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Home My WebLink AboutWQ0006242_2023 Residual Annual Report_20240219 (2)Initial Review Reviewer nathaniel.thorn burg Is this submittal an application? (Excluding additional information.) * Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2023 Permit Number (IR) * W00006242 Applicant/Permittee Town of Sparta Email Notifications Does this need review by the hydrogeologist? * Yes U No Regional Office Winston-Salem CO Reviewer Admin Reviewer Wanda Gerald Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. Name* Lysa Finnerty Email Address* Ifinnerty@SYNAGRO.com Project Information ......................... Application/Document Type* New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Phone Number* 4105376150 Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, N DAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High -Rate Infiltration Other Wastewater Reclaimed Water Closed -Loop Recycle Residuals Single -Family Residence Wastewater Other Irrigation Permit Number:* WQ0006242 Has Current Existing permit number Applicant/Permittee Address* 435 Williams Court, Ste 100, Baltimore, MD 21220 Facility Name* Town of Sparta Class B Residuals Program Please provide comments/notes on your current submittal below. Submission of the 2023 Annual Report for Town of Sparta, NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. (Application Form, Engineering Plans, Specifications, Calculations, Etc.) Sparta NC 2023 Annual Report FINAL.pdf 4.53MB Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Alva �Cit'wt%tt, Submission Date 2/19/2024 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 17, 2024 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2023 Annual Report for Permit No. WQ0006242 Dear NCDEQ: SYNAGRO Synagro is submitting one electronic copy of the above referenced report on behalf of the Town of Sparta, NC. If you have any questions or need additional information, please do not hesitate to contact Ryan Wilmouth at (336) 372-4257 or Alex Fox at (336) 703-8681. Sincerely, Devil ck shhfcm leg Derrick Shivar Environmental Compliance Manager Enclosures cc: Ryan Wilmouth, Town of Sparta Alex Fox, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD TOWN OF SPARTA, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0006242 2023 ANNUAL REPORT Town of Sparta, NC Residuals Land Application Program 2023 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Forms & Metals Field Loading Summary Forms 4. TCLP Analysis 5. Pathogen Reduction/Vector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Pennit #: W00006242 County Alleglrany Year 2023 Facility Name (as shown on pen -nit) Town ofSnarta WWTP NPDES No. NCO026913 Land Application Operator Synagro Phone# (336) 999-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total member of application fields in the permit: 7 Total number of fields utilized for land application during the year: 2 Total amount of dry tons applied during the year for all application sites: 32.07 Total number of acres utilized for land application during the year: 55.30 Part B — Annual Compliance Statement. Facility was compliant during calendar year 2023 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality X YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. l . Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pI-I of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3 ) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .l 105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T .l I I I were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was performed on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Rvan Wilmoth, Town Manager Pennittee Name and Title (type or print) Signature of Preparer* Date (if different from Pennittee) 3tMj nature of Pe itnee Date 0l/31 !2024 S n rare of La Applier Date (if different rom Pennittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2023 - 12/31/2023 SPARTA,NC SPARTA, NC LIME STABILIZED LIQUID MONTH/YEAR AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS February 2023 84,000.00 G 5.92 D 5.37 March 2023 136,500.00 G 9.62 D 8.72 July 2023 91,000.00 G 6.41 D 5.82 November 2023 84,000.00 G 5.92 D 5.37 December 2023 59,500.00 G 4.19 D 3.80 TOTAL Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards Report Date: 1/25/2024 2:12:38 PM 455,000.00 G 32.07 D 29.08 SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: WQ0006242 Laboratory: Facility Name: SPARTA, NC PACE ANALYTICAL Residual Source WQ # or NPDES#: NCO026913 WWTP Name: SPARTA Residual Analysis Data Product Type LSLIQ Sample or Composite Date 01/10/23 Parameter (mg/kg dry weight) Ceiling Conc. Limit Percent Solids (%) NA 1.69 Arsenic 75 <4.8 Cadmium 85 <1.2 Copper 4300 440 Chromium NA 22 Lead 840 15 Mercury 57 <1 Molybdenum 75 <9.6 Nickel 420 19 Selenium 100 <7.8 Zinc 7500 490 Total Phosphorus NA 22000 TKN NA 30000 Ammonia -Nitrogen NA 1400 Nitrate and Nitrite NA 5888 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penally of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and 1p oft lent for knowing violations." 1.3 Zoz�f Signature of Preparer' Date `Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF (12/2006) Printed: 1/25/2024 4:31:37 PM For: 2040 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0006242 Facility Name: SPARTA, NC Residual Source NPDES # or WQ#: NCO026913 WWTP Name: SPARTA Residual Analysis Data Product Type LSLIQ Sample or Composite Date 01/10/23 Parameters (mg/kg dry weight) Aluminium 12000 Calcium 180000 Magnesium 5000 pH (s.u.) 11.30 Potassium 4600 Sodium 2400 PAN 15168 SAR (Ratio) 0.1977 Laboratory: PACE ANALYTICAL "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Si re of Preparer' ate 'Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) Printed: 1125/2024 4:32:31 PM For: 2040 01 DENR FORM RSSF-B (1212006) aceAnalytical an- Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Sparta Lot Number:YA12100 Date Completed:01/30/2023 01/30/2023 3:09 PM Approved and released by: Project Manager II: Lucas Odom 4�Q pC14A " ANSI National AnnMdWon BWd ACCREDITED TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 7 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: YA12100 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPS), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPS or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight unless flagged with a "W" qualifier. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Inorganic Metals Sample -001 has been analyzed using approximately three grams of sample due to the low percent solid level. The LOQs have been adjusted accordingly. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 2 of 7 Client:Synagro Laboratory I D: YA1 2100-001 Description: SPARTA Matrix: Solid Date Sampled:01/10/2023 0700 % Solids: 1.69 01/16/2023 1842 Date Received:01/12/2023 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 254OG 1 01/16/2023 1842 TAD 65010 1 350.1 (Ammonia - N ) 350.1 1 01/25/2023 1329 DMA 65582 1 (Nitrate - N ) 353.2 10 01/26/2023 1145 CMM 66119 1 (Nitrite - N ) 353.2 10 01/26/2023 1145 CMM 66116 1 (Phosphorus) 365.1 25 01/16/2023 1810 DMA 01/16/2023 0859 64846 1 (Soil pH meas) 9045D 1 01/17/2023 1206 BMG2 64825 2 351.4 (TKN) 351.2 1 01/19/2023 1820 DMA 01/17/2023 1258 64991 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 2540G 1.69 % 1 Ammonia - N (gas diffusion) 350.1 1400 59 31 mg/kg 1 Nitrate - N (soluble) 353.2 5800 S 120 16 mg/kg 1 Nitrite - N (soluble) 353.2 88 J 120 16 mg/kg 1 Phosphorus 7723-14-0 365.1 22000 7400 1500 mg/kg 1 Soil pH measured in water @ 11.7 ° C 9045D 11.3 su 1 TKN 351.2 30000 3000 1500 mg/kg 2 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 01/14/2023 1425 MRW2 01/14/2023 1025 64810 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 4.3 1.0 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 01/18/2023 0034 JMH 01/17/2023 0843 64804 2 3050B 601OD 1 01/19/2023 0454 JMH 01/17/2023 0843 64804 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 12000 390 140 mg/kg 1 Arsenic 7440-38-2 6010D ND 14 4.8 mg/kg 1 Cadmium 7440-43-9 6010D ND 4.8 1.2 mg/kg 1 Calcium 7440-70-2 6010D 180000 4800 600 mg/kg 1 Chromium 7440-47-3 6010D 22 9.6 2.4 mg/kg 1 Copper 7440-50-8 6010D 440 9.6 4.3 mg/kg 1 Iron 7439-89-6 6010D 16000 96 44 mg/kg 1 Lead 7439-92-1 6010D 15 9.6 4.3 mg/kg 1 Magnesium 7439-95-4 6010D 5000 