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HomeMy WebLinkAboutWQ0003034_Application_19990809A�fiS[•le� TO: FROM: SUBJECT: _ , DIVISION OF WATER QUALM GROUNDWATER SECTION RzECEIVED AUG 1 1 1999 Fi4i'EI"'1 FViLLE REG. OFFICE New Permit _Repair/Alteration of Exist. Disposal System [DEH] Facility Name: County: Type of Project: / .7�Ccdp/�a�/o� APPLICABLE PERMIT NO.s: WQ n2o O3 r DEH EPA (CONST. GRANTS) ANIMAL WASTE (DWQ) AtoC The Groundwater Section has received ONLY ONE fl l(1l copy of the referenced permit application. A copy of the application should have been sent to your Regional Water Quality Supervisor, so please use that copy for your review - IF A COPY HAS NOT BEEN RECEIVED N THE REGIONAL OFFICE, PLEASE LET ME KNOW. The Groundwater Section has received ONLY ONE f 11 copy of the referenced permit application. A copy of the application should have been sent to , DEH's Regional Soil Specialist, so please use that copy for your review - IF A COPY HAS NOT BEEN RECEIVED IN THE REGIONAL OFFICE, PLEASE �LET ME KNOW. The Groundwater Section received two (2) copies of the referenced permit application. One copy of the application documents we received is attached. Please review the application materials for rccomp leteness. If you feel additional information is necessary, please let me know no later than A copy of any formal request for additional iniotma::on will be forwarded to you. If you o not neejl•anv additional information to complete your review, please provide your final comments by icyas �0, /99/`—. If you request and/or receive additional information. your final comm=1 \9-98TRAN.SHL (rev. 9/29/93) FIECEIVC® 4UG 1 1 1999 FFlL'E7TCV8LE.E F'E!d'0FFJC2 APPLICATION FOR PERMIT RENEWAL LAND APPLICATION OF RESIDUAL SOLIDS ROCCO FARM FOODS, INC. ST.PAULS, NORTH CAROLINA NON -DISCHARGE PERMIT NO. W00003034 RECEIVED WATI�n nl 1Ar trrsFM ON JUL 2 91999 Non -Discharge Permitting Prepared For: Rocco Farm Foods, Inc. P.O. Box 9 St. Pauls, North Carolina 28384 Compiled By: S&ME, Inc. 3718 Old Battleground Road Greensboro, North Carolina 27410 July 1999 July 27, 1999 N.C. Department of Environment and Natural Resources Water Quality Section Permits and Engineering Unit Post Office Box 29535 512 North Salisbury Street 27604 Raleigh, North Carolina 27626-0535 /:M��el�Y1(�7►A Mr. Kim Colson REFERENCE: RENEWAL OF PERMU NO. WQ0003034 Rocco Farm Foods, Inc. (formerly Rocco Turkeys, Inc.) S&ME Project No. 1588-93-014A Dear Mr. Colson: S&ME, Inc. is under contract with Rocco Farm Foods, Inc. (Rocco) formerly Rocco Turkeys, Inc. for the management of their land application of residual solids program. S&ME on behalf of Rocco wishes to renew current Non -Discharge Permit No. WQ0003034. With this renewal we wish to - decrease the permitted Dry Tons (DT) from 984 DT/Year to 290 DT/Year (reference Section H — I�. Operating procedures will involve the land application of the SBR and DAF residual solids onto the - currently permitted acreage in Permit No. WQ0003034 (382.5 acres). Land application activities will be done within agronomic rates in accordance with Permit No. WQ0003034 and monitored closely by Rocco and S&ME. Operations will continue to involve application of currently permitted wastewater residuals to the permitted sites. All applications of the residual solids will be subsurface injected. L1 S&ME, Inc. )336) 288-7180 3718 Old Battleground Road )336) 288-8980 fax Greensboro, North Carolina 27410 )800) 849-2985 w smellne.com � I Renewal of Permit No. WQ0003034 S&ME Job No. 1588-93-014A Rocco Farm Foods, Inc. July 27, 1999 Your prompt attention in the review of this renewal would be greatly appreciated. Please contact us immediately if you require additional information or have questions in the review of the renewal application. Sincerely, S&ME, Inc. d4' br � Robert P. Willcox, Jr., L.S.S. Residuals Management Department Manager Enclosure: Permit Package cc: Barry Tyner, Rocco Scott D. Berg Project Manager TABLE OF CONTENTS Section No. Title I MANAGEMENT PLAN SPILL CONTROL PLAN APPLICATION RATES RESIDUAL SOLIDS GENERATION AND CHARCTERISTICS MONITORING RECORDS II LAND APPLICATION OF OTHER RESIDUAL SOLIDS APPLICATION FORM SBR AND DAF RESIDUAL SOLIDS WEIGHTED AVERAGES III CALCULATIONS WORKSHEET DAF RESIDUAL SOLIDS IV CALCULATIONS WORKSHEET SBR RESIDUAL SOLIDS RENEWAL SITES V SUMMARY OF RENEWAL SITES VI OWNER/OPERATOR AGREEMENT FORMS VII UPDATED CUMULATIVE LOADING RECORDS VIII UPDATED SOILS ANALYSIS REPORTS APPENDICES APPENDIX I : SBR AND DAF NUTRIENT AND METAL ANALYSIS APPENDIX II: SBR AND DAF TCLP ANALYSIS Page No. 1 4 5 7 8 9 SECTION I MANAGEMENT PLAN SPILL CONTROL PLAN APPLICATION RATES RESIDUAL SOLIDS GENERATION AND CHARACTERISTICS MONITORING RECORDS MANAGEMENT PLAN The residual solids management plan describes the process by which the residual solids from the Rocco Farm Foods, Inc. (Rocco) Poultry Processing Facility's Wastewater Treatment Plant (WWTP) will be land applied to the currently permitted fields as an agricultural resource at agronomic rates. The residual solids will be applied to row crop land at agronomic rates for total or partial replacement of conventional nitrogen (N) and phosphorus (P) fertilizers. The actual amount of residual solids applied will be dependent upon the nutrient requirement of the specific crop and the nutrient content of the residual solids. Residual solids application scheduling will be dependent upon residual solids production, storage at the respective treatment plant, and the crop management program. On farms utilized for row crops, residual solids will be land applied between crop rotations. The fields will receive residual solids in an agronomic manner based on requirements listed in Permit Number WQ0003034. Residual solids will be applied at agronomic rates whicfi are limited by nitrogen loading rates. An acceptable pH will be maintained in the soil, residual and lime mixture greater than 6.0 on all land application sites to insure optimum yield for the crop being grown. Prior to an application event, an application rate will be determined based on a current residual solids nutrient analysis. Representative residual solids samples will be collected prior to the application event and composited for analysis. This composite sample will then be delivered to a qualified laboratory familiar with residual solids analysis and analyzed for ammonia nitrogen, nitrate/nitrite nitrogen, percent total solids, total Kjeldahl nitrogen, phosphorus, potassium, calcium, magnesium, sodium, copper, zinc, cadmium, nickel, lead, aluminum, chlorides, sulfate, and pH. Plant available nitrogen (PAN) will then be calculated from this residual solids analysis. This information will be used to calculate the loading rate for the field and crop. Once the appropriate application rate has been calculated, the residual solids will be removed from the respective treatment plant and transported to the site in tankers adapted for liquid residual 1 solids. Liquid residual solids will be loaded into tankers which will then travel major traffic routes to the fields whenever possible. Once at the field, the tanker will proceed to a designated staging area. The liquid residual solids will then be transferred to a residual solids applicator designed and operated to obtain an even application consistent with agricultural requirements. An AG Chem Terragator 2505 or equivalent will be utilized to land apply the liquid residual solids. All residual solids will be removed from the staging area by the end of the working day, unless equipment breakdown or weather prohibits the residual solids application. At the start of each day, the field superintendent will inspect all fields. Equipment will only enter a field when conditions are appropriate for the application. Residual solids will only be applied when the field is capable of supporting equipment. When field conditions are not appropriate for an application, such as during wet periods, the residual solids will remain at the WWTP until field conditions are suitable for land application. Prior to the residual solids operations, the field superintendent and appropriate Rocco personnel will inspect the site. During the field inspection, the field superintendent will note the standard North Carolina Department of Environment and Natural Resources - Division of Water Quality (DWQ) buffer zones, including: homes, drainage ditches, roads, wells, surface water, and property boundaries (listed in Table 1 below). Standard DWQ buffers for land application programs will be established in the field. These buffers will be identified by the placement of pin . flags. 2 TABLE 1 DWQ Buffer Distances as listed in Permit No. WQ0003034 Application Method Surface Area Description Injection Spreading ---- --------------------- feet ----------------- -------------------- Property boundary 50 50 Public road 50 50 Development (residential) 200 400 Inhabited dwelling 200 400 Potable wells private 100 100 public 100 100 Drainageways 25 25 Surface water 100 100 3 SPILL CONTROL PLAN ROCCO FARM FOODS, INC. ST. PAULS, NORTH CAROLINA In the case of a spill, the following action shall be taken immediately: Halt the source of the spill: Ruptured line or valve, or damaged tank unit. 2. Contain spill: Use straw bales to form a barrier. Straw or hay bales can be obtained from several sources for this purpose. Soil near the site can also be used to form a barrier for containment. Clean up: Use residual solids application equipment to recover as much of the material as possible. After the application equipment has recovered as much material as possible, it will be land applied as per the management plan. A temporary sump pit may be dug in the containment area and spilled material washed into it to enhance recovery. 4. Final Clean up: Any unrecoverable material will be washed from the road surface and incorporated into an adjacent tillable area. Notification: As soon as possible after a spill occurs notify: A. Rocco Farm Foods, Inc. (910) 865-6611 B. Department of Environment and Natural Resources Division of Water Quality Fayetteville Regional Office (910) 486-1541 C. Robeson County Sheriffs Department (910) 671-3100 D. Fire Department if assistance is required for washdown E. S&NfE, Inc. Greensboro Branch (336) 288-7180 6. Management of clean up efforts: The field superintendent shall take immediate charge of the clean up activities. Additional labor will be requested from the treatment plant and other departments as needed. Reporting: Within 24 hours of a spill the field superintendent shall present a written report detailing the cause of the spill and all action taken in response to the spill. 11 APPLICATION RATES The residual solids application rate will be based on the plant available nitrogen (PAN) requirement for the crop and the PAN content in the residual solids. The PAN requirement for the specific crop will be derived from limits in current Permit No. WQ0003034 (Table 2). Crops typically grown in the area counties are coastal bermuda, small grains, soybeans, com, cotton and fescue. TABLE 2 Plant Available Nitrogen (PAN) Limits for Crops Commonly Grown in the Area Crop Alfalfa Bermuda Grass (Hay, Pasture) Blue Grass Corn (Grain) Corn (Silage) Cotton Fescue Forest (Hardwood & Softwood) Milo Small Grain (Wheat, Barley, Oats) Sorghum, Sudex (Pasture) Sorghum, Sudex (Silage) Soybeans Timothy, Orchard, & Rye Grass Coastal Bermuda PAN Recommendations (lbs/Ac) 200 220 120 160 200 70 250 75 100 100 180 220 200 200 350 The PAN content of the residual solids will be based on total Kjeldahl nitrogen (TKN), ammonium - nitrogen (NH4 N), nitrate -nitrogen (N0; N), nitrite nitrogen (NO2 N) content, and the mineralization of organic N into inorganic N. Most of the nitrogen in -the residual solids is in an organic form. As the residual solids are incorporated into the soil, the soil microorganisms utilize the residual solids as an energy and nutrient source. In the process, a portion of the organic N is mineralized or biologically converted into inorganic N. Various environmental factors such as temperature, moisture, and carbon to nitrogen ratio will 5 affect the mineralization rate. - Mineralization rates can also be established in relation to the treatment process which occurs at each plant. Typical mineralization factors range from 0.20 to 0.40. A mineralization rate of 0.40 has been selected for the Rocco dissolved air flotation (DAF) solids because of the treatment process. A mineralization rate of 0.30 has been selected for the Rocco sequencing batch reactor (SBR) residual solids because of the aerobic digestion process. An overall mineralization rate of 0.385 has been selected for the weighted average of the SBR and DAF residual solids. The PAN application rate will be calculated based on the mineralization rate, TKN, NHg N, N0; N, NOZ N content, and method of application. Residual solids that are injected into the soil typically retain a large portion of the NH, gas, which is found in the residual solids or is converted from the NH4 N form. However, when the residual solids are surface applied to hay or fallow row crop fields, a large portion of the NH3 N is volatilized and lost as a nutrient for crop uptake. The actual plant available nitrogen content for equal residual solids is less when the residual solids are surface applied compared to when the residual solids are injected into the soil and the NH; N gas is trapped by the soil. To reflect the lower PAN content for surface applied residual solids due to the volatilization of NH3-N gas, the portion of NH4 N in the residual solids contributing to the PAN is reduced by 50 percent. The PAN content of the residual solids is then calculated for injected and surface applications as follows: A. PAN injected =0.30(TKN -NH4-N)+NH4N+NO3N+NO,N B. PAN surface applied = 0.30 (TKN - NHa N) + 0.5 (NH4-N) + NO3-N +NO2 N WHERE: 0.30 = mineralization factor (SBR residual solids) TKN = Total Kjeldahl Nitrogen NH4-N = Ammonium nitrogen NO3 N = Nitrate nitrogen NO_ N = Nitrite nitrogen 0.5 = Volatilization factor PAN Applied = (gallac)(8.34 lb/gal)(% Solids)(% PAN) = lbs PAN/ac C RESIDUAL SOLIDS GENERATION AND CHARACTERISTICS The Rocco Farm Foods, Inc. Wastewater Treatment Facility currently generates about 1,800,000 gallons per year of residual solids and has approximately 300,000 gallons of residual solids storage capacity at the treatment plant. This breakdown for annual production is approximately 600,000 gallons for the SBR residual solids and approximately 1,200,000 gallons for the DAF residual solids. Characteristics of the combined residual solids are shown on the attached application form in Section H. Calculations within Section II (LAORS Application Form) indicate that sufficient acreage is available to handle the residual solids production. Results of the TCLP for the WWTP analysis are contained in Appendix I. The residual solids are typical of other residual solids generated by poultry processing WWTP's in North Carolina. Likewise, the TCLP results are well below the maximum limits for a waste to be characterized as non -hazardous. The current permit for the Rocco Farm Foods — WWTP (WQ0003034 — dated April 10, 1997), which is effective until December 31, 1999, contains Performance Standards (Section I, Item 11) which specify: When the residuals from an animal processing facility are being land applied, one of the following stabilization methods must be completed to control possible nuisance conditions: a. The residuals are subsurfacely injected, or b. The residuals are incorporated into the soil within 24 hours, or c. Sufficient lime is added to the residuals to create a uniform mixture and achieve a pH of 12. for two hour prior to being surface land applied. 