NC0024911_Renewal (Application)_20150508

I
Qo�\.0,,N SEWFAgCI �o
Qo 1
I 3"4_
• RECEIVED/DENR/DWR
m ,. Q
Gy0O '.-
k .: Qor MAY 8 2015
1 4fB -
F
-ouNrr, 1400' Water Quality
Permitting Section
1
1
Metropolitan Sewerage District
I
of Buncombe County
I
IFrench Broad River Water Reclamation Facility
NPDES Permit # NC0024911
I
I - --- - ' - , .
-'7.1--f�, -.Is `fir,,,
f.
: ex _
h
i '• ..:vii,%,-0 go
1 Renew Application Submittal
I

t
6
50,N SEWER 4C
FQ Metropolitan Sewerage District
Buncombe County, North Carolina
111 0UU,I h.
RECEIVED/p
NC-DENR/DWQ/Point Source Branch May 5, 2015 ENR/pwR
1617 Mail Service Center MAY 8 2015
Raleigh,NC 27699-1617
Attention: Mr.Tom Belnick
' Water Quality
Re: NPDES Permit#NC0024911 Renewal Application Submittal Permitting Section
' Mr. Belnick:
Enclosed herewith is the subject NPDES permit renewal application for the Metropolitan
Sewerage District of Buncombe County,North Carolina (MSD)-French Broad River Water
Reclamation Facility. MSD owns/operates the subject reclamation facility located at 2225
Riverside Drive,Asheville,NC 28804. The facility is a 40 MGD plant that incorporates a secondary
treatment,fixed film design. The current permit expires on December 31,2015 and MSD does
' hereby request renewal with this application submittal. Enclosed with the application is all of the
requested supportive documentation.
Also included in this submittal is an Ammonia Reduction Evaluation required under Special
Condition A of the 2011 NPDES Permit.Submittal of this evaluation is required within 4.5 years of
the current permit effective date of April 1,2011. This report presents an evaluation of existing
treatment plant performance data,including extensive intra-process data.Based on those
findings HDR Consulting has provided recommendations for optimizing ammonia removal
through both operational refinements and capital improvements to be constructed over the next
several years.Please note that the attached material identifies options for a comprehensive,step-
wise process to address a full range of issues at our Water Reclamation Facility. MSD will be
incorporating these projects into its Capital Improvement Plan (CIP) in a phased approach so as
to maintain treatment throughout the period necessary to accomplish needed plant
improvements. As I'm sure you understand,maintaining protection of the water quality in the
' French Broad is a primary objective. MSD will continue to do that by undertaking first the most
critical system improvements,careful management and maintenance of MSD existing facilities,
and a carefully planned total CIP program.
MSD is keenly aware of the role the NPDES permitting program plays in this effort. MSD would
request the opportunity to review and discuss a preliminary draft renewal permit before DWR
finalizes the draft for public notice.Please notify me when DWR gets to the preliminary draft
' stage to arrange a review and a meeting. Certainly we are available to answer any questions you
or your staff may have concerning our renewal application.
' If there is any additional information needed to proceed with processing this renewal request,
please do not hesitate to contact Peter Weed at 828-225-8204.
Sincerely,
j2 � . 61 /-
' Thomas E.Hartye,PE%
General Manager
cc: Peter Weed-Director,Water Reclamation
2028 Riverside Drive,Asheville,North Carolina 28804
[phone] website:www.msdbc.org

