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HomeMy WebLinkAboutNC0088692_Permit Issuance_20171013K` Water Resources w Environmental Quality October 13, 2017 Mr. Jerry Sparks, President Sparks Oil Company 412 N. Scales Street ROY COOPER Governor MICHAEL S. REGAN Secretary S. JAY ZIMMERMAN Director Reidsville, North Carolina NC 27320-2909 Subject: Issuance of NPDES Permit NC0088692 J.W. Smith/Camp Springs 76 (GW-REM) — PC-1 8920 Cherry Grove Road, Reidsville 27320 Caswell County Dear Mr. Sparks: The Division of Water Resources (the Division) hereby issues thea ttached NPDES permit for the an facility. This permit is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated October 15, 2007, or as subsequently amended. We have made the following updates to your previous permit: 1. The facility map has been updated. The location of Outfall 001 is corrected to the following: Latitude: 360 17' 46" (36.296111) Longitude -79' 29' 3 1 " (-79.491944) 2. Regulatory citations have been added. 3. Effluent quarterly monitoring for Total Hardness has been added. Please see discussion below for more information. Effluent hardness sampling should be performed in conjunction with sampling for hardness dependent metals (Lead). Please note that since the outfall location is under zero flow conditions, no instream hardness sampling will be required. 4. For all parameters with limits both monthly average limits and daily maximum limits have been applied. The US EPA requires both a Monthly Average and a Daily Maximum for parameters that are limited [40 CFR 122.45 (d.)]. 5. The limits for Isopropyl Ether (µg/L), 1,2-Didhloroethane (µgfL) and Naphthalene (µg2) have been updated to 10 mglL, 5 µg/L and 6 µgIL, respectively. 6. Monitoring of Phenol has been changed to Total Recoverable Phenolics (parameter code 32730). 7. Electronic reporting of discharge monitoring reports (eDMR) has been added in Section A. (2.). We have made the following updates for the final permit: S. The flow limit of 0.009 MGD was corrected to be a monthly average limit. The NC 2007-2014 Water Quality Standard (W QS) Triennial Review was approved by the NC Environmental Management Committee (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016 with some exceptions. The NC Division of Water Resources NPDES Permitting Unit is required to implement the new dissolved metal standards in all permits public noticed after April 6, 2016. State of North Carolina I Environmental Quality 1617 Mail Service Center I Raleigh, North Carolina 27699-1617 919-707-9000 Mr. Sparks October 13, 2017 Page 2 of 2 The new standards for most metals include acute standards. The freshwater standards for several metals are expressed as the dissolved form of the metals, and seven metals have hardness -dependent equations. As a result, the NPDES Permitting Unit will need site -specific effluent hardness data and instream hardness data, upstream of the discharge, for each facility monitoring these metals in order to calculate permit limitations. Effluent hardness has been added to this permit at a monitoring frequency of quarterly. No instream monitoring will be required due to zero flow conditions. See Section A. (L) Effluent Limitations and Monitoring Requirements. If any parts, measurement frequencies, or sampling requirements contained in this permit are unacceptable, you have the right to an adjudicatory hearing, upon written request submitted within thirty (30) days after receiving this letter. Your request must take the form of a written petition conforming to Chapter 150B of North Carolina General Statutes, and you must file it with the Office of Administrative Hearings, 6714 Mail Service Center, Raleigh, North Carolina 27699-6714. Unless such a demand is made, this permit shall remain final and binding. Please note that this permit is not transferable except after notice to the Division. The Division may require modification or revocation and reissuance of the permit. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Resources or any other Federal, State, or Local governmental permits that may be required. If you have questions, or if we can be of further service, please contact Derek Denard at [derek.denard@ncdenr.gov] or call (919) 807-6307. Resp tfully, 7. �J S. Jay Zimmerm ,Dire Division of Water Resources, NCDEQ Enclosure: NPDES Permit NC0088692 (Issuance Final) hc: Central Files NPDES Program Files WSRO Files/ Attn: George Smith ec: Jerry Sparks, Sparks Oil Company jjeny@sparksoil.com] NPDES Permit NCO088692 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENTAL QUALITY DIVISION OF WATER RESOURCES PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM NPDES In compliance with the provisions of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, Sparks Oil Company is hereby authorized to discharge wastewater from a facility located at the J.W. Smith/Camp Springs 76 (GW-REM) 8920 Cherry Grove Road, Camp Springs 27320-0227 Caswell County to receiving waters designated as a designated as an unnamed tributary to Country Line Creek in the Roanoke River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, H, III and IV hereof. This permit shall become effective November 1, 2017. This permit and authorization to discharge shall expire at midnight on October 31, 2022. Signed this day October 13, • G- S y Zimmerman, P.G., Dire or Division of Water Resources By Authority of the Environmental Management Commission Page 1 of 6 NPDES Permit NCO088692 SUPPLEMENT TO PERMIT COVER SHEET r All previous NPDES Permits issued to this facility, whether for operation or discharge are hereby revoked. As of this permit issuance, any previously issued permit bearing this number is no longer effective. Therefore, the exclusive authority to operate and discharge from this facility arises under the permit conditions, requirements, terms, and provisions included herein. Sparks oil Company is hereby authorized to: 1. Continue to operate a 0.009 MGD Groundwater Remediation System / Soil — Vapor Extraction System consisting of the following components; • three (3) recovery wells • an 80-gallon 7.5 Hp air compressor • a 235-gallon oil -water separator • a 65-gallon sump tank with a 1 Hp centrifugal pump • a shallow 5 tray low profile air stripper with a 7.5 Hp air stripper blower • a 0.5 Hp air stripper discharge centrifugal pump • a 160-gallon sump pump with two (2) centrifugal pumps • a bag filter • one multimedia aggregate filter • hydro -solenoid backwash system with a backwash trickle filter • four (4) high pressure carbon filters • a totalizing meter for system discharge • a soil vapor extraction well converted from an existing monitoring well • a soil vapor extraction knock out drum with a 10 Hp blower and 0.5 Hp centrifugal PUMPS located at the W. Smith/Camp Springs 76 Petroleum Contaminated Groundwater Remediation Site (GW-REM), 8920 Cherry Grove Road, Reidsville, Caswell County; and 2. discharge from said treatment works at the location specified on the attached map into an unnamed tributary to Country Line Creek, currently classified WS-II; HQW within Subbasin 03-02-04 [HUC: 030101040202] of the Roanoke River Basin. Page 2 of 6 NPDES Permit NCO088692 PART I A. (1.) EF FLUENT LIMITATIONS AND MONITORING REQUIREMENTS [15A NCAC 02B .0400 et seq., 02B .0500 et seq.] During the period beginning on the effective date of this permit and lasting until expiration, the limited Permittee is authorized to discharge filter backwash from outfall 001. Such discharges shall 1 th P 'ttee ass ecified below: monitored and reported by a errru p MONITURNG ELIlVITS Ts, EFFLUENT CHARACTERISTICS Monthly Daily Measurement :` Sample: :a� �: Sample I PARAMETER CODES] Average a Maximum. w FXe uenc` _ , T e ".. Location 2 50050 0.009 MGD Continuous 2 2 Recording Effluent Flow (MGD) Total Suspended Solids (TSS) (mg/L) C0530 20.0 m 1 20.0 mg/L Monthly Grab Effluent MTBE {µg/L) 22417 9.5 µ91L 9.5 µg/L Monthly Grab Effluent Benzene (µg/L) 34030 0.60 µg/L 0.60 µg/L Monthly Y Grab Effluent Toluene (µg/L) 34010 5.5 µg/L 5.5 µg/L Monthly Grab Effluent Ethylbenzene (µg/L) 34371 48.5 µg1L 48.5 µg/L Monthly Grab Effluent Total.Xylenes (µg/L) 81551 335 µg/L 335 µg/L Monthly Grab Effluent Isopropyl Ether (µg/L) 77117 10 mg/L 10 mg/L Monthly Grab Effluent 1,2-Dichloroethane (µg/L) 32103 5 µg/L 5 µg/L Monthly Grab Effluent Quarterly Grab Effluent Ethylene Dibromide (µg/L) 77651 1,2,4-Trimethylbenzene(µg/L) 77222 195 µg/L 195 µg/L Monthly Grab Effluent 1,3,5-Trimethylbenzene(µg/L) 77226 315 µg/L 315 µg/L Monthly :� Grab Effluent Quarterly Grab Effluent n-Propyl Benzene (µg/L) 77224 Naphthalene (µg/L) 3406 6 µg/L 6 µg/L Monthly Grab Effluent Total Recoverable Phenolics (µg/L) 32730 150 µg/L 150 µg/L Monthly Grab Effluent Hardness Total as 3 00900 Monitor &Report QuarterlyGrab Effluent [CaCO3 or (Ca + Mg)] (mg/L) Quarterly Grab Effluent Lead (µme) 3 01051 Footnotes: 1. The Permittee shall begin submitting Discharge Monitoring Reports electronically using NC DWR's eDMR application system. See Condition A. (2.). 2. Flow may be measured using a totalizing flow meter. 3. Effluent hardness sampling should be performed in conjunction with sampling for hardness dependent metals (Lead). Conditions: There shall be no discharge of floating solids or visible foam in other than trace amounts. Page 3 of 6 NPDES Permit NCO088692 A. (2.) ELECTRONIC REPORTING OF MONITORING REPORTS [G. S. 143-215.1(b)] Federal regulations require electronic submittal of all discharge monitoring reports (DMRs) and program reports. The final NPDES Electronic Reporting Rule was adopted and became effective on December 21, 2015. NOTE: This special condition supplements or supersedes the following sections within Part H of this permit (Standard Conditions for NPDES Permits): • Section B. (11.) • Section D. (2.) • Section D. (6.) • Section E. (5.) Signatory Requirements Reporting Records Retention Monitoring Reports 1. Reporting Requirements [Supersedes Section D. (2.) and Section E. (5.) (a)1 The permittee shall report discharge monitoring data electronically using the NC DWR's Electronic Discharge Monitoring Report (eDMR) internet application. Monitoring results obtained during the previous month(s) shall be summarized for each month and submitted electronically using eDMR. The eDMR system allows permitted facilities to enter monitoring data and submit DMRs electronically using the internet. Until such time that the state's eDMR application is compliant with EPA's Cross -Media Electronic Reporting Regulation (CROMERR), permittees will be required to submit all discharge monitoring data to the state electronically using eDMR and will be required to complete the eDMR submission by printing, signing, and submitting one signed original and a copy of the computer printed eDMR to the following address: NC DEQ / Division of Water Resources / Water Quality Permitting Section ATTENTION: Central Files 1617 Mail Service Center Raleigh, North Carolina 27699-1617 If a permittee is unable to use the eDMR system due to a demonstrated hardship or due to'the facility being physically located in an area where less than 10 percent of the households have broadband access, then a temporary waiver from the NPDES electronic reporting requirements may be granted and discharge monitoring data may be submitted on paper DMR forms (MR 1, 1. 1, 2, 3) or alternative forms approved by the Director. Duplicate signed copies shall be submitted to the mailing address above. See "How to Request a Waiver from Electronic Reporting" section below. Regardless of the submission method, the first DMR is due on the last day of the month following the issuance of the permit or in the case of a new facility, on the last day of the month following the commencement of discharge. Starting on December 21, 2020, the permittee must electronically report the following compliance monitoring data and reports, when applicable: Sewer Overflow/Bypass Event Reports; Pretreatment Program Annual Reports; and Clean Water Act (CWA) Section 316(b) Annual Reports. Page 4 of 6 NPDES Permit NC0088692 The permittee may seek an electronic reporting waiver from the Division (see "How to Request a Waiver from Electronic Reporting" section below). 2. Electronic Submissions In accordance with 40 CFR 122.41(1)(9), the permittee must identify the initial recipient at the time of each electronic submission. The permittee should use the EPA's website resources to identify the initial recipient for the electronic submission. Initial recipient of electronic NPDES information from NPDES-regulated facilities means the entity (EPA or the state authorized by EPA to implement the NPDES program) that is the designated entity for receiving electronic NPDES data [see 40 CFR 127.2(b)]. EPA plans to establish a website that will also link to the appropriate electronic reporting tool for each type of electronic submission and for each state. Instructions on how to access and use the appropriate electronic reporting tool will be available as well. information on EPA's NPDES Electronic Reporting Rule is found at: http //www2 epa Gov/compliance/final-national-pollutant-discharge-elimination-system-npdes- electronic-reporting-rule. Electronic submissions must start by the dates listed in the "Reporting Requirements" section above. 3. How to Request a Waiver from Electronic Reporting The permittee may seek a temporary electronic reporting waiver from the Division. 'To obtain an electronic reporting waiver, a permittee must first submit an electronic reporting waiver request to the Division. Requests for temporary electronic reporting waivers must be submitted in writing to the Division for written approval at least sixty (60) days prior to the date the facility would be required under this permit to begin submitting monitoring data and reports. The duration of a temporary waiver shall not exceed 5 years and shall thereupon expire. At such time, monitoring data and reports shall be submitted electronically to the Division unless the permittee re -applies for and is granted a new temporary electronic reporting waiver by the Division. Approved electronic reporting waivers are not transferrable. Only permittees with an approved reporting waiver request may submit monitoring data and reports on paper to the Division for the period that the approved reporting waiver request is effective. Information on eDMR and the application for a temporary electronic reporting waiver are found on the following web page: http://deg.nc.gov/about/divisions/water-resources/edinr 4. Signatory Requirements 1Supplements Section B. (11.) (b) and Supersedes Section B. (11.) Id 1 All eDMRs submitted to the permit issuing authority shall be signed by a person described in Part 11, Section B. (I 1.)(a) or by a duly authorized representative of that person as described in Part I1, Section B. (11.)