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HomeMy WebLinkAboutWQ0004972_Monitoring - 02-2024_20240430Monitoring Report Submittal Permit Number#* Name of Facility:* Month: * February Report Information WQ0004972 Forest Lake RV WWTP Type * Revised - NDMR, NDAR-1, NDAR-2, NDMLR Year:* 2024 Upload Document* 2024_February_Forest Lake_WQ0004972_REV 1.54MB Complete.pdf PDF Only Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-1, NDAR-2, NDMLR, GW-59). Confirmation Email Address: * agrenier@greenerehssolutions.com Name of Submitter: * Amanda Grenier Signature: 6VIO'W ada e*Aw t Date of submittal: 4/30/2024 This will be filled in automatically Initial Review Reviewer: Wanda.Gerald Is the project number correct?* WQ0004972 Is the monitoring report accepted?* Yes No Regional Office* Winston-Salem Reviewer: _anonymous Review Date: 5/20/2024 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB NON -DISCHARGE MONITORING REPORT NDMR Permit No.: WQ0004972 Facility Name: Forest Lake Preserve ELS County: Davie Month: February Year: 2024 PPI: 001 Flow Measuring Point: Parameter Monitoring Point: Parameter Code 50050 00400 50060 70300 00530 00310 31616 00600 00610 00625 00630 00620 00615 00665 00940 Qm �' ~ O ° ° U 0 ° LL a: o H V 2 F L U cap ' a o ~ 7 rn y m c = LL i0 ~ Z 1 6 o E E Q s cc m Y o�o Z ° t- m ._. Z Z M .. Z ' =•. ` Z L° oE -E tW oo ~° a `o U 24-hr hrs GPD su mg/L mg/L mg/L mg/L #/100 mL mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L 1 08:00 5 31,504 6.39 3.6 2 08:00 5 25,446 6.41 4.2 3 21,313 4 20,590 5 08:00 5 21,822 6.53 0.6 6 08:00 5 21,729 6.74 0.7 267 11.2 10.2 7 40.2 35.1 40.1 0.065 7.7 7 08:00 5 24,019 6.9 1.3 8 8:00 5 20,628 6.65 2.4 9 08:00 5 17,598 6.59 2.8 10 30,147 11 27,532 12 08:00 5 41,017 7.1 0.1 13 08:00 5 43,599 7.12 0.3 14 08:00 5 29,529 7.16 1.2 15 08:00 5 22,631 6.55 0.6 16 08:00 5 22,935 6.37 0.8 17 21,490 18 28,987 19 08:00 5 34,800 6.9 0.2 20 08:00 5 26,858 6.97 0.6 21 08:00 5 28,531 6.93 0.6 22 08:00 5 23,723 6.94 0.8 23 11:00 21,425 6.9 0.5 24 34,988 25 30,782 26 08:00 5 23,192 7.26 0.8 27 08:00 5 25,300 7.18 0.8 28 08:00 5 42,084 7.07 1.1 29 08:00 5 47,313 7.21 0.9 30 31 Average: 27,983 1.19 267.00 11.20 10.20 7.00 40.20 35.10 40.10 0.07 7.70 Daily Maximum: 47,313 7.26 4.20 267.00 11.20 10.20 7.00 40.20 35.10 40.10 0.07 7.70 Daily Minimum: 17,598 6.37 0.10 267.00 11.20 10.20 7.00 40.20 35.10 40.10 0.07 7.70 Sampling Type: Monthly Avg. Limit: Daily Limit: LSample Frequency: Continuous 5x/Week 5X/Week Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly Monthly 3X/year Law TLLL Sam Perry (Apr 30, 202 16:38 EDT) DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB Sampling Person(s) Certified Laboratories Name: Sam Perry Name: Name: Greener EHS Solutions, LLC Name: Pace Analytical Does all monitoring data and sampling frequencies meet the requirements in Attachment A of your permit? ❑ Compliant O Non -Compliant If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective action(s) taken. Attach additional sheets if necessary. The Monthly average flow exceeded the permitted flow of 24,400 gpd. The permitted application rate was not exceeded. The flow meter was calibrated on June 27, 2023 and the meter was reading significantly low before the calibration. This was noted on the June 2023 NDMR. The plant is in the process of an upgrade to increase the capacity as well as investigating extraneous flow for 1/1 and leaking fixtures. Lab Qualifiers, February 6, 2024 - Fecal Coliform, D6 - The precision between the sample and sample duplicate exceeded laboratory control limits. TKN, R1 - RPD value was outside control limits. Phosphorus and TKN, M1 - Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. Operator in Responsible Charge (ORC) Certification Permittee Certification ORC: Sam Perry Permittee: MHC TT, LP Certification No.: 1014038 Signing Official: George Gudgeon Grade: SI Phone Number: 919-548-2381 Signing Officials Title: Sr. Vice President Has the ORC changed since the previous NDMR? Phone Number: 312-279-1400 Permit Expiration: 10/31/2027 Saw e 4/29/2024 � 4/30/24 Signature Date Signature Date By this signature, I certify that this report is accurrate and complete to the best of my knowledge. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that all qualified personnel properly gathered and evaluated the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Mail Original and Two Copies to: Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 FORM: NDAR-1 05-16 NON -DISCHARGE APPLICATION REPORT (NDAR-1) Page of DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB Permit No.: WQ0004972 Facility Name: Forest Lake County: Davie Month: February Year: 2024 Did irrigation Field Name: Field Name: Field Name: Field Name: occur Area (acres): 6 Area (acres): Area (acres): Area (acres): at this facility? Cover Crop:Grass/Trees Cover Crop: p� Cover Crop: p� Cover Crop: p: Hourly Rate (in): 0.11 Hourly Rate (in): Hourly Rate (in): Hourly Rate (in): Annual Rate (in): 46.8 Annual Rate (in): Annual Rate (in): Annual Rate (in): Weather Freeboard Field Irrigated? Field Irrigated? Field Irrigated? Field Irrigated? o m 'a O v O CD l6 m Q N F_ 4 :° Q c.� a m °' i N w N Q O_ M v T O. O R 4) 'a E _d _3 o O O' i Q m w E O) 'C i rn >. C R' D O J E rn 3 �` C L R 2 O J a)-0 E. N ' O O CL i Q a� r E ~ .L i > C @@ D O J E rn 7 �' C £@ R 2 0 J 4)7 E 2 = a O Q i Q m w E O) ~ 'C i rn >. C f6 D O J E rn 3 �` C L ' R 2 O J a)-0 2 E ._ ' O O O- i E a, ~ 'C rn _T R O E rn i E' R 2 O °F in ft ft gal min in in gal min in in gal min in in gal min in in 1 C 56 0 2.3' 2 CL 61 0 2.2' 45,617 300 0.28 0.06 3 C 53 0 4 CL 53 0 5 C 56 0 2.5' 54,709 360 0.34 0.06 6 C 50 0 1 3.6' 7 C 51 0 3.5' 8 CL 56 0 3.2' 38,310 240 0.24 0.06 9 CL 54 0 4' 10 CL 67 0 11 R 57 0.25 12 CL 56 0.73 3' 13 C 57 0 2.8' 14 C 59 0 2.5' 48,249 300 0.30 0.06 15 CL 64 0 3.1' 16 CL 55 0 2.9' 17 CL 51 0 18 CL 46 0 19 C 55 0 2.6' 41,549 240 0.26 0.06 20 CL 54 0 3.3' 21 C 55 0 3' 30,549 180 0.19 0.06 22 CL 66 0 3.6' 23 CL 58 0 3.25' 24 C L 54 0 25 C 51 0.5 26 CL 69 1.5 2.6' 37,993 240 0.23 0.06 27 CL 62 0 3.4' 28 CL 67 0 3.2' 29 CL 49 2.75 3' 33,088 240 0.20 0.05 30 PC 0 0 311 CL 1 0 1 0 Monthly Loading: 330,064 2.03 0 0.00 0 0.00 0 0.00 12 Month Floating Total (in): 23.89 FORM: NDAR-1 05-16 NON -DISCHARGE APPLICATION REPORT (NDAR-1) Page of DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB Did the application rates exceed the limits in Attachment B of your permit? Ll Compliant ❑ Non -Compliant Were adequate measures taken to prevent effluent ponding in or runoff from the sites? O Compliant ❑ Non -Compliant Was a suitable vegetative cover maintained on all sites as specified in your permit? O Compliant ❑ Non -Compliant Were all setbacks listed in your permit maintained for every application to each permitted site? O Compliant ❑ Non -Compliant Were all freeboards maintained in accordance with the specified freeboard heights in your permit? O Compliant ❑ Non -Compliant If the facility is non -compliant, please explain in the space below the reason(s) the facility was not in compliance. Provide in your explanation the date(s) of the non-compliance and describe the corrective action(s) taken. Attach additional sheets if necessary. Operator in Responsible Charge (ORC) Certification Permittee Certification ORC: Sam Perry Permittee: MHC TT, LP Certification No.: 1014038 Signing Official: George Gudgeon Grade: SI Phone Number: 919-548-2381 Signing Officials Title: Sr. Vice President Has the ORC changed since the previous NDAR-1? Phone Number: 312-279-1400 Permit Exp.: 10/31/27 Sawn TLL; 4/30/24 Sam Per A r 30 2022r16:38 EDT 4/29/2024 Signature Date Signature Date By this signature, I certify that this report is accurrate and complete to the best of my knowledge. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that all qualified personnel properly gathered and evaluated the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Mail Original and Two Copies to: Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, North Carolina 27699-1617 ):05 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB ,ace - February 19, 2024 Amanda D. Grenier Greener EHS Solutions 21 Selby Ct. Holly Springs, NC 27540 RE: Project: FOREST LAKE- MONTHLY Pace Project No.: 92711960 Dear Amanda Grenier: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on February 06, 2024. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: • Pace Analytical Services - Asheville • Pace Analytical Services - Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com 704-977-0942 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 17 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB ,ace - Project: FOREST LAKE- MONTHLY Pace Project No.: 92711960 Pace Analytical Services Charlotte South Carolina Laboratory ID: 99006 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 South Carolina Laboratory ID: 99006 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 North Carolina Drinking Water Certification #: 37712 North Carolina Wastewater Certification #: 40 CERTIFICATIONS South Carolina Certification #: 99006001 South Carolina Drinking Water Cert. #: 99006003 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Louisiana DoH Drinking Water #: LA029 VirginiaNELAP Certification #: 460221 South Carolina Laboratory ID: 99030 South Carolina Certification #: 99030001 VirginiaNELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 17 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB Pace Analytical Services, LLC �ace- 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: FOREST LAKE- MONTHLY Pace Project No.: 92711960 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92711960001 EFFLUENT SM 9222D-2015 KDF 1 PASI-C SM 2540C-2015 JMH1 1 PASI-A SM 2540D-2015 JMH1 1 PASI-A SM 521OB-2016 MDM 1 PASI-A TKN+NO3+NO2 Calculation MDW 1 PASI-A EPA 350.1 Rev 2.0 1993 NCF 1 PASI-A EPA 351.2 Rev 2.0 1993 MFO 1 PASI-A EPA 353.2 Rev 2.0 1993 NCF 1 PASI-A EPA 365.1 Rev 2.0 1993 Zip 1 PASI-A PASI-A = Pace Analytical Services - Asheville PASI-C = Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 17 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB ,ace ­ ANALYTICAL RESULTS Project: FOREST LAKE- MONTHLY Pace Project No.: 92711960 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: EFFLUENT Lab ID: 92711960001 Collected: 02/06/24 11:25 Received: 02/06/24 12:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MBIO 9222D Fecal Coliform CHT Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015 Pace Analytical Services - Charlotte Fecal Coliforms 7.0 CFU/100 mL 1.0 1 02/06/24 17:58 02/07/24 15:59 2540C Total Dissolved Solids Analytical Method: SM 2540C-2015 Pace Analytical Services -Asheville Total Dissolved Solids 267 mg/L 25.0 1 02/09/24 17:36 2540D Total Suspended Solids Analytical Method: SM 2540D-2015 Pace Analytical Services -Asheville Total Suspended Solids 11.2 mg/L 5.0 1 02/09/24 17:27 5210B BOD, 5 day Analytical Method: SM 521OB-2016 Pace Analytical Services -Asheville BOD, 5 day 10.2 mg/L 2.0 1 02/08/24 07:09 02/13/24 07:31 Total Nitrogen Calculation Analytical Method: TKN+NO3+NO2 Calculation Pace Analytical Services -Asheville Total Nitrogen 40.2 mg/L 0.040 1 02/16/24 14:05 350.1 Ammonia Analytical Method: EPA 350.1 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Ammonia 35.1 mg/L 1.0 10 02/17/24 02:14 7664-41-7 351.2 Total Kjeldahl Nitrogen Analytical Method: EPA 351.2 Rev 2.0 1993 Preparation Method: EPA 351.