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HomeMy WebLinkAboutWI0400035_Application_20230815REVISED North Carolina Department of Environmental Quality — Division of Water Resources APPLICATION FOR PERMIT TO CONSTRUCT AND/OR USE A WELL(S) FOR INJECTION Groundwater Remediation (15A NCAC 02C .02251 Do not use this form for UIC wells Permitted by Rule (ref. 15A NCAC 02C .0217) Permit Number (to be completed by DWR for new projects): WI I. APPLICATION INFORMATION 1. Project is: [ ] New [ ] Modification [ ] Renewal without modification [X] Renewal with modification 2. If this application is being submitted for Renewal and/or Modification to an existing permit, provide: Existing permit number WI0400035 Issued Date: 11/22/2013 & Expiration Date: 4/30/2019 For all Renewals, attach an updated site map and status report including monitoring results of all injection activities to date. For Renewal without modification only, fill out sections I & II only, sign the certification on the last page of this form, and obtain the property owner's signature to indicate consent (if the applicant is not the owner). II. WELL OWNER(S)/PERMIT APPLICANT (generally the responsible party) 1. Name(s): Mr. Phil LeRoy — Ares Capital Corporation 2. Signing Official's Name*: Joshua Bloomstein Title: Partner * Signing Official must be in accordance with instructions in Part XII. 3. Mailing address of Permittee/Applicant: 2200 Pennsylvania Avenue NW, Suite 600-W City: Washington, State: DC Zip: 20037 4. Telephone number: (202) 721-6146 Email: 5. Status (choose one): Individual X Business/Org. Federal State County Municipality III. PROPERTY OWNER(S) (if different than well owners) 1. Name(s): Mr. Kyle Winslow BSC Land Investments, LLC 2. Mailing address: 845 Windalier Lane City: Winston-Salem State: NC Zip: 27106 3. Telephone number: (336) 244-8749 Email: kwinslowkbriggsbeams.com IV. PROJECT CONTACT — (generally the environmental/engineering consultant). 1. Name: Chris Hay Title: Principal 2. Company: EnviroTrac, Ltd. 3. Address: 7343 West Friendly Ave, Suite J 4. City: Greensboro State: NC Zip: 27410 5. Telephone number: (336) 763-6025 Email: christopherh =,envirotrac.com Groundwater Remediation Application Rev. 2-17-2020 Pagel of 8 V. FACILITY INFORMATION 1. Facility name: Rotork Phone No. (if available) (336)659-3400 2. Physical address: 3920 Westpoint Boulevard City: Winston-Salem County: Forsyth Zip: 27103 3. Geographic Coordinates: Latitude: 36.038075 Longitude:-80.325756 Reference Datum: Google Accuracy: Method of Collection (i.e., Google Earth, GPS, etc.): hLtp://itouchmap.com/latlong.html 4. Brief description of business: Industrial manufacturing warehouse VI. INCIDENT DESCRIPTION 1. Source and date of contamination: June 26, 1998 the release of tetrachloroethene (PCE)was reported. PCE was detected in the soil and groundwater in the area of the process room. 2. List all contaminants present in soils or groundwater at the site (contaminants may be listed in groups, e.g., gasoline, diesel, jet fuel, fuel oil, chlorinated ethenes, chlorinated ethanes, metals, pesticides/herbicides, etc): Tetrachloroeth. lene PCE), trichloroethene (TCE), cis-1,2-dichloroethene (DCE), and vinyl chloride are the primary contaminants of concern. 3. Has LNAPL or DNAPL ever been observed at the site (even if outside the injection zone)? [ ] Yes If yes, list maximum measured separate phase thickness: feet [X] No If no, list maximum concentration of total VOCs observed at site: 8,170 (from MW-9 5/1/02I ppb 4. Agency managing the contamination incident: [ ] UST Section [X] Superfund Section (including REC Program and DSCA sites) [ ] DWR Aquifer Protection Section [ ] Solid Waste Section [ ] Hazardous Waste Section [ ] Other: 5. Incident manager's name: Dianne Thomas Phone No.: (919) 707-8349 6. Incident number or other incident mgmt. agency tracking number: NONCD0001700 VII. PERMITS List all applicable permits or construction approvals issued for the facility or incident: 1. Previous or other UIC permits issued by DWR (e.g., NOIs) WI0400021-HRC Pilot Study W10400035 - 3DMe injection 2. Other Non -Discharge or NPDES permit issued by DWR: None 3. County or DEH subsurface wastewater disposal permits: None 4. Hazardous waste management or other environmental permits required by state or federal law: None Groundwater Remediation Application Rev. 2-17-2020 Page 2 of 8 VIII. INJECTION SUMMARY 1. List all proposed injectants/additives. NOTE: Only injectants approved by the epidemiology section of the NC Division of Public Health, Department of Health and Human Services can be injected. Approved injectants can be found online at hllp: Hdeq.nc. gov/about/divisions/water-resources/water-resources-permits/wastewater-branch/ground-water- protection/gxound-water-approved-injectants. All other substances must be reviewed by the DHHS prior to use. Contact the UIC Program for more info if you wish to get approval for a different additive. However, please note it may take 3 months or longer. If no injectants are to be used use N/A. Injectant: Potassium Pennan ag n�KMn04) Total Amt. to be injected (gal)/event: 138 Injectant: Total Amt. to be injected (gal)/event: Injectant: Total Amt. to be injected (gal)/event: Injectant: Total Amt. to be injected (gal)/event: Injectant: Total Amt. to be injected (gal)/event: Total Amt. to be injected (gal/event): 138 gal/event = 8 injections twice a month for 4 months No. of separate injection events: 8 Total Amt. to be injected (gal): 1,104 Source of Water (if applicable): City of Winston-Salem 2. Estimated Injection rate per well: 0.25 — 1.0 GPM 3. Estimated Injection pressure: < 10 pounds/square inch (PSI) 4. Temperature at point of injection: ambient OF 5. Injection will be via: Existing well(s)- Total No.: 18 ; Well Type (DPT, Permanent, etc.): Permanent Proposed well(s)- Total No.: N/A ; Well Type (DPT, Permanent, etc.): N/A 6. NC Certified Well Drilling Contractor's Name (if known): NC Well Contractor Certification No.: N/A N/A 7. Date to be constructed if proposed: N/A (attach well construction records [GW-Is] for existing injection wells) 8. Screened interval/Injection interval of injection wells: See Table 1 and 2 Depth from 8.46 to 54.80 feet below land surface (BLS)(if multiple intervals, indicate shallowest to deepest depth) 9. Well casing (leave blank if Geoprobes®): Type (PVC, stainless steel, other): PVC Casing depth: 0 to 49.80 ft. BLS Type (PVC, stainless steel, other): Casing depth: to ft. BLS Groundwater Remediation Application Rev. 2-17-2020 Page 3 of 8 10. Grout (leave blank if Geoprobes): Type (cement, bentonite, other): cement Grout depth: 0 to 46.80 ft. BLS Type (cement, bentonite, other): Grout depth: to ft. BLS IX. ATTACHMENTS — provide the following information in separate attachments. The attachments should be clearly identified and presented in the order below to expedite review of the permit application package. 1. INJECTION ZONE — Per 15A NCAC 02C .0225(f)(3), specify the horizontal and vertical portion of the subsurface within which the proposed injection activity will take place and beyond which no violations of groundwater quality standards shall result from the injection as determined by an approved monitoring plan. The determination shall be based on the hydraulic properties of the specified zone. Provide any supporting documentation in a separate attachment. See attachment Figures 3-10 2. HYDROGEOLOGIC EVALUATION —Per 15A NCAC 02C .0225(f)(4), provide a hydrogeologic evaluation of the injection zone that includes all of the following: (A) Regional and local geology and hydrology; (B) Changes in lithology underlying the facility; (C) Depth to bedrock; (D) Depth to the mean seasonal high water table; (E) Hydraulic conductivity, transmissivity, and storativity, of the injection zone based on tests of site -specific material, including a description of the test(s) used to determine these parameters; (F) Rate and direction of groundwater flow as determined by predictive calculations or computer modeling; (G) Lithostratigraphic and hydrostratigraphic logs of any existing test and injection wells; and (H) For systems re -injecting treated on -site contaminated groundwater only- evaluation of infiltration galleries or injection wells. 