(b). A person, and not a position, must be delegated signatory authority for eDMR reporting purposes. For eDMR submissions, the person signing and submitting the DMR must obtain an eDMR user account and login credentials to access the eDMR system. For more information on North Carolina's eDMR system, registering for eDMR and obtaining an eDMR user account, please visit the following web page: Page 5 of 6 NPDES Permit NCO088692 hqp:Hdeg,.nc.gov/about/divisions/water-resources/edmr Certification. Any person submitting an electronic DMR using the state's eDMR system shall make the following certification [40 CFR 122.22]. NO OTHER STATEMENTS OF CERTIFICATION WILL BE ACCEPTED: 7 certify, under penalty of law, that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system, or those persons directly responsible for gathering the information, the information submitted is, to the best of my knowlediand belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. " 5. Records Retention [Supplements Section D. (6.)] The permittee shall retain records of all Discharge Monitoring Reports, including eDMR submissions. These records or copies shall be maintained for a period of at least 3 years from the date of the report. This period may be extended by request of the Director at any time [40 CFR 122.41]. Page 6 of 6 r, £'.�-1 Country Line Creek [flows northeast] t. •��i ) �vr .\ tit : t. 1 't :i �` �5 �� J: l is {1 t �� �" — � •y`�- !� �'�/_ - �_; � •r—•-�1! _ _ �' ` �J�� ,r..r' fir, t ` � • � vim" )� �� f + r !�1(� �� ��,1.�- J� I �✓ `� ,;t ;` ;,� r� ; •;�� fir/ � �%!!� Lf ��'.� Ce It IL Ic L_ 46 UT to Country Line Creek r t= [flows northwest] t 1133 ~�'`� �� � `�`1 � \ ,�• ~.. ,:�.� ?tr�'•- j `\ � r �,' fir , 00 II NOW N 36.2961110N,-79.491944° W SCALE NC Grid: B21 SW 1:24,000 USGS Quad: Cherry Grove, NC Sparks Oil Company J.W. Smith/Camp Springs 76 (GW-REM) NPDES Permit NCO088692 8920 Cherry Grove Road, Reidsville 27320-0227 Receiving Stream: UT to Country Line Creek Stream Class: WS-II;HQW Stream Segment: 22-56-(1) Sub -Basin M 03-02-04 River Basin: Roanoke HUC: 030101040202 County: Caswell CLIPPING OF LEGAL NORTH CAROLINA ADVERTISEMENT CASWELL COUNTY ATTACHED HERE AFFIDAVIT OF PUBLICATION Before the undersigned, a Notary Public of said County and Public Notice North Carolina Environmental State, duly commissioned, qualified, and authorized by law to Management Commission/NP- DES unit administer oaths, personally appeared Patricia Cheek who being 1617 Mail Service Center Raleigh, NC 27699-1617 first duly sworn, deposes and says: that she is an authorized Notice of Intent to Issue a NP- DES Wastewater Permit employee of The Caswell Messenger, engaged in the publication The North Carolina Environ- mental Management Com- of a newspaper known as The Caswell Messenger published, is - mission proposes to issue a NPDES wastewater discharge sued, and entered as second class mail in the City of Yanceyville, permit to the person(s) listed below. Written comments re- in said County and State; that she is authorized to make this af- garding the proposed permit will be accepted until 30 days fidavit and swom statement; that the notice or other legal adver- after the publish date of this notice. The Director of the NC tisement, a true copy of which is attached hereto, was published Division of Water Resources (DWR) may hold a public hear- in The Caswell Messenger on the following date, August 23, ing should there be a signifi- cant degree of public interest. 2017 date the said newspaper in which such notice, paper, docu- Please mail comments and/ or information requests to ment, or legal advertisement was published was, at the time of DWR at the above address. Interested persons may visit each and every such publication, a newspaper meeting all of the the DWR at 512 N. Salisbury Street, Raleigh, NC to review requirements and qualifications of Section 8-597 of the General information on file. Additional information on NPDES permits Statutes of North Carolina and was qualified newspaper within and this notice may be found on our websde: hftp:udeq. the meaning of Section 1-597 of the General Statutes of North nc.gov/about/divisions/water- resources/water-resources- Carolina. permits/wastewater-bra nrh/ notices,or by calling (919) 807-6397. Sparks oil Corn Z ris 23rd day of Au ust 17 Perry applied to renew NPDES -- permit for J.W. Smith/Camp L Springs 76 [NC0088692), 8920 Cherry Grove Road, Reidsville, Caswell County, discharging remediated groundwater to (Signature of person making affidavit) oun ry Line Greek, Roanoke war a- Swom to and subscribed before me, this 23rd day of August sin.8/23/17 -'�� 2017JA" Notary Public .. ANITA B. SMITH `T_ Notary Public, North Carolina Caswell County My Coygmission Expires Weaver, Charles From: Mika Trifunovic < mika@pyramidenvironmental.com > Sent: Wednesday, November 02, 201612:07 PM To: Kinney, Maureen; ndannyoldham@gmail.com;jerry@sparksoil.com Cc: Boone, Ron; Mike Jones; Weaver, Charles Subject: RE: Operator Designations: NCO088692 Sparks Oil Company Attachments: DOC.PDF Hello Maureen, I would like to inform you that the JW Smith/Camp Springs 76 groundwater remediation system that holds NPDES permit # NC0088692 has designated ORC and backup ORC. ORC Info: ' Nathan Daniel Oldham, Jr. Current NCDEQ ORC Certifications: PC-1 # 991232 W W-1 # 27281 Backup ORC Info: James David Remaes, Jr. Current NCDEQ ORC Certifications: PC-1 # 991170 I'll send you the WPCSOCC form signed by the ORC and backup ORC so you can update your records. Mr. Oldham has been the JW Smith remediation system ORC since the system became operational in December 2010. Two NPDES compliance inspections conducted in December 2012 and July 2016 found no noncompliance issues. Please see the attached Compliance Evaluation Inspection reports from 2012 and 2016. If you need any additional information or clarification, please let me know. Best regards, Mika Trifunovic Project Engineer/Manager Pyramid Environmental & Engineering, P.C. Phone # (336) 335-3174 From: Kinney, Maureen [mailto:Maureen.Kinney@ncdenr.gov] Sent: Tuesday, November 01, 2016 12:35 PM To: ndannyoldham@gmail.com; jerry@sparksoil.com Cc: Mika Trifunovic <mika@pyramidenvironmental.com> Subject: Operator Designations: NCO088692 Sparks Oil Company From: Kinney, Maureen Sent: Friday, October 14, 2016 1:19 PM To: 'jerry@sparksoil.com' <ierry@soarksoil.com>; 'mika@pyramidenvironmental.com' <mika()a ovramidenvironmental.com> Cc: Boone, Ron <ron.boone@ncdenr.gov>; Charles Weaver (Charles.Weaver@ncdenr.eov) <Charles.Weaver@ncdenr.aov> Subject: Operator Designations: NCO088692 Sparks Oil Company Upon review of the subject permit, it was noted that there is no designated Operator in Responsible Charge'(ORC) or back up ORC for this facility; per rule (see below). CLICK HERE to VERIFY NPDES wastewater operator designations for this facility (You need permit number). CLICK HERE to download the ORC Designation Form and submit by email or USPS. LSAN(7ACOSC.0201 RESPONSIBILrtSOFSI'.%TE1103YNERtiTODFSI(;VATEC'ERTIf7EDOPERATOP—% (Toncns of classified water pollution control systems must designate operators, cenified by the water Pollution Control %v stem Operators Cenif ication Commission (W PCSOCC ). of the appropriate h pc and grade for the sstem, and, for each classification must: (1) designate one Operator In Responsible Charge IORC) who possesses a valid cenificate of the g pc and grade at least equivalent to the q pc and grade of the ss stem; (2) de irwteoneormore Back-up Operaton(s)m Res{wnsiNeCharge(Back-up ORCs)whoposx--s sa valid certificate of the hpe of the system and no more than one grade less than the grade of the system, with the c\cepuon of no backup operator in responsible charge is required for systems whose mnimuin %isnation requirements are twice per %ear, and 13) submit a signed compleud 'Waw Pollution Control System Operator Designation Form' to the Commission (or to the local health department for owners of subsurface systems) countersigned by the designated certified operators, designating the Operator in Responsible Charge (ORC 1 and the Back-up Operator in Responsible Charge (Back-up ORC): la) 60 calendar days prior to wastewater on residuals being introduced into a new system. or IN within 120 calendar days following: 11) receiving notification of a change in the classification of the system requiring the designation ofa new Operator in Responsible Charge (ORC) and Back-up Operator in Responsible Charge ( Back-up ORC) ot'tltc proper h pe and grade, or (u) a vacancy in the position of Operator in Responsible Charge (ORC) or Back-up Operator in Responsible Charge (Back-up ORC). I c 1 within seven calendar daps of vacancies in both ORC and Back-up ORC positrons replacing or designating at least onne of the responsibilities. Thank you for your prompt attention to this. Maureen Ma, weer ("' U ey Extension Education & Training Specialist NC Operator Certification Program Dept of Environmental Quality - DWR PH:919-707-9038 FX: 919-715-2726 http://deg. nc.gov/a bo ut/divisions/water-resources/wastewater-operator-certification NORTH CAROLINA OPERATOR CERTIFICATION —PROGRAM— ap rties unless the content is exempt by statute or other regulation. i DEQ / DWR / NPDES EXPEDITED FACT SHEET - NPDES PERMIT DEVELOPMENT NPDES Permit NCO088692 Derek Denard, Compliance & Expedited Permitting Unit / 919-807-6307 120ct2017 FacilityInf6iiiiation :.. Applicant/Facility. Name ' Sparks Oil Company J.W. Smith/Camp Springs 76 (GW-REM) Applicant Address 412 N. Scales Street, Reidsville, NC 27320-2909 Facility -Address 8920 Cherry Grove Road, Reidsville, NC 27320-0227 Permitted Flow (MGD) 0.009 Type of Waste Groundwater Remediation Discharge 100% Industrial Facility Class : PC-1 County( Caswell Permit Status Renewal Regional Office . WSRO Stream Characteristics . .... - - Receiving Stream UT to Country Line Creek - ... Stream Classification'- WS-II;HQW Stream Segment [22-56-(1)] Dtainage basin Roanoke Summer 7Q 10 (cfs) 0 Subbasin [MC] 03-02-04 [030101040202] Winter 7010:(cfs) 0 Use Support Supporting (Cat 2) cfs � Q ( ) 0 �33 Listed .0O _ _ Average Flow (cfs) 0 State Grid. B21 SW IWC '(°/o) 100% USGS"Topo Quad Cherry Grove, NC FACILITY SUMMARY: This facility is a 0.009 MGD Groundwater Remediation System / Soil — Vapor Extraction System consisting of the following components; • three (3) recovery wells • an 80-gallon 7.5 Hp air compressor • a 235-gallon oil -water separator • a 65-gallon sump tank with a 1 Hp centrifugal pump • a shallow 5 tray low profile air stripper with a 7.5 Hp air stripper blower • a 0.5 Hp air stripper discharge centrifugal pump • a 160-gallon sump pump with two (2) centrifugal pumps • a bag filter • one multimedia aggregate filter • hydro -solenoid backwash system with a backwash trickle filter • four (4) high pressure carbon filters • a totalizing meter for system discharge • a soil vapor extraction well converted from an existing monitoring well • a soil vapor extraction knock out drum with a 10 Hp blower and 0.5 Hp centrifugal pumps. Fact Sheet Renewal 2017 — NPDES Pennit NCO088692 Page 1 RENEWAL SUMMARY: This permit reflects discharge at Outfall 001. DWR updated the following: 1. The facility map has been updated. The location of Outfall 001 is corrected to the following: Latitude: 36017' 46" (36.296111) Longitude -790 29' 3 1 " (-79.491944) 2. Regulatory citations have been added. 3. Effluent quarterly monitoring for Total Hardness has been added. Please see discussion below for more information. Effluent hardness sampling should be performed in conjunction with sampling for hardness dependent metals (Lead). Please note that since the outfall location is under zero flow conditions, no instream hardness sampling will be required. 4. For all parameters with limits both monthly average limits and daily maximum limits have been applied. The US EPA requires both a Monthly Average and a Daily Maximum for parameters that are limited [40 CFR 122.45 (d.)]. 5. The limits for Isopropyl Ether (µg/L), 1,2-Dichloroethane (µg/L) and Naphthalene (µg/L) have been updated to 10 mg/L, 5 µg/L and 6 µg/L, respectively. 6. Monitoring of Phenol has been changed to Total Recoverable Phenolics (parameter code 32730). 7. Electronic reporting of discharge monitoring reports (eDMR) has been added in Section A. (2.). EFFLUENT CHARACTERISTICS DISCUSSION OF CHANGES -FOR PARAMETERS -OF CONCERl�fi AND. LEWTS _.. _...: [parameter codes] Flow (MGD) 50050 Flow limit is a monthly average limit. Discharges of total suspended solids (TSS) shall be limited to effluent concentrations of 10 mg/1 for trout waters and PNA's, and to 20 mg/1 for Total Suspended Solids (TSS) all other High Quality Waters [15A NCAC 02B .0224 (1)(b)(ii)]. The 20 (mg/L) C0530 mg/l limit is applied as both a monthly average limit and daily maximum limit. The US EPA requires both a Monthly Average and a Daily Maximum for parameters that are limited [40 CFR 122.45 (d.)]. MTBE (µg/L) 22417 For these parameters limits are applied as both a monthly average limit and daily maximum limit. The US EPA requires both a Monthly Benzene (µg/L) 34030 Toluene (µg/L) 34010 Ethylbenzene (µg/L) 34371 Average and a Daily Maximum for parameters that are limited [40 CFR Total Xylenes (µg/L) 81551 122.45 (d.)]. 1,2,4-Trimethylbenzene(µg/L) 77222 1,3,5-Trimethylbenzene(µg/L) 77226 A new limit of 10 mg/L is applied as both a monthly average limit and Isopropyl Ether (' ) 77117 daily maximum limit. The US EPA requires both a Monthly Average and a Daily Maximum for parameters that are limited [40 CFR 122.45 (d•)]• A new limit of 5 µg/L is applied as both a monthly average limit and daily limit. The US EPA both Monthly Average 1,2-Dichloroethane (µg/L) 32103 maximum requires a and a Daily Maximum for all parameters that are limited [40 CFR 122.45 (d.)]. Please note the parameter code is changed to 32103. Ethylene Dibromide (µg/L) 77651 Maintain quarterly monitoring. n-Pro 1 Benzene pY (µg/L) 77224 Naphthalene A new limit of is applied as both a monthly average limit and daily limit. (µg/L) 34696 maximum The US EPA requires both a Monthly Average and a Daily Maximum for limited CFR 122.45 parameters that are (40 (d.)]. Fact Sheet Renewal 2017 — NPDES Permit NCO088692 Page 2 Total Recoverable Phenolics W/L) 32730 Replaced Phenol (parameter code 34694 with Total Recoverable Phenolics [32730]. DVWR Memo: Rationale and Implementation of Water -Quality Standards for Phenolic Compounds and Chlorinated Phenolic Compounds, December 15, 2010. Effluent hardness sampling should be performed in conjunction with sampling for hardness dependent metals (Lead). Effluent hardness sampling and instream hardness sampling, upstream of the discharge, Hardness Total as are inserted into all permits with facilities monitoring for hardness- [CaCO3 or (Ca + Mg)] (mg/L) 00900 dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. Since the outfall location is under zero flow conditions, no instream hardness samplin will be required. Please seethe section titled NPDES Implementation r Instream Metals Standards in this factsheet for more detailed information. Lead (µg/L) 01051 Effluent hardness sampling should be performed in conjunction with sampling for hardness dependent metals (Lead). DATA SUMMARY: DAM Dailv Parameter Values for Dec2U12-Mav2U17 (4 1/2 years Parameter 1,w Max '; Min I Average ; Count PQL ! UoM 5 ug/l 01051 - Lead, Total (as Pb_) 5' 5', 5.01 33 22417 - Methyl Tert-Butyl Ether (MTBE) 4.5i 0.51 0.91 36 0.5 ug/l 34010 - Toluene 0.5' 0.5 0.5 33 0.5; ug/l 34030 - Benzene 0.5 0.5 0.5 33 0.5 ug/l 34371 - Ethylbenzene 0.5' 0.5 0.5 33 0.5; ug/l 34531-1,2-dichloroethane (ethylene dichloride, 1,2-DCA) 0.5, 0.19 0.4� 33 0.5'ug/l 34694 - Phenol 160 5 20.6 40 5; ug/l 34696 - Naphthalene 2 2 2.0 33 2 ug/l 50050 - Flow, in conduit or thru treatment plant 0.002 0.0001; 0.0005 42 ug/l 77117 - Isopropyl Ether 500 ` 500 500.01 33 0.5' ug/l 77222 -1,2,4 Tdmethylbenzene 0.5 0.5 0.5 33 0.5 u9/1 77224 - n-Propylbenzene 0.5 0.5 0.5 33 0.5; ug/l 77226 - 1,3,5-Trimethylbenzene 0.5 0.5 0.5' 33 0.5 ug/l 77651 - Ethylene Dibromide 0.5 0.5 0.5 33 0.5, ug/l 81551 - Xylene (mix of m+o+p) 1 1 1.0 33 1 ug/l C0530 - Solids, Total Suspended - Concentration 15.7 2.5, 4.8 38 2.5 mg/I RPA: The need for toxicant limits is based upon a demonstration of reasonable potential to exceed water quality standards, a statistical evaluation that is conducted during every permit renewal utilizing the most recent effluent data for each outfall..The RPA is conducted in accordance with 40 CFR 122.44 (d) (i). The NC RPA procedure utilizes the following: 1) 95% Confidence Level/95% Probability; 2) assumption of zero background; 3) use of V2 detection limit for "less than" values; and 4) streamflows used for dilution consideration based on 15A NCAC 2B.0206. Effective April 6, 2016, NC began implementation of dissolved metals criteria in the RPA process in accordance with guidance titled NPDES Implementation of Instream Dissolved Metals Standards, dated June 10, 2016. 