4800 600 mg/kg 1 Manganese 7439-96-5 6010D 170 14 5.7 mg/kg 1 Molybdenum 7439-98-7 6010D ND 39 9.6 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 7 Client:Synagro Laboratory I D: YA1 2100-001 Description: SPARTA Matrix: Solid Date Sampled:01/10/2023 0700 % Solids: 1.69 01/16/2023 1842 Date Received:01/12/2023 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 01/18/2023 0034 JMH 01/17/2023 0843 64804 2 3050B 601OD 1 01/19/2023 0454 JMH 01/17/2023 0843 64804 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Nickel 7440-02-0 Potassium 7440-09-7 Selenium 7782-49-2 Sodium 7440-23-5 Zinc 7440-66-6 6010D 19 J 39 10 mg/kg 2 6010D 4600 J 4800 600 mg/kg 1 6010D ND 19 7.8 mg/kg 1 6010D 2400 J 4800 600 mg/kg 1 6010D 490 48 12 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 7 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 7 PACE ANALYTICAL SERVICES. LLC c Ip 1D S ram. i i Y U e J Z X/ fil nn Ll p d r yyJ G N Z i N �... m •if O z 1 rtl O Q O x W a `� _ Cn cV� U. Y/ E r, Lll G Q 2<t�t:r, r• a z ~ L n t uog•»Ilv: I 2 M rCC Y j ons�ewc�:� x _ W x x .6 � 3 } d £0 I N cc Itl a ,= nP ai F. I � r o .5 I , O E W a _ a Z r ILO t C 1=C LL rn i,- ciS il. •� L m U U C� O. E n m A� 'tp E V i C C y a mar, ti_ O C U I +1 C c •,4 g � v Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 7 e a O o w PACE ANALYTICAL SERVICES, LLC DC# Title: ENV-FRM-WCOL-0286 v02_Samptes Roccipt CheckRA- {SRC) Mective Date: 8/2f 2022 Sample Receipt Checklist (SRC LIIenE, • •••' •` • -- - LOOLU InSMCtea O)jar. C: ••- - I V l .- - Lot 4: lea euw Yesl li(INOI IL Were custody seals present otl ille Cooley! JYcsj I INolv% NA 2. If listod seals were resent, were they Intact turd unbroken? Ldh"od: p lll; vA CMoriW Strip ID: N A Tested by: wA l temperature upon receiln i Derived (('ol>•eLje(I) leulperatlur. upou receipt °'oSolid Slur)-Oip ID: 2a-2027 1.5 oC kA ;NA :AC NA I NA °C NA / NA oC [%]7 cmperahnC 131ank- inst Botd IRGiln ID: h IR Gun Coricctlon R✓ 01. 0°C of Coolant: ✓ Vet Ic ice Pacla QDwke 0 Nonc 21Yes ❑\o ❑CIA 3. Wets all coolers received at er below 6.0`'C? If no. tvas Project �SslraLrr notific(i? Ptii was Notified by: phone! email i face-ro-faLe (circle nrle). 4. Is the corunlercW courier's pacldng slip attached to this fanii? Yes Ito 5. were proper custodyproeeduncs 1'relilultlisllcd!rcceived) followedl., Yes UNo 6. Were sample IDS listed Oil 111C C F) , and all sample colwWRrs? 7. Was collectimi elate & time listed ou tllr CCW and ail sample eaatalilwn? Yes T-1n Yea nNk, R_ Did all contiiurr label iufonuaticut (ID, date. rune) aArc: ii ai isle COC? Yes Rio 9. Were tests to be perfbirmtd listed on dx COC? QYcs ❑No 10.Did all stunples anive in the proper musilleis for cac11 test anfVor in good condition (unbrolom lids o11. etc)? - No i 1. Was adei 11alc sat Vic vultutic available? No 12. Were all sammles received within 1/1 the holding tin a or 481wuN.whichrver cotucs first? ❑No 13. Were all samples containers accomllcd for? (;�o mimbipiexcess) rV_Yles ❑ Na iNA 14. Were VOA. 901 SC ana IiSIC-175 s(urlplcs free of bubbles "pea-sire"('/�'or tirnm in diameter) ill any of the VOA vials^ 15. Were all DR011netelsinnrrient sally Des received at a H of< 27 No J A Ne7 �/ 16. Were all cvazidr. s 1csrcccircdlit a H= 12and sulfidesampic. =i%TLI nt��,,� ❑No Ir l"A Wcr�c . app ical)leNHy�!c)7ujide/ iC '625.1!608.3 (<0.5111g sa1111t esfrre o residual chlnrinO ❑✓ No ❑NA 18. Was the quote number listed on d1: container' label'! if }vs. Quote SAruple Preser41ation jjvItut be eMWicted forallysample(s) inconrrctlypreservati orwitllheadspacc.) Sample(s) N , weie received 1llcoliectly prrserved and 1i'Prt adjusred ucordingly in sample receiving Kith NA mL of circle one: MSU1,1-NO3. HCl, NAOH using Sit � � A Time of preservation NA u. If more than one preser aathv is needed, please tote 111 die commews below. NA. were veceived with bobbles ?6 um in diameter. 'nlples(s) NA urrc received with 'IRC 0.5 Ir1gg., (IfV19 is nu) and were f djwpv'i -,:v �diii l}- in sample receiving with sodium thiosillfaw (Na2S241) with lhlique M. NA Qualtraz in: 56360 Pace' !Analytical Services, LLC Page 1 of 1 Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 7 SECTION 3 FACILITY NAME: SPARTA, NC LANDOWNER: GREG WAGONER OPERATOR:GREG WAGONER CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): ' See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WO PERMIT#: W00006242 FIELD#: NC-AG-00005-0-0001- ANNUAL DRY TONS APPLIED: 21.96 SITE #: NC AG 00005 PREDOMINANT SOIL SERIES: CHESTER CROP 1 MAX. PAN: 178 CROP 2 NAME: ACRES UTILIZED: 29.6 ACRES PERMITTED: 29.6 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Solids Dry Tons/Ac Source Moist Inches Method' Rate" Rate- mg/kg mg/kg mg/kg Amount U0M Crop 1 Crop 2 Crop 1 Crop 2 2/8/2023 42,000.00 (G) 1.690 0.100 SPLSL MOIST 0-<1/2"" SUR 0.5 0.30 30,000.00 1.400.00 5,888.00 3.033 FSH 2/9/2023 17,500.00 (G) 1.690 0.042 SPLSL MOIST 0-<1/2"" SUR 0.5 0.30 30,000.00 1.400.00 5.888.00 1.264 FSH 2/10/2023 24,500.00 (G) 1.690 0.058 SPLSL MOIST 0-<1/2"" SUR 0.5 0.30 30.000.00 1,400.00 5,888.00 1.770 FSH Feb-23 84,000.00 (G) 3/16/2023 24,500.00 (G) 1.690 0.058 SPLSL DRY 0-<1/2"" SUR 0.5 0.30 30,000.00 1,400.00 5,888.00 1.770 FSH 3/2012023 24,500.00 (G) 1.690 0.058 SPLSL DRY 0-<1/2"" SUR 0.5 0.30 30,000.00 1,400.00 5,888.00 1.770 FSH 3/2112023 24.500.00 (G) 1.690 0.058 SPLSL DRY 0-<1/2"" SUR 0.5 0.30 30,000.00 1,400.00 5,888.00 1.770 FSH 3/22/2023 14,000.00 (G) 1.690 0.033 SPLSL MOIST 0-<1/2"" SUR 0.5 0.30 30,000.00 1,400.00 5.888.00 1,011 FSH 3/2312023 24,500.00 (G) 1.690 0.058 SPLSL DRY 0-<1/2"" SUR 0.5 0.30 30.000.00 1.400.00 5.888.00 1.770 FSH 3124/2023 24,500.00 (G) 1.690 0.058 SPLSL DRY 0-<1/2"" SUR 0.5 0.30 30,000.00 1,400.00 5,888.00 1.770 FSH Mar-23 136,500.00 (G) 7/6/2023 56,000.00 (G) 1.690 0.133 SPLSL DRY 0-<1/2"" SUR 0.5 0.30 30,000.00 1.400.00 5.888.00 4.045 FSH 717/2023 24.500.00 (G) 1.690 0.058 SPLSL DRY 0-<112" SUR 0.5 0.30 30,000.00 1,400.00 5,888.00 1.770 FSH 711112023 10.500.00 (G) 1.690 0.025 SPLSL DRY 0-<1/2"" SUR 0.5 0.30 30,000.00 1,400.00 5,888.00 0.758 FSH Jul-23 91,000.00 (G) Total 22.501 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.007 0.002 0.653 0.033 0.022 0.002 0.014 0.028 0.012 0.727 32.632 Date LbslAc Cumulative Ibs/acre Applied 0.077 I 0.041 I 11.933 I 0.837 I 0.618 I 0.020 0.314 0.659 0.092 13.479 Permit PAN Limit(lbs/acre) 1st Crop I 178 Federal C.P.L.R. (Ibs/acre)-* 36.6 34.8 1,339.0 I 267.9 15.0 375.0 1 89.0 2,500.0 SPLSL = SPARTA, NC LIME STABILIZED LIQUID "I certify, under penalty of that this docu repared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signi Wattles or su itt g false information, including the possibility of fines and imprisonment for knowing violations." 1-TJ_ At SIG OF LAND APPLIER DATE NR = Not Reported or Not Required '** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation *"** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injectionlincorporation 1.0 *"** See Site pH & Lime Application Records Section of Report Printed: 1/2412024 DENR FORM FSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM` Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): Facility Name: SPARTA, NC Permit.7: W00006242 Cation Exchange Capacity (non 503 only): Operator: GREG WAGONER GREG WAGONER Predominant Soil Series: Owner: Acres Used: 29.60 Acres Permitted: 29.60 Site #: Field #: NC AG 00005 21.95 CHESTER NC AG 00005 0001 Source SPLSL Sample or Composite Date 1 1l10123 2 3 4 5 6 7 8 9 10 11 12 Solids 1.69 Arsenic 4.800 Cadmium 1 1.200 Copper 440 Chromium 22.00 Lead 15.00 Mercury 1.000 Molybdenum 9.60 Nickel 19.00 Selenium 7.80 Zinc 490 Total Phosphorus 22000 enmwt Heavv U-1 ointd t nadinnc lC.1-1 tnd in the/nr•rol• Source SPLSL Total DTIAc. App.Evenl 1 0.74 2 3 4 5 r, 7 8 9 10 11 12 Totals Arsenic 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.653 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.653 Chromium 0.033 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.033 Lead 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.022 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molybdenum 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Nickel 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.028 Selenium 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.012 Zinc 0.727 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.727 Total Phosphorus 32.632 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 32.632 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted.) am aware that there arc sib c n penalties for subminin false information, including the possibility of fines and imprisonment for knowing Niolations'". 