)
0.031
Boron (B)
< 0.05
Iron (Fe)
1.24
Manganese (Mn)
0.015
Strontium (Sr)
0.018
Zinc (Zn)
< 0.005
Page 5 of 134
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037769
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
M1 0.005
1
EPA 200.7
12/07/2015 14:27
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:27
MHH7131
mg/L
0.05
1
EPA 200.7
12/07/2015 14:27
MHH7131
mg/L
0.01
1
EPA 200.7
12/07/2015 14:27
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:27
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:27
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:27
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:07
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:07
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:07
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:07
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:07
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:07
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:07
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:07
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:07
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:07
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:07
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/07/2015 18:07
MHALL3
Vanadium (V) Low Level
1.85
ug/L
0.3
1
EPA 200.8
12/07/2015 18:07
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:51
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:51
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:51
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:51
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:51
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:51
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:51
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:51
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:51
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:51
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:51
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/07/2015 23:51
MHALL3
Vanadium (V) Low Level
1.66
ug/L
0.3
1
EPA 200.8
12/07/2015 23:51
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -2S
Collection Date: 02 -Dec -15 4:25 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
1.42
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
1.66
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
4.42
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
62
mg/L
25
1
Total Carbon
Page 6 of 134
Sample #:
2015037769
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/08/2015 17:25
MHALL3
EPA 200.8
12/08/2015 17:25
MHALL3
EPA 200.8
12/08/2015 17:25
MHALL3
EPA 200.8
12/08/2015 17:25
MHALL3
EPA 200.8
12/08/2015 17:25
MHALL3
EPA 200.8
12/08/2015 17:25
MHALL3
EPA 200.8
12/08/2015 17:25
MHALL3
EPA 200.8
12/08/2015 17:25
MHALL3
EPA 200.8
12/08/2015 17:25
MHALL3
EPA 200.8
12/08/2015 17:25
MHALL3
EPA 200.8
12/08/2015 17:25
MHALL3
EPA 200.8
12/08/2015 17:25
MHALL3
EPA 200.8
12/08/2015 17:25
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/04/201511:24 CJELLIO
TOC 3.0 mg/L 1 10 SM5310C/EPA9060A 12/07/201514:46 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS 9.0 mg/L 5 1 SM2540D 12/07/2015 09:55 CJELLIO

Certificate of Laboratory Analysis Page 7 of 134
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -21
Collection Date: 02 -Dec -15 1:40 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.050 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
1 EPA 300.0
12/03/2015 20:20
INORGANIC IONS BY IC
1 EPA 245.1
12/04/2015 11:17
ACPAYNE
Chloride
4.8
mg/L
0.1
Sulfate
0.26
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
1 EPA 200.7
12/04/2015 12:27
Mercury (Hg)
0.23
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
12/04/2015 12:27
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
FCJORDA
1 EPA 200.7
12/04/2015 14:34
Aluminum (AI)
0.076
mg/L
0.005
Barium (Ba)
0.015
mg/L
0.005
Boron (B)
0.055
mg/L
0.05
Iron (Fe)
0.841
mg/L
0.01
Manganese (Mn)
0.026
mg/L
0.005
Strontium (Sr)
0.191
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (AI)
0.070
mg/L
0.005
Barium (Ba)
0.014
mg/L
0.005
Boron (B)
0.053
mg/L
0.05
Iron (Fe)
0.758
mg/L
0.01
Manganese (Mn)
0.026
mg/L
0.005
Strontium (Sr)
0.189
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
45.3
mg/L
0.01
Magnesium (Mg)
1.05
mg/L
0.005
Potassium (K)
1.44
mg/L
0.1
Sodium (Na)
30.4
mg/L
0.05
Sample #: 2015037770
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/08/2015 08:49 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
12/03/2015 20:20
BGN9034
1 EPA 300.0
12/03/2015 20:20
BGN9034
1 EPA 245.1
12/04/2015 11:17
ACPAYNE
1 EPA 245.1
12/05/2015 13:53
ACPAYNE
1 EPA 245.1
12/08/2015 17:18
TLINN
1 EPA 200.7
12/04/2015 12:27
FCJORDA
1 EPA 200.7
12/04/2015 12:27
FCJORDA
1 EPA 200.7
12/04/2015 12:27
FCJORDA
1 EPA 200.7
12/04/2015 12:27
FCJORDA
1 EPA 200.7
12/04/2015 12:27
FCJORDA
1 EPA 200.7
12/04/2015 12:27
FCJORDA
1 EPA 200.7
12/04/2015 12:27
FCJORDA
1 EPA 200.7
12/04/2015 14:34
FCJORDA
1 EPA 200.7
12/04/2015 14:34
FCJORDA
1 EPA 200.7
12/04/2015 14:34
FCJORDA
1 EPA 200.7
12/04/2015 14:34
FCJORDA
1 EPA 200.7
12/04/2015 14:34
FCJORDA
1 EPA 200.7
12/04/2015 14:34
FCJORDA
1 EPA 200.7
12/04/2015 14:34
FCJORDA
1 EPA 200.7
12/06/2015 13:46
FCJORDA
1 EPA 200.7
12/06/2015 13:46
FCJORDA
1 EPA 200.7
12/06/2015 13:46
FCJORDA
1 EPA 200.7
12/06/2015 13:46
FCJORDA

Site: BW -21
Collection Date: 02 -Dec -15 1:40 PM
Analyte
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
37.6
Barium (Ba)
0.081
Boron (B)
0.074
Iron (Fe)
12.6
Manganese (Mn)
0.064
Strontium (Sr)
0.272
Zinc (Zn)
0.029
Page 8 of 134
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED
Antimony (Sb)
< 1
ug/L
Sample #:
2015037770
EPA 200.8
12/07/2015 18:13
MHALL3
Arsenic (As)
Matrix:
GW WW
1
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.05
10
EPA 200.7
12/07/2015 14:39
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:39
MHH7131
mg/L
0.05
1
EPA 200.7
12/07/2015 14:39
MHH7131
mg/L
0.01
1
EPA 200.7
12/07/2015 14:39
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:39
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:39
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:39
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:13
MHALL3
Arsenic (As)
1.50
ug/L
1
1
EPA 200.8
12/07/2015 18:13
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:13
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:13
MHALL3
Chromium (Cr)
3.02
ug/L
1
1
EPA 200.8
12/07/2015 18:13
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:13
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:13
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:13
MHALL3
Molybdenum (Mo)
7.60
ug/L
1
1
EPA 200.8
12/07/2015 18:13
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:13
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:13
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/07/2015 18:13
MHALL3
Vanadium (V) Low Level
7.83
ug/L
0.3
1
EPA 200.8
12/07/2015 18:13
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:57
MHALL3
Arsenic (As)
1.36
ug/L
1
1
EPA 200.8
12/07/2015 23:57
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:57
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:57
MHALL3
Chromium (Cr)
2.46
ug/L
1
1
EPA 200.8
12/07/2015 23:57
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:57
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:57
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:57
MHALL3
Molybdenum (Mo)
7.01
ug/L
1
1
EPA 200.8
12/07/2015 23:57
MHALL3
Nickel (Ni)
1.02
ug/L
1
1
EPA 200.8
12/07/2015 23:57
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 23:57
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/07/2015 23:57
MHALL3
Vanadium (V) Low Level
6.06
ug/L
0.3
1
EPA 200.8
12/07/2015 23:57
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -21
Collection Date: 02 -Dec -15 1:40 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
6.50
ug/L
1
1
Beryllium (Be)
2.11
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
67.0
ug/L
1
1
Cobalt (Co)
2.63
ug/L
1
1
Copper (Cu)
5.43
ug/L
1
1
Lead (Pb)
20.9
ug/L
1
1
Molybdenum (Mo)
12.8
ug/L
1
1
Nickel (Ni)
6.03
ug/L
1
1
Selenium (Se)
2.08
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
79.0
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
970
mg/L
25
1
Total Carbon
Page 9 of 134
Sample #:
2015037770
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/08/2015 17:31
MHALL3
EPA 200.8
12/08/2015 17:31
MHALL3
EPA 200.8
12/08/2015 17:31
MHALL3
EPA 200.8
12/08/2015 17:31
MHALL3
EPA 200.8
12/08/2015 17:31
MHALL3
EPA 200.8
12/08/2015 17:31
MHALL3
EPA 200.8
12/08/2015 17:31
MHALL3
EPA 200.8
12/08/2015 17:31
MHALL3
EPA 200.8
12/08/2015 17:31
MHALL3
EPA 200.8
12/08/2015 17:31
MHALL3
EPA 200.8
12/08/2015 17:31
MHALL3
EPA 200.8
12/08/2015 17:31
MHALL3
EPA 200.8
12/08/2015 17:31
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/04/201511:24 CJELLIO
TOC 9.8 mg/L 1 10 SM5310C/EPA9060A 12/07/201514:46 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS 180 mg/L 25 1 SM2540D 12/07/2015 09:55 CJELLIO

Certificate of Laboratory Analysis Page 10 of 134
This report shall not be reproduced, except in full.
Order # J15120075
Site: MW -07
Collection Date: 02 -Dec -15 2:10 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
10
INORGANIC IONS BY IC
12/03/2015 22:18
BGN9034
1
Chloride
4.0
mg/L
0.1
Sulfate
20
mg/L
1
MERCURY (COLD VAPOR) IN WATER
12/04/2015 12:30
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 200.7
12/04/2015 12:30
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1
EPA 200.7
12/04/2015 12:30
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.042
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.581
mg/L
0.01
Manganese (Mn)
0.036
mg/L
0.005
Strontium (Sr)
0.269
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
1
EPA 200.7
12/07/2015 14:43
Calcium (Ca)
51.2
mg/L
0.01
Magnesium (Mg)
1.16
mg/L
0.005
Potassium (K)
1.34
mg/L
0.1
Sodium (Na)
9.49
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
1
EPA 200.7
Aluminum (AI)
0.009
mg/L
0.005
Barium (Ba)
0.042
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.635
mg/L
0.01
Manganese (Mn)
0.035
mg/L
0.005
Strontium (Sr)
0.278
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Sample #: 2015037771
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/08/2015 08:50 LSTARL1
Vendor Method V_PACE
1
EPA 300.0
12/03/2015 22:18
BGN9034
10
EPA 300.0
12/03/2015 22:18
BGN9034
1
EPA 245.1
12/04/2015 10:10
ACPAYNE
1
EPA 245.1
12/05/2015 13:55
ACPAYNE
1
EPA 200.7
12/04/2015 12:30
FCJORDA
1
EPA 200.7
12/04/2015 12:30
FCJORDA
1
EPA 200.7
12/04/2015 12:30
FCJORDA
1
EPA 200.7
12/04/2015 12:30
FCJORDA
1
EPA 200.7
12/04/2015 12:30
FCJORDA
1
EPA 200.7
12/04/2015 12:30
FCJORDA
1
EPA 200.7
12/04/2015 12:30
FCJORDA
1
EPA 200.7
12/06/2015 13:50
FCJORDA
1
EPA 200.7
12/06/2015 13:50
FCJORDA
1
EPA 200.7
12/06/2015 13:50
FCJORDA
1
EPA 200.7
12/06/2015 13:50
FCJORDA
1
EPA 200.7
12/07/2015 14:43
MHH7131
1
EPA 200.7
12/07/2015 14:43
MHH7131
1
EPA 200.7
12/07/2015 14:43
MHH7131
1
EPA 200.7
12/07/2015 14:43
MHH7131
1
EPA 200.7
12/07/2015 14:43
MHH7131
1
EPA 200.7
12/07/2015 14:43
MHH7131
1
EPA 200.7
12/07/2015 14:43
MHH7131

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: MW -07
Collection Date: 02 -Dec -15 2:10 PM
Analyte Result Units Qualifiers RDL
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.58
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
TOTAL RECOVERABLE METALS BY ICP -MS
EPA 200.8
12/07/2015 18:20
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
1.53
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
190
mg/L
25
Total Carbon
TOC
1.3
mg/L
0.1
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
Page 11 of 134
1 EPA 200.8
Sample #:
2015037771
1 EPA 200.8
12/08/2015 17:38
Matrix:
GW WW
12/08/2015 17:38
DF
Method
Analysis Date/Time
Analyst
1
EPA 200.8
12/07/2015 18:20
MHALL3
1
EPA 200.8
12/07/2015 18:20
MHALL3
1
EPA 200.8
12/07/2015 18:20
MHALL3
1
EPA 200.8
12/07/2015 18:20
MHALL3
1
EPA 200.8
12/07/2015 18:20
MHALL3
1
EPA 200.8
12/07/2015 18:20
MHALL3
1
EPA 200.8
12/07/2015 18:20
MHALL3
1
EPA 200.8
12/07/2015 18:20
MHALL3
1
EPA 200.8
12/07/2015 18:20
MHALL3
1
EPA 200.8
12/07/2015 18:20
MHALL3
1
EPA 200.8
12/07/2015 18:20
MHALL3
1
EPA 200.8
12/07/2015 18:20
MHALL3
1
EPA 200.8
12/07/2015 18:20
MHALL3
1 EPA 200.8
12/08/2015 17:38
MHALL3
1 EPA 200.8
12/08/2015 17:38
MHALL3
1 EPA 200.8
12/08/2015 17:38
MHALL3
1 EPA 200.8
12/08/2015 17:38
MHALL3
1 EPA 200.8
12/08/2015 17:38
MHALL3
1 EPA 200.8
12/08/2015 17:38
MHALL3
1 EPA 200.8
12/08/2015 17:38
MHALL3
1 EPA 200.8
12/08/2015 17:38
MHALL3
1 EPA 200.8
12/08/2015 17:38
MHALL3
1 EPA 200.8
12/08/2015 17:38
MHALL3
1 EPA 200.8
12/08/2015 17:38
MHALL3
1 EPA 200.8
12/08/2015 17:38
MHALL3
1 EPA 200.8
12/08/2015 17:38
MHALL3
Vendor Method
V_SHEALY
Vendor Method V_ELE1
1 SM2540C 12/04/201511:24 CJELLIO
1 SM5310C/EPA9060A 12/07/201514:46 GHUTCHI
1 SM2540D 12/07/2015 09:55 CJELLIO

Certificate of Laboratory Analysis Page 12 of 134
This report shall not be reproduced, except in full.
Order # J15120075
Site: MW-44SA
Collection Date: 02 -Dec -15 9:40 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
50
INORGANIC IONS BY IC
12/03/2015 22:35
BGN9034
1
Chloride
56
mg/L
1
Sulfate
270
mg/L
5
MERCURY (COLD VAPOR) IN WATER
12/08/2015 17:21
TLINN
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 200.7
12/04/2015 12:34
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
1
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
12/04/2015 12:34
FCJORDA
1
Aluminum (AI)
0.027
mg/L
0.005
Barium (Ba)
0.167
mg/L
0.005
Boron (B)
1.49
mg/L
0.05
Iron (Fe)
6.30
mg/L
0.01
Manganese (Mn)
0.209
mg/L
0.005
Strontium (Sr)
2.03
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
12/04/2015 14:38
FCJORDA
Aluminum (AI)
0.019
mg/L
0.005
Barium (Ba)
0.178
mg/L
0.005
Boron (B)
1.53
mg/L
0.05
Iron (Fe)
6.50
mg/L
0.01
Manganese (Mn)
0.214
mg/L
0.005
Strontium (Sr)
2.14
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
187
mg/L
0.1
Magnesium (Mg)
10.3
mg/L
0.005
Potassium (K)
4.14
mg/L
0.1
Sodium (Na)
35.9
mg/L
0.05
Sample #: 2015037772
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/08/2015 08:51 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
12/03/2015 22:35
BGN9034
50
EPA 300.0
12/03/2015 22:35
BGN9034
1
EPA 245.1
12/04/2015 10:03
ACPAYNE
1
EPA 245.1
12/05/2015 13:58
ACPAYNE
1
EPA 245.1
12/08/2015 17:21
TLINN
1
EPA 200.7
12/04/2015 12:34
FCJORDA
1
EPA 200.7
12/04/2015 12:34
FCJORDA
1
EPA 200.7
12/04/2015 12:34
FCJORDA
1
EPA 200.7
12/04/2015 12:34
FCJORDA
1
EPA 200.7
12/04/2015 12:34
FCJORDA
1
EPA 200.7
12/04/2015 12:34
FCJORDA
1
EPA 200.7
12/04/2015 12:34
FCJORDA
1
EPA 200.7
12/04/2015 14:38
FCJORDA
1
EPA 200.7
12/04/2015 14:38
FCJORDA
1
EPA 200.7
12/04/2015 14:38
FCJORDA
1
EPA 200.7
12/04/2015 14:38
FCJORDA
1
EPA 200.7
12/04/2015 14:38
FCJORDA
1
EPA 200.7
12/04/2015 14:38
FCJORDA
1
EPA 200.7
12/04/2015 14:38
FCJORDA
10
EPA 200.7
12/06/2015 13:54
FCJORDA
1
EPA 200.7
12/06/2015 13:54
FCJORDA
1
EPA 200.7
12/06/2015 13:54
FCJORDA
1
EPA 200.7
12/06/2015 13:54
FCJORDA

Site: MW-44SA
Collection Date: 02 -Dec -15 9:40 AM
Analyte
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.150
Barium (Ba)
0.166
Boron (B)
1.52
Iron (Fe)
6.63
Manganese (Mn)
0.208
Strontium (Sr)
2.08
Zinc (Zn)
< 0.005
Page 13 of 134
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED
Antimony (Sb)
< 1
ug/L
Sample #:
2015037772
EPA 200.8
12/07/2015 18:27
MHALL3
Arsenic (As)
Matrix:
GW WW
1
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/07/2015 14:47
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:47
MHH7131
mg/L
0.05
1
EPA 200.7
12/07/2015 14:47
MHH7131
mg/L
0.01
1
EPA 200.7
12/07/2015 14:47
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:47
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:47
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:47
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:27
MHALL3
Arsenic (As)
89.2
ug/L
1
1
EPA 200.8
12/07/2015 18:27
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:27
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:27
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:27
MHALL3
Cobalt (Co)
2.01
ug/L
1
1
EPA 200.8
12/07/2015 18:27
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:27
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:27
MHALL3
Molybdenum (Mo)
9.21
ug/L
1
1
EPA 200.8
12/07/2015 18:27
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:27
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 18:27
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/07/2015 18:27
MHALL3
Vanadium (V) Low Level
1.74
ug/L
0.3
1
EPA 200.8
12/07/2015 18:27
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:02
MHALL3
Arsenic (As)
92.7
ug/L
1
1
EPA 200.8
12/08/2015 00:02
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:02
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:02
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:02
MHALL3
Cobalt (Co)
1.58
ug/L
1
1
EPA 200.8
12/08/2015 00:02
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:02
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:02
MHALL3
Molybdenum (Mo)
9.28
ug/L
1
1
EPA 200.8
12/08/2015 00:02
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:02
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:02
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/08/2015 00:02
MHALL3
Vanadium (V) Low Level
1.70
ug/L
0.3
1
EPA 200.8
12/08/2015 00:02
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: MW-44SA
Collection Date: 02 -Dec -15 9:40 AM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
89.0
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
2.12
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
8.21
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
2.09
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
750
mg/L
25
1
Total Carbon
Page 14 of 134
Sample #:
2015037772
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/08/2015 17:44
MHALL3
EPA 200.8
12/08/2015 17:44
MHALL3
EPA 200.8
12/08/2015 17:44
MHALL3
EPA 200.8
12/08/2015 17:44
MHALL3
EPA 200.8
12/08/2015 17:44
MHALL3
EPA 200.8
12/08/2015 17:44
MHALL3
EPA 200.8
12/08/2015 17:44
MHALL3
EPA 200.8
12/08/2015 17:44
MHALL3
EPA 200.8
12/08/2015 17:44
MHALL3
EPA 200.8
12/08/2015 17:44
MHALL3
EPA 200.8
12/08/2015 17:44
MHALL3
EPA 200.8
12/08/2015 17:44
MHALL3
EPA 200.8
12/08/2015 17:44
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/04/201511:24 CJELLIO
TOC 4.3 mg/L 0.1 1 SM5310C/EPA9060A 12/07/201514:46 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS 19 mg/L 5 1 SM2540D 12/07/2015 09:55 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: MW -491
Collection Date: 02 -Dec -15 12:03 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
10
INORGANIC IONS BY IC
12/03/2015 21:10
BGN9034
1
Chloride
71
mg/L
1
Sulfate
97
mg/L
1
MERCURY (COLD VAPOR) IN WATER
12/05/2015 13:04
ACPAYNE
Mercury (Hg)
< 0.05
ug/L
M2 0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 200.7
12/04/2015 12:38
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
1
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
12/04/2015 12:38
FCJORDA
1
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.079
mg/L
0.005
Boron (B)
3.38
mg/L
0.05
Iron (Fe)
6.00
mg/L
0.01
Manganese (Mn)
0.108
mg/L
0.005
Strontium (Sr)
0.737
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
12/04/2015 14:53
FCJORDA
Aluminum (AI)
0.007
mg/L
0.005
Barium (Ba)
0.079
mg/L
0.005
Boron (B)
3.38
mg/L
0.05
Iron (Fe)
5.74
mg/L
0.01
Manganese (Mn)
0.110
mg/L
0.005
Strontium (Sr)
0.740
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
143
mg/L
0.1
Magnesium (Mg)
5.93
mg/L
0.005
Potassium (K)
6.09
mg/L
0.1
Sodium (Na)
64.2
mg/L
0.05
Page 15 of 134
Sample #: 2015037773
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/08/2015 08:52 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
12/03/2015 21:10
BGN9034
10
EPA 300.0
12/03/2015 21:10
BGN9034
1
EPA 245.1
12/04/2015 10:18
ACPAYNE
1
EPA 245.1
12/05/2015 14:00
ACPAYNE
1
EPA 245.1
12/05/2015 13:04
ACPAYNE
1
EPA 200.7
12/04/2015 12:38
FCJORDA
1
EPA 200.7
12/04/2015 12:38
FCJORDA
1
EPA 200.7
12/04/2015 12:38
FCJORDA
1
EPA 200.7
12/04/2015 12:38
FCJORDA
1
EPA 200.7
12/04/2015 12:38
FCJORDA
1
EPA 200.7
12/04/2015 12:38
FCJORDA
1
EPA 200.7
12/04/2015 12:38
FCJORDA
1
EPA 200.7
12/04/2015 14:53
FCJORDA
1
EPA 200.7
12/04/2015 14:53
FCJORDA
1
EPA 200.7
12/04/2015 14:53
FCJORDA
1
EPA 200.7
12/04/2015 14:53
FCJORDA
1
EPA 200.7
12/04/2015 14:53
FCJORDA
1
EPA 200.7
12/04/2015 14:53
FCJORDA
1
EPA 200.7
12/04/2015 14:53
FCJORDA
10
EPA 200.7
12/06/2015 13:58
FCJORDA
1
EPA 200.7
12/06/2015 13:58
FCJORDA
1
EPA 200.7
12/06/2015 13:58
FCJORDA
1
EPA 200.7
12/06/2015 13:58
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: MW -491
Collection Date: 02 -Dec -15 12:03 PM
Analyte
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.043
Barium (Ba)
0.077
Boron (B)
3.36
Iron (Fe)
6.40
Manganese (Mn)
0.108
Strontium (Sr)
0.717
Zinc (Zn)
< 0.005
Page 16 of 134
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037773
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/07/2015 14:57
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:57
MHH7131
mg/L
0.05
1
EPA 200.7
12/07/2015 14:57
MHH7131
mg/L
0.01
1
EPA 200.7
12/07/2015 14:57
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:57
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:57
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 14:57
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:14
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:14
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:14
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:14
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:14
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:14
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:14
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:14
MHALL3
Molybdenum (Mo)
3.78
ug/L
1
1
EPA 200.8
12/07/2015 19:14
MHALL3
Nickel (Ni)
2.70
ug/L
1
1
EPA 200.8
12/07/2015 19:14
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:14
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/07/2015 19:14
MHALL3
Vanadium (V) Low Level
0.362
ug/L
0.3
1
EPA 200.8
12/07/2015 19:14
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:00
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:00
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:00
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:00
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:00
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:00
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:00
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:00
MHALL3
Molybdenum (Mo)
3.45
ug/L
1
1
EPA 200.8
12/08/2015 01:00
MHALL3
Nickel (Ni)
1.57
ug/L
1
1
EPA 200.8
12/08/2015 01:00
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:00
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/08/2015 01:00
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/08/2015 01:00
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: MW -491
Collection Date: 02 -Dec -15 12:03 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
3.33
ug/L
1
1
Nickel (Ni)
1.70
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
610
mg/L
25
1
Total Carbon
Page 17 of 134
Sample #:
2015037773
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/08/2015 18:52
MHALL3
EPA 200.8
12/08/2015 18:52
MHALL3
EPA 200.8
12/08/2015 18:52
MHALL3
EPA 200.8
12/08/2015 18:52
MHALL3
EPA 200.8
12/08/2015 18:52
MHALL3
EPA 200.8
12/08/2015 18:52
MHALL3
EPA 200.8
12/08/2015 18:52
MHALL3
EPA 200.8
12/08/2015 18:52
MHALL3
EPA 200.8
12/08/2015 18:52
MHALL3
EPA 200.8
12/08/2015 18:52
MHALL3
EPA 200.8
12/08/2015 18:52
MHALL3
EPA 200.8
12/08/2015 18:52
MHALL3
EPA 200.8
12/08/2015 18:52
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/04/201511:24 CJELLIO
TOC 5.7 mg/L 1 10 SM5310C/EPA9060A 12/07/201514:46 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS 15 mg/L 5 1 SM2540D 12/07/2015 09:55 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -1
Collection Date: 02 -Dec -15 11:05 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.682 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
10
INORGANIC IONS BY IC
12/03/2015 21:27
BGN9034
1
Chloride
19
mg/L
1
Sulfate
57
mg/L
1
MERCURY (COLD VAPOR) IN WATER
12/08/2015 17:35
TLINN
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 200.7
12/04/2015 12:42
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
1
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
12/04/2015 12:42
FCJORDA
1
Aluminum (AI)
3.92
mg/L
0.005
Barium (Ba)
0.082
mg/L
0.005
Boron (B)
0.053
mg/L
0.05
Iron (Fe)
0.100
mg/L
0.01
Manganese (Mn)
0.036
mg/L
0.005
Strontium (Sr)
0.040
mg/L
0.005
Zinc (Zn)
0.013
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
12/04/2015 14:57
FCJORDA
Aluminum (AI)
3.86
mg/L
0.005
Barium (Ba)
0.081
mg/L
0.005
Boron (B)
0.053
mg/L
0.05
Iron (Fe)
0.096
mg/L
0.01
Manganese (Mn)
0.036
mg/L
0.005
Strontium (Sr)
0.040
mg/L
0.005
Zinc (Zn)
0.014
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
5.03
mg/L
0.01
Magnesium (Mg)
2.30
mg/L
0.005
Potassium (K)
14.8
mg/L
0.1
Sodium (Na)
11.9
mg/L
0.05
Page 18 of 134
Sample #: 2015037774
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/08/2015 08:53 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
12/03/2015 21:27
BGN9034
10
EPA 300.0
12/03/2015 21:27
BGN9034
1
EPA 245.1
12/04/2015 11:14
ACPAYNE
1
EPA 245.1
12/05/2015 14:02
ACPAYNE
1
EPA 245.1
12/08/2015 17:35
TLINN
1
EPA 200.7
12/04/2015 12:42
FCJORDA
1
EPA 200.7
12/04/2015 12:42
FCJORDA
1
EPA 200.7
12/04/2015 12:42
FCJORDA
1
EPA 200.7
12/04/2015 12:42
FCJORDA
1
EPA 200.7
12/04/2015 12:42
FCJORDA
1
EPA 200.7
12/04/2015 12:42
FCJORDA
1
EPA 200.7
12/04/2015 12:42
FCJORDA
1
EPA 200.7
12/04/2015 14:57
FCJORDA
1
EPA 200.7
12/04/2015 14:57
FCJORDA
1
EPA 200.7
12/04/2015 14:57
FCJORDA
1
EPA 200.7
12/04/2015 14:57
FCJORDA
1
EPA 200.7
12/04/2015 14:57
FCJORDA
1
EPA 200.7
12/04/2015 14:57
FCJORDA
1
EPA 200.7
12/04/2015 14:57
FCJORDA
1
EPA 200.7
12/06/2015 14:01
FCJORDA
1
EPA 200.7
12/06/2015 14:01
FCJORDA
1
EPA 200.7
12/06/2015 14:01
FCJORDA
1
EPA 200.7
12/06/2015 14:01
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -1
Collection Date: 02 -Dec -15 11:05 AM
Analyte
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
4.10
Barium (Ba)
0.081
Boron (B)
0.062
Iron (Fe)
0.313
Manganese (Mn)
0.035
Strontium (Sr)
0.040
Zinc (Zn)
0.016
Page 19 of 134
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037774
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/07/2015 15:02
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:02
MHH7131
mg/L
0.05
1
EPA 200.7
12/07/2015 15:02
MHH7131
mg/L
0.01
1
EPA 200.7
12/07/2015 15:02
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:02
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:02
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:02
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:36
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:36
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:36
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:36
MHALL3
Chromium (Cr)
2.06
ug/L
1
1
EPA 200.8
12/07/2015 19:36
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:36
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:36
MHALL3
Lead (Pb)
1.86
ug/L
1
1
EPA 200.8
12/07/2015 19:36
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:36
MHALL3
Nickel (Ni)
1.24
ug/L
1
1
EPA 200.8
12/07/2015 19:36
MHALL3
Selenium (Se)
1.29
ug/L
1
1
EPA 200.8
12/07/2015 19:36
MHALL3
Thallium (TI) Low Level
0.551
ug/L
0.2
1
EPA 200.8
12/07/2015 19:36
MHALL3
Vanadium (V) Low Level
5.16
ug/L
0.3
1
EPA 200.8
12/07/2015 19:36
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:43
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:43
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:43
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:43
MHALL3
Chromium (Cr)
2.09
ug/L
1
1
EPA 200.8
12/08/2015 00:43
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:43
MHALL3
Copper (Cu)
1.03
ug/L
1
1
EPA 200.8
12/08/2015 00:43
MHALL3
Lead (Pb)
1.85
ug/L
1
1
EPA 200.8
12/08/2015 00:43
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:43
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 00:43
MHALL3
Selenium (Se)
1.05
ug/L
1
1
EPA 200.8
12/08/2015 00:43
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/08/2015 00:43
MHALL3
Vanadium (V) Low Level
5.08
ug/L
0.3
1
EPA 200.8
12/08/2015 00:43
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -1
Collection Date: 02 -Dec -15 11:05 AM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
2.20
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
2.22
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
1.22
ug/L
1
1
Selenium (Se)
1.50
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
6.81
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
130
mg/L
25
1
Total Carbon
Page 20 of 134
Sample #:
2015037774
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/08/2015 18:34
MHALL3
EPA 200.8
12/08/2015 18:34
MHALL3
EPA 200.8
12/08/2015 18:34
MHALL3
EPA 200.8
12/08/2015 18:34
MHALL3
EPA 200.8
12/08/2015 18:34
MHALL3
EPA 200.8
12/08/2015 18:34
MHALL3
EPA 200.8
12/08/2015 18:34
MHALL3
EPA 200.8
12/08/2015 18:34
MHALL3
EPA 200.8
12/08/2015 18:34
MHALL3
EPA 200.8
12/08/2015 18:34
MHALL3
EPA 200.8
12/08/2015 18:34
MHALL3
EPA 200.8
12/08/2015 18:34
MHALL3
EPA 200.8
12/08/2015 18:34
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/04/201511:24 CJELLIO
TOC 12 mg/L 1 10 SM5310C/EPA9060A 12/07/201514:46 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS 29 mg/L 10 1 SM2540D 12/07/2015 09:55 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -03S
Collection Date: 02 -Dec -15 12:40 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L M2 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
1 EPA 300.0
12/04/2015 04:15
INORGANIC IONS BY IC
1 EPA 245.1
12/04/2015 09:54
ACPAYNE
Chloride
16
mg/L
0.5
Sulfate
7.5
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
1 EPA 200.7
12/04/2015 12:46
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
12/04/2015 12:46
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
FCJORDA
1 EPA 200.7
12/04/2015 15:01
Aluminum (AI)
0.178
mg/L
0.005
Barium (Ba)
0.019
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
4.08
mg/L
0.01
Manganese (Mn)
0.037
mg/L
0.005
Strontium (Sr)
0.021
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (AI)
0.179
mg/L
0.005
Barium (Ba)
0.019
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
4.03
mg/L
0.01
Manganese (Mn)
0.037
mg/L
0.005
Strontium (Sr)
0.021
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
3.02
mg/L
0.01
Magnesium (Mg)
1.45
mg/L
0.005
Potassium (K)
1.19
mg/L
0.1
Sodium (Na)
9.78
mg/L
0.05
Page 21 of 134
Sample #: 2015037775
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/08/2015 08:59 LSTARL1
Vendor Method V_PACE
5 EPA 300.0
12/04/2015 04:15
BGN9034
1 EPA 300.0
12/04/2015 04:15
BGN9034
1 EPA 245.1
12/04/2015 09:54
ACPAYNE
1 EPA 245.1
12/05/2015 14:05
ACPAYNE
1 EPA 245.1
12/08/2015 17:28
TLINN
1 EPA 200.7
12/04/2015 12:46
FCJORDA
1 EPA 200.7
12/04/2015 12:46
FCJORDA
1 EPA 200.7
12/04/2015 12:46
FCJORDA
1 EPA 200.7
12/04/2015 12:46
FCJORDA
1 EPA 200.7
12/04/2015 12:46
FCJORDA
1 EPA 200.7
12/04/2015 12:46
FCJORDA
1 EPA 200.7
12/04/2015 12:46
FCJORDA
1 EPA 200.7
12/04/2015 15:01
FCJORDA
1 EPA 200.7
12/04/2015 15:01
FCJORDA
1 EPA 200.7
12/04/2015 15:01
FCJORDA
1 EPA 200.7
12/04/2015 15:01
FCJORDA
1 EPA 200.7
12/04/2015 15:01
FCJORDA
1 EPA 200.7
12/04/2015 15:01
FCJORDA
1 EPA 200.7
12/04/2015 15:01
FCJORDA
1 EPA 200.7
12/06/2015 14:13
FCJORDA
1 EPA 200.7
12/06/2015 14:13
FCJORDA
1 EPA 200.7
12/06/2015 14:13
FCJORDA
1 EPA 200.7
12/06/2015 14:13
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -03S
Collection Date: 02 -Dec -15 12:40 PM
Analyte
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.284
Barium (Ba)
0.019
Boron (B)
< 0.05
Iron (Fe)
4.10
Manganese (Mn)
0.036
Strontium (Sr)
0.021
Zinc (Zn)
< 0.005
Page 22 of 134
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037775
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/07/2015 15:06
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:06
MHH7131
mg/L
0.05
1
EPA 200.7
12/07/2015 15:06
MHH7131
mg/L
0.01
1
EPA 200.7
12/07/2015 15:06
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:06
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:06
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:06
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:41
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:41
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:41
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:41
MHALL3
Chromium (Cr)
1.54
ug/L
1
1
EPA 200.8
12/07/2015 19:41
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:41
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:41
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:41
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:41
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:41
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:41
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/07/2015 19:41
MHALL3
Vanadium (V) Low Level
2.47
ug/L
0.3
1
EPA 200.8
12/07/2015 19:41
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:05
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:05
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:05
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:05
MHALL3
Chromium (Cr)
1.48
ug/L
1
1
EPA 200.8
12/08/2015 01:05
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:05
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:05
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:05
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:05
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:05
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:05
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/08/2015 01:05
MHALL3
Vanadium (V) Low Level
2.67
ug/L
0.3
1
EPA 200.8
12/08/2015 01:05
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -03S
Collection Date: 02 -Dec -15 12:40 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
1.44
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
2.63
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
74
mg/L
25
1
Total Carbon
Page 23 of 134
Sample #:
2015037775
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/08/2015 18:58
MHALL3
EPA 200.8
12/08/2015 18:58
MHALL3
EPA 200.8
12/08/2015 18:58
MHALL3
EPA 200.8
12/08/2015 18:58
MHALL3
EPA 200.8
12/08/2015 18:58
MHALL3
EPA 200.8
12/08/2015 18:58
MHALL3
EPA 200.8
12/08/2015 18:58
MHALL3
EPA 200.8
12/08/2015 18:58
MHALL3
EPA 200.8
12/08/2015 18:58
MHALL3
EPA 200.8
12/08/2015 18:58
MHALL3
EPA 200.8
12/08/2015 18:58
MHALL3
EPA 200.8
12/08/2015 18:58
MHALL3
EPA 200.8
12/08/2015 18:58
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/04/201511:24 CJELLIO
TOC 0.832 mg/L 0.1 1 SM5310C/EPA9060A 12/07/201514:46 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 12/07/2015 09:55 CJELLIO