8. A reasonable potential analysis was conducted on effluent toxicant data collected between Dec2012- May2017. Pollutants of concern included toxicants with positive detections and associated water quality standards/criteria. Based on this analysis, limits for Isopropyl Ether (µg/L), 1,2-Dichloroethane (µg/L) and Naphthalene (µg/L) have been updated to 10 mg/L, 5 µg/L and 6 µg/L, respectively. Lead will not receive a lmit at this time because there was no detection and no effluent hardness data available to set a limit. Fact Sheet Renewal 2017 - NPDES Pennit NCO088692 Page 3 STREAM: The stream index number was corrected in BIMS from 22-56-(3.5) to 22-56-(1). The 22-56- (3.5) index number is for the Farmer Lake segment of Country Line Creek, which is currently a class W S- ll;HQW,CA waterbody (See Figure 1.) The Country Line Creek segment nearest to Outfall 001 is 22-56- (1), which is a class WS-H;HQW waterbody (See Figure 2.). Outfall 001 discharges into an unnamed tributary to County Line Creek. 'I ycm eFm.a. aaa mk xi4 �S�Iv�8W0C. °R�r J� Q ^pp.nrP 9p tf 2 p,pf 0 �Pp � p `pa wpn I,�yeRv' i \\ �. - title. 2236(3S) .e-< CvurmFlmpGW(Feme bbl v.v Fran Fpam OSmb � upmumgmapF dNm Fwtm CFmn Brmobb i RPvngYvicgn(ee naur uPPN iinib) . WSlIrIW2.0 A.g 2 1W2 xwnq. o I r pPp Imo`„ fil:nll.� Figure 1. Stream Index 22-56-(3.5), Country Line Creek (Farmer Lake), WS-H;HQW,CA Fact Sheet Renewal 2017 — NPDES Permit NC0088692 Pa,-e 4 N Glove ROM. R< X I V r. m. evmc 0.e;Jmrltr � t „ a I' � SubWo O�bbc Smn. Jae. 22-5<10 . I I Sv..�n A4ew Cwmry Lee Geak �„ OewnM— Fr wpm McWIt 01, of A OI Ni4 Foh OruFe<ra. W lHow Dm JGe Ap 2. IW2 WAn Jon N.• t Inr. - - I ,ono. Summil m ® OStrte MNeM rW,MGGT. Un, HE Go—n,,nt—p, USGS.Wk4E USDA Nn wjAEI Figure 2. Stream Index 22-56-(1), Country Line Creek, WS-II;HQW Fact Sheet Renewa12017 — NPDES Permit NC0088692 Page 5 OUTFALL 001: The location of Outfall 001 in the previous permit and BIMS is not near the facility property. The coordinates [369 T46"N, 7912942"W] on a property not indicated on the original permit application. Plans with the original application proposed piping it closer to a spring across several properties. As noted in the July 28, 2010 inspection after the treatment system was constructed: The effluent is discharged into dry ditch along the store owner's driveway. Ultimately, the ditch discharges to an unnamed tributary of Country Line Creek in the Roanoke River Basin. The location of Outfall 001 is corrected to the following (See Figure 3): Latitude: 36' 17' 46' (36.296111) Longitude -79" 29' 3 1 " (-79.491944) Figure 3. Outfall 001 coordinates are changed to the facility property. Fact Sheet Renewal 2017 — NPDHS Pennit NCO088692 Page 6 NPDES Implementation of Instream Dissolved Metals Standards - Freshwater Standards The NC 2007-2015 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Commission (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016, with some exceptions. Therefore, metal limits in draft permits out to public notice after April 6, 2016 must be calculated to protect the new standards - as approved. Table 1. NC Dissolved Metals Water Ouality Standards/Aquatic Life Protection Parameter Acute FW, µg/1 (Dissolved) Chronic FW, µg/l (Dissolved) Acute SW, µg/1 (Dissolved) Chronic SW, µg/1 (Dissolved) Arsenic 340 150 69 36 Beryllium 65 6.5 Cadmium Calculation Calculation 40 8.8 Chromium III Calculation Calculation --- --- Chromium VI 16 11 1100 50 Copper Calculation Calculation 4.8 3.1 Lead I Calculation Calculation 210 8.1 Nickel Calculation Calculation 74 8.2 Silver Calculation 0.06 1.9 0.1 Zinc Calculation Calculation 90 81 Table 1 Notes: 1. FW= Freshwater, SW= Saltwater 2. Calculation = Hardness dependent standard 3. Only the aquatic life standards listed above are expressed in dissolved form. Aquatic life standards for Mercury and selenium are still expressed as Total Recoverable Metals due to bioaccumulative concerns (as are all human health standards for all metals). It is still necessary to evaluate total recoverable aquatic life and human health standards listed in 15A NCAC 2B.0200 (e.g., arsenic at 10 µg/1 for human health protection; cyanide at 5 µg/L and fluoride at 1.8 mg/L for aquatic life protection). Table 2. Dissolved Freshwater Standards for Hardness -Dependent Metals The Water Effects Ratio (WER) is equal to one unless determined otherwise under 15A NCAC 02B .0211 Subparagraph (11)(d) Metal NC Dissolved Standard, 1 Cadmium, Acute WER*{1.136672-[In hardness](0.041838)) - e^{0.9151 [in hardness]-3.1485) Cadmium, Acute Trout waters WER*{1.136672-[In hardness](0.041838)) e^{0.9l5l[1n hardness]-3.6236j Cadmium, Chronic WER*{1.101672-[/n bardness](0.041838)1 • e^{0.7998[/n hardness]-4.44511 Chromium III, Acute WER*0.316 • e^(0.8190[ln hardness]+3.7256) Chromium III, Chronic WER*0.860 • e^{0.8190[In hardness]+0.68481 Copper, Acute WER*0.960 • e^(0.9422[ln hardness]-1.700) Copper, Chronic WER*0.960 • e^(0.8545[ln hardness]-1.702) Lead, Acute WER*{1.46203-[In hardness](0.145712)) e^{1.273[In hardness]-1.460) Lead, Chronic WER*{1.46203-[/n hardness](0.145712)) • e^{1.273[in hardness]-4.705) Nickel, Acute WER*0.998 • e^{0.8460[ln hardness]+2.255) Nickel, Chronic WER*0.997 • e^{0.8460[In hardness]+0.0584) Fact Sheet Renewal 2017 - NPDES Permit. NCO088692 Page 7 Silver, Acute WER*0.85 - e^ { 1.72[ln hardness]-6.59 ) Silver, Chronic Not applicable Zinc, Acute WER*0.978 - e^ {0.8473 [In hardness]+0.884) Zinc, Chronic WER*0.986 - e^(0.8473[ln hardness]+0.884) General Information on the Reasonable Potential Analysis (RPA) The RPA process itself did not change as the result of the new metals standards. However, application of the dissolved and hardness -dependent standards requires additional consideration in order to establish the numeric standard for each metal of concern of each individual discharge. The hardness -based standards require some knowledge of the effluent and instream (upstream) hardness and so must be calculated case -by -case for each discharge. Metals limits must be expressed as `total recoverable' metals in accordance with 40 CFR 122.45(c). The discharge -specific standards must be converted to the equivalent total values for use in the RPA calculations. We will generally rely on default translator values developed for each metal (more on that below), but it is also possible to consider case -specific translators developed in accordance with established methodology. RPA Permitting Guidance/WOBELs for Hardness -Dependent Metals - Freshwater The RPA is designed to predict the maximum likely effluent concentrations for each metal of concern, based on recent effluent data, and calculate the allowable effluent concentrations, based on applicable standards and the critical low -flow values for the receiving stream. If the maximum predicted value is greater than the maximum allowed value (chronic or acute), the discharge has reasonable potential to exceed the standard, which warrants a permit limit in most cases. If monitoring for a particular pollutant indicates that the pollutant is not present (i.e. consistently below detection level), then the Division may remove the monitoring requirement in the reissued permit. 1. To perform a RPA on the Freshwater hardness -dependent metals the Permit Writer compiles the following information: • Critical low flow of the receiving stream, 7Q 10 (the spreadsheet automatically calculates the 1 Q 10 using the formula 1 Q 10 = 0.843 (s7Q 10, cfs) 0.993 • Effluent hardness and upstream hardness, site -specific data is preferred • Permitted flow • Receiving stream classification 2. In order to establish the numeric standard for each hardness -dependent metal of concern and for each individual discharge, the Permit Writer must first determine what effluent and instream (upstream) hardness values to use in the equations. The permit writer reviews DMR's, Effluent Pollutant Scans, and Toxicity Test results for any hardness data and contacts the Permittee to see if any additional data is available for instream hardness values, upstream of the discharge. If no hardness data is available, the permit writer may choose to do an initial evaluation using a default hardness of 25 mg/L (CaCO3 or (Ca + Mg)). Minimum and maximum limits on the hardness value used for water quality calculations are 25 mg/L and 400 mg/L, respectively. Fact Sheet Renewal 2017 — NPDES Permit NC0088692 Page 8 If the use of a default hardness value results in a hardness -dependent metal showing reasonable potential, the permit writer contacts the Permittee and requests 5 site -specific effluent and upstream hardness samples over a period of one week. The RPA is rerun using the new data. The overall hardness value used in the water quality calculations is calculated as follows: Combined Hardness (chronic) = (Permitted Flow, cfs *Avg. Effluent Hardness, mg/L) + (s7Q 10. cfs *Avg. Upstream Hardness, mg/L) (Permitted Flow, cfs + s7Q 10, cfs) The Combined Hardness for acute is the same but the calculation uses the IQ 10 flow. 3. The permit writer converts the numeric standard for each metal of concern to a total recoverable metal, using the EPA Default Partition Coefficients (DPCs) or site -specific translators, if any have been developed using federally approved methodology. EPA default partition coefficients or the "Fraction Dissolved" converts the value for dissolved metal at laboratory conditions to total recoverable metal at in -stream ambient conditions. This factor is calculated using the linear partition coefficients found in The Metals Translator. Guidance for Calculating a Total Recoverable Permit Limit from a Dissolved Criterion (EPA 823-B-96-007, June 1996) and the equation: C iss - 1 Ctotal 1 + { [Kpol [ssit+ai] [10�1 } Where: ss = in -stream suspended solids concentration [mg/1], minimum of 10 mg/L used, and Kpo and a = constants that express the equilibrium relationship between dissolved and adsorbed forms of metals. A list of constants used for each hardness -dependent metal can also be found in the RPA program under a sheet labeled DPCs. 4. The numeric standard for each metal of concern is divided by the default partition coefficient (or site -specific translator) to obtain a Total Recoverable Metal at ambient conditions. In some cases, where an EPA default partition coefficient translator does not exist (ie. silver), the dissolved numeric standard for each metal of concern is divided by the EPA conversion factor to obtain a Total Recoverable Metal at ambient conditions. This method presumes that the metal is dissolved to the same extent as it was during EPA's criteria development for metals. For more information on conversion factors see the June, 1996 EPA Translator Guidance Document. 5. The RPA spreadsheet uses a mass balance equation to determine the total allowable concentration (permit limits) for each pollutant using the following equation: Ca = (s7Q 10 + Qw) (Cwgs) — (s7Q 10) (Cb) Qw Where: Ca = allowable effluent concentration (µg/L or mg/L) Cwqs = NC Water Quality Standard or federal criteria (µg/L or mg/L) Cb = background concentration: assume zero for all toxicants except NH3* (µg/L or mg/L) Qw = permitted effluent flow (cfs, match s7Q 10) s7Q 10 = summer low flow used to protect aquatic life from chronic toxicity and human health through the consumption of water, fish, and shellfish from noncarcinogens (cfs) Fact Shect Renewa12017 — NPDES Pennit NCO088692 Page 9 * Discussions are on -going with EPA on how best to address background concentrations Flows other than s7Q 10 may be incorporated as applicable: IQ 10 = used in the equation to protect aquatic life from acute toxicity QA = used in the equation to protect human health through the consumption of water, fish, and shellfish from carcinogens 30Q2 = used in the equation to protect aesthetic quality 6. The permit writer enters the most recent 2-3 years of effluent data for each pollutant of concern. Data entered must have been taken within four and one-half years prior to the date of the permit application (40 CFR 122.21). The RPA spreadsheet estimates the 95th percentile upper concentration of each pollutant. The Predicted Max concentrations are compared to the Total allowable concentrations to determine if a permit limit is necessary. If the predicted max exceeds the acute or chronic Total allowable concentrations, the discharge is considered to show reasonable potential to violate the water quality standard, and a permit limit (Total allowable concentration) is included in the permit in accordance with the U.S. EPA Technical Support Document for Water Quality -Based Toxics Control published in 1991. 7. When appropriate, permit writers develop facility specific compliance schedules in accordance with the EPA Headquarters Memo dated May 10, 2007 from James Hanlon to Alexis Strauss on 40 CFR 122.47 Compliance Schedule Requirements. 8. The Total Chromium NC WQS was removed and replaced with trivalent chromium and hexavalent chromium Water Quality Standards. As a cost savings measure, total chromium data results may be used as a conservative surrogate in cases where there are no analytical results based on chromium III or VI. In these cases, the projected maximum concentration (95th %) for total chromium will be compared against water quality standards for chromium III and chromium VI. 9. Effluent hardness sampling and instream hardness sampling, upstream of the discharge, are inserted into all permits with facilities monitoring for hardness -dependent metals to ensure the accuracy of the permit limits and to build a more robust hardness dataset. 