WQ0014543_Renewal Application_20240123

Initial Review
Reviewer nathaniel.thorn burg
Is this submittal an application? (Excluding additional information.) *
Yes No
Permit Number (IR) * WQ0014543
Applicant/Permittee City of Statesville
Applicant/Permittee Address PO Box 1111 Statesville, NC 28687-1111
Is the owner in BIMS? Yes ) No Is the facility in BIMS? Yes No
Owner Type
Facility Name
County
Fee Category Minor
Is this a complete application?*
Yes No
Signature Authority
Signature Authority Title
Signature Authority Email
Document Type (if non -application)
Email Notifications
Municipal
City of Statesville Class B Residuals Program
Iredell
Does this need review by the hydrogeologist? * Yes No
Regional Office
CO Reviewer
Admin Reviewer
Fee Amount
Complete App Date
01/23/2024
$0
Below list any additional email address that need notification about a new project.
Email Address
Comments to be added to email notfication
Comments for Admin
Comments for RO

Comments for Reviewer
Comments for Applicant

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Ken Galloway
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
7048783438
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ0014543
Has Current Existing permit number
Applicant/Permittee *
City of Statesville
Applicant/Permittee Address*
PO Box 1111 Statesville, NC 28687-1111
Facility Name*
City of Statesville Class B Residuals Program
Please provide comments/notes on your current submittal below.
This permit has not been used. We keep this permit active for redundancy. City is also the Land Owner, so no LOA included.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
Complete LA Renwal.pdf 14.6MB
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
Submission Date
��trllorru�
1 /23/2024

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SUMM111
ENVIRONMENTAL TECHN❑LOMZ3. INC
Arraly0ca1 Laboralorfas
January 24, 2023
Alex Fox
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL:
FAX:
RE: 3rd Creek
Dear Alex Fox:
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com
Order No.: 23010842
Summit Environmental Technologies, Inc. received 1 sample(s) on 1/13/2023 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
Jennifer Woolf
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
Arkansas 88-0735, California 2943, Colorado, Connecticut PH-0108, Florida NELAC E87688, Idaho 01100923, Illinois 200061, Indiana C-011-13,
ISO/IEC 17025:2017 119125 1.22-544, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Maryland 339, Michigan 9988,
Minnesota 1780279, Nevada 011009232020-1, New Hampshire 2996, New Jersey 011006, New York 11777, North Carolina 39705 and 631, North Dakota
R-201, Ohio DW, Ohio VAP C1,0052, Oklahoma 2019-155, Oregon 0112O0001, Pennsylvania 68-01335, Rhode Island LA000317, South Carolina
92016001, Texas T104704466-19-16, Utah 011009232020-12, Virginia VELAP 10381, West Virginia 9957C
Page 1 of 39

MM' Y Summit Environmental Technologies, Inc. Case Narrative
SU3310 Win St.
ENVIRONMENTAL TEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 WO#: 23010842
Arralyi9cal Laboralorlas TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com Date: 1/24/2023
CLIENT: Synagro
Project: 3rd Creek
WorkOrder Narrative:
23010842: This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program
Analytes Report" for accredited analytes list.
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry" designation on the reporting units.
This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any
comments or problems with the analytical events associated with this report are noted below.
Analytical Sequence Sample Notes:
23010842-OOIA TCLP-SVOC_8270E: Possible low bias for Pyridine due to low recovery in the CCV.
Compound demonstrates adequate instrument sensitivity in RLC.
23010842-OOIA TCLP-VOC-MSTR 8260D: CCV/LCS exhibit high recoveries for I, I -Dichloroethene
and Vinyl chloride. Investigative sample are non -detect for these compounds.
Analytical Sequence QC Notes:
MB/LCS-62313 SVOC-BNA_TCLP(8270): Possible low bias for Pyridine due to low recovery in the
CCV. RLC demonstrates control for this analyte.
Original
Page 2 of 39

MM' Summit Environmental Technologies, In Qualifiers and Acronyms
SU3310 Win S
Ekiwlt OMM@N-rALTECHN❑LOG{r,23.INC Cuyahoga Falls, Ohio442� WO#: 23010842
Arraly0cal Laboralorlas TEL: [phone] FAX.- (330) 253-44E
Wehsite: httn:11www.settek.co Date: 1/24/2023
These commonly used Qualifiers and Acronyms may or may not be present in this report.
Qualifiers
U The compound was analyzed for but was not detected.
J The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
H The hold time for sample preparation and/or analysis was exceeded.
D The result is reported from a dilution.
E The result exceeded the linear range of the calibration or is estimated due to interference.
MC The result is below the Minimum Compound Limit.
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
in Manual integration was used to determine the area response.
d Manual integration in which peak was deleted
N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response.
P The second column confirmation exceeded 25% difference.
C The result has been confirmed by GUMS.
X The result was not confirmed when GUMS Analysis was performed.
B/MB+ The analyte was detected in the associated blank.
G The ICB or CCB contained reportable amounts of analyte.
QC-/+ The CCV recovery failed low () or high (+).
R/QDR The RPD was outside of accepted recovery limits.
QL-/+ The LCS or LCSD recovery failed low () or high (+).
QLR The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+ The MS or MSD recovery failed low () or high (+).
QMR The MS/MSD RPD was outside of accepted recovery limits.
QV-/+ The ICV recovery failed low () or high (+).
S The spike result was outside of accepted recovery limits.
Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for
additional information
Acronyms
ND
Not Detected
RL
Reporting Limit
QC
Quality Control
MDL
Method Detection Limit
MB
Method Blank
LOD
Level of Detection
LCS
Laboratory Control Sample
LOQ
Level of Quantitation
LCSD
Laboratory Control Sample Duplicate
PQL
Practical Quantitation Limit
QCS
Quality Control Sample
CRQL
Contract Required Quantitation Limit
DUP
Duplicate
PL
Permit Limit
MS
Matrix Spike
RegLvl
Regulatory Limit
MSD
Matrix Spike Duplicate
MCL
Maximum Contamination Limit
RPD
Relative Percent Different
MinCL
Minimum Compound Limit
ICV
Initial Calibration Verification
RA
Reanalysis
ICB
Initial Calibration Blank
RE
Reextraction
CCV
Continuing Calibration Verification
TIC
Tentatively Identified Compound
CCB
Continuing Calibration Blank
RT
Retention Time
PLC
Reporting Limit Check
CF
Calibration Factor
DF
Dilution Factor
RF
Response Factor
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Original
Page 3 of 39

�� 1 � Summit Environmental Technologies, Inc.
SU3310 Win St.
ENVIROMMEWAL YECHNO ijULES. JNG, Cuyahoga Falls, Ohio 44223
Analytical Laboralorlas TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com
CLIENT: Synagro
Project: 3rd Creek
Lab SampleID Client Sample ID
23010842-001 3rd Creek
Tag No Date Collected
1/10/2023 8:00:00 AM
Workorder
Sample Summary
WO#: 23010842
24 Jan-23
Date Received Matrix
1/13/2023 10:20:00 AM Solid
Page 4 of 39

SUMMIT
Summit Environmental Technologies, Inc.
3310 Win St.
DATES REPORT
ENVIRONMENTALTECHN❑L0G1ES,1rJG
Cuyahoga Falls, Ohio44223
WO#: 23010842
ArWyft cal tai5oralonas
TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
3rd Creek
Sample ID
Client Sample ID Collection Date Matrix Test Name Leachate Date
Prep Date Analysis Date
23010842-OOIA 3rd Creek 1/10/2023 8:00:00 AM Solid Ignitability of Solids (SW-846: 1030)
1/18/2023 7:17:11 PM
pH (SW9045D)
1/20/2023 4:11:32 PM
Reactive Cyanide (9014/7.3.32)-Solid
1/23/2023 1:45:00 PM
Reactive Sulfide (9034)/7.3.42
1/23/2023 1:45:00 PM
TCLP Herbicides by EPA 8321B
1/17/2023 5:33:00 PM
TCLP Mercury Analysis (SW1311/7471/17/2023 4:15:00 PM
1/18/2023 2:30:00 PM 1/19/2023 11:04:00 AM
TCLP Metals Analysis (SW1311/6010'1/17/2023 4:15:00 PM
1/18/2023 2:00:00 PM 1/19/2023 2:07:00 PM
TCLP Pesticides Analysis (SW1311/8(1/17/2023 4:15:00 PM
1/18/2023 10:31:44 AM 1/19/2023 6:39:00 AM
TCLP Pesticides Analysis (SW1311/8(1/17/2023 4:15:00 PM
1/18/2023 10:31:44 AM 1/19/2023 6:39:00 AM
TCLP Semi-Volatiles Analysis 1/17/2023 4:15:00 PM
1/19/2023 10:40:00 AM 1/20/2023 10:40:00 PM
(SW1311/8270)
TCLP Volatiles Analysis
1/23/2023 4:13:00 PM
Original
Page 5 of 39

SUMMIT Summit Environmental Technologies, Inc.
3310 Win St.
ENVITtONMENTALTECHNQLOGIE$,IRC Cuyahoga Falls, Ohio44223
Arralyt9cal Laboralorfas TEL: [phone] FAX. [phone]
Website: http://�i,-"-m,.settek.com
Analytical Report
(base report)
WO#: 23010842
Date Reported: 1/24/2023
CLIENT: Synagro Tag Number:
Matrix: SOLID Collection Date: 1/10/2023 8:00:00 AM
Lab ID: 23010842-OOIA
Project: 3rd Creek
Client Sample ID 3rd Creek
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP MERCURY ANALYSIS (SW1311/7470)
TCLP Mercury
ND 0.00200 mg/L
SW7470A SW7470A Analyst: ICA
1 1/19/2023 11:04:00 AM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW6010
SW301OA Analyst: RJE
TCLP METALS ANALYSIS (SW1311/6010)
TCLP Arsenic(As)
ND
0.500
mg/L
1
1/19/2023 2:07:00 PM
TCLP Barium(Ba)
ND
5.00
mg/L
1
1/19/2023 2:07:00 PM
TCLP Cadmium(Ccl)
ND
0.100
mg/L
1
1/19/2023 2:07:00 PM
TCLP Chromium(Cr)
ND
0.200
mg/L
1
1/19/2023 2:07:00 PM
TCLP Lead(Pb)
ND
0.500
mg/L
1
1/19/2023 2:07:00 PM
TCLP Selenium(Se)
ND
0.0500
mg/L
1
1/19/2023 2:07:00 PM
TCLP Silver(Ag)
ND
0.500
mg/L
1
1/19/2023 2:07:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8270
SW351OC Analyst: JAP
TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270)
1,4-Dichlorobenzene
ND
0.100
mg/L
1
1/20/2023 10:40:00 PM
2,4,5-Trichlorophenol
ND
0.250
mg/L
1
1/20/2023 10:40:00 PM
2,4,6-Trichlorophenol
ND
0.250
mg/L
1
1/20/2023 10:40:00 PM
2,4-Dinitrotoluene
ND
0.0500
mg/L
1
1/20/2023 10:40:00 PM
Cresols, Total
ND
5.00
mg/L
1
1/20/2023 10:40:00 PM
Hexachloro-1,3-butadiene
ND
0.0200
mg/L
1
1/20/2023 10:40:00 PM
Hexachlorobenzene
ND
0.0500
mg/L
1
1/20/2023 10:40:00 PM
Hexachloroethane
ND
0.100
mg/L
1
1/20/2023 10:40:00 PM
Nitrobenzene
ND
0.100
mg/L
1
1/20/2023 10:40:00 PM
Pentachlorophenol
ND
0.250
mg/L
1
1/20/2023 10:40:00 PM
Pyridine
ND
0.250
QC- mg/L
1
1/20/2023 10:40:00 PM
Surr: 2-Fluorophenol
68.9
10- 157
%Rec
1
1/20/2023 10:40:00 PM
Surr: Phenol-d6
76.1
10 - 169
%Rec
1
1/20/2023 10:40:00 PM
Surr: Nitrobenzene-d5
66.9
32.1 - 130
%Rec
1
1/20/2023 10:40:00 PM
Surr: 2,4,6-Tribromophenol
102
45.4 - 166
%Rec
1
1/20/2023 10:40:00 PM
Surr: 2-Fluorobiphenyl
75.0
35.7 - 130
%Rec
1
1/20/2023 10:40:00 PM
Surr: p-Terphenyl-d14
92.2
70 - 145
%Rec
1
1/20/2023 10:40:00 PM
Qualifiers: B Analyte detected in the associated Method Blank
E Value above quantitation range
H Holding times for preparation or
analysis exceeded
M Manual Integration
used to determine area response
MC Value is below Minimum Compound
Limit.
N Tentatively identified compounds
ND Not Detected
OGI
P Second column confirmation exceeds
PL Permit Limit
Origin
R RPD outside accepted recovery limits
RL Reporting Detection Limit
Page 6 of 39

SUMMIT Summit Environmental Technologies, Inc.
3310 Win St.
ENVITtONMENTALTECHNQLOGIE$,IRC Cuyahoga Falls, Ohio44223
Arrafyt9caf Laboralorfas TEL: [phone] FAX. [phone]
Website: http://�i,-"-m,.settek.com
Analytical Report
(base report)
WO#: 23010842
Date Reported: 1/24/2023
CLIENT: Synagro Tag Number:
Matrix: SOLID Collection Date: 1/10/2023 8:00:00 AM
Lab ID: 23010842-OOIA
Project: 3rd Creek
Client Sample ID 3rd Creek
Analyses
Result
RL
Qual Units
DF
Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8081
SW351OC Analyst: PGP
TCLP PESTICIDES ANALYSIS
(SW1311/8081)
Chlordane, total
ND
0.0125
mg/L
5
1/19/2023 6:39:00 AM
Toxaphene
ND
0.0250
mg/L
5
1/19/2023 6:39:00 AM
Endrin
ND
0.00250
mg/L
5
1/19/2023 6:39:00 AM
gamma-BHC
ND
0.00250
mg/L
5
1/19/2023 6:39:00 AM
Heptachlor
ND
0.00250
mg/L
5
1/19/2023 6:39:00 AM
Heptachlor epoxide
ND
0.00250
mg/L
5
1/19/2023 6:39:00 AM
Methoxychlor
ND
0.00250
mg/L
5
1/19/2023 6:39:00 AM
Surr: TCMX
83.6
10 - 119
%Rec
5
1/19/2023 6:39:00 AM
Surr: DCB
79.7
10 - 119
%Rec
5
1/19/2023 6:39:00 AM
TCLP HERBICIDES BY EPA 8321B
SW8321
Analyst: SRA
2,4-D
ND
0.500
mg/L
50
1/17/2023 5:33:00 PM
2,4,5-TP
ND
0.500
mg/L
50
1/17/2023 5:33:00 PM
Surr: 2,4-Dichlorophenylacetic aci
100
70 - 130
%Rec
50
1/17/2023 5:33:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8260
Analyst: EMB
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene
ND
0.100
QC+ mg/L
20
1/23/2023 4:13:00 PM
1,2-Dichloroethane
ND
0.100
mg/L
20
1/23/2023 4:13:00 PM
MEK
ND
2.00
mg/L
20
1/23/2023 4:13:00 PM
Benzene
ND
0.100
mg/L
20
1/23/2023 4:13:00 PM
Carbon tetrachloride
ND
0.100
mg/L
20
1/23/2023 4:13:00 PM
Chlorobenzene
ND
1.00
mg/L
20
1/23/2023 4:13:00 PM
Chloroform
ND
0.100
mg/L
20
1/23/2023 4:13:00 PM
Tetrachloroethene
ND
0.100
mg/L
20
1/23/2023 4:13:00 PM
Trichloroethene
ND
0.100
mg/L
20
1/23/2023 4:13:00 PM
Vinyl chloride
ND
0.0400QC+QL+mg/L
20
1/23/2023 4:13:00 PM
Surr: 4-Bromofluorobenzene
88.9
70 - 130
%Rec
20
1/23/2023 4:13:00 PM
Surr: Dibrom ofluorom ethane
98.2
70 - 130
%Rec
20
1/23/2023 4:13:00 PM
Surr: Toluene-d8
106
70 - 130
%Rec
20
1/23/2023 4:13:00 PM
Qualifiers: B Analyte detected in the associated Method Blank
E Value above quantitation range
H Holding times for preparation or analysis exceeded
M Manual Integration
used to determine area response
MC Value is below Minimum Compound Limit.
N Tentatively identified compounds
ND Not Detected
OGI
P Second column confirmation exceeds
PL Permit Limit
Origin
R RPD outside accepted recovery
limits
RL Reporting Detection Limit
Page 7 of 39

MMIT
Summit Environmental Technologies, Inc. Analytical Report
SU3310 Win St.
ENVI110NMENTAL1rECHNQL0G4E$,IRC Cuyahoga Falls, Ohio44223 (base report)
Arrafyt9caf Laboralorfas TEL: [phone] FAX. [phone] WO#: 23010842
Website: http://www.settek.com Date Reported: 1/24/2023
CLIENT: Synagro Tag Number:
Matrix: SOLID Collection Date: 1/10/2023 8:00:00 AM
Lab ID: 23010842-OOIA
Project: 3rd Creek
Client Sample ID 3rd Creek
Analyses
Result
RL Qual Units
DF
Date Analyzed
RCI
SW9014
Analyst: MS
REACTIVE CYANIDE (9014/7.3.3.2)-SOLID
Cyanide, Reactive
ND
0.485 mg/Kg
1
1/23/2023 1:45:00 PM
IGNITABILITY OF SOLIDS (SW-846: 1030)
SW1030
Analyst: SMZ
Ignitability Non-flammable
mm/sec
1
1/18/2023 7:17:11 PM
RCI
SW9045D
Analyst: SMZ
PH (SW9045D)
pH
7.2
s.u.@20.8C
1
1/20/2023 4:11:32 PM
RCI
SW9034
Analyst: MS
REACTIVE SULFIDE (9034)/7.3.4.2
Sulfide, Reactive
ND
25.0 mg/Kg
1
1/23/2023 1:45:00 PM
Qualifiers: B
Analyte detected in the associated Method Blank
E
Value above quantitation range
H
Holding times for preparation or analysis exceeded
M
Manual Integration used to determine area response
MC
Value is below Minimum Compound Limit.
N
Tentatively identified compounds
ND
Not Detected
OGI
P
Second column confirmation exceeds
PL
Permit Limit Origin
R
RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 8 of 39

Summit Environmental Technologies, Inc.
Accreditation
Program
SUMMIEF
fr3310 Win St.
Analv n tes Report
ENwIROMMEWALYECHNOL.OG{r,S,INC
Cuyahoga Falls, Ohio44223
J
Y
Arraly0cal Laboralorlas
TEL: [phone] FAX.- [phone]
WO#:
23010842
Wehsite: http://www.settek.com
24 Jan-23
Client: Synagro
State: NW
Project: 3rd Creek
Program Name: NC_WW_SCM
Sample ID Matrix
Test Name
Analyte
Status
23010842-OOIA Solid
Ignitability of Solids (SW-846: 1030)
Ignitability
A
Solid
pH (SW9045D)
Hydrogen Ion (pH)
A
Solid
Reactive Cyanide (9014/7.3.32)-Solid
Cyanide, Reactive
U
Solid
Reactive Sulfide (9034)/7.3.42
Sulfide, Reactive
U
Solid
TCLP Herbicides by EPA 832113
2,4,5-TP
A
Solid
TCLP Herbicides by EPA 832113
2,4-D
A
Solid
TCLP Mercury Analysis (SW1311/7470)
Mercury
A
Solid
TCLP Metals Analysis (SW1311/6010)
Arsenic
A
Solid
TCLP Metals Analysis (SW1311/6010)
Barium
A
Solid
TCLP Metals Analysis (SW1311/6010)
Cadmium
A
Solid
TCLP Metals Analysis (SW1311/6010)
Chromium
A
Solid
TCLP Metals Analysis (SW1311/6010)
Lead
A
Solid
TCLP Metals Analysis (SW1311/6010)
Selenium
A
Solid
TCLP Metals Analysis (SW1311/6010)
Silver
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
Chlordane, total
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
Endrin
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
gamma-BHC
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
Heptachlor
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
Heptachlor epoxide
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
Methoxychlor
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
Toxaphene
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
1,4-Dichlorobenzene
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4,5-Trichlorophenol
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4,6-Trichlorophenol
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4-Dinitrotoluene
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Cresols, Total
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Hexachlorobenzene
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Hexachlorobutadiene
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Hexachloroethane
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Nitrobenzene
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Pentachlorophenol
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Pyridine
A
Original # 1
Page 9 of 39

Summit Environmental Technologies, Inc.
Accreditation
Program
SUMMIEF
fr3310 Win St.
Anal�7n tes Report
ENVIROMMEWAL IrECHHOL,t
01ES, INC Cuyahoga Falls, Ohio 44223
J
Y
Arraly0cal Laboralorlas
TEL: [phone] FAX.- [phone]
WO#:
23010842
Wehsite: http://www.settek.com
24 Jan-23
Client: Synagro
State: NW
Project: 3rd Creek
Program Name: NC_WW_SCM
Sample ID Matrix
Test Name
Analyte
Status
23010842-OOIA Solid
TCLP Volatiles Analysis
1,1-Dichloroethene
A
Solid
TCLP Volatiles Analysis
1,2-Dichloroethane
A
Solid
TCLP Volatiles Analysis
2-Butanone
A
Solid
TCLP Volatiles Analysis
Benzene
A
Solid
TCLP Volatiles Analysis
Carbon tetrachloride
A
Solid
TCLP Volatiles Analysis
Chlorobenzene
A
Solid
TCLP Volatiles Analysis
Chloroform
A
Solid
TCLP Volatiles Analysis
Tetrachloroethene
A
Solid
TCLP Volatiles Analysis
Trichloroethene
A
Solid
TCLP Volatiles Analysis
Vinyl chloride
A
Original # 1
Page 10 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO Lggir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010842
24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: 62279
Sample ID: MB-62279
SampType: MBLK
TestCode: TCLP-SVOC- Units: mg/L
Prep Date: 1/18/2023
RunNo: 156731
Client ID: PBS
Batch ID: 62279
TestNo: SW8081 SW3510C
Analysis Date: 1/18/2023
SegNo: 4172749
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Chlordane, total
ND
0.00250
Toxaphene
ND
0.00500
Endrin
ND
0.000500
gamma-BHC
ND
0.000500
Heptachlor
ND
0.000500
Heptachlor epoxide
ND
0.000500
Methoxychlor
ND
0.000500
Surr: TCMX
11.7
Surr: DCB
11.6
20.00 58.4 10 119
20.00 57.8 10 119
d
d
d
d
d
Sample ID: LCS-62279
SampType: LCS
TestCode: TCLP-SVOC- Units: mg/L
Prep Date: 1/18/2023
RunNo: 156731
Client ID: LCSS
Batch ID: 62279
TestNo: SW8081 SW3510C
Analysis Date: 1/18/2023
SegNo: 4172750
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Chlordane, tot
Toxaphene
Endrin
gamma-BHC
Heptachlor
Heptachlor epo
Methoxychlor
Surr: TCMX
Qualifiers:
al 0.0183 0.0
ND 0.0
0.0108 0.00
0.00848 0.00
0.0103 0.00
xide 0.00917 0.00
0.0114 0.00
12.0
B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
0250 0 0 70
0500 0 0 70
0500 0.0100 0 108 10
0500 0.0100 0 84.8 10
0500 0.0100 0 103 10
0500 0.0100 0 91.7 10
0500 0.0100 0 114 10
20.00 60.1 10
E Value above quantitation range
M Manual Integration used to determine area response
OGI
R RPD outside accepted recovery limits
130
130
130
130
130
130
178
130
H Holding times for preparation or anal)
MC Value is below Minimum Compound
P Second column confirmation exceeds
RL Reporting Detection Limit
Original
Page 11 of 39
B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
0250 0 0 70
0500 0 0 70
0500 0.0100 0 108 10
0500 0.0100 0 84.8 10
0500 0.0100 0 103 10
0500 0.0100 0 91.7 10
0500 0.0100 0 114 10
20.00 60.1 10
E Value above quantitation range
M Manual Integration used to determine area response
OGI
R RPD outside accepted recovery limits
130
130
130
130
130
130
178
130
H Holding times for preparation or anal)
MC Value is below Minimum Compound
P Second column confirmation exceeds
RL Reporting Detection Limit
Original
Page 11 of 39
130
130
130
130
130
130
178
130
H Holding times for preparation or anal)
MC Value is below Minimum Compound
P Second column confirmation exceeds
RL Reporting Detection Limit
Original
Page 11 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010842
24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: 62279
Sample ID: LCS-62279
SampType: LCS
TestCode: TCLP-SVOC- Units: mg/L
Prep Date: 1/18/2023
RunNo: 156731
'.Iient ID: LCSS
Batch ID: 62279
TestNo: SW8081 SW3510C
Analysis Date: 1/18/2023
SegNo: 4172750
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Surr: DCB
8.64
20.00
43.2 10 130
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGI P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 12 of 39

MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT
SU3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010842
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://www.settek.com 24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: 62288
Sample ID: 23010844-001AMS
SampType: MS
TestCode: MTL-TCLP-7( Units: mg/L
Prep Date: 1/18/2023
RunNo: 156724
Client ID: BatchQC
Batch ID: 62288
TestNo: SW6010 SW3010A
Analysis Date: 1/19/2023
SegNo: 4174124
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
TCLP Arsenic(As)
2.06
0.500
2.000
0
103
70
130
TCLP Barium(Ba)
ND
5.00
2.000
0.1455
100
70
130
TCLP Cadmium(Cd)
1.78
0.100
2.000
0
89.2
70
130
TCLP Chromium(Cr)
1.81
0.200
2.000
0.002100
90.3
70
130
TCLP Lead(Pb)
1.81
0.500
2.000
0
90.4
70
130
TCLP Selenium(Se)
1.98
0.0500
2.000
0
99.1
70
130
TCLP Silver(Ag)
2.06
0.500
2.000
0
103
70
130
Sample ID: 23010844-001AMSD
SampType: MSD
TestCode: MTL-TCLP-7( Units: mg/L
Prep Date: 1/18/2023
RunNo: 156724
Client ID: BatchQC
Batch ID: 62288
TestNo: SW6010 SW3010A
Analysis Date: 1/19/2023
SegNo: 4174125
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
TCLP Arsenic(As)
1.96
0.500
2.000
0
98.2
70
130
2.058
4.72
20
TCLP Barium(Ba)
ND
5.00
2.000
0.1455
95.0
70
130
0
0
20
TCLP Cadmium(Cd)
1.71
0.100
2.000
0
85.5
70
130
1.784
4.22
20
TCLP Chromium(Cr)
1.72
0.200
2.000
0.002100
85.8
70
130
1.807
5.08
20
TCLP Lead(Pb)
1.73
0.500
2.000
0
86.6
70
130
1.809
4.34
20
TCLP Selenium(Se)
1.90
0.0500
2.000
0
94.9
70
130
1.982
4.35
20
TCLP Silver(Ag)
1.96
0.500
2.000
0
98.2
70
130
2.056
4.63
20
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 13 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010842
24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: 62288
Sample ID: MB-62288
SampType: MBLK
TestCode: MTL-TCLP-7( Units: mg/L
Prep Date: 1/18/2023
RunNo: 156724
Client ID: PBS
Batch ID: 62288
TestNo: SW6010 SW3010A
Analysis Date: 1/19/2023
SegNo: 4173032
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
TCLP Arsenic(As)
ND
0.100
TCLP Barium(Ba)
ND
5.00
TCLP Cadmium(Cd)
ND
0.100
TCLP Chromium(Cr)
ND
0.200
TCLP Lead(Pb)
ND
0.100
TCLP Selenium(Se)
ND
0.100
TCLP Silver(Ag)
ND
0.100
Sample ID: LCS-62288
SampType: LCS
TestCode: MTL-TCLP-7( Units: mg/L
Prep Date: 1/18/2023
RunNo: 156724
Client ID: LCSS
Batch ID: 62288
TestNo: SW6010 SW3010A
Analysis Date: 1/19/2023
SegNo: 4173033
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
TCLP Arsenic(As)
2.14
0.100
2.000
0
107
80
120
TCLP Barium(Ba)
ND
5.00
2.000
0
103
80
120
TCLP Cadmium(Cd)
2.01
0.100
2.000
0
100
80
120
TCLP Chromium(Cr)
2.03
0.200
2.000
0
101
80
120
TCLP Lead(Pb)
2.04
0.100
2.000
0
102
80
120
TCLP Selenium(Se)
1.97
0.100
2.000
0
98.6
80
120
TCLP Silver(Ag)
2.11
0.100
2.000
0
106
80
120
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 14 of 39