7 MONITORING The residual solids and soil will be sampled at specific intervals to insure the beneficial utilization for agricultural production. The residual solids samples will be collected and delivered to a qualified laboratory that is familiar with routine environmental sample preparation and standards. A residual solids analysis will be conducted for, but not limited to, the following parameters: percent total solids, chlorides, phosphorus, lead, copper, cadmium, sodium, total Kjeldahl nitrogen, nitrate nitrogen, nitrite nitrogen, magnesium, sulfate, potassium, zinc, nickel, calcium, ammonia nitrogen, and pH. Annual Toxicity Characteristics Leaching Procedure (TCLP) analysis for regulatory compliance will also be conducted. Once each year, the fields will be sampled for routine soil fertility and lime requirements. Although the soil samples will likely be collected in the fall or winter seasons, they may also be collected between croppings. Once the soil samples are collected, they will be delivered to either the North Carolina Department of Agriculture -Agronomic Division or A & L Eastern Agricultural Laboratories, Inc. for routine soil analysis. K. RECORDS Records pertinent to the successful management of the land application program will be maintained for the benefit of DWQ, Rocco, S&ME and the landowner. Each year an annual summary of the activities of the program will be prepared and delivered to the appropriate agencies and participants on or before the 1 st of March. The annual summary will include: 1. A) Source of residual solids B) Date of residual solids application C) Location of residual solids application (field number) D) Method of application E) Weather conditions F) Soil conditions G) Type of crop or crop to be grown on field H) Volume of residual solids applied in gallons/acre and dry tons/acre 1) Annual and cumulative totals of dry tons/acre of residual solids, annual and cumulative pounds/acre of each heavy metal (which shall include, but not be limited to lead, nickel, cadmium, copper, zinc), annual pounds/acre of plant available nitrogen (PAN), and annual pounds/acre of phosphorus applied to each field 2. A representative annual soil analysis which will include the following parameters: standard soil fertility test, percent base saturation, phosphorus, potassium, lead', zinc, magnesium, pH, manganese, cation exchange capacity, sodium, nickel', cadmium', copper, and calcium. 3. A minimum of quarterly residual solids analyses which will include the following parameters: percent total solids, chlorides, phosphorus, lead, copper, cadmium, sodium; total nitrogen, nitrate . nitrogen, nitrite nitrogen, magnesium, sulfate, potassium, zinc, nickel, calcium, ammonia nitrogen and pH. 4. An annual TCLP analysis of residual solids. ' Soil analysis for these parameters shall be conducted once prior to permit renewal on each site which has received sludge during the permit cycle. 0 SECTION H LAND APPLICATION OF OTHER RESIDUAL SOLIDS APPLICATION FORM SBR AND DAF RESIDUAL SOLIDS WEIGHTED AVERAGE ROCCO SBR & DAF COMBINED LAORS State of North Carolina ����"" rp Department of Environment, Health and Natural Resource��"+1Fqol qE/ I/"z- Division of Environmental Management SECD Non -Discharge Permit Application Form U 2 oN (THIS FORM MAYBE PHOTOCOPIED FOR USE AS AN ORIGINAh),' QD" 9 ipSly LAND APPLICATION OF OTHER RESIDUAL SOLIDS s pe?%%V This application is intended for facilities which are EXEMPT from 40 CFR Part 503 I. GENERAL INFORMATION 1. Applicant's name (please specify the name of the municipality, corporation, individual, etc.): Rocco Farm Foods, Inc. 2. Print Owner's or Signing Official's name and title (the person who is legally responsible for the facility and its compliance): Everett Brown - General Manaeer 3. Mailing address: City: Post Office Box 9 St. Pauls State: Telephone: ( 910 ) 865-3800 4. Application Date: July, 1999 NC Zip: 28384 5. Fee Submitted: $ 325.00 [The permit processing fee should be as specified in 15A NCAC 211.0205(c)(5).] 6. Specify whether these residuals will be land applied to: X agricultural lands, _forest, _public contact sites, _reclamation sites; (Please be advised, if these residuals will be distributed for lawn or home garden use, the application for the "DISTRIBUTION OF RESIDUAL SOLIDS" should be completed rather than this application.) -. 7. If the alternative for residual disposal consists of"surface disposal" as defined under 40 CFR Part 503, please complete the application titled "SURFACE DISPOSAL OF RESIDUAL SOLIDS." Please identify if there is any storage of residuals in a surface impoundment or disposal thru landfilling. Explain: N/A 8. For Class B Residuals (or Class A Residuals to be land applied on a dedicated site), please specify the number of acres on which residual solids are to be land applied underthe authority of this permit: Proposed in this application: acres; total (current and proposed): 382.5 acres 9. County(ies) where residuals will be land applied: II. PERMIT INFORMATION 1. Application No. (will be completed by DEM): Robeson 2. Specify whether project is: new; X renewal *; modification * For renewals, complete all sections included in the application, in addition, please submit updated cumulative loadings for the ten (10) pollutants and updated owner's agreement for each site. 3. If this application is being submitted as a result of a renewal or modification to an existing permit, list the existing permit number W00003034 and its issue date April 10, 1997 FORM: LAORS 02/95 Page 1 of 18 ROCCO SBR & DAF COMBINED LAORS III. FACILITY INFORMATION (attach additional pages for additional sources of residuals): 1. Name of facility where residuals are generated or prepared: Rocco Farm Foods, Inc. - W WTP 2. Facility permit number: W00001173 facility permit holder: Rocco Farm Foods, Inc. 3. Specify whether facility in Section III.1 is owned by: _ federal; X private; _state; _ local government. 4. Specify facility design flow: MGD; facility average daily flow: 0.705 MGD; Type of residual storage: 2 - 150,000 Gallon Digesters Volume of residual storage: 300,000 Gallons Length of residuals storage at facility: 60 days (the Division requires a minimum 30 days storage in units that are separate from treatment system, i.e. not in clarifiers, aeration basins, etc.); Maximum storage time of residuals between application events: 30 - 45 days. Estimated volume of residuals: 290 (drytons/yr.); 5. Are there any other storage facilities, other than the above, currently on site: _Yes; X No. If Yes, please identify: 6. Facility contact (person familiar with residuals preparation): Barry Tyner 7. Facility contact's telephone number: ( 910 ) 865-6611 8. Location of treatment facility: St. Pauls, NC State 9. Mailing address: Post Office Box 9 St. Pauls, North Carolina 28384 10. Latitude: 340 47' 53" 11 Longitude : 780 54' 00" Robeson County Specify the source of the residuals: treatment of water (alum sludges);treatment of industrial wastewater (100% industrial residuals); X treatment of industrial wastewater mixed with domestic wastewater (please specify appropriate percentages of 98 % industrial wastewater, 2 % domestic wastewater); other (explain) : Attach an explanation of either the treatment process, manufacturing process, or how the wasteis generated. Provide full And complete details of the entire process. 12. Does the facility which generates the residuals have an approved pretreatment program? Yes; X No. This includes facilities which are classified as a "Class I" facility (any publicly owned treatment works required, under 40 CFR 403.8, to have an approved pretreatment program or any facility treating domestic sewage that is classified as "Class I" by the appropriate Federal or State authority). IV. RESIDUALS INFORMATION (attach additional pages for additional sources of residuals): Information for Hazardous Waste (RCRA) Determination. The information requested on the limitations specified below pertain only to those residuals that are generated from a municipal wastewater treatment facility with industrial contribution or active pretreatment program and from any other treatment facility with wastewater sources that include industrial sources. a. Are any of the residuals covered by this application listed in 40 CFR 261.31-261.33? _ Yes; X No. If Yes, list the number(s): *REFERENCE APPENDIX II FORM: LAORS 02/95 Page 2 of 18 ROCCO SBR & DAF COMBINED LAORS b. Do the residuals exhibit any of the four characteristics defined by 40 CFR 261.31-261.33? _Yes; X No. Attach laboratory results for the Toxicity Characteristic Leaching Procedure Analyses, Reactivity, Ignitability, and Corrosivity for each residual. Note: If the following constituent levels (as determined by the Toxicity Characteristic Leaching Procedure Analyses) are exceeded in the residuals or if the pH of the residual is not within the range listed below, the residual is by definition a Hazardous Waste. Chemical analyses must be made to Minimum Detection Levels. PPM PPM Arsenic 5.0 Barium 100.0 Benzene 0.5 Cadmium 1.0 Carbon tetrachloride 0.5 Chlordane 0.03 Chlorobenzene 100.0 Chloroform 6.0 Chromium 5.0 o-Cresol 200.0 m-Cresol 200.00 p-Cresol 200.0 Cresol 200.00 2,4-D 10.0 1,4-Dichlorobenzene 7.7 1,2-Dichloroethane 0.5 1,1-Dichloroethylene 0.7 2,4-Dinitrotoluene 0.13 Endrin 0.02 Heptachlor ( and its hydroxide) 0.008 Hexachlorobenzene 0.13 Hexachloro-1,3-butadiene 0.5 Hexachloroethane 3.0 Lead 5.0 Lindane 0.4 Mercury 0.2 Methoxychlor 10.0 Methyl ethyl ketone 200.0 Nitrobenzene 2.0 Pentachlorophenol 100.0 Pyridine 5.0 Selenium 1.0 Silver 5.0 Tetrachloroethylene 0.7 Toxaphene 0.5 Trichloroethylene 0.5 2,4,5-Trichlorophenol 400.0 2,4,6-Trichlorophenol 2.0 2,4,5-TP (Silvex) 1.0 Vinyl chloride 0.2 pH (2:1 vbl. / wt): >2.0s.u. - <l2.5 s.0 NOTE: IF ANY OF THE RESIDUALS MEET THE DEFINITIONS OF A HAZARDOUS WASTE, AS NOTED IN EITHER "A" OR "B" ABOVE, A PERMIT CANNOT BE ISSUED FOR THAT RESIDUAL AND IT SHOULD NOT BE INCLUDED AS PART OF THIS APPLICATION. 2. For each residual, please attach a complete chemical analysis of the material. This analysis must be comprehensive enough to completely characterize the residual and must be based upon a review of the process that generates the material. If the facility that will generate the residual is not yet in operation, the characterization must be based on similar existing facilities and projection based on the type of facility. The analysis must include a minimum of the following parameters and any other known and suspected contaminants that are tributary to the system. Cadmium Aluminum pH Cooper Ammonia -Nitrogen Phosphorus Lead Calcium Potassium Nickel Magnesium Sodium Zinc Nitrate -Nitrite Nitrogen TKN % Total Solids Plant available Nitrogen (by calculation) 3. Wastewater residuals shall not be applied to the land if the concentration of any pollutant in the residuals exceeds the ceiling concentrations specified in the table below. Specify the pollutant ,concentration of these residuals (attach lab analysis): From Weighted Averages Pollutant Pollutant Ceiling Concentration (mg/kg) Dry Weight Basis Pollutant Concentration (mg/kg) Dry Weight Basis Cadmium 85 1.860 Copper 4300 226.30 Lead 840 7.24 Nickel 420 21.08 Zinc 7500 404.36 FORM: LAORS 02/95 Page 3 of 18 ROCCO SBR & DAF COMBINED LAORS V. PATHOGEN REDUCTION INFORMATION (attach additional pages for additional sources of residuals): In accordance with 15A NCAC 2H. 0200 pathogen reduction can be achieved using either 40 CFR Part 257 or 40 CFR Part 503. Since the pathogen reduction requirements found in 40 CFR Part 257 (note, "Processes to Significantly Reduce Pathogens" or PSRP) are incorporated into 40 CFR Part 503, only Part 503 is listed below. Please check which of the following applies to the subject residual: _100 % Industrial Residuals with no domestic contribution ( Skip this section, proceed to Section VI ): _Residuals from the treatment of water (Alum Sludges) with no domestic contribution ( Skip this section, proceed to Section VI) X Residuals from animal processing plants ( if the residuals are being injected into the soil, please explain the process and the equipment used, skip this section and proceed to Section VI). Industrial residuals with domestic contribution In accordance with 40 CFR Part 503, a residual can not be land applied if it does not meet one of the following alternatives for Class B pathogen reduction. * Reference Section I — Residual Solids Generation and Characteristics Please specify a, b I, b2, b3, b4, b5 or c from below (submit all lab analysis, test results and calculations): a. at least seven residuals samples should be collected at the time of use and analyzed for Fecal coliforms during each monitoring period. The geometric mean of the densities of these samples will be calculated and should be less than 2,000,000 most probable number per gram of total dry solids, or less than 2,000,000 Colony Forming Units per gram of total dry solids. b.the residuals must be treated by one of the following " Process to Significantly Reduce Pathogens" (PSRP). 1. Aerobic Digestion - residuals are agitated with air or oxygen to maintain aerobic conditions for a specific mean cell residence time and temperature between 40 days at 20*C and 60 days at 15°C. 2. Air Drving - residuals are dried on sand beds or on paved or unpaved basins for a minimum of three months. During two of the three month, the ambient average daily temperature is above 0°C. 3. Anaerobic Digestion - residuals are treated in the absence of air for a specific mean cell residence time and temperature between 15 days at 35°C to 55*C and 60 days at 20*C. 4. Composting - using either the within -vessel, static aerated pile, or windrow composting methods, the temperature of the residuals is raised to 40°C or higher for five days. For four hours during the five days, the temperature in the compost pile exceeds 55°C. 5. Lime Stabilization - sufficient lime is added to the residuals to raise the pH of the residuals to 12 after two hours of contact. c.The residuals shall be treated by a process that is equivalent to a "Process to Significantly Reduce Pathogens" (PSRP), as determined by the permitting authority, based on an evaluation of the recommendations provided by the Pathogen Equivalency Committee. VI. RESIDUALS TRANSPORT AND APPLICATION: 1. How will the residuals be delivered to the application sites (leak proof trucks, etc.)