WQ0038087_2023 Residual Annual Report_20240301 (4)

Initial Review
Reviewer
nathaniel.thorn burg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2023
Permit Number (IR) * WQ0038087
Applicant/Permittee Terra Renewal Services, Inc.
Email Notifications
Does this need review by the hydrogeologist? * Yes U No
Regional Office Winston-Salem
CO Reviewer
Admin Reviewer Wanda Gerald

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* David C. Coyle
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
479-747-8192
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation High -Rate Infiltration
Other Wastewater Reclaimed Water
Closed -Loop Recycle Residuals
Single -Family Residence Wastewater Other
Irrigation
Permit Number:*
WQ0038087
Has Current Existing permit number
Applicant/Permittee Address*
P.O. Box 1746, Watkinsville GA 30677
Facility Name*
Terra Renewal Services Class B Residuals Program
Please provide comments/notes on your current submittal below.
Annual Report for land application of Class-B residuals under Permit # WQ0038087.
Permittee: Terra Renewal Services.
Land Sites located in Wilkes & Yadkin Counties.
David Coyle
Senior Environmental Manager
Denali Water Solutions
(dba: Terra Renewal Services)
479-747-8192
[e-mail]
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
NC—WQ0038087—Terra Renewal_RLAP_2023 Ann
25.98MB
Report.pdf
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center

Raleigh, NC 27699-1617
Signature
OAOW &. &ire
Submission Date 3/1/2024

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PO BOX 399 - DARDANELLE - ARKAN A a - 72334
479.747.3192
tarrarenewal.com
2023 ANNUAL REPORT
for NC Land Application Permit Number:
WQ0038087
(Class B Residuals)
Permittee / Submitted By:
Terra Renewal Services
P.O. Box 399
Dardanelle, AR 72834
Attention:
North Carolina Department of Environmental Quality
Division of Water Resources
Water Quality Permitting Section
Non -Discharge Permitting Unit
512 N. Salisbury Street; 6t" Floor
Raleigh, NC 27604

1
Annual Land Application Certification Form (ACF)

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0038087 County: Wilkes & Yadkin Year:
Facility Name (as shown on permit):
Land Application Operator:
Terra Renewal Services, Inc
2023
Terra Renewal Services, Inc Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
R1 Yes [J No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summary.
Total number of application fields in the permit:
62
Total number of fields utilized for land application during the year:
28
Total amount of dry tons applied during the year for all application sites:
2,851
Total number of acres utilizes for land application during the year:
829
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2023 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Resources. Rd Yes LJ No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective
action taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or
the limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies
of laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three
(3) copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant
Loading Rates in 15A NCAC 02T . 1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T. I I I I were complied with (applicable to 40 CFR Part
503 regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Resources.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as
specified in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the
possibility of fines and imprisonment for knowing violations."
David C. Coyle; Senior Environmental Manager
Permittee Name and Title (type or print) Signature of Permittee Date
' 3/l/2024
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T. 1102 (26)
DENR FORM ACF (12/2006)

2
Annual Residuals Sampling Summary Form (RSSF)
Annual Residuals Sampling Summary Form — B (RSSF-B)

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3
Annual Metals Field Loading Summary Form (MFLSF)
Annual Land Application Field Summary Form (FSF)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 109.04
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
21.8 Acres Permitted: 21.8 Site #: WK-CH-01 Field #:
lows
�Wrmunn1�
Residual Analvsis Data (Heavv Metals and Total Phosphorus use m2/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI
5/18/23
Tyson-
Wilkes
5/18/23
.....3....
AdvPier
9/21/23
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
4.3
9.7
14.3
Arsenic
5.2
2.2
1.6
Cadmium
1.7
0.7
0.5
Copper
6.6
25.0
300.0
Chromium
Lead
3.5
1.5
3.6
Mercury
1.9
0.8
0.6
Molyb-
denum
14.0
5.9
4.2
Nickel
14.0
5.9
69.0
Selenium
6.9
2.9
2.1
Zinc
32.0
33.0
140.0
Total
Phos-
horus
7,700
1,400
2,700
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
1.71
3.13
0.16
Arsenic
0.018
0.014
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.032
Cadmium
0.006
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
Copper
0.023
0.156
0.098
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.277
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.012
0.009
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.023
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0.007
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
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0.048
0.037
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.086
denum
Nickel
0.048
0.037
0.023
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.107
Selenium
0.024
0.018
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.042
Zinc
0.110
0.206
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.362
Total
Phos-
26.349
8.756
0.886
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
35.991
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
e
3/1/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 280.55
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
41.6 Acres Permitted: 41.6 Site #: WK-CH-03 Field #:
I / h
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI
5/18/23
Tyson-
Wilkes
5/18/23
.....3....
AdvPier
9/21/23
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
4.3
9.7
14.3
Arsenic
5.2
2.2
1.6
Cadmium
1.7
0.7
0.5
Copper
6.6
25.0
300.0
Chromium
Lead
3.5
1.5
3.6
Mercury
1.9
0.8
0.6
Molyb-
denum
14.0
5.9
4.2
Nickel
14.0
5.9
69.0
Selenium
6.9
2.9
2.1
Zinc
32.0
33.0
140.0
Total
Phos-
horus
7,700
1,400
2,700
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
2.56
4.10
0.09
Arsenic
0.027
0.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.045
Cadmium
0.009
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Copper
0.034
0.205
0.052
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.290
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.018
0.012
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.031
Mercury
0.010
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
Molyb-
0.072
0.048
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.121
denum
Nickel
0.072
0.048
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.132
Selenium
0.035
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.059
Zinc
0.164
0.270
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.458
Total
Phos-
39.455
11.469
0.464
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
51.388
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
e
3/1/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 262.66
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
35.8 Acres Permitted: 35.8 Site #: WK-CH-04 Field #:
uvi
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI
5/18/23
Tyson-
Wilkes
5/18/23
.....3....
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
4.3
9.7
Arsenic
5.2
2.2
Cadmium
1.7
0.7
Copper
6.6
25.0
Chromium
Lead
3.5
1.5
Mercury
1.9
0.8
Molyb-
denum
14.0
5.9
Nickel
14.0
5.9
Selenium
6.9
2.9
Zinc
32.0
33.0
Total
Phos-
horus
7,700
1,400
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
2.44
4.90
Arsenic
0.025
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.047
Cadmium
0.008
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
Copper
0.032
0.245
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.277
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.017
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.032
Mercury
0.009
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
Molyb-
0.068
0.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.126
denum
Nickel
0.068
0.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.126
Selenium
0.034
0.028
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.062
Zinc
0.156
0.323
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.479
Total
Phos-
37.591
13.709
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
51.300
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
�3/1/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 65.39
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: George F Ireland Trust Predominant Soil Series:
21 Acres Permitted: 21 Site #: YK-DM-05 Field #:
x r,
�W 19 a 1kTj R I L7
Residual Analvsis Data (Heavv Metals and Total Phosphorus use m2/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
3/2/23
Tyson-
Wilke
3/2/23
.....3....
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
2.2
20.7
Arsenic
10.0
1.1
Cadmium
3.4
0.4
Copper
13.0
2.5
Chromium
Lead
6.7
370.0
Mercury
3.6
0.4
Molyb-
denum
27.0
3.0
Nickel
27.0
3.0
Selenium
13.0
1.5
Zinc
43.0
3.9
Total
Phos-
horus
12,000
440
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.15
2.96
Arsenic
0.003
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Cadmium
0.001
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Copper
0.004
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.002
2.190
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.192
Mercury
0.001
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
Molyb-
0.008
0.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
denum
Nickel
0.008
0.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Selenium
0.004
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Zinc
0.013
0.023
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.036
Total
Phos-
3.696
2.605
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
6.301
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
e
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 135.14
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: George F Ireland Trust Predominant Soil Series:
26.2 Acres Permitted: 26.2 Site #: YK-DM-08 Field #:
17AM
Residual Analvsis Data (Heavv Metals and Total Phosphorus use m2/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
3/2/23
Tyson-
Wilke
3/2/23
.....3....
AdvPier
9/21/23
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
2.2
20.7
14.3
Arsenic
10.0
1.1
1.6
Cadmium
3.4
0.4
0.5
Copper
13.0
2.5
300.0
Chromium
Lead
6.7
370.0
3.6
Mercury
3.6
0.4
0.6
Molyb-
denum
27.0
3.0
4.2
Nickel
27.0
3.0
69.0
Selenium
13.0
1.5
2.1
Zinc
43.0
3.9
140.0
Total
Phos-
horus
12,000
440
2,700
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.47
4.55
0.14
Arsenic
0.009
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
Cadmium
0.003
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
0.012
0.023
0.082
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.117
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.006
3.365
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.372
Mercury
0.003
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Molyb-
0.026
0.027
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.054
denum
Nickel
0.026
0.027
0.019
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.072
Selenium
0.012
0.014
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.027
Zinc
0.041
0.035
0.038
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.115
Total
Phos-
11.376
4.001
0.740
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
16.117
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
e
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 64.39
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
13.2 Acres Permitted: 13.2 Site #: WK-NM-09 Field #:
I i I
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Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
3/2/23
Tyson-
Wilke
3/2/23
.....3....
RVI-
Harm
11/28/23
4....
Tyson-
Wilke
11/28/23
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
2.2
20.7
1.8
1.4
Arsenic
10.0
1.1
13.0
17.0
Cadmium
3.4
0.4
4.3
5.6
Copper
13.0
2.5
35.0
160.0
Chromium
Lead
6.7
370.0
8.6
11.0
Mercury
3.6
0.4
4.2
5.5
Molyb-
denum
27.0
3.0
34.0
45.0
Nickel
27.0
3.0
34.0
45.0
Selenium
13.0
1.5
27.0
23.0
Zinc
43.0
3.9
57.0
150.0
Total
Phos-
horus
12,000
440
8,500
9,100
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.49
3.92
0.27
0.19
Arsenic
0.010
0.009
0.007
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.032
Cadmium
0.003
0.003
0.002
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
Copper
0.013
0.020
0.019
0.061
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.112
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.007
2.904
0.005
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.919
Mercury
0.004
0.003
0.002
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
Molyb-
0.027
0.024
0.019
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.086
denum
Nickel
0.027
0.024
0.019
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.086
Selenium
0.013
0.012
0.015
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
Zinc
0.042
0.031
0.031
0.057
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.161
Total
Phos-
11.784
3.453
4.641
3.458
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
23.336
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 159.58
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
19.6 Acres Permitted: 19.6 Site #: WK-NM-10 Field #:
I i N
��.I I IV Ia1O-
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
3/2/23
Tyson-
Wilke
3/2/23
.....3....
RVI-
Harm
11/28/23
4....
Tyson-
Wilke
11/28/23
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
2.2
20.7
1.8
1.4
Arsenic
10.0
1.1
13.0
17.0
Cadmium
3.4
0.4
4.3
5.6
Copper
13.0
2.5
35.0
160.0
Chromium
Lead
6.7
370.0
8.6
11.0
Mercury
3.6
0.4
4.2
5.5
Molyb-
denum
27.0
3.0
34.0
45.0
Nickel
27.0
3.0
34.0
45.0
Selenium
13.0
1.5
27.0
23.0
Zinc
43.0
3.9
57.0
150.0
Total
Phos-
horus
12,000
440
8,500
9,100
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.41
5.29
0.25
2.19
Arsenic
0.008
0.012
0.007
0.074
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.101
Cadmium
0.003
0.004
0.002
0.025
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.033
Copper
0.011
0.026
0.018
0.701
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.756
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.006
3.911
0.004
0.048
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.969
Mercury
0.003
0.004
0.002
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.033
Molyb-
0.022
0.032
0.017
0.197
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.268
denum
Nickel
0.022
0.032
0.017
0.197
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.268
Selenium
0.011
0.016
0.014
0.101
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.141
Zinc
0.036
0.041
0.029
0.657
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.763
Total
Phos-
9.936
4.651
4.301
39.858
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
58.746
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 86.90
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
22.5 Acres Permitted: 22.5 Site #: WK-MF-I I Field #:
I / h
��.I I IV Ia1O-
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
3/2/23
Tyson-
Wilke
3/2/23
.....3....
RVI-
Harm
11/28/23
4....
Tyson-
Wilke
11/28/23
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
2.2
20.7
1.8
1.4
Arsenic
10.0
1.1
13.0
17.0
Cadmium
3.4
0.4
4.3
5.6
Copper
13.0
2.5
35.0
160.0
Chromium
Lead
6.7
370.0
8.6
11.0
Mercury
3.6
0.4
4.2
5.5
Molyb-
denum
27.0
3.0
34.0
45.0
Nickel
27.0
3.0
34.0
45.0
Selenium
13.0
1.5
27.0
23.0
Zinc
43.0
3.9
57.0
150.0
Total
Phos-
horus
12,000
440
8,500
9,100
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.38
2.99
0.20
0.29
Arsenic
0.008
0.007
0.005
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.029
Cadmium
0.003
0.002
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Copper
0.010
0.015
0.014
0.092
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.130
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.005
2.214
0.003
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.229
Mercury
0.003
0.002
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Molyb-
0.021
0.018
0.014
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.078
denum
Nickel
0.021
0.018
0.014
0.026
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.078
Selenium
0.010
0.009
0.011
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.043
Zinc
0.033
0.023
0.023
0.086
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.165
Total
Phos-
9.216
2.633
3.400
5.205
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
20.454
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
3/1/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
33.8 Acres Permitted: 33.8 Site #: WK-NM-13 Field #:
17.10
12.0
Fairview
WK-MF-13
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
11/28/23
Tyson-
Wilke
11/28/23
.....3....
Tyson-
Danville
11/28/23
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
1.8
1.4
3.9
Arsenic
13.0
17.0
6.3
Cadmium
4.3
5.6
2.1
Copper
35.0
160.0
4.2
Chromium
Lead
8.6
11.0
4.2
Mercury
4.2
5.5
2.0
Molyb-
denum
34.0
45.0
17.0
Nickel
34.0
45.0
17.0
Selenium
27.0
23.0
8.4
Zinc
57.0
150.0
21.0
Total
Phos-
horus
8,500
9,100
7,400
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.33
0.12
0.06
Arsenic
0.009
0.004
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Cadmium
0.003
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
0.023
0.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.061
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.006
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Mercury
0.003
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Molyb-
0.023
0.010
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.035
denum
Nickel
0.023
0.010
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.035
Selenium
0.018
0.005
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.024
Zinc
0.038
0.035
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.075
Total
Phos-
5.661
2.111
0.844
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
8.616
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
13.8 Acres Permitted: 13.8 Site #: WK-NM-15 Field #:
34.24
13.2
Fairview
WK-MF-15
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
5/18/23
Tyson-
Wilke
5/16/23
.....3....
RVI-
Harm
11/28/23
4....
Tyson-
Wilke
11/28/23
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
4.3
9.7
1.8
1.4
Arsenic
5.2
2.2
13.0
17.0
Cadmium
1.7
0.7
4.3
5.6
Copper
6.6
25.0
35.0
160.0
Chromium
Lead
3.5
1.5
8.6
11.0
Mercury
1.9
0.8
4.2
5.5
Molyb-
denum
14.0
5.9
34.0
45.0
Nickel
14.0
5.9
34.0
45.0
Selenium
6.9
2.9
27.0
23.0
Zinc
32.0
33.0
57.0
150.0
Total
Phos-
horus
7,700
1,400
8,500
9,100
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.62
1.41
0.29
0.16
Arsenic
0.006
0.006
0.008
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.026
Cadmium
0.002
0.002
0.003
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
Copper
0.008
0.070
0.021
0.050
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.149
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.004
0.004
0.005
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
Mercury
0.002
0.002
0.002
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Molyb-
0.017
0.017
0.020
0.014
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.068
denum
Nickel
0.017
0.017
0.020
0.014
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.068
Selenium
0.009
0.008
0.016
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.040
Zinc
0.040
0.093
0.034
0.047
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.213
Total
Phos-
9.610
3.940
4.998
2.839
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
21.386
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
48.8 Acres Permitted: 48.8 Site #: WK-NM-16 Field #:
76.03
8.9
Fairview
WK-MF-16
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
11/28/23
Tyson-
Wilke
12/12/23
.....3....
Tyson-
Danville
11/28/23
4....
AdvPier
9/21/23
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
1.8
4.3
3.9
14.3
Arsenic
13.0
5.6
6.3
1.6
Cadmium
4.3
1.9
2.1
0.5
Copper
35.0
67.0
4.2
300.0
Chromium
Lead
8.6
6.2
4.2
3.6
Mercury
4.2
1.8
2.0
0.6
Molyb-
denum
34.0
15.0
17.0
4.2
Nickel
34.0
15.0
17.0
69.0
Selenium
27.0
7.5
8.4
2.1
Zinc
57.0
81.0
21.0
140.0
Total
Phos-
horus
8,500
4,000
7,400
2,700
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.45
0.78
0.07
0.26
Arsenic
0.012
0.009
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.022
Cadmium
0.004
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
0.032
0.104
0.001
0.155
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.291
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.008
0.010
0.001
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
Mercury
0.004
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Molyb-
0.031
0.023
0.002
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.059
denum
Nickel
0.031
0.023
0.002
0.036
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.092
Selenium
0.024
0.012
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.038
Zinc
0.052
0.126
0.003
0.072
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.252
Total
Phos-
7.684
6.200
1.080
1.393
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
16.358
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 115.89
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
39.5 Acres Permitted: 39.5 Site #: WK-NM-17 Field #:
low
��.I I IV Ia1O-
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
3/2/23
Tyson-
Wilke
3/2/23
.....3....
RVI-
Harm
11/28/23
4....
Tyson-
Wilke
11/28/23
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
2.2
20.7
1.8
1.4
Arsenic
10.0
1.1
13.0
17.0
Cadmium
3.4
0.4
4.3
5.6
Copper
13.0
2.5
35.0
160.0
Chromium
Lead
6.7
370.0
8.6
11.0
Mercury
3.6
0.4
4.2
5.5
Molyb-
denum
27.0
3.0
34.0
45.0
Nickel
27.0
3.0
34.0
45.0
Selenium
13.0
1.5
27.0
23.0
Zinc
43.0
3.9
57.0
150.0
Total
Phos-
horus
12,000
440
8,500
9,100
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.22
2.23
0.21
0.28
Arsenic
0.004
0.005
0.005
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.024
Cadmium
0.001
0.002
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
Copper
0.006
0.011
0.014
0.090
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.121
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.003
1.649
0.004
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.662
Mercury
0.002
0.002
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.008
Molyb-
0.012
0.013
0.014
0.025
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.064
denum
Nickel
0.012
0.013
0.014
0.025
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.064
Selenium
0.006
0.007
0.011
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.036
Zinc
0.019
0.017
0.023
0.084
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.144
Total
Phos-
5.256
1.962
3.485
5.114
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
15.817
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
3/1/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 273.50
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
59.2 Acres Permitted: 59.2 Site #: WK-NM-23 Field #:
uM
��.I I IV Ia1O-
VV N_IVIN_11
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
5/18/23
Tyson-
Wilke
5/16/23
.....3....
RVI-
Harm
11/28/23
4....
Tyson-
Wilke
11/28/23
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
4.3
9.7
1.8
1.4
Arsenic
5.2
2.2
13.0
17.0
Cadmium
1.7
0.7
4.3
5.6
Copper
6.6
25.0
35.0
160.0
Chromium
Lead
3.5
1.5
8.6
11.0
Mercury
1.9
0.8
4.2
5.5
Molyb-
denum
14.0
5.9
34.0
45.0
Nickel
14.0
5.9
34.0
45.0
Selenium
6.9
2.9
27.0
23.0
Zinc
32.0
33.0
57.0
150.0
Total
Phos-
horus
7,700
1,400
8,500
9,100
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.84
3.32
0.31
0.15
Arsenic
0.009
0.015
0.008
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.037
Cadmium
0.003
0.005
0.003
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
Copper
0.011
0.166
0.022
0.048
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.247
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.006
0.010
0.005
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
Mercury
0.003
0.005
0.003
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Molyb-
0.023
0.039
0.021
0.014
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.097
denum
Nickel
0.023
0.039
0.021
0.014
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.097
Selenium
0.012
0.019
0.017
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.055
Zinc
0.054
0.219
0.036
0.045
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.354
Total
Phos-
12.874
9.299
5.304
2.748
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
30.225
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
3/1/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
18.9 Acres Permitted: 18.9 Site #: WK-MRF-03 Field #:
28.05
15.3
Danripple
W K-MRF-03
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft
Sample or
Com-
posite
Date
......1..........
Mathis-1
5/18/23
Mathis-1
11/28/23
.....3....
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
3.6
1.4
Arsenic
6.1
17.0
Cadmium
2.0
5.8
Copper
27.0
75.0
Chromium
Lead
4.1
12.0
Mercury
2.0
5.5
Molyb-
denum
16.0
46.0
Nickel
16.0
46.0
Selenium
8.1
23.0
Zinc
36.0
87.0
Total
Phos-
horus
850
8,700
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.87
0.62
Arsenic
0.011
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.032
Cadmium
0.003
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
Copper
0.047
0.093
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.139
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.007
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.022
Mercury
0.003
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Molyb-
0.028
0.057
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.085
denum
Nickel
0.028
0.057
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.085
Selenium
0.014
0.028
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.042
Zinc
0.062
0.107
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.170
Total
Phos-
1.474
10.736
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
12.210
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 45.14
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
25.3 Acres Permitted: 25.3 Site #: WK-MRF-05 Field #:
�Wrmunn1�
�1., a91 / I!A:W I L7
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
Mathis-1
5/18/23
Mathis-1
11/28/23
.....3....
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
3.6
1.4
Arsenic
6.1
17.0
Cadmium
2.0
5.8
Copper
27.0
75.0
Chromium
Lead
4.1
12.0
Mercury
2.0
5.5
Molyb-
denum
16.0
46.0
Nickel
16.0
46.0
Selenium
8.1
23.0
Zinc
36.0
87.0
Total
Phos-
horus
850
8,700
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
1.30
0.49
Arsenic
0.016
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.032
Cadmium
0.005
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
Copper
0.070
0.073
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.143
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.011
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.022
Mercury
0.005
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
Molyb-
0.041
0.045
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.086
denum
Nickel
0.041
0.045
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.086
Selenium
0.021
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.043
Zinc
0.093
0.085
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.178
Total
Phos-
2.203
8.491
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
10.694
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 105.21
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
21 Acres Permitted: 21 Site #: WK-MRF-06 Field #:
Ih /
�Wrmunn1�
W K _ IVI K N'_I1"
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
Mathis-1
5/18/23
Mathis-1
11/28/23
.....3....
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
3.6
1.4
Arsenic
6.1
17.0
Cadmium
2.0
5.8
Copper
27.0
75.0
Chromium
Lead
4.1
12.0
Mercury
2.0
5.5
Molyb-
denum
16.0
46.0
Nickel
16.0
46.0
Selenium
8.1
23.0
Zinc
36.0
87.0
Total
Phos-
horus
850
8,700
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
3.64
1.37
Arsenic
0.044
0.047
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.091
Cadmium
0.015
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.030
Copper
0.197
0.206
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.402
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.030
0.033
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.063
Mercury
0.015
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.030
Molyb-
0.116
0.126
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.243
denum
Nickel
0.116
0.126
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.243
Selenium
0.059
0.063
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.122
Zinc
0.262
0.238
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.500
Total
Phos-
6.188
23.838
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
30.026
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 88.85
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
26.5 Acres Permitted: 26.5 Site #: WK-MRF-12 Field #:
1EM-1
��ruuwau�
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
Mathis-1
5/18/23
Mathis-1
11/28/23
.....3....
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
3.6
1.4
Arsenic
6.1
17.0
Cadmium
2.0
5.8
Copper
27.0
75.0
Chromium
Lead
4.1
12.0
Mercury
2.0
5.5
Molyb-
denum
16.0
46.0
Nickel
16.0
46.0
Selenium
8.1
23.0
Zinc
36.0
87.0
Total
Phos-
horus
850
8,700
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
!.:M W.
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
2.89
0.47
Arsenic
0.035
0.016
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
Cadmium
0.012
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
Copper
0.156
0.070
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.226
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.024
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.035
Mercury
0.012
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
Molyb-
0.092
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.135
denum
Nickel
0.092
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.135
Selenium
0.047
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.068
Zinc
0.208
0.081
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.289
Total
Phos-
4.908
8.108
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
13.016
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 91.27
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
41 Acres Permitted: 41 Site #: WK-MRF-13 Field #:
I i /
�.401H@ �
�1. ,'qL , I !A :ram K�
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
Mathis-1
5/18/23
Mathis-1
11/28/23
.....3....
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
3.6
1.4
Arsenic
6.1
17.0
Cadmium
2.0
5.8
Copper
27.0
75.0
Chromium
Lead
4.1
12.0
Mercury
2.0
5.5
Molyb-
denum
16.0
46.0
Nickel
16.0
46.0
Selenium
8.1
23.0
Zinc
36.0
87.0
Total
Phos-
horus
850
8,700
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
1.60
0.63
Arsenic
0.020
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.041
Cadmium
0.006
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
Copper
0.086
0.094
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.180
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.013
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.028
Mercury
0.006
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Molyb-
0.051
0.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.109
denum
Nickel
0.051
0.058
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.109
Selenium
0.026
0.029
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.055
Zinc
0.115
0.109
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.224
Total
Phos-
2.718
10.910
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
13.628
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 65.95
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
18.5 Acres Permitted: 18.5 Site #: WK-MRF-14 Field #:
�Wrmunn1�
�X'A'91 J I !A:M P �
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
Mathis-1
5/18/23
Mathis-1
11/28/23
.....3....
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
3.6
1.4
Arsenic
6.1
17.0
Cadmium
2.0
5.8
Copper
27.0
75.0
Chromium
Lead
4.1
12.0
Mercury
2.0
5.5
Molyb-
denum
16.0
46.0
Nickel
16.0
46.0
Selenium
8.1
23.0
Zinc
36.0
87.0
Total
Phos-
horus
850
8,700
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
2.95
0.61
Arsenic
0.036
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.057
Cadmium
0.012
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Copper
0.160
0.092
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.251
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.024
0.015
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.039
Mercury
0.012
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Molyb-
0.095
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.151
denum
Nickel
0.095
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.151
Selenium
0.048
0.028
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.076
Zinc
0.213
0.106
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.319
Total
Phos-
5.022
10.631
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
15.653
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 18.50
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
34.9 Acres Permitted: 34.9 Site #: WK-MRF-15 Field #:
I / 4
�.401H@ �
�1., a9,, I!A:ram L7
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Com-
posite
Date
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.53
Arsenic
0.018
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
Cadmium
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
Copper
0.080
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.080
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Mercury
0.006
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.006
Molyb-
0.049
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.049
denum
Nickel
0.049
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.049
Selenium
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.024
Zinc
0.092
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.092
Total
Phos-
9.222
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
9.222
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 28.87
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
52.3 Acres Permitted: 52.3 Site #: WK-MRF-20 Field #:
uvi
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
11/28/23
Tyson-
Wilke
11/28/23
.....3....
Tyson-
Danville
11/28/23
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
1.8
1.4
3.9
Arsenic
13.0
17.0
6.3
Cadmium
4.3
5.6
2.1
Copper
35.0
160.0
4.2
Chromium
Lead
8.6
11.0
4.2
Mercury
4.2
5.5
2.0
Molyb-
denum
34.0
45.0
17.0
Nickel
34.0
45.0
17.0
Selenium
27.0
23.0
8.4
Zinc
57.0
150.0
21.0
Total
Phos-
horus
8,500
9,100
7,400
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.34
0.12
0.09
Arsenic
0.009
0.004
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
Cadmium
0.003
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
0.024
0.039
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.064
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.006
0.003
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Mercury
0.003
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Molyb-
0.023
0.011
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.037
denum
Nickel
0.023
0.011
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.037
Selenium
0.018
0.006
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
Zinc
0.038
0.037
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.079
Total
Phos-
5.712
2.239
1.376
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
9.327
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
3/l /2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 15.04
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
27.8 Acres Permitted: 27.8 Site #: WK-MRF-21 Field #:
lows
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
11/28/23
Tyson-
Wilke
11/28/23
.....3....
Tyson-
Danville
11/28/23
4....
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
1.8
1.4
3.9
Arsenic
13.0
17.0
6.3
Cadmium
4.3
5.6
2.1
Copper
35.0
160.0
4.2
Chromium
Lead
8.6
11.0
4.2
Mercury
4.2
5.5
2.0
Molyb-
denum
34.0
45.0
17.0
Nickel
34.0
45.0
17.0
Selenium
27.0
23.0
8.4
Zinc
57.0
150.0
21.0
Total
Phos-
horus
8,500
9,100
7,400
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.37
0.06
0.10
Arsenic
0.010
0.002
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Cadmium
0.003
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Copper
0.026
0.020
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.047
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.006
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.009
Mercury
0.003
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
Molyb-
0.025
0.006
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.035
denum
Nickel
0.025
0.006
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.035
Selenium
0.020
0.003
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
Zinc
0.043
0.019
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.066
Total
Phos-
6.341
1.165
1.539
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
9.045
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
3/l /2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 26.34
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Johnson, J L Predominant Soil Series:
45.1 Acres Permitted: 45.1 Site #: WK-RJ-05 Field #:
Residual Analvsis Data (Heavv Metals and Total Phosphorus use m2/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
11/28/23
Tyson-
Wilke
11/28/23
.....3....
Tyson-
Danville
11/28/23
4....
AdvPier
9/21/23
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
1.8
1.4
3.9
14.3
Arsenic
13.0
17.0
6.3
1.6
Cadmium
4.3
5.6
2.1
0.5
Copper
35.0
160.0
4.2
300.0
Chromium
Lead
8.6
11.0
4.2
3.6
Mercury
4.2
5.5
2.0
0.6
Molyb-
denum
34.0
45.0
17.0
4.2
Nickel
34.0
45.0
17.0
69.0
Selenium
27.0
23.0
8.4
2.1
Zinc
57.0
150.0
21.0
140.0
Total
Phos-
horus
8,500
9,100
7,400
2,700
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
0.28
0.18
0.04
0.08
Arsenic
0.007
0.006
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
Cadmium
0.002
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
0.020
0.058
0.000
0.047
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.126
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.005
0.004
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Mercury
0.002
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Molyb-
0.019
0.016
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.038
denum
Nickel
0.019
0.016
0.001
0.011
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
Selenium
0.015
0.008
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
Zinc
0.032
0.055
0.002
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.110
Total
Phos-
4.760
3.312
0.636
0.427
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
9.135
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/l /2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
13.5 Acres Permitted: 13.5 Site #: YK-YF-01 Field #:
69.78
14.4
Nathalie
YK-YF-01
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
5/18/23
Tyson-
Wilke
5/16/23
.....3....
RVI-
Harm
11/28/23
4....
Tyson-
Wilke
11/28/23
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
4.3
9.7
1.8
1.4
Arsenic
5.2
2.2
13.0
17.0
Cadmium
1.7
0.7
4.3
5.6
Copper
6.6
25.0
35.0
160.0
Chromium
Lead
3.5
1.5
8.6
11.0
Mercury
1.9
0.8
4.2
5.5
Molyb-
denum
14.0
5.9
34.0
45.0
Nickel
14.0
5.9
34.0
45.0
Selenium
6.9
2.9
27.0
23.0
Zinc
32.0
33.0
57.0
150.0
Total
Phos-
horus
7,700
1,400
8,500
9,100
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
1.36
3.42
0.13
0.27
Arsenic
0.014
0.015
0.003
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.042
Cadmium
0.005
0.005
0.001
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
Copper
0.018
0.171
0.009
0.085
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.283
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.009
0.010
0.002
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.028
Mercury
0.005
0.006
0.001
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Molyb-
0.038
0.040
0.009
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.111
denum
Nickel
0.038
0.040
0.009
0.024
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.111
Selenium
0.019
0.020
0.007
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.058
Zinc
0.087
0.225
0.015
0.080
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.407
Total
Phos-
20.867
9.565
2.261
4.823
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
37.516
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 167.07
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only):
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series:
22.3 Acres Permitted: 22.3 Site #: YK-YF-03 Field #:
14 1
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
5/18/23
Tyson-
Wilke
5/16/23
.....3....
RVI-
Harm
11/28/23
4....
Tyson-
Wilke
11/28/23
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
4.3
9.7
1.8
1.4
Arsenic
5.2
2.2
13.0
17.0
Cadmium
1.7
0.7
4.3
5.6
Copper
6.6
25.0
35.0
160.0
Chromium
Lead
3.5
1.5
8.6
11.0
Mercury
1.9
0.8
4.2
5.5
Molyb-
denum
14.0
5.9
34.0
45.0
Nickel
14.0
5.9
34.0
45.0
Selenium
6.9
2.9
27.0
23.0
Zinc
32.0
33.0
57.0
150.0
Total
Phos-
horus
7,700
1,400
8,500
9,100
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
2.12
4.90
0.26
0.21
Arsenic
0.022
0.022
0.007
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.058
Cadmium
0.007
0.007
0.002
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
Copper
0.028
0.245
0.018
0.067
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.358
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.015
0.015
0.005
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.039
Mercury
0.008
0.008
0.002
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.021
Molyb-
0.059
0.058
0.018
0.019
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.154
denum
Nickel
0.059
0.058
0.018
0.019
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.154
Selenium
0.029
0.028
0.014
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.082
Zinc
0.136
0.323
0.030
0.063
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.552
Total
Phos-
32.694
13.712
4.471
3.804
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
54.681
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
m
3/1/2024
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
23.3 Acres Permitted: 23.3 Site #: YK-YF-04 Field #:
147.93
14.4
Clifford
YK-YF-04
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
5/18/23
Tyson-
Wilke
5/16/23
.....3....
AdvPier
9/21/23
4....
RVI-
Harm
11/28/23
.....5....
Tyson-
Wilke
11/28/23
6....
.........
8....
.....9....
10
11
12
% Solids
4.3
9.7
14.3
1.8
1.4
Arsenic
5.2
2.2
1.6
13.0
17.0
Cadmium
1.7
0.7
0.5
4.3
5.6
Copper
6.6
25.0
300.0
35.0
160.0
Chromium
Lead
3.5
1.5
3.6
8.6
11.0
Mercury
1.9
0.8
0.6
4.2
5.5
Molyb-
denum
14.0
5.9
4.2
34.0
45.0
Nickel
14.0
5.9
69.0
34.0
45.0
Selenium
6.9
2.9
2.1
27.0
23.0
Zinc
32.0
33.0
140.0
57.0
150.0
Total
Phos-
horus
7,700
1,400
2,700
8,500
9,100
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
1.99
3.75
0.15
0.27
0.19
Arsenic
0.021
0.017
0.000
0.007
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
Cadmium
0.007
0.006
0.000
0.002
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
Copper
0.026
0.188
0.092
0.019
0.060
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.386
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.014
0.011
0.001
0.005
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.035
Mercury
0.008
0.006
0.000
0.002
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
Molyb-
0.056
0.044
0.001
0.018
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.137
denum
Nickel
0.056
0.044
0.021
0.018
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.157
Selenium
0.027
0.022
0.001
0.015
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.073
Zinc
0.127
0.248
0.043
0.031
0.057
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.505
Total
Phos-
30.569
10.500
0.832
4.607
3.440
0.000
0.000
0.000
0.000
0.000
0.000
0.000
49.947
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
......................................
Signature of Land Applier
2/28/2023
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Terra Renewal Services, Inc Total Dry Tons Applied (Annual): 205.07
Permit #:
Operator:
Acres Used:
WQ0038087 Cation Exchange Capacity (non 503 only): 14.9
Terra Renewal Services Owner: Mathis Properties, LLC Predominant Soil Series: Fairview
51.5 Acres Permitted: 51.5 Site #: WK-YK-YF-5 Field #: WK-YK-YF-5
Residual Analvsis Data (Heavv Metals and Total Phosphorus use ma/ka, % Solids use Raw Percent #):
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
5/18/23
Tyson-
Wilke
5/16/23
.....3....
AdvPier
9/21/23
4....
RVI-
Harm
11/28/23
.....5....
Tyson-
Wilke
11/28/23
6....
.........
8....
.....9....
10
11
12
% Solids
4.3
9.7
14.3
1.8
1.4
Arsenic
5.2
2.2
1.6
13.0
17.0
Cadmium
1.7
0.7
0.5
4.3
5.6
Copper
6.6
25.0
300.0
35.0
160.0
Chromium
Lead
3.5
1.5
3.6
8.6
11.0
Mercury
1.9
0.8
0.6
4.2
5.5
Molyb-
denum
14.0
5.9
4.2
34.0
45.0
Nickel
14.0
5.9
69.0
34.0
45.0
Selenium
6.9
2.9
2.1
27.0
23.0
Zinc
32.0
33.0
140.0
57.0
150.0
Total
Phos-
horus
7,700
1,400
2,700
8,500
9,100
Annual Heavv Metal Field Loadings (Calculated in Ibs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
1.07
2.40
0.07
0.34
0.10
Arsenic
0.011
0.011
0.000
0.009
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.034
Cadmium
0.004
0.004
0.000
0.003
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.011
Copper
0.014
0.120
0.041
0.024
0.033
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.233
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.007
0.007
0.000
0.006
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.023
Mercury
0.004
0.004
0.000
0.003
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.012
Molyb-
0.030
0.028
0.001
0.023
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.091
denum
Nickel
0.030
0.028
0.010
0.023
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.100
Selenium
0.015
0.014
0.000
0.018
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.052
Zinc
0.068
0.159
0.019
0.039
0.031
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.316
Total
Phos-
16.401
6.728
0.373
5.797
1.893
0.000
0.000
0.000
0.000
0.000
0.000
0.000
31.192
horus
"i certny, unaer penalty of iaw, tnat tms aocument was preparea unaer my airection or supervision in accoraance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name:
Permit #:
Operator:
Acres Used:
Terra Renewal Services, Inc Total Dry Tons Applied (Annual):
WQ0038087
Terra Renewal Services
Cation Exchange Capacity (non 503 only):
Owner: Mathis Properties, LLC Predominant Soil Series:
10.3 Acres Permitted: 10.3 Site #: WK-YF-07 Field #:
67.38
17.1
Fairview
WK-YF-07
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent ft
Sample or
Com-
posite
Date
......1..........
RVI-
Harm
5/18/23
Tyson-
Wilke
5/16/23
.....3....
RVI-
Harm
11/28/23
4....
Tyson-
Wilke
11/28/23
.....5....
6....
.........
8....
.....9....
10
11
12
% Solids
4.3
9.7
1.8
1.4
Arsenic
5.2
2.2
13.0
17.0
Cadmium
1.7
0.7
4.3
5.6
Copper
6.6
25.0
35.0
160.0
Chromium
Lead
3.5
1.5
8.6
11.0
Mercury
1.9
0.8
4.2
5.5
Molyb-
denum
14.0
5.9
34.0
45.0
Nickel
14.0
5.9
34.0
45.0
Selenium
6.9
2.9
27.0
23.0
Zinc
32.0
33.0
57.0
150.0
Total
Phos-
horus
7,700
1,400
8,500
9,100
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
1
2
3
4
5
6
7
8
9
10
11
12
DT/Ac./
y
o
App.
:=
14
Event
1.15
4.95
0.31
0.14
Arsenic
0.012
0.022
0.008
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.046
Cadmium
0.004
0.007
0.003
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
Copper
0.015
0.247
0.021
0.044
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.328
Chromium
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Lead
0.008
0.015
0.005
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.031
Mercury
0.004
0.008
0.003
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.017
Molyb-
0.032
0.058
0.021
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.124
denum
Nickel
0.032
0.058
0.021
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.124
Selenium
0.016
0.029
0.017
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.067
Zinc
0.074
0.327
0.035
0.042
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.477
Total
Phos-
17.695
13.854
5.202
2.530
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
39.281
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance
with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.
I am aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
3/1/2024
Date
DENR FORM MFLSF (12/2006)