1-3i-a Signature I p r Dale DENR FORM MFLSF (12/2006) FACILITY NAME: SPARTA, NC LAND OWNER: JUSTIN DALTON DALTON FARMS, I I rr OPERATOR: JUSTIN DALTON DALTON FARMS, CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): ` See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WO PERMIT #: W00006242 FIELD#: NC-AG-00008-0-0001- ANNUAL DRY TONS APPLIED: 10.11 SITE #: NC AG 00008 PREDOMINANT SOIL SERIES: HAYESVILLE CROP 1 MAX. PAN: 232 CROP 2 NAME: ACRES UTILIZED: 25.7 ACRES PERMITTED: 25.7 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibslacre) Application Month Solids Dry Tons/Ac Source Moist Inches Method' Rate" Rate""` mg/kg mg/kg mg/kg Amount UOM Crop 1 Crop 2 Crop 1 Crop 2 11/28/2023 10,500.00 (G) 1.690 0.029 SPLSL DRY 0-<1/2"" SUR 0.5 0.30 30,000.00 1,400.00 5.888.00 0.873 FSH 11/29/2023 35.000.00 (G) 1.690 0.096 SPLSL DRY 0-<1/2"" SUR 0.5 0.30 30,000.00 1.400.00 5,888.00 2.911 FSH 11/30/2023 38,500.00 (G) 1.690 0.106 SPLSL DRY 0-<1/2"" SUR 0.5 0.30 30,000.00 1,400.00 5.888.00 3.203 FSH Nov-23 84,000.00 (G) 12/1/2023 14,000.00 (G) 1.690 0.038 SPLSL DRY 0-<1/2"" SUR 0.5 0.30 30,000.00 1,400.00 5,888.00 1.165 FSH 12/4/2023 24,500.00 (G) 1.690 0.067 SPLSL DRY 0-<1/2"" SUR 0.5 0.30 30,000.00 1,400.00 5,888.00 2.038 FSH 12/512023 21,000.00 (G) 1.690 0.058 SPLSL MOIST 0-<1/2"" SUR 0.5 0.30 30,000.00 1,400.00 5,888.00 1.747 FSH Dec-23 59,500.00 (G) Total 0.394 Total 11.937 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibslacre Applied 0.004 <0.001 0.346 0.017 0.012 <0.001 0.008 0.015 0.006 0.386 17.314 Date Lbs/Ac Cumulative Ibslacre Applied 0.023 0.010 2.347 0.130 0.080 0.005 0.041 0.113 0.037 2.133 Permit PAN Limit (Ibs/acre) 1st Crop 232 Federal C.P.L.R. (Ibs/acre)"" 36.6 1 34.8 1 1,339.0 267.9 1 15.0 375.0 1 89.0 1 2,500.0 SPLSL = SPARTA, NC LIME STABILIZED LIQUID "1 certify, under penalty of law, th t ris docu�tred under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. 1 am aware that there are significant p a es forinformation, including the possibility of fines and imprisonment for knowing violations." IGNOWCOF LAND APPLIER DATE NR = Not Reported or Not Required "•* Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 *`**` See Site pH & Lime Application Records Section of Report Printed: 1/2412024 DENR FORM FSF (12/2006) Facility Name: Permit #: Operator: Acres Used ANNUAL METALS FIELD LOADING SUMMARY FORM' Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): SPARTA, NC W00006242 Cation Exchange Capacity (non 503 only): JUSTIN DALTON DALTON FARMS, LLC JUSTIN DALTON DALTON FARMS, Predominant Soil Series: LLC Owner: 25.70 Acres Permitted: 25.70 Site #: Field #: NC AG 00008 Qn�Linal anah.�l� na1� 141naw Mn1�1� anel Tn1a1 DA..enM..n,� „ .....IL.. o� C..1:.1� ,. HAYESVILLE NC AG 00008 0001 Source SPLSL Sample or Composite Date 1 1/10123 2 3 4 5 6 7 8 9 10 11 12 Solids 1.69 Arsenic 4.800 Cadmium 1.200 Copper 440 Chromium 22,00 Lead 15.00 Mercury 1.000 Molybdenum 9.60 Nickel 19.00 Selenium 7.80 Zinc 490 Total Phosphorus 22000 Annual Heavv Metal Field Loadings ICaleulatad In Ibslaeraf: Source SPLSL Total DTIAc. I App.Event 1 0.39 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Cadmium 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Copper 0.346 0.000 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.346 Chromium 0.017 0.000 0.000 0.000 0.000 O.ODO 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Lead 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.012 Mercury 0.001 0.0DO 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0,000 O.DO1 Molybdenum 0.008 O.ODO 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.008 Nickel 0.015 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.015 Selenium 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Zinc 0.386 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.386 Total Phosphorus 17.314 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 17.314 .'I cemty, and r penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are Bien c t penalties for itting false information, including the possibility of fines and imprisonment for knowing violations". 1- Signature pplie Dale OENR FORM MFLSF (12/2006) SECTION 4 SUMMIT ENVIRONMENTAL TECHNOLOGIES, INC Analytical Laboratories January 24, 2023 Alex Fox Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: FAX: RE: Sparta Dear Alex Fox: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http:llwww.settek.com Order No.: 23010838 Summit Environmental Technologies, Inc. received 1 sample(s) on 1/13/2023 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, i 7, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 2943, Colorado, Connecticut PH-0108, Florida NELAC E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, ISO/IEC 17025:2017 119125 L22-544, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Maryland 339, Michigan 9988, Minnesota 1780279, Nevada 011009232020-1, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP C1,0052, Oklahoma 2019-155, Oregon OH200001, Pennsylvania 011, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-19-16, Utah 01-1009232020-12, Virginia VELAP 10381, West Virginia 9957C Page 1 of 38 summly Summit Environmental Technologies, Inc. Case Narrative 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC. Cuyahoga Falls, Ohio 44223 wo#: 23010838 Analytical Laboratories TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com Date: 1/24/2023 CLIENT: Synagro Project: Sparta WorkOrder Narrative: 23010838: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence Sample Notes: 23010838-OOIA TCLP-VOC-MSTR_8260D: CCV and LCS-R156823 exhibited high recoveries for Vinyl chloride. Sample is ND for this analyte. 23010838-OOIA TCLP-SVOC_8270E: Possible low bias for Pyridine due to low recovery in the CCV. Compound demonstrates adequate instrument sensitivity in RLC. Analytical Sequence QC Notes: LCS VOC-MSTR_NPW(8260): LCS-R156823 exhibited high recovery for Vinyl chloride. Associated samples are ND for this analyte. Possible high bias for Vinyl chloride due to high recovery in CCV MB/LCS-62313 SVOC-BNA_TCLP(8270): Possible low bias for Pyridine due to low recovery in the CCV. RLC demonstrates control for this analyte. Original Page 2 of 38 SUMMIT Summit Environmental Technologies, In Qualifiers and Acronyms 3310 Win,' ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 442, WO#: 23010838 Analytical Laboratories TEL: (330) 253-8211 FAX.- (330) 253-44E Website: httv:11Www.settek.co Date: 1/24/2023 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. * The result exceeds the Regulatory Limit or Maximum Contamination Limit. m Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GC/MS. X The result was not confirmed when GUMS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit NIB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time RLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 3 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com CLIENT: Synagro Project: Sparta Lab SampleID Client Sample ID 23010838-001 Sparta Tag No Date Collected 1/10/2023 11:45:00 AM Workorder Sample Summary WO#: 23010838 Date Received 1/13/2023 10:20:00 AM 24-Jan-23 Matrix Solid Page 4 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. DATES REPORT ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 WO#: 23010838 Analytical Laboratories TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Sparta Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 23010838-OOIA Sparta 1/10/2023 11:45:00 AM Solid Ignitability of Solids (SW-846: 1030) 1/18/2023 7:17:11 PM pH (SW9045D) 1/20/2023 4:11:32 PM Reactive Cyanide (9014/7.3.3.2)-Solid 1/23/2023 1:45:00 PM Reactive Sulfide (9034)/7.3.4.2 1/23/2023 1:45:00 PM TCLP Herbicides by EPA 8321B 1/18/2023 7:23:00 PM TCLP Mercury Analysis (SW1311/7471/17/2023 4:15:00 PM 1/18/2023 2:30:00 PM 1/19/2023 10:58:00 AM TCLP Metals Analysis (SW1311/6010'1/17/2023 4:15:00 PM 1/18/2023 2:00:00 PM 1/19/2023 2:01:00 PM TCLP Pesticides Analysis (SW1311/8(1/17/2023 4:15:00 PM 1/18/2023 10:31:44 AM 1/19/2023 3:42:00 AM TCLP Pesticides Analysis (SW1311/8(1/17/2023 4:15:00 PM 1/18/2023 10:31:44 AM 1/19/2023 3:42:00 AM TCLP Semi-Volatiles Analysis 1/17/2023 4:15:00 PM 1/19/2023 10:40:00 AM 1/20/2023 9:34:00 PM (SW1311/8270) TCLP Volatiles Analysis 1/19/2023 4:00:00 PM 1/20/2023 4:23:00 PM Original Page 5 of 38 SUMMIT Summit Environmental Technologies, Inc. Analytical Report 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 (base report) Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 WO#: 23010838 Website: htW.