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Home My WebLink AboutNC0003433_Historical_20017-2019DUKE ENERGY. October 29, 2019 Mr. Jeff Poupart NC DWR Permitting Section 1617 Mail Service Center Raleigh, NC 27699-1617 NC Dept of Environmental Quality Nov -1 22019 Raleigh Regional Oft%e RE: Initiation of Dewatering NPDES Permit Number NC0003433 Duke Energy Progress LLC — Cape Fear Steam Electric -Power Plant Chatham Count Dear Mr. Poupart: Cape Fear Steam Electric Plant 500 CPBL Road Monwre. NC 27559 Per the requirement in Condition A. (5)(e) in the referenced permit, Duke Energy respectfully submits this letter as notification that Cape Fear Steam Electric Power Plant intends to commence dewatering of the ash basins. Should you have any questions regarding this submittal or require additional information, please contact Joyce Dishmon at (336) 623-0238 or email joyce.dishmon@duke-energy.com. 1 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Sincerely, Issa J. Zarzar General Manager —East Region CCP Operations and Maintenance t 4S DUKE Cape Fear Steam Electric Plant SM CPaL Road ENERGY. Moncure, NC 27559 Cc: Rick Bollick, NC DWR, Water Quality Regional Office, 3800 Barrett Drive, Raleigh, NC 27609 Shannon Langley Joyce Dishtnon (filenet) Jonathan Stamas Manuel, Vanessa From: Dishmon, Joyce Martin <Joyce.Dishmon@duke-energy.com> Sent: Wednesday, October 30, 2019 10:02 AM To: Chernikov, Sergei; Poupart, Jeff Cc: Langley, Shannon; Stamas, Jonathan; Manuel, Vanessa Subject: [External) NC0003433 Notification of Initiation of Dewatering of Ash Basins Attachments: NC0003433 - Initialon of Dewatering.pdf Jeff, Per the requirement in Condition A.(5)(e), I have attached a letter of notification that Duke Energy Cape Fear Steam Electric Power Plant intends to commence dewatering of the ash basins for your review and file. Please let me know if you have any questions or require additional information concerning this submittal. Regards, Joyce Dishmon Permitting and Compliance, Carolinas Office: 336-623-0238 Cell: 336-394-5524 Email: joyce.dishmon@duke-energy.com DUKE r. ENERGY. October 29, 2019 Mr. Jeff Poupart NC DWR Permitting Section 1617 Mail Service Center Raleigh, NC 27699-1617 RE: Initiation of Dewatering NPDES Permit Number NC0003433 Duke Energy Progress LLC— Cape Fear Steam Electric -Power Plant Chatham Count Dear Mr. Poupart: Cape Fear Steam Electric Plant 500 CPSL Road Monwre. NC 27559 Per the requirement in Condition A. (5)(e) in the referenced permit, Duke Energy respectfully submits this letter as notification that Cape Fear Steam Electric Power Plant intends to commence dewatering of the ash basins. Should you have any questions regarding this submittal or require additional information, please contact Joyce Dishmon at (336) 623-0238 or email joyce.dishmon@duke-energy.com. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. Sincerely, Issa J. Zarzar General Manager —East Region CCP Operations and Maintenance (� DUKE ENERGY® Cape Fear Steam Electric Plant 500 CPBL Road Moncure, NC 27559 Cc: Rick Bollick, NC DWR, Water Quality Regional Office, 3800 Barrett Drive, Raleigh, NC 27609 Shannon Langley Joyce Dishmon (filenet) Jonathan Stamas DUKE �'"ENERGY April 1, 2019 NC Division of Water Resources Water Quality Regional Office Operations Section Supervisor Attn: Rick Bollick Duke Energy Cape Fear Steam Electric Power Plant 500 CP&l Road Moncure, NC NC Dept of Environmental Qualit) APR - 2 2019 3800 Barrett Drive Raleigh Regional Officc Raleigh, NC 27609 Subject: Commissioning of Outfall 008 NPDES Permit Number NC0003433 Duke Energy Progress LLC - Cape Fear Steam Electric Power Plant Chatham County Dear Mr. Bollick, Duke Energy respectfully submits notification of the commissioning of Wastewater Outfall 008 - Ash Pond (decanting)- no later than fourteen days prior to discharge of flows, as required by Supplement to Permit Cover Sheet section 2. of the NPDES Wastewater Permit NC0003433. With the commissioning of Outfall 008, Duke Energy requests this outfall be made active in the eDMR system as of April 15, 2019. Should you have any questions regarding this submittal or require additional information, please contact Steve Cahoon at 919-546-7457 or email steve.cahoon@duke-energy.com. "I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system design to assure that qualified personnel properly gatherandevaluate the information submitted. Basedon myinquityofthe person orpersons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Issa Zarzar CCP O&M, General Manager Cape Fear Steam Electric Plant Cc: Issa Zarzar, Shannon Langley, Steve Cahoon -54�E G Imo+ aAcr: q19-5416-1464 invb 'le : ql9- 432- 1119 ROY COOPER' Governor WCHAEL S. REGAN Secretary LINDA CULPEPPER interim Director NORTH CAROLINA Environmental Quality r December 14, 2018 Paul Draovitch Duke Energy Progress, LLC am 526 S Church Street — Ec3 xp Charlotte, NC 28202 Subject: Compliance Evaluation Inspection Cape Fear Steam Electric Power Plant NPDES Permit NC0003433 Chatham County Dear Mr. Draovitch: On Tuesday, December 4, 2018, Vanessa Manuel of the Raleigh Regional Office conducted a compliance evaluation inspection of the treatment facilities located at the decommissioned Cape Fear Steam Electric Power Plant, hereinafter referred to as the Cape Fear Plant. The purpose of this visit was to conduct an inspection of the subject NPDES facility. During the inspection, the presence and cooperation of Jonathan Stamas, Operator in Responsible Charge (ORC), and Joyce Dishmon, Subject Matter Expert for Wastewater, were helpful and appreciated. The Cape Fear Plant is located at 500 CP&L Road in Moncure North Carolina. The facility is classified as a Physical/Chemical-1 wastewater treatment plant that treats industrial wastewater and is authorized to discharge the treated wastewater through outfall 007 into an unnamed tributary to the Cape Fear River and through outfalls 008 and 009 into the Cape Fear River. The receiving waters of the discharges are classified as WS-IV in the Cape Fear River Basin. This NPDES compliance evaluation inspection consisted of the following: • Review of the NPDES permit; • Review of the owner/facility information; • Review of October 2016 — September 2018 monitoring data; • Review of October 2016 — September 2018 compliance history; • On -site inspection of the wastewater treatment units; and • On -site inspection of the discharge outfall. Findings during the pre -inspection file review were as follows: 1. The current NPDES permit was issued effective October 1, 2018, and will expire June 30, 2023. North Carolina Department of Environmental Quality I Division of Water Resources I Raleigh Regional Office 3800 Barrett Drive 11628 Mail service Center I Raleigh, North Carolina 27699-1628 919.791.4200 Paul Draovitch, NC0003433 December 14, 2018 Page 2 of 2 2. As listed in the subject permit, the treatment systems include: 1978 Ash Basin (internal outfall 001); 1985 Ash Basin (internal outfall 005); Combined wastewater to an unnamed tributag,to the Cape Fear River (outfall 007); Combined wastewater to the Cape Fear River 0%9 b08); 19634970 Ash Basins (outfall 008A); Ash beneficiation retention pond 'tewater (outfall 009); Constructed French drain (internal outfall S-05). 3. Beginning December.21, 20I drlrr NPIES Electronic Reporting Rule requires permittees _ to submittt 1e1i discharge monttartng repora (DMRs) electronically, instead of on paper. The first DMR the Divis' ly from the permittee was for November 2016. To learn more about the eDMR system, please visit the Division's eDMR website at his://deq.nc.gov/about/divisions/water-resources/edmr. 4. For the review period October 2016 — September 2018, the following violation was detected: Aquatic toxicity permit limit violation on August 14, 2017. No enforcement actions have been issued during the review period to Duke Energy for the subject permit. Findings during the inspection were as follows: 5. The operator's log and supporting analytical documentation were consistent and up to date. 6. During the period October 2016 through September 2018, no discharge was recorded on the DMRs for October through December 2016, and January through September 2018. The inspector compared the April 2017 DMR data against the ORC's bench lab data and Duke Energy's lab results. No discrepancies were noted. 7. The treatment systems were maintained and no apparent issues of concern were noted. 8. Sanitary wastewater generated at the Cape Fear Plant is pumped and hauled off -site. 9. The inspector observed the receiving streams for effluent discharges to be clear with no observable solids or foam. No detrimental impacts to the UT to the Cape Fear River and to the Cape Fear River from the effluent discharges were observed. If you have questions or comments about the inspection, this report or the requirements to take corrective action (if applicable), please contact Vanessa Manuel at 919-791-4255 or via email at Vanessa. Manuel(a,ncdenr. eov. Sincerely, icklol�ich, LG, Assistant Regional Supervisor Water Quality Regional Operations Section Raleigh Regional Office Attachments: EPA Water Compliance Inspection Report Cc: RRO/SWP Files Central Files QS North Carolina Department of Environmental Quality I Division of Water Resources 512 North Salisbury Street 11617 Mall Service Center I Raleigh. North Carolina 27699-1617 919.707.9000 Dnited States Environmental PraterLm Agency Fonn Approved. EPA Washington. D C 2040 OMB No. 2040-0057 Water Compliance Inspection Report Approval expires 8-31-98 Section A: National Data System Coding (i.e., PCs) Transaction Code NPDES yr/rnoiday Inspection Type Inspector Fac Type 1 �N 2 Is 1 3 L NC0003433 I11 12 I 18,12,04 I17 18 Ld 19I c I 201 I 21111111111111111111111jII I I I I I I I IIIIIIIIIII I66 Inspection Work Days Facility Self-Mondoring Evaluation Rating B 1 CA Reserved 67I I 701 LI 711 I 72 (r� ( I� � LJ 731 I 174 751 I I I I I I 180 Section B: Facility Data Name and Location of Facility Inspected (For Industrial Users discharging to POTW, also include Entry Tme/Date Permit Effective Date POTW name and NPDES permit Number) 09:45AM 18/12/04 18)10/01 Cape Fear Steam Electric Power Plant Exit Time/Date Permit Expiration Date 500 CP L Rd Moncure NC 27559 12:OOPM 1812/04 23/06/30 Name(s) of Onsite Representabve(s)/Tldes(s)/Phone and Fax Numbers) Other Facility Data 1/1 Jonathan Christian SWmas/ORC/512-913-8524/ Name, Address of Responsible Official/Tide/Phone and Fax Number Hershel) McCarty S00 CP L Rd Moncure NC 275591// Contacted Yes Section C: Areas Evaluated During Inspection (Check only those areas evaluated) Permit Operations & Maintenance Records/Reports Self -Monitoring Program Facility Site Review Efituent/Receiving Waters Laboratory Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) (See attachment summary) Names) and Signatures) of Inspecton(s) Agency/Office/Phone and Fax Numbers Date Vanessa E Manuel RRO ��c. /3, zo /0 i 9i9 9i yzss Signature of Manoemer A Reviewer Agency/Office/Phone and Fax Numbers Date AZOV EPA Form 3560-3 (Rev 9-94) Previous editions are obsolete. Page# NPDES 31 NC0003433 I11 yr/mo/day Inspection Type 12 18/12/04 17 18 1 C Section D: Summary of Finding/Comments (Attach additional sheets of narrative and checklists as necessary) See attached report. Page# Permit: NC0003433 Inspection Date: 12104,2013 Owner - Facility: Cape Fear Steam Electric Power Plant Inspection Type: Compliance Evaluation Permit Yes No NA NE (If the present permit expires in 6 months or less). Has the permittee submitted a new ❑ ❑ M ❑ application? Is the facility as described in the permit? 0 ❑ ❑ ❑ # Are there any special conditions for the permit? ❑ M ❑ ❑ Is access to the plant site restricted to the general public? 0 ❑ ❑ ❑ Is the inspector granted access to all areas for inspection? 0 ❑ ❑ ❑ Comment Record Keening Yes No NA NE Are records kept and maintained as required by the permit? 0 ❑ ❑ ❑ Is all required information readily available, complete and current? M ❑ ❑ ❑ Are all records maintained for 3 years (lab, reg. required 5 years)? M ❑ ❑ ❑ Are analytical results consistent with data reported on DMRs? M ❑ ❑ ❑ Is the chain -of -custody complete? M ❑ ❑ ❑ Dates, times and location of sampling Name of individual performing the sampling Results of analysis and calibration Dates of analysis Name of person performing analyses Transported COCs Are DMRS complete: do they include all permit parameters? M ❑ ❑ ❑ Has the facility submitted its annual compliance report to users and DWO? ❑ ❑ M ❑ (If the facility is = or > 5 MGD permitted flow) Do they operate 24/7 with a certified operator ❑ ❑ M ❑ on each shift? Is the ORC visitation log available and current? 0 ❑ ❑ ❑ Is the ORC certified at grade equal to or higher than the facility classification? ❑ ❑ ❑ Is the backup operator certified at one grade less or greater than the facility classification? ❑ ❑ ❑ Is a copy of the current NPDES permit available on site? ❑ ❑ ❑ Facility has copy of previous year's Annual Report on file for review? ❑ ❑ M ❑ Comment: Operations & Maintenance Yes No NA NE Is the plant generally dean with acceptable housekeeping? 0 ❑ ❑ ❑ Page# 3 Permit N00003433 Inspection Date: 12,M2018 Owner • Facility: Cape Fear Steam Electric Power Plant Inspection Type: Compliance Evaluation Operations & Maintenance Does the facility analyze process control parameters, for ex: MLSS, MCRT, Settleable Solids, pH, DO, Sludge Judge, and other that are applicable? Comment: Effluent Pipe Is right of way to the outfall properly maintained? Are the receiving water free of foam other than trace amounts and other debris? If effluent (diffuser pipes are required) are they operating properly? Comment: Yes No NA NE ❑ ❑ ■ ❑ Yes No NA NE ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ■ ❑ Page# 4 Inspection Agenda Cape Fear Steam Electric, N.,.,J03433 2018Deco4 vtr Si-/E� �%'�%5,4.�-� �r,ar+.e f : � 2 ,,•.x„y O ening Conference 1 • Purpose of inspection • Flow of inspection Pf• dY1•-3, 716' • Overview of plant layout (treatment components) Pe it Requirements �. NPDES WW Contacts Report • Permit status 2 ✓O y<L �,:t� �tr",, -sue �� S,w�j: MmF-Gi Ex�� • Electronic reporting - VteDMR: AW.2o/4* ,^A (--*.we) • Other /446�1141YGW($5t,-4 /( oar // / Laboratory �H /�affe'f;CEjY+ = iv��<i Sif++ ?