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HomeMy WebLinkAboutWQ0004609_2023 Residual Annual Report_20240228 (2)Initial Review Reviewer nathaniel.thorn burg Is this submittal an application? (Excluding additional information.) * Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2023 Permit Number (IR) * W00004609 Applicant/Permittee Wayne Farms LLC Email Notifications Does this need review by the hydrogeologist? * Yes U No Regional Office Winston-Salem CO Reviewer Admin Reviewer Wanda Gerald Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. Name* Lysa Finnerty Email Address* Ifinnerty@SYNAGRO.com Project Information ......................... Application/Document Type* New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Phone Number* 4105376150 Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, N DAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High -Rate Infiltration Other Wastewater Reclaimed Water Closed -Loop Recycle Residuals Single -Family Residence Wastewater Other Irrigation Permit Number:* WQ0004609 Has Current Existing permit number Applicant/Permittee Address* 435 Williams Court, Ste 100, Baltimore, MD 21220 Facility Name* Wayne Farms Class B Residuals Program Please provide comments/notes on your current submittal below. Submission of the 2023 Annual Report for Wayne Farms, L.L.C. - Dobson, NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. (Application Form, Engineering Plans, Specifications, Calculations, Etc.) Wayne Farms NC 2023 Annual Report FINAL.pdf 9.76MB Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Alva �Cit'wt%tl� Submission Date 2/28/2024 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 28, 2024 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2023 Annual Report for Permit No. WQ0004609 Dear NCDEQ: SYNAGRO Synagro is submitting an electronic copy of the above referenced report on behalf of Wayne Farms, L.L.C.-Dobson, NC. If you have any questions or need additional information, please do not hesitate to contact Matthew Wooten at (336) 386-5822 or Alex Fox at (704) 881-3429. Sincerely, 01171 Y--�m Derrick Shivar Environmental Compliance Manager Enclosures cc: Matthew Wooten, Wayne Farms, L.L.C.-Dobson Alex Fox, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD WAYNE FARMS, L.L.C. , NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0004609 2023 ANNUAL REPORT Wayne Farms, L.L.C. - Dobson, NC Residuals Land Application Program 2023 Annual Report TABLE OF CONTENTS 1. Certification Form & Annual Operations Summary 2. Annual Residual Sampling Summary Forms 3. Annual Land Application Field Summary Forms 4. TCLP Analysis 5. Control of Possible Nuisance Conditions 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: WQ000460 County S� Year 2023 Facility Name (as shown an permit) Wayne Farms NPDES No. NG0006548 Land Application Operator 5vnaaxa Phone# (336) 998-715.0 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO_ If NO, ship Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A —Residuals application Strrnmarv: Total number of application fields in the permit: 26 Total number of fields utilized for land application during the year: 3 Total amount of dry tons applied during the year for all application sites; 6771 Total number of acres utilized for land app] ication during the year: 34.10 Part B — Annual Co liancc Staterttonv Facility was compliant during calendar year = with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality 2L A'ES NO. If no, please provide a written desetiption why the facility was not compliant, the dates, and explain corrective action taken. l . Only residuals approved for this permit were applied to the permitted sites. 2. Soil pli was adjusted as specified in the permit and time was applied (if needed) to achieve a soil plq, of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the pass calendar year and three (3) copies of I aboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3 ) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15,A, NCAC 02T. I 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .I 105(b) (APpticable to 40 CFR Part 503 regulated facilities). 7_ All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in I SA NCAC 02T .l 111 were complied with (applicable to 40 CFR Part 503 regulated facilities). 9_ All operations and maintenance requirements in the permit were complied with or, in the case of deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remudiations. 11. 'Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals froth the application sites onto adjactrtt property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, sander penalty of law, that the above information is, to the best of my lmawledge and belief, true, accurate, and complete. l am aware that there are significant penalties for submitting ",e information, including the possibility of fines arid imprisonment for knowing violations," Matthew Wooten Co: alex Manager Petmittee Name and Title (type or print) Signature of Preparer* Date (if different from Permittee) dy Signature P 'ttae Date 02101 /2024 a of d Applier Date (if dif t from Pe ee and Preparer) *Prepamr is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (2b) DFNR FORM ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2023 - 12/31/2023 WAYNE FARMS, L.L.C., NC WAYNE FARMS LLC, NC FOOD PROCESSING LIQUID MONTH/YEAR July 2023 August 2023 IEel /_1I Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards Report Date: 1/29/2024 4:06:15 PM AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS 396,800.00 G 48.15 D 43.67 161,200.00 G 19.56 D 17.74 558,000.00 G 67.71 D 61.41 SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Ploase note that your permit may contain additional parameters to be analyzed. The parameters can be reporter! in FORM RS8F - B WQ Permit Number: WQ0004609 Laboratory: Facility Name: WAYNE FARMS, L.L.C.. NC PACE ANALYTICAL Residual Source WO # or NPDES#: NC0006548 WWTP Name: WAYNE FARMS L.L.C. Residual Analysis Data Product Type FPLIQ Sample or Composite Date 01/12/23 Parameter (mglkg dry weight) Ceiling Conc. Limit Percent Solids (°l°) NA 2.91 Arsenic 75 <2.7 Cadmium 85 <0.67 Copper 4300 390 Chromium NA 13 Lead 840 6A Mercury 57 <0.64 Molybdenum 75 12 Nickel 420 18 Selenium 100 6 Zinc 75.00 590 Total Phosphorus NA 26000 T€CN NA 84000 Ammonia -Nitrogen NA 3900 Nitrate and Nitrite NA 153.5 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under n-ry direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fin s and Imprisonment for knowing viol lions," `t 2/28/2024 Signature of. Preparer' Date 'Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) r)rNR FARM RSSF (1212006) Printed: VZW2024 4,55:02 PM For: 2061 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Alumber: WQ000460.9 Facility Name: WAYNE FARMS, L.L_C.. NC Residual Source NPDES # or WQ#: NCO006548 WWTP Name: WAYNE FARMS L.L.C. Residual Analysis Data Product Type FPLIQ Sample or Composite Date 01/12/23 Parameters (mglkg dry weight) Aluminium 3200 Calcium 16000 Magnesium 15000 pM (s.u.) 6.50 Potassium 7500 Sodium 3600 PAN 26134 SAIL (Ratio) 0.8340 Laboratory: PACE ANALYTICAL "I certify, under pertally of law, that this document was prepared under my direction or supervision in accordlance with a system designed to assure that qualified personnel properly gathered and evaluated the Information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations,' 2/28/2024 Signature of Preparer Date 'Prewar is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) Printed: 1129/2024 5:00:00 PM For: 206101 I]FNR FORM RSSF-B (1212006) 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Wayne Farms Lot Number:YA12101 Date Completed:02/02/2023 Project Manager:Lucas Odom E01, I , W101 1 M, � 02/02/2023 4:10 PM Approved and released by: Project Manager I: Kayla S. Holliday Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: YA12101 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight unless flagged with a "W" qualifier. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvww.pacelabs.com Page 2 of 7 Client:Synagro Laboratory ID:YA12101-001 Description: WAYNE FARMS Matrix: Solid Date Sampled:01/12/2023 0600 % Solids: 2.91 01/16/2023 1842 Date Received:01/12/2023 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 01/16/2023 1842 TAD 65010 2 350.1 (Ammonia - N ) 350.1 5 02/01/2023 1215 CMM 66110 1 (Nitrate - N ) 353.2 1 01/26/2023 1150 CMM 66119 1 (Nitrite - N ) 353.2 1 01/26/2023 1150 CMM 66116 1 (Phosphorus) 365.1 25 01/16/2023 1846 DMA 01/16/2023 0859 64846 1 (Soil pH meas) 9045D 1 01/17/2023 1208 BMG2 64825 1 351.4 (TKN) 351.2 5 01/18/2023 1813 DMA 01/17/2023 1258 64991 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 2.91 % 1 Ammonia - N (gas diffusion) 350.1 3900 170 89 mg/kg 2 Nitrate - N (soluble) 353.2 150 6.9 0.92 mg/kg 1 Nitrite - N (soluble) 353.2 3.5 J 6.9 0.90 mg/kg 1 Phosphorus 7723-14-0 365.1 26000 4300 860 mg/kg 1 Soil pH measured in water @ 12.5 ° C 9045D 6.5 su 1 TKN 351.2 84000 8600 4300 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 01/14/2023 1428 MRW2 01/14/2023 1025 64810 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 2.7 0.64 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 01/18/2023 0038 JMH 01/17/2023 0843 64804 2 3050B 601OD 1 01/19/2023 0458 JMH 01/17/2023 0843 64804 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 3200 210 80 mg/kg 1 Arsenic 7440-38-2 6010D ND 8.0 2.7 mg/kg 1 Cadmium 7440-43-9 6010D ND 2.7 0.67 mg/kg 1 Calcium 7440-70-2 6010D 16000 2700 330 mg/kg 1 Chromium 7440-47-3 6010D 13 5.3 1.3 mg/kg 1 Copper 7440-50-8 6010D 390 5.3 2.4 mg/kg 1 Iron 7439-89-6 6010D 9300 53 24 mg/kg 1 Lead 7439-92-1 6010D 6.4 5.3 2.4 mg/kg 1 Magnesium 7439-95-4 6010D 15000 2700 330 mg/kg 1 Manganese 7439-96-5 6010D 710 8.0 3.2 mg/kg 1 Molybdenum 7439-98-7 6010D 12 J 21 5.3 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory ID:YA12101-001 Description: WAYNE FARMS Matrix: Solid Date Sampled:01/12/2023 0600 % Solids: 2.91 01/16/2023 1842 Date Received:01/12/2023 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 01/18/2023 0038 JMH 01/17/2023 0843 64804 2 3050B 6010D 1 01/19/2023 0458 JMH 01/17/2023 0843 64804 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 6010D 18 J 21 5.6 mg/kg 2 Potassium 7440-09-7 6010D 7500 2700 330 mg/kg 1 Selenium 7782-49-2 6010D 6.0 J 11 4.3 mg/kg 1 Sodium 7440-23-5 6010D 3600 2700 330 mg/kg 1 Zinc 7440-66-6 6010D 590 27 6.7 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES, LLC q2 .13 a £ Q a, at r d S e`1 3 z y 1 C rn Q T{'7 n •a z 41 ❑ o x rL E yyFFL [0 9! LL s 1, i7 Q V � 47 � a rt :z a z S' rA C dC Ml P M z _ ri} G i y Lu Tl i5h Y Q � E R • C 1 t' & C � Q } {i 1 V} C G p� Q O � G :l u F o I M E u iF , h E i m dF ]P M O LK .CL � L? I I 5, I m m .. x _ Or � � C;LU J a ' ' 4l C J � r QI U f � � W 1J {Ifl 0 O f Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 PACE ANALYTICAL SERVICES, LLC DC# TEt1e. ENV-FCRA+I.1NCf]L-0286 v4�_Samp:es ltetei�# �hackl�t [SR�I Effective IDa"- 8f 2 f 2O22 fir, ample Receipt Checklist (SRC) C-Nera: R'�WACrPO Cnplerlilsl ctc�lUy�'(latc: iS1t�t + hlr12+23 Loth: YAI-41(-1 c Yes WNo 1. NYem Coto 'sells lireselit. ol) the Uti-x,ln? Y rs lea .e N 2 _ If cws si als -1hTre reseui, wcrz ilttact and ruklirolacn? pH Strip ID" "T' (IIIOTi±le Strip Ili' ]YA 1-ff.kd by, Nk OI'i ulal tt3n rlitlure 11 oii rer� 1 } Dr —rived corrected ten W11 RCCip( °� Mid Snap-01.1, ID: �- 2c•�r � � P= � 1P { ) ]]peratxlrc I NA }7:.k q NA INA hlcthod: 7jFenlpsaafw-c R1MkF]APt i1Et Botdts IRCTm ID; 8 W Gin C;ortlecifon Factor: �c Method of Loalm t- ❑, WC( ICe Lj Ic - Packq E] DE he N� e $ �144 �]1 A ] Wcre all coolers xeoaved aF rw below 6,0'U? If no, was Plojec> NIW]Hgrr IlalJfted? Pl4i WAR Otificrt by; phom f rrna el j+ face-w lace CUE& (RIC). Ycs tic, ,/ _ 4, Is dic cammircial co"ier's pauking slip amched to this form^ yef No 5- Were etcmlodyrrncerl111ca (rrlinquislicd/m rived) follvtvod? yrs Ala 6, 11Vere satnpleMi hsicd un the C.AO and ali mnil;le Coiraimers? 7, VIFHs COLLccCtolE dark bole lisEcd 4]i tl]c {'t7{'. aild all f°d11g)le Coftaiiim? ,l YLn D No ycs A rO . Did aU onotaiur4 laWiufOM1aLxm (1u, date, time} agce wiTh dic ("oc? Ycs ]NoIFIV, I .Were tuts to br crformed listcd @n the COC-? x ©Yes EjNu 10. Did all uumples miiwin fc.proper colltttims far each Teat 31arlAn iil: p(A oandidon f1TnlmEi,;.n, fibs mE, rtc-)? '0' ym NO 11. Wns adei]etate smwle volxmw avaffablc? Y cs NO l2.V(;1C all _W_111lFeS rccej%Td'%jlll.ill the lloldtlrg Lni1C. or d 8 hour._ whirlimr cooees WJ3rea MNo 13. WM ali samples coutaims ruruuuCt-d f`or? (Nc? 1ii155n1�2titeS'1 Q 5 �I TO 1- Were'O_ 801C rind 1QY-I JS snlEttr]c.? lice (]f bubL�Ecs ?"pea-sie" {;}."ai 4'ltvi ila diaA ,1 t,:) ru anyi7f the VOA vie]O Yes lS. -Wriz all J)RO1merFdsfnu4jcuj sm1ples Im-civerl V a pH of < 2? NO V A 7 _; J_JNO J,f A l6- Wcrc all cyniilc :, i s r€ceiwd at i pH> 32 and Sulfide samu[cs received At a plT 7 ���5 � No �NA 17. WcEr a AlYjl 1a NkII 1r1lc auideJpJEella S.I �G B.a ( {t.5m€`L) sal]] lus rrcc a a irhial chladne? 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Cluaftr3x Il? 5 3b0 Race",An0Mica I Services, LLC Page 1 of I Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 SECTION 3 FACILITY NAME: WAYNE FARMS, L.L.C., NC LAND OWNER: BEN WATSON OPERATOR: BEN WATSON CROP 1 NAME: FESCUE PASTURE (FSP) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: W00004609 FIELD#: NC-SU-00022-0-0001- ANNUAL DRY TONS APPLIED: 27.84 SITE #: NC SU 00022 PREDOMINANT SOIL SERIES: CLIFFORD CROP 1 MAX. PAN: 151 CROP 2 NAME: ACRES UTILIZED: 12.8 ACRES PERMITTED: 12.8 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 7/20/2023 43,400.00 (G) 2.910 0.411 WFFPL DRY 0-<1/2"" SUR 0.5 0.30 84,000.00 3,900.00 153.50 21.505 FSP 7/21/2023 80,600.00 (G) 2.910 0.764 WFFPL DRY 0-<1/2" SUR 0.5 0.30 84,000.00 3,900.00 153.50 39.938 FSP 7/25/2023 68,200.00 (G) 2.910 0.647 WFFPL DRY 0-<1/2"" SUR 0.5 0.30 84,000.00 3,900.00 153.50 33.793 FSP 7/26/2023 37,200.00 (G) 2.910 0.353 WFFPL DRY 0-<1/2"" SUR 0.5 0.30 84,000.00 3,900.00 153.50 18.433 FSP Jul-23 229,400.00 (G) "" Total 113.669 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.012 0.003 1.696 0.057 0.028 0.003 1.052 0.078 0.026 2.566 113.088 Date Lbs/Ac Cumulative Ibs/acre Applied 0.121 0.026 4.885 0.216 0.103 0.008 0.160 0.260 0.158 9.201 Permit PAN Limit (Ibs/acre) 1st Crop 151 Federal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 I ( 267.9 1 15.0 375.0 1 89.0 1 2,500.0 WFFPL = WAYNE FARMS LLC, NC FOOD PROCESSING LIQUID " I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties,�ing false i tion, including the possibility of fines and imprisonment for ]mowing violations." �S GNATURE OF LAND APPLIER DATE�� NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/29/2024 DENR FORM FSF (12/2006) Facility Name: Permit #: Operator: Acres Used: 12.80 ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): WAYNE FARMS, L.L.C., NC W00004609 Cation Exchange Capacity (non 503 only): BEN WATSON BEN WATSON Predominant Soil Series: Owner: Acres Permitted: 12.80 Site #: Field #: NC SU 00022 27.84 CLIFFORD NC SU 00022 0001 Source WFFPL Sample or Composite Date 1 1/12/23 2 3 4 5 6 7 8 9 10 11 12 % Solids 2.91 Arsenic 2.700 Cadmium 0.670 Copper 390 Chromium 13.00 Lead 6.40 Mercury 0.640 Molybdenum 12.00 Nickel 18.00 Selenium 6.00 Zinc 590 Total Phosphorus 