SUMM' T
Summit Environmental Technologies, Inc.
3310 Win St.
QC SUMMARY REPORT
ENVIRONMEWAL I ECHNO LQgir,-3, INC
Cuyahoga Falls, Ohio 44223
WO#: 23010842
4rrafyt�cal iaboralorfas
TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
3rd Creek
BatchID: 62305
TCLP Mercury ND 0.00200
TCLP Mercury 0.00407 0.00200 0.00400 0 102 80 120
TCLP Mercury 0.00413 0.00200 0.00400 0.0000230 103 75 125
Sample ID: 23010844-001AMSD
SampType: MSD
TestCode: HG_TCLP(74 Units: PPM
Prep Date: 1/18/2023
RunNo: 156722
Client ID: BatchQC
Batch ID: 62305
TestNo: SW7470A SW7470A
Analysis Date: 1/19/2023
SegNo: 4172607
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
TCLP Mercury 0.00419 0.00200
0.00400 0.0000230 104 75
125
0.00413 1.44 20
Qualifiers: B Analyte detected in the associated Method Blank
E Value above quantitation range
H
Holding times for preparation or anal)
J Analyte detected below quantitation limits
M Manual Integration used to determine area response
MC
Value is below Minimum Compound
Original
ND Not Detected
OGl
P
Second column confirmation exceeds
PL Permit Limit
R RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 15 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
Client: Synagro
Project: 3rd Creek BatchID: 62305
WO#: 23010842
24-Jan-23
Sample ID: 23010844-001AMSD
SampType: MSD
TestCode: HG_TCLP(74 Units: PPM
Prep Date: 1/18/2023
RunNo: 156722
Dient ID: BatchQC
Batch ID: 62305
TestNo: SW7470A SW7470A
Analysis Date: 1/19/2023
SegNo: 4172607
4nalyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGI P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 16 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
Client: Synagro
Project: 3rd Creek BatchID: 62313
WO#: 23010842
24-Jan-23
Sample ID: 23010844-001AMS
SampType: MS
TestCode: TCLP-SVOC_ Units: mg/L
Prep Date: 1/19/2023
RunNo: 156871
Dient ID: BatchQC
Batch ID: 62313
TestNo: SW8270 SW3510C
Analysis Date: 1/20/2023
SegNo: 4175972
4nalyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1,4-Dichlorobenzene
0.475
0.100
0.8000
0
59.4
15.2
124
2,4,5-Trichlorophenol
0.802
0.250
0.8000
0
100
30.6
152
2,4,6-Trichlorophenol
0.815
0.250
0.8000
0
102
27.6
150
2,4-Dinitrotoluene
0.760
0.0500
0.8000
0
95.0
58
141
o-Cresol
0.654
0.250
0.8000
0
81.8
26.9
132
Cresols, Total
ND
5.00
1.600
0
83.4
27.6
132
Hexachloro-1,3-butadiene
0.533
0.0200
0.8000
0
66.6
10
156
Hexachlorobenzene
0.742
0.0500
0.8000
0
92.8
54.3
142
Hexachloroethane
0.465
0.100
0.8000
0
58.1
1.92
131
Nitrobenzene
0.653
0.100
0.8000
0
81.6
21
135
Pentachlorophenol
0.762
0.250
0.8000
0
95.2
47.4
134
Pyridine
0.422
0.250
0.8000
0
52.7
10
130
Surr:2-Fluorophenol
0.726
1.000
72.6
9.77
146
Surr: Phenol-d6
0.758
1.000
75.8
20.7
130
Surr: Nitrobenzene-d5
0.646
1.000
64.6
13.9
156
Surr:2,4,6-Tribromophenol
1.08
1.000
108
27.3
183
Surr:2-Fluorobiphenyl
0.709
1.000
70.9
21.4
153
Surr: p-Terphenyl-d14
0.883
1.000
88.3
54.8
154
QC -
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 17 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
Client: Synagro
Project: 3rd Creek BatchID: 62313
WO#: 23010842
24-Jan-23
Sample ID: 23010844-001AMSD
SampType: MSD
TestCode: TCLP-SVOC_ Units: mg/L
Prep Date: 1/19/2023
RunNo: 156871
Dient ID: BatchQC
Batch ID: 62313
TestNo: SW8270 SW3510C
Analysis Date: 1/20/2023
SegNo: 4175973
4nalyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1,4-Dichlorobenzene
0.470
0.100
0.8000
0
58.8
15.2
124
0.4750
1.06
30
2,4,5-Trichlorophenol
0.857
0.250
0.8000
0
107
30.6
152
0.8018
6.70
30
2,4,6-Trichlorophenol
0.872
0.250
0.8000
0
109
27.6
150
0.8152
6.71
30
2,4-Dinitrotoluene
0.827
0.0500
0.8000
0
103
58
141
0.7602
8.39
30
o-Cresol
0.686
0.250
0.8000
0
85.8
26.9
132
0.6544
4.74
30
Cresols, Total
ND
5.00
1.600
0
88.5
27.6
132
0
0
30
Hexachloro-1,3-butadiene
0.540
0.0200
0.8000
0
67.5
10
156
0.5330
1.27
30
Hexachlorobenzene
0.832
0.0500
0.8000
0
104
54.3
142
0.7424
11.4
30
Hexachloroethane
0.460
0.100
0.8000
0
57.5
1.92
131
0.4650
1.08
30
Nitrobenzene
0.668
0.100
0.8000
0
83.5
21
135
0.6528
2.27
30
Pentachlorophenol
0.846
0.250
0.8000
0
106
47.4
134
0.7618
10.5
30
Pyridine
0.416
0.250
0.8000
0
52.0
10
130
0.4218
1.43
30
Surr:2-Fluorophenol
0.705
1.000
70.5
9.77
146
0
Surr: Phenol-d6
0.806
1.000
80.6
20.7
130
0
Surr: Nitrobenzene-d5
0.693
1.000
69.3
13.9
156
0
Surr:2,4,6-Tribromophenol
1.16
1.000
116
27.3
183
0
Surr:2-Fluorobiphenyl
0.794
1.000
79.4
21.4
153
0
Surr: p-Terphenyl-d14
0.950
1.000
95.0
54.8
154
0
QC -
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGI P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 18 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010842
24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: 62313
Sample ID: MB-62313
SampType: MBLK
TestCode: SVOC-BNA_T Units: mg/L
Prep Date: 1/19/2023
RunNo: 156871
'.Iient ID: PBS
Batch ID: 62313
TestNo: SW8270 SW3510C
Analysis Date: 1/20/2023
SegNo: 4175949
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1,4-Dichlorobenzene
ND
0.0250
2,4,5-Trichlorophenol
ND
0.0250
2,4,6-Trichlorophenol
ND
0.0250
2,4-Dinitrotoluene
ND
0.0250
o-Cresol
ND
0.250
Cresols, Total
ND
0.0500
Hexachloro-1,3-butadiene
ND
0.0250
Hexachlorobenzene
ND
0.0250
Hexachloroethane
ND
0.0250
Nitrobenzene
ND
0.0250
Pentachlorophenol
ND
0.0250
Pyridine
ND
0.0250
Surr: 2-Fluorophenol
0.735
Surr: Phenol-d6
0.858
Surr: Nitrobenzene-d5
0.727
Surr: 2,4,6-Tribromophenol
1.03
Surr: 2-Fluorobiphenyl
0.800
Surr: p-Terphenyl-d14
1.02
1.000
73.5
10
135
1.000
85.8
10
161
1.000
72.7
16.8
150
1.000
103
32.5
179
1.000
80.0
34
133
1.000
102
60.8
163
QC -
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGI P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 19 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010842
24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: 62313
Sample ID: LCS-62313
SampType: LCS
TestCode: SVOC-BNA_T Units: mg/L
Prep Date: 1/19/2023
RunNo: 156871
'.Iient ID: LCSS
Batch ID: 62313
TestNo: SW8270 SW3510C
Analysis Date: 1/20/2023
SegNo: 4175950
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1,4-Dichlorobenzene
0.463
0.0250
0.8000
0
57.8
35
130
2,4,5-Trichlorophenol
0.858
0.0250
0.8000
0
107
44
144
2,4,6-Trichlorophenol
0.873
0.0250
0.8000
0
109
45
141
2,4-Dinitrotoluene
0.845
0.0250
0.8000
0
106
56
136
o-Cresol
0.729
0.250
0.8000
0
91.1
36
134
Cresols, Total
1.48
0.0500
1.600
0
92.5
36
135
Hexachloro-1,3-butadiene
0.547
0.0250
0.8000
0
68.4
30
130
Hexachlorobenzene
0.825
0.0250
0.8000
0
103
58
130
Hexachloroethane
0.448
0.0250
0.8000
0
56.0
28
130
Nitrobenzene
0.698
0.0250
0.8000
0
87.3
39
133
Pentachlorophenol
0.849
0.0250
0.8000
0
106
33
151
Pyridine
0.191
0.0250
0.8000
0
23.9
10
130
Surr: 2-Fluorophenol
0.742
1.000
74.2
10
135
Surr: Phenol-d6
0.844
1.000
84.4
10
161
Surr: Nitrobenzene-d5
0.739
1.000
73.9
16.8
150
Surr:2,4,6-Tribromophenol
1.20
1.000
120
32.5
179
Surr:2-Fluorobiphenyl
0.834
1.000
83.4
34
133
Surr: p-Terphenyl-d14
0.963
1.000
96.3
60.8
163
QC -
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 20 of 39

SUMMIT
Summit Environmental Technologies, Inc.
3310 Wm St.
QC SUMMARY REPORT
ENVIRONMEWAL I ECHNO Lggir,-3, INC
Cuyahoga Falls, Ohio 44223
WO#: 23010842
4rrafyt�cal iaboralorlas
TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
3rd Creek
BatchID: R156631
2,4-D ND 0.0100
2,4,5-TP ND 0.0100
Surr: 2,4-Dichlorophenylacetic acid 0.945 1.000 94.5 70 130
2,4-D
0.0195
0.0100 0.01000
0 195
50
150 S
2,4,5-TP
ND
0.0100 0.01000
0 83.0
50
150
Surr: 2,4-Dichlorophenylacetic acid
0.00850
0.01000
85.0
70
130
Sample ID: LCS TCLP 0.3 ppm
SampType: LCS
TestCode: TCLP-SVOC- Units: mg/L
Prep Date:
RunNo: 156631
Client ID: LCSS
Batch ID: R156631
TestNo: SW8321
Analysis Date: 1/17/2023
SegNo: 4170273
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
2,4-D
0.302 0.0100
0.3000 0 101 60.5
141
2,4,5-TP
0.287 0.0100
0.3000 0 95.7 68.3
144
Surr: 2,4-Dichlorophenylacetic acid 0.287
0.3000 95.5 70
130
Qualifiers: B
Analyte detected in the associated Method Blank
E Value above quantitation range
H
Holding times for preparation or anal}
J
Analyte detected below quantitation limits
M Manual Integration used to determine area response
MC
Value is below Minimum Compound
Original
ND
Not Detected
OGl
P
Second column confirmation exceeds
PL
Permit Limit
R RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 21 of 39

MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT
SU3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010842
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://www.settek.com 24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: R156631
Sample ID: LCSD TCLP 0.3 ppm SampType:
LCSD
TestCode: TCLP-SVOC- Units: mg/L
Prep Date:
RunNo: 156631
Client ID: LCSS02 Batch ID:
R156631
TestNo: SW8321
Analysis Date: 1/17/2023
SegNo: 4170274
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
2,4-D 0.296 0.0100 0.3000 0 98.8 60.5 141 0.3023 2.00 30
2,4,5-TP 0.278 0.0100 0.3000 0 92.8 68.3 144 0.2872 3.08 30
Surr: 2,4-Dichlorophenylacetic acid 0.279 0.3000 93.1 70 130 0 0
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGI P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 22 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010842
24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: R156695
Sample ID: LCS-R156695
SampType: LCS
TestCode: Ignitability_S Units: mm/sec
Prep Date:
RunNo: 156695
Client ID: LCSS
Batch ID: R156695
TestNo: SW1030
Analysis Date: 1/18/2023
SegNo: 4171894
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Ignitability
7.69
7.240 0 106 70 130
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 23 of 39

SUMM' T
Summit Environmental Technologies, Inc.
3310 Win St.
QC SUMMARY REPORT
ENVIRONMEWAL I ECHNO LQgir,-3, INC
Cuyahoga Falls, Ohio 44223
WO#: 23010842
4rrafyt�cal iaboralorfas
TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
3rd Creek
BatchID: R156838
pH 7.0 7.0 0 100 90 110
pH 12.5 0 0 0 0 12.5 0.2 10
pH 7.0 7.0 0 100 90 110
Sample ID: 23011173-001ADUP
SampType: DUP
TestCode: pH_S(9045D) Units: s.u.@20.5C
Prep Date:
RunNo: 156838
Client ID: BatchQC
Batch ID: R156838
TestNo: SW9045D
Analysis Date: 1/20/2023
SegNo: 4175312
Analyte
Result
PQL SPK value SPK Ref Val %REC
Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
pH 6.5 0 0 0 0 6.4 0.6 10
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGI P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 24 of 39

SUMM' T
Summit Environmental Technologies, Inc.
3310 Win St.
QC SUMMARY REPORT
ENVIRONMEWAL I ECHNO LQgir,-3, INC
Cuyahoga Falls, Ohio 44223
WO#: 23010842
4rrafyt�cal iaboralorfas
TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
3rd Creek
BatchID: R156838
pH 7.0 7.0 0 100 90 110
pH 7.6 0 0 0 0 7.6 0 10
Sample ID: LCS-R156838
SampType: LCS
TestCode: pH_S(9045D) Units: s.u.@20.5C
Prep Date:
RunNo: 156838
Client ID: LCSS
Batch ID: R156838
TestNo: SW9045D
Analysis Date: 1/20/2023
SegNo: 4175326
Analyte
Result
PQL SPK value SPK Ref Val %REC
LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Qual
pH 7.0
7.0 0 101 90
110
Qualifiers: B Analyte detected in the associated Method Blank
E Value above quantitation range
H
Holding times for preparation or anal)
J Analyte detected below quantitation limits
M Manual Integration used to determine area response
MC
Value is below Minimum Compound
Original
ND Not Detected
OGI
P
Second column confirmation exceeds
PL Permit Limit
R RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 25 of 39

SUMM' T
Summit Environmental Technologies, Inc.
3310 Win St.
QC SUMMARY REPORT
ENVIRONMEWAL I ECHNO LQgir,-3, INC
Cuyahoga Falls, Ohio 44223
WO#: 23010842
4rrafyt�cal iaboralorfas
TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
3rd Creek
BatchID: R156838
pH 7.0 7.0 0 100 98.6 101.4
pH 6.9 6.9 0.4 5 H
pH 7.0 7.0 0 100 98.6 101.4
Sample ID: 23010912-001ADUP
SampType: DUP
TestCode: pH_NPW(450 Units: s.u.@19.7C
Prep Date:
RunNo: 156838
Client ID: BatchQC
Batch ID: R156838
TestNo: SW9045D
Analysis Date: 1/20/2023
SegNo: 4175285
Analyte
Result
PQL SPK value SPK Ref Val %REC
Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
pH 6.3 6.3 0.5 5 H
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 26 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010842
24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: R156838
Sample ID: 23010912-001ADUP
SampType: DUP
TestCode: pH_NPW(450 Units: s.u.@19.7C
Prep Date:
RunNo: 156838
Dient ID: BatchQC
Batch ID: R156838
TestNo: SW9045D
Analysis Date: 1/20/2023
SegNo: 4175285
4nalyte
Result
PQL SPK value SPK Ref Val %REC
Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 27 of 39

SUMM' T
Summit Environmental Technologies, Inc.
3310 Win St.
QC SUMMARY REPORT
ENVIRONMEWAL I ECHNO LQgir,-3, INC
Cuyahoga Falls, Ohio 44223
WO#: 23010842
4rrafyt�cal iaboralorfas
TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
3rd Creek
BatchID: R156913
Cyanide, Reactive ND 0.495
Cyanide, Reactive 9.17 0.500 10.00 0 91.7 85 115
Cyanide, Reactive ND 0.481 0.5000 0 62.0 50 150
Sample ID: 23010840-001AMS
SampType: MS
TestCode: Cyanide,Rea Units: mg/Kg
Prep Date:
RunNo: 156913
Client ID: BatchQC
Batch ID: R156913
TestNo: SW9014
Analysis Date: 1/23/2023
SegNo: 4176952
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Cyanide, Reactive
7.77 0.495
10.00 0 77.7 75
125
Qualifiers: B
Analyte detected in the associated Method Blank
E Value above quantitation range
H
Holding times for preparation or anal)
J
Analyte detected below quantitation limits
M Manual Integration used to determine area response
MC
Value is below Minimum Compound
Original
ND
Not Detected
OGI
P
Second column confirmation exceeds
PL
Permit Limit
R RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 28 of 39

MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT
SU3310 Win St.
ENVIRONMEWAL I ECHNO Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010842
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://www.settek.com 24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: R156913
Sample ID: 23010840-001AMS
SampType: MS
TestCode: Cyanide,Rea Units: mg/Kg
Prep Date:
RunNo: 156913
Client ID: BatchQC
Batch ID: R156913
TestNo: SW9014
Analysis Date: 1/23/2023
SegNo: 4176952
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Sample ID: 23010840-001AMSD
SampType: MSD
TestCode: Cyanide,Rea Units: mg/Kg
Prep Date:
RunNo: 156913
Client ID: BatchQC
Batch ID: R156913
TestNo: SW9014
Analysis Date: 1/23/2023
SegNo: 4176953
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Cyanide, Reactive 8.43 0.495 10.00 0 84.3 75 125 7.772 8.19 10
Qualifiers: B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
E Value above quantitation range H Holding times for preparation or anal)
M Manual Integration used to determine area response MC Value is below Minimum Compound
OGI P Second column confirmation exceeds
R RPD outside accepted recovery limits RL Reporting Detection Limit
Original
Page 29 of 39

SUMMIT Summit Environmental Technologies, Inc. QC SUMMARY REPORT
3310 Wm St.
ENVIRONMEWAL I ECHNO Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010842
4rrafyt�cal iaboralorlas TEL: [phone] FAX.- [phone]
Website: http://www.settek.com 24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: R156917
Sample ID: 23010840-001AMS
SampType: MS
TestCode: Sulfide,React Units: mg/Kg
Prep Date:
RunNo: 156917
Client ID: Batch=
Batch ID: R156917
TestNo: SW9034
Analysis Date: 1/23/2023
SegNo: 4177055
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Sulfide, Reactive 1590 25.0 1710 0 93.0 80 120
Sample ID: 23010840-001AMSD
SampType: MSD
TestCode: Sulfide,React Units: mg/Kg
Prep Date:
RunNo: 156917
Client ID: Batch=
Batch ID: R156917
TestNo: SW9034
Analysis Date: 1/23/2023
SegNo: 4177056
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Sulfide, Reactive 1660 25.0 1710 0 97.1 80 120 1590 4.31 30
Qualifiers: B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
E Value above quantitation range H Holding times for preparation or anal}
M Manual Integration used to determine area response MC Value is below Minimum Compound
OGl P Second column confirmation exceeds
R RPD outside accepted recovery limits RL Reporting Detection Limit
Original
Page 30 of 39

MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT
SU3310 Win St.
ENVIRONMEWAL I ECHNO Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010842
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://www.settek.com 24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: R156917
Sample ID: MB-R156917
SampType: MBLK
TestCode: Sulfide,React Units: mg/L
Prep Date:
RunNo: 156917
Client ID: PBW
Batch ID: R156917
TestNo: SW9034
Analysis Date: 1/23/2023
SegNo: 4177039
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Sulfide, Reactive ND 25.0
Sample ID: LCS-R156917
SampType: LCS
TestCode: Sulfide,React Units: mg/L
Prep Date:
RunNo: 156917
Client ID: LCSW
Batch ID: R156917
TestNo: SW9034
Analysis Date: 1/23/2023
SegNo: 4177040
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Sulfide, Reactive
1670 25.0 1710 0 97.7 85 115
Qualifiers: B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
E Value above quantitation range H Holding times for preparation or anal)
M Manual Integration used to determine area response MC Value is below Minimum Compound
OGl P Second column confirmation exceeds
R RPD outside accepted recovery limits RL Reporting Detection Limit
Original
Page 31 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010842
24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: R156931
Sample ID: LCS
SampType: LCS
TestCode: VOC-MSTR_ Units: mg/L
Prep Date:
RunNo: 156931
Client ID: LCSW
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177590
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1, 1 -Dichloroethene
0.0238
0.00500
0.0200
0
119
49
161 QC+
1,2-Dichloroethane
0.0206
0.00500
0.0200
0
103
48
151
MEK
0.124
0.0250
0.100
0
124
10
190
Benzene
0.0222
0.00500
0.0200
0
ill
34
169
Carbon tetrachloride
0.0203
0.00500
0.0200
0
101
76
134
Chlorobenzene
0.0200
0.00500
0.0200
0
99.8
54
144
Chloroform
0.0203
0.00500
0.0200
0
102
70
130
Tetrachloroethene
0.0189
0.00500
0.0200
0
94.4
66
134
Trichloroethene
0.0201
0.00500
0.0200
0
101
70
136
Vinyl chloride
0.0340
0.00200
0.0200
0
170
49
136 SQC+
Surr:4-Bromofluorobenzene
46.9
50.00
93.8
70
130
Surr: Di bromofluorom ethane
49.8
50.00
99.7
70
130
Surr: Toluene-d8
53.1
50.00
106
70
130
Sample ID: MBLK
SampType: MBLK
TestCode: VOC-MSTR_ Units: mg/L
Prep Date:
RunNo: 156931
Client ID: PBW
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177592
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1, 1 -Dichloroethene
ND
0.00500
QC+
1,2-Dichloroethane
ND
0.00500
MEK
ND
0.0250
Benzene
ND
0.00500
Qualifiers: B
Analyte detected in the associated Method Blank E Value above quantitation range
H Holding times for preparation or anal)
J
Analyte detected below quantitation limits
M Manual Integration used to determine area response
MC Value is below Minimum Compound
Original
ND
Not Detected
OGI
P Second column confirmation exceeds
PL
Permit Limit
R RPD outside accepted recovery limits
RL Reporting Detection Limit
Page 32 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010842
24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: R156931
Sample ID: MBLK
SampType: MBLK
TestCode: VOC-MSTR_ Units: mg/L
Prep Date:
RunNo: 156931
Client ID: PBW
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177592
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Carbon tetrachloride
ND
0.00500
Chlorobenzene
ND
0.00500
Chloroform
ND
0.00500
Tetrachloroethene
ND
0.00500
Trichloroethene
ND
0.00500
Vinyl chloride
ND
0.00200
Surr: 4-Bromofluorobenzene
45.5
Surr: Di bromofluorom ethane
49.9
Surr: Toluene-d8
53.4
50.00 91.0 70 130
50.00 99.7 70 130
50.00 107 70 130
QC+
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGI P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 33 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010842
24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: R156931
Sample ID: 23010928-001AMS
SampType: MS
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177602
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1, 1 -Dichloroethene
0.461
0.100
0.400
0
115
13.6
202 QC+
1,2-Dichloroethane
0.372
0.100
0.400
0
93.0
55.7
138
MEK
ND
2.00
2.00
0
88.6
65.3
130
Benzene
0.438
0.100
0.400
0
110
49.2
145
Carbon tetrachloride
0.375
0.100
0.400
0
93.6
26.7
156
Chlorobenzene
ND
1.00
0.400
0
96.2
33.7
159
Chloroform
0.384
0.100
0.400
0
96.0
48.5
145
Tetrachloroethene
0.359
0.100
0.400
0
89.8
19.2
191
Trichloroethene
0.376
0.100
0.400
0
94.0
38.4
167
Vinyl chloride
0.605
0.0400
0.400
0
151
27.3
161 QL+QC+
Surr:4-Bromofluorobenzene
928
1000
92.8
70
130
Surr: Di bromofluorom ethane
982
1000
98.2
70
130
Surr: Toluene-d8
1040
1000
104
70
130
Sample ID: 23010928-001AMSD
SampType: MSD
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177603
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1, 1 -Dichloroethene
0.471 0.100
0.400 0 118
13.6
202
0.461 2.23
25 QC+
1,2-Dichloroethane
0.393 0.100
0.400 0 98.2
55.7
138
0.372 5.39
25
MEK
ND 2.00
2.00 0 94.1
65.3
130
0 0
25
Benzene
0.441 0.100
0.400 0 110
49.2
145
0.438 0.683
25
Qualifiers: B
Analyte detected in the associated Method Blank
E
Value above quantitation range
H
Holding times for preparation or anal)
J
Analyte detected below quantitation limits
M
Manual Integration used to determine area
response
MC
Value is below Minimum Compound
Original
ND
Not Detected
OGI
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 34 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010842
24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: R156931
Sample ID: 23010928-001AMSD
SampType: MSD
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177603
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Carbon tetrachloride
0.389
0.100
0.400
0
97.2
26.7
156
0.375
3.72
25
Chlorobenzene
ND
1.00
0.400
0
102
33.7
159
0
0
25
Chloroform
0.395
0.100
0.400
0
98.8
48.5
145
0.384
2.93
25
Tetrachloroethene
0.377
0.100
0.400
0
94.2
19.2
191
0.359
4.79
25
Trichloroethene
0.389
0.100
0.400
0
97.3
38.4
167
0.376
3.40
25
Vinyl chloride
0.601
0.0400
0.400
0
150
27.3
161
0.605
0.630
25 QL+QC+
Surr:4-Bromofluorobenzene
920
1000
92.0
70
130
0
25
Surr: Di bromofluorom ethane
999
1000
99.9
70
130
0
25
Surr: Toluene-d8
1050
1000
105
70
130
0
25
Sample ID: 23011160-001AMS
SampType: MS
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177606
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1, 1 -Dichloroethene
0.449
0.100
0.400 0 112
13.6
202
QC+
1,2-Dichloroethane
0.343
0.100
0.400 0 85.7
55.7
138
MEK
ND
2.00
2.00 0 75.9
65.3
130
Benzene
0.416
0.100
0.400 0 104
49.2
145
Carbon tetrachloride
0.367
0.100
0.400 0 91.8
26.7
156
Chlorobenzene
ND
1.00
0.400 0 95.2
33.7
159
Chloroform
0.374
0.100
0.400 0 93.4
48.5
145
Tetrachloroethene
0.345
0.100
0.400 0 86.2
19.2
191
Qualifiers: B
Analyte detected in the associated Method Blank
E
Value above quantitation range
H
Holding times for preparation or anal)
J
Analyte detected below quantitation limits
M
Manual Integration used to determine area
response
MC
Value is below Minimum Compound
Original
ND
Not Detected
OGI
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 35 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010842
24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: R156931
Sample ID: 23011160-001AMS
SampType: MS
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177606
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Trichloroethene
0.360 0.100
0.400
0 90.1
38.4
167
Vinyl chloride
0.610 0.0400
0.400
0 153
27.3
161 QL+QC+
Surr:4-Bromofluorobenzene
918
1000
91.8
70
130
Surr: Di bromofluorom ethane
974
1000
97.4
70
130
Surr: Toluene-d8
1060
1000
106
70
130
Sample ID: 23011160-001AMSD
SampType: MSD
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177607
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1, 1 -Dichloroethene
0.459
0.100
0.400 0
115
13.6
202
0.449 2.29
25 QC+
1,2-Dichloroethane
0.368
0.100
0.400 0
92.1
55.7
138
0.343 7.20
25
MEK
ND
2.00
2.00 0
89.8
65.3
130
0 0
25
Benzene
0.428
0.100
0.400 0
107
49.2
145
0.416 2.70
25
Carbon tetrachloride
0.372
0.100
0.400 0
92.9
26.7
156
0.367 1.19
25
Chlorobenzene
ND
1.00
0.400 0
93.1
33.7
159
0 0
25
Chloroform
0.379
0.100
0.400 0
94.8
48.5
145
0.374 1.54
25
Tetrachloroethene
0.344
0.100
0.400 0
86.1
19.2
191
0.345 0.116
25
Trichloroethene
0.366
0.100
0.400 0
91.6
38.4
167
0.360 1.60
25
Vinyl chloride
0.633
0.0400
0.400 0
158
27.3
161
0.610 3.64
25 QL+QC+
Surr:4-Bromofluorobenzene
905
1000
90.5
70
130
0
25
Surr: Di bromofluorom ethane 987
1000
98.7
70
130
0
25
Qualifiers: B
Analyte detected in the associated Method Blank
E
Value above quantitation range
H
Holding times for preparation or anal)
J
Analyte detected below quantitation limits
M
Manual Integration used to determine area
response
MC
Value is below Minimum Compound
Original
ND
Not Detected
OGI
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery
limits
RL
Reporting Detection Limit
Page 36 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010842
24-Jan-23
Client: Synagro
Project: 3rd Creek BatchID: R156931
Sample ID: 23011160-001AMSD
SampType: MSD
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177607
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Surr: Toluene-d8
1040
W
104 70 130
0 25
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 37 of 39

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Page 38 of 39

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMENTAL TECHN❑L4Ga1�S.IfiC Cuyahoga Falls, Ohio44223 Sample Log -In Check List
Arrafocal Laboralorias TEL: [phone] FAX.- [phone]
Website: http://`h,,",m,.settek.com
Client Name: SYN-NC-27028 Work Order Number: 23010842 RcptNo: 1
Logged by: Anthony W. Britton 1/13/2023 10:20:00 AM�
Completed By: Anthony W. Britton 1/13/2023 6:16:55 PM
Reviewed By: Jennifer Woolf 1/16/2023 4:18:40 PM
Chain of Custody
1. Is Chain of Custody complete? Yes ❑d No ❑ Not Present ❑
2. How was the sample delivered? UPS
Log In
3. Coolers are present? Yes ❑d No ❑ NA ❑
4. Shipping container/cooler in good condition?
Yes
d❑
No
❑
Custody seals intact on shipping container/cooler?
Yes
❑
No
❑
Not Present V
No. Seal Date:
Signed By:
5. Was an attempt made to cool the samples?
Yes
❑d
No
❑
NA ❑
6. Were all samples received at a temperature of >0° C to 6.0°C
Yes
❑d
No
❑
NA ❑
7. Sample(s) in proper container(s)?
Yes
❑d
No
❑
8. Sufficient sample volume for indicated test(s)?
Yes
❑d
No
❑
9. Are samples (except VOA and ONG) properly preserved?
Yes
❑d
No
❑
10. Was preservative added to bottles?
Yes
❑
No
❑d
NA ❑
1 1 . Is the headspace in the VOA vials less than 1/4 inch or 6 mm?
Yes
❑
No
❑ No VOA Vials ❑�
12. Were any sample containers received broken?
Yes
❑
No
❑d
13. Does paperwork match bottle labels?
Yes
No
❑
(Note discrepancies on chain of custody)
14. Are matrices correctly identified on Chain of Custody?
Yes
❑
No
❑d
15. Is it clear what analyses were requested?
Yes
❑d
No
❑
16. Were all holding times able to be met?
Yes
No
❑
(If no, notify customer for authorization.)
Special Handling (if applicable)
17. Was client notified of all discrepancies with this order?
Yes
❑
No
❑ NA V
Person Notified: Date:
By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person
Regarding:
Client Instructions:
18. Additional remarks:
Cooler Information
Cooler No
Temp °C
Condition
I Seal Intact
Seal No
Seal Date
Signed By
1
15.0
Goodl
Not Present
Page 39 of 39

State of North Carolina
DWR
Department of Environmental Quality
Division of Water Resources
Division of Water Resources LAND APPLICATION SITE CERTIFICATION
INSTRUCTIONS FOR FORM: LASC 06-16
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and
supporting documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit
General — This certification provides detailed information of receiving sites for land application of Class B residuals (may include
water treatment plant or other type residuals) in accordance with 15A NCAC 02T .1100. Do not submit this certification for review
without a corresponding application form (FORM: RLAP 06-16 or FORM: SDR 06-16).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Land Application Site Certification (FORM: LASC 06-16):
❑ Submit the completed and appropriately executed Land Application Site Certification (FORM: LASC 06-16) form. Please
do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments
to the application may be made, as long as the attachments are numbered to correspond to the section and item to which they
refer.
❑ For new or renewed permits, submit the requested information for all land application sites.
❑ For modified permits, submit the requested information for only those sites that are new, transferred or affected by the
proposed modification.
B. Land Application Site Information:
❑ The status of the land application site with respect to this residuals land application program must be provided in table I. The
status categories and their corresponding codes are as follows:
♦ New (N) ♦ Renewed (R) ♦ Modified (M) ♦ Transferred (T) ♦ Deleted (D)
❑ Attach the following in accordance with each status code:
Status Code
Required Item
N
R
T
M
County Board
Notification.doc
Land Owner
Agreement
(If applicable)
Setback Waiver
Agreement
An updated vicinity/setback map in accordance with the "Man Guidance
for Residuals Land Application Permits"
✓
✓
✓
A soils and agronomic evaluation in accordance with the "Soil Scientist
✓
Evaluation Policy"
INSTRUCTIONS FOR FORM: LASC 06-16 Page 1 of 3