3. INJECTANT INFORMATION — Per 15A NCAC 02C .0225(f)(6), provide information on each injectant as indicated below: See Section IX Attachments (A) MSDS, concentration at the point of injection, and percentage if present in a mixture with other injectants; (B) The source of fluids used to dilute, carry, or otherwise distribute the injectant throughout the injection zone. If any well within the area of review of the injection facility is to be used as the fluid source, then the following information shall be submitted: location/ID number, depth of source, formation, rock/sediment type, and a chemical analysis of the water from the source well, including analyses for all contaminants suspected or historically recognized in soil or groundwater on the site; (C) A description of the rationale for selecting the injectants and concentrations proposed for injection, including an explanation or calculations of how the proposed injectant volumes and concentrations were determined; (D) A description of the reactions between the injectants and the contaminants present including specific breakdown products or intermediate compounds that may be formed by the injection; (E) A summary of results if modeling or testing was performed to investigate the injectant's potential or susceptibility for biological, chemical, or physical change in the subsurface; and (F) An evaluation concerning the development of byproducts of the injection process, including increases in the concentrations of naturally occurring substances. Such an evaluation shall include the identification of the specific byproducts of the injection process, projected concentrations of byproducts, and areas of migration as determined through modeling or other predictive calculations. 4. INJECTION PROCEDURE — Per 15A NCAC 02C .0225(f)(7), submit a table with a detailed description of the proposed injection procedure that includes the following: See Section IX Attachments Groundwater Remediation Application Rev. 2-17-2020 Page 4 of 8 (A) The proposed average and maximum daily rate and quantity of injectant; (B) The average maximum injection pressure expressed in units of pounds per square inch (psi); and (C) The total or estimated total volume to be injected. 5. FRACTURING PLAN (if applicable) — Per 15A NCAC 02C .0225(f)(9). submit a detailed description of the fracturing plan that includes the following: Not Applicable (A) Material Safety Data Sheets of fracturing media including information on any proppants used; (B) a map of fracturing well locations relative to the known extent of groundwater contamination plus all buildings, wells, septic systems, underground storage tanks, and underground utilities located within the Area of Review; (C) a demonstration that buildings, wells, septic systems, underground storage tanks, and underground utilities will not be adversely affected by the fracturing process; (D) injection rate and volume; (E) orientation of bedding planes, joints, and fracture sets of the fracture zone; (F) performance monitoring plan for determining the fracture well radius of influence; and (G) if conducted, the results of geophysical testing or pilot test of fracture behavior conducted in an uncontaminated area of the site. 6. WELL CONSTRUCTION DETAILS — Per 15A NCAC 02C .0225(f)(10). submit the following information in tabular or schematic form as appropriate for each item: See Tables 1 and 2 (A) number and depth of injection wells; (B) number and depth of borings if using multi -level or "nested" well systems; (C) indication whether the injection wells are existing or proposed; (D) depth and type of casing; (E) depth and type of screen material; (F) depth and type of grout; (G) indication whether the injection wells are permanent or temporary "direct push" points; and (H) plans and specifications of the surface and subsurface construction details. 7. MONITORING PLAN — Per 15A NCAC 02C .0225(ff(11), submit a monitoring plan that includes the following: (A) target contaminants plus secondary or intermediate contaminants that may result from the injection; (B) other parameters that may serve to indicate the progress of the intended reactions; (C) a list of existing and proposed monitoring wells to be used; and (D) a sampling schedule to monitor the proposed injection. See attached workplan for Potassium Permanganate Injection and Semi-annual Groundwater Monitoring Monitoring wells shall be of sufficient quantity and location to detect any movement of injection fluids, injection process byproducts, or formation fluids outside the injection zone. The monitoring schedule shall be consistent with the proposed injection schedule, pace of the anticipated reactions, and rate of transport of the injectants and contaminants. 8. WELL DATA TABULATION —Per 15A NCAC 02C .0225(f)(12)= provide a tabulation of data on all existing or abandoned wells within the area of review of the injection well(s) that penetrate the proposed injection zone, including monitoring wells and wells proposed for use as injection wells. Such data shall include a description of each well's type, depth, and record of construction or abandonment. See Tables 1 and 2 9. MAPS AND CROSS -SECTIONS — Per 15A NCAC 02C .0225(f)(13), provide scaled, site -specific site plans or maps depicting the location, orientation, and relationship of facility components including the following: (A) area map based on the most recent USGS 7.5' topographic map of the area, at a scale of 1:24,000 and showing the location of the proposed injection site; Figures 1 and 2 (B) topographic contour intervals showing all facility related structures, property boundaries, streams, springs, lakes, ponds, and other surface drainage features; Figures 1 (C) all existing or abandoned wells within the area of review of the wells listed in the well data tabulation that penetrate the proposed injection zone; Figures 3 (D) potentiometric surface map(s) that show the direction of groundwater movement, existing and proposed wells; (E) contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, and existing and proposed wells; Figures 5 Groundwater Remediation Application Rev. 2-17-2020 Page 5 of 8 (F) cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, major changes in lithology, and existing and proposed wells Figures 7-10; and (G) any existing sources of potential or known groundwater contamination, including waste storage, treatment, or disposal systems within the area of review of the injection well or well system. Figures 6 X. UIC SYSTEMS RE -INJECTING TREATED ON -SITE CONTAMINATED GROUNDWATER ONLY Not Applicable 1. FEES — Per 15A NCAC 02C .0225(m), submit/attach fees for new permits or modifications (refer to fee schedule at h!Ws://deq.nc.gov/about/divisions/water-resources/water-resources-permits/wastewater-branch/,ground-water- protection/non-discharge-,groundwater-remediation 2. SOILS EVALUATION - Per 15A NCAC 02C .0225(f)(2), for systems with proposed discharge within seven feet of land surface and above the seasonal high water table, a soil evaluation of the disposal site shall be provided to the Division by the applicant. If required by G.S. 89F, a soil scientist shall submit this evaluation. This evaluation shall be presented in a report that includes the following information: (A) Field description of soil profile. Based on examinations of excavation pits or auger borings, the following parameters shall be described by individual horizons to a depth of seven feet below land surface or to bedrock: thickness of the horizon; texture; color and other diagnostic features; structure; internal drainage; depth, thickness, and type of restrictive horizons; pH; cation exchange capacity; and presence or absence of evidence of any seasonal high water table. Applicants shall dig pits when necessary for evaluation of the soils at the site. (B) Recommendations concerning annual and instantaneous loading rates of liquids, solids, other wastewater constituents and amendments. Annual hydraulic loading rates shall be based on in -situ measurement of saturated hydraulic conductivity in the most restrictive horizon. 