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Kjeldahl, Total 40.1 mg/L 2.5 5 02/15/24 14:17 02/16/24 04:48 7727-37-9 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Pace Analytical Services -Asheville Nitrogen, Nitrate 0.065 mg/L 0.040 1 02/07/24 01:19 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Pace Analytical Services -Asheville Phosphorus 7.7 mg/L 0.10 2 02/19/2411:31 02/19/2416:47 7723-14-0 Date: 02/19/2024 08:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 17 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB Pace Analytical Services, LLC �ace- 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE- MONTHLY Pace Project No.: 92711960 QC Batch: 830457 Analysis Method: SM 9222D-2015 QC Batch Method: SM 9222D-2015 Analysis Description: 9222D Fecal Coliform(MF) - CHT Laboratory: Pace Analytical Services - Charlotte Associated Lab Samples: 92711960001 METHOD BLANK: 4292376 Associated Lab Samples: 92711960001 Parameter Fecal Coliforms SAMPLE DUPLICATE: 4292377 Parameter Fecal Coliforms Matrix: Water Blank Reporting Units Result Limit Analyzed Qualifiers CFU/100 mL ND 1.0 02/07/24 15:59 92711901001 Dup Units Result Result RPD Qualifiers CFU/100 mL 97.0 70.0 32 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/19/2024 08:09 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 17 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE- MONTHLY Pace Project No.: 92711960 QC Batch: 831333 Analysis Method: SM 2540C-2015 QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92711960001 METHOD BLANK: 4296466 Associated Lab Samples: 92711960001 Parameter Units Total Dissolved Solids mg/L LABORATORY CONTROL SAMPLE: 4296467 Parameter Units Total Dissolved Solids mg/L SAMPLE DUPLICATE: 4296468 Parameter Units Total Dissolved Solids mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 25.0 02/09/24 17:34 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 250 258 103 90-110 92711015024 Dup Result Result RPD Qualifiers 1490 1520 2 SAMPLE DUPLICATE: 4296469 92711696002 Dup Parameter Units Result Result Total Dissolved Solids mg/L 198 203 RPD Qualifiers 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/19/2024 08:09 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 17 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE- MONTHLY Pace Project No.: 92711960 QC Batch: 831331 Analysis Method: SM 2540D-2015 QC Batch Method: SM 2540D-2015 Analysis Description: 2540D Total Suspended Solids Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92711960001 METHOD BLANK: 4296458 Associated Lab Samples: 92711960001 Parameter Units Total Suspended Solids mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.5 02/09/24 17:26 LABORATORY CONTROL SAMPLE & LCSD: 4296459 4297713 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Total Suspended Solids mg/L 250 244 246 98 98 90-110 1 25 SAMPLE DUPLICATE: 4297126 92712235001 Dup Parameter Units Result Result RPD Qualifiers Total Suspended Solids mg/L 3550 3350 6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/19/2024 08:09 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 17 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE- MONTHLY Pace Project No.: 92711960 QC Batch: 830836 Analysis Method: SM 521 OB-2016 QC Batch Method: SM 521OB-2016 Analysis Description: 5210E BOD, 5 day Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92711960001 METHOD BLANK: 4294221 Associated Lab Samples: 92711960001 Parameter Units BOD, 5 day mg/L LABORATORY CONTROL SAMPLE: 4294223 Parameter Units BOD, 5 day mg/L SAMPLE DUPLICATE: 4294224 Parameter Units BOD, 5 day mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 02/13/24 05:49 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 198 224 113 84.6-115 92711922002 Dup Result Result RPD Qualifiers 2.2 2.2 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/19/2024 08:09 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 17 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE- MONTHLY Pace Project No.: 92711960 QC Batch: 832844 Analysis Method: EPA 350.1 Rev 2.0 1993 QC Batch Method: EPA 350.1 Rev 2.0 1993 