An updated accounting of the land application site's cumulative
pollutant loading rates (CPLRs)
Status Code
Required Item
N
R
T
M
For previously permitted sites without a soil series name indicated in the
Attachment B, submit County Soil Survey Map (or equivalent) clearly
indicate the location of the land application site and in accordance with
the soil map requirements in the "Soil Scientist Evaluation Policy"
Acknowledgement of field transfer from Land Owner (Fields may not
be permitted to multiple Permittees over the same timeperiod)
* This item may be required for land application site with a status code "M', please contact the Division if you need assistant in
determining attachment requirements.
❑ Crop Type should include the most likely crop types for the life of the permit (five years).
❑ Predominant Soils Series Name must be either the name of the soil indicated in Attachment `B" of the existing permit, or
name of the soil series as provided by the licensed soil scientist.
❑ Predominant Soil Mapping Unit or Representative Slope: Either the Soil Mapping Unit or the representative slope of each
site must be provided. The predominant soil -mapping unit must be consistent with the predominant soil series name. Please
note that the soil mapping units are variable between Counties, so care should be taken in properly identifying the correct
mapping unit. If a representative slope is provided, it must be determined accordingly:
❑ For sites previously permitted for use, but do not have an established soil mapping unit (the mapping unit provides
information on both the soil series name and the slope of the soil), the Applicant may determine the representative slope
by using the average slope provided in the County Soil Survey (or equivalent). A soil type with a slope range of 4 - 8%
would have a representative slope of 6%.
❑ New Sites to be permitted must have slopes determined as part of the soils report prepared by a licensed soil scientist.
❑ Acceptable methods for determining location coordinates (i.e., latitude and longitude) and their corresponding codes are as
follows:
• Address Matching (ADD) • Digital or Raw Photo Extraction (EXT)
• Aerial Photography with Ground Control (AER) • Geodetic Quality GPS Survey (GEO)
• Cadastral Survey (SUR) • LORAN-C Navigation Device (LOR)
• Conversion from Coordinate Plane (CP) • Navigation Quality GPS (GPS)
• Conversion from Township -Section -Range (TSR) • Remote Sensing (RS)
• Conversion from Universal Trans Mere (UTM) • Zip Code Centroid (ZIP)
• Map Interpretation by Digital or Manual Extraction (MAP)
C. Waterbody and Classifications Information: (new sites only)
❑ Use an 8.5 by 11-inch copy of the portion of a 7.5-minute USGS Topographic Map to identify the location where the
residuals program activities are planned to occur as well as the closest downslope surface waters as clearly as possible. Each
map portion must be labeled with the map name and number, the identified location, and be of clear and reproducible quality.
❑ Surface water body classifications information may be found at: http:Hdeg.nc.gov/about/divisions/water-
resources/planning/classification-standards/classifications
❑ Any questions concerning the waterbody and its classification, please contact the Division's regional offices.
❑ A list of the Division's regional offices, their county coverage, and their contact information may be downloaded at:
hLtp:Hdeg.nc.gov/contact/regional-offices
❑ General Instructions: There are 17 river basins in North Carolina. Each basin has associated waterbodies with assigned
subbasins, location descriptions, stream index numbers and established classifications.
1. Identify the project area on a 7.5 minute USGS topographical map (an 8.5 x 11-inch sheet showing the project area
should be submitted with the permit application regardless of whether a Stream classification was completed).
2. Determine the names of all the closest down slope surface waters from the project site. For unnamed tributaries, see
Table 1: Unnamed Tributaries Entering Other States or for Specific Basin Areas. Label any unnamed tributaries as
"UT to stream name" as the waterbody name.
3. Open the link hLtp:Hdeg.nc.gov/about/divisions/water-resources/planning/classification-standards/classifications.
❑ Stream Classification Process: One of the options below may be used depending on the known initial project information.
❑ KNOWN BASIN WHERE CLOSEST DOWN SLOPE SURFACE WATER IS LOCATED
1. Select proper basin from the List all Waterbodies in Basin sorted report. Sort hydrologically as this will provide
the proper location descriptions if multiple runs.
INSTRUCTIONS FOR FORM: LASC 06-16 Page 2 of 3

2. Locate the name of the identified waterbody (from General Directions) on the list.
3. For multiple listings of the same waterbody name in the report, select and verify the location description. The term
"source" in the description means the beginning of the waterbody segment (most upstream point).
4. Record all Basins, Stream Index Numbers and Classifications applicable to the project.
❑ KNOWN COUNTY WHERE CLOSEST DOWN SLOPE SURFACE WATER IS LOCATED
1. Select the proper county from the List all Waterbodies in county, hydrologically report.
2. Locate the name of the identified waterbody (from General Directions) on the list.
3. For multiple listings of the same waterbody name in the report, select and verify the location description. The term
"source" in the description means the beginning of the waterbody segment (most upstream point).
4. Record all Basins, Stream Index Numbers and Classifications applicable to the project.
❑ UNKNOWN BASIN WHERE CLOSEST DOWN SLOPE SURFACE WATER IS LOCATED
1. Use the Clickable basin map to hydrologically sorted list report.
2. Click on the approximate project location to bring up the hydrologically sorted list.
3. Locate the name of the identified waterbody (from General Directions) on the list.
4. For multiple listings of the same waterbody name in the report, select and verify the location description. The tern
"source" in the description means the beginning of the waterbody segment (most upstream point).
5. Record all Basins, Stream Index Numbers and Classifications applicable to the project.
❑ Notes on index number and unnamed streams:
Unnamed Streams 15A NCAC 02B .0301(i).
❑ Any stream which is not named in the schedule of stream classifications carries the same classification as that assigned
to the stream segment to which it is tributary (at the point of entry) except:
(A) unnamed streams specifically described in the schedule of classifications;
(B) unnamed freshwaters tributary to tidal saltwaters will be classified "C"; or
(C) after November 1, 1986, any newly created areas of tidal saltwater which are connected to Class SA waters by
approved dredging projects will be classified "SC" unless case -by -case reclassification proceedings are conducted.
❑ The following river basins have different policies for unnamed streams entering other states or for specific areas of the
basin:
Unnamed Tributaries Entering Other States or for Specific Basin Areas
Hiwassee River Basin
Streams entering Georgia or Tennessee shall be classified "C Tr."
Little Tennesse River
Basin And Savannah
River Drainage Area
Streams entering Georgia or Tennessee shall be classified "C Tr." Such streams in the Savannah
River drainage area entering South Carolina shall be classified 'B Tr."
French Broad River
Basin
Streams entering Tennessee will be classified 'B."
Watauga River Basin
Streams entering the State of Tennessee are classified "C."
Broad River Basin
Streams entering South Carolina are classified "C."
New River Basin
Streams entering the State of Tennessee are classified "C."
Catawba River Basin
Streams entering South Carolina are classified "C."
Yadkin -Pee Dee River
Basin
Streams entering Virginia are classified "C," and such streams entering South Carolina are
classified "C."
Lumber River Basin
Streams entering South Carolina are classified "C Sw."
Roanoke River Basin
Streams entering Virginia are classified "C." Except that all backwaters of John H. Kerr
Reservoir and the North Carolina portion of streams tributary thereto not otherwise named or
described shall carry the classification 'B," and all backwaters of Lake Gaston and the North
Carolina portion of streams tributary thereto not otherwise named or described shall carry the
classification "C and B."
Chowan River Basin
Streams entering Virginia are classified "C."
Tar -Pamlico River
Basin
All drainage canals not noted in the schedule are classified "C Sw." except the main drainage
canals to Pamlico Sound and its bays which shall be classified "SC."
Pas uotank River Basin
All drainage canals not noted in the schedule are classified "C."
INSTRUCTIONS FOR FORM: LASC 06-16 Page 3 of 3

LAND APPLICATION SITE CERTIFICATION
Applicant's name:
Land application sites currently certified: `net acres and Total to be certified: _ net acres.
L LAND APPLICATION SITE INFORMATION (See Instruction B):
Status
Codes
Site/Field
ID
Landowners
O
Lessees or Operator(s)
O
Net Acres
County
Crop(s) s
PO
Predominant Soil
Series Nameb
Mapping Unit
or Rep. Slope°
R
02
City of Statesville
3d Creek WWTP
14.10
Iredell
Fescue
Cecil
CeB2 2-6%
N
I E
N
PPM
N
N
r
N
N
N
0011
a Status Code for land application sites are: ♦ N (New) ♦ R (Renewed) ♦ M (Modified) ♦ T (Transferred) ♦ D (Deleted)
b Soil Series Name (i.e. Appling, Cecil, etc.)
Mapping Unit must be consistent with those used in the County Soil Survey (i.e. for a 2-8% slope Cecil in Anson County the mapping unit is CeB2)
IL WATERBODY AND CLASSIFICATIONS INFORMATION (See Instruction C):
Site/Field ID
Latitude
Longitude
Location
Datum
Location Method Code
Location Accuracy
Waterbody Subbasin and
Stream Index No.
Current and Proposed
p
Class
02
350 44' 24"
800 50' 24"
NAD 83
ADD
Nearest Second
03-07-06/03040102
C
C
_
00 Ell "
00 O'."
NAD 83
ADD
Nearest Second
W
_
°.', "
7°.'Ell
NAD 83
ADD
Nearest Second
IN
_
d°.', "
0 O'."
NAD 83
ADD
Nearest Second
IN
_
.° PM' W "
410.'."
NAD 83
ADD
Nearest Second
IN
_
`° 'ff_dO
El Ell
NAD 83
ADD
Nearest Second
IN
_
101 '
00 O'."
NAD 83
ADD
Nearest Second
IN
_
S° &"
00 O'."
NAD 83
ADD
Nearest Second
IN
Note: Please keep the site information (I.) and waterbody information (II.) of the same field on the same page.
FORM: LASC 06-16 Page 1

State of North Carolina
DWR
Department of Environmental Quality
Division of Water Resources
Division of Water Resources 15A NCAC 02T .1100 — RESIDUALS LAND APPLICATION PROGRAM
INSTRUCTIONS FOR FORM: RLAP 06-16 & SUPPORTING DOCUMENTATION
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and
sunnorting documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit
General — This application is for treatment, storage, transport, and/or land application of Class B residuals (may include residuals that
are generated from a water treatment plant or other type facilities) on the proposed or currently approved land application site(s) under
15A NCAC 02T .1100.
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Residuals Land Application Program (FORM: RLAP 06-16) Application: (All Application Packages):
Submit the completed and appropriately executed Residuals Land Application Program (FORM: RLAP 06-16) form. Please
do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to
the application may be made, as long as the attachments are numbered to correspond to the section and item to which they
refer.
The Applicant's Certification on Page 5 of this form shall be signed in accordance with 15A NCAC 02T .0106(b). An alternate
person may be designated as the signing official if a delegation letter is provided from a person who meets the criteria in 15A
NCAC 02T .0106(b).
❑ If this project is for a modification of an existing permit, submit one copy of the existing permit.
❑ Please submit this application form at least 180 days prior to the expiration date on the existing permit, or 90 days prior to
operation of proposed facility(ies) for application packages involving new or changes to treatment and storage units.
B. Application Fee (New and Major Modification Application Packages)
❑ Submit a check, money order or electronic funds transfer made payable to: North Carolina Department of Environmental
Quality (NCDEQ).
Facility Classification New Permit Major Modification'
Major (land are permitted for > 300 acres) F $1,310 F $395
Minor (land are permitted for < 300 acres) F_ $810 $245
' - A major modification shall be defined as any permit modification that: increases the generating facility's residuals dry tonnage;
adds additional land application areas not previously approved for that particular program [including transferring of field(s) from
one program to another]; adds additional residuals sources; or includes the addition of new treatment or storage units/processes not
previously permitted. There is no fee for minor modifications to a permit.
C. Cover Letter (All Application Packages)
❑ List all items included in the application package, as well as a brief description of the requested permitting action.
D. Environmental Assessments (Maybe Required —See 15A NCAC 1C .03
❑ Submit a copy of the Findings of No Significant Impact (FONSI) or Environmental Impact Statement (EIS). Also, include
information on any mitigating factor(s) from the Environmental Assessment (EA) that impact the construction of the residuals
treatment and storage facilities. An EA may also be required for private systems if any public funds and/or lands are used for
the construction of the subject facilities.
INSTRUCTIONS FOR FORM: RLAP 06-16 Page 1 of 3

E. Operation and Maintenance Plan (New and Renewal Application Packages)
❑ For Modification Application, if there are any changes to the existing plan, submit an updated O&M plan.
❑ Submit the O&M Plan in accordance with 15A NCAC 02T .1110 and include at a minimum:
❑ Operational functions; describe the operation of the program to show what operations are necessary for the program to
function and by whom the functions are to be conducted.
❑ Maintenance schedules; may include equipment calibration, maintenance of signs, etc.
❑ Safety measures; may include safety training program, manuals, signs, etc.
❑ Spill response plan; including control, containment, remediation, emergency contact information, etc.
❑ Inspection plan including the following information;
❑ Names and titles of personnel responsible for conducting the inspections.
❑ Frequency and location of inspections, including those to be conducted by the ORC, and procedures to assure that the
selected location(s) and inspection frequency are representative of the residuals management program.
❑ Detailed description of inspection procedures including record keeping and actions to be taken by the inspector in the event
that noncompliance is observed.
❑ Sampling and monitoring plan including the following information;
❑ Names and titles of personnel responsible for conducting the sampling and monitoring.
❑ Detailed description of monitoring procedures including parameters to be monitored.
❑ Sampling frequency and procedures to assure that representative samples are being collected. Fluctuation in temperature,
flow, and other operating conditions can affect the quality of the residuals gathered during a particular sampling event. The
sampling plan shall account for any foreseen fluctuations in residuals quality and indicate the most limiting times for
residuals to meet pathogen and vector attraction reduction requirements (e.g. facilities that land apply multiple times per
year but have an annual sampling frequency, may need to sample during winter months when pathogen reduction is most
likely to be negatively affected by cold temperatures.
THE FOLLOWING ADDITIONAL ITEMS (G to M) ARE REQUIRED FOR DEDICATED PROGRAM ONLY.
F. Program Determination
❑ Dedicated residuals land application programs are ones in which land application sites meet the criteria in 15A NCAC 02T
.110202). Specifically, a residuals land application program is designated as dedicated if any of the following are applicable:
❑ Any land application site certified for the residuals land application program that receives residuals at rates or frequencies
greater than agronomic rates.
❑ Any land application site certified for the residuals land application program that is used primarily for residuals disposal,
and agricultural crop production is of secondary importance.
❑ Any land application site certified for the residuals land application program that receives residuals through fixed irrigation
facilities or irrigation facilities fed through a fixed supply system.
❑ Please contact the Non -Discharge Permitting Unit if you need any assistance in determining whether your residuals program
falls under the dedicated program definitions.
G. Program Information
Q Provide an explanation of why a dedicated system is required instead of a conventional non -dedicated system.
❑ Provide an explanation of the dedicated system and its operation.
H. Detailed Site Maps (All New or Modification Application Packages)
❑ Submit three (3) sets of standard size plans and two (2) sets of I I" by 17" plans (electronic format is acceptable - Adobe PDF
only). For Modifications, submit plans specific to the modification(s) only.
❑ Plans must include the following minimum items:
❑ A general location map, a vicinity map and a topographic map with contours not exceeding 10 feet or 25% of the total site
relief and showing all facility related structures and fences within the land application area.
❑ The location of all wells (including usage and construction details if available), streams (ephemeral, intermittent, and
perennial), springs, lakes, ponds, and other surface drainage features within 500 feet of the land application site(s).
❑ Delineation of the review and compliance boundaries
❑ Setbacks as required by 15A NCAC 02T .1108
❑ Site property boundaries within 500 feet of all waste treatment, storage, and disposal site(s).
❑ A map showing the entire irrigation area with an overlay of the suitable irrigation area depicted by the soil scientist's
evaluation. The irrigation plans shall show each nozzle/emitter and wetted area (when applicable). Clearly label spray
irrigation zones as they will be operated.
❑ Plans must depict a completed design and not be labeled with preliminary phrases (e.g., FOR REVIEW ONLY, NOT FOR
CONSTRUCTION, etc.) that indicate that they are anything other than final plans. However, the plans may be labeled with
the phrase: FINAL DESIGN - NOT RELEASED FOR CONSTRUCTION
INSTRUCTIONS FOR FORM: RLAP 06-16 Page 2 of 3

I. Project Evaluation and Receiver Site Management Plan (All New Application Packages or Modifications that include new sites)
❑ Submit a project evaluation and a receiver site management plan (if applicable) with recommendations concerning cover crops
and their ability to accept the proposed application rates.
J. Hydrogeologic Report (All New Application Packages or Modifications involving increasing the total design capacity)
❑ Submit a detailed hydrogeologic evaluation in accordance with 15A NCAC 02T .1104(d)(4) and current Division Policy
available at: http://www.ncwater.org/Rules_ Policies_ and_Regulations/. The document shall be signed, sealed and dated by a
qualified professional.
K. Engineering Design Documents (All New or Modification Application Packages with fixed irrigation facilities or irrigation
facilities fed through fixed supply system)
❑ Submit engineering design documents that have been signed, sealed, and dated by a NC licensed Professional Engineer and/or
Professional Land Surveyor in accordance with 15A NCAC 02T . 1104(d)(2). For Modifications, submit an updated site map
specific to the modification(s) only.
❑ The design documents must include the following minimum items:
❑ Engineering plans for the facility and equipment except those previously permitted unless they are directly tied into the new
units or are critical to the understanding of the complete process;
❑ Specifications describing materials to be used, method of construction, and means for ensuring quality and integrity of the
finished product including leaking testing; and
❑ Engineering calculations including hydraulic and pollutant loading, sizing criteria, hydraulic profile, total dynamic head
curve analysis for each pump, and irrigation design.
❑ Soil mapping units shown on all disposal sites.
L. Water Balance (All New Application Packages or Modifications that include new sites utilizing fixed irrigation facilities or
irrigation facilities fed through fixed supply systems)
❑ Submit a completed and accurate water balance in accordance with 15A NCAC 02T .1104(d)(5) and current Division Policy
available at: http://www.ncwater.org/Rules_ Policies_ and Regulations/.
M. Property Ownership Documentation (All New or Modification Application Packages involving new and/or relocated treatment
or irrigation components)
❑ Property ownership documentation shall consist of one of the following:
❑ Legal documentation of ownership (i.e., GIS, deed or article of incorporation), or
❑ Written notarized intent to purchase agreement signed by both parties with a plat or survey map, or
n An easement running with the land specifically indicating the intended use of the property and meeting the requirements of
15A NCAC 02L .0107(f), or
❑ A written notarized lease agreement signed by both parties, indicating the intended use of the property, as well as a plat or
survey map.
ONE ORIGINAL AND TWO COPIES OF THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL
SUPPORTING INFORMATION AND MATERIALS, SHALL BE SENT TO THE FOLLOWING ADDRESS:
NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY
DIVISION OF WATER RESOURCES
WATER QUALITY PERMITTING SECTION
NON -DISCHARGE PERMITTING UNIT
By U.S. Postal Service:
1617 MAIL SERVICE CENTER
RALEIGH, NORTH CAROLINA 27699-1617
TELEPHONE NUMBER: [phone]
By Courier/Special Delivery:
512 N. SALISBURY STREET
RALEIGH, NORTH CAROLINA 27604
FAX NUMBER: [phone]
INSTRUCTIONS FOR FORM: RLAP 06-16 Page 3 of 3

State of North Carolina
DWR
Department of Environmental Quality
Division of Water Resources
Division of Water Resources 15A NCAC 02T .1100 — RESIDUALS LAND APPLICATION PROGRAM
FORM: RLAP 06-16
I. APPLICANT INFORMATION:
1. Applicant's name: City of Statesville
Applicant type: ❑ Individual ❑ Corporation ❑ General Partnership Privately -Owned Public Utility
❑ Federal 0 State ® Municipal E7 County
Signature authority's name per 15A NCAC 02T .0106: Ken Galloway Title: 4'i' Creek WWTP Supervisor
Applicant's mailing address: PO Box I I I I
City: Statesville State: NC Zip: 28687-1111
Telephone number: [phone] Email Address: kgallowaykstatesvillenc.net
2. Consultant's name: M License Number (for P.E.): _
Affiliation: ❑ On Staff ❑ Retained (Firm: )
Consultant's mailing address:
City: State:
Zip: �-
Telephone number: (_) _ _"
Email Address:
3. Agronomist's name:
License Number:
Affiliation: ❑ N/A ❑i On Staff
0 Retained (Firm:
Agronomist's mailing address: —1
City: State:
Zip: W-no
Telephone number: (_) _
Email Address: _
4. Soil Scientist's name: _�
License Number: 7V
Affiliation: ❑ N/A q On Staff
0 Retained (Firm: )
Soil Scientist's mailing address:
City: State:
Zip: E__-_AE
Telephone number: (_) =
Email Address: _
5. Fee submitted: I (See Instruction B)
IL PERMIT INFORMATION:
1. Application is for (check all that apply): 0 new, ❑ modified, ® renewed permit
2. If this application is being submitted to renew or modify an existing permit, provide the following:
Permit number: W00014543
Date of most -recently issued permit: March 1, 2019
Date of most -recently certified Attachment A (if different than the permit): d
Date of most -recently certified Attachment B (if different than the permit): _
FORM: RLAP 06-16 Page 1 of 5

III. RESIDUALS LAND APPLICATION PROGRAM INFORMATION:
1. Residuals Processing Facility's physical address: 444 31d Creek Rd
City: Statesville State: NC Zip: 28677-,
Coordinates: Latitude: 35' 44' 24" Longitude: 80' 50' 24"
Datum: Level of accuracy:
Method of measurement: GPS
2. County where residuals land application program is headquartered:
3. List the Operator In Responsible Charge (ORC) and all Back -Up ORCs for the residuals land application program, their
certification numbers, and their affiliations in the following table:
Designation
Name
Affiliation
Certification Number
ORC
Andy Smith
City of Statesville
LA 985516
Back -Up ORC
Scott Austin
City of Statesville
LA 991939
Additional Back -Up
ORCs
(if applicable)
If an ORC and at least one Back -Up ORC are not currently designated for this residuals land application program, provide the
candidates' names, affiliations, and an estimated time schedule for each candidate's completion of the required training school
and certification test:
4. Complete the following tables regarding management of the residuals land application program:
a. Plant Available Nitrogen Summary: Determine the maximum plant available nitrogen (PAN) generated by all residuals
source -generating facilities as currently certified and proposed for certification with this application and list the results in the
following table:
Maximum amount of residuals to be certified: 500 dry tons per year.
PAN
Pounds of PAN per Dry Ton
(Weighted Average)
Pounds of PAN per Year
Surface
Incorporation
or Injection
Surface
Incorporation
or Injection
First -Year
34.8
17,400
Five -Year Maximum Adjusted
174
87,000
b. Land Application Site Use Summary: Summarize information regarding the land application sites as currently certified and
proposed for certification with this application:
Category
Use
Acres
Comments
Crops
Forest or Plantation
Row Crops
Hay
14.1
Fescue Hay
Pasture
Total:
Methods
Surface
Incorporation or Injection
Total:
FORM: RLAP 06-16 Page 2 of 5

c. Residuals Land Application Summary: Determine the minimum acreage required to land apply the residuals as currently
certified and proposed for certification assuming the scenarios listed in the following table:
Assumed
Application Rate
(lbs PAN/ac yr)
Acres Required Using
First -Year PAN Concentrations
Acres Required Using
Five -Year Maximum Adjusted PAN
Concentrations
Surface
Incorporation or
Injection
Surface
Incorporation or
Injection
50
348
1740
100
174
870
150
116
580
200
87
435
_
6. If applicable, provide a plan and a schedule to resolve any known issues that would prevent land application of the proposed
residuals due to the violation of North Carolina Administrative Code (e.g. not enough storage, not enough land, vector reduction
practices not in place, etc.): -M
7. Specify type of residuals program (See Instruction F): E Non -dedicated ❑ Dedicated
If Dedicated, specify the following (check all that apply):
Residuals program contains any land application site(s) that receives residuals at rates or frequencies greater than agronomic
rates, explain;
❑ Residuals program contains any land application site(s) that is used primarily for residuals disposal, and agricultural crop
production is of secondary importance, explain;
❑ Residuals program contains any land application site(s) that receives residuals through fixed irrigation facilities or irrigation
facilities fed through a fixed supply system, explain;
IV. RESIDUALS SOURCE INFORMATION: (Required for all new, renewed, or modified residuals source)
Complete and submit the following Residuals Source Certification and all associated documentation.
R
Residuals Source
Certification
V. LAND APPLICATION SITE INFORMATION: (Required for all new, renewed, or modified land application site)
Complete and submit the following Land Applications Site Certification and all associated documentation.
19-1
Land Application Siite
Certification. doc
FORM: RLAP 06-16 Page 3 of 5

Note: Item VI. Applicable to Dedicated Program with fixed irrigation system only.
VI. DESIGN INFORMATION FOR FIXED IRRIGATION SYSTEM
1. The irrigation system is: a Spray ❑ Drip
2. Disposal system is: ❑ existing ❑ proposed.
3. Minimum depth to mean seasonal high water table (SHWT) within irrigation sites(s) per Soil Scientist's Evaluation: feet
below ground surface. Rules 15A NCAC 02T .0505(p) requires at least one -foot vertical separation between SHWT and ground
surface.
4. Are there any artificial drainage or water movement structures within 200 feet of any irrigation area?
❑ Yes or ❑ No If Yes, please explain if the soil scientist report addresses artificial structures and please indicate if
structures are to be maintained or modified:
5. Loading rates recommended by the Soil Scientist Evaluation:
Soil Series
Fields within Soil Area
Recommended
Loading Rate
(in/hr)
Recommended
Loading Rate
in/yr
6. Design loading rates are equal or less than the loading rates recommended by Soil Scientist?
❑ Yes or ❑ No If No, explain why 15A NCAC 02T .0505(n) is not met:
7. Non -dedicated System Design (fill in the appropriate information for either a spray or drip irrigation system):
Field / Zone
Design Area
(ft2)
Number of
Nozzles
Maximum Application
Rate ( allons/hr)
Design Annual Loading
Rate ( allons/ r)
Total
Spray Irrigation Design Element
Plan Sheet
Number
Specification
Pa a Number
Wetted diameter of nozzles
ft
Wetted area of nozzles
It,
Nozzle capacity
gpm
Nozzle manufacturer / model
/
Elevation of highest nozzle
ft
FORM: RLAP 06-16 Page 4 of 5

Applicant's Certification (signing authority must be in compliance with 15A NCAC 02T .0106):
The applicant or any affiliate has not been convicted of an environmental crime, has not abandoned a wastewater facility without proper
closure, does not have an outstanding civil penalty where all appeals have been exhausted or abandoned, are compliant with any active
compliance schedule, and do not have any overdue annual fees under Rule 15A NCAC 02T .0105.
® Yes JU No, Explain;
I, Ken Galloway 4thCreek WWTP Supervisor
(Signature Authority's Name — PLEASE PRINT) (Title)
attest that this application for 3rd Creek WWTP
(Facility Name)
has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that the Division of Water Resources
may not conduct a technical review of this program and approval does not constitute a variance to any rules or statutes unless specifically
granted in the permit. Further, any discharge of residuals to surface waters or the land will result in an immediate enforcement action,
which may include civil penalties, injunctive relief, and/or criminal prosecution. I will make no claim against the Division of Water
Resources should a condition of this permit be violated. I also understand that if all required parts of this application are not completed
and that if all required supporting information and attachments are not included, this application package will be returned to me as
incomplete.
Note: In accordance with North Carolina General Statutes § 143-215.6A and § 143-215.613, any person who knowingly makes any false
statement, representation, or certification in any application shall be guilty of a Class 2 misdemeanor, which may include a fine not to
exceed $10,000 as well as civil penalties up to $25,000 per violation.
Signature:
Date:
FORM: RLAP 06-16 Page 5 of 5

State of North Carolina
DWR
Department of Environmental Quality
Division of Water Resources
Division of Water Resources RESIDUALS SOURCE CERTIFICATION
INSTRUCTIONS FOR FORM: RSC 06-16
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and
supporting documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit
General — This certification provides detailed information of residuals source generating facility and its residuals quality for land
application, distribution, or disposal in accordance with 15A NCAC 02T .1100. Do not submit this certification for review without
a corresponding application form (FORM: RLAP 11-15, FORM: DCAR 11-15, or FORM: SDR 11-15).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Residuals Source Certification (FORM: RSC 11-15):
❑ Submit the completed and appropriately executed Residuals Source Certification (FORM: RSC 11-15) form. Please do not
make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the
application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer.
❑ For new or renewed permits, submit a separate certification for each source facility.
❑ For modified permits, submit a separate certification for only those facilities that are affected by the proposed modification.
❑ Complete the residuals source facility summary page. List all new, renewed, or modified facilities.
B. Residuals Source -Generating Facility Information:
❑ For each source facility, attach the following:
❑ Vicinity map - A vicinity map that shows the location of the facility and meets all of the criteria in the "Map Guidance for
Residuals Land Application Permits".
❑ Process flow diagram and/or narrative - A detailed narrative and/or process flow diagram that describes how the residuals
are to be generated, treated, processed, and stored at the facility.
❑ Quantitative justification for residuals production rate - A quantitative justification for the value provided in Item I. 8.
Ensure that the amount of residuals listed is the maximum amount expected to be generated by the facility for the life of
the permit. In addition, ensure that this amount is equivalent to that which is actually to be land applied, distributed,
and/or disposed, including any chemicals, amendments, or other additives that are added to the residuals during
processing.
❑ Sampling plan - A detailed sampling plan for the residuals source -generating facility. Ensure that the plan identifies
sampling points, sampling frequency, sample type, as well as the Division -certified laboratory to be used. In addition,
ensure that the plan details how the facility and/or the residuals are monitored for any applicable pathogen reduction and
vector attraction reduction requirements. Note that all sampling and monitoring must be completed on the residuals as
they are to be land applied, distributed, and/or disposed.
C. Residuals Quality Information:
❑ For each source facility, attach the following:
❑ Laboratory analytical reports and operational data - reports for all laboratory analyses used to complete this certification.
❑ Documentation that the facility complies and/or the residuals comply with any applicable pathogen reduction and vector
attraction reduction requirements.
❑ For new facility that may have not yet been constructed and analytical results of residuals cannot be obtained, please
attach analytical results of residuals generated from a similar facility along with the description of similarities of the two
facilities.
INSTRUCTIONS FOR FORM: RSC 06-16 Page 1 of 1

RESIDUALS SOURCE FACILITY SUMMARY
Applicant's name: m
Status
Code
Facility Permit Holder
Facility Name
County
Permit Number
Maximum Dry Tons Per Year
Current b
Proposed
R
City of Statesville
Third Creek WWTP
Iredell
NCO020591
500
'Status Code for source facility are: ♦ N (New) ♦ R (Renewed) ♦ M (Modified) ♦ D (Deleted)
b The amount of residuals currently permitted for distribution, land application, or disposal (i.e, not applicable to new facility).
SUMMARY FOR FORM: RSC 06-16 Page 1