3. ENGINEERING PLANNING DOCUMENTS — Per 15A NCAC 02C .0225(f)(8), the following documents shall be provided to the Division by the applicant (Note: if required by G.S. 89C, a professional engineer shall prepare these documents): (A) engineering plans for the entire system, including treatment, storage, application, and disposal facilities and equipment, except those previously permitted unless they are directly tied into the new units or are critical to the understanding of the complete process; (B) specifications describing materials to be used, methods of construction, and means for ensuring quality and integrity of the entire groundwater remediation system; (C) plans that include construction details of recovery, injection, and monitoring wells and infiltration galleries; (D) operating plans that include: (i) the operating schedule including any periodic shut -down times; (ii) required maintenance activities for all structural and mechanical elements; (iii) a list of all consumable and waste materials with their intended source and disposal locations; (iv) restrictions on access to the site and equipment; (v) provisions to ensure the quality of the treated effluent and hydraulic control of the system at all times when any portion of the system ceases to function, such as standby power capability, complete system -off status, or duplicity of system components; and (E) Completed, signed, and sealed Professional Engineer's Certification for new permit applications (form attached). Groundwater Remediation Application Rev. 2-17-2020 Page 6 of 8 \tt a t t i 1t it 11 ION se,luitiJ hcl„+a kit l)ti tlsat lr tsrm's nuthc�oi+CJ ;it":nt' i \ ,ttlllk that ,tll pc•taatit appl1c;atwns'11a11 INC signwd a, fiyllems t "k .. , C Torlsil,ic colpolille oilicet piopIictolshrp' by ;I ►tcnenal partner of the propUetttr, tespcciscc•h• ltc. Ccklrsal• e,a olhet public agency: by either a principal cxcCtttiic of iccr f;s� txikm,' pnl,lich rlc•Ct,JOiiici;tl 1 !gin ;tll,�thc's, by tiu vvc-ll , vk1let -11 ,tat .1mbol ireal agent is sighing rsn hehnlf art the applicant, then sttpplti a letter signed b% the applit ant that n.m es and authorims their agent. 1 herrl1r e•,rtttt Iris l',�tt,III a' of' laar III, it I hare- p,•rcvnally ertnrrIli ed aucl curt lutuihor with Mc rn/ormatton r:htr:,ttr,.i nr dus Klocimiew mul all anachincvnk dw?—e r, tanrl thus, hated ort Inv mqutr3• ol.thou' urtitaithr /k ntt,Ii,,IWICA' rcvp,tusihleparr oluauting scud irlfrrnuttiou, 1 hrlie°ae that the rnjormotion is true°, wturtrtc, antl 1 tau mi it � that there rate' pe educe%, tnc/ukling the possthrlitt• olfines anal imprisonment, fo sulr mining r,r1,, utturrrratr¢»t. 1 a} r„ t,, inmt� ue t, operutt, rturintoin, rep oir, aracl rf ipplicahle, uharalnn the urlrctirut WCU(s) �r,r ,tll r, l,ur,l orpurlcri. c•> rn tutlaurr wJ1h thw apltrtra e,t cl„�c'rlicatrnm tarµl cortelruom of thr Permit i l+cci c r }'r9nte.i `,true and 1 i11C. ,�05�l, u- _� i� kJ;lt..a.12C-0 Z,l.tt NAr Date: ✓ �___." Z \tll, CONSENT OF PROPERTI' O'1'!'NE.R (if the property is not owned by the permit applicant) "C')vrncr'" paeans any person viho holds the fee or other property rights in the well being constructed_ A Hell is real property and its construction on land shall be deemcd to vest ownership in the land owner, in the .absence of eontrary 3"reernent in writing. "As owlier of they property' on which the miec•ttorr 11 CII(s) are to he comtructecl awl opermetl 1 herehr 4 wme'ni to 011ou, the applicant to convtruc t eot /r rrtic•ctton well av outltrmerl itr this uppliccition uael agree that it shall he the n'.kponsihtlitY of the: appliccutt to vmul,e that dw tnlectran well(s) coulornr to the We// Com;traction umckirth 1 kprd of Printed Name and Title: 1 � V Signature: Date: _-- submit T'1'4'O hard copies of the completed application trackage m ith an electronic version in CD or USI1 t"lash Drive to; DIVISION OF WATER RESO1?RCES — UIC PROGRAM 16361NAll, SERVICE CENTER RALEIGH, NORTH CAROLINA 27699-1636 TELEPHONE NUMBER: (919) 707-9000 r:,o,mchNam Remediation Application Rev 2-17-2020 1'.,rr ;; Professional Engineer's Certification (for new permit application for UIC systems re -injecting treated on -site contaminated groundwater only): Permit No.: WI Typed or Printed Name of Professional Engineer: License Number: Name of Engineering Firm (if applicable): Mailing Address: City: State: Zip: Office Number: () Mobile Number: () Email Address: I, attest that this application for has been reviewed by me and is accurate and complete to the best of my knowledge. I further attest that to the best of my knowledge the proposed design has been prepared in accordance with the applicable regulations. Although certain portions of this submittal package may have been developed by other professionals, inclusion of these materials under my signature and seal signifies that I have reviewed this material and have judged it to be consistent with the proposed design. North Carolina Professional Engineer's Seal, Signature, and Date: Groundwater Remediation Application Rev. 2-17-2020 Page 8 of 8 IX. ATTACHMENTS IX. Attachments 1 Injection Zone The injection zone will consist of the immediate vicinity of existing wells MW-1, DW-2, MW-6R, MW-8, MW-9, MW-10, MW-11, MW-13, DW-16 and DW-19 as well as injection wells IW-8, IW-9, IW-11, IW-12, IW-13, IW-14, IW-15 and IW-16. The monitoring wells are screened from approximately 8.46 feet to 54.80 feet below ground surface. The injection wells are screened from the top of the water table to the bed rock surface. Monitoring well construction details are summarized in Table 1. Existing injection well construction details are summarized in Table 2. 2 Hydrology Description A. The site is located in the Carolina Slate Belt of the Piedmont Physiographic Province of North Carolina. The surficial geology consists of residual soil which has formed from the in -place chemical and physical weathering of the underlying bedrock. The surrounding topography consists of rolling land and broad ridges. According to the Geologic Map of North Carolina, the regional bedrock generally consists of metamorphosed rock meta gabbro, metadiorite and plutonoic-volcanic complexes. Groundwater generally flows to the southeast discharging into tributaries of Salem Creek. Based on cross sections in the UIC Permit Application — Class 51 Wells, the subsurface soils were silty sand south and northwest of the onsite build, from the surface to 25 feet Beneath the onsite building consisted of fill material to approximately 6 feet followed by silty sand, sandy silts, and clayey silt to 45 feet. Subsequent investigation confirmed residual soil texture ranged from predominantly decomposed rock (saprolite) and fine grained sandy silts and clays. Soil extends to depths ranging from approximately 2 to 45 feet below ground surface. According to the USGS Topographic Map, Winston-Salem West, North Carolina Quadrangle (Figure 1), tributary to Salem Creek is located south of the site and flows into Salem Creek southeast of the site. Groundwater at the site was encountered at depths ranging from 14.26 to 22.22 below ground surface. Based on the water level measurements from the September 15, 2022 shallow groundwater flow direction at the site is generally to the southeast. B. Based on the soil boring logs and monitoring well logs silty SANDS were observed in the southern and northern borders of the site. The center of the site consisted of fill material to approximately 6 feet followed by silty sand, sandy silts, and clayey silt to 45 feet. C. Depth to bedrock at the site is approximately 45 feet below ground surface. D. Depth to mean seasonal high water table on average occurs in March, the mean elevation below ground surface ranges from 14.12 to 21.76 across the site. E&F. A low