I
I
NPDES Application
1 2 Facility Description
} r— Effluent DMR's and
�
v- Summary Metals
I
U 0 � Expanded Efluent
I
� V 4 Testing Data (PPA)
Z Toxicity Reports
E
i o
I V �— Significant Industrial
� � 6 Users
I m � Pretreatment Annual
1 0 LU 7 Report - 2014
CI Q Pretreatment Performance
I * Z $ Summary - 2011 thru 2013
1 9 CERCLA Sites
I Ammonia Reduction
1 10 Evaluation
I

r
r

i
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911. MSD — French Broad River WRF Renewal French Broad
FORM
2A NPDES FORM 2A APPLICATION OVERVIEW
NPDES
APPLICATION OVERVIEW
IForm 2A has been developed in a modular format and consists of a "Basic Application Information" packet
and a "Supplemental Application Information" packet. The Basic Application Information packet is divided
into two parts. All applicants must complete Parts A and C. Applicants with a design flow greater than or
equal to 0.1 mgd must also complete Part B. Some applicants must also complete the Supplemental
Application Information packet. The following items explain which parts of Form 2A you must complete.
iBASIC APPLICATION INFORMATION:
A. Basic Application Information for all Applicants. All applicants must complete questions A.1 through A.8. A treatment works
that discharges effluent to surface waters of the United States must also answer questions A.9 through A.12.
IB. Additional Application Information for Applicants with a Design Flow>_0.1 mgd. All treatment works that have design flows
greater than or equal to 0.1 million gallons per day must complete questions B.1 through B.6.
C. Certification. All applicants must complete Part C (Certification).
SUPPLEMENTAL APPLICATION INFORMATION:
ID. Expanded Effluent Testing Data. A treatment works that discharges effluent to surface waters of the United States and meets
one or more of the following criteria must complete Part D(Expanded Effluent Testing Data):
I 1. Has a design flow rate greater than or equal to 1 mgd,
2. Is required to have a pretreatment program (or has one in place), or
3. Is otherwise required by the permitting authority to provide the information.
IE. Toxicity Testing Data. A treatment works that meets one or more of the following criteria must complete Part E (Toxicity Testing
Data):
1. Has a design flow rate greater than or equal to 1 mgd,
2. Is required to have a pretreatment program (or has one in place), or
3. Is otherwise required by the permitting authority to submit results of toxicity testing.
I F. Industrial User Discharges and RCRA/CERCLA Wastes. A treatment works that accepts process wastewater from any
significant industrial users(SIUs)or receives RCRA or CERCLA wastes must complete Part F(Industrial User Discharges
and RCRA/CERCLA Wastes). SlUs are defined as:
I 1. All industrial users subject to Categorical Pretreatment Standards under 40 Code of Federal Regulations(CFR)403.6 and
40 CFR Chapter I, Subchapter N(see instructions); and
2. Any other industrial user that
1 a. Discharges an average of 25,000 gallons per day or more of process wastewater to the treatment works(with certain
exclusions); or
b. Contributes a process wastestream that makes up 5 percent or more of the average dry weather hydraulic or organic
I capacity of the treatment plant;or
c. Is designated as an SIU by the control authority.
I G. Combined Sewer Systems. A treatment works that has a combined sewer system must complete Part G (Combined Sewer
Systems).
ALL APPLICANTS MUST COMPLETE PART C (CERTIFICATION)
IEPA Form 3510-2A(Rev. 1-99). Replaces EPA forms 7550-6&7550-22. Page 1 of 22

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD—French Broad River WRF Renewal French Broad
BASIC APPLICATION INFORMATION
PART A.BASIC APPLICATION INFORMATION FOR ALL APPLICANTS: '
All treatment works must complete questions A.1 through A.8 of this Basic Application Information Packet
A.1. Facility Information.
Facility Name MSD— French Broad River WRF
Mailing Address MSD of Buncombe County
2028 Riverside Drive.Asheville.NC 28804
Contact Person Peter Weed111
Title Director of Treatment and Maintenance.MSD
Telephone Number [phone]
111
Facility Address 2225 Riverside Drive
(not P.O.Box) Woodfin,NC
A.2. Applicant Information. If the applicant is different from the above,provide the following:
Applicant Name Peter Weed
Mailing Address MSD of Buncombe County
2028 Riverside Drive.Asheville,NC 28804
Contact Person Peter Weed
Title Director of Treatment and Maintenance.MSD
Telephone Number [phone]
Is the applicant the owner or operator(or both)of the treatment works?
0 owner ]operator
Indicate whether correspondence regarding this permit should be directed to the facility or the applicant.
® facility 0 applicant
A.3. Existing Environmental Permits. Provide the permit number of any existing environmental permits that have been issued to the treatment works
(include state-issued permits).
NPDES NC0024911 AIR WNCRAQA#11-0772-14A
UIC Other WQ0007174—Nutri-Lime
RCRA Other WQCS00004-Collections
A.4. Collection System Information. Provide information on municipalities and areas served by the facility. Provide the name and population of each
entity and,if known,provide information on the type of collection system(combined vs.separate)and its ownership(municipal,private,etc.).
Name Population Served Type of Collection System Ownership
MSD—Service Area —125.000 Sanitary Sewer MSD
Total population served —125.000
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 2 of 22