10. Hardness and flow values used in the Reasonable Potential Analysis for this permit included: Parameter Value Comments (Data Source) Average Effluent Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] 25 default hardness Average Upstream Hardness (mg/L) [Total as, CaCO3 or (Ca+Mg)] 25 default hardness 7Q10 summer (cfs) 0 NPDES Files and BIMS 1 Q 10 (cfs) 0 NPDES Files and BIMS Permitted Flow (MGD) 0.009 NPDES Files and BIMS Date: July 31, 2017 Permit Writer: Derek Denard Fact Shcet Renewal 2017 — NPDES Pennit NC0088692 Page 10 North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters Freshwater resh&Safi Saltwater All, aters Class WS All waters All waters Class B (Class C& Class SB Class SA Supplemental Classifications (1- Vi (Class Q Lass SQ Aquatic Aquatic Prima Primary Water t Life & Human r Life & Prima Primary Swam P High Cancer Pollutant or CAS# s Recreation Supply` Secondary a Health Secondary e Recreaton a Shellfish Trout' s Waters Quality 7 Synonyms &Other ra Endpoint Reference Soi nfo (See Parsmeter a < Waters Information supporting info tab) Recreaton Recreation (HH & W$) All values reported as ug/Lunless labeled otherwise. Benzene 71-43-2 1.19 51 Yes IRIS 2000 Hardness NA 100 mg/L As Ca CO3 or Ca&Mg NA EPA QCW 1963 Acute: Acute: Click to Cal culate EPA AWQC - lead freshwateraquatic life Lead" 7439-92.1 Ca lc(d,h) 210(d) NA 1984; EPA NRWQC- Chronic Calc dh Chronic 8.1 d Correct on 1999 standard Aesthetic narrative Phenolic 300(P) 300(P) standard for taste &odor Compounds NA aesthetic aesthetic In fish tissue. Based on NA EPA QCW 1976 public policy document. Suspended t Total suspended solids NA 10000(E) I 20000 (E) I Effluent Unlit. See 15A I NA EPA QCW 1986 SolidsI NCAC 028 .0224 The values in these tables do not substitute for any written regulations, nor are they themselves regulations. Hardness -Dependent Metal Calculations Enter in -stream Metal Equations for Hardness -Dependent Metals(ug/L) Calculated standard(ug/L) hardness [nri Lead, acute WER'[{1.46203+n hardness](0.145712))•e4(1.273[ln hardness]-1A60)] 25 13.88 Lead, chronic WER'H1.46203-l1n hardness](0.145712))•e A(1.273[1n hardness]-4.705)] 25 0.54 See the Supporting Info tab for information on all footnotes, notes, and abbreviations Freshwater RPA - 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY CHECK WQS Table 1. Project Information I]CHECK IF HQW OR ORW WQS Facility Name Sparks Oil Co./JW Smith/Camp Springs 76 GWR W WTP/WTP Class PC-1 NPDES Permit NCO088692 Outfall 001 Flow, Qw (MGD) 0.009 Receiving Stream UT to Country Line Creek HUC Number 030101040202 Stream Class WS-II;HQW QApply WS Hardness WQC 7010s (cfs) 0.00 701 Ow (cfs) 0.00 30Q2 (cfs) 0.00 QA (cfs) 0.00 1010s (cfs) 0.00 Effluent Hardness 25 ni (Avg) Upstream Hardness _ _ _ _ _ _ 25 mg/L (Avg) Combined Hardness Chronic 25 mg/L Combined Hardness Acute 25 mg/L Data Sourcets) BIMS DMRs Dec2012 to May2017 UCHECK TO APPLY MODEL v directions for data entry. In some cases a Tent menu list the available choices or a sown menu will provide a list you may select, Error message occur if data entry does not input criteria. Par01 Par02 Par03 Par04 Parts Pai Par07 Parts Par09 Par10 Par11 Par12 Par13 Parl4 Paris Parts Par17 Paris Par19 Par20 Par21 Par22 Par23 Par24 Pails Table 2. Parameters of Concern Name Wos Typo Chronic Modifier Acute PQL Units Total Phenolic Compounds NCO088692 9595 Final FW RPA w_upstream avg data column_diss to totalmetals_nodetects_limiteddefaults 2016_822, input 7/31/2017 REASONABLE POTENTIAL ANALYSIS H7 H2 U.'PASTE SPECIAL Uae'PASTE SPECIAL Effluent Hardness Values" than "COPY'• Upstream Hardness Values"then"COPY^ . Maximum data . Max mum data points = 56 Points = 56 Date Data BDL=112DL Results Date Data BDL=112DL Results 1 25 25 Sld Dev. N/A 1 25 25 Std Dev. NIA 2 Mean 25.0000 2 Mean 25.0000 3 C.V. 0.0000 3 C.V. 0.0000 4 n 1 4 n 1 5 10th Per value 25.00 mg/L 5 10th Per value 25.00 mg/L 6 Average Value 25.00 mg/L 6 Average Value 25.00 mg/L 7 Max. Value 25.00 mg/L 7 Max. Value 25.00 mg/L 8 8 9 9 10 10 11 11 12 12 13 13 14 14 15 15 16 16 17 17 18 18 19 19 20 20 21 21 22 22 23 23 24 24 25 25 26 26 27 27 28 28 29 29 30 30 31 31 32 32 33 33 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 NC0088692 9595 Final FW RPA w_upstream avg data column_diss to totalmetals_nodetects_limiteddefaults 2016 822, data - 1 - 7/31/2017 REASONABLE POTENTIAL ANALYSIS Par67 Par14 Use 'PASTE SPECIAL U.'PASTE SPECIAL Total Phenolic Compounds Values" then "COPY" Lead Values"then "COPY" . Maximum data . Maximum data Points = 58 points = SS Date Data BDL=112DL Results Date BDL=112DL Results 1 12/5/2012 38 38 Std Dev. 26,9785 1 5/7/2014 < 5 2.5 Std Dev. 0.0000 2 1/9/2013 14 14 Mean 18.6275 2 6/4/2014 < 5 2.5 Mean 2.5000 3 2/6/2013 8.1 8.1 C.V. 1.4483 3 7/7/2014 < 5 2.5 C.V. 0.0000 4 3/612013 7.5 7.5 In 40 4 8/2612014 < 5 2.5 n 33 5 10/14/2013 9 9 5 9/10/2014 < 5 2.5 6 2/512014 22 22 Mult Factor = 1.22 6 11142015 < 5 2.5 Mult Factor= 1.00 7 4/10/2014 44 44 Max. Value 160.0 ug/L 7 2/11/2015 < 5 2.5 Max. Value 2.500 ug/L 8 5/7/2014 160 160 Max. Pred Cw 195.2 ug/L 8 4/16/2015 < 5 2.5 Max. Pred Cw O DETECTS ug/L 9 6/4/2014 22 22 9 5/4/2015 < 5 2.5 10 7/7/2014 < 5 2.5 10 6/24/2015 < 5 2.5 11 8/26/2014 < 10 5 11 7/13/2015 < 5 2.5 12 9/10/2014 14 14 12 8/19/2015 < 5 2.5 13 1/14/2015 < 10 5 13 9/16/2015 < 5 2.5 14 2/11/2015 < 10 5 14 10/14/2015 < 5 2.5 15 4/16/2015 11 11 15 1112&2015 < 5 2.5 16 5/4/2015 < 10 5 16 12/16/2015 < 5 2.5 17 6/24/2015 < 10 5 17 1/612016 < 5 2.5 18 7/13Y2015 < 10 5 18 2/1012016 < 5 2.5 19 8/19/2015 < 10 5 19 W=2016 < 5 2.5 20 9/1612015 11 11 20 4/19/2016 < 5 2.5 21 10/14/2015 45 45 21 5111/2016 < 5 2.5 22 11/23/2015 < 10 5 22 6/1512016 < 5 2.5 23 12116/2015 < 10 5 23 71132016 < 5 2.5 24 1/6/2016 16 16 24 8/172016 < 5 2.5 25 2/10/2016 17 17 25 9/212016 < 5 2.5 26 3/22/2016 20 20 26 10/12/2016 < 5 2.5 27 4/19/2016 12 12 27 11/1612016 < 5 2.5 28 5111/2016 < 10 5 28 12/72016 < 5 2.5 29 6/152016 < 10 5 29 1/112017 < 5 2.5 30 7/13/2016 28 28 30 2/712017 < 5 2.5 31 8/172016 10 10 31 3/142017 < 5 2.5 32 91212016 62 62 32 4/192017 < 5 2.5 33 10/122016 17 17 33 5/102017 < 5 2.5 34 11/16/2016 < 10 5 34 35 12f72016 12 12 35 36 1/11/2017 18 18 36 37 2/7/2017 50 50 37 38 3/142017 < 10 5 38 39 4/192017 < 10 5 39 40 5/102017 < 10 5 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 NCO088692 9595 Final FW RPA w_upstream av9 data column_diss to totalmetals_nodetects_limiteddefaults 2016_822, data -2- 7/312017 REASONABLE POTENTIAL ANALYSIS Par22 Par23 U.'PASTE SPECIAL Use 'PASTE SPECIAL Benzene Values then "COPY" Benzene Values"then"COPY" . Maxfmum data Maximum data points = 56 points = 50 Date Data BDL=112DL Results Date Data BDL=I2DL Results 1 5f7/2014 < 0.5 0,25 Sid Dev. 0.0000 1 5RI2014 < 0.5 0.25 Std Dev. 0.0000 2 6/4/2014 < 0.5 0.25 Mean 0.2500 2 8/4/2014 < 0.5 0.25 Mean 0.2500 3 7/7/2014 < 0.5 0.25 C.V. 0.0000 3 717/2014 < 0.5 0.25 C.V. 0.0000 4 8/26/2014 < 0.5 0.25 n 33 4 8/26/2014 < 0.5 0.25 n 33 5 91102014 < 0.5 0.25 5 9/1012014 < 0.5 0.25 6 1/142015 < 0.5 0.25 Mult Factor= 1.00 6 1/1412015 < 0.5 0.25 Mull Factor= 1.00 7 2/112015 < 0.5 0.25 Max. Value 0.250000 pg/L 7 2/112015 < 0.5 0.25 Max. Value 0.250000 pglL 8 41162015 < 0.5 0.25 Max. Fred Cw O DETECTS pg1L 8 4/162015 < 0.5 0.25 Max. Fred Cw 0 DETECTS pg/L 9 5/4/2015 < 0.5 0.25 9 5/4/2015 < 0.5 0.25 10 61242015 < 0.5 0.25 10 6/24/2015 < 0.5 0.25 11 7113/2015 < 0.5 0.25 11 7/13/2015 < 0.5 0.25 12 8/1912015 < 0.5 0.25 12 8/19/2015 < 0.5 0.25 13 9116/2015 < 0.5 0.25 13 9/16/2015 < 0.5 0.25 14 1011412015 < 0.5 0.25 14 10/14/2015 < 0.5 0.25 15 1123/2015 < 0.5 0.25 15 112312015 < 0.5 0.25 16 1211612015 < 0.5 0.25 16 12116/2015 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 18 2/102016 < 0.5 0.25 18 2/102016 < 0.5 0.25 19 3/222016 < 0.5 0.25 19 3/222016 < 0.5 0.25 20 4119/2016 < 0.5 0.25 20 4/192016 < 0.5 0.25 21 51112016 < 0.6 0.25 21 5/112016 < 0.5 0.25 22 6/15/2016 < 0.5 0.25 22 6/15/2016 < 0.5 0.25 23 7/132016 < 0.5 0.25 23 7113/2016 < 0.5 0.25 24 8/172016 < 0.5 0.25 24 8/17/2016 < 0.5 0.25 25 9/212016 < 0.5 0.25 25 9/2112016 < 0.5 0.25 26 10/12/2016 < 0.5 0.25 26 10/12/2016 < 0.5 0.25 27 111162016 < 0.5 0.25 27 1111612016 < 0.5 0.25 28 12/7/2016 < 0.5 0.25 28 12172016 < 0.5 0.25 29 1/112017 < 0.5 0.25 29 1/1112017 < 0.5 0.25 30 2/7/2017 < 0.5 0.25 30 21712017 < 0.5 0.25 31 3114/2017 < 0.5 0.25 31 3/14/2017 < 0.5 0.25 32 4/19/2017 < 0.5 0.25 32 4/19/2017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 1 58 NCO088692 9595 Final FW RPA w_upstream avg data column_diss to totalmetals_nodetects_limitedde%ults 2016_822, data -3- 7/31/2017 REASONABLE POTENTIAL ANALYSIS Par24 CIAL Toluene pro -..COPY" . m.i..m Oat. points = 58 Date Data BDL=112DL Results 1 6/7/2014 < 0.5 0.25 SW Dev. 0.0000 2 6/4/2014 < 0.5 0.25 Mean 0.2500 3 7/7/2014 < 0.5 0.25 C.V. 0.0000 4 8/26/2014 < 0.5 0.25 n 33 5 9/10/2014 < 0.5 0.25 6 1/14/2015 < 0.5 0.25 Mull Factor = 1.00 7 2/11/2015 < 0.5 0.25 Max. Value 0.250000 pg/L 8 4/16/2015 < 0.5 0.25 Max. Pred Cw O DETECTS pg/L 9 5/4/2015 < 0.5 0.25 10 6/24/2015 < 0.5 0.25 11 7/13/2015 < 0.5 0.25 12 8/19/2015 < 0.5 0.25 13 9/16/2015 < 0.5 0.25 14 10/14/2015 < 0.5 0.25 15 11/23/2015 < 0.5 0.25 16 12/16/2015 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 18 2/1012016 < 0.5 0.25 19 3/22/2016 < 0.5 0.25 20 4/19/2016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 22 6/15/2016 < 0.5 0.25 23 7/13/2016 < 0.5 0.25 24 8/17/2016 < 0.5 0.25 25 9/21/2016 < 0.5 0.25 26 10/12/2016 < 0.5 0.25 27 11/16/2016 < 0.5 0.25 28 12/7/2016 < 0.5 0.25 29 1/11/2017 < 0.5 0.25 30 2/7/2017 < 0.5 0.25 31 3/14/2017 < 0.5 0.25 32 4/19/2017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 NCO088692 9595 Final FW RPA w_upstream avg data column -din to totalmetals_nodelecls_limiteddefaults 2016 822, data - 4 - 7/31/2017 Sparks Oil Co./JW Smith/Camp Springs 76 GWR NCO088692 Freshwater RPA- 95% Probability/95% Confidence Using Metal Translators MAXIMUM DATA POINTS = 58 Qw(MGD)= 0.01 WW"IP/WI'P Class: PC-1 IQIOS(cfs)= 0.00 RVC%@1Q10S = 100 7QIOS(cfs)= 0.00 IWC%@7QIOS= 100 7Q10W(cfs)= 0.00 IWC%@7QIOW= 100 30Q2(cfs)= 0.00 IWC%@30Q2= 100 Avg. Stream Flow, QA (cfs) = 0.00 IW%uC @ QA = 100 Receiving Stream: UT to Country Line Creek HUC 030101040202 Stream Class: WS-II;HQW Outfall 001 Qw = 0.009 MGD YOU HAVE DESIGNATED THIS RECEIVING STREAM AS HQW OR ORW COMBINED HARDNESS tmz/L) Acute = 25 mg/L Chronic = 25 mg/L YOU HAVE DESIGNATED THIS RECEIVING STREAM AS WATER SUPPLY Effluent Hard: 0 value 1100 mg/L Effluent Hard Avg = 25 mg/L PARAMETER NC STANDARDS OR EPA CRITERIA REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE J Chronic Standard Acute n #Det. Max Pred Cw Allowable Cw (11 g Acute: NO WQS Total Phenolic Compounds NC 150 A ug/L 40 24 1952 Chronic: 150.0 RP shown- apply Monthly Monitoring with Limit I values > Allowable Cw Acute: 37.744 No detects - POC Maintain Monitoring Lead NC 1.4708 FW 37.7436 ug/L 33 0 NO DETECTS _ __ Chronic: 1.471 _ _ _ _ _ _ _ _ ________ No detects - POC Maintain Monitoring Max MDL = 5 Acute: NO WQS Benzene C 0.595 WS pg/L 33 0 NO DETEC7S _ _ _ _ _ _ __ Chronic: 0.595 _ _ _ _ _ _ _ _ _ _ _ _ _ No detects- POC Maintain Monitodng Max MDL = 0.5 Acute: NO WQS Benzene C _.-..- HH pg/L 33 0 NO DETECTS _ _ _ ____ _ __ Chronic: 25.5 _ _ _ _ _ _ _ _______ No deteCW-POC Maintain Monitoring Max MDL = 0.5 Acute: NO WQS Toluene NC i s FW pg/L 33 0 NO DETECTS _ _ _ _ _ _ _ ______ _ Chronic: 5.5 _ _ _ _ _ _ ______ No detects- POC Maintain Monitoring VPic 41DI_ —0.5 NCO088692 9595 Final FW RPA w_upst ream avg data column_diss to totalmetels_nodelecls_limiteddefaults 2016_822, pa Page 1 of 1 7/31/2017 Date: 7/31 /2017 FACILITY: Sparks Oil CoJJW Smith/Camp Springs 76 GWR NPDES PERMIT: NCO088692 Dissolved to Total Metal Calculator In accordance with Federal Regulations, permit limitations must be written as Total Metals per 40 CFR 122.45(c) Receiving Receiving Rec. Stream NPDES Total Suspended Combined Combinetl mstream Instr Upstream Hard Avg (mg/L) = 25 EFF Hard Avg (mg/L) = 25 PARAMETER Dissolved Metals U EPA Translators. using Default Partition Coefficients streams Maornum Allawat eEMuent Conceration (MAEC) as a Total Meal -Oiwlwd Metel•Tmhwxx COMMENTS (identify parameters to PERCS Branch to maintain in facility's LTMP/STMP): Chronic Acute Chronic Acute to u u u Cadmium (d) Cd -Trout stream Chromium III (d)(h) Chromium VI (d) Chromium, Total (t Copper (d)(h) _ Lead (d)(h) Nickel (d)(h) 0.15 0.82 0.252 0.59 0.59 117.73 11.00 WA 7.88 2.94 37.231 3.24 _ 0.15 0.51 24, 183 0.252 2.01 0.202 1.000 0.348 0.184 905.0 11 16 16.00 WA 2.71 3.6 10.47 0.54 14 75.49 16 145 0.432 335.21 NI - WS streams (t) Sliver (d)(h,acute Zinc (d)(h) 1.000 0.288 25 WA 0.06 0.30 126.73 125.71 0.06 0.30 36 36 Be Ilium 6.5 65 1.000 6.5 65 Arsenic d 150 340 1.000 150 340 (d) = dissolved metal standard. See ISA NCAC 02B .0211 for more Information. (h) = hardness -dependent dissolved metal standard. See 15A NCAC 02B .0211 for more Information. (t) = based upon measurementof WWI recoveable metal. See 15A NCAC 02B.0211 for more Information. The Human Health standard for Nickel in Water Supply Streams is 25 mg/L which Is Total Recoverable metal standard, The Human Health standard for Arsenic is 10 µg/L which is Total Recoverable metal standard. Stream Stream Solids Hardness Hardness Waslewdter eam Wastewater Effluent Upstream Hardness Summer summer 7010 1010 Flow Limit -Fixed Value- chronic Acute Canwniratlon Concentration Hardness Average 7010 (CFS) (MGD) MGD GD (mgA) (mglL) (mglL) (Chrenk) (Awls) Average (mgA.) (mglL) 0.0000 0.0000 0.0000 0.0090 10 25.000 25.000 700.0000 11 100.0000 25 25 North Carolina Protective Values for Surface Waters These criteria maybe based on limited toxicological information and are offered as guidelines only, Contact DW R staff for further inform ati on. Freshwater Fresh &Salt I Saltwater Class WS All waters All waters All waters Supplemental Class 0 Class SB Class SA 1-V) s as C& asss IH Inns Primary Water Aquatic Life' &Secondary Aquatic Life' &Secondary primary z Swamp High Quality Cance Reference Sourte Ran s Supply Human Healths a Recreation Shell0shs Trout s Waters Synaryms&Other Pollutardar Parameter CAS# , Renlatlar x Recreation t Waters Inlormatlon Endpoint"(Seesupponinginlo (HH&WS) tab) All values reported as ug/L unless labeled otherwise. 