State of North Carolina
DWR
Department of Environmental Quality
Division of Water Resources
Division of Water Resources RESIDUALS SOURCE CERTIFICATION
FORM: RSC 06-16
I. RESIDUALS SOURCE -GENERATING FACILITY INFORMATION (See Instruction B.):
1. Facility Name: 31d Creek WWTP
2. Facility permit holder is: Federal, 0 State, 0 Local Government, or 0 Private.
Facility permit issued by: Div. of Water Resources, Div. of Environmental Health,
or Other (explain: M.
3. Facility contact person and title: Ken Galloway 4' Creek WWTP Supervisor
Complete mailing address: PO Box 1111
City: Statesville State: NC Zip: 28687-1111
Telephone number: [phone] E-mail address: kgallowaykstatesvillenc.net
4. Facility physical address: 444 Third Creek Road
City: Statesville State: NC Zip: 28677=
Coordinates: Latitude: 35' 44' 24" Longitude: 80' 50' 24"
Datum: In- Level of accuracy: _
Method of measurement: GPS
5. Purpose of the facility:
treatment of municipal wastewater, treatment of 100% domestic wastewater,
treatment of potable water, treatment of 100% industrial wastewater,
treatment of industrial wastewater mixed with domestic wastewater,
(approximate percentages: 60 % industrial and 40 % domestic)
other (explain: _ ).
6. Does the facility have an approved pretreatment program: Yes No
7. Facility permitted/design flow: 6 MGD and facility average daily flow: 09 MGD
8. Average amount of residuals being generated at this facility 500 dry tons per year.
9. Specify the following regarding treatment and storage volumes available at the facility:
Type and volume of residuals treatment: Dual 2 Meter belts
Type and volume of residuals storage (i.e., outside of residuals treatment units): 3 million gallon aerobic digester
II. RESIDUALS QUALITY INFORMATION (See Instruction C.):
1. Specify if residuals are regulated under:
40 CFR Part 503 or 40 CFR Part 257.
Note: Only residuals that are generated during domestic/municipal wastewater treatment processes are regulated under 40
CFR Part 503, otherwise, the residuals are regulated under 40 CFR Part 257.
2. Specify if residuals are defined under 15A NCAC 02T.1102(6) as:
Biological 0 Non -Biological
Note: Biological residuals are residuals that have been generated during the treatment of domestic wastewater, animal
processing wastewater, or the biological treatment of industrial wastewater (biological treatment is a system that utilizes
biological processes including lagoons, activated sludge systems, extended aeration systems, and fixed film systems).
FORM: RSC 06-16 Page 1 of 5

3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non -hazardous under
RCRA: (Note - this item does not have to be completed for facilities that are less than 0.5 MGD in design flow that treat
100% non -municipal, domestic wastewater only)
a. Are the residuals listed in 40 CFR §261.31-§261.33: 0 yes ® no.
If yes, list the number(s): _
b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21-
261.24: 0 yes 0 no.
Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as
well as those for corrosivity, ignitability, and reactivity:
Laboratory: Summit and Date of analysis: 1/19/23
Passed corrosivity test: yes 11 no. pH: s.u. (2 <pH < 12.5)
Passed ignitability test: yes ❑ no. Flashpoint: = OF (> 140°F)
Passed reactivity test: ® yes ❑no. HCN: __A mg/kg (<250) & H2S: _ mg/kg (<500)
TCLP Parameter
Limit
(mgfi)
Result
(m917)
TCLP Parameter
Limit
(m917)
Result
(mgfi)
Arsenic
5.0
<0.5
Hexachlorobenzene
0.13
<0.05
Barium
100.0
<5
Hexachloro-1,3-Butadiene
0.5
<0.02
Benzene
0.5
<0.1
Hexachloroethane
3.0
<0.1
Cadmium
1.0
<0.1
Lead
5.0
<0.5
Carbon Tetrachloride
0.5
<0.1
Lindane
0.4
Chlordane
0.03
<0.025
Mercury
0.2
<0.002
Chlorobenzene
100.0
<1
Methoxychlor
10.0
<0.0025
Chloroform
6.0
<0.1
Methyl Ethyl Ketone
200.0
<2
Chromium
5.0
<0.2
Nitrobenzene
2.0
<0.1
m-Cresol
200.0
Pentachlorophenol
100.0
<0.25
o-Cresol
200.0
Pyridine
5.0
<0.25
p-Cresol
200.0
Selenium
1.0
<0.05
Cresol
200.0
<5
Silver
5.0
<0.5
2,4-D
10.0
<0.5
Tetrachloroethylene
0.7
<0.1
1,4-Dichlorobenzene
7.5
<0.1
Toxaphene
0.5
<0.025
1,2-Dichloroethane
0.5
<0.1
Trichloroethylene
0.5
<0.1
1,1-Dichloroethylene
0.7
<0.1
2,4,5-Trichlorophenol
400.0
<0.25
2,4-Dinitrotoluene
0.13
<0.05
2,4,6-Trichlorophenol
2.0
<0.25
Endrin
0.02
<0.0025
2,4,5-TP (Silvex)
1.0
<0.5
Heptachlor and its Hydroxide
0.008
<0.0025
Vinyl Chloride
0.2
<0.04
FORM: RSC 06-16 Page 2 of 5

4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not
violate the ceiling concentrations for metals regulated under 15A NCAC 02T .1105.
a. For Distribution/Land Application: Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: Waypoint and Date of analysis: 10/3/23
Parameter
Ceiling
Concentration Limits
(ClassA & ClassB)
(mglkg)
Monthly Average
Concentration Limits
(Class A Only)
(mglkg)
Result
(mglkg)
Arsenic
75
41
4.69
Cadmium
85
39
2.62
Copper
4,300
1,500
312
Lead
840
300
22.1
Mercury
57
17
<1.02
Molybdenum
75
n/a
16
Nickel
420
420
33.9
Selenium
100
100
4.86
Zinc
7,500
2,800
701
b. For Surface Disposal Unit (landfill): Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: = and Date of analysis: =
Distance from Disposal
Unit to Boundary to
Closest Property Line
(meters, check one)
Arsenic
(mg/kg)
Chromium
(mg/kg)
Nickel
(mg/kg)
❑ > 0 but < 25
30
200
210
❑ > 25 but < 50
34
220
240
❑ > 50 but < 75
39
260
270
❑ > 75 but < 100
46
300
320
❑ > 100 but < 125
53
360
390
❑ > 125
62
450
420
Result (mg/kg)
FORM: RSC 06-16 Page 3 of 5

5. Nutrient/Micronutrient Determination: Complete the following:
a. Total solids: 17.7 %.
b. Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following nutrient and
rmcronutnent parameters:
Laboratory: Waypoint and Date of analysis: 10/3/23
Parameter
Result
(mg1kg)
Aluminum
26200
Ammonia -Nitrogen
3300
Calcium
8250
Magnesium
2540
Nitrate -Nitrite Nitrogen
39.7
pH (Standard Unit)
6.9
Phosphorus
29900
Potassium
2630
Sodium
672
Total Kjeldahl Nitrogen
55600
c. Using the results listed in Item IL 5b. above, calculate the sodium adsorption ration (SAR): 1.29
[Note: If residuals contain SAR of 10 or higher, the applicant shall obtain recommendations from the local Cooperative
Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, a
North Carolina Licensed Soil Scientist, or an agronomist, prior to land application of residuals. The recommendations shall
address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a mechanism for maintaining site integrity
and conditions conducive to crop growth].
d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: 30 %. This
rate is a (check one): JW default value, or ❑ actually established.
If the residuals are not generated from the treatment of municipal or domestic wastewater, ex lain or provide technical
justification as to why the selected default value is appropriate to be applied to these residuals:
e. Calculate the PAN for the residuals (i.e., on a dry weight basis) and fill the results in the following table:
Application Method
First (1s) Year PAN
Five -Year
Maximum Adjusted PAN
(mg1kg)
(mg/kg)
Surface
17395
86975
Injection/Incorporation
19045
95225
6. Other Pollutants Determination: S ecify whether or not there are any other pollutants of concern in the residuals and provide
the results of the latest analyses:
FORM: RSC 06-16 Page 4 of 5

7. Pathogen Reduction: Per 15A NCAC 02T.1106, specify how residuals will meet the pathogen reduction requirements:
a. For Distribution/Land Application of Class A or Equivalent:
71 A fecal coliform density that is demonstrated to be less than 1,000 MPN per gram of total dry solids,
or
JJ A salmonella sp. density that is demonstration to be less than 3 MPN per 4 grams of total dry solids.
AND one of the followings (except for non -biological residuals):
14 Alternative 1 [15A NCAC 02T.I 106(b)(3)(A)] - Time/Temperature Compliance.
q Alternative 2 [15A NCAC 02T.I 106(b)(3)(B)] - Alkaline Treatment.
q Alternative 3 [15A NCAC 02T.I 106(b)(3)(C)] - Prior Testing for Enteric Virus/Viable Helminth Ova.
q Alternative 4 [15A NCAC 02T.I 106(b)(3)(D)] - No Prior Testing for Enteric Virus/Viable Helminth Ova.
JA Alternative 5 [15A NCAC 02T.I 106(b)(3)(E)-(K)] - Process to Further Reduce Pathogens (PFRP).
Specify one: composting, 0 heat drying, 77 heat treatment,
thermophilic aerobic digestion, ❑ beta ray irradiation,
El gamma ray irradiation, or ❑ pasteurization.
b. For Land Application of Class B:
J Alternative 1 [15A NCAC 02T.I 106(c)(1)] - Fecal Coliform Density Demonstration.
J Alternative 2 [15A NCAC 02T.I 106(c)(2 - Process to Significantly Reduce Pathogens (PSRP).
Specify one: aerobic digestion, air drying, ❑ anaerobic digestion,
composting, or lime stabilization.
c. For Surface Disposal:
11 Select One of the Class A or Equivalent Pathogen Reduction Alternatives in Item II. 7a. above.
J Select One of the Class B or Equivalent Pathogen Reduction Alternatives in Item II. 7b. above.
J Exempt -If Daily Cover Alternative is chosen in Item II.8. below [15A NCAC 02T.1106(a)(2)].
J Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
8. Vector Attraction Reduction (VAR): Per 15A NCAC 02T.1107, specify how residuals will meet the VAR requirements:
El Alternative 1 [15A NCAC 02T.I 107(a)(1)] - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion).
Alternative 2 [15A NCAC 02T.I 107(a)(2)] - 40-Day Bench Scale Test (Anaerobic Digestion).
Alternative 3 [15A NCAC 02T.I 107(a)(3)] - 30-Day Bench Scale Test (Aerobic Digestion).
Alternative 4 [15A NCAC 02T.I 107(a)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion).
Alternative 5 [15A NCAC 02T.I 107(a)(5)] - 14-Day Aerobic Processes.
Alternative 6 [15A NCAC 02T.I 107(a)(6)] - Alkaline Stabilization.
Alternative 7 [15A NCAC 02T.I 107(a)(7)] - Drying of Stabilized Residuals.
Alternative 8 [15A NCAC 02T.I 107(a)(8)] - Drying of Unstabilized Residuals.
Alternative 9 [15A NCAC 02T.I 107(a)(9)] - Injection.
Alternative 10 [15A NCAC 02T.I 107(a)(10)] - Incorporation.
q Alternative for Surface Disposal Units Only - Soil/Other Material Cover [ 15A NCAC 02T.I 107(b)(2)].
Ja Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
Note: For animal processing residuals, only alternatives 9 or 10 may be chosen due to the nuisance conditions that typically
occur when these residuals are applied and left on the land surface.
FORM: RSC 06-16 Page 5 of 5

PLANTINFLUENT
COVERED
METERING
DECHLORINATION EFFLUENT SLUDGE
FLUME
MH
BUILDING
SLUDGE STORAGE
TREATMENT
FACILITIES
BAR SCREENS
CHLORINE
LIME
BASIN
CONVEYOR SLUDGE
STORAGE
INFLUENT
PAD
PUMP STATION
RAS
BELT
PRESS
CLARIFIERS
RAS
WET
WELL
SLUDGE
PUMP
FLOW
SPUTTER SLUDGE
STA.
BOX PUMPS
WAS
'
AEROBICSLUDGE
AERATION
AERATION
BASIN
*
BASIN I DIGESTER
NO. 1
NO. 2
AERATORS
AERATORS
AERATORS
L - �
* FLOW
DISTRIBUTION
BOX
FLOW SCHEMATIC & WATER BALANCE
FOURTH CREEK WASTEWATER TREATMENT PLANT
CITY OF STATESVILLE

SUMM111
ENVIRONMENTAL TECHN❑LOMZ3. INC
Arraly0ca1 Laboralorfas
January 24, 2023
Alex Fox
Synagro
284 Boger Rd.
Mocksville, NC 27028
TEL:
FAX:
RE: 4th Creek
Dear Alex Fox:
Summit Environmental Technologies, Inc.
3310 Win St.
Cuyahoga Falls, Ohio 44223
TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com
Order No.: 23010840
Summit Environmental Technologies, Inc. received 1 sample(s) on 1/13/2023 for the
analyses presented in the following report.
There were no problems with the analytical events associated with this report unless noted
in the Case Narrative.
Quality control data is within laboratory defined or method specified acceptance limits
except where noted.
If you have any questions regarding these tests results, please feel free to call the
laboratory.
Sincerely,
Jennifer Woolf
Project Manager
3310 Win St.
Cuyahoga Falls, Ohio 44223
Arkansas 88-0735, California 2943, Colorado, Connecticut PH-0108, Florida NELAC E87688, Idaho 01100923, Illinois 200061, Indiana C-011-13,
ISO/IEC 17025:2017 119125 1.22-544, Kansas E-10347, Kentucky (Underground Storage Tank) 3, Kentucky 90146, Maryland 339, Michigan 9988,
Minnesota 1780279, Nevada 011009232020-1, New Hampshire 2996, New Jersey 011006, New York 11777, North Carolina 39705 and 631, North Dakota
R-201, Ohio DW, Ohio VAP C1,0052, Oklahoma 2019-155, Oregon 0112O0001, Pennsylvania 68-01335, Rhode Island LA000317, South Carolina
92016001, Texas T104704466-19-16, Utah 011009232020-12, Virginia VELAP 10381, West Virginia 9957C
Page 1 of 40

MM' Y Summit Environmental Technologies, Inc. Case Narrative
SU3310 Win St.
ENVIRONMENTAL rEC„HQLOG4r;S,INC. Cuyahoga Falls, Ohio44223 WO#: 23010840
Arralyi9cal Laboralorlas TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com Date: 1/24/2023
CLIENT: Synagro
Project: 4th Creek
WorkOrder Narrative:
23010840: This report in its entirety consists of the following documents: Cover Letter, Case Narrative,
Analytical Results, QC Summary Report, Applicable Accreditation Information, Chain -of -Custody,
Cooler Receipt Form, and other applicable forms as necessary. All documents contain the Summit
Environmental Technologies, Inc., Work Order Number assigned to this report.
Summit Environmental Technologies, Inc., holds the accreditations/certifications listed at the bottom of
the cover letter that may or may not pertain to this report. Please refer to the "Accreditation Program
Analytes Report" for accredited analytes list.
The information contained in this analytical report is the sole property of Summit Environmental
Technologies, Inc. and that of the customer. It cannot be reproduced in any form without the consent of
Summit Environmental Technologies, Inc. or the customer for which this report was issued. The results
contained in this report are only representative of the samples received. Conditions can vary at different
times and at different sampling conditions. Summit Environmental Technologies, Inc. is not responsible
for use or interpretation of the data included herein.
All results for Solid Samples are reported on an "as received" or "wet weight" basis unless indicated as
"dry weight" using the "-dry" designation on the reporting units.
This report is believed to meet all of the requirements of the accrediting agency, where applicable. Any
comments or problems with the analytical events associated with this report are noted below.
Analytical Sequence Sample Notes:
23010840-OOIA TCLP-SVOC_8270E: Surrogate recoveries biased low due to suspected sample matrix
effect; confirmed by re-injection/re-analysis. Associated sample results may be biased accordingly.
23010840-OOIA TCLP-VOC-MSTR 8260D: CCV/LCS exhibit high recoveries for 1,1-Dichloroethene
and Vinyl chloride. Investigative sample are non -detect for these compounds.
Original
Page 2 of 40

MM' Summit Environmental Technologies, In Qualifiers and Acronyms
SU3310 Win S
Ekiwlt OMM@N-rALTECHN❑LOG{r,23.INC Cuyahoga Falls, Ohio442� WO#: 23010840
Arraly0cal Laboralorlas TEL: [phone] FAX.- (330) 253-44E
Wehsite: httn:11www.settek.co Date: 1/24/2023
These commonly used Qualifiers and Acronyms may or may not be present in this report.
Qualifiers
U The compound was analyzed for but was not detected.
J The reported value is greater than the Method Detection Limit but less than the Reporting Limit.
H The hold time for sample preparation and/or analysis was exceeded.
D The result is reported from a dilution.
E The result exceeded the linear range of the calibration or is estimated due to interference.
MC The result is below the Minimum Compound Limit.
The result exceeds the Regulatory Limit or Maximum Contamination Limit.
in Manual integration was used to determine the area response.
d Manual integration in which peak was deleted
N The result is presumptive based on a Mass Spectral library search assuming a 1:1 response.
P The second column confirmation exceeded 25% difference.
C The result has been confirmed by GUMS.
X The result was not confirmed when GUMS Analysis was performed.
B/MB+ The analyte was detected in the associated blank.
G The ICB or CCB contained reportable amounts of analyte.
QC-/+ The CCV recovery failed low () or high (+).
R/QDR The RPD was outside of accepted recovery limits.
QL-/+ The LCS or LCSD recovery failed low () or high (+).
QLR The LCS/LCSD RPD was outside of accepted recovery limits.
QM-/+ The MS or MSD recovery failed low () or high (+).
QMR The MS/MSD RPD was outside of accepted recovery limits.
QV-/+ The ICV recovery failed low () or high (+).
S The spike result was outside of accepted recovery limits.
Z Deviation; A deviation from the method was performed; Please refer to the Case Narrative for
additional information
Acronyms
ND
Not Detected
RL
Reporting Limit
QC
Quality Control
MDL
Method Detection Limit
MB
Method Blank
LOD
Level of Detection
LCS
Laboratory Control Sample
LOQ
Level of Quantitation
LCSD
Laboratory Control Sample Duplicate
PQL
Practical Quantitation Limit
QCS
Quality Control Sample
CRQL
Contract Required Quantitation Limit
DUP
Duplicate
PL
Permit Limit
MS
Matrix Spike
RegLvl
Regulatory Limit
MSD
Matrix Spike Duplicate
MCL
Maximum Contamination Limit
RPD
Relative Percent Different
MinCL
Minimum Compound Limit
ICV
Initial Calibration Verification
RA
Reanalysis
ICB
Initial Calibration Blank
RE
Reextraction
CCV
Continuing Calibration Verification
TIC
Tentatively Identified Compound
CCB
Continuing Calibration Blank
RT
Retention Time
PLC
Reporting Limit Check
CF
Calibration Factor
DF
Dilution Factor
RF
Response Factor
This list of Qualifiers and Acronyms reflects the most commonly utilized Qualifiers and Acronyms for reporting.
Please refer to the Analytical Notes in the Case Narrative for any Qualifiers or Acronyms that do not appear in this
list or for additional information regarding the use of these Qualifiers on reported data.
Original
Page 3 of 40

�� 1 � Summit Environmental Technologies, Inc.
SU3310 Win St.
ENVIROMMEWAL YECHNO ijULES. JNG, Cuyahoga Falls, Ohio 44223
Analytical Laboralorlas TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com
CLIENT: Synagro
Project: 4th Creek
Lab SampleID Client Sample ID
23010840-001 4th Creek
Tag No Date Collected
1/10/2023 8:10:00 AM
Workorder
Sample Summary
WO#: 23010840
24 Jan-23
Date Received Matrix
1/13/2023 10:20:00 AM Solid
Page 4 of 40

SUMMIT
Summit Environmental Technologies, Inc.
3310 Win St.
DATES REPORT
ENVIRONMENTALTECHN❑L0G1ES,1ptC
Cuyahoga Falls, Ohio44223
WO#: 23010840
ArWyft cal tai5oralonas
TEL: [phone] FAX.- [phone]
Wehsite: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
4th Creek
Sample ID
Client Sample ID Collection Date Matrix Test Name Leachate Date
Prep Date Analysis Date
23010840-OOIA 4th Creek 1/10/2023 8:10:00 AM Solid Ignitability of Solids (SW-846: 1030)
1/18/2023 7:17:11 PM
pH (SW9045D)
1/20/2023 4:11:32 PM
Reactive Cyanide (9014/7.3.32)-Solid
1/23/2023 1:45:00 PM
Reactive Sulfide (9034)/7.3.42
1/23/2023 1:45:00 PM
TCLP Herbicides by EPA 8321B
1/17/2023 5:04:00 PM
TCLP Mercury Analysis (SW1311/7471/16/2023 2:00:00 PM
1/17/2023 1:30:00 PM 1/18/2023 1:09:00 PM
TCLP Metals Analysis (SW1311/6010' 1/16/2023 2:00:00 PM
1/17/2023 1:00:00 PM 1/18/2023 1:26:00 PM
TCLP Pesticides Analysis (SW1311/8(1/16/2023 2:00:00 PM
1/18/2023 10:31:44 AM 1/19/2023 6:16:00 AM
TCLP Pesticides Analysis (SW1311/8(1/16/2023 2:00:00 PM
1/18/2023 10:31:44 AM 1/19/2023 6:16:00 AM
TCLP Semi-Volatiles Analysis 1/16/2023 2:00:00 PM
1/17/2023 11:20:00 AM 1/19/2023 12:53:00 PM
(SW1311/8270)
TCLP Semi-Volatiles Analysis 1/16/2023 2:00:00 PM
1/17/2023 11:20:00 AM 1/18/2023 4:21:00 AM
(SW1311/8270)
TCLP Volatiles Analysis
1/23/2023 3:48:00 PM
Original
Page 5 of 40

SUMMIT Summit Environmental Technologies, Inc.
3310 Win St.
ENVITtONMENTALTECHNQLOGIE$,IRC Cuyahoga Falls, Ohio44223
Arralyt9cal Laboralorfas TEL: [phone] FAX. [phone]
Website: http://�i,-"-m,.settek.com
Analytical Report
(base report)
WO#: 23010840
Date Reported: 1/24/2023
CLIENT: Synagro Tag Number:
Matrix: SOLID Collection Date: 1/10/2023 8:10:00 AM
Lab ID: 23010840-OOIA
Project: 4th Creek
Client Sample ID 4th Creek
Analyses Result RL Qual Units DF Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
TCLP MERCURY ANALYSIS (SW1311/7470)
TCLP Mercury
ND 0.00200 mg/L
SW7470A SW7470A Analyst: JJF
1 1/18/2023 1:09:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW6010
SW301OA Analyst: RJE
TCLP METALS ANALYSIS (SW1311/6010)
TCLP Arsenic(As)
ND
0.500
mg/L
1
1/18/2023 1:26:00 PM
TCLP Barium(Ba)
ND
5.00
mg/L
1
1/18/2023 1:26:00 PM
TCLP Cadmium(Ccl)
ND
0.100
mg/L
1
1/18/2023 1:26:00 PM
TCLP Chromium(Cr)
ND
0.200
mg/L
1
1/18/2023 1:26:00 PM
TCLP Lead(Pb)
ND
0.500
mg/L
1
1/18/2023 1:26:00 PM
TCLP Selenium(Se)
ND
0.0500
mg/L
1
1/18/2023 1:26:00 PM
TCLP Silver(Ag)
ND
0.500
mg/L
1
1/18/2023 1:26:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8270
SW351OC Analyst: JAP
TCLP SEMI-VOLATILES ANALYSIS (SW1311/8270)
1,4-Dichlorobenzene
ND
0.100
mg/L
1
1/19/2023 12:53:00 PM
2,4,5-Trichlorophenol
ND
0.250
mg/L
1
1/19/2023 12:53:00 PM
2,4,6-Trichlorophenol
ND
0.250
mg/L
1
1/19/2023 12:53:00 PM
2,4-Dinitrotoluene
ND
0.0500
mg/L
1
1/19/2023 12:53:00 PM
Cresols, Total
ND
5.00
mg/L
1
1/19/2023 12:53:00 PM
Hexachloro-1,3-butadiene
ND
0.0200
mg/L
1
1/19/2023 12:53:00 PM
Hexachlorobenzene
ND
0.0500
mg/L
1
1/19/2023 12:53:00 PM
Hexachloroethane
ND
0.100
mg/L
1
1/19/2023 12:53:00 PM
Nitrobenzene
ND
0.100
mg/L
1
1/19/2023 12:53:00 PM
Pentachlorophenol
ND
0.250
mg/L
1
1/19/2023 12:53:00 PM
Pyridine
ND
0.250
mg/L
1
1/19/2023 12:53:00 PM
Surr: 2-Fluorophenol
26.6
10- 157
%Rec
1
1/19/2023 12:53:00 PM
Surr: Phenol-d6
36.7
10 - 169
%Rec
1
1/19/2023 12:53:00 PM
Surr: Nitrobenzene-d5
17.5
32.1 - 130
S %Rec
1
1/19/2023 12:53:00 PM
Surr: 2,4,6-Tribromophenol
50.3
45.4 - 166
%Rec
1
1/19/2023 12:53:00 PM
Surr: 2-Fluorobiphenyl
21.1
35.7 - 130
S %Rec
1
1/19/2023 12:53:00 PM
Surr: p-Terphenyl-d14
55.9
70 - 145
S %Rec
1
1/19/2023 12:53:00 PM
Qualifiers: B Analyte detected in the associated Method Blank
E Value above quantitation range
H Holding times for preparation or
analysis exceeded
M Manual Integration
used to determine area response
MC Value is below Minimum Compound
Limit.
N Tentatively identified compounds
ND Not Detected
OGI
P Second column confirmation exceeds
PL Permit Limit
Origin
R RPD outside accepted recovery limits
RL Reporting Detection Limit
Page 6 of 40

SUMMIT Summit Environmental Technologies, Inc.
3310 Win St.
ENVITtONMENTALTECHNQLOGIE$,IRC Cuyahoga Falls, Ohio44223
Arrafyt9caf Laboralorfas TEL: [phone] FAX. [phone]
Website: http://�i,-"-m,.settek.com
Analytical Report
(base report)
WO#: 23010840
Date Reported: 1/24/2023
CLIENT: Synagro Tag Number:
Matrix: SOLID Collection Date: 1/10/2023 8:10:00 AM
Lab ID: 23010840-OOIA
Project: 4th Creek
Client Sample ID 4th Creek
Analyses
Result
RL
Qual Units
DF
Date Analyzed
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8081
SW351OC Analyst: PGP
TCLP PESTICIDES ANALYSIS
(SW1311/8081)
Chlordane, total
ND
0.0125
mg/L
5
1/19/2023 6:16:00 AM
Toxaphene
ND
0.0250
mg/L
5
1/19/2023 6:16:00 AM
Endrin
ND
0.00250
mg/L
5
1/19/2023 6:16:00 AM
gamma-BHC
ND
0.00250
mg/L
5
1/19/2023 6:16:00 AM
Heptachlor
ND
0.00250
mg/L
5
1/19/2023 6:16:00 AM
Heptachlor epoxide
ND
0.00250
mg/L
5
1/19/2023 6:16:00 AM
Methoxychlor
ND
0.00250
mg/L
5
1/19/2023 6:16:00 AM
Surr: TCMX
85.5
10 - 119
%Rec
5
1/19/2023 6:16:00 AM
Surr: DCB
78.0
10 - 119
%Rec
5
1/19/2023 6:16:00 AM
TCLP HERBICIDES BY EPA 8321B
SW8321
Analyst: SRA
2,4-D
ND
0.500
mg/L
50
1/17/2023 5:04:00 PM
2,4,5-TP
ND
0.500
mg/L
50
1/17/2023 5:04:00 PM
Surr: 2,4-Dichlorophenylacetic aci
98.2
70 - 130
%Rec
50
1/17/2023 5:04:00 PM
TCLP METALS, VOC, BNA, PEST, HERB -SOLID
SW8260
Analyst: EMB
TCLP VOLATILES ANALYSIS
1,1-Dichloroethene
ND
0.100
QC+ mg/L
20
1/23/2023 3:48:00 PM
1,2-Dichloroethane
ND
0.100
mg/L
20
1/23/2023 3:48:00 PM
MEK
ND
2.00
mg/L
20
1/23/2023 3:48:00 PM
Benzene
ND
0.100
mg/L
20
1/23/2023 3:48:00 PM
Carbon tetrachloride
ND
0.100
mg/L
20
1/23/2023 3:48:00 PM
Chlorobenzene
ND
1.00
mg/L
20
1/23/2023 3:48:00 PM
Chloroform
ND
0.100
mg/L
20
1/23/2023 3:48:00 PM
Tetrachloroethene
ND
0.100
mg/L
20
1/23/2023 3:48:00 PM
Trichloroethene
ND
0.100
mg/L
20
1/23/2023 3:48:00 PM
Vinyl chloride
ND
0.0400QC+QL+mg/L
20
1/23/2023 3:48:00 PM
Surr: 4-Bromofluorobenzene
89.1
70 - 130
%Rec
20
1/23/2023 3:48:00 PM
Surr: Dibrom ofluorom ethane
99.2
70 - 130
%Rec
20
1/23/2023 3:48:00 PM
Surr: Toluene-d8
106
70 - 130
%Rec
20
1/23/2023 3:48:00 PM
Qualifiers: B Analyte detected in the associated Method Blank
E Value above quantitation range
H Holding times for preparation or analysis exceeded
M Manual Integration
used to determine area response
MC Value is below Minimum Compound Limit.
N Tentatively identified compounds
ND Not Detected
OGI
P Second column confirmation exceeds
PL Permit Limit
Origin
R RPD outside accepted recovery
limits
RL Reporting Detection Limit
Page 7 of 40

MMIT
Summit Environmental Technologies, Inc. Analytical Report
SU3310 Win St.
ENVI110NMENTAL1rECHNQL0G4E$,IRC Cuyahoga Falls, Ohio44223 (base report)
Arrafyt9caf Laboralorfas TEL: [phone] FAX. [phone] WO#: 23010840
Website: http://www.settek.com Date Reported: 1/24/2023
CLIENT: Synagro Tag Number:
Matrix: SOLID Collection Date: 1/10/2023 8:10:00 AM
Lab ID: 23010840-OOIA
Project: 4th Creek
Client Sample ID 4th Creek
Analyses
Result
RL Qual Units
DF
Date Analyzed
RCI
SW9014
Analyst: MS
REACTIVE CYANIDE (9014/7.3.3.2)-SOLID
Cyanide, Reactive
ND
0.495 mg/Kg
1
1/23/2023 1:45:00 PM
IGNITABILITY OF SOLIDS (SW-846: 1030)
SW1030
Analyst: SMZ
Ignitability Non-flammable
mm/sec
1
1/18/2023 7:17:11 PM
RCI
SW9045D
Analyst: SMZ
PH (SW9045D)
pH
6.5
s.u.@20.7C
1
1/20/2023 4:11:32 PM
RCI
SW9034
Analyst: MS
REACTIVE SULFIDE (9034)/7.3.4.2
Sulfide, Reactive
ND
25.0 mg/Kg
1
1/23/2023 1:45:00 PM
Qualifiers: B
Analyte detected in the associated Method Blank
E
Value above quantitation range
H
Holding times for preparation or analysis exceeded
M
Manual Integration used to determine area response
MC
Value is below Minimum Compound Limit.
N
Tentatively identified compounds
ND
Not Detected
OGI
P
Second column confirmation exceeds
PL
Permit Limit Origin
R
RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 8 of 40

