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Home My WebLink AboutWQ0001800_2023 Residual Annual Report_20240219 (2)Initial Review Reviewer nathaniel.thorn burg Is this submittal an application? (Excluding additional information.) * Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2023 Permit Number (IR) * WQ0001800 Applicant/Permittee Town of Yadkinville Email Notifications Does this need review by the hydrogeologist? * Yes U No Regional Office Winston-Salem CO Reviewer Admin Reviewer Wanda Gerald Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. Name* Lysa Finnerty Email Address* Ifinnerty@SYNAGRO.com Project Information ......................... Application/Document Type* New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Phone Number* 4105376150 Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, N DAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High -Rate Infiltration Other Wastewater Reclaimed Water Closed -Loop Recycle Residuals Single -Family Residence Wastewater Other Irrigation Permit Number:* WQ0001800 Has Current Existing permit number Applicant/Permittee Address* 435 Williams Court, Ste 100, Baltimore, MD 21220 Facility Name* Town of Yadkinville Class B Residuals Program Please provide comments/notes on your current submittal below. Submission of the 2023 Annual Report for Town of Yadkinville, NC At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. (Application Form, Engineering Plans, Specifications, Calculations, Etc.) Yadkinville NC 2023 Annual Report FINAL.pdf 24.79MB Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Alva �Cit'wt%tt, Submission Date 2/19/2024 435 Williams Court, Suite 100 Baltimore, MD 21220 www.synagro.com FEBRUARY 17, 2024 NCDEQ Division of Water Resources Information Processing Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2023 Annual Report for Permit No. WQ0001800 Dear NCDEQ: SYNAGRO Synagro is submitting one electronic copy of the above referenced report on behalf of the Town of Yadkinville, NC. If you have any questions or need additional information, please do not hesitate to contact Jacob Swaim at (336) 403-2444 or Alex Fox at (336) 703-8681. Sincerely, Devd& skkc" Derrick Shivar Environmental Compliance Manager Enclosures cc: Jacob Swaim — Town of Yadkinville Alex Fox, Synagro YOUR PARTNER FORA CLEANER, GREENERWORLD TOWN OF YADKINVILLE, NC RESIDUALS LAND APPLICATION PROGRAM Permit No. WQ0001800 2023 ANNUAL REPORT Town of Yadkinville, NC Residuals Land Application Program 2023 Annual Report TABLE OF CONTENTS 1. Certification Form and Annual Operations Summary 2. Annual Residual Sampling Summary Forms and Residuals Analyses 3. Annual Land Application Field Summary Forms & Metal Field Loading Summary Forms 4. TCLP Analyses 5. Pathogen ReductionNector Attraction Reduction 6. Soil pH & Lime Application Records 7. Soil Analyses SECTION 1 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit #: W00001800 County Yadkin Year 2023 Facility Name (as shown on permit) Town of Yadkinville WWTP & WTP NPDES No. NCO020338 Land Application Operator Synaero Phone# (336) 998-7150 Land application of residuals as allowed by the above permit occurred during the past calendar year? X YES NO. If NO, skip Part A, and Part B and proceed to Part C. Also, if residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A — Residuals Application Summary: Total number of application fields in the permit: 15 Total number of fields utilized for land application during the year: 8 Total amount of dry tons applied daring the year for all application sites: 146.59 Total number of acres utilized for land application during the year: 68.80 Part B — Annual Compliance Statement: Facility was compliant during calendar year 2023 with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water QualityX YES NO. If no, please provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1. Only residuals approved for this permit were applied to the permitted sites. 2. Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3. Annual soils analysis was performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4. Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5. All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6. The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1 105(a) or the Pollutant Loading Rates in 15A NCAC 02T .1105(b) (Applicable to 40 CFR Part 503 regulated facilities). 7. All general requirements as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8. All monitoring and reporting requirements in 15A NCAC 02T. I I I I were complied with (applicable to 40 CFR Part 503 regulated facilities). 9. All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10. No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11. Vegetative cover was maintained and proper crop management was perfonned on each site receiving residuals, as specified in the permit. 12. No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13. All buffer requirements as specified on the permit were maintained during each application of residuals. Part C — Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Jacob Swaim. Director of Public Works _ � V1 XIAq Pen 'ttee Name and Title (type or print) ign e f e i ee Date 2/1/2024 Signature of Preparer* Date Sig r f-Landl&plier Date (if different from Permittee) (if different from Permittee and Preparer) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 02T .1102 (26) DENR FORM ACF (12/2006) OPERATIONS SUMMARY - LAND APPLICATION - NORTH CAROLINA ALL COUNTIES - ALL SITES DATE RANGE: 1/1/2023 - 12/31/2023 YADKINVILLE, NC YADKINVILLE, NC WWTP LIQUID MONTH/YEAR March 2023 July 2023 November 2023 TOTAL YADKINVILLE, NC WTP LIQUID AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS 458,800.00 G 57.59 D 52.23 378,200.00 G 47.47 D 43.06 189,000.00 G 23.72 D 21.52 1,026,000.00 G 128.78 D 116.80 MONTH/YEAR AMOUNT UNIT DRY TONS UNIT DRY METRIC TONS February 2023 38,500.00 G 4.00 D 3.63 March 2023 52,500.00 G 5.45 D 4.94 June 2023 35,000.00 G 3.63 D 3.30 October 2023 45,500.00 G 4.72 D 4.29 TOTAL Units Key: D - Dry Tons; G — Gallons; W — Wet Tons; Y — Cubic Yards Report Date: 1/29/2024 4:05:45 PM 171,500.00 G 17.81 D 16.15 SECTION 2 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: W00001800 Laboratory: Facility Name: YADKINVILLE, NC PACE ANALYTICAL Residual Source WQ # or NPDES#: NCO020338 WWTP Name: YADKINVILLE WWTP Residual Analysis Data Product Type Sample or Composite Date LIQ 01/10/23 Parameter (mg/kg dry weight) Ceiling Conc. Limit Percent Solids (%) NA 3.01 Arsenic 75 4 Cadmium 85 1.2 Copper 4300 390 Chromium NA 53 Lead 840 22 Mercury 57 <0.64 Molybdenum 75 6.4 Nickel 420 41 Selenium 100 5.1 Zinc 7500 1900 Total Phosphorus NA 45000 TKN NA 48000 Ammonia -Nitrogen NA 14000 Nitrate and Nitrite NA 148.8 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer' Date 'Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF (1212006) Printed: 1/29/2024 4:56:01 PM For: 2056 01 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: W00001800 Facility Name: YADKINVILLE, NC Residual Source NPDES # or WQ#: NCO020338 WWTP Name: YADKINVILLE WWTP Residual Analysis Data Product Type LIQ Sample or Composite Date 01/10/23 Parameters (mg/kg dry weight) Aluminium 47000 Calcium 12000 Magnesium 3300 pH (s.u.) 7.50 Potassium 3400 Sodium 2800 PAN 17349 SAR (Ratio) 1.0098 Laboratory: PACE ANALYTICAL "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Sig ture of PreparerDate Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) Printed: 1/29/2024 5:00:46 PM For: 2056 01 DENR FORM RSSF-B (12/2006) 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Yadkinville Lot Number:YA12102 Date Completed:02/14/2023 NIM�� Mr� 02/14/2023 5:04 PM Approved and released by: Project Manager II: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 9 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: YA12102 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight unless flagged with a "W" qualifier. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Inorganic Metals The following samples were classified as biosolids therefore they were weighed out at around 3.0-3.5 grams to ensure proper digestion: YA12102-001, YA12102-002. The LOQ has been adjusted accordingly. Inorganic Non-metals Reanalysis of the following sample was performed outside of the analytical holding time: YA12102-002. Run 3 was performed because runs 1 and 2 did not match. The result from run 3 was 8,400 mg/kg, which most closely matches the in hold result of 7,100 mg/kg. The in -hold result will be reported. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 9 Client:Synagro Laboratory ID:YA12102-001 Description: YADKINVILLE WWTP Matrix: Solid Date Sampled:01/10/2023 1000 % Solids: 3.01 01/16/2023 1842 Date Received:01/12/2023 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 01/16/2023 1842 TAD 65010 1 350.1 (Ammonia - N ) 350.1 10 01/25/2023 1331 DMA 65582 1 (Nitrate - N ) 353.2 1 01/26/2023 1151 CMM 66119 1 (Nitrite - N ) 353.2 1 01/26/2023 1151 CMM 66116 1 (Phosphorus) 365.1 50 01/16/2023 1805 DMA 01/16/2023 0859 64846 1 (Soil pH meas) 9045D 1 01/17/2023 1211 BMG2 64825 1 351.4 (TKN) 351.2 2 01/18/2023 1820 DMA 01/17/2023 1258 64991 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 3.01 % 1 Ammonia - N (gas diffusion) 350.1 14000 330 170 mg/kg 1 Nitrate - N (soluble) 353.2 140 6.6 0.89 mg/kg 1 Nitrite - N (soluble) 353.2 8.8 6.6 0.87 mg/kg 1 Phosphorus 7723-14-0 365.1 45000 8300 1700 mg/kg 1 Soil pH measured in water @ 12.4 ° C 9045D 7.5 su 1 TKN 351.2 48000 3300 1700 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 01/14/2023 1431 MRW2 01/14/2023 1025 64810 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 2.7 0.64 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 01/18/2023 0049 JMH 01/17/2023 0843 64804 2 3050B 601OD 1 01/19/2023 0502 JMH 01/17/2023 0843 64804 3 3050B 6010D 1 01/20/2023 0024 JMH 01/17/2023 0843 64804 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 47000 190 72 mg/kg 1 Arsenic 7440-38-2 6010D 4.0 J 7.2 2.4 mg/kg 1 Cadmium 7440-43-9 6010D 1.2 J 2.4 0.61 mg/kg 1 Calcium 7440-70-2 6010D 12000 2400 300 mg/kg 1 Chromium 7440-47-3 6010D 53 4.8 1.2 mg/kg 3 Copper 7440-50-8 6010D 390 4.8 2.2 mg/kg 1 Iron 7439-89-6 6010D 22000 48 22 mg/kg 1 Lead 7439-92-1 6010D 22 4.8 2.2 mg/kg 1 Magnesium 7439-95-4 6010D 3300 2400 300 mg/kg 1 Manganese 7439-96-5 6010D 2700 7.2 2.8 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 3 of 9 Client:Synagro Laboratory ID:YA12102-001 Description: YADKINVILLE WWTP Matrix: Solid Date Sampled:01/10/2023 1000 % Solids: 3.01 01/16/2023 1842 Date Received:01/12/2023 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 01/18/2023 0049 JMH 01/17/2023 0843 64804 2 3050B 601OD 1 01/19/2023 0502 JMH 01/17/2023 0843 64804 3 3050B 601OD 1 01/20/2023 0024 JMH 01/17/2023 0843 64804 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Molybdenum 7439-98-7 6010D 6.4 J 19 4.8 mg/kg 1 Nickel 7440-02-0 6010D 41 19 5.0 mg/kg 2 Potassium 7440-09-7 6010D 3400 2400 300 mg/kg 1 Selenium 7782-49-2 6010D 5.1 J 9.6 3.9 mg/kg 1 Sodium 7440-23-5 6010D 2800 2400 300 mg/kg 1 Zinc 7440-66-6 6010D 1900 24 6.0 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 4 of 9 Client:Synagro Laboratory ID:YA12102-002 Description: YADKINVILLE WTP Matrix: Solid Date Sampled:01/10/2023 1015 % Solids: 2.49 01/16/2023 1842 Date Received:01/12/2023 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 01/16/2023 1842 TAD 65010 1 350.1 (Ammonia - N ) 350.1 1 01/25/2023 1305 DMA 65582 1 (Nitrate - N ) 353.2 1 01/26/2023 1153 CMM 66119 1 (Nitrite - N ) 353.2 1 01/26/2023 1153 CMM 66116 1 (Phosphorus) 365.1 1 01/16/2023 1800 DMA 01/16/2023 0859 64846 1 (Soil pH meas) 9045D 1 01/17/2023 1212 BMG2 64825 1 351.4 (TKN) 351.2 1 01/18/2023 1929 DMA 01/17/2023 1258 64991 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 254OG 2.49 % 1 Ammonia - N (gas diffusion) 350.1 260 40 21 mg/kg 1 Nitrate - N (soluble) 353.2 69 8.0 1.1 mg/kg 1 Nitrite - N (soluble) 353.2 3.2 J 8.0 1.1 mg/kg 1 Phosphorus 7723-14-0 365.1 1300 200 40 mg/kg 1 Soil pH measured in water @ 12.4 ° C 9045D 6.5 su 1 TKN 351.2 7100 2000 1000 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471B 7471B 1 01/14/2023 1433 MRW2 01/14/2023 1025 64810 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 3.0 0.73 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 601OD 1 01/18/2023 0053 JMH 01/17/2023 0843 64804 2 3050B 601OD 1 01/19/2023 0506 JMH 01/17/2023 0843 64804 3 3050B 6010D 3 01/19/2023 0510 JMH 01/17/2023 0843 64804 4 3050B 6010D 1 01/20/2023 0028 JMH 01/17/2023 0843 64804 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 260000 760 290 mg/kg 3 Arsenic 7440-38-2 6010D 9.5 9.5 3.2 mg/kg 1 Cadmium 7440-43-9 6010D ND 3.2 0.80 mg/kg 1 Calcium 7440-70-2 6010D 1300 J 3200 400 mg/kg 1 Chromium 7440-47-3 6010D 51 6.3 1.6 mg/kg 4 Copper 7440-50-8 6010D 72 6.3 2.9 mg/kg 1 Iron 7439-89-6 6010D 40000 63 29 mg/kg 1 Lead 7439-92-1 6010D 29 19 8.6 mg/kg 3 Magnesium 7439-95-4 6010D 1400 J 3200 400 mg/kg 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 9 Client:Synagro Laboratory ID:YA12102-002 Description: YADKINVILLE WTP Matrix: Solid Date Sampled:01/10/2023 1015 % Solids: 2.49 01/16/2023 1842 Date Received:01/12/2023 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 01/18/2023 0053 JMH 01/17/2023 0843 64804 2 3050B 601OD 1 01/19/2023 0506 JMH 01/17/2023 0843 64804 3 3050B 601OD 3 01/19/2023 0510 JMH 01/17/2023 0843 64804 4 3050B 6010D 1 01/20/2023 0028 JMH 01/17/2023 0843 64804 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Manganese 7439-96-5 6010D 11000 29 11 mg/kg 3 Molybdenum 7439-98-7 6010D ND 25 6.3 mg/kg 1 Nickel 7440-02-0 6010D 24 J 25 6.7 mg/kg 2 Potassium 7440-09-7 6010D 1300 J 3200 400 mg/kg 1 Selenium 7782-49-2 6010D 11 J 13 5.1 mg/kg 1 Sodium 7440-23-5 6010D 760 J 3200 400 mg/kg 1 Zinc 7440-66-6 6010D 120 32 7.9 mg/kg 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit Q = Surrogate failure ND = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL L = LCS/LCSD failure H = Out of holding time W = Reported on wet weight basis S = MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 9 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 9 PACE ANALYTICAL SERVICES, LLC o E 1 r O n m � A _ Lr} p} # Q I O }{ 3 r QQ G 17 qL.Lj t yV sis E'a - 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C W % -" ! V R L 8 L 1� a i a Ic y y o .J t Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 9 ra -�i I c2 _ r r= s � � G} ❑ 0 u a} 7 LL. 3 2 f � r J � L N F J w F< n cd5 i r% L E ,� cn ❑ 13 n w a J a � n m �in 2 PACE ANALYTICAL SERVICES, LLC DC4 7ttt4' ENV-FRNJ-WCOL-0226 02_Sarnp?es Receipt C;uckfrst (SRr-] We-ctive Dwe: Sf2 f 2422 ample Reccipt C heeklist (,SR(-') C1icnL. SYNAORO CMer Tns+:ecled b 5`darc: 1 { M V13 Lot r#, Y A12102 LAYcs +l Toro 1 _ Weir L-w4rjd s vtlls cscnt an the corAW 'Gex NO IV INA12, I2 C1151Uth- seals )h= preStnt, were Aley iRM-ct and a 1mo ? Pitt Z:m1p -LU_ "^ _ IL,nLOnLIC $1np 1>a; r" � Tested LT A origiuRl t lUl;e31c'11r UPoa lecaipt IDeri%'ed (CEurc.Ctcd) V TrCMtt1'e upo21 r&CiFt 09alid �1W-C111] ID= 2"�'2 1-5 f 1.5 OC %iA I-Nk 0r ?xA f Y2�y repL } 1 Off`+ �. Meawd: ZI'C1npmMlre BIMIk�] -f M FQtaees IRGnn ID: IR Gun Codrectioo Factor, 0 or Seiod of eoalant: [?]Wei c Ioc Plucks LjDfXIvc Alome QYes Ej 1*10 ❑RYA 3' W e ,aIi cooiets rcccivcd ar ar c -DW G,0'C? If no, was Pro leerI�Iagtr na+.:Merl? PM x&;! Notified by, }limn J cnla it I face-to-1aut: (circle ()Ile), Ycs jNo l A 4. Is die e4,rinl vial evluiCr s pPCMEp Slip atInhod to Elms fa17n? Ycs ND S. # ffe'ir)ucustadygiucedurf--soelinquislrcdlr ecived)followcxl? Yes No 6. Wi:ie sample IDs Astd bra ale C7 and all ym1+11c cotjtainers? Yes LjNio 7. W215 eollccti:sn dare & tiitt listed an t11� C_OC and 01 sxa44e eourahiers7 Yes FINo S_ Did SE contain-~r taint inibi-matk m C D, date, til=) djpLvG witL dx C? ILIY—CSI ING �_ Wrl:c tests to btt perfozwed lisped On the 00C? [aYes E]NO 10, Did all samriples mare in the prcgxr conTR:LiWB AN C%gcl3 tw fiR&Griu good rm' ilion (uiybrokt34lids um, ctc-)F ,I YYes Na 11. Was adaq=W mmplevohimc aim j1ablc`r ,�;Y TV() T2. AVM LtLi sa,nlplrs lWeiaed %OtUll. L,-� 111e boldinL Time or48 hems %VWC1levcr colnc; ;JTS . -V" [:] NO 15. Were all sar11 ks cuiA I LUS KC011l1[sd fa-? (Ne Frlisslu e cessj / Ycs � Na ZN 14, Were VOA, 901 nd R,1- -175 santes frcc of bubbles c itC" (, '-or Grljtt) iu eliaulwtra) ivaav-afthe %70A tiiialN" S Nia ri,�, d 5. ril ! a ll DRO =m]s! n1lt nqr saui les Divert at a pH Yes EA T 1 G_ Wcrc all cya.aide s 1�s recz(ved ttt a H ] �' and Stride suinplcs received at a pH > 97 LJN 1 Z I. —.