1,2-Dibrumomethane 106.93-4 0.02 0.1 EDS, Ethylene Dibromide Yes IRIS 8/10 Isopropyl Ether 108-20-3 20000 330000 2,2'-Oxybispropane NA ECOTOX 8/10 Methyl Tertiary -butyl ECOTOX 9/15& MTBE 1634-04-0 19 34000 1500 SOOOD Ether Y!s CALEPA 1999 Naphthalene 91-20-3 12 52 Mothballs NA ECOTOX 8/10 n-Propyl Benzene 103-55-1 I500 80 2700 4600 No ECOTOX&RATS 9/15 Toluene 108-88-3 370 NA ECOTOX 8/07 1,2,4-Td meth yl be nzen a 95-63-6 1 390 1 220 NA ECOTOX 8/10 ECOTOX 9/15&RATS 1,3,5- Td methyl ben ze ne 108-67-8 130 630 215 220 Mesitirlene No 8/10 Xylene Mixture 1330-20-7 6200 670 57000 370 450 No IRIS & ECOTOX6/12 1,3-Dimethobenzene, Human Health and Water m-Xylene 208-38-3 6200 420 57000 180 420 NA ECOTOX 6/22 Supply use xyl ene Mixture as surrogate 1,4-DI methyl benzene, Human Health and Water p-Xylene 106-42-3 6200 420 57000 100 130 NA ECOTOX 6/12 Supply use Xyl ene Mixtureas sumo ate 1,2-DI methyl benze ne, Human Health and Water o-Xylene 95-47-6 62M 600 57000 60 411 NA ECOTOX 6/12 Supplyuse Xylene Mixture as surrogate Seethe Supporting Info tab for information on all footnotes, notes, and abbreviations 2016 Generic RPA (non -hardness dependent) - 95% Probability/95% Confidence MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 1. Project Information ❑+ QIECK IF HQW OR ORW Facility Name W WTP/WTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream Stream Class Mills (cfs) 7410w (cfs) 30Q2 (cfs) QA (cfs) 1010s lots) Data Source(s) ❑CHECK TO APPLY MODEL Sparks Oil Co./JW Smith/Camp Springs 76 GWR PC-1 NCO088692 001 _ — 0.00900 UT to Country Line Creek WS-II;HQW 0.00 0.00 0.00 0.00 0,00 BIMS DMRs Dec2012 to May2017 RPA for NC Protective Values: These criteria are calculated based on allowances in 15A NCAC 02B .0211 & .0208. These values my be based on limited toxicological information. Follow directions for data entry. In some cases a comment menu list the available choices or a dropdown menu will provide a list you may select from. Error message occur if data entry does not meet input criteria. Par01 Par02 Par03 Par04 Pare5 Par06 Par07 Par08 Par09 Par10 Par11 Par12 Par13 Par14 Par15 Par16 Par17 Parl8 Par19 Par20 Par21 Par22 Table 2. Parameters of Concern Name Type Chronic Modifier Acute PQL Units Ethylene Dibromide C 0.02 WS pg/L Ethylene Dibromide C 0.1 HH pg/L Ethylbenzene NC 97 WS pg/L Isopropyl Ether NC 20000 FW pg/L MTBE (Methyl Tertiary -butyl Ether) C 19 WS pg/L MTBE (Methyl Tertiary -butyl Ether) C 34000 FW pg/L MTBE (Methyl Tertiary -butyl Ether) C 1500 HH pg/L Naphthalene NCI 12 FW pg/L n-Propyl Benzene NCI 1500 WS pg/L n-Propyl Benzene NC 80 FW pg/L n-Propyl Benzene NC 2700 HH pg/L 1,2,4-Trimethylbenzene NC 390 FW pg/L 1,3,5-Trimethylbenzene NC 130 WS pg/L 1,3,5-Trimethylbenzene NC 630 FW pg/L 1,3,5-Trimethylbenzene NC 215 HH pg/L Xylenes, Mixture NC 6200 WS pglL Xylenes, Mixture NC 1 670 FW pg/L Xylenes, Mixture NC 57000 HH pg/L NCO088692 NC Protective 9595 GENERIC non —hardness RPA2016_53, input 7/31/2017 REASONABLE POTENTIAL ANALYSIS 1 2 Uaa'PASTE SPECIAL Use'PASTE SPECIAL Ethylene Dibromide Y Values^ than 'COPY" Ethylene Iene Dibromide Values"than "COPY" . Maximum data . Maximum data points = 58 points = 58 Date Data BDL=112DL Results Date Data BDL=112DL Results 1 5/712014 < 0.5 0.25 Sld Dev. 0.0000 1 5l7/2014 < 0.5 0.25 Sad Dev. 0,0000 2 6/4/2014 < 0.5 0.25 Mean 0.2500 2 6/4/2014 < 0.5 0.25 Mean 0.2500 3 7/7/2014 < 0.5 0.25 C.V. 0.0000 3 717/2014 < 0.5 0.25 C.V. 0.0000 4 8/26/2014 < 0.5 0.25 n 33 4 8/26/2014 < 0.5 0.25 It 33 5 911012014 < 0.5 0.25 5 9/10/2014 < 0.5 0.25 6 1/142015 < 0.5 0.25 Mult Factor = 1.0000 6 1/14/2015 < 0.5 0.25 Muft Factor = 1.0000 7 2/1112015 < 0.5 0.25 Max. Value 0.3 pg/L 7 2/11/2015 < 0.5 0.25 Max. Value 0.3 pg/L 8 4/162015 < 0.5 0.25 Max. Pred Cw O DETECTS pg/L 8 4/162015 < 0.5 0.25 Max. Pred Cw 0 DETECTS pg/L 9 5/4/2015 < 0.5 0.25 9 5/4/2015 < 0.5 0.25 10 6/24/2015 < 0.5 0.25 10 6/24/2015 < 0.5 0.25 11 71132015 < 0.5 0.25 11 7/13/2015 < 0.5 0.25 12 8/192015 < 0.5 0.25 12 8/1912015 < 0.5 0.25 13 9/162015 < 0.5 0.25 13 911612015 < 0.5 0.25 14 10/14/2015 < 0.5 0.25 14 10/14/2015 < 0.5 0.25 15 11/23/2015 < 0.5 0.25 15 1123/2015 < 0.5 0.25 16 12116/2015 < 0.5 0.25 16 12116/2015 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 18 2/10/2016 < 0.5 0.25 18 2/102016 < 0.5 0.25 19 3/22/2016 < 0.5 0.25 19 3/22/2016 < 0.5 0.25 20 4/1912016 < 0.5 0.25 20 4/192016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 22 6/152016 < 0.5 0.25 22 6/152016 < 0.5 0.25 23 7/132016 < 0.5 0.25 23 7/132016 < 0.5 0.25 24 8/17/2016 < 0.5 0.25 24 8117/2016 < 0.5 0.25 25 91212016 < 0.5 0.25 25 9121/2016 < 0.5 0.25 26 10/12/2016 < 0.5 0.25 26 W12/2016 < 0.5 0.25 27 11/16/2016 < 0.5 0.25 27 11/16/2016 < 0.5 0.25 28 12/7/2016 < 0.5 0.25 28 12/712016 < 0.5 0.25 29 1/11/2017 < 0.5 0.25 29 1/11/2017 < 0.5 0.25 30 2/7/2017 < 0.5 0.25 30 21712017 < 0.5 0.25 31 3/14/2017 < 0.5 0.25 31 3/1412017 < 0.5 0.25 32 4119/2017 < 0.5 0.25 32 4/19=17 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 33 5/102017 < 0.5 0.25 34 34 35 35 36 36 37 37 3B 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 5B 58 NCO088692 NC Protective 9595 GENERIC non hardness RPA2016_53, data -1- 7/31/2017 REASONABLE POTENTIAL ANALYSIS 3 4 Use 'PASTE SPECIAL Use 'PASTE SPECIAL Ethylbenzene Values"Men "COPY" Isopropyl Ether Values"Men"COPY" . Maximum date . Muimum d.1 points = 58 Points = 58 Date Data BDL=112DL Results Date Data BDL=112DL Results 1 5/7/2014 < 0.5 0.25 Sul Dev. 0.0000 1 5/7/2014 < 500 250 Sld Dev. 0.0000 2 6/412014 < 0.5 0.25 Mean 0.2500 2 6/4/2014 < 500 250 Mean 250.0000 3 7/7/2014 < 0.5 0.25 C.V. 0.0000 3 7/7/2014 < 500 250 C.V. 0.0000 4 8/26/2014 < 0.5 0.25 n 33 4 8/26/2014 < 500 250 n 33 5 9/10/2014 < 0.5 0.25 5 9/10/2014 < 500 250 6 1/14/2015 < 0.5 0.25 Mult Factor = 1.0000 6 1/1412015 < 500 250 Mult Factor = 1.0000 7 2/1112015 < 0.5 0.25 Max. Value 0.3 Y91L 7 2/1112015 < 500 250 Max. Value 250.0 Pg/L 8 411612015 < 0.5 0.25 Max. Pred Cw O DETECTS pg/L 8 411612015 < 500 250 Max. Pred Cw O DETECTS yg/L 9 5/4/2015 < 0.5 0.25 9 514/2015 < 500 250 10 6/2412015 < 0.5 0.25 10 6/2412015 < 500 250 11 7113/2015 < 0.5 0.25 11 7/13/2015 < 500 250 12 8/19/2015 < 0.5 0.25 12 8/19/2016 < 500 250 13 9/16/2015 < 0.5 0.25 13 9/16/2015 < 500 250 14 10/14/2015 < 0.5 0.25 14 10/14/2015 < 500 250 15 11/23/2015 < 0.5 0.25 15 11/23/2015 < 500 250 16 12/16/2015 < 0.5 0.25 16 12/16/2015 < 500 250 17 116/2016 < 0.5 0.25 17 116/2016 < 500 250 18 2110/2016 < 0.5 0.25 18 2110/2016 < 500 250 19 3122I2016 < 0.5 0.25 19 3/22I2016 < 500 250 20 4119/2016 < 0.6 0.25 20 4/19/2016 < 500 250 21 5/11/2016 < 0.5 0.25 21 5/11/2016 < 500 250 22 6/15/2016 < 0.5 0.25 22 6/15/2016 < 500 250 23 7113/2016 < 0.5 0.25 23 7/13/2016 < 500 250 24 8/17/2016 < 0.5 0.25 24 8/17/2016 < 500 250 25 9/21/2016 < 0.5 0.25 25 9121/2016 < 500 250 26 10/12I2016 < 0.5 0.25 26 10/12/2016 < 500 250 27 11/16/2016 < 0.5 0.25 27 11/16/2016 < 500 250 28 1217/2016 < 0.5 0.25 28 1217/2016 < 500 250 29 1/1112017 < 0.5 0.25 29 1/1112017 < 500 250 30 2/7/2017 < 0.5 0.25 30 2/712017 < 500 250 31 3/14/2017 < 0.5 0.25 31 3t14/2017 < 500 250 32 4/19/2017 < 0.5 0.25 32 4/19/2017 < 600 250 33 5/10/2017 < 0.5 0.25 33 5/10/2017 < 500 250 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 NC0088692 NC Protective 9595 GENERIC non -hardness RPA2016_63, data 2- 7/3112017 REASONABLE POTENTIAL ANALYSIS 5 Use 'PASTE SPECIAL 6 Use 'PASTE SPECIAL MTBE (Methyl Tertiary -butyl Ether) VaI"ES "0" "COPY- MTBE (Methyl Tertiary -butyl Ether) vaiues" then "COPY" . Maximum data . Maximum data Points = 58 Points a 58 Date Data BDL-112DL Results _ Date Data BDL=112DL Results 11, 1 12/512012 4.5 4.5 Std Day. 0.9565 1 12/5/2012 4.5 4.5 Std Dev. 0.9565 2 1/9/2013 1.2 1.2 Mean 0.7564 2 1/9/2013 1.2 1.2 Mean 0.7564 3 216/2013 2.5 2.5 C.V. 1.2645 3 2/612013 2.5 2.5 C.V. 1.2645 4 5/7/2014 < 0.5 0.25 n 36 4 5/7/2014 < 0.5 0.25 n 36 5 6/4/2014 < 0.5 0.25 5 61412014 < 0.5 0.25 6 7/7/2014 < 0.5 0.25 Mull Factor = 1.2600 6 717/2014 < 0.5 0.25 Mull Factor = 1.2600 7 8126/2014 < 0.5 0.25 Max. Value 4.5 ug/L 7 8/26/2014 < 0.5 0.25 Max. Value 4.5 pg/L 8 9/10/2014 < 0.5 0.25 Max. Pred Cw 5.7 Ng/L 8 9110/2014 < 0.5 0.25 Max. Pred Cw 5.7 Ng/L 9 1/14/2015 < 0.5 0.25 9 1114/2015 < 0.5 0.25 10 2/11/2015 < 0.5 0.25 10 2/11/2015 < 0.5 0.25 11 4/16/2015 < 0.5 0.25 11 4116/2015 < 0.5 0.25 12 5/412015 < 0.5 0.25 12 5/412015 < 0.5 0.25 13 6/24/2015 < 0.5 0.25 13 6/24/2015 < 0.5 0.25 14 7/13/2015 < 0.5 0.25 14 7/13/2015 < 0.5 0.25 15 8119/2015 < 0.5 0.25 15 8/19/2015 < 0.5 0.25 16 9/16/2015 0.64 0.64 16 9/16/2015 0.64 0.64 17 10/1412015 < 0.5 0.26 17 10/14/2015 < 0.5 0.25 18 11/23/2015 < 0.5 0.25 18 11/23I2015 < 0.5 0.25 19 12/1612015 < 0.5 0.25 19 12/16/2015 < 0.5 0.25 20 116/2016 < 0.5 0.25 20 1/6/2016 < 0.5 0.25 21 2110/2016 0.8 0.8 21 2/10/2016 0.8 0.8 22 3/22/2016 2.1 2.1 22 312212016 2.1 2.1 23 4/19/2016 < 0.5 0.25 23 4/19/2016 < 0.5 0.25 24 5/11/2016 < 0.5 0.25 24 5/11/2016 < 0.5 0.25 25 6/15/2016 0.94 0.94 25 6/15/2016 0.94 0.94 26 7/1312016 1.07 1.07 26 7/13/2016 1.07 1.07 27 8/1712016 < 0.5 0.25 27 8/17/2016 < 0.5 0.25 28 9/21/2016 0.72 0.72 28 9/21/2016 0.72 0.72 29 10/12/2016 < 0.5 0.25 29 10/12/2016 < 0.5 0.25 30 11/16/2016 < 0.5 0.25 30 11/16/2016 < 0.5 0.25 31 12/7/2016 < 0.5 0.25 31 12/712016 < 0.5 0.25 32 1111/2017 < 0.5 0.25 32 1/11/2017 < 0.5 0.25 33 2/7/2017 0.61 0.61 33 217/2017 0.61 0.61 34 3114/2017 1.5 1.5 34 3/14/2017 1.5 1.5 35 4/19/2017 3 3 35 4/19/2017 3 3 36 5/10/2017 1.9 1.9 36 5/10/2017 1.9 1.9 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 1 58 NCO088692 NC Protective 9595 GENERIC non -hardness; RPA2016_53, data -3- 7/31/2017 REASONABLE POTENTIAL ANALYSIS 7 8 U.-PASTE SPECIAL Use 'PASTE SPECIAL MTBE (Methyl Tertiary -butyl Ether) Values'men -COPY' Naphthalene YaluWMan'COPY' . Maximum data . Maximum data Points = 58 Paints = 58 Date Data BDL=112DL Results Date Data BDL=112DL Results 1 12/5/2012 4.5 4.5 Sid Dev. 0.9565 1 5I712014 < 2 1 Std Dev. 0.0000 2 1/9/2013 1.2 1.2 Mean 0,7564 2 6/4/2014 < 2 1 Mean 1,0000 3 2/6/2013 2.5 2.5 C.V. 1.2645 3 7/7/2014 < 2 1 C.V. 0.0000 4 5/7/2014 < 0.5 0.25 n 36 4 8/2612014 < 2 1 n 33 5 6/4/2014 < 0.5 0.25 5 9/1012014 < 2 1 6 7/7/2014 < 0.5 0.25 Mult Factor = 1.2600 6 1/14/2015 < 2 1 Mull Factor = 1.0000 7 8/26/2014 < 0.5 0.25 Max. Value 4.5 p9/L 7 2/11/2015 < 2 1 Max. Value 1.0 V9/L 8 9/10/2014 < 0.5 0.25 Max. Fred Cw 5.7 p9/L 8 4/16/2015 < 2 1 Max. Pred Cw O DETECTS Ng/L 9 1/14/2015 < 0.5 0.25 9 5/412015 < 2 1 10 2/11/2015 < 0.5 0.25 10 6/24/2015 < 2 1 it 4/1612015 < 0.5 0.25 11 7/13I2015 < 2 1 12 5/4/2015 < 0.5 0.25 12 811912015 < 2 1 13 6/24/2015 < 0.5 0.25 13 9/162015 < 2 1 14 7/13/2015 < 0.5 0.25 14 10/14/2015 < 2 1 15 8119/2015 < 0.5 0.25 15 11/23/2015 < 2 1 16 9/16/2015 0.64 0.64 16 12/16/2015 < 2 1 17 10/142015 < 0.5 0.25 17 1/612016 < 2 1 18 11/23/2015 < 0.5 0.25 18 2/10/2016 < 2 1 19 12/16/'2015 < 0.5 0.25 19 3/22/2016 < 2 1 20 1/6/2016 < 0.5 0.25 20 4/19/2016 < 2 1 21 2110/2016 0.8 0.8 21 5111/2016 < 2 1 22 3/222016 2.1 2.1 22 6/15/2016 < 2 1 23 4/192016 < 0.5 0.25 23 7/132016 < 2 1 24 5/112016 < 0.5 0.25 24 8/172016 < 2 1 25 6/1512016 0.94 0.94 25 9/21/2016 < 2 1 26 7/13/2016 1.07 1.07 26 10/12/2016 < 2 1 27 8/172016 < 0.5 0.25 27 11116/2016 < 2 1 28 91212016 0.72 0.72 28 12/72016 < 2 1 29 10/12/2016 < 0.5 0.25 29 1/112017 < 2 1 30 11/16/2016 < 0.5 0.25 30 2/7/2017 < 2 1 31 12/7/2016 < 0.5 0.25 31 3/142017 < 2 1 32 1/11/2017 < 0.5 0.25 32 4/19/2017 < 2 1 33 21712017 0.61 0.61 33 5/102017 < 2 1 34 3/142017 1.5 1.5 34 35 41192017 3 3 35 36 5/10/2017 1.9 1.9 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 NCO088692 NC Protective 9595 GENERIC non hardness RPA2016_53, data -4- 7/312017 REASONABLE POTENTIAL ANALYSIS 9 10 Use 'PASTE SPECIAL Use 'PASTE SPECIAL n-Propyi Benzene Values' then -COPY n-Propyi Benzene Values" then'COPY" . Maximum data . Mulmum data Palms = 58 points a 58 Date Data BOL=112DL Results Date Data 8DL=112DL Results _ 1 5/7/2014 < 0.5 0.25 Std Dev. 0.0000 1 5/7/2014 < 0.5 0.25 Std Dev. 0.00 2 6/412014 < 0.5 0.25 Mean 0.2500 2 6/412014 < 0.5 0.25 Mean 0.25 3 7/7/2014 < 0.5 0.25 C.V. 0.0000 3 7/7/2014 < 0.5 0.25 C.V. 0.0000 4 8126/2014 < 0.5 0.25 n 33 4 8126/2014 < 0.5 0.25 n 33 5 9/1012014 < 0.5 0.25 5 9/10/2014 < 0.5 0.25 6 1/14/2015 < 0.5 0.25 Mult Factor = 1.00 6 1114/2015 < 0.5 0.25 Mult Factor = 1.0000 7 2111Y2015 < 0.5 0.25 Max. Value 0.3 Ug/L 7 2/11/2015 < 0.5 0.25 Max. Value 0.3 pg/L 8 4/1612015 < 0.5 0.25 Max. Pred Cw O DETECTS Pg/L 8 4/16/2015 < 0.5 0.25 Max. Pred Cw O DETECTS pg/L 9 5/412015 < 0.5 0.25 9 5/4/2015 < 0.5 0.25 10 6/24/2015 < 0.5 0.25 10 6124/2015 < 0.5 0.25 11 7113/2015 < 0.5 0.25 11 7/13/2015 < 0.5 0.25 12 8/19/2015 < 0.5 0.25 12 8/19/2015 < 0.5 0.25 13 9/16/2015 < 0.5 0.25 13 911612015 < 0.5 0.25 14 1011412015 < 0.5 0.25 14 1011412015 < 0.5 0.25 15 11/2312015 < 0.5 0.25 15 1112312015 < 0.5 0.25 16 12/16/2015 < 0.5 0.25 16 12116/2015 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 18 2/1012016 < 0.5 0.25 18 2/10/2016 < 0.5 0.25 19 3/22/2016 < 0.5 0.25 19 3/22/2016 < 0.5 0.25 20 4/19/2016 < 0.5 0.25 20 4/19/2016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 22 6/1512016 < 0.5 0.25 22 6/15/2016 < 0.5 0.25 23 7/13/2016 < 0.5 0.25 23 7/13/2016 < 0.5 0.25 24 8/17/2016 < 0.5 0.25 24 8/17/2016 < 0.5 0.25 25 9/21/2016 < 0.5 0.25 25 9/21/2016 < 0.5 0.25 26 10/1212016 < 0.5 0.25 26 10/12/2016 < 0.5 0.25 27 11/16/2016 < 0.5 0.25 27 11/16/2016 < 0.5 0.25 28 12/7/2016 < 0.5 0.25 28 12/7/2016 < 0.5 0.25 29 1/11/2017 < 0.5 0.25 29 1/11/2017 < 0.5 0.25 30 2/7/2017 < 0.5 0.25 30 2/7/2017 < 0.5 0.25 31 3/14/2017 < 0.5 0.25 31 3/14/2017 < 0.5 0.25 32 4/19/2017 < 0.5 0.25 32 4/19/2017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 1 58 NCO088692 NC Protective 9595 GENERIC non hardness RPA2016_53, data -5- 7/31/2017 REASONABLE POTENTIAL ANALYSIS 11 12 Use 'PASTE SPECIAL U.'PASTE SPECIAL n-Propyl Benzene WOW then 'COPY•' 1,2,4•Trimeth (benzene y Values- then -COPY" . Maximum data .Maximum date points = 58 points - 58 Date Data BDL=1/2DL Results Date Data BDL=112DL Results 1 5/7/2014 < 0.5 0.25 Std Dev. 0.0000 1 5/7/2014 < 0.5 0.25 Sid Dev. 0.0000 2 6/4/2014 < 0.5 0.25 Mean 0.2500 2 6/4/2014 < 0.5 0.25 Mean 0.2500 3 7/7/2014 < 0.5 0.25 C.V. 0.0000 3 717/2014 < 0.5 0.25 C.V. 0.0000 4 8/26/2014 < 0.5 0.25 n 33 4 8/26/2014 < 0.5 0.25 n 33 5 9/10/2014 < 0.5 0.25 5 9/10/2014 < 0.5 0.25 6 1/1412015 < 0.5 0.25 Mult Factor = 1.0000 6 1/14/2015 < 0.5 0.25 Mult Factor = 1.0000 7 2/11/2015 < 0.5 0.25 Max. Value 0.3 yg/L 7 2/11/2015 < 0.5 0.25 Max. Value 0.3 Vg/L 8 4/16/2015 < 0.5 0.25 Max. Pred Cw O DETECTS yg/L 8 4/16/2016 < 0.5 0.25 Max. Pred Cw O DETECTS yg/L 9 5/4/2015 < 0.5 0.25 9 5/4/2015 < 0.5 0.25 10 6/24/2015 < 0.5 0.25 10 6/24/2015 < 0.5 0.25 11 7/13/2015 < 0.5 0.25 11 7/13/2015 < 0.5 0.25 12 8/19/2015 < 0.5 0.25 12 8/19/2015 < 0.5 0.25 13 9/16/2015 < 0.5 0.25 13 9/16/2015 < 0.5 0.25 14 10/14/2015 < 0.5 0.25 14 10/14/2015 < 0.5 0.25 15 11/23/2015 < 0.5 0.25 15 11/23/2015 < 0.5 0.25 16 12/16/2015 < 0.5 0.25 16 12/16/2015 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 18 2/10/2016 < 0.5 0.25 18 2/10/2016 < 0.5 0.25 19 3/22/2016 < 0.5 0.25 19 3/22/2016 < 0.5 0.25 20 4/19/2016 < 0.5 0.25 20 4/19/2016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 22 6/15/2016 < 0.5 0.25 22 6/15/2016 < 0.5 0.25 23 7/13/2016 < 0.5 0.25 23 7/13/2016 < 0.5 0.25 24 8/17/2016 < 0.5 0.25 24 8/17/2016 < 0.5 0.25 25 9/2112016 < 0.5 0.25 25 9/21/2016 < 0.5 0.25 26 10/12/2016 < 0.5 0.25 26 10/12/2016 < 0.5 0.25 27 11/16/2016 < 0.5 0.25 27 11/16/2016 < 0.5 0.25 28 12/7/2016 < 0.5 0.25 28 12/712016 < 0.5 0.25 29 1/11/2017 < 0.5 0.25 29 1/11/2017 < 0.5 0.25 30 2/7/2017 < 0.5 0.25 30 2/7/2017 < 0.5 0.25 31 3/14/2017 < 0.5 0.25 31 3/14/2017 < 0.5 0.25 32 4/19/2017 < 0.5 0.25 32 4/19/2017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 NCO088692 NC Protective 9595 GENERIC non hardness RPA2016_53, data -6- 7131/2017 REASONABLE POTENTIAL ANALYSIS 13 Use 'PASTE SPECIAL 14 Use 'PASTE SPECIAL 1,3,5-Trimeth (benzene values" then "COPY' 1,3,5-Trimeth Y (benzene values" then "COPY" Y . Maximum data . Maximum data points = 68 points = 58 Date Data BDL=112DL Results Date Data BDL=112DL Results 1 5/7/2014 < 0.5 0.25 Std Dev. 0.0000 1 5/712014 < 0.5 025 Std Dev. 0.0000 2 6/4/2014 < 0.5 0.25 Mean 0.2500 2 6/4/2014 < 0.5 0.25 Mean 0.2500 3 7/7/2014 < 0.5 0.25 C.V. 0.0000 3 7/7/2014 < 0.5 0.25 C.V. 0.0000 4 8/26/2014 < 0.5 0.25 It 33 4 8/26/2014 < 0.5 0.25 n 33 5 9/10/2014 < 0.5 0.25 5 9/1012014 < 0.5 0.25 6 1/14/2015 < 0.5 0.25 Mult Factor = 1.0000 6 1/14/2015 < 0.5 0.25 Mult Factor = 1.0000 7 2111/2015 < 0.5 0.25 Max. Value 0.3 4g/L 7 2111/2015 < 0.5 0.25 Max. Value 0.3 pg/L 8 4116/2015 < 0.5 0.25 Max. Pred Cw 0 DETECTS Vg/L 8 4116/2015 < 0.5 0.25 Max. Pred Cw O DETECTS pg/L 9 5/4/2015 < 0.5 0.25 9 5/4/2015 < 0.5 0.25 10 6/24/2015 < 0.5 0.25 10 6/24/2015 < 0.5 0.25 11 7/13/2015 < 0.5 0.25 11 7/13/2015 < 0.5 0.25 12 8/19/2015 < 0.5 0.25 12 8119/2015 < 0.5 0.25 13 9/16/2015 < 0.5 0.25 13 9/16/2015 < 0.5 0.25 14 10/14/2015 < 0.5 0.25 14 10IM2015 < 0.5 0.25 15 11/23/2015 < 0.5 0.25 15 11123/2015 < 0.5 0.25 16 12/16/2015 < 0.5 0.25 