Summit Environmental Technologies, Inc.
Accreditation
Program
SUMMIEF
fr3310 Win St.
Analv n tes Report
ENwIROMMEWALYECHNOL.OG{r,S,INC
Cuyahoga Falls, Ohio44223
J
Y
Arraly0cal Laboralorlas
TEL: [phone] FAX.- [phone]
WO#:
23010840
Wehsite: http://www.settek.com
24 Jan-23
Client: Synagro
State: NW
Project: 4th Creek
Program Name: NC_WW_SCM
Sample ID Matrix
Test Name
Analyte
Status
23010840-OOIA Solid
Ignitability of Solids (SW-846: 1030)
Ignitability
A
Solid
pH (SW9045D)
Hydrogen Ion (pH)
A
Solid
Reactive Cyanide (9014/7.3.32)-Solid
Cyanide, Reactive
U
Solid
Reactive Sulfide (9034)/7.3.42
Sulfide, Reactive
U
Solid
TCLP Herbicides by EPA 832113
2,4,5-TP
A
Solid
TCLP Herbicides by EPA 832113
2,4-D
A
Solid
TCLP Mercury Analysis (SW1311/7470)
Mercury
A
Solid
TCLP Metals Analysis (SW1311/6010)
Arsenic
A
Solid
TCLP Metals Analysis (SW1311/6010)
Barium
A
Solid
TCLP Metals Analysis (SW1311/6010)
Cadmium
A
Solid
TCLP Metals Analysis (SW1311/6010)
Chromium
A
Solid
TCLP Metals Analysis (SW1311/6010)
Lead
A
Solid
TCLP Metals Analysis (SW1311/6010)
Selenium
A
Solid
TCLP Metals Analysis (SW1311/6010)
Silver
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
Chlordane, total
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
Endrin
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
gamma-BHC
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
Heptachlor
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
Heptachlor epoxide
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
Methoxychlor
A
Solid
TCLP Pesticides Analysis (SW1311/8081)
Toxaphene
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
1,4-Dichlorobenzene
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4,5-Trichlorophenol
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4,6-Trichlorophenol
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
2,4-Dinitrotoluene
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Cresols, Total
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Hexachlorobenzene
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Hexachlorobutadiene
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Hexachloroethane
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Nitrobenzene
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Pentachlorophenol
A
Solid
TCLP Semi-Volatiles Analysis (SW1311/8270)
Pyridine
A
Original # 1
Page 9 of 40

Summit Environmental Technologies, Inc.
Accreditation
Program
SUMMIEF
fr3310 Win St.
Anal�7n tes Report
ENVIROMMEWAL IrECHHOL,t
01ES, INC Cuyahoga Falls, Ohio 44223
J
Y
Arraly0cal Laboralorlas
TEL: [phone] FAX.- [phone]
WO#:
23010840
Wehsite: http://www.settek.com
24 Jan-23
Client: Synagro
State: NW
Project: 4th Creek
Program Name: NC_WW_SCM
Sample ID Matrix
Test Name
Analyte
Status
23010840-OOIA Solid
TCLP Volatiles Analysis
1,1-Dichloroethene
A
Solid
TCLP Volatiles Analysis
1,2-Dichloroethane
A
Solid
TCLP Volatiles Analysis
2-Butanone
A
Solid
TCLP Volatiles Analysis
Benzene
A
Solid
TCLP Volatiles Analysis
Carbon tetrachloride
A
Solid
TCLP Volatiles Analysis
Chlorobenzene
A
Solid
TCLP Volatiles Analysis
Chloroform
A
Solid
TCLP Volatiles Analysis
Tetrachloroethene
A
Solid
TCLP Volatiles Analysis
Trichloroethene
A
Solid
TCLP Volatiles Analysis
Vinyl chloride
A
Original # 1
Page 10 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010840
24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: 62252
Sample ID: MB-62252
SampType: MBLK
TestCode: SVOC-BNA_T Units: mg/L
Prep Date: 1/17/2023
RunNo: 156649
'.Iient ID: PBS
Batch ID: 62252
TestNo: SW8270 SW3510C
Analysis Date: 1/17/2023
SegNo: 4170702
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1,4-Dichlorobenzene
ND
0.0250
2,4,5-Trichlorophenol
ND
0.0250
2,4,6-Trichlorophenol
ND
0.0250
2,4-Dinitrotoluene
ND
0.0250
o-Cresol
ND
0.250
Cresols, Total
ND
0.0500
Hexachloro-1,3-butadiene
ND
0.0250
Hexachlorobenzene
ND
0.0250
Hexachloroethane
ND
0.0250
Nitrobenzene
ND
0.0250
Pentachlorophenol
ND
0.0250
Pyridine
ND
0.0250
Surr: 2-Fluorophenol
0.426
Surr: Phenol-d6
0.526
Surr: Nitrobenzene-d5
0.431
Surr: 2,4,6-Tribromophenol
0.818
Surr: 2-Fluorobiphenyl
0.481
Surr: p-Terphenyl-d14
0.805
1.000
42.6
10
135
1.000
52.6
10
161
1.000
43.1
16.8
150
1.000
81.8
32.5
179
1.000
48.1
34
133
1.000
80.5
60.8
163
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 11 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
Client: Synagro
Project: 4th Creek BatchID: 62252
WO#: 23010840
24-Jan-23
Sample ID: LCS-62252
SampType: LCS
TestCode: SVOC-BNA_T Units: mg/L
Prep Date: 1/17/2023
RunNo: 156649
Dient ID: LCSS
Batch ID: 62252
TestNo: SW8270 SW3510C
Analysis Date: 1/17/2023
SegNo: 4170703
4nalyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1,4-Dichlorobenzene
0.297
0.0250
0.8000
0
37.1
35
130
2,4,5-Trichlorophenol
0.660
0.0250
0.8000
0
82.6
44
144
2,4,6-Trichlorophenol
0.671
0.0250
0.8000
0
83.9
45
141
2,4-Dinitrotoluene
0.679
0.0250
0.8000
0
84.9
56
136
o-Cresol
0.494
0.250
0.8000
0
61.7
36
134
Cresols, Total
1.03
0.0500
1.600
0
64.3
36
135
Hexachloro-1,3-butadiene
0.341
0.0250
0.8000
0
42.6
30
130
Hexachlorobenzene
0.620
0.0250
0.8000
0
77.5
58
130
Hexachloroethane
0.290
0.0250
0.8000
0
36.3
28
130
Nitrobenzene
0.432
0.0250
0.8000
0
54.0
39
133
Pentachlorophenol
0.606
0.0250
0.8000
0
75.8
33
151
Pyridine
0.265
0.0250
0.8000
0
33.1
10
130
Surr: 2-Fluorophenol
0.477
1.000
47.7
10
135
Surr: Phenol-d6
0.565
1.000
56.5
10
161
Surr: Nitrobenzene-d5
0.430
1.000
43.0
16.8
150
Surr:2,4,6-Tribromophenol
0.926
1.000
92.6
32.5
179
Surr:2-Fluorobiphenyl
0.532
1.000
53.2
34
133
Surr: p-Terphenyl-d14
0.756
1.000
75.6
60.8
163
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGI P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 12 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
Client: Synagro
Project: 4th Creek BatchID: 62252
WO#: 23010840
24-Jan-23
Sample ID: 23010716-008AMS
SampType: MS
TestCode: SVOC-BNA_T Units: mg/L
Prep Date: 1/17/2023
RunNo: 156649
Dient ID: BatchQC
Batch ID: 62252
TestNo: SW8270 SW3510C
Analysis Date: 1/17/2023
SegNo: 4170705
4nalyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1,4-Dichlorobenzene
0.358
0.0250
0.8000
0
44.8
38.3
130
2,4,5-Trichlorophenol
0.638
0.0250
0.8000
0
79.8
43.9
157
2,4,6-Trichlorophenol
0.649
0.0250
0.8000
0
81.1
37.5
159
2,4-Dinitrotoluene
0.619
0.0250
0.8000
0
77.4
52.1
151
o-Cresol
0.531
0.250
0.8000
0
66.4
25.1
143
Cresols, Total
1.08
0.0500
1.600
0
67.8
10
184
Hexachloro-1,3-butadiene
0.407
0.0250
0.8000
0
50.8
36.2
130
Hexachlorobenzene
0.597
0.0250
0.8000
0
74.6
57.1
139
Hexachloroethane
0.350
0.0250
0.8000
0
43.8
30.4
130
Nitrobenzene
0.501
0.0250
0.8000
0
62.7
34
140
Pentachlorophenol
0.582
0.0250
0.8000
0
72.7
24.1
171
Pyridine
0.327
0.0250
0.8000
0
40.8
10
130
Surr: 2-Fluorophenol
0.531
1.000
53.1
10
135
Surr: Phenol-d6
0.598
1.000
59.8
10
161
Surr: Nitrobenzene-d5
0.470
1.000
47.0
16.8
150
Surr:2,4,6-Tribromophenol
0.805
1.000
80.5
32.5
179
Surr:2-Fluorobiphenyl
0.537
1.000
53.7
34
133
Surr: p-Terphenyl-d14
0.711
1.000
71.1
60.8
163
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 13 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
Client: Synagro
Project: 4th Creek BatchID: 62252
WO#: 23010840
24-Jan-23
Sample ID: 23010716-008AMSD
SampType: MSD
TestCode: SVOC-BNA_T Units: mg/L
Prep Date: 1/17/2023
RunNo: 156649
Dient ID: BatchQC
Batch ID: 62252
TestNo: SW8270 SW3510C
Analysis Date: 1/17/2023
SegNo: 4170706
4nalyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1,4-Dichlorobenzene
0.419
0.0250
0.8000
0
52.4
38.3
130
0.3580
15.7
30
2,4,5-Trichlorophenol
0.729
0.0250
0.8000
0
91.2
43.9
157
0.6382
13.3
30
2,4,6-Trichlorophenol
0.741
0.0250
0.8000
0
92.6
37.5
159
0.6486
13.3
30
2,4-Dinitrotoluene
0.756
0.0250
0.8000
0
94.5
52.1
151
0.6194
19.9
30
o-Cresol
0.592
0.250
0.8000
0
74.1
25.1
143
0.5312
10.9
30
Cresols, Total
1.22
0.0500
1.600
0
76.2
10
184
1.085
11.7
30
Hexachloro-1,3-butadiene
0.448
0.0250
0.8000
0
56.0
36.2
130
0.4066
9.60
30
Hexachlorobenzene
0.732
0.0250
0.8000
0
91.6
57.1
139
0.5968
20.4
30
Hexachloroethane
0.400
0.0250
0.8000
0
50.0
30.4
130
0.3504
13.3
30
Nitrobenzene
0.547
0.0250
0.8000
0
68.4
34
140
0.5012
8.74
30
Pentachlorophenol
0.756
0.0250
0.8000
0
94.5
24.1
171
0.5818
26.0
30
Pyridine
0.309
0.0250
0.8000
0
38.6
10
130
0.3266
5.60
30
Surr: 2-Fluorophenol
0.601
1.000
60.1
10
135
0
Surr: Phenol-d6
0.686
1.000
68.6
10
161
0
Surr: Nitrobenzene-d5
0.535
1.000
53.5
16.8
150
0
Surr:2,4,6-Tribromophenol
0.988
1.000
98.8
32.5
179
0
Surr:2-Fluorobiphenyl
0.615
1.000
61.5
34
133
0
Surr: p-Terphenyl-d14
0.834
1.000
83.4
60.8
163
0
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 14 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010840
24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: 62265
Sample ID: MB-62265
SampType: MBLK
TestCode: Mtl-TCLP-7(6 Units: mg/L
Prep Date: 1/17/2023
RunNo: 156653
Client ID: PBS
Batch ID: 62265
TestNo: SW6010 SW3010A
Analysis Date: 1/18/2023
SegNo: 4170960
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
TCLP Arsenic(As)
ND
0.100
TCLP Barium(Ba)
ND
5.00
TCLP Cadmium(Cd)
ND
0.100
TCLP Chromium(Cr)
ND
0.200
TCLP Lead(Pb)
ND
0.100
TCLP Selenium(Se)
ND
0.100
TCLP Silver(Ag)
ND
0.100
Sample ID: LCS-62265
SampType: LCS
TestCode: Mtl-TCLP-7(6 Units: mg/L
Prep Date: 1/17/2023
RunNo: 156653
Client ID: LCSS
Batch ID: 62265
TestNo: SW6010 SW3010A
Analysis Date: 1/18/2023
SegNo: 4170964
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
TCLP Arsenic(As)
2.12
0.100
2.000
0
106
80
120
TCLP Barium(Ba)
ND
5.00
2.000
0
102
80
120
TCLP Cadmium(Cd)
2.03
0.100
2.000
0
101
80
120
TCLP Chromium(Cr)
2.10
0.200
2.000
0
105
80
120
TCLP Lead(Pb)
2.10
0.100
2.000
0
105
80
120
TCLP Selenium(Se)
1.92
0.100
2.000
0
96.2
80
120
TCLP Silver(Ag)
2.11
0.100
2.000
0
105
80
120
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGI P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 15 of 40

MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT
SU3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010840
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://www.settek.com 24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: 62265
Sample ID: 23010805-001AMS
SampType: MS
TestCode: Mtl-TCLP-7(6 Units: mg/L
Prep Date: 1/17/2023
RunNo: 156653
Client ID: BatchQC
Batch ID: 62265
TestNo: SW6010 SW3010A
Analysis Date: 1/18/2023
SegNo: 4170970
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
TCLP Arsenic(As)
2.00
0.100
2.000
0
99.9
70
130
TCLP Barium(Ba)
ND
5.00
2.000
0.5863
76.0
70
130
TCLP Cadmium(Cd)
1.78
0.100
2.000
0
89.0
70
130
TCLP Chromium(Cr)
1.84
0.200
2.000
0
92.0
70
130
TCLP Lead(Pb)
1.81
0.100
2.000
0
90.7
70
130
TCLP Selenium(Se)
1.90
0.100
2.000
0
94.9
70
130
TCLP Silver(Ag)
1.99
0.100
2.000
0
99.4
70
130
Sample ID: 23010805-001AMSD
SampType: MSD
TestCode: Mtl-TCLP-7(6 Units: mg/L
Prep Date: 1/17/2023
RunNo: 156653
Client ID: BatchQC
Batch ID: 62265
TestNo: SW6010 SW3010A
Analysis Date: 1/18/2023
SegNo: 4170971
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
TCLP Arsenic(As)
1.99
0.100
2.000
0
99.7
70
130
1.997
0.150
20
TCLP Barium(Ba)
ND
5.00
2.000
0.5863
76.8
70
130
0
0
20
TCLP Cadmium(Cd)
1.76
0.100
2.000
0
88.1
70
130
1.780
1.04
20
TCLP Chromium(Cr)
1.82
0.200
2.000
0
91.1
70
130
1.841
1.05
20
TCLP Lead(Pb)
1.80
0.100
2.000
0
89.8
70
130
1.814
1.01
20
TCLP Selenium(Se)
1.89
0.100
2.000
0
94.4
70
130
1.899
0.523
20
TCLP Silver(Ag)
1.97
0.100
2.000
0
98.4
70
130
1.987
0.929
20
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 16 of 40

SUMM' T
Summit Environmental Technologies, Inc.
3310 Win St.
QC SUMMARY REPORT
ENVIRONMEWAL I ECHNO LQgir,-3, INC
Cuyahoga Falls, Ohio 44223
WO#: 23010840
4rrafyt�cal iaboralorfas
TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
4th Creek
BatchID: 62271
TCLP Mercury ND 0.00200
TCLP Mercury 0.00403 0.00200 0.00400 0 101 80 120
TCLP Mercury 0.00444 0.00200 0.00400 0.0000260 110 75 125
Sample ID: 23010805-001AMSD
SampType: MSD
TestCode: HG_TCLP(74 Units: PPM
Prep Date: 1/17/2023
RunNo: 156669
Client ID: BatchQC
Batch ID: 62271
TestNo: SW7470A SW7470A
Analysis Date: 1/18/2023
SegNo: 4171496
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
TCLP Mercury 0.00405 0.00200
0.00400 0.0000260 101 75
125
0.00444 9.19 20
Qualifiers: B Analyte detected in the associated Method Blank
E Value above quantitation range
H
Holding times for preparation or anal)
J Analyte detected below quantitation limits
M Manual Integration used to determine area response
MC
Value is below Minimum Compound
Original
ND Not Detected
OGl
P
Second column confirmation exceeds
PL Permit Limit
R RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 17 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
Client: Synagro
Project: 4th Creek BatchID: 62271
WO#: 23010840
24-Jan-23
Sample ID: 23010805-001AMSD
SampType: MSD
TestCode: HG_TCLP(74 Units: PPM
Prep Date: 1/17/2023
RunNo: 156669
Dient ID: BatchQC
Batch ID: 62271
TestNo: SW7470A SW7470A
Analysis Date: 1/18/2023
SegNo: 4171496
4nalyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 18 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO Lggir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010840
24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: 62279
Sample ID: MB-62279
SampType: MBLK
TestCode: TCLP-SVOC- Units: mg/L
Prep Date: 1/18/2023
RunNo: 156731
Client ID: PBS
Batch ID: 62279
TestNo: SW8081 SW3510C
Analysis Date: 1/18/2023
SegNo: 4172749
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Chlordane, total
ND
0.00250
Toxaphene
ND
0.00500
Endrin
ND
0.000500
gamma-BHC
ND
0.000500
Heptachlor
ND
0.000500
Heptachlor epoxide
ND
0.000500
Methoxychlor
ND
0.000500
Surr: TCMX
11.7
Surr: DCB
11.6
20.00 58.4 10 119
20.00 57.8 10 119
d
d
d
d
d
Sample ID: LCS-62279
SampType: LCS
TestCode: TCLP-SVOC- Units: mg/L
Prep Date: 1/18/2023
RunNo: 156731
Client ID: LCSS
Batch ID: 62279
TestNo: SW8081 SW3510C
Analysis Date: 1/18/2023
SegNo: 4172750
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Chlordane, tot
Toxaphene
Endrin
gamma-BHC
Heptachlor
Heptachlor epo
Methoxychlor
Surr: TCMX
Qualifiers:
al 0.0183 0.0
ND 0.0
0.0108 0.00
0.00848 0.00
0.0103 0.00
xide 0.00917 0.00
0.0114 0.00
12.0
B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
0250 0 0 70
0500 0 0 70
0500 0.0100 0 108 10
0500 0.0100 0 84.8 10
0500 0.0100 0 103 10
0500 0.0100 0 91.7 10
0500 0.0100 0 114 10
20.00 60.1 10
E Value above quantitation range
M Manual Integration used to determine area response
OGI
R RPD outside accepted recovery limits
130
130
130
130
130
130
178
130
H Holding times for preparation or anal)
MC Value is below Minimum Compound
P Second column confirmation exceeds
RL Reporting Detection Limit
Original
Page 19 of 40
B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
0250 0 0 70
0500 0 0 70
0500 0.0100 0 108 10
0500 0.0100 0 84.8 10
0500 0.0100 0 103 10
0500 0.0100 0 91.7 10
0500 0.0100 0 114 10
20.00 60.1 10
E Value above quantitation range
M Manual Integration used to determine area response
OGI
R RPD outside accepted recovery limits
130
130
130
130
130
130
178
130
H Holding times for preparation or anal)
MC Value is below Minimum Compound
P Second column confirmation exceeds
RL Reporting Detection Limit
Original
Page 19 of 40
130
130
130
130
130
130
178
130
H Holding times for preparation or anal)
MC Value is below Minimum Compound
P Second column confirmation exceeds
RL Reporting Detection Limit
Original
Page 19 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010840
24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: 62279
Sample ID: LCS-62279
SampType: LCS
TestCode: TCLP-SVOC- Units: mg/L
Prep Date: 1/18/2023
RunNo: 156731
'.Iient ID: LCSS
Batch ID: 62279
TestNo: SW8081 SW3510C
Analysis Date: 1/18/2023
SegNo: 4172750
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Surr: DCB
8.64
20.00
43.2 10 130
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 20 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010840
24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: R153421
Sample ID: RLC 5 ppm
SampType: RLC
TestCode: SVOC-MSTR Units: %Rec
Prep Date:
RunNo: 153421
:lient ID: BatchQC
Batch ID: R153421
TestNo: SW8270
Analysis Date: 11/11/2022
SegNo: 4088656
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Surr: 2-Fluorophenol
4.36
Surr: Phenol-d6
4.84
Surr: Nitrobenzene-d5
4.89
Surr: 2,4,6-Tribromophenol
5.16
Surr: 2-Fluorobiphenyl
5.50
Surr: p-Terphenyl-d14
4.45
Surr: Phenol-d5
0
Surr: Terphenyl-d14
4.45
Surr: Terphenyl-d14 (CLP)
4.45
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 21 of 40

SUMMIT
Summit Environmental Technologies, Inc.
3310 Wm St.
QC SUMMARY REPORT
ENVIRONMEWAL I ECHNO Lggir,-3, INC
Cuyahoga Falls, Ohio 44223
WO#: 23010840
4rrafyt�cal iaboralorlas
TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
4th Creek
BatchID: R156631
2,4-D ND 0.0100
2,4,5-TP ND 0.0100
Surr: 2,4-Dichlorophenylacetic acid 0.945 1.000 94.5 70 130
2,4-D
0.0195
0.0100 0.01000
0 195
50
150 S
2,4,5-TP
ND
0.0100 0.01000
0 83.0
50
150
Surr: 2,4-Dichlorophenylacetic acid
0.00850
0.01000
85.0
70
130
Sample ID: LCS TCLP 0.3 ppm
SampType: LCS
TestCode: TCLP-SVOC- Units: mg/L
Prep Date:
RunNo: 156631
Client ID: LCSS
Batch ID: R156631
TestNo: SW8321
Analysis Date: 1/17/2023
SegNo: 4170273
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
2,4-D
0.302 0.0100
0.3000 0 101 60.5
141
2,4,5-TP
0.287 0.0100
0.3000 0 95.7 68.3
144
Surr: 2,4-Dichlorophenylacetic acid 0.287
0.3000 95.5 70
130
Qualifiers: B
Analyte detected in the associated Method Blank
E Value above quantitation range
H
Holding times for preparation or anal}
J
Analyte detected below quantitation limits
M Manual Integration used to determine area response
MC
Value is below Minimum Compound
Original
ND
Not Detected
OGl
P
Second column confirmation exceeds
PL
Permit Limit
R RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 22 of 40

MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT
SU3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010840
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://www.settek.com 24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: R156631
Sample ID: LCSD TCLP 0.3 ppm SampType:
LCSD
TestCode: TCLP-SVOC- Units: mg/L
Prep Date:
RunNo: 156631
Client ID: LCSS02 Batch ID:
R156631
TestNo: SW8321
Analysis Date: 1/17/2023
SegNo: 4170274
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
2,4-D 0.296 0.0100 0.3000 0 98.8 60.5 141 0.3023 2.00 30
2,4,5-TP 0.278 0.0100 0.3000 0 92.8 68.3 144 0.2872 3.08 30
Surr: 2,4-Dichlorophenylacetic acid 0.279 0.3000 93.1 70 130 0 0
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 23 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010840
24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: R156695
Sample ID: LCS-R156695
SampType: LCS
TestCode: Ignitability_S Units: mm/sec
Prep Date:
RunNo: 156695
Client ID: LCSS
Batch ID: R156695
TestNo: SW1030
Analysis Date: 1/18/2023
SegNo: 4171894
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Ignitability
7.69
7.240 0 106 70 130
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGI P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 24 of 40

SUMM' T
Summit Environmental Technologies, Inc.
3310 Win St.
QC SUMMARY REPORT
ENVIRONMEWAL I ECHNO LQgir,-3, INC
Cuyahoga Falls, Ohio 44223
WO#: 23010840
4rrafyt�cal iaboralorfas
TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
4th Creek
BatchID: R156838
pH 7.0 7.0 0 100 90 110
pH 12.5 0 0 0 0 12.5 0.2 10
pH 7.0 7.0 0 100 90 110
Sample ID: 23011173-001ADUP
SampType: DUP
TestCode: pH_S(9045D) Units: s.u.@20.5C
Prep Date:
RunNo: 156838
Client ID: BatchQC
Batch ID: R156838
TestNo: SW9045D
Analysis Date: 1/20/2023
SegNo: 4175312
Analyte
Result
PQL SPK value SPK Ref Val %REC
Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
pH 6.5 0 0 0 0 6.4 0.6 10
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 25 of 40

SUMM' T
Summit Environmental Technologies, Inc.
3310 Win St.
QC SUMMARY REPORT
ENVIRONMEWAL I ECHNO LQgir,-3, INC
Cuyahoga Falls, Ohio 44223
WO#: 23010840
4rrafyt�cal iaboralorfas
TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
4th Creek
BatchID: R156838
pH 7.0 7.0 0 100 90 110
pH 7.6 0 0 0 0 7.6 0 10
Sample ID: LCS-R156838
SampType: LCS
TestCode: pH_S(9045D) Units: s.u.@20.5C
Prep Date:
RunNo: 156838
Client ID: LCSS
Batch ID: R156838
TestNo: SW9045D
Analysis Date: 1/20/2023
SegNo: 4175326
Analyte
Result
PQL SPK value SPK Ref Val %REC
LowLimit HighLimit RPD Ref Val
%RPD RPDLimit Qual
pH 7.0
7.0 0 101 90
110
Qualifiers: B Analyte detected in the associated Method Blank
E Value above quantitation range
H
Holding times for preparation or anal)
J Analyte detected below quantitation limits
M Manual Integration used to determine area response
MC
Value is below Minimum Compound
Original
ND Not Detected
OGl
P
Second column confirmation exceeds
PL Permit Limit
R RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 26 of 40

SUMM' T
Summit Environmental Technologies, Inc.
3310 Win St.
QC SUMMARY REPORT
ENVIRONMEWAL I ECHNO LQgir,-3, INC
Cuyahoga Falls, Ohio 44223
WO#: 23010840
4rrafyt�cal iaboralorfas
TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
4th Creek
BatchID: R156838
pH 7.0 7.0 0 100 98.6 101.4
pH 6.9 6.9 0.4 5 H
pH 7.0 7.0 0 100 98.6 101.4
Sample ID: 23010912-001ADUP
SampType: DUP
TestCode: pH_NPW(450 Units: s.u.@19.7C
Prep Date:
RunNo: 156838
Client ID: BatchQC
Batch ID: R156838
TestNo: SW9045D
Analysis Date: 1/20/2023
SegNo: 4175285
Analyte
Result
PQL SPK value SPK Ref Val %REC
Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
pH 6.3 6.3 0.5 5 H
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 27 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010840
24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: R156838
Sample ID: 23010912-001ADUP
SampType: DUP
TestCode: pH_NPW(450 Units: s.u.@19.7C
Prep Date:
RunNo: 156838
Dient ID: BatchQC
Batch ID: R156838
TestNo: SW9045D
Analysis Date: 1/20/2023
SegNo: 4175285
4nalyte
Result
PQL SPK value SPK Ref Val %REC
Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGI P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 28 of 40

SUMM' T
Summit Environmental Technologies, Inc.
3310 Win St.
QC SUMMARY REPORT
ENVIRONMEWAL I ECHNO LQgir,-3, INC
Cuyahoga Falls, Ohio 44223
WO#: 23010840
4rrafyt�cal iaboralorfas
TEL: [phone] FAX.- [phone]
Website: http://www.settek.com
24-Jan-23
Client:
Synagro
Project:
4th Creek
BatchID: R156913
Cyanide, Reactive ND 0.495
Cyanide, Reactive 9.17 0.500 10.00 0 91.7 85 115
Cyanide, Reactive ND 0.481 0.5000 0 62.0 50 150
Sample ID: 23010840-001AMS
SampType: MS
TestCode: Cyanide,Rea Units: mg/Kg
Prep Date:
RunNo: 156913
Client ID: 4th Creek
Batch ID: R156913
TestNo: SW9014
Analysis Date: 1/23/2023
SegNo: 4176952
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Cyanide, Reactive
7.77 0.495
10.00 0 77.7 75
125
Qualifiers: B
Analyte detected in the associated Method Blank
E Value above quantitation range
H
Holding times for preparation or anal)
J
Analyte detected below quantitation limits
M Manual Integration used to determine area response
MC
Value is below Minimum Compound
Original
ND
Not Detected
OGl
P
Second column confirmation exceeds
PL
Permit Limit
R RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 29 of 40

MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT
SU3310 Win St.
ENVIRONMEWAL I ECHNO Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010840
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://www.settek.com 24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: R156913
Sample ID: 23010840-001AMS
SampType: MS
TestCode: Cyanide,Rea Units: mg/Kg
Prep Date:
RunNo: 156913
Client ID: 4th Creek
Batch ID: R156913
TestNo: SW9014
Analysis Date: 1/23/2023
SegNo: 4176952
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Sample ID: 23010840-001AMSD
SampType: MSD
TestCode: Cyanide,Rea Units: mg/Kg
Prep Date:
RunNo: 156913
Client ID: 4th Creek
Batch ID: R156913
TestNo: SW9014
Analysis Date: 1/23/2023
SegNo: 4176953
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Cyanide, Reactive 8.43 0.495 10.00 0 84.3 75 125 7.772 8.19 10
Qualifiers: B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
E Value above quantitation range H Holding times for preparation or anal)
M Manual Integration used to determine area response MC Value is below Minimum Compound
OGl P Second column confirmation exceeds
R RPD outside accepted recovery limits RL Reporting Detection Limit
Original
Page 30 of 40

MM' T Summit Environmental Technologies, Inc. QC SUMMARY REPORT
SU3310 Win St.
ENVIRONMEWAL I ECHNO Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010840
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://www.settek.com 24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: R156917
Sample ID: 23010840-001AMS
SampType: MS
TestCode: Sulfide,React Units: mg/Kg
Prep Date:
RunNo: 156917
Client ID: 4th Creek
Batch ID: R156917
TestNo: SW9034
Analysis Date: 1/23/2023
SegNo: 4177055
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Sulfide, Reactive 1590 25.0 1710 0 93.0 80 120
Sample ID: 23010840-001AMSD
SampType: MSD
TestCode: Sulfide,React Units: mg/Kg
Prep Date:
RunNo: 156917
Client ID: 4th Creek
Batch ID: R156917
TestNo: SW9034
Analysis Date: 1/23/2023
SegNo: 4177056
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Sulfide, Reactive 1660 25.0 1710 0 97.1 80 120 1590 4.31 30
Qualifiers: B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
E Value above quantitation range H Holding times for preparation or anal)
M Manual Integration used to determine area response MC Value is below Minimum Compound
OGl P Second column confirmation exceeds
R RPD outside accepted recovery limits RL Reporting Detection Limit
Original
Page 31 of 40