� f • Parameters analyzed N 'fy A •I�'� (Kv t Af*( • Field Parameters p _� • k�xl�r Y/ k7T (`jEC�' �6 �% • Meter calibration logs and standards -Calibration frequency • Analytical bench sheets • Thermometer calibration dates) - NIST certified & in-house thermometers Paper Trail - Data Comparison (Lab Data to DMRs) g 2•// 2dr} CpJ[ret� per,'eg: • Review period: October 2016 -September 2018 • Selected DMRs (n=2 max.): Afir, 2^, l Tr e ment Components �1 ^�`SC<•i�"�r`•�— ORC logbook (see /L' n e�? p►cr�) • Plant walk-through Backup Generator • Run schedule • Auto switch on i run under load? Flow Measurement • Meter calibration date • On -site flow measurement (ISCO handbook) Sample Collection • Sample storage temperature • Sample handling after collection Receiving Waters • Appearance Closing Conference • BIMS inspection checklist • Findings • Expectations Ci'lCY' ve 11Page (t-PP air yes !� / � �$ crlN3) N .' s� �/ clt � j �^ ��77 p ✓y/ , (/ ""'u'S `%o 71Jw •>vJ>S�J nN--J�.;�� %s/' Q I P,Y")J r tn0 �0 .5 ITY f.'`% 1 `'� 9l st'`T`n Q crfz rir 9"1 fwr, E oy,*- ,, f , . , boo J/ f �0 3/r� °/ ^/ 5S',O? ' ,7 Vv/ fC �rba1 �7l �U�� o vnf 501) sV z goo ��Nti �,� �r�y�0 f`' -1 I North Carolina Department of Environmental Quality Division of Water Resources Permit Number: NC0003433 Permit Type: Industrial Process & Commercial Wastewater Discharce Facility Name: Cape Fear Steam Electric Power Plant Facility Addressl: 500 CP L Rd Facility Address2: City, State & Zip: Moncvre. NC 27559 Owner Information Details: MUST submit a Change of Name/Ownership form to DWR to make any changes to this Owner information. (Click here for "Change of Name/Ownership"Form) Owner Name: Duke Energy Progress LLC Owner Type: Non -Government Owner Type Group: Orgaarr.;,on *** Legally Responsible for Permit *** (Responsible corporate officer/principle executive officer or ranking elected official/general partner or proprietor; or any other person with delegated signatory authority from the legally responsible person.) Owner Affiliation: Paul Drawitch ti Title: $ EN 5 Senior VP Add ressl: 526 S Church St - EG3xn Address2: City, State & Zip: Charlotte_ NC 28202 Work Phone: 980-373-0408 Fax: Email Address: Paul DraovitchOld uke-energy com Owner Contact Person(s) Contact Name Iit(e Address phone Eaa mil Tram-F�'ppt-�-� M1taeagq'fFa i ner p� U..611 ac 1�r - '1� com Fadlity Contact Person(s) fir Contact Name IiSle '%(y phone EAK Address Cl Email ___ ____ _11. S 411 Fayetteville St, Raleigh, NC 27601 _ m t 4t'- m Permit Contact Person(s) Contact Name Ti le Address phone E" t:mail � 500 CP L Rd, Moncure, NC 27559 � Ly n� ql��Yty � _ - \� 1 �iW C.v�[JtIL e.,e nr Permit Billing Contact Person(s) , C, Contact Name Iltle Address Phone Fax Email Pay -I Dracv t-P 526 S Ch„,-^ St-Ec3xp, CharloGe, riC 980-373-OaCS s.. -' �.7uke-energ 28202 Persons with Signatory Authority I= Contact Name IitLa Address Phone Fax Email 11/28/2018 Page 1 Permit Number: NC0003433 Permit Type: Industrial Process & Commercial Wastewater Discharge Facility Name: Cam Fear Steam Electric Power Plant Facility Addressl: 500 CP L Rd Facility Addressl: City, State & lip: Moncure NC 27559 Designated Operators If the designated operators listed below are inoonrct orno longerassociated with the collection system, the Information can be updated by submitting a rompleted 'Operator designation Form "(Click Here for OSCOesionabon form). Please provide specific details as to the d ianges requested, including the addition/removal of designated operators. For a//otter operator questions or issues, please call 919-807-6353. Facility Classification: FCl Ooerator Name Rah Cert Tym Cert Status Cert # Effective Date Jonathan Christian Stamas ORC PC-1 � 'e 1003108 12/1/2016 William Michael Graham Backup PC-1 Active 1003536 12/1/2016 Dulcie F. Phillips Backup PC-1 Active 27889 12/1/2016 11/28/2018 Page 2 MONITORING REPORT(MR) VIOLATIONS for: Report Date 11/28/18 Page 1 of 1 Permit: nc0003433 MRs Between 10 - 2016 and 9 - 2016 Region: Raleigh Violation Category:% Program Category: NPDES WW Facility Name:% Param Name % County: % Subbasin:a Violation Action:% _-, Major Minor: % PERMIT: NC0003433 FACILITYDuke Energy Progress LLC - Cape Fear Steam Electric COUNTY: Chatham REGION: Raleigh Power Plant Other Violation MONITORING OUTFALL/ VIOLATION UNIT OF CALCULATED % REPORT PPI LOCATION PARAMETER DATE FREQUENCY MEASURE LIMIT VALUE Over VIOLATION TYPE VIOLATION ACTION 08-2017 08/14/17 Aquatic toxicity Permit Proceed to NOV limit violation flee. 201.9 Whole Effluent Toxicity Testing and Self Monitoring Summary Duke Energy Lee Steam Plant NCOD03417/001 County: Wayne Region: WARD Basin: NEU12 Mar Jun Sep Dec SOC_JOC: Ceri7dPF Begin: 11/1/2009 chr lim: 2.1% NonComp: Single 7Q10: 263.0 PF: VAR IWC: 0.47 Fret: 1/Qtr J F M A M J J A S 0 N D 2014 H - H H H H H H H 2015 H H H H - H H - H H - H 2016 - H H H H Pass - - H H - H 2017 H H H H - H H H H H H Pass 2018 - - Pass H Pass - Pass H H - - - Duke Energy -Cape Fear S.E./007 NC0003433/007 County: Chatham Region: RRO Basin: CPF07 Feb May Aug Nov SOC JOC: Ceri7dPF Begin: 9/1/2011 chr lim: 90% NonComp: Single 7010: 0.0 PF: NA IWC: 100 Freq: Q J F M A M J J A S O N D 2014 - Pass - - Pass - - H - - H - 2015 - H - - H - - H - - H - 2016 H H - - H - - H - - H - 2017 - Pass - - Pass - - Fail >100 >100 Pass - 2018 - H - - H - - H - - - Duke Energy-Roxboro/003 NC0003425/003 County: Person Region: RRO Basin: ROA05 Mar Jun Sep Dec SOC JOC: Fthd24PF Begin: 5/1/2007 24hracp/flim:90%f NonComp: Single 7Q10: lake PF: NA IWC: NA Freq: Q J F M A M / J A S O N D 2014 - - Pass - - Pass - - Pass - - Pass 2015 - - Pass - - Pass - - Pass - - Pass 2016 - - Pass - - Pass - - Pass - - Pass 2017 - - Pass - - Pass - - Pass - - Pass 2018 - - Pass - - Pass - - Pass - - - Duke Energy-Roxboro/006 NC0003425/006 County: Person Region: RRO Basin: ROA05 SOC_JOC: Fthd24Ac Begin: 5/1/2007 24hr LC50 ac monit a NonComp: 7Q10: Lake PF: NA IWC: NA Fret: A J F M A M J J A S O N D 2014 - >100 - - - - - - - - - 2015 >100 - - - - - - - - - - 2016 - - >100 - - - - - - - - 2017 - - - - >100 2018 _ - _ >100 - - - - _ _ Duke Power -Allen 002 NC0004979/002 County: Gaston Region: MRO Basi¢ CTB34 Jan Apr Jul Oct SOC_JOC: Cer17dPF Begin: 8/1/2018 chr lim: 23.6%for no NonComp: Single 7Q10: 95.0 PP: NA IWC 24 Freq: Q J F M A M J J A S O N D 2014 Pass - - Pass - - Pass - - Pass - - 2015 Pass - - Pass - - Pass - - Pass - - 2016 Pass - - Pass - - Pass - - Pass - - 2017 Pass - - Pass - - Pass - - Pass - - 2018 Pass - - Pass - - Pass - - - - Legend: P= Fathead minnow (Pimphales aromelas). H=No Flow (facility is active), s = Split test between Certified Labs Page 38 of 125 (> DUKE ENERGY. September 28, 2018 Mr. Jeffrey Poupart, Section Chief NC Division of Water Resources 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: Cape Fear Steam Electric Plant Amendment request for NPDES permit NC0003433 Chatham County Dear Mr. Poupart, Cape Fear Steam Electric Plant SOO.CP&L Roao Moncure, NC 27559 RECEIVED/DENR/DWR OCT 0 3 20 N 1'` *tens�uroes S As discussed previously with staff from Duke Energy (Duke) EHS, Duke hereby requests amendment of the subject permit. A check for $1,030.00 is included with this submittal. Duke requests that the Combined Wastewater outfall to the Cape Fear river (Outfall 008) be relocated to the following location, 35°35'29.54"N 79003'03.85"W. Please see the attached figure depicting the approximate requested location of the Outfall. Additionally, Duke requests a change to Part I. Section A. (13.) Instream Monitoring. The table describes the Instream Sample location relative to the existing Outfall 008. With the request to relocate outfall 008, Duke requests the Instream Sample Location description be changed as follows: Instteam Sample Deserl tion Location Upstream Outfall 008 10.9 miles upstream from Outfall 008A in Fear River Downstream Outfa11008 Approximately 250 meters downstream from outfall 008A in Cape Fear River If you have any questions regarding this letter, please contact Mr. Steve Cahoon at (919) 546-7457. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel property gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the btforntalum submitted a, to the best of my knowledge and belief, true, accurate, and compkie. 1 am aware that there are significant penalties for submitting false information, including the passibility of fines and bnprisonment for knowing violations. Sincerely, Issa I Zarzar GM CCP Regional OPS & Maintenance Enclosures Cc. Danny Smith - DWR Raleigh Regional office Steve Cahoon/FileNet - NC 15 Ion Stamas - Cape Fear Shannon Langley - NC 15 ON Cvc3wutod s3.05 +' +f Ou1fal! 009 tt �'wt Requested outfall ', U 008 location 35035'29.54"N tramalrnnfll�nut '• � \ nr, l 79003'03,85"W sw.,d,t.. Outf l008 •4 p =r ,. Ip -c+ , Y • a` USGS Quad- E22SE Nloncure. %'C LRtdN 007 OntfaD 008 Ouffall 009 Laricude. 35` 35- V N W 35' 37.i" N 35' 35- 37.9" . Longitu3e. 790 2' 27" W i9' 3' 4.tP W 79'- 3' 4.1" W Stream CIMS: US -IV %ftnisitr 01-"-07 HUC; 030.." 0? R=i,dng Stman• Cade Fetes Rim I Facility Location North DUKE Cape Fear Steam Electric Plant oad ENERGY® Ma curre NC CP&L27559 May. 22, 2017 S. Daniel Smith NC Dept of Environmental Quality Raleigh Regional Office North Carolina Department MAY 2 4 2017 of Environmental quality 1628 Mail Service Center Raleigh Regional Office Raleigh, NC 27699-1628 Subject: Compliance Evaluation Inspection, Cape Fear Steam Electric Power Plant J4 Ccop3,132) Dear Mr. Smith: � qµ Cpu y, On behalf of Duke Energy Progress, LLC ("DEP"), this letter responds to your letter of April 25, 2017 stating the findings of your March 24 Compliance Evaluation Inspection. Item 12 directed DEP to provide your office with an update on the development of the Ash Pond Closure Plan and to indicate whether decanting from the East and West Ash Basins and the voluntary use of the reverse osmosis treatment system would be part of the plant's closure plan. DEP's response is as follows: 1. Development of Ash Pond Closure Plan DEP has developed a draft closure plan for Cape Fear, but the plan has not been finalized. The company does not have a planned date for submitting the plan to the Department. The five impoundments at Cape Fear are classified by the Department as "intermediate -risk" under the Coal Ash Management Act of 2014 ("CAMA"), meaning that a closure plan is not due under the statute until December 31, 2019.' For these reasons, DEP has elected not to finalize the closure plans while additional details of the CAMA process are worked out. As an additional consideration, Cape Fear has been one of the subjects of a law suit by the Department in Wake County Superior Court. Last year, the Superior Court issued an Order Granting Motion for Partial Summary Judgment, which resolved the case as to Cape Fear and two other sites (H.F. Lee and Weatherspoon). The Order was negotiated and agreed to by both DEP and the Department (although the Department identified certain provisions to which neither objected nor endorsed). Among the requirements of the Order, the following are most relevant to closure planning: 32. Duke Energy Progress shall comply with the following requirements: a. Excavate and remove all CCR and Coal Combustion Products from the Cape Fear Impoundments ("Cape Fear Removed Ash") to lined locations for disposal in a CCR landfill, industrial landfill, or municipal solid waste landfill or for use as structural fill or other beneficial use pursuant to applicable law, and thereafter stabilize and close the area where the Cape Fear Impoundments are ' Cape Fear is not subject to the federal CCR Rule and is not required to generate a closure plan under that regulation. DUKE Cape Few Steam Electric Plwt Road ENERGY® Mores 27559 located pursuant to applicable law. Excavation shall include all coal ash, and such additional soil as is necessary for the protection of groundwater or as may be ordered by any regulatory agency or applicable law. b. Defendant shall ensure that the Cape Fear Removed Ash transferred for disposal is transferred to a lined CCR landfill, industrial landfill, or municipal solid waste landfill meeting applicable permitting, siting, construction, and engineering requirements established by applicable law, statute or regulation. 34. The Cape Fear Impoundments shall be closed according to the following timetable: For the 1956, 1963, and 1970 Ash Ponds, Duke Energy Progress shall begin excavation within five years of receiving the required permits and shall complete excavation within ten years of receiving the required permits. For the 1978 and 1985 Ash Ponds, Duke Energy Progress shall begin dewatering within one year of receiving the required permit(s), shall begin excavation within three years of dewatering, and shall complete excavation within ten years of dewatering. 41. The terms of this Order define Duke Energy Progress' minimum obligations regarding closure. Any closure plan submitted by Duke Energy Progress shall not be inconsistent with this Order. 42. A decision by any agency on the closure plan for Cape Fear that is final under the North Carolina Administrative Procedure Act and otherwise appealable under applicable law may be challenged by Duke Energy Progress and/or any of the Plaintiff - Intervenors by filing a contested case in the Office of Administrative Hearings, but only to the extent it is inconsistent with this Order. The terms of the Order dictate to a large extent the contents of the closure plan, but DEP recognizes that they do not supersede the requirement to submit a closure plan one year prior to the closure of the facility, as stated in the NPDES permit. 