16 12/1612015 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 18 2/10/2016 < 0.5 0.25 18 2/10/2016 < 0.5 0.25 19 3/22/2016 < 0.5 0.25 19 3122/2016 < 0.5 0.25 20 4/19/2016 < 0.5 0.25 20 4/1912016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 22 6/15/2016 < 0.5 0.25 22 6/15/2016 < 0.5 0.25 23 7113/2016 < 0.5 0.25 23 7113/2016 < 0.5 0.25 24 8117/2016 < 0.5 0.25 24 8117/2016 < 0.5 0.25 25 9/21/2016 < 0.5 0.25 25 9/21/2016 < 0.5 0.25 26 10/12/2016 < 0.5 0.25 26 1OJ12/2016 < 0.5 0.25 27 1111612016 < 0.5 0.25 27 11/1612016 < 0.5 0.25 28 12012016 < 0.5 0.25 28 127/2016 < 0.5 0.25 29 1/11/2017 < 0.5 0.25 29 1/1112017 < 0.5 0.25 30 21712017 < 0.5 0.25 30 217/2017 < 0.5 0.25 31 3114/2017 < 0.5 0.25 31 3/14/2017 < 0.5 0.25 32 4119/2017 < 0.5 0.25 32 411912017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 NCO088692 NC Protective 9595 GENERIC non hardness RPA2016_53, data -7- 7/31/2017 REASONABLE POTENTIAL ANALYSIS 15 16 Use -PAST SPECULL Use'PASM SPECUIL 1,3,5-Trimethylbenzene values' then 'COPY' Xylenes, Mixture Yalues"thou"COPY" . Maximum data . Maximum data points = 58 points = 58 Date Data BDL=112DL Results Date Data BDL=112DL Results 1 5/712014 < 0.5 0.25 Std Dev. 0.0000 1 5/7/2014 < 1 0.5 Sid Dev. 0.0000 2 6/4/2014 < 0.5 0.25 Mean 0.2500 2 6/4/2014 < 1 0.5 Mean 0.5000 3 7/7/2014 < 0.5 0.25 C.V. 0.D000 3 7/7/2014 < 1 0.5 C.V. 0.0000 4 8/26/2014 < 0.5 0.25 n 33 4 8/2612014 < 1 0.5 n 33 5 9/10/2014 < 0.5 0.25 5 9/10/2014 < 1 0.5 6 1/14/2015 < 0.5 0.25 Mult Factor = 1.0000 6 1/14/2015 < 1 0.5 Mull Factor = 1.0000 7 2/1112015 < 0.5 0.25 Max. Value 0.3 yg/L 7 2/11/2015 < 1 0.5 Max. Value 0.5 Ug/L 8 4/16/2015 < 0.5 0.25 Max. Pred Cw O DETECTS yg/L 8 4/16/2015 < 1 0.5 Max. Fred Cw 0 DETECTS pg/L 9 5/4/2015 < 0.5 0.25 9 5/4/2015 < 1 0.5 10 6/24/2015 < 0.5 0.25 10 6/24/2015 < 1 0.5 11 7/13/2015 < 0.5 0.25 11 7113/2015 < 1 0.5 12 8/19/2015 < 0.5 0.25 12 8/192015 < 1 0.5 13 9/16/2015 < 0.5 0.25 13 9/16/2015 < 1 0.5 14 10/142015 < 0.5 0.25 14 10/14/2015 < 1 0.5 15 11232015 < 0.5 0.25 15 1123/2015 < 1 0.5 16 12/16/2015 < 0.5 0.25 16 1211612015 < 1 0.5 17 1/6/2016 < 0.5 0.25 17 116/2016 < 1 0.5 18 2/102016 < 0.5 0.25 18 2/10/2016 < 1 0.5 19 3/222016 < 0.5 0.25 19 W222016 < 1 0.5 20 4/19/2016 < 0.5 0.25 20 4/19/2016 < 1 0.5 21 5/11/2016 < 0.5 0.25 21 5/11/2016 < 1 0.5 22 6/152016 < 0.5 0.25 22 6/15/2016 < 1 0.5 23 7/132016 < 0.5 0.25 23 7/13/2016 < 1 0.5 24 6/172016 < 0.5 0.25 24 8/17/2016 < 1 0.5 25 9/21/2016 < 0.5 0.25 25 9/2112016 < 1 0.5 26 10/12/2016 < 0.5 0.25 26 10112/2016 < 1 0.5 27 11/16/2016 < 0.5 0.25 27 11/162016 < 1 0.5 28 1217/2016 < 0.5 0.25 28 12/7/2016 < 1 0.5 29 1/11/2017 < 0.6 0.25 29 1/11/2017 < 1 0.5 30 2/7/2017 < 0.5 0.25 30 2/7/2017 < 1 0.5 31 3/14/2017 < 0.5 0.25 31 3/14/2017 < 1 0.5 32 4/192017 < 0.5 0.25 32 4/19/2017 < 1 0.5 33 5/10/2017 < 0.5 0.25 33 5/10/2017 < 1 0.5 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 1 58 NCO088692 NC Protective 9595 GENERIC non -hardness RPA2016_53, data 8- 7/31/2017 REASONABLE POTENTIAL ANALYSIS 17 78 U.'PASTE SPECIAL U.'PASTE SPECIAL XyleneS,Mixture Values" then'COPY" Xylene9,Mixture Values"then"COPY" . Maximum data . Maximum tlata points = 58 points _ 58 Date Data DDL=112DL Results Date Data BDL=112DL Results 1 5/7/2014 < 1 0.5 Std Dev. 0.0000 1 5/7/2014 < 1 0.5 Std Dev. 0.0000 2 614/2014 < 1 0.5 Mean 0.5000 2 6/4/2014 < 1 0.5 Mean 0.5000 3 7/7/2014 < 1 0.5 C.V. 0.0000 3 7/7/2014 < 1 0.5 C.V. 0.0000 4 8/26/2014 < 1 0.5 n 33 4 8/262014 < 1 0.5 In 33 5 9/10/2014 < 1 0.5 5 9/10/2014 < 1 0.5 6 1114/2015 < 1 0.5 Mult Factor = 1.0000 6 1/14/2015 < 1 0.5 Mull Factor = 1.0000 7 2111/2015 < 1 0.5 Max. Value 0.5 pg/L 7 2JI112015 < 1 0.5 Max. Value 0.5 pg/L 8 4/16/2015 < 1 0.5 Max. Pred Cw O DETECTS pg/L 8 4/1612015 < 1 0.5 Max. Pred Cw O DETECTS pg/L 9 5/4/2015 < 1 0.5 9 5/4/2015 < 1 0.5 10 6/24/2015 < 1 0.5 10 6/24/2015 < 1 0.5 11 7/13/2015 < 1 0.5 11 7/13/2015 < 1 0.5 12 8/192015 < 1 0.5 12 8/1912015 < 1 0.5 13 9/16/2015 < 1 0.5 13 9/162015 < 1 0.5 14 10/14/2015 < 1 0.5 14 10/14/2015 < 1 0.5 15 11/23/2015 < 1 0.5 15 11/23/2015 < 1 0.5 16 121162015 < 1 0.5 16 12/1 6/2015 < 1 0.5 17 1/6/2016 < 1 0.5 17 1/6/2016 < 1 0.5 18 2110/2016 < 1 0.5 18 2/10/2016 < 1 0.5 19 3/222016 < 1 0.5 19 31222016 < 1 0.5 20 4/19/2016 < 1 0.5 20 4/192016 < 1 0.5 21 5/112016 < 1 0.5 21 5/11/2016 < 1 0.5 22 6/15/2016 < 1 0.5 22 6/15/2016 < 1 0.5 23 71132016 < 1 0.5 23 7/13/2016 < 1 0.5 24 8/172016 < 1 0.5 24 8/172016 < 1 0.5 25 9/21/2016 < 1 0.5 25 9/212016 < 1 0.5 26 10/1212016 < 1 0.5 26 10/12/2016 < 1 0.5 27 11/16/2016 < 1 0.5 27 11116/2016 < 1 0.5 28 12f7/2016 < 1 0.5 28 12/72016 < 1 0.5 29 1/112017 < 1 0.5 29 1/11/2017 < 1 0.5 30 2/7/2017 < 1 0.5 30 2/7/2017 < 1 0.5 31 3/142017 < 1 0.5 31 3/142017 < 1 0.5 32 4/192017 < 1 0.5 32 4/19/2017 < 1 0.5 33 5110/2017 < 1 0.5 33 6/10/2017 < 1 0.5 34 34 35 35 36 36 37 37 3B 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 1 58 NCO088692 NC Protective 9595 GENERIC non hardness RPA2016_53, data -9- 7/312017 Sparks Oil Co./JW Smith/Camp SpringsR6AINIIIIIABLE POTENTIAL ANALYSIS NCO088692 2016 Generic RPA (non -hardness dependent) - 95% Probability/95% Confidence MAXIMUM DATA POINTS m 58 Qw(MGD)= 0.00900 WWTP/WTP Class: PC-1 IQIOS (cfs)= 0.00 [WC @ 1QIOS = 100.0% 7QIOS(ch)= 0.00 IWC @7Q10S= 100.0% 7QIOW(cfs)= 0.00 IWC@7QIOW= 100.0% 30Q2 (cfs) = 0.00 1WC @ 31= 100.0% Avg. Stream Flow, QA (cfs) = 0.00 IWC @ QA = 100.0% Receiving Stream: UT to Country Line Creek Stream Class: WS-II;HQW Outfall 001 Qw = 0.009 MGD YOU HAVE DESIGNATED THIS RECEIVING STREAM AS HOW OR ORW PARAMETER TYPE STANDARDS & CRITERIA (2) 9 REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION [1 p Dec Max Pred Cw Allowable Cw (1) NC WQS / Applied '/2 FAV / Z Chronic Standard Acute Acute: NO WQS Ethylene Dibromide C 0.01 WS µi 33 0 NO DETECTS Chronic: 0.01 No detects- POC Maintain Monitoring Max MDL = 0.5 Acute: NO WQS Ethylene Dibromide C 0A5 HH µg/L 33 0 NO DETECTS ___ _ _ _ _ __ Chronic: 0.05 _____ _ _____ _____ _ _ _ No detects -POC Maintain Monitoring Max MDL = 0.5 Acute: NO WQS Ethymenzene NCIS� WS µg/L 33 0 NO DETECTS ___ _ _ __ Chronic: 48.50 _________________________ No detects -POC Maintain Monitoring Max MDL = 0.5 Acute: NO WQS Isopropyl Ether NC 10000 FW µg/L 33 0 NO DETECTS___ _ ___ _ _ Chronic: to'000.00 __________________________ No detects- POC Maintain Monitoring Max MDL = 500 Acute: NO WQS MTBE (Methyl Tertiary -butyl Ether) C 11,5 WS pg(L 36 13 5.7 Chronic: 9.50 _ No RP, Predicted Max a 50%of Allowable Cw - POD No value> Allowable Cw Maintain Monitoring Acute: NO WQS MTBE(Methyl Tertiary -butyl Ether) C 17000 1'\\' pg/L 36 13 57 ___ _ _ _ Chronic: 17,000.00 _ _ _ _ _ _ NO RP, Predicted Max<50%ofAllowbaleCw- No value> Allowable Cw POC Maintain Monitoring Acute: NO WQS MTBE(Methyl Tertiary -butyl Ether) C 7iO HH pg/L 36 13 5.7 Chronic: 750.00 No RP, Predicted Max <50%ofAllowbaleCw- No value> Allowable Cw POC Maintain Monitoring Acute: NO WQS Naphthalene NC 6 f\\ pg/L 33 0 NO DETECTS ___ _ Chronic: 6.00 No detects-POC Maintain Monitoring Max MDL = 2 Acute: NO WQS n-Propyl Benzene NC 150 \\'s pg/L 33 0 NO DETECTS _ Chronic: 750.00 No RP, Pretlicletl Maz z 50% 01 Allowable Cw- POC Max MDL 0.5 Maintain Monitoring Acute: NO WQS n-Propyl Benzene NC 10 f\\ pg/L 33 0 NO DETECTS ___ _ Chronic: 40.00 No RP, Predicted Max < 50 % of Alluwbale Cw - Max MDL= 0.5 POC Maintain Monitoring NC0088692 NC Protective 9595 GENERIC non —hardness RPA2010_53, rya Page 1 of 2 71312017 Sparks Oil Co./JW Smith/Camp SpringsR6AU®IIIABLE POTENTIAL ANALYSIS NCO088692 2016 Generic RPA (non -hardness dependent) - 95% Probability/95% Confidence Outfall 001 Qw = 0.009 MGD Acute: NO WQS n-Propyl Benzene NC 1350 HH µg/L 33 0 NO DETECTS _ _ ____ _ _-_-_-_-_-_-_-_- Chronic: I'350.00 No detects- POC Maintain Monitoring Max MDL=0.5 Acute: NO WQS 1,2,4-Trimethylbenzene NC 195 FW µg/L 33 0 NO DETECTS _ ___ _ _ _ _ _ __ Chronic: 195.00 _ _ _ _ _ _-_ _-_ No detects- POC Maintain Monitoring Max MDL=0.5 Acute: NO WQS 1,3,5.Trimethylbenzene NC 65 WS µg/L 33 0 NO DETECTS __ _ _ _ _ _ _ _ _ _ _ Chronic: 65.00 No detects- POC Maintain Monaonng Max MDL = 0.5 Acute: NO WQS 1,3,5-Trimethylbenzene NC 315 I\\ Pg/L 33 0 NO DETECTS _-_-_-_-_-_-_-_-_-_-_-_-_ ___ _ _ _ __ Cbronic: 315.00 No detects- POC Maintain Monitoring Max MDL=0.5 Acute: NO WQS 1,3,5-Trimethylbenzene NC 107.5 HH µg/L 33 0 NO DETECTS _ _ _-_ _-_-_ _ _-_-_-_-__ - ___ _ _ _ __ Cbronic: 107.50 No detects- POC Maintain Monitoring Max MDL=0.5 Acute: NO WQS Xylenes, Mixture NC :Inn WS µg/L 33 0 NO DETECTS __Ch_ _ _ _ _ _ roaic: 3,100.00 _-_-_-_-_-_-_-_-_-_-_-_-_ No detects- POC Maintain Monitoring Max MDL= I Acute: NO WQS Xylenes, Mixture NC 335 FW µg/L 33 0 NO DETECTS ___ _ _ _ __ Chronic: 335.00 _-_-_-_-_-_-_-_-_-_-_-_-_ No detects- POC Maintain Monitoring Max MDL= 1 Acute: NO WQS Xylenes, Mixture NC 28500 HH µg/L 33 0 NO DETECTS ___ _ _28,500.00 _ _ -------------------------- Chronic: No detects- POC Maintain Monitoring Max MDL= 1 NCO088692 NC Protective 9595 GENERIC non hardness RPA2016_53, rpa Page 2 of 2 7/31/2017 EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Healdi Below are all Nationally Recommended Water Quality Criteria for which NC does not have a Water Quality Standard for one or more uses Freshwater Fresh &Salt Saltwater Class INS pass C Class C&SC Gass SC 0-h Water e s Human Health" a Cancer Most Recent Is therean Is therean Supply Aquatic Life (HH) Aquatic Llfe Synonyms & Other EPA Cdtedon NCAgwtic NC HH w Is the EPA Criterion being reviewed for Pollutant Or Parameter (ASg (wsl Endpoint Information PubllaHon Life WS adoption as NC Standard? (HH& Ws) Year Standard? Standard? All values reported as ug/Lunless labeled otherwise. 1,2-Dichloroethane 107-06-2 9.9 650 Yes 2015 No No Reviewing 2015 Criterion for HH& WS Ethylbenzene 100-41-4 68 130 2015 No No Reviewing 2015 criterion for HH&WS See NC See NC Standard Standard Phenol 108-95-2 4000 for Total 300000 for Total 2015 Yes No Reviews ng 2015 crite0 on for HH&WS Phenolic Phenolic Compounds Compounds Toluene IM88-3 57 See NC 520 2015 Yes, for No Revi ewi ng 2015 Criterion for HH&WS Standard Freshwat see NC l standard for YeWS r Td rhlorobobenzene 120-82-1 Chlorinated 0.076 2015 No Reviewing 2015 Criterion for HH&WS Benzenes The Nationally Recommended Water Quality Criteria values presented in this table are based on the values reported on EPA's Nationally Recommended Water Quality Criteria website as of 7/22/2016. Seethe Supporting Info tab for information on all footnotes, notes, and abbreviations 2016 Generic RPA (non -hardness dependent) - 95% Probability/95% Confidence MAXIMUM DATA POINTS = 58 REQUIRED DATA ENTRY Table 1. Project Information ❑+ CHECK IF HQW OR ORW Facility Name W WTPJWTP Class NPDES Permit Outfall Flow, Qw (MGD) Receiving Stream Stream Class 7010s (cfs) 7Q10w (cfs) 30Q2 (cfs) CIA (cfs) 1 Q105 (cfs) Data Source(s) _ ❑CHECK TO APPLY MODEL Sparks Oil Co./JW Smith/Camp Springs 76 GWR PC-1 NCO088692 001 0.00900 UT to Country Line Creek WS-II;HQW 0.00 0.00 0.00 0.00 0.00 - BIMS DMRs Dec2012 to May2017 RPA for EPA Nationally Recommended Water Quality Criteria for which NO does not have a Water Quality Standard for one or more uses. Follow directions for data entry. In some cases a comment menu list the available choices or a dropdown menu will provide a list you may select from. Error message occur if data entry does not meet input criteria. Perot Par02 Par03 Par04 0 PM05 Par06 PW07 Peres Par09 Par10 Party Par12 Par13 Par14 Par15 Par16 Parl7 Par18 Por19 Par20 Par21 Par22 Table 2. Parameters of Concern Name Type Chronic mmifier Acute PQL Units Ethylbenzene Ethylbenzene NCO088692 EPA NRWQC 9595 GENERIC non —hardness RPA2016_53, input 7/31/2017 REASONABLE POTENTIAL ANALYSIS 1 2 U.'PAS TESPECIAL Use 'PASTE SPECIAL 1,2•Dichloroethane Values" then "COPY" 1,2.Dichloroethane Values"Man"COPY' . Mulmum tlata . Maximum tlata points = 58 points = 58 Date Data BDL=1/2DL Results Date Data BDL=112DL Results 1 5/7/2014 < 0.19 0.095 Std Dev. 0.0701 1 5/712014 < 0.19 0.095 Std Oev. 0.0701 2 6/4/2014 < 0.19 0.095 Mean 0.2077 2 6/412014 < 0.19 0.095 Mean 0.2077 3 717/2014 < 0.19 0.095 C.V. 0.3375 3 7/7/2014 < 0.19 0.095 C.V. 0.3375 4 8/26/2014 < 0.19 0.095 In 33 4 8/26/2014 < 0.19 0,095 n 33 5 9/1012014 < 0.19 0.095 5 9110/2014 < 0.19 0.095 6 1/14/2015 < 0.19 0.095 Mult Factor= 1.1000 6 1/14/2015 < 0.19 0.095 Mult Factor = 1.1000 7 2/11/2015 < 0.19 0.095 Max. Value 0.3 pg/L 7 2/11/2015 < 0.19 0.095 Max. Value 0.3 pg/L 8 411612015 < 0.19 0.095 Max. Fred Cw O DETECTS yg/L 8 4116/2015 < 0.19 0.095 Max. Fred Cw O DETECTS pg/L 9 514/2015 < 0.19 0.095 9 5/412015 < 0.19 0.095 10 6/24/2015 < 0.5 0.25 10 6/24/2015 < 0.5 0.25 11 7/13/2015 < 0.5 0.25 11 7113/2015 < 0.5 0.25 12 8/19/2015 < 0.5 0.25 12 8/19/2015 < 0.5 0.25 13 9/16/2015 < 0.5 0.25 13 9116/2015 < 0.5 0.25 14 10/1412015 < 0.5 0.25 14 10/14/2015 < 0.5 0.25 15 11/23/2015 < 0.5 0.25 15 11/23/2015 < 0.5 0.25 16 12/16/2015 < 0.5 0.25 16 121IM015 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 18 2/10/2016 < 0.5 0.25 18 2/10/2016 < 0.5 0.25 19 3/22/2016 < 0.5 025 19 3122/2016 < 0.5 0.25 20 4/19/2016 < 0.5 0.25 20 4119/2016 < 0.5 0.25 21 5/1112016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 22 6/15/2016 < 0.5 0.25 22 6115/2016 < 0.5 0.25 23 7/13/2016 < 0.5 0.25 23 7113/2016 < 0.5 0.25 24 8/17/2016 < 0.5 0.25 24 8/17/2016 < 0.5 0.25 25 9121/2016 < 0.5 0.25 25 9/21/2016 < 0.5 0.25 26 10/12/2016 < 0.5 0.25 26 10/12/2016 < 0.5 0.25 27 11/16/2016 < 0.5 0.25 27 11/16/2016 < 0.5 0.25 28 12/7/2016 < 0.5 0.25 28 12/7/2016 < 0.5 0.25 29 1/1112017 < 0.5 0.25 29 1/11/2017 < 0.5 0.25 30 2/7/2017 < 0.5 0.25 30 2/7/2017 < 0.5 0.25 31 3/14/2017 < 0.5 0.25 31 3/14/2017 < 0.5 0.25 32 4/1912017 < 0.5 0.25 32 4/19/2017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 58 NCO088692 EPA NRWQC 9595 GENERIC non -hardness RPA2016_53, data - 1 - 7131/2017 REASONABLE POTENTIAL ANALYSIS a a 1 Use 'PASTE SPECIAL Uae'PASTE SPECIAL Ethylbenzene Values" Men "core Ethylbenzene �alues"1hum"COPY . Maximum data . Maiimum data points = 58 Points = 58 Date Data BDL=112DL Results Date Data BDL=112DL Results 1 517/2014 < 0.5 0.25 Still Dev. 0.0000 1 517/2014 < 0.5 0.25 Std Dev. 0.0000 2 6/4/2014 < 0.5 0.25 Mean 0.2500 2 6/4/2014 < 0.5 0.25 Mean 0.2500 3 7/7/2014 < 0.5 0.25 C.V. O.000O 3 7/7/2014 < 0.5 0.25 C.V. 0.0000 4 8/26/2014 < 0.5 0.25 n 33 4 8/26/2014 < 0.5 0.25 n 33 5 9/10/2014 < 0.5 0.25 5 9/10/2014 < 0.5 0.25 6 1/1412015 < 0.5 0.25 Mult Factor = 1.0000 6 1/14/2015 < 0.5 0.25 Mult Factor = 1.0000 7 2111/2015 < 0.5 0.25 Max. Value 0.3 pg/L 7 2111/2015 < 0.5 0.25 Max. Value 0.3 pg/L 8 4/16/2015 < 0.5 0.25 Max. Pred Cw O DETECTS Ug/L 8 4116/2015 < 0.5 0.25 Max. Fred Cw O DETECTS pg/L 9 5/`412015 < 0.5 0.25 9 5/4/2015 < 0.5 0.25 10 6/24/2015 < 0.5 0.25 10 6/24/2015 < 0.5 0.25 11 7/13/2015 < 0.5 0.25 11 7/13/2015 < 0.5 0.25 12 8/19/2015 < 0.5 0.25 12 8/19/2015 < 0.5 0.25 13 9/16/2015 < 0.5 0.25 13 9/16/2015 < 0.5 0.25 14 10/14/2015 < 0.5 0.25 14 10/14/2015 < 0.5 0.25 15 11/23/2015 < 0.5 0.25 15 11/23/2015 < 0.5 0.25 16 12/1612015 < 0.5 0.25 16 12/16/2015 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 18 2/10/2016 < 0.5 0.25 18 2/10/2016 < 0.5 0.25 19 3/22/2016 < 0.5 0.25 19 3/22/2016 < 0.5 0.25 20 4/19/2016 < 0.5 0.25 20 4/19/2016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 22 6/15/2016 < 0.5 0.25 22 6115/2016 < 0.5 0.25 23 7/13/2016 < 0.5 0.25 23 