? Reference Section I - "Management Plan" 2. What type of equipment will be utilized for land application? Reference Section I - "Management Plan" 3. How will the application of the residual be controlled to ensure that there is proper distribution over the site? Reference Section I - "Management Plan" FORM: LAORS 02/93 Page 4 of 18 ROCCO SBR & DAF COMBINED LAORS 4. Will the land application operation utilize a contractor who specializes in Residuals Management or will the permittee manage the program? X Contractor; _ Permittee. If a contractor is utilized, provide the name of the firm, a contact, address, and telephone number: S&ME, Inc. - Attn: Robert P. Willcox 3718 Old Battleeround Road Greensboro, NC 27410 (336) 288-7180 VII. SITE EVALUATION AND RECOMMENDED LOADING RATES: 1. The following sites are to be used for land application under this permit application [please attach map(s), see La.]: Application Area [acres] Maximum Slope Site No. County Owner/Lessee (Excluding buffers) (in percent) N/A NO NEW SITES TO BE PERMITTED. Note: If more than ten (10) sites are to be covered by this application, please attach a form listing all of the sites along with the information listed below: a. A vicinity map must be attached. ' This map must show the location of each site in relation to at least two geographical references and major intersection (numbered roads, named streams/rivers, etc.). b. For all new or modified sites, a detailed site location map must be attached delineating both total and buffered acres. This map must be drawn to scale with topographical contour intervals not exceeding ten feet of 25% of total site relief (whichever is more descriptive) and showing the property lines; all existing wells, all surface waters and drainage ways and all dwellings within 500 feet of the land application areas; and all buffers. Note: At least the following buffers must be maintained. If residuals are sprayed on the sites, larger buffers may be required: 1. 400 feet from"any habitable residence or place of public assembly under separate ownership or which is to be sold for surface residual application, 200 feet from any habitable residence or place of public assembly under separate ownership or which is to be sold for subsurface residual injection. 2. 100 feet between the disposal area and any public or private water supply source, all streams classified as WS or B, waters classified as SA or SB and any Class I or Class II impounded reservoir used as a source of drinking watent 3. 100 feet between any surface residual application area and any stream, lake, river, or natural drainage way, 50 feet between any subsurface residual injection area and any stream, lake, river, or natural drainage way.t 4. 50 feet between the residual application area and property lines for both surface and subsurface application (if the original permit was issued with the buffer distance to property line as 100 feet, updated maps must be submitted and new acreage delineated for the buffer to be reduced). 5. 10 feet between the disposal area and any interceptor drains or surface water diversions (upslope). 6. 25 feet between the disposal area and any interceptor drains or surface water diversions (downslope). 7. 25 feet between the disposal area and any groundwater lowering and surface drainage ditches. t SPECIFY THE NAME OF AND CLASSIFICATION OF THE CLOSEST DO WNSLOPE SURFACE WATERS (as established by the Environmental Management Commission) TO THE LAND APPLICATION SITE(S). USE THE ATTACHED INFORMATION SHEET (PAGE 9 OF 18) TO OBTAIN THIS INFORMATION. FORM: LAORS 02/95 Page 5 of 18 ROCCO SBR & DAF COMBINED LAORS Note: The maximum slope for land application of residuals is 10% for surface application and 18% for subsurface application. 2. For each land application site, attach a soil evaluation by a soils scientist (the evaluation must be signed by the soil scientist) which addresses soil color; the depth, thickness and type of restrictive horizons; the presence or absence of a seasonal high water table or bedrock within three vertical feet of the deepest point of residual application; pH and cation exchange capacity. If the depth to either groundwater or bedrock is less than three feet, please also attach a demonstration, using predictive calculations or modeling methods acceptable to the Director of the Division of Environmental Management, that the use of this site will not result in the contravention of classified groundwater standards as contained in NCAC 21, .0200. In no case shall the separation be less than one foot. This report must be signed by the soil scientist and submitted with application. * N/A - No new sites to be permitted. 3. For each site, please attach a project evaluation conducted by an agronomist including recommendations concerning cover crops and their ability to accept the proposed loading of liquids, solids, nitrogen, phosphorus, heavy metals, salts and any other contaminant known to be in the residual. A part of the agronomist's recommendations must be a crop management plan. This plan must determine the crops to be grown on the site(s), when they should be grown and how they should be harvested and marketed. This report must be signed by the agronomist and submitted with application. * N/A —No new sites to be permitted. 4. Attach a representative soils analysis of each site. The soils analysis shall include the following parameters, along with any other significant parameter that has been shown to be contained in the residual: Standard Soil Fertility Test includes): And the following Pollutants: PH Phosphorus Acidity Calcium Magnesium Zinc % Humic Matter Sodium Base Saturation (by calculation) Cadmium Lead Potassium Manganese Copper Cation Exchange Capacity Nickel 5. In order to assist DEM in the review of the proposed loading rates, please complete the calculations contained in the attachment titled "Calculations Work Sheet" (beginning on Page 11 of 18). If more than one residual is to be covered by this permit, additional worksheets must be attached. VI. GENERAL INFORMATION: 1. Five (5) complete copies of the permit application and five (5) copies of all required supporting information, including cover letters must be submitted or the application package will be returned as incomplete. 2. Please explain how access to the land application sites, by both people and animals, will be controlled following the application of residuals: Reference Section I - "Management Plan" a. Animals shall not be grazed on the land application sites within 30 days after the application of residuals. b. Appropriate measures must be taken to control public access to the land application sites during the active site use and for 12 months following the last application event. Such controls may include the posting of signs indicating the activities being conducted at the site. 3. Please explain the procedures that will be used to establish and maintain the buffers during the application process (i.e. will the sites be flagged): Reference Section I - "Management Plan" 4. Please attach an executed "Agreement For the Land Application of Residuals to Private Lands" for each land application site that is not owned by the applicant. A copy of the DEM approved form is attached. If the applicant wishes to use a different form or a modified form, prior approval must be received from DEM. 5. Each application site must be assigned a site identification number. 6. Attachments may be utilized to provide the information that is requested in this application form; however, if attachments are utilized, their location should be so indicated on the application form. All attachments must be numbered to correspond to the individual parts of the application that require the attachment. If the attachments are part of a larger document, a table must be provided that lists the locations of the required information. FORM: LAORS 02/95 Page 6 of 18 ROCCO SBR & DAF COMBINED LAORS Applicant's Certification: I Everett Brown attest that this application for WQ0003034 has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that if all required parts of this application are not completed and that if all required supporting information and attachments are, not included, this application package will be returned as incomplete. Signature Fpe�,O- �_zL Date THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL SUPPORTING INFORMATION AND MATERIALS, SHOULD BE SENT TO THE FOLLOWING ADDRESS: NORTH CAROLINA DIVISION OF ENVIRONMENTAL MANAGEMENT WATER QUALITY SECTION PERMITS AND ENGINEERING UNIT POST OFFICE BOX 29535 RALEIGH, NORTH CAROLINA 27626-0535 TELEPHONE NUMBER: (919) 733-5083 FAX NUMBER: (919) 733-9919 FORM: LAORS 02/95 Page 7 of 18 ROCCO SBR & DAF COMBINED LAORS Instructions: Processing of this application will not be initiated until five (5) copies of all of the following items have been submitted in addition to five (5) copies of the completed application form. If any of the below items have been excluded from the package, please explain. 1. Is a general location map included? YES or NO X Items checked "No" are not applicable - Permit Renewal only 2. Is a site map (drawn to scale) included which delineates total and buffered acres and shows all property lines, buffers, existing wells within 500 feet, topography, drainage features, and any surface waters? YES or NO X 3. Is a vicinity map enclosed which clearly indicates the project's location with respect to State roads and named Surface waters? YES or NO X 4. Is a signed soil scientist report included which defines the following: a) field descriptions of texture, color, and structure, b) depth and thickness of soil horizons, c) presence of any restrictive soil horizons or layers, d) depth to seasonal high water table, e) the hydraulic conductivity, f) recommended loading rate for the site, YES or NO X 5. Is a signed agronomist's report included which identifies the crop and loading recommendations for N-P-K? YES or NO X 6. Is the Crop Management Plan included in the application package? YES or NO X Has the Land Owner's agreement been completed and signed? YES X or NO 8. Appropriate fee in accordance with 15A NCAC 2H .0205(c)(5)-(eff. February 1, 1993): New Applications, Modifications or Late Renewals $400.00 Timely Renewals without Modifications $250.00 YES X or NO 9. Five (5) copies of all reports, evaluations, agreements, supporting calculations, etc. must be included as a part of the application package. FORM: LAORS 02/95 Page 8 of 18 ROCCO SBR & DAF COMBINED LAORS This form must be completed by the appropriate Regional Office and included with the submission of the application package. N/A - No new sites (Permit Renewal) INSTRUCTIONS TO APPLICANT In order to determine the classification of the watershed in which these land application activities will be located, you are required to submit this form, with items 1 through 8 completed, to the appropriate Division of Environmental Management Regional Water Quality Supervisor (see attached listing). At a minimum, you must include an 8.5" by I I" copy of the portion of a 7.5 minute USGS Topographic Map which shows the subject surface waters. You must identify the location of the facility and the closest downslope surface waters (waters for which you are requesting the classification) on the submitted map copy. The application may not be submitted until this form is completed and included with the submittal. 1. Applicant (please specify the name of the municipality, corporation, individual, or other): 2. Name and Complete Address of Applicant: City: Telephone Number: ( ) 3. Project Name: State: 4. Volume of residuals to be land applied: 5. Name of closest surface waters: 6. County(s) where land application site is located: 7. Map name and date: 8. Applicant Signature: TO: REGIONAL WATER QUALITY SUPERVISOR Zip: dry tons per year Please provide me with the classification of the watershed where these land application activities Will occur, as identified on the attached map segment: Name of surface waters: Classification (as established by the Environmental Management Commission): Proposed Classification, if applicable: Signature of regional office personnel: Date: FORM: LAORS 02/95 Page 9 of 18 ROCCO SBR & DAF COMBINED LAORS DIVISION OF ENVIRONMENTAL MANAGEMENT REGIONAL OFFICES (12/94) Asheville Regional WQ Supervisor 59 Woodbin Place Asheville, NC 28801 (704)251-6208 Fax (704) 251-6452 Avery Macon Buncombe Madison Burke McDowell Caldwell Mitchell Cherokee Polk Clay Rutherford Graham Swain Haywood Transylvania Henderson Yancy Jackson Fayetteville Regional WQ Supervisor Wachovia Building, Suite 714 Fayetteville, NC 28301 (910)486-1541 Fax (910) 486-0707 Anson Moore Bladen Robeson Cumberland Richmond Harnett Sampson Hoke Scotland Montgomery Washington Regional WQ Supervisor Post Office Box 1507 Washington, NC 27889 (919)946-6481 Fax (919)975-3716 Beauport Jones Bertie Lenoir Camden Martin Chowan Pamlico Craven Pasquotank Currituck Perquimans Dare Pitt Gates Tyrell Greene Washington Hertford Wayne Hyde Mooresville Regional WQ Supervisor 919 North Main Street Mooresville, NC 28115 (704) 663-1699 Fax (704) 663-6040 Alexander Mecklenburg Cabarrus Rowan Catawba Stanly Gaston Union Iredell Cleveland Lincoln Winston-Salem Regional WQ Supervisor 585 Waughtown Street Winston-Salem, NC 27107 (910)771-4600 Fax (910)771-4631 Alamance Rockingham Alleghany Randolph Ashe Stokes Caswell Surry Davidson Watauga Davie Wilkes Forsyth Yadkin Guilford Raleigh Regional WQ Supervisor Post Office Box 27687 Raleigh, NC 27611 (919)571-4700 Fax (919) 571-4718 Chatham Nash Durham Northampton Edgecombe Orange Franklin Person Granville Vance Halifax Wake Johnston Warren Lee Wilson Wilmington Regional WQ Supervisor 127 Cardinal Drive Extension Wilmington, NC 28405-3845 (910)395-3900 Fax (910) 350-2004 Brunswick New Hanover Carteret Onslow Columbus Pender Duplin FORM: LAORS 02/95 Page 10 of 18 ROCCO SBR & DAF COMBINED LAORS CALCULATIONS WORK SHEET This work sheet is designed to assist the Division of Environmental Management in reviewing this application as expeditiously as possible. Its preparation in a complete and accurate manner is critical to this review. For permits that cover multiple sources of residuals or different residuals from the same source, use additional work sheets. A. List the specific residual that is covered by these calculations (place or process of origin) Rocco Farm Foods, Inc. SBR & DAF Residual Solids Weighted Average What are the total dry tons of this residual to be land applied each year? Total Dry Tons = Gallons of Residuals * % Solids * 8.34 lbs./gallon produced annually 100 2,000 lbs./ton Total Dry Tons = * _ * 8.34 IbsJgallon 100 2,000 lbs./ton = 290 Dry Tons per year Weighted Average DT/Year * SBR Residual Solids 40 (14%) * DAF Residual Solids 250 (86%) Total 290 (100%) If the quantity of residual will vary significantly or if there will be a larger initial application, please attach a detailed explanation and provide calculations for each variation. B. Complete the following calculations to establish the portion of the residual that is made up of the various parameters: % Total Solids = 7.67 (.14 X.36) + (.86 X 8.86) = 7.67 (PLEASE NOTE THAT ALL CONSTITUENTS ARE TO BE IN TOTAL CONCENTRATIONS) PARAMETER mg/L _ % Solids (Decimal) = mg/kg (dry wt.) x 0.002 = lbs./dry ton Cadmium = 1.860 x 0.002 = 0.004 Copper = 226.3 x 0.002 = 0.453 Lead = 7.24 x 0.002 = 0.014 Nickel = 21.08 x 0.002 = 0.042 Zinc = 404.36 x 0.002 = 0.809 Ammonia-N = 20,770 x 0.002 = 41.540 Calcium = 9,470 x 0.002 = 18.940 Magnesium = 2,214 x 0.002 = 4.428 NO3-NO2-N = 2,127 x 0.002 = 4.254 Phosphorus = 12,670 x 0.002 = 25.340 Potassium = 2,552 x 0.002 = 5.104 Sodium = 2,352 x 0.002 = 4.704 TKN = 57,466 x 0.002 = 114.932 OTHER: = x 0.002 = x 0.002 = x 0.002 = FORM: LAORS 02/95 Page 11 of 18 ROCCO: SBR & DAF COMBINED FLOW CALCULATION SHEET Parameters Arsenic Cadmium Chromium Copper Lead Mercury Molybdenum Nickel Selenium Zinc Ammonia-N Calcium Magnesium NO,NO,-N Phosphorus Potassium Sodium TKN Weighted Averages Facili % Avg. SBR 14.0� DAF 86.0 SBR DAF SBR DAF me/ke me/ke 0.560 0.001 1.000 2.000 72.000 20.000 523.000 178.000 21.000 5.000 0.380 0.620 11.000 5.000 40.000 18.000 2.310 0.480 1,070.000 296.000 11 111 :11 III 11 111 11 111 1 •11 111 :11 111 • . 