SUMMIT Summit Environmental Technologies, Inc. QC SUMMARY REPORT
3310 Wm St.
ENVIRONMEWAL I ECHNO Lggir,-3, INC Cuyahoga Falls, Ohio 44223 WO#: 23010840
�lrrafyt�cal iaboralorlas TEL: [phone] FAX.- [phone]
Website: http://www.settek.com 24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: R156917
Sample ID: MB-R156917
SampType: MBLK
TestCode: Sulfide,React Units: mg/L
Prep Date:
RunNo: 156917
Client ID: PBW
Batch ID: R156917
TestNo: SW9034
Analysis Date: 1/23/2023
SegNo: 4177039
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Sulfide, Reactive ND 25.0
Sample ID: LCS-R156917
SampType: LCS
TestCode: Sulfide,React Units: mg/L
Prep Date:
RunNo: 156917
Client ID: LCSW
Batch ID: R156917
TestNo: SW9034
Analysis Date: 1/23/2023
SegNo: 4177040
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Sulfide, Reactive
1670 25.0 1710 0 97.7 85 115
Qualifiers: B Analyte detected in the associated Method Blank
J Analyte detected below quantitation limits
ND Not Detected
PL Permit Limit
E Value above quantitation range H Holding times for preparation or anal}
M Manual Integration used to determine area response MC Value is below Minimum Compound
OGl P Second column confirmation exceeds
R RPD outside accepted recovery limits RL Reporting Detection Limit
Original
Page 32 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010840
24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: R156931
Sample ID: LCS
SampType: LCS
TestCode: VOC-MSTR_ Units: mg/L
Prep Date:
RunNo: 156931
Client ID: LCSW
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177590
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1, 1 -Dichloroethene
0.0238
0.00500
0.0200
0
119
49
161 QC+
1,2-Dichloroethane
0.0206
0.00500
0.0200
0
103
48
151
MEK
0.124
0.0250
0.100
0
124
10
190
Benzene
0.0222
0.00500
0.0200
0
ill
34
169
Carbon tetrachloride
0.0203
0.00500
0.0200
0
101
76
134
Chlorobenzene
0.0200
0.00500
0.0200
0
99.8
54
144
Chloroform
0.0203
0.00500
0.0200
0
102
70
130
Tetrachloroethene
0.0189
0.00500
0.0200
0
94.4
66
134
Trichloroethene
0.0201
0.00500
0.0200
0
101
70
136
Vinyl chloride
0.0340
0.00200
0.0200
0
170
49
136 SQC+
Surr:4-Bromofluorobenzene
46.9
50.00
93.8
70
130
Surr: Di bromofluorom ethane
49.8
50.00
99.7
70
130
Surr: Toluene-d8
53.1
50.00
106
70
130
Sample ID: MBLK
SampType: MBLK
TestCode: VOC-MSTR_ Units: mg/L
Prep Date:
RunNo: 156931
Client ID: PBW
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177592
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1, 1 -Dichloroethene
ND
0.00500
QC+
1,2-Dichloroethane
ND
0.00500
MEK
ND
0.0250
Benzene
ND
0.00500
Qualifiers: B
Analyte detected in the associated Method Blank E Value above quantitation range
H Holding times for preparation or anal)
J
Analyte detected below quantitation limits
M Manual Integration used to determine area response
MC Value is below Minimum Compound
Original
ND
Not Detected
OGl
P Second column confirmation exceeds
PL
Permit Limit
R RPD outside accepted recovery limits
RL Reporting Detection Limit
Page 33 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010840
24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: R156931
Sample ID: MBLK
SampType: MBLK
TestCode: VOC-MSTR_ Units: mg/L
Prep Date:
RunNo: 156931
Client ID: PBW
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177592
Analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Carbon tetrachloride
ND
0.00500
Chlorobenzene
ND
0.00500
Chloroform
ND
0.00500
Tetrachloroethene
ND
0.00500
Trichloroethene
ND
0.00500
Vinyl chloride
ND
0.00200
Surr: 4-Bromofluorobenzene
45.5
Surr: Di bromofluorom ethane
49.9
Surr: Toluene-d8
53.4
50.00 91.0 70 130
50.00 99.7 70 130
50.00 107 70 130
QC+
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGl P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 34 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010840
24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: R156931
Sample ID: 23010928-001AMS
SampType: MS
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177602
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1, 1 -Dichloroethene
0.461
0.100
0.400
0
115
13.6
202 QC+
1,2-Dichloroethane
0.372
0.100
0.400
0
93.0
55.7
138
MEK
ND
2.00
2.00
0
88.6
65.3
130
Benzene
0.438
0.100
0.400
0
110
49.2
145
Carbon tetrachloride
0.375
0.100
0.400
0
93.6
26.7
156
Chlorobenzene
ND
1.00
0.400
0
96.2
33.7
159
Chloroform
0.384
0.100
0.400
0
96.0
48.5
145
Tetrachloroethene
0.359
0.100
0.400
0
89.8
19.2
191
Trichloroethene
0.376
0.100
0.400
0
94.0
38.4
167
Vinyl chloride
0.605
0.0400
0.400
0
151
27.3
161 QL+QC+
Surr:4-Bromofluorobenzene
928
1000
92.8
70
130
Surr: Di bromofluorom ethane
982
1000
98.2
70
130
Surr: Toluene-d8
1040
1000
104
70
130
Sample ID: 23010928-001AMSD
SampType: MSD
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177603
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1, 1 -Dichloroethene
0.471 0.100
0.400 0 118
13.6
202
0.461 2.23
25 QC+
1,2-Dichloroethane
0.393 0.100
0.400 0 98.2
55.7
138
0.372 5.39
25
MEK
ND 2.00
2.00 0 94.1
65.3
130
0 0
25
Benzene
0.441 0.100
0.400 0 110
49.2
145
0.438 0.683
25
Qualifiers: B
Analyte detected in the associated Method Blank
E
Value above quantitation range
H
Holding times for preparation or anal)
J
Analyte detected below quantitation limits
M
Manual Integration used to determine area
response
MC
Value is below Minimum Compound
Original
ND
Not Detected
OGl
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 35 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010840
24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: R156931
Sample ID: 23010928-001AMSD
SampType: MSD
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177603
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Carbon tetrachloride
0.389
0.100
0.400
0
97.2
26.7
156
0.375
3.72
25
Chlorobenzene
ND
1.00
0.400
0
102
33.7
159
0
0
25
Chloroform
0.395
0.100
0.400
0
98.8
48.5
145
0.384
2.93
25
Tetrachloroethene
0.377
0.100
0.400
0
94.2
19.2
191
0.359
4.79
25
Trichloroethene
0.389
0.100
0.400
0
97.3
38.4
167
0.376
3.40
25
Vinyl chloride
0.601
0.0400
0.400
0
150
27.3
161
0.605
0.630
25 QL+QC+
Surr:4-Bromofluorobenzene
920
1000
92.0
70
130
0
25
Surr: Di bromofluorom ethane
999
1000
99.9
70
130
0
25
Surr: Toluene-d8
1050
1000
105
70
130
0
25
Sample ID: 23011160-001AMS
SampType: MS
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177606
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1, 1 -Dichloroethene
0.449
0.100
0.400 0 112
13.6
202
QC+
1,2-Dichloroethane
0.343
0.100
0.400 0 85.7
55.7
138
MEK
ND
2.00
2.00 0 75.9
65.3
130
Benzene
0.416
0.100
0.400 0 104
49.2
145
Carbon tetrachloride
0.367
0.100
0.400 0 91.8
26.7
156
Chlorobenzene
ND
1.00
0.400 0 95.2
33.7
159
Chloroform
0.374
0.100
0.400 0 93.4
48.5
145
Tetrachloroethene
0.345
0.100
0.400 0 86.2
19.2
191
Qualifiers: B
Analyte detected in the associated Method Blank
E
Value above quantitation range
H
Holding times for preparation or anal)
J
Analyte detected below quantitation limits
M
Manual Integration used to determine area
response
MC
Value is below Minimum Compound
Original
ND
Not Detected
OGl
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery limits
RL
Reporting Detection Limit
Page 36 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010840
24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: R156931
Sample ID: 23011160-001AMS
SampType: MS
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177606
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Trichloroethene
0.360 0.100
0.400
0 90.1
38.4
167
Vinyl chloride
0.610 0.0400
0.400
0 153
27.3
161 QL+QC+
Surr:4-Bromofluorobenzene
918
1000
91.8
70
130
Surr: Di bromofluorom ethane
974
1000
97.4
70
130
Surr: Toluene-d8
1060
1000
106
70
130
Sample ID: 23011160-001AMSD
SampType: MSD
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177607
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
1, 1 -Dichloroethene
0.459
0.100
0.400 0
115
13.6
202
0.449 2.29
25 QC+
1,2-Dichloroethane
0.368
0.100
0.400 0
92.1
55.7
138
0.343 7.20
25
MEK
ND
2.00
2.00 0
89.8
65.3
130
0 0
25
Benzene
0.428
0.100
0.400 0
107
49.2
145
0.416 2.70
25
Carbon tetrachloride
0.372
0.100
0.400 0
92.9
26.7
156
0.367 1.19
25
Chlorobenzene
ND
1.00
0.400 0
93.1
33.7
159
0 0
25
Chloroform
0.379
0.100
0.400 0
94.8
48.5
145
0.374 1.54
25
Tetrachloroethene
0.344
0.100
0.400 0
86.1
19.2
191
0.345 0.116
25
Trichloroethene
0.366
0.100
0.400 0
91.6
38.4
167
0.360 1.60
25
Vinyl chloride
0.633
0.0400
0.400 0
158
27.3
161
0.610 3.64
25 QL+QC+
Surr:4-Bromofluorobenzene
905
1000
90.5
70
130
0
25
Surr: Di bromofluorom ethane 987
1000
98.7
70
130
0
25
Qualifiers: B
Analyte detected in the associated Method Blank
E
Value above quantitation range
H
Holding times for preparation or anal)
J
Analyte detected below quantitation limits
M
Manual Integration used to determine area
response
MC
Value is below Minimum Compound
Original
ND
Not Detected
OGl
P
Second column confirmation exceeds
PL
Permit Limit
R
RPD outside accepted recovery
limits
RL
Reporting Detection Limit
Page 37 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMEWAL I ECHNO LQgir,-3, INC Cuyahoga Falls, Ohio 44223
4rrafyt�cal iaboralorfas TEL: [phone] FAX.- [phone]
Website: http://nnn.settek.com
QC SUMMARY REPORT
WO#: 23010840
24-Jan-23
Client: Synagro
Project: 4th Creek BatchID: R156931
Sample ID: 23011160-001AMSD
SampType: MSD
TestCode: TCLP-VOC-M Units: mg/L
Prep Date:
RunNo: 156931
:lient ID: BatchQC
Batch ID: R156931
TestNo: SW8260
Analysis Date: 1/23/2023
SegNo: 4177607
analyte
Result
PQL SPK value SPK Ref Val
%REC Lowl-imit HighLimit RPD Ref Val
%RPD RPDLimit Qual
Surr: Toluene-d8
1040
W
104 70 130
0 25
Qualifiers: B Analyte detected in the associated Method Blank E Value above quantitation range H Holding times for preparation or anal)
J Analyte detected below quantitation limits M Manual Integration used to determine area response MC Value is below Minimum Compound
ND Not Detected OGI P Second column confirmation exceeds Original
PL Permit Limit R RPD outside accepted recovery limits RL Reporting Detection Limit
Page 38 of 40

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Page 39 of 40

Summit Environmental Technologies, Inc.
SUMMIT 3310 Win St.
ENVIRONMENTAL TECHN❑L4Ga1�S.IfiC Cuyahoga Falls, Ohio44223 Sample Log -In Check List
Arrafocal Laboralorias TEL: [phone] FAX.- [phone]
Website: http://`h,,",m,.settek.com
Client Name: SYN-NC-27028 Work Order Number: 23010840 RcptNo: 1
Logged by: Anthony W. Britton 1/13/2023 10:20:00 AM�
Completed By: Anthony W. Britton 1/13/2023 6:12:01 PM
Reviewed By: Jennifer Woolf 1/16/2023 4:15:09 PM
Chain of Custody
1. Is Chain of Custody complete? Yes ❑d No ❑ Not Present ❑
2. How was the sample delivered? UPS
Log In
3. Coolers are present? Yes ❑d No ❑ NA ❑
4. Shipping container/cooler in good condition?
Yes
d❑
No
❑
Custody seals intact on shipping container/cooler?
Yes
❑
No
❑
Not Present V
No. Seal Date:
Signed By:
5. Was an attempt made to cool the samples?
Yes
❑d
No
❑
NA ❑
6. Were all samples received at a temperature of >0° C to 6.0°C
Yes
❑d
No
❑
NA ❑
7. Sample(s) in proper container(s)?
Yes
❑d
No
❑
8. Sufficient sample volume for indicated test(s)?
Yes
❑d
No
❑
9. Are samples (except VOA and ONG) properly preserved?
Yes
❑d
No
❑
10. Was preservative added to bottles?
Yes
❑
No
❑d
NA ❑
1 1 . Is the headspace in the VOA vials less than 1/4 inch or 6 mm?
Yes
❑
No
❑ No VOA Vials ❑�
12. Were any sample containers received broken?
Yes
❑
No
❑d
13. Does paperwork match bottle labels?
Yes
No
❑
(Note discrepancies on chain of custody)
14. Are matrices correctly identified on Chain of Custody?
Yes
❑
No
❑d
15. Is it clear what analyses were requested?
Yes
❑d
No
❑
16. Were all holding times able to be met?
Yes
No
❑
(If no, notify customer for authorization.)
Special Handling (if applicable)
17. Was client notified of all discrepancies with this order?
Yes
❑
No
❑ NA V
Person Notified: Date:
By Whom: Via: ❑ eMail ❑ Phone ❑ Fax ❑ In Person
Regarding:
Client Instructions:
18. Additional remarks:
Cooler Information
Cooler No
Temp °C
Condition
I Seal Intact
Seal No
Seal Date
Signed By
1
15.0
Goodl
Not Present
Page 40 of 40

State of North Carolina
DWR
Department of Environmental Quality
Division of Water Resources
Division of Water Resources LAND APPLICATION SITE CERTIFICATION
INSTRUCTIONS FOR FORM: LASC 06-16
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and
supporting documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit
General — This certification provides detailed information of receiving sites for land application of Class B residuals (may include
water treatment plant or other type residuals) in accordance with 15A NCAC 02T .1100. Do not submit this certification for review
without a corresponding application form (FORM: RLAP 06-16 or FORM: SDR 06-16).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Land Application Site Certification (FORM: LASC 06-16):
❑ Submit the completed and appropriately executed Land Application Site Certification (FORM: LASC 06-16) form. Please
do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments
to the application may be made, as long as the attachments are numbered to correspond to the section and item to which they
refer.
❑ For new or renewed permits, submit the requested information for all land application sites.
❑ For modified permits, submit the requested information for only those sites that are new, transferred or affected by the
proposed modification.
B. Land Application Site Information:
❑ The status of the land application site with respect to this residuals land application program must be provided in table I. The
status categories and their corresponding codes are as follows:
♦ New (N) ♦ Renewed (R) ♦ Modified (M) ♦ Transferred (T) ♦ Deleted (D)
❑ Attach the following in accordance with each status code:
Status Code
Required Item
N
R
T
M
County Board
Notification.doc
Land Owner
Agreement
(If applicable)
Setback Waiver
Agreement
An updated vicinity/setback map in accordance with the "Man Guidance
for Residuals Land Application Permits"
✓
✓
✓
A soils and agronomic evaluation in accordance with the "Soil Scientist
✓
Evaluation Policy"
INSTRUCTIONS FOR FORM: LASC 06-16 Page 1 of 3

An updated accounting of the land application site's cumulative
pollutant loading rates (CPLRs)
Status Code
Required Item
N
R
T
M
For previously permitted sites without a soil series name indicated in the
Attachment B, submit County Soil Survey Map (or equivalent) clearly
indicate the location of the land application site and in accordance with
the soil map requirements in the "Soil Scientist Evaluation Policy"
Acknowledgement of field transfer from Land Owner (Fields may not
be permitted to multiple Permittees over the same timeperiod)
* This item may be required for land application site with a status code "M', please contact the Division if you need assistant in
determining attachment requirements.
❑ Crop Type should include the most likely crop types for the life of the permit (five years).
❑ Predominant Soils Series Name must be either the name of the soil indicated in Attachment `B" of the existing permit, or
name of the soil series as provided by the licensed soil scientist.
❑ Predominant Soil Mapping Unit or Representative Slope: Either the Soil Mapping Unit or the representative slope of each
site must be provided. The predominant soil -mapping unit must be consistent with the predominant soil series name. Please
note that the soil mapping units are variable between Counties, so care should be taken in properly identifying the correct
mapping unit. If a representative slope is provided, it must be determined accordingly:
❑ For sites previously permitted for use, but do not have an established soil mapping unit (the mapping unit provides
information on both the soil series name and the slope of the soil), the Applicant may determine the representative slope
by using the average slope provided in the County Soil Survey (or equivalent). A soil type with a slope range of 4 - 8%
would have a representative slope of 6%.
❑ New Sites to be permitted must have slopes determined as part of the soils report prepared by a licensed soil scientist.
❑ Acceptable methods for determining location coordinates (i.e., latitude and longitude) and their corresponding codes are as
follows:
• Address Matching (ADD) • Digital or Raw Photo Extraction (EXT)
• Aerial Photography with Ground Control (AER) • Geodetic Quality GPS Survey (GEO)
• Cadastral Survey (SUR) • LORAN-C Navigation Device (LOR)
• Conversion from Coordinate Plane (CP) • Navigation Quality GPS (GPS)
• Conversion from Township -Section -Range (TSR) • Remote Sensing (RS)
• Conversion from Universal Trans Mere (UTM) • Zip Code Centroid (ZIP)
• Map Interpretation by Digital or Manual Extraction (MAP)
C. Waterbody and Classifications Information: (new sites only)
❑ Use an 8.5 by 11-inch copy of the portion of a 7.5-minute USGS Topographic Map to identify the location where the
residuals program activities are planned to occur as well as the closest downslope surface waters as clearly as possible. Each
map portion must be labeled with the map name and number, the identified location, and be of clear and reproducible quality.
❑ Surface water body classifications information may be found at: http:Hdeg.nc.gov/about/divisions/water-
resources/planning/classification-standards/classifications
❑ Any questions concerning the waterbody and its classification, please contact the Division's regional offices.
❑ A list of the Division's regional offices, their county coverage, and their contact information may be downloaded at:
hLtp:Hdeg.nc.gov/contact/regional-offices
❑ General Instructions: There are 17 river basins in North Carolina. Each basin has associated waterbodies with assigned
subbasins, location descriptions, stream index numbers and established classifications.
1. Identify the project area on a 7.5 minute USGS topographical map (an 8.5 x 11-inch sheet showing the project area
should be submitted with the permit application regardless of whether a Stream classification was completed).
2. Determine the names of all the closest down slope surface waters from the project site. For unnamed tributaries, see
Table 1: Unnamed Tributaries Entering Other States or for Specific Basin Areas. Label any unnamed tributaries as
"UT to stream name" as the waterbody name.
3. Open the link hLtp:Hdeg.nc.gov/about/divisions/water-resources/planning/classification-standards/classifications.
❑ Stream Classification Process: One of the options below may be used depending on the known initial project information.
❑ KNOWN BASIN WHERE CLOSEST DOWN SLOPE SURFACE WATER IS LOCATED
1. Select proper basin from the List all Waterbodies in Basin sorted report. Sort hydrologically as this will provide
the proper location descriptions if multiple runs.
INSTRUCTIONS FOR FORM: LASC 06-16 Page 2 of 3

2. Locate the name of the identified waterbody (from General Directions) on the list.
3. For multiple listings of the same waterbody name in the report, select and verify the location description. The term
"source" in the description means the beginning of the waterbody segment (most upstream point).
4. Record all Basins, Stream Index Numbers and Classifications applicable to the project.
❑ KNOWN COUNTY WHERE CLOSEST DOWN SLOPE SURFACE WATER IS LOCATED
1. Select the proper county from the List all Waterbodies in county, hydrologically report.
2. Locate the name of the identified waterbody (from General Directions) on the list.
3. For multiple listings of the same waterbody name in the report, select and verify the location description. The term
"source" in the description means the beginning of the waterbody segment (most upstream point).
4. Record all Basins, Stream Index Numbers and Classifications applicable to the project.
❑ UNKNOWN BASIN WHERE CLOSEST DOWN SLOPE SURFACE WATER IS LOCATED
1. Use the Clickable basin map to hydrologically sorted list report.
2. Click on the approximate project location to bring up the hydrologically sorted list.
3. Locate the name of the identified waterbody (from General Directions) on the list.
4. For multiple listings of the same waterbody name in the report, select and verify the location description. The tern
"source" in the description means the beginning of the waterbody segment (most upstream point).
5. Record all Basins, Stream Index Numbers and Classifications applicable to the project.
❑ Notes on index number and unnamed streams:
Unnamed Streams 15A NCAC 02B .0301(i).
❑ Any stream which is not named in the schedule of stream classifications carries the same classification as that assigned
to the stream segment to which it is tributary (at the point of entry) except:
(A) unnamed streams specifically described in the schedule of classifications;
(B) unnamed freshwaters tributary to tidal saltwaters will be classified "C"; or
(C) after November 1, 1986, any newly created areas of tidal saltwater which are connected to Class SA waters by
approved dredging projects will be classified "SC" unless case -by -case reclassification proceedings are conducted.
❑ The following river basins have different policies for unnamed streams entering other states or for specific areas of the
basin:
Unnamed Tributaries Entering Other States or for Specific Basin Areas
Hiwassee River Basin
Streams entering Georgia or Tennessee shall be classified "C Tr."
Little Tennesse River
Basin And Savannah
River Drainage Area
Streams entering Georgia or Tennessee shall be classified "C Tr." Such streams in the Savannah
River drainage area entering South Carolina shall be classified 'B Tr."
French Broad River
Basin
Streams entering Tennessee will be classified 'B."
Watauga River Basin
Streams entering the State of Tennessee are classified "C."
Broad River Basin
Streams entering South Carolina are classified "C."
New River Basin
Streams entering the State of Tennessee are classified "C."
Catawba River Basin
Streams entering South Carolina are classified "C."
Yadkin -Pee Dee River
Basin
Streams entering Virginia are classified "C," and such streams entering South Carolina are
classified "C."
Lumber River Basin
Streams entering South Carolina are classified "C Sw."
Roanoke River Basin
Streams entering Virginia are classified "C." Except that all backwaters of John H. Kerr
Reservoir and the North Carolina portion of streams tributary thereto not otherwise named or
described shall carry the classification 'B," and all backwaters of Lake Gaston and the North
Carolina portion of streams tributary thereto not otherwise named or described shall carry the
classification "C and B."
Chowan River Basin
Streams entering Virginia are classified "C."
Tar -Pamlico River
Basin
All drainage canals not noted in the schedule are classified "C Sw." except the main drainage
canals to Pamlico Sound and its bays which shall be classified "SC."
Pas uotank River Basin
All drainage canals not noted in the schedule are classified "C."
INSTRUCTIONS FOR FORM: LASC 06-16 Page 3 of 3

LAND APPLICATION SITE CERTIFICATION
Applicant's name: City of Statesville
Land application sites currently certified: 29.4 net acres and Total to be certified: 29.4 net acres.
L LAND APPLICATION SITE INFORMATION (See Instruction B):
Status
Codes
Site/Field
ID
Landowners
O
Lessees or Operator(s)
O
Net Acres
County
Crop(s) s
PO
Predominant Soil
Series Nameb
Mapping Unit
or Rep. Slope°
R
01
City of Statesville
4'b Creek WWTP
15.30
Iredell
Corn & Small Grain
Lloyd
LcC2 6-10%
N
I E
N
PPM
N
N
r
N
N
N
0011
a Status Code for land application sites are: ♦ N (New) ♦ R (Renewed) ♦ M (Modified) ♦ T (Transferred) ♦ D (Deleted)
b Soil Series Name (i.e. Appling, Cecil, etc.)
Mapping Unit must be consistent with those used in the County Soil Survey (i.e. for a 2-8% slope Cecil in Anson County the mapping unit is CeB2)
IL WATERBODY AND CLASSIFICATIONS INFORMATION (See Instruction C):
Site/Field ID
Latitude
Longitude
Location
Datum
Location Method Code
Location Accuracy
Waterbody Subbasin and
Stream Index No.
Current and Proposed
p
Class
01
350 46' 12"
-800 47' 24"
NAD 83
ADD
Nearest Second
03-07-06/03040102
C
C
_
00 Ell "
00 O'."
NAD 83
ADD
Nearest Second
W
_
°.', "
7°.'Ell
NAD 83
ADD
Nearest Second
IN
_
d°.', "
0 O'."
NAD 83
ADD
Nearest Second
IN
_
.° PE' N "
410.'."
NAD 83
ADD
Nearest Second
IN
_
`° 'ff_dO
El Ell
NAD 83
ADD
Nearest Second
IN
_
101 '
00 O'."
NAD 83
ADD
Nearest Second
IN
_
S° &"
00 O'."
NAD 83
ADD
Nearest Second
IN
Note: Please keep the site information (I.) and waterbody information (II.) of the same field on the same page.
FORM: LASC 06-16 Page 1

State of North Carolina
DWR
Department of Environmental Quality
Division of Water Resources
Division of Water Resources 15A NCAC 02T .1100 — RESIDUALS LAND APPLICATION PROGRAM
INSTRUCTIONS FOR FORM: RLAP 06-16 & SUPPORTING DOCUMENTATION
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and
sunnorting documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit
General — This application is for treatment, storage, transport, and/or land application of Class B residuals (may include residuals that
are generated from a water treatment plant or other type facilities) on the proposed or currently approved land application site(s) under
15A NCAC 02T .1100.
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Residuals Land Application Program (FORM: RLAP 06-16) Application: (All Application Packages):
Submit the completed and appropriately executed Residuals Land Application Program (FORM: RLAP 06-16) form. Please
do not make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to
the application may be made, as long as the attachments are numbered to correspond to the section and item to which they
refer.
The Applicant's Certification on Page 5 of this form shall be signed in accordance with 15A NCAC 02T .0106(b). An alternate
person may be designated as the signing official if a delegation letter is provided from a person who meets the criteria in 15A
NCAC 02T .0106(b).
❑ If this project is for a modification of an existing permit, submit one copy of the existing permit.
❑ Please submit this application form at least 180 days prior to the expiration date on the existing permit, or 90 days prior to
operation of proposed facility(ies) for application packages involving new or changes to treatment and storage units.
B. Application Fee (New and Major Modification Application Packages)
❑ Submit a check, money order or electronic funds transfer made payable to: North Carolina Department of Environmental
Quality (NCDEQ).
Facility Classification New Permit Major Modification'
Major (land are permitted for > 300 acres) F $1,310 F $395
Minor (land are permitted for < 300 acres) F_ $810 $245
' - A major modification shall be defined as any permit modification that: increases the generating facility's residuals dry tonnage;
adds additional land application areas not previously approved for that particular program [including transferring of field(s) from
one program to another]; adds additional residuals sources; or includes the addition of new treatment or storage units/processes not
previously permitted. There is no fee for minor modifications to a permit.
C. Cover Letter (All Application Packages)
❑ List all items included in the application package, as well as a brief description of the requested permitting action.
D. Environmental Assessments (Maybe Required —See 15A NCAC 1C .03
❑ Submit a copy of the Findings of No Significant Impact (FONSI) or Environmental Impact Statement (EIS). Also, include
information on any mitigating factor(s) from the Environmental Assessment (EA) that impact the construction of the residuals
treatment and storage facilities. An EA may also be required for private systems if any public funds and/or lands are used for
the construction of the subject facilities.
INSTRUCTIONS FOR FORM: RLAP 06-16 Page 1 of 3

E. Operation and Maintenance Plan (New and Renewal Application Packages)
❑ For Modification Application, if there are any changes to the existing plan, submit an updated O&M plan.
❑ Submit the O&M Plan in accordance with 15A NCAC 02T .1110 and include at a minimum:
❑ Operational functions; describe the operation of the program to show what operations are necessary for the program to
function and by whom the functions are to be conducted.
❑ Maintenance schedules; may include equipment calibration, maintenance of signs, etc.
❑ Safety measures; may include safety training program, manuals, signs, etc.
❑ Spill response plan; including control, containment, remediation, emergency contact information, etc.
❑ Inspection plan including the following information;
❑ Names and titles of personnel responsible for conducting the inspections.
❑ Frequency and location of inspections, including those to be conducted by the ORC, and procedures to assure that the
selected location(s) and inspection frequency are representative of the residuals management program.
❑ Detailed description of inspection procedures including record keeping and actions to be taken by the inspector in the event
that noncompliance is observed.
❑ Sampling and monitoring plan including the following information;
❑ Names and titles of personnel responsible for conducting the sampling and monitoring.
❑ Detailed description of monitoring procedures including parameters to be monitored.
❑ Sampling frequency and procedures to assure that representative samples are being collected. Fluctuation in temperature,
flow, and other operating conditions can affect the quality of the residuals gathered during a particular sampling event. The
sampling plan shall account for any foreseen fluctuations in residuals quality and indicate the most limiting times for
residuals to meet pathogen and vector attraction reduction requirements (e.g. facilities that land apply multiple times per
year but have an annual sampling frequency, may need to sample during winter months when pathogen reduction is most
likely to be negatively affected by cold temperatures.
THE FOLLOWING ADDITIONAL ITEMS (G to M) ARE REQUIRED FOR DEDICATED PROGRAM ONLY.
F. Program Determination
❑ Dedicated residuals land application programs are ones in which land application sites meet the criteria in 15A NCAC 02T
.110202). Specifically, a residuals land application program is designated as dedicated if any of the following are applicable:
❑ Any land application site certified for the residuals land application program that receives residuals at rates or frequencies
greater than agronomic rates.
❑ Any land application site certified for the residuals land application program that is used primarily for residuals disposal,
and agricultural crop production is of secondary importance.
❑ Any land application site certified for the residuals land application program that receives residuals through fixed irrigation
facilities or irrigation facilities fed through a fixed supply system.
❑ Please contact the Non -Discharge Permitting Unit if you need any assistance in determining whether your residuals program
falls under the dedicated program definitions.
G. Program Information
Q Provide an explanation of why a dedicated system is required instead of a conventional non -dedicated system.
❑ Provide an explanation of the dedicated system and its operation.
H. Detailed Site Maps (All New or Modification Application Packages)
❑ Submit three (3) sets of standard size plans and two (2) sets of I I" by 17" plans (electronic format is acceptable - Adobe PDF
only). For Modifications, submit plans specific to the modification(s) only.
❑ Plans must include the following minimum items:
❑ A general location map, a vicinity map and a topographic map with contours not exceeding 10 feet or 25% of the total site
relief and showing all facility related structures and fences within the land application area.
❑ The location of all wells (including usage and construction details if available), streams (ephemeral, intermittent, and
perennial), springs, lakes, ponds, and other surface drainage features within 500 feet of the land application site(s).
❑ Delineation of the review and compliance boundaries
❑ Setbacks as required by 15A NCAC 02T .1108
❑ Site property boundaries within 500 feet of all waste treatment, storage, and disposal site(s).
❑ A map showing the entire irrigation area with an overlay of the suitable irrigation area depicted by the soil scientist's
evaluation. The irrigation plans shall show each nozzle/emitter and wetted area (when applicable). Clearly label spray
irrigation zones as they will be operated.
❑ Plans must depict a completed design and not be labeled with preliminary phrases (e.g., FOR REVIEW ONLY, NOT FOR
CONSTRUCTION, etc.) that indicate that they are anything other than final plans. However, the plans may be labeled with
the phrase: FINAL DESIGN - NOT RELEASED FOR CONSTRUCTION
INSTRUCTIONS FOR FORM: RLAP 06-16 Page 2 of 3