2. Decanting of the East and West Ash Basins The decanting currently taking place at Cape Fear is not part of the closure process. Rather, it is taking place as part of the Duty to Mitigate found in Part II.B.2. of the NPDES permit standard conditions. The authorization to decant was communicated to DEP by the Department by letter dated December 17, 2015. The authorization was later modified the Department by letter dated July 20, 2016, which mandated the use of physical -chemical treatment facilities. Both letters are attached for your reference. The current decanting is not designed to bring the impoundments to the point that they are ready for closure. The Department's authorizations only allow drawdown to three feet above the ash in the vicinity of the pump under current permits. Further decanting and dewatering of interstitial water must be authorized by a new permit. The current decanting is an interim measure to mitigate risks until a new permit is issued and closure can begin. As a result, some additional dewatering may be required as part of the closure plan, but that would be a separate operation with different goals. �( DUKE ENERGY® Please let us know if you have any further questions. Sincerely, Issa J. Zarzar General Manager — East Region CCP Operations and Maintenance Enclosures Cape Fear Steam Electric Plant 500 CP&l Road Moncure. NC 27559 d(� DUKE P' ENERGY. Mr. Danny Smith NC Division of Water Resources 3800 Barrett Drive Raleigh, NC 27609 Subject: Duke Energy Progress LLC, Cape Fear Steam Electric Plant 5 Day Follow-up Notification Chatham County gC'U003rf3oj Dear Mr. Smith, Cape Fear Steam Electric Plant 500 CPBL Road Moncure. NC 27559 NC Dept of Environmental Qualiry MAY 11 2017 Raleigh Regional Office As you are aware the central North Carolina Region experienced a large rain event early Friday morning May 5, 2017. The rain event at Cape Fear Steam Electric Plant (Cape Fear Plant) measured approximately 1.7 inches within 90 minutes Prior to the rain event Cape Fear Plant grading contractors had been working to remove the sediment basin associated with the plant demolition project CHATH-2013-015. The demolition area had been stabilized with ground cover and was in preparation for final grading. All that was left to complete final grading was to remove the detention basin and establish ground cover. The final grading contractor, as well as Duke Energy personnel were aware of the potential for rain in the forecast on Thursday evening/Friday morning. In preparation for the upcoming rain, the final grading contractor had placed 5-6 yards of rip rap, along with 2-3 yards of 57 stone in front of the silt fence outlet. The North Carolina Division of Water Resources (DWR) Construction General Permit, NCG 10000 requires an inspection of all erosion control BMP's after a rainfall event of over 0.5 inches. During the after rain event inspection, it was discovered that sediment laden water had overtopped the silt fence associated with the plant demolition project CHATH-2013-015. Approximately 1 cubic yard of sediment laden water overtopped the silt fence and discharged into the neighboring wetlands. As mentioned above, Cape Fear Plant had approximately 1.7 inches of rain within an hour and a half, which flooded the area resulting in sediment laden water overtopping the silt fence. After the inspection Duke Energy took immediate action. Additional 57 stone was used to dress the area in front of the silt fence. With the area inundated with water it is not accessible to equipment. Therefore with the situation mitigated ( no sediment was leaving the construction site) and no other rain expected over the weekend a plan was formulated to make repairs and remove as much sediment as possible from the wetlands area on Monday, May 8. On Monday May 8, Duke Energy took the following steps to further mitigate the off -site sedimentation issue experienced at the Cape Fear Plant on Friday May 5: • Cleaned out sediment in the neighboring wetlands with hand tools, Duke energy removed as much sediment by hand tools as possible. • Any sediment remaining in front of the silt fence was dug out and removed • Duke Energy installed an approximate 25' section of additional silt fence in the main area the discharge occurred • Installed 2 additional silt fence outlets with 57 stone • Installed an additional approximate 75' check dam utilizing 9 yards of riprap and 9 yards of 57 stone • Re -graded the entire disturbed area • Added thick layer of compost along entire surface area to aid in establishment of ground cover • Reseeded the area of the detention basin If you have any questions regarding this notification please contact Steve Cahoon at (919) 546- 7457 orsteve.cahoon@duke-energy.com. I certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility offines and imprisonment for knowing violations. Sincerely, Issa J. Zatzar General Manager CCP Regional Operations and Maintenance DUKE ENERGY. April 5. 2017 Cape Fear Steam Eleefm Nam Sit? CPS'_ Foao hfancure, NC 27559 NC Dept of Environmental Quality Mr. Jeffrey Poupart, Section Chief �� NC Division or Water Resources 1617 Mail Service Center Raleigh, NC 27699-1617 Raleigh Regional Offlee Subject: Cape Fear Steam Electric Plant Request for us of Chemicals in the Dewaiering Treatment Process Amendment to existing NPDES permit renewal application NC0003433 Chatham County Dear Mr. Poupart, As requested and approved previously at our HF Ue Energy Complex in May 2016, Duke Energy (Duke) submits this letter to amend our existing PDES application under which the plant currently operates. The amc ndment is to disclose the use of two chemical Products for use in the dewatering treatment system, one or the produc is is for pH adjustment, the other for the rem val of chlorine. An updated list or chemicals is attached. Please inclide this with the relevant permit talcs. Based on discussion, it is our understanding that with this modification to the existing permit application, no permit modification would be necessary and Duke is authorized to utilize these additives 10 assure compliance with NPDES permit limits and keep the dewalering system operational. If you have any questions regarding this letter, please contact Mr. Steve Cahoon at (919) 546.7457 or .stevc.cahharofdduke-enerev coin. J certify, underpenalry oflaw, that this document and all arrachnhents were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Bared on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowledge and belief, true, accurate, and complete. 1 am mvare that there are significant penalties for submitting false infornmtion, including the possibility offines and imprisonment for knowing violations. Sincerely, lssa J 2arcar General Manager— East Region CCP Operations & Maintenance Cc. Danny Smith - DWR Raleigh Regional office Steve Cahoon — NC 15 Jon Stamas — Cape Fear Shannon Langley —NCRH 15ih floor Duke Energy Progress, Inc. %DES Permil NC000M33 Cape Fear Steam Electric Plant 2011 Permit Application Amendment Attachment Form 2C - Item VI Potential Discharges Not Covered by Analysis Estimated Quantity Chemical er ear Frequency Purpose Wood fibers in proprietary binder mixture 350.750 Ib/acre per Every 4 months or Soil stabilizer and dust control BioCoverSS ( ) a lication as needed for ash pond Anionic Water Soluble Polymer in 825 gal Every 4 months or Soil stabilizer and dust control Emulsion (EcoGreen Barrier) for ash pond as needed Recycled paper (Country Boy Cellulose 700 bales Every 4 months or Soil stabilizer and dust control Fiber) as needed for ash pond Bentonife, hydrated aluminum silicate 12,500 IDS Every 4 months or Sail stabilizer and dust control (BEN -GEL) as needed for ash pond Ash Pond Water Wastewater Treatment System Chlorine Dioxide I < 500 As needed Biofouling control gallons Sulfuric Acid (96*4 < 500 As needed Membrane cleaning gallons ChemTreat P860E Polymer <1000 Continuous Polymer gallons Ferric Chloride 30,000 Continuous Wastewater treatment additive allons Sodium Hypochlorite 30,000 Continuous Wastewater treatment additive gallons Sodium Bisulfite 2,000 Continuous Wastewater treatment additive gallons ChemTreat RL9004 <1000 As needed Antiscalant gallons Sodium Hydroxide <10,000 Continuous Wastewater treatmentaddilive gallons Listed chemicals are no longer being utilized/or the purposes ldentified below. However, they were used during historic operations and trace amounts have the potential to be discharged during plant demolition. No Longer Aluminum sulfate None Used Water treatment flocculent No Longer Aluminum chtoroh drate None Used Water treatment coagulant GEBetz Spectrus OX103 (1-bromo-3-chloro-5,5- No Longer dimeth h ntoin) None Used Biofouling control No Longer Biofouling control In sewage Calcium hypochlonte None Used treatment Sanuril 115 (calcium hypochlorite and 1-bromo-3- No Longer Biofouling control in sewage chloro-5,5-dimeth Ih anloin) None Used treatment AB Culdne Plus (copper carbonate, triethanclamine, No Longer monoethanolamine) None Used Algae control in ash pOnd5 A4-1 Duke Energy Progress, Inc* NPOES Permit NC0003433 Cape Feer Steam Electric Plant 2011 Permit Application Amendment Estimated Quantity Chemical -_(per ear Frequency Purpose Cygent Plus (alkyl hydroxypoly oxyethylene, No Longer d'limonene) None Used Algae control in Ash Ponds No Longer VITEC 3000 (proprietary) None Used Antiscalant No Longer Oxygen scavenger, passivating Sleamate PAS3040 (proprietary) None Used agent GEBetz Steamate PAS3040 No Longer Oxygen scavenger, passivaling h r uinone None Used agent GEBetz Steamate NA0240 No Longer mo holine None Used pH control in condensate No Longer Sodium hydroxide None Used pH control No Longer Caustic soda anh rous None Used pH control GEBetz Optisperse HP9410 No Longer Solids dispersant In boiler, pH monosodium Phosphate) None Used control No Longer Solids dispersant in boiler, pH DisDdiurrI Phosphate None Used ontrol No Longer olids dispersant in boiler, pH Trisodiu phosphate None Used ontrol No Longer 'Solids dispersant in boiler, pH Sodium polypho5phale None Used control Dianodic DN2126 (phosphoric acid, potassium hydroxide, No Longer 1-H-benzoiriazole, methyl tot Itdazole) None Used Corrosion inhibitor No Longer NOx control during ozone Aqueous urea 50% None Used months No Longer Citric acid 50% None Used Boiler cleaning No Longer Sodium nitrite None Used Boiler cleaning No Longer Ammonium bicarbonate None Used Boiler cleaning No Longer Soda ash None Used Bailer cleaning, it needed No Longer Ammonium persuffate None Used Boiler clearing, if needed No Longer Ammonium bifluoride None Used Boiler cleaning, if needed No Longer Sodium bromate None Used Boiler cleaning, if needed No Longer Hydrochloric acid None Used Boiler cleaning, it needed No Longer Ethylenediaminetetraacelic acid EDTA None Used Boiler cleaning, if needed No Longer ChelClean 575 (proprietary) None Used Bailer cleaning. it needed Renewz No Longer sodium hydroxide. potassium silicate None Used Condenser coil cleaning TCA10 Plus No Langer sodium hydroxide) None Used Steam cleaning A4-2 Duke Energy Progress, Inc. %DES Permit NC0003433 Cape Fear Sham Electric Plant 2011 Permit Application Amendment Estimated Quantity Chemical er ear Fre uenc Purpose No Longer RoClean L403 (proprietary) None Used RO membrane cleaning No Longer RoClean P111 (proprietary) None Used RO membrane cleaning No Longer RoClean P303A ro rieta None Used RO membrane cleanin 20 Degree Baume Muriatic Acid No Longer (hydrochloric acid None Used RO membrane cleaning No Longer Morton softener salt None Used RO softener recleneration No Longer Cargill salt None Used EDI cleanin Cl 388 (Alum) No Longer aluminum chloroh rate None Used TSS control in ash pond No Longer Laund detergent (e.g.. Tide None Used Laundry cleaner No Longer Bleach None Used Laundry cleaner No onger Weed herbicide (e.g., Roundup)None led Weed killer treatment Ant pesticide No onger —e.g.. hydramethyinon inerls None tlsed Ant killer treatment No Longer Alkyll alcohol None Used Freeze conclitionino aclent No Longer Propylene glycol None Used Freeze conditioning agent No Longer Calcium chloride None Used Freeze conditioning agent No Longer Diethyfene glycol None Used Freeze conditioning agent No Longer Glycerin None Used Freeze conditioning agent A4.3 SollChem SOUTHERN OSINCORPORATED(SII) Ionks SAFETY DATA SHEET nI SDS NO.207 Effective Date: April 17, 2015 Revision Date: - 1. Product and Company Information Sil Product Name(s): Sodium Bisulfite Solution Synonym: SBS Chemical Name: Sodium Bisulfite Solution CAS Number: 7631-90-5 Manufacturer's Name: Emergency Contacts: Southern Ionics Incorporated Afterhours (Southern Ionics)1-888-610-2379 210 Commerce Street West Point, MS 39773 For Chemical Emergency, Spill or Accident Customer Service: 1-800-953-3585 Call CHEMTREC at 1-800-424-9300 Web Site www.southernion.cs.com CHEMTREC CCN - 20596 II. Hazard Identification OSHA HCS / GHS Classification(s): Hazard Statement(s): Acute Toxicity Oral, Category 4 Harmful if swallowed. Skin Irritation, Category 3 Causes mild skin irritation. Eye Irritation, Category 2A Causes serious eye irritation. Specific Target Organ Toxicity - Single Exposure, Category 3 May cause respiratory irriation. Corrosive to Metals, Category 1 May be corrosive to metals. Signal Word: Precautionary Statement(s): Warning Prevention: Wash affected body arts after handling. Symbol(s): Do not eat, drink or smoke when using this product Avoid breathing vapors. Wear eye face protection. Use in well ventilated areas. Keep in or final container. Response: IF SWALLOWED: Rinse mouth and call a doctor if you feel unwell. IF INHALED: Remove victim to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. If eye irritationpersists: Get medical attention. If skin irritation occurs: Get medical attention. Forspecific treatment: See First Aid section IV. III. Composition Information on Ingredients Chemical Name: CAS Reg #'s % Sodium Bisulfite(NaHS03) 7631-90-5 15-44 Sodium Sulfite (Na2SO3) 7757-83-7 <1 Sodium Sulfate (Na2SO4) 7757-82-6 <4 Water 7732-18-5 Balance �-7 . First Aid Measures Eyes: Immediately Flush eyes with running water for at least 15 minutes, keeping eyelids open. Remove any contact lenses. Seek medical attention, if you feel unwell. Dermal / Skin: Remove contaminated clothing and wash exposed area thoroughly with soap and water. Seek medical attention, if you feel unwell. Inhalation: Move to fresh air immediately. If breathing is difficult, give oxygen. Seek medical attention, if you feel unwell. Ingestion: If swallowed, DO NOT induce vomiting. Rinse mouth, Seek medical attention, if you feel unwell. V. Fire Fighting Measures NFPA Hazard Rating: Health Blue Fire Red Reactivity Yellow Special Instructions White 2 0 1 None NFPA Hazard Classification: 0 = Least 1=Sli ht 2= Moderate 3= High 4= Extreme Extinguishing Media: Use extinguishing media appropriate for surrounding fire. Special Firefighting Procedure: Wear NIOSH-approved self-contained breathing apparatus (SCBA). Use water spray to keep containers cool and to knock down fumes. CAUTION: when subject to excess heat, product releases additional sulfur dioxide gas. VI. Accidental Release Measures Precaution if Steps should be taken to contain spilled liquids and prevent discharges to streams 1 Neutralizing Chemicals: Neutralize with appropriate alkali such as sodium hydroxide, or soda ash to neutral pH. Avoid conditions where the pH of spilled material is maintained at lower than pH 6, since sulfur dioxide can be released at ambient temperatures below this pH. VII. Handling and Storage Handling: Handle all chemicals with respect. Keep separated from incompatible substances. Handle only with equipment, materials and supplies specified by their manufacturer as being compatible and appropriate for use with this product. Storage: Store at appropriate temperature to protect from freezing or crystallization. Consult the appropriate SII Product Bulletin for temperature recommendations. Do not store this material near food, animal feed or drinking water. Store in well ventilated area. Store away from excessive heat (e.g. steam pipes, radiators), and from reactive materials. Keep container tightly closed when not in use. VIII. Exposure Control Personal Protective Equipment Component Workplace Control Parameters: Components: CAS -No. Value I Parameters I Basis Sodium Bisulfite 7631-90-5 TWA IS mg/m3 I solid sodium bisulfite (metabisulfite) Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. General Hygiene: Practice good personal hygiene after using this material, especially before eating, drinkinp, smoking or using the toilet Personal Protection E ui ment: Eye: Use chemical splash goggles and face shield. Eye protection worn must be compatible with respiratory rotection system employed. Skin: Chemically resistant gloves should be worn whenever this material is handled. Gloves should be removed and replaced immediately if there is any indication of degradation or chemical breakthrough. SDS NO. 207 Effective Date: April 17, 2015 Revision Date: Page 2 of 4 do do Respiratory: one required under normal conditions. n conditions warrant a respirator, use NIOSH approved respirator and cartridge for particulates and Sulfur Dioxide. Other Protective Items: Where splash is possible, full chemically resistant protective clothing and boots are required. Ensure that eyewash stations and safety showers are proximal to the work -station location. HMISClassification: Health Blue Flammability Red Physical Hazard ellow PPE ite 1 2 0 1 1 See Above Hazard Classification: 0 = Minimal 1=Sli ht 2= Moderate 3= Serious 4= Severe IX. Physical and Chemical Properties Physical State: Liquid pH: 3.5 to 5.0 Appearance: Clear to yellow Molecular Weight: 104.1 for NaHSO; Odor: Pungent odor Odor Threshold: No Data Available Specific Gravity:(H2O=1) 1.13 to 1.38 @ 77°F/25°C Weight per gallon (lbs) 9.4 to 11.3 @ 770F/250C Vapor Density: (Air=1) Similar to water Vapor Pressure: 5 32 mm Hg total (12 mm Hg SOx) @ 77°F 25°C Boiling Point: 2177 /103°C Estimated Freezing/Melting Point: 15.8°F/ -90C Lower Explosive Limit Not Applicable Upper Explosive Limit Not Applicable Flash Point Not Applicable Autoignition Temp. Not Applicable Solubility in water: Dilutable Other: X. Stability and Reactivity Data Chemical Stability: Product is stable under normal or expected use. Conditions To Avoid: Avoid exposure to excessive heat. Incompatible Materials: Avoid contact with the following: acids and oxidizing agents. Hazardous Products of Decomposition: Thermal decomposition may yield the following: sulfur dioxide - toxic fumes. Xl. Toxicological Information Routes of Entry: ® Eyes ® Skin ® Ingestion ® Inhalation Sign and symptoms of Exposure: I May cause irritation toe es, skin and respitatory passages. Eye Contact: Causes serious eye irritation. Ingestion: May be harmful if swallowed. Skin Contact: Causes mild skin irritation. Inhalation: May be harmful if inhaled. May cause respiratory tract irritation. Carcinogenicity: NPT Not Listed IARC Not Listed OSHA Not Regulated Ingredient Name: Species Test Route Results Sodium Bisulfite Solution Rat 2000 mg/kg oral LD50 Comments: I Sulfite sensitive individuals may experience an allergic reaction. XII. Ecolo icaI Information Ingredient Name: Species Test Period Results Sodium Bisulfite Solution Mosquitofish 240ppm 96 hours LC50 Comments: XIII. Disposal Considerations. Waste Disposal: Always dispose of material in accordance with local, state, and federal regulations. SDS NO.207 Effective Date: April 17, 2015 Revision Date: Page 3 of 4 L", lil XIV. 1ransportation Information Proper Shipping Name: Bisulfites, aqueous solutions, n.o.s. (contains Sodium Bisulfite) DOT Classification: 8 Identification Number: UN2693 Packing Group: I III Other Labels: I Corrosive XV. Regulatory Information Inventory Status: US Regulations: U. S. TSCA Yes SARA 302 TPQ Not Listed Europe EINECS Yes SARA 304 RQ Not Listed Canadian DSL Yes SARA 313 List Not Listed Japan ENCS Yes CERCLA (RQ) 5,000 lbs on dry weight basis for sodium bisulfite. Korean KECI Yes RCRA 261.33 Not Listed Philippines PICCS Yes CAA-112-r Not Listed Australian AICS Yes SARA 311/312 ® Acute ❑ Chronic ❑ Fire ❑ Release of Pressure ❑ Reactive International Regulations: Other Regulations: Canada WHIMS D-28 Material causing other toxic effects California PROP 65 Not Listed Canada WHIMS E Corrosive FDA GRAS 21 CFR 182.3739 EINECS 231-548-0 XVI.Other Information NSF Certification: Sodium Bisulfite manufactured at Pasadena, TX, Williamsport, MD and Tuscaloosa, AL are NSF-60 Certified. Maximum use in potable water is 50 m 1. Other: Revision Notes: MSDS Replacements SII MSDS O48Sodium Bisulfite Solution (15%-28%) , SII MSDS 118 Sodium Bisulfite Solution, 30%, SII MSDS 024 Sodium Bisulfite Solution (38%44%) and SII MSDS 054 SI- SBS 40 For Product Information: TEL: 662-494-3055 FAX:662-494-2828 SALES OFFICE Post Office Drawer 1217 West Point, MS 39773 IMPORTANT To Place An Order: TEL: 800-953-3585 FAX:800-953-3588 Although the information contained is offered in good faith, SUCH INFORMATION IS EXPRESSLY GIVEN WITHOUT ANY WARRANTY (EXPRESS OR IMPLIED) OR ANY GUARANTEE OF ITS ACCURACY OR SUFFICIENCY and is taken at the user's sole risk User is solely responsible for determining the suitability of use in each particular situation. SII specifically DISCLAIMS ANY LIABILITY WHATSOEVER FOR THE USE OF SUCH INFORMATION, including without limitation any recommendation which user may construe and attempt to apply which may infringe or violate valid patents, licenses, and/or copyright. SDS NO.207 Effective Date: April 17, 2015 Revision Date: Page 4 of 4 Trade Name: Sulfuric Acid CAS Number: 7664-93-9 Synonym: Oil of Vitriol Distributor: Industrial Chemicals, Inc. Industrial Chemicals, Inc. 2540 Bellwood Road Richmond, VA 23237 804-275-9292 24 Hour Emergency Assistance: Chemtrec: 800-424-9300 CLASSIFICATION: LABELING: SIGNAL WORD: HAZARD PICTOGRAM: Skin Corrosion, Category IA See right: Danger Corrosive r Industrial Chemicals Inc. HAZARD STATEMENT: Causes severe skin burns and eye damage PRECAUTIONARY STATEMENTS: Do not breath dust/ fume/ gas/ mist/ vapors/ spray. Wash hands, face and skin thoroughly after handling. Wear protective gloves/ protective clothing/ eye protection/ face protection. => IF SWALLOWED: rinse mouth. DO NOT induce vomiting. =:, IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/shower. => Wash contaminated clothing before reuse. => IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. => Immediately call a POISON CENTER or doctor/physician. => Specific treatment (see on this label). => IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Dispose of contents/ container in full compliance with Federal, State, and local regulations. OTHER HAZARDS: Extremely corrosive. Harmful or fatal if swallowed. Harmful if inhaled. Severe eyes and skin irritation. Possibility of damage to the upper respiratory tract and lung tissues. ENVIRONMENTAL HAZARDS: Strong acid. Highly toxic to plants and aquatic organisms Page I Distributed by Industrial Chemicals. Inc. 2540 Bellwood Road. Richmond. VA 23237. 804275-9292 Ingredient Name CAS Number Concentration SULFURIC ACID 7664-93-9 6-100% SKIN: Immediately flush skin with plenty of water, for at least 15 minutes, while removing contaminated clothing and shoes. GET IMMEDIATE MEDICAL ATTENTION! Place contaminated clothing in closed container for storage until laundered or discarded. If clothing is to be laun- dered, inform person performing operation of contaminants hazardous properties. Discard contaminated leather goods. EYE: Flush immediately with large amounts of water for at least IS minutes. Eyelids should be held away from the eye- ball to ensure thorough rinsing. GET IMMEDIATE MEDICAL ATTENTION! INHALATION: Remove to fresh air. If not breathing, institute rescue breathing. If breathing is difficult, ensure airway is clear and give oxygen. Keep affected person warm and at rest. GET IMMEDIATE MEDICAL ATTENTION! INGESTION: If victim is conscious and alert, give 1-3 glasses of water to dilute stomach contents. Rinse mouth out with water. Do not induce vomiting unless directed by medical personnel. Never give anything by mouth to an unconscious person. If spontaneous vomiting occurs keep head below hips to prevent aspiration and monitor for breathing diffi- culty. Keep affected person warm and at rest. GET IMMEDIATE MEDICAL ATTENTION! FLASH POINT Not available FLAMMABLE LIMITS Not available AUTOIGNITION TEMP Not available HAZARDOUS COMBUSTION PRODUCTS: FIRE HAZARD Not flammable Decomposes to form sulfur dioxide and sulfur trioxide. EXPLOSION HAZARD Reacts with most metals (especially dilute concentrations): Hydrogen gas release (EXTREMELY FLAMMABLE, EXPLOSIVE). Risk of explosion if acid combined with water, organic materials or base solutions in enclosed spaces (Vacuum trucks, tanks). Mixing acids of different strengths can also pose an explosive risk in an enclosed space/container. EXINGUISHING MEDIA ERG (Emergency Response Guidebook): Guide 137 When material is not involved in fire, do not use water on material itself. Page 2 Distributed by Industrial EXTINGUISHING MEDIA: Small fire: Use carbon dioxide or dry chemical to extinguish fire. Large fire: Flood fire area with large quantities of water, while knocking down vapors with fog. If insufficient water supply, knock down vapors only Tank fire: Cool containers with flooding quantities of water until well after fire is out. Do not get water inside containers. Evacuate immediately if sound from safety vents or discoloration of tank. Stay clear of tanks engulfed in fire. PROTECTIVE EQUIPMENT: Evacuate personnel to a safe area. Keep personnel removed and upwind of fire. Generates heat upon addition of water, with possibility of spattering. Wear full protective clothing. Runoff from fire control may cause pollution. Neutralize run-off with sodium bicarbonate or soda ash to prevent corrosion of metals and formation of hydrogen gas. Wear self-contained breathing apparatus if fumes or mists are present. EMERGENCY PROCEDURES: Review Fire and Explosion Hazards [Section #51 . Take immediate steps to stop and contain release if possible. CLEAN-UP METHODS: Soak up small spills with dry sand or diatomaceous earth. Contain large spills and cautiously dilute and neutralize with lime or soda ash. Caution should be exercised regarding personnel safety and exposure to the released product. Notify local authorities and the National Response Center, if required. If the product is spilled and not recovered, or is recovered as a waste for treatment or disposal, the Reportable Quantity (US DOT) is 1,000 Ibs (based on the sulfuric acid content of the solution spilled). PROTECTIVE EQUIPMENT: See "Exposure Controls/Personal Protection" [Section #8]. HANDLING: DO NOT get in eyes, on skin, or on clothing. Avoid breathing vapors or mist. Wear approved respirators if adequate ventilation can not be provided. Wash thoroughly after handling. Do not eat, drink or smoke in areas of use or storage. NEVER add water to acid. STORAGE: Avoid contact with combustible materials, water, metals and alkalis. Store in a vented container. This material should be stored and shipped in containers specially designed for sulfuric acid. DO NOT add water or other products to contents in containers as violent reactions with resulting high heat, pressure, and/or generation of hazardous acid mists. Page 3 Distributed by Industrial Chemicals, Inc. 2540 Bellwood Road. Richmond. VA 23237. 804-275-9292 ENGINEERING CONTROLS: Ventilation and other forms of engineering controls are the preferred means for controlling exposures. PERSONAL PROTECTION: Chemical splash goggles; Full-length face shield/chemical splash goggles combination; Acid -proof gauntlet gloves, and boots; Appropriate NIOSH approved respiratory protection if acid mist is present. An apron can be used in place of acid proof suit if the employer's risk assessment deems it is safe for the type of handling taking place (i.e. laboratories and small quantities). For emergencies where possibility of exposure is high, wear complete acid suit with hood, boots, and gloves. NIOSH approved respiratory protection should be worn if acid mist is present or exposure limits are exceeded. EXPOSURE LIMITS / HEALTH HAZARDS: I mg/m3 8-Hour PEL-TWA (OSHA) 0.2 mg/m3 8-Hour TLV-TWA (ACGIH) (thoracic fr.) I mg/m3 NIOSH REL-TWA (510 hours) 15 mg/m3 IDLH APPEARANCE: ODOR: ODOR THRESHOLD: VAPOR PRESSURE: VAPOR DENSITY: RELATIVE DENSITY: PH: FREEZING POINT: BOILING POINT: SOLUBILITY: PARTITION COEEFICIENT: EVAPORATION RATE: FLAMMABILITY: UEL/LEL: AUTO-IGNTION TEMP: DECOMPOSITION TEMP: VISCOSITY: MOLECULAR FORMULA MOLECULAR WEIGHT CHEMICAL FAMILY Colorless to cloudy, oily looking liquid Odorless N/A <0.3 mmHg @ 75T (77'C), <0.6 mmHg @ 100T (38`C) 3.4 1.84 >93% <1.0 30°F- -40°F (6-85%), 46-F (85%), -20°F (93%), 5.5°F (96%), 40T (99%) 215° - 440°F (6-85%), 541 °F (93%), 621 °F (98%), 625°F (99%) @ 760 mmHg 100% in Water N/A N/A N/A N/A N/A 340'C Negligible H2SO4 98.08 MINERAL ACID Page 4 Distributed by Industrial Chemicals, Inc. 2540 Bellwood Road, Richmond, VA STABILITY: Stable under normal, ambient conditions REACTIVITY: Reacts violently with water, organic substances and base solutions with evolution of heat and hazardous mists. DECOMPOSITION: Possibility of hazardous decomposition if heated and in contact with sources of ignition. Release of toxic gases and vapors (Sulfur oxides (SOZ, SO,)), POLYMERIZATION: Will not occur MATERIALS TO AVOID: Water; alkaline solutions; metals, metal powder; carbides; chlorates; fulminates; nitrates; picrates; strong oxidizing, reducing or combustible organic materials. Hazardous gases are evolved on contact with chemicals such as cyanides, sulfides, and carbides. ROUTES OF ENTRY: Ingestion. Inhalation. Skin and eye contact. CARCINOGENICITY: [ARC has determined that there is sufficient evidence for the carcinogenicity of occupational exposure to strong inorganic acid mists containing sulfuric acid in humans (IARC Class 1) ACUTE TOXICITY: ORAL acute (LD50): 2140 mg/kg (Rat). TOXILOGICAL Acute or chronic overexposure to this material or its components may cause INFORMATION: systemic toxicity, including adverse effects to the following: kidney, liver, teeth, respiratory and cardiovascular systems. Exposure to components of this material may cause the following specific symptoms, depending on the concentration and duration of exposure: attacks enamel of teeth, vomiting, clammy skin, weak and rapid pulse. Other symptoms of exposure may include the following: shallow respiration, chronic bronchitis, lung function changes and scanty urine. PRE-EXISTING CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing medical conditions which may be aggravated by exposure include disorders of the skin and respiratory system. ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION. ENVIRONMENTAL MOBILITY (SOIL & AIR): When released into the soil, this material may leach into groundwater. When released into the air, this material may be removed from the atmosphere to a moderate extent by dry deposition. ECOTOXICITY: Aquatic toxicity range Slightly to moderately toxic Bluegill sunfish, 48 Hour; LC50, 49 mg/L (Tap water, 20°C) Flounder, 48 Hour; LC50, 100-330mg/L (Aerated water, conditions of bioassay not specified) Shrimp, 48 Hour; LC50, 80-90mg/L (Aerated water, conditions of bioassay not specified) Page 5 Inc. 2540 Bellwood Road, Richmond, VA 23237. 804-275-9292 WASTE DISPOSAL: This product as supplied, when discarded or disposed of, is a hazardous waste according to Federal regulations (40 CFR 261) due to its corrosiveness and reactivity. Under the Resource Conservation and Recovery Act (RCRA), it is the responsibility of the user of the product to determine, at the time of disposal, whether the material is a haz- ardous waste subject to RCRA. The transportation, storage, treatment and disposal of RCRA waste material must be conducted in compliance with 40 CFR 262. 263, 264, 268, 270. Disposal can occur only in properly permitted facilities. Check state and local regulations for any additional requirements as these may be more restrictive than federal laws and regulations. Chemical additions, processing or otherwise altering this material may make the waste management information presented in this MSDS incomplete, inaccurate or otherwise inappropriate. Disposal of this material must be con- ducted in compliance with all federal, state and local regulations. BILL OF LADING - BULK (U. S. DOT): RQ, Sulfuric Acid, 8, UN 1830, PG II (use with more than 51% acid) RQ, Sulfuric Acid, 8, UN 2796, PG II (use with not more than 51 % acid) BILL OF LADING - NON -BULK (U. S. DOT) RQ, Sulfuric Acid, 8, UN 1830, PG II (use with more than 51 % acid) RQ, Sulfuric Acid, 8, UN 2796, PG II (use with more than 51 % acid) U. S. DEPARTMENT OF TRANSPORTATION (DOT) REQUIREMENTS: General Transportation Information for Bulk Shipments Proper Shipping Name Sulfuric Acid Hazard Class 8 ERG Guide 137 UN/NA Code Packaging Group Labels Required Placards Required Reportable Quantity General Transportation Proper Shipping Name Hazard Class UN/NA Code Packaging Group Labels Required Reportable Quantity UN 1830, UN 2796 PG II Corrosive Corrosive, UN 1830 (>5I%), UN 2796 (551%) See Regulatory Information [Section #15] Information for Non -Bulk Shipments Sulfuric Acid 8 ERG Guide 137 UN 1830, UN 2796 PG II Corrosive See Regulatory Information [Section #IS] (The above description may not cover shipping in all cases. Please consult 49 CFR 172.101 for specific shipping information) Page 6 Distributed by Industrial Chemicals, Inc. 2540 Bellwood Road, Richmond, VA FEDERAL REGULATIONS: TSCA Inventory: Listed CERCLA Section 103 Hazardous Substances SARA Section 302 Extremely Hazardous Substance: Yes SARA Title III, Toxic Chemicals: Immediate: X Delayed: X Fire: Pressure: Reactivity: X Reportable Quantity (Sulfuric Acid): 1,000 pounds. This product contains one or more components designated as hazardous substances or toxic pollutants under Section 112 of the Clean Air Act. HCS CLASSIFICATION: Corrosive Liquid STATE REGULATIONS: Based on available information this product contains components or chemicals currently known to the state of California to cause cancer. Reformulation, use or processing of this product may affect its composition and require re-evaluation. NFPA RATINGS Health 3 Flammability 0 Reactivity 2 Special Hazards W HMIS RATINGS Health 3 Flammability 0 Reactivity 2 Following ingredients of this product are listed in SARA 313 SARA Listed Ingredient Name CAS Number Maximum% SULFURIC ACID 7664-93-9 100.0 DISCLAIMER: NOTICE: The information presented herein is based on data considered to be accurate as of the date of preparation of this Material Safety Data Sheet. However, MSDS may not be used as a commercial specification sheet of manufacturer or seller, and no warranty or representa- tion, expressed or implied, is made as to the accuracy or comprehensiveness of the foregoing data and safety information, nor is any authori- zation given or implied to practice any patented invention without a license. In addition, no responsibility can be assumed by vendor for any damage or injury resulting from abnormal use, from any failure to adhere to recommended practices, or from any hazards inherent in the nature of the product Distributed by Industrial Chemicals, Inc. 2540 Bellwood Road, Richmond, VA 23237. 804-275-9292 Last Updated 02/28/13 Page 7 Manuel, Vanessa From: Smith, Danny Sent: Friday, May 05, 2017 5:10 PM To: Manuel, Vanessa Subject: FW: Duke energy's Cape Fear Plant - Off Site Sedimentation Categories: Compli./Enf. g coO 03433 f fYi J Danny Smith, Supervisor Raleigh Regional Office Water Quality Regional Operations Division of Water Resources (919)791-4252 From: Cahoon, Steve [mailto:Steve.Cahoon@duke-energy.com) Sent: Friday, May 05, 2017 11:03 AM To: Smith, Danny <danny.smith@ncdenr.gov> Subject: Duke energy's Cape Fear Plant - Off Site Sedimentation Danny, I left you a voicemail this morning concerning a minor offsite sediment event due to the rain received at the site early this morning. During routine inspection after rainfall, it was discovered that sediment laden water had overtopped the silt fence in the area of the formal coal pile. This area has been stabilized with grass and the grading contractor had been working to take the pond out of service for final E&SC plan closure. The pond area had been prepped and re- seeded. In preparation for the upcoming rain, the final grading contractor had placed 5-6 yards of rip rap, along with 2-3 yards of 57 stone in front of the silt fence outlet. We had approximately 1.7" of rain, within an hour and a half, which backed up the wetlands water over the silt fence resulting in a discharge. Approximately 1 cubic yard of sediment discharged into the neighboring wetlands. Actions taken this morning were to add additional 57 stone to dress the area in front of the silt fence. With the area inundated with water it is not accessible to equipment. As we are no longer discharging sediment, and with no rain forecasted for the weekend we will be making final repairs first thing Monday morning. We will make an attempt to remove the sediment with hand tools in the wetland area once the area is accessible and we can remove the sediment. If it is more damaging to the resource to remove the sediment, we will leave it in place and stabilize it with a wetlands seeding mix. Please let me know if you have any further questions. Steve Steve Cahoon Duke Energy EHS —CCP Permitting and Compliance Office - (919) 546-7457 Cell - (919) 632-0129 steve.ca hoon @d u ke-e nerw.com • Manuel, Vanessa From: Stamas, Jonathan <Jonathan.Stamas@duke-energy.com> Sent: Thursday, April 06, 2017 3:02 PM To: Manuel, Vanessa Cc: Cahoon, Steve Subject: FW: Cape Fear Plant Inspection - Amended Jan. 2017 eDMR Categories: Inspections Vanessa, To answer your questions: The amended January 2017 eDMR was submitted electronically on 3/31/17. 1 have separate pH and temperature meters. The pH meter is a Fisher Scientific Accumet AB15. As far as the lab certification numbers, I didn't realize it was an option to include multiple. I had listed the Huntersville lab as they are the ones analyzing the non -field parameters. Their certification number is 248. Both myself and the Pace team collect the field parameters. The Cape Fear certification number is 5101 and Pace's is 67. Going forward we'll be sure to include all three on the eDMRs. Please let us know if you have any additional questions or concerns. Thanks, Jonathan Stamas Cape Fear Environmental Support Office: 919-516-1986 Mobile: 781-726-2826 Duke Energy Jonathan.Stamas@duke-energy.com From: Manuel, Vanessa rmailto:vanessa.manuelCalncdenr.gov] Sent: Wednesday, April 05, 2017 1:09 PM To: Stamas, Jonathan Subject: Cape Fear Plant Inspection - Amended Jan. 2017 eDMR *** Exercise caution. This is an EXTERNAL email. DO NOT open attachments or click links from unknown senders or unexpected email. *** Hi Jonathan — 1 I am in the process of writing up the inspection report for our site visit on March 24`^, and want to include the date you amended the Jan. 2017 eDMR to correct the mercury data. I recall your phone call about the amended eDMR, but I didn't record the date of that call. Please let me know when the eDMR was amended. Also, do you use your pH meter to measure temperature, or do you have a separate meter? I recorded the temperature meter as a Fisher Scientific digital meter. Please confirm if you have a separate meters, and if so, what is the model for the pH meter? Also, per our certified lab's website, the certification number for the field parameters for the Cape Fear Plant is 5101. 1 noticed on the January 2017 monitoring report the certified lab number is listed as 248, which is the certification number for Duke Power Company lab in Huntersville, North Carolina. The Huntersville lab is certified as a commercial lab for both field and non -field parameters. During the inspection you indicated that you analyze pH and temperature 4 days per week and Pace Analytical collects samples (field and non -field parameters) on Tuesdays and provides analyzes for these collected samples. Pace's certification number is not indicated on the January 2017 eDMR. Please confirm which commercial lab analyzes the field and non -field parameters and verify the certification numbers. As I prepare this report, I may contact you again if additional questions arise. Thanks. Vanessa E. Manuel Environmental Program Consultant Division of Water Resources — Raleigh Regional Office Department of Environmental Quality 919 791-4255 office vanessa. manuel C@ncdenr.gov Physical: 3800 Barrett Drive, Raleigh, NC 27609 Mailing: 1628 Mail Service Center, Raleigh, NC 27699-1628 c:- -55 'Nothing Compares.—..._ Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. MONITORING REPORT(MR) VIOLATIONS for: Report Date. 04/05/17 Page. 1 of 1 Permit: nc0003433 MRS Between 2 - 2015 and 1 - 2017 Region: Raleigh Violation Category:% - Program Category: NPDES VVW Facility Name: % Param Name % County: % Subbasin: % Violation Action: % Major Minor: % PERMIT: NC0003433 FACILITY: Duke Energy Progress LLC -Cape Fear Steam Electric COUNTY: Chatham REGION: Raleigh Power Plant Limit Violation MONITORING OUTFAW VIOLATION UNIT OF CALCULATED % REPORT PPI LOCATION PARAMETER DATE FREOUENCY MEASURE LIMIT VALUE Over VIOLATION TYPE VIOLATION ACTION 01 _2016 005 Effluent Solids, Total Suspended- 01/28/16 Semi-annually mgA 100 158 58 Daily Maximum Proceed to NOV Concentration Exceeded 01.2016 005 Effluent Solids, Total Suspended - 01/31/16 SemFannually m96 30 158 426.7 Monthly Average Proceed to NOV Concentration Exceeded Monitonno Violation MONRORING OUTFAW VIOLATION UNIT OF CALCULATED % REPORT PPI LOCATION PARAMETER DATE FREQUENCY MEASURE LIMIT VALUE DIM VIOLATION TYPE VIOLATION ACTION 01 -2016 007 Effluent Flaw, in conduct or thru 01/02J16 5 X wreak mgd Frequency Violation No Action, BPJ treatment plant 01_2016 007 Effluent pH 01/02J16 5Xaeek su Frequency Violation No Action, BPJ 01 _2018 007 Effluent Temperature, Water Deg. 01/02/16 5 X week deg c Frequency Violation No Action, BPJ Centigrade Permit Enforcement History Owner/Facility Name: Duke Energy Progress LLC / Cape Fear Steam Electric Pow NPDES Permit: NOV-2015-PC-0019 NOV-2016-DV-0094 NOV-2016-LV-0646 Total Cases: 3 1/28/2015 A S A 3/4/2016 — I,�r4-.4-�,.> t,C 71 sc far ors c�( IJIJ ,�r y� cs.i.en, M.