Certificate of Laboratory Analysis Page 24 of 134
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -031
Collection Date: 02 -Dec -15 3:40 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
1 EPA 300.0
12/04/2015 15:25
INORGANIC IONS BY IC
1 EPA 245.1
12/04/2015 09:56
ACPAYNE
Chloride
11
mg/L
0.2
Sulfate
0.89
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
1 EPA 200.7
12/04/2015 13:01
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
12/04/2015 13:01
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
FCJORDA
1 EPA 200.7
12/04/2015 15:04
Aluminum (AI)
0.048
mg/L
0.005
Barium (Ba)
0.019
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
2.10
mg/L
0.01
Manganese (Mn)
0.020
mg/L
0.005
Strontium (Sr)
0.036
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (AI)
0.047
mg/L
0.005
Barium (Ba)
0.019
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
2.03
mg/L
0.01
Manganese (Mn)
0.019
mg/L
0.005
Strontium (Sr)
0.036
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
6.23
mg/L
0.01
Magnesium (Mg)
0.389
mg/L
0.005
Potassium (K)
0.908
mg/L
0.1
Sodium (Na)
6.07
mg/L
0.05
Sample #: 2015037776
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/08/2015 09:03 LSTARL1
Vendor Method V_PACE
2 EPA 300.0
12/04/2015 15:25
BGN9034
1 EPA 300.0
12/04/2015 15:25
BGN9034
1 EPA 245.1
12/04/2015 09:56
ACPAYNE
1 EPA 245.1
12/05/2015 14:07
ACPAYNE
1 EPA 245.1
12/08/2015 17:37
TLINN
1 EPA 200.7
12/04/2015 13:01
FCJORDA
1 EPA 200.7
12/04/2015 13:01
FCJORDA
1 EPA 200.7
12/04/2015 13:01
FCJORDA
1 EPA 200.7
12/04/2015 13:01
FCJORDA
1 EPA 200.7
12/04/2015 13:01
FCJORDA
1 EPA 200.7
12/04/2015 13:01
FCJORDA
1 EPA 200.7
12/04/2015 13:01
FCJORDA
1 EPA 200.7
12/04/2015 15:04
FCJORDA
1 EPA 200.7
12/04/2015 15:04
FCJORDA
1 EPA 200.7
12/04/2015 15:04
FCJORDA
1 EPA 200.7
12/04/2015 15:04
FCJORDA
1 EPA 200.7
12/04/2015 15:04
FCJORDA
1 EPA 200.7
12/04/2015 15:04
FCJORDA
1 EPA 200.7
12/04/2015 15:04
FCJORDA
1 EPA 200.7
12/06/2015 14:17
FCJORDA
1 EPA 200.7
12/06/2015 14:17
FCJORDA
1 EPA 200.7
12/06/2015 14:17
FCJORDA
1 EPA 200.7
12/06/2015 14:17
FCJORDA

Site: BW -031
Collection Date: 02 -Dec -15 3:40 PM
Analyte
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.330
Barium (Ba)
0.020
Boron (B)
< 0.05
Iron (Fe)
2.20
Manganese (Mn)
0.019
Strontium (Sr)
0.036
Zinc (Zn)
< 0.005
Page 25 of 134
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037776
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/07/2015 15:10
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:10
MHH7131
mg/L
0.05
1
EPA 200.7
12/07/2015 15:10
MHH7131
mg/L
0.01
1
EPA 200.7
12/07/2015 15:10
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:10
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:10
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:10
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:47
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:47
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:47
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:47
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:47
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:47
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:47
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:47
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:47
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:47
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:47
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/07/2015 19:47
MHALL3
Vanadium (V) Low Level
1.88
ug/L
0.3
1
EPA 200.8
12/07/2015 19:47
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:11
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:11
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:11
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:11
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:11
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:11
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:11
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:11
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:11
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:11
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:11
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/08/2015 01:11
MHALL3
Vanadium (V) Low Level
1.83
ug/L
0.3
1
EPA 200.8
12/08/2015 01:11
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Page 26 of 134
Site: BW -031
Sample #: 2015037776
Collection Date: 02 -Dec -15 3:40 PM
Matrix: GW
WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 19:03
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 19:03
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 19:03
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 19:03
MHALL3
Chromium (Cr)
1.18
ug/L
1
1
EPA 200.8
12/08/2015 19:03
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 19:03
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 19:03
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 19:03
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 19:03
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 19:03
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 19:03
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/08/2015 19:03
MHALL3
Vanadium (V) Low Level
2.57
ug/L
0.3
1
EPA 200.8
12/08/2015 19:03
MHALL3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
72
mg/L
25
1
SM2540C
12/04/201511:24
CJELLIO
Total Carbon
TOC
0.395
mg/L
0.1
1
SM5310C/EPA9060A
12/07/201514:46
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
9.0
mg/L
5
1
SM2540D
12/07/2015 09:55
CJELLIO

Certificate of Laboratory Analysis Page 27 of 134
This report shall not be reproduced, except in full.
Order # J15120075
Site: CW -2
Collection Date: 02 -Dec -15 9:55 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.048 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
2 EPA 300.0
12/04/2015 15:43
INORGANIC IONS BY IC
1 EPA 245.1
12/04/2015 10:01
ACPAYNE
Chloride
4.5
mg/L
0.1
Sulfate
11
mg/L
0.2
MERCURY (COLD VAPOR) IN WATER
1 EPA 200.7
12/04/2015 13:05
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
12/04/2015 13:05
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
FCJORDA
1 EPA 200.7
12/04/2015 15:08
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.022
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.017
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
0.202
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.022
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.014
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
0.200
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
49.2
mg/L
0.01
Magnesium (Mg)
1.21
mg/L
0.005
Potassium (K)
0.526
mg/L
0.1
Sodium (Na)
3.37
mg/L
0.05
Sample #: 2015037777
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/08/2015 09:04 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
12/04/2015 15:43
BGN9034
2 EPA 300.0
12/04/2015 15:43
BGN9034
1 EPA 245.1
12/04/2015 10:01
ACPAYNE
1 EPA 245.1
12/05/2015 14:10
ACPAYNE
1 EPA 245.1
12/08/2015 17:40
TLINN
1 EPA 200.7
12/04/2015 13:05
FCJORDA
1 EPA 200.7
12/04/2015 13:05
FCJORDA
1 EPA 200.7
12/04/2015 13:05
FCJORDA
1 EPA 200.7
12/04/2015 13:05
FCJORDA
1 EPA 200.7
12/04/2015 13:05
FCJORDA
1 EPA 200.7
12/04/2015 13:05
FCJORDA
1 EPA 200.7
12/04/2015 13:05
FCJORDA
1 EPA 200.7
12/04/2015 15:08
FCJORDA
1 EPA 200.7
12/04/2015 15:08
FCJORDA
1 EPA 200.7
12/04/2015 15:08
FCJORDA
1 EPA 200.7
12/04/2015 15:08
FCJORDA
1 EPA 200.7
12/04/2015 15:08
FCJORDA
1 EPA 200.7
12/04/2015 15:08
FCJORDA
1 EPA 200.7
12/04/2015 15:08
FCJORDA
1 EPA 200.7
12/06/2015 14:20
FCJORDA
1 EPA 200.7
12/06/2015 14:20
FCJORDA
1 EPA 200.7
12/06/2015 14:20
FCJORDA
1 EPA 200.7
12/06/2015 14:20
FCJORDA

Site: CW -2
Collection Date: 02 -Dec -15 9:55 AM
Analyte
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.009
Barium (Ba)
0.021
Boron (B)
< 0.05
Iron (Fe)
0.097
Manganese (Mn)
< 0.005
Strontium (Sr)
0.208
Zinc (Zn)
< 0.005
Page 28 of 134
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037777
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/07/2015 15:14
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:14
MHH7131
mg/L
0.05
1
EPA 200.7
12/07/2015 15:14
MHH7131
mg/L
0.01
1
EPA 200.7
12/07/2015 15:14
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:14
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:14
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:14
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:52
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:52
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:52
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:52
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:52
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:52
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:52
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:52
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:52
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:52
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 19:52
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/07/2015 19:52
MHALL3
Vanadium (V) Low Level
0.346
ug/L
0.3
1
EPA 200.8
12/07/2015 19:52
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:17
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:17
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:17
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:17
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:17
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:17
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:17
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:17
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:17
MHALL3
Nickel (Ni)
1.02
ug/L
1
1
EPA 200.8
12/08/2015 01:17
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:17
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/08/2015 01:17
MHALL3
Vanadium (V) Low Level
0.323
ug/L
0.3
1
EPA 200.8
12/08/2015 01:17
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: CW -2
Collection Date: 02 -Dec -15 9:55 AM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
0.306
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
170
mg/L
25
1
Total Carbon
Page 29 of 134
Sample #:
2015037777
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/08/2015 19:09
MHALL3
EPA 200.8
12/08/2015 19:09
MHALL3
EPA 200.8
12/08/2015 19:09
MHALL3
EPA 200.8
12/08/2015 19:09
MHALL3
EPA 200.8
12/08/2015 19:09
MHALL3
EPA 200.8
12/08/2015 19:09
MHALL3
EPA 200.8
12/08/2015 19:09
MHALL3
EPA 200.8
12/08/2015 19:09
MHALL3
EPA 200.8
12/08/2015 19:09
MHALL3
EPA 200.8
12/08/2015 19:09
MHALL3
EPA 200.8
12/08/2015 19:09
MHALL3
EPA 200.8
12/08/2015 19:09
MHALL3
EPA 200.8
12/08/2015 19:09
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/04/201511:24 CJELLIO
TOC 0.216 mg/L 0.1 1 SM5310C/EPA9060A 12/07/201514:46 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 12/07/2015 09:55 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: CW -3
Collection Date: 02 -Dec -15 11:11 AM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.016 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
1 EPA 300.0
12/04/2015 03:40
INORGANIC IONS BY IC
1 EPA 245.1
12/04/2015 10:08
ACPAYNE
Chloride
5.7
mg/L
0.1
Sulfate
5.5
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
1 EPA 200.7
12/04/2015 13:09
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
12/04/2015 13:09
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
FCJORDA
1 EPA 200.7
12/04/2015 15:12
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.031
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.134
mg/L
0.01
Manganese (Mn)
0.016
mg/L
0.005
Strontium (Sr)
0.190
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.030
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.144
mg/L
0.01
Manganese (Mn)
0.017
mg/L
0.005
Strontium (Sr)
0.185
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
35.1
mg/L
0.01
Magnesium (Mg)
1.02
mg/L
0.005
Potassium (K)
0.644
mg/L
0.1
Sodium (Na)
4.39
mg/L
0.05
Page 30 of 134
Sample #: 2015037778
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/08/2015 09:05 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
12/04/2015 03:40
BGN9034
1 EPA 300.0
12/04/2015 03:40
BGN9034
1 EPA 245.1
12/04/2015 10:08
ACPAYNE
1 EPA 245.1
12/05/2015 14:12
ACPAYNE
1 EPA 245.1
12/08/2015 17:42
TLINN
1 EPA 200.7
12/04/2015 13:09
FCJORDA
1 EPA 200.7
12/04/2015 13:09
FCJORDA
1 EPA 200.7
12/04/2015 13:09
FCJORDA
1 EPA 200.7
12/04/2015 13:09
FCJORDA
1 EPA 200.7
12/04/2015 13:09
FCJORDA
1 EPA 200.7
12/04/2015 13:09
FCJORDA
1 EPA 200.7
12/04/2015 13:09
FCJORDA
1 EPA 200.7
12/04/2015 15:12
FCJORDA
1 EPA 200.7
12/04/2015 15:12
FCJORDA
1 EPA 200.7
12/04/2015 15:12
FCJORDA
1 EPA 200.7
12/04/2015 15:12
FCJORDA
1 EPA 200.7
12/04/2015 15:12
FCJORDA
1 EPA 200.7
12/04/2015 15:12
FCJORDA
1 EPA 200.7
12/04/2015 15:12
FCJORDA
1 EPA 200.7
12/06/2015 14:24
FCJORDA
1 EPA 200.7
12/06/2015 14:24
FCJORDA
1 EPA 200.7
12/06/2015 14:24
FCJORDA
1 EPA 200.7
12/06/2015 14:24
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: CW -3
Collection Date: 02 -Dec -15 11:11 AM
Analyte
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.026
Barium (Ba)
0.030
Boron (B)
< 0.05
Iron (Fe)
0.295
Manganese (Mn)
0.011
Strontium (Sr)
0.187
Zinc (Zn)
< 0.005
Page 31 of 134
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037778
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/07/2015 15:19
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:19
MHH7131
mg/L
0.05
1
EPA 200.7
12/07/2015 15:19
MHH7131
mg/L
0.01
1
EPA 200.7
12/07/2015 15:19
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:19
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:19
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:19
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:00
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:00
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:00
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:00
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:00
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:00
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:00
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:00
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:00
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:00
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:00
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/07/2015 20:00
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/07/2015 20:00
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:22
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:22
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:22
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:22
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:22
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:22
MHALL3
Copper (Cu)
1.02
ug/L
1
1
EPA 200.8
12/08/2015 01:22
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:22
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:22
MHALL3
Nickel (Ni)
2.84
ug/L
1
1
EPA 200.8
12/08/2015 01:22
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:22
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/08/2015 01:22
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/08/2015 01:22
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: CW -3
Collection Date: 02 -Dec -15 11:11 AM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
0.338
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
120
mg/L
25
1
Total Carbon
Page 32 of 134
Sample #:
2015037778
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/08/2015 19:15
MHALL3
EPA 200.8
12/08/2015 19:15
MHALL3
EPA 200.8
12/08/2015 19:15
MHALL3
EPA 200.8
12/08/2015 19:15
MHALL3
EPA 200.8
12/08/2015 19:15
MHALL3
EPA 200.8
12/08/2015 19:15
MHALL3
EPA 200.8
12/08/2015 19:15
MHALL3
EPA 200.8
12/08/2015 19:15
MHALL3
EPA 200.8
12/08/2015 19:15
MHALL3
EPA 200.8
12/08/2015 19:15
MHALL3
EPA 200.8
12/08/2015 19:15
MHALL3
EPA 200.8
12/08/2015 19:15
MHALL3
EPA 200.8
12/08/2015 19:15
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/04/201511:24 CJELLIO
TOC 0.604 mg/L 0.1 1 SM5310C/EPA9060A 12/07/201514:46 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 12/07/2015 09:55 CJELLIO

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: MW -411
Collection Date: 02 -Dec -15 12:32 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
BGN9034
10
INORGANIC IONS BY IC
12/04/2015 03:57
BGN9034
1
Chloride
10
mg/L
1
Sulfate
18
mg/L
1
MERCURY (COLD VAPOR) IN WATER
12/05/2015 13:30
ACPAYNE
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 200.7
12/04/2015 13:13
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
1
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
12/04/2015 13:13
FCJORDA
1
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.033
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.343
mg/L
0.01
Manganese (Mn)
0.022
mg/L
0.005
Strontium (Sr)
0.308
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
12/04/2015 15:16
FCJORDA
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.033
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
0.329
mg/L
0.01
Manganese (Mn)
0.023
mg/L
0.005
Strontium (Sr)
0.310
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
57.1
mg/L
0.01
Magnesium (Mg)
1.06
mg/L
0.005
Potassium (K)
0.666
mg/L
0.1
Sodium (Na)
2.80
mg/L
0.05
Page 33 of 134
Sample #: 2015037779
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/08/2015 09:07 LSTARL1
Vendor Method V_PACE
10
EPA 300.0
12/04/2015 03:57
BGN9034
10
EPA 300.0
12/04/2015 03:57
BGN9034
1
EPA 245.1
12/04/2015 09:45
ACPAYNE
1
EPA 245.1
12/05/2015 14:19
ACPAYNE
1
EPA 245.1
12/05/2015 13:30
ACPAYNE
1
EPA 200.7
12/04/2015 13:13
FCJORDA
1
EPA 200.7
12/04/2015 13:13
FCJORDA
1
EPA 200.7
12/04/2015 13:13
FCJORDA
1
EPA 200.7
12/04/2015 13:13
FCJORDA
1
EPA 200.7
12/04/2015 13:13
FCJORDA
1
EPA 200.7
12/04/2015 13:13
FCJORDA
1
EPA 200.7
12/04/2015 13:13
FCJORDA
1
EPA 200.7
12/04/2015 15:16
FCJORDA
1
EPA 200.7
12/04/2015 15:16
FCJORDA
1
EPA 200.7
12/04/2015 15:16
FCJORDA
1
EPA 200.7
12/04/2015 15:16
FCJORDA
1
EPA 200.7
12/04/2015 15:16
FCJORDA
1
EPA 200.7
12/04/2015 15:16
FCJORDA
1
EPA 200.7
12/04/2015 15:16
FCJORDA
1
EPA 200.7
12/06/2015 14:28
FCJORDA
1
EPA 200.7
12/06/2015 14:28
FCJORDA
1
EPA 200.7
12/06/2015 14:28
FCJORDA
1
EPA 200.7
12/06/2015 14:28
FCJORDA

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: MW -411
Collection Date: 02 -Dec -15 12:32 PM
Analyte
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.116
Barium (Ba)
0.039
Boron (B)
< 0.05
Iron (Fe)
1.39
Manganese (Mn)
0.026
Strontium (Sr)
0.317
Zinc (Zn)
< 0.005
Page 34 of 134
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037779
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/07/2015 15:32
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:32
MHH7131
mg/L
0.05
1
EPA 200.7
12/07/2015 15:32
MHH7131
mg/L
0.01
1
EPA 200.7
12/07/2015 15:32
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:32
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:32
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:32
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:07
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:07
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:07
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:07
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:07
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:07
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:07
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:07
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:07
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:07
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:07
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/07/2015 20:07
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/07/2015 20:07
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:28
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:28
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:28
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:28
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:28
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:28
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:28
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:28
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:28
MHALL3
Nickel (Ni)
2.75
ug/L
1
1
EPA 200.8
12/08/2015 01:28
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:28
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/08/2015 01:28
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/08/2015 01:28
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: MW -411
Collection Date: 02 -Dec -15 12:32 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
0.432
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
190
mg/L
25
1
Total Carbon
Page 35 of 134
Sample #:
2015037779
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/08/2015 19:20
MHALL3
EPA 200.8
12/08/2015 19:20
MHALL3
EPA 200.8
12/08/2015 19:20
MHALL3
EPA 200.8
12/08/2015 19:20
MHALL3
EPA 200.8
12/08/2015 19:20
MHALL3
EPA 200.8
12/08/2015 19:20
MHALL3
EPA 200.8
12/08/2015 19:20
MHALL3
EPA 200.8
12/08/2015 19:20
MHALL3
EPA 200.8
12/08/2015 19:20
MHALL3
EPA 200.8
12/08/2015 19:20
MHALL3
EPA 200.8
12/08/2015 19:20
MHALL3
EPA 200.8
12/08/2015 19:20
MHALL3
EPA 200.8
12/08/2015 19:20
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/04/201511:24 CJELLIO
TOC 0.585 mg/L 0.1 1 SM5310C/EPA9060A 12/07/201514:46 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS 9.0 mg/L 5 1 SM2540D 12/07/2015 09:55 CJELLIO

Certificate of Laboratory Analysis Page 36 of 134
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -3D
Collection Date: 02 -Dec -15 1:47 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
1 EPA 300.0
12/04/2015 10:08
INORGANIC IONS BY IC
1 EPA 245.1
12/04/2015 10:06
ACPAYNE
Chloride
3.3
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
1 EPA 200.7
12/04/2015 13:17
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
12/04/2015 13:17
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
FCJORDA
1 EPA 200.7
12/04/2015 15:20
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.052
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.33
mg/L
0.01
Manganese (Mn)
0.037
mg/L
0.005
Strontium (Sr)
0.161
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (AI)
0.006
mg/L
0.005
Barium (Ba)
0.050
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.32
mg/L
0.01
Manganese (Mn)
0.038
mg/L
0.005
Strontium (Sr)
0.161
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
30.0
mg/L
0.01
Magnesium (Mg)
1.11
mg/L
0.005
Potassium (K)
1.53
mg/L
0.1
Sodium (Na)
7.27
mg/L
0.05
Sample #: 2015037780
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/08/2015 09:08 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
12/04/2015 10:08
BGN9034
1 EPA 300.0
12/04/2015 10:08
BGN9034
1 EPA 245.1
12/04/2015 10:06
ACPAYNE
1 EPA 245.1
12/05/2015 14:26
ACPAYNE
1 EPA 245.1
12/08/2015 17:44
TLINN
1 EPA 200.7
12/04/2015 13:17
FCJORDA
1 EPA 200.7
12/04/2015 13:17
FCJORDA
1 EPA 200.7
12/04/2015 13:17
FCJORDA
1 EPA 200.7
12/04/2015 13:17
FCJORDA
1 EPA 200.7
12/04/2015 13:17
FCJORDA
1 EPA 200.7
12/04/2015 13:17
FCJORDA
1 EPA 200.7
12/04/2015 13:17
FCJORDA
1 EPA 200.7
12/04/2015 15:20
FCJORDA
1 EPA 200.7
12/04/2015 15:20
FCJORDA
1 EPA 200.7
12/04/2015 15:20
FCJORDA
1 EPA 200.7
12/04/2015 15:20
FCJORDA
1 EPA 200.7
12/04/2015 15:20
FCJORDA
1 EPA 200.7
12/04/2015 15:20
FCJORDA
1 EPA 200.7
12/04/2015 15:20
FCJORDA
1 EPA 200.7
12/06/2015 14:32
FCJORDA
1 EPA 200.7
12/06/2015 14:32
FCJORDA
1 EPA 200.7
12/06/2015 14:32
FCJORDA
1 EPA 200.7
12/06/2015 14:32
FCJORDA

Site: BW -3D
Collection Date: 02 -Dec -15 1:47 PM
Analyte
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.007
Barium (Ba)
0.052
Boron (B)
< 0.05
Iron (Fe)
1.55
Manganese (Mn)
0.039
Strontium (Sr)
0.164
Zinc (Zn)
< 0.005
Page 37 of 134
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037780
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/07/2015 15:44
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:44
MHH7131
mg/L
0.05
1
EPA 200.7
12/07/2015 15:44
MHH7131
mg/L
0.01
1
EPA 200.7
12/07/2015 15:44
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:44
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:44
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:44
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:15
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:15
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:15
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:15
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:15
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:15
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:15
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:15
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:15
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:15
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:15
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/07/2015 20:15
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/07/2015 20:15
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:33
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:33
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:33
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:33
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:33
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:33
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:33
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:33
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:33
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:33
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:33
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/08/2015 01:33
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/08/2015 01:33
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -3D
Collection Date: 02 -Dec -15 1:47 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
1.47
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
110
mg/L
25
1
Total Carbon
Page 38 of 134
Sample #:
2015037780
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/08/2015 19:26
MHALL3
EPA 200.8
12/08/2015 19:26
MHALL3
EPA 200.8
12/08/2015 19:26
MHALL3
EPA 200.8
12/08/2015 19:26
MHALL3
EPA 200.8
12/08/2015 19:26
MHALL3
EPA 200.8
12/08/2015 19:26
MHALL3
EPA 200.8
12/08/2015 19:26
MHALL3
EPA 200.8
12/08/2015 19:26
MHALL3
EPA 200.8
12/08/2015 19:26
MHALL3
EPA 200.8
12/08/2015 19:26
MHALL3
EPA 200.8
12/08/2015 19:26
MHALL3
EPA 200.8
12/08/2015 19:26
MHALL3
EPA 200.8
12/08/2015 19:26
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/04/201511:24 CJELLIO
TOC 1.1 mg/L 0.1 1 SM5310C/EPA9060A 12/07/201514:46 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 12/07/2015 09:55 CJELLIO

Certificate of Laboratory Analysis Page 39 of 134
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -31D DUP
Collection Date: 02 -Dec -15 1:47 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) < 0.01 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
1 EPA 300.0
12/04/2015 10:59
INORGANIC IONS BY IC
1 EPA 245.1
12/04/2015 11:09
ACPAYNE
Chloride
3.4
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
1 EPA 200.7
12/04/2015 13:21
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (Filtered)
12/04/2015 13:21
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
Mercury Dissolved (cold vapor) in Water (0.1mm FILTER)
FCJORDA
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
FCJORDA
1 EPA 200.7
12/04/2015 15:24
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.051
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.36
mg/L
0.01
Manganese (Mn)
0.038
mg/L
0.005
Strontium (Sr)
0.162
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
DISSOLVED METALS BY ICP (0.1mm FILTER)
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
0.051
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
1.36
mg/L
0.01
Manganese (Mn)
0.038
mg/L
0.005
Strontium (Sr)
0.163
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
UNDIGESTED METALS BY ICP
Calcium (Ca)
28.9
mg/L
0.01
Magnesium (Mg)
1.07
mg/L
0.005
Potassium (K)
1.49
mg/L
0.1
Sodium (Na)
7.26
mg/L
0.05
Sample #: 2015037781
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method V_SHEALY
1 EPA 353.2 12/08/2015 09:09 LSTARL1
Vendor Method V_PACE
1 EPA 300.0
12/04/2015 10:59
BGN9034
1 EPA 300.0
12/04/2015 10:59
BGN9034
1 EPA 245.1
12/04/2015 11:09
ACPAYNE
1 EPA 245.1
12/05/2015 14:28
ACPAYNE
1 EPA 245.1
12/08/2015 17:47
TLINN
1 EPA 200.7
12/04/2015 13:21
FCJORDA
1 EPA 200.7
12/04/2015 13:21
FCJORDA
1 EPA 200.7
12/04/2015 13:21
FCJORDA
1 EPA 200.7
12/04/2015 13:21
FCJORDA
1 EPA 200.7
12/04/2015 13:21
FCJORDA
1 EPA 200.7
12/04/2015 13:21
FCJORDA
1 EPA 200.7
12/04/2015 13:21
FCJORDA
1 EPA 200.7
12/04/2015 15:24
FCJORDA
1 EPA 200.7
12/04/2015 15:24
FCJORDA
1 EPA 200.7
12/04/2015 15:24
FCJORDA
1 EPA 200.7
12/04/2015 15:24
FCJORDA
1 EPA 200.7
12/04/2015 15:24
FCJORDA
1 EPA 200.7
12/04/2015 15:24
FCJORDA
1 EPA 200.7
12/04/2015 15:24
FCJORDA
1 EPA 200.7
12/06/2015 14:36
FCJORDA
1 EPA 200.7
12/06/2015 14:36
FCJORDA
1 EPA 200.7
12/06/2015 14:36
FCJORDA
1 EPA 200.7
12/06/2015 14:36
FCJORDA