- R....17,....�,,,, -AS +"A y1-0uuvc,q Inu-LlL r4. ,7.1f4U� � �� U.L magi ` .) buil it - Iry a `.�....t I lot 118_ Rrns the c Iuuul>z listed on the em miler la1:e1? If vcs. oatc jR DYes MPk Pj-e-wrvatioa (Must be compleked for any sa es, hicon-ectly pscscr Td or "`ltil hcA4%pace,) rrlple(s) '`11' x�U c rcec1"k in 01T-,cfly presefved amd mane ad.�Wked a sample receiving wi111 I4A mL.of circh, fine' i2 4, FIA 3,114Ci, NaUH Ws kg SR # NA ne 4f PnWrvadou NA J€nllM thou arse preservative is IrL ded, please pore ill I cuutmiis below. Nn 14C1 C rcccived with hobbles >G llxn is diamtl tu, ampl y) NA WM TMived with TRC > 0.51TWL (IC#1 is 1)0} And wCEC d 1stedarc(Oft lyin saiiTle Ieceiving wiTh Stldhinj tt-iosulCaLc (Pla2S,0,) With Uni{1t>e TT); NA C1)a1L12Cnc5: rlsltrax IC>; �3fi4 Pace* }InirlytieaI 5erVkes, Etc Page 1 of :t Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 9 ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: Laboratory: Facility Name: YADKINVILLE, NC PACE ANALYTICAL Residual Source WQ # or NPDES#: WQ0001800 WWTP Name: YADKINVILLE WTP Residual Analysis Data Product Type Sample or Composite Date WPL 01/10/23 Parameter (mg/kg dry weight) Ceiling Conc. Limit Percent Solids (%) NA 2.49 Arsenic 75 9.5 Cadmium 85 <0,8 Copper 4300 72 Chromium NA 51 Lead 840 29 Mercury 57 <0.73 Molybdenum 75 <6.3 Nickel 420 24 Selenium 100 11 Zinc 7500 120 Total Phosphorus NA 1300 TKN NA 7100 Ammonia -Nitrogen NA 260 Nitrate and Nitrite NA 72.2 For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." ►�� H Signat of P are ` Date 'Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) DENR FORM RSSF (12/2006) Printed: 2/7/2024 1:20:11 PM For: 2056 02 ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: Facility Name: Residual Source NPDES # or WQ#: WWTP Name: YADKINVILLE, NC WQ0001800 YADKINVILLE WTP Residual Analysis Data Product Type WPL Sample or Composite Date 01/10/23 Parameters (mg/kg dry weight) Aluminium 260000 Calcium 1300 Magnesium 1400 PH (s.u.) 6.50 Potassium 1300 Sodium 760 PAN 2938 SAR (Ratio) 0.5471 Laboratory: PACE ANALYTICAL "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordiance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." - - �2O/ q Sign e of arer Date `Preparer is defined in 40 CFR Part 503.9(r) and 15 A NCAC 2T.1102(26) Printed: 2/7/2024 1:21:04 PM For: 2056 02 DENR FORM RSSF-B (12/2006) 0p 0 PaceAnalyfical Report of Analysis Synagro 12701 Lancaster Hwy Pineville, NC 28134 Attention: Alex Fox Project Name: Yadkinville Lot Number:YA12102 Date Completed:02/14/2023 NIM�� Mr� 02/14/2023 5:04 PM Approved and released by: Project Manager II: Lucas Odom Q PCCRBp�� AAW 'ye I ANSI NdmlAccre00- Board eORft Al A C C R E D I T E D TESTING LABORATORY The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Pace Analytical Services, LLC. Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 Tel:803-791-9700 Fax:803-791-9111 www.pacelabs.com Page 1 of 9 PACE ANALYTICAL SERVICES, LLC SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative Synagro Lot Number: YA12102 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Where sampling is conducted by the client, results relate to the accuracy of the information provided, and as the samples are received. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved The NELAC Institute (TNI) standards, the Pace Analytical Services, LLC ("Pace") Laboratory Quality Manual, standard operating procedures (SOPs), and Pace policies. Any exceptions to the TNI standards, the Laboratory Quality Manual, SOPs or policies are qualified on the results page or discussed below. Pace is a TNI accredited laboratory; however, the following analyses are currently not listed on our TNI scope of accreditation: Drinking Water: VOC (excluding BTEX, MTBE, Naphthalene, & 1,2- dichloroethane) EPA 524.2, E. coli and Total coliforms SM 9223 B-2004, Solid Chemical Material: TOC Walkley-Black, Biological Tissue: All, Non -Potable Water: SGT-HEM EPA 1664B, Silica EPA 200.7, Boron, Calcium, Silicon, Strontium EPA 200.8, Bicarbonate, Carbonate, and Hydroxide Alkalinity SM 2320 B-2011, SM 9221 C E-2006 & SM 9222D-2006, Strontium SW-846 6010D, VOC SM 6200 B-2011, Fecal Coliform Colilert-18. Where applicable, all soil sample results (including LOQ and DL if requested) are corrected for dry weight unless flagged with a "W" qualifier. If you have any questions regarding this report, please contact the Pace Project Manager listed on the cover page. The pH analysis associated with the sample(s) in this report was/were performed after the method recommended 15 minute holding time. Inorganic Metals The following samples were classified as biosolids therefore they were weighed out at around 3.0-3.5 grams to ensure proper digestion: YA12102-001, YA12102-002. The LOQ has been adjusted accordingly. Inorganic Non-metals Reanalysis of the following sample was performed outside of the analytical holding time: YA12102-002. Run 3 was performed because runs 1 and 2 did not match. The result from run 3 was 8,400 mg/kg, which most closely matches the in hold result of 7,100 mg/kg. The in -hold result will be reported. Pace Analytical Services, LLC (formerly Shealy Environmetal Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 vvvvvv.pacelabs.com Page 2 of 9 Client: Synagro Laboratory ID: YA12102-002 Description: YADKINVILLE WTP Matrix: Solid Date Sampled:01/10/2023 1015 % Solids: 2.49 01/16/2023 1842 )ate Received: 01 /12/2023 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (% Solids) SM 2540G 1 01/16/2023 1842 TAD 65010 1 350.1 (Ammonia - N ) 350.1 1 01/25/2023 1305 DMA 65582 1 (Nitrate - N ) 353.2 1 01/26/2023 1153 CMM 66119 1 (Nitrite - N ) 353.2 1 01/26/2023 1153 CMM 66116 1 (Phosphorus) 365.1 1 01/16/2023 1800 DMA 01/16/2023 0859 64846 1 (Soil pH meas) 9045D 1 01/17/2023 1212 BMG2 64825 1 351.4 (TKN) 351.2 1 01/18/2023 1929 DMA 01/17/2023 1258 64991 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run % Solids SM 2540G 2.49 % 1 Ammonia - N (gas diffusion) 350.1 260 40 21 mg/kg 1 Nitrate - N (soluble) 353.2 69 8.0 1.1 mg/kg 1 Nitrite - N (soluble) 353.2 3.2 J 8.0 1.1 mg/kg 1 Phosphorus 7723-14-0 365.1 1300 200 40 mg/kg 1 Soil pH measured in water @ 12.4 ° C 9045D 6.5 su 1 TKN 351.2 7100 2000 1000 mg/kg 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7471 B 7471 B 1 01/14/2023 1433 MRW2 01/14/2023 1025 64810 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7471B ND 3.0 0.73 mg/kg 1 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 01/18/2023 0053 JMH 01/17/2023 0843 64804 2 3050B 6010D 1 01/19/2023 0506 JMH 01/17/2023 0843 64804 3 3050B 6010D 3 01/19/2023 0510 JMH 01/17/2023 0843 64804 4 3050B 6010D 1 01/20/2023 0028 JMH 01/17/2023 0843 64804 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6010D 260000 760 290 mg/kg 3 Arsenic 7440-38-2 601OD 9.5 9.5 3.2 mg/kg 1 Cadmium 7440-43-9 601OD ND 3.2 0.80 mg/kg 1 Calcium 7440-70-2 601OD 1300 J 3200 400 mg/kg 1 Chromium 7440-47-3 601OD 51 6.3 1.6 mg/kg 4 Copper 7440-50-8 601OD 72 6.3 2.9 mg/kg 1 Iron 7439-89-6 601OD 40000 63 29 mg/kg 1 Lead 7439-92-1 601OD 29 19 8.6 mg/kg 3 Magnesium 7439-95-4 601OD 1400 J 3200 400 mg/kg 1 LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 5 of 9 Client: Synagro Laboratory ID: YA12102-002 Description: YADKINVILLE WTP Matrix: Solid Date Sampled:01/10/2023 1015 % Solids: 2.49 01/16/2023 1842 Date Received: 01 /12/2023 ICP-AES Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3050B 6010D 1 01/18/2023 0053 JMH 01/17/2023 0843 64804 2 3050B 6010D 1 01/19/2023 0506 JMH 01/17/2023 0843 64804 3 3050B 6010D 3 01/19/2023 0510 JMH 01/17/2023 0843 64804 4 3050B 6010D 1 01/20/2023 0028 JMH 01/17/2023 0843 64804 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Manganese 7439-96-5 6010D 11000 29 11 mg/kg 3 Molybdenum 7439-98-7 6010D ND 25 6.3 mg/kg 1 Nickel 7440-02-0 6010D 24 J 25 6.7 mg/kg 2 Potassium 7440-09-7 6010D 1300 J 3200 400 mg/kg 1 Selenium 7782-49-2 6010D 11 J 13 5.1 mg/kg 1 Sodium 7440-23-5 6010D 760 J 3200 400 mg/kg 1 Zinc 7440-66-6 6010D 120 32 7.9 mg/kg 2 LOQ - Limit of Quantitation B - Detected in the method blank E - Quantitation of compound exceeded the calibration range DL - Detection Limit Q - Surrogate failure ND - Not detected at or above the DL N - Recovery is out of criteria P - The RPD between two GC columns exceeds 40% J - Estimated result < LOQ and > DL L - LCS/LCSD failure H - Out of holding time W - Reported on wet weight basis S - MS/MSD failure Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 6 of 9 Chain of Custody and Miscellaneous Documents Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 7 of 9 PACE ANALYTICAL SERVICES, LLC g � o E 1 r O n m G:L A _ Lr} p} # Q I O }{ 3 r QQ s�5E8Lr - N I dLLM ;ildwt! 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V R f v C? ,y CL 41 8 L 1� a i 0 ZKm a y y o < V a 'r+ Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 8 of 9 ra -�i _ r r= x � � G} ❑ i 0 u a} CJ Ena m _ ,j Qj m 7 LL' Lj s� v` 3 2 fy � .w f � r Ir J � L N F J w P P n cl 5 i D E L do cn ❑ o' n w a J a � n m in 2 3 fJ W L LO 5 R PACE ANALYTICAL SERVICES, LLC DC4 7ttt4' ENV-FRNJ-WCOL-0226 02_Sarnp?es Receipt C;uckfrst (SRr-] We-ctive Dwe: Sf2 f 2422 ample Reccipt C heeklist (,SRC) C1icnL: SYNAORO CMer Tns+:ecled b 5`darc: 1 { MU13 Lot r#, YA12102 LAYcs +l Toro 1 _ Weir me4rjd s vtlls cscnt an the corAW 'Gex NO IV INA12, I2 cliKuth- seals )h= preStnt, were Aley iRM-ct and L> 1mo ? pri Z:m1p -LU_ "^ _ IL.nl na mC 51np 1>a; r" � Tested LT w origiuRl t lUl;e31c'11r UPDa lecaipt IDeri1'ed (CUIrUCtCd) V TrCMtt1'e UPM1 rocciFt 09alid �LW-C111] ID= 2"�'2 1-5 f 1.5 OC %rA I-k 0r 1xA f Y2�y repL } 1 Off`+ �. Meawd: ZI'C1npmMlre BIMIk�] -f M FQtaees IRGnn ID: IR Gun Codrectioo Factor, 4 or Seiod of eoalant: [?]Wei c Ioc Plucks LjDfXIvc Alome QYes Ej 1*10 ❑KA 3' W e ,aIi cooiets rcccivcd ar ar c -DW G,0'C? If no, was Pro leerI�Iagtr na+.:Merl? 1x14i &;! Notified by, }limn J cnla Il I face-to-1aur (circle ()Ile), Ycs jNo l A 4. Is die e4,rinl vial evlrricr s pPCMEp Slip atInhod to Elms fn17n? Ycs ND S. # ffe'ir)ucustadygiucedurf--soelinquislrcdlr ecived)followcxl? Yes No 6. RFcre sample IDs Astd bra ale C7 and all yml+lJc cotjtaiws? Yes LjNio 7. W215 eollccti:sn date & Iiitt lisrcd an t11� C_OC and 01 sxa44e eourahiers7 Yes FINo S_ Did SE contain-~r laWl. inibi-matk m C D, date, fli=) djpLvG witL dx C? ILIY—CS I ING 9_ Wrl:c tests to hr perliornled lisped on the 00 ? [aYes Q NO 10, Did all swriples mare in the proper conTR:LiWB AN rBCh tw tmdfor iu good rm' it ion (ubrokt34 lids um, ctc-)F ,I YYes Na 11. Was adcq=W mmplevohimc aim j1ablc`r ,�;Y TV() T2. AVM LIR sa,nlplrs 11aceMd %OtUll. L,-� 111e boldinL Time or48 hems %VWC1Ievcr colnc; ;JTS . -V" [:] NO 15. Were all sar11 ks cuiA In US KC011l1[cd fo-? (Ne Frlisslu e cessj / ❑Ycs �Na ZN 14, Were VOA, 901 nd R,1- -175 santes frcc of bubbles c it " (, '-or Grljtt) iu eliaul�tra) ivaav-afthe %70A tiiialN" S EA Nia ri,�, d 5, ril ! all l}1��11I1�rfL]s!n11tngr sau1 les L ived at a pH Yes T 16_ Wcrc all cya.aide s 1�s recz(ved ttt a gH > ] -2 and Stride suinplcs received at a pH > 97 � I � I. — .- R • -IT--AS +"A y1-0U.UUV Inu-LlL r4. ,7, 1fwlo � �� U-Lmagi `1.) bull it - Iry a `.�....t I l of 118_ Rrns the c Iuuul>z listed on the em airier ia1:e1? If vcs. oatc jR DYes MPk Pj-e-wrvatioa (Must be compleked for any sa es, hicon-ectly pscscr Td or "`ltil hcA4%pace,) rnple(s) '`11' x�U c rcec1"k in 01T-,cfly presefved amd mane ad.�Wked a sample receiving wi111 14A mL.of circh, fie' i2 4, FIA 3,114Ci, NaUH Ws kg SR # NA ne 4f PnWrvadou NA J€nllM thw orke preservative is IrL ded, please pore ill I Cuuj mils below. Nn 14C1 C rcccived with hobbles >G ahn ill diamtl tu, amplrs(s) NA 1- M TMived with TRC > 0.511WL (11'#1 is 1)0) And wCEC 1stC'dacc(Oftoy in saiiTle Ieceiving wiTh S{1dhinj tL'iosulCaLc (Pla2S,0,) 7fiLth ilni(p L. T D, NA C1)a1L12Cne5: QuA'ax ID: 536D Race*Artirlytica Ser++kes, LLC Pagt I of :t Pace Analytical Services, LLC (formerly Shealy Environmental Services, Inc.) 