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4
Laboratory Analyses:
- Nutrients, Metals, TCLP, Other

®R
cleAnalyfical
Terra Renewal Services, In
PO Box 30136
Russellville, AR 7281!1
Attention: David Coyle
Project Name: SC Samples
Lot Number:YC03,031
gam=4 =0 "47mazom
03122/2023 2:27 Mli
Approved and released by:
Project Manager 11 Lucas OdoiM
ifs
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, ILLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point lDrive West Columbia, SC 29172
Tel: [phone] Fax: 803-791!-91111 www.pacelabs.com
Page 1 of 17
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, ILLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point lDrive West Columbia, SC 29172
Tel: [phone] Fax: 803-791!-91111 www.pacelabs.com
Page 1 of 17

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: YC03031
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Metals
Sample -001 was classified as biosolids therefore in order to ensure proper digestion, the sample was
weighed out around 3.0 - 3.5 grams. The LOQ has been adjusted accordingly.
Inorganic Non -Metals
The Method Blank associated with sample -001 yielded a detection for Nitrate -Nitrite. No corrective action
is required as teh detection in the samples is greater than 1 OX the detection in the blank.
Subcontracted Analysis
The analysis of % Volatile Solids was performed by Waypoint. This data has been ammended to this lot.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 17

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: YC03031
Sample Number Sample ID Matrix Date Sampled Date Received
001 Tyson Harmony Solid 03/02/2023 1330 03/03/2023
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 17

PACE ANALYTICAL SERVICES,
LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: YC03031
Sample
Sample ID
Matrix Parameter Method
Result Q
Units
Page
001
Tyson Harmony
Solid Ammonia - N (gas 350.1
32000
mg/kg
5
001
Tyson Harmony
Solid Nitrate -Nitrite - N (soluble) 353.2
120
mg/kg
5
001
Tyson Harmony
Solid Phosphorus 365.1
12000
mg/kg
5
001
Tyson Harmony
Solid TKN 351.2
54000
mg/kg
5
001
Tyson Harmony
Solid Aluminum 6010D
7600
mg/kg
6
001
Tyson Harmony
Solid Calcium 6010D
16000
mg/kg
6
001
Tyson Harmony
Solid Copper 6010D
13
mg/kg
6
001
Tyson Harmony
Solid Potassium 6010D
6600
mg/kg
6
001
Tyson Harmony
Solid Sodium 6010D
9900
mg/kg
6
001
Tyson Harmony
Solid Zinc 6010D
43
mg/kg
6
(10 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 17

Client: Terra Renewal Services, Inc. Laboratory ID:YC03031-001
Description: Tyson Harmony Matrix: Solid
Date Sampled:03/02/2023 1330 % Solids: 2.16 03/07/2023 1746
Date Received:03/03/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1 350.1
(Ammonia - N ) 350.1
25
03/13/2023 1358 DMA
69904
2
(Nitrate-Nitr) 353.2
1
03/14/2023 1430 MSG
70317
1
(Phosphorus) 365.1
10
03/09/2023 1904 DMA
03/09/2023 1154 69398
1
(Soil pH meas) 9045D
1
03/10/2023 1425 GGC
69735
2 351.4
(TKN) 351.2
2
03/20/2023 1728 BMG2
03/15/2023 1046 70078
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Ammonia - N (gas diffusion)
350.1
32000
12000
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
120
9.2
mg/kg
2
Phosphorus
7723-14-0 365.1
12000
2300
mg/kg
1
Soil pH measured in water @ 12.8 o C
9045D
6.0
su
1
TKN
351.2
54000
4600
mg/kg
2
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 03/06/2023 2323 SAF
03/05/2023 1230 69156
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
780
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
780
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
780
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
780
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
780
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
780
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
780
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
59 41-132
Tetrachloro-m-xylene
63 35-106
CVAA
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 7471 B 7471 B
1 03/10/2023 1632 MRW2
03/11/2023 1155 69202
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Mercury
7439-97-6 7471B
ND
3.6
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 17

Client: Terra Renewal Services, Inc. Laboratory ID:YC03031-001
Description: Tyson Harmony Matrix: Solid
Date Sampled:03/02/2023 1330 % Solids: 2.16 03/07/2023 1746
Date Received:03/03/2023
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 601 OD 1 03/13/2023 0107 JMH 03/06/2023 0958 69182
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
7600
270
mg/kg
1
Arsenic
7440-38-2
601OD
ND
10
mg/kg
1
Cadmium
7440-43-9
601OD
ND
3.4
mg/kg
1
Calcium
7440-70-2
6010D
16000
3400
mg/kg
1
Copper
7440-50-8
6010D
13
6.7
mg/kg
1
Lead
7439-92-1
601OD
ND
6.7
mg/kg
1
Magnesium
7439-95-4
601OD
ND
3400
mg/kg
1
Molybdenum
7439-98-7
601OD
ND
27
mg/kg
1
Nickel
7440-02-0
601OD
ND
27
mg/kg
1
Potassium
7440-09-7
6010D
6600
3400
mg/kg
1
Selenium
7782-49-2
601OD
ND
13
mg/kg
1
Sodium
7440-23-5
6010D
9900
3400
mg/kg
1
Zinc
7440-66-6
6010D
43
34
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 17
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure

Chain of Custody
5TIM
I Lyi MTM I RTMOTO ITINT I =I- I V
Pace Analyfican Services, LLC (fonnerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Pagge 7 of 17

PACE ANALYTICAL SERVICES, LLC
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1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Pagge 8 of 17

PACE ANALYTICAL SERVICES, LLC
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Pace Analytical Services, LLC (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pagge 9 of 17

I 'f
3/21 /2023
Pace Analytical
Lucas Odom
106 Vantage Point Drive
West Columbia, SC, 29172
Ref: Analytical Testing
Lab Report Number: 23-068-0023
Client Project Description: YC03031
Dear Lucas Odom:
449 Springbroak Rd, Charlotte, NC 217
Main 704. 29,636r4
www,waypointarn lytuc lxam
Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/9/2023 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
4JI-% �Z
Jamie Corporaal
Laboratory Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 10 of 17
Page 1 of 8

Way to
�I R�
w #milk, . P
Main 704.529.636A
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2023
North Carolina
State Program
402
12/31/2023
South Carolina
State Program
99012
07/31/2023
South Carolina
State Program
99012
12/31/2022
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/29/2024
Arkansas
State Program
88-0650
02/07/2024
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
11/14/2025
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2023
Louisiana
State Program
- NELAP
LA037
12/31/2023
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
47701
07/31/2023
North Carolina
State Program
415
12/31/2023
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2023
Tennessee
State Program
02027
11/14/2025
Texas
State Program
- NELAP
T104704180
09/30/2023
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 Page 11 of 17 00016/23-068-0023
Page 2 of 8

(D
Waypoint,449
Springbrook
d, Charlotte, NC 28217
Main 704,529.6364
AN�ALYTICALrawtiw.w
ar po1ntanaIytica1.com
Sample Summary Table
Report Number: 23-068-0023
Client Project Description: YCO3O31
Lab No Client Sample ID
Matrix
Date Collected
Date Received Method Lab ID
90748 Tyson Harmony
Solids
03/02/2023 13:30
03/09/2023 11:30 SW-DRYWT WP MTN
90748 Tyson Harmony
Solids
03/02/2023 13:30
03/09/2023 11:30 2540G-2011 WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 12 of 17
Page 3 of 8

(D
Waypoint,449 Springbrook Rd, Charlotte, NC 28217
Main 704.59.6364
AN�ALYTICALrawtiw.w ar pointanaIytica1.com
Summary of Detected Analytes
Project: YC03031
Report Number: 23-068-0023
Client Sample ID Lab Sample ID
Method Parameters Result Units Report Limit Analyzed Qualifiers
Tyson Harmony V 90748
2540G-2011 Total Volatile Solids
SW-DRYWT Moisture
84.3 %
98.5 %
0.010 03/16/202317:06 H
03/16/2023 17:06
Page 13 of 17
Page 4 of 8

I 'f
449 Springbroak Rdl,, Charlotte, NC 217
Maim 704. 29,636r4
www.waypointanalyfical.com
Client: Pace Analytical CASE NARRATIVE
Project: YC03031
Lab Report Number: 23-068-0023
Date: 3/21 /2023
Report Comments
Authorized to run sample outside of hold time per L.Odom.
Page 14 of 17
Page 5 of 8

Way to
PMJLI'1IA
00148
Pace Analytical Project YC03031
Lucas Odom
106 Vantage Point Drive Information
West Columbia , SC 29172
w ti
Main 704.529.63641
Report Number : 23-068-0023 REPORT OFANALYSIS
Report Date : 03/21/2023
Received : 03/09/2023
Lab No : 90748
Sample ID : Tyson Harmony
Matrix: Solids
Sampled: 3/2/2023 13:30
Test
Results Units MQL DF Date / Time By Analytical
Analyzed Method
Moisture
98.5 % 1 03/16/2317:06 CJD SW-DRYWT
Total Volatile Solids
84.3 H % 0.010 1 03/16/23 17:06 CJD 2540G-2011
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
H Beyond holding time
Page 15 of 17
Page 6 of 8

Wayp nt,q
rsr
449 Springbrack Rdi, Chaflatte, NC 28217
Main 70,4.529.6364
w,ww,waiyprow ntaiin,)IIVtical.cot-n
Shipment Receipt Form
Customer Number: 00,148
Customer Nlame- Pace Analytical
Report Number: 23-068-01023
Shipping Method
0 Fed Ex 0 US Postal # Lab
0 UPS 0 Client 0 Courieir
0 Other -
Thermometer 0:
F-
Il R"T 1 5-3--i"C' . .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .... . .. ... . .. .. .
Shipping container/codler uncompromised?
Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample labelI(s)?
Yes
0 No
COO properly complleted
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
* Yes
0 No
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
(0) Yes
* Yes
0 No
0 No
Cooler temperature in compliance?
(0) Yes
0 No
Cooler/Samplles arrived at the laboratory on ice.
Samples were consideredacceptable as cooling
process, had begun.
C Yes
0 No
Water - Sample containers properly preserved
# Yes
0 No
C) N/A
Water - VOA vials, free of headspace
C) Yes
C) No
N/A
Trip Blanks received with VOAs
C) Yes
0 No
N/A
SoH VOA method, 5035 — compliance criteria Imet
0 Yes,
0 No
# N/A
F— High concentration container (48 hr)
F High concentration pre -weighed (methanol - 14 d)
I— Low concentirafion EnCore samplers (48 hr)
I— Low cone pre -weighted vials (Sod is - 14 d)
Special precautions or instructions included?
0 Yes
* No
Comments
cmple recievedthe day h6lding time expired. Authodzed to run sample outside
hdId time per L.O,dom.
gnature: IPaula Blakeborough Date Vflrne03/09/2023 13:21:46 1
Page 16 of 17
Pac ge '7 of 8

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Page 17 of 17
Page 8 of 8

®R
cleAnalyfical
Terra Renewal Services, In
PO Box 30136
Russellville, AR 7281!1
Attention: David Coyle
Project Name: SC Samples
gam=4 =0 "47mazopal
03122/2023 2:2f-Mli
Approved and released by:
Project Manager 11 Lucas OdoiM
ifs
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, ILLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point lDrive West Columbia, Sc 29172
Tel: [phone] Fax: 803-791!-91111 www.pacelabs.com
Page 1 of 16
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, ILLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point lDrive West Columbia, Sc 29172
Tel: [phone] Fax: 803-791!-91111 www.pacelabs.com
Page 1 of 16

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: YC03028
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Metals
Sample -001 was classified as biosolids therefore in order to ensure proper digestion, the sample was
weighed out around 3.0 - 3.5 grams. The LOQ has been adjusted accordingly.
Inorganic Non -Metals
The Method Blank associated with sample -001 yielded a detection for Nitrate -Nitrite. No corrective action
is required as teh detection in the samples is greater than 1 OX the detection in the blank.
Subcontracted Analysis
The analysis of % Volatile Solids was performed by Waypoint. This data has been ammended to this lot.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 16

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: YC03028
Sample Number Sample ID Matrix Date Sampled Date Received
001 Mathis-1 Solid 03/02/2023 0800 03/03/2023
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 16

PACE ANALYTICAL SERVICES, LLC
Sample
Sample ID
001
Mathis-1
001
Mathis-1
001
Mathis-1
001
Mathis-1
001
Mathis-1
001
Mathis-1
001
Mathis-1
001
Mathis-1
(8 detections)
Detection Summary
Terra Renewal Services, Inc.
Lot Number: YC03028
Matrix Parameter Method Result Q Units Page
Solid
Ammonia - N (gas
350.1
7900
mg/kg 6
Solid
Nitrate -Nitrite - N (soluble)
353.2
120 B
mg/kg 6
Solid
Phosphorus
365.1
3000
mg/kg 6
Solid
TKN
351.2
52000
mg/kg 6
Solid
Aluminum
601OD
1400
mg/kg 7
Solid
Copper
601OD
56
mg/kg 7
Solid
Sodium
601OD
8400
mg/kg 7
Solid
Zinc
601OD
64
mg/kg 7
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 16

Client: Terra Renewal Services, Inc. Laboratory ID:YC03028-001
Description: Mathis-1 Matrix: Solid
Date Sampled:03/02/2023 0800 % Solids: 2.26 03/13/2023 1819
Date Received:03/03/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1 350.1
(Ammonia - N ) 350.1
5
03/13/2023 1446 DMA
69904
1
(Nitrate-Nitr) 353.2
1
03/08/2023 1558 CLL2
69576
1
(Phosphorus) 365.1
2
03/09/2023 1904 DMA
03/09/2023 1154 69398
1
(Soil pH meas) 9045D
1
03/10/2023 1420 GGC
69735
1 351.4
(TKN) 351.2
1
03/15/2023 1647 BMG2
03/15/2023 1046 70078
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Ammonia - N (gas diffusion)
350.1
7900
2200
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
120 B
8.9
mg/kg
1
Phosphorus
7723-14-0 365.1
3000
440
mg/kg
1
Soil pH measured in water @ 11.9 o C
9045D
5.5
su
1
TKN
351.2
52000
2200
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 03/06/2023 2216 SAF
03/05/2023 1230 69156
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
750
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
750
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
750
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
750
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
750
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
750
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND S
750
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
63 41-132
Tetrachloro-m-xylene
68 35-106
CVAA
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 7471 B 7471 B
1 03/10/2023 1624 MRW2
03/11/2023 1155 69202
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Mercury
7439-97-6 7471B
ND
3.2
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 16

Client: Terra Renewal Services, Inc. Laboratory ID:YC03028-001
Description: Mathis-1 Matrix: Solid
Date Sampled:03/02/2023 0800 % Solids: 2.26 03/13/2023 1819
Date Received:03/03/2023
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 601 OD 1 03/13/2023 0059 JMH 03/06/2023 0958 69182
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
1400
290
mg/kg
1
Arsenic
7440-38-2
601OD
ND
11
mg/kg
1
Cadmium
7440-43-9
601OD
ND
3.6
mg/kg
1
Calcium
7440-70-2
601OD
ND
3600
mg/kg
1
Copper
7440-50-8
6010D
56
7.1
mg/kg
1
Lead
7439-92-1
601OD
ND
7.1
mg/kg
1
Magnesium
7439-95-4
601OD
ND
3600
mg/kg
1
Molybdenum
7439-98-7
601OD
ND
29
mg/kg
1
Nickel
7440-02-0
601OD
ND
29
mg/kg
1
Potassium
7440-09-7
601OD
ND
3600
mg/kg
1
Selenium
7782-49-2
601OD
ND
14
mg/kg
1
Sodium
7440-23-5
6010D
8400
3600
mg/kg
1
Zinc
7440-66-6
6010D
64
36
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 16
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure

Chain of Custody
5TIM
I Lyi MTM I RTMOTO ITINT I =I- I V
Pace Analyfican Services, LLC (fonnerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Pagge 7 of 16

PACE ANALYTICAL SERVICES, LLC
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Pace Anabytucan Services, LLG (formerly Shealy Environmental Services, Mc. )
1016 "vantage Paint. Drive West Columbia, SC 29172 Q8+83y 791-9700 Fax [phone] www.lpacelalbs.com
Pagge 8 of 16

PACE ANALYTICAL SERVICES, LLC
Ifferlivo Datc 8/2J20,22
Sample Receipt C"becklist (SRC)
`piee,11 TEP.14'ali RE.NTAVAT,
Coolel: rubpictiml byAlate- �'-Mlli 10!43,2) 1.01: i4i, 11"t"03,11 M
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124 YA / NA mC NA INA, tA i N!A
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17—
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LJYL-N Ej No DNA 3� wat all 1: rermwed al of bM777,)--"( wx wm projat -Awagim wof!CO
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Yets No 'iA 4� b the coaumorcial coluirr's 'pacldug slip atmelliol lio tbis, form?
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Yes No LiAll C ot it ni ii w r Mbel jukruumoi i (ID, thi lv, tuwr),
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Z'N"'o l rM 10 DRI Al vampilts anive ill Ttae pup er conminers fur' epcil Its t aitrFor in good caridwian
,vr,l Tv� 'Nrr I L- Was a(�ju,,'ft 0114)!e vtiluMC EMM'11"Ac'?
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aws,mujplc rou,iving, Ivj7-11 ""—ulLof ciii-cle F12SO4. M(A. IR-111, Na()I-i jj-r�jjg Sk pp' NA
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ln1wrilts bekov,
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Pam* Ana hjtjcji'asuit ms, LLC pvp I of I
Pace Ananyfican Services, LLC (fonnerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Pagge 9 of 16

I 'f
3/21 /2023
Pace Analytical
Lucas Odom
106 Vantage Point Drive
West Columbia, SC, 29172
Ref: Analytical Testing
Lab Report Number: 23-068-0021
Client Project Description: YC03028
Dear Lucas Odom:
449 Springbroak Rd, Charlotte, NC 217
Main 704. 29,6364
www,waypointarn lytuc lxam
Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/9/2023 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
4JI-% �Z
Jamie Corporaal
Laboratory Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 10 of 16
Page 1 of 7

Way to
�I R�
w #milk, . P
Main 704.529.636A
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2023
North Carolina
State Program
402
12/31/2023
South Carolina
State Program
99012
07/31/2023
South Carolina
State Program
99012
12/31/2022
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/29/2024
Arkansas
State Program
88-0650
02/07/2024
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
11/14/2025
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2023
Louisiana
State Program
- NELAP
LA037
12/31/2023
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
47701
07/31/2023
North Carolina
State Program
415
12/31/2023
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2023
Tennessee
State Program
02027
11/14/2025
Texas
State Program
- NELAP
T104704180
09/30/2023
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 Page 11 of 16 00016/23-068-0021
Page 2 of 7

(D
Waypoint,449
Springbrook
d, Charlotte, NC 28217
Main 74,529.6364
AN�ALYTICALr
wtiw.w ar po1ntanaIytica1.com
Sample Summary Table
Report Number: 23-068-0021
Client Project Description: YCO3O28
Lab No Client Sample ID
Matrix
Date Collected
Date Received Method Lab ID
90746 Mathis - 1
Solids
03/02/2023 08:00
03/09/2023 11:30 SW-DRYWT WP MTN
90746 Mathis - 1
Solids
03/02/2023 08:00
03/09/2023 11:30 2540G-2011 WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 12 of 16
Page 3 of 7

I 'f
449 Springbroak Rdl,, Charlotte, NC 217
Maim 704. 29,6364
www.waypointanalyfical.com
Client: Pace Analytical CASE NARRATIVE
Project: YC03028
Lab Report Number: 23-068-0021
Date: 3/21 /2023
Report Comments
Authorized to run sample outside of hold time per L.Odom.
Page 13 of 16
Page 4 of 7

Way to
PMJLI'1IA
00148
Pace Analytical Project YC03028
Lucas Odom
106 Vantage Point Drive Information
West Columbia , SC 29172
w ti
Main 704.529.63641
Report Number : 23-068-0021 REPORT OFANALYSIS
Report Date : 03/21/2023
Received : 03/09/2023
Lab No : 90746
Sample ID : Mathis - 1
Matrix: Solids
Sampled: 3/2/2023 8:00
Test
Results Units MQL DF Date / Time By Analytical
Analyzed Method
Moisture
97.8 % 1 03/16/2317:06 CJD SW-DRYWT
Total Volatile Solids
96.7 H % 0.010 1 03/16/23 17:06 CJD 2540G-2011
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
H Beyond holding time
Page 14 of 16
Page 5 of 7

Wayp nt,q
rsr
449 Springbrack Rdi, Chaflatte, NC 28217
Main 70,4.529.6364
w,ww,waiyprow ntaiin,)IIVtical.cot-n
Customer Number: 00,148
Customer Nlame- Pace Analytical
Report Number: 23-068-01021
Shipping Method
0 Fed Ex 0 US Postal # Lab
0 UPS 0 Client 0 Courieir
0 Other -
Thermometer 0:
F-
Il R"T 1 5-3--i"C' . .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .... . .. ... . .. .. .
Shipping container/codler uncompromised?
Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample labelI(s)?
Yes
0 No
COO properly complleted
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
* Yes
0 No
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
(0) Yes
* Yes
0 No
0 No
Cooler temperature in compliance?
(0) Yes
0 No
Cooler/Samplles arrived at the laboratory on ice.
Samples were consideredacceptable as cooling
process, had begun.
C Yes
0 No
Water - Sample containers properly preserved
# Yes
0 No
C) N/A
Water - VOA vials, free of headspace
C) Yes
C) No
N/A
Trip Blanks received with VOAs
C) Yes
0 No
N/A
SoH VOA method, 5035 — compliance criteria Imet
0 Yes,
0 No
# N/A
F- High concentration container (48 hr)
F High concentration pre -weighed (methanol - 14 d)
I— Low concentration EnCore samplers (48 hr)
I— Low cone pre -weighted vials (Sod is - 14 d)
Special precautions or instructions included?
0 Yes
* No
Comments
cmple recievedthe day h6lding time expired. Authodzed to run sample outside
hdId time per L.O,dom.
S�ignature: IPaula Blakeborough Date Vflrne03/09/2023 13:14:43 1
Page 15 of 16
Page 6 of 7

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Page 16 :01 7 of 7

®R
cleAnalyfical
Terra Renewal Services, In
PO Box 30136
Russellville, AR 7281!1
Attention: David Coyle
Project Name: SC Samples
gam=4 =0 "47magoval
03122/2023 2:25 RY-i
Approved and released by:
Project Manager 11 Lucas OdoiM
ifs
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, ILLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point lDrive West Columbia, Sc 29172
Tel: [phone] Fax: 803-791!-91111 www.pacelabs.com
Page 1 of 16
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, ILLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point lDrive West Columbia, Sc 29172
Tel: [phone] Fax: 803-791!-91111 www.pacelabs.com
Page 1 of 16

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: YC03029
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Metals
Sample -001 was classified as biosolids therefore in order to ensure proper digestion, the sample was
weighed out around 3.0 - 3.5 grams. The LOQ has been adjusted accordingly.
Inorganic Non -Metals
The Method Blank associated with sample -001 yielded a detection for Nitrate -Nitrite. No corrective action
is required as teh detection in the samples is greater than 1 OX the detection in the blank.
Subcontracted Analysis
The analysis of % Volatile Solids was performed by Waypoint. This data has been ammended to this lot.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 16