permeability, water -table aquifer is present beneath the site. This water -table aquifer is recharged primarily by precipitation events. Static water level measurements collected on September 15, 2022 are summarized in Table 1. Potentiometric surface maps produced with the September 15, 2022, water level data shows that groundwater in the surficial aquifer flows generally towards the southeast (Figure 5). The horizontal hydraulic gradient calculated between monitoring wells MW-3 and MW-7 with September 15, 2022 groundwater measurements was 0.02. Foot/foot. Aquifer testing performed at monitoring wells MW-1 and MW-5 on October 9, 1998 indicated that the surface aquifer has an average hydraulic conductivity of 1.19 feet per day. The hydraulic conductivity value was used to calculate the average linear horizontal groundwater 11.990015.00 1 May 2023 velocity at the site. Using the value of 1.19 feet/day for the hydraulic conductivity, the horizontal gradient for 0.02 foot/foot calculated between monitoring wells MW-3 and MW-7, and an estimated effective porosity of 0.30, the average linear horizontal groundwater velocity was calculated to be 0.09 feet/day. G. Lithostratigraphic and hydrostratigraphic logs were not used. 3 Injection Information A A Material Safety Data Sheet for Potassium Permanganate (KMnO4) provided by Dawn SCI is attached. This product has been previously reviewed and approved by the UIC Program for injection. KMnO4 will be mixed with municipal water at a ratio of 10 parts water to 1 part KMnO4. B Municipal water from the City of Winston-Salem distribution system will be used to dilute the KMnO4 as well as chase the injectant with one to two injectant volumes of water. C Diluted solution to potassium permanganate will be used to reduce the concentration of perchloroethene (PCE) in the groundwater. Permanganate has been used for wastewater and drinking water treatment for many years. In contrast, permanganate has been used for groundwater remediation for less than 20 years. Based on this stochiometry, 1.81 gram (g) of permanganate is needed to degrade 1 g of TCE, releasing 1.32 g of manganese dioxide, 0.67 g of carbon dioxide and 0.81 g of chlorine. Potassium permanganate (KMnO4) and sodium permanganate (NaMnO4) have been injected at hundreds of sites to chemically oxidize chlorinated solvents and other ground water contaminants. In this process, a permanganate (MnO4) solution is injected into the subsurface using temporary points or permanent wells. Once injected, the MnO4 is transported through the aquifer by ambient or induced groundwater flow. When permanganate is injected into the subsurface, a portion of the material reacts with the target contaminant and a portion reacts with the aquifer material. The amount of permanganate that reacts with non -target chemicals is often referred to as the natural oxidant demand (NOD). When estimating the required amount of reagent to inject, designers must account for both permanganate consumed by the target chemicals and the NOD. If the NOD is not considered, the permanganate will be depleted more rapidly than expected and treatment efficiency may be less than desired. EnviroTrac will inject a 10% solution of potassium permanganate to eleven of the existing monitoring wells at the property. Monitoring wells included in the initial treatment will include: monitoring wells MW-1, DW-2, MW-6R, MW-8, MW-9, MW-10, MW-11, MW-13, DW-16 and DW- 19 as well as injection wells IW-8, IW-9, IW-11, IW-12, IW-13, IW-14, IW-15 and IW-16. Application rates and treatment volumes will be recorded for each monitoring well. D Recent work has shown permanganate to be an effective oxidant for treatment of chlorinated solvents (PCE and trichloroethene {TCE}) and aromatic hydrocarbon (naphthalene, phenanthrene, 11.990015.00 2 May 2023 pyrene and phenols). Representative reactions illustrating the oxidation of PCE (C2C14) and TCE (C2HC13) by permanganate are shown below. C204 + 1 1/3 MnO4 1/3 Mn02 + 2 CO2 + 2 2/3 H + 4 Cl (PCE) C2HC13 + 2 MnO4 2 MnO2 + 2 COz + H + 3 CI (TCE) E No site -specific testing or modeling has been performed. F Development of byproducts is not anticipated at the site. 4 Injection Procedure Following approval of the injection strategy, EnviroTrac will order 440 pounds of KMnO4 to be shipped to the site. A sample of the municipal water has previously been collected from the facility and analyzed for volatile organic compounds (VOCs) by Standard Method 6200B. The municipal water supply was free of VOCs and suitable for use in the injection strategy. EnviroTrac will mix KMnO4 and municipal water from the City of Winston-Salem distribution system in a container with wheels and a hose connection at the base. The 5 percent KMnO4 solution will be gravity fed into each of the ten monitoring wells and eight injection wells. Once the KMnO4 solution has been injected into each monitoring and injection well, municipal water from the City of Winston-Salem distribution system will be used to chase the injectant with one to two injectant volumes. (A) The average rate of injection at any locations is anticipated to range between 0.25 and 1.0 gallons per minute. The maximum daily rate of injection will be limited to one injection solution volume (138 gallons per day). (B) The head created by the elevation of the liquid above the water table will range from 5 to 10 pounds per square inch. (C) The estimated total volume of KMnO4 solution and municipal water to be injected is 1,104 gallons. 5 Fracturing Plan Fracturing will not be completed at the site. 6 Well Construction Details A. The number and depth of existing monitoring and injection wells at the site are summarized in Tables 1 and 2. There are eighteen monitoring well and sixteen injection wells, although only ten monitoring wells and eight injection wells are proposed to be used for injection during this event. B. Not applicable. C. All monitoring wells exist currently at the site. D. The depth of each monitoring and injection well is summarized in Table 1 and 2. Each monitoring and injection well is constructed of 2 inch schedule 40 poly vinyl chloride riser and well screen. 11.990015.00 3 May 2023 E. The screen interval of each monitoring and injection well is summarized in Table 1 and 2. Each monitoring and injection well is constructed of 2 inch schedule 40 poly vinyl chloride well screen. F. Each monitoring and injection well is constructed with an approximate two to three foot bentonite seal above the screened interval and is grouted to the ground surface with neat cement grout. G. Each monitoring and injection well is a permanent installation. H. The surface of each monitoring well is completed with an expandable locking well cap and flush mount protective cover set in concrete. 7 Monitoring Plan A — D. Semi-annually a groundwater sampling and injection monitoring event will be completed at the site to track chlorinated ethene levels in groundwater. Static water levels will be collected from all the monitoring wells on -site. Field parameters of temperature, pH, conductivity, dissolved oxygen, and oxidation-reduction potential will be recorded as groundwater samples are collected from monitoring wells MW-1, DW-2, MW-5, MW-6R, MW-7, MW-8, MW-9, MW-10, MW-11, MW- 13, DW-16, DW-19, BW-20, and BW-22. The groundwater samples will be analyzed for VOCs by EPA Method 8260 and manganese by SW-846 6010. A report of semi-annual sampling event will be prepared summarizing our observations, the results of the groundwater analysis, analysis of the efficiency of the remediation process, figures displaying the extent of PCE, a groundwater flow map, conclusions, and recommendations. 8 Well Data Tabulation All monitoring and injection wells proposed for use currently exist at the site. Details of the monitoring wells construction are summarized in Table 1 and 2. 