Site: BW -31D DUP
Collection Date: 02 -Dec -15 1:47 PM
Analyte
Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Result
TOTAL RECOVERABLE METALS BY ICP
Aluminum (AI)
0.006
Barium (Ba)
0.050
Boron (B)
< 0.05
Iron (Fe)
1.36
Manganese (Mn)
0.036
Strontium (Sr)
0.156
Zinc (Zn)
< 0.005
Page 40 of 134
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Sample #:
2015037781
Antimony (Sb)
< 1
ug/L
Matrix:
GW WW
EPA 200.8
Units
Qualifiers RDL
DF
Method
Analysis Date/Time
Analyst
mg/L
0.005
1
EPA 200.7
12/07/2015 15:48
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:48
MHH7131
mg/L
0.05
1
EPA 200.7
12/07/2015 15:48
MHH7131
mg/L
0.01
1
EPA 200.7
12/07/2015 15:48
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:48
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:48
MHH7131
mg/L
0.005
1
EPA 200.7
12/07/2015 15:48
MHH7131
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:22
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:22
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:22
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:22
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:22
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:22
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:22
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:22
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:22
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:22
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/07/2015 20:22
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/07/2015 20:22
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/07/2015 20:22
MHALL3
Total Recoverable Metals Dissolved 0.1mm Filter
Antimony (Sb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:41
MHALL3
Arsenic (As)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:41
MHALL3
Beryllium (Be)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:41
MHALL3
Cadmium (Cd)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:41
MHALL3
Chromium (Cr)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:41
MHALL3
Cobalt (Co)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:41
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:41
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:41
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:41
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:41
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/08/2015 01:41
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/08/2015 01:41
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/08/2015 01:41
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: BW -31D DUP
Collection Date: 02 -Dec -15 1:47 PM
Analyte
Result
Units Qualifiers
RDL
DF
TOTAL RECOVERABLE METALS BY ICP -MS
Method
Analysis Date/Time
Analyst
Antimony (Sb)
< 1
ug/L
1
1
Arsenic (As)
< 1
ug/L
1
1
Beryllium (Be)
< 1
ug/L
1
1
Cadmium (Cd)
< 1
ug/L
1
1
Chromium (Cr)
< 1
ug/L
1
1
Cobalt (Co)
< 1
ug/L
1
1
Copper (Cu)
< 1
ug/L
1
1
Lead (Pb)
< 1
ug/L
1
1
Molybdenum (Mo)
< 1
ug/L
1
1
Nickel (Ni)
< 1
ug/L
1
1
Selenium (Se)
< 1
ug/L
1
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
TOTAL DISSOLVED SOLIDS
TDS
140
mg/L
25
1
Total Carbon
Page 41 of 134
Sample #:
2015037781
Matrix:
GW WW
Method
Analysis Date/Time
Analyst
EPA 200.8
12/08/2015 19:31
MHALL3
EPA 200.8
12/08/2015 19:31
MHALL3
EPA 200.8
12/08/2015 19:31
MHALL3
EPA 200.8
12/08/2015 19:31
MHALL3
EPA 200.8
12/08/2015 19:31
MHALL3
EPA 200.8
12/08/2015 19:31
MHALL3
EPA 200.8
12/08/2015 19:31
MHALL3
EPA 200.8
12/08/2015 19:31
MHALL3
EPA 200.8
12/08/2015 19:31
MHALL3
EPA 200.8
12/08/2015 19:31
MHALL3
EPA 200.8
12/08/2015 19:31
MHALL3
EPA 200.8
12/08/2015 19:31
MHALL3
EPA 200.8
12/08/2015 19:31
MHALL3
Vendor Method V_SHEALY
Vendor Method V_ELE1
SM2540C 12/04/201511:24 CJELLIO
TOC 0.938 mg/L 0.1 1 SM5310C/EPA9060A 12/07/201514:46 GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS < 5 mg/L 5 1 SM2540D 12/07/2015 09:55 CJELLIO

Certificate of Laboratory Analysis Page 42 of 134
This report shall not be reproduced, except in full.
Order # J15120075
Site: Filter Blank
Collection Date: 02 -Dec -15 6:00 PM
Analyte
Result
Units Qualifiers
RDL
Mercury Dissolved (cold vapor) in Water (Filtered)
EPA 245.1
12/05/2015 14:31
Mercury (Hg)
< 0.05
ug/L
0.05
DISSOLVED METALS BY ICP
1
EPA 200.7
12/04/2015 13:24
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
TOTAL RECOVERABLE METALS BY ICP -MS (DISSOLVED)
1
Antimony (Sb)
< 1
ug/L
1
Arsenic (As)
< 1
ug/L
1
Beryllium (Be)
< 1
ug/L
1
Cadmium (Cd)
< 1
ug/L
1
Chromium (Cr)
< 1
ug/L
1
Cobalt (Co)
< 1
ug/L
1
Copper (Cu)
< 1
ug/L
1
Lead (Pb)
< 1
ug/L
1
Molybdenum (Mo)
< 1
ug/L
1
Nickel (Ni)
< 1
ug/L
1
Selenium (Se)
< 1
ug/L
1
Thallium (TI) Low Level
< 0.2
ug/L
0.2
Vanadium (V) Low Level
< 0.3
ug/L
0.3
Sample #: 2015037782
Matrix: GW WW
DF
Method
Analysis Date/Time
Analyst
1
EPA 245.1
12/05/2015 14:31
ACPAYNE
1
EPA 200.7
12/04/2015 13:24
FCJORDA
1
EPA 200.7
12/04/2015 13:24
FCJORDA
1
EPA 200.7
12/04/2015 13:24
FCJORDA
1
EPA 200.7
12/04/2015 13:24
FCJORDA
1
EPA 200.7
12/04/2015 13:24
FCJORDA
1
EPA 200.7
12/04/2015 13:24
FCJORDA
1
EPA 200.7
12/04/2015 13:24
FCJORDA
1
EPA 200.8
12/07/2015 20:29
MHALL3
1
EPA 200.8
12/07/2015 20:29
MHALL3
1
EPA 200.8
12/07/2015 20:29
MHALL3
1
EPA 200.8
12/07/2015 20:29
MHALL3
1
EPA 200.8
12/07/2015 20:29
MHALL3
1
EPA 200.8
12/07/2015 20:29
MHALL3
1
EPA 200.8
12/07/2015 20:29
MHALL3
1
EPA 200.8
12/07/2015 20:29
MHALL3
1
EPA 200.8
12/07/2015 20:29
MHALL3
1
EPA 200.8
12/07/2015 20:29
MHALL3
1
EPA 200.8
12/07/2015 20:29
MHALL3
1
EPA 200.8
12/07/2015 20:29
MHALL3
1
EPA 200.8
12/07/2015 20:29
MHALL3

Certificate of Laboratory Analysis
This report shall not be reproduced, except in full.
Order # J15120075
Site: Equipment Blank
Collection Date: 02 -Dec -15 6:00 PM
Analyte Result Units Qualifiers RDL
ALKALINITY - (Analysis Performed by Shealy Labs)
Vendor Parameter Complete
NITRITE + NITRATE (COLORIMETRIC)
Nitrite + Nitrate (Colorimetric) 0.011 mg-N/L 0.01
CHROMIUM 6/ CHROMIUM 3 (CALC) - (Analysis Performed by Pace Laboratories)
Vendor Parameter
Complete
1 EPA 353.2
12/08/2015 09:10
INORGANIC IONS BY IC
Vendor Method
V_PACE
Chloride
< 0.1
mg/L
0.1
Sulfate
< 0.1
mg/L
0.1
MERCURY (COLD VAPOR) IN WATER
1 EPA 200.7
12/06/2015 14:39
Mercury (Hg)
< 0.05
ug/L
0.05
UNDIGESTED METALS BY ICP
12/06/2015 14:39
FCJORDA
1 EPA 200.7
Calcium (Ca)
< 0.01
mg/L
0.01
Magnesium (Mg)
< 0.005
mg/L
0.005
Potassium (K)
< 0.1
mg/L
0.1
Sodium (Na)
< 0.05
mg/L
0.05
TOTAL RECOVERABLE METALS BY ICP
1 EPA 200.7
12/07/2015 15:53
Aluminum (AI)
< 0.005
mg/L
0.005
Barium (Ba)
< 0.005
mg/L
0.005
Boron (B)
< 0.05
mg/L
0.05
Iron (Fe)
< 0.01
mg/L
0.01
Manganese (Mn)
< 0.005
mg/L
0.005
Strontium (Sr)
< 0.005
mg/L
0.005
Zinc (Zn)
< 0.005
mg/L
0.005
Page 43 of 134
Sample #: 2015037783
Matrix: GW WW
DF Method Analysis Date/Time Analyst
Vendor Method
V_SHEALY
1 EPA 353.2
12/08/2015 09:10
LSTARL1
Vendor Method
V_PACE
1 EPA 300.0
12/04/2015 09:51
BGN9034
1 EPA 300.0
12/04/2015 09:51
BGN9034
1 EPA 245.1
12/04/2015 11:12
ACPAYNE
1 EPA 200.7
12/06/2015 14:39
FCJORDA
1 EPA 200.7
12/06/2015 14:39
FCJORDA
1 EPA 200.7
12/06/2015 14:39
FCJORDA
1 EPA 200.7
12/06/2015 14:39
FCJORDA
1 EPA 200.7
12/07/2015 15:53
MHH7131
1 EPA 200.7
12/07/2015 15:53
MHH7131
1 EPA 200.7
12/07/2015 15:53
MHH7131
1 EPA 200.7
12/07/2015 15:53
MHH7131
1 EPA 200.7
12/07/2015 15:53
MHH7131
1 EPA 200.7
12/07/2015 15:53
MHH7131
1 EPA 200.7
12/07/2015 15:53
MHH7131

Certificate of Laboratory Analysis Page 44 of 134
This report shall not be reproduced, except in full.
Order # J15120075
Site: Equipment Blank
Sample #: 2015037783
Collection Date: 02 -Dec -15 6:00 PM
Matrix: GW
WW
Analyte
Result
Units Qualifiers
RDL
DF
Method
Analysis Date/Time
Analyst
TOTAL RECOVERABLE METALS BY ICP -MS
Antimony (Sb)
<1
ug/L
1
1
EPA 200.8
12/09/2015 12:00
MHALL3
Arsenic (As)
<1
ug/L
1
1
EPA 200.8
12/09/2015 12:00
MHALL3
Beryllium (Be)
<1
ug/L
1
1
EPA 200.8
12/09/2015 12:00
MHALL3
Cadmium (Cd)
<1
ug/L
1
1
EPA 200.8
12/09/2015 12:00
MHALL3
Chromium (Cr)
<1
ug/L
1
1
EPA 200.8
12/09/2015 12:00
MHALL3
Cobalt (Co)
<1
ug/L
1
1
EPA 200.8
12/09/2015 12:00
MHALL3
Copper (Cu)
< 1
ug/L
1
1
EPA 200.8
12/09/2015 12:00
MHALL3
Lead (Pb)
< 1
ug/L
1
1
EPA 200.8
12/09/2015 12:00
MHALL3
Molybdenum (Mo)
< 1
ug/L
1
1
EPA 200.8
12/09/2015 12:00
MHALL3
Nickel (Ni)
< 1
ug/L
1
1
EPA 200.8
12/09/2015 12:00
MHALL3
Selenium (Se)
< 1
ug/L
1
1
EPA 200.8
12/09/2015 12:00
MHALL3
Thallium (TI) Low Level
< 0.2
ug/L
0.2
1
EPA 200.8
12/09/2015 12:00
MHALL3
Vanadium (V) Low Level
< 0.3
ug/L
0.3
1
EPA 200.8
12/09/2015 12:00
MHALL3
METHANE - (Analysis Performed by
Shealy Labs)
Methane (CH4)
Complete
Vendor Method
V_SHEALY
SULFIDE - (Analysis Performed by
Element One)
Vendor Parameter
Complete
Vendor Method
V_ELE1
TOTAL DISSOLVED SOLIDS
TDS
< 25
mg/L
25
1
SM2540C
12/04/2015 11:24
CJELLIO
Total Carbon
TOC
0.188
mg/L
0.1
1
SM5310C/EPA9060A
12/07/201514:46
GHUTCHI
TOTAL SUSPENDED SOLIDS
TSS
< 5
mg/L
5
1
SM2540D
12/07/2015 09:55
CJELLIO
Qualifiers:
M1 Matrix spike recovery was High: the associated Laboratory Control Spike (LCS) was acceptable.
M2 Matrix spike recovery was Low: the associated Laboratory Control Spike (LCS) was acceptable.
-- Additional Information --
M2 - For sample 2015037773 (MW -491), method 245.1, the MS/MSD for this sample had recoveries below the
control limits (65%).

Page 45 of 134
Element One Inca
6319-D Carolina (Beach Rd.
Wilmington, VAC 28412
Phone: [phone]
Fax.: [phone]
ellabraiellab corn
26268-8* BW -031 Sulfide < 0.2 mg/L 2 0.1 12/02/15 1540
*Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Ken mith, Laboratory Director Page 1 of 2
26268 Duke Report Packet Compiled by -VO'--c2
NC Certifications: DW 37788 and DWQ DENR 604
m n tO n e
REPORT OF ANALYSES
Duke Energy
December 9, 2015
Laboratory Services
Client Project Name AB GW Assessment water Phase 3 (wells)
Weatherspoon
13339 Hagers Ferry Road Bld.
MG03A Client Project Number J15120075
Huntersville, NC 28078
PO Number
Sample Matrix GW WW
Sample Type Grab
Date Received
12/04/2015
Date Analyzed 12/04/2015
Method SM 4500 S2_ D
Time Received
1245
Delivered by Courier
Received by
LLB
eOne ID Duke Energy ID
Parameter Result Unit
Dil
DL Date
Time
Sampled
Sampled
26268-1 BW -2S
Sulfide < 0.1 mg/L
1
0.1 12/02/15
1625
26268-2* BW -21
Sulfide < 4.0 mg/L
40
0.1 12/02/15
1340
26268-3 MW -07
Sulfide < 0.1 mg/L
1
0.1 12/02/15
1410
26268-4* MW-44SA
Sulfide < 0.2 mg/L
2
0.1 12/02/15
0940
26268-5 MW -491
Sulfide < 0.1 mg/L
1
0.1 12/02/15
1203
26268-6* BW -1
Sulfide < 1.0 mg/L
10
0.1 12/02/15
1105
26268-7 BW -03S
Sulfide 0.150 mg/L
1
0.1 12/02/15
1240
26268-8* BW -031 Sulfide < 0.2 mg/L 2 0.1 12/02/15 1540
*Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Ken mith, Laboratory Director Page 1 of 2
26268 Duke Report Packet Compiled by -VO'--c2
NC Certifications: DW 37788 and DWQ DENR 604

REPORT OF ANALYSES
Page 46 of 134
Element One Inco
63119-D Carolina Beach Rd.
WHmington, SIC 284112
Phone: [phone]
Fax: [phone]
e1 laPnOai lalb_c®nn
Duke Energy
December 9, 2015
Laboratory Services
Client Project Name AB GW Assessment water Phase 3 (wells)
Weatherspoon
13339 Hagers
Ferry Road Bid. MG03A
Client Project Number J15120075
Huntersville, NC 28078
PO Number
Sample Matrix
GW WW
Sample Type Grab
Date Received
12/04/2015
Date Analyzed
12/04/2015
Method SM 4500 SZ- D
Time Received
1245
Delivered by
Courier
Received by
LLB
eOne ID
Duke Energy ID
Parameter Result Unit
Dil
DL Date
Time
Sampled
Sampled
26268-9
CW -2
Sulfide < 0.1 mg/L
1
0.1 12/02/15
0955
26268-10
CW -3
Sulfide < 0.1 mg/L
1
0.1 12/02/15
1111
26268-11*
MW -41 F
Sulfide < 0.2 mg/L
2
0.1 12/02/15
1232
26268-12
BW -3D
Sulfide < 0.1 mg/L
1
0.1 12/02/15
1347
26268-13
BW -3D Dup
Sulfide < 0.1 mg/L
1
0.1 12/02/15
1347
26268-14
Equipment Blank
Sulfide < 0.1 mg/L
1
0.1 12/02/15
1800
*Sample spike recovery outside of QA limits of 85-115%; dilution necessary to meet laboratory QA limits.
Page 2 of 2
NC Certifications: DW 37788 and DWQ DENR 604

Page 47 of 134
e
I
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POnjosslp - 3
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Z! -------------
vl C u u u h ti
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Liq F ; N d VN
= pp w
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iii '7 = =S o
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a J 3Y 3 (tp 1 �r, i E
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W _J I ._.._.. .S-.._ ._.. .._.. w w wf
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S Q ; B � }},�
7
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^�l
l

leme tOne SAMPLE SUBMISSION FORM
Report TAT 7 Days
Hold Time Expiration 12.09.15 @ 0940
Client: Duke Energy
LIMS No J15120075
Project ID Weathers oon
Lab I&,e16�t8
Analysis Due Date 12.08.15
Report Due Date 12.15.15
H >9
Date Rec:
12.04.15
If No, Record I If No, Record I
Time Rec:
1245
1625
Rec By
LLB
H >9
No Tem <_ 6°C es No
Ref. Method:
SM4500 S2 D
If No, Record I If No, Record I
sample wentification & conection information
Lab ID
Client ID Collection Date
Collection Time
Analysis Requested
1
BW -2S 12.02.15
1625
ulfide ,
2
BW -21 12.02.15
1340
u 1
3
MW -07 12.02.15
1410
u
4
MW-44SA 12.02.15
0940
ul#ae
5
MW 491 12.02.15
1203
ulf'
6
BW -1 12.02.15
1105
u "
7
BW -03S 12.02.15
1240
8
BW -031 12.02.15
1540
of i
9
CW -2 12.02.15
0955
ulfid
10
CW -3 12.02.15
1111
-
11
MW -41 F 12.02.15
1232
u
12
BW -3D 12.02.15
1347
Su
13
BW -3D Dup 12.02.15
1347
e
14
Equipment Blank 12.02.15
1800
ulfi'
The MS/MSD spike should approximate 2 to 3
times the sample concentration.
If no sulfide detected
NOTE for
Sulfide
at 100 pg/L spike the sample to render the final
spike concentration at
— 500 Ng/L

Page 49 of 134
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT gM
1.000
CLIENT: Duke
SPK LEVELLuM
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
XY
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17.10
KAM / DAM
------
0
STD 0.600--- -
ABS 0'°°
0.000 ��
0.094 0.400
0.240 0300
0.200
0.443 0.100 ----
0.633 0000
0.00 2.00 4.00 6.00
0.826 i X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
_0 0.626
6
800 1000
10.00
X
10
10
Y
-
-'S0
12.00
Slope
0.082116484
Correlation
0.999009688
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810 1
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26260-1
0.007
-0.2996
10
10
10
<
26260-1 SPK
0.319
3.6534
10
10
10
0.365
73%
5.0
26260-2
0.167
1.7276
10
10
10
0.173
26260-2 DUP
0.154
1.5629
10
10
10
0.156'' '
10%
26260-2 SPK
0.563
6.7448
10
10
10
0.674
104%
5.0
26260-3
0.041
0.1312
10
10
10
< 0.1
26260-3 SPK
0.447
5.2751
10
10
10
0.528
106%
5.0
26260-4
0.001
-0.3756
10
10
10
< OA -
26260 -4 SPK
0.417
4.8950
10
10
10
0.490
98%
5.0
26260-5
0.001
-0.3756
10
10
10
<
26260-5 SPK
0.313
3.5774
10
10
10
0.358
72%
5.0
26260-6
0.007
-0.2996
10
10
10
<
26260-6 SPK
0.187
1.9810
10
10
10
0.198
40%
5.0
26260-7
2.350
29.3857
10
10
10
2.939
26260-7 SPK
2.454
30.7034
10
10
10
3.070
26%
5.0
26260-8
0.003
-0.3503
10
10
10
<
26260-8 SPK
0.307
3.5014
10
10
10
0.350
70%
5.0
26260-9
0.000
0.0000
10
10
10
26260-9 SPK
0.466
5.5158
10
10
10
0.552
110%
5.0
#VALUE!
Blank
0.000
0.0000
10
10
10
<
QC
0.458 1
5.4145 1
10
10
10
0.541
108%
0
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 1 of 16

Page 50 of 134
METHOD:
SM 4555 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVEL (ug)
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
ug STD
SOLUTION
0.00
1.00
2.50
500
7.50
10.00
26260 / 261 / 262 ! 266 / 267 / 268
12/04/15 Na2S•91-12O Lot #
8:00 40721
17:10
KAM / DAM
0.
STD o.eoo
ABS 0700
-U70-00' °�
0.094 0.400
0.240 1 0300
0.200 .240
0.443-
0.633 00°°.� z.W 4.00 6.00
0.826
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
e
13s
3.00 low
10.00
X
10
10
Y
--500
�'.50
12100
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26260-10
0.000
0.0000
10
10
10
<_0.1
26260-10 SPK
0.447
5.2751
10
10
10
0.528
106%
5.0
26261-1
0.013
-0.2236
10
10
10
26261-1 DUP
0.001
-0.3756
10
10
10
< 0.1
N/A
26261-1 SPK
0.435
5.1231
10
10
10
0.512
102%
5.0
26261-2
0.002
-0.3629
10
10
10
< 0.1
26261-2 SPK
0.408
4.7810
10
10
10
0.478
96%
5.0
26261-3
0.004
-0.3376
10
10
10
< 0.1
26261-3 SPK
0.436
5.1358
10
10
10
0.514
103%
5.0
26261-4
0.000
0.0000
10
10
10
<
26261-4 SPK
0.337
3.8814
10
10
10
0.388
78%
5.0
26261-5
0.003
-0.3503
10
10
10
<
26261-5 SPK
0.338
3.8941
10
10
10
0.389
78%
5.0
26261-6
0.003
-0.3503
10
10
10
< 0.1
26261-6 SPK
0.433
5.0977
10
10
10
0.510
102%
5.0
26261-7
0.013
-0.2236
10
10
10
< 0.1
26261-7 SPK
0.407
4.7683
10
10
10
0.477
95%
5.0
26261-8
0.000
0.0000
10
10
10
'50.1
26261-8 SPK
0.450
5.3131
10
10
10
0.531
106%
5.0
Blank
0.000
0.0000
10
10
10 1
<
QC
0.459
5.4272
10
10 1
10 1
0.543
109%
5.0
Submitted for QA/QC- Date: 12/07/15
By: (Print) IKAM
/ DAM
(sign):
Page 2 of 16
/ ��

Page 51 of 134
METHOD:
SM 4500 S2- U
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT (u
1.000
CLIENT: Duke
SPK LEVELLucjl
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y
o.eox
STD aeon
ABS 0.700
0.000 0.600
0001
0.094 0.400
0.240 0.200 .240
0.443 0-1w
0.633 0.1x0.00 2.00 401 e.0o
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
1QC Std Lot: SD -44-4
STD ABSORPTION
One
-
011 low
10.00
X
10
10
Y
---°�
-'�
12.00
_
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26261-9
0.373
4.3376
10 1
10
10
26261-9 SPK
0.773
9.4055
10
10
10
0.941
101%
5.0
26261-10
0.003
-0.3503
10
10
10
26261-10 SPK
0.442
5.2118
10
10
10
0.521
104%
5.0
26261-11
0.003
-0.3503
10
10
10
0.1
26261-11 DUP
0.004
-0.3376
10
10
10
< 0.1
N/A
26261-11 SPK
0.440
5.1864
10
10
10
0.519
104%
5.0
26261-12
0.399
4.6670
10
10
10
777,
'0.467:
26261-12 SPK
0.802
9.7729
10
10
10
0.977
102%
5.0
26261-13
0.001
-0.3756
10
10
10
<Q.1:
26261-13 SPK
0.443
5.2244
10
10
10
0.522
104%
5.0
26262-1
0.004
-0.3376
10
10
10
26262-1 SPK
0.399
4.6670
10
10
10
0.467
93%
5.0
26262-2
0.000
0.0000
10
10
10
' 0.'1
26262-2 SPK
0.375
4.3629
10
10
10
0.436
87%
5.0
26262-3
0.179
1.8796
10
10
10
7777ER
26262-3 SPK
0.604
7.2643
10
10
10
0.726
108%
5.0
26262-4
0.004
-0.3376
10
10
10
<
26262-4 SPK
0.358
4.1475
10
10
10
0.415
83%
5.0
Blank
0.000
0.0000 1
10
10
10
<
QC
0.458
5.4145 1
10
10
10
0.541
108%
5.0
Submitted for QA/QC- Date:12/07/15
By: (Print)
KAM / DAM
(sign): , ,
Page 3 of 16

Page 52 of 134
METHOD:
SM 4555 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT (u
1.000
CLIENT: Duke
SPK LEVEL u
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y
STD 0.000 --
ABS 0700 -
0.000 0.800
V500 -
0.094 + 0.400
0.240 1 0� --
0.200
0.443 alm -
0.633 0000
0.00 2.00 4.00 8.00
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
0. B
8.00 1000
10.00
X
10
10
Y
4�
-+-250
-'�
taco
12.00
Slope
0.082116484
Correlation
0.999009688
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26262-5
0.023
-0.0969
10
10
10
< 0.1
26262-5 SPK
0.443
5.2244
10
10
10
0.522
104%
5.0
26262-6
0.000
0.0000
10
10
10
0.1
26262-6 SPK
0.376
4.3756
10
10
10
0.438
88%
5.0
26262-7
0.178
1.8669
10
10
10
0.187
26262-7 SPK
0.572
6.8588
10
10
10
0.686
100%
5.0
26262-8
0.000
0.0000
10
10
10
< 0.11
26262-8 DUP
0.000
0.0000
10
10
10
< 0.1
N/A
26262-8 SPK
0.375
4.3629
10
10
10
0.436
87%
5.0
26262-9
0.009
-0.2742
10
10
10
<
26262-9 SPK
0.120
1.1321
10
10
10
0.113
23%
5.0
26262-10
0.011
-0.2489
10
10
10
< 0.1
26262-10 SPK
0.400
4.6796
10
10
10
0.468
94%
5.0
26262-11
0.010
-0.2616
10
10
10
< Q.
26262-11 SPK
0.419
4.9204
10
10
10
0.492
98%
5.0
26262-12
0.393
4.5910
10
10
10
0.459,
26262-12 SPK
0.809
9.8616
10
10
10
0.986
105%
5.0
26262-13
0.882
10.7865
10
10
10
1.079
26262-13 SPK
1.221 1
15.0815
10
10
10
1.508
86%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.459
5.4272
10
10
10
0.543
109%
5
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 4 of 16 1

Page 53 of 134
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVEL (uM
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot#
8:00 40721
17:10
KAM / DAM
Y
STD
ABS °'°°
0.000 °. --- - - -
0.094 °^°° __-
0.240 °.200 --- ---- - 2<° �.
0.443--
0.633 0."
0.00 2.00 4.00 600
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
0.826
3°�
B00 low 12.00
10.00
X
10
10
Y
�,�
_ _ z�
�'�
_
Slope
0.082116484
Correlation 0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74/0
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26262-14
0.490
5.8199
10
10
10
0.582
26262-14 SPK
0.932
11.4200
10
10
10
1.142
112%
5.0
26262-15
0.001
-0.3756
10
10
10
< 0.1
26262-15 SPK
0.380
4.4262
10
10
10
0.443
89%
5.0
26262-16
0.000
0.0000
10
10
10
< 0.1
26262-16 SPK
0.432
5.0851
10
10
10
0.509
102%
5.0
26262-17
0.070
0.4986
10
10
10
< 0.1
26262-17 SPK
0.432
5.0851
10
10
10
0.509
102%
5.0
26262-18
0.077
0.5873
10
10
10
< 0.1
26262-18 DUP
0.077
0.5873
10
10
10
< 0.1
N/A
26262-18 SPK
0.428
5.0344
10
10
10
0.503
101 1G
5.0
26262-19
0.070
0.4986
10
10
10
<,0.1
26262-19 SPK
0.480
5.6932
10
10
10
0.569
114%
5.0
26262-20
0.725
8.7973
10
10
10
0.880
26262-20 SPK
1.046
12.8643
10
10
10
1.286
81%
5.0
26262-21
0.027
-0.0462
10
10
10
i} 111
26262-21 SPK
0.385
4.4896
10
10
10
0.449
90%
5.0
26262-22
0.063
0.4099
10
10
10
<
26262-22 SPK
0.489
5.8073
10
10
10
0.581
116%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.459
5.4272
10
10
10
0.543
109%
5
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 5 of 16 9

Page 54 of 134
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
u /mL
DETECTION LIMIT (ug)
1,000
CLIENT: Duke
SPK LEVEL(ug)
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y
STD 0800
ABS D.00
0.000 0.500
0.094 °
o�
0.240
0.443-
0.633 00.00 2.00 4.00 8.00
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
IQC Std Lot: SD -44-4
ISTDABSORPTION IY
r
6.00 ,0.00 12.00
10.00
X
10
10
�zs°
Slope
0.082116484
Correlation 0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26262-23
0.012
-0.2362
10 1
10
10
<0.1
26262-23 SPK
0.414
4.8570
10
10
10
0.486
97%
5.0
26262-24
0.003
-0.3503
10
10
10
<
26262-24 SPK
0.343
3.9575
10
10
10
0.396
79%
5.0
26262-25
0.350
4.0462
10
10
10
0.405
26262-25 SPK
0.752
9.1394
10 1
10
10
0.914
102%
5.0
26262-26
0.004
-0.3376
10
10
10
< 0.1
26262-26 SPK
0.440
5.1864
10
10
10
0.519
104%
5.0
26260-1
0.004
-0.3376
10
10
5
< 0.2
26260-1 SPK
0.366
4.2489
10
10
5
0.850
85%
5.0
26260-5
0.011
-0.2489
10
10
5
< 0.2'r .
26260-5 SPK
0.368
4.2742
10
10
5
0.855
85%
5.0
26260-6
0.002
-0.3629
10
10
5
<
26260-6 SPK
0.295
3.3493
10
10
5
0.670
67%
5.0
26260-7
1.378
17.0707
10
10
5
3.414
26260-7 SPK
1.646
20.4662
10
10
5
4.093
68%
5.0
26260-8
0.003
-0.3503
10
10
5
<
26260-8 SPK
0.345
3.9828
10
10
5
0.797
80%
5.0
26261-4
0.000
0.0000
10
10
5777777,
��9' r "e 0.2
26261-4 SPK
0.381
4.4389
10
10
5
0.888
89%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.459
5.4272
10
10 1
10
0.543
109%
0
Submitted for QA/QC- Date:12/07/15
By: (Print) I
KAM / DAM
(sign):
Page 6 of 16
��2%c

Page 55 of 134
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT (ug)
1.000
CLIENT:
Duke
SPK LEVEL (ug)
5
Lab ID#
26260 / 261 / 262 / 266 /
12/04/15
8:00
17:10
KAM / DAM
Y
267 / 268
Na2S•9H2O Lot #
40721
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
10.00
X
10
10
Y
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
STD
°600-A
992
0700
ABS
0.600
-000
0.00
1.00
2.50
5.00
7.50
10.00
0.000
600
2.50
0.094 ° 400
° 300
0.240
0.200
T X044
0.443
0.633
0.826
0.00
2.00
4.00
6.00
X
6.00
1000 12.00
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26261-5
0.000
0.0000
10
10
5
< 0.2
26261-5 SPK
0.402
4.7050
10
10
5
0.941
94%
5.0
26262-4
0.005
-0.3249
10
10
5
< 0.2
26262-4 SPK
0.374
4.3502
10
10
5
0.870
87%
5.0
26262-9
0.003
-0.3503
10
10
5
<
26262-9 SPK
0.249
2.7665
10
10
5
0.553
55%
5.0
26262-13
0.525
1 6.2634
10
10
5
1.25
26262-13 SPK
0.888
10.8625
10
10
5
2.173
92%
5.0
26262-20
0.377
4.3882
10
10
5
0.878
26262-20 SPK
0.757
9.2028
10
10
5
1.841
96%
5.0
26262-22
0.035
0.0552
10
10
5
< 0.2
26262-22 SPK
0.458 1
5.4145
10
10
5
1.083
108%
5.0
26262-24
0.006
-0.3123
10
10
5
< 0.2
26262-24 SPK
0.387
4.5149
10
10
5
0.903
90%
5.0
26260-6
0.005
-0.3249
10
10
2
<
26260-6 SPK
0.347
4.0081
10
10
2
2.004
80%
5.0
26260-7
0.671
8.1132
10
10
2
4.057
26260-7 SPK
1.000
12.2815
10
10
2
6.141
83%
5.0
26260-8
0.005
-0.3249
10
10
2
< 0.5
26260-8 SPK
0.405
4.7430
10
10
2
2.371
95%
5.0
Blank
0.000 1
0.0000
10
10
10
<
QC 1
0.460 1
5.4398
10
10
10
0.544
109%
5.0
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign): ice.
i
Page 7 of 16