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: YC03029
Sample Number Sample ID Matrix Date Sampled Date Received
001 Tyson Wilkesboro Solid 03/02/2023 0930 03/03/2023
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 16

PACE ANALYTICAL SERVICES,
LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: YC03029
Sample
Sample ID
Matrix Parameter Method
Result Q
Units
Page
001
Tyson Wilkesboro
Solid Ammonia - N (gas 350.1
120
mg/kg
5
001
Tyson Wilkesboro
Solid Nitrate -Nitrite - N (soluble) 353.2
7.8
mg/kg
5
001
Tyson Wilkesboro
Solid Phosphorus 365.1
440
mg/kg
5
001
Tyson Wilkesboro
Solid TKN 351.2
13000
mg/kg
5
001
Tyson Wilkesboro
Solid Copper 601OD
2.5
mg/kg
6
001
Tyson Wilkesboro
Solid Zinc 601OD
3.9
mg/kg
6
(6 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 16

Client: Terra Renewal Services, Inc. Laboratory ID:YC03029-001
Description: Tyson Wilkesboro Matrix: Solid
Date Sampled:03/02/2023 0930 % Solids: 20.7 03/07/2023 1746
Date Received:03/03/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1 350.1
(Ammonia - N ) 350.1
1
03/13/2023 1448 DMA
69904
2
(Nitrate-Nitr) 353.2
1
03/14/2023 1428 MSG
70317
1
(Phosphorus) 365.1
2
03/09/2023 1904 DMA
03/09/2023 1154 69398
1
(Soil pH meas) 9045D
1
03/10/2023 1421 GGC
69735
1 351.4
(TKN) 351.2
5
03/15/2023 1654 BMG2
03/15/2023 1046 70078
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Ammonia - N (gas diffusion)
350.1
120
48
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
7.8
0.96
mg/kg
2
Phosphorus
7723-14-0 365.1
440
48
mg/kg
1
Soil pH measured in water @ 12 o C
9045D
4.1
su
1
TKN
351.2
13000
1200
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 03/06/2023 2257 SAF
03/05/2023 1230 69156
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
80
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
80
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
80
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
80
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
80
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
80
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
80
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
104 41-132
Tetrachloro-m-xylene
100 35-106
CVAA
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 7471 B 7471 B
1 03/10/2023 1626 MRW2
03/11/2023 1155 69202
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Mercury
7439-97-6 7471B
ND
0.37
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 16

Client: Terra Renewal Services, Inc. Laboratory ID:YC03029-001
Description: Tyson Wilkesboro Matrix: Solid
Date Sampled:03/02/2023 0930 % Solids: 20.7 03/07/2023 1746
Date Received:03/03/2023
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 601 OD 1 03/13/2023 0102 JMH 03/06/2023 0958 69182
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
601OD
ND
30
mg/kg
1
Arsenic
7440-38-2
601OD
ND
1.1
mg/kg
1
Cadmium
7440-43-9
601OD
ND
0.37
mg/kg
1
Calcium
7440-70-2
601OD
ND
370
mg/kg
1
Copper
7440-50-8
6010D
2.5
0.74
mg/kg
1
Lead
7439-92-1
601OD
ND
0.74
mg/kg
1
Magnesium
7439-95-4
601OD
ND
370
mg/kg
1
Molybdenum
7439-98-7
601OD
ND
3.0
mg/kg
1
Nickel
7440-02-0
601OD
ND
3.0
mg/kg
1
Potassium
7440-09-7
601OD
ND
370
mg/kg
1
Selenium
7782-49-2
601OD
ND
1.5
mg/kg
1
Sodium
7440-23-5
601OD
ND
370
mg/kg
1
Zinc
7440-66-6
6010D
3.9
3.7
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 16
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure

Chain of Custody
5TIM
I Lyi MTM I RTMOTO ITINT I =I- I V
Pace Analyfican Services, LLC (fonnerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Pagge 7 of 16

PACE ANALYTICAL SERVICES, LLC
Pace Analyfican Services, LLC (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Pagge 8 of 16

PACE ANALYTICAL SERVICES, LLC
DC#-TMw� ENV, F RM Receipt Chr.,,x'*Pi�t tsF.Cj
Pffnth* Date, 4/2jz10Z2
Sample Receipt Checklist (SRC)
C"lk"Itt. TrlkRAu'�,�;Lw.4.7. g1cic"'I byl"Iate- KIM W ; q34!t2'3 L01 4- YCCA"))'�
NOW
C Item F-] T fps Fel T-.X
L - Nvur. Cuumly sv;45 r PCscut Oil 111C co"Al"?
UNY7111111-11
K-JE41,12, it r1woule scar l were tjllinNo 4trul umbrolcim,?
............ ............ .
11111 ' itip a), MA Ctkiine Strip 11): MA Tis' ttd by-, NA
Otiefital, tempmolil j1poll mce�ll iDnived all I.C.Ceipt %SG1ildSVm'p-C11jl
9 r-C, VA J�;jk A(,, NA � NIA NA INA oc,
the elk] eintlill Mu&la�Raausl Buidlc!� IR Ohm M- 0 cc
T Ut fillu CorTerficin Famw
Micifirgid (')f cor"ll!"Aw 1 AV
'A Ice Tre RIC Dukc M
1�
F!�'TID
Jlids L—INO EIN�A 3. Wire oil umit N received at of, b .o',c"o it U0. wmu pioled &FIlagm ImIlhed"
PNI!
4, Is die pacidil slip mulchvxf to this fial
ve P
Yoe, s No 6 wtic wlu - K lqfle couhiazrs'r
L 'alldottsl
ylcs' Nr) Was collectioni
wdDid mlicnritainelafwA W01MAtimi M, dwe, finic)
Z—"Y-�� 17l�4 9, "'try Wts W bc Wforuled bstrd on thr ("W"?
No
Ul Vid all sunples alinve loll the P1101m,m emit'kns for cilcll rest "JuJjljor jr1i 'od CD11'(1iji0j,
t"J
�(wlbrok-cll
lids cm, ezc.1'19
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My-ETRO
-7
1 Wei�c all si mplies %yttidill lv' Ik- liolding rowans t)j 49 Nvhicbtyrr cnmes flow'?
wyesi
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13 V.1'errall, sawl
01 yts
-NO ZKA
57 WZT70A, 80, 15(' Wild RSK- 111 "V'l tite (A Mb—b !Z
diallorter) 41 anyofific'MAvuh.0
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', Wel,'eall DTZ0!wrtmK1mnjo.,j,, s3��jyj(�s re civcd
N A 1 (5 . Wmr a I c wu i0c -,3111 le
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IT Met ILI applICAOIC N"HqtTKN,,;vy-,1wd I e;P miciV625, 1 4M-'� Ujne�,'T) s—m-u-pl, c of
resichial cv.301 itle'?
L]Y1,1
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t"z 4-001C mol liszrd ou the cool label? lies, Qmolt e',„
3mupleftesm,atiou (Alpit tK-, coll fiz ally wiwpiers) Of With
receiveJ mdwene r"dji;btcd luxlrw(lial"
n �Nnqjp�c
mcciviu? wifli 111L 0(clICk mlc�MIS04, IFN03, SRV 0`�
NA
(1141,11 Mic Pfesel`Mwc is netd:d, please ihotov co=smf's lnlorz
--:wnr mcived rum bubblaw >6 nrn inckametec
'ATU' re,0mcd wit TRC > 0ui,2,11 ("Ifoiq m, no) aud wcre
dig t I wcordim& mi sati ircelvilig "Vifl)l S'0611i N Iliosr'L'Ale wi] 0 1",'nique IT) NA
- - - ---------- I
. .............
In
plavtw I of 1,
Pace Anallyfican Services, LLCM (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Pagge 9 of 16

I 'f
3/21 /2023
Pace Analytical
106 Vantage Point Drive
West Columbia, SC, 29172
Ref: Analytical Testing
Lab Report Number: 23-068-0022
Client Project Description: YC03029
449 Springbroak Rd, Charlotte, NC 217
Main 704. 29,6364
www,waypointarn lytuc lxam
Waypoint Analytical, LLC (Charlotte) received sample(s) on 3/9/2023 for the analyses presented in the
following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters were performed in accordance with guidelines established by the USEPA (including 40 CFR 136
Method Update Rule May 2021) unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
4JI-% �Z
Jamie Corporaal
Laboratory Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 10 of 16
Page 1 of 7

Way to
�I R�
w #milk, . P
Main 704.529.636A
Certification Summary
Laboratory ID: WP CNC: Waypoint Analytical Carolina, Inc. (C), Charlotte, NC
State
Program
Lab ID
Expiration Date
North Carolina
State Program
37735
07/31/2023
North Carolina
State Program
402
12/31/2023
South Carolina
State Program
99012
07/31/2023
South Carolina
State Program
99012
12/31/2022
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/29/2024
Arkansas
State Program
88-0650
02/07/2024
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
11/14/2025
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2023
Louisiana
State Program
- NELAP
LA037
12/31/2023
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
47701
07/31/2023
North Carolina
State Program
415
12/31/2023
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2023
Tennessee
State Program
02027
11/14/2025
Texas
State Program
- NELAP
T104704180
09/30/2023
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 Page 11 of 16 00016/23-068-0022
Page 2 of 7

(D
Waypoint,449
5prinbrook
d, Charlotte, NC 2217
Main 704,529.6364
AN�ALYTICALrawtiw.w
ar po1ntanaIytica1.com
Sample Summary Table
Report Number: 23-068-0022
Client Project Description: YCO3O29
Lab No Client Sample ID
Matrix
Date Collected
Date Received Method Lab ID
90747 Tyson Wilkesboro
Solids
03/02/2023 09:30
03/09/2023 11:30 SW-DRYWT WP MTN
90747 Tyson Wilkesboro
Solids
03/02/2023 09:30
03/09/2023 11:30 2540G-2011 WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 12 of 16
Page 3 of 7

I 'f
449 Springbroak Rdl,, Charlotte, NC 217
Maim 704. 29,6364
www.waypointanalyfical.com
Client: Pace Analytical CASE NARRATIVE
Project: YC03029
Lab Report Number: 23-068-0022
Date: 3/21 /2023
Report Comments
Authorized to run sample outside of hold time per L.Odom.
Page 13 of 16
Page 4 of 7

Way to
PMJLI'1IA
00148
Pace Analytical Project YC03029
106 Vantage Point Drive
Information
West Columbia , SC 29172
w ti
Main 704.529.63641
Report Number : 23-068-0022 REPORT OFANALYSIS
Report Date : 03/21/2023
Received : 03/09/2023
Lab No : 90747
Sample ID : Tyson Wilkesboro
Matrix: Solids
Sampled: 3/2/2023 9:30
Test
Results Units MQL DF Date / Time By Analytical
Analyzed Method
Moisture
92.2 % 1 03/16/2317:06 CJD SW-DRYWT
Total Volatile Solids
99.1 H % 0.010 1 03/16/23 17:06 CJD 2540G-2011
Qualifiers/ DF Dilution Factor
Definitions MQL Method Quantitation Limit
H Beyond holding time
Page 14 of 16
Page 5 of 7

Wayp nt,q
rsr
449 Springbrack Rdi, Chaflatte, NC 28217
Main 70,4.529.6364
w,ww,waiyprow ntaiin,)IIVtical.cot-n
Shipment Receipt Form
Customer Number: 00,148
Customer Nlame- Pace Analytical
Report Number: 23-068-01022
Shipping Method
0 Fed Ex 0 US Postal # Lab
0 UPS 0 Client 0 Courieir
0 Other -
Thermometer 0:
F-
Il R"T 1 5-3--i"C' . .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .... . .. ... . .. .. .
Shipping container/codler uncompromised?
Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
Yes
0 No
COC agrees with sample labelI(s)?
Yes
0 No
COO properly complleted
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
* Yes
0 No
Sufficient sample volume for indicated test(s)?
All samples received within holding time?
(0) Yes
* Yes
0 No
0 No
Cooler temperature in compliance?
(0) Yes
0 No
Cooler/Samplles arrived at the laboratory on ice.
Samples were consideredacceptable as cooling
process, had begun.
C Yes
0 No
Water - Sample containers properly preserved
# Yes
0 No
C) N/A
Water - VOA vials, free of headspace
C) Yes
C) No
N/A
Trip Blanks received with VOAs
C) Yes
0 No
N/A
SoH VOA method, 5035 — compliance criteria Imet
0 Yes,
0 No
# N/A
F— High concentration container (48 hr)
F High concentration pre -weighed (methanol - 14 d)
I— Low concentration EnCore samplers (48 hr)
I— Low cone pre -weighted vials (Sod is - 14 d)
Special precautions or instructions included?
0 Yes
* No
Comments
cmple recievedthe day h6lding time expired. Authodzed to run sample outside
hdId time per L.O,dom.
gnature: IPaula Blakeborough Date V03/09/2023 13:18:54 1
Page 15 of 16
Page 6 of 7

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Page 16 of 16
Page 7 of '7

®R
cleAnalyfical
Terra Renewal Services, In
PO Box 30136
Russellville, AR 7281!1
Attention: David Coyle
Project Name: SC Samples
Lot Number:YE22018
0 FUM In Lei IN MA IMNOYA 1^01ris
O2023 2:28 RT
Approved and released by:
Project Manager 11: Lucas OdolM
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, ILLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point lDrive West Columbia, Sc 29172
Tel: [phone] Fax: 803-791!-91111 www.pacel,abs.com
Page 1 of 9

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: YE22018
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
This report supersedes all other versions of the same lot number
Inorganic Metals
Due to low percent solids, sample -001 has been analyzed using three times the method defined amount.
The LOQs have been adjusted accordingly.
Report Revision
Per client request, the analysis of TKN and Ammonia were re -performed. The Ammonia run yielded a
similar result. The TKN value nearly doubled. Both values have been reported.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 9

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: YE22018
Sample Number Sample ID Matrix Date Sampled Date Received
001 TYHARMO Solid 05/18/20231300 05/22/2023
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 9

PACE ANALYTICAL SERVICES,
LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: YE22018
Sample
Sample ID
Matrix Parameter Method
Result Q
Units
Page
001
TYHARMO
Solid % Volatile Solids SM 2540G-
85
%
5
001
TYHARMO
Solid Nitrate -Nitrite - N (soluble) 353.2
59
mg/kg
5
001
TYHARMO
Solid Phosphorus 365.1
7700
mg/kg
5
001
TYHARMO
Solid Ammonia - N (gas 350.1
19000 H
mg/kg
5
001
TYHARMO
Solid TKN 351.2
31000 H
mg/kg
6
001
TYHARMO
Solid Aluminum 6010D
4800
mg/kg
7
001
TYHARMO
Solid Calcium 6010D
23000
mg/kg
7
001
TYHARMO
Solid Copper 6010D
6.6
mg/kg
7
001
TYHARMO
Solid Potassium 6010D
2300
mg/kg
7
001
TYHARMO
Solid Sodium 6010D
3300
mg/kg
7
001
TYHARMO
Solid Zinc 6010D
32
mg/kg
7
(11 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:YE22018-001
Description: TYHARMO Matrix: Solid
Date Sampled:05/18/2023 1300 % Solids: 4.26 05/23/2023 2035
Date Received:05/22/2023
Inorganic
non-metals
Run
Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
05/23/2023 2218 CBP
76021
1
350.1
(Ammonia - N ) 350.1
25
06/02/2023 1048 CMM
76744
2
350.1
(Ammonia - N ) 350.1
25
06/19/2023 1243 CMM
77927
1
(Nitrate-Nitr) 353.2
1
05/26/2023 1547 CLL2
76561
1
(Phosphorus) 365.1
10
05/30/2023 1720 DMA
05/24/2023 2155 76153
1
(Soil pH meas) 9045D
1
05/24/2023 2111 CLL
76327
1
351.4
(TKN) 351.2
1
05/26/2023 1520 DMA
05/25/2023 1536 76152
2
351.4
(TKN) 351.2
2
06/20/2023 1312 BMG2
06/19/2023 2106 78040
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
85
%
1
Nitrate -Nitrite - N (soluble)
353.2
59
4.7
mg/kg
1
Ammonia - N (gas diffusion)
350.1
18000
5900
mg/kg
1
Phosphorus
7723-14-0 365.1
7700
1200
mg/kg
1
Ammonia - N (gas diffusion)
350.1
19000 H
5900
mg/kg
2
Soil pH measured in water @ 19.3 o C
9045D
6.4
su
1
TKN
351.2
17000
1200
mg/kg
1
TKN
351.2
31000 H
2300
mg/kg
2
PCBs by GC
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 8082A
1 05/30/2023 1734 MEZ
05/26/2023 2100 76345
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
400
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
400
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
400
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
400
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
400
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
400
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
400
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
65 41-132
Tetrachloro-m-xylene
63 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 06/01/2023 0935 KAJ 05/31/2023 1550 76364
Parameter
CAS Analytical
Number Method Result Q LOQ
Units Run
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:YE22018-001
Description: TYHARMO Matrix: Solid
Date Sampled:05/18/2023 1300 % Solids: 4.26 05/23/2023 2035
Date Received:05/22/2023
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 7471 B
7471 B
1 06/01/2023 0935 KAJ
05/31/2023 1550 76364
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Mercury
7439-97-6 7471B
ND
1.9
mg/kg
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601OD
1 06/05/2023 1553 LAB
05/31/2023 1925 76607
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 6010D
4800
140
mg/kg
1
Arsenic
7440-38-2 601OD
ND
5.2
mg/kg
1
Cadmium
7440-43-9 601OD
ND
1.7
mg/kg
1
Calcium
7440-70-2 6010D
23000
1700
mg/kg
1
Copper
7440-50-8 6010D
6.6
3.5
mg/kg
1
Lead
7439-92-1 601OD
ND
3.5
mg/kg
1
Magnesium
7439-95-4 601OD
ND
1700
mg/kg
1
Molybdenum
7439-98-7 601OD
ND
14
mg/kg
1
Nickel
7440-02-0 601OD
ND
14
mg/kg
1
Potassium
7440-09-7 6010D
2300
1700
mg/kg
1
Selenium
7782-49-2 601OD
ND
6.9
mg/kg
1
Sodium
7440-23-5 6010D
3300
1700
mg/kg
1
Zinc
7440-66-6 6010D
32
17
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 9
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure

Chain of Custody
5TIM
I Lyi MTM I RTMOTO ITINT I =I- I V
Pace Analyfican Services, LLC (fonnerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 7 of 9

PACE ANALYTICAL SERVICES, LLC
ON
I I 4
A
A
X
I
Pace Analyfican Services, LLC (formerly Shealy Environmental Services, Inc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 8 of 9

PACE ANALYTICAL SERVICES, LLC
DC#Jidei:
Ofective Z)atA#: 8/2/210,22
Sample Revelpt Checklist (SRC
lurawt:7 11"Ok YE2 2,0119
C"alicla hispiccicd 4yktac� I Lot 0:
T _5 C—i —Fr
intact a nd
16-tMod qm*'x�lr "U"Mretll-y
ID r Stnp NA
04*111101 IcirprTamfe upw reed pt 0' De Bawd (�"Ojmcwd) I'ZIUpiclattuc upiml Icccipt 23-244
4-9 'P-119 cC NA iNA NA ',14A v(", N,A�NA t(7
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McOlcd Ofawilaut: wd Ice
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'Yes Imo 6 Wewr "'aliplic IDs listed on the COC and all smiq)k muta6er'?
Y" No 7, Was col lev iw, i irLit .-, & itituc, fisted of.,lac CO C wid at f"lavic coilmi"els
�YCS No, 5 . 1, id alt conuilina Imbel anal orimation (M, dvitc, tiujc) a Mitt, aje COO?
Ycs I r—TN74), 15. Weic tnts to be plafarnicki hsted on UCOCI?
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YV4, No 'wu t � mtcquaic smsirple vokan't mrail abIc?
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diamicter) in noy ixf dic'VOA viab"!
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NA ML OfCh',Je uut. 11"N(Xi, Ns011 usk1g,sK N
NA
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wrir mmmidwith bubbilrs>6 aun in di;:mxlcr,
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Om SerAces, LLC Pace I of I
Pace Anaayficat Services, LLC (fonnerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 9

®R
cleAnalyfical
Terra Renewal Services, In
""Ni Box 30136
Russellville, AR 7281!1
Attention: David Coyle
Project Name: SC Samples
Lot Number:YE22017
gza=s mmotlanommoval
06/07/2023 228 RT
Approved and released by:
Project Manager 11: Lucas OdolM
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, ILLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point lDrive West Columbia, Sc 29172
Tel: [phone] Fax: 803-791!-91111 www.pacel,abs.com
Page 1 of 9

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: YE22017
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Metals
Due to low percent solids, sample -001 has been analyzed using three times the method defined amount.
The LOQs have been adjusted accordingly.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 9

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: YE22017
Sample Number Sample ID Matrix Date Sampled Date Received
001 MATHIS-1 Solid 05/18/20231100 05/22/2023
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 9

PACE ANALYTICAL SERVICES, LLC
Sample
Sample ID
001
MATHIS-1
001
MATHIS-1
001
MATHIS-1
001
MATHIS-1
001
MATHIS-1
001
MATHIS-1
001
MATHIS-1
001
MATHIS-1
(8 detections)
Detection Summary
Terra Renewal Services, Inc.
Lot Number: YE22017
Matrix Parameter Method Result Q Units Page
Solid
% Volatile Solids
SM 2540G-
98
% 5
Solid
Ammonia - N (gas
350.1
2400
mg/kg 5
Solid
Nitrate -Nitrite - N (soluble)
353.2
40
mg/kg 5
Solid
Phosphorus
365.1
850
mg/kg 5
Solid
TKN
351.2
20000
mg/kg 5
Solid
Aluminum
601OD
300
mg/kg 6
Solid
Copper
601OD
27
mg/kg 6
Solid
Zinc
601OD
36
mg/kg 6
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:YE22017-001
Description: MATHIS-1 Matrix: Solid
Date Sampled:05/18/2023 1100 % Solids: 3.64 05/23/2023 2035
Date Received:05/22/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
05/23/2023 2218 CBP
76021
1 350.1
(Ammonia - N ) 350.1
5
06/02/2023 1046 CMM
76744
1
(Nitrate-Nitr) 353.2
1
05/26/2023 1545 CLL2
76561
1
(Phosphorus) 365.1
1
05/30/2023 1729 DMA
05/24/2023 2155 76153
1
(Soil pH meas) 9045D
1
05/24/2023 2110 CLL
76327
1 351.4
(TKN) 351.2
1
05/26/2023 1520 DMA
05/25/2023 1536 76152
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
98
%
1
Ammonia - N (gas diffusion)
350.1
2400
1400
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
40
5.5
mg/kg
1
Phosphorus
7723-14-0 365.1
850
140
mg/kg
1
Soil pH measured in water @ 19.4 o C
9045D
3.6
su
1
TKN
351.2
20000
1400
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 05/31/20231630 SAF
05/23/20231741 75998
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
470
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
470
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
470
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
470
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
470
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
470
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
470
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
69 41-132
Tetrachloro-m-xylene
64 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 06/01/2023 0932 KAJ 05/31/2023 1550 76364
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 2.0
mg/kg 1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:YE22017-001
Description: MATHIS-1 Matrix: Solid
Date Sampled:05/18/2023 1100 % Solids: 3.64 05/23/2023 2035
Date Received:05/22/2023
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 601OD 1 06/05/2023 1550 LAB 05/31/2023 1925 76607
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
300
160
mg/kg
1
Arsenic
7440-38-2
601OD
ND
6.1
mg/kg
1
Cadmium
7440-43-9
601OD
ND
2.0
mg/kg
1
Calcium
7440-70-2
601OD
ND
2000
mg/kg
1
Copper
7440-50-8
6010D
27
4.1
mg/kg
1
Lead
7439-92-1
601OD
ND
4.1
mg/kg
1
Magnesium
7439-95-4
601OD
ND
2000
mg/kg
1
Molybdenum
7439-98-7
601OD
ND
16
mg/kg
1
Nickel
7440-02-0
601OD
ND
16
mg/kg
1
Potassium
7440-09-7
601OD
ND
2000
mg/kg
1
Selenium
7782-49-2
601OD
ND
8.1
mg/kg
1
Sodium
7440-23-5
601OD
ND
2000
mg/kg
1
Zinc
7440-66-6
6010D
36
20
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 9
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure

Chain of Custody
5TIM
I Lyi MTM I RTMOTO ITINT I =I- I V
Pace Analyfican Services, LLC (fonnerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 7 of 9

PACE ANALYTICAL SERVICES, LLC
7
al Z'
s
7
11
Pace Analyfican Services, LLC (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 8 of 9

PACE ANALYTICAL SERVICES, LLC
Effedive
Sample ReMpt(r1teck1kit (SRC)
clica: TEPkk MNEWYAL Ill 111sucOcd bvAulc�, CDR / Lot 4 V E 112017
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S4 pi �q ac NA /N�A. NA 0A aC KA INA -C
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" Icthod of ccohAt: Nw-4 Tvc � ice MOLV Ice
joye, []No LJNA , W 3et e all cooleirs recrive'ri at (it -acto", &1l Itun. Ivas Froji'NI Manam 11o:1bed?
I j7N A PM iv,a!s Notified by- phont "1' taialill, ,i (circle, otw)a
Yes, El Nol j:*flNA 4 hs, flic corl=MW CM16r-s plkckdnt Slip all lvkid's Ru'lu",
5, Were propti atAudypriwedium Yes Fi ROT
4YC51, LjNo 61 Ivele Aliu!p!e IM fis'al 03 k the C101C ap"d lift oulahm, °S?
Fes, No 7r Was colt:kmi dale&, viale h', oc COLa At"', 111, ndaillsall)k "'OutllinevO
1 Nul�� chd ildl "OST1,41film [Awl .3ifni-nultion (JD� (lare. ii
- ,rc ividL thc Call
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ONO 10. Di4lall smupk-s api iin r1w props: cont.idlels fm catch tcv 1,14tol ju good C011(litioll,
101ablokem L& on- etc.)?
11, Was adt(pata smilyk, volill avridable?
12, Wul: nU t-,-Drain es received 'wit Lin `/� lii holdi ng 61ne ar
-owrs r I
ZYOS n) 11 Were rill Naml4ic-,r conuiium accoill for? (No riln.�,Onvmcss)
L:]Yes LJ'No �ZNA 14� Wice VOA� 8015C awi RSK- 115 i-arul1ics free of Boastsit%
diauxler) bi any of tIx VOA vink?
To E,/�NVA 15, Wci c all DR0,1welpiss/burrient sonlipto mcc lived w i pit IV'
"I
NX I& WracilliM a ptl-- 12 mid suffide saAriples, 1p.ceived ata pH >
Yes Mo A
IT Wm e All aphicable ON'lly 05.aWL) su)ples ku. cil:
:]Yct� E]Nu 2MOk
W] Nol [INA 116. NWas Itic ado to janti4xr Usill (ill iJjc, c(iljijjj!jej, I,f ycs QpOite- 11
Pivisturvatiao (M tiMi bc completted for Rill y 5 filrlple(s) hilcul voctly jAzu rVai Or with Le'l dspl 1ce , )p
NA
preserved allid, Nvere adjuved ace wy
soalple reonvint%irlith,mm uZor6jl AM040, HNLO.31 11CL NalOH unit w SR d
uz of pircurvnill "A
wei,t rece-Div ed mith, Libbles >6 nAmn in dianteivjc,
NA
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acconlicsgly III sallple r&6%40gWith SICKULL11, IMUSUlfa,'t (Nni,,14,0.1) kvO, (Till LD-.
Calrullcil
OtuATt 7ax 3, 6675 Pace At tytical WAces,, LLC
Pace Analyficar Services, LLC (fonnerly Shealy Environmental Services, Inc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 9 of 9

®R
cleAnalyfical
Terra Renewal Services, In
""Ni Box 30136
Russellville, AR 7281!1
Attention: David Coyle
Project Name: SC Samples
Lot Number:YE22013
gaE=4 mmotsualmnow
06/07/2023 2:24 Mi.i
Approved and released by:
Project Manager 11: Lucas OdolM
AP6
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, ILLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point lDrive West Columbia, Sc 29172
Tel: [phone] Fax: 803-791!-91111 www.pacel,abs.com
Page 1 of 9

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: YE22013
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Metals
Due to low percent solids, sample -001 has been analyzed using three times the method defined amount.
The LOQs have been adjusted accordingly.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 9

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: YE22013
Sample Number Sample ID Matrix Date Sampled Date Received
001 TYSON WILKESBORO Solid 05/16/2023 0800 05/22/2023
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 9

PACE ANALYTICAL SERVICES,
LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: YE22013
Sample
Sample ID
Matrix Parameter Method
Result Q
Units
Page
001
TYSON WILKESBORO
Solid % Volatile Solids SM 2540G-
98
%
5
001
TYSON WILKESBORO
Solid Ammonia - N (gas 350.1
1600
mg/kg
5
001
TYSON WILKESBORO
Solid Nitrate -Nitrite - N (soluble) 353.2
17
mg/kg
5
001
TYSON WILKESBORO
Solid Phosphorus 365.1
1400
mg/kg
5
001
TYSON WILKESBORO
Solid TKN 351.2
15000
mg/kg
5
001
TYSON WILKESBORO
Solid Aluminum 6010D
260
mg/kg
6
001
TYSON WILKESBORO
Solid Copper 6010D
25
mg/kg
6
001
TYSON WILKESBORO
Solid Zinc 6010D
33
mg/kg
6
(8 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:YE22013-001
Description: TYSON WILKESBORO Matrix: Solid
Date Sampled:05/16/2023 0800 % Solids: 9.73 05/31/2023 2154
Date Received:05/22/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
05/23/2023 2218 CBP
76021
1 350.1
(Ammonia - N ) 350.1
5
06/02/2023 1028 CMM
76744
1
(Nitrate-Nitr) 353.2
1
05/26/2023 1534 CLL2
76561
1
(Phosphorus) 365.1
5
05/30/2023 1657 DMA
05/24/2023 2155 76153
1
(Soil pH meas) 9045D
1
05/24/2023 2052 CLL
76327
1 351.4
(TKN) 351.2
2
05/26/2023 1638 DMA
05/25/2023 1536 76152
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
98
%
1
Ammonia - N (gas diffusion)
350.1
1600
510
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
17
2.1
mg/kg
1
Phosphorus
7723-14-0 365.1
1400
260
mg/kg
1
Soil pH measured in water @ 19.5 o C
9045D
4.2
su
1
TKN
351.2
15000
1000
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 05/31/20231537 SAF
05/23/20231741 75998
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
170
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
170
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
170
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
170
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
170
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
170
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
170
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
69 41-132
Tetrachloro-m-xylene
62 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 06/01/2023 0916 KAJ 05/31/2023 1550 76364
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 0.82
mg/kg 1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 9

Client: Terra Renewal Services, Inc. Laboratory ID:YE22013-001
Description: TYSON WILKESBORO Matrix: Solid
Date Sampled:05/16/2023 0800 % Solids: 9.73 05/31/2023 2154
Date Received:05/22/2023
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 601OD 1 06/05/2023 1508 LAB 05/31/2023 1925 76607
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
260
59
mg/kg
1
Arsenic
7440-38-2
601OD
ND
2.2
mg/kg
1
Cadmium
7440-43-9
601OD
ND
0.74
mg/kg
1
Calcium
7440-70-2
601OD
ND
740
mg/kg
1
Copper
7440-50-8
6010D
25
1.5
mg/kg
1
Lead
7439-92-1
601OD
ND
1.5
mg/kg
1
Magnesium
7439-95-4
601OD
ND
740
mg/kg
1
Molybdenum
7439-98-7
601OD
ND
5.9
mg/kg
1
Nickel
7440-02-0
601OD
ND
5.9
mg/kg
1
Potassium
7440-09-7
601OD
ND
740
mg/kg
1
Selenium
7782-49-2
601OD
ND
2.9
mg/kg
1
Sodium
7440-23-5
601OD
ND
740
mg/kg
1
Zinc
7440-66-6
6010D
33
7.4
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 9
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure

Chain of Custody
5TIM
I Lyi MTM I RTMOTO ITINT I =I- I V
Pace Analyfican Services, LLC (fonnerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 7 of 9

PACE ANALYTICAL SERVICES, LLC
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Pace Analyfican Services, LLC (fonnerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 8 of 9

PACE ANALYTICAL SERVICES, LLC
DC#—TRlw
Effective Datw. 812/2022'
SliMple ReCtij)t CIMdidiSt (SRC")
Mcm TERPARENEVY'AL COOICT In cici byidallz COA 5,12123 YF22'01!
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yes o
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7
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dUstcd accorotntiy iu smlipif4 feccivWg wi, " aluu dukw4fate wak Unique M
Rkialtrax IDI 56360 Pace" Analytical Services, LLC page I of I
Pace Anaayficat Services, LLC (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 9 of 9

®R
cleAnalyfical
Terra Renewal Services, In
PO Box 30136
Russellville, AR 7281!1
Attention: David Coyle
12EMM-M-R
Lot Number:Y120026
gZEL4=0 M moulmanom
10/11/2023 1:42 hT1
Approved and released by:
Project Manager 11: Lucas OdolM
Iw
ifs
pP13J Nat anal Am.' nu tmlarc Eri,zd
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, ILLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point lDrive West Columbia, SC 29172
Tel: [phone] Fax: 803-791!-91111 www.pacelabs.com
Page 1 of 21

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: Y120026
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18, PFAS by Isotope Dilution SOP.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
Inorganic Non -Metals
Y120026-001, Y120026-002, Y120026-003, and Y120026-004 were run at 2X dilutions due to sample
matrix interference causing uneven peaks to form when run at 1X. The data has been reported and LOQs
have been adjusted accordingly.
SVOCs by GC/MS
Surrogate recovery for the following sample was outside control limits: Y120026-002. Evidence of matrix
interference is present; therefore, re -extraction and/or re -analysis was not performed.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 21

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: Y120026
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
Tyson Wilkes
Solid
09/19/2023 0930
09/20/2023
002
Mathis 1
Solid
09/19/2023 1000
09/20/2023
003
Tyson Harmony
Solid
09/19/2023 1045
09/20/2023
004
Wayne Farms Dobson
Solid
09/19/2023 1135
09/20/2023
(4 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 21

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: Y120026
Sample
Sample ID
Matrix
Parameter
Method
Result Q
Units
Page
001
Tyson Wilkes
Solid
Nitrate -Nitrite - N (soluble)
353.2
17
mg/kg
6
001
Tyson Wilkes
Solid
TKN
351.2
62000 S
mg/kg
6
001
Tyson Wilkes
Solid
3+4-Methylphenol
8270E
0.071
mg/L
6
001
Tyson Wilkes
Solid
Barium
6010D
0.56
mg/L
8
001
Tyson Wilkes
Solid
Aluminum
6010D
580
mg/kg
9
001
Tyson Wilkes
Solid
Copper
6010D
75
mg/kg
9
001
Tyson Wilkes
Solid
Zinc
6010D
110
mg/kg
9
002
Mathis 1
Solid
Nitrate -Nitrite - N (soluble)
353.2
43
mg/kg
10
002
Mathis 1
Solid
TKN
351.2
79000 S
mg/kg
10
002
Mathis 1
Solid
Barium
6010D
0.26
mg/L
12
002
Mathis 1
Solid
Aluminum
6010D
700
mg/kg
13
002
Mathis 1
Solid
Copper
6010D
86
mg/kg
13
002
Mathis 1
Solid
Zinc
6010D
130
mg/kg
13
003
Tyson Harmony
Solid
Nitrate -Nitrite - N (soluble)
353.2
8.0
mg/kg
14
003
Tyson Harmony
Solid
TKN
351.2
15000
mg/kg
14
003
Tyson Harmony
Solid
Copper
6010D
24
mg/kg
17
003
Tyson Harmony
Solid
Zinc
6010D
21
mg/kg
17
004
Wayne Farms Dobson
Solid
Nitrate -Nitrite - N (soluble)
353.2
16
mg/kg
18
004
Wayne Farms Dobson
Solid
TKN
351.2
45000
mg/kg
18
004
Wayne Farms Dobson
Solid
Calcium
6010D
3400
mg/kg
18
004
Wayne Farms Dobson
Solid
Copper
6010D
97
mg/kg
18
004
Wayne Farms Dobson
Solid
Zinc
6010D
130
mg/kg
19
(22 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-001
Description: Tyson Wilkes Matrix: Solid
Date Sampled:09/19/2023 0930 % Solids: 6.67 09/21/2023 2219
Date Received: 09/20/2023
Inorganic non-metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Nitrate-Nitr) 353.2 2 09/27/2023 1705 CLL2 86147
1 351.4 (TKN) 351.2 5 09/25/2023 1727 BMG2 09/24/2023 1642 85181
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Nitrate -Nitrite - N (soluble)
353.2
17
6.0
mg/kg
1
TKN
351.2
62000 S
3700
mg/kg
1
TCLP Volatiles
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/5030B
8260D 10 10/04/2023 1341 AMR2
86504 09/20/2023 2025
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Benzene
71-43-2 8260D
ND
0.050
mg/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
0.10
mg/L
1
Carbon tetrachloride
56-23-5 8260D
ND
0.050
mg/L
1
Chlorobenzene
108-90-7 8260D
ND
0.050
mg/L
1
Chloroform
67-66-3 8260D
ND
0.050
mg/L
1
1,2-Dichloroethane
107-06-2 8260D
ND
0.050
mg/L
1
1,1-Dichloroethene
75-35-4 8260D
ND
0.050
mg/L
1
Tetrachloroethene
127-18-4 8260D
ND
0.050
mg/L
1
Trichloroethene
79-01-6 8260D
ND
0.050
mg/L
1
Vinyl chloride
75-01-4 8260D
ND
0.010
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
92 70-130
1,2-Dichloroethane-d4
105 70-130
Toluene-d8
98 70-130
TCLP Semivolatiles
Run Prep Method
1 1311/3520C
Analytical Method Dilution Analysis Date Analyst
8270E 1 10/02/2023 1845 JCG
Prep Date Batch Leachate Date
09/27/2023 1625 85899 09/20/2023 2305
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
mg/L
1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
mg/L
1
Hexachlorobenzene
118-74-1 8270E
ND
0.040
mg/L
1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
mg/L
1
Hexachloroethane
67-72-1 8270E
ND
0.040
mg/L
1
2-Methylphenol
95-48-7 8270E
ND
0.040
mg/L
1
3+4-Methylphenol
106-44-5 8270E
0.071
0.040
mg/L
1
Nitrobenzene
98-95-3 8270E
ND
0.040
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-001
Description: Tyson Wilkes Matrix: Solid
Date Sampled:09/19/2023 0930 % Solids: 6.67 09/21/2023 2219
Date Received:09/20/2023
TCLP Semivolatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E
1 10/02/2023 1845 JCG
09/27/2023 1625 85899 09/20/2023 2305
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
Pentachlorophenol
87-86-5 8270E
ND
0.20
mg/L
1
Pyridine
110-86-1 8270E
ND L
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
72 37-129
2-Fluorophenol
54 24-127
Nitrobenzene-d5
96 38-127
Phenol-d5
67 28-128
Terphenyl-d 14
84 10-148
2,4,6-Tribromophenol
80 41-144
TCLP Herbicides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
2 1311/8151A
8151A
1 10/02/2023 1559 SCC
09/29/2023 1808 86177 09/27/2023 1916
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
2,4-D
94-75-7 8151A
ND
0.020
mg/L
2
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
mg/L
2
Run 2 Acceptance
Surrogate
Q % Recovery Limits
DCAA
60 50-112
PCBs by GC
Run Prep Method
Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C
366013/3665A 8082A
1 10/03/2023 2238 JMR
09/21/2023 1812 85394
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
250
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
250
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
250
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
250
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
250
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
250
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
250
ug/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-001
Description: Tyson Wilkes Matrix: Solid
Date Sampled:09/19/2023 0930 % Solids: 6.67 09/21/2023 2219
Date Received: 09/20/2023
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl 60 41-132
Tetrachloro-m-xylene 70 35-106
TCLP Pesticides
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8081 B 1 09/29/2023 0516 MEZ 09/27/2023 1441 85904 09/20/2023 2305
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
gamma-BHC (Lindane)
58-89-9
8081B
ND
0.00040
mg/L
1
Chlordane
57-74-9
8081B
ND
0.0040
mg/L
1
Endrin
72-20-8
8081B
ND
0.00040
mg/L
1
Heptachlor
76-44-8
8081B
ND
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3
8081 B
ND
0.00040
mg/L
1
Methoxychlor
72-43-5
8081B
ND
0.0016
mg/L
1
Toxaphene
8001-35-2
8081B
ND
0.0080
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
38 20-131
Tetrachloro-m-xylene
100 26-132
TCLP Metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3010A 601 OD 1 09/28/2023 1414 LAB 09/26/2023 0541 85631 09/20/2023 2305
1 1311/7470A 7470A 1 09/26/2023 2314 KJEW 09/25/2023 0930 85481 09/20/2023 2305
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
Units
Run
Arsenic
7440-38-2
601OD
ND
0.15
mg/L
1
Barium
7440-39-3
6010D
0.56
0.25
mg/L
1
Cadmium
7440-43-9
601OD
ND
0.050
mg/L
1
Chromium
7440-47-3
601OD
ND
0.10
mg/L
1
Lead
7439-92-1
601OD
ND
0.10
mg/L
1
Mercury
7439-97-6
7470A
ND
0.0020
mg/L
1
Selenium
7782-49-2
601OD
ND
0.20
mg/L
1
Silver
7440-22-4
601OD
ND
0.10
mg/L
1
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 601OD 1 09/25/20231609 LAB 85469
2 3050B 601OD 1 09/27/20231615 LAB 85469
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-001
Description: Tyson Wilkes Matrix: Solid
Date Sampled:09/19/2023 0930 % Solids: 6.67 09/21/2023 2219
Date Received:09/20/2023
ICP-AES
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601OD 1 09/25/20231609 LAB
85469
2 3050B
601OD 1 09/27/20231615 LAB
85469
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 6010D
580
250
mg/kg
1
Arsenic
7440-38-2 601OD
ND
9.5
mg/kg
1
Cadmium
7440-43-9 601OD
ND
3.2
mg/kg
1
Calcium
7440-70-2 601OD
ND
3200
mg/kg
1
Copper
7440-50-8 6010D
75
6.3
mg/kg
1
Lead
7439-92-1 601OD
ND
6.3
mg/kg
1
Magnesium
7439-95-4 601OD
ND
3200
mg/kg
1
Molybdenum
7439-98-7 601OD
ND
25
mg/kg
1
Nickel
7440-02-0 601OD
ND
25
mg/kg
1
Potassium
7440-09-7 601OD
ND
3200
mg/kg
1
Selenium
7782-49-2 601OD
ND
13
mg/kg
2
Sodium
7440-23-5 601OD
ND
3200
mg/kg
1
Zinc
7440-66-6 6010D
110
32
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-002
Description: Mathis 1 Matrix: Solid
Date Sampled:09/19/2023 1000 % Solids: 2.29 09/21/2023 2219
Date Received: 09/20/2023
Inorganic non-metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Nitrate-Nitr) 353.2 2 09/27/2023 1707 CLL2 86147
1 351.4 (TKN) 351.2 2 09/25/2023 1551 BMG2 09/24/2023 1642 85181
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Nitrate -Nitrite - N (soluble)
353.2
43
17
mg/kg
1
TKN
351.2
79000 S
4400
mg/kg
1
TCLP Volatiles
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/5030B
8260D 10 10/04/2023 1406 AMR2
86504 09/20/2023 2025
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Benzene
71-43-2 8260D
ND
0.050
mg/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
0.10
mg/L
1
Carbon tetrachloride
56-23-5 8260D
ND
0.050
mg/L
1
Chlorobenzene
108-90-7 8260D
ND
0.050
mg/L
1
Chloroform
67-66-3 8260D
ND
0.050
mg/L
1
1,2-Dichloroethane
107-06-2 8260D
ND
0.050
mg/L
1
1,1-Dichloroethene
75-35-4 8260D
ND
0.050
mg/L
1
Tetrachloroethene
127-18-4 8260D
ND
0.050
mg/L
1
Trichloroethene
79-01-6 8260D
ND
0.050
mg/L
1
Vinyl chloride
75-01-4 8260D
ND
0.010
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
96 70-130
1,2-Dichloroethane-d4
95 70-130
Toluene-d8
98 70-130
TCLP Semivolatiles
Run Prep Method
1 1311/3520C
Analytical Method Dilution Analysis Date Analyst
8270E 1 10/02/2023 1909 JCG
Prep Date Batch Leachate Date
09/27/2023 1625 85899 09/20/2023 2305
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
1,4-Dichlorobenzene
106-46-7 8270E
ND Q
0.040
mg/L
1
2,4-Dinitrotoluene
121-14-2 8270E
ND Q
0.080
mg/L
1
Hexachlorobenzene
118-74-1 8270E
ND Q
0.040
mg/L
1
Hexachlorobutadiene
87-68-3 8270E
ND Q
0.040
mg/L
1
Hexachloroethane
67-72-1 8270E
ND Q
0.040
mg/L
1
2-Methylphenol
95-48-7 8270E
ND Q
0.040
mg/L
1
3+4-Methylphenol
106-44-5 8270E
ND Q
0.040
mg/L
1
Nitrobenzene
98-95-3 8270E
ND Q
0.040
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-002
Description: Mathis 1 Matrix: Solid
Date Sampled:09/19/2023 1000 % Solids: 2.29 09/21/2023 2219
Date Received:09/20/2023
TCLP Semivolatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E
1 10/02/2023 1909 JCG
09/27/2023 1625 85899 09/20/2023 2305
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
Pentachlorophenol
87-86-5 8270E
ND Q
0.20
mg/L
1
Pyridine
110-86-1 8270E
ND QL
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND Q
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND Q
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
68 37-129
2-Fluorophenol
N
21 24-127
Nitrobenzene-d5
93 38-127
Phenol-d5
55 28-128
Terphenyl-d 14
86 10-148
2,4,6-Tribromophenol
66 41-144
TCLP Herbicides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
2 1311/8151A
8151A
1 10/02/2023 1622 SCC
09/29/2023 1808 86177 09/27/2023 1916
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
2,4-D
94-75-7 8151A
ND
0.020
mg/L
2
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
mg/L
2
Run 2 Acceptance
Surrogate
Q % Recovery Limits
DCAA
56 50-112
PCBs by GC
Run Prep Method
Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C
366013/3665A 8082A
1 10/03/2023 2251 JMR
09/21/2023 1812 85394
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
740
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
740
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
740
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
740
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
740
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
740
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
740
ug/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-002
Description: Mathis 1 Matrix: Solid
Date Sampled:09/19/2023 1000 % Solids: 2.29 09/21/2023 2219
Date Received: 09/20/2023
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl 63 41-132
Tetrachloro-m-xylene 73 35-106
TCLP Pesticides
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8081 B 1 09/29/2023 0547 MEZ 09/27/2023 1441 85904 09/20/2023 2305
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
gamma-BHC (Lindane)
58-89-9
8081B
ND
0.00040
mg/L
1
Chlordane
57-74-9
8081B
ND
0.0040
mg/L
1
Endrin
72-20-8
8081B
ND
0.00040
mg/L
1
Heptachlor
76-44-8
8081B
ND
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3
8081 B
ND
0.00040
mg/L
1
Methoxychlor
72-43-5
8081B
ND
0.0016
mg/L
1
Toxaphene
8001-35-2
8081B
ND
0.0080
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
58 20-131
Tetrachloro-m-xylene
101 26-132
TCLP Metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3010A 601 OD 1 09/28/2023 1426 LAB 09/26/2023 0541 85631 09/20/2023 2305
1 1311/7470A 7470A 1 09/26/2023 2317 KJEW 09/25/2023 0930 85481 09/20/2023 2305
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
Units
Run
Arsenic
7440-38-2
601OD
ND
0.15
mg/L
1
Barium
7440-39-3
6010D
0.26
0.25
mg/L
1
Cadmium
7440-43-9
601OD
ND
0.050
mg/L
1
Chromium
7440-47-3
601OD
ND
0.10
mg/L
1
Lead
7439-92-1
601OD
ND
0.10
mg/L
1
Mercury
7439-97-6
7470A
ND
0.0020
mg/L
1
Selenium
7782-49-2
601OD
ND
0.20
mg/L
1
Silver
7440-22-4
601OD
ND
0.10
mg/L
1
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 601OD 1 09/25/20231631 LAB 85469
2 3050B 601OD 1 09/27/20231632 LAB 85469
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-002
Description: Mathis 1 Matrix: Solid
Date Sampled:09/19/2023 1000 % Solids: 2.29 09/21/2023 2219
Date Received:09/20/2023
ICP-AES
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601OD 1 09/25/20231631 LAB
85469
2 3050B
601OD 1 09/27/20231632 LAB
85469
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 6010D
700
680
mg/kg
1
Arsenic
7440-38-2 601OD
ND
26
mg/kg
1
Cadmium
7440-43-9 601OD
ND
8.5
mg/kg
1
Calcium
7440-70-2 601OD
ND
8500
mg/kg
1
Copper
7440-50-8 6010D
86
17
mg/kg
1
Lead
7439-92-1 601OD
ND
17
mg/kg
1
Magnesium
7439-95-4 601OD
ND
8500
mg/kg
1
Molybdenum
7439-98-7 601OD
ND
68
mg/kg
1
Nickel
7440-02-0 601OD
ND
68
mg/kg
1
Potassium
7440-09-7 601OD
ND
8500
mg/kg
1
Selenium
7782-49-2 601OD
ND
34
mg/kg
2
Sodium
7440-23-5 601OD
ND
8500
mg/kg
1
Zinc
7440-66-6 6010D
130
85
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-003
Description: Tyson Harmony Matrix: Solid
Date Sampled:09/19/2023 1045 % Solids: 10.7 09/21/2023 2219
Date Received: 09/20/2023
Inorganic non-metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Nitrate-Nitr) 353.2 2 09/27/2023 1708 CLL2 86147
1 351.4 (TKN) 351.2 2 09/25/2023 1558 BMG2 09/24/2023 1642 85181
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Nitrate -Nitrite - N (soluble)
353.2
8.0
3.7
mg/kg
1
TKN
351.2
15000
930
mg/kg
1
TCLP Volatiles
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/5030B
8260D 10 10/04/2023 1431 AMR2
86504 09/20/2023 2025
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Benzene
71-43-2 8260D
ND
0.050
mg/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
0.10
mg/L
1
Carbon tetrachloride
56-23-5 8260D
ND
0.050
mg/L
1
Chlorobenzene
108-90-7 8260D
ND
0.050
mg/L
1
Chloroform
67-66-3 8260D
ND
0.050
mg/L
1
1,2-Dichloroethane
107-06-2 8260D
ND
0.050
mg/L
1
1,1-Dichloroethene
75-35-4 8260D
ND
0.050
mg/L
1
Tetrachloroethene
127-18-4 8260D
ND
0.050
mg/L
1
Trichloroethene
79-01-6 8260D
ND
0.050
mg/L
1
Vinyl chloride
75-01-4 8260D
ND
0.010
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
95 70-130
1,2-Dichloroethane-d4
96 70-130
Toluene-d8
96 70-130
TCLP Semivolatiles
Run Prep Method
1 1311/3520C
Analytical Method Dilution Analysis Date Analyst
8270E 1 10/02/2023 1933 JCG
Prep Date Batch Leachate Date
09/27/2023 1625 85899 09/20/2023 2305
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
mg/L
1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
mg/L
1
Hexachlorobenzene
118-74-1 8270E
ND
0.040
mg/L
1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
mg/L
1
Hexachloroethane
67-72-1 8270E
ND
0.040
mg/L
1
2-Methylphenol
95-48-7 8270E
ND
0.040
mg/L
1
3+4-Methylphenol
106-44-5 8270E
ND
0.040
mg/L
1
Nitrobenzene
98-95-3 8270E
ND
0.040
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-003
Description: Tyson Harmony Matrix: Solid
Date Sampled:09/19/2023 1045 % Solids: 10.7 09/21/2023 2219
Date Received:09/20/2023
TCLP Semivolatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E
1 10/02/2023 1933 JCG
09/27/2023 1625 85899 09/20/2023 2305
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
Pentachlorophenol
87-86-5 8270E
ND
0.20
mg/L
1
Pyridine
110-86-1 8270E
ND L
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
70 37-129
2-Fluorophenol
35 24-127
Nitrobenzene-d5
82 38-127
Phenol-d5
40 28-128
Terphenyl-d 14
84 10-148
2,4,6-Tribromophenol
79 41-144
TCLP Herbicides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
2 1311/8151A
8151A
1 10/02/2023 1645 SCC
09/29/2023 1808 86177 09/27/2023 1916
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
2,4-D
94-75-7 8151A
ND
0.020
mg/L
2
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
mg/L
2
Run 2 Acceptance
Surrogate
Q % Recovery Limits
DCAA
54 50-112
PCBs by GC
Run Prep Method
Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C
366013/3665A 8082A
1 10/03/2023 2304 JMR
09/21/2023 1812 85394
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
160
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
160
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
160
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
160
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
160
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
160
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
160
ug/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-003
Description: Tyson Harmony Matrix: Solid
Date Sampled:09/19/2023 1045 % Solids: 10.7 09/21/2023 2219
Date Received: 09/20/2023
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl 79 41-132
Tetrachloro-m-xylene 90 35-106
TCLP Pesticides
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8081 B 1 09/29/2023 0602 MEZ 09/27/2023 1441 85904 09/20/2023 2305
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
gamma-BHC (Lindane)
58-89-9
8081B
ND
0.00040
mg/L
1
Chlordane
57-74-9
8081B
ND
0.0040
mg/L
1
Endrin
72-20-8
8081B
ND
0.00040
mg/L
1
Heptachlor
76-44-8
8081B
ND
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3
8081 B
ND
0.00040
mg/L
1
Methoxychlor
72-43-5
8081B
ND
0.0016
mg/L
1
Toxaphene
8001-35-2
8081B
ND
0.0080
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
43 20-131
Tetrachloro-m-xylene
93 26-132
TCLP Metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3010A 601 OD 1 09/28/2023 1429 LAB 09/26/2023 0541 85631 09/20/2023 2305
1 1311/7470A 7470A 1 09/26/2023 2330 KJEW 09/25/2023 0930 85481 09/20/2023 2305
CAS
Analytical
Parameter
Number
Method
Result Q
LOQ
Units
Run
Arsenic
7440-38-2
601OD
ND
0.15
mg/L
1
Barium
7440-39-3
601OD
ND
0.25
mg/L
1
Cadmium
7440-43-9
601OD
ND
0.050
mg/L
1
Chromium
7440-47-3
601OD
ND
0.10
mg/L
1
Lead
7439-92-1
601OD
ND
0.10
mg/L
1
Mercury
7439-97-6
7470A
ND
0.0020
mg/L
1
Selenium
7782-49-2
601OD
ND
0.20
mg/L
1
Silver
7440-22-4
601OD
ND
0.10
mg/L
1
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 601OD 1 09/25/20231629 LAB 85469
2 3050B 601OD 1 09/27/20231634 LAB 85469
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 15 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-003
Description: Tyson Harmony Matrix: Solid
Date Sampled:09/19/2023 1045 % Solids: 10.7 09/21/2023 2219
Date Received:09/20/2023
ICP-AES
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601OD 1 09/25/20231629 LAB
85469
2 3050B
601OD 1 09/27/20231634 LAB
85469
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 601OD
ND
160
mg/kg
1
Arsenic
7440-38-2 601OD
ND
6.0
mg/kg
1
Cadmium
7440-43-9 601OD
ND
2.0
mg/kg
1
Calcium
7440-70-2 601OD
ND
2000
mg/kg
1
Copper
7440-50-8 6010D
24
4.0
mg/kg
1
Lead
7439-92-1 601OD
ND
4.0
mg/kg
1
Magnesium
7439-95-4 601OD
ND
2000
mg/kg
1
Molybdenum
7439-98-7 601OD
ND
16
mg/kg
1
Nickel
7440-02-0 601OD
ND
16
mg/kg
1
Potassium
7440-09-7 601OD
ND
2000
mg/kg
1
Selenium
7782-49-2 601OD
ND
8.0
mg/kg
2
Sodium
7440-23-5 601OD
ND
2000
mg/kg
1
Zinc
7440-66-6 6010D
21
20
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-004
Description: Wayne Farms Dobson Matrix: Solid
Date Sampled:09/19/2023 1135 % Solids: 7.24 09/21/2023 2219
Date Received:09/20/2023
Inorganic non-metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 (Nitrate-Nitr) 353.2 2 09/27/2023 1717 CLL2 86147
1 351.4 (TKN) 351.2 5 09/25/2023 1558 BMG2 09/24/2023 1642 85181
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Nitrate -Nitrite - N (soluble)
353.2
16
5.5
mg/kg
1
TKN
351.2
45000
3500
mg/kg
1
PCBs by GC
Run Prep Method Cleanup
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 3660B/3665A
8082A 1 10/03/2023 2317 JMR
09/21/2023 1812 85394
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
230
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
230
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
230
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
230
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
230
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
230
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
230
ug/kg
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
89 41-132
Tetrachloro-m-xylene
99 35-106
ICP-AES
Run Prep Method
1 3050B
2 3050B
Analytical Method Dilution Analysis Date Analyst
601OD 1 09/25/20231627 LAB
601OD 1 09/27/20231637 LAB
Prep Date
Batch
85469
85469
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 601OD
ND
220
mg/kg
1
Arsenic
7440-38-2 601OD
ND
8.3
mg/kg
1
Cadmium
7440-43-9 601OD
ND
2.8
mg/kg
1
Calcium
7440-70-2 6010D
3400
2800
mg/kg
1
Copper
7440-50-8 6010D
97
5.5
mg/kg
1
Lead
7439-92-1 601OD
ND
5.5
mg/kg
1
Magnesium
7439-95-4 601OD
ND
2800
mg/kg
1
Molybdenum
7439-98-7 601OD
ND
22
mg/kg
1
Nickel
7440-02-0 601OD
ND
22
mg/kg
1
Potassium
7440-09-7 601OD
ND
2800
mg/kg
1
Selenium
7782-49-2 601OD
ND
11
mg/kg
2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 17 of 21

Client: Terra Renewal Services, Inc. Laboratory ID:YI20026-004
Description: Wayne Farms Dobson Matrix: Solid
Date Sampled:09/19/2023 1135 % Solids: 7.24 09/21/2023 2219
Date Received:09/20/2023
ICP-AES
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601OD 1 09/25/20231627 LAB
85469
2 3050B
601OD 1 09/27/20231637 LAB
85469
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units Run
Sodium
7440-23-5 601OD
ND
2800
mg/kg 1
Zinc
7440-66-6 6010D
130
28
mg/kg 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 18 of 21

Chain of Custody
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Pace Analyfican Services, LLC (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 19 of 1

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Pace Anabyfican Services, LLC (fomierly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 20 of 21

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Pace Anaayfican Services, LLC (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 21 of 21

®R
cleAnalyfical
Terra Renewal Services, In
PO Box 30136
Russellville, AR 7281!1
Attention: David Coyle
12EMM-M-R
Lot Number:Y121017
10/18/2023 11:05 Affri
Approved and released �by:
Project Manager 11 Lucas OdolM
Iw
pP13J Nat anal Am.' nu tmlarc Eri,zd
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, ILLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point lDrive West Columbia, SC 29172
Tel: [phone] Fax: 803-791!-91111 www.pacelabs.com
Page 1 of I I

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: Y121017
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2-
dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320
B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal
Coliform Colilert-18, PFAS by Isotope Dilution SOP.
Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight
unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Metals
The following samples are classified as biosolids; therefore, the sample amount weighed out is 3.0-3.5
grams to allow for proper digestion: Y121017-001.
Inorganic Non -Metals
Y121017-001 Nitrate -Nitrite was run at 2X dilutions due to sample matrix interference causing uneven
peaks to form when run at 1X. The data has been reported.
TCLP Pesticides
Surrogate recovery for the following sample(s) was outside control limits: Y121017-001. Evidence of
matrix interference is present; therefore, re -extraction and/or re -analysis was not performed.
The laboratory control sample (LCS) for analytical batch 86446 exceeded acceptance criteria for the
following analytes: toxaphene. These analytes were biased high and were not detected in the samples
affected: Y121017-001.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 11

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: Y121017
Sample Number Sample ID Matrix Date Sampled Date Received
001 TYSON CLAREMONT Solid 09/21/2023 0813 09/21/2023
(1 sample)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 11

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: Y121017
Sample
Sample ID
Matrix
Parameter
Method
Result Q
Units
Page
001
TYSON CLAREMONT
Solid
% Volatile Solids
SM 2540G-
94
%
6
001
TYSON CLAREMONT
Solid
Flashpoint (Pensky-
1010B
>140
° F
6
001
TYSON CLAREMONT
Solid
Nitrate -Nitrite - N (soluble)
353.2
7.3
mg/kg
6
001
TYSON CLAREMONT
Solid
Phosphorus
365.1
2700
mg/kg
6
001
TYSON CLAREMONT
Solid
TKN
351.2
27000
mg/kg
6
001
TYSON CLAREMONT
Solid
2-Butanone (MEK)
8260D
0.16
mg/L
6
001
TYSON CLAREMONT
Solid
gamma-BHC (Lindane)
8081 B
0.00060 PQ
mg/L
8
001
TYSON CLAREMONT
Solid
Heptachlor
8081 B
0.00070 PQ
mg/L
8
001
TYSON CLAREMONT
Solid
Aluminum
6010D
8400
mg/kg
9
001
TYSON CLAREMONT
Solid
Calcium
6010D
3200
mg/kg
9
001
TYSON CLAREMONT
Solid
Copper
6010D
300
mg/kg
9
001
TYSON CLAREMONT
Solid
Lead
6010D
3.6
mg/kg
9
001
TYSON CLAREMONT
Solid
Nickel
6010D
69
mg/kg
9
001
TYSON CLAREMONT
Solid
Potassium
6010D
660
mg/kg
9
001
TYSON CLAREMONT
Solid
Sodium
6010D
4000
mg/kg
9
001
TYSON CLAREMONT
Solid
Zinc
6010D
140
mg/kg
9
(16 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 11