26000 Annual Heald Metal Field Loadings (Calculated in Ibs/acre): Source WFFPL Total DT/Ac. / App.Event 1 2.17 2 3 4 5 16 7 8 9 10 11 12 Totals Arsenic 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Cadmium 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Copper 1.696 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 1.696 Chromium 0.057 0.000 0.000 0.000 0.000 0.000 -' 0.000 0.000 0.000 0.000 0.000 0.000 0.057 Lead 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.028 Mercury 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molybdenum 0.052 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.052 Nickel 0.078 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.078 Selenium 0.026 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.026 Zinc 2.566 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.566 Total Phosphorus 113.088 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 113.088 "1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significa p lties for submitti g false information, including the possibility of fines and imprisonment for knowing violations". '2-,20-�u Signature of Land Applier Date DENR FORM MFLSF (1212006) FACILITY NAME: WAYNE FARMS, L.L.C., NC LAND OWNER: BEN WATSON OPERATOR: BEN WATSON CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: WQ0004609 FIELD#: NC-SU-00022-0-0002- ANNUAL DRY TONS APPLIED: 15.80 SITE #: NC SU 00022 PREDOMINANT SOIL SERIES: CLIFFORD CROP 1 MAX. PAN: 209 CROP 2 NAME: ACRES UTILIZED: 7.6 ACRES PERMITTED: 7.6 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Amount I UOM Crop 1 Crop 2 Crop 1 Crop 2 7/28/2023 86,800.00 (G) 2.910 1.386 WFFPL DRY 0-<1/2"" SUR 0.5 0.30 84,000.00 3,900.00 153.50 72.437 FSH Jul-23 86,800.00 (G) 8/2/2023 43,400.00 (G) 2.910 0.693 WFFPL DRY 0-<1/2"" SUR 0.5 0.30 84,000.00 3,900.00 153.50 36.219 FSH Aug-23 43,400.00 (G) I 1 1 1 1 1 i otal 2.079 Total 108.656 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.011 0.003 1.622 0.054 0.027 0.003 0.050 0.075 0.025 2.453 108.101 Date Lbs/Ac Cumulative Ibs/acre Applied 0.046 0.011 2.807 0.148 0.060 0.005 0.113 0.167 0.078 5.200 Permit PAN Limit (Ibs/acre) 1st Crop 209 Federal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 267.9 15.0 375.0 1 89.0 1 2,500.0 WFFPL = WAYNE FARMS LLC, NC FOOD PROCESSING LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel property gathered and evaluated the information submitted. I am aware that there are significant pen i for submitti false information, including the possibility of fines and imprisonment for knoowingg violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/29/2024 DENR FORM FSF (12/2006) Facility Name Permit #: Operator: Acres Used: 7.60 ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): WAYNE FARMS, L.L.C., NC W00004609 Cation Exchange Capacity (non 503 only): BEN WATSON BEN WATSON Predominant Soil Series: Owner: Acres Permitted: 7.60 Site #: Field #: NO SU 00022 15.80 CLIFFORD NO SU 00022 0002 Source WFFPL Sample or Composite Date 1 1112/23 2 3 4 5 6 7 8 9 10 11 12 Solids 2.91 Arsenic 2.700 Cadmium 0.670 Copper 390 Chromium 13.00 Lead 6.40 Mercury 0.640 Molybdenum 12.00 Nickel 18.00 Selenium 6.00 Zinc 590 Total Phosphorus 26000 Annual Heavv Metal Field Loadinas (Calculated in Ibs/acrel: Source WFFPL Total DT/Ac. / App.Event 1 2.08 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Cadmium 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Copper 1.622 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.622 Chromium 0.054 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.054 Lead 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.027 Mercury 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molybdenum 0.050 0.000 0.000 0.000 0.000 0.000 0:060 0.000 0.000 0.000 0.000 0.000 0.050 Nickel 0.075 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.075 Selenium 0.025 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.025 Zinc 2.453 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.453 Total Phosphorus 108.101 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 108.101 "I certify, trader penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant n ties for submitting Ise information, including the possibility of fines and imprisonment for knowing violations". 2 av-.2 Signature of Land pplier Date DENR FORM MFLSF (12/2006) FACILITY NAME: WAYNE FARMS, L.L.C., NC LAND OWNER: MAX & PEGGY WALL OPERATOR: MAX WALL CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WO PERMIT #: W00004609 FIELD#: NC-SU-00023-0-0001- ANNUAL DRY TONS APPLIED: 24.08 SITE M NC SU 00023 PREDOMINANT SOIL SERIES: BRADDOCK CROP 1 MAX. PAN: 247 CROP 2 NAME: ACRES UTILIZED: 13.7 ACRES PERMITTED: 13.7 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Amount I UOM Month Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 7/27/2023 80,600.00 (G) 2.910 0.714 WFFPL DRY 0-<1/2"" SUR 0.5 0.30 84,000.00 3,900.00 153.50 37.314 FSH Jul-23 80,600.00 (G) 8/1/2023 62,000.00 (G) 2.910 0.549 WFFPL DRY 0-<1/2" SUR 0.5 0.30 84,000.00 3,900.00 153.50 28.703 FSH 8/2/2023 55,800.00 (G) 2.910 0.494 WFFPL DRY 0-<1/2" SUR 0.5 0.30 84,000.00 3,900.00 153.50 25.833 FSH Aug-23 117,800.00 (G) Ibs/acre Applied tive Ibs/acre Applied 1st Crop AS CD CU 0.010 0.002 1.371 0.120 0.026 4.573 CR I PB HG MO NI SE 0.046 0.023 0.002 0.042 0.063 1 0.021 0.207 0.099 0.007 1 0.153 1 0.247 1 0.155 Total 91.850 0.000 ZN IP Lime Applied 2.074 91.380 Date Lbs/Ac 8.754 247 Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1 1,339.0 267.9 1 15.0 375.0 89.0 1 2,500.0 WFFPL = WAYNE FARMS LLC, NC FOOD PROCESSING LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pe 1 s for submitting false information, including the possibility of fines and imprisonment for knowing violations." f 27_ 1- o, SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 " Application Method: SUR - Surface, [NJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/29/2024 DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): Facility Name: WAYNE FARMS, L.L.C., NC 24.08 Permit #: WO0004609 Cation Exchange Capacity (non 503 only): Operator: MAX WALL MAX & PEGGY WALL Predominant Soil Series: BRADDOCK Owner: Acres Used: 13.70 Acres Permitted: 13.70 Site #: Field #: NC SU 00023 0001 NC SU 00023 Reeid-1 a-i.ic n- lw.- u-i. Ana T- or.-r................._:�_ Source WFFPL Sample or Composite Date 1 1/12123 2 3 4 5 6 7 8 9 10 11 12 Solids 2.91 Arsenic 2.700 Cadmium 0.670 Copper 390 Chromium 13.00 Lead 6.40 Mercury 0.640 Molybdenum 12.00 Nickel 18.00 Selenium 6.00 Zinc 590 Total Phosphorus 26000 Source WFFPL Total DT/Ac. / App.Event 1 1.76 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.010 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 1.371 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.371 Chromium 0.046 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0746 Lead 0.023 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.023 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molybdenum 0.042 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.042 Nickel 0.063 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0:000 0.000 0.000 0.000 0.063 Selenium 0.021 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.021 Zinc 2.074 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.074 Total Phosphorus 91.380 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 91.380 . ,, -y, - yo.,nuy o, I-, u,aL mis ducualem was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant Ides for submitting false information, including the possibility of fines and imprisonment for knowing violations". 