Analysis Description: 350.1 Ammonia Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92711960001 METHOD BLANK: 4303880 Associated Lab Samples: 92711960001 Parameter Units Nitrogen, Ammonia mg/L LABORATORY CONTROL SAMPLE: 4303881 Parameter Units Nitrogen, Ammonia mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.10 02/16/24 23:12 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 5 5.0 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4303882 4303883 MS MSD 92711832001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 19.5 5 5 24.4 24.6 99 102 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4303884 4303885 MS MSD 92711944001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Ammonia mg/L 2.8 5 5 7.8 7.8 101 101 90-110 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/19/2024 08:09 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 17 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE- MONTHLY Pace Project No.: 92711960 QC Batch: 832576 Analysis Method: EPA 351.2 Rev 2.0 1993 QC Batch Method: EPA 351.2 Rev 2.0 1993 Analysis Description: 351.2 TKN Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92711960001 METHOD BLANK: 4302481 Associated Lab Samples: 92711960001 Parameter Units Nitrogen, Kjeldahl, Total mg/L LABORATORY CONTROL SAMPLE: 4302482 Parameter Units Nitrogen, Kjeldahl, Total mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.50 02/16/24 02:39 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 10 9.7 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4302755 4302756 MS MSD 92712559001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 0.72 10 10 10.5 28.9 98 282 90-110 94 M1,R1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4302757 4302758 MS MSD 92712559002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Kjeldahl, Total mg/L 3.7 10 10 13.4 13.5 96 97 90-110 1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/19/2024 08:09 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 17 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE- MONTHLY Pace Project No.: 92711960 QC Batch: 830491 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92711960001 METHOD BLANK: 4292525 Associated Lab Samples: 92711960001 Parameter Units Nitrogen, Nitrate mg/L LABORATORY CONTROL SAMPLE: 4292526 Parameter Units Nitrogen, Nitrate mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.040 02/07/24 01:07 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 1.5 1.5 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4292527 4292528 MS MSD 92711832001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Nitrogen, Nitrate mg/L ND 1.5 1.5 1.5 1.5 98 101 90-110 4 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/19/2024 08:09 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 17 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB Pace Analytical Services, LLC �ace­ 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: FOREST LAKE- MONTHLY Pace Project No.: 92711960 QC Batch: 832923 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Laboratory: Pace Analytical Services -Asheville Associated Lab Samples: 92711960001 METHOD BLANK: 4304132 Associated Lab Samples: 92711960001 Parameter Units Phosphorus mg/L LABORATORY CONTROL SAMPLE: 4304133 Parameter Units Phosphorus mg/L Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 0.050 02/19/2413:46 Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 2.5 2.6 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4304134 4304135 MS MSD 92711774001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 0.27 2.5 2.5 2.7 2.7 97 96 90-110 1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 4304136 4304137 MS MSD 92711801001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Phosphorus mg/L 10.3 2.5 2.5 13.3 13.5 120 128 90-110 2 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/19/2024 08:09 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 17 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB ,ace ­ QUALIFIERS Project: FOREST LAKE- MONTHLY Pace Project No.: 92711960 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as "Total" may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TN -The NELAC Institute. ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/19/2024 08:09 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 17 DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB ,ace - QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: FOREST LAKE- MONTHLY 92711960 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92711960001 EFFLUENT SM 9222D-2015 830457 SM 9222D-2015 830458 92711960001 EFFLUENT SM 254OC-2015 831333 92711960001 EFFLUENT SM 2540D-2015 831331 92711960001 EFFLUENT SM 521OB-2016 830836 SM 521OB-2016 830896 92711960001 EFFLUENT TKN+NO3+NO2 833012 Calculation 92711960001 EFFLUENT EPA 350.1 Rev 2.0 1993 832844 92711960001 EFFLUENT EPA 351.2 Rev 2.0 1993 832576 EPA 351.2 Rev 2.0 1993 832840 92711960001 EFFLUENT EPA 353.2 Rev 2.0 1993 830491 92711960001 EFFLUENT EPA 365.1 Rev 2.0 1993 832923 EPA 365.1 Rev 2.0 1993 833334 Date: 02/19/2024 08:09 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 17 101-_l I DG#_Title: ENV+KIYI-HUN1-0083 v03_5ample Condition Upon Keceipt DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB Effective Date: 11/29/202-3 4:16:30 PM Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville E Raleigh❑ Mechanicsville❑ Atlanta❑ Kernersville❑ • Client Name: -Uponc-r S S fib 5 Project #: WO#:92711960 Courier. ed Ex L1 UPS Ll USPS Client 111111111111 IIII I II III ❑ Commercial Pace ❑ Other: Custody Seal Present? ❑ Yes El No Packing Material: ❑ Bubble Wrap Thermom er• ,,��,,// 92711960 Seals Intact? El Yes ❑No IJN/A Date/Initials Person Examining Contents-, ! �� Bubble Bags ❑ None ❑ Other Biological Tissue FF zen? ❑ Yes ❑ No L�J N/A KI IR Gun ID: 9�T4� _ Type of Ice: Wet El Blue Correction Factor: ] Cooler Temp: «' V Add/Subtract (°C) �' I C. Cooler Temp Corrected (° USDA Regulated Soil ( Ed N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check mancl? F1 Yes n Nn ❑None Temp should be above freezing to 6°C ❑ Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, includine Hawaii and Puerto Ricol? MYPS ❑No Comments/Discrepancy: Chain of Custody Present? Yes ❑ No ] N/A 1. Samples Arrived within Hold Time? ❑ No ❑ N/A 2. Short Hold Time Analysis (<72 hr.)? ,2Yes ICJ Yes ❑ No ❑ N/A 3. Rush Turn Around Time Requested? ❑ Yes 0 No ❑ N/A 4. Sufficient Volume? Mes Cl No ❑ N/A S. Correct Containers Used? Pace Containers Used? (eyes E Yes [I No ❑ No ❑N/A ❑ N/A 6. Containers Intact? Yes ❑ No ❑ N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes e-No ❑N/A 8. Sample Labels Match COC? -Includes Date/Tme/ID/Analysis Matrix: (�� es "" r ❑ No ❑ N/A 9. Headspace in VOA Vials (>5-6mm)? ❑ Yes ClNo U✓ N/A 10. Trip Blank Present? TripBlank Custody Seals Present? ❑Yes ❑ Yes ❑No O No `N/A [� N/A 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: Project Manager SRF Review: Lot ID of split containers: Date/Time: Date: Date: Field Data Required? U Yes U No Qualtrax ID: 69614 Paae 1 of 2 Page 15 of 17 �I Jnnn I V VTr_ a.c. �.�. . .�In-..v.� .-v vv.r• vv6_�7anIF.JIG LVIIV Ill V11 uf,/Vll RCI.Clt.1l DocuSign Envelope ID: E2B64DB8-9491-48F9-B05D-A55CB17A27FB I I - Effective Date: 11/14/2022 *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC. LLHS **Bottom half of box is to list number of bottles ***Check all unpreserved Nitrates for chlorine Projec WO#:92711960 PM: MWB Due Date: 02/20/24 CLIENT: 92-Greener 6, cJ 6r Q V V A A O U Z N Z Q z � � M M Z .� a C a C Z) n C D v n C O N = O Z 2 < N ry z l) diV a C O U M 2!= v C a`i V i a H N = a N i _ Q Z C = Z ` Z u ? N 'A A U V Q c \ ? 0 m v 2, y O. C O Y ry = a- Q Z u N ' a Q Z u .., a v O N S Z v n C ,n C O Z v O. C O Iv J Inn N I-1 io a J o tf1 N N moo a J C) O l,1 " va d °= — ry a J In N ,..I a J o N ry a J nn N .