Client: Terra Renewal Services, Inc. Laboratory ID:YI21017-001
Description: TYSON CLAREMONT Matrix: Solid
Date Sampled:09/21/2023 0813 % Solids: 14.3 09/27/2023 2015
)ate Received:09/21/2023
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 (% Volatile S) SM 254OG-1997
1 09/27/2023 2309 CBP
85987
1 350.1
(Ammonia - N ) 350.1
1 10/02/2023 0944 CMM
86127
1
(Flashpoint () 1010B
1 09/29/2023 1920 CBP
86420
1
(Nitrate-Nitr) 353.2
2 09/27/2023 1703 CLL2
86147
1
(Phosphorus) 365.1
25 10/04/2023 1909 BMG2
10/02/2023 2024
86253
1
(Reactive Cya) 7.3.3
1 09/26/2023 2015 NAB
09/25/2023 1620
1
(Reactive Sul) 7.3.4
1 09/26/2023 1151 CVR
09/25/2023 1620
1
(Soil pH meas) 9045D
1 09/27/2023 2047 GGC
85989
1 351.4
(TKN) 351.2
5 09/25/2023 1545 BMG2
09/24/2023 1642
85181
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
94
%
1
Ammonia - N (gas diffusion)
350.1
ND S
70
mg/kg
1
Flashpoint (Pensky-Martens Closed -Cup)
1010E
>140
140
o F
1
Nitrate -Nitrite - N (soluble)
353.2
7.3
2.8
mg/kg
1
Phosphorus
7723-14-0 365.1
2700
870
mg/kg
1
Reactive Cyanide
7.3.3
ND
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
mg/kg
1
Soil pH measured in water @ 17.3 o C
9045D
4.6
su
1
TKN
351.2
27000
1700
mg/kg
1
TCLP Volatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/5030B
8260D
10 10/06/20231514 CCO
86758 09/24/20231538
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Benzene
71-43-2 8260D
ND
0.050
mg/L
1
2-Butanone (MEK)
78-93-3 8260D
0.16
0.10
mg/L
1
Carbon tetrachloride
56-23-5 8260D
ND
0.050
mg/L
1
Chlorobenzene
108-90-7 8260D
ND
0.050
mg/L
1
Chloroform
67-66-3 8260D
ND
0.050
mg/L
1
1,2-Dichloroethane
107-06-2 8260D
ND
0.050
mg/L
1
1,1-Dichloroethene
75-35-4 8260D
ND
0.050
mg/L
1
Tetrachloroethene
127-18-4 8260D
ND
0.050
mg/L
1
Trichloroethene
79-01-6 8260D
ND
0.050
mg/L
1
Vinyl chloride
75-01-4 8260D
ND
0.010
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
103 70-130
1,2-Dichloroethane-d4
109 70-130
Toluene-d8
103 70-130
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD
failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 11

Client: Terra Renewal Services, Inc. Laboratory ID:YI21017-001
Description: TYSON CLAREMONT Matrix: Solid
Date Sampled:09/21/2023 0813 % Solids: 14.3 09/27/2023 2015
Date Received:09/21/2023
TCLP Semivolatiles
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E
1 10/05/2023 1558 DJC
09/29/2023 1735 86200 09/22/2023 2319
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
1,4-Dichlorobenzene
106-46-7 8270E
ND Q
0.040
mg/L
1
2,4-Dinitrotoluene
121-14-2 8270E
ND Q
0.080
mg/L
1
Hexachlorobenzene
118-74-1 8270E
ND Q
0.040
mg/L
1
Hexachlorobutadiene
87-68-3 8270E
ND Q
0.040
mg/L
1
Hexachloroethane
67-72-1 8270E
ND Q
0.040
mg/L
1
2-Methylphenol
95-48-7 8270E
ND Q
0.040
mg/L
1
3+4-Methylphenol
106-44-5 8270E
ND Q
0.040
mg/L
1
Nitrobenzene
98-95-3 8270E
ND Q
0.040
mg/L
1
Pentachlorophenol
87-86-5 8270E
ND Q
0.20
mg/L
1
Pyridine
110-86-1 8270E
ND QL
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND Q
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND Q
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
60 37-129
2-Fluorophenol
71 24-127
Nitrobenzene-d5
82 38-127
Phenol-d5
93 28-128
Terphenyl-d 14
73 10-148
2,4,6-Tribromophenol
N
1.1 41-144
TCLP Herbicides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/8151A
8151A
1 10/03/2023 0028 SCC
09/28/2023 1603 86059 09/22/2023 2319
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
2,4-D
94-75-7 8151A
ND
0.020
mg/L
1
2,4,5-TP (Silvex)
93-72-1 8151A
ND
0.0050
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
62 50-112
PCBs by GC
Run Prep Method
Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C
366013/3665A 8082A
1 10/03/2023 0042 JMR
09/29/2023 1701 86194
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
120
ug/kg
1
LOQ = Limit of Quantitation
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above
the LOQ N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD
failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD
failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 11

Client: Terra Renewal Services, Inc. Laboratory ID:YI21017-001
Description: TYSON CLAREMONT Matrix: Solid
Date Sampled:09/21/2023 0813 % Solids: 14.3 09/27/2023 2015
Date Received:09/21/2023
PCBs by GC
Run Prep Method Cleanup
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A
8082A
1 10/03/2023 0042 JMR
09/29/2023 1701 86194
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1221
11104-28-2 8082A
ND
120
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
120
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
120
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
120
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
120
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
120
ug/kg
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
91 41-132
Tetrachloro-m-xylene
90 35-106
TCLP Pesticides
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8081 B
1 10/03/2023 2034 MEZ
09/29/2023 1400 86149 09/22/2023 2319
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
gamma-BHC (Lindane)
58-89-9 8081B 0.00060 PQ
0.00040
mg/L
1
Chlordane
57-74-9 8081B
ND Q
0.0040
mg/L
1
Endrin
72-20-8 8081B
ND Q
0.00040
mg/L
1
Heptachlor
76-44-8 8081B 0.00070 PQ
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3 8081 B
ND Q
0.00040
mg/L
1
Methoxychlor
72-43-5 8081B
ND Q
0.0016
mg/L
1
Toxaphene
8001-35-2 8081B
ND QL
0.0080
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
N
15 20-131
Tetrachloro-m-xylene
N
24 26-132
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 7471 B
7471 B
1 10/06/2023 0947 KAJ
10/04/2023 0834 86438
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Mercury
7439-97-6 7471B
ND
0.55
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 11

Client: Terra Renewal Services, Inc. Laboratory ID:YI21017-001
Description: TYSON CLAREMONT Matrix: Solid
Date Sampled:09/21/2023 0813 % Solids: 14.3 09/27/2023 2015
Date Received:09/21/2023
TCLP Metals
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3010A
601 OD 1 10/06/2023 1122 LAB
09/30/2023 2335 85965 09/22/2023 2319
1 1311/7470A
7470A 1 10/06/2023 1715 KAJ
10/05/2023 1728 86083 09/22/2023 2319
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Arsenic
7440-38-2 601OD
ND
0.15
mg/L
1
Barium
7440-39-3 601OD
ND
0.25
mg/L
1
Cadmium
7440-43-9 601OD
ND
0.050
mg/L
1
Chromium
7440-47-3 601OD
ND
0.10
mg/L
1
Lead
7439-92-1 601OD
ND
0.10
mg/L
1
Mercury
7439-97-6 7470A
ND
0.0020
mg/L
1
Selenium
7782-49-2 601OD
ND
0.20
mg/L
1
Silver
7440-22-4 601OD
ND
0.10
mg/L
1
ICP-AES
Run Prep Method
1 3050B
2 3050B
Analytical Method Dilution Analysis Date Analyst
601OD 1 09/25/2023 1634 LAB
601OD 1 09/27/2023 1639 LAB
Prep Date Batch
09/22/2023 1135 85469
09/22/2023 1135 85469
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 6010D
8400
42
mg/kg
1
Arsenic
7440-38-2 601OD
ND
1.6
mg/kg
1
Cadmium
7440-43-9 601OD
ND
0.53
mg/kg
1
Calcium
7440-70-2 6010D
3200
530
mg/kg
1
Copper
7440-50-8 6010D
300
1.1
mg/kg
1
Lead
7439-92-1 6010D
3.6
1.1
mg/kg
1
Magnesium
7439-95-4 601OD
ND
530
mg/kg
1
Molybdenum
7439-98-7 601OD
ND
4.2
mg/kg
1
Nickel
7440-02-0 6010D
69
4.2
mg/kg
1
Potassium
7440-09-7 6010D
660
530
mg/kg
1
Selenium
7782-49-2 601OD
ND
2.1
mg/kg
2
Sodium
7440-23-5 6010D
4000
530
mg/kg
1
Zinc
7440-66-6 6010D
140
5.3
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 11

Chain of Custody
5TIM
I Lyi MTM I RTMOTO ITINT I =I- I V
Pace Analyfican Services, LLC (fonnerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Pagge 9 of I I

PACE ANALYTICAL SERVICES, LLC
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Pace Anabyfican Services, LLC (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax (B03) 791-9111 www.lpacelabs.com
Page 10 of 1 I

PACE ANALYTICAL SERVICES, LLC
................
GC70-Tit1w,
Effactive Dutw
Sample Receipt Cheddist (SRQ
clicu*: TUJU RLD4rA7.%L Coolew Insmud byldate° BXS2 / 09�21,23 'Lot 11,v =21017
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5-PrvIJces, ILLC page I of I
Pace Ananyfican Services, LLC (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 11

®R
cleAnalyfical
Terra Renewal Services, In
PO Box 30136
Russellville, AR 7281!1
Attention: David Coyle
Project Name: NC Samples
� !Z M =s I=* to] li 0113NOM
0 1 /09/2024 9:24 AM
Approved and released by:
Project Manager 11 Lucas OdolM
pPl3J Nat anal Am. nu tmuurc Eri�rd
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, ILLC.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point lDrive West Columbia, SC 29172
Tel: [phone] Fax: 803-791!-91111 www.pacelabs.com
Page 1 of 26

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: YK28031
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM
2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011,
Fecal Coliform Colilert-18. Where applicable, all soil sample results (including LOQ and DL if requested)
are corrected for dry weight unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Metals
The following samples are classified as biosolids; therefore, the initial amount weighed is 3.0-3.5 grams to
allow for proper digestion: YK28031-001, YK28031-002, YK28031-003, YK28031-004, YK28031-005, and
YK28031-006.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 26

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: YK28031
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
Wilkes -Tyson
Solid
11/28/2023 0700
11/28/2023
002
Harmony -Tyson
Solid
11/28/2023 0730
11/28/2023
003
Mathis 1
Solid
11/28/2023 0800
11/28/2023
004
Dobson
Solid
11/28/2023 0830
11/28/2023
005
Danville
Solid
11/28/2023 0900
11/28/2023
006
Brake Bush
Solid
11/28/2023 0930
11/28/2023
(6 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 26

PACE ANALYTICAL SERVICES, LLC
Detection Summary
Terra Renewal Services, Inc.
Lot Number: YK28031
Sample
Sample ID
Matrix
Parameter
Method
Result Q
Units
Page
001
Wilkes -Tyson
Solid
% Volatile Solids
SM 2540G-
98
%
6
001
Wilkes -Tyson
Solid
Ammonia - N (gas
350.1
5000
mg/kg
6
001
Wilkes -Tyson
Solid
Nitrate -Nitrite - N (soluble)
353.2
59
mg/kg
6
001
Wilkes -Tyson
Solid
Phosphorus
365.1
9100
mg/kg
6
001
Wilkes -Tyson
Solid
TKN
351.2
130000
mg/kg
6
001
Wilkes -Tyson
Solid
Aluminum
601OD
940
mg/kg
7
001
Wilkes -Tyson
Solid
Copper
601OD
160
mg/kg
7
001
Wilkes -Tyson
Solid
Zinc
601OD
150
mg/kg
7
002
Harmony -Tyson
Solid
% Volatile Solids
SM 2540G-
89
%
8
002
Harmony -Tyson
Solid
Ammonia - N (gas
350.1
23000
mg/kg
8
002
Harmony -Tyson
Solid
Nitrate -Nitrite - N (soluble)
353.2
40
mg/kg
8
002
Harmony -Tyson
Solid
Phosphorus
365.1
8500
mg/kg
8
002
Harmony -Tyson
Solid
TKN
351.2
48000
mg/kg
8
002
Harmony -Tyson
Solid
Aluminum
601OD
7700
mg/kg
9
002
Harmony -Tyson
Solid
Calcium
601OD
26000
mg/kg
9
002
Harmony -Tyson
Solid
Copper
601OD
35
mg/kg
9
002
Harmony -Tyson
Solid
Sodium
601OD
6900
mg/kg
9
002
Harmony -Tyson
Solid
Zinc
601OD
57
mg/kg
9
003
Mathis 1
Solid
% Volatile Solids
SM 2540G-
95
%
10
003
Mathis 1
Solid
Ammonia - N (gas
350.1
12000
mg/kg
10
003
Mathis 1
Solid
Nitrate -Nitrite - N (soluble)
353.2
55
mg/kg
10
003
Mathis 1
Solid
Phosphorus
365.1
8700
mg/kg
10
003
Mathis 1
Solid
TKN
351.2
81000
mg/kg
10
003
Mathis 1
Solid
Aluminum
601OD
4900
mg/kg
11
003
Mathis 1
Solid
Calcium
601OD
16000
mg/kg
11
003
Mathis 1
Solid
Copper
601OD
75
mg/kg
11
003
Mathis 1
Solid
Zinc
601OD
87
mg/kg
11
004
Dobson
Solid
% Volatile Solids
SM 2540G-
97
%
12
004
Dobson
Solid
Ammonia - N (gas
350.1
8200
mg/kg
12
004
Dobson
Solid
Nitrate -Nitrite - N (soluble)
353.2
24
mg/kg
12
004
Dobson
Solid
Phosphorus
365.1
3100
mg/kg
12
004
Dobson
Solid
TKN
351.2
43000
mg/kg
12
004
Dobson
Solid
Aluminum
601OD
110
mg/kg
13
004
Dobson
Solid
Calcium
601OD
6000
mg/kg
13
004
Dobson
Solid
Copper
601OD
79
mg/kg
13
004
Dobson
Solid
Potassium
601OD
1000
mg/kg
13
004
Dobson
Solid
Zinc
601OD
140
mg/kg
13
005
Danville
Solid
% Volatile Solids
SM 2540G-
96
%
14
005
Danville
Solid
Ammonia - N (gas
350.1
3100
mg/kg
14
005
Danville
Solid
Flashpoint (Pensky-
1010B
>140
° F
14
005
Danville
Solid
Nitrate -Nitrite - N (soluble)
353.2
25
mg/kg
14
005
Danville
Solid
Paint Filter Test
9095B
Fail
pass/fail
14
005
Danville
Solid
Phosphorus
365.1
7400
mg/kg
14
005
Danville
Solid
TKN
351.2
39000
mg/kg
14
005
Danville
Solid
3+4-Methylphenol
8270E
0.11
mg/L
15
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 26

Detection Summary (Continued)
Lot Number: YK28031
Sample
Sample ID
Matrix
Parameter
Method
Result Q
Units
Page
005
Danville
Solid
Calcium
601OD
3600
mg/kg
17
006
Brake Bush
Solid
% Volatile Solids
SM 2540G-
93
%
18
006
Brake Bush
Solid
Ammonia - N (gas
350.1
13000
mg/kg
18
006
Brake Bush
Solid
Flashpoint (Pensky-
1010B
>140
° F
18
006
Brake Bush
Solid
Nitrate -Nitrite - N (soluble)
353.2
38
mg/kg
18
006
Brake Bush
Solid
Paint Filter Test
9095B
Fail
pass/fail
18
006
Brake Bush
Solid
Phosphorus
365.1
6700
mg/kg
18
006
Brake Bush
Solid
TKN
351.2
52000
mg/kg
18
006
Brake Bush
Solid
3+4-Methylphenol
8270E
0.48
mg/L
19
006
Brake Bush
Solid
Barium
601OD
0.32
mg/L
21
006
Brake Bush
Solid
Calcium
601OD
16000
mg/kg
21
(56 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-001
Description: Wilkes -Tyson Matrix: Solid
Date Sampled:11/28/2023 0700 % Solids: 1.43 12/04/2023 2215
Date Received:11/28/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/04/2023 2252 CBP
91461
1 350.1
(Ammonia - N ) 350.1
5
12/06/2023 1150 CMM
91029
1
(Nitrate-Nitr) 353.2
1
12/06/2023 1451 CLL2
91745
1
(Phosphorus) 365.1
5
12/04/2023 1306 BMG2
12/03/2023 2049 91349
1
(Soil pH meas) 9045D
1
11/29/2023 1613 BMG2
89994
1 351.4
(TKN) 351.2
2
12/04/2023 1858 BMG2
12/03/2023 2020 91348
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
98
%
1
Ammonia - N (gas diffusion)
350.1
5000
3500
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
59
14
mg/kg
1
Phosphorus
7723-14-0 365.1
9100
1700
mg/kg
1
Soil pH measured in water @ 13.5 o C
9045D
4.2
su
1
TKN
351.2
130000
7000
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 3550C 366013/3665A 8082A
1 12/11/2023 1137 JMR
12/06/2023 1646 91638
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
1200
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
1200
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
1200
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
1200
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
1200
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
1200
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
1200
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
90 41-132
Tetrachloro-m-xylene
73 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/09/2023 0351 KAJ 12/01 /2023 0848 91084
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 5.5
mg/kg 1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-001
Description: Wilkes -Tyson Matrix: Solid
Date Sampled:11/28/2023 0700 % Solids: 1.43 12/04/2023 2215
Date Received:11/28/2023
ICP-AES
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601 OD 1 12/19/2023 0303 LAB
12/01/2023 1100 91195
2 3050B
601OD 1 12/29/2023 1827 JMT2
12/01/2023 1100 91195
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 6010D
940
450
mg/kg
2
Arsenic
7440-38-2 601OD
ND
17
mg/kg
1
Cadmium
7440-43-9 601OD
ND
5.6
mg/kg
2
Calcium
7440-70-2 601OD
ND
5600
mg/kg
1
Copper
7440-50-8 6010D
160
11
mg/kg
2
Lead
7439-92-1 601OD
ND
11
mg/kg
2
Magnesium
7439-95-4 601OD
ND
5600
mg/kg
2
Molybdenum
7439-98-7 601OD
ND
45
mg/kg
2
Nickel
7440-02-0 601OD
ND
45
mg/kg
2
Potassium
7440-09-7 601OD
ND
5600
mg/kg
2
Selenium
7782-49-2 601OD
ND
23
mg/kg
2
Sodium
7440-23-5 601OD
ND
5600
mg/kg
1
Zinc
7440-66-6 6010D
150
56
mg/kg
2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-002
Description: Harmony -Tyson Matrix: Solid
Date Sampled:11/28/2023 0730 % Solids: 1.80 12/08/2023 0000
Date Received:11/28/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/04/2023 2252 CBP
91461
1 350.1
(Ammonia - N ) 350.1
25
12/06/2023 1152 CMM
91029
1
(Nitrate-Nitr) 353.2
1
12/06/2023 1453 CLL2
91745
1
(Phosphorus) 365.1
5
12/04/2023 1342 BMG2
12/03/2023 2049 91349
1
(Soil pH meas) 9045D
1
11/29/2023 1615 BMG2
89994
1 351.4
(TKN) 351.2
1
12/04/2023 1850 BMG2
12/03/2023 2020 91348
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
89
%
1
Ammonia - N (gas diffusion)
350.1
23000
14000
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
40
11
mg/kg
1
Phosphorus
7723-14-0 365.1
8500
1400
mg/kg
1
Soil pH measured in water @ 13.2 o C
9045D
6.3
su
1
TKN
351.2
48000
2800
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 12/11/2023 1150 JMR
12/06/2023 1646 91638
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
940
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
940
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
940
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
940
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
940
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
940
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
940
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
89 41-132
Tetrachloro-m-xylene
70 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/09/2023 0354 KAJ 12/01 /2023 0848 91084
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 4.2
mg/kg 1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-002
Description: Harmony -Tyson Matrix: Solid
Date Sampled:11/28/2023 0730 % Solids: 1.80 12/08/2023 0000
Date Received:11/28/2023
ICP-AES
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601 OD 1 12/19/2023 0309 LAB
12/01/2023 1100 91195
2 3050B
601OD 1 12/29/2023 1830 JMT2
12/01/2023 1100 91195
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 6010D
7700
340
mg/kg
2
Arsenic
7440-38-2 601OD
ND
13
mg/kg
1
Cadmium
7440-43-9 601OD
ND
4.3
mg/kg
2
Calcium
7440-70-2 6010D
26000
4300
mg/kg
1
Copper
7440-50-8 6010D
35
8.6
mg/kg
2
Lead
7439-92-1 601OD
ND
8.6
mg/kg
2
Magnesium
7439-95-4 601OD
ND
4300
mg/kg
2
Molybdenum
7439-98-7 601OD
ND
34
mg/kg
2
Nickel
7440-02-0 601OD
ND
34
mg/kg
2
Potassium
7440-09-7 601OD
ND
4300
mg/kg
2
Selenium
7782-49-2 601OD
ND
17
mg/kg
2
Sodium
7440-23-5 6010D
6900
4300
mg/kg
1
Zinc
7440-66-6 6010D
57
43
mg/kg
2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-003
Description: Mathis 1 Matrix: Solid
Date Sampled:11/28/2023 0800 % Solids: 1.37 12/04/2023 2215
Date Received:11/28/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/04/2023 2252 CBP
91461
1 350.1
(Ammonia - N ) 350.1
5
12/06/2023 1154 CMM
91029
1
(Nitrate-Nitr) 353.2
1
12/06/2023 1454 CLL2
91745
1
(Phosphorus) 365.1
5
12/04/2023 1342 BMG2
12/03/2023 2049 91349
1
(Soil pH meas) 9045D
1
11/29/2023 1618 BMG2
89994
1 351.4
(TKN) 351.2
1
12/04/2023 1850 BMG2
12/03/2023 2020 91348
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
95
%
1
Ammonia - N (gas diffusion)
350.1
12000
3700
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
55
15
mg/kg
1
Phosphorus
7723-14-0 365.1
8700
1800
mg/kg
1
Soil pH measured in water @ 14.7 o C
9045D
5.5
su
1
TKN
351.2
81000
3700
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 12/11/2023 1203 JMR
12/06/2023 1646 91638
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
1200
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
1200
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
1200
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
1200
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
1200
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
1200
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
1200
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
92 41-132
Tetrachloro-m-xylene
74 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/09/2023 0356 KAJ 12/01 /2023 0848 91084
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 5.5
mg/kg 1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-003
Description: Mathis 1 Matrix: Solid
Date Sampled:11/28/2023 0800 % Solids: 1.37 12/04/2023 2215
Date Received:11/28/2023
ICP-AES
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601 OD 1 12/19/2023 0315 LAB
12/01/2023 1100 91195
2 3050B
601OD 1 12/29/2023 1832 JMT2
12/01/2023 1100 91195
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 6010D
4900
460
mg/kg
2
Arsenic
7440-38-2 601OD
ND
17
mg/kg
1
Cadmium
7440-43-9 601OD
ND
5.8
mg/kg
2
Calcium
7440-70-2 6010D
16000
5800
mg/kg
1
Copper
7440-50-8 6010D
75
12
mg/kg
2
Lead
7439-92-1 601OD
ND
12
mg/kg
2
Magnesium
7439-95-4 601OD
ND
5800
mg/kg
2
Molybdenum
7439-98-7 601OD
ND
46
mg/kg
2
Nickel
7440-02-0 601OD
ND
46
mg/kg
2
Potassium
7440-09-7 601OD
ND
5800
mg/kg
2
Selenium
7782-49-2 601OD
ND
23
mg/kg
2
Sodium
7440-23-5 601OD
ND
5800
mg/kg
1
Zinc
7440-66-6 6010D
87
58
mg/kg
2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-004
Description: Dobson Matrix: Solid
Date Sampled:11/28/2023 0830 % Solids: 9.28 12/04/2023 2215
Date Received:11/28/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/04/2023 2252 CBP
91461
1 350.1
(Ammonia - N ) 350.1
50
12/06/2023 1338 CMM
91029
1
(Nitrate-Nitr) 353.2
1
12/06/2023 1456 CLL2
91745
1
(Phosphorus) 365.1
10
12/04/2023 1342 BMG2
12/03/2023 2049 91349
1
(Soil pH meas) 9045D
1
12/05/2023 1414 BMG2
91448
1 351.4
(TKN) 351.2
5
12/04/2023 1858 BMG2
12/03/2023 2020 91348
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
97
%
1
Ammonia - N (gas diffusion)
350.1
8200
5400
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
24
2.2
mg/kg
1
Phosphorus
7723-14-0 365.1
3100
540
mg/kg
1
Soil pH measured in water @ 11.2 o C
9045D
5.6
su
1
TKN
351.2
43000
2700
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 12/11/2023 1216 JMR
12/06/2023 1646 91638
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
180
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
180
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
180
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
180
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
180
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
180
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
180
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
94 41-132
Tetrachloro-m-xylene
75 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/09/2023 0359 KAJ 12/01 /2023 0848 91084
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 0.87
mg/kg 1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-004
Description: Dobson Matrix: Solid
Date Sampled:11/28/2023 0830 % Solids: 9.28 12/04/2023 2215
Date Received:11/28/2023
ICP-AES
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601 OD 1 12/19/2023 0322 LAB
12/01/2023 1100 91195
2 3050B
601OD 1 12/29/2023 1835 JMT2
12/01/2023 1100 91195
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 6010D
110
71
mg/kg
2
Arsenic
7440-38-2 601OD
ND
2.6
mg/kg
1
Cadmium
7440-43-9 601OD
ND
0.88
mg/kg
2
Calcium
7440-70-2 6010D
6000
880
mg/kg
1
Copper
7440-50-8 6010D
79
1.8
mg/kg
2
Lead
7439-92-1 601OD
ND
1.8
mg/kg
2
Magnesium
7439-95-4 601OD
ND
880
mg/kg
2
Molybdenum
7439-98-7 601OD
ND
7.1
mg/kg
2
Nickel
7440-02-0 601OD
ND
7.1
mg/kg
2
Potassium
7440-09-7 6010D
1000
880
mg/kg
2
Selenium
7782-49-2 601OD
ND
3.5
mg/kg
2
Sodium
7440-23-5 601OD
ND
880
mg/kg
1
Zinc
7440-66-6 6010D
140
8.8
mg/kg
2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-005
Description: Danville Matrix: Solid
Date Sampled:11/28/2023 0900 % Solids: 3.87 12/04/2023 2215
Date Received:11/28/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/04/2023 2252 CBP
91461
1 350.1
(Ammonia - N ) 350.1
10
12/06/2023 1158 CMM
91029
1
(Flashpoint () 1010B
1
11/29/2023 2008 NAB
91165
1
(Nitrate-Nitr) 353.2
1
12/06/2023 1458 CLL2
91745
1
(Paint Filter) 9095B
1
12/11/2023 1829 GGC
1
(Phosphorus) 365.1
10
12/04/2023 1342 BMG2
12/03/2023 2049 91349
1
(Reactive Cya) 7.3.3
1
12/13/2023 2037 NAB
12/10/2023 1721
1
(Reactive Sul) 7.3.4
1
12/13/2023 1238 CLL2
12/10/2023 1721
1
(Soil pH meas) 9045D
1
12/05/2023 1415 BMG2
91448
1 351.4
(TKN) 351.2
2
12/04/2023 1858 BMG2
12/03/2023 2020 91348
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
96
%
1
Ammonia - N (gas diffusion)
350.1
3100
2600
mg/kg
1
Flashpoint (Pensky-Martens Closed -Cup)
1010E
>140
140
° F
1
Nitrate -Nitrite - N (soluble)
353.2
25
5.2
mg/kg
1
Paint Filter Test
9095E
Fail
pass/fail
1
Phosphorus
7723-14-0 365.1
7400
1300
mg/kg
1
Reactive Cyanide
7.3.3
ND
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
mg/kg
1
Soil pH measured in water @ 11 ° C
9045D
3.7
su
1
TKN
351.2
39000
2600
mg/kg
1
TCLP Volatiles
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/5030B 8260D
10 12/05/2023 1225 AMR2
91493 11/29/2023 1245
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Benzene
71-43-2 8260D
ND
0.050
mg/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
0.10
mg/L
1
Carbon tetrachloride
56-23-5 8260D
ND
0.050
mg/L
1
Chlorobenzene
108-90-7 8260D
ND
0.050
mg/L
1
Chloroform
67-66-3 8260D
ND
0.050
mg/L
1
1,2-Dichloroethane
107-06-2 8260D
ND
0.050
mg/L
1
1,1-Dichloroethene
75-35-4 8260D
ND
0.050
mg/L
1
Tetrachloroethene
127-18-4 8260D
ND
0.050
mg/L
1
Trichloroethene
79-01-6 8260D
ND
0.050
mg/L
1
Vinyl chloride
75-01-4 8260D
ND
0.010
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-005
Description: Danville Matrix: Solid
Date Sampled:11/28/2023 0900 % Solids: 3.87 12/04/2023 2215
)ate Received:11/28/2023
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
102 70-130
1,2-Dichloroethane-d4
ill 70-130
Toluene-d8
ill 70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E 1 12/06/2023 1517 JCG
11/30/2023 1345 91141 11/29/2023 1245
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
mg/L
1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
mg/L
1
Hexachlorobenzene
118-74-1 8270E
ND
0.040
mg/L
1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
mg/L
1
Hexachloroethane
67-72-1 8270E
ND
0.040
mg/L
1
2-Methylphenol
95-48-7 8270E
ND
0.040
mg/L
1
3+4-Methylphenol
106-44-5 8270E
0.11
0.040
mg/L
1
Nitrobenzene
98-95-3 8270E
ND
0.040
mg/L
1
Pentachlorophenol
87-86-5 8270E
ND
0.20
mg/L
1
Pyridine
110-86-1 8270E
ND
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
55 37-129
2-Fluorophenol
38 24-127
Nitrobenzene-d5
55 38-127
Phenol-d5
72 28-128
Terphenyl-d 14
77 10-148
2,4,6-Tribromophenol
57 41-144
TCLP Herbicides
Run Prep Method
Analytical Method Dilution Analysis Date Analyst Prep Date
Batch Leachate Date
1 1311/8151A
8151A 1 12/06/2023 1624 JMR 11/30/2023 1122 91143 11/29/2023 1245
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units Run
2,4-D
94-75-7 8151A ND
0.020
mg/L 1
2,4,5-TP (Silvex)
93-72-1 8151A ND
0.0050
mg/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
82 50-112
LOQ = Limit of Quantitation
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 15 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-005
Description: Danville Matrix: Solid
Date Sampled:11/28/2023 0900 % Solids: 3.87 12/04/2023 2215
Date Received:11/28/2023
PCBs by GC
Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3550C 366013/3665A 8082A 1 12/11/2023 1230 JMR 12/06/2023 1646 91638
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Aroclor 1016
12674-11-2
8082A
ND
430
ug/kg
1
Aroclor 1221
11104-28-2
8082A
ND
430
ug/kg
1
Aroclor 1232
11141-16-5
8082A
ND
430
ug/kg
1
Aroclor 1242
53469-21-9
8082A
ND
430
ug/kg
1
Aroclor 1248
12672-29-6
8082A
ND
430
ug/kg
1
Aroclor 1254
11097-69-1
8082A
ND
430
ug/kg
1
Aroclor 1260
11096-82-5
8082A
ND
430
ug/kg
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
89 41-132
Tetrachloro-m-xylene
70 35-106
TCLP Pesticides
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8081B 1 12/01/20231747 MEZ 11/30/2023 1314 91142 11/29/2023 1245
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
gamma-BHC (Lindane)
58-89-9
8081B
ND
0.00040
mg/L
1
Chlordane
57-74-9
8081B
ND
0.0040
mg/L
1
Endrin
72-20-8
8081B
ND
0.00040
mg/L
1
Heptachlor
76-44-8
8081B
ND
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3
8081 B
ND
0.00040
mg/L
1
Methoxychlor
72-43-5
8081B
ND
0.0016
mg/L
1
Toxaphene
8001-35-2
8081B
ND
0.0080
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
78 20-131
Tetrachloro-m-xylene
83 26-132
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/09/2023 0407 KAJ 12/01 /2023 0848 91084
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 2.0
mg/kg 1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 16 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-005
Description: Danville Matrix: Solid
Date Sampled:11/28/2023 0900 % Solids: 3.87 12/04/2023 2215
Date Received:11/28/2023
TCLP Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3010A
601OD
1 12/29/2023 1924 JMT2
12/03/2023 0121 91272 11/29/2023 1245
1 1311/7470A
7470A
1 12/12/2023 1246 KAJ
12/06/2023 0719 91337 11/29/2023 1245
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Arsenic
7440-38-2 601OD
ND
0.15
mg/L
1
Barium
7440-39-3 601OD
ND
0.25
mg/L
1
Cadmium
7440-43-9 601OD
ND
0.050
mg/L
1
Chromium
7440-47-3 601OD
ND
0.10
mg/L
1
Lead
7439-92-1 601OD
ND
0.10
mg/L
1
Mercury
7439-97-6 7470A
ND
0.0020
mg/L
1
Selenium
7782-49-2 601OD
ND
0.20
mg/L
1
Silver
7440-22-4 601OD
ND
0.10
mg/L
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601 OD
1 12/19/2023 0328 LAB
12/01/2023 1100 91195
2 3050B
601OD
1 12/29/2023 1924 JMT2
12/01/2023 1100 91195
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 601OD
ND
170
mg/kg
2
Arsenic
7440-38-2 601OD
ND
6.3
mg/kg
1
Cadmium
7440-43-9 601OD
ND
2.1
mg/kg
2
Calcium
7440-70-2 6010D
3600
2100
mg/kg
1
Copper
7440-50-8 601OD
ND
4.2
mg/kg
2
Lead
7439-92-1 601OD
ND
4.2
mg/kg
2
Magnesium
7439-95-4 601OD
ND
2100
mg/kg
2
Molybdenum
7439-98-7 601OD
ND
17
mg/kg
2
Nickel
7440-02-0 601OD
ND
17
mg/kg
2
Potassium
7440-09-7 601OD
ND
2100
mg/kg
2
Selenium
7782-49-2 601OD
ND
8.4
mg/kg
2
Sodium
7440-23-5 601OD
ND
2100
mg/kg
1
Zinc
7440-66-6 601OD
ND
21
mg/kg
2
Footnote(s): 'Paint Filter Volume Recovered = 48 mL
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 17 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-006
Description: Brake Bush Matrix: Solid
Date Sampled:11/28/2023 0930 % Solids: 1.81 12/04/2023 2215
Date Received:11/28/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/04/2023 2252 CBP
91461
1 350.1
(Ammonia - N ) 350.1
10
12/06/2023 1244 CMM
91029
1
(Flashpoint () 1010B
1
11/29/2023 2028 NAB
91165
1
(Nitrate-Nitr) 353.2
1
12/06/2023 1459 CLL2
91745
1
(Paint Filter) 9095B
1
12/11/2023 1829 GGC
1
(Phosphorus) 365.1
5
12/04/2023 1344 BMG2
12/03/2023 2049 91349
1
(Reactive Cya) 7.3.3
1
12/13/2023 2037 NAB
12/10/2023 1721
1
(Reactive Sul) 7.3.4
1
12/13/2023 1238 CLL2
12/10/2023 1721
1
(Soil pH meas) 9045D
1
12/05/2023 1417 BMG2
91448
1 351.4
(TKN) 351.2
1
12/04/2023 1850 BMG2
12/03/2023 2020 91348
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
93
%
1
Ammonia - N (gas diffusion)
350.1
13000
5500
mg/kg
1
Flashpoint (Pensky-Martens Closed -Cup)
1010E
>140
140
° F
1
Nitrate -Nitrite - N (soluble)
353.2
38
11
mg/kg
1
Paint Filter Test
9095E
Fail
pass/fail
1
Phosphorus
7723-14-0 365.1
6700
1400
mg/kg
1
Reactive Cyanide
7.3.3
ND
50
mg/kg
1
Reactive Sulfide
7.3.4
ND
50
mg/kg
1
Soil pH measured in water @ 11 ° C
9045D
6.1
su
1
TKN
351.2
52000
2800
mg/kg
1
TCLP Volatiles
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/5030B 8260D
10 12/05/2023 1248 AMR2
91493 11/29/2023 1245
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Benzene
71-43-2 8260D
ND
0.050
mg/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
0.10
mg/L
1
Carbon tetrachloride
56-23-5 8260D
ND
0.050
mg/L
1
Chlorobenzene
108-90-7 8260D
ND
0.050
mg/L
1
Chloroform
67-66-3 8260D
ND
0.050
mg/L
1
1,2-Dichloroethane
107-06-2 8260D
ND
0.050
mg/L
1
1,1-Dichloroethene
75-35-4 8260D
ND
0.050
mg/L
1
Tetrachloroethene
127-18-4 8260D
ND
0.050
mg/L
1
Trichloroethene
79-01-6 8260D
ND
0.050
mg/L
1
Vinyl chloride
75-01-4 8260D
ND
0.010
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 18 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-006
Description: Brake Bush Matrix: Solid
Date Sampled:11/28/2023 0930 % Solids: 1.81 12/04/2023 2215
)ate Received:11/28/2023
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
102 70-130
1,2-Dichloroethane-d4
106 70-130
Toluene-d8
109 70-130
TCLP Semivolatiles
Run Prep Method
Analytical Method Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3520C
8270E 1 12/06/2023 1607 JCG
11/30/2023 1345 91141 11/29/2023 1245
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units
Run
1,4-Dichlorobenzene
106-46-7 8270E
ND
0.040
mg/L
1
2,4-Dinitrotoluene
121-14-2 8270E
ND
0.080
mg/L
1
Hexachlorobenzene
118-74-1 8270E
ND
0.040
mg/L
1
Hexachlorobutadiene
87-68-3 8270E
ND
0.040
mg/L
1
Hexachloroethane
67-72-1 8270E
ND
0.040
mg/L
1
2-Methylphenol
95-48-7 8270E
ND
0.040
mg/L
1
3+4-Methylphenol
106-44-5 8270E
0.48
0.040
mg/L
1
Nitrobenzene
98-95-3 8270E
ND
0.040
mg/L
1
Pentachlorophenol
87-86-5 8270E
ND
0.20
mg/L
1
Pyridine
110-86-1 8270E
ND
0.040
mg/L
1
2,4,5-Trichlorophenol
95-95-4 8270E
ND
0.040
mg/L
1
2,4,6-Trichlorophenol
88-06-2 8270E
ND
0.040
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
2-Fluorobiphenyl
61 37-129
2-Fluorophenol
44 24-127
Nitrobenzene-d5
75 38-127
Phenol-d5
65 28-128
Terphenyl-d 14
80 10-148
2,4,6-Tribromophenol
56 41-144
TCLP Herbicides
Run Prep Method
Analytical Method Dilution Analysis Date Analyst Prep Date
Batch Leachate Date
1 1311/8151A
8151A 1 12/06/2023 1647 JMR 11/30/2023 1122 91143 11/29/2023 1245
CAS Analytical
Parameter
Number Method Result Q
LOQ
Units Run
2,4-D
94-75-7 8151A ND
0.020
mg/L 1
2,4,5-TP (Silvex)
93-72-1 8151A ND
0.0050
mg/L 1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
DCAA
75 50-112
LOQ = Limit of Quantitation
B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 19 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-006
Description: Brake Bush Matrix: Solid
Date Sampled:11/28/2023 0930 % Solids: 1.81 12/04/2023 2215
Date Received:11/28/2023
PCBs by GC
Run Prep Method Cleanup Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3550C 366013/3665A 8082A 1 12/11/2023 1243 JMR 12/06/2023 1646 91638
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
Aroclor 1016
12674-11-2
8082A
ND
920
ug/kg
1
Aroclor 1221
11104-28-2
8082A
ND
920
ug/kg
1
Aroclor 1232
11141-16-5
8082A
ND
920
ug/kg
1
Aroclor 1242
53469-21-9
8082A
ND
920
ug/kg
1
Aroclor 1248
12672-29-6
8082A
ND
920
ug/kg
1
Aroclor 1254
11097-69-1
8082A
ND
920
ug/kg
1
Aroclor 1260
11096-82-5
8082A
ND
920
ug/kg
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
94 41-132
Tetrachloro-m-xylene
77 35-106
TCLP Pesticides
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch Leachate Date
1 1311/3520C 8081B 1 12/01/20231802 MEZ 11/30/2023 1314 91142 11/29/2023 1245
CAS Analytical
Parameter Number Method Result Q LOQ Units Run
gamma-BHC (Lindane)
58-89-9
8081B
ND
0.00040
mg/L
1
Chlordane
57-74-9
8081B
ND
0.0040
mg/L
1
Endrin
72-20-8
8081B
ND
0.00040
mg/L
1
Heptachlor
76-44-8
8081B
ND
0.00040
mg/L
1
Heptachlor epoxide
1024-57-3
8081 B
ND
0.00040
mg/L
1
Methoxychlor
72-43-5
8081B
ND
0.0016
mg/L
1
Toxaphene
8001-35-2
8081B
ND
0.0080
mg/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Decachlorobiphenyl
63 20-131
Tetrachloro-m-xylene
84 26-132
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
1 7471 B
7471 B
1 12/09/2023 0415 KAJ 12/01 /2023 0848 91084
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 4.3
mg/kg 1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 20 of 26