I. Project Evaluation and Receiver Site Management Plan (All New Application Packages or Modifications that include new sites)
❑ Submit a project evaluation and a receiver site management plan (if applicable) with recommendations concerning cover crops
and their ability to accept the proposed application rates.
J. Hydrogeologic Report (All New Application Packages or Modifications involving increasing the total design capacity)
❑ Submit a detailed hydrogeologic evaluation in accordance with 15A NCAC 02T .1104(d)(4) and current Division Policy
available at: http://www.ncwater.org/Rules_ Policies_ and_Regulations/. The document shall be signed, sealed and dated by a
qualified professional.
K. Engineering Design Documents (All New or Modification Application Packages with fixed irrigation facilities or irrigation
facilities fed through fixed supply system)
❑ Submit engineering design documents that have been signed, sealed, and dated by a NC licensed Professional Engineer and/or
Professional Land Surveyor in accordance with 15A NCAC 02T . 1104(d)(2). For Modifications, submit an updated site map
specific to the modification(s) only.
❑ The design documents must include the following minimum items:
❑ Engineering plans for the facility and equipment except those previously permitted unless they are directly tied into the new
units or are critical to the understanding of the complete process;
❑ Specifications describing materials to be used, method of construction, and means for ensuring quality and integrity of the
finished product including leaking testing; and
❑ Engineering calculations including hydraulic and pollutant loading, sizing criteria, hydraulic profile, total dynamic head
curve analysis for each pump, and irrigation design.
❑ Soil mapping units shown on all disposal sites.
L. Water Balance (All New Application Packages or Modifications that include new sites utilizing fixed irrigation facilities or
irrigation facilities fed through fixed supply systems)
❑ Submit a completed and accurate water balance in accordance with 15A NCAC 02T .1104(d)(5) and current Division Policy
available at: http://www.ncwater.org/Rules_ Policies_ and Regulations/.
M. Property Ownership Documentation (All New or Modification Application Packages involving new and/or relocated treatment
or irrigation components)
❑ Property ownership documentation shall consist of one of the following:
❑ Legal documentation of ownership (i.e., GIS, deed or article of incorporation), or
❑ Written notarized intent to purchase agreement signed by both parties with a plat or survey map, or
n An easement running with the land specifically indicating the intended use of the property and meeting the requirements of
15A NCAC 02L .0107(f), or
❑ A written notarized lease agreement signed by both parties, indicating the intended use of the property, as well as a plat or
survey map.
ONE ORIGINAL AND TWO COPIES OF THE COMPLETED APPLICATION PACKAGE, INCLUDING ALL
SUPPORTING INFORMATION AND MATERIALS, SHALL BE SENT TO THE FOLLOWING ADDRESS:
NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY
DIVISION OF WATER RESOURCES
WATER QUALITY PERMITTING SECTION
NON -DISCHARGE PERMITTING UNIT
By U.S. Postal Service:
1617 MAIL SERVICE CENTER
RALEIGH, NORTH CAROLINA 27699-1617
TELEPHONE NUMBER: [phone]
By Courier/Special Delivery:
512 N. SALISBURY STREET
RALEIGH, NORTH CAROLINA 27604
FAX NUMBER: [phone]
INSTRUCTIONS FOR FORM: RLAP 06-16 Page 3 of 3

DWR
Division of Water Resources
State of North Carolina
Department of Environmental Quality
Division of Water Resources
15A NCAC 02T .1100 — RESIDUALS LAND APPLICATION PROGRAM
FORM: RLAP 06-16
I. APPLICANT INFORMATION:
1. Applicant's name:
Applicant type: ❑ Individual
❑ Corporation ❑ General Partnership Privately -Owned Public Utility
❑ Federal
0 State ❑ Municipal
County
Signature authority's name per 15A NCAC 02T .0106: Ken Galloway
Title: Plant Supervisor 4' Creek
Applicant's mailing address: PO Box I I I I
City: Statesville State: NC
Zip: 28687-1111
Telephone number: [phone]
Email Address: kgallowaykstatesvillenc.net
2. Consultant's name: M
License Number (for P.E.): _
Affiliation: ❑ On Staff ❑ Retained (Firm: )
Consultant's mailing address:
City: State:
Zip: �-
Telephone number: (_) _ _"
Email Address:
3. Agronomist's name:
License Number:
Affiliation: ❑ N/A ❑i On Staff
0 Retained (Firm:
Agronomist's mailing address: —1
City: State:
Zip: W-no
Telephone number: (_) _
Email Address: _
4. Soil Scientist's name: _�
License Number: 7V
Affiliation: ❑ N/A q On Staff
0 Retained (Firm: )
Soil Scientist's mailing address:
City: State:
Zip: a ----Am
Telephone number: (_) =
Email Address: _
5. Fee submitted: I (See Instruction B)
IL PERMIT INFORMATION:
1. Application is for (check all that apply): 0 new, ❑ modified, X renewed permit
2. If this application is being submitted to renew or modify an existing permit, provide the following:
Permit number: W00014543
Date of most -recently issued permit: March 2019
Date of most -recently certified Attachment A (if different than the permit): d
Date of most -recently certified Attachment B (if different than the permit): _
FORM: RLAP 06-16 Page 1 of 5

III. RESIDUALS LAND APPLICATION PROGRAM INFORMATION:
1. Residuals Processing Facility's physical address: 693 Bell Farm Road
City: Statesville State: NC Zip: 28625M
Coordinates: Latitude: 35' 46' 29N" Longitude: 80' 48' 50W"
Datum: Level of accuracy:
Method of measurement: GPS
2. County where residuals land application program is headquartered: IREDELL
3. List the Operator In Responsible Charge (ORC) and all Back -Up ORCs for the residuals land application program, their
certification numbers, and their affiliations in the following table:
4
Designation
Name
Affiliation
Certification Number
ORC
Andy Smith
City of Statesville
LA 985516
Back -Up ORC
Scott Austin
City of Statesville
LA 991939
Additional Back -Up
ORCs
(if applicable)
If an ORC and at least one Back -Up ORC are not currently designated for this residuals land application program, provide the
candidates' names, affiliations, and an estimated time schedule for each candidate's completion of the required training school
and certification test:
Complete the following tables regarding management of the residuals land application program:
a. Plant Available Nitrogen Summary: Determine the maximum plant available nitrogen (PAN) generated by all residuals
source -generating facilities as currently certified and proposed for certification with this application and list the results in the
following table:
Maximum amount of residuals to be certified: 1000 dry tons per year.
PAN
Pounds of PAN per Dry Ton
(Weighted Average)
Pounds of PAN per Year
Surface
Incorporation
or Injection
Surface
Incorporation
or Injection
First -Year
35.8
35,800
Five -Year Maximum Adjusted
179
179,000
b. Land Application Site Use Summary: Summarize information regarding the land application sites as currently certified and
proposed for certification with this application:
Category
Use
Acres
Comments
Crops
Forest or Plantation
Row Crops
15.3
Corn & Small Grain
Hay
Pasture
Total:
Methods
Surface
Incorporation or Injection
Total:
FORM: RLAP 06-16 Page 2 of 5

c. Residuals Land Application Summary: Determine the minimum acreage required to land apply the residuals as currently
certified and proposed for certification assuming the scenarios listed in the following table:
Assumed
Application Rate
(lbs PAN/ac yr)
Acres Required Using
First -Year PAN Concentrations
Acres Required Using
Five -Year Maximum Adjusted PAN
Concentrations
Surface
Incorporation or
Injection
Surface
Incorporation or
Injection
50
716
3580
100
358
1790
150
239
1195
200
179
895
6. If applicable, provide a plan and a schedule to resolve any known issues that would prevent land application of the proposed
residuals due to the violation of North Carolina Administrative Code (e.g. not enough storage, not enough land, vector reduction
practices not in place, etc.): -M
7. Specify type of residuals program (See Instruction F): E Non -dedicated ❑ Dedicated
If Dedicated, specify the following (check all that apply):
Residuals program contains any land application site(s) that receives residuals at rates or frequencies greater than agronomic
rates, explain;
❑ Residuals program contains any land application site(s) that is used primarily for residuals disposal, and agricultural crop
production is of secondary importance, explain;
❑ Residuals program contains any land application site(s) that receives residuals through fixed irrigation facilities or irrigation
facilities fed through a fixed supply system, explain;
IV. RESIDUALS SOURCE INFORMATION: (Required for all new, renewed, or modified residuals source)
Complete and submit the following Residuals Source Certification and all associated documentation.
Residuals Source
Certification
V. LAND APPLICATION SITE INFORMATION: (Required for all new, renewed, or modified land application site)
Complete and submit the following Land Applications Site Certification and all associated documentation.
Land Application Siite
Certification.doc
FORM: RLAP 06-16 Page 3 of 5

Note: Item VI. Applicable to Dedicated Program with fixed irrigation system only.
VI. DESIGN INFORMATION FOR FIXED IRRIGATION SYSTEM
1. The irrigation system is: a Spray ❑ Drip
2. Disposal system is: ❑ existing ❑ proposed.
3. Minimum depth to mean seasonal high water table (SHWT) within irrigation sites(s) per Soil Scientist's Evaluation: feet
below ground surface. Rules 15A NCAC 02T .0505(p) requires at least one -foot vertical separation between SHWT and ground
surface.
4. Are there any artificial drainage or water movement structures within 200 feet of any irrigation area?
❑ Yes or ❑ No If Yes, please explain if the soil scientist report addresses artificial structures and please indicate if
structures are to be maintained or modified:
5. Loading rates recommended by the Soil Scientist Evaluation:
Soil Series
Fields within Soil Area
Recommended
Loading Rate
(in/hr)
Recommended
Loading Rate
in/yr
6. Design loading rates are equal or less than the loading rates recommended by Soil Scientist?
❑ Yes or ❑ No If No, explain why 15A NCAC 02T .0505(n) is not met:
7. Non -dedicated System Design (fill in the appropriate information for either a spray or drip irrigation system):
Field / Zone
Design Area
(ft2)
Number of
Nozzles
Maximum Application
Rate ( allons/hr)
Design Annual Loading
Rate ( allons/ r)
Total
Spray Irrigation Design Element
Plan Sheet
Number
Specification
Pa a Number
Wetted diameter of nozzles
ft
Wetted area of nozzles
It,
Nozzle capacity
gpm
Nozzle manufacturer / model
/
Elevation of highest nozzle
ft
FORM: RLAP 06-16 Page 4 of 5

Applicant's Certification (signing authority must be in compliance with 15A NCAC 02T .0106):
The applicant or any affiliate has not been convicted of an environmental crime, has not abandoned a wastewater facility without proper
closure, does not have an outstanding civil penalty where all appeals have been exhausted or abandoned, are compliant with any active
compliance schedule, and do not have any overdue annual fees under Rule 15A NCAC 02T .0105.
® Yes JU No, Explain;
I, Ken Galloway Plant Supervisor 4' Creek
(Signature Authority's Name — PLEASE PRINT) (Title)
attest that this application for City of Statesville 41 Creek WWTP Land Application
(Facility Name)
has been reviewed by me and is accurate and complete to the best of my knowledge. I understand that the Division of Water Resources
may not conduct a technical review of this program and approval does not constitute a variance to any rules or statutes unless specifically
granted in the permit. Further, any discharge of residuals to surface waters or the land will result in an immediate enforcement action,
which may include civil penalties, injunctive relief, and/or criminal prosecution. I will make no claim against the Division of Water
Resources should a condition of this permit be violated. I also understand that if all required parts of this application are not completed
and that if all required supporting information and attachments are not included, this application package will be returned to me as
incomplete.
Note: In accordance with North Carolina General Statutes § 143-215.6A and § 143-215.613, any person who knowingly makes any false
statement, representation, or certification in any application shall be guilty of a Class 2 misdemeanor, which may include a fine not to
exceed $10,000 as well as civil penalties up to $25,000 per violation.
Signature:
Date:
FORM: RLAP 06-16 Page 5 of 5

State of North Carolina
DWR
Department of Environmental Quality
Division of Water Resources
Division of Water Resources RESIDUALS SOURCE CERTIFICATION
INSTRUCTIONS FOR FORM: RSC 06-16
Please use the following instructions as a checklist in order to ensure all required items are submitted. Adherence to these
instructions and checking the provided boxes will help produce a quicker review time and reduce the amount of additional
information requested. Failure to submit all of the required items will lead to additional processing and review time for the
permit application. Unless otherwise noted, the Applicant shall submit one original and two copies of the application and
supporting documentation
For more information, visit the Water Quality Permitting Section's Non -Discharge Permitting Unit
General — This certification provides detailed information of residuals source generating facility and its residuals quality for land
application, distribution, or disposal in accordance with 15A NCAC 02T .1100. Do not submit this certification for review without
a corresponding application form (FORM: RLAP 11-15, FORM: DCAR 11-15, or FORM: SDR 11-15).
Unless otherwise noted, the Applicant shall submit one original and two copies of the application and supporting documentation listed
below.
A. Residuals Source Certification (FORM: RSC 11-15):
❑ Submit the completed and appropriately executed Residuals Source Certification (FORM: RSC 11-15) form. Please do not
make any unauthorized content changes to this form. If necessary for clarity or due to space restrictions, attachments to the
application may be made, as long as the attachments are numbered to correspond to the section and item to which they refer.
❑ For new or renewed permits, submit a separate certification for each source facility.
❑ For modified permits, submit a separate certification for only those facilities that are affected by the proposed modification.
❑ Complete the residuals source facility summary page. List all new, renewed, or modified facilities.
B. Residuals Source -Generating Facility Information:
❑ For each source facility, attach the following:
❑ Vicinity map - A vicinity map that shows the location of the facility and meets all of the criteria in the "Map Guidance for
Residuals Land Application Permits".
❑ Process flow diagram and/or narrative - A detailed narrative and/or process flow diagram that describes how the residuals
are to be generated, treated, processed, and stored at the facility.
❑ Quantitative justification for residuals production rate - A quantitative justification for the value provided in Item I. 8.
Ensure that the amount of residuals listed is the maximum amount expected to be generated by the facility for the life of
the permit. In addition, ensure that this amount is equivalent to that which is actually to be land applied, distributed,
and/or disposed, including any chemicals, amendments, or other additives that are added to the residuals during
processing.
❑ Sampling plan - A detailed sampling plan for the residuals source -generating facility. Ensure that the plan identifies
sampling points, sampling frequency, sample type, as well as the Division -certified laboratory to be used. In addition,
ensure that the plan details how the facility and/or the residuals are monitored for any applicable pathogen reduction and
vector attraction reduction requirements. Note that all sampling and monitoring must be completed on the residuals as
they are to be land applied, distributed, and/or disposed.
C. Residuals Quality Information:
❑ For each source facility, attach the following:
❑ Laboratory analytical reports and operational data - reports for all laboratory analyses used to complete this certification.
❑ Documentation that the facility complies and/or the residuals comply with any applicable pathogen reduction and vector
attraction reduction requirements.
❑ For new facility that may have not yet been constructed and analytical results of residuals cannot be obtained, please
attach analytical results of residuals generated from a similar facility along with the description of similarities of the two
facilities.
INSTRUCTIONS FOR FORM: RSC 06-16 Page 1 of 1

RESIDUALS SOURCE FACILITY SUMMARY
Applicant's name: m
Status
Code
Facility Permit Holder
Facility Name
County
Permit Number
Maximum Dry Tons Per Year
Current b
Proposed
R
City of Statesville
41 Creek WWTP
Iredell
NCO031836
1000
'Status Code for source facility are: ♦ N (New) ♦ R (Renewed) ♦ M (Modified) ♦ D (Deleted)
b The amount of residuals currently permitted for distribution, land application, or disposal (i.e, not applicable to new facility).
SUMMARY FOR FORM: RSC 06-16 Page 1

DWR
Division of Water Resources
State of North Carolina
Department of Environmental Quality
Division of Water Resources
RESIDUALS SOURCE CERTIFICATION
FORM: RSC 06-16
I. RESIDUALS SOURCE -GENERATING FACILITY INFORMATION (See Instruction B.):
1. Facility Name: 4' Creek WWTP
2. Facility permit holder is: I[] Federal, 0 State, 0 Local Government, or 0 Private.
Facility permit issued by: Div. of Water Resources, Div. of Environmental Health,
or Other (explain: �.
3. Facility contact person and title: Ken Galloway
Complete mailing address: PO Box 1111
City: Statesville State: NC Zip: 28687-1111
Telephone number: (704) 878-343/ E-mail address: kgallowaykstatesvillenc.net
4. Facility physical address: 693 Bell Farm Road
City: Statesville State: NC Zip: 28625=
Coordinates: Latitude: 35' 46' 29N" Longitude: -80. 48' 50W"
Datum: _ Level of accuracy: _
Method of measurement: GPS
5. Purpose of the facility:
treatment of municipal wastewater, treatment of 100% domestic wastewater,
treatment of potable water, treatment of 100% industrial wastewater,
treatment of industrial wastewater mixed with domestic wastewater,
(approximate percentages: 40 % industrial and 60 % domestic)
other (explain: _ ).
6. Does the facility have an approved pretreatment program: Yes No
7. Facility permitted/design flow: 6 MGD and facility average daily flow: 3.0 MGD
8. Average amount of residuals being generated at this facility 1200 dry tons per year.
9. Specify the following regarding treatment and storage volumes available at the facility:
Type and volume of residuals treatment: 3 METER BELT
Type and volume of residuals storage (i.e., outside of residuals treatment units): 1.5 mg Aerobic Digester
II. RESIDUALS QUALITY INFORMATION (See Instruction C.):
1. Specify if residuals are regulated under:
40 CFR Part 503 or 40 CFR Part 257.
Note: Only residuals that are generated during domestic/municipal wastewater treatment processes are regulated under 40
CFR Part 503, otherwise, the residuals are regulated under 40 CFR Part 257.
2. Specify if residuals are defined under 15A NCAC 02T.1102(6) as:
Biological 0 Non -Biological
Note: Biological residuals are residuals that have been generated during the treatment of domestic wastewater, animal
processing wastewater, or the biological treatment of industrial wastewater (biological treatment is a system that utilizes
biological processes including lagoons, activated sludge systems, extended aeration systems, and fixed film systems).
FORM: RSC 06-16 Page 1 of 5

3. Hazardous Waste Determination: Complete the following to demonstrate that the residuals are non -hazardous under
RCRA: (Note - this item does not have to be completed for facilities that are less than 0.5 MGD in design flow that treat
100% non -municipal, domestic wastewater only)
a. Are the residuals listed in 40 CFR §261.31-§261.33: 0 yes ® no.
If yes, list the number(s): _
b. Specify whether or not the residuals exhibit any of the characteristics defined by 40 CFR §261.21-
261.24: 0 yes 0 no.
Fill in the following tables with the results of the latest toxicity characteristic leaching procedure (TCLP) analysis as
well as those for corrosivity, ignitability, and reactivity:
Laboratory: Summit and Date of analysis: 1/19/23
Passed corrosivity test: yes ❑ no. pH: s.u. (2 <pH < 12.5)
Passed ignitability test: yes ❑ no. Flashpoint: = OF (> 140°F)
Passed reactivity test: ® yes ❑no. HCN: M mg/kg (<250) & H2S: _ mg/kg (<500)
TCLP Parameter
Limit
(mgfi)
Result
(m917)
TCLP Parameter
Limit
(m917)
Result
(mgfi)
Arsenic
5.0
<0.5
Hexachlorobenzene
0.13
<0.05
Barium
100.0
<5
Hexachloro-1,3-Butadiene
0.5
<0.02
Benzene
0.5
<0.1
Hexachloroethane
3.0
<0.1
Cadmium
1.0
<0.1
Lead
5.0
<0.5
Carbon Tetrachloride
0.5
<0.1
Lindane
0.4
Chlordane
0.03
<0.0125
Mercury
0.2
<0.002
Chlorobenzene
100.0
<1
Methoxychlor
10.0
<0.0025
Chloroform
6.0
<0.1
Methyl Ethyl Ketone
200.0
<2
Chromium
5.0
<0.2
Nitrobenzene
2.0
<0.1
m-Cresol
200.0
Pentachlorophenol
100.0
<0.25
o-Cresol
200.0
Pyridine
5.0
<0.25
p-Cresol
200.0
Selenium
1.0
<0.05
Cresol
200.0
Silver
5.0
<0.5
2,4-D
10.0
<0.5
Tetrachloroethylene
0.7
<0.1
1,4-Dichlorobenzene
7.5
<0.1
Toxaphene
0.5
<0.025
1,2-Dichloroethane
0.5
<0.1
Trichloroethylene
0.5
<0.1
1,1-Dichloroethylene
0.7
<0.1
2,4,5-Trichlorophenol
400.0
<0.25
2,4-Dinitrotoluene
0.13
<0.05
2,4,6-Trichlorophenol
2.0
<0.25
Endrin
0.02
<0.0025
2,4,5-TP (Silvex)
1.0
<0.5
Heptachlor and its Hydroxide
0.008
<0.0025
Vinyl Chloride
0.2
<0.04
FORM: RSC 06-16 Page 2 of 5

4. Metals Determination: Complete one of the following tables (i.e., as applicable) to demonstrate that the residuals do not
violate the ceiling concentrations for metals regulated under 15A NCAC 02T .1105.
a. For Distribution/Land Application: Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: Waypoint Analytical and Date of analysis: 10/04/23
Parameter
Ceiling
Concentration Limits
(ClassA & ClassB)
(mglkg)
Monthly Average
Concentration Limits
(Class A Only)
(mglkg)
Result
(mglkg)
Arsenic
75
41
37.1
Cadmium
85
39
6.5
Copper
4,300
1,500
77.7
Lead
840
300
83.5
Mercury
57
17
<1.37
Molybdenum
75
n/a
2.37
Nickel
420
420
129
Selenium
100
100
3.98
Zinc
7,500
2,800
554
b. For Surface Disposal Unit (landfill): Fill in the following table with the results of the latest analyses (i.e., on a dry weight
basis) for the following metal parameters:
Laboratory: = and Date of analysis: =
Distance from Disposal
Unit to Boundary to
Closest Property Line
(meters, check one)
Arsenic
(mg/kg)
Chromium
(mg/kg)
Nickel
(mg/kg)
❑ > 0 but < 25
30
200
210
❑ > 25 but < 50
34
220
240
❑ > 50 but < 75
39
260
270
❑ > 75 but < 100
46
300
320
❑ > 100 but < 125
53
360
390
❑ > 125
62
450
420
Result (mg/kg)
FORM: RSC 06-16 Page 3 of 5

5. Nutrient/Micronutrient Determination: Complete the following:
a. Total solids: 13.9 %.
b. Fill in the following table with the results of the latest analyses (i.e., on a dry weight basis) for the following nutrient and
rmcronutnent parameters:
Laboratory: Waypoint Analytical and Date of analysis: 10/04/23
Parameter
Result
(mg1kg)
Aluminum
100000
Ammonia -Nitrogen
5460
Calcium
623
Magnesium
13200
Nitrate -Nitrite Nitrogen
<36
pH (Standard Unit)
7.8
Phosphorus
1780
Potassium
3940
Sodium
<180
Total Kjeldahl Nitrogen
55900
c. Using the results listed in Item IL 5b. above, calculate the sodium adsorption ration (SAR): 0.31
[Note: If residuals contain SAR of 10 or higher, the applicant shall obtain recommendations from the local Cooperative
Extension Office, the Department of Agriculture and Consumer Services, the Natural Resource Conservation Service, a
North Carolina Licensed Soil Scientist, or an agronomist, prior to land application of residuals. The recommendations shall
address the sodium application rate, soil amendments (e.g., gypsum, etc.), or a mechanism for maintaining site integrity
and conditions conducive to crop growth].
d. Specify the mineralization rate to be used in calculating the plant available nitrogen (PAN) of the residuals: 30 %. This
rate is a (check one): ❑ default value, or 0 actually established.
If the residuals are not generated from the treatment of municipal or domestic wastewater, ex lain or provide technical
justification as to why the selected default value is appropriate to be applied to these residuals:
e. Calculate the PAN for the residuals (i.e., on a dry weight basis) and fill the results in the following table:
Application Method
First (1s) Year PAN
Five -Year
Maximum Adjusted PAN
(mg1kg)
(mg/kg)
Surface
17898
89490
Injection/Incorporation
20628
103140
6. Other Pollutants Determination: S ecify whether or not there are any other pollutants of concern in the residuals and provide
the results of the latest analyses:
FORM: RSC 06-16 Page 4 of 5

7. Pathogen Reduction: Per 15A NCAC 02T.1106, specify how residuals will meet the pathogen reduction requirements:
a. For Distribution/Land Application of Class A or Equivalent:
71 A fecal coliform density that is demonstrated to be less than 1,000 MPN per gram of total dry solids,
or
JJ A salmonella sp. density that is demonstration to be less than 3 MPN per 4 grams of total dry solids.
AND one of the followings (except for non -biological residuals):
14 Alternative 1 [15A NCAC 02T.I 106(b)(3)(A)] - Time/Temperature Compliance.
q Alternative 2 [15A NCAC 02T.I 106(b)(3)(B)] - Alkaline Treatment.
q Alternative 3 [15A NCAC 02T.I 106(b)(3)(C)] - Prior Testing for Enteric Virus/Viable Helminth Ova.
q Alternative 4 [15A NCAC 02T.I 106(b)(3)(D)] - No Prior Testing for Enteric Virus/Viable Helminth Ova.
JA Alternative 5 [15A NCAC 02T.I 106(b)(3)(E)-(K)] - Process to Further Reduce Pathogens (PFRP).
Specify one: composting, 0 heat drying, 77 heat treatment,
thermophilic aerobic digestion, ❑ beta ray irradiation,
El gamma ray irradiation, or ❑ pasteurization.
b. For Land Application of Class B:
Alternative 1 [15A NCAC 02T.I 106(c)(1)] - Fecal Coliform Density Demonstration.
Alternative 2 [15A NCAC 02T.I 106(c)(2 - Process to Significantly Reduce Pathogens (PSRP).
Specify one: El aerobic digestion, air drying, ❑ anaerobic digestion,
El composting, or lime stabilization.
c. For Surface Disposal:
Select One of the Class A or Equivalent Pathogen Reduction Alternatives in Item II. 7a. above.
Select One of the Class B or Equivalent Pathogen Reduction Alternatives in Item II. 7b. above.
J Exempt -If Daily Cover Alternative is chosen in Item II.8. below [15A NCAC 02T.1106(a)(2)].
J Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
8. Vector Attraction Reduction (VAR): Per 15A NCAC 02T.1107, specify how residuals will meet the VAR requirements:
El Alternative 1 [15A NCAC 02T.I 107(a)(1)] - 38% Volatile Solids Reduction (Aerobic/Anaerobic Digestion).
El Alternative 2 [15A NCAC 02T.I 107(a)(2)] - 40-Day Bench Scale Test (Anaerobic Digestion).
El Alternative 3 [15A NCAC 02T.I 107(a)(3)] - 30-Day Bench Scale Test (Aerobic Digestion).
Alternative 4 [15A NCAC 02T.I 107(a)(4)] - Specific Oxygen Uptake Rate Test (Aerobic Digestion).
El Alternative 5 [15A NCAC 02T.I 107(a)(5)] - 14-Day Aerobic Processes.
El Alternative 6 [15A NCAC 02T.I 107(a)(6)] - Alkaline Stabilization.
El Alternative 7 [15A NCAC 02T.I 107(a)(7)] - Drying of Stabilized Residuals.
El Alternative 8 [15A NCAC 02T.I 107(a)(8)] - Drying of Unstabilized Residuals.
El Alternative 9 [15A NCAC 02T.I 107(a)(9)] - Injection.
El Alternative 10 [15A NCAC 02T.I 107(a)(10)] - Incorporation.
q Alternative for Surface Disposal Units Only - Soil/Other Material Cover [ 15A NCAC 02T.I 107(b)(2)].
Ja Not Applicable - Non -Biological Residuals with NO Domestic Wastewater Contribution.
Note: For animal processing residuals, only alternatives 9 or 10 may be chosen due to the nuisance conditions that typically
occur when these residuals are applied and left on the land surface.
FORM: RSC 06-16 Page 5 of 5

January 25, 2024
Non -Discharge Permitting Unit
Water Quality Permitting Section
Raleigh Central Office
1617 Mail Service Center
Raleigh, NC 27699-1636
Re: City of Statesville Land Application Program Permit Renewal
Permit No. WO0014543
To Whom It May Concern,
The City of Statesville is requesting a permit renewal for permit # WO0014543.
Enclosed you will find Forms RLAP 06-16, RSC 06-16 and LASC 06-16 with additional supporting
documents per the instruction sheet for the aforementioned forms. The following is a list of these
documents.
• A brief narrative explaining how the City of Statesville handles its bio solids. How the residuals
are processed and treated, where the residuals will be stored and how the residuals will be
distributed.
• Lab data.
• Vicinity maps.
• Flow Schematic.
• Spill Control Plan.
• Sampling schedule for the bio-solids.
• Sample and Monitoring Plan Narrative.
CC: City of Statesville

The following is a brief narrative regarding the sludge management plan for the City of Statesville:
Bio solids generated at both of the WWTP's. The bio-solids at both of these facilities
are currently stabilized using an aerobic digester and dewatered using a 2 meter belt
filter press. After dewatering, the residuals are transferred by a dump truck to the
sludge storage pad or pumped to the existing Sta-Lime processing area. After the Sta-
Lime process has been completed, the final product is made available to the local
farmers at no cost or set aside for land application by a private contractor through an
existing agreement held with the City.
The permit WO0014543 has never been utilized and is considered a back-up to the existing
permits in the City of Statesville sludge management program.
Should you require more information, or if further action is required, you can contact me at
704-878-3438 or email me at [e-mail]
Sincerely,
Ken Galloway
Plant Supervisor, Fourth Creek WWTP

284 Boger Avenue
Mocksville, NC 27028
www.synagro.com
JANUARY 13, 2024
Mr. Ken Galloway
City of Statesville
PO Box 1111
Statesville, NC 28687
Dear Mr. Galloway:
SYNAGRO
Enclosed is Synagro's monthly report for December 2023. This report covers land application
operations in Iredell and Rowan Counties.
If you have any questions, please contact me at 704-881-3429.
Sincerely,
Alex Fox
Technical Services Specialist
Enclosure
YOUR PARTNER FORA CLEANER, GREENERWORLD

SYNAGRO
December 2023
LAND APPLICATION OF RESIDUALS
MONTHLY REPORT
Statesville, NC
Iredell and Rowan Counties

SYNAGRO CENTRAL, LLC
435 WILLIAMS COURT, SUITE 100
BALTIMORE, MD 21220
Project: 2084 - STATESVILLE, NC
Plant: 01 - FOURTH CREEK
Date Applied: 12/1/2023 thru 12/31/2023
Field Where Applied: NC-IR-00036-0-0004-
Farmer/Site Operator: CHRIS CARTNER
Date Applied Total UNIT Type
12/07/2023 128.00 Y CAK
12/08/2023 112.00 Y CAK
CAK Cubic Yards 240.00
Field Where Applied: NC-RA-00005-0-0002-
Farmer/Site Operator: TIM LIVINGGOOD
Date Applied Total UNIT Type
12/20/2023 45.00 Y CAK
12/21 /2023 15.00 Y CAK
CAK Cubic Yards 60.00
Plant total (Cu Yards) 300.00
Report Run Date: 1/10/2024 1 of 2

SYNAGRO CENTRAL, LLC
435 WILLIAMS COURT, SUITE 100
BALTIMORE, MD 21220
Project: 2084 - STATESVILLE, NC
Plant: 02 - THIRD CREEK
Date Applied: 12/1/2023 thru 12/31/2023
Field Where Applied: NC-RA-00005-0-0002-
Farmer/Site Operator: TIM LIVINGGOOD
Date Applied Total
12/21 /2023 15.00
CAK Cubic Yards 15.00
Plant total (Cu Yards) 15.00
UNIT Tvae
Y CAK
Report Run Date: 1/10/2024 2 of 2