I
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
INC0024911, MSD— French Broad River WRF Renewal French Broad
A.S. Indian Country.
Ia. Is the treatment works located in Indian Country?
❑ Yes ® No
I b. Does the treatment works discharge to a receiving water that is either in Indian Country or that is upstream from(and eventually flows
through)Indian Country?
❑ Yes ® No
I A.6. Flow. Indicate the design flow rate of the treatment plant(i.e.,the wastewater flow rate that the plant was built to handle). Also provide the
average daily flow rate and maximum daily flow rate for each of the last three years. Each year's data must be based on a 12-month time period
with the 12th month of"this year"occurring no more than three months prior to this application submittal.
I a. Design flow rate 40 mgd
Two Years Mo Last Year This Year
b. Annual average daily flow rate 19.2 MGD In 2012 24.9 MGD in 2013 20.3 MGD in 2014
Ic. Maximum daily flow rate 50.2 MGD 74.6 MGD 58.3 MGD
A.7. Collection System. Indicate the type(s)of collection system(s)used by the treatment plant. Check all that apply. Also estimate the percent
I contribution(by miles)of each.
® Separate sanitary sewer 100 %
0 Combined storm and sanitary sewer %
IA.8. Discharges and Other Disposal Methods.
a. Does the treatment works discharge effluent to waters of the U.S.? ® Yes 0 No
IIf yes,list how many of each of the following types of discharge points the treatment works uses:
i. Discharges of treated effluent one(11
IIIii. Discharges of untreated or partially treated effluent N/A
iii. Combined sewer overflow points N/A
Iiv. Constructed emergency overflows(prior to the headworks) N/A
v. Other N/A
I b. Does the treatment works discharge effluent to basins,ponds,or other surface impoundments
that do not have outlets for discharge to waters of the U.S.? 0 Yes ® No
If yes,provide the following for each surface imooundment:
ILocation: N/A
Annual average daily volume discharge to surface impoundment(s) - mgd
IIs discharge 0 continuous or 0 intermittent?
c. Does the treatment works land-apply treated wastewater? 0 Yes ®No
IIf yes,provide the following for each land application site:
Location: NIA
INumber of acres:
Annual average daily volume applied to site: - mgd
I Is land application 0 continuous or 0 intermittent?
d. Does the treatment works discharge or transport treated or untreated wastewater to another
treatment works? 0 Yes ® No
IEPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 3 of 22

I
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD—French Broad River WRF Renewal French Broad
If yes,describe the mean(s)by which the wastewater from the treatment works is discharged or transported to the other treatment works
(e.g.,tank truck,pipe).
i
If transport is by a party other than the applicant,provide:
Transporter Name N/A
Mailing Address
I
Contact Person
Title
Telephone Number (
For each treatment works that receives this discharge,provide the following:
Name N/A
Mailing Address
Contact Person
Title I
Telephone Number (
If known,provide the NPDES permit number of the treatment works that receives this discharge
Provide the average daily flow rate from the treatment works into the receiving facility. mgd
e. Does the treatment works discharge or dispose of its wastewater in a manner not included
in A.8.through A.8.d above(e.g.,underground percolation,well injection): 0 Yes ® No
If yes,provide the following for each disoosal method:
Description of method(including location and size of site(s)if applicable): I
N/A
Annual daily volume disposed by this method:
Is disposal through this method ❑ continuous or 0 intermittent?
I
1
1
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 4 of 22