7`A3-2A{ Signature of Land Applier Date DENR FORM MFLSF (12/2006) SECTION 4 SUMM111 ENVIRONMENTAL TECHNOLOMZ3. INC Arraly0ca1 Laboralorfas August 21, 2019 Nate Roth Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: (336) 998-7150 FAX: (336) 998-8450 RE: Wayne Farms Dear Nate Roth: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com Order No.: 19071834 Summit Environmental Technologies, Inc. received 1 sample(s) on 7/26/2019 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 07256CA, Colorado, Connecticut PH-0108, Delaware, Florida NELAC E87688, Georgia E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Louisiana 04061, Maryland 339, Minnesota 409711, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP CL0052, Oklahoma 9940, Oregon OH2O0001, Pennsylvania 010, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-11-5, Utah OH009232011-1, Virginia VELAP 9456, Washington C891 Page 1 of 36 MM' Y Summit Environmental Technologies, Inc. Case Narrative SU3310 Win St. ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 wo#: 19071834 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 8/21/2019 CLIENT: Synagro Project: Wayne Farms WorkOrder Narrative: 19071834: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence Sample Notes: 19071834-OOIA TCLP-SVOC_8270E: Surrogate recovery was outside of the laboratory established acceptance criteria for: p-Terphenyl-d14. All other surrogates exhibited recoveries within the acceptance criteria. Original Page 2 of 36 MM' Summit Environmental Technologies, In Qualifiers and Acronyms SU3310 Win S EkiwllOMM@NTALTECHN❑LOG{r,S,INC Cuyahoga Falls, Ohio442� WO#: 19071834 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-446 Wehsite: httn:11www.settek.co, Date: 8/21/2019 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GC/MS. X The result was not confirmed when GC/MS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time PLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 3 of 36 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. EkiV1RONM@NtaL YECHHQ WGhES, INQ Cuyahoga Falls, Ohio 44223 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com CLIENT: Synagro Project: Wayne Farms Lab SampleID Client Sample ID 19071834-001 Wayne Farms Tag No Date Collected 7/25/2019 9:00:00 AM Workorder Sample Summary WO#: 19071834 2l Aug-l9 Date Received Matrix 7/26/2019 9:50:00 AM Sludge Page 4 of 36 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. DATES R POAT ENVIRON M EN?AL 1 ECHN❑ L0G1E5,1rJG Cuyahoga Falls, Ohio 44223 WO#: 19071834 ArWyft cal Laboraloriag TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com 21Aug-l9 Client: Synagro Project: Wayne Farms Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 19071834-OOIA Wayne Farms 7/25/2019 9:00:00 AM Sludge Flashpoint Determination (1010) 7/31/2019 12:01:41 PM pH (SW9045D) 7/29/2019 3:21:02 PM Reactive Cyanide (9014/7.3.3.2)-Solid 7/31/2019 12:26:00 PM Reactive Sulfide (9034)/7.3.4.2 7/31/2019 12:26:00 PM TCLP Herbicides Analysis (SW1311/8 8/7/2019 12:15:00 PM 8/13/2019 5:34:00 PM solid TCLP Mercury Analysis (SW1311/74 i 8/1/2019 5:00:00 PM 8/2/2019 2:40:00 PM 8/2/2019 5:29:00 PM TCLP Metals Analysis (SW 1311/6010 8/1/2019 5:00:00 PM 8/5/2019 9:30:00 AM 8/5/2019 6:03:12 PM TCLP Pesticides Analysis (SW 1311/8(8/l/2019 5:00:00 PM 8/6/2019 11:10:00 AM 8/6/2019 4:13:00 PM TCLP Semi-Volatiles Analysis 8/1/2019 5:00:00 PM 8/5/2019 1:00:00 PM 8/6/2019 6:13:00 PM (SW1311/8270) TCLP Volatiles Analysis 8/5/2019 2:00:00 PM TCLP Volatiles Analysis 8/1/2019 5:00:00 PM 8/5/2019 2:00:00 PM Original Page 5 of 36 Summit Environmental Technologies, Inc. PESUMMIT 3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arralyt9cal Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://n,n-m,.settek.com Analytical Report (base report) WO#: 19071834 Date Reported: 8/21/2019 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 7/25/2019 9:00:00 AM Lab ID: 19071834-OOIA Project: Wayne Farms Client Sample ID Wayne Farms Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP MERCURY ANALYSIS (SW1311/7470) TCLP Mercury ND TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP METALS ANALYSIS (SW131116010) TCLP Arsenic(As) ND TCLP Barium(Ba) ND TCLP Cadmium(Cd) ND TCLP Chromium(Cr) ND TCLP Lead(Pb) ND TCLP Selenium(Se) ND TCLP Silver(Ag) ND FLASHPOINT DETERMINATION (1010) Flashpoint (140°F) ND TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 2,4,5-Trichlorophenol ND 2,4,6-Trichlorophenol ND 2,4-Dinitrotoluene ND Cresols, Total ND Hexachloro-1,3-butadiene ND Hexachlorobenzene ND Hexachloroethane ND Nitrobenzene ND Pentachlorophenol ND Pyridine ND Surr: 2-Fluorophenol 20.7 Surr: Phenol-d6 26.9 Surr: Nitrobenzene-d5 24.2 SW7470A SW7470A Analyst: DNS 0.00500 mg/L 1 8/2/2019 5:29:00 PM SW6010D SW3010A Analyst: EAM 0.500 mg/L 1 8/5/2019 6:03:12 PM 5.00 mg/L 1 8/5/2019 6:03:12 PM 0.100 mg/L 1 8/5/2019 6:03:12 PM 0.200 mg/L 1 8/5/2019 6:03:12 PM 0.500 mg/L 1 8/5/2019 6:03:12 PM 0.0500 mg/L 1 8/5/2019 6:03:12 PM 0.500 mg/L 1 8/5/2019 6:03:12 PM SW1010 Analyst: TAH °F 1 7/31/2019 12:01:41 PM SW8270 SW3510C Analyst: BJH 0.200 mg/L 2 8/6/2019 6:13:00 PM 0.500 mg/L 2 8/6/2019 6:13:00 PM 0.500 mg/L 2 8/6/2019 6:13:00 PM 0.100 mg/L 2 8/6/2019 6:13:00 PM 10.0 mg/L 2 8/6/2019 6:13:00 PM 0.0400 mg/L 2 8/6/2019 6:13:00 PM 0.100 mg/L 2 8/6/2019 6:13:00 PM 0.200 mg/L 2 8/6/2019 6:13:00 PM 0.200 mg/L 2 8/6/2019 6:13:00 PM 0.500 mg/L 2 8/6/2019 6:13:00 PM 0.500 mg/L 2 8/6/2019 6:13:00 PM 10 - 109 %Rec 2 8/6/2019 6:13:00 PM 10 - 109 %Rec 2 8/6/2019 6:13:00 PM 19 - 120 %Rec 2 8/6/2019 6:13:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Original U Samples with CaleVal < MDL Page 6 of 36 Summit Environmental Technologies, Inc. PESUMMIT 3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://n,n-m,.settek.com Analytical Report (base report) WO#: 19071834 Date Reported: 8/21/2019 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 7/25/2019 9:00:00 AM Lab ID: 19071834-OOIA Project: Wayne Farms Client Sample ID Wayne Farms Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) Surr: 2,4,6-Tribromophenol 27.0 10 - 120 %Rec Surr: 2-Fluorobiphenyl 24.7 22 - 117 %Rec Surr: p-Terphenyl-d14 25.9 34 - 116 S %Rec TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND Toxaphene ND Endrin ND gamma-BHC ND Heptachlor ND Heptachlor epoxide ND Methoxychlor ND Surr: TCMX 47.1 Surr: DCB 50.1 SW8270 SW3510C Analyst: BJH 2 8/6/2019 6:13:00 PM 2 8/6/2019 6:13:00 PM 2 8/6/2019 6:13:00 PM SW8081 SW3510C Analyst: MES 0.0250 mg/L 10 8/6/2019 4:13:00 PM 0.0500 mg/L 10 8/6/2019 4:13:00 PM 0.00500 mg/L 10 8/6/2019 4:13:00 PM 0.00500 mg/L 10 8/6/2019 4:13:00 PM 0.00500 mg/L 10 8/6/2019 4:13:00 PM 0.00500 d mg/L 10 8/6/2019 4:13:00 PM 0.00500 d mg/L 10 8/6/2019 4:13:00 PM 10 - 119 %Rec 10 8/6/2019 4:13:00 PM 10 - 119 %Rec 10 8/6/2019 4:13:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP HERBICIDES ANALYSIS (SW1311/8151)-SOLID 2,4-D ND 0.0100 2,4,5-TP ND 0.00500 Surr: DCAA 99.9 20 - 140 TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 1,2-Dichloroethane ND MEK ND Benzene ND Carbon tetrachloride ND Chlorobenzene ND Chloroform ND Tetrachloroethene ND SW8151A SW8151A Analyst: MES d mg/L 1 8/13/2019 5:34:00 PM mg/L 1 8/13/2019 5:34:00 PM %Rec 1 8/13/2019 5:34:00 PM SW8260 Analyst: CTB 0.250 mg/L 50 8/5/2019 2:00:00 PM 0.250 mg/L 50 8/5/2019 2:00:00 PM 5.00 mg/L 50 8/5/2019 2:00:00 PM 0.250 mg/L 50 8/5/2019 2:00:00 PM 0.250 mg/L 50 8/5/2019 2:00:00 PM 2.50 mg/L 50 8/5/2019 2:00:00 PM 0.250 mg/L 50 8/5/2019 2:00:00 PM 0.250 mg/L 50 8/5/2019 2:00:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Original U Samples with CaleVal < MDL Page 7 of 36 MMIT Summit Environmental Technologies, Inc. Analytical Report PESU3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3, IRC Cuyahoga Falls, Ohio 44223 (base report) Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 WO#: 19071834 Website: http://www.settek.com Date Reported: 8/21/2019 CLIENT: Synagro Tag Number: Matrix: SLUDGE Collection Date: 7/25/2019 9:00:00 AM Lab ID: 19071834-OOIA Project: Wayne Farms Client Sample ID Wayne Farms Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260 Analyst: CTB TCLP VOLATILES ANALYSIS Trichloroethene ND 0.250 mg/L 50 8/5/2019 2:00:00 PM Vinyl chloride ND 0.100 mg/L 50 8/5/2019 2:00:00 PM Surr: 4-Bromofluorobenzene 93.9 70 - 130 %Rec 50 8/5/2019 2:00:00 PM Surr: Dibromofluoromethane 97.3 70 - 130 %Rec 50 8/5/2019 2:00:00 PM Surr: Toluene-d8 97.0 70 - 130 %Rec 50 8/5/2019 2:00:00 PM RCISOLID-W/ IGNITABILITY1030 SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND 0.490 mg/Kg 1 7/31/2019 12:26:00 PM RCISOLID-W/ IGNITABILITY1030 SW9045D Analyst: VVK PH (SW9045D) pH 6.7 s.u.