7/13/2016 < 0.5 0.25 24 8/17/2016 < 0.5 0.25 24 8/17/2016 < 0.5 0.25 25 9/21/2016 < 0.5 0.25 25 9/21/2016 < 0.5 0.25 26 10/12/2016 < 0.5 0.25 26 10/12/2016 < 0.5 0.25 27 11116/2016 < 0.5 0.25 27 11/16/2016 < 0.5 0.25 28 12/7/2016 < 0.5 0.25 28 12/7/2016 < 0.5 0.25 29 1/11/2017 < 0.5 0.25 29 1/11/2017 < 0.5 0.25 30 2/7/2017 < 0.5 0.25 30 2/7/2017 < 0.5 0.25 31 3/14/2017 < 0.5 0.25 31 3114/2017 < 0.5 0.25 32 4/19/2017 < 0.5 0.25 32 4/19/2017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 34 34 35 35 36 36 37 37 38 38 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 1 58 NCO088692 EPA NRWOC 9595 GENERIC non hardness RPA2016_53, data -2- 7/3112017 REASONABLE POTENTIAL ANALYSIS 6 6 U.'PAM SPECIAL U.'PAInE SPECIAL Toluene values^ then ^COPY' Toluene Values" men"COPY" . Maximum data . Mazlmum data points = 58 polnts = 58 Date Data BDL=112DL Results Date Data BDL=112DL Results 1 5/7/2014 < 0.5 0.25 Std Dev. 0.0000 1 5/712014 < 0.5 0.25 Sld Dev. 0,0000 2 6/4/2014 < 0.5 0.25 Mean 0.2500 2 6/4/2014 < 0.5 0.25 Mean 0.2500 3 7/7/2014 < 0.5 0.25 C.V. 0.0000 3 7/712014 < 0.5 0.25 C.V. 0.0000 4 8/2612014 < 0.5 0.25 n 33 4 8126/2014 < 0.5 0.25 n 33 5 9/10/2014 < 0.5 0.25 5 9/10/2014 < 0.5 0.25 6 11142015 < 0.5 0.25 Mult Factor = 1.0000 6 1/14/2015 < 0.5 0.25 Mult Factor = 1.0000 7 21112015 < 0.5 0.25 Max. Value 0.3 yg/L 7 2/1112015 < 0.5 0.25 Max. Value 0.3 pg/L 6 4/16/2015 < 0.5 0.25 Max. Prod Cw O DETECTS V9/L 8 4116/2015 < 0.5 0.25 Max. Pred Cw O DETECTS pg/L 9 514/2015 < 0.5 0.25 9 5/4/2015 < 0.5 0.25 10 6/242015 < 0.5 0.25 10 6/242015 < 0.5 0.25 11 7/13/2015 < 0.5 0.25 11 7/13/2015 < 0.5 0.25 12 81192015 < 0.5 0.25 12 8/192015 < 0.5 0.25 13 91IM015 < 0.5 0.25 13 9/16/2015 < 0.5 0.25 14 10/14/2015 < 0.5 0.25 14 10/1412015 < 0.5 0.25 15 1123/2015 < 0.5 0.25 15 1123/2015 < 0.5 0.25 16 12/16/2015 < 0.5 0.25 16 12116/2015 < 0.5 0.25 17 116/2016 < 0.5 0.25 17 1/6/2016 < 0.5 0.25 18 2/102016 < 0.5 0.25 18 2/10/2016 < 0.5 0.25 19 3/222016 < 0.5 0.25 19 3/22/2016 < 0.5 0.25 20 411912016 < 0.5 0.25 20 4/192016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 21 5/11/2016 < 0.5 0.25 22 6/152016 < 0.5 0.25 22 6/15/2016 < 0.5 0.25 23 7113/2016 < 0.5 0.25 23 7/132016 < 0.5 0.25 24 8/172016 < 0.5 0.25 24 8/172016 < 0.5 0.25 25 9/212016 < 0.5 0.25 25 91212016 < 0.5 0.25 26 10/12/2016 < 0.5 0.25 26 10/1212016 < 0.5 0.25 27 11/16/2016 < 0.5 0.25 27 11/16/2016 < 0.5 0.25 28 12I72016 < 0.5 0.25 28 12/72016 < 0.5 0.25 29 1/112017 < 0.5 0.25 29 V1112017 < 0.5 0.25 30 2/7/2017 < 0.5 0.25 30 2/7/2017 < 0.5 0.25 31 31142017 < 0.5 0.25 31 3/142017 < 0.5 0.25 32 4/19/2017 < 0.5 0.25 32 4/19/2017 < 0.5 0.25 33 5/102017 < 0.5 0.25 33 5/10/2017 < 0.5 0.25 34 34 35 35 36 36 37 37 38 3B 39 39 40 40 41 41 42 42 43 43 44 44 45 45 46 46 47 47 48 48 49 49 50 50 51 51 52 52 53 53 54 54 55 55 56 56 57 57 58 1 58 NC0088692 EPA NRWOC 9595 GENERIC non hardness RPA2016_53, data -3- 7/31/2017 Sparks Oil Co./JW Smith/Camp Springs i E159I NABLE POTENTIAL ANALYSIS NCO088692 2016 Generic RPA (non -hardness dependent) - 95% Probability/95% Confidence MAXIMUM DATA POINTS = 58 Qw (MGD) = 0.00900 W WTP/WTP Class: PC-1 IQ10S lets)= 0.00 lWC @1QIOS = 100.0% 7Q10S(cfs)= 0.00 IWC @7QIOS= 100.0% 7QIOW(cfs)= 0.00 IWC@7Q10W= 100.0% 30Q2 (cfs) = 0.00 IWC @ 30Q2 = 100.0% Avg. Stream Flow, QA (cfs) = 0.00 IWC @ QA = 100.0% Receiving Stream: UT to Country Line Creek Stream Class: WS-II;HQW Outfall 001 Qw = 0.009 MGD YOU HAVE DESIGNATED THIS RECEIVING STREAM AS HOW OR ORW PARAMETER STANDARDS B CRITERIA(2) m REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE (1) NC WQS / Applied '/x FAV / J ii z n # Det. Max Pred Cw Allowable Cw Chronic Standard Acute Acute: NO WQS 1,2.Dichloroethane C 4.95 WS pg/L 33 0 NO DETECTS Chro 4.95 No detects- POC Maintain Monitoring Max MDLL = 0.5 Acute: NO WQS 1,2-Dichloroethane C 325 Ills pg/L 33 0 NO DETECTS _ _ ___-_ _ _ Chmnle: 325.00 _ _ _ _ _ _ _ _ _ _ _ _ _ No detects- POC Maintain Monitoring Max MDL = 0.5 Acute: NO WQS Ethylbenzene NC i4 WS pg/L 33 0 NO DETECTS __ _ __ _____ ___________________ Chronic: 3--04.0 No detects- POC Maintain Monitoring Max MDL = 0.5 Acute: NO WQS Elhylbenzene NC a5 HH µg/L 33 0 NO DETECTS Chronic: 65.00 No detects- POC Maintain Monitoring = Max MDL 0.5 Acute: NO WQS Toluene NC 28.5 WS µp/L 33 0 NO DETECTS _ _______ ___ Chronic: 28.50 _ _ _ _ _ _ _ _ _ ________ No detects- POC Maintain Monitoring Max MDL = 0.5 Acute: NO WQS t oluenc NC 360 Ii li pg/L 33 0 NO DETECTS _ _ _ Chronic: 260.00 No detects- POC Maintain MonBoring Max MDL = 0.5 NCO088692 EPA NRWQC 9595 GENERIC non —hardness RPA2018 53, rpe Page 1 of 1 7/331/2017 Supporting Information Notes & Descriptors Calc = hardness -dependent metal standards are calculated based on in -stream hardness (d) = dissolved metal standard. See 15A NCAC 02B .0211 for more information. (E) = effluent limit for High Quality Waters. See 15A NCAC 02B .0224. (h) = hardness -dependent dissolved metal standard. See below for hardness -dependent dissolved metal equations. See 15A NCAC 026.0211 for more Information. (HH) = Human Health (LD) = limited data. (N) = narrative standard. (P) = public policy document. (s) = toxicity exceeds solubility, no visible sheen or free product in water or on sediment or shoreline per 15A NCAC 02B .0211 & .0220 (t) = based upon measurement of total recoverable metal. See 15A NCAC 02B .0212 for more information. WER = Water Effects Ratio. See 15A NCAC 028.0211 for more information. (WS) = Water Supply. Designated Use Definitions (1) Aquatic We standards protect both fresh and saltwater aquatic organisms to promote biological integrity. See 15A NCAC 028.0211 and .0220. (2) Trout Waters are protected for natural trout propagation and survival of stocked trout. See 15A NCAC 026.0101 and .0301. (3) Human Health standards are based on fish consumption only unless dermal contact studies are available. See 15A NCAC 028.0208. (4) Secondary Recreation standards apply to activities in surface waters that result In Incidental body contact. See 15A NCAC 02B .0211 and .0220. (5) Swamp Waters have low velocities and other natural characteristics which are different from adjacent streams. See 1SA NCAC 02B .0101. (6) Water Supply standards are applicable to all Water Supply Classifications (WS I-V) and are based on consumption of fish and water. See i5A NCAC 028.0208, .0212, .0214, .0215, .0216, and .0218. (7) High Quality Waters area subset of waters with quality higher than the standards and are described In 15A NCAC 02B .0101 and .0224. (8) Primary Recreation standards apply to activities in surface waters that result in full -body contact. See 15A NCAC 02B .0219 and .0222. (9) Shellfish Area standards apply to surface waters that are used for shellfishing for market purposes. See 15A NCAC 02B .0221. (10) Carcinogens are listed in 15A NCAC 026.0208 and relate to Human Health (HH) and Water Supply (WS) standards. All standards in this table that are designated as carcinogens were calculated from oral cancer slope values obtained through EPXs Integrated Risk Information System (IRIS). (11) Acute & chronic values for all metals on the NC 02B Standards table are based on the following language in iSA NCAC 028.0211: Acute = "Compliance with acute instream metals standards shall only be evaluated using an average of two or more samples collected with one hour." Chronic = "Compliance with chronic instreom metals standards shall only be evaluated using averages of a minimum of foursamples taken on consecutive days, or as a 96-hour average" Reference Sources = Code of Federal Regulations - Title 40 EPA AW C = Enviromental Protection Agency Ambient Water Quality Criteria EPA QCW = Enviromental Protection Agency Quality Criteria for Water EPA NRWQC = Environmental Protection Agency Nationally Recommended Water Quality Criteria. (HH) denotes the Human Health Water Quality Criteria and (AL) denotes the Aquatic Life Water Quality Criteria. ECOTOX = The ECOTOXicology knowledgebase. FDA NSSP = US Food & Drug Administration National Shellfish Sanitation Program. GEI-CED = GEI Consultants -Chadwick Ecological Division. Reviewed EPA 2001 Update of Ambient Water Quality Criteria for Cadmium. IRIS = Integrated Risk Information System. NPDWR = National Primary Drinking Water Regulations (EPA) NSDWR = National Secondary Drinking Water Regulations (EPA) RAIS = The Risk Assessment Information System _ Water Resources Environmental Quality August 9, 2017 UT u_ I : V01-1 1ul To: Jeff Bryan Assistant Regional Engineer (DWR/PWSS) Winston-Salem Regional Office From: Derek C. Denard DWR / NPDES Program 919-807-6307; Fax 919-807-6495; derek.denard@ncdenr.gov Subject: Review of Discharge to Surface Waters Designated Water Supply (WS) UT to Country Line Creek [22-(25.5)], WS-II;HQW Subbasin 03-02-04 [HUC 030101040202], Roanoke River Basin for: Permit Renewal NPDES NCO088692 Sparks Oil Company—J.W. Smith/Camp Springs 76 (GW-REM) 8920 Cherry Grove Road, Reidsville 27320 Caswell County Please provide your comments by September 8, 2017 [email OK] ROY COOPER Governor MICHAEL S. REGAN Secretary S. JAY ZIMMERMAN Director RESPONSE: I concur with the issuance of this permit provided the Permittee properly operates and maintains the facility; the Permittee meets the stated effluent limits prior to discharge; and the discharge does not contravene the designated water quality standards. I concur with issuance of the above permit provided the following conditions are met: I oppose the issuance of the above permit based on reasons stated below, or attached: Signed: Date: cc: file State of North Carolina I Environmental Quality 1617 Mail Service Center I Raleigh, North Carolina 27699-1617 919-707-90DO (N MO C_�7 e4_f- Denard, Derek From: Smith, George Sent: Friday, August 25, 2017 9:32 AM To: Denard, Derek Subject: RE: Draft NPDES Permit NCO088692 - Sparks Oil Company - J.W. Smith/Camp Springs 76 (GW-REM) - PC-1 Derek, Recommend the Classification of PC-1 be added to the permit cover letter. Recommend the permit be issued. George Smith, Assistant Regional Supervisor email: georae.smith@ncdenr.gov Division of Water Resources 450 West Hanes Mill Road, Suite 300 Winston-Salem, NC 27105 Direct phone: (336) 776-9700 E-mail correspondence to and from this address may be subject to the North Carolina Public Records Law and may be disclosed to third parties. From: Denard, Derek Sent: Wednesday, August 16, 2017 1:58 PM To: jerry@sparksoil.com Cc: Smith, George <george.smith@ncdenr.gov>; Meadows, Susan <susan.meadows@ncdenr.gov>; Moore, Cindy <cindy.a.moore@ncdenr.gov>; Kinney, Maureen <Maureen.Kinney@ncdenr.gov> Subject: Draft NPDES Permit NCO088692 - Sparks Oil Company - J.W. Smith/Camp Springs 76 (GW-REM) - PC-1 Dear Mr. Sparks: In response to your request to renew the subject NPDES permit, the Division of Water Resources (DWR or the Division) hereby transmits this draft for your review and comment. Please review this document to assure your understanding of the permit limits and monitoring conditions, and to correct errors, if any. http•//edocs dep nc gov/WaterResources/0/doc/556374/Pagel aspx?searchid=d84bd65c-1ad6-4ebb-9825- 77f24bb3c14b We have made the following updates to your previous permit: 1. The facility map has been updated. The location of Outfall 001 is corrected to the following: Latitude: 362 17' 46" (36.296111) Longitude -792 29' 31" (-79.491944) 2. Regulatory citations have been added. 3. Quarterly Total Hardness monitoring has been added for the effluent. Please see discussion below for more information. Effluent hardness sampling should be performed in conjunction with sampling for hardness dependent metals (Lead). Please note that since the outfall location is under zero flow conditions, no instream hardness sampling will be required. 4. For all parameters with limits both monthly average limits and daily maximum limits have been applied. The US EPA requires both a Monthly Average and a Daily Maximum for parameters that are limited [40 CFR 122.45 (d.)]. 5. The limits for Isopropyl Ether (µg/L),1,2-Dichloroethane (µg/L) and Naphthalene (µg/L) has been updated to 10 mg/L, 5 µg/L and 6 µg/L, respectively. 6. Monitoring of Phenol has been changed to Total Recoverable Phenolics (parameter code 32730). 7. Electronic reporting of discharge monitoring reports (eDMR) has been added in Section A. (2.). The NC 2007-2014 Water Quality Standard (WQS) Triennial Review was approved by the NC Environmental Management Committee (EMC) on November 13, 2014. The US EPA subsequently approved the WQS revisions on April 6, 2016 with some exceptions. The NC Division of Water Resources NPDES Permitting Unit is required to implement the new dissolved metal standards in all permits public noticed after April 6, 2016. The new standards for most metals include acute standards. The freshwater standards for several metals are expressed as the dissolved form of the metals, and seven metals have hardness -dependent equations. As a result, the NPDES Permitting Unit will need site -specific effluent hardness data and instream hardness data, upstream of the discharge, for each facility monitoring these metals in order to calculate permit limitations. Effluent hardness and instream hardness sampling, upstream of the discharge, has been added to this permit at a monitoring frequency of quarterly. See Section A. (1.) Effluent Limitations and Monitoring Requirements. Concurrent with this notification, the Division will solicit public comment on this draft by publishing a notice in newspapers having circulation in the general Caswell County area, as required by the NPDES Program. Please provide your comments, if any, to me via email [derek.denard@ncdenr.gov] or write to my attention care of DEQ/ DWR / NPDES Program no later than September 8, 2017. Your written comments are welcome but not mandatory. Following the mandatory 30-day public comment period, the Division will review all pertinent comments on your permit draft, and take appropriate action prior to issuing your final NPDES permit. If you have questions concerning this draft, please e-mail me or call my direct line (919) 807-6307. Sincerely, Derek Denard Environmental Specialist N.C. Division of Water Resources N.C. Department of Environmental Quality 919 807 6307 office derek.denard (a)ncdenr. aov 1617 Mail Service Center Raleigh, NC 27699-1617 Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. PYRAM I D ENVIRONMENTAL & ENGINEERING, P.C. November 14, 2016 Mrs. Dina Sprinkle NCDEQ / DWQ / Point Source Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Re: NPDES Permit Renewal Request for JW Smith / Camp Springs 76 Groundwater Remediation System 8920 Cherry Grove Road Reidsville, Caswell County, NC NPDESPermit# NCO088692 RECEIVEDfNCDEQlDWR Incident#21685 Dear Mrs. Sprinkle: NOV 2 2 2016 Water Quality As requested by Sparks Oil Company, Pyramid Environmental & Eng L `MWipp'%.fias pn completed a renewal request package for the NPDES Permit # NC0088692. Enclosed please find the NPDES Permit renewal request package containing all required documentation. The Camp Springs 761JW Smith remediation system has not been changed since the issuance of the current NPDES permit that expires on May 31, 2017. Please note that there is an incorrect number of carbon vessels listed in the current permit. The new permit should list four (4) carbon vessels. Please see the documents in the enclosed Residuals Management Plan regarding the carbon vessel number. If you have any questions or need any additional information regarding this permit renewal request, please call me at 336-335-3174. Sincerely, Mika Trifunovic Project Manager Enclosures: NPDES Permit Renewal Package P.O. Box 16265 • Greensboro, NC 27416 5031ndustrial Ave • Greensboro, NC 27406 Phone (336)335-3174 • Fax (336)691-0648 • Toll Free (866)545-9507 Email: Info@pwanlidenvimnmcntal.com www pvramidenvimnmental com Water Resources ENVIRONMENTAL OUALfTY December 09, 2016 Mr. Jerry Sparks, President Sparks Oil Company 412 N. Scales Street Reidsville, NC 27320-2909 PAT MCCRORY GovNna DONALD R. VAN DER VAART saner.'), S. JAY ZIMMERMAN Dlre&r , Subject: Permit Renewal Application No. NCO088692 J.W. Smith/Camp Spring 76 Caswell County Dear Mr. Sparks: The Water Quality Permitting Section acknowledges receipt of your permit application and supporting documentation received on November 22, 2016. The primary reviewer for this renewal application is Derek Denard. The primary reviewer will review your application, and he will contact you if additional information is required to complete your permit renewal. Per G.S. 15OB-3 your current permit does not expire until permit decision on the application is made. Continuation of the current permit is contingent on timely and sufficient application for renewal of the current permit. Please respond in a timely manner to requests for additional information necessary to complete the permit application. If you have any additional questions concerning renewal of the subject permit, please contact.Mr. Denard at 919-807-6307 or Derek.Denard@ncdenr.gov. cc: Central Files NPDES Winston-Salem Office Sincerely, 'd!