I
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
INC0024911, MSD— French Broad River WRF Renewal French Broad
WASTEWATER DISCHARGES:
I If you answered"Yes"to auestion A.8.a,complete questions A.9 throuah A.12 once for each outfall(including bypass points)through
which effluent Is discharged. Do not Include Information on combined sewer overflows In this section. If you answered"No"to auestion
A.!.a,go to Part B,"Additional Application Information for Applicants with a Design Flow Greater than or Equal to 0.1 mgd."
A.9. Description of Outfall.
a. Outfall number 001
I b. Location Asheville.NC(Woodfin is the Dhvsical address/location) 28804
(City or town,if applicable) (Zip Code)
Buncombe County NC
(County) (State)
35 deg..39 min..02 sec. 82 deg..35 min..54 sec.
(Latitude) (Longitude)
c. Distance from shore(if applicable) N/A ft.
Depth below surface(if applicable) N/A ft.
Id.
' e. Average daily flow rate 21.5 MGD(3-year average) mgd
f. Does this outfall have either an intermittent or a periodic discharge?
0 Yes ®No (go to A.9.g.)
If yes,provide the following information:
I Number f times per year discharge occurs: N/A
Average duration of each discharge:
IAverage flow per discharge: mgd
Months in which discharge occurs:
g. Is outfall equipped with a diffuser? 0 Yes ® No
A.10. Description of Receiving Waters.
Ia. Name of receiving water French Broad River
b. Name of watershed(if known) French Broad Watershed
IUnited States Soil Conservation Service 14-digit watershed code(if known): -
c. Name of State Management/River Basin(if known):-
I
United States Geological Survey 8-digit hydrologic cataloging unit code(if known): #06010105
d. Critical low flow of receiving stream(if applicable)
Iacute 373(1Q10) cfs chronic 466(7Q10) cfs
e. Total hardness of receiving stream at critical low flow(if applicable): 15.24(2014 annual average) mg/l of CaCO3
I
I
IEPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 5 of 22

I
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD— French Broad River WRF Renewal French Broad
I
A.11. Description of Treatment
a. What level of treatment are provided? Check all that apply.
I
❑ Primary ® Secondary
® Advanced Q Other. Describe:
b. Indicate the following removal rates(as applicable):
II
Design BOD5 removal or Design CBOD5 removal 88% %
Design SS removal 88% %
I
Design P removal N/A 94
Design N removal N/A °k
Other - -
c. What type of disinfection is used for the effluent from this outfall? If disinfection varies by season,please describe:
Liquid Sodium Hvoochlorite (NaOCI-)
If disinfection is by chlorination is dechlorination used for this outfall? ®Yes 0 No
Does the treatment plant have post aeration? 0 Yes ® No
A.12. Effluent Testing Information. All Applicants that discharge to waters of the US must provide effluent testing data for the following
parameters. Provide the indicated effluent testing required by the permitting authority for each outfall through which effluent Is
discharged. Do not include information on combined sewer overflows in this section. All information reported must be based on data
collected through analysis conducted using 40 CFR Part 136 methods. In addition,this data must comply with QA/QC requirements of
40 CFR Part 136 and other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. At a
minimum,effluent testing data must be based on at least three samples and must be no more than four and one-half years apart.
Outfall number: 001 *see attached Data summaries
MAXIMUM DAILY VALUE AVERAGE DAILY VALUE I
PARAMETER
Value Units Value Units Number of Samples
pH(Minimum) 6.9 s.u. '
pH(Maximum) 7.6 s.u. 4
Flow Rate 74.6 MGD 21.5 MGD 365(x 3 years)
Temperature(Winter) 16.9 Celsius 13.6 Celsius 365(x 3 years)
Temperature(Summer) 26.1 Celsius 21.7 Celsius 365(x 3 years)
'For pH please report a minimum and a maximum daily value
MAXIMUM DAILY AVERAGE DAILY DISCHARGE
DISCHARGE ANALYTICAL
POLLUTANT ML/MDL
Number of METHOD
Conc. Units Conc. Units Samples
CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS
BIOCHEMICAL OXYGEN BOD5 N/A N/A
DEMAND(Report one) CBOD5 47.0 mg/I 12.9 mg/I 260(x 3 years) EPA 405.1 2 mg/I
CoI/100 CoI/100 Std mthd
FECAL COLIFORM
2420ml 7.5 ml 260(x 3 years) 9220 1 col/100 ml
TOTAL SUSPENDED SOLIDS(TSS) 125.0 mg/I 13.7 mg/I 260(x 3 years) EPA 160.2 1 mg/I I
END OF PART A.
REFER TO THE APPLICATION OVERVIEW(PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 6 of 22