Page 56 of 134
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT (u
1.000
CLIENT: Duke
SPK LEVELLuM
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
SAMPLE
I.D.
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y o.�
STD
ABS °'°°
0.000 0.600
0soo
0.094 0.4W ,•'
0.240 o.
0.443 i 0.100 - -
0.633 0000.w 2.00 4.00 6.00
0.826 i X
Slope
SAMP ug PER ALI in mL PREP ALI in mL
ABS ALIQUOT ANALYZED VOL in mL TAKEN
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
1 QC Std Lot: SD -44-4
JSTD ABSORPTION
3
Boo low
0.082116484 Correlation
RESULTS % RPD
ug/mL % SPK REC
10.00
X
10
10
I Y
T5�
12.00
0.999009688
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26262-9
0.002
-0.3629
10
10
2
< 0.5 III
26262-9 SPK
0.377
4.3882
10
10
2
2.194
88%
5.0
26260-6
0.012
-0.2362
10
10
1
<,1,0 ,
26260-6 SPK
0.386
4.5023
10
10
1
4.502
90%
5.0
26260-7
0.343
3.9575
10
10
1
3.96.1.
26260-7 SPK
0.733
8.8987
10
10
1
8.899
99%
5.0
26266-1
0.005
-0.3249
10
10
10
< 0.1
26266-1 SPK
0.431
5.0724
10
10
10
0.507
101%
5.0
26266-2
0.002
-0.3629
10
10
10
<
26266-2 DUP
0.001
-0.3756
10
10
10
<
N/A
26266-2 SPK
0.347
4.0081
10
10
10
0.401
80%
5.0
26266-3
0.003
-0.3503
10
10
10
<
26266-3 SPK
0.224
2.4498
10
10
10
0.245
49%
5.0
26266-4
0.000
0.0000
10
10
10
26266-4 SPK
0.404
4.7303
10
10
10
0.473
95%
5.0
26266-5
0.180
1.8923
10
10
10
0.189
26266-5 SPK
0.563
6.7448
10
10
10
0.674
97%
5.0
26266-6
0.000
0.0000
10
10
10
< 0.1
26266-6 SPK
0.431
5.0724
10
10
10
0.507
101%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.460
5.4398
10
10
10
0.544
1099/.
5.0
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 8 of 16 c

METHOD:
SM 4500 S2- 1)
ELEMENT ASSAY:
Sulfide
CLIENT:
Duke
Lab ID#
26260 / 261 / 262 / 266 / 267 1268
Date:
12/04/15
Time Analysis Begun
8:00
Time Analysis Ended
17:10
Analyst:
X
KAM / DAM
Y
ug STD
STD
1.000
SOLUTION
ABS
Na2S•9H2O Lot #
40721
0.00
0.000
STANDARD conc(ppm)
1.00
0.094
10
2.50
0.240
STD ABSORPTION
5.00
0.443
0.000
750
0 633
Page 57 of 134
ELEMENT ONE
Wave Length 664
DETECTION LIMIT (uM
1.000
SPK LEVEL (uM
5
Na2S•9H2O Lot #
40721
MAX ALIQUOT
10.00
STANDARD conc(ppm)
X
Cal Std Lot: SD -44-3
10
QC Std Lot: SD -44-4
10
STD ABSORPTION
Y
.6 13
0.000
0.500
O.e00
Slope
0.082116484
Correlation
0.700
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
0.600
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
.6 13
0.000
0.500
10
10
10
<
0.400
0
Std. B. 1.00
0.097
443
10
10
0.300
<
84.07%
1.0
Std. B. 2.50
0.236
0.200
10
240
10
0.260
104.07%
.1w
Std. B. 5.00
0.454
5.3638
10
10
0.000
- -
107.28%
5.0
Std. B. 7.50
0.638
0.00 2.00 4.00 8:00 8.00 1000
10.00 0.826 X
SOU
00
Page 9 of 16 ���!�
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
1 7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26266-7
0.004
1 -0.3376
10
10
10
<0
26266-7 SPK
0.347
4.0081
10
10
10
0.401
80%
5.0
26266-8
0.000
0.0000
10
10
10
<
26266-8 SPK
0.331
3.8054
10
10
10
0.381
76%
5.0
26266-9
0.003
-0.3503
10
10
10
26266-9 SPK
0.368
1 4.2742
10
10
10
0.427
85%
5.0
26266-10
0.001
-0.3756
10
10
10`,
e. < 0.1"'
26266-10 SPK
0.405
4.7430
10
10
10
0.474
95%
5.0
26266-11
0.105
0.9421
10
10
10
<
26266-11 DUP
0.099
0.8660
10
10
10
<
N/A
26266-11 SPK
0.488
5.7946
10
10
10
0.579
116%
5.0
26266-12
0.406
4.7557
10
10
10
0.476
26266-12 SPK
0.696
8.4299
10
10
10
0.843
73%
5.0
26266-13
0.000
0.0000
10
10
10
< 0.1
26266-13 SPK
0.387
4.5149
10
10
10
0.451
90%
5.0
26266-14
0.000
0.0000
10
10
10
< 0.1
26266-14 SPK
0.365
4.2362
10
10
10
0.424
85%
5.0
26266-15
0.000
0.0000
10
10
10
< 0.1
26266-15 SPK
0.441
5.1991
10
10
10
0.520
104%
5.0
Blank
0.000
0.0000
10
10 1
10
<
QC
1 0.440
5.1864
10
10
10
0.519
104%
5,0
Submitted for QA/QC-
Date: 12/07/15
By: (Print)
KAM
/ DAM
(sign):
Page 9 of 16 ���!�

Page 58 of 134
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT (ug)
1.000
CLIENT: Duke
SPK LEVEL (ug)
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y a.�
STD 0.
ABS 0700
0.000 0600
y
0.094 0d00
0.240 0300
0.200 .240
0.443 Ota
0.633 I o"000m 2.00 4.00 6.0o
0.826 j X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
IQC Std Lot: SD -44-4
JSTD ABSORPTION
0'
eoo low
10.00
X
10
10
Y
12.00
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26266-16
0.031 1
0.0045
10
10
10
< 0.1
26266-16 SPK
0.387 1
4.5149
10
10
10
0.451
90%
5.0
26266-17
0.010
-0.2616
10
10
10
< 0.1
26266-17 SPK
0.408
4.7810
10
10
10
0.478
96%
5.0
26266-18
0.000
0.0000
10
10
10
< 0.1
26266-18 SPK
0.433
5.0977
10
10
10
0.510
102%
5.0
26266-19
0.011 1
-0.2489
10
10
10
< 0.1
26266-19 SPK
0.431
5.0724
10
10
10
0.507
101%
5.0
26266-20
0.001
-0.3756
10
10
10
< 0.1
26266-20 SPK
0.426
5.0091
10
10
10
0.501
100%
5.0
26266-21
0.000
0.0000
10
10
10
< 0.1
26266-21 DUP
0.000
0.0000
10
10
10
< 0.1
N/A
26266-21 SPK
0.417 1
4.8950
10
10
10
0.490
98%
5.0
26266-22
0.000
0.0000
10
10
10
< 0.1
26266-22 SPK
0.418
4.9077
10
10
10
0.491
98%
5.0
26267-1
0.000
0.0000
10
10
10
< 0.1
26267-1 SPK
0.418
4.9077
10
10
10
0.491
98%
5.0
26267-2
0.077
0.5873
10
10
10
<
26267-2 SPK
0.498
5.9213
10
10
10
0.592
118%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.438
5.1611
10
10
10
0.516
103%
50
Submitted for QA/QC- Date:12/07/15
By: (Print)
KAM / DAM
(sign): w'
Page 10 of 16
c

Page 59 of 134
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVELLugj
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y
STD o
ABS 0.700
osao
0.000 osoo --
0.094 I 0400 `"9
0.240 1
0.443
0.633 I o.000 2.00 aoo 6.00
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
0.840
13
-
a.00 low
10.00
X
10
10
Y
--no
-500
uoo
Slope
0.082116484
Correlation
0.999009688
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26267-3
0.033
0.0298
10
10
10
<
26267-3 SPK
0.114
1.0561
10
10
10
0.106
21%
5.0
26267-4
0.005
-0.3249
10
10
10
< 0.1
26267-4 SPK
0.392
4.5783
10 1
10
10
0.458
92%
5.0
26267-5
0.002
-0.3629
10
10
10
< 0.1
26267-5 SPK
0.401
4.6923
10
10
10
0.469
94%
5.0
26267-6
0.010
-0.2616
10
10
10
< 0.1
26267-6 SPK
0.438
5.1611
10
10
10
0.516
103%
5.0
26267-7
0.002
-0.3629
10
10
10
< 0.1
26267-7 SPK
0.451
5.3258
10
10
10
0.533
107%
5.0
26267-8
0.068
0.4733
10
10
10
<
26267-8 SPK
0.493
5.8579
10
10
10
0.586
117%
5.0
26267-9
0.000
0.0000
10
10
10
< 0.1
26267-9 DUP
0.000
0.0000
10
10
10
< 0.1
N/A
26267-9 SPK
0.424
4.9837
10
10
10
0.498
100%
5.0
26267-10
0.260
2.9059
10
10
10
0.291
26267-10 SPK
0.649
7.8344
10
10
10
0.783
99%
5.0
26267-11
0.074
0.5493
10
10
10
i. < 0.1
26267-11 SPK
0.457
5.4018
10
10
10
0.540
108%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.442
5.2118
10
10
10
0.521
104%
.0
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 11 of 16//i%��
G

Page 60 of 134
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVELLuM
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
750
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y o.�
STD --
ABS 070°
0.000 osoo ------
0.094 i o..00
0.240 1111 0.a - -_
oao - - z�
0.443 0.+�
0.633 + o.000 m z.00 4.00 6.00
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
13
e00 lo.w
10.00
X
10
10
Y
o�
- -
000
iz.00
Slope
0.082116484
Correlation
0.999009688
SAMPLE
1. D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74/0
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26267-12
0.009
-0.2742
10
10
10
;z< 0.1, ,.
26267-12 SPK
0.431
5.0724
10
10
10
0.507
101%
5.0
26267-13
0.001
-0.3756
10
10
10
"'<,01-,,
'< 0.1-
26267-13
26267-13 SPK
0.403
4.7177
10
10
10
0.472
94%
5.0
26267-14
0.022
-0.1095
10
10
10
<
26267-14 SPK
0.133
1.2968
10
10
10
0.130
26%
5.0
26268-1
0.075
0.5620
10
10
10
0.1
26268-1 SPK
0.450
5.3131
10
10
10
0.531
106%
5.0
26268-2
0.074
0.5493
10
10
10
<
26268-2 SPK
0.201
2.1584
10
10
10
0.216
43%
5.0
26268-3
0.017
-0.1729
10
10
10
< 0.1
26268-3 SPK
0.447
5.2751
10
10
10
0.528
106%
5.0
26268-4
0.000
0.0000
10
10
10
<
26268-4 SPK
0.303
3.4507
10
10
10
0.345
69%
5.0
26268-5
0.024
-0.0842
10
10
10
< 0.1
26268-5 DUP
0.010
-0.2616
10
10
10
< 0.1
N/A
26268-5 SPK
0.389
4.5403
10
10
10
0.454
91%
5.0
26268-6
0.013
-0.2236
10
10
10
< 0.1
26268-6 SPK
0.104
0.9294
10
10
10
<
19%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.442
5.2118
10
10
10
0.521
104%
5.0
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
�-
Page 12 of 16 4�/��

Page 61 of 134
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT (u
1.000
CLIENT: Duke
SPK LEVEL (uq)
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H20 Lot #
8:00 40721
17:10
KAM / DAM
Y
STD 0. o
ABS 0.700
0.000 °�
0. 0.°094
0.240 °
0.443 0.100
0.633 0.000 00 zoo aw 6.00
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
0M
&W loan
10.00
X
10
10
Y
T ,000
1200
SAMPLE SAMP ug PER
1. D. ABS ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
Slope
ALI in mL
TAKEN
0.082116484
RESULTS
ug/mL
Correlation
% RPD
% SPK REC
0.999009688
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26268-7
0.149
1.4995
10
10
10
0.150'
26268-7 SPK
0.565
6.7702
10
10
10
0.677
105%
5.0
26268-8
0.070
0.4986
10
10
10
<
26268-8 SPK
0.489
5.8073
10
10
10
0.581
116%
5.0
26268-9
0.001
-0.3756
10
10
10
< 0.1
26268-9 SPK
0.434
5.1104
10
10
10
0.511
102%
5.0
26268-10
0.000
0.0000
10
10
10
< 0.1
26268-10 SPK
0.421
4.9457
10
10
10
0.495
99%
5.0
26268-11
0.001
-0.3756
10
10
10
<
26268-11 SPK
0.341
3.9321
10
10
10
0.393
79%
5.0
26268-12
0.030
-0.0082
10
10
10
< 0.1
26268-12 SPK
0.463
5.4778
10
10
10
0.548
110%
5.0
26268-13
0.024
-0.0842
10
10
10
< 0.1
26268-13 SPK
0.451
5.3258
10
10
10
0.533
107%
5.0
26268-14
0.000
0.0000
10
10
10
< 0.1
26268-14 SPK
0.442
5.2118
10
10
10
0.521
104%
5.0
26266-2
0.000
0.0000
10
10
5
< 0.2
26266-2 DUP
0.013
-0.2236
10
10
5
< 0.2
N/A
26266-2 SPK
0.385
4.4896
10
10
5
0.898
90%
5.0
Blank
0.000
0.0000 1
10
10
10
<
QC
0.441
5.1991
10
10
10
0.520
104%
50
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 13of 1616

Page 62 of 134
M Ti-i0D : SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY: Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER ug/mL
DETECTION LIKEjug) 1.000
CLIENT: Duke
SPK LEVELLu5
Lab ID# 26260 / 261 / 262 / 266 / 267 / 268
Na2S•9H2O Lot #
40721
MAX ALIQUOT 10.00
Date: 12/04/15
STANDARD conc(ppm) X
Time Analysis Begun 8:00
Cal Std Lot: SD -44-3 10
Time Analysis Ended 17:10
QC Std Lot: SD -44-4 10
Analyst: KAM / DAM
STD ABSORPTION Y
X Y
0.0000
ug STD
STD
0.70
SOLUTION
ABS
Slope
0.00
0.000
Y
0.400
1.00
0.094
-
2.50
0.240
o.,m
5.00
0.443
SPIKE
LEVEL
7.50
0.633
0.0000
10.00 0.826
0.800
0.500
aza
0.70
0. 0
Slope
0.500
Correlation
Y
0.400
443
0.30
-
0.20
.240
o.,m
--
a"
SPIKE
LEVEL
0.0
2.0 40 800
Page 14 of 16
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26266-3
0.022
-0.1095
10
10
5
< 0.2:' `
26266-3 SPK
0.398
4.6543
10
10
5
0.931
93%
5.0
26266-7
0.000
0.0000
10
10
5
<
26266-7 SPK
0.361
4.1855
10
10
5
0.837
84%
5.0
26266-8
0.008
-0.2869
10
10
5
<
26266-8 SPK
0.358
4.1475
10
10
5
0.830
83%
5.0
26266-11
0.049
0.2325
10
10
5
< 0.2
26266-11 DUP
0.049
0.2325
10
10
5
< 0.2
N/A
26266-11 SPK
0.445
5.2498
10
10
5
1.050
105%
5.0
26266-12
0.225
2.4624
10
10
5
0.492
26266-12 SPK
0.599
7.2009
10 1
10
5
1.440
95%
5.0
26267-2
0.037
0.0805
10
10
5
26267-2 SPK
0.464
5.4905
10
10
5
1.098
110%
5.0
26267-3
0.014
-0.2109
10
10
5
<
26267-3 SPK
0.148
1.4869
10
10
5
0.297
30%
5.0
26267-8
0.040
0.1185
10
10
5
< 01'
26267-8 SPK
0.447
5.2751
10
10
5
1.055
106%
5.0
26267-14
0.013
-0.2236
10
10
5
< 0.1
26267-14 SPK
0.243
2.6905
10
10
5
0.538
54%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.442
5.2118
10
10
10
0.521
104%
.0
Submitted for QA/QC-
Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 14 of 16

Page 63 of 134
METHOD:
SM 4500 S2-
E
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVELLu
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10 00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM / DAM
Y
0.000
STD 060D
ABS 0J00 -
0.600---
0.000 0560
0°° -
0.094 lifll aa--_-sao
0.240 0300
0.200
0.443
0.633 O�.oO 2A0 6.00 6.00
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
63
6.00 10.00
10.00
X
10
10
Y
a6
0
-'S6
12.00
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER ALI in mL
ALIQUOT ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26268-2
0.007
-0.2996
10
10
5
<
26268-2 SPK
0.290
3.2860
10
10
5
0.657
66%
5.0
26268-4
0.000
0.0000
10
10
5
< 0.2
26268-4 SPK
0.368
4.2742
10
10
5
0.855
85%
5.0
26268-6
0.006
-0.3123
10
10
5
<
26268-6 SPK
0.193
2.0570
10
10
5
0.411
41%
5.0
26268-8
0.037
0.0805
10
10
5
�° < 0.2
26268-8 SPK
0.453
5.3511
10 1
10
5
1.070
107%
5.0
26268-11
0.004
-0.3376
10
10
5
-<'0.2'
26268-11 SPK
0.372
4.3249
10
10
5
0.865
86%
5.0
26266-7
0.001
-0.3756
10
10
2
26266-7 SPK
0.384
4.4769
10
10
2
2.238
90%
5.0
26266-8
0.006
-0.3123
10
10
2
26266-8 SPK
0.375
4.3629
10
10
2
2.181
87%
5.0
26267-3
0.004
-0.3376
10
10
2
<
26267-3 SPK
0.297
3.3747
10
10
2
1.687
67%
5.0
26267-14
0.005
-0.3249
10
10
2
<
26267-14 SPK
0.357
4.1348
10
10
2
2.067
83%
5.0
26268-2
0.020
-0.1349
10
10
2
<
26268-2 SPK
0.225
2.4624
10
10
2
1.231
49%
5.0
Blank
0.000
0.0000
10
10 1
10
<
QC
0.443
5.2244
10
10
10
0.522
104%
5.
Submitted for QA/QC- Date: 12/07/15
By: (Print)
KAM / DAM
(sign):
Page 15 of 16

Page 64 of 134
METHOD:
SM 4500 S2- D
ELEMENT ONE
ELEMENT ASSAY:
Sulfide
Spectrophotometer
Wave Length 664
UNITS OF ANSWER
ug/mL
DETECTION LIMIT u
1.000
CLIENT: Duke
SPK LEVEL (ug)
5
Lab ID#
Date:
Time Analysis Begun
Time Analysis Ended
Analyst:
X
ug STD
SOLUTION
0.00
1.00
2.50
5.00
7.50
10.00
26260 / 261 / 262 / 266 / 267 / 268
12/04/15 Na2S•9H2O Lot #
8:00 40721
17:10
KAM /DAM
Y
6.600
STD 0.600
ABS 0.700 -
0.600 -- - _--
0.000 0600 ----
0.094 °'°° -- - -
0.240 1 0.200
0.443 j o.+. - - -
0.633 2.00 4.00 sao
0.826 X
MAX ALIQUOT
STANDARD conc(ppm)
Cal Std Lot: SD -44-3
QC Std Lot: SD -44-4
STD ABSORPTION
6
0
6.00 10,00
10.00
X
10
10
Y
--- a�
2W
7°°
�,000
12,00
Slope
0.082116484
Correlation
0.999009688
SAMPLE
I.D.
SAMP
ABS
ug PER
ALIQUOT
ALI in mL
ANALYZED
PREP
VOL in mL
ALI in mL
TAKEN
RESULTS
ug/mL
% RPD
% SPK REC
SPIKE
LEVEL
Std. B. 0.00
0.000
0.0000
10
10
10
<
0
Std. B. 1.00
0.097
0.8407
10
10
10
<
84.07%
1.0
Std. B. 2.50
0.236
2.6018
10
10
10
0.260
104.07%
2.5
Std. B. 5.00
0.454
5.3638
10
10
10
0.536
107.28%
5.0
Std. B. 7.50
0.638
7.6951
10
10
10
0.770
102.60%
7.5
Std. B. 10.00
0.810
9.8743
10
10
10
0.987
98.74%
10
LRB
0.010
-0.2616
10
10
10
<
0
LRB SPK
0.460
5.4398
10
10
10
0.544
109%
5.0
QC
0.459
5.4272
10
10
10
0.543
109%
5.0
26268-6
0.003
-0.3503
10
10
2
<
26268-6 SPK
0.324
3.7167
10
10
2
1.858
74%
5.0
26267-3
0.001
-0.3756
10
10
1
<
26267-3 SPK
0.347
4.0081
10
10
1
4.008
80%
5.0
26267-14
0.002
-0.3629
10
10
1
< 1.0 ".
26267-14 SPK
0.375
4.3629
10
10
1
4.363
87%
5.0
26268-2
0.011
-0.2489
10
10
1
<
26268-2 SPK
0.320
3.6661
10
10
1
3.666
73%
5.0
26268-6
0.001
-0.3756
10
10
1
< 1.0
26268-6 SPK
0.370
4.2995
10
10
1
4.300
86%
5.0
26267-3
0.000
0.0000
10
10
0.5
�' <2.6��,
26267-3 SPK
0.390
4.5529
10
10
0.5
9.106
91%
5.0
26268-2
0.008
-0.2869
10
10
0.5
<
26268-2 SPK
0.331
3.8054
10
10
0.5
7.611
76%
5.0
26268-2
0.009
-0.2742
10
10
0.25
". < 4,0
26268-2 SPK
0.378
4.4009
10
10
0.25
17.604
88%
5.0
Blank
0.000
0.0000
10
10
10
<
QC
0.443
5.2244
10
10
10
0.522
104%
5.0
Submitted for QA/QC- Date: 12/07/15
By: (Print)
K:AM / DAM
(sign):
Page 16 of 16 G�c��

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
Duke Energy
13339 Hagers Ferry Rd
Bldg 7405
Huntersville, NC 28078
Attention: Mary Ann Ogle
Project Name:AB GW Assessment Water - Weatherspoon
Project Number:J15120075
Lot Number:QL03073
Date Completed: 12/11/2015
Grant Wilton
Project Manager
— LAUCRATORY
Y = �Ir�Gll ACCREDITATION
TNI BUREAU­­tt�
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
The following non -paginated documents are considered part of this report: Chain of Custody Record and Sample Receipt Checklist.
Shealy Environmental Services, Inc. Page: 1 of 32
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SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Duke Energy
Lot Number: QL03073
Project Name: AB GW Assessment Water - Weatherspoon
Project Number: J15120075
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample
receiving date is documented in the header information associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the
Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy
policies. Any exceptions to the NELAC standards, the QAMP, SOPs or policies are qualified on the results page or discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page
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SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
Duke Energy
Lot Number: QL03073
Project Name: AB GW Assessment Water - Weatherspoon
Project Number: J15120075
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
2015037769
Aqueous
12/02/20151625
12/03/2015
002
2015037770
Aqueous
12/02/20151340
12/03/2015
003
2015037771
Aqueous
12/02/20151410
12/03/2015
004
2015037772
Aqueous
12/02/2015 0940
12/03/2015
005
2015037773
Aqueous
12/02/20151203
12/03/2015
006
2015037774
Aqueous
12/02/20151105
12/03/2015
007
2015037775
Aqueous
12/02/20151240
12/03/2015
008
2015037776
Aqueous
12/02/20151540
12/03/2015
009
2015037777
Aqueous
12/02/2015 0955
12/03/2015
010
2015037778
Aqueous
12/02/20151111
12/03/2015
011
2015037779
Aqueous
12/02/20151232
12/03/2015
012
2015037780
Aqueous
12/02/20151347
12/03/2015
013
2015037781
Aqueous
12/02/20151347
12/03/2015
014
2015037783
Aqueous
12/02/20151800
12/03/2015
(14 samples)
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(32 detections)
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SHEALY ENVIRONMENTAL
SERVICES, INC.
Executive Summary
Duke Energy
Lot Number: QL03073
Project Name: AB GW Assessment Water - Weatherspoon
Project Number: J15120075
Sample Sample ID
Matrix
Parameter
Method
Result Q
Units
Page
001
2015037769
Aqueous
Methane
RSK - 175
75
ug/L
6
002
2015037770
Aqueous
Alkalinity
SM 2320B-
140
mg/L
7
002
2015037770
Aqueous
Bicarbonate Alkalinity
SM 2320B-
140
mg/L
7
002
2015037770
Aqueous
Methane
RSK - 175
1900
ug/L
8
003
2015037771
Aqueous
Alkalinity
SM 2320B-
130
mg/L
9
003
2015037771
Aqueous
Bicarbonate Alkalinity
SM 2320B-
130
mg/L
9
003
2015037771
Aqueous
Methane
RSK - 175
1300
ug/L
10
004
2015037772
Aqueous
Alkalinity
SM 2320B-
210
mg/L
11
004
2015037772
Aqueous
Bicarbonate Alkalinity
SM 2320B-
210
mg/L
11
004
2015037772
Aqueous
Methane
RSK - 175
37
ug/L
12
005
2015037773
Aqueous
Alkalinity
SM 2320B-
290
mg/L
13
005
2015037773
Aqueous
Bicarbonate Alkalinity
SM 2320B-
290
mg/L
13
005
2015037773
Aqueous
Methane
RSK - 175
3300
ug/L
14
007
2015037775
Aqueous
Methane
RSK - 175
560
ug/L
18
008
2015037776
Aqueous
Alkalinity
SM 2320B-
16
mg/L
19
008
2015037776
Aqueous
Bicarbonate Alkalinity
SM 2320B-
16
mg/L
19
008
2015037776
Aqueous
Methane
RSK - 175
710
ug/L
20
009
2015037777
Aqueous
Alkalinity
SM 2320B-
120
mg/L
21
009
2015037777
Aqueous
Bicarbonate Alkalinity
SM 2320B-
120
mg/L
21
009
2015037777
Aqueous
Methane
RSK - 175
26
ug/L
22
010
2015037778
Aqueous
Alkalinity
SM 2320B-
83
mg/L
23
010
2015037778
Aqueous
Bicarbonate Alkalinity
SM 2320B-
82
mg/L
23
010
2015037778
Aqueous
Methane
RSK - 175
37
ug/L
24
011
2015037779
Aqueous
Alkalinity
SM 2320B-
120
mg/L
25
011
2015037779
Aqueous
Bicarbonate Alkalinity
SM 232013-
120
mg/L
25
011
2015037779
Aqueous
Methane
RSK - 175
170
ug/L
26
012
2015037780
Aqueous
Alkalinity
SM 2320B-
87
mg/L
27
012
2015037780
Aqueous
Bicarbonate Alkalinity
SM 2320B-
87
mg/L
27
012
2015037780
Aqueous
Methane
RSK - 175
190
ug/L
28
013
2015037781
Aqueous
Alkalinity
SM 2320B-
82
mg/L
29
013
2015037781
Aqueous
Bicarbonate Alkalinity
SM 2320B-
82
mg/L
29
013
2015037781
Aqueous
Methane
RSK - 175
170
ug/L
30
(32 detections)
Shealy Environmental Services, Inc. Page: 4 of 32
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Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-001
Description: 2015037769 Matrix: Aqueous
Date Sampled:12/02/2015 1625 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0813 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0813 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0813 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 5 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
ND
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 5 of 32
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Methane
Client: Duke Energy Laboratory ID:QL03073-001
Description: 2015037769 Matrix: Aqueous
Date Sampled:12/02/2015 1625 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 1 12/10/2015 2326 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 75 10 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-002
Description: 2015037770 Matrix: Aqueous
Date Sampled:12/02/2015 1340 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0820 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0820 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0820 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 7 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
140
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
140
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID:QL03073-002
Description: 2015037770 Matrix: Aqueous
Date Sampled:12/02/2015 1340 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 5 12/10/2015 2335 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 1900 50 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-003
Description: 2015037771 Matrix: Aqueous
Date Sampled: 12/02/2015 1410 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0831 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0831 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0831 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 9 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
130
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
130
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID:QL03073-003
Description: 2015037771 Matrix: Aqueous
Date Sampled: 12/02/2015 1410 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
3 RSK - 175 5 12/11/2015 0154 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 1300 50 ug/L 3
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-004
Description: 2015037772 Matrix: Aqueous
Date Sampled: 12/02/2015 0940 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0839 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0839 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0839 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 11 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
210
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
210
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID:QL03073-004
Description: 2015037772 Matrix: Aqueous
Date Sampled: 12/02/2015 0940 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 1 12/10/2015 2355 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 37 10 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-005
Description: 2015037773 Matrix: Aqueous
Date Sampled:12/02/2015 1203 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0848 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0848 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0848 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 13 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
290
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
290
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID:QL03073-005
Description: 2015037773 Matrix: Aqueous
Date Sampled:12/02/2015 1203 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 10 12/11/2015 0005 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 3300 100 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-006
Description: 2015037774 Matrix: Aqueous
Date Sampled:12/02/2015 1105 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0908 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0908 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0908 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 15 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
ND
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Methane
Client: Duke Energy Laboratory ID:QL03073-006
Description: 2015037774 Matrix: Aqueous
Date Sampled:12/02/2015 1105 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 1 12/11/2015 0015 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-007
Description: 2015037775 Matrix: Aqueous
Date Sampled:12/02/2015 1240 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0913 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0913 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0913 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 17 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
ND
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 17 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID:QL03073-007
Description: 2015037775 Matrix: Aqueous
Date Sampled:12/02/2015 1240 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 1 12/11/2015 0033 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 560 10 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 18 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-008
Description: 2015037776 Matrix: Aqueous
Date Sampled:12/02/2015 1540 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0931 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0931 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0931 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 19 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
16
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
16
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 19 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID:QL03073-008
Description: 2015037776 Matrix: Aqueous
Date Sampled:12/02/2015 1540 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 2 12/11/2015 0042 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 710 20 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 20 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-009
Description: 2015037777 Matrix: Aqueous
Date Sampled: 12/02/2015 0955 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0938 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0938 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0938 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 21 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
120
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
120
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 21 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID:QL03073-009
Description: 2015037777 Matrix: Aqueous
Date Sampled: 12/02/2015 0955 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 1 12/11/2015 0052 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 26 10 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 22 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-010
Description: 2015037778 Matrix: Aqueous
Date Sampled: 12/02/2015 1111 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0944 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0944 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0944 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 23 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
83
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
82
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 23 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID:QL03073-010
Description: 2015037778 Matrix: Aqueous
Date Sampled: 12/02/2015 1111 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 1 12/11/2015 0101 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 37 10 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 24 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-011
Description: 2015037779 Matrix: Aqueous
Date Sampled:12/02/2015 1232 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0951 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0951 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0951 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 25 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
120
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
120
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 25 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID:QL03073-011
Description: 2015037779 Matrix: Aqueous
Date Sampled:12/02/2015 1232 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 1 12/11/20150110 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 170 10 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 26 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-012
Description: 2015037780 Matrix: Aqueous
Date Sampled:12/02/2015 1347 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 0958 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 0958 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 0958 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 27 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
87
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
87
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 27 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID:QL03073-012
Description: 2015037780 Matrix: Aqueous
Date Sampled:12/02/2015 1347 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 1 12/11/2015 0122 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 190 10 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 28 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-013
Description: 2015037781 Matrix: Aqueous
Date Sampled:12/02/2015 1347 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 1004 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 1004 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 1004 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 29 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
82
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
82
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 29 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID:QL03073-013
Description: 2015037781 Matrix: Aqueous
Date Sampled:12/02/2015 1347 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 1 12/11/2015 0131 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 170 10 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 30 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals
Client: Duke Energy Laboratory ID:QL03073-014
Description: 2015037783 Matrix: Aqueous
Date Sampled:12/02/2015 1800 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Alkalinity) SM 2320B-2011 1 12/05/2015 1008 MJI 91408
1 (Bicarbonate ) SM 2320B-2011 1 12/05/2015 1008 MJI
1 (Carbonate Al) SM 2320B-2011 1 12/05/2015 1008 MJI
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 31 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
CAS Analytical
Parameter
Number Method
Result Q
PQL
Units Run
Alkalinity
SM 2320B-20
ND
10
mg/L 1
Bicarbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
Carbonate Alkalinity
SM 2320B-20
ND
10
mg/L 1
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Shealy Environmental Services, Inc. Page: 31 of 32
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane
Client: Duke Energy Laboratory ID:QL03073-014
Description: 2015037783 Matrix: Aqueous
Date Sampled:12/02/2015 1800 Project Name: AB GW Assessment Water -
Date Received: 12/03/2015 Project Number: J 15120075
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 RSK - 175 1 12/11/2015 0140 JJG 91910
CAS Analytical
Parameter Number Method Result Q PQL Units Run
Methane 74-82-8 RSK - 175 ND 10 ug/L 2
PQL = Practical quantitation limit B = Detected in the method blank E = Quantitation of compound exceeded the calibration range H = Out of holding time
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
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QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03073
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - MB
Sample ID: QQ91408-001 Matrix: Aqueous
Batch: 91408
Analytical Method: SM 2320B-2011
Parameter Result Q Dil PQL Units Analysis Date
Alkalinity ND 1 10 mg/L 12/05/2015 0711
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03073
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - LCS
Sample ID: QQ91408-002 Matrix: Aqueous
Batch: 91408
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 94 1 94 90-110 12/05/2015 0717
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03073
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - MS
Sample ID: QL03073-005MS Matrix: Aqueous
Batch: 91408
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 290 100 360 N 1 66 70-130 12/05/2015 0856
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03073
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Inorganic non-metals - MSD
Sample ID: QL03073-005MD Matrix: Aqueous
Batch: 91408
Analytical Method: SM 2320B-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Alkalinity 290 100 360 N 1 67 0.27 70-130 20 12/05/2015 0904
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03073
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - MB
Sample ID: QQ91910-001 Matrix: Aqueous
Batch:91910
Analytical Method: RSK - 175
Parameter Result Q Dil PQL Units Analysis Date
Methane ND 1 10 ug/L 12/10/2015 2301
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03073
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - LCS
Sample ID: QQ91910-002 Matrix: Aqueous
Batch:91910
Analytical Method: RSK - 175
Spike
Amount Result % Rec
Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date
Methane 150 150 1 100 70-130 12/10/2015 2234
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03073
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Methane - LCSD
Sample ID: QQ91910-003 Matrix: Aqueous
Batch:91910
Analytical Method: RSK - 175
Spike
Amount Result % Rec % RPD
Parameter (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Methane 150 150 1 98 2.4 70-130 30 12/10/2015 2245
PQL = Practical quantitation limit P = The RPD between two GC columns exceeds 40% N = Recovery is out of criteria
ND = Not detected at or above the PQL J = Estimated result < PQL and > MDL + = RPD is out of criteria
Where applicable, all soil sample analysis are reported on a dry weight basis unless flagged with a "W"
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: QL03073
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