-Ilwww.settek.com Date Reported: 1/24/2023 CLIENT: Synagro Tag Number: Matrix: SOLID Collection Date: 1/10/2023 11:45:00 AM Lab ID: 23010838-001A Project: Sparta Client Sample ID Sparta Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW7470A SW7470A Analyst: ICA TCLP MERCURY ANALYSIS (SW1311/7470) TCLP Mercury ND 0.0100 mg/L 1 1/19/2023 10:58:00 AM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW6010 SW3010A Analyst: RJE TCLP METALS ANALYSIS (SW1311/6010) TCLP Arsenic(As) ND 0.500 mg/L 1 1/19/2023 2:01:00 PM TCLP Barium(Ba) ND 5.00 mg/L 1 1/19/2023 2:01:00 PM TCLP Cadmium(Cd) ND 0.100 mg/L 1 1/19/2023 2:01:00 PM TCLP Chromium(Cr) ND 0.200 mg/L 1 1/19/2023 2:01:00 PM TCLP Lead(Pb) ND 0.500 mg/L 1 1/19/2023 2:01:00 PM TCLP Selenium(Se) ND 0.0500 mg/L 1 1/19/2023 2:01:00 PM TCLP Silver(Ag) ND 0.500 mg/L 1 1/19/2023 2:01:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270 SW3510C Analyst: JAP TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 0.100 mg/L 1 1/20/2023 9:34:00 PM 2,4,5-Trichlorophenol ND 0.250 mg/L 1 1/20/2023 9:34:00 PM 2,4,6-Trichlorophenol ND 0.250 mg/L 1 1/20/2023 9:34:00 PM 2,4-Dinitrotoluene ND 0.0500 mg/L 1 1/20/2023 9:34:00 PM Cresols, Total ND 5.00 mg/L 1 1/20/2023 9:34:00 PM Hexachloro-1,3-butadiene ND 0.0200 mg/L 1 1/20/2023 9:34:00 PM Hexachlorobenzene ND 0.0500 mg/L 1 1/20/2023 9:34:00 PM Hexachloroethane ND 0.100 mg/L 1 1/20/2023 9:34:00 PM Nitrobenzene ND 0.100 mg/L 1 1/20/2023 9:34:00 PM Pentachlorophenol ND 0.250 mg/L 1 1/20/2023 9:34:00 PM Pyridine ND 0.250 QC- mg/L 1 1/20/2023 9:34:00 PM Surr: 2-Fluorophenol 66.4 10 - 157 %Rec 1 1/20/2023 9:34:00 PM Surr: Phenol-d6 75.4 10 - 169 %Rec 1 1/20/2023 9:34:00 PM Surr: Nitrobenzene-d5 69.1 32.1 - 130 %Rec 1 1/20/2023 9:34:00 PM Surr: 2,4,6-Tribromophenol 100 45.4 - 166 %Rec 1 1/20/2023 9:34:00 PM Surr: 2-Fluorobiphenyl 74.8 35.7 - 130 %Rec 1 1/20/2023 9:34:00 PM Surr: p-Terphenyl-d14 87.9 70 - 145 %Rec 1 1/20/2023 9:34:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected P Second column confirmation exceeds R RPD outside accepted recovery limits E M N OGl PL RL Value above quantitation range Manual Integration used to determine area response Tentatively identified compounds Permit Limit Reporting Detection Limit Original Page 6 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: htW.-Ilwww.settek.com CLIENT: Synagro Matrix: SOLID Lab ID: 23010838-001A Project: Sparta Client Sample ID Sparta Analytical Report (base report) WO#: 23010838 Date Reported: 1/24/2023 Tag Number: Collection Date: 1/10/2023 11:45:00 AM Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8081 SW3510C Analyst: PGP TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND 0.00250 mg/L 1 1/19/2023 3:42:00 AM Toxaphene ND 0.00500 mg/L 1 1/19/2023 3:42:00 AM Endrin ND 0.000500 mg/L 1 1/19/2023 3:42:00 AM gamma-BHC ND 0.000500 mg/L 1 1/19/2023 3:42:00 AM Heptachlor ND 0.000500 mg/L 1 1/19/2023 3:42:00 AM Heptachlor epoxide ND 0.000500 mg/L 1 1/19/2023 3:42:00 AM Methoxychlor ND 0.000500 mg/L 1 1/19/2023 3:42:00 AM Surr: TCMX 59.4 10 - 119 %Rec 1 1/19/2023 3:42:00 AM Surr: DCB 53.2 10 - 119 %Rec 1 1/19/2023 3:42:00 AM TCLP HERBICIDES BY EPA 8321 B SW8321 Analyst: SRA 2,4-D ND 0.500 mg/L 50 1/18/2023 7:23:00 PM 2,4,5-TP ND 0.500 mg/L 50 1/18/2023 7:23:00 PM Surr: 2,4-Dichlorophenylacetic aci 89.9 70 - 130 %Rec 50 1/18/2023 7:23:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260 Analyst: EMB TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 0.100 mg/L 20 1/20/2023 4:23:00 PM 1,2-Dichloroethane ND 0.100 mg/L 20 1/20/2023 4:23:00 PM MEK ND 2.00 mg/L 20 1/20/2023 4:23:00 PM Benzene ND 0.100 mg/L 20 1/20/2023 4:23:00 PM Carbon tetrachloride ND 0.100 mg/L 20 1/20/2023 4:23:00 PM Chlorobenzene ND 1.00 mg/L 20 1/20/2023 4:23:00 PM Chloroform ND 0.100 mg/L 20 1/20/2023 4:23:00 PM Tetrachloroethene ND 0.100 mg/L 20 1/20/2023 4:23:00 PM Trichloroethene ND 0.100 mg/L 20 1/20/2023 4:23:00 PM Vinyl chloride ND 0.0400 QC+QL+ mg/L 20 1/20/2023 4:23:00 PM Surr: 4-Bromofluorobenzene 93.6 70 - 130 %Rec 20 1/20/2023 4:23:00 PM Surr: Dibromofluoromethane 98.6 70 - 130 %Rec 20 1/20/2023 4:23:00 PM Surr: Toluene-d8 105 70 - 130 %Rec 20 1/20/2023 4:23:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected P Second column confirmation exceeds R RPD outside accepted recovery limits E M N OGl PL RL Value above quantitation range Manual Integration used to determine area response Tentatively identified compounds Permit Limit Reporting Detection Limit Original Page 7 of 38 SUMMIT Summit Environmental Technologies, Inc. Analytical Report 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 (base report) Analytical Laboratories TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 23010838 Website: http://www.settek.com Date Reported: 1/24/2023 CLIENT: Synagro Tag Number: Matrix: SOLID Collection Date: 1/10/2023 11:45:00 AM Lab ID: 23010838-OOIA Project: Sparta Client Sample ID Sparta Analyses Result RL Qual Units DF Date Analyzed RCI SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND 0.490 mg/Kg 1 1/23/2023 1:45:00 PM IGNITABILITY OF SOLIDS (SW-846: 1030) SW1030 Analyst: SMZ Ignitability Non-flammable mm/sec 1 1/18/2023 7:17:11 PM RCI SW9045D Analyst: SMZ PH (SW9045D) pH 12.5 s.u.@20.4C 1 1/20/2023 4:11:32 PM RCI SW9034 Analyst: MS REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive ND 25.0 mg/Kg 1 1/23/2023 1:45:00 PM Qualifiers: B Analyte detected in the associated Method Blank H Holding times for preparation or analysis exceeded MC Value is below Minimum Compound Limit. ND Not Detected P Second column confirmation exceeds R RPD outside accepted recovery limits E Value above quantitation range M Manual Integration used to determine area response N Tentatively identified compounds OGl PL Permit Limit Original RL Reporting Detection Limit Page 8 of 38 Summit Environmental Technologies, Inc. Accreditation Program 3310 Win St. SUMMIEF Anal te5 Report Y p ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 23010838 Website: hgp:llwww.settek.com 24-Jan-23 Client: Synagro State: NW Project: Sparta Program Name: NC WW SCM Sample ID Matrix Test Name Analyte Status 23010838-OOIA Solid Ignitability of Solids (SW-846: 1030) Ignitability A Solid pH (SW9045D) Hydrogen Ion (pH) A Solid Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive U Solid Reactive Sulfide (9034)/7.3.4.2 Sulfide, Reactive U Solid TCLP Herbicides by EPA 8321B 2,4,5-TP A Solid TCLP Herbicides by EPA 8321B 2,4-D A Solid TCLP Mercury Analysis (SW1311/7470) Mercury A Solid TCLP Metals Analysis (SW1311/6010) Arsenic A Solid TCLP Metals Analysis (SW1311/6010) Barium A Solid TCLP Metals Analysis (SW1311/6010) Cadmium A Solid TCLP Metals Analysis (SW1311/6010) Chromium A Solid TCLP Metals Analysis (SW1311/6010) Lead A Solid TCLP Metals Analysis (SW1311/6010) Selenium A Solid TCLP Metals Analysis (SW1311/6010) Silver A Solid TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Solid TCLP Pesticides Analysis (SW1311/8081) Endrin A Solid TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Solid TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Solid TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Solid TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Solid TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Original #1 Page 9 of 38 Summit Environmental Technologies, Inc. Accreditation Program 3310 Win St. SUMMIEF Anal te5 Report Y p ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 23010838 Website: hgp:llwww.settek.com 24-Jan-23 Client: Synagro State: NW Project: Sparta Program Name: NC WW SCM Sample ID Matrix Test Name Analyte Status 23010838-OOIA Solid TCLP Volatiles Analysis 1,1-Dichloroethene A Solid TCLP Volatiles Analysis 1,2-Dichloroethane A Solid TCLP Volatiles Analysis 2-Butanone A Solid TCLP Volatiles Analysis Benzene A Solid TCLP Volatiles Analysis Carbon tetrachloride A Solid TCLP Volatiles Analysis Chlorobenzene A Solid TCLP Volatiles Analysis Chloroform A Solid TCLP Volatiles Analysis