Dosage Rate Evaluation Report
Product Type: STATESVILLE, NC
FOURTH CREEK CAKE (STFCC)
Sample Date: 10/3/2023
Usage From: 10/1/2023 To 12/31/2023
Report #: 23-277-0005
Parameter
PPM (mg/ka)
Lbs/Dry Ton
PA-N (Injected)
20628
41.256
PA-N (Surface w/ Incorp.)
20628
41.256
PA-N (Surface w/o Incorp.)
17898
35.796
TKN (TKN)
55900
111.8
Ammonia Nitrogen (Am)
5460
10.92
Nitrate Nitrogen (Nin)
<36
<0.072
Organic Nitrogen (Orn)
50440
100.88
Total Phosphorus (P)
1780
3.56
Total Phosphate (P205)
4094
8.188
Estimated Avail. P205
2047
4.094
Total Potassium (K)
3940
7.88
Total Potash (K20)
4728
9.456
Arsenic (As)
37.1
0.074
Cadmium (Cd)
6.5
0.013
Chromium (Cr)
104
0.208
Copper (Cu)
77.7
0.155
Lead (Pb)
83.5
0.167
Mercury (Hg)
<1.37
<0.003
Molybdenum (Mo)
2.37
0.005
Nickel (Ni)
129
0.258
Selenium (Se)
3.98
0.008
Zinc (Zn)
554
1.108
Aluminum (AI)
100000
200
Calcium (Ca)
623
1.246
Iron (Fe)
150000
300
Sodium (Na)
<180
<0.36
Sulfur (S)
460
0.92
Magnesium (Mg)
13200
26.4
Manganese (Mn)
6000
12
Percent Solids: 13.90 % pH Level: 7.80
Calculations:
PA-N (ppm) = [ (fl) (ppm Org. N) ] + [ (V1) (ppm Ammonia N) ] + (ppm Nitrate N)
P x 2.3 = Total P205 Total P205 x .5 = Estimated available P205
Kx1.2=K20
ppm or mg/kg x .002 = Ibs/dry ton
Biosolids/Residuals Application State: NORTH CAROLINA
Organic Nitrogen Mineralization Rate (fl ): For AEROBICALLY DIGESTED: 30.00%
Ammonia Nitrogen Non -Volatilized Fraction (V1): For Injected: 1.00
For Surface Appl.: 0.50
For Surface w/Incorp.: 1.00
NR = Data not Reported to Synagro or Data not Required
Notes:
2084 01 CAK Control # 87581 Report Date: 1/2/2024

Waypointo
ANALYTICAL
10/18/2023
Synagro Central LLC/ Technical
Mary Brewer
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 23-277-0005
Project Description: 4th Creek
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Dear Mary Brewer:
Waypoint Analytical Virginia, Inc. received sample(s) on 10/4/2023 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information
Sincerely,
&;'-� ­AldA�
Brandi Watson
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

•
7621 Whitepine Road, Richmond, VA 23237
Waypoint
Main 804-743-9401 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 23-277-0005
Client Project Description: 4th Creek
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
63607
4th
Creek
Solids
10/03/2023
09:30
10/04/2023
63607
4th
Creek
Solids
10/03/2023
09:30
10/04/2023
63607
4th
Creek
Solids
10/03/2023
09:30
10/04/2023
63607
4th
Creek
Solids
10/03/2023
09:30
10/04/2023
63607
4th
Creek
Solids
10/03/2023
09:30
10/04/2023
63607
4th
Creek
Solids
10/03/2023
09:30
10/04/2023
63607
4th
Creek
Solids
10/03/2023
09:30
10/04/2023
63607
4th
Creek
Solids
10/03/2023
09:30
10/04/2023
SM-4500-NH3C
WP MTN
9045D
WP MTN
4500NO3F-2016
WP MTN
6010D
WP MTN
SW-7471B
WP MTN
SM-4500-NH3C-TKN
WP MTN
SM-2540G
WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 2 of 8

Waypointo
ANALYTICAL
46622
Synagro Central LLC/ Technical
Project 4th Creek
Mary Brewer
284 Boger Road
Information
Mocksville , NC 27028
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Report Number : 23-277-0005 REPORT OFANALYSIS
Report Date : 10/18/2023
Received : 10/04/2023
Brandi Watson
Lab No : 63607
Sample ID : 4th Creek
Matrix: Solids
Sampled: 10/3/2023 9:30
Test
Results
Units
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
86.1
%
0.010
1
10/05/2316:10
CAH
SM-2540G
Phosphorus
1780
mg/Kg -
dry
36.0
1
10/07/23 02:01
BKN
6010D
Sulfur
460
mg/Kg -
dry
71.9
1
10/07/23 02:01
BKN
6010D
Calcium
623
mg/Kg -
dry
360
1
10/07/23 02:01
BKN
6010D
Aluminum
100000
mg/Kg -
dry
360
10
10/09/23 12:58
TJS
6010D
Manganese
6000
mg/Kg -
dry
36.0
10
10/09/23 12:58
TJS
6010D
Copper
77.7
mg/Kg -
dry
3.60
1
10/07/23 02:01
BKN
6010D
Zinc
554
mg/Kg -
dry
8.99
1
10/07/23 02:01
BKN
6010D
Organic N
50440
mg/Kg -
dry
1799
1
10/16/23 14:30
CALCULATION
Nickel
129
mg/Kg -
dry
1.80
1
10/07/23 02:01
BKN
6010D
Lead
83.5
mg/Kg -
dry
2.16
1
10/07/23 02:01
BKN
6010D
Arsenic
37.1
mg/Kg -
dry
3.60
1
10/07/23 02:01
BKN
6010D
Selenium
3.98
mg/Kg -
dry
3.60
1
10/07/23 02:01
BKN
6010D
Test
Results
Units
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Total Solids 13.9 % 0.010 1 10/05/23 16:10 CAH SM-2540G
Qualifiers/ DF Dilution Factor
Definitions
MQL Method Quantitation Limit
Page 3 of 8

Waypointo
ANALYTICAL
46622
Synagro Central LLC/ Technical
Project 4th Creek
Mary Brewer
284 Boger Road
Information
Mocksville , NC 27028
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Report Number : 23-277-0005 REPORT OFANALYSIS
Report Date : 10/18/2023
Received : 10/04/2023
Brandi Watson
Lab No : 63607
Sample ID : 4th Creek
Matrix: Solids
Sampled: 10/3/2023 9:30
Test
Results
Units
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Total Kjeldahl Nitrogen
55900
mg/Kg -
dry
1800
1
10/18/23 10:30
JPJ ;M-4500-NH3C-TKI`
Potassium
3940
mg/Kg -
dry
71.9
1
10/07/23 02:01
BKN
6010D
Magnesium
13200
mg/Kg -
dry
36.0
1
10/07/23 02:01
BKN
6010D
Sodium
<180
mg/Kg -
dry
180
1
10/07/23 02:01
BKN
6010D
Iron
150000
mg/Kg -
dry
719
10
10/09/23 12:58
TJS
6010D
Ammonia Nitrogen
5460
mg/Kg -
dry
719
1
10/16/23 14:30
JPJ
SM-4500-NH3C
Nitrate+Nitrite-N
<36.0
mg/Kg -
dry
36.0
1
10/11/23 15:35
CLP
4500NO3F-2016
Cadmium
6.50
mg/Kg -
dry
0.719
1
10/07/23 02:01
BKN
6010D
Chromium
104
mg/Kg -
dry
1.80
1
10/07/23 02:01
BKN
6010D
Mercury
<1.37
mg/Kg -
dry
1.37
1
10/09/23 11:26
MRE
SW-7471B
pH
7.8
S.U.
1
10/06/2316:07
CNB
9045D
Total Volatile Solids
65.3
%
0.010
1
10/05/23 16:10
CAH
SM-2540G
Molybdenum
2.37
mg/Kg -
dry
1.80
1
10/07/23 02:01
BKN
6010D
Qualifiers/ DF Dilution Factor
Definitions
MQL Method Quantitation Limit
Page 4 of 8

Waypointo
ANALYTICAL
Client: Synagro Central LLC/ Technical
Project: 4th Creek
Lab Report Number: 23-277-0005
Date: 10/18/2023
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Aluminum
QC Batch No: 1-709731/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Calcium
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Cadmium
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Copper
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Iron
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Potassium
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Magnesium
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Page 5 of 8

Waypointo
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Analyte: Manganese
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Phosphorus
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Lead
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Zinc
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 97716 (Annual Sludge)
Analyte: Mercury
QC Batch No: 1-709569/1-709290
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 6 of 8

WayPAoInt..
NALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46622
Customer Name: Synagro Central LLC/ Technical
Report Number: 23-277-0005
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: IDavid Lennon Date & Time: 10/04/2023 09:59:25
Page 7 of 8

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Page 8 of 8

Dosage Rate Evaluation Report
Product Type: STATESVILLE, NC THIRD CREEK CAKE (STTCC)
Sample Date: 10/3/2023
Usage From: 10/1/2023 To 12/31/2023
Report #: 23-277-0004
Parameter
PPM (mg/kg)
Lbs/Dry Ton
PA-N (Injected)
19045
38.089
PA-N (Surface w/ Incorp.)
19045
38.089
PA-N (Surface w/o Incorp.)
17395
34.789
TKN (TKN)
55600
111.2
Ammonia Nitrogen (Am)
3300
6.6
Nitrate Nitrogen (Nin)
39.7
0.079
Organic Nitrogen (Orn)
52350
104.7
Total Phosphorus (P)
29900
59.8
Total Phosphate (P2O5)
68770
137.54
Estimated Avail. P2O5
34385
68.77
Total Potassium (K)
2630
5.26
Total Potash (K2O)
3156
6.312
Arsenic (As)
4.69
0.009
Cadmium (Cd)
2.62
0.005
Chromium (Cr)
39
0.078
Copper (Cu)
312
0.624
Lead (Pb)
22.1
0.044
Mercury (Hg)
<1.02
<0.002
Molybdenum (Mo)
16
0.032
Nickel (Ni)
33.9
0.068
Selenium (Se)
4.86
0.01
Zinc (Zn)
701
1.402
Aluminum (AI)
26200
52.4
Calcium (Ca)
8250
16.5
Iron (Fe)
27600
55.2
Sodium (Na)
672
1.344
Sulfur (S)
8470
16.94
Magnesium (Mg)
2540
5.08
Manganese (Mn)
1230
2.46
Percent Solids: 17.70 % pH Level: 6.90
Calculations:
PA-N (ppm) _ [ (fl) (ppm Org. N) ] + [ (V1) (ppm Ammonia N) ] + (ppm Nitrate N)
P x 2.3 = Total P2O5 Total P2O5 x .5 = Estimated available P2O5
Kx1.2=K2O
ppm or mg/kg x .002 = Ibs/dry ton
Biosolids/Residuals Application State: NORTH CAROLINA
Organic Nitrogen Mineralization Rate (fl ): For AEROBICALLY DIGESTED: 30.00%
Ammonia Nitrogen Non -Volatilized Fraction (V1): For Injected: 1.00
For Surface Appl.: 0.50
For Surface w/Incorp.: 1.00
NR = Data not Reported to Synagro or Data not Required
Notes:
2084 02 CAK Control # 87580 Report Date: 1/2/2024

Waypointo
ANALYTICAL
10/18/2023
Synagro Central LLC/ Technical
Mary Brewer
284 Boger Road
Mocksville, NC, 27028
Ref: Analytical Testing
Report Number: 23-277-0004
Project Description: 3rd Creek
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Dear Mary Brewer:
Waypoint Analytical Virginia, Inc. received sample(s) on 10/4/2023 for the analyses presented in the following
report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Sub -contracted testing is noted on the Sample Summary Table
if applicable.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2012) and NELAC unless otherwise indicated.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information
Sincerely,
&;'-� ­AldA�
Brandi Watson
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

•
7621 Whitepine Road, Richmond, VA 23237
Waypoint
Main 804-743-9401 0 Fax [phone]
ANALYTICAL www.waypointanalytical.com
Sample Summary Table
Report Number: 23-277-0004
Client Project Description: 3rd Creek
Lab No Client Sample ID Matrix Date Collected Date Received Method Lab ID
63606
3rd
Creek
Solids
10/03/2023
07:30
10/04/2023
63606
3rd
Creek
Solids
10/03/2023
07:30
10/04/2023
63606
3rd
Creek
Solids
10/03/2023
07:30
10/04/2023
63606
3rd
Creek
Solids
10/03/2023
07:30
10/04/2023
63606
3rd
Creek
Solids
10/03/2023
07:30
10/04/2023
63606
3rd
Creek
Solids
10/03/2023
07:30
10/04/2023
63606
3rd
Creek
Solids
10/03/2023
07:30
10/04/2023
63606
3rd
Creek
Solids
10/03/2023
07:30
10/04/2023
SM-4500-NH3C
WP MTN
9045D
WP MTN
4500NO3F-2016
WP MTN
6010D
WP MTN
SW-7471B
WP MTN
SM-4500-NH3C-TKN
WP MTN
SM-2540G
WP MTN
WP MTN - Memphis, TN: Waypoint Analytical - TN, Memphis, TN
Page 2 of 8

Waypointo
ANALYTICAL
46622
Synagro Central LLC/ Technical
Project 3rd Creek
Mary Brewer
284 Boger Road
Information
Mocksville , NC 27028
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Report Number : 23-277-0004 REPORT OFANALYSIS
Report Date : 10/18/2023
Received : 10/04/2023
Brandi Watson
Lab No : 63606
Sample ID : 3rd Creek
Matrix: Solids
Sampled: 10/3/2023 7:30
Test
Results
Units
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
82.3
%
0.010
1
10/05/2316:10
CAH
SM-2540G
Phosphorus
29900
mg/Kg -
dry
28.2
1
10/07/23 01:55
BKN
6010D
Sulfur
8470
mg/Kg -
dry
56.5
1
10/07/23 01:55
BKN
6010D
Calcium
8250
mg/Kg -
dry
282
1
10/07/23 01:55
BKN
6010D
Aluminum
26200
mg/Kg -
dry
28.2
1
10/07/23 01:55
TJS
6010D
Manganese
1230
mg/Kg -
dry
2.82
1
10/07/23 01:55
BKN
6010D
Copper
312
mg/Kg -
dry
2.82
1
10/07/23 01:55
BKN
6010D
Zinc
701
mg/Kg -
dry
7.06
1
10/07/23 01:55
BKN
6010D
Organic N
52350
mg/Kg -
dry
1412
1
10/16/23 14:30
CALCULATION
Nickel
33.9
mg/Kg -
dry
1.41
1
10/07/23 01:55
BKN
6010D
Lead
22.1
mg/Kg -
dry
1.69
1
10/07/23 01:55
BKN
6010D
Arsenic
4.69
mg/Kg -
dry
2.82
1
10/07/23 01:55
BKN
6010D
Selenium
4.86
mg/Kg -
dry
2.82
1
10/07/23 01:55
BKN
6010D
Test
Results
Units
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Total Solids 17.7 % 0.010 1 10/05/23 16:10 CAH SM-2540G
Qualifiers/ DF Dilution Factor
Definitions
MQL Method Quantitation Limit
Page 3 of 8

Waypointo
ANALYTICAL
46622
Synagro Central LLC/ Technical
Project 3rd Creek
Mary Brewer
284 Boger Road
Information
Mocksville , NC 27028
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Report Number : 23-277-0004 REPORT OFANALYSIS
Report Date : 10/18/2023
Received : 10/04/2023
Brandi Watson
Lab No : 63606
Sample ID : 3rd Creek
Matrix: Solids
Sampled: 10/3/2023 7:30
Test
Results
Units
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Total Kjeldahl Nitrogen
55600
mg/Kg -
dry
1410
1
10/18/23 10:30
JPJ ;M-4500-NH3C-TKI`
Potassium
2630
mg/Kg -
dry
56.5
1
10/07/23 01:55
BKN
6010D
Magnesium
2540
mg/Kg -
dry
28.2
1
10/07/23 01:55
BKN
6010D
Sodium
672
mg/Kg -
dry
141
1
10/07/23 01:55
BKN
6010D
Iron
27600
mg/Kg -
dry
56.5
1
10/07/23 01:55
BKN
6010D
Ammonia Nitrogen
3300
mg/Kg -
dry
565
1
10/16/23 14:30
JPJ
SM-4500-NH3C
Nitrate+Nitrite-N
39.7
mg/Kg -
dry
28.2
1
10/11/23 15:34
CLP
4500NO3F-2016
Cadmium
2.62
mg/Kg -
dry
0.565
1
10/07/23 01:55
BKN
6010D
Chromium
39.0
mg/Kg -
dry
1.41
1
10/07/23 01:55
BKN
6010D
Mercury
<1.02
mg/Kg -
dry
1.02
1
10/06/23 12:04
MRE
SW-7471B
pH
6.9
S.U.
1
10/06/2316:07
CNB
9045D
Total Volatile Solids
63.7
%
0.010
1
10/05/23 16:10
CAH
SM-2540G
Molybdenum
16.0
mg/Kg -
dry
1.41
1
10/07/23 01:55
BKN
6010D
Qualifiers/ DF Dilution Factor
Definitions
MQL Method Quantitation Limit
Page 4 of 8

Waypointo
ANALYTICAL
Client: Synagro Central LLC/ Technical
Project: 3rd Creek
Lab Report Number: 23-277-0004
Date: 10/18/2023
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Aluminum
QC Batch No: 1-709731/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Calcium
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Cadmium
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Copper
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Iron
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Potassium
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Magnesium
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Page 5 of 8

Waypointo
ANALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Analyte: Manganese
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Phosphorus
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Lead
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 63602 (61A-0146-Syncon-Replace Cooling Tower)
Analyte: Zinc
QC Batch No: 1-709473/1-709057
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Page 6 of 8

WayPAoInt..
NALYTICAL
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 0 Fax [phone]
www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46622
Customer Name: Synagro Central LLC/ Technical
Report Number: 23-277-0004
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: IDavid Lennon Date & Time: 10/04/2023 09:53:49
Page 7 of 8

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Page 8 of 8

NORTH CAROLINA FIELD REPORT
STATESVILLE, NC
December 2023
Synagro Field: NC-IR-00036-0-0004-
Permit No:
WQ0016247
County:
IREDELL
Latitude:
35.85'25"
Crop:
FESCUE HAY
Longitude:
80.78'59"
Acres:
41.50 (16.81 ha)
Rate:
188 LBS PAN/ACRE
Applic. Method:
SURFACE APPL.
CUBIC YARDS AAPLIED
Month to Date: 240.00
Year to Date: 240.00
DRY TONS / ACRE
APPLIED:
Month to Date: 0.68
Year to Date: 0.68
POUNDS PER ACRE APPLIED
(Kilograms per Hectare Applied)
PARAMETER
MONTH TO DATE
YEAR TO DATE CUMULATIVE
PAN
24.24
24.24
P
2.41
2.41
K
5.34
5.34
As
0.05 (0.06)
0.05 (0.06)
0.05 (0.06)
Cd
<.01 (<.01)
<.01 (<.01)
<.01 (<.01)
Cr
0.14 (0.16)
0.14 (0.16)
0.14 (0.16)
Cu
0.11 (0.12)
0.11 (0.12)
0.11 (0.12)
Pb
0.11 (0.12)
0.11 (0.12)
0.11 (0.12)
Hg
<.01 (<.01)
<.01 (<.01)
<.01 (<.01)
Mo
<.01 (<.01)
<.01 (<.01)
<.01 (<.01)
Ni
0.17 (0.19)
0.17 (0.19)
0.17 (0.19)
Se
<.01 (<.01)
<.01 (<.01)
<.01 (<.01)
Zn
0.75 (0.84)
0.75 (0.84)
0.75 (0.84)
December 2023
DAILY FIELD LOADING SHEET
Synagro Field: NC-IR-00036-0-0004-
Weather Soil Rainfall
Date Applied
Type %Solids
Amount Unit Dry Tons
Conditions Conditions Past 24 Hr
12/07/2023
STFCC 13.90
128.00 CUBIC 14.98
FAIR MOIST 0-<1/2
YARDS
12/08/2023
STFCC 13.90
112.00 CUBIC 13.11
FAIR DRY 0-<1/2
YARDS
TOTALS:
240.00 CUBIC 28.10 DT
YARDS
GRAND TOTALS: 28.10 DT
25.48 MT
"NR" = Data not reported to Synagro Technologies, Inc. or data not required

NORTH CAROLINA FIELD REPORT
STATESVILLE, NC
December 2023
Synagro Field: NC-RA-00005-0-0002-
Permit No:
W00016247
County:
ROWAN
Latitude:
35.70'66"
Crop:
FESCUE HAY
Longitude:
80.66"7"
Acres:
44.80 (18.14 ha)
Rate:
188 LBS PAN/ACRE
Applic. Method:
SURFACE APPL.
CUBIC YARDS AAPLIED
Month to Date: 75.00
Year to Date: 495.00
DRY TONS / ACRE
APPLIED:
Month to Date: 0.21
Year to Date: 1.36
POUNDS PER ACRE APPLIED
(Kilograms per Hectare Applied)
PARAMETER
MONTH TO DATE
YEAR TO DATE CUMULATIVE
PAN
7.35
60.29
P
3.54
62.96
K
1.50
11.08
As
0.01 (0.01)
0.03 (0.03)
0.09 (0.10)
Cd
<.01 (<.01)
<.01 (<.01)
0.12 (0.13)
Cr
0.04 (0.04)
0.15 (0.17)
1.20 (1.34)
Cu
0.06 (0.07)
0.99 (1.11)
5.42 (6.07)
Pb
0.03 (0.03)
0.10 (0.11)
0.81 (0.91)
Hg
<.01 (<.01)
<.01 (<.01)
<.01 (<.01)
Mo
<.01 (<.01)
0.04 (0.04)
0.25 (0.28)
Ni
0.04 (0.04)
0.12 (0.13)
0.68 (0.76)
Se
<.01 (<.01)
0.02 (0.02)
0.07 (0.08)
Zn
0.24 (0.27)
2.21 (2.48)
13.03 (14.59)
December 2023
DAILY FIELD LOADING SHEET
Synagro Field: NC-RA-00005-0-0002-
Weather Soil Rainfall
Date Applied
Type %Solids
Amount Unit Dry Tons
Conditions Conditions Past 24 Hr
12/20/2023
STFCC 13.90
45.00 CUBIC 5.27
FAIR DRY 0-<1/2
YARDS
12/21/2023
STFCC 13.90
15.00 CUBIC 1.76
PARTLY MOIST 0-<1/2
YARDS
CLOUDY
12/21/2023
STTCC 17.70
15.00 CUBIC 2.24
FAIR DRY 0-<1/2
YARDS
TOTALS:
75.00 CUBIC 09.26 DT
YARDS
GRAND TOTALS: 09.26 DT
08.40 MT
"NR" = Data not reported to Synagro Technologies, Inc. or data not required

SPILL RESPONSE PLAN
PROJECT: City of Statesville Land Application Permit W00014543
IN THE UNLIKELY EVENT OF A SPILL_ THE FOLLOWING ACTIONS SHALL BE TAKEN
IMMEDIATELY:
1. MANAGEMENT OF SPILL CLEAN-UP ACTIVITIES:
The Fourth Creek WWTP Supervisor shall take immediate charge and initiate clean-up activities. The City of Statesville
labor and equipment is to be utilized. In the event additional labor and equipment is required, assistance may be requested
from the NC Department of Transportation and other private contractors as necessary.
2. HALT THE SOURCE OF THE SPILL: Such as
a ruptured container or damaged transport unit.
3. CONTAIN THE SPILL:
Form a barrier. Sufficient quantities of straw shall be used for such purposes. Earthen barriers may be constructed to
augment the straw bale containment area of the spill. The Operations Manager or the person in charge on the spill site will
advise the clean-up personnel where to get the straw, lime, and other items necessary to complete the clean-up operation,
i.e., local farmers, farm supply centers, nurseries, etc.
4. CLEAN-UP:
Employ front-end loaders, vacuum equipment, sludge application vehicles, and/or local septic tank service to remove as
much of the spilled material as possible. Straw and/or sand should be scattered in the spill area to soak up the remaining
material. The straw- and sand -soaked material will be collected and removed to a disposal area approved by representatives
of the state regulatory agency.
5. FINAL CLEAN-UP:
Employ rotary brush sweeper if needed and apply lime to the spill area upon the approval of the clean-up efforts by the state
regulatory representative. If the event occurs on private property, the clean-up will be completed to the satisfaction of the
property owner and state regulatory representatives. The ultimate goal will be to restore the spill area to its original condition
if possible.
6. NOTIFICATION:
As soon as possible after the spill occurs, the City of Statesville Operations staff will notify the Fourth Creek WWTP
Supervisor, and they will then be responsible for notifying other key City of Statesville personnel.
7. REPORTING:
The City of Statesville personnel will notify the Mooresville Regional office [phone] as soon as possible, but not
more than 24 hours after, or on the next working day following the occurrence. The Fourth Creek WWTP Supervisor shall
provide a written report within 48 hours of the spill to the Technical Services Director. The report shall list all relative
information and actions taken. The City of Statesville personnel will file a written report to the Mooresville Regional office
of the NCDENR within 5 days of the occurrence. For after-hours reporting the Division's emergency number shall be called
to report all incidences (800-662-7956 or 800-858-0368 or 919-733-3300)
IIPage
1 /25/24

OPERATIONS AND MAINTENANCE PLAN
The City of Statesville Land Application Permit WQ0014543
Inspection Plan
Inspections for the Land Application site will be conducted on an as needed basis. The inspection frequency is based on the time frame
that it is going to take to complete the project and the amount of dry tons to be processed from this facility. The inspections will consist
of inspecting the Bio-Solids loading area. These inspections will consist of:
1. Verifying that all of the equipment is working properly.
2. Verify that all containment walls and curbing are working properly.
3. Ensure that all manned equipment has a copy of the spill control plan, the permit, and the operations and maintenance
plan.
4. Verifying that the correct number samples of the Class B product have been taken and that it meets the criteria for the
Land Application Permit.
5. The records will be kept in the project files in the respective office for the project.
6. The Permittee or Inspector shall report by telephone to the Mooresville Regional Office at 704-235-2198 as soon as possible
but no later than 24 hours after or the next working day following the occurrence or the first knowledge of the occurrence of
the following.
• Any occurrence with the distribution program resulting in the land application of significant amounts of material that is
abnormal in quantity or characteristics.
• Any time that self -monitoring indicates that the facility has gone out of compliance with the permit.
• Any process failure that results in the system not adequately treating the residuals.
• Any spill or discharge from a vehicle or piping system during residuals transportation.
• Any release that requires immediate reporting outside of normal business hours shall be called in to DENR at 1800-
662-7956, 1-800-858-0368, or 1-919-733-3300. These numbers are to be called in the event of a release to surface
waters, imminent failure of a storage system when the event occurs outside of normal business hours.
• Within 5 days of the first notice of an occurrence a written response in the form of a letter shall be sent to DENR
outlining the actions taken or purposed actions taken to ensure that the problem does not recur. Persons responsible
for inspections on this project are as follows:
Andy Smith, 41h Creek WWTP ORC or his designee
Andy Smith is the designated WWTP ORC for this project and his designees are the backup ORC's for this project.
2 1 P a g e
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OPERATIONS AND MAINTENANCE PLAN
The City of Statesville Land Application Permit WQ0014543
Sampling Plan
Sampling for this project consists of sampling the residuals during the time that land application is occurring. This
will result in one round of sampling to occur before land application commences in order to insure that the residuals
are suitable for land application. Based on the dry tonnage of this plant this will be six samples for all parameters per
year.
The residuals shall be sampled annually for the following: (Regulatory level in milligrams per liter in parentheses.)
Arsenic (5.0) 1, 4-Dichlorobenzene (7.5) Nitrobenzene (2.0)
Barium (100.0) 1, 2-Dichloroethane (0.5) Pentachlorophenol (100.0)
Benzene (0.5)
Cadmium (1.0)
Carbon tetrachloride
(0.5) Chlordane
(0.03)
Chlorobenzene
(100.0) Chloroform
(6.0) Chromium (5.0)
M-Cresol (200.0) o-
Cresol (200.0) p-
Cresol (200.0) Cresol
(200.0) 2,4-D (10.0)
1, 1-Dichloroethylene (0.7)
Pyridine (5.0)
2, 4-Dinitrotoluene (0.13)
Selenium (1.0)
Endrin (0.02)
Silver (5.0)
Hexachlorobenzene (0.13
Tetrachloroethylene (0.7)
Heptachlor (and its hydroxide) (0.008) Toxaphene (0.5)
Hexachloro-1,3-butadiene (0.5)
Trichloroethylene (0.5)
Hexachlorethane (3.0)
2,4,5-Trichlorophenol (400.0)
Lead (5.0)
2,4,6-Trichlorophenol (2.0)
Lindane (0.4)
2,4,5 TP ( Silvex) (1.0)
Mercury (0.2)
Vinyl Chloride (0.2)
Methoxychlor (10.0)
Methyl ethyl ketone (200.0)
The residuals will also be sampled based on the chart below for the following constituents
Dry Tons Generated
(short tons per year)
Monitoring Frequency
(Established in 40 CFR 503 and 15A NCAC 02T.1111)
<319
1 time per year
=>319-<1,650
1 per Quarter (4 times per year)
=>1,650-<16,500
1 every 60 days (6 times per year)
=>16,500
1 every month (12 times per year)
Aluminum
Ammonia -Nitrogen
Arsenic
Cadmium
Calcium
Copper
Lead
Sodium Adsorption Ratio (SAR)
Magnesium
Mercury
Molybdenum
Nickel
Nitrate -Nitrite Nitrogen
Phosphorous
Potassium
pH
Plant Available Nitrogen (calculation)
Selenium
Sodium
% Total Solids
Total Kjeldahl Nitrogen
Zinc
In order to meet pathogen and vector requirements the material will go through an aerobically digested treatment process. The
residuals will meet pathogen and vector requirements through pH, time and temperature requirements. The samples will be
pulled from the storage pads that are currently holding the Sta-Lime product. The samples that will be pulled are a TCLP and
nutrient and metals sample to prove that the material is suitable for distribution. The nutrient and metal and TCLP sample will be
collected randomly and consist of individual samples mixed together in order to get the composite sample for these parameters.
This material is very consistent based on the fact that these residuals are thoroughly digested and mixed before processing and
should not experience any seasonal fluctuations in the residuals.
The following people are responsible for sampling:
Andy Smith, Plant Manager or his designee.
3 1 P a g e
1 /25/24

OPERATIONS AND MAINTENANCE PLAN
The City of Statesville Land Application Permit WQ0014543
Operational Functions
The operation function of this project is going to involve loading dewatered belt press sludge. The dewatered belt press
sludge will be loaded into the trucks that are suitable to transport and spread this product without spillage or leakage
during transport. The dewatered belt press sludge will be spread at agronomic rates that are determined by the soil
samples from the fields that the City of Statesville staff has collected.
SAFETY MEASURES
The City of Statesville believes in operating in a safety conscious manner and is has all employees participate in monthly
safety courses that are designed to help its employees recognize safety issues and take steps to prevent accidents from
occurring. In addition, all City of Statesville, Water Resources employees have the authority to stop operations if they think
any aspect of the operation is going to cause environmental or personal harm.
Maintenance Schedule
The City of Statesville will follow the maintenance schedule as recommended by the processing equipment
manufacturer.
4 1 P a g e
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