@20.00 1 7/29/2019 3:21:02 PM RCISOLID-W/ IGNITABILITY1030 SW9034 Analyst: MS REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive ND 25.0 mg/Kg 1 7/31/2019 12:26:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected PL Permit Limit RL Reporting Detection Limit E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds P Second column confirmation exceeds R RPD outside accepted recovery limits Original U Samples with CaleVal < MDL Page 8 of 36 Summit Environmental Technologies, Inc. Accreditation Program fr 3310 Win St. summlmr Analv n tes Report ENOROMMEWAL YECHNOL.OG{r,S, INC Cuyahoga Falls, Ohio 44223 J Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wo#: 19071834 Wehsite: http://www.settek.com 21Aug-l9 Client: Synagro State: NW Project: Wayne Farms Program Name: NC_WW_SCM Sample ID Matrix Test Name Analyte Status 19071834-OOIA Sludge Flashpoint Determination (1010) Flashpoint (1407) A Sludge pH (SW9045D) Hydrogen Ion (pH) A Sludge Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive U Sludge Reactive Sulfide (9034)/7.3.4.2 Sulfide, Reactive U Sludge TCLP Herbicides Analysis (SW1311/8151)-solid 2,4,5-TP A Sludge TCLP Herbicides Analysis (SW1311/8151)-solid 2,4-D A Sludge TCLP Mercury Analysis (SW1311/7470) Mercury A Sludge TCLP Metals Analysis (SW1311/6010) Arsenic A Sludge TCLP Metals Analysis (SW1311/6010) Barium A Sludge TCLP Metals Analysis (SW1311/6010) Cadmium A Sludge TCLP Metals Analysis (SW1311/6010) Chromium A Sludge TCLP Metals Analysis (SW1311/6010) Lead A Sludge TCLP Metals Analysis (SW1311/6010) Selenium A Sludge TCLP Metals Analysis (SW1311/6010) Silver A Sludge TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Sludge TCLP Pesticides Analysis (SW1311/8081) Endrin A Sludge TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Sludge TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Sludge TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Sludge TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Key Key NC WW SCM A Accredited NC WW SCM U Unavailable Version #2 Page 9 of 36 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Analv n tes Report EMOROMMEWAL YECHHOL.OG{r,S, INC Cuyahoga Falls, Ohio 44223 J Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wo#: 19071834 Wehsite: http://www.settek.com 21Aug-l9 Client: Synagro State: NW Project: Wayne Farms Program Name: NC_WW_SCM Sample ID Matrix Test Name Analyte Status 19071834-OOIA Sludge TCLP Volatiles Analysis 1, 1 -Dichloroethene A Sludge TCLP Volatiles Analysis 1,2-Dichloroethane A Sludge TCLP Volatiles Analysis 2-Butanone A Sludge TCLP Volatiles Analysis Benzene A Sludge TCLP Volatiles Analysis Carbon tetrachloride A Sludge TCLP Volatiles Analysis Chlorobenzene A Sludge TCLP Volatiles Analysis Chloroform A Sludge TCLP Volatiles Analysis Tetrachloroethene A Sludge TCLP Volatiles Analysis Trichloroethene A Sludge TCLP Volatiles Analysis Vinyl chloride A NC WW SCM A Accredited NC WW SCM U Unavailable Version #2 Page 10 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38679 Sample ID MB-38679 SampType: MBLK TestCode: TCLP-voc-M Units: %Rec Prep Date: 8/1/2019 RunNo: 101545 Client ID: PBS Batch ID: 38679 TestNo: SW8260 SW1311M Analysis Date: 8/2/2019 SegNo: 2253693 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Surr:4-Bromofluorobenzene 509 500.0 102 70 130 Surr: Dibromofluoromethane 500 500.0 100 70 130 Surr: Toluene-d8 498 500.0 99.6 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 11 of 36 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38692 TCLP Mercury ND 0.00200 TCLP Mercury 0.00403 0.00200 0.00400 0 101 80 120 TCLP Mercury ND 0.00200 Sample ID 19071918-002AMS SampType: MS TestCode: HG_TCLP(74 Units: PPM Prep Date: 8/2/2019 RunNo: 101551 Client ID: Batch= Batch ID: 38692 TestNo: SW7470A SW7470A Analysis Date: 8/2/2019 SegNo: 2254325 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00258 0.00200 0.00400 0 64.5 75 125 S Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 12 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38692 Sample ID 19071918-002AMS SampType: MS TestCode: HG_TCLP(74 Units: PPM Prep Date: 8/2/2019 RunNo: 101551 Client ID: Batch= Batch ID: 38692 TestNo: SW7470A SW7470A Analysis Date: 8/2/2019 SegNo: 2254325 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID 19071918-002AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 8/2/2019 RunNo: 101551 Client ID: Batch= Batch ID: 38692 TestNo: SW7470A SW7470A Analysis Date: 8/2/2019 SegNo: 2254328 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual FCLP Mercury 0.00214 0.00200 0.00400 0 53.5 75 125 0.00258 18.6 20 S Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 13 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38702 Sample ID MB-38702 SampType: MBLK TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 8/5/2019 RunNo: 101580 Client ID: PBS Batch ID: 38702 TestNo: SW6010D SW3010A Analysis Date: 8/5/2019 SegNo: 2257435 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.500 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.500 TCLP Selenium(Se) ND 0.0500 TCLP Silver(Ag) ND 0.500 Sample ID LCS-38702 SampType: LCS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 8/5/2019 RunNo: 101580 Client ID: LCSS Batch ID: 38702 TestNo: SW6010D SW3010A Analysis Date: 8/5/2019 SegNo: 2257436 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.89 0.500 2.000 0 94.7 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 101 80 120 TCLP Cadmium(Cd) 1.77 0.100 2.000 0 88.5 80 120 TCLP Chromium(Cr) 2.01 0.200 2.000 0 100 80 120 TCLP Lead(Pb) 2.02 0.500 2.000 0 101 80 120 TCLP Selenium(Se) 1.89 0.0500 2.000 0 94.3 80 120 TCLP Silver(Ag) 2.08 0.500 2.000 0 104 80 120 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 14 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38702 Sample ID 19072115-004AMS SampType: MS TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 8/5/2019 RunNo: 101580 Client ID: Batch= Batch ID: 38702 TestNo: SW6010D SW3010A Analysis Date: 8/5/2019 SegNo: 2257448 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.32 0.500 2.000 0 116 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.2739 102 70 130 TCLP Cadmium(Cd) 2.03 0.100 2.000 0 102 70 130 TCLP Chromium(Cr) 2.10 0.200 2.000 0.0009437 105 70 130 TCLP Lead(Pb) 2.16 0.500 2.000 0 108 70 130 TCLP Selenium(Se) 2.43 0.0500 2.000 0 122 70 130 TCLP Silver(Ag) 2.32 0.500 2.000 0 116 70 130 Sample ID 19072115-004AMSD SampType: MSD TestCode: Mtl-TCLP-7(6 Units: mg/L Prep Date: 8/5/2019 RunNo: 101580 Client ID: Batch= Batch ID: 38702 TestNo: SW6010D SW3010A Analysis Date: 8/5/2019 SegNo: 2257449 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.28 0.500 2.000 0 114 70 130 2.315 1.47 20 TCLP Barium(Ba) ND 5.00 2.000 0.2739 99.2 70 130 0 0 20 TCLP Cadmium(Cd) 1.98 0.100 2.000 0 99.0 70 