Tetrachloroethene A Solid TCLP Volatiles Analysis Trichloroethene A Solid TCLP Volatiles Analysis Vinyl chloride A Original #1 Page 10 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: 62279 Sample ID: MB-62279 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 1/18/2023 RunNo: 156731 Client ID: PBS Batch ID: 62279 TestNo: SW8081 SW3510C Analysis Date: 1/18/2023 SegNo: 4172749 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, total ND 0.00250 Toxaphene ND 0.00500 Endrin ND 0.000500 gamma-BHC ND 0.000500 Heptachlor ND 0.000500 Heptachlor epoxide ND 0.000500 Methoxychlor ND 0.000500 Sum TCMX 11.7 Sum DCB 11.6 20.00 58.4 10 119 20.00 57.8 10 119 d d d d d Sample ID: LCS-62279 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 1/18/2023 RunNo: 156731 Client ID: LCSS Batch ID: 62279 TestNo: SW8081 SW3510C Analysis Date: 1/18/2023 SegNo: 4172750 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, tota Toxaphene Endrin gamma-BHC Heptachlor Heptachlor epo Methoxychlor Surr: TCMX Qualifiers: 1 0.0183 0.0 ND 0.0 0.0108 0.00 0.00848 0.00 0.0103 0.00 xide 0.00917 0.00 0.0114 0.00 12.0 B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit 0250 0 0 70 0500 0 0 70 0500 0.0100 0 108 10 0500 0.0100 0 84.8 10 0500 0.0100 0 103 10 0500 0.0100 0 91.7 10 0500 0.0100 0 114 10 20.00 60.1 10 E Value above quantitation range M Manual Integration used to determine area response OGl R RPD outside accepted recovery limits 130 130 130 130 130 130 178 130 H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds RL Reporting Detection Limit Original Page 11 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: hgp:llwww.settek.com Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchID: 62279 Sample ID: LCS-62279 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 1/18/2023 RunNo: 156731 Nent ID: LCSS Batch ID: 62279 TestNo: SW8081 SW3510C Analysis Date: 1/18/2023 SegNo: 4172750 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Surr: DCB 8.64 20.00 43.2 10 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 12 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: 62288 Sample ID: MB-62288 SampType: MBLK TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 1/18/2023 RunNo: 156724 Client ID: PBS Batch ID: 62288 TestNo: SW6010 SW3010A Analysis Date: 1/19/2023 SegNo: 4173032 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.100 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.100 TCLP Selenium(Se) ND 0.100 TCLP Silver(Ag) ND 0.100 Sample ID: LCS-62288 SampType: LCS TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 1/18/2023 RunNo: 156724 Client ID: LCSS Batch ID: 62288 TestNo: SW6010 SW3010A Analysis Date: 1/19/2023 SegNo: 4173033 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.14 0.100 2.000 0 107 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 103 80 120 TCLP Cadmium(Cd) 2.01 0.100 2.000 0 100 80 120 TCLP Chromium(Cr) 2.03 0.200 2.000 0 101 80 120 TCLP Lead(Pb) 2.04 0.100 2.000 0 102 80 120 TCLP Selenium(Se) 1.97 0.100 2.000 0 98.6 80 120 TCLP Silver(Ag) 2.11 0.100 2.000 0 106 80 120 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 13 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: 62288 Sample ID: 23010844-001AMS SampType: MS TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 1/18/2023 RunNo: 156724 Client ID: Batch= Batch ID: 62288 TestNo: SW6010 SW3010A Analysis Date: 1/19/2023 SegNo: 4174124 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.06 0.500 2.000 0 103 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.1455 100 70 130 TCLP Cadmium(Cd) 1.78 0.100 2.000 0 89.2 70 130 TCLP Chromium(Cr) 1.81 0.200 2.000 0.002100 90.3 70 130 TCLP Lead(Pb) 1.81 0.500 2.000 0 90.4 70 130 TCLP Selenium(Se) 1.98 0.0500 2.000 0 99.1 70 130 TCLP Silver(Ag) 2.06 0.500 2.000 0 103 70 130 Sample ID: 23010844-001AMSD SampType: MSD TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 1/18/2023 RunNo: 156724 Client ID: Batch= Batch ID: 62288 TestNo: SW6010 SW3010A Analysis Date: 1/19/2023 SegNo: 4174125 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.96 0.500 2.000 0 98.2 70 130 2.058 4.72 20 TCLP Barium(Ba) ND 5.00 2.000 0.1455 95.0 70 130 0 0 20 TCLP Cadmium(Cd) 1.71 0.100 2.000 0 85.5 70 130 1.784 4.22 20 TCLP Chromium(Cr) 1.72 0.200 2.000 0.002100 85.8 70 130 1.807 5.08 20 TCLP Lead(Pb) 1.73 0.500 2.000 0 86.6 70 130 1.809 4.34 20 TCLP Selenium(Se) 1.90 0.0500 2.000 0 94.9 70 130 1.982 4.35 20 TCLP Silver(Ag) 1.96 0.500 2.000 0 98.2 70 130 2.056 4.63 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 14 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni QC SUMMARY REPORT WO#: 23010838 24-Jan-23 Client: Synagro Project: Sparta BatchlD: 62305 TCLP Mercury ND 0.00200 TCLP Mercury 0.00407 0.00200 0.00400 0 102 80 120 TCLP Mercury 0.00413 0.00200 0.00400 0.0000230 103 75 125 Sample ID: 23010844-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/18/2023 RunNo: 156722 Client ID: BatchQC Batch ID: 62305 TestNo: SW7470A SW7470A Analysis Date: 1/19/2023 SegNo: 4172607 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00419 0.00200 0.00400 0.0000230 104 75 125 0.00413 1.44 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OGl P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 15 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: hgp:llwww.settek.com Client: Synagro Project: Sparta QC SUMMARY REPORT BatchID: 62305 WO#: 23010838 24-Jan-23 Sample ID: 23010844-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/18/2023 RunNo: 156722 client ID: Batch= Batch ID: 62305 TestNo: SW7470A SW7470A Analysis Date: 1/19/2023 SegNo: 4172607 4nalyte Result PQL SPK value SPK Ref Val %REC LowLimit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 16 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT BatchlD: 62313 WO#: 23010838 24-Jan-23 Sample ID: MB-62313 SampType: MBLK TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/19/2023 RunNo: 156871 3lient ID: PBS Batch ID: 62313 TestNo: SW8270 SW3510C Analysis Date: 1/20/2023 SegNo: 4175949 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.0250 2,4,5-Trichlorophenol ND 0.0250 2,4,6-Trichlorophenol ND 0.0250 2,4-Dinitrotoluene ND 0.0250 o-Cresol ND 0.250 Cresols, Total ND 0.0500 Hexachloro-1,3-butadiene ND 0.0250 Hexachlorobenzene ND 0.0250 Hexachloroethane ND 0.0250 Nitrobenzene ND 0.0250 Pentachlorophenol ND 0.0250 Pyridine ND 0.0250 Surr: 2-Fluorophenol 0.735 Surr: Phenol-d6 0.858 Surr: Nitrobenzene-d5 0.727 Surr: 2,4,6-Tribromophenol 1.03 Surr: 2-Fluorobiphenyl 0.800 Surr: p-Terphenyl-d14 1.02 1.000 73.5 10 135 1.000 85.8 10 161 1.000 72.7 16.8 150 1.000 103 32.5 179 1.000 80.0 34 133 1.000 102 60.8 163 QC - Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 17 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT BatchlD: 62313 WO#: 23010838 24-Jan-23 Sample ID: LCS-62313 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/19/2023 RunNo: 156871 3lient ID: LCSS Batch ID: 62313 TestNo: SW8270 SW3510C Analysis Date: 1/20/2023 SegNo: 4175950 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.463 0.0250 0.8000 0 57.8 35 130 2,4,5-Trichlorophenol 0.858 0.0250 0.8000 0 107 44 144 2,4,6-Trichlorophenol 0.873 0.0250 0.8000 0 109 45 141 2,4-Dinitrotoluene 0.845 0.0250 0.8000 0 106 56 136 o-Cresol 0.729 0.250 0.8000 0 91.1 36 134 Cresols, Total 1.48 0.0500 1.600 0 92.5 36 135 Hexachloro-1,3-butadiene 0.547 0.0250 0.8000 0 68.4 30 130 Hexachlorobenzene 0.825 0.0250 0.8000 0 103 58 130 Hexachloroethane 0.448 0.0250 0.8000 0 56.0 28 130 Nitrobenzene 0.698 0.0250 0.8000 0 87.3 39 133 Pentachlorophenol 0.849 0.0250 0.8000 0 106 33 151 Pyridine 0.191 0.0250 0.8000 0 23.9 10 130 Surr: 2-Fluorophenol 0.742 1.000 74.2 10 135 Surr: Phenol-d6 0.844 1.000 84.4 10 161 Surr: Nitrobenzene-d5 0.739 1.000 73.9 16.8 150 Surr:2,4,6-Tribromophenol 1.20 1.000 120 32.5 179 Surr:2-Fluorobiphenyl 0.834 1.000 83.4 34 133 Surr: p-Terphenyl-d14 0.963 1.000 96.3 60.8 163 QC - Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 18 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT BatchlD: 62313 WO#: 23010838 24-Jan-23 Sample ID: 23010844-001AMS SampType: MS TestCode: TCLP-SVOC_ Units: mg/L Prep Date: 1/19/2023 RunNo: 156871 3lient ID: Batch= Batch ID: 62313 TestNo: SW8270 SW3510C Analysis Date: 1/20/2023 SegNo: 4175972 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.475 0.100 0.8000 0 59.4 15.2 124 2,4,5-Trichlorophenol 0.802 0.250 0.8000 0 100 30.6 152 