Chain of Custody
and
Miscellaneous Documents
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

SHEALY ENVIRONMENTAL SERVICES, INC.
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

SHEALY ENVIRONMENTAL SERVICES, INC.
%calyfLvirannwrwaa SerwkeS, Irle-
ui wnGratNYllnbcr; MIWISC-43
PMLc 1 wf I
Rephccs Ihtc; 695
n 3fl15
Sample Receipt Checklist (SRC
Client: '* '� 1:.00lerInspeuedby�idaletik--i-�-•1 Luk# " -
MCark. Of rocelipl' ;;Ell ❑ Cluaml ❑ LIPS ❑ t'edux ❑ odw
Yes No E111
1- Were custody reap rrselrl on the cooler?
Y Iia Lj I NA 2- Tf custody semis were pment, were they intaec i+i,rd unbwlrerr?
pri :strip [D; C.1 strip IID;
-Coiner IDlCiri&al tempesat,arc upc r, TCL: rijiVDetived (corrected) tcmpcnVurc upon rcx>rr 0:
Method: ❑ Temperatureplnk Against Bottivs IF, Gun ID"� AI Gan Corraection Factor, 0- 0 °C
Method �f coolant-, [�]'Wet Ice ❑ clue lce ❑ Dry Ice 2 Nme
Yes ❑ ',IL1 MA
I
3. if temperature of any 0001er excwded fi-WC, W33 PT -0j= MaLnaLFcT notiticxl? YM
notilledbySRC, phone,note(circlecncc),Other
(Far wolers rece'iwd via cornmeroial ecsuner, Phis are to be notified
ixrniediate:ly.)
Yes ❑ LNfi ❑ NA
4- L, the commercial courier's pwekin g slip attdrhed To this form?
Yes V1 Nr,
j S- Were pTyper -custody Wocc&rcs rclin uisWe -e ived) followed?
Yes ❑No NA
Ss Were sure, les relifl uishcd by Aim[ to IY ann reial courier'?
k as No ❑
6- Were sam le IDs listed on the CCC?
Yee 0❑
7. W sun le IDF: lis:ted anall samplu cmataimm?
Yes o
8. Was collection date & time lisW on the COC?
Yes PO ❑
+9- Woo ei,llectiu» date & time Iistcd on all smple conts xbers?
'acs Nu
10. Did all container label information 11D circm tune 2 13e with the C:UC=?
yrs Pio
l 1. Were tests to br petiarnied luted on the COC?
Yes EZ No El
1 12. Did all samples arrive in the pMer Containers for each Imt?
Yes No ❑
l3. Did all containers arrive in glood rmditi,on unbroken, Iids un, UtCF 7
Yes No
14, Wam ark wale same pie vrllumc available?
Yea 1.11 N ❑
les received withi ,: the hcalrlin,g tine or 4$ ho fs, Abch+e�r
15, cm ail s o
comes Fimt`F
Yes No
16. Were any semen 6s containers missing?
Y'es ❑ No a 1
17, sanyles not Listed on COC?
Yes No NA
18. Were bubbles�" ems -eine" ('pi' air Grmun in di3triet In all ' ' v t l s'-'
Yeas No ❑ NA
19. Were all aletalAAGM EMfnutrient sS21cs received ata i3 of <??
Yrs Zen ❑ NA
les rived ata pH1"
24. Wcrc Bill c Ora ailiditlr sulfide sar ece
Yes ❑ 140 ❑ NA
21. Wcrc all appli4tAble N4H3+TK_N/cyaniddphc of ( D-2m;'L) samples frac of
ideal chlorine?
Yes Ej No Lj NA
2:2, Ware collucticrn temperatures dcacumcnted on the C+L71= far NC..samples?
Yes Noo 1ilA
23. Were client rerrmarks!rNuests ri.c. rugmted dilutiow, MS/MSD designatiew,
etc...) correctly traav+:ribed fxm the CCW into the comment sectiarm firs >v[MS7
{ No
24- Was the quote neambcr u taken from the conteki=1001'
Sample l' "Servatiuu (Rust becornpleted for any Hample(H) incorrectlypreserv6d or withh dspaee.)
.Sample(s) Nvcrc rccoiwti incmectly+ pressed and were adjustad
accordingly in sample rec6%qng with Hz$04 HNO3, HCl, NaOH)using SR #
Sample(sl
werc rectived with bubbles _-6,nm in diamesei.
sample(s))
wcru rcceived vrith TRC r0.2 ingiL (if x'21 is No)
SC T)-Hnlcing Watm-Prujes;t ° ple(s) pH vcrifrrxi tc>, he >� 2 by Date -
Sam 1 s were not received ata pH of <2 emd wov 4ed vgVM accordingly us SRO
Sam lc laboln 3 lied
Verified by,
f p1r1MelitS;
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com

aceAnaiXical
www.pacelabs.com
December 08, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
Padg"WfY3 Suite 100
Huntersville, INC 28078
[phone]
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 03, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Program Manager, Duke Energy
Rodney Wilke, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 1 of 26

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CERTIFICATIONS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
Padg"WM3 44e.Suite 100
Huntersville, NC 28078
[phone]
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Nebraska Certification: NE -OS -28-14
Alabama Certification #: 41320
Nevada Certification: FL NELAC Reciprocity
Connecticut Certification M PH -0216
New Hampshire Certification M 2958
Delaware Certification: FL NELAC Reciprocity
New York Certification #: 11608
Florida Certification #: E83079
North Carolina Environmental Certificate #: 667
Georgia Certification #: 955
North Carolina Certification #: 12710
Guam Certification: FL NELAC Reciprocity
North Dakota Certification #: R-216
Hawaii Certification: FL NELAC Reciprocity
Oklahoma Certification #: D9947
Illinois Certification #: 200068
Pennsylvania Certification #: 68-00547
Indiana Certification: FL NELAC Reciprocity
Puerto Rico Certification #: FLO1264
Kansas Certification #: E-10383
South Carolina Certification: #96042001
Kentucky Certification #: 90050
Tennessee Certification #: TN02974
Louisiana Certification #: FL NELAC Reciprocity
Texas Certification: FL NELAC Reciprocity
Louisiana Environmental Certificate M 05007
US Virgin Islands Certification: FL NELAC Reciprocity
Maryland Certification: #346
Virginia Environmental Certification #: 460165
Michigan Certification #: 9911
West Virginia Certification #: 9962C
Mississippi Certification: FL NELAC Reciprocity
Wisconsin Certification #: 399079670
Missouri Certification #: 236
Wyoming (EPA Region 8): FL NELAC Reciprocity
Montana Certification #: Cert 0074
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 2 of 26

aceAnaiXical
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SAMPLE SUMMARY
Project: J15120075
Pace Project No.: 92278323
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92278323001
2015037769
Water
12/02/1516:25
12/03/1514:25
92278323002
2015037770
Water
12/02/1513:40
12/03/1514:25
92278323003
2015037771
Water
12/02/1514:10
12/03/1514:25
92278323004
2015037772
Water
12/02/15 09:40
12/03/15 14:25
92278323005
2015037773
Water
12/02/1512:03
12/03/1514:25
92278323006
2015037774
Water
12/02/1511:05
12/03/1514:25
92278323007
2015037775
Water
12/02/1512:40
12/03/1514:25
92278323008
2015037776
Water
12/02/1515:40
12/03/1514:25
92278323009
2015037777
Water
12/02/15 09:55
12/03/15 14:25
92278323010
2015037778
Water
12/02/1511:11
12/03/1514:25
92278323011
2015037779
Water
12/02/1512:32
12/03/1514:25
92278323012
2015037780
Water
12/02/1513:49
12/03/1514:25
92278323013
2015037781
Water
12/02/1513:47
12/03/1514:25
92278323014
2015037783
Water
12/02/1518:00
12/03/1514:25
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
P a 89 OP1 b r6f Y 3W e. Suite 100
Huntersville, NC 28078
[phone]
Page 3 of 26

aceAnaiXical
www.pacelabs.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, Inc.
Pa89QP1l1ir6fY3'We. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
J15120075
92278323
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92278323001
2015037769
EPA 218.7
TK1
1
PASI-0
92278323002
2015037770
EPA 218.7
TK1
1
PASI-0
92278323003
2015037771
EPA 218.7
TK1
1
PASI-0
92278323004
2015037772
EPA 218.7
TK1
1
PASI-0
92278323005
2015037773
EPA 218.7
TK1
1
PASI-0
92278323006
2015037774
EPA 218.7
TK1
1
PASI-0
92278323007
2015037775
EPA 218.7
TK1
1
PASI-0
92278323008
2015037776
EPA 218.7
TK1
1
PASI-0
92278323009
2015037777
EPA 218.7
TK1
1
PASI-0
92278323010
2015037778
EPA 218.7
TK1
1
PASI-0
92278323011
2015037779
EPA 218.7
TK1
1
PASI-0
92278323012
2015037780
EPA 218.7
TK1
1
PASI-0
92278323013
2015037781
EPA 218.7
TK1
1
PASI-0
92278323014
2015037783
EPA 218.7
TK1
1
PASI-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 4 of 26

aceAnaiXical
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Project: J15120075
Pace Project No.: 92278323
Lab Sample ID
Method
Client Sample ID
Parameters
92278323001
2015037769
EPA 218.7
Chromium, Hexavalent
92278323002
2015037770
EPA 218.7
Chromium, Hexavalent
92278323006
2015037774
EPA 218.7
Chromium, Hexavalent
92278323007
2015037775
EPA 218.7
Chromium, Hexavalent
92278323008
2015037776
EPA 218.7
Chromium, Hexavalent
SUMMARY OF DETECTION
Result
UnitE
0.30
0.063
ug/L
0.44
ug/L
0.056
ug/L
0.049
ug/L
0.047
ug/L
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
PadgOM eYdWe. Suite 100
Huntersville, NC 28078
[phone]
Report Limit Analyzed Qualifiers
0.030
12/07/15 17:41
0.30
12/08/15 08:52
0.030
12/07/15 20:17
0.030
12/07/15 20:30
0.030
12/07/15 20:43
Page 5 of 26

aceAnaiXical
www.pacelabs.com
PROJECT NARRATIVE
Project: J15120075
Pace Project No.: 92278323
Method: EPA 218.7
Description: Hexavalent Chromium by IC
Client: Duke Energy
Date: December 08, 2015
Pace Analytical Services, Inc.
PadgOM leYdWe. Suite 100
Huntersville, NC 28078
[phone]
General Information:
14 samples were analyzed for EPA 218.7. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 6 of 26

aceAnaiXical
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ANALYTICAL RESULTS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
P a 89 OP1 W r6f Y 3W e. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037769 Lab ID: 92278323001 Collected: 12/02/15 16:25 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent 0.063 ug/L 0.030 1 12/07/15 17:41 18540-29-9
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 7 of 26

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Pace Analytical Services, Inc.
Pa890PA leYdWe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15120075
Pace Project No.: 92278323
Sample: 2015037770 Lab ID: 92278323002 Collected: 12/02/15 13:40 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent 0.44 ug/L 0.30 10 12/08/15 08:52 18540-29-9
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/08/2015 04:00 PM without the written consent of Pace Analytical Services, Inc.. Page 8 of 26

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
Pa890P* leY3'We. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037771 Lab ID: 92278323003 Collected: 12/02/15 14:10 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/07/15 18:07 18540-29-9
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
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Page 9 of 26

aceAnaiXical
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ANALYTICAL RESULTS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
PadgOM leYdWe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037772 Lab ID: 92278323004 Collected: 12/02/15 09:40 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/07/15 18:20 18540-29-9
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 10 of 26

aceAnaiXical
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ANALYTICAL RESULTS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
Pa890PA leYdWe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037773 Lab ID: 92278323005 Collected: 12/02/15 12:03 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/07/15 20:04 18540-29-9
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 11 of 26

aceAnaiXical
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ANALYTICAL RESULTS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
P a 89 OP1 9 r6f Y 3W e. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037774 Lab ID: 92278323006 Collected: 12/02/15 11:05 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent 0.056 ug/L 0.030 1 12/07/15 20:17 18540-29-9
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 12 of 26

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ANALYTICAL RESULTS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
Padg�rWY3 Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037775 Lab ID: 92278323007 Collected: 12/02/15 12:40 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent 0.049 ug/L 0.030 1 12/07/15 20:30 18540-29-9
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
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ANALYTICAL RESULTS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
Padg"IirfY3'We. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037776 Lab ID: 92278323008 Collected: 12/02/15 15:40 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent 0.047 ug/L 0.030 1 12/07/15 20:43 18540-29-9
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
Padg"WM3 44e.Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037777 Lab ID: 92278323009 Collected: 12/02/15 09:55 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/07/15 20:56 18540-29-9
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 15 of 26

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ANALYTICAL RESULTS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
Padg"WM3 44e.Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037778 Lab ID: 92278323010 Collected: 12/02/15 11:11 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/07/15 21:09 18540-29-9
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 16 of 26

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www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
Pa89�4ir6fY3 Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037779 Lab ID: 92278323011 Collected: 12/02/15 12:32 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/07/15 21:22 18540-29-9
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 17 of 26

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ANALYTICAL RESULTS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
Padg"WM3 44e.Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037780 Lab ID: 92278323012 Collected: 12/02/15 13:49 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/07/15 21:35 18540-29-9
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 18 of 26

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ANALYTICAL RESULTS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
Pa89�r6fY3 Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037781 Lab ID: 92278323013 Collected: 12/02/15 13:47 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/07/15 21:48 18540-29-9
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 19 of 26

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120075
Pace Project No.: 92278323
Pace Analytical Services, Inc.
Padg"WM3 44e.Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015037783 Lab ID: 92278323014 Collected: 12/02/15 18:00 Received: 12/03/15 14:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Hexavalent Chromium by IC Analytical Method: EPA 218.7
Chromium, Hexavalent ND ug/L 0.030 1 12/07/15 22:27 18540-29-9 M1
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 20 of 26

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
Padg"WM3 44e.Suite 100
Huntersville, NC 28078
[phone]
Project: J15120075
Pace Project No.: 92278323
QC Batch: WETA/52762
Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7
Analysis Description: Chromium,
Hexavalent IC
Associated Lab Samples: 92278323001, 92278323002,
92278323003, 92278323004
METHOD BLANK: 1412102
Matrix: Water
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chromium, Hexavalent ug/L
ND 0.030
12/07/15 12:26
LABORATORY CONTROL SAMPLE: 1412103
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chromium, Hexavalent ug/L
.075 0.077
103 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1412104 1412105
MS MSD
92278325021
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L 2.7
.5 .5 2.9
3.0 39 55 85-115 3 20 M6
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1412106 1412107
MS MSD
92278329009 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chromium, Hexavalent ug/L ND .075 .075 0.084 0.086 112 115 85-115 3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/08/2015 04:00 PM without the written consent of Pace Analytical Services, Inc..
Page 21 of 26

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, Inc.
Padg"WM3 44e.Suite 100
Huntersville, NC 28078
[phone]
Project: J15120075
Pace Project No.: 92278323
QC Batch: WETA/52785
Analysis Method: EPA 218.7
QC Batch Method: EPA 218.7
Analysis Description: Chromium,
Hexavalent IC
Associated Lab Samples: 92278323005, 92278323006,
92278323007, 92278323008, 92278323009, 92278323010, 92278323011,
92278323012,92278323013,92278323014
METHOD BLANK: 1412718
Matrix: Water
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Chromium, Hexavalent ug/L
ND 0.030
12/07/15 18:59
LABORATORY CONTROL SAMPLE: 1412719
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chromium, Hexavalent ug/L
.075 0.078
104 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1412720 1412721
MS MSD
92278325003
Spike Spike MS
MSD MS MSD
% Rec
Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits
RPD RPD Qual
Chromium, Hexavalent ug/L 0.40
.38 .38 0.66
0.57 70 45
85-115
16 20 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1412722 1412723
MS MSD
92278323014
Spike Spike MS
MSD MS MSD
% Rec
Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits
RPD RPD Qual
Chromium, Hexavalent ug/L ND
.075 .075 0.087
0.086 116 115
85-115
1 20 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/08/2015 04:00 PM without the written consent of Pace Analytical Services, Inc..
Page 22 of 26

aceAnaiXical
www.pacelabs.com
QUALIFIERS
Project: J15120075
Pace Project No.: 92278323
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
Pace Analytical Services, Inc.
Pa89�r6fY3 Suite 100
Huntersville, NC 28078
[phone]
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/08/2015 04:00 PM without the written consent of Pace Analytical Services, Inc.. Page 23 of 26

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15120075
Pace Project No.: 92278323
Lab ID Sample ID QC Batch Method QC Batch
92278323001
2015037769
EPA 218.7
WETA/52762
92278323002
2015037770
EPA 218.7
WETA/52762
92278323003
2015037771
EPA 218.7
WETA/52762
92278323004
2015037772
EPA 218.7
WETA/52762
92278323005
2015037773
EPA 218.7
WETA/52785
92278323006
2015037774
EPA 218.7
WETA/52785
92278323007
2015037775
EPA 218.7
WETA/52785
92278323008
2015037776
EPA 218.7
WETA/52785
92278323009
2015037777
EPA 218.7
WETA/52785
92278323010
2015037778
EPA 218.7
WETA/52785
92278323011
2015037779
EPA 218.7
WETA/52785
92278323012
2015037780
EPA 218.7
WETA/52785
92278323013
2015037781
EPA 218.7
WETA/52785
92278323014
2015037783
EPA 218.7
WETA/52785
Date: 12/08/2015 04:00 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Pace Analytical Services, Inc.
Padg"lirfY3'We. Suite 100
Huntersville, NC 28078
[phone]
Analytical Method
Analytical
Batch
Page 24 of 26

Document Name: Document Revised: November 11, 2111b
Analytical- Sample Condition Upon Receipt SOUR *'
Pae 1 of 2
Document Number: Issuing Authoritpge 132 of 13
F-CHR-CS-003-rev.16.1 Pace Huntersville Qualit ©ffice
^,..lieflt Name. 0(,A .nc j * Page 2 of2Is for Internal Use Only
;ourier: ❑ Fed ESC] UP❑ USP❑ Clier��n.
mmerc!❑ ac Other O tionai
;ustody Seal on Cooler/Box Present: El Seals intact: El yes E] no Due Date: no Proj. Name:
)lacking Material: ❑ Bubble Wrap ❑ Bubble Bags'[5 None M Other
rhermometer Used: IR Gun T6/ Type of Ice;et Blue None samples on ice, cooling process has begun
temp Correction Factor No Correction
Date and Initials of person exa,Unming
corrected Cooler Temp.:� �d •C Biological Tissue is Frozen: Yes No 6/contents: A{'`'�' J
remD should be above freezing to 6°C Comments:
;hain of Custody Present:
Cafes ONO
❑N/A
1.
;hain of Custody Filled Out:es
11 No
❑NIA
2.
;hain of Custody Relinquished:
w s ❑No
❑N1A
3.
Sampler Name & Signature on COC:
De, -,"'E] No
❑NIA
4.
Samples Arrived within Hold Time:
es No
❑NIA
5.
Short Hold Time Analysis (<72hr):
Yes ONO
❑NIA
6.
Rush Turn Around Time Requested:
❑lyes 1110
El NIA
7.
Sufficient Volume:
❑Yes o
QNIA
$. Al(i �� } r
-orrect Containers Used:
D est❑Nv
0N1A
9.
-Pace Containers Used:
Cees ONO
❑N/A
Containers Intact:
es ONO
L1 N/A
12,
Filtered volume received for Dissolved tests
QYes No
Q rA
11.
Sample Labels match COC:
❑ es ON
El NIA
12.
-Includes dateftime/ID/Analysis Matrix:
w
All containers needing preservation have been checked.
E]Yes ONO
D /A
13.
All containers needing preservation are found to be in
❑Yes ONO
❑N1A
compliance with EPA recommendation.
exceptions: VOA, coliform, TGC, GBG, WI -DRO (water)
❑Yes
o
Samples checked for dechlorination:
❑Yes
❑No
NIA
14.
Headspace in VOA Vials ( >6mm):
Dyes
❑No
❑tA
15.
Trip Blank Present:
Dyes
ONO
SIM
16,
Trip Blank Custody Seals Present
Dyes
❑No
❑
Pace Trip Blank Lot # (if purchased):
Client Notification/ Resolution:
Field Data Required? Y 1 N
Person Contacted:
Date/Time:
Comments/ Resolution:
SCURF Review: "o Date: Li�`11,ZJ
SRF Review: Date: y
Note: Whenever there is a discrepancy affecting North Carolina compliance
samples, a copy of this form will be sent to the North Carolina DEHNR
Certification Office (i,e out of hold, incorrect preservative, out of temp,
incorrect containers)
WOR:92278323
11111111111111111111111
9221832-3
Page 25 of 26

0-1
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vt n [yrs
Toiar� lig `1

Duke Energy Analytical Laboratory
DUKE Analytical Laboratory Page 1of62
ENERGY
Order Number:
Project Name:
Customer Name(s):
Customer Address:
Lab Contact:
Report Authorized By:
(Signature)
Program Comments
13339 Hagers Ferry Road
Huntersville, NC 28078-7929
McGuire Nuclear Complex - MG03A2
Phone: [phone] Fax: [phone]
Order Summary Report
J15120373
WEATHERSPOON - AB GW ASSESSMENT SOIL
Mark Taylor, Tim Hunsucker, Fred Holt, Brandon Russo, Kathy Webb, John Toe
Rodney G Wike Phone: [phone]
Date:
Please contact the Program Manager (Rodney G Wike) with any questions regarding this report.
Data Flags & Calculations:
1/15/2016
Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality
system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results)
under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data
included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the
subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have
been qualified by Duke Energy to perform these analyses except where noted.
Data Package:
This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of
the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except
in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The
order of individual sections within this report is as follows:
Job Summary Report, Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis,
Analytical Laboratory QC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports &
Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC)
Certification:
The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina
(DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of
specific methods.

Sample ID's & Descriptions:
Collection
Sample ID Plant/Station Date and Time
2015039114
2015039115
2015039116
2015039117
2015039118
2015039119
2015039120
2015039121
8 Total Samples
Duke Energy Analytical Laboratory
Page 1 of 62
Collected By Sample Description
Weatherspoon
14 -Dec -15 1:25 PM
Synterra
DG -49 (29-30)
Weatherspoon
14 -Dec -15 3:25 PM
Synterra
DG -44 (53-55)
Weatherspoon
14 -Dec -15 9:45 AM
Synterra
DG -04-05 (8-12)
Weatherspoon
14 -Dec -15 9:45 AM
Synterra
DG -04-05 dup (8-12)
Weatherspoon
14 -Dec -15 10:20 AM
Synterra
DG -04-05 (24-28)
Weatherspoon
14 -Dec -15 2:45 PM
Synterra
DG -44 (38-42) DUP
Weatherspoon
14 -Dec -15 2:45 PM
Synterra
DG -44 (38-42)
Weatherspoon
14 -Dec -15 11:10 AM
Synterra
DG -55 (13-15)

Duke Energy Analytical Laboratory
Page 1 of 62
Technical Validation Review
Checklist:
COC and .pdf report are in agreement with sample totals 0 Yes No
and analyses (compliance programs and procedures).
All Results are less than the laboratory reporting limits. ❑ Yes 0 No
All laboratory QA/QC requirements are acceptable. 0 Yes ❑ No
Report Sections Included:
CI Job Summary Report
❑� Sample Identification
Technical Validation of Data Package
❑� Analytical Laboratory Certificate of Analysis
❑ Analytical Laboratory QC Report
❑d Sub -contracted Laboratory Results
❑ Customer Specific Data Sheets, Reports, & Documentation
❑ Customer Database Entries
❑� Chain of Custody
❑� Electronic Data Deliverable (EDD) Sent Separately
Reviewed By: DBA Account Date: 1/15/2016

Duke Energy Analytical Laboratory
Certificate of Laboratory Analysis Page 1 of 62
This report shall not be reproduced, except in full.
Order # J15120373
Site: DG -49 (29-30)
Collection Date: 14 -Dec -15 1:25 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015039114
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Duke Energy Analytical Laboratory
Certificate of Laboratory Analysis Page 1 of 62
This report shall not be reproduced, except in full.
Order # J15120373
Site: DG -44 (53-55)
Collection Date: 14 -Dec -15 3:25 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015039115
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Duke Energy Analytical Laboratory
Certificate of Laboratory Analysis Page 1 of 62
This report shall not be reproduced, except in full.
Order # J15120373
Site: DG -04-05 (8-12)
Collection Date: 14 -Dec -15 9:45 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015039116
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Duke Energy Analytical Laboratory
Certificate of Laboratory Analysis Page 1 of 62
This report shall not be reproduced, except in full.
Order # J15120373
Site: DG -04-05 dup (8-12)
Collection Date: 14 -Dec -15 9:45 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015039117
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Duke Energy Analytical Laboratory
Certificate of Laboratory Analysis Page 1 of 62
This report shall not be reproduced, except in full.
Order # J15120373
Site: DG -04-05 (24-28)
Collection Date: 14 -Dec -15 10:20 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015039118
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Duke Energy Analytical Laboratory
Certificate of Laboratory Analysis Page 1 of 62
This report shall not be reproduced, except in full.
Order # J15120373
Site: DG -44 (38-42) DUP
Collection Date: 14 -Dec -15 2:45 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015039119
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Duke Energy Analytical Laboratory
Certificate of Laboratory Analysis Page 1 of 62
This report shall not be reproduced, except in full.
Order # J15120373
Site: DG -44 (38-42)
Collection Date: 14 -Dec -15 2:45 PM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015039120
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