Client: Terra Renewal Services, Inc. Laboratory ID:YK28031-006
Description: Brake Bush Matrix: Solid
Date Sampled:11/28/2023 0930 % Solids: 1.81 12/04/2023 2215
Date Received:11/28/2023
TCLP Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch Leachate Date
1 1311/3010A
601OD
1 12/29/2023 1937 JMT2
12/03/2023 0121 91272 11/29/2023 1245
1 1311/7470A
7470A
1 12/12/2023 1254 KAJ
12/06/2023 0719 91337 11/29/2023 1245
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Arsenic
7440-38-2 601OD
ND
0.15
mg/L
1
Barium
7440-39-3 6010D
0.32
0.25
mg/L
1
Cadmium
7440-43-9 601OD
ND
0.050
mg/L
1
Chromium
7440-47-3 601OD
ND
0.10
mg/L
1
Lead
7439-92-1 601OD
ND
0.10
mg/L
1
Mercury
7439-97-6 7470A
ND
0.0020
mg/L
1
Selenium
7782-49-2 601OD
ND
0.20
mg/L
1
Silver
7440-22-4 601OD
ND
0.10
mg/L
1
ICP-AES
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3050B
601 OD
1 12/19/2023 0334 LAB
12/01/2023 1100 91195
2 3050B
601OD
1 12/29/2023 1937 JMT2
12/01/2023 1100 91195
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aluminum
7429-90-5 601OD
ND
350
mg/kg
2
Arsenic
7440-38-2 601OD
ND
13
mg/kg
1
Cadmium
7440-43-9 601OD
ND
4.4
mg/kg
2
Calcium
7440-70-2 6010D
16000
4400
mg/kg
1
Copper
7440-50-8 601OD
ND
8.9
mg/kg
2
Lead
7439-92-1 601OD
ND
8.9
mg/kg
2
Magnesium
7439-95-4 601OD
ND
4400
mg/kg
2
Molybdenum
7439-98-7 601OD
ND
35
mg/kg
2
Nickel
7440-02-0 601OD
ND
35
mg/kg
2
Potassium
7440-09-7 601OD
ND
4400
mg/kg
2
Selenium
7782-49-2 601OD
ND
18
mg/kg
2
Sodium
7440-23-5 601OD
ND
4400
mg/kg
1
Zinc
7440-66-6 601OD
ND
44
mg/kg
2
Footnote(s): 'Paint Filter Volume Recovered = 47 mL
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range Q = Surrogate failure
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % L = LCS/LCSD failure
H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 21 of 26

Chain of Custody
5TIM
I Lyi MTM I RTMOTO ITINT I =I- I V
Pace Analyfican Services, LLC (fonnerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax (B03) 791-9111 www.lpacelabs.com
Page 22 of 26

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Pace AnaIlyfican Services, LLC (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 23 of 26
IL
r,

PACE ANALYTICAL SERVICES, LLC
Korth Carolina Permit Paramotors
I lUaiduats atiall Ix nnulrved to deimmtrMA, Jov A( 0A,—Aur4mis
and, RcouvM &,.' (RCRA� Tlu-
uhu T-mjuzm:)sIgeificid �u
Ailach-mut k =6 the ?ermiUte $6075-ultlift lbew remiliq rar a minimiun ol'Jivi yeaj,,i, Any
z,v,*�t)ft)n,R frrwn the retiWremerAs in thli, cundAiolc shall be spec iij AllAr,"iment k
Thc�jwly4i4 0,03 Jualude the fog pmramWem (thcrcgulatori j Ar ttllligrams ptw bter
is ill parmplhew�
3,. Au unulysi!� Qua H ',,e cmdw,"tad ICAU residual's frmmi, eacti saunz: 6maulitig fwAlcy al tim: ftoqurnuy
speeffied in Attachimmt A.,,wrjJ 10 pelmi"tee 51111.1 Oulinlain tha re -wits for a Imnimutu d Zve years,
Tlw QuAlysLs all laclikc than foHm in po mmetevr
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vollat4e, salfids
MaipcMIUM
PU'S
......... ..
TERRA RENEWAL SERVICES
479-14e-8192
WQX11036936 Vw,)kv. 1.10 Skml Vmiom 140210 Far 8 of 12
Pace Anaayficaa Services, LLC (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 24 of 26

PACE ANALYTICAL SERVICES, LLC
. . ........................... . . . .. . . . . . ............................................................
North Carolina Permit Parameters
I Residumls sum It be,, walywd to d=,unuirtle they are 'Ourrx ems"tirvatim
EM'd Reoovery Act (RCILA)� The V an -6� pm�jvsMty, "—ftabilitY, rot ikAd toxicity
s
charsderikk lewhiug N
proee4 , TCLF
quency pecified iu
OI,
A1,46bmwt A, aad tho Poudueor Rhall maintain these mulls, fw at iniaiu= of five year& Any
C=#WW, *OM +M Mjuiremmts bi this couditim shall be spwifiet, in Atrachinent A.
Mic TCL? anabisis shall nioludo the fallow ir-O pararaem! (1.k vVdatury level in tyjillixtrius per litor,
is ic. purenthege%),,
Bar!= (10014)
Bcmzcw
caiton teMachlolide (0.5)
CUavdaue (OM)
CjAwiaU' (100A)
eblamfom (&:0)
(11MITlium (5.0)
M-CM801 (2,0OX)
-ire sol (200.0)
Crcwl (200.01)
Nkrab=we (24)
Selenium (1.0)
Salver (3,O)
Tetradtinmeffiy1cum (03)
2,4,5-Trirbio"henol (40100)
2A6-Thr,h1rwMhem,a1 (2M
2'4"�-Tp (Sil~ X) (I x))
vinyl ckoride, (0.2)
11. Aafiwlysa .11 be eon6ucteNi on rtsWupis ftom each soume gmCrafinji fooifity at die freqvemay
.q,wmficd in Batt .-bTncnt A, wW Lite Pcrva4tee sholi = Intam th� rmultt -*,P. tHrimum of fiov yuam
'"sae walysis shrdl itialude tho Mcpvbig parayneterg:
Aluminum
ag=
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Mbiybducu=
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perwit TOW SO&
2MMM
ShaliVersim 14010
potasikun
81cdium
TKN
Zinc
Voia Is &V ds
SM
Page 8 of 12
Pace Anakyfican Services, LLC (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 25 of 26

PACE ANALYTICAL SERVICES, LLC
DiCk Tiltle,
f4fiective Clam 6//2022
Sample Receipt Checklist (SIAC)
17
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Pace'l`Analyocal page I I
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Pace AnalyficaI Services, LLCM (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 26 of 26

®R
cleAnalyfical
Terra Renewal Services, In
PO Box 30136
Russellville, AR 7281!1
Attention: David Coyle
fiemgrr,TM-14@&=$
Lot Niurnber:YL12057
ga M =0 =0 no
01/16/2024 8:57 AM
Approved and released by:
Project Manager 11: Lucas Odola
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, ILL.C.
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point lDrive West Columbia, SC 29172
Tel: [phone] Fax: 803-791!-91111 www.pacelabs.com
Page 1 of IS

PACE ANALYTICAL SERVICES, LLC
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
Terra Renewal Services, Inc.
Lot Number: YL12057
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report. Where
sampling is conducted by the client, results relate to the accuracy of the information provided, and as the
samples are received.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace")
Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to
the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or
discussed below.
Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI
scope of accreditation: E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC
Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7,
Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM
2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011,
Fecal Coliform Colilert-18. Where applicable, all soil sample results (including LOQ and DL if requested)
are corrected for dry weight unless flagged with a "W" qualifier.
If you have any questions regarding this report, please contact the Pace Project Manager listed on the
cover page.
The pH analysis associated with the sample(s) in this report was/were performed after the method
recommended 15 minute holding time.
Inorganic Metals
The following samples are classified as biosolids; therefore, the initial amount weighed is 3.0-3.5 grams to
allow for proper digestion: YL12057-001, YL12057-002, YL12057-003, YL12057-004, YL12057-005. The
LOQ has been adjusted accordingly.
Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] vvvvvv.pacelabs.com
Page 2 of 18

PACE ANALYTICAL SERVICES, LLC
Sample Summary
Terra Renewal Services, Inc.
Lot Number: YL12057
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
TYSON-WILKESBORO
Solid
12/12/2023 0815
12/12/2023
002
TYSON-HARMONY
Solid
12/12/2023 0915
12/12/2023
003
TYSON-DANVILLE
Solid
12/12/20231100
12/12/2023
004
MATHIS-1
Solid
12/12/20231030
12/12/2023
005
TYSON-HARMONY CAKE
Solid
12/12/2023 1115
12/12/2023
(5 samples)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 3 of 18

PACE ANALYTICAL SERVICES, LLC
Sample Sample ID
Detection Summary
Terra Renewal Services, Inc.
Lot Number: YL12057
Matrix Parameter
Method Result Q Units
001
TYSON-WILKESBORO
Solid
% Volatile Solids
SM 2540G-
98
%
001
TYSON-WILKESBORO
Solid
Ammonia - N (gas
350.1
1700
mg/kg
001
TYSON-WILKESBORO
Solid
Nitrate -Nitrite - N (soluble)
353.2
39
mg/kg
001
TYSON-WILKESBORO
Solid
Phosphorus
365.1
4000
mg/kg
001
TYSON-WILKESBORO
Solid
TKN
351.2
73000
mg/kg
001
TYSON-WILKESBORO
Solid
Aluminum
6010D
230
mg/kg
001
TYSON-WILKESBORO
Solid
Copper
6010D
67
mg/kg
001
TYSON-WILKESBORO
Solid
Lead
6010D
6.2
mg/kg
001
TYSON-WILKESBORO
Solid
Zinc
6010D
81
mg/kg
002
TYSON-HARMONY
Solid
% Volatile Solids
SM 2540G-
89
%
002
TYSON-HARMONY
Solid
Ammonia - N (gas
350.1
48000
mg/kg
002
TYSON-HARMONY
Solid
Nitrate -Nitrite - N (soluble)
353.2
110
mg/kg
002
TYSON-HARMONY
Solid
Phosphorus
365.1
21000
mg/kg
002
TYSON-HARMONY
Solid
TKN
351.2
110000
mg/kg
002
TYSON-HARMONY
Solid
Aluminum
6010D
39000
mg/kg
002
TYSON-HARMONY
Solid
Calcium
6010D
26000
mg/kg
002
TYSON-HARMONY
Solid
Copper
6010D
32
mg/kg
002
TYSON-HARMONY
Solid
Sodium
6010D
11000
mg/kg
002
TYSON-HARMONY
Solid
Zinc
6010D
160
mg/kg
003
TYSON-DANVILLE
Solid
% Volatile Solids
SM 2540G-
95
%
003
TYSON-DANVILLE
Solid
Ammonia - N (gas
350.1
2000
mg/kg
003
TYSON-DANVILLE
Solid
Nitrate -Nitrite - N (soluble)
353.2
35
mg/kg
003
TYSON-DANVILLE
Solid
Phosphorus
365.1
6800
mg/kg
003
TYSON-DANVILLE
Solid
TKN
351.2
33000
mg/kg
003
TYSON-DANVILLE
Solid
Aluminum
6010D
1300
mg/kg
003
TYSON-DANVILLE
Solid
Calcium
6010D
2100
mg/kg
003
TYSON-DANVILLE
Solid
Copper
6010D
18
mg/kg
003
TYSON-DANVILLE
Solid
Nickel
6010D
23
mg/kg
003
TYSON-DANVILLE
Solid
Zinc
6010D
51
mg/kg
004
MATHIS-1
Solid
% Volatile Solids
SM 2540G-
96
%
004
MATHIS-1
Solid
Ammonia - N (gas
350.1
6000
mg/kg
004
MATHIS-1
Solid
Nitrate -Nitrite - N (soluble)
353.2
30
mg/kg
004
MATHIS-1
Solid
Phosphorus
365.1
5500
mg/kg
004
MATHIS-1
Solid
TKN
351.2
38000
mg/kg
004
MATHIS-1
Solid
Aluminum
6010D
3800
mg/kg
004
MATHIS-1
Solid
Copper
6010D
51
mg/kg
004
MATHIS-1
Solid
Zinc
6010D
78
mg/kg
005
TYSON-HARMONY CAKE
Solid
% Volatile Solids
SM 2540G-
95
%
005
TYSON-HARMONY CAKE
Solid
Ammonia - N (gas
350.1
5500
mg/kg
005
TYSON-HARMONY CAKE
Solid
Nitrate -Nitrite - N (soluble)
353.2
8.3
mg/kg
005
TYSON-HARMONY CAKE
Solid
Phosphorus
365.1
3200
mg/kg
005
TYSON-HARMONY CAKE
Solid
TKN
351.2
36000
mg/kg
005
TYSON-HARMONY CAKE
Solid
Aluminum
6010D
6100
mg/kg
005
TYSON-HARMONY CAKE
Solid
Calcium
6010D
11000
mg/kg
005
TYSON-HARMONY CAKE
Solid
Copper
6010D
15
mg/kg
Page
7
7
7
7
7
8
8
8
8
9
9
9
9
9
10
10
10
10
10
11
11
11
11
11
12
12
12
12
12
13
13
13
13
13
14
14
14
15
15
15
15
15
16
16
16
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 4 of 18

Detection Summary (Continued)
Lot Number: YL12057
Sample
Sample ID
Matrix
Parameter
Method
Result Q
Units
Page
005
TYSON-HARMONY CAKE
Solid
Lead
6010D
1.2
mg/kg
16
005
TYSON-HARMONY CAKE
Solid
Magnesium
6010D
1100
mg/kg
16
005
TYSON-HARMONY CAKE
Solid
Nickel
6010D
3.0
mg/kg
16
005
TYSON-HARMONY CAKE
Solid
Potassium
6010D
1100
mg/kg
16
005
TYSON-HARMONY CAKE
Solid
Sodium
6010D
980
mg/kg
16
005
TYSON-HARMONY CAKE
Solid
Zinc
6010D
70
mg/kg
16
(51 detections)
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 5 of 18

Client: Terra Renewal Services, Inc. Laboratory ID:YL12057-001
Description: TYSON-WI LKESBORO Matrix: Solid
Date Sampled:12/12/2023 0815 % Solids: 4.32 12/15/2023 0136
Date Received:12/12/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/18/2023 1901 CBP
92582
1 350.1
(Ammonia - N ) 350.1
5
12/19/2023 1020 CMM
92188
1
(Nitrate-Nitr) 353.2
1
12/16/2023 1119 CLL2
92473
1
(Phosphorus) 365.1
5
12/14/2023 1542 DMA
12/13/2023 1902 92233
1
(Soil pH meas) 9045D
1
12/14/2023 1519 LMM2
91449
2 351.4
(TKN) 351.2
5
12/19/2023 1456 BMG2
12/17/2023 1752 92347
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
98
%
1
Ammonia - N (gas diffusion)
350.1
1700
1200
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
39
4.6
mg/kg
1
Phosphorus
7723-14-0 365.1
4000
580
mg/kg
1
Soil pH measured in water @ 9 o C
9045D
4.7
su
1
TKN
351.2
73000
5800
mg/kg
2
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 12/14/2023 1704 JMR
12/13/2023 1736 92204
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
390
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
390
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
390
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
390
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
390
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
390
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
390
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
114 41-132
Tetrachloro-m-xylene
79 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
2 7471 B
7471 B
1 12/19/2023 0439 KJEW 12/19/2023 0058 92601
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 1.8
mg/kg 2
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 6 of 18

Client: Terra Renewal Services, Inc. Laboratory ID:YL12057-001
Description: TYSON-WI LKESBORO Matrix: Solid
Date Sampled:12/12/2023 0815 % Solids: 4.32 12/15/2023 0136
Date Received:12/12/2023
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 601OD 1 01/12/2024 1742 JMT2 12/18/2023 1026 92393
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
230
150
mg/kg
1
Arsenic
7440-38-2
601OD
ND
5.6
mg/kg
1
Cadmium
7440-43-9
601OD
ND
1.9
mg/kg
1
Calcium
7440-70-2
601OD
ND
1900
mg/kg
1
Copper
7440-50-8
6010D
67
3.7
mg/kg
1
Lead
7439-92-1
6010D
6.2
3.7
mg/kg
1
Magnesium
7439-95-4
601OD
ND
1900
mg/kg
1
Molybdenum
7439-98-7
601OD
ND
15
mg/kg
1
Nickel
7440-02-0
601OD
ND
15
mg/kg
1
Potassium
7440-09-7
601OD
ND
1900
mg/kg
1
Selenium
7782-49-2
601OD
ND
7.5
mg/kg
1
Sodium
7440-23-5
601OD
ND
1900
mg/kg
1
Zinc
7440-66-6
6010D
81
19
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 7 of 18
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure

Client: Terra Renewal Services, Inc. Laboratory ID:YL12057-002
Description: TYSON-HARMONY Matrix: Solid
Date Sampled:12/12/2023 0915 % Solids: 0.717 12/15/2023 0136
Date Received:12/12/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/18/2023 1901 CBP
92582
1 350.1
(Ammonia - N ) 350.1
25
12/19/2023 1022 CMM
92188
1
(Nitrate-Nitr) 353.2
1
12/16/2023 1121 CLL2
92473
1
(Phosphorus) 365.1
5
12/14/2023 1542 DMA
12/13/2023 1902 92233
1
(Soil pH meas) 9045D
1
12/14/2023 1520 LMM2
91449
1 351.4
(TKN) 351.2
1
12/18/2023 1840 BMG2
12/17/2023 1752 92347
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
89
%
1
Ammonia - N (gas diffusion)
350.1
48000
35000
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
110
28
mg/kg
1
Phosphorus
7723-14-0 365.1
21000
3500
mg/kg
1
Soil pH measured in water @ 10.5 o C
9045D
6.9
su
1
TKN
351.2
110000
7000
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 3550C 366013/3665A 8082A
1 12/14/2023 1717 JMR
12/13/2023 1736 92204
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
2400
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
2400
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
2400
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
2400
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
2400
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
2400
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
2400
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
99 41-132
Tetrachloro-m-xylene
79 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
2 7471 B
7471 B
1 12/19/2023 0442 KJEW 12/19/2023 0058 92601
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 11
mg/kg 2
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 8 of 18

Client: Terra Renewal Services, Inc. Laboratory ID:YL12057-002
Description: TYSON-HARMONY Matrix: Solid
Date Sampled:12/12/2023 0915 % Solids: 0.717 12/15/2023 0136
Date Received:12/12/2023
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 601OD 1 01/12/2024 1744 JMT2 12/18/2023 1026 92393
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
39000
880
mg/kg
1
Arsenic
7440-38-2
601OD
ND
33
mg/kg
1
Cadmium
7440-43-9
601OD
ND
11
mg/kg
1
Calcium
7440-70-2
6010D
26000
11000
mg/kg
1
Copper
7440-50-8
6010D
32
22
mg/kg
1
Lead
7439-92-1
601OD
ND
22
mg/kg
1
Magnesium
7439-95-4
601OD
ND
11000
mg/kg
1
Molybdenum
7439-98-7
601OD
ND
88
mg/kg
1
Nickel
7440-02-0
601OD
ND
88
mg/kg
1
Potassium
7440-09-7
601OD
ND
11000
mg/kg
1
Selenium
7782-49-2
601OD
ND
44
mg/kg
1
Sodium
7440-23-5
6010D
11000
11000
mg/kg
1
Zinc
7440-66-6
6010D
160
110
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 9 of 18
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure

Client: Terra Renewal Services, Inc. Laboratory ID:YL12057-003
Description: TYSON-DANVILLE Matrix: Solid
Date Sampled:12/12/2023 1100 % Solids: 4.00 12/15/2023 0136
Date Received:12/12/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/18/2023 1901 CBP
92582
1 350.1
(Ammonia - N ) 350.1
5
12/19/2023 1158 CMM
92188
1
(Nitrate-Nitr) 353.2
1
12/16/2023 1122 CLL2
92473
1
(Phosphorus) 365.1
10
12/14/2023 1542 DMA
12/13/2023 1902 92233
1
(Soil pH meas) 9045D
1
12/14/2023 1522 LMM2
91449
1 351.4
(TKN) 351.2
2
12/18/2023 1847 BMG2
12/17/2023 1752 92347
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
95
%
1
Ammonia - N (gas diffusion)
350.1
2000
1200
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
35
5.0
mg/kg
1
Phosphorus
7723-14-0 365.1
6800
1200
mg/kg
1
Soil pH measured in water @ 9.2 o C
9045D
3.7
su
1
TKN
351.2
33000
2500
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 12/14/2023 1731 JMR
12/13/2023 1736 92204
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
420
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
420
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
420
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
420
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
420
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
420
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
420
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
105 41-132
Tetrachloro-m-xylene
74 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
2 7471 B
7471 B
1 12/19/2023 0445 KJEW 12/19/2023 0058 92601
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 2.0
mg/kg 2
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 10 of 18

Client: Terra Renewal Services, Inc. Laboratory ID:YL12057-003
Description: TYSON-DANVILLE Matrix: Solid
Date Sampled:12/12/2023 1100 % Solids: 4.00 12/15/2023 0136
Date Received:12/12/2023
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 601OD 1 01/12/2024 1747 JMT2 12/18/2023 1026 92393
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
1300
160
mg/kg
1
Arsenic
7440-38-2
601OD
ND
5.9
mg/kg
1
Cadmium
7440-43-9
601OD
ND
2.0
mg/kg
1
Calcium
7440-70-2
6010D
2100
2000
mg/kg
1
Copper
7440-50-8
6010D
18
3.9
mg/kg
1
Lead
7439-92-1
601OD
ND
3.9
mg/kg
1
Magnesium
7439-95-4
601OD
ND
2000
mg/kg
1
Molybdenum
7439-98-7
601OD
ND
16
mg/kg
1
Nickel
7440-02-0
6010D
23
16
mg/kg
1
Potassium
7440-09-7
601OD
ND
2000
mg/kg
1
Selenium
7782-49-2
601OD
ND
7.9
mg/kg
1
Sodium
7440-23-5
601OD
ND
2000
mg/kg
1
Zinc
7440-66-6
6010D
51
20
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 11 of 18
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure

Client: Terra Renewal Services, Inc. Laboratory ID:YL12057-004
Description: MATHIS-1 Matrix: Solid
Date Sampled:12/12/2023 1030 % Solids: 2.11 12/15/2023 0136
Date Received:12/12/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/18/2023 1901 CBP
92582
1 350.1
(Ammonia - N ) 350.1
5
12/19/2023 1032 CMM
92188
1
(Nitrate-Nitr) 353.2
1
12/16/2023 1124 CLL2
92473
1
(Phosphorus) 365.1
5
12/14/2023 1543 DMA
12/13/2023 1902 92233
1
(Soil pH meas) 9045D
1
12/14/2023 1523 LMM2
91449
1 351.4
(TKN) 351.2
1
12/18/2023 1840 BMG2
12/17/2023 1752 92347
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
96
%
1
Ammonia - N (gas diffusion)
350.1
6000
2400
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
30
9.5
mg/kg
1
Phosphorus
7723-14-0 365.1
5500
1200
mg/kg
1
Soil pH measured in water @ 9.8 o C
9045D
5.2
su
1
TKN
351.2
38000
2400
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 12/14/2023 1744 JMR
12/13/2023 1736 92204
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
800
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
800
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
800
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
800
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
800
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
800
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
800
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
116 41-132
Tetrachloro-m-xylene
82 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
2 7471 B
7471 B
1 12/19/2023 0447 KJEW 12/19/2023 0058 92601
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND 3.8
mg/kg 2
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 12 of 18

Client: Terra Renewal Services, Inc. Laboratory ID:YL12057-004
Description: MATHIS-1 Matrix: Solid
Date Sampled:12/12/2023 1030 % Solids: 2.11 12/15/2023 0136
Date Received:12/12/2023
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 601OD 1 01/12/2024 1749 JMT2 12/18/2023 1026 92393
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
3800
300
mg/kg
1
Arsenic
7440-38-2
601OD
ND
11
mg/kg
1
Cadmium
7440-43-9
601OD
ND
3.8
mg/kg
1
Calcium
7440-70-2
601OD
ND
3800
mg/kg
1
Copper
7440-50-8
6010D
51
7.5
mg/kg
1
Lead
7439-92-1
601OD
ND
7.5
mg/kg
1
Magnesium
7439-95-4
601OD
ND
3800
mg/kg
1
Molybdenum
7439-98-7
601OD
ND
30
mg/kg
1
Nickel
7440-02-0
601OD
ND
30
mg/kg
1
Potassium
7440-09-7
601OD
ND
3800
mg/kg
1
Selenium
7782-49-2
601OD
ND
15
mg/kg
1
Sodium
7440-23-5
601OD
ND
3800
mg/kg
1
Zinc
7440-66-6
6010D
78
38
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 13 of 18
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure

Client: Terra Renewal Services, Inc. Laboratory ID:YL12057-005
Description: TYSON-HARMONY CAKE Matrix: Solid
Date Sampled:12/12/2023 1115 % Solids: 22.6 12/15/2023 0136
Date Received:12/12/2023
Inorganic
non-metals
Run Prep Method
Analytical Method
Dilution
Analysis Date Analyst
Prep Date Batch
1
(% Volatile S) SM 254OG-1997
1
12/18/2023 1901 CBP
92582
1 350.1
(Ammonia - N ) 350.1
50
12/19/2023 1110 CMM
92188
1
(Nitrate-Nitr) 353.2
1
12/16/2023 1126 CLL2
92473
1
(Phosphorus) 365.1
25
12/14/2023 1621 DMA
12/13/2023 1902 92233
1
(Soil pH meas) 9045D
1
12/14/2023 1524 LMM2
91449
1 351.4
(TKN) 351.2
10
12/18/2023 1847 BMG2
12/17/2023 1752 92347
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
% Volatile Solids
SM 254OG-1997
95
%
1
Ammonia - N (gas diffusion)
350.1
5500
2200
mg/kg
1
Nitrate -Nitrite - N (soluble)
353.2
8.3
0.89
mg/kg
1
Phosphorus
7723-14-0 365.1
3200
550
mg/kg
1
Soil pH measured in water @ 10.6 o C
9045D
7.0
su
1
TKN
351.2
36000
2200
mg/kg
1
PCBs by GC
Run Prep Method Cleanup Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3550C 366013/3665A 8082A
1 12/14/2023 1757 JMR
12/13/2023 1736 92204
CAS Analytical
Parameter
Number Method
Result Q
LOQ
Units
Run
Aroclor 1016
12674-11-2 8082A
ND
74
ug/kg
1
Aroclor 1221
11104-28-2 8082A
ND
74
ug/kg
1
Aroclor 1232
11141-16-5 8082A
ND
74
ug/kg
1
Aroclor 1242
53469-21-9 8082A
ND
74
ug/kg
1
Aroclor 1248
12672-29-6 8082A
ND
74
ug/kg
1
Aroclor 1254
11097-69-1 8082A
ND
74
ug/kg
1
Aroclor 1260
11096-82-5 8082A
ND
74
ug/kg
1
Run 1 Acceptance
Surrogate Q % Recovery Limits
Decachlorobiphenyl
123 41-132
Tetrachloro-m-xylene
94 35-106
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date Batch
2 7471 B
7471 B
1 12/19/2023 0450 KJEW 12/19/2023 0058 92601
CAS Analytical
Parameter
Number Method Result Q LOQ
Units Run
Mercury
7439-97-6 7471B ND S 0.35
mg/kg 2
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
Q = Surrogate failure
ND = Not detected at or above the LOQ
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
L = LCS/LCSD failure
H = Out of holding time
W = Reported on wet weight basis
S = MS/MSD failure
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 14 of 18

Client: Terra Renewal Services, Inc. Laboratory ID:YL12057-005
Description: TYSON-HARMONY CAKE Matrix: Solid
Date Sampled:12/12/2023 1115 % Solids: 22.6 12/15/2023 0136
Date Received:12/12/2023
ICP-AES
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3050B 601OD 1 01/12/2024 1752 JMT2 12/18/2023 1026 92393
Parameter
CAS Analytical
Number Method Result Q LOQ Units Run
Aluminum
7429-90-5
6010D
6100
25
mg/kg
1
Arsenic
7440-38-2
601OD
ND
0.95
mg/kg
1
Cadmium
7440-43-9
601OD
ND
0.32
mg/kg
1
Calcium
7440-70-2
6010D
11000
320
mg/kg
1
Copper
7440-50-8
6010D
15
0.63
mg/kg
1
Lead
7439-92-1
6010D
1.2
0.63
mg/kg
1
Magnesium
7439-95-4
6010D
1100
320
mg/kg
1
Molybdenum
7439-98-7
601OD
ND
2.5
mg/kg
1
Nickel
7440-02-0
6010D
3.0
2.5
mg/kg
1
Potassium
7440-09-7
6010D
1100
320
mg/kg
1
Selenium
7782-49-2
601OD
ND
1.3
mg/kg
1
Sodium
7440-23-5
6010D
980
320
mg/kg
1
Zinc
7440-66-6
6010D
70
3.2
mg/kg
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range
ND = Not detected at or above the LOQ N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 %
H = Out of holding time W = Reported on wet weight basis
Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.pacelabs.com
Page 15 of 18
Q = Surrogate failure
L = LCS/LCSD failure
S = MS/MSD failure

Chain of Custody
5TIM
I Lyi MTM I RTMOTO ITINT I =I- I V
Pace Analyfican Services, LLC )'formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 16 of 18

PACE ANALYTICAL SERVICES, LLC
I!
L
7,
o
Pace AnaIlyficaN Services, LLC )'formerly Shealy Environmental Services, Mc.)
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page 17 of 18

PACE ANALYTICAL SERVICES, LLC
. .. . . ...
OC#.-'nfie: Et�V-FRM-W'COL-0286vO2_Sampe#sc�ptCh*cPl�,st(SRC)
Eftctiva Date. 8/2/2022
Sampte Receipt Cheddist (SRQ
clxw�, I'LlUUJUNEWAL CoDla It) ecred 01�tWa: C010, �� Lot * V1,12I
hvk-anlico� I'rrceip*:
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pH SvqN ID'
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Wetbot E]"reinn q),erature 31WAZ6lc
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E]Aret Ic e PACks 71 Dry Ice 7 N(Mse
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NO
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No
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V Yes
6, .mplrIDS timl pudic COC'mrill sCmijAcC011!3ina1s?
MNo
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W�Vrm rLs
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Yes
No
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4/ Yes
EN01
1.k W rc m,% m be7—eNc—sued lk�,Ted Ou te COC?
M Yes,
ONo
10, Did all samples anive ill'be Proper cmukirtm, rar em h Tesu"IC14.1ir ill q "dmAlf
(tuibrokcim, Us an, c1c)?
a
11, Was adeimtt sale voltmeavab-ble)
No
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[WA]ye,
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ah appiticable, NNII , 1 160E-3 (-� (),impl)mnM
7y" N A 17� Wcir 1) es free of
resi&ilaf chlorine"
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LZ,�
�01 A ]$'Was titeorlote k1lall ba listed OR UIC coulainer label? If Yes, Qvicite
�a:[ITJC(5) NA
weir mvivrd ivicormcAy prin-ved ;ijud
in snulpk mcch'ing With IUL Of ChLkIJUC tU, SO4. FIM03, HCL NuOH u�itlg SR # "N" A
ime of preselvation NA It"1111mr IbAlt Ime pluservalive is jtcolvd pleasc nkj'�c iu i5ic �LoutImos Iftlow,
S,11,11ple(s) NA
wen i ectivedwith blibbles � um in dinumler,
salmlesi(s),
mmic reccivrid Mt RC > O��, ing
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C0jnmC11t,,;:
Qualtrax ID: 56360 P!;t7e-7'Arai 1yfm-al Services, LLC ?;g; 1 of I
Pace Ananyfican Services, LLC (formerly Shealy Environmental Services, Mc.)
1016 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.lpacelabs.com
Page IS of 38

Laboratory Analyses:
- Seven Set Fecal Coliform Data

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 02/28/2023
Reported: 03/02/2023
For: Advance Claremont
Comments: GEOMETRIC MEAN: 223,673 MPN/g
j F S r l0 f 9 L U ,,,
A LY T ICA L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
230228-24-01
Fecal Coliforms
AC1
231481
MPN/g
SM92210E-2006
02/28/2023
MD
230228-24-01
Percent Solids
AC1
2.16
%
SM2540B-2011
02/28/2023
MD
230228-24-02
Fecal Coliforms
AC2
393939
MPN/g
SM92210E-2006
02/28/2023
MD
230228-24-02
Percent Solids
AC2
3.3
%
SM2540B-2011
02/28/2023
MD
230228-24-03
Fecal Coliforms
AC3
601504
MPN/g
SM92210E-2006
02/28/2023
MD
230228-24-03
Percent Solids
AC3
1.33
%
SM2540B-2011
02/28/2023
MD
230228-24-04
Fecal Coliforms
AC4
105505
MPN/g
SM92210E-2006
02/28/2023
MD
230228-24-04
Percent Solids
AC4
2.18
%
SM2540B-2011
02/28/2023
MD
230228-24-05
Fecal Coliforms
AC5
669291
MPN/g
SM92210E-2006
02/28/2023
MD
230228-24-05
Percent Solids
AC5
2.54
%
SM2540B-2011
02/28/2023
MD
230228-24-06
Fecal Coliforms
AC6
77320
MPN/g
SM92210E-2006
02/28/2023
MD
230228-24-06
Percent Solids
AC6
3.88
%
SM2540B-2011
02/28/2023
MD
230228-24-07
Fecal Coliforms
AC7
93525
MPN/g
SM92210E-2006
02/28/2023
MD
230228-24-07
Percent Solids
AC7
1.39
%
SM2540B-2011
02/28/2023
MD
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 230228-24-01 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 230228-24-02 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 230228-24-03 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 230228-24-04 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 230228-24-05 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 230228-24-06 Temp on Arrival: 2.5
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 230228-24-07 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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PO Box 228 9 Statesville, NC 28687 9 704/872/4697
Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 02/28/2023
Reported: 03/02/2023
For: Mathis 1
Comments: GEOMETRIC MEAN: 319,364 MPN/g
j F S r l0 f 9 L U ,,,
A LY T ICA L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
230228-23-01
Fecal Coliforms
M1
468750
MPN/g
SM92210E-2006
02/28/2023
MD
230228-23-01
Percent Solids
M1
6.4
%
SM2540B-2011
02/28/2023
MD
230228-23-02
Fecal Coliforms
M2
430107
MPN/g
SM92210E-2006
02/28/2023
MD
230228-23-02
Percent Solids
M2
5.58
%
SM2540B-2011
02/28/2023
MD
230228-23-03
Fecal Coliforms
M3
443548
MPN/g
SM92210E-2006
02/28/2023
MD
230228-23-03
Percent Solids
M3
4.96
%
SM2540B-2011
02/28/2023
MD
230228-23-04
Fecal Coliforms
M4
356564
MPN/g
SM92210E-2006
02/28/2023
MD
230228-23-04
Percent Solids
M4
6.17
%
SM2540B-2011
02/28/2023
MD
230228-23-05
Fecal Coliforms
M5
260000
MPN/g
SM92210E-2006
02/28/2023
MD
230228-23-05
Percent Solids
M5
5.0
%
SM2540B-2011
02/28/2023
MD
230228-23-06
Fecal Coliforms
M6
232975
MPN/g
SM92210E-2006
02/28/2023
MD
230228-23-06
Percent Solids
M6
5.58
%
SM2540B-2011
02/28/2023
MD
230228-23-07
Fecal Coliforms
M7
175438
MPN/g
SM92210E-2006
02/28/2023
MD
230228-23-07
Percent Solids
M7
6.27
%
SM2540B-2011
02/28/2023
MD
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 230228-23-01 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Chemicals in containers, lab
Received on Ice
Sample Number 230228-23-02 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230228-23-03 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230228-23-04 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230228-23-05 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Chemicals in containers, lab
Received on Ice
Sample Number 230228-23-06 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230228-23-07 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 03/02/2023
Reported: 03/06/2023
For: Tyson Wilkesboro
Comments: GEOMETRIC MEAN: 7552 MPN/g
j F S r l0 f 9 L U ,,,
A LY T ICA L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
230302-13-01
Fecal Coliforms
W1
10000
MPN/g
SM92210E-2006
03/02/2023
MD
230302-13-01
Percent Solids
W1
8.0
%
SM2540B-2011
03/02/2023
MD
230302-13-02
Fecal Coliforms
W2
3128
MPN/g
SM92210E-2006
03/02/2023
MD
230302-13-02
Percent Solids
W2
9.59
%
SM2540B-2011
03/02/2023
MD
230302-13-03
Fecal Coliforms
W3
8403
MPN/g
SM92210E-2006
03/02/2023
MD
230302-13-03
Percent Solids
W3
9.52
%
SM2540B-2011
03/02/2023
MD
230302-13-04
Fecal Coliforms
W4
6361
MPN/g
SM92210E-2006
03/02/2023
MD
230302-13-04
Percent Solids
W4
7.86
%
SM2540B-2011
03/02/2023
MD
230302-13-05
Fecal Coliforms
W5
14870
MPN/g
SM92210E-2006
03/02/2023
MD
230302-13-05
Percent Solids
W5
5.38
%
SM2540B-2011
03/02/2023
MD
230302-13-06
Fecal Coliforms
W6
7535
MPN/g
SM92210E-2006
03/02/2023
MD
230302-13-06
Percent Solids
W6
9.29
%
SM2540B-2011
03/02/2023
MD
230302-13-07
Fecal Coliforms
W7
7477
MPN/g
SM92210E-2006
03/02/2023
MD
230302-13-07
Percent Solids
W7
10.7
%
SM2540B-2011
03/02/2023
MD
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 5

Condition of Receipt
Sample Number 230302-13-01 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Chemicals in containers, lab
Received on Ice
Sample Number 230302-13-02 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230302-13-03 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230302-13-04 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230302-13-05 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 5

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Chemicals in containers, lab
Received on Ice
Sample Number 230302-13-06 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230302-13-07 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 5

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Page 4 of 5

PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 5 of 5

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 03/23/2023
Reported: 03/27/2023
For: Tyson Harmony
Comments:
j AT ' r l0 f 9 1:
A LY T ICA L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
230323-17-01
Fecal Coliforms
TH-1
<16129
MPN/g
SM92210E-2006
03/23/2023
MD
230323-17-01
Percent Solids
TH-1
1.24
%
SM2540B-2011
03/23/2023
MD
230323-17-02
Fecal Coliforms
TH-2
13889.0
MPN/g
SM92210E-2006
03/23/2023
MD
230323-17-02
Percent Solids
TH-2
1.44
%
SM2540B-2011
03/23/2023
MD
230323-17-03
Fecal Coliforms
TH-3
<20000
MPN/g
SM92210E-2006
03/23/2023
MD
230323-17-03
Percent Solids
TH-3
1.00
%
SM2540B-2011
03/23/2023
MD
230323-17-04
Fecal Coliforms
TH-4
<15625
MPN/g
SM92210E-2006
03/23/2023
MD
230323-17-04
Percent Solids
TH-4
1.28
%
SM2540B-2011
03/23/2023
MD
230323-17-05
Fecal Coliforms
TH-5
<15748
MPN/g
SM92210E-2006
03/23/2023
MD
230323-17-05
Percent Solids
TH-5
1.27
%
SM2540B-2011
03/23/2023
MD
230323-17-06
Fecal Coliforms
TH-6
59259.0
MPN/g
SM92210E-2006
03/23/2023
MD
230323-17-06
Percent Solids
TH-6
1.35
%
SM2540B-2011
03/23/2023
MD
230323-17-07
Fecal Coliforms
TH-7
<13605
MPN/g
SM92210E-2006
03/23/2023
MD
230323-17-07
Percent Solids
TH-7
1.47
%
SM2540B-2011
03/23/2023
MD
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 230323-17-01 Temp on Arrival: 2.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 230323-17-02 Temp on Arrival: 2.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 230323-17-03 Temp on Arrival: 2.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 230323-17-04 Temp on Arrival: 2.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 230323-17-05 Temp on Arrival: 2.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 230323-17-06 Temp on Arrival: 2.0
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 230323-17-07 Temp on Arrival: 2.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 04/18/2023
Reported: 04/21 /2023
For: TYHARMO
Comments: GEOMETRIC MEAN: 2499 MPN/g
j F S r l0 f 9 L U ,,,
A LY T ICA L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
230418-37-01
Fecal Coliforms
TH1
1389
MPN/g
SM92210E-2006
04/18/2023
MD
230418-37-01
Percent Solids
TH1
1.44
%
SM2540B-2011
04/18/2023
MD
230418-37-02
Fecal Coliforms
TH2
2740
MPN/g
SM92210E-2006
04/18/2023
MD
230418-37-02
Percent Solids
TH2
1.46
%
SM2540B-2011
04/18/2023
MD
230418-37-03
Fecal Coliforms
TH3
2759
MPN/g
SM92210E-2006
04/18/2023
MD
230418-37-03
Percent Solids
TH3
1.45
%
SM2540B-2011
04/18/2023
MD
230418-37-04
Fecal Coliforms
TH4
1389
MPN/g
SM92210E-2006
04/18/2023
MD
230418-37-04
Percent Solids
TH4
1.44
%
SM2540B-2011
04/18/2023
MD
230418-37-05
Fecal Coliforms
TH5
2740
MPN/g
SM92210E-2006
04/18/2023
MD
230418-37-05
Percent Solids
TH5
1.46
%
SM2540B-2011
04/18/2023
MD
230418-37-06
Fecal Coliforms
TH6
5517
MPN/g
SM92210E-2006
04/18/2023
MD
230418-37-06
Percent Solids
TH6
1.45
%
SM2540B-2011
04/18/2023
MD
230418-37-07
Fecal Coliforms
TH7
2759
MPN/g
SM92210E-2006
04/18/2023
MD
230418-37-07
Percent Solids
TH7
1.45
%
SM2540B-2011
04/18/2023
MD
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 230418-37-01 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230418-37-02 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230418-37-03 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230418-37-04 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230418-37-05 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230418-37-06 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230418-37-07 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 04/20/2023
Reported: 04/21 /2023
For: Mathis
Comments: GEOMETRIC MEAN: 37867 MPN/g
j F S r l0 f 9 L U ,,,
A LY T ICA L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
230420-12-01
Fecal Coliforms
M1
46154
MPN/g
SM92210E-2006
04/20/2023
WC
230420-12-01
Percent Solids
M1
0.65
%
SM2540B-2011
04/20/2023
WC
230420-12-02
Fecal Coliforms
M2
44776
MPN/g
SM92210E-2006
04/20/2023
WC
230420-12-02
Percent Solids
M2
0.67
%
SM2540B-2011
04/20/2023
WC
230420-12-03
Fecal Coliforms
M3
16418
MPN/g
SM92210E-2006
04/20/2023
WC
230420-12-03
Percent Solids
M3
0.67
%
SM2540B-2011
04/20/2023
WC
230420-12-04
Fecal Coliforms
M4
18841
MPN/g
SM92210E-2006
04/20/2023
WC
230420-12-04
Percent Solids
M4
0.69
%
SM2540B-2011
04/20/2023
WC
230420-12-05
Fecal Coliforms
M5
33824
MPN/g
SM92210E-2006
04/20/2023
WC
230420-12-05
Percent Solids
M5
0.68
%
SM2540B-2011
04/20/2023
WC
230420-12-06
Fecal Coliforms
M6
36145
MPN/g
SM92210E-2006
04/20/2023
WC
230420-12-06
Percent Solids
M6
0.83
%
SM2540B-2011
04/20/2023
WC
230420-12-07
Fecal Coliforms
M7
142857
MPN/g
SM92210E-2006
04/20/2023
WC
230420-12-07
Percent Solids
M7
0.77
%
SM2540B-2011
04/20/2023
WC
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 230420-12-01 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230420-12-02 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230420-12-03 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230420-12-04 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230420-12-05 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230420-12-06 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230420-12-07 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 05/16/2023
Reported: 05/17/2023
For: Tyson Wilkesboro
Comments: GEOMETRIC MEAN: 233,469 MPN/g
j F S r l0 f 9 L U ,,,
A LY T ICA L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
230516-22-01
Fecal Coliforms
TW1
225166
MPN/g
SM92210E-2006
05/16/2023
MD
230516-22-01
Percent Solids
TW1
7.55
%
SM2540B-2011
MD
230516-22-02
Fecal Coliforms
TW2
264386
MPN/g
SM92210E-2006
05/16/2023
MD
230516-22-02
Percent Solids
TW2
6.43
%
SM2540B-2011
MD
230516-22-03
Fecal Coliforms
TW3
281030
MPN/g
SM92210E-2006
05/16/2023
MD
230516-22-03
Percent Solids
TW3
8.54
%
SM2540B-2011
MD
230516-22-04
Fecal Coliforms
TW4
234483
MPN/g
SM92210E-2006
05/16/2023
MD
230516-22-04
Percent Solids
TW4
7.25
%
SM2540B-2011
MD
230516-22-05
Fecal Coliforms
TW5
125786
MPN/g
SM92210E-2006
05/16/2023
MD
230516-22-05
Percent Solids
TW5
6.36
%
SM2540B-2011
MD
230516-22-06
Fecal Coliforms
TW6
417827
MPN/g
SM92210E-2006
05/16/2023
MD
230516-22-06
Percent Solids
TW6
7.18
%
SM2540B-2011
MD
230516-22-07
Fecal Coliforms
TW7
183387
MPN/g
SM92210E-2006
05/16/2023
MD
230516-22-07
Percent Solids
TW7
9.27
%
SM2540B-2011
MD
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 230516-22-01 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230516-22-02 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230516-22-03 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230516-22-04 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230516-22-05 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230516-22-06 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230516-22-07 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 09/12/2023
Reported: 09/13/2023
For: TYWILK
Comments: Geometric Mean: <1483 MPN/g
j AT ' r l0 f 9 1:
A LY T ICA L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
230912-28-01
Fecal Coliforms
1
<1471
MPN/g
SM9221 CE-2014
09/12/2023
MD
230912-28-01
Percent Solids
1
13.6
%
SM2540B-2011
09/12/2023
MD
230912-28-02
Fecal Coliforms
2
<1538
MPN/g
SM9221 CE-2014
09/12/2023
MD
230912-28-02
Percent Solids
2
13.0
%
SM2540B-2011
09/12/2023
MD
230912-28-03
Fecal Coliforms
3
<1493
MPN/g
SM9221 CE-2014
09/12/2023
MD
230912-28-03
Percent Solids
3
13.4
%
SM2540B-2011
09/12/2023
MD
230912-28-04
Fecal Coliforms
4
<1471
MPN/g
SM9221 CE-2014
09/12/2023
MD
230912-28-04
Percent Solids
4
13.6
%
SM2540B-2011
09/12/2023
MD
230912-28-05
Fecal Coliforms
5
<1439
MPN/g
SM9221 CE-2014
09/12/2023
MD
230912-28-05
Percent Solids
5
13.9
%
SM2540B-2011
09/12/2023
MD
230912-28-06
Fecal Coliforms
6
<1481
MPN/g
SM9221 CE-2014
09/12/2023
MD
230912-28-06
Percent Solids
6
13.5
%
SM2540B-2011
09/12/2023
MD
230912-28-07
Fecal Coliforms
7
<1493
MPN/g
SM9221 CE-2014
09/12/2023
MD
230912-28-07
Percent Solids
7
13.4
%
SM2540B-2011
09/12/2023
MD
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 230912-28-01 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230912-28-02 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230912-28-03 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230912-28-04 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230912-28-05 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230912-28-06 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230912-28-07 Temp on Arrival: 2.5
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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PO Box 228 9 Statesville, NC 28687 9 704/872/4697
Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 09/14/2023
Reported: 09/15/2023
For: Tyson Harmony
Comments: Geometric Mean: 4049 MPN./g
j AT ' r l0 f 9 1:
A LY T ICA L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
230914-21-01
Fecal Coliforms
1
<3846
MPN/g
SM9221 CE-2014
09/14/2023
MD
230914-21-01
Percent Solids
1
0.52
%
SM2540B-2011
09/14/2023
MD
230914-21-02
Fecal Coliforms
2
<4348
MPN/g
SM9221 CE-2014
09/14/2023
MD
230914-21-02
Percent Solids
2
0.46
%
SM2540B-2011
09/14/2023
MD
230914-21-03
Fecal Coliforms
3
3922
MPN/g
SM9221 CE-2014
09/14/2023
MD
230914-21-03
Percent Solids
3
0.51
%
SM2540B-2011
09/14/2023
MD
230914-21-04
Fecal Coliforms
4
<4082
MPN/g
SM9221 CE-2014
09/14/2023
MD
230914-21-04
Percent Solids
4
0.49
%
SM2540B-2011
09/14/2023
MD
230914-21-05
Fecal Coliforms
5
<4000
MPN/g
SM9221 CE-2014
09/14/2023
MD
230914-21-05
Percent Solids
5
0.50
%
SM2540B-2011
09/14/2023
MD
230914-21-06
Fecal Coliforms
6
<4000
MPN/g
SM9221 CE-2014
09/14/2023
MD
230914-21-06
Percent Solids
6
0.50
%
SM2540B-2011
09/14/2023
MD
230914-21-07
Fecal Coliforms
7
<4167
MPN/g
SM9221 CE-2014
09/14/2023
MD
230914-21-07
Percent Solids
7
0.48
%
SM2540B-2011
09/14/2023
MD
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 230914-21-01 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230914-21-02 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230914-21-03 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230914-21-04 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230914-21-05 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230914-21-06 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230914-21-07 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 09/19/2023
Reported: 09/20/2023
For: Mathis
Comments:
j AT ' r l0 f 9 1:
A LY T ICA L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
230919-24-01
Fecal Coliforms
1
<2967
MPN/g
SM9221 CE-2014
09/19/2023
MD
230919-24-01
Percent Solids
1
6.74
%
SM2540B-2011
09/19/2023
MD
230919-24-02
Fecal Coliforms
2
<2959
MPN/g
SM9221 CE-2014
09/19/2023
MD
230919-24-02
Percent Solids
2
6.76
%
SM2540B-2011
09/19/2023
MD
230919-24-03
Fecal Coliforms
3
<2976
MPN/g
SM9221 CE-2014
09/19/2023
MD
230919-24-03
Percent Solids
3
6.72
%
SM2540B-2011
09/19/2023
MD
230919-24-04
Fecal Coliforms
4
<2981
MPN/g
SM9221 CE-2014
09/19/2023
MD
230919-24-04
Percent Solids
4
6.71
%
SM2540B-2011
09/19/2023
MD
230919-24-05
Fecal Coliforms
5
<2954
MPN/g
SM9221 CE-2014
09/19/2023
MD
230919-24-05
Percent Solids
5
6.77
%
SM2540B-2011
09/19/2023
MD
230919-24-06
Fecal Coliforms
6
<3003
MPN/g
SM9221 CE-2014
09/19/2023
MD
230919-24-06
Percent Solids
6
6.66
%
SM2540B-2011
09/19/2023
MD
230919-24-07
Fecal Coliforms
7
<2976
MPN/g
SM9221 CE-2014
09/19/2023
MD
230919-24-07
Percent Solids
7
6.72
%
SM2540B-2011
09/19/2023
MD
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 230919-24-01 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230919-24-02 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230919-24-03 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230919-24-04 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230919-24-05 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230919-24-06 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 230919-24-07 Temp on Arrival: 2.3
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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PO Box 228 9 Statesville, NC 28687 9 704/872/4697
Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 11/30/2023
Reported: 12/01 /2023
For: Tyson -Harmony
Comments: GEOMETRIC MEAN: 21230 MPN/g
j F S r l0 f 9 L U ,,,
A LY T ICA L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
231130-16-01
Fecal Coliforms
TH-1
20410
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-16-01
Percent Solids
TH-1
0.98
%
SM2540B-2011
11/30/2023
MD
231130-16-02
Fecal Coliforms
TH-2
20833
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-16-02
Percent Solids
TH-2
0.96
%
SM2540B-2011
11/30/2023
MD
231130-16-03
Fecal Coliforms
TH-3
21280
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-16-03
Percent Solids
TH-3
0.94
%
SM2540B-2011
11/30/2023
MD
231130-16-04
Fecal Coliforms
TH-4
22222
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-16-04
Percent Solids
TH-4
0.90
%
SM2540B-2011
11/30/2023
MD
231130-16-05
Fecal Coliforms
TH-5
22222
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-16-05
Percent Solids
TH-5
0.90
%
SM2540B-2011
11/30/2023
MD
231130-16-06
Fecal Coliforms
TH-6
20000
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-16-06
Percent Solids
TH-6
1.0
%
SM2540B-2011
11/30/2023
MD
231130-16-07
Fecal Coliforms
TH-7
21053
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-16-07
Percent Solids
TH-7
0.95
%
SM2540B-2011
11/30/2023
MD
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 231130-16-01 Temp on Arrival: 2.6
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 231130-16-02 Temp on Arrival: 2.6
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 231130-16-03 Temp on Arrival: 2.6
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 231130-16-04 Temp on Arrival: 2.6
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 231130-16-05 Temp on Arrival: 2.6
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 231130-16-06 Temp on Arrival: 2.6
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 231130-16-07 Temp on Arrival: 2.6
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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PO Box 228 9 Statesville, NC 28687 9 704/872/4697
Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 11/30/2023
Reported: 12/01 /2023
For: Tyson -Wilkesboro
Comments: GEOMETRIC MEAN: 4446 MPN/g
j F S r l0 f 9 L U ,,,
A LY T ICA L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
231130-17-01
Fecal Coliforms
TW-1
1000
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-17-01
Percent Solids
TW-1
1.1
%
SM2540B-2011
11/30/2023
MD
231130-17-02
Fecal Coliforms
TW-2
3846
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-17-02
Percent Solids
TW-2
1.04
%
SM2540B-2011
11/30/2023
MD
231130-17-03
Fecal Coliforms
TW-3
7207
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-17-03
Percent Solids
TW-3
1.11
%
SM2540B-2011
11/30/2023
MD
231130-17-04
Fecal Coliforms
TW-4
8247
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-17-04
Percent Solids
TW-4
0.97
%
SM2540B-2011
11/30/2023
MD
231130-17-05
Fecal Coliforms
TW-5
2062
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-17-05
Percent Solids
TW-5
0.97
%
SM2540B-2011
11/30/2023
MD
231130-17-06
Fecal Coliforms
TW-6
8537
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-17-06
Percent Solids
TW-6
0.82
%
SM2540B-2011
11/30/2023
MD
231130-17-07
Fecal Coliforms
TW-7
9091
MPN/g
SM9221 CE-2014
11/30/2023
MD
231130-17-07
Percent Solids
TW-7
0.88
%
SM2540B-2011
11/30/2023
MD
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 231130-17-01 Temp on Arrival: 1.9
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 231130-17-02 Temp on Arrival: 1.9
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 231130-17-03 Temp on Arrival: 1.9
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 231130-17-04 Temp on Arrival: 1.9
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 231130-17-05 Temp on Arrival: 1.9
Parameter Schedule: Percent Solids
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 231130-17-06 Temp on Arrival: 1.9
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
Sample Number 231130-17-07 Temp on Arrival: 1.9
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Chemicals in containers, lab
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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PO Box 228 9 Statesville, NC 28687 9 704/872/4697
Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 12/07/2023
Reported: 12/11/2023
For: Mathis 1
Comments:
j AT ' r l0 f 9 1:
A LY T ICA L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
231207-13-01
Fecal Coliforms
M F-1
1902748
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-13-01
Percent Solids
M F-1
4.73
%
SM2540B-2011
12/08/2023
MD
231207-13-02
Fecal Coliforms
M F-2
283224
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-13-02
Percent Solids
M F-2
4.59
%
SM2540B-2011
12/08/2023
MD
231207-13-03
Fecal Coliforms
M F-3
182119
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-13-03
Percent Solids
M F-3
6.04
%
SM2540B-2011
12/08/2023
MD
231207-13-04
Fecal Coliforms
M F-4
200236
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-13-04
Percent Solids
M F-4
8.49
%
SM2540B-2011
12/08/2023
MD
231207-13-05
Fecal Coliforms
M F-5
189189
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-13-05
Percent Solids
M F-5
7.40
%
SM2540B-2011
12/08/2023
MD
231207-13-06
Fecal Coliforms
M F-6
155945
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-13-06
Percent Solids
M F-6
5.13
%
SM2540B-2011
12/08/2023
MD
231207-13-07
Fecal Coliforms
M F-7
214477
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-13-07
Percent Solids
M F-7
3.73
%
SM2540B-2011
12/08/2023
MD
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 231207-13-01 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 231207-13-02 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 231207-13-03 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 231207-13-04 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 231207-13-05 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 231207-13-06 Temp on Arrival:
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 231207-13-07 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Page 4 of 4