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.pacelabs.com Page 9 of 9 SECTION 3 FACILITY NAME: YADKINVILLE, NC LAND OWNER: LARRY STYERS OPERATOR: BILLY GRIFFIN CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT M W00001800 FIELD#: NC-YK-00008-0-0006- ANNUAL DRY TONS APPLIED: 7.03 SITE M NC YK 00008 PREDOMINANT SOIL SERIES: CLIFFORD CROP 1 MAX. PAN: 216 CROP 2 NAME: ACRES UTILIZED: 5.0 ACRES PERMITTED: 5.0 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 11/14/2023 56,000.00 (G) 3.010 1.406 YL DRY 0-<1/2"" SUR 0.5 0.30 48,000.00 14,000.00 148.80 48.778 FSH Nov-23 56,000.00 (G) Total 1.406 Total 48.778 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.011 1 0.003 1 1.097 0.149 0.062 0.002 0.018 0.115 0.014 5.342 126.521 Date Lbs/Ac Applied 0.041 1 0.035 1 10.796 1 0.558 1 1.610 1 0.022 1 0.718 1 0.516 1 0.045 1 13.171 Permit PAN Limit (Ibs/acre) 1st Crop 216 Federal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 267.9 1 15.0 375.0 1 89.0 1 2,500.0 YL = YADKINVILLE, NC W WTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significa p alties fors itting false information, including the possibility of fines and imprisonment for ]mowing violations." �'� S16NATORE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) Facility Name: Permit #: Operator: Acres Used: 5.00 ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): YADKINVILLE, NC W00001800 Cation Exchange Capacity (non 503 only): BILLY GRIFFIN LARRY STYERS Predominant Soil Series: Owner: Acres Permitted: 5.00 Site #: Field #: NC YK 00008 7.03 CLIFFORD NC YK 00008 0006 Source YL Sample or Composite Date 1 1/10123 2 3 4 5 6 7 8 9 10 11 12 %Solids 3.01 Arsenic 4.000 Cadmium 1.200 Copper 390 Chromium 53.00 Lead 22.00 Mercury 0.640 Molybdenum 6.40 Nickel 41.00 Selenium 5.10 Zinc 1900 Total Phosphorus 45000 Annual Heaw Metal Field Loadinas (Calculated in Ibs/acrel: Source YL Total DT/Ac. / App.Event 1 1.41 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Cadmium 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Copper 1.097 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.097 Chromium 0.149 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.149 Lead 0.062 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.062 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molybdenum 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 Nickel 0.115 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.115 Selenium 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Zinc 5.342 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 5.342 Total Phosphorus 126,521 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 126.521 1 certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are signific nalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". 2_��'� Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 FACILITY NAME: YADKINVILLE, NC WQ PERMIT #: W00001800 FIELD#: NC-YK-00009-0-0001- ACRES UTILIZED: 7.5 LAND OWNER: JACK ADAMS ANNUAL DRY TONS APPLIED: 16.69 SITE #: NC YK 00009 ACRES PERMITTED: 7.5 OPERATOR: JACK ADAMS PREDOMINANT SOIL SERIES: CLIFFORD CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: FESCUE HAY (FSH) CROP 1 MAX. PAN: 216 CROP 2 NAME: CROP 2 MAX. PAN: RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 11/8/2023 21,000.00 (G) 3.010 0.351 YL DRY 0-<1/2"" SUR 0.5 0.30 48,000.00 14,000.00 148.80 12.194 FSH 11/9/2023 56,000.00 (G) 3.010 0.937 YL DRY 0-<1/2"" SUR 0.5 0.30 48,000.00 14,000.00 148.80 32.518 FSH 11/13/2023 56,000.00 (G) 3.010 0.937 YL DRY 0-<1/2"" SUR 0.5 0.30 48,000.00 14,000.00 148.80 32.518 FSH Nov-23 133,000.00` (G) I ;Annual Ibs/acre Applied Cumulative Ibs/acre Applied Permit PAN Limit (Ibs/acre) 1 st Crop Total 2.225 AS CD 0.018 0.005 0.071 0.038 CU CR PB HG MO NI SE ZN 1.736 0.236 0.098 0.003 0.029 0.183 0.023 8.458 16.311 1.439 0.790 0.021 0.225 0.923 0.095 36.717 Total 77.230 0.000 P Lime Applied 025 Date Lbs/A YL = YADKINVILLE, NC WWTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel property gathered and evaluated the information submitted. I am aware that there are significant p es f�r sub ' 'ng false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) Facility Name: Permit #: Operator: Acres Used: ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): YADKINVILLE, NC W 00001800 Cation Exchange Capacity (non 503 only): JACK ADAMS JACK ADAMS Predominant Soil Series: Owner: 7.50 Acres Permitted P-14 1 A..-,- n- rues.... Me - - r- or...... - .. _ .. -- ,... ......... -- 7.50 Site #: NC YK 00009 Field #: 16.69 CLIFFORD NC YK 00009 0001 Source YL Sample or Composite Date 1 1/10/23 2 3 4 5 6 7 8 9 10 11 12 Solids 3.01 Arsenic 4.000 Cadmium 1.200 Copper 390 Chromium 53.00 Lead 22.00 Mercury 0.640 Molybdenum 6.40 Nickel 41.00 Selenium 5.10 Zinc 1900 Total Phosphorus 45000 Annual Haaw Matal Field Loadinae rCalculatad in Iha/anml- Source YL Total DT/Ac. / App.Event 1 2.23 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 Cadmium 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 1.736 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.736 Chromium 0.236 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.236 Lead 0.098 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.098 Mercury 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molybdenum 0.029 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Nickel 0.183 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.183 Selenium 0.023 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.023 Zinc 8.458 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 8.458 Total Phosphorus 200.325 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 200.325 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pebmittiag4se information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (12/2006) FACILITY NAME: YADKINVILLE, NC LAND OWNER: TOWN OF YADKINVILLE OPERATOR: TOWN OF YADKINVILLE CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: W00001800 FIELD#: NC-YK-00029-0-0001- ANNUAL DRY TONS APPLIED: 17.81 SITE #: INC YK 00029 PREDOMINANT SOIL SERIES: CLIFFORD CROP 1 MAX. PAN: 216 CROP 2 NAME: ACRES UTILIZED: 11.5 ACRES PERMITTED: 11.5 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 2/20/2023 38,500.00 (G) 2.490 0.348 YWPL MOIST 0-<1/2"" SUR 0.5 0.40 7,100.00 260.00 72.20 2.043 FSH Feb-23 38,500.00 (G) 3/30/2023 24,500.00 (G) 2.490 0.221 YWPL DRY 0-<1/2"" SUR 0.5 0.40 7,100.00 260.00 72.20 1.300 FSH 3/31/2023 28,000.00 (G) 2.490 0.253 YWPL DRY 0-<1/2"" SUR 0.5 0.40 7,100.00 260.00 72.20 1.486 FSH Mar-23 52,500.00 (G) 6/29/2023 21,000.00 (G) 2.490 0.190 YWPL DRY 0-<1/2"" SUR 0.5 0.40 7,100.00 260.00 72.20 1.114 FSH 6/30/2023 14,000.00 (G) 2.490 0.126 YWPL DRY 0-<1/2"" SUR 0.5 0.40 7,100.00 260.00 72.20 0.743 FSH Jun-23 35,000.00 (G) 10/25/2023 45,500.00 (G) 2.490 0.411 YWPL DRY 0-<1/2"" SUR 0.5 0.40 7,100.00 260.00 72.20 2.414 FSH Oct-23 45,500.00 (G) Total 1.549 Total 9.100 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.029 0.002 0.223 0.158 0.090 0.002 0.020 0.074 0.034 0.372 4.026 Date Lbs/Ac Cumulative Ibs/acre Applied 0.217 0.055 2.266 0.962 0.876 0.015 0.163 0.425 0.239 4.668 Permit PAN Limit (Ibs/acre) 1st Crop 216 Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0 YWPL = YADKINVILLE, NC WTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant nalties for submitting false information, including the possibility of fines and imprisonment for ]mowing violations." SIGNATURE OF LAND APPLIER L - % '�� DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **" C.P.L.R.: Cumulative Pollutant Loading Rate Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM' Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): Facility Name: YADKINVILLE, NC Permit #: W00001800 Cation Exchange Capacity (non 503 only): Operator: TOWN OF YADKINVILLE TOWN OF YADKINVILLE Predominant Soil Series: Owner: Acres Used: 11.50 Acres Permitted: 11.50 Site #: Field #: NC YK 00029 Rncirlal A-1-ie n- 114- M-1� -d T-1 Pl.ncnl.nn•..• Q-11A. •• n Raw Dn.�nnr 3n• 17.81 CLIFFORD NC YK 00029 0001 Source YWPL Sample or Composite Date 1 1/10/23 2 3 4 5 6 7 8 9 10 11 12 Solids 2.49 Arsenic 9.500 Cadmium 0.800 Copper 72 Chromium 51.00 Lead 29.00 Mercury 0.730 Molybdenum 6.30 Nickel 24.00 Selenium 11.00 Zinc 120 Total Phosphorus 1300 Annual Heavv Metal Field Loadinqs (Calculated in Ibs/acre): Source YWPL Total DT/Ac. / App.Event 1 1.55 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.029 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.223 0.000 0.000 0.000 0.000 0.000 0,000 0.000 0.000 0.000 0.000 0.000 0.223 Chromium 0.158 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.158 Lead 0.090 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.090 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molybdenum 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 Nickel 0.074 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.074 Selenium 0.034 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.034 Zinc 0.372 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.372 Total Phosphorus 4.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.026 "I certify, tinder penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant n ties for submitting false information, including the possibility of fines and imprisonment for (mowing violations". 2-4-74 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 FACILITY NAME: YADKINVILLE, NC WQ PERMIT #: W00001800 FIELD#: NC-YK-00033-0-0001- ACRES UTILIZED: 7.6 LAND OWNER: KENNETH GRAY HOBSON ANNUAL DRY TONS APPLIED: 24.13 SITE #: NC YK 00033 ACRES PERMITTED: 7.6 OPERATOR: JAMES HOBSON PREDOMINANT SOIL SERIES: CLIFFORD CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: FESCUE HAY (FSH) CROP 1 MAX. PAN: 216 CROP 2 NAME: CROP 2 MAX. PAN: RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 3/20/2023 80,600.00 (G) 3.010 1.331 YL DRY 0-<1/2" SUR 0.5 0.30 48,000.00 14,000.00 148.80 46.187 FSH 3/21/2023 31,000.00 (G) 3.010 0.512 YL DRY 0-<1/2" SUR 0.5 0.30 48,000.00 14,000.00 148.80 17.764 FSH Mar-23 111,600.00 (G) 7/19/2023 80,600.00 (G) 3.010 1.331 YL DRY 0-<1/2""_]_ SUR 0.5 0.30 48,000.00 14,000.00 148.80 46.187 FSH Jul-23 80,600.00 (G) Total 3.174 Total 110.138 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.025 0.008 2.476 0.336 0.140 0.004 0.041 0.260 0.032 12.062 285.683 Date Lbs/Ac Cumulative Ibs/acre Applied 0.086 0.019 9.688 0.985 0.463 0.015 0.121 0.857 0.111 35.375 Permit PAN Limit (Ibs/acre) 1st Crop 216 YL = YADKINVILLE, NC W WTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pena Lfor submitting false information, including the possibility of fines and imprisonment for knowing violations." I- - 4W.2 SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): Facility Name: YADKINVILLE, NC Permit #: W00001800 Cation Exchange Capacity (non 503 only): Operator: JAMES HOBSON KENNETH GRAY HOBSON Predominant Soil Series: Owner: Acres Used: 7.60 Acres Permitted: 7.60 Site #: Field #: NC YK 00033 24.12 CLIFFORD NC YK 00033 0001 Source YL Sample or Composite Date 1 1/10/23 2 3 4 5 6 7 8 9 10 11 12 % Solids 3.01 Arsenic 4.000 Cadmium 1.200 Copper 390 Chromium 53.00 Lead 22.00 Mercury 0.640 Molybdenum 6.40 Nickel 41.00 Selenium 5.10 Zinc 1900 Total Phosphorus 45000 Annual Heaw Mefal Field Loadinas !Calculated in Ihs/acre!: Source YL Total DT/Ac. / App. Event 1 3.17 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.025 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.025 Cadmium 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.008 Copper 2.476 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.476 Chromium 0.336 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.336 Lead 0.140 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.140 Mercury 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molybdenum 0.041 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.041 Nickel 0.260 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.260 Selenium 0.032 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.032 Zinc 12.062 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 12.062 Total Phosphorus 285.683 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 285.683 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are stgntfic �altiies for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 FACILITY NAME: YADKINVILLE, NC WQ PERMIT #: WQ0001800 FIELD#: NC-YK-00033-0-0002- ACRES UTILIZED: 6.4 LAND OWNER: KENNETH GRAY HOBSON ANNUAL DRY TONS APPLIED: 24.90 SITE #: NC YK 00033 ACRES PERMITTED: 6.4 OPERATOR: JAMES HOBSON PREDOMINANT SOIL SERIES: CLIFFORD CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: FESCUE HAY (FSH) CROP 1 MAX. PAN: 216 CROP 2 NAME: CROP 2 MAX. PAN: RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg ni mg/kg Crop 1 Crop 2 Crop 1 Crop 2 3/16/2023 93,000.00 (G) 3.010 1.824 YL DRY 0-<1/2"" SUR 6.5 0.30 48,000.00 14,000.00 148.80 63.286 FSH 3/17/2023 18,600.00 (G) 3.010 0.365 YL DRY 0-<1/2"" SUR 0.5 0.30 48,000.00 14,000.00 148.80 12.657 FSH 3/21/2023 6,200.00 (G) 3.010 0.122 YL DRY 0-<1/2" SUR 0.5 0.30 48,000.00 14,000.00 148.80 4.219 FSH Mar-23 117,800.00 (G) 7/19/2023 80,600.00 (G) 3.010 1.581 YL DRY 0-<1/2"" SUR 0.5 0.30 48,000.00 14,000.00 148.80 54.848 FSH Jul-23 80,600.00 (G) Total 3.892 Total 135.010 0.000 AS CD CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.031 0.009 3.035 0.412 0.171 0.005 0.050 0.319 0.040 14.786 350.192 Date Lbs/Ac Cumulative Ibs/acre Applied 0.124 1 0.028 15.018 1.448 0.699 0.026 0.182 1.269 0.160 52.504 1Permit PAN Limit (Ibs/acre) 1st Crop 216 Fderai'b.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1,339.0 267.9 1 15.0 375.0 89.0 2,500.0 YL = YADKINVILLE, NC WWTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pe 1 s for submittiN false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DEN FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): Facility Name: YADKINVILLE, NC 24.90 Permit #: WO0001800 Cation Exchange Capacity (non 503 only): Operator: JAMES HOBSON KENNETH GRAY HOBSON Predominant Soil Series: Owner: CLIFFORD Acres Used: 6.40 Acres Permitted: 6.40 Site #: Field #: NC YK 00033 0002 NC YK 00033 Residual Analysis Data (Heavy Metals and Total Phosphorus use ma/ko. % Solids use Raw Percent #1: Source YL Sample or Composite Date 1 1/10/23 2 3 4 5 6 7 8 9 10 11 12 Solids 3.01 Arsenic 4.000 Cadmium 1.200 Copper 390 Chromium 53.00 Lead 22.00 Mercury 0.640 Molybdenum 6.40 Nickel 41.00 Selenium 5.10 Zinc 1900 Total Phosphorus 45000 Annual Heavy Metal Field Loadings (Calculated in Ibslacre): Source YL Total DT/Ac. / App.Event 1 3.89 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.031 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.031 Cadmium 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Copper 3.035 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.035 Chromium 0.412 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.412 Lead 0.171 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.171 Mercury 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Molybdenum 0.050 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.050 Nickel 0.319 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.319 Selenium 0.040 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.040 Zinc 14.786 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 14.786 Total Phosphorus 350.192 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 350.192 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant p a es for submitti g false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM Page: 1 FACILITY NAME: YADKINVILLE, NC WQ PERMIT #: WQ0001800 FIELD#: NC-YK-00033-0-0003- ACRES UTILIZED: 8.5 LANDOWNER: JAMES K HOBSON ANNUAL DRY TONS APPLIED: 11.67 SITE #: NC YK 00033 ACRES PERMITTED: 8.5 OPERATOR: JAMES K HOBSON PREDOMINANT SOIL SERIES: CLIFFORD CATION EXCHANGE CAPACITY (NON-503): CROP 1 NAME: FESCUE HAY (FSH) CROP 1 MAX. PAN: 216 CROP 2 NAME: CROP 2 MAX. PAN: RESIDUAL SOURCE(S): * See list at bottom of report Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 3/21/2023 68,200.00 (G) 3.010 