9 Maps and Cross Sections A. USGS Topographic Map —Attached Figure 1 B. Site Map —Attached Figure 2 C. Injection Zone Wells —Attached Figure 3 D. Potentiometric Surface Map — Attached Figure 5 E. Tetrachloroethene Isoconcentration Map — Attached Figure 6 F. Cross Sections — Attached Figures 8-10 G. Not applicable, chlorinated solvent use was discontinued at the site following discovery of the release. 11.990015.00 4 May 2023 SAFTY DATA SHEET POTASSIUM PERMANGANATE z DAWN SCI ,,4 We supply quality products Potassium Permanganate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 01/01/2019 Revision date: NA Supersedes: NA Version: 1.0 1.1. Identification Product form Substance Substance name Potassium Permanganate CAS -No. 7722-64-7 Product code C6550 Formula KMnO4 Synonyms permanganate of potash / potassium salt permanganic acid 1.2. Recommended use and restrictions on use Use of the substance/mixture Oxidant Bleaching agent Reagent Disinfectant Deodorizer Algicide Dyestuff/pigment: component Medicine Laboratory chemical Food industry: additive Insecticide Germicide Recommended use Laboratory chemicals Restrictions on use Not for food, drug or household use 1.3. Supplier DAWN SCI 121 Liberty street Metuchen, NJ 08840 T: 732-902-6300, F : 973-802-1005 www.dawnsci.com care@dawnsci.com 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 • • rinn. • 2.1. Classification of the substance or mixture GHS-US classification Oxidizing solids Category 2 H272 Acute toxicity (oral) H302 Category 4 Hazardous to the aquatic H400 environment - Acute Hazard Category 1 Hazardous to the aquatic H410 environment - Chronic Hazard Category 1 Full text of H statements : see section 16 May intensify fire; oxidizer Harmful if swallowed Very toxic to aquatic life Very toxic to aquatic life with long lasting effects 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) < > < > GHS03 GHS07 GHS09 Signal word (GHS-US) Danger Hazard statements (GHS-US) H272 - May intensify fire; oxidizer H302 - Harmful if swallowed Potassium Permanganate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations H410 - Very toxic to aquatic life with long lasting effects Precautionary statements (GHS-US) P210 - Keep away from heat, sparks, open flames, hot surfaces. - No smoking. P220 - Keep/Store away from clothing, combustible materials P221 - Take any precaution to avoid mixing with combustibles P264 - Wash exposed skin thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P273 - Avoid release to the environment. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P301+P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 - If swallowed, rinse mouth P391 - Collect spillage. P501 - Dispose of contents/container to comply with local, state and federal regulations 2.3. Other hazards which do not result in classification Other hazards not contributing to the None under normal conditions. classification 2.4. Unknown acute toxicity (GHS US) Not applicable 3.1. Substances Substance type Mono -constituent Name Product identifier % GHS-US classification Potassium Permanganate (CAS -No.) 7722-64-7 100 Ox. Sol. 2, H272 (Main constituent) Acute Tox. 4 (Oral), H302 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 Full text of hazard classes and H-statements : see section 16 3.2. Mixtures Not applicable SECTION• measures 4.1. Description of first aid measures First -aid measures general Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with labored breathing: half -seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. First -aid measures after inhalation Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. First -aid measures after skin contact Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing agents. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take victim to hospital. First -aid measures after eye contact Rinse immediately with plenty of water for 15 minutes. Do not apply neutralizing agents. Take victim to an ophthalmologist. First -aid measures after ingestion Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce vomiting. Immediately consult a doctor/medical service. Call Poison Information Centre (www.big.be/antigif.htm). Take the container/vomit to the doctor/hospital. Ingestion of large quantities: immediately to hospital. 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects after inhalation AFTER INHALATION OF DUST: Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. EXPOSURE TO HIGH CONCENTRATIONS: Respiratory difficulties. FOLLOWING SYMPTOMS MAY APPEAR LATER: Risk of lung edema. Symptoms/effects after skin contact Tingling/irritation of the skin. May stain the skin. ON CONTINUOUS EXPOSURE/CONTACT: Caustic burns/corrosion of the skin. Symptoms/effects after eye contact Corrosion of the eye tissue. Inflammation/damage of the eye tissue. ON CONTINUOUS EXPOSURE/CONTACT: Permanent eye damage. Symptoms/effects after ingestion Nausea. Vomiting. Diarrhoea. Irritation of the gastric/intestinal mucosa. AFTER ABSORPTION OF LARGE QUANTITIES: Possible esophageal perforation. Shock. Slowing heart action. Low arterial pressure. Possible laryngeal spasm/oedema. Respiratory difficulties. 2 Potassium Permanganate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Chronic symptoms ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Respiratory difficulties. Impairment of the nervous system. Movement disturbances. Coordination disorders. Myasthenia. Tremor. Paralysis. Cramps/uncontrolled muscular contractions. Impaired memory. Emotional instability. 4.3. Immediate medical attention and special treatment, if necessary No additional information available 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media Adapt extinguishing media to the environment. Preferably: quantities of water. Unsuitable extinguishing media No unsuitable extinguishing media known. 5.2. Specific hazards arising from the chemical Fire hazard DIRECT FIRE HAZARD. Non combustible. INDIRECT FIRE HAZARD. Promotes combustion. Reactions involving a fire hazard: see "Reactivity Hazard". Explosion hazard INDIRECT EXPLOSION HAZARD. Reactions with explosion hazards: see "Reactivity Hazard". Reactivity Decomposes on exposure to temperature rise: oxidation which increases fire hazard. Reacts with combustible materials: risk of spontaneous ignition. Violent to explosive reaction with (some) acids: release of toxic and corrosive gases/vapours. Reacts violently with many compounds e.g.: with organic material and with (strong) reducers. With (some) metals. With (increased) risk of fire/explosion. 5.3. Special protective equipment and precautions for fire-fighters Precautionary measures fire Exposure to fire/heat: keep upwind. Exposure to fire/heat: consider evacuation. Firefighting instructions Cool tanks/drums with water spray/remove them into safety. Do not move the load if exposed to heat. Take account of environmentally hazardous firefighting water. Use water moderately and if possible collect or contain it. Protection during firefighting Heat/fire exposure: compressed air/oxygen apparatus. 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non -emergency personnel Protective equipment Gloves. Face -shield. Protective clothing. Dust cloud production: compressed air/oxygen apparatus. Dust cloud production: dust -tight suit. Reactivity hazard: compressed air/oxygen apparatus. Reactivity hazard: gas -tight suit. See "Material -Handling" to select protective clothing. Emergency procedures Mark the danger area. Prevent dust cloud formation. No naked flames. Keep containers closed. Wash contaminated clothes. In case of hazardous reactions: keep upwind. In case of reactivity hazard: consider evacuation. Measures in case of dust release In case of dust production: keep upwind. Dust production: have neighbourhood close doors and windows. 6.1.2. For emergency responders Protective equipment Equip cleanup crew with proper protection. Do not breathe dust. Emergency procedures If a major spill occurs, all personnel should be immediately evacuated and the area ventilated. Stop release. Ventilate area. 6.2. Environmental precautions Prevent soil and water pollution. Prevent spreading in sewers. 