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD— French Broad River WRF Renewal French Broad
BASIC APPLICATION INFORMATION
PART B. ADDITIONAL APPLICATION INFORMATION FOR APPLICANTS WITH A DESIGN FLOW GREATER THAN OR
EQUAL TO 0.1 MGD(100,000 gallons per day).
All applicants with a design flow rate z 0.1 mgd must answer questions B.1 through B.6. All others go to Part C(Certification).
B.1. Inflow and Infiltration. Estimate the average number of gallons per day that flow into the treatment works from inflow and/or infiltration.
10.347,000 gpd
Briefly explain any steps underway or planned to minimize inflow and infiltration.
MSD continues to pursue an aggressive sewer rehabilitation program(averaging 50.000 lineal feet per year)as part of the
collection system permit requirement.Annual cost exceed$15 million per year for the next 10 years.
B.2. Topographic Map. Attach to this application a topographic map of the area extending at least one mile beyond facility property boundaries. This
map must show the outline of the facility and the following information. (You may submit more than one map if one map does not show the entire
area.)
a. The area surrounding the treatment plant,including all unit processes.
b. The major pipes or other structures through which wastewater enters the treatment works and the pipes or other structures through which
treated wastewater is discharged from the treatment plant. Include outfalls from bypass piping,if applicable.
c. Each well where wastewater from the treatment plant is injected underground.
d. Wells,springs,other surface water bodies,and drinking water wells that are: 1)within Y.mile of the property boundaries of the treatment
works,and 2)listed in public record or otherwise known to the applicant.
e. Any areas where the sewage sludge produced by the treatment works is stored,treated,or disposed.
f. If the treatment works receives waste that is classified as hazardous under the Resource Conservation and Recovery Act(RCRA)by truck,rail,
or special pipe,show on the map where the hazardous waste enters the treatment works and where it is treated,stored,and/or disposed.
B.3. Process Flow Diagram or Schematic. Provide a diagram showing the processes of the treatment plant,including all bypass piping and all
' backup power sources or redundancy in the system. Also provide a water balance showing all treatment units,including disinfection(e.g.,
chlorination and dechlorination). The water balance must show daily average flow rates at influent and discharge points and approximate daily flow
rates between treatment units. Include a brief narrative description of the diagram.
B.4. Operation/Maintenance Performed by Contractor(s).
Are any operational or maintenance aspects(related to wastewater treatment and effluent quality)of the treatment works the responsibility of a
contractor? 0 Yes ® No
If yes,list the name,address,telephone number,and status of each contractor and describe the contractor's responsibilities(attach additional
pages if necessary).
Name:
Mailing Address:
I
Telephone Number: ( 1
Responsibilities of Contractor:
B.S. Scheduled improvements and Schedules of Implementation. Provide information on any uncompleted implementation schedule or
uncompleted plans for improvements that will affect the wastewater treatment,effluent quality,or design capacity of the treatment works. If the
treatment works has several different implementation schedules or is planning several improvements,submit separate responses to question B.5
for each. (If none,go to question B.6.)
a. List the outfall number(assigned in question A.9)for each outfall that is covered by this implementation schedule.
001 —see attached NPDES renewal 2015 summary
b. Indicate whether the planned improvements or implementation schedule are required by local,State,or Federal agencies.
❑ Yes ® No
I
I
' EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 7 of 22