1.007 YL DRY 0-<1/2" SUR 0.5 0.30 48,000.00 14,000.00 148.80 34.944 FSH 3/22/2023 24,800.00 (G) 3.010 0.366 YL DRY 0-<1/2" SUR 0.5 0.30 48,000.00 14,000.00 148.80 12.707 FSH Mar-23 93,000.00 (G) Total 1.373 Total 47.651 0.000 AS CDI CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.011 1 0.003 1 1.071 0.146 0.060 0.002 0.018 0.113 0.014 5.219 123.597 Date ILbs/Ac Cumulative Ibs/acre Applied 0.027 0.007 S 3.340 ' 0.314 I 0.142 I 0.007 I 0.040 0.275 I 0.034 I 11.736 Permit PAN Limit (Ibs/acre) 1st Crop I j j ( ( j 216 Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0 YL = YADKINVILLE, NC WWTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalt or submitting false information, including the possibility of fines and imprisonment for knowing violations." SIGNATURE APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM' Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): Facility Name: YADKINVILLE, NC 11.67 Permit #: WQ0001800 Cation Exchange Capacity (non 503 only): Operator: JAMES K HOBSON JAMES K HOBSON Predominant Soil Series: CLIFFORD Owner: Acres Used: 8.50 Acres Permitted: 8.50 Site #: Field #: NC YK 00033 0003 NC YK 00033 Residual Analvsts Data (Heave Metals and Total Phosphorus use mo/ko. % Solids use Raw Percent #): Source YL Sample or Composite Date 1 1/10/23 2 3 4 5 6 7 8 9 10 11 12 Solids 3.01 Arsenic 4.000 Cadmium 1.200 Copper 390 Chromium 53.00 Lead 22.00 Mercury 0.640 Molybdenum 6.40 Nickel 41.00 Selenium 5.10 Zinc 1900 Total Phosphorus 45000 Annual Heavy Metal Field Loadings (Calculated in Ibs/acre): Source YL Total DT/Ac. / App. Event 1 1.37 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.011 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.011 Cadmium 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Copper 1.071 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.071 Chromium 0.146 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.146 Lead 0.060 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.060 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molybdenum 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 Nickel 0.113 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.113 Selenium 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Zinc 5.219 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 5.219 Total Phosphorus 123.597 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 123.597 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pe E for submitting false information, including the possibility of fines and imprisonment for knowing violations". �2� �(j 24 Signature of Land Applier �- Date DENR FORM MFLSF (12/2006) FACILITY NAME: YADKINVILLE, NC LAND OWNER: ROGER FRANK DAVIS OPERATOR: ROGER FRANK DAVIS CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WO PERMIT #: WQ0001800 FIELD#: NC-YK-00035-0-0001- ANNUAL DRY TONS APPLIED: 27.24 SITE #: NC YK 00035 PREDOMINANT SOIL SERIES: CLIFFORD CROP 1 MAX. PAN: 216 CROP 2 NAME: ACRES UTILIZED: 12.2 ACRES PERMITTED: 12.2 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 7/18/2023 217,000.00 (G) 3.010 2.233 YL DRY 0-<1/2"" SUR 0.5 0.30 48,000.00 14,000.00 148.80 77.464 FSH Jul-23 217,000.00 (G) I otal 2.233 Total 77.464 0.000 AS CD CU CR PB I HG I MO J NI F= ZN P Lime Applied Annual Ibs/acre Applied 0.018 1 0.005 1 1.741 0.237 0.098 1 0.003 1 0.029 1 0.183 0.023 1 8.484 1 200.930 Date Lbs/kc Cumulative Ibs/acre Applied 0.050 1 0.011 4.463 0.547 0.245 0.012 0.073 0.473 0.069 19.298 Permit PAN Limit (Ibs/acre) 1st Crop 216 Federal C.P.L.R. (Ibs/acre)**** 36.6 34.8 1,339.0 267.9 15.0 375.0 89.0 2,500.0 YL = YADKINVILLE, NC WWTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penal t r submitting information, including the possibility of fines and imprisonment for ]mowing violations." Q_4_ate SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (1212006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): Facility Name: YADKINVILLE, NO 27.24 Permit #: W00001800 Cation Exchange Capacity (non 503 only): Operator: ROGER FRANK DAVIS ROGER FRANK DAVIS Predominant Soil Series: CLIFFORD Owner: Acres Used: 12.20 Acres Permitted: 12.20 Site #: Field #: NO YK 00035 0001 NO YK 00035 Residual Analysis Data (Heavy Metals and Total Phosphorus use mq/kq, % Solids use Raw Percent #): Source YL Sample or Composite Date 1 1/10/23 2 3 4 5 6 7 8 9 10 11 12 Solids 3.01 Arsenic 4.000 Cadmium 1.200 Copper 390 Chromium 53.00 Lead 22.00 Mercury 0.640 Molybdenum 6.40 Nickel 41.00 Selenium 5.10 Zinc 1900 Total Phosphorus 45000 Annual Heavy Metal Field Loadings (Calculated in Ibs/acre): Source YL Total DT/Ac. / App.Event 1 2.23 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.018 Cadmium 0.005 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 1.741 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 1.741 Chromium 0.237 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.237 Lead 0.098 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.098 Mercury 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molybdenum 0.029 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Nickel 0.183 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.183 Selenium 0.023 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.023 Zinc 8.484 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 8.484 Total Phosphorus 200.930 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 200.930 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penWC7.z bmitting false information, including the possibility of fines and imprisonment for knowing violations". 2-g-2q Signature of Land Applier Date DENR FORM MFLSF (12/2006) FACILITY NAME: YADKINVILLE, NC LAND OWNER: GENEVA & ROGER DAVIS OPERATOR: GENEVA & ROGER DAVIS CROP 1 NAME: FESCUE HAY (FSH) RESIDUAL SOURCE(S): * See list at bottom of report ANNUAL LAND APPLICATION FIELD SUMMARY FORM WQ PERMIT #: W00001800 FIELD#: NC-YK-00035-0-0002- ANNUAL DRY TONS APPLIED: 17.12 SITE #: NC YK 00035 PREDOMINANT SOIL SERIES: CLIFFORD CROP 1 MAX. PAN: 216 CROP 2 NAME: ACRES UTILIZED: 10.1 ACRES PERMITTED: 10.1 CATION EXCHANGE CAPACITY (NON-503): CROP 2 MAX. PAN: Page: 1 Gallons (G) Site W Name of Crop Type or Cubic Yards (Y) Cond. Precip Volati- Mineral- Ammonia Nitrate PAN Applied Receiving Residual Date or or Wet Tons (W) % Residual Dry, Wet, Past 24 Hrs. Application lization ization TKN Nitrogen and Nitrite (Ibs/acre) Application Month Amount I UOM Solids Dry Tons/Ac Source Moist Inches Method* Rate** Rate*** mg/kg mg/kg mg/kg Crop 1 Crop 2 Crop 1 Crop 2 3/23/2023 55,800.00 (G) 3.010 0.693 YL MOIST 0-<1/2" SUR 0.5 0.30 48,000.00 14,000.00 148.80 24.061 FSH 3/27/2023 80,600.00 (G) 3.010 1.002 YL MOIST 0-<1/2"" SUR 0.5 0.30 48,000.00 14,000.00 148.80 34.755 FSH Mar-23 136,400.00 (G) i otai 1.bub Total 58.816 0.000 AS CD I CU CR PB HG MO NI SE ZN P Lime Applied Annual Ibs/acre Applied 0.014 0.004 1.322 0.180 0.075 0.002 0.022 0.139 0.017 6.441 152.559 Date Lbs/Ac Cumulative Ibs/acre Applied 0.025 0.006 3.581 0.317 0.141 0.003 0.035 0.270 0.029 1 11.877 Permit PAN Limit (Ibs/acre) 1st Crop 216 Federal C.P.L.R. (Ibs/acre)**** 36.6 1 34.8 1 1,339.0 I 267.9 1 15.0 I I 375.0 1 89.0 1 2,500.0 YL = YADKINVILLE, NC WWTP LIQUID "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penaltie r submitting false information, including the possibility of fines and imprisonment for ]mowing violations." SIGNATURE OF LAND APPLIER DATE NR = Not Reported or Not Required *** Mineralization Rates: Compost-0.1, Anaerobically digested-0.2, Aerobically digested-0.3, Raw Sludge-0.4 * Application Method: SUR - Surface, INJ - Injection, SURIN - Incorporation **** C.P.L.R.: Cumulative Pollutant Loading Rate ** Volatilization Rate: Surface 0.5, Injection/Incorporation 1.0 ***** See Site pH & Lime Application Records Section of Report Printed: 1/24/2024 DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Total Dry Tons Applied (Annual): Facility Name: YADKINVILLE, NC Permit #: W00001800 Cation Exchange Capacity (non 503 only): Operator: GENEVA & ROGER DAVIS GENEVA & ROGER DAVIS Predominant Soil Series: Owner: Acres Used: 10.10 Acres Permitted: 10.10 Site #: Field #: NC YK 00035 D-LA -i n- rues.,., u.- end T,.MI DA,.QeA,.n.a .sae .....Ib.. a. ... .�.. .... ......... 17.12 CLIFFORD NC YK 00035 0002 Source YL Sample or Composite Date 1 1/10/23 2 3 4 5 6 7 8 9 10 11 12 Solids 3.01 Arsenic 4.000 Cadmium 1.200 Copper 390 Chromium 53.00 Lead 22.00 Mercury 0.640 Molybdenum 6.40 Nickel 41.00 Selenium 5.10 Zinc 1900 Total Phosphorus 45000 Annual Heald Metal Field Loadings (Calculated in Ibs/acre): Source YL Total DT/Ac. / App.Event 1 1.70 2 3 4 5 6 7 8 9 10 11 12 Totals Arsenic 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Cadmium 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 1.322 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.322 Chromium 0.180 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.180 Lead 0.075 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.075 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molybdenum 0.022 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.022 Nickel 0.139 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.139 Selenium 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Zinc 6.441 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 6.441 Total Phosphorus 152.559 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 152.559 "I certify, tinder penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant pe It s for submitting false information, including the possibility of fines and imprisonment for knowing violations". + 2-g^?y Signature of Land Applier Date DENR FORM MFLSF (12/2006) SECTION 4 SUMM111 ENVIRONMENTAL TECHN❑LOMZ3. INC Arraly0ca1 Laboralorfas January 24, 2023 Alex Fox Synagro 284 Boger Rd. Mocksville, NC 27028 TEL: FAX: RE: Yadkinville Dear Alex Fox: Summit Environmental Technologies, Inc. 3310 Win St. Cuyahoga Falls, Ohio 44223 TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Order No.: 23010839 Summit Environmental Technologies, Inc. received 1 sample(s) on 1/13/2023 for the analyses presented in the following report. There were no problems with the analytical events associated with this report unless noted in the Case Narrative. Quality control data is within laboratory defined or method specified acceptance limits except where noted. If you have any questions regarding these tests results, please feel free to call the laboratory. Sincerely, Jennifer Woolf Project Manager 3310 Win St. Cuyahoga Falls, Ohio 44223 Arkansas 88-0735, California 2943, Colorado, Connecticut PH-0108, Florida NELAC E87688, Idaho OH00923, Illinois 200061, Indiana C-OH-13, ISO/IEC 17025:2017 119125 L22-544, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Maryland 339, Michigan 9988, Minnesota 1780279, Nevada 011009232020-1, New Hampshire 2996, New Jersey OH006, New York 11777, North Carolina 39705 and 631, North Dakota R-201, Ohio DW, Ohio VAP CL0052, Oklahoma 2019-155, Oregon OH2O0001, Pennsylvania 68-01335, Rhode Island LA000317, South Carolina 92016001, Texas T104704466-19-16, Utah 011009232020-12, Virginia VELAP 10381, West Virginia 9957C Page 1 of 39 MM' Y Summit Environmental Technologies, Inc. Case Narrative SU3310 Win St. ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 wo#: 23010839 Arralyi9cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com Date: 1/24/2023 CLIENT: Synagro Project: Yadkinville WorkOrder Narrative: 23010839: This report in its entirety consists of the following documents: Cover Letter, Case Narrative, Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody, Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit Environmental Technologies, Inc., Work Order Number assigned to this report. Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program Analytes Report" for accredited analytes list. The information contained in this analytical report is the sole property of Summit Environmental Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results contained in this report are only representative of the samples received. Conditions can vary at different times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible for use or interpretation of the data included herein. All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as "dry weight" using the "-dry" designation on the reporting units. This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any comments or problems with the analytical events associated with this report are noted below. Analytical Sequence Sample Notes: 23010839-OOIA TCLP-SVOC_8270E: Possible low bias for Pyridine due to low recovery in the CCV. Compound demonstrates adequate instrument sensitivity in RLC. 23010839-OOIA TCLP-VOC-MSTR 8260D: CCV/LCS exhibit high recoveries for I,1-Dichloroethene and Vinyl chloride. Investigative sample are non -detect for these compounds. Analytical Sequence QC Notes: MB/LCS-62313 SVOC-BNA_TCLP(8270): Possible low bias for Pyridine due to low recovery in the CCV. RLC demonstrates control for this analyte. Original Page 2 of 39 MM' Summit Environmental Technologies, In Qualifiers and Acronyms SU3310 Win S EkiwllOMM@NTALTECHN❑LOG{r,23.INC Cuyahoga Falls, Ohio442� WO#: 23010839 Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-44E Wehsite: httn:11www.settek.co Date: 1/24/2023 These commonly used Qualifiers and Acronyms may or may not be present in this report. Qualifiers U The compound was analyzed for but was not detected. J The reported value is greater than the Method Detection Limit but less than the Reporting Limit. H The hold time for sample preparation and/or analysis was exceeded. D The result is reported from a dilution. E The result exceeded the linear range of the calibration or is estimated due to interference. MC The result is below the Minimum Compound Limit. The result exceeds the Regulatory Limit or Maximum Contamination Limit. in Manual integration was used to determine the area response. d Manual integration in which peak was deleted N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response. P The second column confirmation exceeded 25% difference. C The result has been confirmed by GC/MS. X The result was not confirmed when GUMS Analysis was performed. B/MB+ The analyte was detected in the associated blank. G The ICB or CCB contained reportable amounts of analyte. QC-/+ The CCV recovery failed low (-) or high (+). R/QDR The RPD was outside of accepted recovery limits. QL-/+ The LCS or LCSD recovery failed low (-) or high (+). QLR The LCS/LCSD RPD was outside of accepted recovery limits. QM-/+ The MS or MSD recovery failed low (-) or high (+). QMR The MS/MSD RPD was outside of accepted recovery limits. QV-/+ The ICV recovery failed low (-) or high (+). S The spike result was outside of accepted recovery limits. Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for additional information Acronyms ND Not Detected RL Reporting Limit QC Quality Control MDL Method Detection Limit MB Method Blank LOD Level of Detection LCS Laboratory Control Sample LOQ Level of Quantitation LCSD Laboratory Control Sample Duplicate PQL Practical Quantitation Limit QCS Quality Control Sample CRQL Contract Required Quantitation Limit DUP Duplicate PL Permit Limit MS Matrix Spike RegLvl Regulatory Limit MSD Matrix Spike Duplicate MCL Maximum Contamination Limit RPD Relative Percent Different MinCL Minimum Compound Limit ICV Initial Calibration Verification RA Reanalysis ICB Initial Calibration Blank RE Reextraction CCV Continuing Calibration Verification TIC Tentatively Identified Compound CCB Continuing Calibration Blank RT Retention Time PLC Reporting Limit Check CF Calibration Factor DF Dilution Factor RF Response Factor This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting. Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this list or for additional information regarding the use of these Qualifiers on reported data. Original Page 3 of 39 �� 1 � Summit Environmental Technologies, Inc. SU3310 Win St. ENVIROMMEWAL YECHNO ijULES. JNG, Cuyahoga Falls, Ohio 44223 Analytical Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com CLIENT: Synagro Project: Yadkinville Lab SampleID Client Sample ID 23010839-001 Yadkinville Tag No Date Collected 1/10/2023 10:00:00 AM Workorder Sample Summary WO#: 23010839 24 Jan-23 Date Received Matrix 1/13/2023 10:20:00 AM Solid Page 4 of 39 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. DATES R PORT ENVIRONMENTALTECHN❑L0G1ES,11+1C Cuyahoga Falls, Ohio44223 WO#: 23010839 ArWyft cal Laboraloriag TEL: (330) 253-8211 FAX.- (330) 253-4489 Wehsite: http://www.settek.com 24-Jan-23 Client: Synagro Project: Yadlcinville Sample ID Client Sample ID Collection Date Matrix Test Name Leachate Date Prep Date Analysis Date 23010839-OOIA Yadkinville 1/10/2023 10:00:00 AM Solid Ignitability of Solids (SW-846: 1030) 1/18/2023 7:17:11 PM pH (SW9045D) 1/20/2023 4:11:32 PM Reactive Cyanide (9014/7.3.3.2)-Solid 1/23/2023 1:45:00 PM Reactive Sulfide (9034)/7.3.4.2 1/23/2023 1:45:00 PM TCLP Herbicides by EPA 8321B 1/18/2023 7:52:00 PM TCLP Mercury Analysis (SW1311/7471/17/2023 4:15:00 PM 1/18/2023 2:30:00 PM 1/19/2023 11:01:00 AM TCLP Metals Analysis (SW1311/6010:1/17/2023 4:15:00 PM 1/18/2023 2:00:00 PM 1/19/2023 2:04:00 PM TCLP Pesticides Analysis (SW1311/8(1/17/2023 4:15:00 PM 1/18/2023 10:31:44 AM 1/19/2023 4:04:00 AM TCLP Pesticides Analysis (SW1311/8(1/17/2023 4:15:00 PM 1/18/2023 10:31:44 AM 1/19/2023 4:04:00 AM TCLP Semi-Volatiles Analysis 1/17/2023 4:15:00 PM 1/19/2023 10:40:00 AM 1/20/2023 10:07:00 PM (SW1311/8270) TCLP Volatiles Analysis 1/23/2023 3:23:00 PM Original Page 5 of 39 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNQLOGIE$,IRC Cuyahoga Falls, Ohio44223 Arralyt9cal Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.coin Analytical Report (base report) WO#: 23010839 Date Reported: 1/24/2023 CLIENT: Synagro Tag Number: Matrix: SOLID Collection Date: 1/10/2023 10:00:00 AM Lab ID: 23010839-OOIA Project: Yadkinville Client Sample ID Yadkinville Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID TCLP MERCURY ANALYSIS (SW1311/7470) TCLP Mercury ND 0.00200 mg/L SW7470A SW7470A Analyst: ICA 1 1/19/2023 11:01:00 AM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW6010 SW301OA Analyst: RJE TCLP METALS ANALYSIS (SW1311/6010) TCLP Arsenic(As) ND 0.500 mg/L 1 1/19/2023 2:04:00 PM TCLP Barium(Ba) ND 5.00 mg/L 1 1/19/2023 2:04:00 PM TCLP Cadmium(Cd) ND 0.100 mg/L 1 1/19/2023 2:04:00 PM TCLP Chromium(Cr) ND 0.200 mg/L 1 1/19/2023 2:04:00 PM TCLP Lead(Pb) ND 0.500 mg/L 1 1/19/2023 2:04:00 PM TCLP Selenium(Se) ND 0.0500 mg/L 1 1/19/2023 2:04:00 PM TCLP Silver(Ag) ND 0.500 mg/L 1 1/19/2023 2:04:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8270 SW351OC Analyst: JAP TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270) 1,4-Dichlorobenzene ND 0.100 mg/L 1 1/20/2023 10:07:00 PM 2,4,5-Trichlorophenol ND 0.250 mg/L 1 1/20/2023 10:07:00 PM 2,4,6-Trichlorophenol ND 0.250 mg/L 1 1/20/2023 10:07:00 PM 2,4-Dinitrotoluene ND 0.0500 mg/L 1 1/20/2023 10:07:00 PM Cresols, Total ND 5.00 mg/L 1 1/20/2023 10:07:00 PM Hexachloro-1,3-butadiene ND 0.0200 mg/L 1 1/20/2023 10:07:00 PM Hexachlorobenzene ND 0.0500 mg/L 1 1/20/2023 10:07:00 PM Hexachloroethane ND 0.100 mg/L 1 1/20/2023 10:07:00 PM Nitrobenzene ND 0.100 mg/L 1 1/20/2023 10:07:00 PM Pentachlorophenol ND 0.250 mg/L 1 1/20/2023 10:07:00 PM Pyridine ND 0.250 QC- mg/L 1 1/20/2023 10:07:00 PM Surr: 2-Fluorophenol 74.8 10 - 157 %Rec 1 1/20/2023 10:07:00 PM Surr: Phenol-d6 83.1 10 - 169 %Rec 1 1/20/2023 10:07:00 PM Surr: Nitrobenzene-d5 74.5 32.1 - 130 %Rec 1 1/20/2023 10:07:00 PM Surr: 2,4,6-Tribromophenol 97.9 45.4 - 166 %Rec 1 1/20/2023 10:07:00 PM Surr: 2-Fluorobiphenyl 79.7 35.7 - 130 %Rec 1 1/20/2023 10:07:00 PM Surr: p-Terphenyl-d14 93.3 70 - 145 %Rec 1 1/20/2023 10:07:00 PM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit Page 6 of 39 SUMMIT Summit Environmental Technologies, Inc. 3310 Win St. ENVIRONMENTAL TECHNQLOGIE$,IRC Cuyahoga Falls, Ohio44223 Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 Website: http://�i,-"-m,.settek.coin Analytical Report (base report) WO#: 23010839 Date Reported: 1/24/2023 CLIENT: Synagro Tag Number: Matrix: SOLID Collection Date: 1/10/2023 10:00:00 AM Lab ID: 23010839-OOIA Project: Yadkinville Client Sample ID Yadkinville Analyses Result RL Qual Units DF Date Analyzed TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8081 SW351OC Analyst: PGP TCLP PESTICIDES ANALYSIS (SW1311/8081) Chlordane, total ND 0.00250 mg/L 1 1/19/2023 4:04:00 AM Toxaphene ND 0.00500 mg/L 1 1/19/2023 4:04:00 AM Endrin ND 0.000500 mg/L 1 1/19/2023 4:04:00 AM gamma-BHC ND 0.000500 mg/L 1 1/19/2023 4:04:00 AM Heptachlor ND 0.000500 mg/L 1 1/19/2023 4:04:00 AM Heptachlor epoxide ND 0.000500 mg/L 1 1/19/2023 4:04:00 AM Methoxychlor ND 0.000500 mg/L 1 1/19/2023 4:04:00 AM Surr: TCMX 45.6 10 - 119 %Rec 1 1/19/2023 4:04:00 AM Surr: DCB 50.2 10 - 119 %Rec 1 1/19/2023 4:04:00 AM TCLP HERBICIDES BY EPA 8321B SW8321 Analyst: SRA 2,4-D ND 0.500 mg/L 50 1/18/2023 7:52:00 PM 2,4,5-TP ND 0.500 mg/L 50 1/18/2023 7:52:00 PM Surr: 2,4-Dichlorophenylacetic aci 76.2 70 - 130 %Rec 50 1/18/2023 7:52:00 PM TCLP METALS, VOC, BNA, PEST, HERB -SOLID SW8260 Analyst: EMB TCLP VOLATILES ANALYSIS 1,1-Dichloroethene ND 0.100 QC+ mg/L 20 1/23/2023 3:23:00 PM 1,2-Dichloroethane ND 0.100 mg/L 20 1/23/2023 3:23:00 PM MEK ND 2.00 mg/L 20 1/23/2023 3:23:00 PM Benzene ND 0.100 mg/L 20 1/23/2023 3:23:00 PM Carbon tetrachloride ND 0.100 mg/L 20 1/23/2023 3:23:00 PM Chlorobenzene ND 1.00 mg/L 20 1/23/2023 3:23:00 PM Chloroform ND 0.100 mg/L 20 1/23/2023 3:23:00 PM Tetrachloroethene ND 0.100 mg/L 20 1/23/2023 3:23:00 PM Trichloroethene ND 0.100 mg/L 20 1/23/2023 3:23:00 PM Vinyl chloride ND 0.0400QC+QL+mg/L 20 1/23/2023 3:23:00 PM Surr: 4-Bromofluorobenzene 90.5 70 - 130 %Rec 20 1/23/2023 3:23:00 PM Surr: Di brom ofl uorom ethane 99.0 70 - 130 %Rec 20 1/23/2023 3:23:00 PM Surr: Toluene-d8 106 70 - 130 %Rec 20 1/23/2023 3:23:00 PM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit Page 7 of 39 MMIT Summit Environmental Technologies, Inc. Analytical Report SU3310 Win St. ENVIRONMENTAL TECHNOLOGIE_3, IRC Cuyahoga Falls, Ohio 44223 (base report) Arrafyt9caf Laboralorfas TEL: (330) 253-8211 FAX. (330) 253-4489 WO#: 23010839 Website: http://www.settek.com Date Reported: 1/24/2023 CLIENT: Synagro Tag Number: Matrix: SOLID Collection Date: 1/10/2023 10:00:00 AM Lab ID: 23010839-OOIA Project: Yadkinville Client Sample ID Yadkinville Analyses Result RL Qual Units DF Date Analyzed RCI SW9014 Analyst: MS REACTIVE CYANIDE (9014/7.3.3.2)-SOLID Cyanide, Reactive ND 0.495 mg/Kg 1 1/23/2023 1:45:00 PM IGNITABILITY OF SOLIDS (SW-846: 1030) SW1030 Analyst: SMZ Ignitability Non-flammable mm/sec 1 1/18/2023 7:17:11 PM RCI SW9045D Analyst: SMZ PH (SW9045D) pH 7.4 s.u.@20.9C 1 1/20/20234:11:32 PM RCI SW9034 Analyst: MS REACTIVE SULFIDE (9034)/7.3.4.2 Sulfide, Reactive ND 25.0 mg/Kg 1 1/23/2023 1:45:00 PM Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or analysis exceeded M Manual Integration used to determine area response MC Value is below Minimum Compound Limit. N Tentatively identified compounds ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit Original R RPD outside accepted recovery limits RL Reporting Detection Limit Page 8 of 39 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Analv n tes Report ENwIROMMEWALYECHNOL.OG{r,S,INC Cuyahoga Falls, Ohio44223 J Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 23010839 Wehsite: http://www.settek.com 24 Jan-23 Client: Synagro State: NW Project: Yadkinville Program Name: NC_WW_SCM Sample ID Matrix Test Name Analyte Status 23010839-OOIA Solid Ignitability of Solids (SW-846: 1030) Ignitability A Solid pH (SW9045D) Hydrogen Ion (pH) A Solid Reactive Cyanide (9014/7.3.3.2)-Solid Cyanide, Reactive U Solid Reactive Sulfide (9034)/7.3.4.2 Sulfide, Reactive U Solid TCLP Herbicides by EPA 8321B 2,4,5-TP A Solid TCLP Herbicides by EPA 8321B 2,4-D A Solid TCLP Mercury Analysis (SW1311/7470) Mercury A Solid TCLP Metals Analysis (SW1311/6010) Arsenic A Solid TCLP Metals Analysis (SW1311/6010) Barium A Solid TCLP Metals Analysis (SW1311/6010) Cadmium A Solid TCLP Metals Analysis (SW1311/6010) Chromium A Solid TCLP Metals Analysis (SW1311/6010) Lead A Solid TCLP Metals Analysis (SW1311/6010) Selenium A Solid TCLP Metals Analysis (SW1311/6010) Silver A Solid TCLP Pesticides Analysis (SW1311/8081) Chlordane, total A Solid TCLP Pesticides Analysis (SW1311/8081) Endrin A Solid TCLP Pesticides Analysis (SW1311/8081) gamma-BHC A Solid TCLP Pesticides Analysis (SW1311/8081) Heptachlor A Solid TCLP Pesticides Analysis (SW1311/8081) Heptachlor epoxide A Solid TCLP Pesticides Analysis (SW1311/8081) Methoxychlor A Solid TCLP Pesticides Analysis (SW1311/8081) Toxaphene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 1,4-Dichlorobenzene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,5-Trichlorophenol A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4,6-Trichlorophenol A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) 2,4-Dinitrotoluene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Cresols, Total A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobenzene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachlorobutadiene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Hexachloroethane A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Nitrobenzene A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Pentachlorophenol A Solid TCLP Semi-Volatiles Analysis (SW1311/8270) Pyridine A Original #1 Page 9 of 39 Summit Environmental Technologies, Inc. Accreditation Program SUMMIEF fr3310 Win St. Analv n tes Report ENVIROMMEWAL YECHHOL.OG{r,S, INC Cuyahoga Falls, Ohio 44223 J Y Arraly0cal Laboralorlas TEL: (330) 253-8211 FAX.- (330) 253-4489 WO#: 23010839 Wehsite: http://www.settek.com 24 Jan-23 Client: Synagro State: NW Project: Yadkinville Program Name: NC_WW_SCM Sample ID Matrix Test Name Analyte Status 23010839-OOIA Solid TCLP Volatiles Analysis 1,1-Dichloroethene A Solid TCLP Volatiles Analysis 1,2-Dichloroethane A Solid TCLP Volatiles Analysis 2-Butanone A Solid TCLP Volatiles Analysis Benzene A Solid TCLP Volatiles Analysis Carbon tetrachloride A Solid TCLP Volatiles Analysis Chlorobenzene A Solid TCLP Volatiles Analysis Chloroform A Solid TCLP Volatiles Analysis Tetrachloroethene A Solid TCLP Volatiles Analysis Trichloroethene A Solid TCLP Volatiles Analysis Vinyl chloride A Original #1 Page 10 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://nnn.settek.com QC SUMMARY REPORT WO#: 23010839 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: 62279 Sample ID: MB-62279 SampType: MBLK TestCode: TCLP-SVOC- Units: mg/L Prep Date: 1/18/2023 RunNo: 156731 Client ID: PBS Batch ID: 62279 TestNo: SW8081 SW3510C Analysis Date: 1/18/2023 SegNo: 4172749 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, total ND 0.00250 Toxaphene ND 0.00500 Endrin ND 0.000500 gamma-BHC ND 0.000500 Heptachlor ND 0.000500 Heptachlor epoxide ND 0.000500 Methoxychlor ND 0.000500 Surr: TCMX 11.7 Surr: DCB 11.6 20.00 58.4 10 119 20.00 57.8 10 119 Sample ID: LCS-62279 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 1/18/2023 RunNo: 156731 Client ID: LCSS Batch ID: 62279 TestNo: SW8081 SW3510C Analysis Date: 1/18/2023 SegNo: 4172750 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Chlordane, tot Toxaphene Endrin gamma-BHC Heptachlor Heptachlor epo Methoxychlor Surr: TCMX Qualifiers: al 0.0183 0.0 ND 0.0 0.0108 0.00 0.00848 0.00 0.0103 0.00 xide 0.00917 0.00 0.0114 0.00 12.0 B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit 0250 0 0 70 0500 0 0 70 0500 0.0100 0 108 10 0500 0.0100 0 84.8 10 0500 0.0100 0 103 10 0500 0.0100 0 91.7 10 0500 0.0100 0 114 10 20.00 60.1 10 E Value above quantitation range M Manual Integration used to determine area response OG 1 R RPD outside accepted recovery limits 130 130 130 130 130 130 178 130 H Holding times for preparation or anal MC Value is below Minimum Compound P Second column confirmation exceeds RL Reporting Detection Limit Original Page 11 of 39 B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit 0250 0 0 70 0500 0 0 70 0500 0.0100 0 108 10 0500 0.0100 0 84.8 10 0500 0.0100 0 103 10 0500 0.0100 0 91.7 10 0500 0.0100 0 114 10 20.00 60.1 10 E Value above quantitation range M Manual Integration used to determine area response OG 1 R RPD outside accepted recovery limits 130 130 130 130 130 130 178 130 H Holding times for preparation or anal MC Value is below Minimum Compound P Second column confirmation exceeds RL Reporting Detection Limit Original Page 11 of 39 130 130 130 130 130 130 178 130 H Holding times for preparation or anal MC Value is below Minimum Compound P Second column confirmation exceeds RL Reporting Detection Limit Original Page 11 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010839 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: 62279 Sample ID: LCS-62279 SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: 1/18/2023 RunNo: 156731 Client ID: LCSS Batch ID: 62279 TestNo: SW8081 SW3510C Analysis Date: 1/18/2023 SegNo: 4172750 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Surr: DCB 8.64 20.00 43.2 10 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 12 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010839 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: 62288 Sample ID: 23010844-001AMS SampType: MS TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 1/18/2023 RunNo: 156724 Client ID: Batch= Batch ID: 62288 TestNo: SW6010 SW3010A Analysis Date: 1/19/2023 SegNo: 4174124 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.06 0.500 2.000 0 103 70 130 TCLP Barium(Ba) ND 5.00 2.000 0.1455 100 70 130 TCLP Cadmium(Cd) 1.78 0.100 2.000 0 