111 � . 111 • 11 111 : , ff, 111 11 111 •11 111 11 111NS 11 1/1 :1 .11 111 11 111 R186-071 R214-193 0.078 0.001 0.140 1.720 10.080 17.200 73.220 153.080 2.940 4.300 0.053 0.533 1.540 4.300 5.600 15.480 0.323 0.413 149.800 254.560 1,162.000 19,608.000 1,988.000 7,482.000 1,526.000 688.000 2,088.240 39.560 5,446.000 7,224.000 1,778.000 774.000 1,750.0001 602.000 11,284.000 46,182.000 m¢/ke 0.079 1.860 27.280 226.300 7.240 0.586 5.840 21.080 0.736 404.360 20,770.000 9,470.000 2,214.000 2,127.800 12,670.000 2,552.000 2,352.000 57,466.000 Page Ila of 18 ROCCO: SBR & DAF COMBINED FLOW CALCULATION SHEET Parameters Arsenic Cadmium Chromium Copper Lead Mercury Molybdenum Nickel Selenium Zinc Ammonia-N Calcium Magnesium NO3NO3-N Phosphorus Potassium Sodium TKN Weighted Averages Facility % Ave. SBR 14.0 DAF 86.0 SBR DAF Original lbs./dry ton 0.001 0.001 0.002 0.004 0.144 0.040 1.046 0.356 0.042 0.010 0.001 0.001 0.022 0.010 0.080 0.036 0.005 0.001 2.140 0.592 16.600 45.600 28.400 17.400 21.800 1.600 29.832 0.092 77.800 16.800 25.400 1.800 25.0001 1.400 161.2001 107.400 R186-071 R214-193 SBR DAF Weighted lbs./dry ton 1 111 1 11 1 111Emoff, Me 11 1 11 1 .Nm1 1. • 1 111 1 11 1 = 1 11• 11 11 1 11 1 11 1 11 1 1• 2.324 39.216 3.976 14.964 3.052 1.376 4.176 0.079 10.892 14.448 3.556 1.548 3.5001 1.204 22.5681 92.364 41.540 18.940 4.428 4.255 25.340 5.104 4.704 114.932 Page 11b of 18 ROCCO SBR & DAF COMBINED LAORS C. Plant Available Nitrogen (PAN) calculations and land application area requirements: 1. Mineralization Rate (MR) 38.5 % (These values can be established for the specific residual or default values can be used for domestic wastewater treatment residuals. If actual values are established, attach the documentation. The default values are as follows): Unstabilized Primary and Secondary Residuals 40% Aerobically Digested Residuals 30% Anaerobically Digested Residuals 20% Composted Residuals 10% (If the default values are used, attach an explanation as to why the specific chosen default value is appropriate.) 2. Complete the following calculations for the application method proposed (Please note, the Mineralization Rate [MR] should be utilized in the following calculations as a decimal): PAN for Surface Application PAN = [(MR) X (TKN — NH3)] + .5 X (NH3) + (NO; NOz N) PAN = [ .39 X ( 57,466 - 20,770 )] +.5X ( 20,770 ) + 2,127 PAN = 26.823 PPM Dry Weight PAN for Subsurface Application PAN = [(MR) X (TKN — NH3)] + (NH3) + (NO3 NOz N) PAN = [ .39 X ( 57,466 - 20,770 )] + ( 20,770 ) + 2,127 PAN = 37,208 PPM DryWeight 3. Total PAN to be land applied per year Total dry tons of residual to be land applied per year: 290 Total PAN in pounds = (PAN in me/kg Dry Weight) X 2000 Pounds / Ton per dry ton 1,000,000 = (PAN in PPM Dry Weight) X 0.002 = 74.42 Pounds/Dry Ton/Year Total PAN in pounds = (PAN in Pounds / Dry Ton) X Total tons of residual to be land applied — 74.42 X 290 = 21,002 Pounds/Year Due to the fact that organic nitrogen is mineralized slowly over time, the amount of nitrogen that comes available in years following the initial application must be taken into consideration when calculating application rates for the subsequent years. This being the case, please attach an evaluation of this factor and its impact on loading rates. Show the adjusted PAN for at least five years. The maximum adjusted annual PAN is 26,126 Pounds/Year. FORM: LAORS 02/95 Page 12 of 18 S&ME, Inc. Greensboro, North Carolina RESIDUAL PAN CALCULATION Rocco Farm Foods, Inc. SBR and DAF Residuals WeiEhted Average TKN= 57,466 mg/kg NH3= 20,770 mg/kg NO3-NO2-N= 2,127.00 mg/kg Min Rate= 0.39 PAN= [min.rate (TKN - NH3) + 0.5 (NH3) + NO3-NO21 * 0.002 0.39 36,696 10,385 2127.00 PAN= 53.28 LBS/DT Calculate residual nitrogen for years 2,3,4 and 5 following the initial application to determine the amount of PAN/DT remaining. 2ND YEAR RESIDUAL PAN PAN= [min.rate (1st year org. - N 2nd year min. - N] * 0.002 0.19 36,696 14,128 PAN= 8.69 LBS/DT remaining from 1 st year application 3RD YEAR RESIDUAL PAN PAN= [min.rate (2nd year org. - N 3rd year min. - N] * 0.002 0.10 22,568 4,344 PAN= 3.74 LBS/DT remaining from 1st year application 4TH YEAR RESIDUAL PAN PAN= [min.rate (3rd year org. - N 4th year min. -`NJ * 0.002 0.06 18,224 1,871 PAN= 2.10 LBS/DT remaining from lstyear application 5TH YEAR RESIDUAL PAN PAN= [min.rate (4th year org. - N 5th year min. - N] * 0.002 0.04 16,353 1,049 PAN= 1.14 LBS/DT remaining from 1 st year application Residual PAN from years 2 thru 5 after the initial application = 15.67 Lbs/Pan/DT Page 12a of 18 ROCCO SBR & DAF COMBINED LAORS 4. Crop information on nitrogen uptake per year Crop(s) Alfalfa Bermuda Grass (Hay, Pasture) Blue Grass Corn (Grain) Com (Silage) Cotton Fescue Forest (Hardwood & Softwood) Milo Small Grain (Wheat, Barley, Oats) Sorghum, Sudex (Pasture) Sorghum, Sudex (Silage) Soybeans Timothy, Orchard, & Rye Grass Coastal Bermuda (Division Recommendations) (Provide for the Crops Specified) PAN (lbs./acre/year) PAN (lbs./acre/year) 200 200 220 220 120 120 160 160 200 200 70 70 250 250 75 75 100 100 100 100 180 180 220 220 200 200 200 200 350 350 Please provide the basis for the uptake rates used if different than Division Recommendation: 5. Total acres needed to land apply the pounds of available nitrogen calculated above Total acres needed = Maximum total pounds of plant available nitrogen (PAN) Pounds of nitrogen needed for crop* 26,126 lbs. PAN/100 lbs. PAN/AC Minimum acres needed based on most restrictive PAN = 262 acres * This value must be the value for the crop to be grown that has the lowest nitrogen uptake rate per acre. If there are various crops that will only be utilized for certain sites, please attach the calculations for each site and determine the total needed acres using the format outlined below. D. Calculate the Sodium Adsorption Ratio (SAR) (** This section must be completed in mg/I, to convert: mg/kg X % solids [as a decimal] = mg/I **) SAR = Na Milli Equivalent _ [0.5 (Ca Milli Equivalent + Mg Milli Equivalent)]" CONCENTRATION (mg/1) + Equivalent Weight = Milli Equivalents of Ion SODIUM (Na) 180.39 (mg/1) + 23 = 7.843 CALCIUM (Ca) 726.35 (mg/1) = 20 = 36.317 MAGNESIUM(Mg 169.81 (mg/1)+ 12 = 14.151 SAR = 1.561 If calculation sheets are being completed for more than one residual or site, please attach a summary sheet that brings the results of all the calculations sheets to one point. FORM: LAORS 02/95 Page 13 of 18 SAR SAR Calculation Nam ll Ca m ll34 Mg mgll 180.3984 726.9 169.8138 Na Ca Mg SAR 7.843 36.317 14.151 1.561 INa mil eq ICa mil eq Mg mil eq 7.843 36.317 14.151 Enter Enter % TS 1 7.67 Data Na mq/kq 2352 Ca mgikg 9470 Mg mg/kg 2214 Job Name: Rocco Farm Foods, Inc. SBR and DAF Residuals Weighted Average Page 13ix of 1S ROCCO SBR & DAF COMBINED LAORS E. Determine the Site Life for this land application site: The lifetime pollutant loadings shall not be exceeded. The site life is determined by calculating the number of years that the site can receive the residual without exceeding the lifetime pollutant loadings. The site life calculations will be based on the most restrictive crop plant available nitrogen (PAN) requirement specified and the maximum dry tons or residuals to be land applied annually. Therefore, in the table below the Tons of Residuals to be Applied/Acre/Year will be calculated as: 1. Most restrictive crop based on the plant available nitrogen (PAN) requirement: Small Grains Associated plant available nitrogen (PAN) requirement: 100 (lbsJacre/year) 2. Minimum acres needed based on most restrictive PAN (as found in C.5 above): 262 acres 3. Dry Tons of Residuals to be land applied per year: 290 dry tons per year 4. Tons of Residuals to be Applied/Acre/Year = Dry Tons/Year of Residuals to be land analied Minimum number of acres required for land application Tons of Residuals to be Applied/Acre/Year = 1.11 If any of the application sites are to be loaded at greater than the rate specified above, please specify the loading rate and explain: Tons of Residuals to be Applied/Acre/Year (different from above) _ Explanation: For the purpose of site life determination, the lifetime pollutant loadings shall not exceed the following for the corresponding Cation Exchange Capacities (CEC). Site life for the site covered by this application shall be determined by using the lowest CEC. The appropriate column should be chosen and applied in the "Allowable Lifetime Pollutant Loadings based on CEC" in the table below: CEC<5 CEC5-15 CEC> 15 Pollutant Pbs / acre) (Ibs / acre) (Ibs / acre) Lead 500 1,000 2,000 Zinc 250 500 1,000 Copper 125 250 500 Nickel 125 250 500 Cadmium 4.5 9 18 In the table below, the highest annual loading (Tons of Residuals to be Applied/Acre/Year) specified above, will be multiplied by the Ibs./dry ton of each pollutant as found in B above. The Site Life can then be determined by: Site Life (Years) = Allowable Lifetime Loadings (lbs./acre) Projected Pounds to be Applied/Acre/Year Pollutant Tons of lbs./dry ton of each Projected Allowable Lifetime Residuals to be pollutant Pounds to be Pollutant Loadings Site Life Applied per (as found in Part B Applied/Acre Based on CEC. (Years) Acre per Year above) /Year From Chart Above (Ibs./acre) Lead 1.11 ' 0.014 = 0.0155 500 = 32,258 Zinc I.11 ' 0.809 = 0.8980 250 = 278 Copper 1.11 ' 0.453 = 0.5023 125 = 249 Nickel l.11 ' 0.042 = 0.0466 125 = 2,632 Cadmium 1.11 ' 0.004 = 0.0044 4.5 = 1,023 Compare the nine (9) pollutants above and determine which pollutant will result in the shortest life for this site. The Limiting Pollutant is Copper The Site Life is 249 years. FORM: LAORS 02/95 Page 14 of 18 SECTION III CALCULATIONS WORKSHEET SBR RESIDUAL SOLIDS CALCULATIONS WORK SHEET This work sheet is designed to assist the Division of Environmental Management in reviewing this application as expeditiously as possible. Its preparation in a complete and accurate manner is critical to this review. For permits that cover multiple sources of residuals or different residuals from the same source, use additional work sheets. A. List the specific residual that is covered by these calculations (place or process of origin) Rocco Farm Foods, Inc. SBR Residual Solids What are the total dry tons of this residual to be land applied each year? Total DryTons = Gallons of Residuals * % Solids* 8.34 lbs./gallon. produced annually 100 2,000 lbs./ton Total Dry Tons = * _ * 8.34 lbs./gallon 2,000 lbs./ton 40 Dry Tons per year If the quantity of residual will vary significantly or if there will be a larger initial application, please attach a detailed explanation and provide calculations for each variation. B. Complete the following calculations to establish the portion of the residual that is made up of the various parameters: %Total Solids = 0.36 (PLEASE NOTE THAT ALL CONSTITUENTS ARE TO BE IN TOTAL CONCENTRATIONS) PARAMETER mg/L = % Solids (Decimal) = mg/kg (dry wt.) x 0.002 = lbs./dry ton Cadmium = 1.000 x 0.002 = 0.002 Copper = 523.000 x 0.002 = 1.046 Lead = 21.000 x 0.002 = 0.042 Nickel = 40.000 x 0.002 = 0.080 Zinc = 1,070.000 x 0.002 = 2.140 Ammonia-N = 8,300.000 x 0.002 = 16.600 Calcium = 14,200.000 x 0.002 = 28.400 Magnesium = 10,900.000 x 0.002 = 21.800 NO3-NO2-N = 14,916.000 x 0.002 = 29.832 Phosphorus = 38,900.000 x 0.002 = 77.800 Potassium = 12,700.000 x 0.002 = 25.400 Sodium = 12,500.000 x 0.002 = 25.000 TKN = 80,600.000 x 0.002 = 161.20 OTHER: - x 0.002 = x 0.002 = x 0.002 = FORM: LAORS 02/95 1Page 11 of 18 C. Plant Available Nitrogen (PAN) calculations and land application area requirements: 1. Mineralization Rate (MR) 30 % (These values can be established for the specific residual or default values can be used for domestic wastewater treatment residuals. If actual values are established, attach the documentation. The default values are as follows): Unstabilized Primary and Secondary Residuals 40% Aerobically Digested Residuals 30% Anaerobically Digested Residuals 20% Composted Residuals 10% (If the default values are used, attach an explanation as to why the specific chosen default value is appropriate.) 