Duke Energy Analytical Laboratory
Certificate of Laboratory Analysis Page 1 of 62
This report shall not be reproduced, except in full.
Order # J15120373
Site: DG -55 (13-15)
Collection Date: 14 -Dec -15 11:10 AM
Analyte Result Units Qualifiers RDL DF
PERCENT SOLIDS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
DIONEX ANIONS BY VENDOR - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
METALS ANALYSIS BY VENDOR LAB - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
PH IN SOIL - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
TOTAL ORGANIC CARBON IN SOILS - (Analysis Performed by Pace Laboratories)
Vendor Parameter Complete
Sample #: 2015039121
Matrix: SOIL
Method Analysis Date/Time Analyst
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE
Vendor Method V_PACE

aceAnalyical
www.pacelabs.com
December 23, 2015
Program Manager
Duke Energy
13339 Hagers Ferry Road
Bldg. 7405 MG30A2
Huntersville, NC 28078
RE: Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
%py%roe. Suite 100
Huntersville, INC 28078
[phone]
Dear Program Manager:
Enclosed are the analytical results for sample(s) received by the laboratory on December 15, 2015.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Kevin Herring
[e-mail]
HORIZON Database Administrator
Enclosures
cc: Sean DeNeale
Marge Galvin -Karr
Kimberly Hawkins
Tim Hunsucker
Program Manager, Duke Energy
Q p«FO
Maureen Migliorini
Barbara Morson
Mary Ann Ogle, Duke Energy
Rodney Wilke, Duke Energy
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
e7 r7'7 without the written consent of Pace Analytical Services, Inc.. Page 1 of 51

lacmnalyfica(
www.pacelabs.com
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH -0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
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Green Bay Certification IDs
1241 Bellevue Street, Green Bay, WI 54302
Florida/NELAP Certification #: E87948
Illinois Certification #: 200050
Kentucky Certification #: 82
Louisiana Certification #: 04168
Minnesota Certification #: 055-999-334
Virginia VELAP ID: 460263
Duke Energy AnalyticalALaRrIaioryervices, Inc.
902 .g,nlcsfde. Suite 100
Huntersville, NC 28078
[phone]
CERTIFICATIONS
Nebraska Certification: NE -OS -28-14
Nevada Certification: FL NELAC Reciprocity
New Hampshire Certification #: 2958
New York Certification #: 11608
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North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification M TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
North Dakota Certification #: R-150
South Carolina Certification #: 83006001
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Virginia VELAP ID: 460263
Virginia VELAP Certification ID: 460263
Wisconsin Certification #: 405132750
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 2 of 51

aceAnaiXical
www.pacelabs.com
SAMPLE SUMMARY
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92279910001
2015039114
Solid
12/14/1513:25
12/15/1514:07
92279910002
2015039115
Solid
12/14/1515:25
12/15/1514:07
92279910003
2015039116
Solid
12/14/15 09:45
12/15/15 14:07
92279910004
2015039117
Solid
12/14/15 09:45
12/15/15 14:07
92279910005
2015039118
Solid
12/14/1510:20
12/15/1514:07
92279910006
2015039119
Solid
12/14/1514:45
12/15/1514:07
92279910007
2015039120
Solid
12/14/1514:45
12/15/1514:07
92279910008
2015039121
Solid
12/14/1511:10
12/15/1514:07
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 3 of 51

aceAnaiXical
www.pacelabs.com
SAMPLE ANALYTE COUNT
Duke Energy AnalyticalALaRriacioryervices, Inc.
%giy%roe. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
J15120373 WEATHERSPOON
92279910
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92279910001
2015039114
EPA 6010
TAP
16
PASI-0
EPA 6020
CKJ, DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
KEK
2
PASI-O
EPA 9056
KEK
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92279910002
2015039115
EPA 6010
TAP
16
PASI-0
EPA 6020
CKJ, DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
KEK
2
PASI-O
EPA 9056
KEK
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92279910003
2015039116
EPA 6010
TAP
16
PASI-0
EPA 6020
CKJ, DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
KEK
2
PASI-O
EPA 9056
KEK
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92279910004
2015039117
EPA 6010
TAP
16
PASI-0
EPA 6020
CKJ, DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
KEK
2
PASI-O
EPA 9056
KEK
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92279910005
2015039118
EPA 6010
TAP
16
PASI-0
EPA 6020
CKJ, DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 4 of 51

aceAnaiXical
www.pacelabs.com
SAMPLE ANALYTE COUNT
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
Lab ID
Sample ID
Method
Analysts
Analytes
Reported
Laboratory
EPA 9056
KEK
2
PASI-O
EPA 9056
KEK
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92279910006
2015039119
EPA 6010
TAP
16
PASI-0
EPA 6020
CKJ, DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
KEK
2
PASI-O
EPA 9056
KEK
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92279910007
2015039120
EPA 6010
TAP
16
PASI-0
EPA 6020
CKJ, DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
KEK
2
PASI-O
EPA 9056
KEK
1
PASI-O
EPA 9060
TJJ
6
PASI-G
92279910008
2015039121
EPA 6010
TAP
16
PASI-0
EPA 6020
CKJ, DRS
8
PASI-O
EPA 7471
CKJ
1
PASI-O
ASTM D2974-87
MLO
1
PASI-O
EPA 9045
KAM
1
PASI-O
EPA 9056
KEK
2
PASI-O
EPA 9056
KEK
1
PASI-O
EPA 9060
TJJ
6
PASI-G
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 5 of 51

aceAnaiXical
www.pacelabs.com
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Lab Sample ID Client Sample ID
Method Parameters
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92279910001
2015039114
EPA 6010
Aluminum
18700
mg/kg
5.8
12/21/15 02:09
EPA 6010
Barium
15.7
mg/kg
0.58
12/21/15 02:09
EPA 6010
Beryllium
0.10
mg/kg
0.058
12/21/15 02:09
EPA 6010
Boron
5.4
mg/kg
2.9
12/21/15 02:09
EPA 6010
Calcium
330
mg/kg
28.8
12/21/15 02:09
EPA 6010
Chromium
22.8
mg/kg
0.29
12/21/15 02:09
EPA 6010
Copper
5.8
mg/kg
0.29
12/21/15 02:09
EPA 6010
Iron
9960
mg/kg
2.3
12/21/15 02:09
EPA 6010
Magnesium
259
mg/kg
28.8
12/21/15 02:09
EPA 6010
Manganese
11.8
mg/kg
0.29
12/21/15 02:09
EPA 6010
Molybdenum
1.9
mg/kg
0.58
12/21/15 02:09
EPA 6010
Nickel
25.5
mg/kg
0.29
12/21/15 02:09
EPA 6010
Potassium
210
mg/kg
57.5
12/21/15 02:09
EPA 6010
Strontium
9.5
mg/kg
0.58
12/21/15 02:09
EPA 6010
Zinc
8.0
mg/kg
1.2
12/21/15 02:09
EPA 6020
Arsenic
2.4
mg/kg
1.2
12/20/15 21:13
EPA 6020
Cobalt
0.84J
mg/kg
1.2
12/20/15 21:13
EPA 6020
Lead
5.4
mg/kg
1.2
12/21/1510:53
EPA 6020
Vanadium
28.2
mg/kg
1.2
12/21/1510:53
EPA 7471
Mercury
0.030
mg/kg
0.0092
12/21/1517:00
ASTM D2974-87
Percent Moisture
14.6
%
0.10
12/22/15 07:36
EPA 9045
pH at 25 Degrees C
6.0
Std. Units
0.10
12/17/15 08:45
EPA 9060
Total Organic Carbon
2070
mg/kg
706
12/18/15 07:47
EPA 9060
Total Organic Carbon
2010
mg/kg
705
12/18/15 07:52
EPA 9060
Total Organic Carbon
2230
mg/kg
709
12/18/15 07:58
EPA 9060
Total Organic Carbon
2100
mg/kg
705
12/18/15 08:04
EPA 9060
Mean Total Organic Carbon
2100
mg/kg
706
12/18/15 07:47
EPA 9060
RSD%
4.5
%
12/18/15 07:47
92279910002
2015039115
EPA 6010
Aluminum
741
mg/kg
6.1
12/21/15 02:13
EPA 6010
Barium
22.4
mg/kg
0.61
12/21/15 02:13
EPA 6010
Beryllium
0.23
mg/kg
0.061
12/21/15 02:13
EPA 6010
Boron
3.7
mg/kg
3.1
12/21/15 02:13
EPA 6010
Calcium
173000
mg/kg
154
12/21/15 03:12
EPA 6010
Chromium
4.8
mg/kg
0.31
12/21/15 02:13
EPA 6010
Copper
0.49
mg/kg
0.31
12/21/15 02:13
EPA 6010
Iron
2400
mg/kg
2.5
12/21/15 02:13
EPA 6010
Magnesium
490
mg/kg
30.7
12/21/15 02:13
EPA 6010
Manganese
55.7
mg/kg
0.31
12/21/15 02:13
EPA 6010
Molybdenum
1.2
mg/kg
0.61
12/21/15 02:13
EPA 6010
Nickel
0.68
mg/kg
0.31
12/21/15 02:13
EPA 6010
Potassium
94.4
mg/kg
61.4
12/21/15 02:13
EPA 6010
Sodium
1230
mg/kg
61.4
12/21/15 02:13
EPA 6010
Strontium
800
mg/kg
3.1
12/21/15 03:12
EPA 6010
Zinc
2.6
mg/kg
1.2
12/21/15 02:13
EPA 6020
Arsenic
7.1
mg/kg
1.2
12/20/15 21:16
EPA 6020
Cobalt
0.70J
mg/kg
1.2
12/20/15 21:16
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
H6
D4
D4
Qualifiers
Page 6 of 51

aceAnaiXical
www.pacelabs.com
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Lab Sample ID Client Sample ID
Method Parameters
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92279910002
2015039115
EPA 6020
Vanadium
7.5
mg/kg
1.2
12/21/1510:55
ASTM D2974-87
Percent Moisture
18.5
%
0.10
12/22/15 07:36
EPA 9045
pH at 25 Degrees C
8.1
Std. Units
0.10
12/17/15 08:45
EPA 9060
Total Organic Carbon
2300
mg/kg
741
12/18/15 08:56
EPA 9060
Total Organic Carbon
1870
mg/kg
737
12/18/15 09:04
EPA 9060
Total Organic Carbon
1970
mg/kg
743
12/18/15 09:13
EPA 9060
Total Organic Carbon
2220
mg/kg
732
12/18/15 09:25
EPA 9060
Mean Total Organic Carbon
2090
mg/kg
738
12/18/15 08:56
EPA 9060
RSD%
9.7
%
12/18/15 08:56
92279910003
2015039116
EPA 6010
Aluminum
11600
mg/kg
6.0
12/21/15 02:18
EPA 6010
Barium
11.1
mg/kg
0.60
12/21/15 02:18
EPA 6010
Beryllium
0.078
mg/kg
0.060
12/21/15 02:18
EPA 6010
Boron
1.91
mg/kg
3.0
12/21/15 02:18
EPA 6010
Calcium
118
mg/kg
30.0
12/21/15 02:18
EPA 6010
Chromium
8.5
mg/kg
0.30
12/21/15 02:18
EPA 6010
Copper
2.7
mg/kg
0.30
12/21/15 02:18
EPA 6010
Iron
3570
mg/kg
2.4
12/21/15 02:18
EPA 6010
Magnesium
137
mg/kg
30.0
12/21/15 02:18
EPA 6010
Manganese
4.3
mg/kg
0.30
12/21/15 02:18
EPA 6010
Molybdenum
0.36J
mg/kg
0.60
12/21/15 02:18
EPA 6010
Nickel
1.9
mg/kg
0.30
12/21/15 02:18
EPA 6010
Potassium
90.7
mg/kg
59.9
12/21/15 02:18
EPA 6010
Strontium
2.2
mg/kg
0.60
12/21/15 02:18
EPA 6010
Zinc
5.3
mg/kg
1.2
12/21/15 02:18
EPA 6020
Lead
8.7
mg/kg
1.1
12/21/1510:57
EPA 6020
Selenium
0.65J
mg/kg
1.1
12/20/15 21:18
EPA 6020
Vanadium
17.3
mg/kg
1.1
12/21/1510:57
EPA 7471
Mercury
0.11
mg/kg
0.0095
12/21/1517:05
ASTM D2974-87
Percent Moisture
15.9
%
0.10
12/22/15 07:36
EPA 9045
pH at 25 Degrees C
4.6
Std. Units
0.10
12/17/15 08:45
EPA 9060
Total Organic Carbon
841
mg/kg
709
12/18/15 09:37
EPA 9060
Total Organic Carbon
934
mg/kg
713
12/18/15 09:56
EPA 9060
Total Organic Carbon
922
mg/kg
711
12/18/15 10:28
EPA 9060
Total Organic Carbon
942
mg/kg
710
12/18/15 10:33
EPA 9060
Mean Total Organic Carbon
910
mg/kg
711
12/18/15 09:37
EPA 9060
RSD%
5.1
%
12/18/15 09:37
92279910004
2015039117
EPA 6010
Aluminum
12800
mg/kg
6.0
12/21/15 02:36
EPA 6010
Barium
11.2
mg/kg
0.60
12/21/15 02:36
EPA 6010
Beryllium
0.091
mg/kg
0.060
12/21/15 02:36
EPA 6010
Boron
1.91
mg/kg
3.0
12/21/15 02:36
EPA 6010
Calcium
80.8
mg/kg
29.8
12/21/15 02:36
EPA 6010
Chromium
10.0
mg/kg
0.30
12/21/15 02:36
EPA 6010
Copper
2.6
mg/kg
0.30
12/21/15 02:36
EPA 6010
Iron
3620
mg/kg
2.4
12/21/15 02:36
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
0.
H6
Page 7 of 51

aceAnaiXical
www.pacelabs.com
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Lab Sample ID Client Sample ID
Method Parameters
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92279910004
2015039117
EPA 6010
Magnesium
165
mg/kg
29.8
12/21/15 02:36
EPA 6010
Manganese
4.2
mg/kg
0.30
12/21/15 02:36
EPA 6010
Molybdenum
0.42J
mg/kg
0.60
12/21/15 02:36
EPA 6010
Nickel
2.3
mg/kg
0.30
12/21/15 02:36
EPA 6010
Potassium
104
mg/kg
59.6
12/21/15 02:36
EPA 6010
Strontium
2.1
mg/kg
0.60
12/21/15 02:36
EPA 6010
Zinc
6.6
mg/kg
1.2
12/21/15 02:36
EPA 6020
Lead
8.9
mg/kg
1.2
12/21/1510:58
EPA 6020
Selenium
0.66J
mg/kg
1.2
12/20/15 21:21
EPA 6020
Vanadium
19.3
mg/kg
1.2
12/21/1510:58
EPA 7471
Mercury
0.084
mg/kg
0.0094
12/21/1517:07
ASTM D2974-87
Percent Moisture
18.1
%
0.10
12/22/15 07:36
EPA 9045
pH at 25 Degrees C
4.5
Std. Units
0.10
12/17/15 08:45
EPA 9060
Total Organic Carbon
1200
mg/kg
738
12/18/15 10:38
EPA 9060
Total Organic Carbon
1620
mg/kg
731
12/18/15 10:44
EPA 9060
Total Organic Carbon
1080
mg/kg
739
12/18/15 10:49
EPA 9060
Total Organic Carbon
776
mg/kg
732
12/18/15 10:55
EPA 9060
Mean Total Organic Carbon
1170
mg/kg
735
12/18/15 10:38
EPA 9060
RSD%
29.9
%
12/18/15 10:38
92279910005
2015039118
EPA 6010
Aluminum
934
mg/kg
5.6
12/21/15 02:40
EPA 6010
Barium
3.8
mg/kg
0.56
12/21/15 02:40
EPA 6010
Beryllium
0.33
mg/kg
0.056
12/21/15 02:40
EPA 6010
Boron
2.3J
mg/kg
2.8
12/21/15 02:40
EPA 6010
Calcium
407
mg/kg
28.0
12/21/15 02:40
EPA 6010
Chromium
4.9
mg/kg
0.28
12/21/15 02:40
EPA 6010
Copper
0.61
mg/kg
0.28
12/21/15 02:40
EPA 6010
Iron
4570
mg/kg
2.2
12/21/15 02:40
EPA 6010
Magnesium
88.8
mg/kg
28.0
12/21/15 02:40
EPA 6010
Manganese
17.5
mg/kg
0.28
12/21/15 02:40
EPA 6010
Molybdenum
0.78
mg/kg
0.56
12/21/15 02:40
EPA 6010
Nickel
0.68
mg/kg
0.28
12/21/15 02:40
EPA 6010
Potassium
42.2J
mg/kg
56.0
12/21/15 02:40
EPA 6010
Strontium
3.2
mg/kg
0.56
12/21/15 02:40
EPA 6010
Zinc
5.7
mg/kg
1.1
12/21/15 02:40
EPA 6020
Arsenic
1.6
mg/kg
1.2
12/20/15 21:23
EPA 6020
Cobalt
1.4
mg/kg
1.2
12/20/15 21:23
EPA 6020
Lead
1.6
mg/kg
1.2
12/21/1511:06
EPA 6020
Vanadium
3.1
mg/kg
1.2
12/21/1511:06
EPA 7471
Mercury
0.0071J
mg/kg
0.0095
12/21/1517:09
ASTM D2974-87
Percent Moisture
14.3
%
0.10
12/22/15 07:36
EPA 9045
pH at 25 Degrees C
5.6
Std. Units
0.10
12/17/15 08:45
EPA 9060
RSD%
38.4
%
12/18/15 11:13
92279910006
2015039119
EPA 6010
Aluminum
501
mg/kg
7.9
12/21/15 02:44
EPA 6010
Barium
11.6
mg/kg
0.79
12/21/15 02:44
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
H6
H6
Page 8 of 51

aceAnaiXical
www.pacelabs.com
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Lab Sample ID Client Sample ID
Method Parameters
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result Units Report Limit Analyzed Qualifiers
92279910006
2015039119
EPA 6010
Beryllium
0.13
mg/kg
0.079
12/21/15 02:44
EPA 6010
Boron
5.4
mg/kg
4.0
12/21/15 02:44
EPA 6010
Calcium
238
mg/kg
39.7
12/21/15 02:44
EPA 6010
Chromium
1.2
mg/kg
0.40
12/21/15 02:44
EPA 6010
Copper
2.0
mg/kg
0.40
12/21/15 02:44
EPA 6010
Iron
251
mg/kg
3.2
12/21/15 02:44
EPA 6010
Magnesium
61.9
mg/kg
39.7
12/21/15 02:44
EPA 6010
Manganese
2.0
mg/kg
0.40
12/21/15 02:44
EPA 6010
Molybdenum
1.4
mg/kg
0.79
12/21/15 02:44
EPA 6010
Nickel
0.87
mg/kg
0.40
12/21/15 02:44
EPA 6010
Potassium
143
mg/kg
79.3
12/21/15 02:44
EPA 6010
Sodium
72.1J
mg/kg
79.3
12/21/1502:44
EPA 6010
Strontium
17.0
mg/kg
0.79
12/21/15 02:44
EPA 6010
Zinc
1.3J
mg/kg
1.6
12/21/15 02:44
EPA 6020
Arsenic
69.1
mg/kg
1.6
12/20/15 21:26
EPA 6020
Cadmium
0.31
mg/kg
0.19
12/20/15 21:26
EPA 6020
Cobalt
9.5
mg/kg
1.6
12/20/15 21:26
EPA 6020
Lead
16.5
mg/kg
1.6
12/21/1511:08
EPA 6020
Selenium
11.6
mg/kg
1.6
12/20/15 21:26
EPA 6020
Thallium
1.8
mg/kg
1.6
12/21/1511:08
EPA 6020
Vanadium
60.8
mg/kg
1.6
12/21/1511:08
EPA 7471
Mercury
0.28
mg/kg
0.013
12/21/1517:11
ASTM D2974-87
Percent Moisture
36.2
%
0.10
12/22/15 07:37
EPA 9045
pH at 25 Degrees C
7.4
Std. Units
0.10
12/17/15 08:45 H6
EPA 9060
Total Organic Carbon
115000
mg/kg
3600
12/18/15 11:35
EPA 9060
Total Organic Carbon
115000
mg/kg
3620
12/18/15 11:42
EPA 9060
Total Organic Carbon
113000
mg/kg
3540
12/18/15 11:48
EPA 9060
Total Organic Carbon
120000
mg/kg
3520
12/18/15 11:55
EPA 9060
Mean Total Organic Carbon
116000
mg/kg
3570
12/18/15 11:35
EPA 9060
RSD%
2.7
%
12/18/15 11:35
92279910007
2015039120
EPA 6010
Aluminum
635
mg/kg
8.0
12/20/15 18:31
EPA 6010
Barium
14.6
mg/kg
0.80
12/20/15 18:31
EPA 6010
Beryllium
0.16
mg/kg
0.080
12/20/15 18:31
EPA 6010
Boron
6.0
mg/kg
4.0
12/20/15 18:31
EPA 6010
Calcium
297
mg/kg
40.1
12/20/15 18:31
EPA 6010
Chromium
1.3
mg/kg
0.40
12/20/15 18:31
EPA 6010
Copper
2.3
mg/kg
0.40
12/20/15 18:31
EPA 6010
Iron
345
mg/kg
3.2
12/20/15 18:31
EPA 6010
Magnesium
81.2
mg/kg
40.1
12/20/15 18:31
EPA 6010
Manganese
2.6
mg/kg
0.40
12/20/15 18:31
EPA 6010
Molybdenum
1.2
mg/kg
0.80
12/20/15 18:31
EPA 6010
Nickel
1.1
mg/kg
0.40
12/20/15 18:31
EPA 6010
Potassium
170
mg/kg
80.2
12/20/15 18:31
EPA 6010
Sodium
90.5
mg/kg
80.2
12/20/15 18:31
EPA 6010
Strontium
21.5
mg/kg
0.80
12/20/15 18:31
EPA 6010
Zinc
2.4
mg/kg
1.6
12/20/15 18:31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 9 of 51

aceAnaiXical
www.pacelabs.com
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Lab Sample ID Client Sample ID
Method Parameters
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Result Units Report Limit Analyzed
92279910007
2015039120
EPA 6020
Arsenic
75.3
mg/kg
1.6
12/20/15 21:29
EPA 6020
Cadmium
0.33
mg/kg
0.19
12/20/15 21:29
EPA 6020
Cobalt
10.4
mg/kg
1.6
12/20/15 21:29
EPA 6020
Lead
17.9
mg/kg
1.6
12/21/1511:10
EPA 6020
Selenium
11.8
mg/kg
1.6
12/20/15 21:29
EPA 6020
Thallium
1.9
mg/kg
1.6
12/21/1511:10
EPA 6020
Vanadium
63.7
mg/kg
1.6
12/21/1511:10
EPA 7471
Mercury
0.31
mg/kg
0.013
12/21/1517:13
ASTM D2974-87
Percent Moisture
35.9
%
0.10
12/22/15 07:37
EPA 9045
pH at 25 Degrees C
7.4
Std. Units
0.10
12/17/15 08:45
EPA 9060
Total Organic Carbon
123000
mg/kg
4630
12/18/15 12:01
EPA 9060
Total Organic Carbon
115000
mg/kg
4630
12/18/15 12:08
EPA 9060
Total Organic Carbon
121000
mg/kg
4560
12/18/15 12:14
EPA 9060
Total Organic Carbon
122000
mg/kg
4610
12/18/15 12:20
EPA 9060
Mean Total Organic Carbon
120000
mg/kg
4610
12/18/15 12:01
EPA 9060
RSD%
2.8
%
12/18/15 12:01
92279910008
2015039121
EPA 6010
Aluminum
12200
mg/kg
6.3
12/21/15 02:48
EPA 6010
Barium
14.0
mg/kg
0.63
12/21/15 02:48
EPA 6010
Beryllium
0.071
mg/kg
0.063
12/21/15 02:48
EPA 6010
Boron
1.6J
mg/kg
3.2
12/21/15 02:48
EPA 6010
Calcium
24.2J
mg/kg
31.7
12/21/15 02:48
EPA 6010
Chromium
8.1
mg/kg
0.32
12/21/15 02:48
EPA 6010
Copper
0.83
mg/kg
0.32
12/21/15 02:48
EPA 6010
Iron
1060
mg/kg
2.5
12/21/15 02:48
EPA 6010
Magnesium
320
mg/kg
31.7
12/21/15 02:48
EPA 6010
Manganese
5.5
mg/kg
0.32
12/21/15 02:48
EPA 6010
Nickel
2.6
mg/kg
0.32
12/21/15 02:48
EPA 6010
Potassium
207
mg/kg
63.3
12/21/15 02:48
EPA 6010
Strontium
1.8
mg/kg
0.63
12/21/15 02:48
EPA 6010
Zinc
2.9
mg/kg
1.3
12/21/15 02:48
EPA 6020
Lead
6.7
mg/kg
1.2
12/21/1511:11
EPA 6020
Vanadium
5.2
mg/kg
1.2
12/21/1511:11
EPA 7471
Mercury
0.060
mg/kg
0.010
12/21/1517:15
ASTM D2974-87
Percent Moisture
19.6
%
0.10
12/22/15 07:37
EPA 9045
pH at 25 Degrees C
5.8
Std. Units
0.10
12/17/15 08:45
EPA 9060
Total Organic Carbon
5350
mg/kg
1460
12/18/15 12:27
EPA 9060
Total Organic Carbon
4910
mg/kg
1470
12/18/15 12:33
EPA 9060
Total Organic Carbon
5100
mg/kg
1480
12/18/15 12:38
EPA 9060
Total Organic Carbon
4890
mg/kg
1490
12/18/15 12:45
EPA 9060
Mean Total Organic Carbon
5060
mg/kg
1480
12/18/15 12:27
EPA 9060
RSD%
4.2
%
12/18/15 12:27
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
H6
H6
Qualifiers
Page 10 of 51

aceAnaiXical
www.pacelabs.com
PROJECT NARRATIVE
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: December 23, 2015
Duke Energy AnalyticalALaRriacioryervices, Inc.
%Q.�Cinic&yo.. Suite 100
�Huntersville, NC 28078
[phone]
General Information:
8 samples were analyzed for EPA 6010. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/27850
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 35221316005
M1: Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
• MS (Lab ID: 1423779)
• Aluminum
• Calcium
• Iron
• Manganese
• Strontium
• MSD (Lab ID: 1423780)
• Aluminum
• Calcium
• Chromium
• Iron
• Manganese
• Strontium
R1: RPD value was outside control limits.
• MSD (Lab ID: 1423780)
• Aluminum
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 11 of 51

aceAnaiXical
www.pacelabs.com
PROJECT NARRATIVE
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Method: EPA 6010
Description: 6010 MET ICP
Client: Duke Energy
Date: December 23, 2015
QC Batch: MPRP/27850
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s)
R1: RPD value was outside control limits.
• Calcium
• Chromium
• Iron
• Manganese
• Strontium
Additional Comments:
Analyte Comments:
QC Batch: MPRP/27850
D4: Sample was diluted due to the presence of high levels of target analytes.
•2015039115 (Lab ID: 92279910002)
• Calcium
• Strontium
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
[iiiS��'.TI Kai [9III11:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 12 of 51

aceAnaiXical
www.pacelabs.com
PROJECT NARRATIVE
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Method: EPA 6020
Description: 6020 MET ICPMS
Client: Duke Energy
Date: December 23, 2015
Duke Energy AnalyticalALaRriacioryervices, Inc.
%Q.�Cinic&yo.. Suite 100
�Huntersville, NC 28078
[phone]
General Information:
8 samples were analyzed for EPA 6020. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 3050 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Internal Standards:
All internal standards were within QC limits with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
QC Batch: MPRP/27886
A matrix spike and/or matrix spike duplicate (MS/MSD) were performed on the following sample(s): 92279401005
M6: Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
• MS (Lab ID: 1427163)
• Antimony
• MSD (Lab ID: 1427164)
• Antimony
Additional Comments:
Batch Comments:
Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
• QC Batch: ICPM / 11350
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 13 of 51

aceAnaiXical
www.pacelabs.com
PROJECT NARRATIVE
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Method: EPA 7471
Description: 7471 Mercury
Client: Duke Energy
Date: December 23, 2015
Duke Energy AnalyticalALaRriacioryervices, Inc.
%Q.�Cinic&yo.. Suite 100
�Huntersville, NC 28078
[phone]
General Information:
8 samples were analyzed for EPA 7471. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Sample Preparation:
The samples were prepared in accordance with EPA 7471 with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 14 of 51

aceAnaiXical
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PROJECT NARRATIVE
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Method: EPA 9045
Description: 9045 pH Soil
Client: Duke Energy
Date: December 23, 2015
Duke Energy AnalyticalALaRriacioryervices, Inc.
%py%roe. Suite 100
Huntersville, NC 28078
[phone]
General Information:
8 samples were analyzed for EPA 9045. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-16: Analysis initiated outside of the 15 minute EPA recommended holding time.
•2015039114 (Lab ID: 92279910001)
•2015039115 (Lab ID:92279910002)
•2015039116 (Lab ID:92279910003)
•2015039117 (Lab ID:92279910004)
•2015039118 (Lab ID:92279910005)
•2015039119 (Lab ID: 92279910006)
•2015039120 (Lab ID:92279910007)
•2015039121 (Lab ID:92279910008)
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 15 of 51

aceAnaiXical
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PROJECT NARRATIVE
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: December 23, 2015
Duke Energy AnalyticalALaRriacioryervices, Inc.
%py%roe. Suite 100
Huntersville, NC 28078
[phone]
General Information:
8 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/53066
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015039115 (Lab ID:92279910002)
• Chloride
• Sulfate
•2015039119 (Lab ID:92279910006)
• Chloride
• Sulfate
•2015039120 (Lab ID:92279910007)
• Chloride
• Sulfate
QC Batch: WETA/53104
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015039114 (Lab ID: 92279910001)
• Chloride
• Sulfate
•2015039116 (Lab ID: 92279910003)
• Chloride
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 16 of 51

aceAnaiXical
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PROJECT NARRATIVE
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Method: EPA 9056
Description: 9056 IC Anions
Client: Duke Energy
Date: December 23, 2015
Analyte Comments:
QC Batch: WETA/53104
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015039116 (Lab ID: 92279910003)
• Sulfate
•2015039117 (Lab ID: 92279910004)
• Chloride
• Sulfate
•2015039118 (Lab ID: 92279910005)
• Chloride
• Sulfate
•2015039121 (Lab ID: 92279910008)
• Chloride
• Sulfate
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 17 of 51

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PROJECT NARRATIVE
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: December 23, 2015
Duke Energy AnalyticalALaRriacioryervices, Inc.
%py%roe. Suite 100
Huntersville, NC 28078
[phone]
General Information:
8 samples were analyzed for EPA 9056. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
1-13: Sample was received or analysis requested beyond the recognized method holding time.
•2015039114 (Lab ID: 92279910001)
•2015039116 (Lab ID: 92279910003)
•2015039117 (Lab ID: 92279910004)
•2015039118 (Lab ID: 92279910005)
•2015039121 (Lab ID: 92279910008)
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
Analyte Comments:
QC Batch: WETA/53099
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015039115 (Lab ID: 92279910002)
• Nitrate as N
•2015039119 (Lab ID: 92279910006)
• Nitrate as N
•2015039120 (Lab ID: 92279910007)
• Nitrate as N
QC Batch: WETA/53103
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015039114 (Lab ID: 92279910001)
• Nitrate as N
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 18 of 51

aceAnaiXical
www.pacelabs.com
PROJECT NARRATIVE
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Method: EPA 9056
Description: 9056 IC Anions 48hr
Client: Duke Energy
Date: December 23, 2015
Analyte Comments:
QC Batch: WETA/53103
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
D3: Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
•2015039116 (Lab ID: 92279910003)
• Nitrate as N
•2015039117 (Lab ID: 92279910004)
• Nitrate as N
•2015039118 (Lab ID: 92279910005)
• Nitrate as N
•2015039121 (Lab ID: 92279910008)
• Nitrate as N
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 19 of 51

aceAnaiXical
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PROJECT NARRATIVE
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Method: EPA 9060
Description: Total Organic Carbon Quad
Client: Duke Energy
Date: December 23, 2015
Duke Energy AnalyticalALaRriai'oryervices, Inc.
%py%roe. Suite 100
Huntersville, NC 28078
[phone]
General Information:
8 samples were analyzed for EPA 9060. All samples were received in acceptable condition with any exceptions noted below or on the
chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report.
Hold Time:
The samples were analyzed within the method required hold times with any exceptions noted below.
Initial Calibrations (including MS Tune as applicable):
All criteria were within method requirements with any exceptions noted below.
Continuing Calibration:
All criteria were within method requirements with any exceptions noted below.
Method Blank:
All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below.
Laboratory Control Spike:
All laboratory control spike compounds were within QC limits with any exceptions noted below.
Matrix Spikes:
All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below.
Additional Comments:
This data package has been reviewed for quality and completeness and is approved for release.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc.. Page 20 of 51

aceAnaiXical
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ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
%giy%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039114 Lab ID: 92279910001 Collected: 12/14/15 13:25 Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 12/23/2015 05:19 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
18700
mg/kg
5.8
2.9
1
12/17/15 10:40
12/21/15 02:09
7429-90-5
15.7
mg/kg
0.58
0.29
1
12/17/15 10:40
12/21/15 02:09
7440-39-3
0.10
mg/kg
0.058
0.029
1
12/17/15 10:40
12/21/15 02:09
7440-41-7
5.4
mg/kg
2.9
1.4
1
12/17/1510:40
12/21/1502:09
7440-42-8
330
mg/kg
28.8
14.4
1
12/17/15 10:40
12/21/15 02:09
7440-70-2
22.8
mg/kg
0.29
0.14
1
12/17/15 10:40
12/21/15 02:09
7440-47-3
5.8
mg/kg
0.29
0.14
1
12/17/1510:40
12/21/1502:09
7440-50-8
9960
mg/kg
2.3
1.2
1
12/17/15 10:40
12/21/15 02:09
7439-89-6
259
mg/kg
28.8
14.4
1
12/17/15 10:40
12/21/15 02:09
7439-95-4
11.8
mg/kg
0.29
0.14
1
12/17/15 10:40
12/21/15 02:09
7439-96-5
1.9
mg/kg
0.58
0.29
1
12/17/15 10:40
12/21/15 02:09
7439-98-7
25.5
mg/kg
0.29
0.14
1
12/17/1510:40
12/21/1502:09
7440-02-0
210
mg/kg
57.5
28.8
1
12/17/15 10:40
12/21/15 02:09
7440-09-7
ND
mg/kg
57.5
28.8
1
12/17/15 10:40
12/21/15 02:09
7440-23-5
9.5
mg/kg
0.58
0.29
1
12/17/15 10:40
12/21/15 02:09
7440-24-6
8.0
mg/kg
1.2
0.58
1
12/17/15 10:40
12/21/15 02:09
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
2.5
1.2
20
12/19/15 08:24
12/21/15 10:53
7440-36-0
2.4
mg/kg
1.2
0.62
20
12/19/15 08:24
12/20/15 21:13
7440-38-2
ND
mg/kg
0.15
0.089
20
12/19/15 08:24
12/20/15 21:13
7440-43-9
0.84J
mg/kg
1.2
0.62
20
12/19/15 08:24
12/20/15 21:13
7440-48-4
5.4
mg/kg
1.2
1.2
20
12/19/15 08:24
12/21/15 10:53
7439-92-1
ND
mg/kg
1.2
0.62
20
12/19/15 08:24
12/20/15 21:13
7782-49-2
ND
mg/kg
1.2
0.62
20
12/19/15 08:24
12/21/15 10:53
7440-28-0
28.2
mg/kg
1.2
0.62
20
12/19/15 08:24
12/21/15 10:53
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.030 mg/kg 0.0092 0.0046 1 12/20/15 20:00 12/21/15 17:00 7439-97-6
Analytical Method: ASTM D2974-87
14.6 % 0.10 0.10 1 12/22/15 07:36
Analytical Method: EPA 9045
6.0 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
292
146 5
ND mg/kg
292
146 5
Analytical Method: EPA 9056
ND mg/kg
29.2
14.6 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
1POWf6'�II10i
N2
12/17/1511:33 16887-00-6 D3,M1
12/17/1511:33 14808-79-8 D3
12/17/1511:33 14797-55-8 D3,H3
Page 21 of 51