89.2 70 130 TCLP Chromium(Cr) 1.81 0.200 2.000 0.002100 90.3 70 130 TCLP Lead(Pb) 1.81 0.500 2.000 0 90.4 70 130 TCLP Selenium(Se) 1.98 0.0500 2.000 0 99.1 70 130 TCLP Silver(Ag) 2.06 0.500 2.000 0 103 70 130 Sample ID: 23010844-001AMSD SampType: MSD TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 1/18/2023 RunNo: 156724 Client ID: Batch= Batch ID: 62288 TestNo: SW6010 SW3010A Analysis Date: 1/19/2023 SegNo: 4174125 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 1.96 0.500 2.000 0 98.2 70 130 2.058 4.72 20 TCLP Barium(Ba) ND 5.00 2.000 0.1455 95.0 70 130 0 0 20 TCLP Cadmium(Cd) 1.71 0.100 2.000 0 85.5 70 130 1.784 4.22 20 TCLP Chromium(Cr) 1.72 0.200 2.000 0.002100 85.8 70 130 1.807 5.08 20 TCLP Lead(Pb) 1.73 0.500 2.000 0 86.6 70 130 1.809 4.34 20 TCLP Selenium(Se) 1.90 0.0500 2.000 0 94.9 70 130 1.982 4.35 20 TCLP Silver(Ag) 1.96 0.500 2.000 0 98.2 70 130 2.056 4.63 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 13 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010839 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: 62288 Sample ID: MB-62288 SampType: MBLK TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 1/18/2023 RunNo: 156724 Client ID: PBS Batch ID: 62288 TestNo: SW6010 SW3010A Analysis Date: 1/19/2023 SegNo: 4173032 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) ND 0.100 TCLP Barium(Ba) ND 5.00 TCLP Cadmium(Cd) ND 0.100 TCLP Chromium(Cr) ND 0.200 TCLP Lead(Pb) ND 0.100 TCLP Selenium(Se) ND 0.100 TCLP Silver(Ag) ND 0.100 Sample ID: LCS-62288 SampType: LCS TestCode: MTL-TCLP-7( Units: mg/L Prep Date: 1/18/2023 RunNo: 156724 Client ID: LCSS Batch ID: 62288 TestNo: SW6010 SW3010A Analysis Date: 1/19/2023 SegNo: 4173033 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual TCLP Arsenic(As) 2.14 0.100 2.000 0 107 80 120 TCLP Barium(Ba) ND 5.00 2.000 0 103 80 120 TCLP Cadmium(Cd) 2.01 0.100 2.000 0 100 80 120 TCLP Chromium(Cr) 2.03 0.200 2.000 0 101 80 120 TCLP Lead(Pb) 2.04 0.100 2.000 0 102 80 120 TCLP Selenium(Se) 1.97 0.100 2.000 0 98.6 80 120 TCLP Silver(Ag) 2.11 0.100 2.000 0 106 80 120 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 14 of 39 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010839 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: 62305 TCLP Mercury ND 0.00200 TCLP Mercury 0.00407 0.00200 0.00400 0 102 80 120 TCLP Mercury 0.00413 0.00200 0.00400 0.0000230 103 75 125 Sample ID: 23010844-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/18/2023 RunNo: 156722 Client ID: Batch= Batch ID: 62305 TestNo: SW7470A SW7470A Analysis Date: 1/19/2023 SegNo: 4172607 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual TCLP Mercury 0.00419 0.00200 0.00400 0.0000230 104 75 125 0.00413 1.44 20 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 15 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT Client: Synagro Project: Yadkinville BatchID: 62305 WO#: 23010839 24-Jan-23 Sample ID: 23010844-001AMSD SampType: MSD TestCode: HG_TCLP(74 Units: PPM Prep Date: 1/18/2023 RunNo: 156722 Dient ID: Batch= Batch ID: 62305 TestNo: SW7470A SW7470A Analysis Date: 1/19/2023 SegNo: 4172607 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 16 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT Client: Synagro Project: Yadkinville BatchID: 62313 WO#: 23010839 24-Jan-23 Sample ID: 23010844-001AMS SampType: MS TestCode: TCLP-SVOC_ Units: mg/L Prep Date: 1/19/2023 RunNo: 156871 client ID: BatchQC Batch ID: 62313 TestNo: SW8270 SW3510C Analysis Date: 1/20/2023 SegNo: 4175972 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.475 0.100 0.8000 0 59.4 15.2 124 2,4,5-Trichlorophenol 0.802 0.250 0.8000 0 100 30.6 152 2,4,6-Trichlorophenol 0.815 0.250 0.8000 0 102 27.6 150 2,4-Dinitrotoluene 0.760 0.0500 0.8000 0 95.0 58 141 o-Cresol 0.654 0.250 0.8000 0 81.8 26.9 132 Cresols, Total ND 5.00 1.600 0 83.4 27.6 132 Hexachloro-1,3-butadiene 0.533 0.0200 0.8000 0 66.6 10 156 Hexachlorobenzene 0.742 0.0500 0.8000 0 92.8 54.3 142 Hexachloroethane 0.465 0.100 0.8000 0 58.1 1.92 131 Nitrobenzene 0.653 0.100 0.8000 0 81.6 21 135 Pentachlorophenol 0.762 0.250 0.8000 0 95.2 47.4 134 Pyridine 0.422 0.250 0.8000 0 52.7 10 130 Surr:2-Fluorophenol 0.726 1.000 72.6 9.77 146 Surr: Phenol-d6 0.758 1.000 75.8 20.7 130 Surr: Nitrobenzene-d5 0.646 1.000 64.6 13.9 156 Surr:2,4,6-Tribromophenol 1.08 1.000 108 27.3 183 Surr:2-Fluorobiphenyl 0.709 1.000 70.9 21.4 153 Surr: p-Terphenyl-d14 0.883 1.000 88.3 54.8 154 QC - Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 17 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT Client: Synagro Project: Yadkinville BatchID: 62313 WO#: 23010839 24-Jan-23 Sample ID: 23010844-001AMSD SampType: MSD TestCode: TCLP-SVOC_ Units: mg/L Prep Date: 1/19/2023 RunNo: 156871 Dient ID: Batch= Batch ID: 62313 TestNo: SW8270 SW3510C Analysis Date: 1/20/2023 SegNo: 4175973 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.470 0.100 0.8000 0 58.8 15.2 124 0.4750 1.06 30 2,4,5-Trichlorophenol 0.857 0.250 0.8000 0 107 30.6 152 0.8018 6.70 30 2,4,6-Trichlorophenol 0.872 0.250 0.8000 0 109 27.6 150 0.8152 6.71 30 2,4-Dinitrotoluene 0.827 0.0500 0.8000 0 103 58 141 0.7602 8.39 30 o-Cresol 0.686 0.250 0.8000 0 85.8 26.9 132 0.6544 4.74 30 Cresols, Total ND 5.00 1.600 0 88.5 27.6 132 0 0 30 Hexachloro-1,3-butadiene 0.540 0.0200 0.8000 0 67.5 10 156 0.5330 1.27 30 Hexachlorobenzene 0.832 0.0500 0.8000 0 104 54.3 142 0.7424 11.4 30 Hexachloroethane 0.460 0.100 0.8000 0 57.5 1.92 131 0.4650 1.08 30 Nitrobenzene 0.668 0.100 0.8000 0 83.5 21 135 0.6528 2.27 30 Pentachlorophenol 0.846 0.250 0.8000 0 106 47.4 134 0.7618 10.5 30 Pyridine 0.416 0.250 0.8000 0 52.0 10 130 0.4218 1.43 30 Surr:2-Fluorophenol 0.705 1.000 70.5 9.77 146 0 Surr: Phenol-d6 0.806 1.000 80.6 20.7 130 0 Surr: Nitrobenzene-d5 0.693 1.000 69.3 13.9 156 0 Surr:2,4,6-Tribromophenol 1.16 1.000 116 27.3 183 0 Surr:2-Fluorobiphenyl 0.794 1.000 79.4 21.4 153 0 Surr: p-Terphenyl-d14 0.950 1.000 95.0 54.8 154 0 QC - Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 18 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT Client: Synagro Project: Yadkinville BatchID: 62313 WO#: 23010839 24-Jan-23 Sample ID: MB-62313 SampType: MBLK TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/19/2023 RunNo: 156871 client ID: PBS Batch ID: 62313 TestNo: SW8270 SW3510C Analysis Date: 1/20/2023 SegNo: 4175949 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene ND 0.0250 2,4,5-Trichlorophenol ND 0.0250 2,4,6-Trichlorophenol ND 0.0250 2,4-Dinitrotoluene ND 0.0250 o-Cresol ND 0.250 Cresols, Total ND 0.0500 Hexachloro-1,3-butadiene ND 0.0250 Hexachlorobenzene ND 0.0250 Hexachloroethane ND 0.0250 Nitrobenzene ND 0.0250 Pentachlorophenol ND 0.0250 Pyridine ND 0.0250 Surr: 2-Fluorophenol 0.735 Surr: Phenol-d6 0.858 Surr: Nitrobenzene-d5 0.727 Surr: 2,4,6-Tribromophenol 1.03 Surr: 2-Fluorobiphenyl 0.800 Surr: p-Terphenyl-d14 1.02 1.000 73.5 10 135 1.000 85.8 10 161 1.000 72.7 16.8 150 1.000 103 32.5 179 1.000 80.0 34 133 1.000 102 60.8 163 QC - Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 19 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT Client: Synagro Project: Yadkinville BatchID: 62313 WO#: 23010839 24-Jan-23 Sample ID: LCS-62313 SampType: LCS TestCode: SVOC-BNA_T Units: mg/L Prep Date: 1/19/2023 RunNo: 156871 client ID: LCSS Batch ID: 62313 TestNo: SW8270 SW3510C Analysis Date: 1/20/2023 SegNo: 4175950 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 1,4-Dichlorobenzene 0.463 0.0250 0.8000 0 57.8 35 130 2,4,5-Trichlorophenol 0.858 0.0250 0.8000 0 107 44 144 2,4,6-Trichlorophenol 0.873 0.0250 0.8000 0 109 45 141 2,4-Dinitrotoluene 0.845 0.0250 0.8000 0 106 56 136 o-Cresol 0.729 0.250 0.8000 0 91.1 36 134 Cresols, Total 1.48 0.0500 1.600 0 92.5 36 135 Hexachloro-1,3-butadiene 0.547 0.0250 0.8000 0 68.4 30 130 Hexachlorobenzene 0.825 0.0250 0.8000 0 103 58 130 Hexachloroethane 0.448 0.0250 0.8000 0 56.0 28 130 Nitrobenzene 0.698 0.0250 0.8000 0 87.3 39 133 Pentachlorophenol 0.849 0.0250 0.8000 0 106 33 151 Pyridine 0.191 0.0250 0.8000 0 23.9 10 130 Surr: 2-Fluorophenol 0.742 1.000 74.2 10 135 Surr: Phenol-d6 0.844 1.000 84.4 10 161 Surr: Nitrobenzene-d5 0.739 1.000 73.9 16.8 150 Surr:2,4,6-Tribromophenol 1.20 1.000 120 32.5 179 Surr:2-Fluorobiphenyl 0.834 1.000 83.4 34 133 Surr: p-Terphenyl-d14 0.963 1.000 96.3 60.8 163 QC - Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 20 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010839 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156695 Sample ID: LCS-R156695 SampType: LCS TestCode: Ignitability_S Units: mm/sec Prep Date: RunNo: 156695 Client ID: LCSS Batch ID: R156695 TestNo: SW1030 Analysis Date: 1/18/2023 SegNo: 4171894 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Ignitability 7.69 7.240 0 106 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 21 of 39 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010839 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156776 2,4-D ND 0.0100 2,4,5-TP ND 0.0100 Surr: 2,4-Dichlorophenylacetic acid 0.732 1.000 73.2 70 130 2,4-D 0.0120 0.0100 0.01000 0 120 50 150 2,4,5-TP ND 0.0100 0.01000 0 0 50 150 S Surr: 2,4-Dichlorophenylacetic acid 0.00870 0.01000 87.0 70 130 Sample ID: LCS TCLP 0.3 ppm SampType: LCS TestCode: TCLP-SVOC- Units: mg/L Prep Date: RunNo: 156776 Client ID: LCSS Batch ID: R156776 TestNo: SW8321 Analysis Date: 1/18/2023 SegNo: 4173531 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 2,4-D 0.274 0.0100 0.3000 0 91.3 60.5 141 2,4,5-TP 0.267 0.0100 0.3000 0 88.9 68.3 144 Surr: 2,4-Dichlorophenylacetic acid 0.267 0.3000 89.1 70 130 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 22 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010839 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156776 Sample ID: LCSD TCLP 0.3 ppm SampType: LCSD TestCode: TCLP-SVOC- Units: mg/L Prep Date: RunNo: 156776 Client ID: LCSS02 Batch ID: R156776 TestNo: SW8321 Analysis Date: 1/18/2023 SegNo: 4173533 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual 2,4-D 0.292 0.0100 0.3000 0 97.5 60.5 141 0.2740 6.53 30 2,4,5-TP 0.292 0.0100 0.3000 0 97.5 68.3 144 0.2666 9.23 30 Surr: 2,4-Dichlorophenylacetic acid 0.293 0.3000 97.7 70 130 0 0 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range M Manual Integration used to determine area response OG 1 R RPD outside accepted recovery limits Page 23 of 39 H Holding times for preparation or anal MC Value is below Minimum Compound P Second column confirmation exceeds RL Reporting Detection Limit Original SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010839 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156838 pH 7.0 7.0 0 100 90 110 pH 12.5 0 0 0 0 12.5 0.2 10 pH 7.0 7.0 0 100 90 110 Sample ID: 23011173-001ADUP SampType: DUP TestCode: pH_S(9045D) Units: s.u.@20.5C Prep Date: RunNo: 156838 Client ID: Batch= Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175312 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 6.5 0 0 0 0 6.4 0.6 10 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 24 of 39 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010839 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156838 pH 7.0 7.0 0 100 90 110 pH 7.6 0 0 0 0 7.6 0 10 Sample ID: LCS-R156838 SampType: LCS TestCode: pH_S(9045D) Units: s.u.@20.5C Prep Date: RunNo: 156838 Client ID: LCSS Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175326 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 7.0 7.0 0 101 90 110 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 25 of 39 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010839 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156838 pH 7.0 7.0 0 100 98.6 101.4 pH 6.9 6.9 0.4 5 H pH 7.0 7.0 0 100 98.6 101.4 Sample ID: 23010912-001ADUP SampType: DUP TestCode: pH_NPW(450 Units: s.u.@19.7C Prep Date: RunNo: 156838 Client ID: Batch= Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175285 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual pH 6.3 6.3 0.5 5 H Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 26 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010839 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156838 Sample ID: 23010912-001ADUP SampType: DUP TestCode: pH_NPW(450 Units: s.u.@19.7C Prep Date: RunNo: 156838 Dient ID: Batch= Batch ID: R156838 TestNo: SW9045D Analysis Date: 1/20/2023 SegNo: 4175285 4nalyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 27 of 39 SUMM' T Summit Environmental Technologies, Inc. 3310 Win St. QC SUMMARY REPORT ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010839 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156913 Cyanide, Reactive ND 0.495 Cyanide, Reactive 9.17 0.500 10.00 0 91.7 85 115 Cyanide, Reactive ND 0.481 0.5000 0 62.0 50 150 Sample ID: 23010840-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 156913 Client ID: Batch= Batch ID: R156913 TestNo: SW9014 Analysis Date: 1/23/2023 SegNo: 4176952 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 7.77 0.495 10.00 0 77.7 75 125 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 28 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010839 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156913 Sample ID: 23010840-001AMS SampType: MS TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 156913 Client ID: Batch= Batch ID: R156913 TestNo: SW9014 Analysis Date: 1/23/2023 SegNo: 4176952 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sample ID: 23010840-001AMSD SampType: MSD TestCode: Cyanide,Rea Units: mg/Kg Prep Date: RunNo: 156913 Client ID: Batch= Batch ID: R156913 TestNo: SW9014 Analysis Date: 1/23/2023 SegNo: 4176953 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Cyanide, Reactive 8.43 0.495 10.00 0 84.3 75 125 7.772 8.19 10 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound OG1 P Second column confirmation exceeds R RPD outside accepted recovery limits RL Reporting Detection Limit Original Page 29 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010839 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156917 Sample ID: 23010840-001AMS SampType: MS TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 156917 Client ID: Batch= Batch ID: R156917 TestNo: SW9034 Analysis Date: 1/23/2023 SegNo: 4177055 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 1590 25.0 1710 0 93.0 80 120 Sample ID: 23010840-001AMSD SampType: MSD TestCode: Sulfide,React Units: mg/Kg Prep Date: RunNo: 156917 Client ID: Batch= Batch ID: R156917 TestNo: SW9034 Analysis Date: 1/23/2023 SegNo: 4177056 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 1660 25.0 1710 0 97.1 80 120 1590 4.31 30 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound OG1 P Second column confirmation exceeds R RPD outside accepted recovery limits RL Reporting Detection Limit Original Page 30 of 39 MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT SU3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 