/" '7&1 old Wren Thedford Wastewater Branch Stale ofNenh CxwRaa I F-viwmeutal Qulity I Waler Raw. 1617 Mail Servim Center I Raleigh, Nodh Cmolioa 2709LI617 919-S07-6300 Air PYRAMID ENVIRONMENTAL & ENGINEERING, P.C. Authorization for NPDES Renewal Package Preparation I, Jerry Sparks, the president of Sparks Oil Company, authorize Pyramid Environmental & Engineering, P.C. to prepare the NPDES Renewal Package for the JW Smith/ Camp Springs 76 groundwater remediation system. of Sparks Oil Company . Date P.O. Box 16265 • Greensboro, NC 27416 503 industrial Ave • Gre®sbom, NC 27406 Phone (336)335-3174 • Fax (336)691-0648 • Tall Free (866)545-9507 Email: Info@ovramidenvimnmental.mm w .vvremidenvironmeotal.com NC DENR / DWQ / NPDES Renewal Application Checklist The following items are REQUIRED for all renewal. packages: A cover letter requesting renewal of the permit and documenting any changes at the facility since issuance of the last permit. Submit one signed original and two copies. The completed application form (copy attached), signed by the permittee or an Authorized 0/1 Representative. Submit one signed original and two copies. If an Authorized Representative (such as a consulting engineer or environmental consultant) prepares the renewal package, written documentation. must be provided showing the authority delegated to the Authorized Representative (see Part II.B.11.b of the existing NPDES permit). A narrative description of the sludge management plan for the facility. Describe how sludge (or other solids) generated during wastewater treatment are handled and disposed. If your facility has no such plan (or the permitted facility does not generate any solids), explain this in writing. Submit one signed original and two copies. The following items must be submitted byn Municipal or Industrial facilities dish process wastewater: r o Industrial facilities classified as Primary Industries (see Appendices A-D to Title 40 of the Code of Federal Regulations, Part 122) and All Municipal facilities with a permitted flow >_ 1.0 MGD must submit a Priority Pollutant Analysis (PPA) in accordance with 40 CFR Part 122.21. The above requirement does NOT apply to t on-industdal faeiJ.t'ties. Send the completed renewal package to: Mrs. Dina Sprinkle NC DENR / DWQ / Point Source Branch 1617 Mail Service Center Raleighs NC 27699-1617 (919) 807-6304 NPDES PERMIT APPLICATION - SHORT FORM C - GiW For discharges associated with groundwater treatment facilities. Mail the complete application to: N. C. Department of Environment and Natural Resources Division of Water Quality / NPDES Unit 1617 Mail Service Center, Raleigh, NC 27699-1617 NPDES Permit Number NCO088692 If ypu are completing this form in computer use the TAB key or the up — down arrows to move from one field to the next To check the boxes, click your mouse on top of the box Otherwise, please print or type. 1. Contact Information: Owner Name Sparks Oil Company Facility Name JW Smith / Camp Springs 76 remediation system Mailing Address 412 N Scales Street City Reidsville State / Zip Code NC / 27320-2909 Telephone Number (336)349-8231 Fax Number (336)349-9959 e-mail Address jerry@sparksoil.com 2. Location of facility producing discharge: Check here if same as above ❑ Street Address or State Road 8920 Cherry Grove Road City Reidsville State / Zip Code NC / 27320/0227 County Caswell 3. Operator Information: Name of the firm, consultant or other entity that operates the facility. (Note that this is not referring to the Operator in Responsible Charge or ORQ Name Pyramid Environmental & Engineering, P.C. Mailing Address PO Box 16265 City Greensboro State / Zip Code NC / 27416-0265 Telephone Number (336)335-3174 Fax Number • (336)691-0648 4. Ownership Status: Federal ❑ State ❑ Private ® Public ❑ Pago , of 3 C-cw 03105 0 1 S i NPDES PERMIT APPLICATION - SHORT FORM C - GW For discharges associated with groundwater treatment facilities. S. Products recovered: Gasoline ❑ Diesel fuel ❑ Solvents ❑ Other Petroleum contaminated groundwater 6. Number of separate discharge points: z Outfall. Identification numbers) ]. ?. Frequency of discharge: Continuous ® Intermittent ❑ If intermittent: Days -per week discharge occurs: Duration: S. Treatment System Design flow 0.009 NGD ' 9. Name of receiving streams) (Provide a map showing the exact location of each ou(all, including latitude and longitude): Unnamed tributary of County Line Creek 10. Please list all additives to the treatment system, including chemicals or nutrients, that have the potential to be discharged. none 11. Is this facility located on Indian country? (check one) Yes ❑ No 12. Additionallnformation All appliccatios (rnchiOW renewalsj: A USGS topographical map (or copy of the relevant portion) which shows all outfalls > A summary of the most recent analytical results (effluent data, if available) containing the maximum values for each chemical detected NEW Applicants only: Engineering Alternative Analysis > Description of remediation treatment system components, capacities, and removal efficiency for detected compounds. > If the treatment system will discharge to a storm sewer, written approval from the municipality responsible for the sewer. > A list of any chemicals found in detectable amounts at the site, with the maximum observed concentration reported for each chemical (the most recent sample must be collected less than one year prior to the date of this application) > For petroleum -contaminated sites — Analyses for Volatile Organic Compounds (VOC) should be performed. Analyses for any fuel additives likely to be present at the site and for phenol and lead should also be performed. > For sites contaminated with solvents or other contaminants - EPA Method 624/625 analysis should be performed. Page 2 of 3 C-GW 03105 NPDES PERBUT APPLICATION - SHORT FORM C - GW For discharges associated with groundwater treatment facilities. 13. Applicant Certification I certify that I am familiar with the information contained in the application and that to the best of my knowledge and belief such information is true, complete, and accurate. Jerry Sparks President Printed r e of Person Signing 71 le Y r ofFA�.icant / Date lina General Statute 143-215.6 (b)(2) provides that: Any person who knowingly makes any false representation, or certification in any application, record, report, plan, or other document files or required to be maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, or who falsifies, tampers with, or knowingly renders inaccurate any recording or monitoring device or method required to be operated or maintained under Article 21 or regulations of the Environmental Management Commission implementing that Article, shall be guilty of a misdemeanor punishable by a fine not to exceed $25,000, or by imprisonment not to exceed six months, or by both. (18 U.S.C. Section 1001 provides a punishment by a fine of not more than $25,000 or imprisonment not more than 5 years, or both, fora similar offense.) Page 3 of 3 C-M 0M uu14014VII O2.40 aMP44VDOAO Y� u1L rm= 041L9 Sparks Oil Company Camp Springs 67 Groundwater Remediation Site Latitude 360 17' 46" N State Quad: Cherry Grove Longitude: 79' 29' 42' W Paimldad Plow. 0.009 MOD Recelvin4 Stream: Ur to Country Line Creak Stream Gees: W841 HOW Drainage Basle: Roanoke River Basin Sub•Sasin: 03.02-041030MG4 Plan Prepared by: Mika Trifunovic Project En&eer Residuals Management Plan J.W. Smith / Camp Springs 76 Groundwater Remediation System. 8920 Cherry Grove Road Reidsville, Caswell County, NC NPDES Permit # NCO088692 NCDEQ Incident # 21685 Prepared for: Sparks Oil Company 412 N. Scales Street Reidsville, NC 27320 Plan Reviewed*by: 46 Michael G. Jones .Operations r Pyramid Environmental & Engineering, P.C. P.O. Box 16265 503 Industrial Ave. Greensboro, NC 27416-0265 t Residuals Collection, Handling. Processing, Storage & Dismal As requested by the Construction Grants and Loans Section of Division of Water Quality of North Carolina Department of Environmental Quality (NCDEQ), collection, handling, processing, storage and disposal of residuals generated in the product storage drum, oil water separator (OWS), bag filter, aggregate filter, carbon vessels, ion exchange vessels, and backwash filter are addressed in this plan. Oil Water Separator and Product Storage Drum Free product from the OWS discharges by gravity to a 65 gallon polyethylene product storage. drum installed outside of the system building. The product storage drum is equipped with a high- level switch to shut down operation of the remediation system. Residuals from. the OWS and product storage drum are collected and handled by a contractor in accordance with all applicable regulations on an as needed basis. ,After the collection of the residuals, the contractor immediately hauls the residuals off the site. The contractor is also responsible for the proper disposal or storagelprocessing of residuals. Bag Filter The bag filter is changed every month during scheduled monthly maintenance events. The used bag filters are removed from the bag filter housing using disposable gloves and placed in a sealed plastic container. The used bags are immediately shipped as a non -hazardous waste for proper disposal. Pyramid is responsible for the collection, handling, and disposal of used bag filters. Aggregate Filter and Carbon Vessels The aggregate filter and carbon vessels are exchanged every six months by a contractor in accordance with all applicable regulation. Used aggregate filter and carbon vessels are immediately hauled off the site. The contractor is responsible for the residuals handling and proper disposal or storagelprocessing. Ion Exchange Vessels Two ion exchange vessels were replaced with carbon vessels in May 2012. The NCDEQ approved this change, however the number of carbon vessels has never been changed in the current NPDES permit that expires on May 31, 2017. Please see the enclosed correspondence between Pyramid and NCDEQ. Backwash Filter -• The used backwash filter media is collected and handled by a contractor in accordance with all applicable regulations on an as needed. basis. Auer the collection of the used media, the contractor immediately removes the filter media from the site for processing and/or disposal. The contractor is also responsible for proper disposal or storagelprocessing of the used media. Camp Springs 761JW Smith — Residuals Management Plan 1 Mika Trifunovic From: Mika Trifunovic <mika@pyramidenvironmental.com> Sent: Wednesday, June 20, 20121138 AM To: 'Bob Guerra (bob.guerra@ncdenr.gov)' Cc Mike Jones (Mike@pyramidenvironmental.com) Subject: JW Smith/Camp Springs 76 NPDES Permit # NCO088692 Good morning Bob, I have just received the referenced NPDES permit form our client and I've noticed that the Supplement to Permit Cover Sheet (attached as a PDF file) contains an incorrect number of carbon vessels. There should be four (4) carbon vessels listed on the sheet because two (2) Ion exchange vessels have been converted to carbon vessels. Please see the forwarded emails. Could you please email me the NPDES permit with the correct number of carbon vessels. Thank you. Mika From: Guerra, Bob rmailto;hjh.guerra0ncdenr.gov] Sent: Wednesday, March 14, 20121:26 PM To: Mika Trifunovic Subject: RE: Modification of JW Smith/Camp Springs 76 Remedlation System I will be including this request and incorporate the changes into your permit when I issue it. From: Mika Trifunovic rM@Ilto:mikaLMp=midenvironmental.coml Sent: Wednesday, March 14, 201212:12 PM To: Corpomn, Joe; Guerra, Bob . Subject: Modification of JW Smlth/Camp Springs 76 Remedlation System Good afternoon Joe and Bob, As I mentioned during our conversation, we have intent to modify the JW Smith/Camp Springs 76 petroleum contaminated groundwater remediation system which holds the NPDES Individual Permit # NC0088692. The modification will include conversion of two existing ion exchange vessels into carbon filter vessels. Detailed information about the modification Is provided in the attached PDF file. Please let me know if you need any additional information or clarification. Since the permit is currently being renewed, I would like to ask you to include this proposed modification into the permit. Thank you. Mika Trifunovic Project Manager Pyramid Environmental & Engineering 0 SEAL 8000 O 6 (WM NOTE: Tbls Be may be i0N5 in fhe LEVEL FLOAT SWITCH PUMP ON & OFF L RELAY OPENS I .-- — — — — — — — — ----� VEL RELAY CLOSES ---------------- L RELAY OPENS (2) aerkely 6VM SS Muni Stage 1 HP Centrifugal Pumps / (1) Multi —Media Aggregate Filter (2) Hlgh—Pressure GAC V Each With 90 His. (3 cu.ft) carbon JW Smith/Camp Springs 76 Petroleum Contaminated Groundwater Remediation System - NPDES Permit # NCO088692 AIR STRIPPER 4L •F $ NFiP SYSTEMS U' < M N r, \l° Model 2651 z 3 VEfQr TO Shalbw Troy —''0 U M ATMOSPHERE 5—Trey law Profile >� w z Flow Rate: 2-116 WN Nr Sm IHn. 600 CM w ZZ fa m O O W Z O N M e'(JMaZy AIR o INLET FILTER Stainless v I Pump - 1HP AIR STRIPPER �- BLOWER ; SLOWER r--- - I Y7=XH 3 a I I r— I SCMFM I I — —----------1— J —�I r� r 0.5 T i_F1�N �;--- Both ion exchange units will be converted Into carbon filter vessels. Conversion process: - vacuum ion exchange media from the vessels - rinse empty vessels - haul the Ion exchange media and rinse water -- off site for proper disposal LEVEL FL - fill the vessels with virgin carbon PUMP ON There will be no backwash of the carbon filter vessels. The existing ion exchange backwash line and 320-gallon tank will be removed. IGN — NOT RELEASED FOR OONSTRUCTION IACKWASH FLOW TREM CR SMIARM Q lI Q a III����IIIII z w C9 01 a0 z ON