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ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039114
Lab ID:
92279910001
Collected:
12/14/15 13:25
Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
2070
mg/kg
706
353
1
12/18/15 07:47
7440-44-0
Total Organic Carbon
2010
mg/kg
705
352
1
12/18/15 07:52
7440-44-0
Total Organic Carbon
2230
mg/kg
709
355
1
12/18/15 07:58
7440-44-0
Total Organic Carbon
2100
mg/kg
705
352
1
12/18/15 08:04
7440-44-0
Mean Total Organic Carbon
2100
mg/kg
706
353
1
12/18/15 07:47
7440-44-0
Surrogates
RSD%
4.5
%
1
12/18/15 07:47
Date: 12/23/2015 05:19 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 22 of 51

aceAnaiXical
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ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039115 Lab ID: 92279910002 Collected: 12/14/15 15:25 Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 12/23/2015 05:19 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
741
mg/kg
6.1
3.1
1
12/17/15 10:40
12/21/15 02:13
7429-90-5
22.4
mg/kg
0.61
0.31
1
12/17/15 10:40
12/21/15 02:13
7440-39-3
0.23
mg/kg
0.061
0.031
1
12/17/15 10:40
12/21/15 02:13
7440-41-7
3.7
mg/kg
3.1
1.5
1
12/17/15 10:40
12/21/15 02:13
7440-42-8
173000
mg/kg
154
76.8
5
12/17/15 10:40
12/21/15 03:12
7440-70-2 D4
4.8
mg/kg
0.31
0.15
1
12/17/15 10:40
12/21/15 02:13
7440-47-3
0.49
mg/kg
0.31
0.15
1
12/17/1510:40
12/21/1502:13
7440-50-8
2400
mg/kg
2.5
1.2
1
12/17/15 10:40
12/21/15 02:13
7439-89-6
490
mg/kg
30.7
15.4
1
12/17/15 10:40
12/21/15 02:13
7439-95-4
55.7
mg/kg
0.31
0.15
1
12/17/15 10:40
12/21/15 02:13
7439-96-5
1.2
mg/kg
0.61
0.31
1
12/17/15 10:40
12/21/15 02:13
7439-98-7
0.68
mg/kg
0.31
0.15
1
12/17/1510:40
12/21/1502:13
7440-02-0
94.4
mg/kg
61.4
30.7
1
12/17/15 10:40
12/21/15 02:13
7440-09-7
1230
mg/kg
61.4
30.7
1
12/17/15 10:40
12/21/15 02:13
7440-23-5
800
mg/kg
3.1
1.5
5
12/17/15 10:40
12/21/15 03:12
7440-24-6 D4
2.6
mg/kg
1.2
0.61
1
12/17/15 10:40
12/21/15 02:13
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
2.4
1.2
20
12/19/15 08:24
12/21/15 10:55
7440-36-0 N2
7.1
mg/kg
1.2
0.61
20
12/19/15 08:24
12/20/15 21:16
7440-38-2
ND
mg/kg
0.15
0.088
20
12/19/15 08:24
12/20/15 21:16
7440-43-9
0.70J
mg/kg
1.2
0.61
20
12/19/15 08:24
12/20/15 21:16
7440-48-4
ND
mg/kg
1.2
1.2
20
12/19/15 08:24
12/21/15 10:55
7439-92-1
ND
mg/kg
1.2
0.61
20
12/19/15 08:24
12/20/15 21:16
7782-49-2
ND
mg/kg
1.2
0.61
20
12/19/15 08:24
12/21/15 10:55
7440-28-0
7.5
mg/kg
1.2
0.61
20
12/19/15 08:24
12/21/15 10:55
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
ND mg/kg 0.010 0.0050 1 12/20/15 20:00 12/21/15 17:02 7439-97-6
Analytical Method: ASTM D2974-87
18.5 % 0.10 0.10 1 12/22/15 07:36
Analytical Method: EPA 9045
8.1 Std. Units 0.10 0.10 1
Analytical Method: EPA 9056
ND mg/kg 304 152 5
ND mg/kg 304 152 5
Analytical Method: EPA 9056
ND mg/kg 30.4 15.2 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
1POWf6'�II10i
12/16/1513:48 16887-00-6 D3
12/16/1513:48 14808-79-8 D3
12/16/1513:48 14797-55-8 D3
Page 23 of 51

aceAnaiXical
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ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039115
Lab ID:
92279910002
Collected:
12/14/15 15:25
Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
2300
mg/kg
741
371
1
12/18/15 08:56
7440-44-0
Total Organic Carbon
1870
mg/kg
737
369
1
12/18/15 09:04
7440-44-0
Total Organic Carbon
1970
mg/kg
743
372
1
12/18/15 09:13
7440-44-0
Total Organic Carbon
2220
mg/kg
732
366
1
12/18/15 09:25
7440-44-0
Mean Total Organic Carbon
2090
mg/kg
738
369
1
12/18/15 08:56
7440-44-0
Surrogates
RSD%
9.7
%
1
12/18/15 08:56
Date: 12/23/2015 05:19 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 24 of 51

aceAnaiXical
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ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
%giy%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039116 Lab ID: 92279910003 Collected: 12/14/15 09:45 Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 12/23/2015 05:19 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
11600
mg/kg
6.0
3.0
1
12/17/15 10:40
12/21/15 02:18
7429-90-5
11.1
mg/kg
0.60
0.30
1
12/17/15 10:40
12/21/15 02:18
7440-39-3
0.078
mg/kg
0.060
0.030
1
12/17/15 10:40
12/21/15 02:18
7440-41-7
1.91
mg/kg
3.0
1.5
1
12/17/1510:40
12/21/1502:18
7440-42-8
118
mg/kg
30.0
15.0
1
12/17/15 10:40
12/21/15 02:18
7440-70-2
8.5
mg/kg
0.30
0.15
1
12/17/15 10:40
12/21/15 02:18
7440-47-3
2.7
mg/kg
0.30
0.15
1
12/17/1510:40
12/21/1502:18
7440-50-8
3570
mg/kg
2.4
1.2
1
12/17/15 10:40
12/21/15 02:18
7439-89-6
137
mg/kg
30.0
15.0
1
12/17/15 10:40
12/21/15 02:18
7439-95-4
4.3
mg/kg
0.30
0.15
1
12/17/15 10:40
12/21/15 02:18
7439-96-5
0.36J
mg/kg
0.60
0.30
1
12/17/15 10:40
12/21/15 02:18
7439-98-7
1.9
mg/kg
0.30
0.15
1
12/17/1510:40
12/21/1502:18
7440-02-0
90.7
mg/kg
59.9
30.0
1
12/17/15 10:40
12/21/15 02:18
7440-09-7
ND
mg/kg
59.9
30.0
1
12/17/15 10:40
12/21/15 02:18
7440-23-5
2.2
mg/kg
0.60
0.30
1
12/17/15 10:40
12/21/15 02:18
7440-24-6
5.3
mg/kg
1.2
0.60
1
12/17/15 10:40
12/21/15 02:18
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
2.3
1.1
20
12/19/15 08:24
12/21/15 10:57
7440-36-0
ND
mg/kg
1.1
0.57
20
12/19/15 08:24
12/20/15 21:18
7440-38-2
ND
mg/kg
0.14
0.082
20
12/19/15 08:24
12/20/15 21:18
7440-43-9
ND
mg/kg
1.1
0.57
20
12/19/15 08:24
12/20/15 21:18
7440-48-4
8.7
mg/kg
1.1
1.1
20
12/19/15 08:24
12/21/15 10:57
7439-92-1
0.65J
mg/kg
1.1
0.57
20
12/19/15 08:24
12/20/15 21:18
7782-49-2
ND
mg/kg
1.1
0.57
20
12/19/15 08:24
12/21/15 10:57
7440-28-0
17.3
mg/kg
1.1
0.57
20
12/19/15 08:24
12/21/15 10:57
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.11 mg/kg 0.0095 0.0047 1 12/20/15 20:00 12/21/15 17:05 7439-97-6
Analytical Method: ASTM D2974-87
15.9 % 0.10 0.10 1 12/22/15 07:36
Analytical Method: EPA 9045
4.6 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
300
150 5
ND mg/kg
300
150 5
Analytical Method: EPA 9056
ND mg/kg
30.0
15.0 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
1POW16'�II10i
N2
12/17/1512:38 16887-00-6 D3
12/17/1512:38 14808-79-8 D3
12/17/1512:38 14797-55-8 D3,H3
Page 25 of 51

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039116
Lab ID:
92279910003
Collected:
12/14/15 09:45
Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
841
mg/kg
709
355
1
12/18/15 09:37
7440-44-0
Total Organic Carbon
934
mg/kg
713
356
1
12/18/15 09:56
7440-44-0
Total Organic Carbon
922
mg/kg
711
355
1
12/18/15 10:28
7440-44-0
Total Organic Carbon
942
mg/kg
710
355
1
12/18/15 10:33
7440-44-0
Mean Total Organic Carbon
910
mg/kg
711
355
1
12/18/15 09:37
7440-44-0
Surrogates
RSD%
5.1
%
1
12/18/15 09:37
Date: 12/23/2015 05:19 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 26 of 51

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039117 Lab ID: 92279910004 Collected: 12/14/15 09:45 Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 12/23/2015 05:19 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
12800
mg/kg
6.0
3.0
1
12/17/15 10:40
12/21/15 02:36
7429-90-5
11.2
mg/kg
0.60
0.30
1
12/17/15 10:40
12/21/15 02:36
7440-39-3
0.091
mg/kg
0.060
0.030
1
12/17/15 10:40
12/21/15 02:36
7440-41-7
1.91
mg/kg
3.0
1.5
1
12/17/1510:40
12/21/1502:36
7440-42-8
80.8
mg/kg
29.8
14.9
1
12/17/15 10:40
12/21/15 02:36
7440-70-2
10.0
mg/kg
0.30
0.15
1
12/17/15 10:40
12/21/15 02:36
7440-47-3
2.6
mg/kg
0.30
0.15
1
12/17/1510:40
12/21/1502:36
7440-50-8
3620
mg/kg
2.4
1.2
1
12/17/15 10:40
12/21/15 02:36
7439-89-6
165
mg/kg
29.8
14.9
1
12/17/15 10:40
12/21/15 02:36
7439-95-4
4.2
mg/kg
0.30
0.15
1
12/17/15 10:40
12/21/15 02:36
7439-96-5
0.42J
mg/kg
0.60
0.30
1
12/17/15 10:40
12/21/15 02:36
7439-98-7
2.3
mg/kg
0.30
0.15
1
12/17/1510:40
12/21/1502:36
7440-02-0
104
mg/kg
59.6
29.8
1
12/17/15 10:40
12/21/15 02:36
7440-09-7
ND
mg/kg
59.6
29.8
1
12/17/15 10:40
12/21/15 02:36
7440-23-5
2.1
mg/kg
0.60
0.30
1
12/17/15 10:40
12/21/15 02:36
7440-24-6
6.6
mg/kg
1.2
0.60
1
12/17/15 10:40
12/21/15 02:36
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
2.4
1.2
20
12/19/15 08:24
12/21/15 10:58
7440-36-0
ND
mg/kg
1.2
0.59
20
12/19/15 08:24
12/20/15 21:21
7440-38-2
ND
mg/kg
0.14
0.085
20
12/19/15 08:24
12/20/15 21:21
7440-43-9
ND
mg/kg
1.2
0.59
20
12/19/15 08:24
12/20/15 21:21
7440-48-4
8.9
mg/kg
1.2
1.2
20
12/19/15 08:24
12/21/15 10:58
7439-92-1
0.66J
mg/kg
1.2
0.59
20
12/19/15 08:24
12/20/15 21:21
7782-49-2
ND
mg/kg
1.2
0.59
20
12/19/15 08:24
12/21/15 10:58
7440-28-0
19.3
mg/kg
1.2
0.59
20
12/19/15 08:24
12/21/15 10:58
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.084 mg/kg 0.0094 0.0047 1 12/20/15 20:00 12/21/15 17:07 7439-97-6
Analytical Method: ASTM D2974-87
18.1 % 0.10 0.10 1 12/22/15 07:36
Analytical Method: EPA 9045
4.5 Std. Units 0.10 0.10 1
Analytical Method: EPA 9056
ND mg/kg 309 154 5
ND mg/kg 309 154 5
Analytical Method: EPA 9056
ND mg/kg 30.9 15.4 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
1POW16'�II10i
N2
12/17/1516:25 16887-00-6 D3
12/17/1516:25 14808-79-8 D3
12/17/1516:25 14797-55-8 D3,H3
Page 27 of 51

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039117
Lab ID:
92279910004
Collected:
12/14/15 09:45
Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
1200
mg/kg
738
369
1
12/18/15 10:38
7440-44-0
Total Organic Carbon
1620
mg/kg
731
365
1
12/18/15 10:44
7440-44-0
Total Organic Carbon
1080
mg/kg
739
369
1
12/18/15 10:49
7440-44-0
Total Organic Carbon
776
mg/kg
732
366
1
12/18/15 10:55
7440-44-0
Mean Total Organic Carbon
1170
mg/kg
735
367
1
12/18/15 10:38
7440-44-0
Surrogates
RSD%
29.9
%
1
12/18/1510:38
Date: 12/23/2015 05:19 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 28 of 51

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
%giy%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039118 Lab ID: 92279910005 Collected: 12/14/15 10:20 Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 12/23/2015 05:19 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
934
mg/kg
5.6
2.8
1
12/17/15 10:40
12/21/15 02:40
7429-90-5
3.8
mg/kg
0.56
0.28
1
12/17/15 10:40
12/21/15 02:40
7440-39-3
0.33
mg/kg
0.056
0.028
1
12/17/15 10:40
12/21/15 02:40
7440-41-7
2.3J
mg/kg
2.8
1.4
1
12/17/1510:40
12/21/1502:40
7440-42-8
407
mg/kg
28.0
14.0
1
12/17/15 10:40
12/21/15 02:40
7440-70-2
4.9
mg/kg
0.28
0.14
1
12/17/15 10:40
12/21/15 02:40
7440-47-3
0.61
mg/kg
0.28
0.14
1
12/17/1510:40
12/21/1502:40
7440-50-8
4570
mg/kg
2.2
1.1
1
12/17/15 10:40
12/21/15 02:40
7439-89-6
88.8
mg/kg
28.0
14.0
1
12/17/15 10:40
12/21/15 02:40
7439-95-4
17.5
mg/kg
0.28
0.14
1
12/17/15 10:40
12/21/15 02:40
7439-96-5
0.78
mg/kg
0.56
0.28
1
12/17/15 10:40
12/21/15 02:40
7439-98-7
0.68
mg/kg
0.28
0.14
1
12/17/1510:40
12/21/1502:40
7440-02-0
42.2J
mg/kg
56.0
28.0
1
12/17/15 10:40
12/21/15 02:40
7440-09-7
ND
mg/kg
56.0
28.0
1
12/17/15 10:40
12/21/15 02:40
7440-23-5
3.2
mg/kg
0.56
0.28
1
12/17/15 10:40
12/21/15 02:40
7440-24-6
5.7
mg/kg
1.1
0.56
1
12/17/15 10:40
12/21/15 02:40
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
2.4
1.2
20
12/19/15 08:24
12/21/15 11:06
7440-36-0
1.6
mg/kg
1.2
0.60
20
12/19/15 08:24
12/20/15 21:23
7440-38-2
ND
mg/kg
0.14
0.086
20
12/19/15 08:24
12/20/15 21:23
7440-43-9
1.4
mg/kg
1.2
0.60
20
12/19/15 08:24
12/20/15 21:23
7440-48-4
1.6
mg/kg
1.2
1.2
20
12/19/15 08:24
12/21/15 11:06
7439-92-1
ND
mg/kg
1.2
0.60
20
12/19/15 08:24
12/20/15 21:23
7782-49-2
ND
mg/kg
1.2
0.60
20
12/19/15 08:24
12/21/15 11:06
7440-28-0
3.1
mg/kg
1.2
0.60
20
12/19/15 08:24
12/21/15 11:06
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.0071J mg/kg 0.0095 0.0047 1 12/20/15 20:00 12/21/15 17:09 7439-97-6
Analytical Method: ASTM D2974-87
14.3 % 0.10 0.10 1 12/22/15 07:36
Analytical Method: EPA 9045
5.6 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
292
146 5
ND mg/kg
292
146 5
Analytical Method: EPA 9056
ND mg/kg
29.2
14.6 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
1POWf6'�II10i
N2
12/17/1516:46 16887-00-6 D3
12/17/1516:46 14808-79-8 D3
12/17/1516:46 14797-55-8 D3,H3
Page 29 of 51

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039118
Lab ID:
92279910005
Collected:
12/14/15 10:20
Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
ND
mg/kg
702
351
1
12/18/15 11:13
7440-44-0
Total Organic Carbon
ND
mg/kg
694
347
1
12/18/15 11:18
7440-44-0
Total Organic Carbon
ND
mg/kg
702
351
1
12/18/15 11:24
7440-44-0
Total Organic Carbon
ND
mg/kg
699
349
1
12/18/15 11:29
7440-44-0
Mean Total Organic Carbon
ND
mg/kg
699
350
1
12/18/15 11:13
7440-44-0
Surrogates
RSD%
38.4
%
1
12/18/1511:13
Date: 12/23/2015 05:19 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 30 of 51

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
%giy%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039119 Lab ID: 92279910006 Collected: 12/14/15 14:45 Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 12/23/2015 05:19 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
501
mg/kg
7.9
4.0
1
12/17/15 10:40
12/21/15 02:44
7429-90-5
11.6
mg/kg
0.79
0.40
1
12/17/15 10:40
12/21/15 02:44
7440-39-3
0.13
mg/kg
0.079
0.040
1
12/17/15 10:40
12/21/15 02:44
7440-41-7
5.4
mg/kg
4.0
2.0
1
12/17/1510:40
12/21/1502:44
7440-42-8
238
mg/kg
39.7
19.8
1
12/17/15 10:40
12/21/15 02:44
7440-70-2
1.2
mg/kg
0.40
0.20
1
12/17/15 10:40
12/21/15 02:44
7440-47-3
2.0
mg/kg
0.40
0.20
1
12/17/1510:40
12/21/1502:44
7440-50-8
251
mg/kg
3.2
1.6
1
12/17/15 10:40
12/21/15 02:44
7439-89-6
61.9
mg/kg
39.7
19.8
1
12/17/15 10:40
12/21/15 02:44
7439-95-4
2.0
mg/kg
0.40
0.20
1
12/17/15 10:40
12/21/15 02:44
7439-96-5
1.4
mg/kg
0.79
0.40
1
12/17/15 10:40
12/21/15 02:44
7439-98-7
0.87
mg/kg
0.40
0.20
1
12/17/1510:40
12/21/1502:44
7440-02-0
143
mg/kg
79.3
39.7
1
12/17/15 10:40
12/21/15 02:44
7440-09-7
72.1J
mg/kg
79.3
39.7
1
12/17/15 10:40
12/21/15 02:44
7440-23-5
17.0
mg/kg
0.79
0.40
1
12/17/15 10:40
12/21/15 02:44
7440-24-6
1.3J
mg/kg
1.6
0.79
1
12/17/15 10:40
12/21/15 02:44
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
3.1
1.5
20
12/19/15 08:24
12/21/15 11:08
7440-36-0
69.1
mg/kg
1.6
0.78
20
12/19/15 08:24
12/20/15 21:26
7440-38-2
0.31
mg/kg
0.19
0.11
20
12/19/15 08:24
12/20/15 21:26
7440-43-9
9.5
mg/kg
1.6
0.78
20
12/19/15 08:24
12/20/15 21:26
7440-48-4
16.5
mg/kg
1.6
1.5
20
12/19/15 08:24
12/21/15 11:08
7439-92-1
11.6
mg/kg
1.6
0.78
20
12/19/15 08:24
12/20/15 21:26
7782-49-2
1.8
mg/kg
1.6
0.78
20
12/19/15 08:24
12/21/15 11:08
7440-28-0
60.8
mg/kg
1.6
0.78
20
12/19/15 08:24
12/21/15 11:08
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.28 mg/kg 0.013 0.0063 1 12/20/15 20:00 12/21/15 17:11 7439-97-6
Analytical Method: ASTM D2974-87
36.2 % 0.10 0.10 1 12/22/15 07:37
Analytical Method: EPA 9045
7.4 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
392
196 5
ND mg/kg
392
196 5
Analytical Method: EPA 9056
ND mg/kg
39.2
19.6 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
1POWf6'�II10i
N2
12/16/1514:09 16887-00-6 D3
12/16/1514:09 14808-79-8 D3
12/16/1514:09 14797-55-8 D3
Page 31 of 51

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039119
Lab ID:
92279910006
Collected:
12/14/15 14:45
Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
115000
mg/kg
3600
1800
1
12/18/15 11:35
7440-44-0
Total Organic Carbon
115000
mg/kg
3620
1810
1
12/18/15 11:42
7440-44-0
Total Organic Carbon
113000
mg/kg
3540
1770
1
12/18/15 11:48
7440-44-0
Total Organic Carbon
120000
mg/kg
3520
1760
1
12/18/15 11:55
7440-44-0
Mean Total Organic Carbon
116000
mg/kg
3570
1790
1
12/18/15 11:35
7440-44-0
Surrogates
RSD%
2.7
%
1
12/18/1511:35
Date: 12/23/2015 05:19 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 32 of 51

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
%giy%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039120 Lab ID: 92279910007 Collected: 12/14/15 14:45 Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 12/23/2015 05:19 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
635
mg/kg
8.0
4.0
1
12/17/1510:40
12/20/1518:31
7429-90-5
14.6
mg/kg
0.80
0.40
1
12/17/1510:40
12/20/1518:31
7440-39-3
0.16
mg/kg
0.080
0.040
1
12/17/1510:40
12/20/1518:31
7440-41-7
6.0
mg/kg
4.0
2.0
1
12/17/1510:40
12/20/1518:31
7440-42-8
297
mg/kg
40.1
20.0
1
12/17/1510:40
12/20/1518:31
7440-70-2
1.3
mg/kg
0.40
0.20
1
12/17/1510:40
12/20/1518:31
7440-47-3
2.3
mg/kg
0.40
0.20
1
12/17/1510:40
12/20/1518:31
7440-50-8
345
mg/kg
3.2
1.6
1
12/17/1510:40
12/20/1518:31
7439-89-6
81.2
mg/kg
40.1
20.0
1
12/17/1510:40
12/20/1518:31
7439-95-4
2.6
mg/kg
0.40
0.20
1
12/17/1510:40
12/20/1518:31
7439-96-5
1.2
mg/kg
0.80
0.40
1
12/17/1510:40
12/20/1518:31
7439-98-7
1.1
mg/kg
0.40
0.20
1
12/17/1510:40
12/20/1518:31
7440-02-0
170
mg/kg
80.2
40.1
1
12/17/1510:40
12/20/1518:31
7440-09-7
90.5
mg/kg
80.2
40.1
1
12/17/1510:40
12/20/1518:31
7440-23-5
21.5
mg/kg
0.80
0.40
1
12/17/1510:40
12/20/1518:31
7440-24-6
2.4
mg/kg
1.6
0.80
1
12/17/1510:40
12/20/1518:31
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
3.1
1.6
20
12/19/15 08:24
12/21/15 11:10
7440-36-0
75.3
mg/kg
1.6
0.79
20
12/19/15 08:24
12/20/15 21:29
7440-38-2
0.33
mg/kg
0.19
0.11
20
12/19/15 08:24
12/20/15 21:29
7440-43-9
10.4
mg/kg
1.6
0.79
20
12/19/15 08:24
12/20/15 21:29
7440-48-4
17.9
mg/kg
1.6
1.6
20
12/19/15 08:24
12/21/15 11:10
7439-92-1
11.8
mg/kg
1.6
0.79
20
12/19/15 08:24
12/20/15 21:29
7782-49-2
1.9
mg/kg
1.6
0.79
20
12/19/15 08:24
12/21/15 11:10
7440-28-0
63.7
mg/kg
1.6
0.79
20
12/19/15 08:24
12/21/15 11:10
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.31 mg/kg 0.013 0.0063 1 12/20/15 20:00 12/21/15 17:13 7439-97-6
Analytical Method: ASTM D2974-87
35.9 % 0.10 0.10 1 12/22/15 07:37
Analytical Method: EPA 9045
7.4 Std. Units
0.10
0.10 1
Analytical Method: EPA 9056
ND mg/kg
390
195 5
ND mg/kg
390
195 5
Analytical Method: EPA 9056
ND mg/kg
39.0
19.5 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
1POWf6'�II10i
N2
12/16/1514:30 16887-00-6 D3
12/16/1514:30 14808-79-8 D3
12/16/1514:30 14797-55-8 D3
Page 33 of 51

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039120
Lab ID:
92279910007
Collected:
12/14/15 14:45
Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
123000
mg/kg
4630
2310
1
12/18/15 12:01
7440-44-0
Total Organic Carbon
115000
mg/kg
4630
2320
1
12/18/15 12:08
7440-44-0
Total Organic Carbon
121000
mg/kg
4560
2280
1
12/18/15 12:14
7440-44-0
Total Organic Carbon
122000
mg/kg
4610
2300
1
12/18/15 12:20
7440-44-0
Mean Total Organic Carbon
120000
mg/kg
4610
2300
1
12/18/15 12:01
7440-44-0
Surrogates
RSD%
2.8
%
1
12/18/1512:01
Date: 12/23/2015 05:19 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 34 of 51