2,4,6-Trichlorophenol 0.815 0.250 0.8000 0 102 27.6 150 2,4-Dinitrotoluene 0.760 0.0500 0.8000 0 95.0 58 141 o-Cresol 0.654 0.250 0.8000 0 81.8 26.9 132 Cresols, Total ND 5.00 1.600 0 83.4 27.6 132 Hexachloro-1,3-butadiene 0.533 0.0200 0.8000 0 66.6 10 156 Hexachlorobenzene 0.742 0.0500 0.8000 0 92.8 54.3 142 Hexachloroethane 0.465 0.100 0.8000 0 58.1 1.92 131 Nitrobenzene 0.653 0.100 0.8000 0 81.6 21 135 Pentachlorophenol 0.762 0.250 0.8000 0 95.2 47.4 134 Pyridine 0.422 0.250 0.8000 0 52.7 10 130 Surr:2-Fluorophenol 0.726 1.000 72.6 9.77 146 Surr: Phenol-d6 0.758 1.000 75.8 20.7 130 Surr: Nitrobenzene-d5 0.646 1.000 64.6 13.9 156 Surr:2,4,6-Tribromophenol 1.08 1.000 108 27.3 183 Surr:2-Fluorobiphenyl 0.709 1.000 70.9 21.4 153 Surr: p-Terphenyl-d14 0.883 1.000 88.3 54.8 154 QC - Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 19 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT BatchlD: 62313 WO#: 23010838 24-Jan-23 Sample ID: 23010844-001AMSD SampType: MSD TestCode: TCLP-SVOC_ Units: mg/L Prep Date: 1/19/2023 RunNo: 156871 client ID: Batch= Batch ID: 62313 TestNo: SW8270 SW3510C Analysis Date: 1/20/2023 SegNo: 4175973 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.470 0.100 0.8000 0 58.8 15.2 124 0.4750 1.06 30 2,4,5-Trichlorophenol 0.857 0.250 0.8000 0 107 30.6 152 0.8018 6.70 30 2,4,6-Trichlorophenol 0.872 0.250 0.8000 0 109 27.6 150 0.8152 6.71 30 2,4-Dinitrotoluene 0.827 0.0500 0.8000 0 103 58 141 0.7602 8.39 30 o-Cresol 0.686 0.250 0.8000 0 85.8 26.9 132 0.6544 4.74 30 Cresols, Total ND 5.00 1.600 0 88.5 27.6 132 0 0 30 Hexachloro-1,3-butadiene 0.540 0.0200 0.8000 0 67.5 10 156 0.5330 1.27 30 Hexachlorobenzene 0.832 0.0500 0.8000 0 104 54.3 142 0.7424 11.4 30 Hexachloroethane 0.460 0.100 0.8000 0 57.5 1.92 131 0.4650 1.08 30 Nitrobenzene 0.668 0.100 0.8000 0 83.5 21 135 0.6528 2.27 30 Pentachlorophenol 0.846 0.250 0.8000 0 106 47.4 134 0.7618 10.5 30 Pyridine 0.416 0.250 0.8000 0 52.0 10 130 0.4218 1.43 30 Surr:2-Fluorophenol 0.705 1.000 70.5 9.77 146 0 Surr: Phenol-d6 0.806 1.000 80.6 20.7 130 0 Surr: Nitrobenzene-d5 0.693 1.000 69.3 13.9 156 0 Surr:2,4,6-Tribromophenol 1.16 1.000 116 27.3 183 0 Surr:2-Fluorobiphenyl 0.794 1.000 79.4 21.4 153 0 Surr: p-Terphenyl-d14 0.950 1.000 95.0 54.8 154 0 QC - Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 20 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: hgp:llwww.settek.com Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchID: R156695 Sample ID: LCS-R156695 SampType: LCS TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 156695 Client ID: LCSS Batch ID: R156695 TestNo: SW1030 Analysis Date: 1/18/2023 SegNo: 4171894 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit Highl-imit RPD Ref Val %RPD RPDLimit Qual Ignitability 7.69 7.240 0 106 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 21 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: R156776 Sample ID: MB TCLP SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: RunNo: 156776 Client ID: PBS Batch ID: R156776 TestNo: SW8321 Analysis Date: 1/18/2023 SegNo: 4173529 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 2,4-D ND 0.0100 2,4,5-TP ND 0.0100 Sum 2,4-Dichlorophenylacetic acid 0.732 1.000 73.2 70 130 Sample ID: RLC TCLP SampType: RLC TestCode: TCLP-SVOC- Units: mg/L Prep Date: RunNo: 156776 Client ID: Batch= Batch ID: R156776 TestNo: SW8321 Analysis Date: 1/18/2023 SegNo: 4173530 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 2,4-D 0.0120 0.0100 0.01000 0 120 50 150 2,4,5-TP ND 0.0100 0.01000 0 0 50 150 S Surr: 2,4-Dichlorophenylacetic acid 0.00870 0.01000 87.0 70 130 Sample ID: LCS TCLP 0.3 ppm SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: RunNo: 156776 Client ID: LCSS Batch ID: R156776 TestNo: SW8321 Analysis Date: 1/18/2023 SegNo: 4173531 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 2,4-D 0.274 0.0100 0.3000 0 91.3 60.5 141 2,4,5-TP 0.267 0.0100 0.3000 0 88.9 68.3 144 Surr: 2,4-Dichlorophenylacetic acid 0.267 0.3000 89.1 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OGl P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 22 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: hgp:llwww.settek.com Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 Batchll): R156776 Sample ID: LCSD TCLP 0.3 ppm SampType: LCSD TestCode: TCLP-SVOC- Units: mg/L Prep Date: RunNo: 156776 Client ID: LCSS02 Batch ID: R156776 TestNo: SW8321 Analysis Date: 1/18/2023 SegNo: 4173533 Analyte Result PQL SPK value SPK Ref Val %REC LowLimit Highl-imit RPD Ref Val %RPD RPDLimit Qual 2,4-D 0.292 0.0100 0.3000 0 97.5 60.5 141 0.2740 6.53 30 2,4,5-TP 0.292 0.0100 0.3000 0 97.5 68.3 144 0.2666 9.23 30 Surr: 2,4-Dichlorophenylacetic acid 0.293 0.3000 97.7 70 130 0 0 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response OGl R RPD outside accepted recovery limits Page 23 of 38 H Holding times for preparation or anal, MC Value is below Minimum Compound P Second column confirmation exceeds RL Reporting Detection Limit Original SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: R156823 Sample ID: 23011094-001AMS SampType: MS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156823 Client ID: Batch= Batch ID: R156823 TestNo: SW8260 Analysis Date: 1/20/2023 SegNo: 4174711 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.583 0.100 0.400 0 146 13.6 202 1,2-Dichloroethane 0.465 0.100 0.400 0 116 55.7 138 MEK ND 2.00 2.00 0 94.3 70 130 Benzene 0.519 0.100 0.400 0 130 49.2 145 Carbon tetrachloride 0.486 0.100 0.400 0 122 26.7 156 Chlorobenzene ND 1.00 0.400 0 115 33.7 159 Chloroform 0.472 0.100 0.400 0 118 48.5 145 Tetrachloroethene 0.422 0.100 0.400 0 106 19.2 191 Trichloroethene 0.447 0.100 0.400 0 112 38.4 167 Vinyl chloride 0.700 0.0400 0.400 0 175 27.3 161 Sum 4-Bromofluorobenzene 971 1000 97.1 70 130 Sum Dibromofluoromethane 983 1000 98.3 70 130 Surr: Toluene-d8 1080 1000 108 70 130 SQC+ Sample ID: 23011094-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156823 Client ID: BatchQC Batch ID: R156823 TestNo: SW8260 Analysis Date: 1/20/2023 SegNo: 4174712 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.536 0.100 0.400 0 134 13.6 202 0.583 8.41 25 1,2-Dichloroethane 0.450 0.100 0.400 0 112 55.7 138 0.465 3.32 25 MEK ND 2.00 2.00 0 93.0 70 130 0 0 25 Benzene 0.480 0.100 0.400 0 120 49.2 145 0.519 7.97 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OGl P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 24 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: R156823 Sample ID: 23011094-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156823 Client ID: Batch= Batch ID: R156823 TestNo: SW8260 Analysis Date: 1/20/2023 SegNo: 4174712 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride 0.449 0.100 0.400 0 112 26.7 156 0.486 7.91 25 Chlorobenzene ND 1.00 0.400 0 105 33.7 159 0 0 25 Chloroform 0.413 0.100 0.400 0 103 48.5 145 0.472 13.2 25 Tetrachloroethene 0.388 0.100 0.400 0 97.1 19.2 191 0.422 8.39 25 Trichloroethene 0.417 0.100 0.400 0 104 38.4 167 0.447 7.08 25 Vinyl chloride 0.620 0.0400 0.400 0 155 27.3 161 0.700 12.1 25 QC+ Sum 4-Bromofluorobenzene 969 1000 96.9 91.7 109 0 25 Sum Dibromofluoromethane 942 1000 94.2 75.5 118 0 25 Sum Toluene-d8 1020 1000 102 94.1 105 0 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 25 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: R156823 Sample ID: MBLK SampType: MBLK TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 156823 Client ID: PBW Batch ID: R156823 TestNo: SW8260 Analysis Date: 1/20/2023 SegNo: 4174708 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene ND 0.00500 1,2-Dichloroethane ND 0.00500 MEK ND 0.0250 Benzene ND 0.00500 Carbon tetrachloride ND 0.00500 Chlorobenzene ND 0.00500 Chloroform ND 0.00500 Tetrachloroethene ND 0.00500 Trichloroethene ND 0.00500 Vinyl chloride ND 0.00200 Sum 4-Bromofluorobenzene 46.5 Sum Dibromofluoromethane 49.4 Surr: Toluene-d8 53.0 50.00 92.9 70 130 50.00 98.7 70 130 50.00 106 70 130 QC+ Sample ID: LCS SampType: LCS TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 156823 Client ID: LCSW Batch ID: R156823 TestNo: SW8260 Analysis Date: 1/20/2023 SegNo: 4174715 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.0242 0.00500 0.0200 0 121 49 161 1,2-Dichloroethane 0.0254 0.00500 0.0200 0 127 48 151 MEK 0.0972 0.0250 0.100 0 97.2 10 190 Benzene 0.0267 0.00500 0.0200 0 133 34 169 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OGl