6.3. Methods and material for containment and cleaning up For containment Contain released substance, pump into suitable containers. Consult "Material -handling" to select material of containers. Plug the leak, cut off the supply. Dam up the solid spill. Knock down/dilute dust cloud with water spray. If reacting: dilute toxic gas/vapour with water spray. Take account of toxic/corrosive precipitation water. Methods for cleaning up Stop dust cloud by covering with sand/earth. Scoop solid spill into closing containers. Carefully collect the spill/leftovers. Spill must not return in its original container. See "Material -handling" for suitable container materials. Clean contaminated surfaces with an excess of water. Wash clothing and equipment after handling. 6.4. Reference to other sections No additional information available Potassium Permanganate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 7.1. Precautions for safe handling U_ Precautions for safe handling Comply with the legal requirements. Remove contaminated clothing immediately. Clean contaminated clothing. Keep the substance free from contamination. Use corrosionproof equipment. Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Avoid raising dust. Keep away from naked flames/heat. Observe very strict hygiene - avoid contact. Keep container tightly closed. Measure the concentration in the air regularly. Carry operations in the open/under local exhaust/ventilation or with respiratory protection. 7.2. Conditions for safe storage, including any incompatibilities Heat -ignition KEEP SUBSTANCE AWAY FROM: heat sources. Prohibitions on mixed storage KEEP SUBSTANCE AWAY FROM: combustible materials. reducing agents. strong acids. metal powders. cellulosic materials. organic materials. alcohols. peroxides. Storage area Store at ambient temperature. Keep out of direct sunlight. Store in a dry area. Fireproof storeroom. Unauthorized persons are not admitted. Keep only in the original container. Store only in a limited quantity. Meet the legal requirements. Special rules on packaging SPECIAL REQUIREMENTS: closing. clean. correctly labelled. meet the legal requirements. Secure fragile packagings in solid containers. Packaging materials SUITABLE MATERIAL: steel. aluminium. glass. stoneware/porcelain. MATERIAL TO AVOID: wood. cellusosic material. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Potassium Permanganate (7722-64-7) ACGIH ACGIH TWA (mg/m3) 0.1 mg/m3 (Manganese, inorganic compounds, as Mn; USA; Time -weighted average exposure limit 8 h; TLV - Adopted Value; Inhalable fraction) OSHA OSHA PEL (Ceiling) (mg/m3) 5 mg/m3 as Mn IDLH US IDLH (mg/m3) 500 mg/m3 as Mn NIOSH NIOSH REL (TWA) (mg/m3) 1 mg/m3 as Mn NIOSH NIOSH REL (ceiling) (mg/m3) 3 mg/m3 as Mn 8.2. Appropriate engineering controls Appropriate engineering controls Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure. 8.3. Individual protection measures/Personal protective equipment Personal protective equipment: Gloves. Safety glasses. Dust production: dust mask with filter type P3. 0 CO) (0 Materials for protective clothing: GIVE EXCELLENT RESISTANCE: polyethylene. GIVE GOOD RESISTANCE: butyl rubber. PVC. polyethylene/ethylenevinylalcohol Hand protection: Gloves Eye protection: Face shield. In case of dust production: protective goggles Skin and body protection: Protective clothing. In case of dust production: head/neck protection. In case of dust production: dustproof clothing Respiratory protection: 0 Potassium Permanganate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Dust production: dust mask with filter type P3. High dust production: self-contained breathing apparatus 9.1. Information on basic physical and chemical properties Physical state Solid Appearance Crystalline solid. Crystalline powder. Color Dark violet -brown Odor Odorless Odor threshold No data available pH 7.0-8.5(1.6%) pH solution 1.6 % Melting point > 240 °C Freezing point No data available Boiling point Not applicable Flash point Not applicable Relative evaporation rate (butyl acetate=1) No data available Flammability (solid, gas) No data available Vapor pressure < 0.1 hPa (20 °C) Relative vapor density at 20 °C No data available Relative density 2.7 Specific gravity / density 2700 kg/m3 Molecular mass 158.03 g/mol Solubility Moderately soluble in water. Substance sinks in water. Soluble in ethanol. Soluble in methanol. Soluble in acetone. Soluble in acetic acid. Soluble in sulfuric acid. Soluble in pyridine. Water: 6.4 g/100mI Log Pow -1.73 (Estimated value) Auto -ignition temperature Not applicable Decomposition temperature > 240 °C Viscosity, kinematic No data available Viscosity, dynamic No data available Explosion limits No data available Explosive properties No data available Oxidizing properties May intensify fire; oxidiser. 9.2. Other information Minimum ignition energy Not applicable SADT Not applicable VOC content Not applicable Other properties Opaque. Substance has basic reaction. 10.1. Reactivity Decomposes on exposure to temperature rise: oxidation which increases fire hazard. Reacts with combustible materials: risk of spontaneous ignition. Violent to explosive reaction with (some) acids: release of toxic and corrosive gases/vapours. Reacts violently with many compounds e.g.: with organic material and with (strong) reducers. With (some) metals. With (increased) risk of fire/explosion. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions Reacts exothermically with combustible materials: (increased) risk of fire. 10.4. Conditions to avoid Incompatible materials. Potassium Permanganate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 10.5. Incompatible materials Strong reducing agents. Organic compounds. combustible materials. metals. 10.6. Hazardous decomposition products manganese. 11.1. Information on toxicological effects Likely routes of exposure Skin and eye contact; Inhalation Acute toxicity Oral: Harmful if swallowed. Potassium Permanganate (7722-64-7) LD50 oral rat 1090 mg/kg (Rat) ATE US (oral) 1090 mg/kg body weight Skin corrosion/irritation Not classified pH: 7.0 - 8.5 (1.6 %) Serious eye damage/irritation Not classified pH: 7.0 - 8.5 (1.6 %) Respiratory or skin sensitization Not classified Germ cell mutagenicity Not classified Carcinogenicity Not classified Reproductive toxicity Not classified Specific target organ toxicity — single exposure Not classified Specific target organ toxicity — repeated Not classified exposure Aspiration hazard Not classified Symptoms/effects after inhalation AFTER INHALATION OF DUST: Dry/sore throat. Coughing. Irritation of the respiratory tract. Irritation of the nasal mucous membranes. EXPOSURE TO HIGH CONCENTRATIONS: Respiratory difficulties. FOLLOWING SYMPTOMS MAY APPEAR LATER: Risk of lung edema. Symptoms/effects after skin contact Tingling/irritation of the skin. May stain the skin. ON CONTINUOUS EXPOSURE/CONTACT: Caustic burns/corrosion of the skin. Symptoms/effects after eye contact Corrosion of the eye tissue. Inflammation/damage of the eye tissue. ON CONTINUOUS EXPOSURE/CONTACT: Permanent eye damage. Symptoms/effects after ingestion Nausea. Vomiting. Diarrhoea. Irritation of the gastric/intestinal mucosa. AFTER ABSORPTION OF LARGE QUANTITIES: Possible esophageal perforation. Shock. Slowing heart action. Low arterial pressure. Possible laryngeal spasm/oedema. Respiratory difficulties. Chronic symptoms ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Respiratory difficulties. Impairment of the nervous system. Movement disturbances. Coordination disorders. Myasthenia. Tremor. Paralysis. Cramps/uncontrolled muscular contractions. Impaired memory. Emotional instability. 12.1. Toxicity Ecology - general Dangerous for the environment. Ecology - air Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). TA-Luft Klasse 5.2.2/III. Ecology - water Severe water pollutant (surface water). Ground water pollutant. Toxic to fishes. Very toxic to invertebrates (Daphnia). Potassium Permanganate (7722-64-7) IL EC50 Daphnia 1 0.235 mg/I (EC50; 24 h) LC50 fish 2 1.22 mg/I (LC50; 96 h) Threshold limit algae 1 10 mg/I (EC50; 4 h) 12.2. Persistence and degradability Potassium Permanganate (7722-64-7) Persistence and degradability Biodegradability: not applicable. Biochemical oxygen demand (BOD) Not applicable 01 Potassium Permanganate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Potassium Permanganate (7722-64-7) Chemical oxygen demand (COD) Not applicable ThOD Not applicable 12.3. Bioaccumulative potential Potassium Permanganate (7722-64-7) Log Pow -1.73 (Estimated value) Bioaccumulative potential Bioaccumulation: not applicable. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available 13.1. Disposal methods Waste disposal recommendations Additional information Department of Transportation (DOT) In accordance with DOT Transport document description UN-No.(DOT) Proper Shipping Name (DOT) Transport hazard class(es) (DOT) Packing group (DOT) Hazard labels (DOT) Dangerous for the environment Marine pollutant DOT Packaging Non Bulk (49 CFR 173.xxx) DOT Packaging Bulk (49 CFR 173.xxx) Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Recycle/reuse. Immobilize the toxic or harmful components. Remove to an authorized dump (Class 1). LWCA (the Netherlands): KGA category 06. Hazardous waste according to Directive 2008/98/EC. UN1490 Potassium permanganate, 5.1, II U N 1490 Potassium permanganate 5.1 - Class 5.1 - Oxidizer 49 CFR 173.128 II - Medium Danger 5.1 - Oxidizer OXI R 5] Yes Yes ,y r° 212 240 7 Potassium Permanganate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations DOT Special Provisions (49 CFR 172.102) 1B8 - Authorized IBCs: Metal (11 A, 11 B, 11 IN, 21 A, 21 B, 21 N, 31 A, 31 B and 31 N); Rigid plastics (11 H1, 11 H2, 21 H1, 21 H2, 31 H1 and 31 H2); Composite (11 HZi , 11 HZ2, 21 HZi , 21 HZ2, 31 HZi and 31 HZ2); Fiberboard (11 G); Wooden (11 C, 11 D and 11 F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). IP2 - When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. IP4 - Flexible, fiberboard or wooden IBCs must be sift -proof and water-resistant or be fitted with a sift -proof and water-resistant liner. T3 - 2.65 178.274(d)(2) Normal ............. 178.275(d)(2) TP33 - The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure -relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter. DOT Packaging Exceptions (49 CFR 173.xxx) 152 DOT Quantity Limitations Passenger aircraft/rail 5 kg (49 CFR 173.27) DOT Quantity Limitations Cargo aircraft only (49 25 kg CFR 175.75) DOT Vessel Stowage Location D - The material must be stowed "on deck only" on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers or one passenger per each 3 m of overall vessel length, but the material is prohibited on passenger vessels in which the limiting number of passengers is exceeded. DOT Vessel Stowage Other 56 - Stow "separated from" ammonium compounds,58 - Stow "separated from" cyanides Other information No supplementary information available. 15.1. US Federal regulations ` Potassium Permanganate (7722-64-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory Subject to reporting requirements of United States SARA Section 313 RQ (Reportable quantity, section 304 of EPA's List of Lists) 100 Ib SARA Section 311/312 Hazard Classes Reactive hazard All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. Potassium Permanganate CAS -No. 7722-64-7 100% 15.2. International regulations CANADA Potassium Permanganate (7722-64-7) Listed on the Canadian DSL (Domestic Substances List) EU-Regulatlons No additional information available National regulations Potassium Permanganate (7722-64-7) Listed on the Canadian IDL (Ingredient Disclosure List) 15.3. US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm M Potassium Permanganate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date : 02/13/2018 Full text of H-phrases: see section 16: H272 May intensify fire; oxidizer H302 Harmful if swallowed H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects NFPA health hazard NFPA fire hazard NFPA reactivity NFPA specific hazard Hazard Rating Health Flammability Physical Personal protection SDS US Dawnsci 1 - Materials that, under emergency conditions, can cause significant irritation. 0 - Materials that will not burn under typical dire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. 0 - Material that in themselves are normally stable, even under fire conditions. OX - Materials that posses oxidizing properties 1 Slight Hazard - Irritation or minor reversible injury possible 0 Minimal Hazard - Materials that will not burn 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self -react. Non -Explosives. F F - Safety glasses, Gloves, Synthetic apron, Dust respirator Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and dawnsci assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. 9 TABLES TABLE 1: MONITORING WELL CONSTRUCTION DETAILS Monitoring Well Date Constructed Total Depth (feet bgs) Screened Interval (feet bgs) Top of Casing Elevation (100'Datum) Date Water Level Measured Depth to Groundwater (feet TOC) Groundwater Elevation (100' Datum) MW-1 09/01/98 27.37 12.37 - 27.37 94.42 09/15/22 16.92 77.50 DW-2 10/01/98 43.34 38.34 - 43.34 94.09 09/15/22 16.26 77.83 MW-3 09/01/98 22.32 12.32 - 22.32 98.17 09/15/22 18.93 79.24 MW-4 09/01/98 18.65 8.65 - 18.65 91.38 09/15/22 17.30 74.08 MW-5 09/01/98 25.11 15.11 - 25.11 87.07 09/15/22 14.93 72.14 MW-6R 03/04/04 34.40 14.40 - 34.40 91.55 09/15/22 22.22 69.33 MW-7 11/01/98 26.56 11.56 - 26.56 86.81 09/15/22 22.16 64.65 MW-8 11/01/98 26.70 16.70 - 26.70 89.25 09/15/22 21.38 67.87 MW-9 03/01/99 24.41 9.41 - 24.41 94.24 09/15/22 17.00 77.24 MW-10 03/01/99 29.52 14.52 - 29.52 94.09 09/15/22 19.42 74.67 MW-11 05/01/99 24.12 9.12 - 24.12 94.31 09/15/22 18.41 75.90 MW-12 05/01/99 25.70 5.70 - 25.70 94.28 09/15/22 17.68 76.60 MW-13 06/01/99 33.46 8.46 - 33.46 94.22 09/15/22 20.91 73.31 DW-16 10/05/05 35.00 30.00 - 35.00 93.89 09/15/22 19.32 74.57 DW-19 12/05/05 54.80 49.80 - 54.80 87.46 09/15/22 19.01 68.45 BW-20 01/12/12 74.79 69.79 - 74.79 87.46 09/15/22 18.80 68.66 BW-21 01/12/12 63.49 58.49 - 63.49 94.09 09/15/22 17.25 76.84 BW-22 10/17/12 100.30 95.30 - 100.30 j 87.46 j 09/15/22 j 14.26 j 73.20 Notes: feet bgs = Feet below ground surface feet TOC = Feet below top of well casing 100' Datum = Well casings were surveyed to an arbitrary 100 foot Datum. The benchmark is the center of the manhole cover at the south end of Viceroy Street. MW-6, MW-14, MW-15, DW-17, and DW-18 were converted to injection wells IW-12, IW-10, IW-11, IW-15, and IW-16 respectively. 11.990015.00 © 2022 EnviroTrac October 2022 TABLE 2: INJECTION WELL CONSTRUCTION DETAILS Injection Well Total Depth (feet bgs) Screened Injected Interval Date 3DMe (gallons) Water (gallons) Interval feet bgs) 1W-1 24.5 19.5 - 24.5 9/27/10 - 10/8/10 18 432 IW-2 28.0 18.0 - 28.0 9/23/10 - 9/30/10 18 422 IW-3 29.0 19.0 - 29.0 9/14/10 - 9/24/10 18 397 IW-4 27.2 17.2 - 27.2 9/14/10 - 9/24/10 18 382 IW-5 24.5 19.5 - 24.5 9/14/10 - 9/24/10 18 423 IW-6 28.2 18.2 - 28.2 9/9/10 - 9/13/10 18 382 IW-7 34.0 19.0 - 34.0 9/9/10 - 9/13/10 18 397 IW-8 35.0 20.0 - 35.0 9/23/10 - 9/27/10 18 527 1W-9 35.0 20.0 - 35.0 9/27/10 - 9/29/10 18 432 IW-10 30.7 10.7 - 30.7 --- --- --- IW-11 37.0 17.0 - 37.0 9/14/10 - 9/24/10 27 473 IW-12 24.9 14.9 - 24.9 9/7/10 - 9/9/10 18 460 1W-13 25.0 20.0 - 25.0 9/7/10 - 9/9/10 34 605 IW-14 30.0 20.0 - 30.0 9/9/10 - 9/13/10 27 593 1W-15 26.5 21.5 - 26.5 9/23/10 - 9/28/10 18 407 IW-16 32.5 27.5 - 32.5 9/7/10 - 9/9/10 18 407 feet bgs = Feet below ground surface 11.990015.00 © 2022 EnviroTrac October 2022 FIGURES SARA LIN - o a 83JRLWDEfi1 rf qi a a-1�--i ji m r SAtwood 1 � •� .: � m i , i����;k ° . o a�£� r may]- 11' f 4` .� gp-j J IRIt•NF Df�gliE RD �� �-� :..� ,.... SKEAD �, _ _. GRIFF11TH-PLAtD ARMSTRDNs BLVD JJ7 -_ L , \� �.� v SALEM'CREEK RD - I f .. , �y . ., Atwood --Acres 1!`�CLE 4 +tffr}S.4E�- Z .��-• f �� -� -i_ _ �Y ��d �_� �'^..I� 1�f�. rJC'3_-_-. _Muddy Creek - � p� � • �. - �--� �! r ,�--���f�_��/r- „s'' !,' _�'� � 'U �r:,-_� '! ll It � _ - F HALL CIV' ' J '.�; -�/ _ ': j��� _ _ •��; '-,, ;`j ice!%' __ - Is 7 - ti' y f F--fVANS RD ��'' � J •f � l Y IJI a ��.` � j cif i�_� ��_j"�.