-I a n N .-I C, a �S E Q °' Q = E Q J o a E Q ° — .-, E Q J on In N a Q E O V Q > E O V O > E O ? OY` > E O O < > E 0 V a E O N 4 ° N E `� N Ill E O n' E E Q of O 0 � N E O N Ea Q E O Q y _ a m a. m N a. m a in N a co Z a m N a in Co n0 , m 3 n t7 a N to a M ID a I�1 0 a M 0 a a% to o CI t9 o C1 0 > M 0 > a% 0 a r• a. le .Mr t7 > r, 1~A a V1 N N a V1 ,V M a m O 0 a = %n > Cl 0 o 2 i \ 3 NI I N 5 1 6 2 i l 8 \ — 9 10 1112 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot # rJuie. Whenever ureic Is a discrepancy anecung iqortn Carohna compliance samples, a copy of this form will be sent to the North Carolina DENR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Qualtrax ID: 69614 Page 2 of 2 Page 16 of 17 Pace` Location Requested (City/State): Pace Analytical Charlotte CHAIN -OF -CUSTODY Analytical Request Document LAB USE ONLY- Affix Workorder/Login Label Here ace4 9800 Kincey Ave. Suite 100, Huntersville, NC 28078 Chain -of -Custody is a LEGAL DOCUMENT - Complete all relevant fields cti0 gip.• / loriTI, Company Name: Greener EHS Solutions Street Address: 192 Thousand Trail Dr., Advance, NC 27006 contact/Report To: Amanda Grenier Phone u: (919)356-6509 E-Mail: s . Scan QR Coddtions Cc E-Mall: Customer Project n; Specify Container Size " "Container 5i2a: (1) 1L, (2) 500mL, (3) 250mL, (4) Project Name: Forest Lake- Monthly 1 y 12SmL, IS) 100m1, (6) 40n,:v�. �r'ae. (8) TerraCore, (9) 90mL, (10) Other Invoice To: �' . Invoice E-Mall: Identify Container Preservative Type" ••• Preservative Types: (1) None, 12) HNO3, (31 Site Collection Info/Facility ID (as applicable): Purchase Order p (if H2504, 14) NCI, 15) Mott, (6) Zn Acetate, (7) applicable): NaHSO4, 181 Sod. Thiosulfate, (9) Ascorbic Acid, (10) Analysis Requested MCOH, 1111 Other Quote 4: Prof. Mgr: Matthew Brainard a - Time Zone Collected: [ ] AK ( ] PT [ ] MT [ ] CT [ JET County/ State origin of sample(s): North Carolina Data Deliverables: Regulatory Program (DW, RCRA, etc.) as applicable: Reportable [ ] Yes [ ]NO AcctNum / Client ID: ( ) Level II I ] Level III I ] Level IV U Rush (Pro -approval required): DIN PWSID g or WW Permit R as applicable: p` Table R: I I Same Day [ I 1 Day I ] 2 Day ( ] 3 Day [ ] Other Z N E [ ) EQUIS o ti Date Results Field Filtered (if applicable): [ ] Yes [ ] No Profile /Template: e E Other Requested: Analysis: ii H T E o "d a)Water on 14849-8 • Matrix Codes (Insert in Matrix box below): Drinking Water (DWI, Ground (GW), Waste Water (WW), Product (P), Sail Solid (SS), Oil OL), Wipe (WP), Tissue TS), Bioassay Prelog /Bottle Ord. ID: B , Vapor IV), Surface Water SW ,Sediment SEO Sludge SL Caulk CK , Leachate (ILL), Biosolid BS , Other (Or)0 E 11' m _° Z 1162100 d • comp p / Composite Start Collected or Composite End p Res. Chlorine Customer Sample ID Matrix Grab Cont. u (n r/1 Sample Comment p a Date Time Date Results Units < m Li z fN.. Time `H� �) m LL n N Q m to to Q to to 0 m LL OD 0 v p M tional Instructions from Pace•: Collected By: SC�y�1 Customer Remarks /Special Conditions /Possible Hazards: (Printed Name) l L��y oD m Slgnatur �-='--� / g Cooloa: Thefmometer to: Correction to VC); Obi. Temp. (*Cl Corrected Temp. ('Cl On Ice: 8 m ulfitCby(]Company: (Sign Date/Time:: /� - Received b a urel Date/Time: /'t Tracking Number: C14 R uished Me) e) 0_ ir� Da /Timne, gv M `J t •/ p n : (SignaI a /• \; DateJTi e: �l 1563 j63 Delivered by: I ] In. Person (Courier _ N `/ i GC. R O Company:15ignalure) Date/nme: Received by/Company:(Signature) Dal,/The: (D [ ] FedEX I ] UPS ( I Other R C wished by/Company: (Signature) Dale/Time: Received by/Company: (Signature) Date/Time: Lu Page: of c 5 Flitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace* Terms and Conditions found at https://www.pacelabs.com/resource-library/resource/pace-terms-and-conditions/ ENV-FRM-CORQ-0019_v02_110123 U 0