P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 26 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: R156823 Sample ID: LCS SampType: LCS TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 156823 Client ID: LCSW Batch ID: R156823 TestNo: SW8260 Analysis Date: 1/20/2023 SegNo: 4174715 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride 0.0254 0.00500 0.0200 0 127 76 134 Chlorobenzene 0.0240 0.00500 0.0200 0 120 54 144 Chloroform 0.0246 0.00500 0.0200 0 123 70 130 Tetrachloroethene 0.0232 0.00500 0.0200 0 116 66 134 Trichloroethene 0.0245 0.00500 0.0200 0 122 70 136 Vinyl chloride 0.0405 0.00200 0.0200 0 202 49 136 SQC+ Sum 4-Bromofluorobenzene 47.6 50.00 95.1 70 130 Sum Dibromofluoromethane 49.1 50.00 98.2 70 130 Sum Toluene-d8 51.9 50.00 104 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 27 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: R156823 Sample ID: MBLK SampType: MBLK TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156823 Client ID: PBS Batch ID: R156823 TestNo: SW8260 Analysis Date: 1/20/2023 SegNo: 4174709 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene ND 0.100 1,2-Dichloroethane ND 0.100 MEK ND 2.00 Benzene ND 0.100 Carbon tetrachloride ND 0.100 Chlorobenzene ND 1.00 Chloroform ND 0.100 Tetrachloroethene ND 0.100 Trichloroethene ND 0.100 Vinyl chloride ND 0.0400 Sum 4-Bromofluorobenzene 968 Sum Dibromofluoromethane 985 Surr: Toluene-d8 1150 1000 96.8 70 130 1000 98.5 70 130 1000 115 70 130 QC+ Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 28 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni QC SUMMARY REPORT WO#: 23010838 24-Jan-23 Client: Synagro Project: Sparta BatchlD: R156838 pH 7.0 7.0 0 100 98.6 101.4 pH 6.9 6.9 0.4 5 H pH 7.0 7.0 0 100 98.6 101.4 Sample ID: 23010912-001ADUP SampType: DUP TestCode: pH_NPW(450 Units: s.u.@19.7C Prep Date: RunNo: 156838 Client ID: BatchQC Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175285 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 6.3 6.3 0.5 5 H Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 29 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: hgp:llwww.settek.com Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchID: R156838 Sample ID: 23010912-001ADUP SampType: DUP TestCode: pH_NPW(450 Units: s.u.@19.7C Prep Date: RunNo: 156838 client ID: Batch= Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175285 4nalyte Result PQL SPK value SPK Ref Val %REC LowLimit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 30 of 38 SUMMIT Summit Environmental Technologies, Inc 3310 Win St ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: R156838 pH 7.0 7.0 0 100 90 110 pH 12.5 0 0 0 0 12.5 0.2 10 pH 7.0 7.0 0 100 90 110 Sample ID: 23011173-001ADUP SampType: DUP TestCode: pH_S(9045D) Units: s.u.@20.5C Prep Date: RunNo: 156838 Client ID: BatchQC Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175312 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 6.5 0 0 0 0 6.4 0.6 10 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OGl P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 31 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: R156838 Sample ID: 23011173-001ADUP SampType: DUP TestCode: pH_S(9045D) Units: s.u.@20.5C Prep Date: RunNo: 156838 Client ID: Batch= Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175312 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID: LCS-R156838 SampType: LCS TestCode: pH_S(9045D) Units: s.u.@20.4C Prep Date: RunNo: 156838 Client ID: LCSS Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175319 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 100 90 110 Sample ID: 23011209-007ADUP SampType: DUP TestCode: pH_S(9045D) Units: s.u.@21.1C Prep Date: RunNo: 156838 Client ID: BatchQC Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175324 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.6 0 0 0 0 7.6 0 10 Sample ID: LCS-R156838 SampType: LCS TestCode: pH_S(9045D) Units: s.u.@20.5C Prep Date: RunNo: 156838 Client ID: LCSS Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175326 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 101 90 110 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OGl P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 32 of 38 SUMMIT Summit Environmental Technologies, Inc 3310 Win St ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta Cyanide, Reactive ND 0.495 QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: R156913 Cyanide, Reactive 9.17 0.500 10.00 0 91.7 85 115 Cyanide, Reactive ND 0.481 0.5000 0 62.0 50 150 Sample ID: 23010840-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 156913 Client ID: BatchQC Batch ID: R156913 TestNo: SW9014 Analysis Date: 1/23/2023 SegNo: 4176952 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 7.77 0.495 10.00 0 77.7 75 125 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal, J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OGl P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 33 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: R156913 Sample ID: 23010840-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 156913 Client ID: Batch= Batch ID: R156913 TestNo: SW9014 Analysis Date: 1/23/2023 SegNo: 4176952 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID: 23010840-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 156913 Client ID: Batch= Batch ID: R156913 TestNo: SW9014 Analysis Date: 1/23/2023 SegNo: 4176953 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 8.43 0.495 10.00 0 84.3 75 125 7.772 8.19 10 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range H Holding times for preparation or anal, M Manual Integration used to determine area response MC Value is below Minimum Compound OGl P Second column confirmation exceeds R RPD outside accepted recovery limits RL Reporting Detection Limit Original Page 34 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: R156917 Sample ID: 23010840-001AMS SampType: MS TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 156917 Client ID: Batch= Batch ID: R156917 TestNo: SW9034 Analysis Date: 1/23/2023 SegNo: 4177055 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 1590 25.0 1710 0 93.0 80 120 Sample ID: 23010840-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 156917 Client ID: Batch= Batch ID: R156917 TestNo: SW9034 Analysis Date: 1/23/2023 SegNo: 4177056 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 1660 25.0 1710 0 97.1 80 120 1590 4.31 30 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range H Holding times for preparation or anal, M Manual Integration used to determine area response MC Value is below Minimum Compound OGl P Second column confirmation exceeds R RPD outside accepted recovery limits RL Reporting Detection Limit Original Page 35 of 38 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio 44223 Analytical Laboratories TEL: (330) 253-8211 FAX: (330) 253-4489 Website: http://www.settek.coni Client: Synagro Project: Sparta QC SUMMARY REPORT WO#: 23010838 24-Jan-23 BatchlD: R156917 Sample ID: MB-R156917 SampType: MBLK TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 156917 Client ID: PBW Batch ID: R156917 TestNo: SW9034 Analysis Date: 1/23/2023 SegNo: 4177039 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive ND 25.0 Sample ID: LCS-111156917 SampType: LCS TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 156917 Client ID: LCSW Batch ID: R156917 TestNo: SW9034 Analysis Date: 1/23/2023 SegNo: 4177040 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 1670 25.0 1710 0 97.7 85 115 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range H Holding times for preparation or anal, M Manual Integration used to determine area response MC Value is below Minimum Compound OGl P Second column confirmation exceeds R RPD outside accepted recovery limits RL Reporting Detection Limit Original Page 36 of 38 E I (ivs) 0 aminou �o aauepdwo,) Ivraadg :61up A{Q aoj i Z❑ J 7 Q• d r-v O U a O z❑ z ❑ L U C• � � V F a 9 (� a U ❑ - ally-1 oibeuAS v `° z aldwcs jad sjau(clvo3io iaq°mu (siu)tuwoa u(.(lpads) uayio (g :auou (L:YQB (9 YfOvN W ❑ m O £ (y blcpay �u1Z l6 •DH (£ �hOS217 (Z �f0\Ri (f :oop°.