130 2.032 2.63 20 TCLP Chromium(Cr) 2.04 0.200 2.000 0.0009437 102 70 130 2.096 2.53 20 TCLP Lead(Pb) 2.13 0.500 2.000 0 106 70 130 2.159 1.51 20 TCLP Selenium(Se) 2.40 0.0500 2.000 0 120 70 130 2.430 1.36 20 TCLP Silver(Ag) 2.26 0.500 2.000 0 113 70 130 2.317 2.45 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 15 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Wayne Farms BatchID: 38719 WO#: 19071834 21 Aug-19 Sample ID mb-38719 SampType: MBLK TestCode: svoc-bna_tcl Units: mg/L Prep Date: 8/5/2019 RunNo: 101650 client ID: PBS Batch ID: 38719 TestNo: SW8270 SW3510C Analysis Date: 8/6/2019 SegNo: 2258308 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.0400 2,4,5-Trichlorophenol ND 0.100 2,4,6-Trichlorophenol ND 0.100 2,4-Dinitrotoluene ND 0.0200 o-Cresol ND 0.100 Cresols, Total ND 2.00 Hexachloro-1,3-butadiene ND 0.00800 Hexachlorobenzene ND 0.0200 Hexachloroethane ND 0.0400 Nitrobenzene ND 0.0400 Pentachlorophenol ND 0.100 Pyridine ND 0.100 Surr: 2-Fluorophenol 0.395 Surr: Phenol-d6 0.430 Surr: Nitrobenzene-d5 0.400 Surr: 2,4,6-Tribromophenol 0.456 Surr: 2-Fluorobiphenyl 0.362 Surr: p-Terphenyl-d14 0.518 1.000 39.5 10 109 1.000 43.0 10 109 1.000 40.0 19 120 1.000 45.6 10 120 1.000 36.2 22 117 1.000 51.8 34 116 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 16 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Wayne Farms BatchID: 38719 WO#: 19071834 21 Aug-19 Sample ID Ics-38719 SampType: LCS TestCode: svoc-bna_tcl Units: mg/L Prep Date: 8/5/2019 RunNo: 101650 -Iient ID: LCSS Batch ID: 38719 TestNo: SW8270 SW3510C Analysis Date: 8/6/2019 SegNo: 2258309 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.423 0.0400 0.8000 0 52.9 36.4 130 2,4,5-Trichlorophenol 0.523 0.100 0.8000 0 65.3 31.7 132 2,4,6-Trichlorophenol 0.500 0.100 0.8000 0 62.5 31.1 133 2,4-Dinitrotoluene 0.532 0.0200 0.8000 0 66.5 43.3 130 o-Cresol 0.532 0.100 0.8000 0 66.5 32.9 130 Cresols, Total ND 2.00 1.600 0 66.7 31.7 130 Hexachloro-1,3-butadiene 0.421 0.00800 0.8000 0 52.6 31.4 130 Hexachlorobenzene 0.435 0.0200 0.8000 0 54.4 43.1 130 Hexachloroethane 0.423 0.0400 0.8000 0 52.9 36.5 130 Nitrobenzene 0.541 0.0400 0.8000 0 67.7 39.5 130 Pentachlorophenol 0.528 0.100 0.8000 0 66.0 34 130 Pyridine 0.349 0.100 0.8000 0 43.6 10 130 Surr: 2-Fluorophenol 0.556 1.000 55.6 17.1 130 Surr: Phenol-d6 0.640 1.000 64.0 10 130 Surr: Nitrobenzene-d5 0.616 1.000 61.6 32.6 130 Surr:2,4,6-Tribromophenol 0.632 1.000 63.2 4.43 130 Surr:2-Fluorobiphenyl 0.544 1.000 54.4 41.8 130 Surr: p-Terphenyl-d14 0.572 1.000 57.2 36.4 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 17 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Wayne Farms BatchID: 38719 WO#: 19071834 21 Aug-19 Sample ID 19072156-001ams SampType: MS TestCode: svoc-bna_tcl Units: mg/L Prep Date: 8/5/2019 RunNo: 101650 -Iient ID: Batch= Batch ID: 38719 TestNo: SW8270 SW3510C Analysis Date: 8/6/2019 SegNo: 2261123 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.546 0.0800 0.8000 0 68.2 33.8 126 2,4,5-Trichlorophenol 0.643 0.200 0.8000 0 80.4 28.7 144 2,4,6-Trichlorophenol 0.598 0.200 0.8000 0 74.7 12.8 153 2,4-Dinitrotoluene 0.658 0.0400 0.8000 0 82.2 20.4 155 o-Cresol 0.681 0.200 0.8000 0 85.2 10 148 Cresols, Total ND 4.00 1.600 0 86.4 10 148 Hexachloro-1,3-butadiene 0.528 0.0160 0.8000 0 66.1 29 126 Hexachlorobenzene 0.500 0.0400 0.8000 0 62.4 33.7 134 Hexachloroethane 0.560 0.0800 0.8000 0 70.0 32.8 132 Nitrobenzene 0.696 0.0800 0.8000 0 87.0 20 158 Pentachlorophenol 0.693 0.200 0.8000 0 86.7 10 176 Pyridine 0.430 0.200 0.8000 0 53.7 10 130 Surr: 2-Fluorophenol 0.741 1.000 74.1 3.39 130 Surr: Phenol-d6 0.816 1.000 81.6 5 130 Surr: Nitrobenzene-d5 0.791 1.000 79.1 14.5 154 Surr: 2,4,6-Tribromophenol 0.752 1.000 75.2 19.5 130 Surr:2-Fluorobiphenyl 0.665 1.000 66.5 34.4 130 Surr: p-Terphenyl-d14 0.751 1.000 75.1 8.86 156 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 18 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT Client: Synagro Project: Wayne Farms BatchID: 38719 WO#: 19071834 21 Aug-19 Sample ID 19072156-001amsd SampType: MSD TestCode: svoc-bna_tcl Units: mg/L Prep Date: 8/5/2019 RunNo: 101650 -Iient ID: Batch= Batch ID: 38719 TestNo: SW8270 SW3510C Analysis Date: 8/6/2019 SegNo: 2261124 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.547 0.0800 0.8000 0 68.4 33.8 126 0.5460 0.220 30 2,4,5-Trichlorophenol 0.686 0.200 0.8000 0 85.7 28.7 144 0.6432 6.38 30 2,4,6-Trichlorophenol 0.643 0.200 0.8000 0 80.4 12.8 153 0.5976 7.29 30 2,4-Dinitrotoluene 0.648 0.0400 0.8000 0 81.0 20.4 155 0.6580 1.59 30 o-Cresol 0.684 0.200 0.8000 0 85.6 10 148 0.6812 0.469 30 Cresols, Total ND 4.00 1.600 0 86.2 10 148 0 0 30 Hexachloro-1,3-butadiene 0.559 0.0160 0.8000 0 69.8 29 126 0.5284 5.59 30 Hexachlorobenzene 0.536 0.0400 0.8000 0 67.0 33.7 134 0.4996 7.10 30 Hexachloroethane 0.532 0.0800 0.8000 0 66.5 32.8 132 0.5600 5.20 30 Nitrobenzene 0.712 0.0800 0.8000 0 89.0 20 158 0.6956 2.27 30 Pentachlorophenol 0.765 0.200 0.8000 0 95.7 10 176 0.6932 9.87 30 Pyridine 0.542 0.200 0.8000 0 67.8 10 130 0.4296 23.2 30 Surr:2-Fluorophenol 0.740 1.000 74.0 3.39 130 0 Surr: Phenol-d6 0.830 1.000 83.0 10 130 0 Surr: Nitrobenzene-d5 0.776 1.000 77.6 14.5 154 0 Surr: 2,4,6-Tribromophenol 0.745 1.000 74.5 19.5 130 0 Surr:2-Fluorobiphenyl 0.690 1.000 69.0 34.4 130 0 Surr: p-Terphenyl-d14 0.756 1.000 75.6 8.86 156 0 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 19 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38740 Sample ID 19080252-001ams SampType: MS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 8/6/2019 RunNo: 101668 Client ID: Batch= Batch ID: 38740 TestNo: SW8081 SW3510C Analysis Date: 8/6/2019 SegNo: 2260684 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.00544 0.00500 0.0100 0 54.4 10 224 gamma-BHC ND 0.00500 0.0100 0 45.1 10 192 Heptachlor ND 0.00500 0.0100 0 0 10 197 S Heptachlor epoxide ND 0.00500 0.0100 0 42.8 10 208 Methoxychlor ND 0.00500 0.0100 0 32.1 10 251 Surr: TCMX 7.01 20.00 35.1 10 157 Surr: DCB 9.22 20.00 46.1 10 194 Sample ID 19080252-001amsd SampType: MSD TestCode: TCLP-SVOC- Units: mg/L Prep Date: 8/6/2019 RunNo: 101668 Client ID: Batch= Batch ID: 38740 TestNo: SW8081 SW3510C Analysis Date: 8/6/2019 SegNo: 2260686 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.00741 0.00500 0.0100 0 74.1 10 224 0.00544 30.6 gamma-BHC 0.00618 0.00500 0.0100 0 61.8 10 192 0.00451 31.2 Heptachlor ND 0.00500 0.0100 0 0 10 197 0 0 Heptachlor epoxide 0.00630 0.00500 0.0100 0 63.0 10 208 0.00428 38.0 Methoxychlor ND 0.00500 0.0100 0 49.7 10 251 0 0 Surr: TCMX 9.48 20.00 47.4 10 157 0 Surr: DCB 12.5 20.00 62.5 10 194 0 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco 30 R 30 R 30 S 30 R 30 R Original Page 20 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38740 Sample ID mb-38740 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 8/6/2019 RunNo: 101668 Client ID: PBS Batch ID: 38740 TestNo: SW8081 SW3510C Analysis Date: 8/6/2019 SegNo: 2260868 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, total ND 0.00250 Toxaphene ND 0.00500 Endrin ND 0.000500 d gamma-BHC ND 0.000500 d Heptachlor ND 0.000500 d Heptachlor epoxide ND 0.000500 d Methoxychlor ND 0.000500 d Surr: TCMX 10.3 20.00 51.7 10 119 Surr: DCB 10.5 20.00 52.3 10 119 Sample ID Ics-38740 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 8/6/2019 RunNo: 101668 Client ID: LCSS Batch ID: 38740 TestNo: SW8081 SW3510C Analysis Date: 8/6/2019 SegNo: 2260869 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Endrin 0.00395 0.000500 0.0100 0 39.5 20 216 gamma-BHC 0.00268 0.000500 0.0100 0 26.8 20 197 Heptachlor 0.00243 0.000500 0.0100 0 24.3 20 200 Heptachlor epoxide 0.00348 0.000500 0.0100 0 34.8 20 