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039121 Lab ID: 92279910008 Collected: 12/14/15 11:10 Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Aluminum
Barium
Beryllium
Boron
Calcium
Chromium
Copper
Iron
Magnesium
Manganese
Molybdenum
Nickel
Potassium
Sodium
Strontium
Zinc
6020 MET ICPMS
Antimony
Arsenic
Cadmium
Cobalt
Lead
Selenium
Thallium
Vanadium
7471 Mercury
Mercury
Percent Moisture
Percent Moisture
9045 pH Soil
pH at 25 Degrees C
9056 IC Anions
Chloride
Sulfate
9056 IC Anions 48hr
Nitrate as N
Date: 12/23/2015 05:19 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
12200
mg/kg
6.3
3.2
1
12/17/15 10:40
12/21/15 02:48
7429-90-5
14.0
mg/kg
0.63
0.32
1
12/17/15 10:40
12/21/15 02:48
7440-39-3
0.071
mg/kg
0.063
0.032
1
12/17/15 10:40
12/21/15 02:48
7440-41-7
1.6J
mg/kg
3.2
1.6
1
12/17/1510:40
12/21/1502:48
7440-42-8
24.2J
mg/kg
31.7
15.8
1
12/17/15 10:40
12/21/15 02:48
7440-70-2
8.1
mg/kg
0.32
0.16
1
12/17/15 10:40
12/21/15 02:48
7440-47-3
0.83
mg/kg
0.32
0.16
1
12/17/1510:40
12/21/1502:48
7440-50-8
1060
mg/kg
2.5
1.3
1
12/17/15 10:40
12/21/15 02:48
7439-89-6
320
mg/kg
31.7
15.8
1
12/17/15 10:40
12/21/15 02:48
7439-95-4
5.5
mg/kg
0.32
0.16
1
12/17/15 10:40
12/21/15 02:48
7439-96-5
ND
mg/kg
0.63
0.32
1
12/17/15 10:40
12/21/15 02:48
7439-98-7
2.6
mg/kg
0.32
0.16
1
12/17/1510:40
12/21/1502:48
7440-02-0
207
mg/kg
63.3
31.7
1
12/17/15 10:40
12/21/15 02:48
7440-09-7
ND
mg/kg
63.3
31.7
1
12/17/15 10:40
12/21/15 02:48
7440-23-5
1.8
mg/kg
0.63
0.32
1
12/17/15 10:40
12/21/15 02:48
7440-24-6
2.9
mg/kg
1.3
0.63
1
12/17/15 10:40
12/21/15 02:48
7440-66-6
Analytical
Method: EPA
6020 Preparation Method: EPA 3050
ND
mg/kg
2.4
1.2
20
12/19/15 08:24
12/21/15 11:11
7440-36-0
ND
mg/kg
1.2
0.61
20
12/19/15 08:24
12/20/15 21:31
7440-38-2
ND
mg/kg
0.15
0.087
20
12/19/15 08:24
12/20/15 21:31
7440-43-9
ND
mg/kg
1.2
0.61
20
12/19/15 08:24
12/20/15 21:31
7440-48-4
6.7
mg/kg
1.2
1.2
20
12/19/15 08:24
12/21/15 11:11
7439-92-1
ND
mg/kg
1.2
0.61
20
12/19/15 08:24
12/20/15 21:31
7782-49-2
ND
mg/kg
1.2
0.61
20
12/19/15 08:24
12/21/15 11:11
7440-28-0
5.2
mg/kg
1.2
0.61
20
12/19/15 08:24
12/21/15 11:11
7440-62-2
Analytical Method: EPA 7471 Preparation Method: EPA 7471
0.060 mg/kg 0.010 0.0052 1 12/20/15 20:00 12/21/15 17:15 7439-97-6
Analytical Method: ASTM D2974-87
19.6 % 0.10 0.10 1 12/22/15 07:37
Analytical Method: EPA 9045
5.8 Std. Units 0.10 0.10 1
Analytical Method: EPA 9056
ND mg/kg 304 152 5
ND mg/kg 304 152 5
Analytical Method: EPA 9056
ND mg/kg 30.4 15.2 5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
1POWf6'�II10i
N2
12/17/1517:08 16887-00-6 D3
12/17/1517:08 14808-79-8 D3
12/17/1517:08 14797-55-8 D3,H3
Page 35 of 51

aceAnaiXical
www.pacelabs.com
ANALYTICAL RESULTS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
Sample: 2015039121
Lab ID:
92279910008
Collected:
12/14/15 11:10
Received: 12/15/15 14:07 Matrix: Solid
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
Total Organic Carbon Quad
Analytical
Method: EPA 9060
Total Organic Carbon
5350
mg/kg
1460
731
1
12/18/15 12:27
7440-44-0
Total Organic Carbon
4910
mg/kg
1470
737
1
12/18/15 12:33
7440-44-0
Total Organic Carbon
5100
mg/kg
1480
742
1
12/18/15 12:38
7440-44-0
Total Organic Carbon
4890
mg/kg
1490
744
1
12/18/15 12:45
7440-44-0
Mean Total Organic Carbon
5060
mg/kg
1480
739
1
12/18/15 12:27
7440-44-0
Surrogates
RSD%
4.2
%
1
12/18/1512:27
Date: 12/23/2015 05:19 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 36 of 51

aceAnaiXical
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QUALITY CONTROL DATA
Duke Energy AnalyticalALaRriacioryervices, Inc.
%�ginlc&yoe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
QC Batch: MERP/6460
Analysis Method: EPA 7471
QC Batch Method: EPA 7471
Analysis Description: 7471 Mercury
Associated Lab Samples: 92279910001, 92279910002,
92279910003, 92279910004, 92279910005, 92279910006, 92279910007,
92279910008
METHOD BLANK: 1427815
Matrix: Solid
Associated Lab Samples: 92279910001, 92279910002,
92279910003, 92279910004, 92279910005, 92279910006, 92279910007,
92279910008
Blank Reporting
Parameter Units
Result Limit MDL Analyzed Qualifiers
Mercury mg/kg
ND 0.0081 0.0041 12/21/1516:12
LABORATORY CONTROL SAMPLE: 1427816
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mercury mg/kg
.082 0.082 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1427817 1427818
MS MSD
35219805001
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qua]
Mercury mg/kg 1.91.1
37.3 37.3 36.4 35.8 98 97 80-120 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/23/2015 05:19 PM without the written consent of Pace Analytical Services, Inc..
Page 37 of 51

aceAnaiXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: MPRP/27850 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET Solid
Associated Lab Samples: 92279910001, 92279910002, 92279910003, 92279910004, 92279910005, 92279910006, 92279910007,
92279910008
METHOD BLANK: 1423777 Matrix: Solid
Associated Lab Samples: 92279910001, 92279910002, 92279910003, 92279910004, 92279910005, 92279910006, 92279910007,
92279910008
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Aluminum
mg/kg
ND
5.2
2.6
12/19/15 22:04
Barium
mg/kg
ND
0.52
0.26
12/19/15 22:04
Beryllium
mg/kg
ND
0.052
0.026
12/19/15 22:04
Boron
mg/kg
ND
2.6
1.3
12/19/15 22:04
Calcium
mg/kg
ND
26.2
13.1
12/19/15 22:04
Chromium
mg/kg
ND
0.26
0.13
12/19/15 22:04
Copper
mg/kg
ND
0.26
0.13
12/19/15 22:04
Iron
mg/kg
ND
2.1
1.0
12/19/15 22:04
Magnesium
mg/kg
ND
26.2
13.1
12/19/15 22:04
Manganese
mg/kg
ND
0.26
0.13
12/19/15 22:04
Molybdenum
mg/kg
ND
0.52
0.26
12/19/15 22:04
Nickel
mg/kg
ND
0.26
0.13
12/19/15 22:04
Potassium
mg/kg
ND
52.4
26.2
12/19/15 22:04
Sodium
mg/kg
ND
52.4
26.2
12/19/15 22:04
Strontium
mg/kg
ND
0.52
0.26
12/19/15 22:04
Zinc
mg/kg
ND
1.0
0.52
12/19/15 22:04
LABORATORY CONTROL SAMPLE:
1423778
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Aluminum
mg/kg
128
128
100
80-120
Barium
mg/kg
12.8
12.9
101
80-120
Beryllium
mg/kg
1.3
1.3
101
80-120
Boron
mg/kg
128
114
89
80-120
Calcium
mg/kg
639
644
101
80-120
Chromium
mg/kg
12.8
13.1
103
80-120
Copper
mg/kg
12.8
13.3
104
80-120
Iron
mg/kg
128
126
99
80-120
Magnesium
mg/kg
639
620
97
80-120
Manganese
mg/kg
12.8
13.3
104
80-120
Molybdenum
mg/kg
12.8
13.0
102
80-120
Nickel
mg/kg
12.8
12.8
101
80-120
Potassium
mg/kg
639
624
98
80-120
Sodium
mg/kg
639
639
100
80-120
Strontium
mg/kg
12.8
12.7
100
80-120
Zinc
mg/kg
63.9
61.0
96
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/23/2015 05:19 PM without the written consent of Pace Analytical Services, Inc.. Page 38 of 51

aceAnaiXical
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QUALITY CONTROL DATA
Duke Energy AnalyticalALaRriacioryervices, Inc.
%�giyc&yoe. Suite 100
Huntersville, NC 28078
[phone]
Project:
Pace Project No.:
J15120373 WEATHERSPOON
92279910
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
1423779
1423780
MS
MSD
35221316005
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Aluminum
mg/kg
1740
136
138
4430
9020
1980
5280
75-125
68
20 M1,R1
Barium
mg/kg
2.1
13.6
13.8
15.6
17.0
100
109
75-125
9
20
Beryllium
mg/kg
0.076
1.35
1.35
1.4
1.5
99
104
75-125
6
20
Boron
mg/kg
1.51-1
136
138
119
113
88
82
75-125
5
20
Calcium
mg/kg
25700
679
690
6450
8130
-2840
-2550
75-125
23
20 M1,R1
Chromium
mg/kg
3.5
13.6
13.8
18.9
24.8
114
155
75-125
27
20 M1,R1
Copper
mg/kg
0.70
13.6
13.8
14.0
13.5
98
93
75-125
4
20
Iron
mg/kg
1860
136
138
1350
3690
-379
1330
75-125
93
20 M1,R1
Magnesium
mg/kg
101
679
690
801
935
103
121
75-125
15
20
Manganese
mg/kg
21.7
13.6
13.8
22.4
39.6
5
130
75-125
55
20 M1,R1
Molybdenum
mg/kg
0.29U
13.6
13.8
13.2
13.0
97
94
75-125
2
20
Nickel
mg/kg
0.81
13.6
13.8
14.7
16.1
102
111
75-125
9
20
Potassium
mg/kg
65.3
679
690
761
839
102
112
75-125
10
20
Sodium
mg/kg
29.01-1
679
690
689
712
101
103
75-125
3
20
Strontium
mg/kg
38.5
13.6
13.8
31.4
39.3
-53
6
75-125
22
20 M1,R1
Zinc
mg/kg
1.6
67.9
69
65.0
64.0
93
91
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
QC Batch: MPRP/27886 Analysis Method: EPA 6020
QC Batch Method: EPA 3050 Analysis Description: 6020 MET SOLID
Associated Lab Samples: 92279910001, 92279910002, 92279910003, 92279910004, 92279910005, 92279910006, 92279910007,
92279910008
METHOD BLANK: 1427161
Matrix:
Solid
1427164
Associated Lab Samples:
92279910001, 92279910002,
92279910003,
92279910004, 92279910005, 92279910006, 92279910007,
92279910008
MS
MSD
Blank
92279401005
Reporting
Spike
Spike
MS
MSD
Parameter
Units
Result
Limit
Parameter
MDL
Result
Analyzed Qualifiers
Antimony
mg/kg
Result
ND
% Rec
2.0
RPD
1.0
12/21/1510:44 N2
Arsenic
mg/kg
33.3
ND
10.5
1.0
31
0.51
12/20/15 20:27
Cadmium
mg/kg
Arsenic
ND
ND
0.12
0.073
12/20/15 20:27
Cobalt
mg/kg
85
ND
3
1.0
Cadmium
0.51
12/20/15 20:27
Lead
mg/kg
3.3
ND
97
1.0
75-125
1.0
12/21/1510:44
Selenium
mg/kg
8.0
ND
31.6
1.0
39.0
0.51
12/20/15 20:27
Thallium
mg/kg
20
ND
mg/kg
1.0
33.3
0.51
12/21/1510:44
Vanadium
mg/kg
101
ND
0
1.0
Selenium
0.51
12/21/1510:44
LABORATORY CONTROL
SAMPLE: 1427162
28.8
28.0
86
87
75-125
3
20
Thallium
mg/kg
Spike
33.3
LCS
32.4
LCS
97
% Rec
Parameter
Units
Conc.
Vanadium
Result
36.6
% Rec
31.6
Limits Qualifiers
Antimony
mg/kg
25.7
75-125
25.3
20
98
80-120 N2
Arsenic
mg/kg
25.7
26.5
103
80-120
Cadmium
mg/kg
2.6
2.7
104
80-120
Cobalt
mg/kg
25.7
27.4
106
80-120
Lead
mg/kg
25.7
26.3
102
80-120
Selenium
mg/kg
25.7
23.7
92
80-120
Thallium
mg/kg
25.7
26.3
102
80-120
Vanadium
mg/kg
25.7
26.6
103
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
1427163
1427164
MS
MSD
92279401005
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
mg/kg
ND
33.3
31.6
10.5
10.3
31
32
75-125
2
20 M6, N2
Arsenic
mg/kg
ND
33.3
31.6
28.6
27.6
84
85
75-125
3
20
Cadmium
mg/kg
ND
3.35
3.22
3.3
3.2
97
98
75-125
4
20
Cobalt
mg/kg
8.0
33.3
31.6
39.7
39.0
96
98
75-125
2
20
Lead
mg/kg
2.2
33.3
31.6
34.2
34.1
96
101
75-125
0
20
Selenium
mg/kg
ND
33.3
31.6
28.8
28.0
86
87
75-125
3
20
Thallium
mg/kg
ND
33.3
31.6
32.4
31.8
97
100
75-125
2
20
Vanadium
mg/kg
36.6
33.3
31.6
67.8
69.3
94
103
75-125
2
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Duke Energy AnalyticalALaRriacioryervices, Inc.
%�ginlc&yoe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
QC Batch: PMST/4161
Analysis Method:
ASTM D2974-87
QC Batch Method: ASTM
D2974-87
Analysis Description:
Dry Weight/Percent Moisture
Associated Lab Samples:
92279910001, 92279910002, 92279910003, 92279910004,
92279910005, 92279910006,
92279910007,
92279910008
SAMPLE DUPLICATE:
1428919
35220509001
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
66.7
69.0 3
10
SAMPLE DUPLICATE:
1428920
35221366003
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
13.4
11.3 17
10 D6
SAMPLE DUPLICATE:
1428921
35221186006
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
21.3
20.0 6
10
SAMPLE DUPLICATE:
1428922
92279910005
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
14.3
14.5 2
10
SAMPLE DUPLICATE:
1428923
35221402003
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
6.9
7.1 3
10
SAMPLE DUPLICATE:
1428924
35221542025
Dup
Max
Parameter
Units
Result
Result RPD
RPD
Qualifiers
Percent Moisture
%
6.5
5.4 18
10 D6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
QC Batch: WETA/53066 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92279910002, 92279910006, 92279910007
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
METHOD BLANK: 1422623
1422624
Matrix: Solid
Units
Associated Lab Samples:
mg/kg
Sulfate
mg/kg
Blank Reporting
1422626
Parameter
Units
Result Limit
MDL Analyzed Qualifiers
Chloride
mg/kg
ND 49.5
24.8 12/16/1510:14
Sulfate
mg/kg
ND 49.5
24.8 12/16/1510:14
LABORATORY CONTROL SAMPLE:
1422624
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1422626
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1422625
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
494 481 97 80-120
494 478 97 80-120
92279406001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 742 770 78 80-120 M1
884 742 1570 93 80-120
92279406001 Dup
Units Result Result
mg/kg ND 1991
mg/kg 884 844
Max
RPD RPD Qualifiers
20
5 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
QC Batch: WETA/53104 Analysis Method: EPA 9056
QC Batch Method: EPA 9056 Analysis Description: 9056 IC Anions
Associated Lab Samples: 92279910001, 92279910003, 92279910004, 92279910005, 92279910008
Duke Energy AnalyticalALaRriacioryervices, Inc.
qp2py%roe. Suite 100
Huntersville, NC 28078
[phone]
METHOD BLANK: 1424337
1424338
Matrix: Solid
Units
Associated Lab Samples:
mg/kg
Sulfate
mg/kg
Blank Reporting
1424340
Parameter
Units
Result Limit
MDL Analyzed Qualifiers
Chloride
mg/kg
ND 49.9
25.0 12/17/1510:51
Sulfate
mg/kg
ND 49.9
25.0 12/17/1510:51
LABORATORY CONTROL SAMPLE:
1424338
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
MATRIX SPIKE SAMPLE:
1424340
Parameter
Units
Chloride
mg/kg
Sulfate
mg/kg
SAMPLE DUPLICATE: 1424339
Parameter
Chloride
Sulfate
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
500 491 98 80-120
500 489 98 80-120
92279910001 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 578 538 76 80-120 M1
ND 578 663 96 80-120
92279910001 Dup
Units Result Result
mg/kg ND ND
mg/kg ND ND
Max
RPD RPD Qualifiers
20
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Duke Energy AnalyticalALaRriacioryervices, Inc.
%�ginlc&yoe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
QC Batch: WETA/53099
Analysis Method:
EPA 9056
QC Batch Method: EPA 9056
Analysis Description:
9056 IC Anions
Associated Lab Samples: 92279910002, 92279910006, 92279910007
METHOD BLANK: 1424053
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit
MDL
Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0
2.5
12/16/15 10:14
LABORATORY CONTROL SAMPLE:
1424054
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits Qualifiers
Nitrate as N
mg/kg
49.4 50.1
101
80-120
MATRIX SPIKE SAMPLE:
1424539
92279406001 Spike
MS
MS
% Rec
Parameter
Units
Result Conc.
Result
% Rec
Limits Qualifiers
Nitrate as N
mg/kg
ND 74.2
72.2
95
80-120 H3
SAMPLE DUPLICATE: 1424538
92279406001 Dup
Max
Parameter
Units
Result Result
RPD
RPD
Qualifiers
Nitrate as N
mg/kg
ND ND
20 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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aceAnaiXical
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QUALITY CONTROL DATA
Duke Energy AnalyticalALaRriacioryervices, Inc.
%�ginlc&yoe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
QC Batch: WETA/53103
Analysis Method: EPA 9056
QC Batch Method: EPA 9056
Analysis Description: 9056 IC Anions
Associated Lab Samples: 92279910001, 92279910003, 92279910004, 92279910005, 92279910008
METHOD BLANK: 1424331
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter
Units
Result Limit MDL
Analyzed
Qualifiers
Nitrate as N
mg/kg
ND 5.0 2.5
12/17/15 10:51
LABORATORY CONTROL SAMPLE:
1424332
Spike LCS LCS
% Rec
Parameter
Units
Conc. Result % Rec
Limits Qualifiers
Nitrate as N
mg/kg
50 51.3 103
80-120
MATRIX SPIKE SAMPLE:
1424334
92279910001 Spike MS
MS
% Rec
Parameter
Units
Result Conc. Result
% Rec
Limits Qualifiers
Nitrate as N
mg/kg
ND 57.8 56.1
97
80-120 H1
SAMPLE DUPLICATE: 1424333
92279910001 Dup
Max
Parameter
Units
Result Result RPD
RPD
Qualifiers
Nitrate as N
mg/kg
ND ND
20 H1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
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QUALITY CONTROL DATA
Duke Energy AnalyticalALaRriacioryervices, Inc.
%�ginlc&yoe. Suite 100
Huntersville, NC 28078
[phone]
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
QC Batch: WETA/31737
Analysis Method: EPA 9060
QC Batch Method: EPA 9060
Analysis Description: 9060 TOC Average
Associated Lab Samples: 92279910001, 92279910002,
92279910003, 92279910004, 92279910005, 92279910006, 92279910007,
92279910008
METHOD BLANK: 1275222
Matrix: Solid
Associated Lab Samples:
Blank Reporting
Parameter Units
Result Limit MDL Analyzed Qualifiers
Mean Total Organic Carbon mg/kg
ND 600 300 12/18/15 06:17
LABORATORY CONTROL SAMPLE: 1275223
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Mean Total Organic Carbon mg/kg
120000 119000 99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1275224 1275225
MS MSD
92279910001
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Mean Total Organic Carbon mg/kg 2100
7000 7040 9100 9100 100 99 50-150 0 30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALIFIERS
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
DEFINITIONS
Duke Energy AnalyticalALaRriai'oryervices, Inc.
%py%roe. Suite 100
Huntersville, NC 28078
[phone]
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-G Pace Analytical Services - Green Bay
PASI-O Pace Analytical Services - Ormond Beach
BATCH QUALIFIERS
Batch: ICPM/11350
[1] Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
ANALYTE QUALIFIERS
D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference.
D4 Sample was diluted due to the presence of high levels of target analytes.
D6 The relative percent difference (RPD) between the sample and sample duplicate exceeded laboratory control limits.
H1 Analysis conducted outside the EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
H6 Analysis initiated outside of the 15 minute EPA recommended holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M6 Matrix spike and Matrix spike duplicate recovery not evaluated against control limits due to sample dilution.
N2 The lab does not hold TNI accreditation for this parameter.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
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Duke Energy AnalyticalALaRriacioryervices, Inc.
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Huntersville, NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
Analytical
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92279910001
2015039114
EPA
3050
MPRP/27850
EPA 6010
ICP/16767
92279910002
2015039115
EPA
3050
MPRP/27850
EPA 6010
ICP/16767
92279910003
2015039116
EPA
3050
MPRP/27850
EPA 6010
ICP/16767
92279910004
2015039117
EPA
3050
MPRP/27850
EPA 6010
ICP/16767
92279910005
2015039118
EPA
3050
MPRP/27850
EPA 6010
ICP/16767
92279910006
2015039119
EPA
3050
MPRP/27850
EPA6010
ICP/16767
92279910007
2015039120
EPA
3050
MPRP/27850
EPA 6010
ICP/16767
92279910008
2015039121
EPA
3050
MPRP/27850
EPA 6010
ICP/16767
92279910001
2015039114
EPA 3050
MPRP/27886
EPA 6020
ICPM/11350
92279910002
2015039115
EPA 3050
MPRP/27886
EPA 6020
ICPM/11350
92279910003
2015039116
EPA 3050
MPRP/27886
EPA 6020
ICPM/11350
92279910004
2015039117
EPA 3050
MPRP/27886
EPA 6020
ICPM/11350
92279910005
2015039118
EPA 3050
MPRP/27886
EPA 6020
ICPM/11350
92279910006
2015039119
EPA 3050
MPRP/27886
EPA 6020
ICPM/11350
92279910007
2015039120
EPA 3050
MPRP/27886
EPA 6020
ICPM/11350
92279910008
2015039121
EPA 3050
MPRP/27886
EPA 6020
ICPM/11350
92279910001
2015039114
EPA 7471
MERP/6460
EPA 7471
MERC/6440
92279910002
2015039115
EPA 7471
MERP/6460
EPA 7471
MERC/6440
92279910003
2015039116
EPA 7471
MERP/6460
EPA 7471
MERC/6440
92279910004
2015039117
EPA 7471
MERP/6460
EPA 7471
MERC/6440
92279910005
2015039118
EPA 7471
MERP/6460
EPA 7471
MERC/6440
92279910006
2015039119
EPA 7471
MERP/6460
EPA 7471
MERC/6440
92279910007
2015039120
EPA 7471
MERP/6460
EPA 7471
MERC/6440
92279910008
2015039121
EPA 7471
MERP/6460
EPA 7471
MERC/6440
92279910001
2015039114
ASTM D2974-87
PMST/4161
92279910002
2015039115
ASTM D2974-87
PMST/4161
92279910003
2015039116
ASTM D2974-87
PMST/4161
92279910004
2015039117
ASTM D2974-87
PMST/4161
92279910005
2015039118
ASTM D2974-87
PMST/4161
92279910006
2015039119
ASTM D2974-87
PMST/4161
92279910007
2015039120
ASTM D2974-87
PMST/4161
92279910008
2015039121
ASTM D2974-87
PMST/4161
92279910001
2015039114
EPA 9045
WET/34737
92279910002
2015039115
EPA 9045
WET/34737
92279910003
2015039116
EPA 9045
WET/34737
92279910004
2015039117
EPA 9045
WET/34737
92279910005
2015039118
EPA 9045
WET/34737
92279910006
2015039119
EPA 9045
WET/34737
92279910007
2015039120
EPA 9045
WET/34737
92279910008
2015039121
EPA 9045
WET/34737
92279910001
2015039114
EPA 9056
WETA/53104
92279910002
2015039115
EPA 9056
WETA/53066
92279910003
2015039116
EPA 9056
WETA/53104
92279910004
2015039117
EPA 9056
WETA/53104
92279910005
2015039118
EPA 9056
WETA/53104
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL
Project: J15120373 WEATHERSPOON
Pace Project No.: 92279910
DATA CROSS
Duke Energy AnalyticalALaRriacioryervices,Inc.
�$��inlc&fie. Suite 100
Huntersville, NC 28078
[phone]
REFERENCE TABLE
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method Batch
92279910006
2015039119
EPA 9056
WETA/53066
92279910007
2015039120
EPA 9056
WETA/53066
92279910008
2015039121
EPA 9056
WETA/53104
92279910001
2015039114
EPA 9056
WETA/53103
92279910002
2015039115
EPA 9056
WETA/53099
92279910003
2015039116
EPA 9056
WETA/53103
92279910004
2015039117
EPA 9056
WETA/53103
92279910005
2015039118
EPA 9056
WETA/53103
92279910006
2015039119
EPA 9056
WETA/53099
92279910007
2015039120
EPA 9056
WETA/53099
92279910008
2015039121
EPA 9056
WETA/53103
92279910001
2015039114
EPA 9060
WETA/31737
92279910001
2015039114
EPA 9060
WETA/31738
92279910002
2015039115
EPA 9060
WETA/31737
92279910002
2015039115
EPA 9060
WETA/31738
92279910003
2015039116
EPA 9060
WETA/31737
92279910003
2015039116
EPA 9060
WETA/31738
92279910004
2015039117
EPA 9060
WETA/31737
92279910004
2015039117
EPA 9060
WETA/31738
92279910005
2015039118
EPA 9060
WETA/31737
92279910005
2015039118
EPA 9060
WETA/31738
92279910006
2015039119
EPA 9060
WETA/31737
92279910006
2015039119
EPA 9060
WETA/31738
92279910007
2015039120
EPA 9060
WETA/31737
92279910007
2015039120
EPA 9060
WETA/31738
92279910008
2015039121
EPA 9060
WETA/31737
92279910008
2015039121
EPA 9060
WETA/31738
Date: 12/23/2015 05:19 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
Page 49 of 51

Client Name: '\,-)U
Project #:
Courier: EJ Fed Ex ❑UPS ❑USPS ❑Client
❑Commercial ©Pane ❑Other:
wa#:9z279910
111111111111111111111111
92279910
Custody Seal on Cooler/Box Present? ❑Yes Due— Seals Intact? QY-esf No !:
Packing Material: ❑Bubble Wrap QBubbie Bags ❑None ❑Other:
Thermometer El -TI -50 5
Used: Type of Ice: Mfg ❑&lue ❑None GSatYiples on ice, tooting process has begun
Cooler Temp Corrected (°C): Biological Tissue Frozen? ❑Yes Do. E[NLA—_
Temp should be above freezing to 6`C Correction Factor: 0.0 °C Date and Initials of Person Examining .Conteiits:
USDA Regulated Soil (�water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? aid samples originate from a foreign source (internationally,
❑Yes [}46--� Including Hawaii and Puerto Rico)? []Yes No
If Yes to either question, fill out a Regulated Soil Checklist and include with SCUR/COC paperwork.
Document Name:
Document Revised: MCT2015
aeeAnatyticat
Sample Condition Upon Receipt(SCUR)
Duke EpWgJ �pglytical Laboratory
Document No.:
Issuing Authority: Page OT 62
"
'
F-CHR-CS-003-rev.17
Pace Huntersvifle Quality Office.
Client Name: '\,-)U
Project #:
Courier: EJ Fed Ex ❑UPS ❑USPS ❑Client
❑Commercial ©Pane ❑Other:
wa#:9z279910
111111111111111111111111
92279910
Custody Seal on Cooler/Box Present? ❑Yes Due— Seals Intact? QY-esf No !:
Packing Material: ❑Bubble Wrap QBubbie Bags ❑None ❑Other:
Thermometer El -TI -50 5
Used: Type of Ice: Mfg ❑&lue ❑None GSatYiples on ice, tooting process has begun
Cooler Temp Corrected (°C): Biological Tissue Frozen? ❑Yes Do. E[NLA—_
Temp should be above freezing to 6`C Correction Factor: 0.0 °C Date and Initials of Person Examining .Conteiits:
USDA Regulated Soil (�water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? aid samples originate from a foreign source (internationally,
❑Yes [}46--� Including Hawaii and Puerto Rico)? []Yes No
If Yes to either question, fill out a Regulated Soil Checklist and include with SCUR/COC paperwork.
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Resolution:
Field Data.�Required? ❑Yes ❑No
Date/Time:
Project Manager SCURF Review: Date: 12
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of
hold, incorrect preservative, out of temp, incorrect containers).
Page 50 of 51
COMMENTS:
Chain of Custody Present?
Y
❑N/A
1•
Chain of Custody Filled Out?
Ye
_[]No__
[]NO
❑N/A
2•
Chain of Custody Relinquished?
UYA&— ❑No
❑N/A
3.
Sampler Name and/or Signature on COC?
❑No
❑N/A
4.
Samples Arrived within Hold Time?
❑Xesy El NO
❑N/A
S.
Short Hold Time Analysis (<72 hr)?
❑Yes
❑No
[!U/.X
6.
Rush Turn Around Time Requested?
❑Yes
❑No
❑AI/A
7.
Sufficient Volume?
❑Ytf
❑No
❑N/A
8.
Correct Containers Used?
-Pace Containers Used?
9y9ss
❑Yes
[]No
DNo—
❑N/A
❑N/A
9.
Containers Intact?
EI.YeS-
❑No
El N/A
10.
Filtered Volume Received for Dissolved Tests?
❑Yes
❑No
[jJNI A
11. Note if sediment is visible in the dissolved container
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis Matrix:
Q*e
❑No
❑N/A
12,
All containers needing acid/base preservation have been
checked?
All containers needing preservation are found to be in
compliance with EPA recommendation?
(HNO3, 1-12SO4, HCI<2; NaOH >9 Sulfide, NaOH>12 Cyanide)
Exceptions: VOA, Coliform, TOC, Oil and Grease,
DRO/8015 (water) DOC,LLHg
❑Yes
[]Yes
❑Yes
❑No
❑No
❑No
[gN7A
5]<A
JV NTA
13•
Samples checked for dechlorination
❑Yes
❑No
CI1NX
14.
Headspace in VOA Vials (>5-6mm)?
[]Yes
❑No
WR
15. -
Trip Blank Present?
Trip Blank Custody Seals Present?
Pace Trip Blank Lot # (if purchased):
❑Yes
❑Yes
[]No
[:]No
EJWA
UN
16.
CLIENT NOTIFICATION/RESOLUTION
Person Contacted:
Comments/Resolution:
Field Data.�Required? ❑Yes ❑No
Date/Time:
Project Manager SCURF Review: Date: 12
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of
hold, incorrect preservative, out of temp, incorrect containers).
Page 50 of 51

N
0)
Cn
1}Proje[t Name
AB Groundwater Assessment - Soil
2)Phonr No:
a)CH-t/
A GW
Dukkejy'_+yt�11 Liblg ry F 7
SIBusine- Ur,,t:
CRAM OF CUSTODY RECORD AND ANA_L_Y_S_E_S_R_ EQUEST FORM
syn�erra
Page 1 of 62
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DUKE
Analytical Laboratory Services
` ' - - - - - - - - - - - -
i Work Order
- - Analytical Laboratory Use Only ----------------------------------------
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74)commrnzs Metals: Al, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury, pH
j Anions: Cl, Nitrate -N, SO4 Sediment Specific Parameters: CEC, Particle Size Distribution, Redox Potential
`CRher_z4 HL
'Add. Cos, WIn Apply
IfCi
} •,
Mail Code MG03A2 (Building 7405)
13339 Hagers Ferry Rd
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Maanx: SOILC
13Sample D scription or ID
l`--
Sc_SGCH_ I DISTRIBUTION
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l� * r jjj��� ��, ///
F E l,�( — -
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Huntersville, N. C. 28078
875-5245
- .
'- •Logged Date s
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Santa,., Ongin.6.,l From RI to LA
ORIGINAL to 1118.
COPY to CLIENT
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1
SAMPLE PROGRAM Ground
Water_ NPDES�
1}Proje[t Name
AB Groundwater Assessment - Soil
2)Phonr No:
a)CH-t/
A GW
4)Fax No:
SIBusine- Ur,,t:
6)ProjeCt ID:
7)Mail Coda:
G) Operatinq unit:
9)AcUviry ID
to)Pmcess ID
j=_QA3N: When specific accounting has been established and is not indicated abovo
we need the following: 1) Enter correct accounting in all 5 accounting fcelds above. Or
2) Provide correel aceountinq for Operatinu Unit and Procc°.s lo.
VendaOttier
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i LAB USE ONLY
Matrix
RClinquixnrd 8 Daearrime err irne
�— Plan,
I
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DA'rL
4/29Y1015
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a a N
Pace Cooler Tem
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74)commrnzs Metals: Al, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury, pH
j Anions: Cl, Nitrate -N, SO4 Sediment Specific Parameters: CEC, Particle Size Distribution, Redox Potential
`CRher_z4 HL
'Add. Cos, WIn Apply
F
"L -b ID l
(Sail Srdirnrnt, Ash}
13Sample D scription or ID
Dale Time signature
V f_ I
h- c,_
0
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:Pop
' PO 1142081°Preserv.:t=H
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Preservatives when used must be
added within 15 minutes of sample
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collection
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WATER EQUIPMENT BLANK (1 PER DA
&I C�
GO
21)Rclmquished By DatefTime jr7 r �G- yG, Ace pt By: � a r17
[_. ! /
i LAB USE ONLY
Matrix
RClinquixnrd 8 Daearrime err irne
14Collection Information
C m
N
o
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Ut i
a a N
N r
a W Q
• 48 Hr
74)commrnzs Metals: Al, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury, pH
j Anions: Cl, Nitrate -N, SO4 Sediment Specific Parameters: CEC, Particle Size Distribution, Redox Potential
`CRher_z4 HL
'Add. Cos, WIn Apply
F
"L -b ID l
(Sail Srdirnrnt, Ash}
13Sample D scription or ID
Dale Time signature
V f_ I
h- c,_
0
N Q co
tb
N Q
i
`sem%Y"�
J�'i, 1
- ZO
15
;
C'0"( V6, --Oct '-05 C
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WATER EQUIPMENT BLANK (1 PER DA
&I C�
GO
21)Rclmquished By DatefTime jr7 r �G- yG, Ace pt By: � a r17
[_. ! /
2'Requested Turnaround
RClinquixnrd 8 Daearrime err irne
Rel, s� tl 8� Datrrrimc Accepted By: D tel7ime
•7 pays
Scaled Locked By DatclTimc Srale ock Oprnad a Datetr�me
• 48 Hr
74)commrnzs Metals: Al, Sb, As, Ba, Be, B, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Na, Sr, TI, V, Zn, Mercury, pH
j Anions: Cl, Nitrate -N, SO4 Sediment Specific Parameters: CEC, Particle Size Distribution, Redox Potential
`CRher_z4 HL
'Add. Cos, WIn Apply