I
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD— French Broad River WRF Renewal French Broad
II
c. If the answer to B.5.b is"Yes,"briefly describe,including new maximum daily inflow rate(if applicable).
N/A
d. Provide dates imposed by any compliance schedule or any actual dates of completion for the implementation steps listed below,as
I
applicable. For improvements planned independently of local,State,or Federal agencies,indicate planned or actual completion dates,as
applicable. Indicate dates as accurately as possible.
Schedule Actual Completion I Implementation Stage MM/DD/YYYY MM/DD/YYYY
-Begin Construction / / / /
-End Construction / / _ / / I
-Begin Discharge / / I I
-Attain Operational Level / / / /
e. Have appropriate permits/clearances conceming other Federal/State requirements been obtained? 0 Yes 0 No
Describe briefly:
I
B.6. EFFLUENT TESTING DATA(GREATER THAN 0.1 MGD ONLY).
Applicants that discharge to waters of the US must provide effluent testing data for the following parameters. Provide the indicated
effluent testing required by the permitting authority for each outfall through which effluent is discharged. Do not Include information
on combine sewer overflows In this section. All information reported must be based on data collected through analysis conducted
� using 40 CFR Part 136 methods. In addition,this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate
QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. At a minimum effluent testing data must be
based on at least three pollutant scans and must be no more than four and on-half years old.
Outfall Number: 001 -see attached data summaries
MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE I
ANALYTICAL
POLLUTANT METHOD MUMDL
of
Conc. Units Conc. Units Number
Samples
CONVENTIONAL AND NON CONVENTIONAL COMPOUNDS
AMMONIA(as N) 44.9 Mg/I 16.72 Mg/I Yea(�1 EPA-350.1 0.1 mg/I
CHLORINE(TOTAL 40 Mg/I 0.024 Mg/I 260(x 3 EPA-330.5 0.1 mg/I 1
RESIDUAL,TRC) years)
DISSOLVED OXYGEN 10.8 Mg/ 7.76 Mg/I 2yea( j EPA-360.1 1 mg/I
TOTAL KJELDAHL 31.4 Mg/I 25.0 Mg/I 20 EPA—351.2 0.5 mg/I
NITROGEN(TKN)
NITRATE PLUS NITRITE
NITROGEN - Mg/I - Mg/I - EPA—353.2 0.1 mg/I
OIL and GREASE <5 Mg/I <5 Mg/I 3 EPA—166.4 5 mg/I
PHOSPHORUS(Total) 4.1 Mg/I 3.4 Mg/I 25 EPA=365.2 0.1 mg/I i TOTAL DISSOLVED SOLIDS Mg/I Mg/I
(TDS)
OTHER - Mgfl - Mg/I - - - '
END OF PART B.
REFER TO THE APPLICATION OVERVIEW(PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
I
1
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 8 of 22
I

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD— French Broad River WRF Renewal French Broad
BASIC APPLICATION INFORMATION
PART C. CERTIFICATION
All applicants must complete the Certification Section. Refer to instructions to determine who is an officer for the purposes of this
I
certification. All applicants must complete all applicable sections of Form 2A,as explained in the Application Overview. Indicate below which
parts of Form 2A you have completed and are submitting. By signing this certification statement,applicants confirm that they have reviewed
Form 2A and have completed all sections that apply to the facility for which this application is submitted.
Indicate which parts of Form 2A you have completed and are submitting:
® Basic Application Information packet Supplemental Application Information packet:
® Part D(Expanded Effluent Testing Data)
®Part E(Toxicity Testing: Biomonitoring Data)
®Part F(Industrial User Discharges and RCRA/CERCLA Wastes)
ID Part G(Combined Sewer Systems)
ALL APPLICANTS MUST COMPLETE THE FOLLOWING CERTIFICATION.
I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system
Idesigned to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who
manage the system or those persons directly responsible for gathering the information,the information is,to the best of my knowledge and belief,true,
accurate,and complete. I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment
for knowing violations.
Name and official title Thomas E.Hartve.P.E. —MSD General Manager
Signature
Telephone number [phone] or [phone]
Date signed
Upon request of the permitting authority,you must submit any other information necessary to assure wastewater treatment practices at the treatment
works or identify appropriate permitting requirements.
I
SEND COMPLETED FORMS TO:
I
NCDENR/ DWQ
Attn: NPDES Unit
1617 Mail Service Center
Raleigh, North Carolina 27699-1617
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 9 of 22