��anfd (� ❑ r• a s _ �a�cA\ auryuuQ =,11Q 4a1v,1\ algelod-UO.'4 •ny=y'1!O 0•Plnbn-114pn4SIS'P9oS.S:cuivli J 'e � � aldwes°)!sodwoJ , a° aldweS quip , U c � is i S . • '' ^^ P > n A ❑ „ l' n U 9 N „ I 5 e • U E �laoLL ao3� 1 p'i W Or 6 U X I4' a pp i 3 ;L y�{��IM tl u 0 N s (a v az Z�° Q 0�0m coN o E �❑ 5 x o 50 p w '' :❑ I O L.L I E E el nvm m� Z `oi = o yt. u°. x ii Z v: a a - LL @t X v Q Q O T a E N a� co �� Em c eX o3 x a o- co Page 37 of 38 �� Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNOLOGIES, INC Cuyahoga Falls, Ohio44223 Sample Log -in Check List Analytical Laboratories TEL: (330) 253-8211 FAX (330) 253-4489 Website: http://www.settek.coni Client Name: SYN-NC-27028 Work Order Number: 23010838 RcptNo: 1 Logged by: Anthony W. Britton 1/13/2023 10:20:00 AM Completed By: Anthony W. Britton 1/13/2023 5:46:50 PM Reviewed By: Jennifer Woolf 1/16/2023 4:04:11 PM Chain of Custody 1. Is Chain of Custody complete? Yes d❑ No ❑ Not Present ❑ 2. How was the sample delivered? UPS Loa In 3, Coolers are present? Yes d❑ No F NA F 4. Shipping container/cooler in good condition? Yes d❑ No Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes ❑ No F— NA 6. Were all samples received at a temperature of >0° C to 6.0°C Yes d❑ No ❑ NA 7, Sample(s) in proper container(s)? Yes J❑ No ❑ 8. Sufficient sample volume for indicated test(s)? Yes d❑ No ❑ g, Are samples (except VOA and ONG) properly preserved? Yes J❑ No ❑ 10. Was preservative added to bottles? Yes ❑ No d❑ NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes No ❑ No VOA Vials ❑� 12. Were any sample containers received broken? Yes No d❑ 13. Does paperwork match bottle labels? Yes No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes No❑ 15. Is it clear what analyses were requested? Yes No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes No ❑ NA ❑d Person Notified: Date: By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: 18. Additional remarks: Cooler Information Cooler No Temp °C Condition Seal Intact Seal No Seal Date Signed By 1 5.0 Good Not Present Page 38 of 38 SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Sparta WQ Permit Number: WQ 00006242 WWTP Name: Sparta WWTP NPDES Number: NC 0026913 Monitoring Period: From 01/01/2023 To 12/31/2023 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/B (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density Alt. (2) Process to Significantly Reduce Pathogens X If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization X Air Drying Composting Aerobic Digestion Anaerobic Digestion rr ___1___LI- .._ ._1�....�.. •:.... ..,... f.........,1 /f I....,. A ...-!`I..00 R1 ruin nlnen ftin fnlln�vinn MnniMrinO rlaka• Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units deuces Analysis Fecal 2x10 to the 6"' MPN MPN/g Coliform power per gram of total solids CFU/g CFU 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform) Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 Option/Alt. 2 Option/Alt. 3 Option/Alt. 4 (VS reduction) (40-day bench) (30-day bench) (Spec. 02 uptake) Option/Alt. 5 Option/Alt. 6 Option/Alt. 7 Option/Alt. 8 (I4-DayAerobic) (Alk Stabilization) x (Drying — Stable) (Drying — Unstable) Option/Alt. 9 (Injection) OptioniAlt. 10 (Incorporation) No vector attraction reduction alternatives were perfonned CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1 107 have been met." ,11 certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1 107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made tinder my direction and supervision in accordance with the system designed to ensure that qualified ppersonnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including tine and imprisonment." Rvan Wilmoth Town Manager Preparer Name and Title ( type or print) Si raturc of Preparer* Dfite Land Applier Name and Title (if applicable) (type or print) Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) M®NT YEAR: SAMPLING LOCATION CLASS BIPSRP pH LOG SHEET Using a pH Meter with Two -Point Standardization and Automatic Temperature Compensation (ATC) Probe Analysis Method: SW-846 Method 9045D, Soil And Waste pH I+ACMITY/LOCATION: tv ][heal pH > 12.0 S.U. 2 Hour pH > 12.0 S.U. 24 Hour pH >11.5 S.U. w � o w x 5 b M y .r w� EL Initial pH/su. Temp/QC Adjusted Initial p]EI/sumo ° ti b n ? 2-I3r H*!su p Temp/°C Adjusted 2-Hr * pI$/suIP 9 a F. N � M o r"r ' o W T �; a w N 0 K 24-Hr pH/su ° Temp/ C Adjusted 24-Hi H*/su �'�= u 23 l 2 a3 �� 4 t2.lo-(03 :o l� !"" � �� k 4 AM ��I "` Egtuvalent pii value at L5 c:; correction -'actor (Ui,) = u.u:J pri units a �-u i omperature measurement — r guivawm ply — ivAGab- v- P.- L— --v. Comments: -23- SECTION 6 Agricultural Lime Application Log Year: 2023 Project: Sparta WWTP Field So . T171 Lime Requirement Tons/Acre Date Applied (state -county -site -field) pH 11 (from soil analysis) I Applied(CCE Eq.) *Lime is applied with the sludge since they are lime stabilized SECTION 7 NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL033715 Predictive Client: Alex Fox Synagro Advisor: £ x Soil Report Mehlich-3 Extraction 284 Boger Rd Mocksville, NC27028 Links to Helpful Information Sampled County: Alleghany Client ID: 501947 Advisor ID: Sampled: Received: 06/05/2023 Completed: 06/13/2023 Farm: AG-05 Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1- Fescue/OGrass/Tim, M 0.0 120-200 0 100 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 0 100 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.41 0.93 7.2 80 1.4 6.0 214 21 56 23 35 195 134 134 1022 1022 450 0.1 1 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1- Fescue/OGrass/Tim, M 0.5 120-200 50 0 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 50 0 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.32 0.89 6.7 76 1.6 5.7 37 80 45 26 66 78 64 64 128 128 45 0.4 6 North Carolina A� `� J lotwcuo iru%( FtavJ Umnauukm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY23-SLO33715 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at on Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-I potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients. In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NO3-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.gov/apronomi/obpart4.htm1 #sfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-I zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncapr.gov/agronomi/uyrst.htm Page 1 of 1 Report Number: 24-002-0529 • Account Number: 07778 (D Mai Waypoint 2850 Daisy Lane, Wilson, NC 27896 n 252-206-1721 ° Fax 252-206-9973 Send To: Synagro/Alex Fox ANALYTICAL www.waypointanalytical.com Alex Fox "Every acre... Every year. "TM Grower: SPARTA 284 Boger Rd Mocksville NC 27028 Farm: AG-08 SOIL ANALYSIS REPORT Analytical Method(s): Mehlich 3 Lime Index Humic Matter Loss On Ignition Water pH Date Received: 01 /02/2024 Date Of Analysis: 01 /03/2024 Date Of Report: 01 /03/2024 OM W/V ENR Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 Sample ID Lab Field ID Number % Soil Ibs/A M3 K Mg Ca Na Soil Buffer H Class ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate pH Index meq/100g meq/100g 1 24248 1.1 65 27 L 43 VL 125 H 577 M 44 L 6.3 1.0 5.2 NC=22 NC=22 Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts Sample ID Field ID K Mg Ca Na H NO3 N S Zn Mn Fe Cu B SS % % % % % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ms/cm Rate 1 2.1 20.0 55.5 3.7 19.2 11 L 4.8 H 16 M 1.1 M 0.3 VL NC=23 NC=120.0 NC=100 NC=55.0 Values on this report represent the plant available nutrients in the soil. Rating after each value: VL (Very Low), L (Low), M (Medium), H (High), VH (Very High). ENR - Estimated Nitrogen Release. C.E.C. - Cation Exchange Capacity. Date Received: 01/02/2024 Date Of Report: 01/03/2024 Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by: Salts ms/cm x 640 = ppm. Analysis prepared by: Waypoint Analytical Carolina, Inc. SOIL FERTILITY RECOMMENDATIONS Nitrogen Phosphate Potash Magnesium Sulfur Zinc Manganese Iron Copper Boron Sample ID Intended Crop Yield Goal Lime N P205 K20 Mg S Zn Mn Fe Cu B Field ID Tons Tons/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A 1 Fescue Hay 4 0.0 200 66 164 0 10 0 4 0 1.0 Comments: "The recommendations are based on research data and experience, but NO GUARANTEE or WARRANTY expressed or implied, concerning crop performance is made." Our reports and letters are for the exclusive and confidential use of our clients„ and may not be reproduced in whole or part, nor may any reference be made to the work,the results, or the company in any advertising, news release, or other public anouncements without obtaining our prior written authorization. Copy right 1977.