WO#: 23010839 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://www.settek.com 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156917 Sample ID: MB-R156917 SampType: MBLK TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 156917 Client ID: PBW Batch ID: R156917 TestNo: SW9034 Analysis Date: 1/23/2023 SegNo: 4177039 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive ND 25.0 Sample ID: LCS-R156917 SampType: LCS TestCode: Sulfide,React Units: mg/L Prep Date: RunNo: 156917 Client ID: LCSW Batch ID: R156917 TestNo: SW9034 Analysis Date: 1/23/2023 SegNo: 4177040 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Sulfide, Reactive 1670 25.0 1710 0 97.7 85 115 Qualifiers: B Analyte detected in the associated Method Blank J Analyte detected below quantitation limits ND Not Detected PL Permit Limit E Value above quantitation range H Holding times for preparation or anal M Manual Integration used to determine area response MC Value is below Minimum Compound OG1 P Second column confirmation exceeds R RPD outside accepted recovery limits RL Reporting Detection Limit Original Page 31 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010839 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156931 Sample ID: LCS SampType: LCS TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 156931 Client ID: LCSW Batch ID: R156931 TestNo: SW8260 Analysis Date: 1/23/2023 SegNo: 4177590 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1, 1 -Dichloroethene 0.0238 0.00500 0.0200 0 119 49 161 QC+ 1,2-Dichloroethane 0.0206 0.00500 0.0200 0 103 48 151 MEK 0.124 0.0250 0.100 0 124 10 190 Benzene 0.0222 0.00500 0.0200 0 ill 34 169 Carbon tetrachloride 0.0203 0.00500 0.0200 0 101 76 134 Chlorobenzene 0.0200 0.00500 0.0200 0 99.8 54 144 Chloroform 0.0203 0.00500 0.0200 0 102 70 130 Tetrachloroethene 0.0189 0.00500 0.0200 0 94.4 66 134 Trichloroethene 0.0201 0.00500 0.0200 0 101 70 136 Vinyl chloride 0.0340 0.00200 0.0200 0 170 49 136 SQC+ Surr:4-Bromofluorobenzene 46.9 50.00 93.8 70 130 Surr: Dibromofluoromethane 49.8 50.00 99.7 70 130 Surr: Toluene-d8 53.1 50.00 106 70 130 Sample ID: MBLK SampType: MBLK TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 156931 Client ID: PBW Batch ID: R156931 TestNo: SW8260 Analysis Date: 1/23/2023 SegNo: 4177592 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene ND 0.00500 QC+ 1,2-Dichloroethane ND 0.00500 MEK ND 0.0250 Benzene ND 0.00500 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 32 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010839 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156931 Sample ID: MBLK SampType: MBLK TestCode: VOC-MSTR_ Units: mg/L Prep Date: RunNo: 156931 Client ID: PBW Batch ID: R156931 TestNo: SW8260 Analysis Date: 1/23/2023 SegNo: 4177592 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride ND 0.00500 Chlorobenzene ND 0.00500 Chloroform ND 0.00500 Tetrachloroethene ND 0.00500 Trichloroethene ND 0.00500 Vinyl chloride ND 0.00200 Surr: 4-Bromofluorobenzene 45.5 Surr: Dibromofluoromethane 49.9 Surr: Toluene-d8 53.4 50.00 91.0 70 130 50.00 99.7 70 130 50.00 107 70 130 QC+ Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 33 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010839 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156931 Sample ID: 23010928-001AMS SampType: MS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156931 Client ID: Batch= Batch ID: R156931 TestNo: SW8260 Analysis Date: 1/23/2023 SegNo: 4177602 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1, 1 -Dichloroethene 0.461 0.100 0.400 0 115 13.6 202 QC+ 1,2-Dichloroethane 0.372 0.100 0.400 0 93.0 55.7 138 MEK ND 2.00 2.00 0 88.6 65.3 130 Benzene 0.438 0.100 0.400 0 110 49.2 145 Carbon tetrachloride 0.375 0.100 0.400 0 93.6 26.7 156 Chlorobenzene ND 1.00 0.400 0 96.2 33.7 159 Chloroform 0.384 0.100 0.400 0 96.0 48.5 145 Tetrachloroethene 0.359 0.100 0.400 0 89.8 19.2 191 Trichloroethene 0.376 0.100 0.400 0 94.0 38.4 167 Vinyl chloride 0.605 0.0400 0.400 0 151 27.3 161 QL+QC+ Surr:4-Bromofluorobenzene 928 1000 92.8 70 130 Surr: Dibromofluoromethane 982 1000 98.2 70 130 Surr: Toluene-d8 1040 1000 104 70 130 Sample ID: 23010928-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156931 Client ID: Batch= Batch ID: R156931 TestNo: SW8260 Analysis Date: 1/23/2023 SegNo: 4177603 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.471 0.100 0.400 0 118 13.6 202 0.461 2.23 25 QC+ 1,2-Dichloroethane 0.393 0.100 0.400 0 98.2 55.7 138 0.372 5.39 25 MEK ND 2.00 2.00 0 94.1 65.3 130 0 0 25 Benzene 0.441 0.100 0.400 0 110 49.2 145 0.438 0.683 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 34 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010839 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156931 Sample ID: 23010928-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156931 client ID: BatchQC Batch ID: R156931 TestNo: SW8260 Analysis Date: 1/23/2023 SegNo: 4177603 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Carbon tetrachloride 0.389 0.100 0.400 0 97.2 26.7 156 0.375 3.72 25 Chlorobenzene ND 1.00 0.400 0 102 33.7 159 0 0 25 Chloroform 0.395 0.100 0.400 0 98.8 48.5 145 0.384 2.93 25 Tetrachloroethene 0.377 0.100 0.400 0 94.2 19.2 191 0.359 4.79 25 Trichloroethene 0.389 0.100 0.400 0 97.3 38.4 167 0.376 3.40 25 Vinyl chloride 0.601 0.0400 0.400 0 150 27.3 161 0.605 0.630 25 QL+QC+ Surr:4-Bromofluorobenzene 920 1000 92.0 70 130 0 25 Surr: Dibromofluoromethane 999 1000 99.9 70 130 0 25 Surr: Toluene-d8 1050 1000 105 70 130 0 25 'ample ID: 23011160-001AMS SampType: MS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156931 ,lient ID: Batch= Batch ID: R156931 TestNo: SW8260 Analysis Date: 1/23/2023 SegNo: 4177606 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1, 1 -Dichloroethene 0.449 0.100 0.400 0 112 13.6 202 QC+ 1,2-Dichloroethane 0.343 0.100 0.400 0 85.7 55.7 138 MEK ND 2.00 2.00 0 75.9 65.3 130 Benzene 0.416 0.100 0.400 0 104 49.2 145 Carbon tetrachloride 0.367 0.100 0.400 0 91.8 26.7 156 Chlorobenzene ND 1.00 0.400 0 95.2 33.7 159 Chloroform 0.374 0.100 0.400 0 93.4 48.5 145 Tetrachloroethene 0.345 0.100 0.400 0 86.2 19.2 191 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 35 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010839 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156931 Sample ID: 23011160-001AMS SampType: MS TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156931 client ID: BatchQC Batch ID: R156931 TestNo: SW8260 Analysis Date: 1/23/2023 SegNo: 4177606 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual Trichloroethene 0.360 0.100 0.400 0 90.1 38.4 167 Vinyl chloride 0.610 0.0400 0.400 0 153 27.3 161 QL+QC+ Surr:4-Bromofluorobenzene 918 1000 91.8 70 130 Surr: Dibromofluoromethane 974 1000 97.4 70 130 Surr: Toluene-d8 1060 1000 106 70 130 Sample ID: 23011160-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156931 client ID: BatchQC Batch ID: R156931 TestNo: SW8260 Analysis Date: 1/23/2023 SegNo: 4177607 analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 1,1-Dichloroethene 0.459 0.100 0.400 0 115 13.6 202 0.449 2.29 25 QC+ 1,2-Dichloroethane 0.368 0.100 0.400 0 92.1 55.7 138 0.343 7.20 25 MEK ND 2.00 2.00 0 89.8 65.3 130 0 0 25 Benzene 0.428 0.100 0.400 0 107 49.2 145 0.416 2.70 25 Carbon tetrachloride 0.372 0.100 0.400 0 92.9 26.7 156 0.367 1.19 25 Chlorobenzene ND 1.00 0.400 0 93.1 33.7 159 0 0 25 Chloroform 0.379 0.100 0.400 0 94.8 48.5 145 0.374 1.54 25 Tetrachloroethene 0.344 0.100 0.400 0 86.1 19.2 191 0.345 0.116 25 Trichloroethene 0.366 0.100 0.400 0 91.6 38.4 167 0.360 1.60 25 Vinyl chloride 0.633 0.0400 0.400 0 158 27.3 161 0.610 3.64 25 QL+QC+ Surr:4-Bromofluorobenzene 905 1000 90.5 70 130 0 25 Surr: Dibromofluoromethane 987 1000 98.7 70 130 0 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound Original ND Not Detected OG1 P Second column confirmation exceeds PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 36 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMf_WAL I ECHNG LQgir,-3, INC,. Cuyahoga Falls, Ohio 44223 Arrafyt�cal iaboralorfas TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://mmm.settek.com QC SUMMARY REPORT WO#: 23010839 24-Jan-23 Client: Synagro Project: Yadkinville BatchID: R156931 Sample ID: 23011160-001AMSD SampType: MSD TestCode: TCLP-VOC-M Units: mg/L Prep Date: RunNo: 156931 Client ID: Batch= Batch ID: R156931 TestNo: SW8260 Analysis Date: 1/23/2023 SegNo: 4177607 Analyte Result PQL SPK value SPK Ref Val %REC Lowl-imit Highl-imit RPD Ref Val %RPD RPDLimit Qual Surr: Toluene-d8 1040 1000 104 70 130 0 25 Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound ND Not Detected OG1 P Second column confirmation exceeds Original PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit Page 37 of 39 z .4 ly ca F SrS} h aupoo to aauaildwOD Ie!aadg :dIvq Ma 30.4 b a rn C.1 R "S 2.i O O ti E a 'R W d W > Vl Y ad f _a r c s h z qJay}}sad �, ti � yr dilo-1 cuSeuAS a x a�dmag gad s�autiu{ua� jo �aq m ok r � «ur�Ywua uj djpidi] +ayi6 {g :ac6c (L =Va$ iS �#i�°y j,J,j a =L7}i $ i5 :sIuasp a°a 46 WE45iA [L !f6}dfi it � Ja�n�y�3crnouaep4[[l��Ai�l4T�ad-°°BE�l1db! 3 lily =V4i'o- wrprbn-a'aaanis-is,ptios=5mmnq c a�dmega�imd�ugry c c a[duras gea:3 � A H � s ❑ tr a u 2 '? e 3 Y LL 4�LJLJ V Id a � C a O � w9i a G � 14, Q N r � L IF i M Page 38 of 39 Summit Environmental Technologies, Inc. SUMMIT 3310 Win St. ENVIRONMENTAL TECHN❑L4Ga1�S.IfiC Cuyahoga Falls, Ohio44223 Sample Log -In Check List Arrafocaf Laboralorias TEL: (330) 253-8211 FAX.- (330) 253-4489 Website: http://`h,,",m,.settek.coin Client Name: SYN-NC-27028 Work Order Number: 23010839 RcptNo: 1 Logged by: Anthony W. Britton 1/13/2023 10:20:00 AM' Completed By: Anthony W. Britton 1/13/2023 5:49:34 PM Reviewed By: Jennifer Woolf 1/16/2023 4:11:15 PM Chain of Custody 1. Is Chain of Custody complete? Yes ❑d No ❑ Not Present ❑ 2. How was the sample delivered? UPS Lop In 3. Coolers are present? Yes ❑d No ❑ NA ❑ 4. Shipping container/cooler in good condition? Yes d❑ No ❑ Custody seals intact on shipping container/cooler? Yes ❑ No ❑ Not Present V No. Seal Date: Signed By: 5. Was an attempt made to cool the samples? Yes ❑d No ❑ NA ❑ 6. Were all samples received at a temperature of >0° C to 6.0°C Yes ❑d No ❑ NA ❑ 7. Sample(s) in proper container(s)? Yes ❑d No ❑ 8. Sufficient sample volume for indicated test(s)? Yes ❑d No ❑ 9. Are samples (except VOA and ONG) properly preserved? Yes ❑d No ❑ 10. Was preservative added to bottles? Yes ❑ No ❑d NA ❑ 11. Is the headspace in the VOA vials less than 1/4 inch or 6 mm? Yes ❑ No ❑ No VOA Vials ❑� 12. Were any sample containers received broken? Yes ❑ No ❑d 13. Does paperwork match bottle labels? Yes No ❑ (Note discrepancies on chain of custody) 14. Are matrices correctly identified on Chain of Custody? Yes ❑ No ❑d 15. Is it clear what analyses were requested? Yes ❑d No ❑ 16. Were all holding times able to be met? Yes No ❑ (If no, notify customer for authorization.) Special Handling (if applicable) 17. Was client notified of all discrepancies with this order? Yes ❑ No ❑ NA V Person Notified: Date: By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person Regarding: Client Instructions: 18. Additional remarks: Cooler Information Cooler No Temp °C Condition I Seal Intact Seal No Seal Date Signed By 1 15.0 Goodl Not Present Page 39 of 39 SECTION 5 ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: Town of Yadkinville WQ Permit Number: WQ 00001800 WWTP Name: Yadkinville WWTP NPDES Number: N00020338 Monitoring Period: From 01/01/ 2023 To 12/31/2023 Pathogen Reduction (40 CFR 503.32/15A NCAC 02T.1106) - Please indicate level achieved and alternative performed: Class A: Alt. 1/A (time/temp) Alt. 2/13 (Alk Treatment) Alt. 3/C (Prior Testing) Alt. 4/D (No Prior Test) Alt. 5/Process to Further Reduce Pathogens Alt. 6 (Equivalent to PFRP) If applicable to alternative performed (Class A only) indicate "Process to Farther Reduce Pathogens": Compost Heat Drying Heat Treatment Thermophilic Beta Ray Gamma Ray Pasteurization Class B: Alt. (1) Fecal Density X Alt. (2) Process to Significantly Reduce Pathogens If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization Air Drying Composting Aerobic Digestion Anaerobic Digestion if annhen hip to attarnativa nnrf..r—A !!`Incc A ..r !'1..— R..........l..a.. Parameter Allowable Level in Sludge Pathogen Density No. of Frequency Sample Analytical Excee- of Type Technique Minimum Geo. Mean Maximum Units denees Analysis Fecal 2x10to the 60, MPN 807 823 837 MPN/g 0 Annual Grab Sm9221C Coliform power per gram E of total solids CFU CFU/g 1000 MPN per gram of MPN/g total solids (dry weight) Salmonella 3 MPN per 4 grams total bacteria (in solids (dry weight) lieu of fecal coliform Vector Attraction Reduction (40 CFR 503.33/15A NCAC 02T.1107) - Please indicate option/alternative performed: Option/Alt. 1 (VS reduction) X Option/Alt. 2 (40-day bench) Option/Alt. 3 Option/Alt. 4 (30-day bench) (Spec. 02 uptake) Option/Alt. 5 (14-Day Aerobic) Option/Alt. 6 (Alk Stabilization) Option/Alt. 7 Option/Alt. 8 (Drying — Stable) (Drying — Unstable) Option/Alt. 9 Option/Alt. 10 (Injection) (Incorporation) No vector attraction reduction alternatives were performed CERTIFICATION STATEMENT (please check the appropriate statement) "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32./15A NCAC 02T.1 106 and the vector attraction X reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have been met." "I certify, under penalty of law, that the pathogen requirements in 40 CFR 503.32/15A NCAC 02T.1106 and the vector attraction reduction requirement in 40 CFR 503.33/15A NCAC 02T.1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the requirements.) "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Grant Trivette Plant Manager Prepqrjr Name a Title type or rint) Signature of Preparer* Date Land Applier Name and Title (if applicable) (type or print) Signature of Land Applier (if applicable) Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T.1102 (26) Analytical Results STATESVILLE �.. ANALYTICAL Town of Yadkinville l PO Box 816 Yadkinville, NC 27055 Receive Date: 02/07/2023 Reported: 02/08/2023 For: Comments: Geometric Mean: 823 MPN/g Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst 230207-30-01 Fecal Coliforms 1 826 MPN/g SM92210E-2006 02/07/2023 MD 230207-30-01 Percent Solids 1 2.42 % SM2540B-2011 02/07/2023 MD 230207-30-02 Fecal Coliforms 2 837 MPN/g SM92210E-2006 02/07/2023 MD 230207-30-02 Percent Solids 2 2.39 % SM2540B-2011 02/07/2023 MD 230207-30-03 Fecal Coliforms 3 837 MPN/g SM92210E-2006 02/07/2023 MD 230207-30-03 Percent Solids 3 2.39 % SM254OB-2011 02/07/2023 MD 230207-30-04 Fecal Coliforms 4 820 MPN/g SM92210E-2006 02/07/2023 MD 230207-30-04 Percent Solids 4 2.44 % SM2540B-2011 02/07/2023 MD 230207-30-05 Fecal Coliforms 5 816 MPN/g SM92210E-2006 02/07/2023 MD 230207-30-05 Percent Solids 5 2.45 % SM25408-2011 02/07/2023 MD 230207-30-06 Fecal Coliforms 6 807 MPN/g SM92210E-2006 02/07/2023 MD 230207-30-06 Percent Solids 6 2.48 % SM2540B-2011 02/07/2023 MD 230207-30-07 Fecal Coliforms 7 816 MPN/g SM92210E-2006 02/07/2023 MD 230207-30-07 Percent Solids 7 2.45 % SM2540B-2011 02/07/2023 MD Respectfully submitted, 1 lGr1 �z . G�5�% Melissa Myers NC Cert #440, NCDW Cert #37755, EPA #NC00909 PO Box 228 • Statesville, NC 28687 • 704/872/4697 Page 1 of 4 2 2 2 CD / { / i ƒ C. PO ƒ £ :3 / £ E E � 3■ m , g 7 7 CDa . cicr $ § $ q R j j ) ) f ] ] \ 3- 2 2 2 2 £ E ■ £ . . _ |_ c � W R D , / f 0 a e e 9 ) ) 2 ] 6 04 G ® 3 3 3 3 2 U 3 3 3 3 �E E a E E .