�� ��� tS�� � � � ��E {�' a o� r�� { � `", }f- 1��./ � R � 1 '``ll f� ,_ ti4�ti.1�`i� ��_���, :�__� �:-��1 \� ` l\,_—•`!'�11 � } � � m v � '�' -�5 �� _����' f -`�i- `s � •: �_ J % /F� �I ,L] . _ .� _ _`' J(^_ , � tom(-- t�.�'t.•.,.. _ �- ___—` 5 `• \-t\.- . -'•i_..-- ;•�fr�r,s���S E�� Ir<.��1,�..ij:':�f1! cV S�t`-�1 Ii-' ��-:1 ��Sr'��=�/�'.-_. �—���t�_�= ��`—:.��� f71n1 n 1,000 0 2,000 SOURCE: USGS.GOV, 7.5 MINUTE SERIES MAP, WINSTON-SALEM WEST QUADRANGLE APPROXIMATE SCALE s FIGURE 1 SITE VICINITY MAP y nvro Rotork/Fairchild Industrial Products Company L €nvjruexnental f`,yj 3920 Westpoint Boulevard Winston-Salem, North Carolina i i 7343 W. FRIENDLY AVENUE, SUITE J REVISED BY: GGH DRAWN BY: AB APPROVED BY: SCALE: AS SHOWN GREENSBORO, NORTH CAROLINA DATE: 03/30/16 DATE: 03/20/15 CWH PROJECT NO: 11.990015.00 ■ rl A LEGEND APPROXIMATE PROPERTY BOUNDARY ii J SOURCE USGS. GOV, 7.5 MINUTE SERIES MAP, WINSTON-SALEM WEST QUADRANGLE 40 0 40 80 APPROXIMATE SCALE nviro ra Environmental Services 7343 W. FRIENDLY AVENUE, SUITE J GREENSBORO, NORTH CAROLINA FIGURE 2 SITE MAP Rotork/Fairchild Industrial Products Company 3920 Westpoint Boulevard Winston-Salem, North Carolina REVISED BY: AB DRAWN BY: AB APPROVED BY: SCALE: AS SHOWN DATE:02/07/23 DATE:09/11/15 CWH PROJECT NO: 11.990015.00 ANNAPOLIS DRIVE 30 0 30 60 APPROXIMATE SCALE nviro ra Environmental Services APPROXIMATE PROPERTY BOUNDARY BELOW BEDROCK MONITORING WELL LOCATION FIGURE 3 INJECTION ZONE WELLS Rotork/Fairchild Industrial Products Company 3920 Westpoint Boulevard Winston-Salem. North Carolina 7343 W. FRIENDLY AVENUE, SUITE 1 GREENSBORO, NORTH CAROLINA REVISED BY: AB DRAWN BY: AB APPROVED BY: DATE: I I DATE:09/11/15 CWH SCALE: AS SHOWN PROJECT NO: 11.990015.00 ——x—x---- — — — 75 MW- 74.08 a� 70 n rn 3 67 L of C m L LO a� 0 C m 5 a `o m a m ri n n 72.14 c DW-19 MW-61 68.45� 69.33 3 B W-20 68.66 BW-22 73.20 — — — _! tzwz B/W-21 -2 76.84 IDW 77.83 MW-1 77.50 Y MW-9 77.24 DW-16 74.57 VIW-10 74.67 *MW-12 76.60 IT7 ISTING B ING 75 MWM1W-8 I 67.87 L— ANNAPOLIS DRIVE 80 VICEROY MW-3 79.24 80 30 0 30 60 APPROXIMATE SCALE nviro ra Environmental Services 7343 W. FRIENDLY AVENUE, SUITE GREENSBORO, NORTH CAROLINA LEGEND APPROXIMATE PROPERTY BOUNDARY MW-1 MONITORING WELL LOCATION WITH 78.58 GROUNDWATER ELEVATION p DW-2 DEEP MONITORING WELL LOCATION BW-20 BEDROCK MONITORING WELL LOCATION GROUNDWATER POTENTIOMETRIC LINE 0.00 NOTES: DEEP WELLS AND MW-5 WERE NOT INCLUDED IN THE SHALLOW GROUNDWATER MAP. GROUNDWATER ELEVATIONS WERE RECORDED SEPTEMBER 15, 2022. FIGURE S SHALLOW GROUNDWATER MAP (September 15, 2022) Rotork/Fairchild Industrial Products Company 3920 Westpoint Boulevard Winston-Salem, North Carolina REVISED BY: AB DRAWN BY: AB APPROVED BY: SCALE: AS SHOWN DATE:10/03/22 DATE:09/11/15 CWH PROJECT NO: 11.990015.00 41, MW-4 NS {� 'BMW-11 BDL VICEROY DRIVE —.._..—..—.. BDL MW-35 .FC NS INS BW-22 1 . 4. � BDLMw_ Y MW-9 BDL DW-16 139 W-10 BDL MW-12 NS AW-13 Y BDL EXISTING BUILDING DW-19 14.9 MW-6 g c x- Bw-zo i NS D BW-22 c 2 ca BDL BDLJ in m _rn 0 c 2 m I 00 o. o MW-7 D BDL m m MW-8 54.0 Cn 0 nI �__ ANNAPOLIS DRIVE r 30 0 30 60 U APPROXIMATE SCALE nviro ra Environmental Services 7343 W. FRIENDLY AVENUE, SUITE J GREENSBORO, NORTH CAROLINA LEGEND APPROXIMATE PROPERTY BOUNDARY MONITORING WELL LOCATION WITH MW-1 TETRACHLOROETHENE CONCENTRATIONS (ug/L) 0 DW-2 DEEP MONITORING WELL LOCATION BW-20 BELOW BEDROCK MONITORING WELL LOCATION TETRACHLOROETHENE ISOCONCENTRATION LINE BDL BELOW DETECTION LIMITS NS NOT SAMPLED NOTE: GROUNDWATER SAMPLES COLLECTED SEPTEMBER 15, 2022 FIGURE 6 TETRACHLOROETHENE ISOCONCENTRATION MAP Rotork/Fairchild Industrial Products Company 3920 Westpoint Boulevard Winston-Salem, North Carolina REVISED BY: AB DRAWN BY: AB APPROVED BY: SCALE: AS SHOWN DATE:10/03/22 DATE:09/11/15 CWH PROJECT N0: 11.990015.00 ANNAPOLIS DRIVE 0 15 30 45 60 SCALE IN FEET APPROXIMATE PROPERTY BOUNDARY BELOW BEDROCK MONITORING WELL LOCATION ENVIROTRAC - 7343 W. FRIENDLY AVE., SUITE J.1 GREENSBORO, NC 274101 PH: (336) 763-6025 1 FAX: (336) 763-6034 1 www.envirotrac.com A 94 4- MW-7 IP-49 84 74 64 ALL BDL 54 44 34 24 14 U L L O_ O 4 m LEGEND = KMn04 INJECTION LOCATION 2 FFE = FINISHED FLOOR ELEVATION PCE = TETRACHLOROETHENE TCE = TRICHLOROETHENE MC = METHYLENE CHLORIDE -6 3 TRANS-1,2-DCE = TRANS-1,2-DICHLOROETHENE n CIS-1,2-DCE = CIS-1,2-DICHLOROETHENE VC = VINYL CHLORIDE BDL = BELOW DETECTION LIMITS C5 * = GREATER THAN 2L STANDARDS 0 i NOTES -16 > CONCENTRATIONS BASED ON SEPTEMPER 2022 DATA; REPORTED IN ii MICROGRAMS PER LITER. BASED ON DRAWING FROM KLEINFELDER REMEDIAL INVESTIGATION L REPORT. 2 FFE = 94.4 MW-13 M W-6 R I W-9 I W-8 A6 BE-20 2 ��\\DW- IP-1K DW-19 PCE - 14.9* TCE - 1.1 BW-22 ALL BDL SILTY FINE TO MEDIUM SAND _^' 3MW ^11 A, DW-16 0 pQ, �BW-21 MW-10 \-%" IP-31P-31-9� IP-22411P- 1/ GRO WATER VC - 26.6* TOLUENE-1.5 CIS-1,2-DCE - 46.5 VC - 443` PCE - 139` TCE - 70.1 ` TRANS-I,2-DCE - 12 CIS-1,2-DCE - 625' VC - 94.6` CE-3.6* MC-148' TCE - 5.2` CIS-1,2-DCE-11.2 BEDROCK SURFACE VC - 17.8* TCE - 27.1 * TRANS-I,2-DCE - 38.1 CIS-1,2-DCE-1,140* _ VC-817* LIMITS OF CONTAMINATION EXCEEDING 2L STANDARDS SAMPLED TRANS-I,2-DCE - 4.9 CIS-1,2-DCE - 27.9 VC - 192* PCE - 2.5* TCE - 1.1 ALL ANALYTES BDL BW-21 NOT SAMPLED 0 35 70 HORIZONTAL SCALE IN FEET nv ro ra (APPROXIMATE) VERTICAL SCALE: 1"=12.5 Environmental Services 7343 W. FRIENDLY AVENUE, SUITE J GREENSBORO, NORTH CAROLINA PHONE: 336-763-6025 FIGURE 8 CROSS SECTION A -A' Rotork / Fairchild Industrial Products Company 3920 Westpoint Boulevard Winston-Salem, North Carolina REVISED: 08/01/2023 APPROVED BY: SCALE: AS SHOWN CWH DRAWN BY: AB PROJECT NO: 11.990015.00 ENVIROTRAC - 7343 W. FRIENDLY AVE., SUITE J I GREENSBORO, NC 27410 1 PH: (336) 763-6025 1 FAX: (336) 763-6034 1 www.envirotrac.com VA 84 74 64 54 E iu L 44 r_I 34 LL m I LEGEND @ = KMn04 INJECTION LOCATION FFE = FINISHED FLOOR ELEVATION ai PCE = TETRACHLOROETHENE 2 TCE = TRICHLOROETHENE MC = METHYLENE CHLORIDE 6 TRANS-1,2-DCE = TRANS-1,2-DICHLOROETHENE CIS-1,2-DCE = CIS-1,2-DICHLOROETHENE n VC = VINYL CHLORIDE BDL = BELOW DETECTION LIMITS * = GREATER THAN 2L STANDARDS ;I NOTES > CONCENTRATIONS BASED ON SEPTEMBER 2022 DATA; REPORTED IN ii MICROGRAMS PER LITER. BASED ON DRAWING FROM KLEINFELDER REMEDIAL INVESTIGATION L REPORT. 2 ktk M W-3 Bf 0 30 60 HORIZAPPROXIMA E) nv ro ra (APPROXIMATE) VERTICALSCALE: 1"=10' Environmental Services 7343 W. FRIENDLY AVENUE, SUITE J GREENSBORO, NORTH CAROLINA PHONE: 336-763-6025 FIGURE 9 CROSS SECTION B-B' Rotork / Fairchild Industrial Products Company 3920 Westpoint Boulevard Winston-Salem, North Carolina REVISED: 08/01/2023 APPROVED BY: SCALE: AS SHOWN CWH DRAWN BY: AB PROJECT NO: 11.990015.00 ENVIROTRAC - 7343 W. FRIENDLY AVE., SUITE J I GREENSBORO, NC 27410 1 PH: (336) 763-6025 1 FAX: (336) 763-6034 1 www.envirotrac.com CAD FILE: W:\Projects\11.990015.00 Ares Capital Corp Fairchild\Figures\Fairchild_Figures - UIC Permit KMN04.dwg C C1 97 87 77 67 57 47 37 27 17 7 -3 -13 LEGEND = KMn04 INJECTION LOCATION FFE = FINISHED FLOOR ELEVATION PCE = TETRACHLOROETHENE TICE = TRICHLOROETHENE MC = METHYLENE CHLORIDE TRANS-1,2-DCE = TRANS-1,2-DICHLOROETHENE CIS-1,2-DCE = CIS-1,2-DICHLOROETHENE VC = VINYL CHLORIDE BDL = BELOW DETECTION LIMITS * = GREATER THAN 2L STANDARDS NOTES CONCENTRATIONS BASED ON SEPTEMBER 2022 DATA; REPORTED IN MICROGRAMS PER LITER. BASED ON DRAWING FROM KLEINFELDER REMEDIAL INVESTIGATION REPORT. FIGURE 10 0 25 50 CROSS SECTION C-C' HORIZONTAL SCALE nviro ra E)FEET (APPROXIMATE) Rotork /Fairchild Industrial Products Company VERTICAL SCALE: 1"=10' Environmental Services 3920 Westpoint Boulevard Winston-Salem, North Carolina 7343 W. FRIENDLYAVENUE, SUITE J REVISED: 08/01/2023 APPROVED BY: SCALE: AS SHOWN GREENSBORO, NORTH CAROLINA CWH PHONE: 336-763-6025 DRAWN BY: AB PROJECT NO: 11.990015.00 BW-20 DW-19 MW-6R � BW-22 \� I P-46 M W-8 M W-5 I P-47 SILTY FINE TO MEDIUM SAND GROUND — ATER — PCE -sa.o` TCE - 8.2` CIS-1,2-DCE-24.7 CE-3.6` CE=5.2` IS-1,2-DCE-11.2 V C - 17.8` � Rork— '�OF LIMITS OF CONTAMINATIONS EXCEEDING 2L STANDARDS DW-19 PCE - 14.9' TCE - 1.1 ALL BDL