Analytical Results
Terra Renewal
PO Box 306
Yadkinville, NC 27055
Receive Date: 12/07/2023
Reported: 12/11/2023
For: Tyson Danville
Comments:
j F S r l0 f 9 L U ,,,
N i � L fl C A L
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
231207-14-01
Fecal Coliforms
TD F-1
<2985
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-14-01
Percent Solids
TD F-1
6.7
%
SM2540B-2011
12/08/2023
MD
231207-14-02
Fecal Coliforms
TD F-2
<2571
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-14-02
Percent Solids
TD F-2
7.78
%
SM2540B-2011
12/08/2023
MD
231207-14-03
Fecal Coliforms
TD F-3
<2976
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-14-03
Percent Solids
TD F-3
6.72
%
SM2540B-2011
12/08/2023
MD
231207-14-04
Fecal Coliforms
TD F-4
<2594
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-14-04
Percent Solids
TD F-4
7.71
%
SM2540B-2011
12/08/2023
MD
231207-14-05
Fecal Coliforms
TD F-5
<3333
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-14-05
Percent Solids
TD F-5
6.0
%
SM2540B-2011
12/08/2023
MD
231207-14-06
Fecal Coliforms
TD F-6
<4202
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-14-06
Percent Solids
TD F-6
4.76
%
SM2540B-2011
12/08/2023
MD
231207-14-07
Fecal Coliforms
TD F-7
<3396
MPN/g
SM9221 CE-2014
12/07/2023
MD
231207-14-07
Percent Solids
TD F-7
5.89
%
SM2540B-2011
12/08/2023
MD
Respectfully submitted,
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 231207-14-01 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 231207-14-02 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 231207-14-03 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 231207-14-04 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 231207-14-05 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 231207-14-06 Temp on Arrival:
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 231207-14-07 Temp on Arrival:
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 4 of 4

5
Annual Pathogen & Vector Attraction Reduction Form for NCAC 2T Rules
(FORM PVRF 2T)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services,, Inc
WWTP Name- AdvancePierre Foods - Clarernont, NC
WQ Permit Number:
NPDES Number:
Monitoring, Period: From l/1/2023 , I , 0 12/31/2023
WQ0038097
N/A
Pathogen Reduction (15A N CAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A(tirne/ternp) D
I Alt B(Alk'freatment)Lj
I
1; All. (". (Prior Testing)L-1
rior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative Performed (Class A only) indicale "Process to Further Reduce Pathogens":
Compost 1:1 Heat ].)lying Il ffreatment 0 thennophilic I
Beta Ray El Gamma liar' El Pastettrization C
Class B:
[�jlt, (1) Fecal Density &J
Alt, (2) Process to Significantly RCdLLCC Pathogens
If applicable to alternative performed (Clasis B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying L3 1� Composting 0 Aerobic Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density
Nuniber of
Freclumey
Sainple
Parameter
in Sludge
Excee-
of Analysi�;,
Tpe
y
1"cs la-
Mni111111
Cleo. Mean
Maximurr
Units
ences
nioue
2x l0totine
NIPN
77320
222673
669291
MP'N/g
0
I/YR
Grab
92210E
601 power
per gnan of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
Weiglit)
Salmonella bac cria
3 WN per 4 granis
(in lieu offecal
totA solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T .1107') -Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j_
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
Alt. 6 (Alk. Stabilization Ij
Alt 7 (Drying - Stable) L.)
JAIL 8 (Drying - Unstable)
Alt. 9 (InJecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives %vere performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle-, Enviro. Manager
Preparers Narne and 'Title. (type or print)
3/l/2024
Land Applier Narne and Title (if applicable)(type or print)
Signature of Preparer* Date Si; natUre of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 CF`R Part 503.9(r) and 15A NCAC 2T, 1102 (26)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services,, Ine
WW1`P Name- Tyson -Danville, VA
WQ Permit Number:
NPDES Number:
Monitoring, Period: From I/l/2023 , I , 0 12/31/2023
WQ0038097
N/A
Pathogen Reduction (15A N CAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A(firne/ternp) D
I Alt B(Alk'freatment)Lj
I
1; All. C. (11'rior Testing)L-1
o Prior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative Performed (Class A only) indicale "Process to Further Reduce Paillogens"-
Compost 1:1 Heat Drying ID I feat Trcatrn en I thenno
Beta Ray El Gamma Ra' D Pastetifization C
Class B:
LLIt, (1) Fecal Density &J
Alt, (2) 1),ocess to Significantly RCdLLCC Patho,ens
If applicable to alternative performed (Class B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying L3 1� Composting 0 jAerobia Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density
Nuniber of
Freclumey
Sample
Parameter
in Sludge
Excec-
of Analysi�.;,
'Type
Minimum
Geo. Mean
Maximurr
Units
dences
nioue
2 x t Ott) the
NIPN
2571
3111
4202
MP'N/g
0
I/YR
Grab
92210E
601 power
per gnan of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
Weiglit)
Salmonella bac cria
3 WN per 4 granis
(in lieu offecal
totA solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T .1107') -Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j_
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
AIC 6 (Alk. Stabilization Ij
Alt 7 (Drying - Stable) L.)
JAIL 8 (Drying - Unstable)
Alt. 9 (InJecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives were performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle-, Enviro. Manager
Preparer Narne and 'Title. (type or print)
3/l/2024
Land Applier Narne and Title (if applicable)(type or print)
Signature of Preparer* Date Si; natUre of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 CF`R Part 503.9(r) and 15A NCAC 2T, 1102 (26)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services,, lane
WW1`P Name: RVAF ('Tyson) - Harmony, NC1'
WQ Permit Number:
NPDES Number:
Monitoring, Period: From I/l/2023 , I , 0 3/31/2023
WQ0038097
N/A
Pathogen Reduction (15A N CAC 02T .1106) - Please indicate level ach ieved and alternative performed:
Class A.-
Alt. A (lime/ternp) ZJ
I Alt 13 (Alk'freatment)D
All. C. (11'rior TNstirs
o Prior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative performed (Class A only) indicale "Process to Further Reduce Paillogens"-
Compost Heat Drying ID fleatTreatment therm ophilic El
Beta Ray El Gamma Ra' El Pastetifization C
Class B:
[:Llt, (1) Fecal Density &J
Alt, (2) 1),ocess to Significantly RCdLLCC Patho,ens
If applicable to alternative performed (Class B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying L3 1� Composting 0 jAerobic Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density
Nuniber of
Freclumey
Sainple
AnalyhZ77
Parameter
in Sludge
Excee-
of Analysis
'Type
1,ecl,�-
MininWIT],
Geo. Mean
Maximurr
Units
dences
nioue
2 x t Ott) the
NIPN
13605
18984
59259
MP'N/g
0
1 /Qtr
Grab
92210E
601 power
per grarn of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
Weiglit)
Salmonella bac cria
3 WN per 4 granis
(in lieu Oil fecal
LoW solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T.1 107) - Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j-
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
AIC 6 (Alk. Stabilization Ij
Alt 7 (Drying - Stable) L.)
JAIL 8 (Drying - Unstable)
Alt. 9 (Injecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives %vere performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle: Enviro. Manager
Prepares Narne and 'Title (type or print)
3/l/2024
Land Applier Narne and Title (if applicable)(type or print)
Signature of Preparer* Date Si; natUre of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 C`R Part 503.9(r) and 15A NCAC 2T, 1102 (26)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services,, Ine
WW1`P Name: RVAF ('Tyson) - Harmony. NC1'
WQ Permit Number:
NPDES Number:
Monitoring, Period: From 4/l/2023 , I , 0 6/30/2023
WQ0038097
N/A
Pathogen Reduction (15A N CAC 02T .1106) - Please indicate levcll achieved! and alternative performed:
Class A:
Alt. A (lime/ternp) D
I Alt 13 (Alk'freatment)[3
I;! All. C. (11'rior TN stin I
)L""
I
o Prior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative performed (Class A only) indicale "Process to Further Reduce Paillogens"-
Compost Heat Drying ID I feat Trcatrn en I thennophilic El
Beta Ray El Gamma liar' El Pastetifization C
Class B:
[:Llt, (1) Fecal Density &J
Alt, (2) 1),ocess to Significantly RCdLLCC Patho,ens
If applicable to alternative performed (Clasis B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying L3 1� Composting 0 jAerobic Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density
Nuniber of
Freclumey
Sample
AnalyhZ77
Parameter
in Sludge
Excec-
of Analysis
'Type
1,ecl,N-
MinitIM111,
Geo. Mean
Maximurr
Units
dences
nioue
2 x t Ott) the
NIPN
1389
2499
5517
MP'N/g
0
1 /Qtr
Grab
92210E
601 power
per gnan of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
Weiglit)
Salmonella bac cria
3 WN per 4 granis
(in lieu offecal
LoW solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T.1 107) - Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j_
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
AIC 6 (Alk. Stabilization Ij
Alt 7 (Drying - Stable) L.)
JAIL 8 (Drying - Unstable)
Alt. 9 (InJecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives %vere performed
ERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle-, Enviro. Manager
Preparer Narne and 'Title (type or print)
3/l/2024
Land Applier Narne and Title (if applicable)(type or print)
Signature of Preparer* Date Si; natUre of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 CF`R Part 503.9(r) and 15A NCAC 2T, 1102 (26)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services,, Inc
WW1`P Name: RVAF ('Tyson) - Harmony, NC1'
WQ Permit Number:
NPDES Number:
Monitoring, Period: From 7/l/2023 , I , 0 9/30/2023
WQ0038097
N/A
Pathogen Reduction (15A N CAC 02T .1106) - Please indicate levell achieved! and alternative performed:
Class A:
Alt. A (lime/ternp) D
I Alt 13 (Alk'freatment)[3
I;! All. C. (11'rior TN stin I
)
o Prior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative performed (Class A only) indicale "Process to Further Reduce Paillogens"-
Compost Heat Drying ID I feat Trcatrn en I thennophilic El
Beta Ray El Gamma Rai' El Pastetifization C
Class B:
[:Llt, (1) Fecal Density &J
Alt, (2) 1),ocess to Significantly RCdLLCC Patho,ens
If applicable to alternative performed (Clasis B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying L3 1� Composting 0 jAerobia Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density
Nuniber of
Freclumey
Sample
AnalyhZ77
Parameter
in Sludge
Excec-
of Analysis
'Type
1,ecl,N-
MinitIM111,
Cleo. Mean
Maximurr
Units
dences
nioue
2 x t Ott) the
NIPN
3846
4049
4348
MP'N/g
0
1 /Qtr
Grab
92210E
601 power
per grarn of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
Weiglit)
Salmonella bac cria
3 WN per 4 granis
(in lieu offecal
LoW solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T.1 107) - Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j_
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
AIC 6 (Alk. Stabilization Ij
Alt 7 (Drying - Stable) (,.)
JAIL 8 (Drying - Unstable)
Alt. 9 (InJecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives %vere performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle-, Enviro. Manager
Preparers Marne nand 'Title (type or print)
3/l/2024
Land Applier Narne and Title (if applicable)(type or print)
Signature of Preparer* Date Si; natUrC of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T, 1102 (26)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services,, Ine
WW1`P Name: RVAF ('Tyson) - Harniony, NC"
WQ Permit Number:
NPDES Number:
Monitoring, Period: From 10/1/2023 , I , 0 12/31/2023
WQ0038097
N/A
Pathogen Reduction (I 5A N CAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (Iii-ne/ternp) D
I Alt 13 (Alk'freatment)Lj
I
1; All. C. (11'rior TN stirs
o Prior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative performed (Class A only) indicale "Process to Further Reduce Paillogens"-
Compost 1:1 Heat Drying ID fleatTreatment thenno
Beta Ray El Gamma Rai' D Pastetifization C
Class B:
LLIt, (1) Fecal Density &J
Alt, (2) 1),ocess to Significantly RCdLLCC Patho,ens
If applicable to alternative performed (Clasis B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying L3 1� Composting 0 jAerobic Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density
Nuinber of
Freclumey
Sample
AnalyhZ77
Parameter
in Sludge
Excee-
of Analysis
'Type
1,ecl,N-
Mi nitnUIT],
Geo. Mean
M aximurr
Units
dences
11ioue
2 x t Ott) the
NIPN
2000,0
21230
22222
MP'N/g
0
1 /Qtr
Grab
92210E
601 power
per gnan of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
Weiglit)
Salmonella bac cria
3 WN per 4 granis
(irN lieu offecal
LoW solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T.1 107') - Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j_
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
Alt. 6 (Alk. Stabilization j
Alt 7 (Drying - Stable) L.)
JAIL 8 (Drying - Unstable)
Alt. 9 (ln,jecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives %vere performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle-, Enviro. Manager
Preparer Marne nand 'Title (type or print)
3/l/2024
Land Applier Narne and Title (if applicable)(type or print)
Signature of Preparer* Date Si; natUrC of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T, 1102 (26)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services,, Inc
WWTPName- Mathis-I(Storage Facility)
WQ Permit Number:
NPDES Number:
Monitoring, Period: From I/l/2023 , I , 0 3/31/2023
WQ0038097
N/A
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level ach ieved and alternative performed:
Class A:
Alt. A(firne/ternp) ZJ
I Alt B(Alk'freatment)D
All. C. (11'rior TNstirs
o Prior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative performed (Class A only) indicale "Process to Further Reduce Paillogens"-
Compost Heat Drying ID I feat Trcatrn en I thennophilic El
Beta Ray El Gamma RaL El Pastetifization C
Class B:
[:Llt, (1) Fecal Density &J
Alt, (2) 11iocess to Significantly RCdLLCC Pathogeris,
If applicable to alternative performed (Clasis B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying L3 1� Composting 0 jAerobia Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density
Nuniber of
Freclumey
Sample
AnalyhZ77
Parameter
in Sludge
Excee-
of Analysis
'Type
1,ecl,�-
MininlUrr,
GCO. Mean
Maximurr
Units
dences
nioue
2x l0totine
MPN
175438
319364
468750,
MP'N/g
0
1 /Qtr
Grab
92210E
601 power
per grarn of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
Weiglit)
Salmonella bac cria
3 WN per 4 granis
(in lieu Oil fecal
LoW solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T.1107) -Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j_
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
Alt. 6 (Alk. Stabilization Ij
Alt 7 (Drying - Stable) L.)
JAIL It (Drying - Unstable)
Alt. 9 (InJecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives %vere performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle-, Enviro. Manager
Prepares Narne and 'Title. (type or print)
3/1/2024
Land Applier Narne and Title (if applicable)(type or print)
Signature of Preparer* Date Si; natUre of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T, 1102 (26)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services,, Inc
WWTP Name- Mathis-1 (Storage Facility)
WQ Permit Number:
NPDES Number:
Monitoring, Period: From 4/l/2023 , I , 0 6/30/2023
WQ0038097
N/A
Pathogen Reduction (15A N CAC 02T .1106) - Please i ndicate levcll achieved! and alternative performed:
Class A:
Alt. A(firne/ternp) D
I Alt B(Alk'freatment)[-j
I;! All. C. (11'rior TN stin I
)L""
I
o Prior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative performed (Class A only) indicale "Process to Further Reduce Paillogens"-
Compost Heat Drying ID I feat Treatni en I therm ophilic El
Beta Ray El Gamma Rai' El Pastetifization C
Class B:
[:Llt, (1) Fecal Density &J
Alt, (2) Process to Significantly RCdLLCC Pathogeris,
If applicable to alternative performed (Class B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying L3 1� Composting 0 jAerobic Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density
Nuniber of
Freclumey
Sainple
AnalyhZ77
Parameter
in Sludge
Excec-
of Analysis
'Type
1,ecl,N-
Mini][11MY
Geo. Mean
Maximum
Units
dences
nioue
2 x t Ott) the
NIPN
16418
37867
142957
MP,N/g
0
1 /Qtr
Grab
92210E
601 power
per grarn of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
Weiglit)
Salmonella bac cria
3 WN per 4 granis
(in lieu offecal
LoW solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T.1107') -Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j_
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
Alt. 6 (Alk. Stabilization Ij
Alt 7 (Drying - Stable) L.)
JAIL It (Drying - Unstable)
Alt. 9 (InJecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives %vere performed
ERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle-, Enviro. Manager
Preparer Narne and'Title (type or print)
3/l/2024
Land Applier Narne and Title (if applicable)(type or print)
Signature of Preparers` Date Si; natUre of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 C`R Part 503.9(r) and 15A NCAC 2T, 1102 (26)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services,, Inc
WWTPName- Mathis-I(Storage Facility)
WQ Permit Number:
NPDES Number:
Monitoring, Period: From 7/1/2023 , I , 0 9/30/2023
WQ0038097
N/A
Pathogen Reduction (15A N CAC 02T .1106) - Please i ndicate levell achieved! and alternative performed:
Class A:
Alt. A (firne/ternp) ZJ
I Alt 13 (Alk'freatment)[-j
I;! All. C. (Prior TN stin I
)L""
I
o Prior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative performed (Class A only) indicale "Process to Further Reduce Pathogens":
Compost Heat ].)lying D I feat Treatni en I thennophilic El
Beta Ray El Gamma Rai' El Pastetifization C
Class B:
[:Llt, (1) Fecal Density &J
Alt, (2) 11iocess to Significantly RCdLLCC Patho,eras
If applicable to alternative performed (Class B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying LJ 1� Composting 0 jAerobic Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density
Nuniber of
Freclumey
Sainple
AnalyhZ77
Parameter
in Sludge
Excee-
dences
of Analysis
'Type
1,ecl,N-
nioue
MinitIlUrr,
Geo. Mean
Maximum
Units
2 x ll Ott) the
NIPN
2959
2974
3003
MP'N/g
0
1 /Qtr
Grab
92210E
601 power
per grarn of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
Weiglit)
Salmonella bac cria
3 WN per 4 granis
(in lieu offecal
LoW solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T.1 107) - Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j_
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
AIC 6 (Alk. Stabilization Ij
Alt 7 (Drying - Stable) L.)
JAIL 8 (Drying - Unstable)
Alt. 9 (Injecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives %vere performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle-, Enviro. Manager
Preparer Narne and 'Title (type or print)
3/1/2024
Land Applier Narne and Title (if applicable)(type or print)
Signature of Preparers` Date Si; natUre of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T, 1102 (26)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services,, Inc
WWTP Name- Mathis-1 (Storage Facility)
WQ Permit Number:
NPDES Number:
Monitoring, Period: From 10/1/2023 , I , 0 12/31/2023
WQ0038097
N/A
Pathogen Reduction (15A N CAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (firne/ternp) D
I Alt 13 (Alk'freatment)Lj
I
1; All. C. (11'rior TN stirs
o Prior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative performed (Class A only) indicale "Process to Further Reduce Paillogens"-
Compost 1:1 Heat ].)lying D I feat Trcatrn en I thenno
Beta Ray El Gamma Rai' D Pastettrization C
Class B:
LLIt, (1) Fecal Density &J
Alt, (2) Process to Significantly RCdLLCC Pathogeris,
If applicable to alternative performed (Class B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying L3 1� Composting 0 jAerobic Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density
Nuniber of
Freclumey
Sainple
AnalyhZ77
Parameter
in Sludge
Excec-
of Analysis
'Type
1,ecl,N-
Minitnurr
Geo. Mean
Maximum
Units
dences
nioue
2 x lO to the
NIPN
182119
276754
1902748
MP'N/g
0
1 /Qtr
Grab
92210E
601 power
per grarn of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
Weiglit)
Salmonella bac cria
3 WN per 4 granis
(in lieu cal fecal
LoW solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T.1 107') - Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j_
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
Alt. 6 (Alk. Stabilization Ij
Alt 7 (Drying - Stable) L.)
JAIL It (Drying - Unstable)
Alt. 9 (InJecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives %vere performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle-, Enviro. Manager
Preparer Mamie and 'Title (type or print)
3/l/2024
Land Applier Narne and Title (if applicable)(type or print)
Signature of Preparers` Date Si; natUre of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 C`R Part 503.9(r) and 15A NCAC 2T, 1102 (26)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc.
WW"I'P Name- Tyson - Wilkesboro, NC
WQ Permit Number:
NPDES Number:
Monitoring, Period: From l/l/2023 , I , 0 3/31/2023
WQ0038097
N/A
Pathogen Reduction (15A N CAC 02T .1106) - Please indicate level ach ieved and alternative performed:
Class A:
Alt. A(fime/ternp) ZJ
I Alt B(Alk'freatrnent)D
All. C. (Prior TNstirs
o Prior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative performed (Class A only) indicale "Process to Further Reduce Paillogens"-
Compost Heat Dlying ID I feat Treatni en I therm ophilic El
Beta Ray El Gamma Ra' El Pastetifization C
Class B:
[:Llt, (1) Fecal Density &J
Alt, (2) 1),ocess to Significantly RCdLLCC Patho,ens
If applicable to alternative performed (Class B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying L3 Cornposting 0 jAerobic Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density
Nuiriber of
Freclumey
Sarnple
AnalyhZ77
Parameter
in Sludge
Excec-
of Analysis
'Type
1,ecl,N-
Mini][TWIT
Geo. Mean
Maximum
Units
dences
nitrue
2 x t Ott) the
NIPN
3128
7552
14870
MP'N/g
0
1 /Qtr
Grab
92210E
601 power
per gnan of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
weiglit)
Salmonella bac cria
3 NIPN per 4 granis
(in lieu offecal
Lentil solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T .1107') -Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j_
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
AIC 6 (Alk. Stabilization Ij
Alt 7 (Drying - Stable) L.)
JAIL 8 (Drying - Unstable)
Alt. 9 (InJecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives %vere performed
ERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle-, Enviro. Manager
Preparers Narne and'Title (type or print)
3/l/2024
Land Applier Narne and Title (if applicable)(type or -print)
Signature of Preparers` Date Si; natUre of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 CF`R Part 503.9(r) and 15A NCAC 2T, 1102 (26)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc,
WW"I'P Name- Tyson - Wilkesboro, NC
WQ Permit Number:
NPDES Number:
Monitoring, Period: From 4/l/2023 , I , 0 6/30/2023
WQ0038097
N/A
Pathogen Reduction (15A N CAC 02T .1106) - Please indicate level achieved! and alternative performed:
Class A:
Alt. A(firne/ternp) D
I Alt B(Alk'freatment)[-j
I;! All. C. (Prior TN stin) L"" I
I
o Prior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative performed (Class A only) indicale "Process to Further Reduce Paillogens"-
Compost Heat Dlying ID I feat Treatni en I therm ophilic El
Beta Ray El Gamma Ra' El Pastettrization C
Class B:
[:Llt, (1) Fecal Density &J
Alt, (2) Process to Significantly RCdLLCC Patho,ens
If applicable to alternative performed (Class B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying L3 1� Composting 0 jAerobic Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density
Nuiriber of
Freclumey
Sarnple
AnalyhZ77
Parameter
in Sludge
Excec-
of Analysis
'Type
1,ecl,N-
Minitfl.Urr,
GCO. Mean
Maximurr
Units
dences
nitrue
2x l0totine
MPN
125786
233469
417927
MP'N/g
0
1 /Qtr
Grab
92210E
601 power
per gnan of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
weiglit)
Salmonella bac cria
3 NIPN per 4 granis
(in lieu offecal
LoW solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T .1107') -Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j_
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
Alt. 6 (Alk. Stabilization Ij
Alt 7 (Drying - Stable) L.)
JAIL 8 (Drying - Unstable)
Alt. 9 (InJecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives %vere performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle-, Enviro. Manager
Preparers Narne and'Title (type or print)
3/l/2024
Land Applier Narne and Title (if applicable)(type or print)
Signature of Preparer* Date Si; natUre of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 CF`R Part 503.9(r) and 15A NCAC 2T, 1102 (26)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc.
WW"I'P Name- Tyson - Wilkesboro, NC
WQ Permit Number:
NPDES Number:
Monitoring, Period: From 7/l/2023 , I , 0 9/30/2023
WQ0038097
N/A
Pathogen Reduction (15A N CAC 02T .1106) - Please i ndicate level achieved! and alternative performed:
Class A:
Alt. A (fime/ternp) ZJ
I Alt 13 (A1k1reatment)[J
I;! All. C. (Prior TN stin I
o L""
I
o Prior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative performed (Class A only) indicale "Process to Further Reduce Pathogens":
Compost Heat ].)lying D I feat Treatni en I thennophilic El
Beta Ray El Gamma Ran' El Pastetifization C
Class B:
[:Llt, (1) Fecal Density &J
Alt, (2) 1),ocess to Significantly RCdLLCC Patho,ens
If applicable to alternative performed (Clasis B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying LJ 1� Composting 0 jAerobic Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density.
Nuiriber of
Freclumey
Sarnple
AnalyhZ77
Parameter
in Sludge
Excec-
of Analysis
'Type
1,ecl,N-
Mininiurr
Gee). Mean
Maximury
Units
dences
nitrue
2 x t Ott) the
MPN
1471
1483
1538
MP'N/g
0
1 /Qtr
Grab
92210E
601 power
per gnan of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
weiglit)
Salmonella bac cria
3 MPN per 4 granis
(in lieu offecal
LoW solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T.1 107) - Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j_
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
Alt. 6 (Alk. Stabilization Ij
Alt 7 (Drying - Stable) L.)
JAIL 8 (Drying - Unstable)
Alt. 9 (InJecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives %vere performed
ERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle-, Enviro. Manager
Preparer Narne and'Title (type or print)
3/l/2024
Land Applier Narne and Title (if applicable)(type or print)
Signature of Preparers` Date Si; natUre of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T, 1102 (26)

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Terra Renewal Services, Inc.
WW"I'P Name- Tyson - Wilkesboro, NC
WQ Permit Number:
NPDES Number:
Monitoring, Period: From 10/1/2023 , I , 0 12/31/2023
WQ0038097
N/A
Pathogen Reduction (I 5A N CAC 02T .1106) - Please indicate level ach ieved and alternative performed:
Class A:
Alt. A (firne/ternp) [J
I Alt 13 (Alk'freatment)Lj
I
1; All. C. (Prior Testing)z'"I
o Prior Tc
)cess to Further Reduce Pathogengs J
If applicable to alternative performed (Class A only) indicale "Process to Further Reduce Pathogens":
Compost 11 Heat ].)lying D heat Treatni en I thenno
Beta Ray El Gamma Ra' D Pastetifization C
Class B:
LLIt, (1) Fecal Density &J
Alt, (2) 1),ocess to Significantly RCdLLCC Patho,errs
If applicable to alternative performed (Class B oull indicate "Process to Significantly Reduce Pathogens,":
Lime Stabilization Ej Air Drying L3 1� Composting 0 jAerobic Digestion 0
Anaerobic Digestion [J
If applicable to alternative performed (Class A or Class B) complete the following monitoring data:
Allomrable Level
Pathogen Density
Nuiriber of
Freclumey
Sarnple
AnalyhZ77
Parameter
in Sludge
Excec-
of Analysis
'Type
1,ecl,N-
MinitIM111,
Geo. Mean
Maximum
Units
dences
nitrue
2 x t Ott) the
NIPN
10,00
4446
9091
MPN/g
0
1 /Qtr
Grab
92210E
601 power
per gram of
Fecal Coliform
total solids
C, F tj
10,00 rnpn per grain
of total sofid (dry
weiglit)
Salmonella bac cria
3 NIPN per 4 granis
(in lieu offecal
LoW solid (dry
colif,611TI)
I weiglit)
I
I
I
I
I
I
I
I
Vector Attraction Reduction (15A NCAC 02T.1 107') - Please indicate alternative performed:
Alt. I (VS reduction) L]
Alt. 2 (40-day bench) j
Alt. 3 ('30-day bench) L7j_
Alt. 4 (Spec. 0, uptake)
Alt. 5 (14-Day Aerobic)
Alt. 6 (Alk. Stabilization Ij
Alt 7 (Drying - Stable) L.)
JAIL 8 (Drying - Unstable)
Alt. 9 (Injecdon)
Alt, 10 (Incorporation) ?.3
No vector attraction reduction alternatives %vere performed
CERTIFICATION STATEMENT (please check the appropriate statement)
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
"I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T.1 106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been ]net."' (Please note
if you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure, that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
David C. Coyle-, Enviro. Manager
Preparers Narne and 'Title (type or print)
3/l/2024
Land Applier Narne and Title (if applicable)(type or print)
Signature of'Preparer* Date Si; natUre of Land Applier (ifapplicable) Date
*11'reparer is defined in 40 CF`R Part 503.9(r) and 15A NCAC 2T, 1102 (26)

6
Soil Test Reports
(for fields applied in 2023)

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