\ } ƒ « z o = / j \m e / , CL } r o S 3/zA . eD 0 -4 E�§7j\ . �— -- — — -- — — — . �-- PO Box228 • Statesville, NC28687 - 70 / 72 4697 Page 4a4 r�o volatilesolids.xls 2/2/06 % TOTAL SOLIDS % VOLATILE SOLIDS SM 2540 G r Analyzed By: � � N Calculated By: Date In 103-105 oven: Date In 550 furnace: - Time In 103-105 oven: Time In 550 furnace: Time Out 103-105 oven: 0-m q- Time Out 550 furnace: Qg ��j �,LA Samp[le ID INITIAL RAS C^ �� r!� INITIAL RAS (dup) 6 Dry wt. C12 Dish wt. —110 ( 14 Sample vol. Z `� phi TS% - 6 Dish # - Dry wt. 1 . C c' Ash wt. ::Z, VS % 3Cf 1-1 Ll 9 G , 1,, 6 d7 Divide VS% by TS% % volatile L� fraction % volatile �fraction Sample ID FINAL Holding Tank 13 FINAL Holding Tank (dup) -7 Dry wt.1 W 3� Dish wt. �- ,66) 510 (p Sample vol. 2 _ h TS % 3 s a Dish # L� Dry wt. 2 12-.14 3 3 92, Ash wt. ' 3 VS% °J `[ Divide vS% by TS% % volatile r 3 f fraction % volatile fraction Calculation for TS% and VS%: Dry wt. - Dish wt. X 100 Sample vol. 1 cil 6� INITIAL AVERAGE: 0. FINAL AVERAGE: Lc--� ), 9 o USE INITIAL AND FINAL AVERAGES OF YOUR % VOLATILE FRACTION TO CALCULATE THE PERCENT REDUCTION (USE THE VAN KLEECK FORMULA) Van Kleeck Reduction: Initial % vol. frac. - Final % voi. frac. X 100 = % reduction Initial % vol. frac. - (Initial % vol. frac x Final %vol. frac.) minus l G . r x 100 = minus R V b times c. e ��b A *Do multiplication inside[( )] before you subtract on bottom of equation. G< < z-� z bl 1 SECTION 6 Agricultural Lime Application Log Year: 2023 Project: Yadkinville WWTP Field Soil Lime Requirement Tons/Acre Date Applied (state -county -site -field) pH (from soil analysis) Applied(CCE Eq.) YK-Uti-(i b.9 U.0 I /AU YK-33-1 6.0 0.0 T/AC YK-33-2 6.0 O.OT/AC YK-29-1 6.3 O.OT/AC YK-33-3 5.3 1 T/AC 1.0 11 /30/23 YK-9-1 6.0 O.OT/Ac YK-35-1 5.3 .5T/Ac 1 T/Ac 10/05/23 YK-35-2 5.6 .5T/Ac 1 T/Ac 10/05/23 *Lime will be applied when conditions improve SECTION 7 Page 1 of 1 Report Number: 24-002-0533 Account Number: 07778 Send To: Synagro/Alex Fox Alex Fox 284 Boger Rd Mocksville NC 27028 Waypoi nt(D - ANALYTICAL Farm: YK-8 "Every acre... Every year. "rM SOIL ANALYSIS REPORT Date Received: 01/02/2024 Date Of Analysis: 01/03/2024 Date Of Report: 01/03/2024 2850 Daisy Lane, Wilson, NC 27896 Main 252-206-1721 ° Fax 252-206-9973 www.waypointanalytical.com Grower: YADKINVILLE Analytical Method(s): Mehlich 3 Lime Index Humic Matter Loss On Ignition Water pH OM W/V ENR Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 Sample ID Lab Field ID Number % Soil Ibs/A M3 K Mg Ca Na Soil Buffer H Class ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate pH Index meq/100g meq/100g 6 24253 1.7 72 151 VH 33 V L 219 H 1048 M 17 V L 5.9 6.22 1.5 8.7 NC=126 NC=17 Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts Sample ID Field ID K Mg Ca Na H NO3 N S Zn Mn Fe Cu B SS % % % % % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ms/cm Rate 6 1.0 21.0 60.2 0.8 17.2 14 L 40.8 VH 16 M 14.4 VH 0.6 M NC=29 NC=1020.0 NC=100 NC=720.0 Values on this report represent the plant available nutrients in the soil. Rating after each value: VL (Very Low), L (Low), M (Medium) H (High), VH (Very High). ENR - Estimated Nitrogen Release. C.E.C. - Cation Exchange Capacity. Date Received: 01/02/2024 Date Of Report: 01/03/2024 Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by: Salts ms/cm x 640 = ppm. Analysis prepared by: Waypoint Analytical Carolina, Inc. SOIL FERTILITY RECOMMENDATIONS Nitrogen Phosphate Potash Magnesium Sulfur Zinc Manganese Iron Copper Boron Sample ID Intended Crop Yield Goal Lime N P205 K20 Mg S Zn Mn Fe Cu B Field ID Tons Tons/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A 6 Fescue Hay 4 0.8 200 0 250 0 10 0 4 0 0 Comments: "The recommendations are based on research data and experience, but NO GUARANTEE or WARRANTY expressed or implied, concerning crop performance is made." Our reports and letters are for the exclusive and confidential use of our clients„ and may not be reproduced in whole or part, nor may any reference be made to the work,the results, or the company in any advertising, news release, or other public anouncements without obtaining our prior written authorization. Copy right 1977. Page 1 of 1 Report Number: 24-002-0532 Account Number: 07778 Send To: Synagro/Alex Fox Alex Fox 284 Boger Rd Mocksville NC 27028 Waypoi nt(D - ANALYTICAL Farm: YK-9 "Every acre... Every year. "rM SOIL ANALYSIS REPORT Date Received: 01/02/2024 Date Of Analysis: 01/03/2024 Date Of Report: 01/03/2024 2850 Daisy Lane, Wilson, NC 27896 Main 252-206-1721 ° Fax 252-206-9973 www.waypointanalytical.com Grower: YADKINVILLE Analytical Method(s): Mehlich 3 Lime Index Humic Matter Loss On Ignition Water pH OM W/V ENR Phosphorus Potassium Magnesium Calcium Sodium pH Acidity C.E.0 Sample ID Lab Field ID Number % Soil Ibs/A M3 K Mg Ca Na Soil Buffer H Class ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate pH Index meq/100g meq/100g 1 24252 1.9 78 122 VH 50 VL 193 H 679 L 59 L 6.0 6.25 1.4 6.8 NC=102 NC=26 Percent Base Saturation Nitrate Sulfur Zinc Manganese Iron Copper Boron Soluble Salts Sample ID Field ID K Mg Ca Na H NO3 N S Zn Mn Fe Cu B SS % % % % % ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ppm Rate ms/cm Rate 1 1.9 23.7 49.9 3.8 20.6 18 M 30.6 VH 30 H 8.3 VH 0.4 L NC=37 NC=765.0 NC=188 NC=415.0 Values on this report represent the plant available nutrients in the soil. Rating after each value: VL (Very Low), L (Low), M (Medium) H (High), VH (Very High). ENR - Estimated Nitrogen Release. C.E.C. - Cation Exchange Capacity. Date Received: 01/02/2024 Date Of Report: 01/03/2024 Explanation of symbols: % (percent), ppm (parts per million), Ibs/A This report applies to sample(s) tested. Samples are retained a (pounds per acre), ms/cm (milli -mhos per centimeter), meq/100g maximum of thirty days after testing. (milli -equivalent per 100 grams). Conversions: ppm x 2 = Ibs/A, Soluble by: Salts ms/cm x 640 = ppm. Analysis prepared by: Waypoint Analytical Carolina, Inc. SOIL FERTILITY RECOMMENDATIONS Nitrogen Phosphate Potash Magnesium Sulfur Zinc Manganese Iron Copper Boron Sample ID Intended Crop Yield Goal Lime N P205 K20 Mg S Zn Mn Fe Cu B Field ID Tons Tons/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A Ib/A 1 Fescue Hay 4 0.8 200 0 250 0 9 0 3 0 0.5 Comments: "The recommendations are based on research data and experience, but NO GUARANTEE or WARRANTY expressed or implied, concerning crop performance is made." Our reports and letters are for the exclusive and confidential use of our clients„ and may not be reproduced in whole or part, nor may any reference be made to the work,the results, or the company in any advertising, news release, or other public anouncements without obtaining our prior written authorization. Copy right 1977. NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL003597 k5i I"14'4+;4, Client: Alex Fox Advisor: Predictive Synagro 284 Boger Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Links to Helpful Information Sampled: Received: 09/08/2023 Completed: 09/18/2023 Farm:4Y-29 Client ID: Sampled County : Yadkin 501947 Advisor ID: Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 120 80 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 120 80 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.22 0.98 6.1 84 1.0 6.3 9 28 53 29 53 380 241 241 86 86 77 0.3 5 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 1.1 120-200 110 70 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 110 70 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.46 0.86 4.2 54 1.9 5.1 14 35 32 17 59 268 178 178 40 40 64 0.2 5 North Carolina Tcbwim Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL003597 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NOs-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.pov/apronomi/obpart4.htrntfsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.pov/agronomi/uyrst.htm NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL033717 k5i I"14'4+;4, Client: Alex Fox Advisor: Predictive Synagro 284 Boger Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Links to Helpful Information Sampled: Received: 06/05/2023 Completed: 06/13/2023 Farm: YK-33 Client ID: Sampled County : Yadkin 501947 Advisor ID: Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 100 90 0 20 0 0 0 0 Note: 12 2 - Fescue/OGrass/Tim, M 0.0 120-200 100 90 0 20 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.22 0.91 8.7 88 1.0 6.5 17 25 76 11 24 278 177 177 144 144 177 0.1 1 Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 0 100 0 0 pH$ 0 0 0 Note: 12 Note: $ 2 - Fescue/OGrass/Tim, M 0.0 120-200 0 100 0 0 pH$ 0 0 0 Note: 12 Note: $ Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.18 1.07 7.0 89 0.8 6.6 229 18 60 27 31 256 162 162 839 839 383 0.1 1 North Carolina Tcbwim Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL033717 Alex Fox Page 2 of 3 Sample ID: 3 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 1.0 120-200 0 60 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 0 60 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.32 1.04 5.4 67 1.8 5.3 140 40 48 15 45 214 145 145 652 652 331 0.2 4 NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY23-SLO33717 Alex Fox Page 3 of 3 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NOs-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.pov/apronomi/obpart4.htrntfsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.pov/agronomi/uyrst.htm NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL003610 k5i I"14'4+;4, Client: Alex Fox Advisor: Predictive Synagro 284 Boger Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Links to Helpful Information Sampled: Received: 09/08/2023 Completed: 09/18/2023 Farm: YK-35 Sampled County : Davie Client ID: 501947 Advisor ID: Sample ID: 1 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 1.2 120-200 0 0 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 0 0 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.71 0.94 7.9 72 2.2 5.3 77 271 38 17 100 183 127 127 497 497 189 0.2 3 North Carolina Tai wLm Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY24-SL003610 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NOs-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.pov/apronomi/obpart4.htrntfsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.pov/agronomi/uyrst.htm NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL033727 k5i I"14'4+;4, Client: Alex Fox Advisor: Predictive Synagro 284 Boger Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Links to Helpful Information Client ID: Sampled: Received: 06/05/2023 Completed: 06/15/2023 Farm: YK-35 Sampled County : Yadkin 501947 Advisor ID: Sample ID: 2 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.4 120-200 130 50 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 130 50 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.09 0.78 5.8 83 1.0 5.6 6 47 49 31 376 372 240 240 117 117 37 0.1 2 North Carolina Tai wLm Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 664-1600 Website: www.ncagr.gov/agronomi/ Report No. FY23-SLO33727 Alex Fox Page 2 of 2 Understanding the Soil Report: explanation of measurements, abbreviations and units Recommendations Report Abbreviations Lime Ac exchangeable acidity If testing finds that soil pH is too low for the crop(s) indicated, a lime recommendation will be given in units of either B boron ton/acre or Ib/1000 sq ft. For best results, mix the lime into the top 6 to 8 inches of soil several months before planting. BS% % CEC occupied by basic cations For no -till or established plantings where this is not possible, apply no more than 1 to 1.5 ton/acre (50 Ib/1000 sq ft) at onE Ca% % CEC occupied by calcium time, even if the report recommends more. You can apply the rest in similar increments every six months until the full rate CEC cation exchange capacity is applied. If MG is recommended and lime is needed, use dolomitric lime. Cu-I copper index ESP exchangeable sodium percent Fertilizer HM% percent humic matter Recommendations for field crops or other large areas are listed separately for each nutrient to be added (in units of K-1 potassium index lb/acre unless otherwise specified). Recommendations for N (and sometimes for B) are based on research/field studies K20 potash for the crop being grown, not on soil test results. K-1 and P-1 values are based on test results and should be > 50. If they Mg% % CEC occupied by magnesium are not, follow the fertilizer recommendations given. If Mg is needed and no lime is recommended, 0-0-22 (11.5% Mg) is MIN mineral soil class an excellent source; 175 to 250 lb per acre alone or in a fertilizer blend will usually satisfy crop needs, SS-1 levels appear Mn manganese only on reports for greenhouse soil or problem samples. Mn-All Mn-availability index for crop 1 Mn-Al2 Mn-availability index for crop 2 Mn-I manganese index Farmers and other commercial producers should pay special attention to micronutrient levels. If $, pH$, $pH, C or Z Mn- mineral -organic soil class notations appear on the soil report, refer to $Note: Secondary Nutrients and Micronutrients_ In general, homeowners do not N nitrogen need to be concerned about micronutrients. Various crop notes also address lime fertilizer needs; visit Na sodium ncagr.gov/agronomi/pubs.htm. NOs-N nitrate nitrogen ORG organic soil class Recommendations for small areas, such as home lawns/gardens, are listed in units of Ib/1000 sq ft. If you cannot find pH current soil pH the exact fertilizer grade recommended on the report, visit www.ncagr.pov/apronomi/obpart4.htrntfsfind information that P-1 phosphorus index may help you choose a comparable alternate. For more information, read A Homeowner's Guide to Fertilizer. P205 phosphate S-1 sulfur index Test Results SS-1 soluble salt index W/V weight per volume The first seven values [soil class, HM%, W/V, CEC, BS%, Ac and pH] describe the soil and its degree of acidity. The Zn-AI zinc availability index Zn-1 zinc index remaining 16 [P-I, K-I, Ca%, Mg%, Mn-I, Mn-All, Mn-AI2, Zn-I, Zn-AI, Cu-I, S-I, SS -I, Na, ESP, SS -I, NO3-N (not routinel available)] indicate levels of plant nutrients or other fertility measurement. Visit www.ncagr.pov/agronomi/uyrst.htm