2. Complete the following calculations for the application method proposed (Please note, the Mineralization Rate [MR] should be utilized in the following calculations as a decimal): PAN for Surface Application PAN = [(MR) X (TKN — NH3)] + .5 X (NH3) + (NO,-NO2N) PAN = [ 0.3 X ( 80600 - 8,300 )] + .5X ( 8,300 ) + 14,916 PAN = 40,756 PPM Dry Weight PAN for Subsurface Application PAN = [(MR) X (TKN — NH3)] + (NH3) + (NOrNOI-N) PAN = [ 0.3 X ( 80600 - 8,300 )] + ( 8,300 ) + 14916 PAN = 44,906 PPM Dry Weight 3. Total PAN to be land applied per year Total dry tons of residual to be land applied per year: 40 Total PAN in pounds = (PAN in mg/kg Dry Weight) X 2000 Pounds / Ton per dry ton 1,000,000 _ (PAN in PPM Dry Weight) X 0.002 = 81.51 Pounds/Dry Ton/Year Total PAN in pounds = (PAN in Pounds / Dry Ton) X Total tons of residual to be land applied 81.51 X 40 = 3260 Pounds/Year Due to the fact that organic nitrogen is mineralized slowly over time, the amount of nitrogen that comes available in years following the initial application must be taken into consideration when calculating application rates for the subsequent years. This being the case, please attach an evaluation of this factor and its impact on loading rates. Show the adjusted PAN for at least five years. The maximum adjusted annual PAN is 4389 Pounds/Year. FORM: LAORS 02195 Page 12 of 18 S&ME, Inc. Greensboro, North Carolina RESIDUAL PAN CALCULATION Rocco Farm Foods, Inc. SBR Residual Solids THIN= 80,600 mg/kg NH3= 8,300 mg/kg NO3-NO2-N= 14,916.00 mg/kg Min Rate= 0.30 PAN= [min.rate (TKN - NH3) + 0.5 (NH3) + NO3-NO21 * 0.002 0.30 72,300 4,150 14916.0 PAN= 81.51 LBS/DT Calculate residual nitrogen for years 2,3,4 and 5 following the initial application to determine the amount of PAN/DT remaining. 2ND YEAR RESIDUAL PAN PAN= [min.rate (1st year org. - N 2nd year min. - N1 * 0.002 0.15 72,300 21,690 PAN= 15.18 LBS/DT remaining from 1 st year application 3RD YEAR RESIDUAL PAN PAN= [min.rate (2nd year org. - N 3rd year min. - N1 * 0.002 0.08 50,610 7,592 PAN= 6.88 LBS/DT remaining from 1st year application 4TH YEAR RESIDUAL PAN PAN= [min.rate (3rd year org. - N 4th year min. - N1 * 0.002 0.05 43,019 3,441 PAN= 3.96 LBS/DT remaining from 1st year application 5TH YEAR RESIDUAL PAN PAN= [min.rate (4th year org. - N 5th year min. - N1 * 0.002 0.03 39,577 1,979 PAN= 2.19 LBS/DT remaining from 1st year application Residual PAN from years 2 thru 5 after the initial application = 28.21 Lbs/Pan/DT 4. Crop information on nitrogen uptake per year Crop(s) Alfalfa Bermuda Grass (Hay, Pasture) Blue Grass Corn (Grain) Corn (Silage) Cotton Fescue Forest (Hardwood & Softwood) Milo Small Grain (Wheat, Barley, Oats) Sorghum, Sudex (Pasture) Sorghum, Sudex (Silage) Soybeans Timothy, Orchard, & Rye Grass Coastal Bermuda (Division Recommendations) PAN (lbs./acre/year) 200 220 120 160 200 70 250 75 100 100 180 220 200 200 350 (Provide for the Crops Specified) PAN (ibs./acre/year) 200 220 Please provide the basis for the uptake rates used if different than Division Recommendation: 5. Total acres needed to land apply the pounds of available nitrogen calculated above Total acres needed = Maximum total pounds of plant available nitrogen (PAN) Pounds of nitrogen needed for crop* 4,389/100 160 200 75 100 100 180 220 200 200 350 Minimum acres needed based on most restrictive PAN = 44 acres * This value must be the value for the crop to be grown that has the lowest nitrogen uptake rate per acre. If there are various crops that will only be utilized for certain sites, please attach the calculations for each site and determine the total needed acres using the format outlined below. D. Calculate the Sodium Adsorption Ratio (SAR) (** This section must be completed in mg/l, to convert: mg/kg X % solids [as a decimal] = mg/1 **). SAR =Na Milli Equivalent _ [0.5 (Ca Milli Equivalent +Mg Milli Equivalent)]° 5 CONCENTRATION (mg/1)+ Equivalent Weight = SODIUM (Na) 45.00 (mg/1) = 23 = CALCIUM (Ca) 51.12 (mg/1) _ 20 = MAGNESIUM(Mg 39.24 (mg/1) _ 12 = SAR = 1.15 Milli Equivalents of Ion 1.96 2.56 3.27 If calculation sheets are being completed for more than one residual or site, please attach a summary sheet that brings the results of all the calculations sheets to one point. FORM: LAORS 02/95 Page 13 of 18 SAR SAR Calculation Na mg/l Ca mg/I Mg mg/I 45 51.12 39.24 Na Ca Mg SAR 1.957 2.556 3.270 1.146 Na mil eq Ca mil eq Mg mil eq 1.957 2.556 3.270 Enter Enter % TS Na mg/kg 0.36 12500 Data Ca mg/kg 14200 Mg mg/kg 10900 Job Name: Rocco Farm Foods, Inc. SBR Residual Solids Page 2 E. Determine the Site Life for this land application site: The lifetime pollutant loadings shall not be exceeded. The site life is determined by calculating the number of years that the site can receive the residual without exceeding the lifetime pollutant loadings. The site life calculations will be based on the most restrictive crop plant available nitrogen (PAN) requirement specified and the maximum dry tons or residuals to be land applied annually. Therefore, in the table below the Tons of Residuals to be Applied/Acre/Year will be calculated as: 1. Most restrictive crop based on the plant available nitrogen (PAN) requirement: Small Grains Associated plant available nitrogen (PAN) requirement: 100 (lbsJacre/year) 2. Minimum acres needed based on most restrictive PAN (as found in C.5 above): 44 acres 3. Dry Tons of Residuals to be land applied per year: 40 dry tons per year 4. Tons of Residuals to be Applied/Acre/Year = Dry Tons/Year of Residuals to be land annlied Minimum number of acres required for land application Tons of Residuals to be Applied/Acre/Year = 0.91 If any of the application sites are to be loaded at greater than the rate specified above, please specify the loading rate and explain: Tons of Residuals to be Applied/Acre/Year (different from above) _ Explanation: For the purpose of site life determination, the lifetime pollutant loadings shall not exceed the following for the corresponding Cation Exchange Capacities (CEC). Site life for the site covered by this application shall be determined by using the lowest CEC. The appropriate column should be chosen and applied in the "Allowable Lifetime Pollutant Loadings based on CEC" in the table below: CEC <5 CEC5-15 CEC> 15 Pollutant (Ibs / acre) Obs / acre) (lbs / acre) Lead 500 1,000 2,000 Zinc 250 500 1,000 Copper 125 250 500 Nickel 125 250 500 Cadmium 4.5 9 18 In the table below, the highest annual loading (Tons of Residuals to be Applied/Acre/Year) specified above, will be multiplied by the Ibs./dry ton of each pollutant as found in B above. The Site Life can then be determined by: Site Life (Years) = Allowable Lifetime Loadings (Ibs./acre) Projected Pounds to be Applied/Acre/Year Pollutant Tons of lbs./dry ton of each Projected Allowable Lifetime Residuals to be pollutant Pounds to be Pollutant Loadings Site Life Applied per (as found in Part B Applied/Acre Based on CEC. (Years) Acre per Year above) /Year From Chart Above (lbsJacre) Lead 0.91 * 0.042 = 0.0382 500 = 13,089 Zinc 0.91 * 2.140 = 1.9474 250 = 128 Copper 0.91 * 1.046 = 0.9519 125 = 131 Nickel 0.91 * 0.080 = 0.0728 125 = 1,717 Cadmium 0.91 * 0.002 = 0.0018 4.5 = 2,500 Compare the nine (9) pollutants above and determine which pollutant will result in the shortest life for this site. The Limiting Pollutant is zinc The Site Life is 128 years. FORM: LAORS 02/95 Page 14 of 18 SECTION IV CALCULATIONS WORKSHEET DAF RESIDUAL SOLIDS CALCULATIONS WORK SHEET This work sheet is designed to assist the Division of Environmental Management in reviewing this application as expeditiously as possible. Its preparation in a complete and accurate manner is critical to this review. For permits that cover multiple sources of residuals or different residuals from the same source, use additional work sheets. A. List the specific residual that is covered by these calculations (place or process of origin) Rocco Farm Foods, Inc. DAF Residuals Solids What are the total dry tons of this residual to be land applied each year? Total Dry Tons = Gallons of Residuals * % Solids * 8.34 lbs./gallon produced annually 100 2,000 lbs./ton Total Dry Tons = * _ * 8.34 lbs./gallon 2,000 lbs./tan = 250 DryTons per year If the quantity of residual will vary significantly or if there will be a larger initial application, please attach a detailed explanation and provide calculations for each variation. B. Complete the following calculations to establish the portion of the residual that is made up of the various parameters: % Total Solids = 1 8.86 (PLEASE NOTE THAT ALL CONSTITUENTS ARE TO BE IN TOTAL CONCENTRATIONS) PARAMETER mg/L _ % Solids (Decimal) = mg/kg (dry wt.) x 0.002 = Ibs./dry ton Cadmium = 2.000 x 0.002 = 0.004 Copper = 178.000 x 0.002 = 0.356 Lead = 5.000 x 0.002 = 0.010 Nickel = 18.000 x 0.002 = 0.036 Zinc = 296.000 x 0.002 = 0.592 Ammonia-N = 22,800.000 x 0.002 = 45.600 Calcium = 8,700.000 x 0.002 = 17.400 Magnesium = 800.000 x 0.002 = 1.600 NO3-NO2-N = 46.000 x 0.002 = 0.092 Phosphorus = 8,400.000 x 0.002 = 16.800 Potassium = 900.000 x 0.002 = 1.800 Sodium = 700.000 x 0.002 = 1.400 TKN = 53,700.000 x 0.002 = 107.40 OTHER: = x 0.002 = x 0.002 = x 0.002 = FORM: LAORS 02/95 Page 11 of 18 C. Plant Available Nitrogen (PAN) calculations and land application area requirements: 1. Mineralization Rate (MR) 40 % (These values can be established for the specific residual or default values can be used for domestic wastewater treatment residuals. If actual values are established, attach the documentation. The default values are as follows): Unstabilized Primary and Secondary Residuals 40% Aerobically Digested Residuals 30% Anaerobically Digested Residuals 20% Composted Residuals 10% (If the default values are used, attach an explanation as to why the specific chosen default value is appropriate.) 2. Complete the following calculations for the application method proposed (Please note, the Mineralization Rate [MR] should be utilized in the following calculations as a decimal): PAN for Surface Application PAN = [(MR) X (TKN — NH3)] + .5 X (NH3) + (NO3-NO2-N) PAN = [ 0.4 X ( 53700 - 22800 )] +.5$ ( 22800 ) + 46 PAN = 23,806 PPM Dry Weight PAN for Subsurface Application PAN = [(MR) X (TKN — N113)] + (NH3) + (NO3 No.-N) PAN = [ 0.4 X ( 53700 - 22800 )] + ( 22800 ) + 46 PAN = 35,206 PPM Dry Weight 3. Total PAN to be land applied per year Total dry tons of residual to be land applied per year: 250 Total PAN in pounds = (PAN in mg/kg Dry Weight) X 2000 Pounds / Ton per dry ton 1,000,000 = (PAN in PPM DryWeight) X 0.002 47.61 Pounds/DryTon/Year Total PAN in pounds = (PAN in Pounds / Dry Ton) X Total tons of residual to be land applied 47.61 X 250 = 11903 Pounds/Year Due to the fact that organic nitrogen is mineralized slowly over time, the amount of nitrogen that comes available in years following the initial application must be taken into consideration when calculating application rates for the subsequent years. This being the case, please attach an evaluation of this factor and its impact on loading rates. Show the adjusted PAN for at least five years. The maximum adjusted annual PAN is 15230 Pounds/Year. FORM: LAORS 02/95 Page 12 of 18 S&ME, Inc. Greensboro, North Carolina RESIDUAL PAN CALCULATION Rocco Farm Foods, Inc. DAF Residual Solids TKN= 53,700 mg/kg NH3= 22,800 mg/kg NO3-NO2-N= 46.00 mg/kg Min Rate= 0.40 PAN= [min.rate (TKN - NH3) + 0.5 (NH3) + NO3-NO2[ * 0.002 0.40 30,900 11,400 46.00 PAN= 47.61 LBS/DT Calculate residual nitrogen for years 2,3,4 and 5 following the initial application to determine the amount of PAN/DT remaining. 2ND YEAR RESIDUAL PAN PAN= [min.rate (1st year org. - N 2nd year min. - N] * 0.002 0.20 30,900 12,360 PAN= 7.42 LBS/DT remaining from 1st year application 3RD YEAR RESIDUAL PAN PAN= [min.rate (2nd year org. - N 3rd year min. - N] * 0.002 0.11 18,540 3,708 PAN= 3.16 LBS/DT remaining from 1st year application 4TH YEAR RESIDUAL PAN PAN= [min.rate (3rd year org. -.N 4th year mini. - N[ * 0.002 0.07 14,832 1,582 PAN= 1.77 LBS/DT remaining from 1st year application 5TH YEAR RESIDUAL PAN PAN= [min.rate (4th year org. - N 5th year min. - N] * 0.002 0.04 13,250 883 PAN= 0.96 LBS/DT remaining from Istyear application Residual PAN from years 2 thru 5 after the initial application = 13.31 Lbs/Pan/DT Ipa,0-12R 4. Crop information on nitrogen uptake per year Crop(s) Alfalfa Bermuda Grass (Hay, Pasture) Blue Grass Corn (Grain) Corn (Silage) Cotton Fescue Forest (Hardwood & Softwood) Milo Small Grain (Wheat, Barley, Oats) Sorghum, Sudex (Pasture) Sorghum, Sudex (Silage) Soybeans Timothy, Orchard, & Rye Grass Coastal Bermuda (Division Recommendations) PAN (lbsJacre/year) 200 220 120 160 200 70 250 75 100 100 180 220 200 200 350 (Provide for the Crops Specified) PAN (lbs./acre/year) 200 220 120 160 200 70 250 75 100 100 180 220 200 200 350 Please provide the basis for the uptake rates used if different than Division Recommendation: 5. Total acres needed to land apply the pounds of available nitrogen calculated above Total acres needed = Maximum total pounds of plant available nitrogen (PAN) Pounds of nitrogen needed for crop* 15,230/100 Minimum acres needed based on most restrictive PAN = 153 acres * This value must be the value for the crop to be grown that has the lowest nitrogen uptake rate per acre. If there are various crops that will only be utilized for certain sites, please attach the calculations for each site and determine the total needed acres using the format outlined below. D. Calculate the Sodium Adsorption Ratio (SAR) (** This section must be completed in mg/l, to convert: mg/kg X % solids [as a decimal] = mg/1 **) SAR = Na Milli Equivalent = [0.5 (Ca Milli Equivalent + Mg Milli Equivalent)]" CONCENTRATION (mg/1) _ Equivalent Weight = SODIUM (Na) 62.02 (mg/1) _ 23 = CALCIUM (Ca) 770.82 (mg/1) = 20 = MAGNESIUM(Mg 70.88 (mg/1) + 12 = SAR = 0.57 Milli Equivalents of Ion 2.70 38.54 5.91 If calculation sheets are being completed for more than one residual or site, please attach a summary sheet that brings the results of all the calculations sheets to one point. FORM: LAORS 02195 Page 13 of 18 SAR Page 13 f4 E. Determine the Site Life for this land application site: The lifetime pollutant loadings shall not be exceeded. The site life is determined by calculating the number of years that the site can receive the residual without exceeding the lifetime pollutant loadings. The site life calculations will be based on the most restrictive crop plant available nitrogen (PAN) requirement specified and the maximum dry tons or residuals to be land applied annually. Therefore, in the table below the Tons of Residuals to be Applied/Acre/Year will be calculated as: 1. Most restrictive crop based on the plant available nitrogen (PAN) requirement: Small Grains Associated plant available nitrogen (PAN) requirement: 100 (Ibs./acre/year) 2. Minimum acres needed based on most restrictive PAN (as found in C.5 above): 153 acres 3. Dry Tons of Residuals to be land applied per year: 250 dry tons per year 4. Tons of Residuals to be Applied/Acre/Year = Dry Tons/Year of Residuals to be land aonlied Minimum number of acres required for land application Tons of Residuals to be Applied/Acre/Year = 1.63 If any of the application sites are to be loaded at greater than the rate specified above, please specify the loading rate and explain: Tons of Residuals to be Applied/Acre/Year (different from above) _ Explanation: For the purpose of site life determination, the lifetime pollutant loadings shall not exceed the following for the corresponding Cation Exchange Capacities (CEC). Site life for the site covered by this application shall be determined by using the lowest CEC. The appropriate column should be chosen and applied in the "Allowable Lifetime Pollutant Loadings based- on CEC" in the table below: CEC < 5 CEC 5-15 CEC > 15 Pollutant (lbs / acre) (lbs / acre) (Ibs / acre) Lead 500 1,000 2,000 Zinc 250 500 1,000 Copper 125 250 500 Nickel 125 250 500 Cadmium 4.5 9 18 In the table below, the highest annual loading (Tons of Residuals to be Applied/Acre/Year) specified above, will be multiplied by the lbs./dry ton of each pollutant as found in B above. The Site Life can then be determined by: Site Life (Years) = Allowable Lifetime Loadings (lbs./acre) Projected Pounds to be Applied/Acre/Year Pollutant Tons of lbs./dry ton of each Projected Allowable Lifetime Residuals to be pollutant Pounds to be Pollutant Loadings Site Life Applied per (as found in Part B Applied/Acre Based on CEC. (Years) Acre per Year above) [Year From Chart Above (lbs./acre) Lead 1.63 * 0.010 = 0.0163 500 = 30,674 Zinc 1.63 * 0.592 = 09649 250 = 259 Copper 1.63 * 0.356 = 0.5852 125 = 213 Nickel 1.63 * 0.036 = 0.5868 125 = 213 Cadmium 1.63 * 0.004 = 0.0065 4.5 = 692 Compare the nine (9) pollutants above and determine which pollutant will result in the shortest lite for this site. The Limiting Pollutant is copper and nickel The Site Life is 213 years. FORM: LAORS 02195 Page 14 of 18 0Re9colw SUMMARY OF RENEWAL SITES SUMMARY OF SITES REQUESTED FOR PERMIT RENEWAL Site No. Owner Application Area (Acres) 1-1 K.M. Biggs 30.0 1-3 K.M. Biggs 20.0 1-4 K.M. Biggs 60.0 1-6 K.M. Biggs 230.0 1-7 K.M. Biggs 12.5 1-8 K.M. Biggs 30.0 Robeson County Subtotal 382.5 Program Total 382.5 SECTION VI OWNER/OPERATOR AGREEMENT FORMS 07-92-99 99:24 KM BIGGS INC ID-9107393016 P.02 North Carolina Division of Environmental Management AGREEMENT FOR THE LAND APPLICATION OF WASTE WATER RESIDUALS TO PRIVATE LANDS Permittee: Rocco Farm Foods, Inc. Contact Person: _ Everett Brown — General Manager Address of Permittee: Post Office Box 9 St. Pains. North Carolina 28384 List of wastewater residuals to be applied to these lands: Combined SBR and DAF Residual Solids Site ID Number. I Field Number. 