NC0052311_Lab Results Outfall 1/29_20240129

#=CL#
January 26, 2024
LIMS USE: FR - LARRY EDWARDS
LIMS OBJECT ID: 92709444
92709444
Project:
Pace Project No.:
RE:
Larry Edwards
Buckeye Partners, L.P.
4414 Buffalo Rd
Selma, NC 27576
SELMA MONTHLY
Dear Larry Edwards:
Enclosed are the analytical results for sample(s) received by the laboratory on January 22, 2024. The results relate only to
the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte page for analysis unless
otherwise footnoted.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Eden
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
Project Manager
704-977-0942
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 1 of 14
#=CP#
CERTIFICATIONS
Pace Project No.:
Project:
92709444
SELMA MONTHLY
Pace Analytical Services Charlotte
South Carolina Laboratory ID: 99006
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
South Carolina Laboratory ID: 99006
South Carolina Certification #: 99006001
South Carolina Drinking Water Cert. #: 99006003
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Louisiana DoH Drinking Water #: LA029
Virginia/VELAP Certification #: 460221
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification #: 37738
North Carolina Wastewater Certification #: 633
Virginia/VELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 2 of 14
#=SA#
SAMPLE ANALYTE COUNT
Pace Project No.:
Project:
92709444
SELMA MONTHLY
Lab ID Sample ID Method
Analytes
Reported LaboratoryAnalysts
92709444001 POND 1 SM 2130B-2011 1 PASI-EVLG
SM 2540D-2015 1 PASI-EWE
EPA 624.1 4 PASI-CSAS
92709444002 POND 2 SM 2130B-2011 1 PASI-EVLG
SM 2540D-2015 1 PASI-EWE
EPA 624.1 4 PASI-CSAS
92709444003 POND 2 OUT FALL SM 2130B-2011 1 PASI-EVLG
SM 2540D-2015 1 PASI-EWE
EPA 624.1 4 PASI-CSAS
PASI-C = Pace Analytical Services - Charlotte
PASI-E = Pace Analytical Services - Eden
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 3 of 14
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92709444
SELMA MONTHLY
Sample:POND 1 Lab ID:92709444001 Collected:01/22/24 12:15 Received:01/22/24 14:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2130B-2011
Pace Analytical Services - Eden
2130B Turbidity EDN
Turbidity ND NTU 01/23/24 12:471.0 1
Analytical Method: SM 2540D-2015
Pace Analytical Services - Eden
2540D Total Suspended Solids
Total Suspended Solids ND mg/L 01/23/24 15:082.5 1
Analytical Method: EPA 624.1
Pace Analytical Services - Charlotte
624 Volatile Organics
Benzene ND ug/L 01/24/24 19:56 71-43-21.0 1
Surrogates
4-Bromofluorobenzene (S)102 %01/24/24 19:56 460-00-470-130 1
Toluene-d8 (S)101 %01/24/24 19:56 2037-26-570-130 1
1,2-Dichloroethane-d4 (S)86 %01/24/24 19:56 17060-07-070-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/26/2024 02:34 PM
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 4 of 14
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92709444
SELMA MONTHLY
Sample:POND 2 Lab ID:92709444002 Collected:01/22/24 12:25 Received:01/22/24 14:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2130B-2011
Pace Analytical Services - Eden
2130B Turbidity EDN
Turbidity ND NTU 01/23/24 12:481.0 1
Analytical Method: SM 2540D-2015
Pace Analytical Services - Eden
2540D Total Suspended Solids
Total Suspended Solids ND mg/L 01/23/24 15:082.5 1
Analytical Method: EPA 624.1
Pace Analytical Services - Charlotte
624 Volatile Organics
Benzene ND ug/L 01/24/24 20:13 71-43-21.0 1
Surrogates
4-Bromofluorobenzene (S)99 %01/24/24 20:13 460-00-470-130 1
Toluene-d8 (S)101 %01/24/24 20:13 2037-26-570-130 1
1,2-Dichloroethane-d4 (S)86 %01/24/24 20:13 17060-07-070-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/26/2024 02:34 PM
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 5 of 14
#=AR#
ANALYTICAL RESULTS
Pace Project No.:
Project:
92709444
SELMA MONTHLY
Sample:POND 2 OUT FALL Lab ID:92709444003 Collected:01/22/24 12:35 Received:01/22/24 14:25 Matrix:Water
Parameters Results Units DF Prepared Analyzed CAS No.QualReport Limit
Analytical Method: SM 2130B-2011
Pace Analytical Services - Eden
2130B Turbidity EDN
Turbidity 1.1 NTU 01/23/24 12:481.0 1
Analytical Method: SM 2540D-2015
Pace Analytical Services - Eden
2540D Total Suspended Solids
Total Suspended Solids ND mg/L 01/23/24 15:042.5 1
Analytical Method: EPA 624.1
Pace Analytical Services - Charlotte
624 Volatile Organics
Benzene ND ug/L 01/24/24 20:31 71-43-21.0 1
Surrogates
4-Bromofluorobenzene (S)100 %01/24/24 20:31 460-00-470-130 1
Toluene-d8 (S)101 %01/24/24 20:31 2037-26-570-130 1
1,2-Dichloroethane-d4 (S)87 %01/24/24 20:31 17060-07-070-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/26/2024 02:34 PM