200 Methoxychlor 0.00330 0.000500 0.0100 0 33.0 20 227 Surr: TCMX 5.46 20.00 27.3 20 143 Surr: DCB 5.57 20.00 27.9 20 151 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range M Manual Integration used to determine area response P Second column confirmation exceeds RL Reporting Detection Limit H Holding times for preparation or anal) MC Value is below Minimum Compound PL Permit Limit S Spike Recovery outside accepted reco Original Page 21 of 36 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: 38780 2,4-D ND 0.0100 0 0 2,4,5-TP ND 0.00500 0 0 Surr: DCAA 409 500.0 81.8 20 140 m 2,4-D 0.419 0.0100 0.500 0 83.9 43.8 130 2,4,5-TP 0.355 0.00500 0.500 0 71.0 51.5 ill Surr: DCAA 472 500.0 94.3 34.2 150 Sample ID LCSD-38780 SampType: LCSD TestCode: tclp-svoc-her Units: mg/L Prep Date: 8/7/2019 RunNo: 101987 Client ID: LCSS02 Batch ID: 38780 TestNo: SW8151A SW8151A Analysis Date: 8/13/2019 SegNo: 2274711 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit High Limit RPD Ref Val %RPD RPDLimit Qual 2,4-D 0.477 0.0100 0.500 0 95.5 43.8 130 0.419 12.9 30 2,4,5-TP 0.344 0.00500 0.500 0 68.8 51.5 130 0.355 3.11 30 Surr: DCAA 463 500.0 92.6 34.2 150 0 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 22 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101322 Sample ID CHECK 7 SampType: LCS TestCode: pH_S(9045D) Units: s.u.@21.2 Prep Date: RunNo: 101322 Client ID: LCSS Batch ID: R101322 TestNo: SW9045D Analysis Date: 7/29/2019 SegNo: 2241818 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 100 90 110 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 23 of 36 MM'T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101322 Sample ID LCS-R101322 SampType: LCS TestCode: pH_Oil(9045 Units: s.u.@20.6C Prep Date: RunNo: 101322 Client ID: LCSW Batch ID: R101322 TestNo: SW9045D Analysis Date: 7/29/2019 SegNo: 2241117 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 99.9 90 110 Sample ID CHECK 7 SampType: LCS TestCode: pH_Oil(9045 Units: s.u.@20.6C Prep Date: RunNo: 101322 Client ID: LCSW Batch ID: R101322 TestNo: SW9045D Analysis Date: 7/29/2019 SegNo: 2241138 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 100 90 110 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected R RPD outside accepted recovery limits E Value above quantitation range H Holding times for preparation or anal) M Manual Integration used to determine area response MC Value is below Minimum Compound P Second column confirmation exceeds PL Permit Limit RL Reporting Detection Limit S Spike Recovery outside accepted reco Original Page 24 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101322 Sample ID 19071527-001ADUP SampType: DUP TestCode: pH_NPW(450 Units: s.u.@20.6C Prep Date: RunNo: 101322 client ID: BatchQC Batch ID: R101322 TestNo: SW9045D Analysis Date: 7/29/2019 SegNo: 2241137 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 11.9 0.5 5 H Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 25 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101417 Sample ID LCS-R101417 SampType: LCS TestCode: FlashPt_S(10 Units: °F Prep Date: RunNo: 101417 Client ID: LCSS Batch ID: R101417 TestNo: SW1010 Analysis Date: 7/31/2019 SegNo: 2246281 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Flashpoint (140°F) 136 135.4 0 100 98 102 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 26 of 36 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ LQgir,-3, INCCuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101441 Cyanide, Reactive ND 0.495 Cyanide, Reactive 9.25 0.490 10.00 0 92.5 85 110 Cyanide, Reactive 9.43 0.490 10.00 0 94.3 81.6 122 Sample ID 19071654-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 101441 Client ID: Batch= Batch ID: R101441 TestNo: SW9014 Analysis Date: 7/31/2019 SegNo: 2247614 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 9.41 0.490 10.00 0 94.1 81.6 122 9.427 0.208 5 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 27 of 36 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMEWAL I ECHN❑ Lggir,-3, INC„ Cuyahoga Falls, Ohio 44223 4rrafyt�cal iaboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com QC SUMMARY REPORT WO#: 19071834 2l Aug-19 Client: Synagro Project: Wayne Farms Batchll): R101441 Sample ID 19071654-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 101441 Client ID: BatchQC Batch ID: R101441 TestNo: SW9014 Analysis Date: 7/31/2019 SegNo: 2247614 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal; J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 28 of 36 SUMM'T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 19071834 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101444 Sulfide, Reactive ND 25.0 Sulfide, Reactive 4780 25.0 4800 0 99.6 85 115 Sulfide, Reactive 4670 25.0 4800 0 97.3 80 120 Sample ID 19071654-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 101444 Client ID: Batch= Batch ID: R101444 TestNo: SW9034 Analysis Date: 7/31/2019 SegNo: 2247640 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 4640 25.0 4800 0 96.7 80 120 4670 0.644 30 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 29 of 36 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMEWAL I ECHN❑ Lggir,-3, INC„ Cuyahoga Falls, Ohio 44223 4rrafyt�cal iaboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com QC SUMMARY REPORT WO#: 19071834 2l Aug-19 Client: Synagro Project: Wayne Farms Batchll): R101444 Sample ID 19071654-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 101444 Client ID: BatchQC Batch ID: R101444 TestNo: SW9034 Analysis Date: 7/31/2019 SegNo: 2247640 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal; J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 30 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101627A Sample ID LCS-101627 SampType: LCS TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 101627 Client ID: LCSW Batch ID: R101627A TestNo: SW8260 Analysis Date: 8/5/2019 SegNo: 2284872 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1, 1 -Dichloroethene 0.0196 0.00500 0.0200 0 98.0 70 138 1,2-Dichloroethane 0.0194 0.00500 0.0200 0 96.9 70 130 MEK 0.0951 0.0250 0.100 0 95.1 70 130 Benzene 0.0190 0.00500 0.0200 0 95.1 70 132 Carbon tetrachloride 0.0187 0.00500 0.0200 0 93.3 70 130 Chlorobenzene 0.0197 0.00500 0.0200 0 98.4 10 255 Chloroform 0.0185 0.00500 0.0200 0 92.5 47.7 141 Tetrachloroethene 0.0193 0.00500 0.0200 0 96.7 10 130 Trichloroethene 0.0197 0.00500 0.0200 0 98.5 70 130 Vinyl chloride 0.0175 0.00200 0.0200 0 87.6 70 130 Surr: 4-Bromofluorobenzene 50.6 50.00 101 70 130 Surr: Dibromofluoromethane 49.7 50.00 99.4 70 130 Surr: Toluene-d8 50.0 50.00 99.9 70 130 Sample ID MBLK-101627 SampType: MBLK TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 101627 Client ID: PBW Batch ID: R101627A TestNo: SW8260 Analysis Date: 8/5/2019 SegNo: 2284873 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene ND 0.00500 1,2-Dichloroethane ND 0.00500 MEK ND 0.0250 Benzene ND 0.00500 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 31 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101627A Sample ID MBLK-101627 SampType: MBLK TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 101627 Client ID: PBW Batch ID: R101627A TestNo: SW8260 Analysis Date: 8/5/2019 SegNo: 2284873 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride ND 0.00500 Chlorobenzene ND 0.00500 Chloroform ND 0.00500 Tetrachloroethene ND 0.00500 Trichloroethene ND 0.00500 Vinyl chloride ND 0.00200 Surr: 4-Bromofluorobenzene 47.4 Surr: Dibromofluoromethane 48.0 Surr: Toluene-d8 49.2 50.00 94.8 70 130 50.00 96.1 70 130 50.00 98.3 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 32 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101627A Sample