1— 4, 6 - 8 'W 1*44V #'z �e.Kovt27 Location of Land to be used for residual application (include map for each site): Owner of Property used for residual applications .. IC M. Biggs. Tne. Lessee of Property (if appropriate): Land use or cropping patterns: Row Crons -- Intended use or disposition of crops: Livestock feed and market sale # # r # * * r * w * * * * * # # w # # # * # r r r r # # r # # # # # # # # # # * # t Y Y Y The undersigned land owner or his reptescntative hereby permits Rocco Farm Foods Inc. hereinafter referred to as the Pcrrnittee, to apply the above Iisted residuals onto the land at the location shown as described_ herein in accordance with the restrictions and stipulations as given below. The landowner or his representative receives, in consideration, full use of the nutrient value of the applied residuals while the Permitted receives, in consideration, the use of the land described above for the disposal of wastewater residuals. This agreement shall remain in effect for the length of the Division of Environmental Management land application permit and shall be renewed each time the land application permit is renewed. The undersigned land owner or his representative and the Permittee agree to abide with the following restrictions and stipulations until such time as written notification; given thirty (30) days in advance, modifies or cancels this Land owner's Agreement. Notification of cancellation of this agreement shall be immediately forwarded to: Division of Environmental Management Permits and Engineering Unit Pose Office Box 29535 Raleigh, North Carolina 27626.0535 FORM: LAORS 02195 Page 15 of is W=-ZN nn Di NVQ llvu rU-,J 1U(UJ:SW ib Y. ULS 12. Should the landowner or his representative lease or otherwise permit the use of the land by a third party, the landowner shall be responsible to insure the third party agrees and complies with the terms and conditions of this Agreement. 13. The existing lessee, if any, of the site agrees, by execution of this Agreement, to comply with all provisions of this Agreement. 14. This Agreement shall be binding on the grantees, the successors and assigns of the parties hereto with reference to the i ibjcct matteryof this Agreement. 15. Animals should not be grazed on residual applied lands within a thirty (30) day period following the residual application. Application sites that are to be use for grazing shall have fencing that will be used to prevent access during these periods after each application. 16. Prior to a transfer of land to a new owner, a permit modification must be requested and obtained from the Division of Environmental Management. The request shall contain appropriate fees and agreements. In addition, a notice shall be given by the current landowner to the new landowner that gives full details of the materials appliedor incorporated at each site. 17. Any duly authorized officer, employee, or representative of the Division of Environmental Management may, upon presentation of credentials, enter and inspect any property, premises or place on or related to the application site and facility at any reasonable time for the purpose of deterring compliance with this permit; may inspect or copy any records that must be kept under the terms and conditions of this permit; or may obtain samples of groundwater, surface water, or leachate. 18. The landowner shall not enter into any additional waste disposal contracts or agreements with another municipality, connector, or other permitted entity for the land specified by this Agreement The land application of any additional wastewater residual sources, other than the residuals specified by this permit, is prohibited. s s s s s s a s a s .. a• a s s s s s s s s s• s♦ s s s s s s s s* a s s s s a RESTRICTIONS: s a w a t t a s a.a a t a a a s a a a a a•a.x a s a a a a s a x x a a a a a Land Owner: Operator. Address: Address: Phone No.: FORM: LAORS ou9s Phone No.: Page 17 of 18 07-02-99 09:25 KM SIGGS INC ID-9197393016 STIPULATIONS: P.04 1. The landowner or his representative hereby authorizes the Permittee, County and State Officials or their representatives to inspect each parcel of property prior to, during, and after residual application and to establish monitoring facilities on or near the application site as required by the residual land application permit. 2. The landowner or his representative authorizes the Permittee, County and State Officials or their representatives to take necessary soil, surface and ground water samples during the term of, and twelve (12) months after termination of, this Agreement. 3. The Permittee will provide each landowner or his representative with a copy of the land application permit as issued by the N.C. Department of Environment, Health, and Natural Resources (NCDEHNR) Division of Environmental Management (DEM) for the land described above prior to commencement of residual application. The NCDEHNR-DEM permit will specify mat�um application rates, limitations and other restrictions prescribed by the laws and regulations. 4. The Permittee will provide each landowner or his representative with information and data concerning the program for land application of residuals to privately owned lands which includes an analysis of constituents of the residual, residual application methods and schedules for typical cropping patterns and a description of the equipment used by the Pemuttee for residual application. S. The Pcrntittee will ftmrish each landowner or his representative with a copy of the results of each soil analysis. 6. The site shall be adequately limed to a soil pH of at least 6.0 prior to residual application. Residuals may be applied to sites with a pH of less than 6.0 provided a sufficient amount of lime is also applied to achieve a final pH of the lime, residual and soil mixture of at least 6.0. 7. The landowner or his representative will inform the Permittee of any revisions or modifications to the intended use and cropping patterns shown above prior to each planting season to enable the Permittee to amend this Agreement and schedule applications at appropriate periods. Within the limits of the NCDEHNR-DEM permit, the owner or his representative and the Permittee will determine residual application rates and schedules based on crop patterns and the results of soil samples, 8. Crops for direct human consumption shall be harvested in accordance with the conditions of the permit. 9. The landowner or his representatives or successors shall adhere to the provisions of this Agreement for a period of eighteen (18) months from the date of the most recent residual application. 10. Appropriate measures must be taken by the Permittee or Land Owner (Lessee) to control public access to the land application sites during active site use and for the twelve (12) month period following residual application. Such controls may include the posting of signs indicating the activities being conducted at each site. 11. Specific residual application area boundaries shall be clearly marked on each site by the Permittee or Land Owner (Lessee) prior to and during application. FORM: LAORS 02/95 Page 16 or 19 07-02-.99.. 09:25 KM BIGGS INC ID-9187393016 P.05 I, F. K. Biggs, III agreement and do hereby rant permission to the Permittee to apply Land to-&S-99 `" Date NORTH CAROLINA, Q cl� COUNTY, L the undersigned Notary Public, do hereby certify that 4—�i- r�\� personally appeared before me this day and acknowledged the due exe ` WITNESS my hand fficiai seal this day of (Q - a s NOTARY PUBLIC My commission expires SEAL: have read this land owner's my lands as specified herein. forgoing ins ent. 19 M. ♦ # # • ♦ ♦ 4 • • ♦ # # ♦ # r ♦ # • # # ♦ # * # # ♦ # ♦ ♦ • • ♦ r r r • ♦ • • • • • • s a • I, . have read this land owner's agreement and do hereby agree to abide by the stipulations and restrictions as specified herein. Lessee Date I, Everett Brown — General Manaeer have read this land owner's agreement and do hereby agree to abide by the stipulations and restrictions ass ecified herein. Permittee Date FORM: LAORs ov9s Page 18 or 18 SECTION VII UPDATED CUMULATIVE LOADING RECORDS ROCCO TURKEYS - LAND APPLICATION PROGRAM S&ME, INC. Field Loading Rate Report OWNER: K. M. Biggs PERMIT 9 WQ 0003034 OPERATOR: K. M. Biggs RESIDUAL SOURCE: Rocco Turkeys DAF, SBR ACRES PERMITTED: 60.0 CROP: Coastal Bermuda TOTAL DRY TONS APPLIED (ANNUAL) E7,5� " 6/93 27.101 122,0191 4,503 1 9.751 1.83 1 --- 1 0.01 1 0.04 1 0.48 1 0.02 I --- I --- 1 0.04 --- 1 1.65 --- I --- I --- • 6/93 2.20 1 33,661 15,300 1.79 1.14 --- 0.01 0.15 0.73 0.01 --- --- 0.09 --- 1.71 --- --- --- "7/93 26.00 111,126 4,274 9.06 1.61 0.01 0.01 0.03 0.38 0.02 0.01 0.02 0.02 0.01 1.09 --- --- --- "9/93 10.00 95,773 9,577 7.85 3.13 0.00 0.00 0.09 1.32 0.03 0.00 0.00 0.06 0.00 3.01 • 7/97 30.00 120,235 4,008 7.01 1.20 0.00 0.00 0.07 0.37 0.03 0.00 0.00 0.05 0.00 0.60 84.78 39.60 3.0 7l97 30.00 60.454 2.015 0.55 0.05 0.00 0.00 0.01 0.03 0.00 0.00 0.00 0.01 0.00 0.08 4.93 4.23 0.7 Annual Totals Cumulative Totals Cumulative Pollutant Loading Rate (lbs./Acre) • DAP Source • SBR Source o Lagoon Source 6,023 I_ I 1.25 I 0.00 I 0.00 I 0.08 I 0.40 I 0.03 I 0.00 I 0.00 I 0.06 8.96 1 0.01 1 0.03 1 0.39 3.31 1 0.11 1 0.01 1 0.02 1 0.27 ATURE OF LAND APPLIER) Date cument was prepared under my direction or supervision in accordance with a system roperly gathered and evaluated the information submitted. I am aware that there are rmation, including the possibility of fines and imprisonment for knowing violations." 7/7/99 -- 1 4.5 1 --- 1 125 1 500 1 --- I --- 1 125 1250 7 Lime App. Date Lbs/Ac ROCCO TURKEYS -LAND APPLICATION PROGRAM OWNER: IC M. Biggs S&ME, INC. OPERATOR: Field Loading Rate Report RESIDUAL SOURCE: Rocco Turkeys DAF, SBR and Lagoon PERMIT # WQ 0003034 TOTAL DRY TONS APPLIED (ANNUAL) 4(.8 ACRES PERMITTED: 230 Crop: Coastal Bermuda Annual Totals 183,274 17, Cumulative'ilotals Cumulative Pollutant Loading Rate (lbsJacre) • DAF Source • SBR Source o Lagoon Source 1.94 0.00 0.00 0.09 1 0.67 1 0.07. 0.00 0.00 U.04 0.00 1.2G 144.98 34.00 3.54 7.43 0.01 0.01 0.54 2.42 0.08 0.00 0.00 0.19 0.00 4.96 --- — — — 4.5 -- 125 1 500 — — 125 — 250 1 350 1 PAN (lbs./acre/year) (Signature of Land Applier) Date "I certify, under penalty of law, that this document was. prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalities for submitting false information, including the possibility of fines and imprisoment for knowing violations." Limc A Dah Lbs/Ac 12!')G 1,500 7nlss ROCCO TURKEYS -LAND APPLICATION PROGRAM OWNER: IC M. Biggs S&ME, INC. OPERATOR: Field Loading Rate Report RESIDUAL SOURCE: Rocco Turkeys DAP, SBR and Lagoon PERMIT # WQ 0003034 TOTAL DRY TONS APPLIED (ANNUAL) 39.2 4CRRS PERMITTED: 230 Cron: Coastal Bermuda Annual Totals 160,207 1 11,444 1 — I 2.80 000.12006 0.00000010 00.000 3.2ai7 1772 39-r5 L04 0.010.00 026 1.530.0900 .00 0. CUIu1:I1VCIlotals 19 0= Cumulative Pollutant Loading Rate (Ibs./acre) ' DAF Source • SBR Source o Lagoon Source — 4.5 1 - 1 125 1 500 1 - I - 1 125 1 - 1 250 1 350 PAN (Ibs./acre/year) (Signature of Land Applier) Date "I certify, under penalty of law, that t11is document was prepared under my direction or supervision in accordance with a system designed to assure that qualified persontiel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." 7HIS9 Line A Date I ROCCO TURKEYS -LAND APPLICATION PROGRAM OWNER: K. M. Biggs S&ME, INC. OPERATOR: Field Loading Rate Report RESIDUAL SOURCE: Rocco Turkeys DAF, SBR and Lagoon PERMIT # WQ 0003034 AtIPF8 PFRMITTED: 230 Cron: Coastal Bermuda Annual Totals 162,922 8,398 I Cumulative Totals 0.91 1 0.00 1 0.00 1 0.04 1 0.34 1 0.00 1 0.00 1 0.00 1 0.04 1 0.00 1 0.54 II 70.74 1 17.11 1 3.34 — 1 4.29 1 0.02 1 0.00 1 0.27 1 1.42 1 0.01 1 0.00 1 0.00 1 0.11 1 0.00 1 2.7411 -- I — I — Cumulative Pollutant Loading Rate (Ibs./acre) • DAF Source SBR Source o Lagoon Source X (Signature of Land Applier) 'Date "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." — 4.5 — 125 1 500 — — 125 — 250 1 350 1 PAN (Ibs./acre/ ear) I M 717/99 SECTION VIII UPDATED SOILS ANALYSIS REPORTS ti+a� 7ri: F°'u-°� � C4��5"�}"�9 • � °;��'"-Fi -bi Re orr.R 3 T. 06 t►i . _. Stoke +y00 nccu tCtccn doa4 nAlCl' jTJNEr2 �e 7 Grower: Biggs, IL A Copies to: County Extension Director PO Box 967 S&ME Inc. Lumberton, NC 28359 A �sc ' Test Report S&MEInc. Soil �a Farm: Rocco Turkeys Mtn:Rob Willcox 3718 Old Battleground Rd. 1/ 5/98 SERVING N.C. CITIZENS FOR OVER 50 YEARS Robeson County Greensboro NC 27410 Agronomist Comments: Fieldw. `"➢ 6 0,6��, Sample No. Last Crop Ho Yr T/A Crop or Year Lime N I305 KO Mg Cu Zia B Alit See Note 001 Soybeans 1st Crop: Soybeans .5T 0 0 10-30 $ 0 0 0 3 12ndCrop: kjvg-1 Test Results Soil Class IIAf% W/V CECI BS% Ac pH P-I K-I Ca% Mg% Mn-I Mu -AI (1)Mn-Al (2) Zu-1 Zn-Al Cu-1 S-L SS-1 NCS-N M6-N Na MIN 0.46 1.52 4.2 67.0 1.4 5.7 182 63 49.0 2.0 49 39 69 69 39 42 0.1 - .. .