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 6 of 14
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92709444
SELMA MONTHLY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
827178
SM 2130B-2011
SM 2130B-2011
2130B Turbidity EDN
Laboratory:Pace Analytical Services - Eden
Associated Lab Samples:92709444001, 92709444002, 92709444003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4277009
Associated Lab Samples:92709444001, 92709444002, 92709444003
Matrix:Water
Analyzed
Turbidity NTU ND 1.0 01/23/24 12:45
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4277010LABORATORY CONTROL SAMPLE:
LCSSpike
Turbidity NTU 19.820 99 90-110
Parameter Units
Dup
Result QualifiersRPDResult
92709444001
4277011SAMPLE DUPLICATE:
Turbidity NTU .75J 6ND
Parameter Units
Dup
Result QualifiersRPDResult
92709504007
4277571SAMPLE DUPLICATE:
Turbidity NTU 17.9 217.6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/26/2024 02:34 PM
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 7 of 14
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92709444
SELMA MONTHLY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
827240
SM 2540D-2015
SM 2540D-2015
2540D Total Suspended Solids
Laboratory:Pace Analytical Services - Eden
Associated Lab Samples:92709444001, 92709444002, 92709444003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4277340
Associated Lab Samples:92709444001, 92709444002, 92709444003
Matrix:Water
Analyzed
Total Suspended Solids mg/L ND 2.5 01/23/24 15:03
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4277341LABORATORY CONTROL SAMPLE:
LCSSpike
Total Suspended Solids mg/L 238250 95 90-110
Parameter Units
Dup
Result QualifiersRPDResult
92709583001
4277342SAMPLE DUPLICATE:
Total Suspended Solids mg/L 2140 D6281610
Parameter Units
Dup
Result QualifiersRPDResult
92709583004
4277343SAMPLE DUPLICATE:
Total Suspended Solids mg/L 40.0 239.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/26/2024 02:34 PM
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 8 of 14
#=QC#
QUALITY CONTROL DATA
Pace Project No.:
Project:
92709444
SELMA MONTHLY
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
QC Batch:
QC Batch Method:
Analysis Method:
Analysis Description:
827607
EPA 624.1
EPA 624.1
624 MSV
Laboratory:Pace Analytical Services - Charlotte
Associated Lab Samples:92709444001, 92709444002, 92709444003
Parameter Units
Blank
Result
Reporting
Limit Qualifiers
METHOD BLANK:4279135
Associated Lab Samples:92709444001, 92709444002, 92709444003
Matrix:Water
Analyzed
Benzene ug/L ND 1.0 01/24/24 13:09
1,2-Dichloroethane-d4 (S)%85 70-130 01/24/24 13:09
4-Bromofluorobenzene (S)%99 70-130 01/24/24 13:09
Toluene-d8 (S)%102 70-130 01/24/24 13:09
Parameter Units
LCS
Result
% Rec
Limits Qualifiers% RecConc.
4279136LABORATORY CONTROL SAMPLE:
LCSSpike
Benzene ug/L 20.020 100 65-135
1,2-Dichloroethane-d4 (S)%84 70-130
4-Bromofluorobenzene (S)%96 70-130
Toluene-d8 (S)%99 70-130
Parameter Units
MS
Result
% Rec
Limits Qual% RecConc.
4279137MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
MSSpike
Result
92709444001
4279138
MSD
Result
MSD
% Rec RPD
MSDMS
Spike
Conc.
Benzene ug/L 20 112 70-142117 520ND22.3 23.4
1,2-Dichloroethane-d4 (S)%92 70-13088
4-Bromofluorobenzene (S)%97 70-13097
Toluene-d8 (S)%98 70-13098
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/26/2024 02:34 PM
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 9 of 14
#=QL#
QUALIFIERS
Pace Project No.:
Project:
92709444
SELMA MONTHLY
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean-Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
"Total" may vary slightly from the sum of the reported component parameters.
ANALYTE QUALIFIERS
The precision between the sample and sample duplicate exceeded laboratory control limits.D6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/26/2024 02:34 PM
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 10 of 14
#=CR#
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Project No.:
Project:
92709444
SELMA MONTHLY
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
Analytical
Batch
92709444001 827178POND 1 SM 2130B-2011
92709444002 827178POND 2 SM 2130B-2011
92709444003 827178POND 2 OUT FALL SM 2130B-2011
92709444001 827240POND 1 SM 2540D-2015
92709444002 827240POND 2 SM 2540D-2015
92709444003 827240POND 2 OUT FALL SM 2540D-2015
92709444001 827607POND 1 EPA 624.1
92709444002 827607POND 2 EPA 624.1
92709444003 827607POND 2 OUT FALL EPA 624.1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.Date: 01/26/2024 02:34 PM
Pace Analytical Services, LLC
6701 Conference Drive
Raleigh, NC 27607
[phone]
Page 11 of 14
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