�•,.,••d coca ( Is. 12/8/2016 -4--- (7ss County: Chatham Whole Effluent Toxicity Testing and Self Monitoring Summary CP&L-Asheville Ash Pond/ 001 NC0000396/001 County: Buncombe Cer7dChV Begin: 1/1/2006 chr lim: 1.9% NonComp: Single J F M A M 2012 >7.6 - - >7.6 - 2013 >7.6 - - >7.6 - 2014 >7.6 - - >7.6 2015 >7.6 - - >7.6 2016 >7.6 - - Pass CP&[.Cape Fear S.E./007 NCOD03433/007 County: Chatham Cerl7dPF Begin: 9/1/2011 chr lim: 9096 NonComp: Single J F M A M 2012 - Pass - - Pa 201.3 - Pass - - pa 2014 - Pass - - Pa 2015 H - 2016 H H - I Region: ARO Basin: FRB02 Jan Apr Jul Oct 7Q10: 375.0 PF: NA IWC: NA Freq: Q J J A S O - >7.6 - - >7.6 - >7.6 - - >7.6 - >7.6 - - >7.6 - Pass - - >7.6 >7.6 - Region: RRO Basin: CPF07 Feb May Aug Nov 7Q10: 0.0 PF: NA IWC: 100 Freq: Q J J A S O Pass - Pass H H H SQC_JOC: N SOC IOC: N Pass Pass H H CP&L-Mayo Steam Electric Plant NC0038377/002 County: Person Region: RRO Basin: ROA05 Feb May Aug Nov SOCIOC: Fthd24PF Begin: VV2008 24hr fathead p/f ac II NonComp: Single 7Q10: Lake PF: NA IWC: NA Freq: Q J F M A M J l A S O N 2012 - Pass - - Pass - - Pass - - Pass 2013 - Pass - - Pass - - Pass - - Pass 2014 - Pass - - Pass - - Pass - - Pass 2025 - Pass - - Pass Pass - Pass - - Pass 2016 - Pass - - Pass - - Pass - - - CP&L-Sutton/001 Progress Energy NC0001422/001 County: New Hanover Region: WIRO Basin: CPF17 Feb May Aug Nov SOC_JOC: Fthd24PF Begin: 12/7/2015 ACP/F Lim: 90%Fthd NonComp: 7Q10: Tidal PF: NA IWC: NA Freq: M J F M A M J J A S O N 2012 - Pass - - Pass - - Pass - - Pass 2013 - Pass - - Pass - - Pass - - Pass 2014 - H - - H _ _ H - H 2015 - H - - H - - H - - Pass 2016 Pass Pass Pass Pass Pass Pass Pass Pass - - - CP&L-Weathempmn/001 NC0005363/001 County: Robeson Region: FRO Basin: WM51 SOC JOC: Fthd24Ac Begin: 11/1/2004 24 hr LC50 ac monit NonComp: 7Q70: 122 PF: NA IWC: NA Freq: 50WD/A J F M A M J J A S O N 2012 - _ _ _ _ H - - - - - 2013 _ _ _ _ _ H - - - - 2014 - - - - - H - - - - 2015 _ _ _ _ _ H - - - - - 2016 - - - - - H - - - C F] Pass Pass 0 Leeend: P= Fathead minnow (Pimohales oromelas). H=No Flow (facilitv Is active). s = Solit test between Certified Labs Page 31 of 125 North Carolina Department of Environmental Quality Division of Water Resources Permit Number: NC0003433 Permit Type: Industrial Process & Commercial Wastewater Dlscharae Facility Name: Cam Fear Steam Electric Power Plant Facility Addressl: 500 CP L Rd Facility Address2: City, State & Zip: Moncure. NC 27559 Owner Information Details: MUST submit a Change Of Name/Ownership form to DWR to make any changes to this Owner information. See "Miscellaneous Forms" athttp://i)ortal.ncdenr.org/weblwa/swp/ps/nodes/forms Owner Name: Duke Enerav Process LLC Owner Type: Non-Govemmen[ Owner Type Group: Organization *** Legally Responsible for Permit *** (Responsible corporate officer/principle executive officer or ranking elected official/general partner or proprietor; or any other person with delegated signatory authorityfrom the legally responsible person.) Owner Affiliation: Tanya Hamilton Title: Addressl: 5413 Shearon Hams Rd Address2: City, State & Zip: New Hill. NC 27562 Work Phone: 919-362-2000 Fax: Email Address: tanva.hamilton(aiiduke-enemv.mm 3/16/2017 Permit Number: NC0003433 Permit Type: Industrial Process & Commercial Wastewater Discharci Facility Name: Cape Fear Steam Electric Power Plant Facility Addressl: 500 CP L Rd Facility Addressl: City, State & Zip: Moncure. NC 27559 Owner Contact Person(s) Contact Name Tide Adores; Tom Copolo Manager Plant 10660 Boston Rd, Roxboro, NC 27574 Phone fax 336-597-7307 Email tom.copolo@duke-energy. Rick Grant Manager Plant 1199 Black Jack Church Rd, Goldsboro, NC 27530 Jody Thacker 1700 Duannaway Rd Semora, Semore, 336-597-6101 )ody.thacker@duke-energy NC 27343 .corn Garry Whisnant Manager Plant 200 CPL Dr, Arden, NC 28704 828-687-5201 William J Thacker Manager Plant 200 Talley Loop Rd, Roxboro, NC 336-597-7331 27574 Kenneth Brooks 400 S Tryon St, Charlotte, NC 28201 704-868.6302 Richard Brown General Manager 410 S Wilmington St, Raleigh, NC 919-546-3122 919-546-7552 dchard.brown@pgnmail.co 27602 in Rodney Gaddy 410 S Wilmington St, Raleigh, NC 704-382-5591 980-373-5337 27602 Issa Zarzar 411 Fayetteville St, Raleigh, NC 27601 Issa.zarzar@duke-energy.co Rodney Dlr Transmission of 411 Fayetteville St, Raleigh, NC 27601 919-546-2235 919-546-7175 Hutcherson Jason Haynes 491 Energy Way, Hamlet, INC 28345 910-205-2101 )awn.haynes@duke-energ y.com Rick Grant 491 Power Plant Rd, Lumberton, NC 28358 Randy Cox 500 CP L Rd, Moncure, INC 27559 919-774-5200 Caren B Anders President vice 526 S Church St, Ec3xp, Charlotte, NC 919-546-7661 919-546-7175 Ernest J General Manager 5413 Shearon Hams Rd, New Hill, NC 919-362-2000 919-362-2483 emle.kapopoulos@pgnmall. Kapopouios Plant 27562 men Kelvin General Manager 5413 Shearon Hams Rd, New Hill, NC 919-362-2000 keNln.henderson@pgnmall. Henderson Plant 27562 coin Richard Baker Director Mall Code Ec 13k, PO Box 1006, Chadotte, NC 28201-1006 Buzz Bryson Owner PO Box 14042, Saint Petersburg, FL 919-546-6637 buz .bryson@pgnmail.com John R Toepfer PE PO Box 1551, Peb 4, Raleigh, NC 919-546-7863 919-546-6302 John.toepfer@pgnmall.com John F Smith PO Box 1981 - Tpp18, Raleigh, NC 919-546-7661 919-546-7175 27602-1981 Bob Phts PO Box 1981 - Tpp18, Raleigh, NC Reubin Jones E P 919-546-3459 Facility Contact Person(s) Contact Name L1itle Addles; Permit Contact Person(s) Phone En Email Contact Name Title Address Phone EU Email -� Hersnell McCarty 500 CP L Rd, Moncure, INC 27559 C4&,,V �0 4-z2,,7CIL Page 2 Permit Number: N00003433 Permit Type: Industrial Process & Commercial Wastewater Discharae Facility Name: Cane Fear Steam Electric Power Plan[ Facility Addressl: 500 CP L Rd Facility Address2: City, State & Zip: Moncure. INC 27559 Permit Billing Contact Persons) Contact Name Title AQdireq Phone fax Emdj1 Rznay Cox 500 CP L Rd, Moncure, NC 27559 919-774-5200 Persons with Signatory Authority Tvoe Contact Name Title Address Phone fAE Email Owner George T Everett & / Advisor Affairs D Peb 13 PO Box 1551, Raleigh, 919-546-6744 919-546-4511 Energy NC 27602 Environmental Ph Senior Permit Shannon Todd 200 Cp L Dr, Arden, NC 28704 7D4-382-4743 Shannon.Todd@duke-ene ray.com Permit Danny Wimberly 411 Fayetteville St, Raleigh, NC 919-516-1980 danny.wimbedy@duke-en 27601 er0y.com y Permit Issa Zarzar v 411 Fayetteville St, Raleigh, NC Issa.zarzar@duke-energy.c Designated Operators If the designated operators listed below are incorrect or no longer associated with the collection system, the information can be updated by submitting a completed "Operator Designation Form" (C/' k Here for ORC Designation Fyim1 Fleaseprowde specific details as to the changes requested, including the addition/removal of designatedoperators. For all other operator questions or issues, please call 919-807-6353. Facility Classification: PCl Operator Nam InR912 Cent Type Cert Status Cert# Effective Date Jonathan Christian Stamas qlq 51(Q- IWORC PC-1 Active 1003108 12/1/2016 William Michael Graham Backup PC-1 Active 1003536 12/1/2016 Dull F. Phillips Backup PC-1 Active 27889 12/1/2016 3/16/2017 Page 3 DUKE ENERGY ti 10 March 2017 Mr. Ron Berry North Carolina Division of Water Resources 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: Notification of Newly Discovered Pipe at Cape Fear Steam Station Dear Dr. Chemikov, EHS CCP Environmental Programs gC//voc/)3N33 Duke Energy 526 South Church Street Charlotte, NC 28202 Mailing Address: EC13K / P.O. Box 1006 Charlotte, NC 28201-1006 As you are aware during the daily inspection at the Cape Fear Plant last month, one new outlet pipe was identified that flows in to the old cooling tower basin. The coordinates for the pipe are 350 35'25.62" N and 790 02'46.96" W. The pipe has a very low flow and was difficult to sample, however a sample of the discharge from the pipe was obtained. We have continued to monitor the flow from the pipe, we believe the origin of the water is from an old French drain system in the vicinity of the cooling tower. The water in the pipe has been re-routed and combined with Seep S-5 into one discharge point into the discharge canal (effluent channel) so it will be monitored at Outfall 007. Attached are the sampling results. Should you have any questions regarding this submittal or require additional information, please contact me at 919 546-7457 or at steve.cahoon@duke-energy.com. Sincerply, G Steve Cahoon Duke Energy EHS CCP Permitting and Compliance cc: Danny Smith, Raleigh Regional Office, NCDEQ Jeff Poupart, Complex Permitting Unit Sergei Chemikov, Complex Permitting Unit llfft� DUKE Analytical Laboratory %'ENERGY. 13339 Hagers Ferry Road Huntersville, NC 28078-7929 McGuire Nuclear Complex - MG03A2 Phone:980-875-5245 Fax:980-875-4349 Order Summary Report Order Number: J17020407 Project Name: CAPE FEAR - NPDES - AOW Customer Name(s): Ross Hartfield, Tim Hunsucker, Chris Suttell, Kathy Webb, Brandon Russo Customer Address: CP&L ROAD MONCURE, NORTH CAROLINA 27559, Lab Contact: Peggy Kendall Phone: 980-875-5848 Report Authorized By: P� +" 4 % Dr Date: 2/23/2017 (Signature) 'V a#il:�l Pe; .ndall — _---- - Program Comments: Please contact the Program Manager (Peggy Kendall) with any questions regarding this report. Data Flags & Calculations: Pagel of 33 Any analytical tests or individual analytes within a test flagged with a Qualifier indicate a deviation from the method quality system or quality control requirement. The qualifier description is found at the end of the Certificate of Analysis (sample results) under the qualifiers heading. All results are reported on a dry weight basis unless otherwise noted. Subcontracted data included on the Duke Certificate of Analysis is to be used as information only. Certified vendor results can be found in the subcontracted lab final report. Duke Energy Analytical Laboratory subcontracts analyses to other vendor laboratories that have been qualified by Duke Energy to perform these analyses except where noted. Data Package: This data package includes analytical results that are applicable only to the samples described in this narrative. An estimation of the uncertainty of measurement for the results in the report is available upon request. This report shall not be reproduced, except in full, without the written consent of the Analytical Laboratory. Please contact the Analytical laboratory with any questions. The order of individual sections within this report is as follows: Job Summary Report Sample Identification, Technical Validation of Data Package, Analytical Laboratory Certificate of Analysis, Analytical Laboratory CC Reports, Sub -contracted Laboratory Results, Customer Specific Data Sheets, Reports & Documentation, Customer Database Entries, Test Case Narratives, Chain of Custody (COC) Certification: The Analytical Laboratory holds the following State Certifications : North Carolina (DENR) Certificate #248, South Carolina (DHEC) Laboratory ID # 99005. Contact the Analytical Laboratory for definitive information about the certification status of specific methods. Sample ID's & Descriptions: Page 2 of 33 Sample ID Collection Plant/Station Date and Time Collected By Sample Description 2017005283 Cape Fear 14-Feb-17 12:00 PM William Z/Pace New Pipe 2017005284 Cape Fear 14-Feb-17 William Z/Pace FIELD BLANK 2 Total Samples Page 3 of 33 Technical Validation Review Checklist: COC and .pdf report are in agreement with sample totals © Yes ❑ No and analyses (compliance programs and procedures). All Results are less than the laboratory reporting limits. ❑ Yes Ei No All laboratory QA/QC requirements are acceptable. © Yes ❑ No Report Sections Included: N' Job Summary Report Sample Identification Technical Validation of Data Package Analytical Laboratory Certificate of Analysis ❑ Analytical Laboratory QC Report Subcontracted Laboratory Results ❑i Customer Specific Data Sheets, Reports, & Documentation ❑ Customer Database Entries Chain of Custody �J Electronic Data Deliverable (EDD) Sent Separatel Reviewed By: Peggy Kendall Date: 2/23/2017 �zrtificate of Laboratory Anal, -.a This report shall not be reproduced, except in full. Order# J17020407 Site: New Pipe Collection Date: 14-Feb-17 12:00 PM Analyse Result Units Qualifiers RDL DF ALKALINITY - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete SarnDle #: 2017005283 Matrix: NPDES Page 4 of 33 Method Analysis Date/Time Analyst Vendor Method V_PACE Nitrite + Nitrate (Colorimetric) 0.07 mg-N/L 0.01 1 EPA 353.2 02/21/2017 13:34 LSTARLI INORGANIC IONS BY IC Chloride 14 mg/L 1 10 EPA 300.0 02/16/2017 14:12 JAHERMA Fluoride 0.10 mg/L 0.1 1 EPA 300.0 02/161201714:12 JAHERMA Sulfate 130 mg/L 10 100 EPA 300.0 02/16/2017 14:12 JAHERMA MERCURY IN WATER - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE TOTAL RECOVERABLE METALS BY ICP Aluminum (AI) 1.62 mg/L M1 0.005 1 EPA 200.7 02/17/2017 12:51 MHALL3 Barium (Ba) 0.168 mg/L 0.005 1 EPA 200.7 02/17/2017 12:51 MHALL3 Boron (B) < 0.05 mg/L 0.05 1 EPA 200.7 02/17/2017 12:51 MHALL3 Calcium (Ca) 50.2 mg/L 0.01 1 EPA 200.7 02/17/2017 12:51 MHALL3 Iron (Fe) 3.02 mg/L 0.01 1 EPA 200.7 02/17/2017 12:51 MHALL3 Magnesium (Mg) 9.69 mg/L 0.005 1 EPA 200.7 02/17/2017 12:51 MHALL3 Manganese (Mn) 0.560 mg/L 0.005 1 EPA 200.7 02/17/2017 12:51 MHALL3 Potassium (K) 3.80 mg/L 0.1 1 EPA 200.7 02/17/2017 12:51 MHALL3 Sodium (Na) 18.1 mg/L 0.05 1 EPA 200.7 02/17/2017 12:51 MHALL3 Total Hardness (Ca and Mg) 165 mg/L 0.19 1 EPA 200.7 02/17/2017 12:51 MHALL3 (CaCO3) Zinc (Zn) 0.083 mg/L 0.005 1 EPA 200.7 02/17/2017 12:51 MHALL3 TOTAL RECOVERABLE METALS BY ICP-MS Antimony (Sb) < 1 ug/L 1 1 EPA 200.8 02/16/2017 23:59 CWSPEN3 Arsenic (As) <1 ug/L 1 1 EPA 200.8 02/16/201723:59 CWSPEN3 Cadmium(Cd) <1 ug/L 1 1 EPA 200.8 02/16/2017 23:59 CWSPEN3 Chromium(Cr) 1.96 ug/L 1 1 EPA 200.8 02/16/2017 23:59 CWSPEN3 Copper (Cu) 2.06 ug/L 1 1 EPA 200.8 02/16/201723:59 CWSPEN3 Lead (Pb) 1.70 ug/L 1 1 EPA 200.8 02/16/2017 23:59 CWSPEN3 Molybdenum (Mo) < 1 ug/L 1 1 EPA 200.8 02/16/2017 23:59 CWSPEN3 Nickel (Ni) 7.70 ug/L 1 1 EPA 200.8 02/161201723:59 CWSPEN3 Selenium (Se) <1 ug/L 1 1 EPA 200.8 02/16/2017 23:59 CWSPEN3 Thailium(TI) Low Level <0.2 ug/L N1 0.2 1 EPA 200.8 02/16/2017 23:59 CWSPEN3 Field Parameters (certification not covered under DPAL certification) - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Vendor Method V_PACE grtificate of Laboratory Anal, -.a This report shall not be reproduced, except in full. Order# J17020407 Site: New Pipe Collection Date: 14-Feb-17 12:00 PM Analyte Result Units Qualifiers RDL DF TOTAL DISSOLVED SOLIDS TDS 260 mg L 25 1 TOTAL SUSPENDED SOLIDS TSS 17 mg 5 1 Sample #: 2017005283 Matrix: NPDES Page 5 of 33 Method Analysis Daterrinte Analyst SM2540C 02/16/201715:00 MGIGANT SM2540D 02/161201710:00 MGIGANT _ertificate of Laboratory Anal,_.s Page 6of 33 This report shall not be reproduced, except in full. Order# J17020407 Site: FIELD BLANK Sample #: 2017005284 Collection Date: 14-Feb-17 Matrix: NPDES Analyte Result Units Qualifiers RDL DF MERCURY IN WATER - (Analysis Performed by Pace Laboratories) Vendor Parameter Complete Method Analysis Date/Time Analyst Vendor Method V_PACE Qualifiers: M7 Matrix spike recovery was High: the associated Laboratory Control Spike (LCS) was acceptable. N1 See additional information listed below. N1- Target analyte was detected in continuing calibration blank(s) at a concentration greater than Yz the reporting limit but less than the reporting limit. Analyte concentration in sample is valid and may be used for compliance purposes. %,ertificate of Laboratory Ana.,-.s Page 7of 33 This report shall not be reproduced, except in full. Order# J17020407 Level H QC Summary Q17020571 C_NO2NO3 NITRITE + NITRATE (COLORUAETRIC) Blank # 1 Parameter Measured Final 11nMs: Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 0.0014 0.0014 mg-N/L 1 0.01 <1/2 RDL - (Colorimetric) Blank # 2 Parameter Measured haw Units: Oil RDL Relative Concentration Qualifier Nitrite + Nitrate 0.0002 0.0002 mg-N/L 1 0.01 < 1 /2 RDL - (Colorimetric) Blank # 3 Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier Nitrite + Nitrate 0.0008 0.0008 mg-N/L 1 0.01 < 112 RDL - (Colorimetric) Blank # 4 Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier Nitrite + Nitrate -0.0011 -0.0011 mg-N/L 1 0.01 <1/2 RDL - (Colorimetric) Blank # 5 Parameter Measured Final Units: Oil RDL Relative Concentration Qualifier Nitrite + Nitrate -0.0015 -0.0015 mg-N/L 1 0.01 < 1 /2 RDL - (Colorimetric) LCS # 1 Parameter Measured Final UnilE Dil &M %Recovery LCL UCL Qualifier Nitrite + Nitrate 0.301 3.01 mg-N/L 10 3.01 100 90 110 - (Colorimetric) LCS # 2 Parameter Measured Final Units: Mil Soike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0.295 2.95 mg-N/L 10 3.01 98.1 90 110 - (Colorimetric) LCS # 3 Parameter Measured Final Units: Dil Spike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0.29 2.9 mg-N/L 10 3.01 96.2 90 110 - (Colorimetric) LCS # 4 Parameter Measured Final Units: Dil Soike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0.285 2.85 mg-N/L 10 3.01 94.9 90 110 - (Colorimetric) LCS # 5 Parameter Measured Final IWIL Dil Soike % Recovery LCiL UCL Qualifit_r Nitrite + Nitrate 0.284 2.84 mg -NIL 10 3.01 94.3 90 110 - (Colorimetric) artificate of Laboratory Anal,—..3 Page 8of 33 This report shall not be reproduced, except in full. Order# J17020407 Level II QC Summary Q17020571 C_NO2NO3 NITRITE+ NITRATE(COLORIMETRIC) MS # 1 Parent Sample: J17010538 — 2017002436 Parameter Measured Final 11allE Dil 5Q& % Recovery LCL UCL Qualifier Nitrite + Nitrate 0.252 0.252 mg -NIL 1 0.25 96.9 90 110 - (Colorimetric) MSD # 1 Parent Sample: J17010538 — 2017002436 Parameter Measured Final Units: Dil Soike % Recovery LCL UCL RPD Qualifler Nitrite + Nitrate 0.25 0.25 mg -NIL 1 0.25 96.2 90 110 0.663 - (Colorimetric) MS # 2 Parent Sample: J17020345 — 2017004978 Parameter Measured Final UnjlL Dil Soike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0.29 0.29 mg -NIL 1 0.25 94.8 90 110 - (Colorimetric) MSD # 2 Parent Sample: /17020345 — 2017004978 Parameter Measured Fbw Units: Dil Soike %Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0.29 0.29 mg-N/L 1 0.25 94.9 90 110 0.169 - (Colorimetric) MS # 3 Parent Sample: J17010657 — 2017003041 Parameter Measured Final Un Dil Scike %Recovery LOLL Q" Qualiill Nitrite + Nitrate 0.635 0.635 mg-N/L 1 0.25 92.5 90 110 - (ColorimeMc) MSD # 3 Parent Sample: /17010657 — 2017003041 Parameter Measured Final UnilL DII Soike % Recovery LCL UCL RPD Qualifier Nitrite + Nitrate 0.637 0.637 mg-N/L 1 0.25 93.4 90 110 0,947 - (Colorimetric) MS # 4 Parent Sample: J17020378 — 2017005189 Parameter Measured Final Unis: Dil Soike % Recovery LCL UCL Qualfie Nitrite + Nitrate 0.405 0.405 mg-N/L 1 0.25 93.6 90 110 - (Colorimetric) MSD # 4 Parent Sample: /17020378 — 2017005189 Parameter Measur Final ni : Dil Soike %Recovery LL(L UCL RPD Qualifier Nitrite + Nitrate 0.404 0.404 mg -NIL 1 0.25 93.4 90 110 0.128 - (Colorimetric) MS # 5 Parent Sample: /17020225 — 2017004447 Parameter Measured Final Units: Dil Soike % Recovery LCL UCL Qualifier Nitrite + Nitrate 0.177 0.177 mg-N/L 1 0.25 76.9 90 110 - (Colorimetric) MSD # 5 Parent Sample: /17020225 — 2017004447 Parameter Measured Final Units: Dil Soike %Recovery L" RPD Qualifier Nitrite + Nitrate 0.179 0.179 mg-N/L 1 0.25 77.4 90 110 0.622 - (Colorimetric) Drtificate of Laboratory Analyati Page 9of33 This report shall not be reproduced, except in full. Order # J17020407 Level II QC Summary Q17020571 C_NO2NO3 NITRITE + NITRATE (COLORBIETRIC) MS # 6 Parameter Measured Final Nitrite + Nitrate 0.295 0.295 (Colodmetric) MSD # 6 Parameter Measured Final Nitrite + Nitrate 0.295 0.295 (Colorimetric) Parent Sample: J17020225 — 2017004448 Units: Mil S ike % Recovery LCL UCL Quaffier mg-N/L 1 0.25 90.8 90 110 - Parent Sample: /17020225 -- 2017004448 Units: Dil Spike % Recovery LCL UCL RPD Qualifier mg-N/L 1 0.25 90.7 90 110 0.0441 - �rtificate of Laboratory Analyars This report shall not be reproduced, except in full. Order# J17020407 Level II QC Summary Q17020455 Dionex INORGANIC IONS BY IC Page 10 of 33 Blank # 1 Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier Chloride 0 0 mg/L 1 0.1 < 1/2 RDL - Fluoride 0 0 mg/L 1 0.1 < 112 RDL - Sulfate 0 0 mg/L 1 0.1 < 112 RDL - IS # 1 Parameter Measured Final Unit : Dil ike % Recovery LCL UCL Qualifier Chloride 11.5 11.5 mg/L 1 5 108 80 120 - Fluoride 4.92 4.92 mg/L 1 5 97.6 80 120 - Sulfate 8.28 8.28 mg/L 1 5 101 80 120 - ISD # 1 Parameter Measured Final Unit ; Dil Spike % Recovery LCL UCL RPD Qualifier Chloride 11.5 11.5 mg/L 1 5 108 80 120 0.0594 - Fluoride 4.91 4.91 mg/L 1 5 97.5 80 120 0.16 - Sulfate 8.26 8.26 mg/L 1 5 101 80 120 0.398 - IS # 2 Parameter Measured Final Units: oil Spike % Recovery LCL UCL Qualifier Chloride 7.61 7.61 mg/L 1 5 104 80 120 - Fluoride Not Tested mg/L 1 5 80 120 - Sulfate 7.02 7.02 mg/L 1 5 100 80 120 - ISD # 2 Parameter Measured Final UnIlL Dil Spike % Recovery LQL UCL RPD Qualifier Chloride 7.66 7.66 mg/L 1 5 105 80 120 0.91 - Fluoride Not Tested mg/L 1 5 80 120 - Sulfate 7.04 7.04 mg/L 1 5 101 80 120 0.431 - LCS # 1 Parameter Measured Final Units: oil Spike % Recovery LCL UCL Qualifler Chloride 4.83 4.83 mg/L 1 5 96.5 90 110 - Fluoride 4.94 4.94 mg/L 1 5 98.8 90 110 - Sulfate 4.78 4.78 mg/L 1 5 95.6 90 110 - . ertificate of Laboratory Ana.,-.s Page 11 of 33 This report shall not be reproduced, except in full. Order# J17020407 Level II QC Summary Q17020446 ICP-TRM TOTAL RECOVERABLE METALS BY ICP Bank # 1 Parameter Measured Final Units: Oil ROL Relative Concentration Qualifier Aluminum (Al) 0.000407 0.000407 mg/L 1 0.005 <1/2 ROL Barium (Be) (Be) -0.000111 -0.000111 mg/L 1 0.005 < 1/2 ROL - Boron (B) 0,00192 0.00192 mg/L 1 0.05 < 112 ROL - Calcium (Ca) -0.000208 -0.000208 mg/L 1 0.01 < 1/2 ROL - Iron (Fe) 0.000817 0.000817 mg/L 1 0.01 < 1/2 ROL - Magnesium (Mg) -0.0012 -0.0012 mg/L 1 0.005 < 1/2 ROL - Manganese (Mn) -0.000153 -0.000153 mg/L 1 0.005 < 1/2 ROL - Potassium (K) -0.0018 -0.0018 mg/L 1 0.1 < 112 ROL - Sodium (Na) 0.00963 0.00963 mg/L 1 0.05 < 1/2 ROL - Zinc (Zn) 0.000154 0.000154 mg/L 1 0.005 < 1/2 ROL - LCS # 1 Parameter Measured 512W Units: Di S ike %Recovery LCL UCL Qualifier Aluminum (Al) 4.84 4.84 mg/L 1 5 96.8 85 115 Barium (Be) (Be) 5.03 5.03 mg/L 1 5 101 85 115 - Boron (B) 4.93 4.93 mg/L 1 5 98.5 85 115 Calcium (Ca) (Ca) 4.94 4.94 mg/L 1 5 98.8 85 115 - Iron (Fe) 4.97 4.97 mg/L 1 5 99.4 85 115 - Magnesium (Mg) 5.01 5.01 mg/L 1 5 100 85 115 - Manganese (Mn) 4.96 4.96 mg/L 1 5 99.1 85 115 - Potassium (K) 4.9 4.9 mg/L 1 5 98 85 115 Sodium (Na) 4.91 4.91 mg/L 1 5 98.3 85 115 - Zinc (Zn) 4.9 4.9 mg/L 1 5 98.1 85 115 - MS # 1 Parent Sample: J17020407 - 2017005283 Parameter Measured Final Units: Dil Soike % Recovery LCL UCL Quallfi Aluminum (Al) 8.37 8.37 mg/L 1 5 135 70 130 - Badum (Be) 5.26 5.26 mg/L 1 5 102 70 130 - Boron (B) 5.03 5.03 mg/L 1 5 99.8 70 130 - Calcium (Ca) 55.1 55.1 mg/L 1 5 99 70 130 - Iron (Fe) 8.1 8.1 mg/L 1 5 102 70 130 - Magnesium (Mg) 14.4 14.4 mg/L 1 5 93.3 70 130 - Manganese (Mn) 5.53 5.53 mg/L 1 5 99.3 70 130 - Potassium (K) 8.93 8.93 mg/L 1 5 103 70 130 - Sodium (Na) 23.3 23.3 mg/L 1 5 105 70 130 - Zinc (Zn) 4.92 4.92 mg/L 1 5 96.8 70 130 - MSD #1 Parent Sample: J17020407 - 2017005283 Parameter Measured Final Units: Dil Soike % Recovery LCL UCL RPD Qualifier Aluminum (AI) 8.35 8.35 mg/L 1 5 135 70 130 0.238 - . ertificate of Laboratory Ana.,-.s This report shall not be reproduced, except in full. Order# J17020407 Level II QC Summary Q17020446 ICP_TRM TOTAL RECOVERABLE METALS BY ICP lul.-illXXI Parameter Measured Final Units: Dil Spike Barium (Be) 5.32 5.32 mg/L 1 5 Boron (B) 5.09 5.09 mg/L 1 5 Calcium (Ca) 55.7 55.7 mg/L 1 5 Iron (Fe) 8.06 8.06 mg/L 1 5 Magnesium (Mg) 14.5 14.5 mg/L 1 5 Manganese (Mn) 5.59 5.59 mg/L 1 5 Potassium (K) 9.03 9.03 mg/L 1 5 Sodium (Na) 23.6 23.6 mg/L 1 5 Zinc (Zn) 4.98 4.98 mg/L 1 5 Page 12 of 33 Parent Sample: 117020407 — 2017005283 % Recovery LCL UCL RPD Qualifier 103 70 130 1.17 - 101 70 130 1.08 - 110 70 130 10.9 - 101 70 130 0.771 - 96.3 70 130 3.21 - 101 70 130 1.32 - 105 70 130 1.82 - 110 70 130 4.66 - 97.9 70 130 1.15 - certificate of Laboratory Ana.,-.s Page 13 of 33 This report shall not be reproduced, except in full. Order# J17020407 Level II QC Summary Q17020453 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS Blank # 1 Parameter Measured Final Units: Dil RDL Relative Concentration Qualifier Antimony (Sb) -0.031 -0.031 ugfL 1 1 < 1/2 RDL - Arsenic (As) 0.024 0.024 ugfL 1 1 < 1/2 RDL - Cadmium (Cd) 0.002 0.002 ug/L 1 1 < 1/2 RDL - Chromium (Cr) -0.087 -0.087 ug/L 1 1 < 1/2 RDL - Copper (Cu) -0.066 -0.066 ug/L 1 1 < 112 RDL - Lead (Pb) 0.001 0.001 ug/L 1 1 < 1/2 RDL - Molybdenum (Mo) 0.006 0.006 ug/L 1 1 < 1/2 RDL - Nickel (Ni) -0.005 -0.005 ug/L 1 1 < 1/2 RDL - Selenium (Se) 0.004 0.004 ug/L 1 1 < 1/2 RDL - Thallium (TI) Low Level -0.009 -0.009 ug/L 1 0.2 < 1/2 RDL - LCS # 1 Parameter Measured Final Units: Mil Soike % Recovery LQ, L UCL Qualifier Antimony (Sb) 50.8 50.8 ug/L 1 50 102 85 115 - Arsenic (As) 50.7 50.7 ug/L 1 50 101 85 115 - Cadmium (Cd) 50.7 50.7 ug/L 1 50 101 85 115 - Chromium (Cr) 50.5 50.5 ug/L 1 50 101 85 115 - Copper (Cu) 50.3 50.3 ug/L 1 50 101 85 115 - Lead (Pb) 61.4 51.4 ug/L 1 50 103 85 115 - Molybdenum (Mo) 51 51 ug/L 1 50 102 85 115 - Nickel(Ni) 51.1 51.1 ugfL 1 50 102 85 115 - Selenium (Se) 49.4 49.4 ug/L 1 50 98.7 85 115 - Thallium (TI) Low Level 50.5 50.5 ugfL 1 50 101 85 115 - NIS # I Parent Sample: J17020407 - 2017005283 Parameter Measured Final Units: Dil Soike %Recovery LCL UCL Antimony (Sb) 48.1 48.1 ug/L 1 50 96 70 130 - Arsenic (As) 49.9 49.9 ugfL 1 50 98.9 70 130 - Cadmium (Cd) 50 50 ug/L 1 50 99.4 70 130 - Chromium (Cr) 51 51 ug/L 1 50 98.2 70 130 - Copper (Cu) 51.1 51.1 ug/L 1 50 98 70 130 - Lead(Pb) 52 52 ugfL 1 50 101 70 130 - Molybdenum (Mo) 49.2 49.2 ug/L 1 50 98.1 70 130 - Nickel(Ni) 57.1 57.1 ugfL 1 50 98.8 70 130 - Selenium (Se) 48.1 48.1 ugfL 1 50 95.8 70 130 - Thallium (TI) Low Level 47.1 47.1 ug/L 1 50 94.2 70 130 - MSD # 1 Parent Sample: /17020407 - 2017005283 Parameter Measured Final Unhs Dil Soike % Recovery LCL UCL RPD Qualifier Antimony (Sb) 48.3 48.3 ug/L 1 50 96.5 70 130 0.497 - .,ertificate of Laboratory Ana[, -.a This report shall not be reproduced, except in lull. Order# J17020407 Level II QC Summary QI7020453 IMS_TRM TOTAL RECOVERABLE METALS BY ICP-MS MSD # 1 Parameter Measured Pinal Units: Dil Spike Arsenic (As) 50.6 50.6 ug/L 1 50 Cadmium (Cd) 50.2 50.2 ug/L 1 50 Chromium (Cr) 51.3 51.3 ug/L 1 50 Copper (Cu) 51.4 51.4 ugrL 1 50 Lead (Pb) 52.3 52.3 ug/L 1 50 Molybdenum (Mo) 49.2 49.2 ug/L 1 50 Nickel (Ni) 57.9 57.9 ug/L 1 50 Selenium (Se) 48.3 48.3 ug/L 1 50 Thallium (TI) Low Level 48.5 48.5 ug/L 1 50 Page 14 of 33 Parent Sample: J17020407 -- 2017005283 % Recovery LCL UCL RPD QualN�r 100 70 130 1.36 - 99.9 70 130 0.464 - 98.7 70 130 0.52 - 98.7 70 130 0.704 - 101 70 130 0.634 - 98.2 70 130 0,114 - 100 70 130 1.52 - 96.2 70 130 0.423 - 96.9 70 130 2.87 - . artificate of Laboratory Anai,_.s Page 15 of 33 This report shall not be reproduced, except in full. Order# J17020407 Level II QC Summary Q17020438 TDS TOTAL DISSOLVED SOLIDS Blank # 1 Parameter Measured Final TDS 0 0 Blank # 2 Parameter Measured Final TDS 0 0 Duplicate # 1 Parameter Measured Final TDS 242 242 Duplicate # 2 Parameter Measured Final TDS 206 206 Duplicate # 3 Parameter Measured Final TDS 40 40 LCS # I Parameter Measured Final TDS 92 92 nits: Dil RDL Relative Concentration Qualifier mglL 1 25 < 112 RDL - Units: Dil RDL Relative Concentration Qualifier mg/L 1 25 < 1 /2 RDL - Parent Sample: J17010179 — 2017ODD667 nits: PQ Qualifier mg/L 1 0 Parent Sample: /17010214 — 2017000865 Units: Dil RPD Qualifier mg/L 1 1.45 - Parent Sample: J17020345 — 2017004973 Units: Dil RPM Qualiti mg/L 1 0 nits: Dil Soik % Recovery LSI UU Qualifier mg/L 1 100 92 90 110 - %,ertificate of Laboratory Ana.,-.s Page 16 of 33 This report shall not be reproduced, except in full. Order # J17020407 Level 11 QC Summary Q17020424 TSS TOTAL SUSPENDED SOLIDS Blank # 1 Parameter Measured Final TSS 0 0 Duplicate # 1 Parameter Measured Final TSS 1.6 1.6 Duplicate # 2 Parameter Measured Final TSS 8.4 8.4 LCS # 1 Parameter Measured Final TSS 46.8 46.8 Units: Dil RDL Relative Concentration Qualifier mglL 1 5 < 1/2 RDL - Parent Sample: J17010160 — 2017000613 Units: Dil RPD Qualifier mg/L 1 11.8 - Parent Sample: J17010209 — 2017000852 Units: oil RPD Qualifier mg/L 1 2.35 nits: Dil Spike % Recovery LCL UCL Qualifier mg/L 1 50 93.6 90 110 - �2ceAnayical' m wpacelabs. ccm February 21, 2017 Program Manager Duke Energy 13339 Hagers Ferry Road Bldg.7405 MG30A2 Huntersville, NC 28078 RE: Project: J17020407 Pace Project No.: 92330051 Pace Analytical services, LLC 0§6ili"te. Suite too Huntersville, NC 28078 (704)878-9092 Dear Program Manager: Enclosed are the analytical results for sample(s) received by the laboratory on February 15, 2017. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, l<. r zlp� Kevin Herring kevin.herring@pacelabs.com HORIZON Database Administrator Enclosures cc: Program Manager, Duke Energy Anne Pifer 0 z. ,I REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, L-C. Page 1 of 16 m ace Analytical .pacelabs.mm Project: J17020407 Pace Project No.: 92330051 Pace Analytical Services, LLC OgQr�7li rin : Suite 100 �Jy Huntersville, NC 28078 (704)875-9092 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NCO30 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 16 aceAnalytical swwpacelabs. am Pace Analytical Services, LLC ft11fff338. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project J17020407 Pace Project No.. 92330051 Lab ID Sample ID Matrix Date Collected Date Recelved 92330051001 92330051002 2017005283 2017005284 Water Water 02/14/1712:00 02/14/17 00:00 02/15/1713:10 02/15/1713:10 10 :1 261 [i ie1 a 1101 X/_\ 2 /_1 WIN 61 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 16 ceAnaocal e stm /:pxehbamm SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 09yi%ate. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J17020407 92330051 Analysts Lab ID Sample ID Method Analysts Reported Laboratory 92330051001 2017005283 EPA 1631E ANB 1 PASI-A SM 2320B KDF 3 PASI-A 92330OS1002 2017005284 EPA 1631E ANB 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 16 aceAnalytical .parelebs cc SUMMARY OF DETECTION Pace Analytical Services, LLC 0§8�i2wfte. Suite too Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J17020407 92330051 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92330051001 2017005283 Date(s) 2/14/17 02/21/17 09:50 Time(s) 12:00 02/21/17 09:50 Flow <,25 GPM 02/21/17 09:50 Collected By WBT 8 02/21/17 09:51 DKS Collected Date 2/14/17 02121/1709:51 Collected Time 12:D0 02/21/17 09:51 Field pH 5.5 Bid. Units 0.10 02/21/17 09:51 Field Temperature 14.6 deg C 0.50 02/21/17 09:51 Field Specific Conductance 182.8 umhos/cm 1.0 02/21/17 09:51 Turbidity 6.1 NTU 1.0 02/21/17 D9:51 EPA 1631E Mercury 25.8 ng/L 0.50 02120/1712:58 SM 2320B Alkalinity,Bicarbonate (CaCO3) 42.8 mg/L 5.0 02117/17 13:45 SM 23208 Alkalinity, Total as CaCO3 42.8 mg/L 5.0 02/17/17 13:45 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 16 2aceAnalyfical' . pacalabs.ccm PROJECT NARRATIVE Project: J17020407 Pace Project No.: 92330051 Method: EPA 1631 E Description: 1631 E Mercury,Low Level Client: Duke Energy Date: February 21, 2017 Pace Analytical Services, LLC O JQJI 2,&:fte. Suite 100 Huntersville, NC 28078 (704)875-9092 General Information: 2 samples were analyzed for EPA 1631E. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Sample Preparation: The samples were prepared in accordance with EPA 1631 E with any exceptions noted below. Initial Calibrations (including MS Tune as applicable): All criteria were within method requirements with any exceptions noted below Continuing Calibration: All criteria were within method requirements with any exceptions noted below Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below Laboratory Control Spike: All laboratory control spike compounds were within oC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 16 (�'CeA*taa` MaxpeistaDsmm PROJECT NARRATIVE Project: J17020407 Pace Project No.: 92330051 Method: SM 2320B Description: 2320B Alkalinity Client: Duke Energy Date: February 21, 2017 Pace Analytical Services, LLC o$$@x2'9%fhe. Suite too Huntersville, NC 28078 (704)875-9092 General Information: 1 sample was analyzed for SM 2320B. All samples were received in acceptable condition with any exceptions noted below or on the chain -of custody and/or the sample condition upon receipt form (SCUR) attached at the end of this report. Hold Time: The samples were analyzed within the method required hold times with any exceptions noted below. Method Blank: All analytes were below the report limit in the method blank, where applicable, with any exceptions noted below. Laboratory Control Spike: All laboratory control spike compounds were within QC limits with any exceptions noted below. Matrix Spikes: All percent recoveries and relative percent differences (RPDs) were within acceptance criteria with any exceptions noted below. Additional Comments This data package has been reviewed for quality and completeness and is approved for release. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 16 Pace Analytical Services, LLC aceAmlytical e 00609cffhe. Suite 100 Huntersville. NC 28078 '= (704)875-9092 ANALYTICAL RESULTS Project: J17020407 Pace Project No.: 92330051 Sample: 2017005283 Lab ID: 92330051001 Collected: 02/14/17 12:00 Received: 02/15/1713:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Flow Monitoring Data Analytical Method Date(s) 2114117 1 02/21/17 09:50 Time(s) 12:00 1 02/21/17 09:50 Flow <.25 GPM 1 02/21/17 09:50 Field Data Analytical Method: Collected By WBT & 1 02/21/17 09:51 DKS Collected Date 2114/17 1 02/21 /17 09:51 Collected Time 12:00 1 02/21/17 09:51 Field pH 5.5 Std. Units 0.10 1 02/21/17 09:51 Field Temperature 14.6 deg C 0.50 1 02/21/17 09:51 Field Specific Conductance 182.8 umhoslcm 1.0 1 02/21/17 09:51 Turbidity 6.1 NTU 1.0 1 02/21/17 09:51 1631E Mercury,Low Level Analytical Method: EPA 1631E Preparation Method: EPA 1631E Mercury 25.8 ng/L 0.50 1 02/17/1715:29 02/2011712:58 7439-97-6 2320E Alkalinity Analytical Method: SM 2320B Alkalinity,Bicarbonate (CaCO3) 42.8 mg/L 5.0 1 02/17/17 13:45 Alkalinity, Carbonate (CaCO3) ND mg/L 5.0 1 02/17/17 13:45 Alkalinity, Total as CaCO3 42.8 mg/L 5.0 1 02/17/17 13:45 Date: 02/21/2017 02:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced. except in full, without the written consent of Pace Analytical Services, L-C. Page 8 of 16 Pace AnaWal Services, LLC loa6v2Mte. Suite 100 y Huntersvllle. NC 28078 (704)878-9092 ANALYTICAL RESULTS Project: J17020407 Pace Project No.: 92330051 Sample: 2017005284 Lab ID: 92330051002 Collected: 02/14/1700:00 Received: 02115/1713:10 Matfix:Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Dual 1831E Mercury,Low Level Analytical Method: EPA 1631 E Preparation Method: EPA 1631 E Mercury ND ng/L 0.50 1 02/17/1716:29 02/2011715:47 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not fie reproduced, except in full, Date: 02/21/2017 02:44 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 16 aceAnalytical e ..pacelsDs mm QUALITY CONTROL DATA Pace Analytical Services, LLC maglf w" . Suite 100 �! Huntereville, NC 28078 (704)875-9092 Project: J17020407 Pace Project No.: 92330051 QC Batch: 348810 Analysis Method: EPA 1631E QC Batch Method: EPA 1631 E Analysis Description: 1631 E Mercury,Low Level Associated Lab Samples: 92330051001, 92330051002 METHOD BLANK: 1935394 Matrix: Water Associated Lab Samples: 92330051001, 92330051002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ng/L NO 0.50 02/20/17 12:43 METHOD BLANK: 1935395 Matrix: Water Associated Lab Samples: 92330051001, 92330051002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ng/L NO 0.50 02/20/1714:38 METHOD BLANK: 1935396 Matrix: Water Associated Lab Samples: 92330051001, 92330051002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ng/L NO 0.50 02/2011716:02 LABORATORY CONTROL SAMPLE: 1935397 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ng/L 5 5.01 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1935398 1935399 MS MSD 92330051001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conic. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ng/L 25.8 25 25 51.7 51.7 104 104 71-125 0 24 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1935400 1935401 MS MSD 92330385002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conic. Conic. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ng/L 2.79 25 25 29.0 29.1 105 105 71-125 0 24 Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/21/20170244PM without the wntten con sent of Pace Analytical Services,LLC. Page 10 of 16 laceAnalytilcalo wxwpacelabs.ccm QUALITY CONTROL DATA Pace Analytical Services, LLC olip l ile. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: J17020407 Pace Project No.: 92330051 QC Batch: 348490 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320B Alkalinity Associated Lab Samples: 92330051001 METHOD BLANK: 1933464 Matrix: Water Associated Lab Samples: 92330051001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Carbonate (CaCO3) mg/L NO 5.0 02/16/17 21:50 Alkalinity, Total as CaCO3 mg/L NO 5.0 02/16/17 21:60 Alkalinity,Bicarbonate(CaCO3) mg/L NO 5.0 02116/1721:50 LABORATORY CONTROL SAMPLE: 1933465 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ni 50 48.8 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1933466 1933467 MS MSD 92329770005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L 129 50 50 178 178 97 98 80-120 0 25 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1933468 1933469 MS MSD 92329770015 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Alkalinity, Total as CaCO3 mg/L NO 50 50 49.6 48.4 99 96 80-120 2 25 Results presented on this page are in the units indicated by the "Units" calumn except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shell not be reproduced, except in full, Date: 02121/201702:44 PM without the written consent of Pace Analytical Services,LLC. Page 11 of 16 aceAnalAcals wwaprsNDsan QUALIFIERS Project: J17020407 Pace Project No.: 92330051 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MOIL -Adjusted Method Detection Limit. PQL- Practical Quantitation Limit. RL - Reporting Limit. Pace Analytical Services, LLC m$g%wke. Suite 100 Huntersville, NC 28078 (704)975-9092 S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitdle by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services -Asheville PASI-C Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02121/2017 02:44 PM without the written consent of Pace Analytical Services, I.I.C. Page 12 of 16 ac"Analytical e e ..Pscsllaft= QUALITY CONTROL DATA CROSS REFERENCE TABLE Pace Analytical Services, LLC I9AR"1 Whe. Suite too Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: J17020407 92330051 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92330051001 2017005283 92330051001 2017005283 92330OS1001 2017005283 EPA 1631E 348810 EPA 1631E 348811 92330051002 2017005284 EPA 1631E 348810 EPA 1631E 348811 92330051001 2017005283 SM 2320B 348490 Date: 02/21/2017 02:44 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 16 /�>`�ceAnalytica oampie conolnan Upon Racal t(SCUR) Page 1 of 2 Document Na.: I e o � F CAR CS 033 Rev OS Issuing Autho l�9 ntory receiving samples. Pare Quality Office Asheville ❑ Eden❑ Greenwood ❑ Huntersville [� Raleigh[] Mechanicsville[] Client Name: WO## : 92330051 >I ht Projectq: Courier: "rtu Ex DUPS /[ CUSPS DClient II I III II I II I III II II III ❑ Commercial Dtiace D� Seal DOther:_ 92330051 Custody Seal Present? Dyes 1/ s Intact? Dyes 0fl 0 I Packing Material: ❑Rubble Wrap DBubble Ba s Date/Initials Person Examining Contents: J M.'I.T '17 Thermometer: B DNone DOther:_ IR Gun ID: p(�% et ❑Blue Correction Factor: e "Ing to 6 CTempt Corrected ('q: d— Type of Iqe. ❑None Samples on Ice, coaling process -has Temp should be above fr Biological Tissue Frozen? Dyes No DN/A USDA Regulated Soil ( N/A, water sample) Did samples o ' inate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Yes o Correct Containers Used? iample Labels Match COC? rip Blank Present? Did samples originate from a foreign source Including Hawaii and Puerto Rlr„u r"Iv— yes NO N/A 1. es ONO N/A 2. Yes ONO N/A 3. es ❑Na N/A 4. es ONO N/A S. 17+� ❑No ❑N/A 6. caveNo N/A s No N/A 7. ,_,YYes No A R. Note if sedim MYes ONO ON/A 9. CLIENT NOTIFICATION/RESOLUTION Person Contacted: Comments/Sample Discrepancy: Project Manager SCURF Review: 1 Project Manager SRF Review: U4 u—o UNo N 10. ❑Yes ONO N/A' 11. Field Data Required? []Yes ❑No Date/Time: Date: , 2, // r�( �- Date: late: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. 'ut of hold, incorrect preservative, out of temp, Incorrect containers) Page 14 of 16 Document Name: cument Revised: Sept. 21, 2016 ndition Upon Receipt(SCUR) Page 2 of 2 Document No.: Issuing Authority: Page 31 of rep-rc_n1a-pev.o1 Pace Quality Office 'Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. "*Bottom half of box is to list number of bottles i y3 c Project WO# : 92330051 PM: KLH1 Due Dale: 02/21/17 CLIENT: 92-Duke Ener 2 Bi V m 6 E N m Z d v 7 n 6 E 1�f1 m 2 Bi m 7 V m 6 pE O al Z N 6 J N `v rG ry v $ n 4 E N m v V m Z 4 E 0 A °! u Z N m 6 of 6 al ; y n O Z 6 E 1O/1 U 6 la d C 7 C, a E o LL j J a < w C 7 u Q ?: M < v S U < ,`Y., M (� < 2 o L = E < yE� IYI < H v x a a O x E ,`Y, ,�'1 :i < y S n p O N E Q E ,�YI tp < 2 V x z a < y�� N m M ti < Z V O > E P �:: O ¢ \ z m O z < > E T 1p % 6 C O > E O P �% i a \ ? IN O > E $ P � \ Z 4 m N 3 < 0 i r „ m �, i > 6 n \ a i < z 1� Y Vf E N N 6 m 6 C yE� N N 6 ry Z a' E m d C U `_•' .@ Cc VI E N J 1 I 2 3 4 5 . fi 7 g 9 1 33 4J 12 PH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot p Page 15 of 16 CHAIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM ad33o°S I Duke Energy Analytical Laboratory DUKE Meg Cone MGO3A= (euildirp r.05) ) 13339 Hagen Ferry Rd " HunbnvBls, N C. 3eWe ENERGY agog ersszds ; m �. ........................ Far: 70d e75-/3.9 .............. )------ -----•-I Ir,oMvl N.me 21 n No CAPE FEAR -AOW 9 3)Cllenl STEVE CAHOON, JONATHAN STAMAS• STEVEN CONNER Z 918v.Nro°. um. cm OP..: BEMYYYT 7) W, C.lder To: t ,` grmPd m� eN.1mry lo: t0R1.e eedm ................ ue use Owy ' 1;Chem ------------- -Anal ieal Laboratory Use Only ' d `o iwse s.mw cle++ DES i.. { '`PBw _7_ot_1 NP_ INorth C.mfirm i DISTRIBUTION m °p9°dg✓ p» . s,., od91°.Nne_rm^ ORIGINAL to LAB. ODPy top CLIENT PACE SAMPLE PROGRAM NPDES i 1115044 Cooler Te C P�rf}e.r..:1, I z=Nlso, 3=N 4 4 2,4 3 3 4 5 1 4-1 a 5•NR 4 MRa y O I n v T N a � Customer to complete all m aI appropriate non -shaded amps. _ a 0rn Z ; o 3 a "Collection Information e a e _ 'I m a: YIaI m Imole Dtaseriotion or ID D.,. T1 . stalwRre =s o IN- o U :' i m d ? i I I FIELD BLANK. I I I I I X I I I I I I I I I I I I i I I (PACE Please include Field oprameters on the renorL I I I I I I I I I I I I I i I' I -day I 1N ey c4W BY ICP TRM: A �'i'�` 13N.rtbne / 61Y / nwrtlM. eV BMeRime �-l.c. L3si 9. B. Ca. Fe, Mo. Mn. K. Na. Zn, Hardness q R � rrRa4ueste0 Turnaround to Doge I r DayT _>(� 7 _ _ - / / v •3 Days ey, D ,.✓r'm. _ } °' •OIIvv 'Add. Curt Will ApMy arOp!11e?By / Dueni F Opo Or C Dao lme q �L 17 i °' IMS TRM: Sh. As. Cd. Cr. Cu. Pb, Mo, Ni. Se. TI LL CH_ AIN OF CUSTODY RECORD AND ANALYSIS REQUEST FORM page 33 of 33 Duke Energy Analytical Labonlory - --_ - Ana cal Laboratory Use Only �� of '�`--Tw,la,cm.. NPDES ��i- iol�sn:�suno� (.DUKE M.NCodaMrHnw Fwu Ito Tie) -- IbrthCoolba ; DISTRIBUTION 133]7I]W.n Far? Rd i j �` ..�. V /+y' QI1d1• -'ORIGINAL 10 LAB, COPY W ENERGY. qununveb, N C. tame ; I�a o,.a, , CLIENT Iro41 ere -etas Ted /7 - - Fa: 70a e76134f _ _ _ : -T-- SAMPLE PROGRAM NPpEs i -- - - L - - PACE 6. y CAPEFEAR-AOW 1115040 Cooler T. c 41F.. n.: P , 3 s)Cllent STEVE CAHOON, JONA7IMN STAMAS, STEVEN x4-1 e•M ; 4 4 2,4 3 4 5 CONNER _ _..._.___ E--� roc.+.: •EM�wr ?IFLw. n.+w T.; iwn 7 - �.._ tOW.Y Cob: LL ~ 1II i oj.4]a. •p°u•Irr w: Cusfamor to cot ]late atl 0 ll" 0 appropriato non -shaded areas. 12Chem r; :n u Z7 tCP TRM: Al. Ba, B, Ca Fe Mg Mn K Na 7n, Hardnee the X mom L "Requested Temaround 10 Dry" .3 Dees ,F +IYf�nf •C0. 'W0. Cost WWII AppN TUVA- cn A. Cd. Cr. 11Cu. Pb, Mo, NL8e, TI LL 10 March 2017 Mr. Ron Berry North Carolina Division of Water Resources 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: Notification of Newly Discovered Pipe at Cape Fear Steam Station Dear Dr. Chemikov, As you are aware during the daily inspection at the Cape Fear Plant last month, one new outlet pipe was identified that flows in to the old cooling tower basin. The coordinates for the pipe are 350 35'25.62" N and 790 02'46.96" W. The pipe has a very low flow and was difficult to sample, however a sample of the discharge from the pipe was obtained. We have continued to monitor the flow from the pipe, we believe the origin of the water is from an old French drain system in the vicinity of the cooling tower. The water in the pipe has been re-routed and combined with Seep S-5 into one discharge point into the discharge canal (effluent channel) so it will be monitored at Outfall 007. Attached are the sampling results. Should you have any questions regarding this submittal or require additional information, please contact me at 919 546-7457 or at steve.cahoon@duke-energy.com. Sincerely, Steve Cahoon Duke Energy EHS CCP Permitting and Compliance cc: Danny Smith, Raleigh Regional Office, NCDEQ Jeff Poupart, Complex Permitting Unit Sergei Chemikov, Complex Permitting Unit