- Field .me +x'�-Xk: . Ho Yr T/A Crop or Year Linte N h05 KO Mg Cu Zn B Mu See Note Sample A'o. last Crop 002 Berns Ilay/Pas,M Ist Crop: Berm Hay/Pas,M .9T 180-220 0 180-200 0 0 0 0 12 KM8-2 2ndCrop: Test Results Soil Class IIAf% W/V CEC BS% Ac pH P-I K-I Ca% Mg% Mn-1 Mu -Al (1)Mn-Al (2) Zn-1 Zn-Al Cu4 S-1 SS -I NQt-N NIE-N Na MIN o.69 1.46 5.5 78.0 1.2 6.2 183 20 63.0 .14.0 159 105 662 662 7 28 0.1 Field ,Info7taon Linte RecmmelonSw- .� Sample No. Last Crop Ho Yr T/A Crop or Year Lime N @Os A0 A1g Cu Zn B Ain See Note 03A Corn,Silage 1st Crop: Corn,Silage 0 180-220 0 12044o $ 0 0 0 3 I4MQ-3/1 2ndCrop: Test Results Soil Class Ildf% W/V CEC BS% Ac pH P-I K-I Ca% Mg% Mn-I Mn-Al (1)Mn-Al (2) Zn-I Zu-Al Cu-I S-1 SS -I NQt-N NI&N Na MIN 0.76 1.50 4.7 68.0 1.5 5.5 159 35 56.o 8.0 50 49 86 86 26 25 0.0 9:' hD .S vrM1 'Field lufoirmatlonrC w... tS ' z Iia'Lime 7 .ac : v ... •.b Ti ii & �' W P ��ti p P(. S YA 'R 2 a 1 ) i t3 f: a M 7.�,777 : P Mh f ,t, -Recommendatiops � aN.�, � .7�; , z. F{ _ , Sample No. last Crop Ho Yr T/A Crop or Year Litne N PeOs KO Mg Cu Zn B Mn See Note 03B Corn,Silage 1st Crop: Corn,Sllage AT 180-220 10-30 90-110 $ 0 0 0 3 KAB-3B 2ndCrop: Test Results Soil Class IIM% W/V CEC BS% Ac pH P-I K-I Ca% Mg% Mn-I Mn-AI (1)Mn-Al (2) Znd Zn-Al Cu-I S-I SS-1 NQf-N NI&N Na MIN 0.6 1.52 3.8 63.0 1.4 5.8 68 48 49.0 9.0 37 39 49 49 27 22 0.0 N Y 14 {'Wi �Fe"Ill 6ti+2 p: "ei F R'l� @£.s �'x "i ! IA6 omku...isia. ;G,v�nRoa.r ..ale r .0 �i.ovr•�6 vzr 9ly,.r� a� b,• i, � sRe oc No:r�ao99.. � ;; Grower. Biggs, I{. M. Copies to: County Extension Director PO Box 967 S&ME Inc. r�{ A Lumberton, NC 28359 - y4 c. Soil Test Report Farm: Att11nM:RobWillcox 3718 Old Battleground Rd. 1/ 5/98 SERVING N.C. CITIZENS FOR OVER 50 YEARS Robeson County Greensboro NC 27410 Agronomist Conmients: Field'InformatioW ,, . Sample No. last Crop Ho Yr T/A Crop or Year Lime N M5 Ko Mg Cu Zn B Afn See Note 004 Soybeans 1st Crop: Soybeans 0 0 0 40-60 0 0 0 0 3 of 8 - y 2nd Crop: Test Results Soil Class lDf% WIV CEq BS% Ac pN P-1 K-I Ca% Mg% Mn-I Mn-AI (1)Mu-Al (2) Zu-I Zu-AI Cu-1 S-I SS-1 Ad-N NI&N Na MIN 1.02 1.6o 5.0 74.o 1.3 6.2 159 44 55.0 14.0 132 86 104 104 29 30 0.1 Field Iddi iiatidn`3 _.. , $'< "Iigd Lfirk iommeudaktons r„ r a 4 5':w a`, x, t d . , ,1 k.e 'i Sample No. Last Crop no Yr T/A Crop or Year Lime N Peos KO Mg Cu Zu B Mn See Note 007 Soybeans IslCrop: Soybeans 1.7T 0 0 70-90 $ 2 0 0 3 Alfy6- 171 2nd Crop: Test Results Soil Class IIAf% IV/V CEC BS% Ac pH P-1 K-I Ca% Afg% Mn-I Mu -A/ (1)Mu-A/ (2) Zn-I Zn-AI Cu-I S-I SS-1 NC8-N NIA-N No MIN 1.02 1.44 4.0 35.0 2.6 4.9 246 31 26.0 5.0 40 34 67 67 21 46 0.1 t.,.. Field Sample No. Last Crop 610 Yr T/A Crop or Year Lime N P105 KO Mg Cu Zn B bfn See Note 008 Soybeans IslCrop: Soybeans 0 0 0 0 0 0 0 0 3, ,('iy1163 8 2nd Crop: Test Results Soil Class IIAf% W/V CEC BS% Ac pll P-1 K-I Ca% Mg% Mn-1 Mn-Al (1)Mn-AI (2) Zm-1 Zn-Al Cu-1 S-I SS-1 N(b-N AV&N Na MIN 2.01 1.30 12.2 81.0 2.3' 6.1 208 133 62.0 14.o 45 35 484 484 293 52 0.1 ,. .,..a -- � �' i•r .�., _ Sample No. Last Crop Ho Yr T/A Crop or Year Lime N R05 KO Mg Cu & B Mn See Note 06A Berm llay/Pas,M 1st Crop: Berm Hay/Pas,M 0 180-220 0 140-16o 0 0 0 0 12 ,eIM -,!�.4 2nd Crop: . Test Results Soil Class IIM% W/V CEC BS% Ac pH P-I K-1 Ca% Mg% Mn-I Mn-Al (1)bfrr-Al (2) Zu-I Zn-AI Cu-1 S-1 SS-1 NC$-N NIE-N Na MIN 0.56 1.41 5.1 86.0 0.7 6.6 194 34 67.0 17.0 82 57 116 116 60 32 0.1 ky.`�— onu,nicurns�on=rJOhccu �- Cr44..,.b ei .. 27 .,.► 19�, oa Ji1. jjd. FieldlnforriiatiodMr lied`Lrnie rReca+ilmendahofiSMI �,�' 91% 95,u Ok-11,As� -13,1 � k*$r e � ,n1.1i # f t is ` ?. m ,_. �, Sample No. Last Crop Ho Yr T/A Crop or Year Lime N hos mo Mg Cu Zn B hSs See Note 06B Soybeans lsl Crop: Soybeans I 0 0 0 30-50 0 0 0 0 3 a 2ndCrop: Test Results Soil Class Im W/V CEC BS',6 Ac PH P-1 K-1 Ca% Mg% Mn-1 Mrr-Al (1)Mn-Al (2) Zn-1 Zn-AI Cu-1 S-1 SS -I Na-N A7&N Na MIN 0.41 1.43 4.2 7.0 0.9 6.5 128 48 56.o 18.0 130 80 54 54 40 29 0.1 'Fieldlnformationw„.., ,a='- "lied Lime RecoinriieadaUons ,t'`= a�'a� i...a ta:"u..a spa yeag.c.ke.x 5 ° - ...x..5e'. Sample No. Last Crop fo Yr T/A Crop or Year Lime N h05 JW Mg Cu Zn B Bill See Note 06C Berm Hay/1'as,M 1st Crop: Berm flay/Pas,M .5T 180-220 0 180-200 0 0 0 0 12 14H 13 "/o C. 2nd Crop: Test Results Soil Class IIM% W/V CEC BS% Ac pu P-I K-1 Ca% Mg% Mu-1 Mn-AI W A111-AI (2) Zn-I Zn-AI Cu-1 S-I SS-1 NCB-N NI6-N Na MIN 0.41 1.48 3.1 74.0 o.8 6.3 113 18 56.0 14.0 55 42 56 56 36 25 0.0 APPENDIXI SBR AND DAF NUTRIENT AND METAL ANALYSIS ROCCO TURKEY'S LAND APPLICATION PROGRAM RESIDUALS ANALYSIS Residual Type: Wastewater Treatment Plant Date Sampled: 6/28/98 Date Reported: 7/7/98 SBR SLUDGE - No. 2 Digester Suecific Gravitv: 1.002 5.90 pH aauon: a.jo vao 70 ounus 8.060 I1Calcium 1.420 1 14,200.000 1 28.400 11 rntn;nm rn�r,nna�P nn Sodium 1.2501 12,500.000 25.000 Sulfate 1.670 16,700.00 33.400 itrate N + Nitrite N 1.492 14,916.000 29.832 Manganese --- 513.000 1.026 Chloride 20,600.000 41.200 Iron --- 64,000.000 128.000 Aluminum 7,620.000 15.240 Arsenic --- 0.580 0.001 Cadmium --- 1.000 0.002 Chromium --- 72.000 0.144 Copper -- 523.000 1.046 Lead --- 21.000 0.042 Mercury --- 0.380 0.001 Molybdenum --- 11.000 0.022 ickel --- 40.000 0.080 Selenium 2.310 0.005 Zinc -- 1,070.000 1 2.140 d&T. Rnclem Tahn.atnriee Rennrt Nn • RIM-071 -Determination of Plant Available Nitrogen (PAN): Injected Application: 4.491 %PAN (Mineralization Rate)(TKN-Ammonia N) + Ammonia N + Nitrate N +Nitrite N = % PAN Surface Application: 4.076 %PAN (Nacralization Rate)(17KN-Ammonia N) + (0.5)(Ammonia N) +Nitrate N +Nitrite N = % PAN Prepared by S&ME, Inc. 7/7199 A & L EASTERN AGRICULTURAL LABORATORIES, INC. 7621 Whitepine Road " Richmond, Virginia 23237 " (804) 743-9401 AL Fax No. (804) 271-6446 R:L86-071 ACCOUNT 4:`i641 PAGE I REPORT NUMBER S&ME (Rocco TURKEY) PO 07718 JOB 01.588-93-0.14 ROB WJ:LLCOX AT'TNL RICK BAKER 3718 OLD BATTLEGROUND RD GREENSBORO NC_ 2741072314 SLUDGE ANALYSIS REPORT DATE SAMPLED LAB NUMBER = 43287 DATE RECEIVED 06/30/98 SAMPLE. ID = R 0 C C 0 TURKEY SBR DATE REPORTED 07/07/9B I DETECTION RESULT RESULT LIMIT ANALYSIS PARAMETER ( % ) (MG/KG) (MG/KG) ANALYST DATE METHOD REFERENCE SOLIDS(AS IS) 0.36 3600 100 KCS 06/30/98 SM 25406 NITR0GEN(TKN) 8.06 00600 100 KCS 0.7/01/9B EPA 351.3 PHOSPHORUS 3.89 3B900 100 KM 07/01/98 EPA 365.4 POTASSIUM 1.27 12700 100 JCM 07/01/9E3 SW E146-6010 CALCIUM :1.42 14200 100 JCM 07/01/98 SW 846-60:1.0 MAGNESIUM 1.09 10900 100 JCM 07/01/98 E1W E146-6010 SODIUM. 1.25 12500 100 JCM 07/01/98 SW 846•-6010 IRON 64000 1 JCM 07/01/90 SW 846-6010 ALUMINUM 7620 10 .JCM 07/01/98 SW 846-60:1.0 MANGANESE 513 J. JCM 07/01/98 SW 046•-601.0 COPPER 523 1 JCM 07/01/9B SW 846-6010 ZINC 1070 :1. .JCM 07/01/98 S)W 846•-601.0 AMMONIA -NITROGEN 0.83 8300 100 KCS 07/01/98 EF"A 350.2 NO3-NO2 NITROGEN 14916 10 KCS 07/01/98 SM 4500-NO3 F CADMIUM NIl 1 DCH 07/01/98 SW 846 7131A CHROMIUM 72 5 JCM 07/01/98 SW 846--60:1.0 NICKEL 40 5 JCM 07/01/9B SW 846-6010 LE:A1) 21 5 JCM 07/01/98 SW 846••-60:1.0 ALL- VALUES ARE. ON A DRY WEIGHT BASIS EXCEPT AS NOTE..D. " C Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or In part, nor may any reference be made to the work, Ilia results, or Ilia company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Copyright 1971 A & L EASTERN AGRICULTURAL LABORATORIES, INC. 7621 Whitepine Road • Richmond, Virginia 23237 • (804) 743-9401 A � Fax No. (804) 271-6446 R186-0"l':I. ACCOUNT' 45641 PAGE 2 U REPORT NUMBER S&ME (ROCCO TURKEY) PO #7718 JOB 41588-93-01.4 ROB WIL.L_COX ATTN: HICK BAKER 3718 OLD BATTLEGROUND RD GREENSBORO NC 27410-2314 SLUDGE ANALYSIS REPORT LAB NUMBER = 43287 SAMPLE. ID = ROCCO TURKEY SBR DETECTION RESULT RESULT LIMIT ANALYSIS PARAMETER ( "/. ) (MG/KG) (MG/KG) ANALYST DATE DATE SAMPLED DATE RECEIVED 06/30/98 DATE REPORTED 07/07/98 METHOD REFERENCE ARSENIC 0.58 0.4 KM 07/02/98 SW 846-7061A MERCURY 0.38 0.1 KM 07/02/98 SW 846-7471A SELENIUM 2.31 0.1 KM 07/02/98 SW 846•-7741A PH (STD,UNITSvAS IS) 5.90 RD 07/01/98 L'-::PA 150.1 ORGANIC NITROGEN 7.22 72200 100 DCN 07/01/98 CALCULATION MOLYBDENUM 11 5 JCM 07/01/98 SW 846-6010 CHLORIDE 20600 1 AB 07/01/98 SM 4500—CL D SULFATE 16700 10 JCM 07/0.1/99 SW 846-9038 SPEC GRAVITY(AS IS) 1.002 I_DR 07/01/9E3 SM 27101::' WEIGHT(*'S/GALLON) 8.36 ALl... VALUES ARE. ON A DRY WEIGHT BASIS EXCEPT AS NOTED.° �W( 'AUL C. H. HU (;r N(:1RMAN ..IOLdE::: Om reports and lepers are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part, nor may any relerencu be made to lho work. the results, or Ihu company in any advertising, news release, or other public announcements without obtaining our prior written uulhorizatron. Copyrigln Ig// ROCCO TURKEY'S LAND APPLICATION PROGRAM RESIDUALS ANALYSIS Residual Type: Wastewater Treatment Plant Date Sampled: 814/98 Date Reported: 8/19/98 DAF SLUDGE - No.1 Digester Specific Gravity: 0.987 6.80 pH Pounds / Gallon: 8.28 8.86 % Solids TMrameter. °!e kP{iYlDry Weagbt .:ztHfo x 10,00Q P.o tndsiDry Ton <P1kI xfk©li2 Nitrogen (TICN) 5.370 53,700.000 107.400 Phosphorus 0.840 8,400.000 16.800 Potassium 0.090 900.000 1.800 PAN (injected)* 3.521 35,206 000 PAN (surface)* 2.381 23,806.000 47.612 Ammonia Nitrogen 2,280 22,800.000 45.600 Calcium 0.870 8,700.000 17.400 Calcium Carbonate Eq. -- Magnesium 0.080 800.000 1.600 Sodium 0.070 700.000 1.400 Sulfate 0.032 315.000 0.630 Nitrate N + Nitrite N 0.005 46.000 0.092 Manganese --- 109.000 0.218 Chloride 270.000 0.540 Iron --- 14,900.000 29.800 Aluminum --- 2,190.000 4.380 Arsenic --- <0.400 0.000 Cadmium --- 2.000 0.004 Chromium --- 20.000 0.040 Copper --- 178.000 0.356 Lead <5.000 0.000 Mercury --- 0.620 0.001 Molybdenum --- <5.000 0.000 Nickel --- 18.000 0.036 Selenium --- 0.480 0.001 Zinc 299.000 0.592 A&L Emtern Laboratories Report No.: R214-193 (Addition) *Determination of Plant Available Nitrogen (PAN): Injected Application: 3.521 % PAN (Mineralization Rate)(TKN-Ammonia N) + Ammonia N + Nitrate N + Nitrite N = % PAN Surface Application: 2.381 % PAN (Mineralization Rate)(TKN-Ammonia N) + (0.5)(Ammonia N) + Nitrate N + Nitrite N = % PAN Prepared by S&ME, Inc. 5/27/99 A & L EASTERN AGRICULTURAL LABORATORIES, INC. ADDITION 7621 Whitepine Road • Richmond, Virginia 23237 • (804) 743-9401 Fax No. (804) 271-6446 R214-193 ACCOUNT 45641 ' F'AGE 1 REPORT NUMBER S&ME (ROCC(:) TURKEY) PO *7733 .JOB 41588-93-014 ROB WILLCOX A•I'TN* RICK BAKER 3718 OLD BATTLEGROUND RD GREENSBORO NC 27410-•2314 SLUIIGE ANALYSIS REPORT DATE SAMPLED LAD NUMBER = 43947 DATE RECEIVEI:I 08/06/98 SAMPLE ID = I:IAF 41 DIGESTER DATE REPORTEIJ OB/19/9(:3 1 DETECTION RESULT RESULT LIMIT ANALYSIS PARAMETER ( % ) (MG/KG) (MG/KG) ANALYST DATE METHOD REFERENCE SOL_IIIS(AS IS) '8.86 88600 100 KCS 08/06/98 SM 2540B NIT'ROGEN(TKN) 5.37 53700 100 KCS 08/07/90 EPA 351.3 PHOSI''HORUS 0.84 8400 100 KM 08/07/98 EPA 365.4 POTAS!31UM 0.09 900 100 JCM 08/07/98 SW 846--6010 CALCIUM 0.87 (3700 100 JCM 08/07/90 SW 846-601.0 MAGNESIUM 0.08 800 100 JCM 08/07/98 SW 846-60:1.0 SODIUM 0.07 700 100 JCM 08/07/98 SW 846-6010 IRON 14900 1 .JCM 08/07/98 SW 846-6010 ALUMINUM 2190 10 JCM 08/07/98 SW 846-6010 MANGANESE 109 1 JCM 08/07/90 SW 846-60:1.0 COPPER 178 1 .JCM 08/07/98 SW 846-6010 ZINC 296 1 JCM 08/07/98 SW 846-601.0 AMMONIA --NITROGEN 2.28 22BOO 100 KCS 08/07/98 EPA 350.2 NO3-NO2 NITROGEN 46 10 KCS 08/07/98 SM 4500-NO3 1= CAI:tMIUM 2.0 1 ITCH 08/07/98 SW 846-7131A CHROMIUM 20 5 JCM 013/07/98 SW 846-6010 NICKEL 18 5 .)CM 08/07/98 SW 846-601.0 LEAD ND 5 ,JCM 08/07/98 SW 846--6010 ALL. VALUES ARE ON A DRY WEIGNT BASIS EXCEPT AS NOTED." V�/Y*QAqt.C.IA. f..Fll.l C... NC)hMAN ..JL.1Nf. i Our reports and letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part, nor may any reference be made to the work, the results• or the company in any advertising, news release, or other public announcements without obtaining our prior written authorization. Copyright 1977 R214-193 REPORT NUMBER A & L EASTERN AGRICULTURAL LABORATORIES, INC. 7621 Whitepine Road • Richmond, Virginia 23237 • (804) 743-9401 Fax No. (804) 271-6446 ACCOUNT 45641 PAGE: 2 £i RME (ROCCO TURKEY) ATTNt TICK BAKER 3718 OLII BATTLEGROUND RI) GREENSBORO NC 27410-2314 LAD NUMBER m 43947 SAMPLE 1I) =: DAF 01 DIGESTE..R I RESULT PARAMETER PO 07733 JOB #1588-93-014 SLUDGE ANALYSIS REPORT DETECTION RESULT LIMIT (MG/KG) (MG/KG) ANALYST ROD WILL..COX DATE SAMPLED DATE RECEIVED 08/06/9B DATE REPORTED OB/19/96 ANALYSIS HATE METHOD REFERENCE ARSENIC ND 0.4 KM OB/18/98 SW B46-7061A ME:RC:URY 0.62 0.1 KM 08/18/98 SW 846-7471A SELENIUM 0.4B 0.1. KM 08/18/98 SW 846•-7741.A PH (STD.UNITSrAS IS) 6.80 RD OB/07/90 EPA 150.1 ORGANIC NITROGEN 3.09 30900 100 DCN 08/07/98 CALCULATION MOLYBDENUM ND 5 JCM 08/07/98 SW 846-601.0 CHLORIDE 270 1 AB 013/07/98 SM 4500—CL 1) SULFATE 315 10 JCM OB/07/9B SW 846-9038 SPEC GRAV1'TY(AS IS) 0.993 L-DR 08/07/98 SM 27101'-" WE":I:(nl-IT (#' Ei/GAL..L.C1N) 8.28 82B00 ALL VALUES ARE ON A DRY WEIGHT BASIS EXCEPT AS NOTED.- 4; ta F'AUIH. CHU — -l', NOOK NES Our I,;pods antl letters are for the exclusive and confidential use of our clients, and may not be reproduced in whole or in part, nor may any reference be made Io thu YYnlh, Ih,: Iosi II IS, of the compoly in any advertising, news release, or other public announcements will lout obtaininrj our prior written authorization crpylillht la/ APPENDIX II SBR AND DAF TCLP ANALYSIS SBR ANALYSIS Form 1 - Data Summary Report Prepared By: HydroLogic Laboratories, Inc. Client 10: ROCCO TURKEYS SBR 02 Project Number: SME1202B ' Sample ID: L612B-2 Site / Project ID: Not Reported Run 10: R8756 Collection Date: Dl-DEC-97 Received Date: 03-DEC-97 Report Date: TT-DEC-97 Analyte CAS No. Dil Sample Conc. Units- RL SU846 Method 1311/8240 Preparation Date:. 1:1-DEC-9T Analysis Date: 1:1-DEC-97 1,9:05 Yorkgrcup Number: 'WG13399' Benzene 71-43-2 1 '" NO.. -ug/L 50 Carbon tetrachloride 56-23-5 1 :" .. -. NO `-ugA.. `: ''50 - Chlorobenzene 108-90-7 1 ND ug/L..,, 50 . Chloroform 67-66-3 1 NO ug/L 50 1,4-Dichlorobenzene 106-46-7 1 ND ug/L• .. 10D 1,2-Dichloroethane 107-06-2 1 - NO ug/L, 50 1,1-Oichlorcethene 75-35-4 1 - ND Ug/L - 50 Methyl ethyl ketone 78-93-3 1 ND ug/L. 250 Tetrachloroethene 127-18-4 1 140. -ug/L 50 - Trichloroethene 79-01-6 1 NO -ug/t _ 50 Vinyl chloride 75-01-4 1 -- ND .... ug/L :' 160 Dibromofluoromethane SURROGATE 1 81 X - Toluene-d8 SURROGATE 1 r.88 X 4-Bromofluorobenzene SURROGATE S4846.M'ethod 131T/8270 "' Preparation Date 08=DEC 97 Analysis. Vorkgroup Number. 'f7G93372W. Cresol 106-44-5 1 ".ND ug/L -' -_ 2,4-Oinitrotoluene 121-14-2 100 Hexachlorobenzene 118-74-1 1.: . No ug/L.,.? .. 400 Hexachlarobutadiene 87-68-3 1 "ND Ug;,,.. /t t t0O . Hexachloroethane 67-72-1 1 -r Np ugfL 100 ' Nitrobenzene 98-95-3 1"AND ug/L i 100 Pentach lorophenol 87-86-5 1 .. NO ug/t .. ' Pyridine 110-86-1 1 '.... NO UgA :... Soo - • 2,4,5-Trichlorophenol 95-95-4 1. .. "NO- ug/L. ;,'- ..100 . 