ID 19072156-00laMS SampType: MS TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 101627 client ID: BatchQC Batch ID: R101627A TestNo: SW8260 Analysis Date: 8/5/2019 SegNo: 2272450 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.184 0.0500 0.200 0 92.0 39.9 160 1,2-Dichloroethane 0.197 0.0500 0.200 0 98.4 42.5 157 MEK ND 1.00 1.00 0 95.4 16.6 227 Benzene 0.182 0.0500 0.200 0 90.9 38.1 155 Carbon tetrachloride 0.153 0.0500 0.200 0 76.5 40.8 162 Chlorobenzene ND 0.500 0.200 0 94.8 35.7 168 Chloroform 0.180 0.0500 0.200 0 90.2 18.3 199 Tetrachloroethene 0.162 0.0500 0.200 0 80.8 10 261 Trichloroethene 0.175 0.0500 0.200 0 87.6 23.8 175 Vinyl chloride 0.157 0.0200 0.200 0 78.6 10 165 Surr:4-Bromofluorobenzene 512 500.0 102 84.6 130 Surr: Dibromofluoromethane 494 500.0 98.8 71.4 127 Surr: Toluene-d8 508 500.0 102 74.6 127 Sample ID 19072156-00laMSD SampType: MSD TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 101627 client ID: BatchQC Batch ID: R101627A TestNo: SW8260 Analysis Date: 8/5/2019 SegNo: 2272451 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.182 0.0500 0.200 0 91.0 39.9 160 0.184 1.04 25 1,2-Dichloroethane 0.208 0.0500 0.200 0 104 42.5 157 0.197 5.54 25 MEK ND 1.00 1.00 0 97.2 16.6 227 0 0 25 Benzene 0.187 0.0500 0.200 0 93.6 38.1 155 0.182 2.93 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 33 of 36 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL rECHN❑ LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llh settek.com QC SUMMARY REPORT WO#: 19071834 21 Aug-19 Client: Synagro Project: Wayne Farms BatchID: R101627A Sample ID 19072156-00laMSD SampType: MSD TestCode: tclp-voc-mstr Units: mg/L Prep Date: RunNo: 101627 client ID: BatchQC Batch ID: R101627A TestNo: SW8260 Analysis Date: 8/5/2019 SegNo: 2272451 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride 0.148 0.0500 0.200 0 73.8 40.8 162 0.153 3.53 25 Chlorobenzene ND 0.500 0.200 0 97.8 35.7 168 0 0 25 Chloroform 0.192 0.0500 0.200 0 96.1 18.3 199 0.180 6.28 25 Tetrachloroethene 0.164 0.0500 0.200 0 82.0 10 261 0.162 1.54 25 Trichloroethene 0.180 0.0500 0.200 0 90.2 23.8 175 0.175 2.81 25 Vinyl chloride 0.150 0.0200 0.200 0 74.8 10 165 0.157 4.95 25 Surr:4-Bromofluorobenzene 486 500.0 97.1 84.6 130 0 25 Surr: Dibromofluoromethane 506 500.0 101 71.4 127 0 25 Surr: Toluene-d8 509 500.0 102 74.6 127 0 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal) J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit S Spike Recovery outside accepted reco Page 34 of 36 A s C V G T�rrl,tot F, } G aes! "uao jo jagwn, M■��I aleil Nury_ ui-t(j=h1Q'A',V= •a9PnLS= S U7 - 1!()=o •psnbq=� l ,pguy" 'xP)ul,ti � asEUFdwu;3 qrj!) T � rr _ �Y r.� 4'ti f � � v r3 toCF W o a xx. F s Im C rII s= cu N rri C7 <) r _ a _n _ - cn r U c e _ � w a E E rti} ° F v CS U ICJ fi H i LU c� ¢_ rn J Q C) U D LL E [a C� O s U W N 0 Ira U') 9- lY1 V k y 8 Al L. C fr u � y 7 .. X Page 35 of 36 �� � � Summit Environmental Technologies, Inc. SU3310 Win St. ENVIRONMENTALTECHNOLOGiES.lftC Cuyahoga Falls, Ohio44223 Sample Log -In Check List Arrafyacal Laboralnrlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,,",m,.settek.com Client Name: SYN-NC-27028 Work Order Number: 19071834 RcptNo: 1 Logged by: John A.Semenik Completed By: Jacqueline Rasile Reviewed By: Jennifer Woolf 7/26/2019 9:50:00 AM 7/26/2019 11:18:05 PM 7/29/2019 2:54:58 PM Chain of Custody 1. Is Chain of Custody complete? Yes ❑d No ❑ Not Present ❑ 2. How was the sample delivered? FedEx Lop In 3. Coolers are present? Yes ❑d No ❑ NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present V No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes ❑d No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes ❑d No ❑ NA ❑ 7. Sample(s) in proper container(s)? Yes ❑d No ❑ 8. Sufficient sample volume for indicated test(s)? Yes ❑d No ❑ 9. Are samples (except VOA and ONG) properly preserved? Yes ❑d No ❑ 10. Was preservative added to bottles? Yes ❑ No ❑d NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑� 12. Were any sample containers received broken? Yes ❑ No ❑d 13. Does paperwork match bottle labels? Yes No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes ❑d No ❑ 15. Is it clear what analyses were requested? Yes ❑d No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA V Person Notified: Date By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: 18. Additional remarks: Cooler Information Cooler No Temp °C Condition I Seal Intact Seal No Seal Date Signed By 1 14.5 Goodl Not Present Page 36 of 36 SECTION 5 Wayne Farms Land Application Program Permit #WQ0004609 Calendar Year 2023 Animal processing wastewater residuals were land applied in two events in the year 2023. The biosolids were sampled in the start of the year to cover the entire year since we hauled less than 300 dry tons per year. The biosolids land applied in 2023 had sufficient lime added to raise the pH of the uniform mixture to a pH of 10 for thirty minutes prior to being surface land applied. This was performed to control possible nuisance conditions (see Section II, Item 7 in permit #WQ0004609). a bQ cq Sampler & pki anaiysCiniiials Sanpletime! M H PH test time p Date of hour: sample & PH test �6 e-6 � A � � r A � U is Sampler & rLw analystiuifials {€ Sample time/ ti � a PH test timeTj D { Tin eat Y TIei �i 4 y cq sampler &; PH � analystinwals f Sample brae/ `O ; ` p7Ei test drae E Date oiInifiai & 2 hr: � l' Sampee & pH test SECTION 6 Agricultural Lime Application Log Year: 2023 Project: Wayne farms Field Soil Lime Requirement Tons/Acre Date Applied (state -county -site -field) pH (from soil analysis) Applied(CCE Eq.) Lime is in the sludge SECTION 7 NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL003598 k5i I"14'4+;4, Client: Alex Fox Advisor: Predictive Synagro 284 Boger Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Links to Helpful Information Sampled: 08/01/2023 Received: 09/08/2023 Completed: 09/18/2023 Farm: SU-22 Client ID: Sampled County : Surry 501947 Advisor ID: Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 10 60 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 10 60 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.51 0.98 7.1 78 1.5 5.9 56 40 59 16 55 98 76 76 149 149 128 0.2 3 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 10 0 0 0 pH$ 0 0 0 Note: 12 Note: $ 2 - Fescue/OGrass/Tim, M 0.0 120-200 10 0 0 0 pH$ 0 0 0 Note: 12 Note: $ Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.41 0.88 11.5 91 1.0 6.6 58 114 59 27 47 143 94 94 471 471 131 0.2 2 North Carolina Tai wLm Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL003598 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NOs-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.pov/apronomi/obpart4.htrntfsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.pov/agronomi/uyrst.htm NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL003606 k5i I"14'4+;4, Client: Alex Fox Advisor: Predictive Synagro 284 Boger Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Links to Helpful Information Sampled: Received: 09/08/2023 Completed: 09/18/2023 Farm: SU-23 Sampled County : Surry Client ID: 501947 Advisor ID: Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 60 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 0 60 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.36 1.04 8.0 82 1.5 6.0 215 41 65 14 49 132 96 96 373 373 286 0.2 3 North Carolina Tai wLm Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL003606 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NOs-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.pov/apronomi/obpart4.htrntfsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.pov/agronomi/uyrst.htm