2,4; 6-Trichlorophenol ' 88-06-2 1 NO1. ug/t. "'.' - :100 Nitrobenzene-d5 SURROGATE 1 tOD X 2-Fluorobiphenyl SURROGATE 1". 100 Phenol-& SURROGATE 1 100 .. X,.. 2-Fluorophenol SURROGATE 1 100 .. X- 2,4,6-Tribromophenol SURROGATE 1 100 Review By: Rose, Murphy Report Approvec'rBy: ,Karen Kuoppala "Dil" - Sample Dilution Factor "ND" - Sample Concentration Not Detected above RL "RL" - Method Report limit Form 1 - Data Summary Report Prepared By: HydroLogic Laboratories, Inc. Client ID: ROCCO TURKEYS SSR #2 Project Number: SME1202B Sample ID: L6128-2 Site / Project ID: Not Reported Run ID: R8756 Collection Date: 01-DEC-97 Received Date: 03-DEC-97 Report Date: 1.1-DEC-97 AnaLyte CAS Na. •Dirl Sample Conc. Units RL SW846 Methods 1311/8080 . Preparation Date:11-DEC-9T, .. - Analysis. Date:. 12-DEG97 03:23: . ' Yorkgroup Number:. NC1340T Lindane 58-89-9 1: ., -. ND :., •. ug/L...5 Ch Lordane 57-74-9 1 NO USA;. ., 5 Endrin 72-20-8 1 NO ug/L. 1' Heptachlor 76-44-8 1 NO ug/L .5. Methoxychlor 72-43-5 1 NO ugn - '5 ` Toxaphene 8OOi-35-2 1 NO - ug/L 24 Tetrachloro-m-xylene SURROGATE 1 6a X... - Decachlcrobiphenyl SURROGATE 1 - jf 55 _ .X SW846 Methods 1311/8150 Preparation Date- ,10,DEC-97 Analysts: Date 12 DEC 97 0156. work group Number " 2,4D 94-75-7 1 ,.,.NO -.; ug/L.�' 10 2,4,5-TP (Si Lvex) 93-72-1 1 ND ug/L ... :, OCAA SURROGATE X _J zi .. .... _ I Review By: Rose Murphy Report ApproveE-By: Karen Kuoppala -- "Dil" - Sample Dilution Factor "ND" - Sample Concentration Not Detected above RL "RL" - Method Report Limit Form 1 - Data Summary Report Prepared By: HydroLogic Laboratories, Inc. iy Client ID: Project Number: Sample ID: Site / Project ID: Run ID: CoLLection Date: Received Date: Report Date: ROCCO TURKEYS SBR 92 SME1202B L6128-2 Not Reported R8756 01-DEC-97 03-DEC-97 11-DEC-97 . Analyte CAS No. .DiL Sample Conc- units RL SW846 Methods 13T1/6010 Preparation Datet '!l9-DEC-47 Analysis. Dater' 1T-DEC-9709:58 Yorkgrcup Number-. WG13379;...."' Arsenic 7440-38-2 1 NO: ae/C ..: "`^.2 Barium 7440-39-3 1 " .422'�'.. .: mg/L. .. .:.02 .. Cadmium 7440-43-9 1 :: NO mg/L,. .005 Chromium 7440-47-3 1 NO mg/L ".01 Lead 7439-92-1 1 :.i:r :.�., ND,. .;:. ..::?� mg/L, Selenium 7782-49-2 1 NO mg/L .1 Si Lver 7440-22-4 1 NO mg/L -01 SW846 Method. 131117170 .. .. .. .... .. .. .. .. .: - ... Analysis Date: T1-DE69714:44**'" _ q Workgroup Number: W013406 Mercury 7439-97-6 1ND mg/G. Review By: Rose Murphy Report Approved -Sy; Karen Kucppala "Di L" - Sample Dilution Factor "ND" - Sample Concentration Not Detected above RL "RL" - Method Report Limit Farm 1 - Data Summary Report Prepared By: MydroLogic Laboratories, Inc. A Client ID: Project Number: Sample ID: Site / Project ID: Run ID: Collection Date: Received Date: Report Date: ROCCO TURKEYS SBR 92 SKE12029 L6128-2 Not Reported R8756 01-DEC-97 03-DEC-97 11-DEC-97 Analyte CAS No., Di'l Sample Cone. Units Dual MDL RL S4-846, Method 9045 - Analysis Date: 04-DEC-97 12:20: , Vorkgrcup Number: :... . pN .. .. N/A ... 1 SL846, Method'1610 Analysis Date:, 09-DEC-97 12:10' " Vorkgroup Number: Ignitability N/A 1 EPA- Method.7.3.3.2 Analysis Date: 15-DEC-97 13-10 Vorkgroup Number: YO.13437 Reactive Cyanide N/A 1 EPA,. Method 7.3.4.2 Analysis.Date '16-6EC 97 1t 00 Yorkgroup. Numbee. .. WG13394._...,J Reactive Sulfide N/A 1 Review By: Rose Murphy Report Approved By: Karen Kucppala Dual - U = Analyte Not Detected above the Method Detection Limit - J = Estimated Concentration, B = Analyte Detected in the Blank - E = Analyte Cone. is above the Method Calibration Range Dil - Sample Dilution Factor NO - Sample Concentration Not Detected above MDL MDL - Method Detection Limit RL - Method Reporting Limit Chain of CustodyReca•d —1 m I JF1bLJ,4IV, 1I11}/. S M1r /aO0! U3 Page-1- of 'I n nshaville, NC n Norcross, OA f] Frankfurt KY L Lund,enon, l7 Charlotte, NC 17 Morrisville, NC (7(m) 254-5169 (771) 368.0636 (502) 223-0251 7 0 738- (704) 392-1164 1919) 38169697 Rrigblon, CO M Orlundo, FL 0 Lexin O Richmond. VA n Burlington. NC 1-I Mncon, GA . 3) 659-0497 (407) 851-2560 (8( 796-8989 ON) 358-3145 (911) 570 4661 (912) 757 0811 Client: S�MC Tide• Project No.: 1588-93.014 REQUESTED PARAMETERS 19IIMME D. A = Asheville, NC. RR nAddress: .�•/Zfl Ocn BATREA&I,,n �GqD Invoice Address: SAME li = Millington, NC C = Charlotte. NC u = Denver, CO k R = Lexington, SC O G = Macon,llA VT K = Frankfort. KY 1. = Lumbenan, NC p M= Morrisville, NC J`v N= Norcross, CA k v U = 01'l:ndu, Fl, J, It = Richmond, VA J/Y S = Suirconlructed � 1>eErNseoen, M1 C M410 Attn: 'r�� n8 �I�lce,C Alan: Phone No,: Cg 161 2S8- r1126 l Sampled By: Fax No.: C910) 2845- 89W P.O. No: Val+ State Salples Collected TIIRNAROUND TIME •� Cl 24 (fours n 48 Hours O 5Days 10 Days Date Needed: Na ,e4A Sumple 11) (late Time Court)/ Grub Matrix Continue F1'reserv. REMARKS acre Ttieks s- D F-u I E017 4t45 6eAe Saaae 4 6ece TueKe 5- seert2 lzjt qri 4:45 e2eA8 .5(40GE ¢ I Ix r 3}j l e 4 �� 1 j r dyet r/ ii 3} "t', ti' t r a r(� Ir p !�rr i 4 Cruilal91Seoll ` Y�Ntt''I'j/Af itl r lii`rr f r r [n I WNW' l s. t:. j�p .�J 4i +ic (i11 'G I:, r 4 1 ,t I ��l1:) REEE •,I . p. bdl Loh Temp,Rec.La4 Temp COMh1MNTS: J-os : �oCcb TueKEYS Relinquished By: • Dal Time �2�t� : je A.M Received By. \ _ A ,h-I - q p,c pt J (J .I.nb Use Onlyl ' ; (.., :' ,I: • :. ; :: i :: /''r ' ,i•-':•' "(��'$�'• .. .l U,'•t ; Relinquished By: el r ne /Cl Of Received By: Date "I uuc+i:. Relinquished By: Dale lime Received By: Dane 'lime Relinquished By: Date Time Received By: Dam Tinnu HYDROLOGIC LABORATORIES, INC Sample Cross Reference Table Company Name: HydroLogic-Lumberton HydroLogic Login Number: L6128 — . .Hy&9L"9" "-AS.q'wpIg N....t"...nb.. * Gent Sample ................ ........ . Sample:Dafeff L6128-1 ROCCO TURKEYS DAF #1 01 Dec 97 16:45 L6128-2 ROCCO TURKEYS SER #2 01 Dec 97 16:45 HYDROLOGIC LABORATORIES, INC DATE AND TIbi E SLTNL IARY SAiviPIE.L�ER L6128.1... CL LI .T ID :ROCCO:nT—WMY.S,DAF al, , ktAATRIGES Leac}iaie:Sail — SW846 1311/8150 12/01/97 16:45 12/10/97 12/12/97 01:20 SW846 1311/8080 12/01/97 16:45 12/11/97 12/12/97 03 23 SW846 1010 12/01/97 16:45 12/09/97 12/09/97 11:10 SW1311 12/01/97 16:45 12/11/97 12/11/97 14:42 SW I311 12/01/97 16:45 12/08/97 12/11/97 13:41 . SW 1311 12/01/97 16:45 12/09/97 12/11/97 09:54 SW1311 12/01/97 16:45 12/11/97 12/11/97 18:24 SW-846, METHOD 904512/01197 16:45 12/04/97 12/04/97 12:18 E 7.3.4.2 12/01/97 16:45 12/09/97 12/10/97 11:00 E 7.3.3.2 12/01/97 16:45 12/09/97 '12/15197 13:10 SAi�IPLE;,NLt14ER 16128.2; ...GLIFrTID.. ROCCO.T,URKEYS.SBK/�2 'lY1ATRIGF.S_ieachate Soil..,.. SW846 1311/8150 12/01/97 16:45 12/10/97 12/12/97 01:56 ` SW846 1311/8080 12/01/97 16:45 12/11/97 12/12197 03:23 SW846 1010 12/01/97 16:45 12/09/97 12/09/97 12:10 SW1311 12/01/97 16:45 12/11/97 12/11/97 14:44 SW1311 12/01/97 16:45 12/08/97 12/11/97 14:28 SW1311 12/01/97 16:45 12/09/97 12/11/97 09:58 SW1311 12/01/97 16:45 12/11/97 12/11/97 19:05 SW-846, METHOD 904512/01/97 16:45 12/04/97 12/04/97 12:20 E 7.3.4.2 12/01/97 16:45 12/09/97 12/10/97 11:00 E 7.3.3.2 12/01/97 16:45 12/09/97 12/15/97 13:10 Page 1 DAF ANALYSIS Farm 1 - Data Summary Report Prepared By: HydroLogic Laboratories, Inc. Client to: Project Number: Sample 10: Site / Project ID: Run ID: Collection Date: Received Date: Report Date: CAS Mo. SY846 Method 1311/8240. Preparation Date: 11-DEC-97 Analysis Date: 11-OEC-97 18:24. Yorkgroup Number: WGI3399 Benzene 71-43-2 Carbon tetrachloride 56-23-5 ChLorcbenzene 108-90-7 Chloroform 67-66-3 1,4-Dichlorobenzene 106-46-7 1,2-Oichloroethane 107-06-2 1,1-Dichloroethene 75-35-4 Methyl ethyl ketone 78-93-3 Tetrachloroethene 127-18-4 TrichLoroethene 79-01-6 Vinyl chloride 75-01-4 Dibromof Luaromethane SURROGATE To Luene-d8 SURROGATE 4-eromcfluorobenzene SURROGATE 511846 Me4h6d 1311/8276.,. Preparation, Date v 08-DEC 97 Analysu.Date 1.1. OEC-9T 13 41�- 1lorkgroup,'Numbecr WG13372 Cresol 106-44-5 2,4-Dinitrotoluene 121-14-2 Hexachlarobenzene 118-74-1 Hexachlarobutadiene 87-68-3 HexachLaroethane 67-72-1 Nitrobenzene 98-95-3 PentachLorophenoL 87-86-5 Pyridine 110-86-1 2,4,5-TrichloraphenoL 95-95-4 2,4,6-Trish LoropherioL 88-06-2 Nitrobenzene-d5 SURROGATE 2-FLuorabiphenyL SURROGATE Phenol-d6 SURROGATE 2-FLuorophenoL SURROGATE 2,4,6-Tribromophenol SURROGATE Review By: Rose Murphy DiL 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ROCCO TURKEYS DAF AM SME12028 L6128.1 Not Reported R8756 01-DEC-97 03-DEC-97 11-DEC-97 e Conc. Units ND ug/L NO'.,. ... ug/L ND ug/L ND ug/L NO ug/L NO ug/L ND ug/L ND ug/L NO ug/L ND ug/L ND .� ug/L 80 87 84 .:.; . X i No ug/L .. No ug/L .. .,.No ug/L . NO ug/L .,. No s ug/L .. .. ND Ug/L .. NO ug/L ND .. ug/L. 76. X. - 74 % 75 .. X . 68 X 77 X Report Approver By:` Karen Kuoppala "Bit" - Sample Dilution Factor "NO'. - Sample Concentration Not Detected above RL "RL" - Method Report Limit RL 50 50 50 50 T00 5o 50 250 50 50 100 ,'a00 100 100 100 100 100 500 .500 :100 100 Form 1 - Data Summary Report Prepared By: HydroLogic Laboratories, Inc. Client ID: Project Number: Sample ID: Site / Project ID: Run ID: Collection Date: Received Date: Report Date: ROCCO TURKEYS OAF $1 SME12028 L6128-1 Not Reported R8756 01-DEC-97 03-DEC-97 11-DEC-97 Analyte CAS No. " Di'C Sample Conc. Units RL SW846 Methods 1311/8080 .` Preparation;Date:.� 1.1:-DEC-97 ,. . Analysis. Date. 12-DEC-97 03:23- ... .. Workgroup Number:- WG13407'. _:. ... Lindane 58-89-9 1 NO - _. WL Chlordane 57-74-9 1 1, NO •-ug/C Endrin 72-20-8 1 - ND' • ug/L Heptachlor 76-44-8 1 .. NO - ug/L .5 Methoxychlor 72-43-5 1 '> NO.. ..., :ug/L r 5 =. - Toxaphene 8001-35-2 1 NO ug/L 24 Tetrachloro-m-xytene SURROGATE -55 Decachlorobiphenyt SURROGATE 1 SW846 Methods:131i/8150.- Preparation Date: 10-DEC-97 '. AnaCysis:Date:.112-DEC-97 01:20': Workgrcup Nl Ti r 1WG13395 .. .. 2,4 D 94 75-7 1..: 2, 4,5-TP (Si lvex) 93-72-1 1 - ::. NO''- OCAA SURROGATE 1 ^.86 X Review By: Rose Murphy Report Approved By: Karen KuoppaLa -- "DiL" - Sample Dilution Factor "ND" - Sample Concentration Not Detected above RL "RL" - Method Report Limit Form 1 - Data Summery Report Prepared By: HydroLcgic Laboratories, Inc. Client ID: ROCCO TURKEYS DAF *1 Project Number: SME12028 ' Sample ID: L6128-1 Site / Project ID: Not Reported" Run ID: R8756 Collection Date: 01-DEC-97 Received Date: 03-DEC-97 Report Date: TT-DEC-97 - Ana lyte-. CAS No. Oil" Sample Conc. Units- RL SW846 Methods 1311/6010 . Preparation Dater 09-DEC-97 Analysis Dater l.f-DEC-97 09:54 Workgroup Numbers WG13379 :.. ..." .... - .. . Arsenic 7440-38-2 1 ND mg/L :Z , Barium 7"0-39-3 1 Y 468. - "mg/L'.' --02 ... Cadmium 7440-43-9 1 - NO mg/L .005 Chromium 7440-47-3 1 NO "mg/L - .01 Lead 7439-92-1 ND :?:.. ' :..:. `mg/L ' '. ., '... ..I . .:.. .t. Selenium 7782-49-2 1 .. ..:.2T .... ' ::" mg/L -. Silver 7440-22-4 1 ND. ,mg/L .01 SW846 Method 131177470 ` Analysis Date: '11-DEC-97 14.-42'. ".. Workgroup Number: WG13405`'. - - Mercury 7439-97-6 1-,NO . mg/L 0002 Review By: Rose Murphy Report ApproveiiBy: Karen Kucppa La "Dil" - Sample Dilution Factor "ND'. - Sample Concentration Not Detected above RL , "RL" - Method Report Limit Form 1 - Data Summary Report Prepared By: HydroLogic Laboratories, Inc. Client ID: Project -Number: Sample ID: Site /Project ID: Run ID: Collection Date: Received Date: Report Date: ROCCO TURKEYS OAF #1 SME1202B L6128-1 Not Reported R8756 01-DEC-97 03-DEC-97 11-DEC-97 Review By: Rose Murphy Report Approved By: Karen Kuoppala Oual - U = Analyte Not Detected above the Method Detection Limit - J = Estimated Concentration, B = Analyt&Deteeted in the Blank - E = Analyte Ccnc- is above the Method Calibration Range --� Dil - Sample Dilution Factor — ND - Sample Concentration Not Detected above MDL MDL - Method Detection Limit RL - Method Reporting Limit a.harn of Outing decoru - L err i f.:.eiL�r w� �Crvrr■ L 70 h-I A n cwv- Page I of ! (l Asheville, NC Ll Norcross, GA O Frankfort KY Lumberton, NO O Charlotte, NC Ll Morrisville, NC (70-1)254-5169s,� (770) 368-0636 (502)223-0251 )738 6190 (7(A)392-1164 (919)380-9699 ' y;� Ilriglnon, CO n Orlando, F1, 0 Lexin ton,-$C� `� Richmond, VA n Burlington, NC 17 Macon, CA '� ,) 659IM97 (407) 951-2560 (803) 796-89 19 (804) 358-3145 (910) 570-4661 (912) 757-0811 Client: PojectNh° I.AtefL REQUESTED AR — af.. 7A= Asheville, NC Re in Address: Invoice Address: i B = Burlington, NC �Jy, 0 15M7T1l/eabem kortD J/lnir C = Clmrinue, NC -'1 r ' H6eq ALL L2416 �. A. D = Denver, CO ,�3s r = Lexington, SC Ann: Attn: 6 Il l Co v 6 = Macon,GA h . e K = Frankfurt, KY L = Lumberton. NC Phone No.; / ') I4) r. ,, . 't 3U 1 Sampled By: Fax No.: jIU� 7' - " P.O.No: - M= Morrisville, NC �'.c -. N= Norcross, GA Slate Samples Collected IIHNAROUNU TIM1IE �L „ O = Orlando, 11. 171 24 Hours 1-] 48 Dours ^ R = liichnunul, VA I-1 Days 10 Days Dale Needed: Ali �" 5� ` ? y' S = Subcontracted 5 V, Sample 11) hale I Time Corali, Grab Matrix contullwn Preserv. REMARKS /(ot're71,+-11r�- /F>!.I 111.17 AS I{71- s1:raG! q -r �,G01 2 hf l g9 A A S CC1113 -k49Yfq #t't a'Ctr ' j'�,+'7/� �t� rr IIIIYA�M * ,. I,Y6lIse Onl bd el ]' r+ 1 (. 7 I p+ c! !v A r "� 1IKff p� -r. r.- c�,. r. ,1 IS ^� a,i ', ,i+.r-., �4.,,rt? {5� ..Q-'.r.. ri. „r COMMENTS: Jo.a Pgcco TuPKr1I5 Relinquished By: Date Time Received By'-' r DalTi ne 17, l;Yb ' i Relinquished By:' Dale 3'iyure Received By: Dale Time Relinquished By: Dale Time Received By: Date Time 1� p ' r •h Relinquished BY: Dale lime Received By: I�T171 HYDROLOGIC LABORATORIES, WC Sample Cross Reference Table' Company Name: HydroLogic-Lumberton HydroLogic Login Number: L6128 IEN& 9 ""'i Si- y ..... ..... L6128-1 ROCCO TURKEYS DAF #1 01 Dec 97 16:45 L6128-2 ROCCO TURKEYS SBR #2 01 Dec 97 16:45 I HYDROLOGIC LABORATORIES, INC DATE AND TIVi EE SUN fARY Company Name: HydroLogic-Lumberton Project: SME1202B HydroLogic Login Number: L6128 SAMPLE NT31Y1SER:: L6t28 1 .. . ... :, ROCCO:Tt7RKEYS DAF .:..MAT'RICES Leachare; SotI > . SW846 1311/8150 12/01/97 16:45 SW846 1311/8080 12/01/97 16:45 SW846 1010 12/01/97 16:45 SW1311 12/01/97 16:45 SW1311 12/01/97 16:45 SW1311 12/01/97 16:45 SW1311 12/01/97 16:45 SW-846, METHOD 904512/01/97 16:45 E 7.3.4.2 12/01/97 16:45 E 7.3.3.2 12/01/97 16:45 12/10/97 12/12/97 01:20 12/11/97 12/12/97 03:23 12/09/97 12/09/97 11:10 12/11/97 12/11/97 14:42 12/08/97 12/11/97 13:41 12/09/97 12/11/97 09:54 12/11/97 12/11/97 18:24 12/04/97 12/04/97 12:18 12/09/97 12/10/97 11:00 12/09/97 12/15/97 13:10 SAMPLE:NUM3ER _L61282. CLIEriT ED ROCCO:TURKEYSSBk*2: MATRICES.Leachate,_soil . SW846 1311/8150 12/01/97 16:45 12/10/97 12/12/97 01:56 SW846 1311/8080 12/01/97 16:45 12/11/97 12/12/97 03:23 SW846 1010 12/01/97 16:45 12/09/97 12/09/97 12:10 SW1311 12/01/97 16:45 12/11/97 12/11/97 14:44 SW1311 12/01/97 16:45 12/08/97 12/11/97 14:28 SW1311 12/01/97 16:45 12/09/97 12/11/97 09:58 SW1311 12/01/97 16:45 12/11/97 12/11/97 19:05 SW-846, METHOD 904512/01197 16:45 12/04/97 12/04/97 12:20 E 7.3.4.2 12/0J/97 16:45 12/09/97 12/10/97 11:00 E 7.3.3.2 12/01/97 16:45 12/09/97 12/15/97 13:10 Page 1