i
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD— French Broad River WRF Renewal French Broad
111
SUPPLEMENTAL APPLICATION INFORMATION
PART D. EXPANDED EFFLUENT TESTING DATA ,
Refer to the directions on the cover page to determine whether this section applies to the treatment works.
Effluent Testing: 1.0 mgd and Pretreatment Works. If the treatment works has a design flow greater than or equal to 1.0 mgd or it has(or is required
to have)a pretreatment program,or is otherwise required by the permitting authority to provide the data,then provide effluent testing data for the following
pollutants. Provide the indicated effluent testing information and any other information required by the permitting authority for each outfall through which
effluent is discharged. Do not include information on combined sewer overflows in this section. All information reported must be based on data collected
through analyses conducted using 40 CFR Part 136 methods. In addition,these data must comply with QA/QC requirements of 40 CFR Part 136 and
other appropriate QA/QC requirements for standard methods for analytes not addressed by 40 CFR Part 136. Indicate in the blank rows provided below
any data you may have on pollutants not specifically listed in this form. At a minimum,effluent testing data must be based on at least three pollutant
scans and must be no more than four and one-half years old.
Outfall number: 001—See attached reports (Complete once for each outfall discharging effluent to waters of the United States.)
MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE
POLLUTANT Number ANALYTICAL ML/MDL
Conc. Units Mass Units Conc. Units Mass Units of METHOD
Samples
METALS(TOTAL RECOVERABLE),CYANIDE,PHENOLS,AND HARDNESS.
ANTIMONY I
ARSENIC
BERYLLIUM 1
CADMIUM
CHROMIUM
COPPER I
LEAD
MERCURY I
NICKEL
SELENIUM 1
SILVER
THALLIUM I
ZINC 1
CYANIDE
TOTAL PHENOLIC
COMPOUNDS
HARDNESS(as CaCO3)
Use this space(or a separate sheet)to provide information on other metals requested by the permit writer 1
I
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 10 of 22

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
' NC0024911, MSD— French Broad River WRF Renewal French Broad
Outfall number: 001—see attached scans (Complete once for each outfall discharging effluent to waters of the United States.)
MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE
POLLUTANT Number ANALYTICAL MLJMDL
Conc. Units Mass Units Conc. Units Mass Units of METHOD
Samples
VOLATILE ORGANIC COMPOUNDS
ACROLEIN
ACRYLONITRILE
BENZENE
' BROMOFORM
CARBON
TETRACHLORIDE
CHLOROBENZENE
CHLORODIBROMO-
METHANE
CHLOROETHANE
' 2-CHLOROETHYLVINYL
ETHER
CHLOROFORM
DICHLOROBROMO-
METHANE
1,1-DICHLOROETHANE
1,2-DICHLOROETHANE
TRANS-1,2-DICHLORO-
ETHYLENE
1,1-DICHLORO-
ETHYLENE
1,2-DICHLOROPROPANE
1,3-DICHLORO-
I PROPYLENE
ETHYLBENZENE
METHYL BROMIDE
METHYL CHLORIDE
' METHYLENE CHLORIDE
1,1,2,2-TETRA-
CHLOROETHANE
TETRACHLORO-
ETHYLENE
TOLUENE
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 11 of 22

I
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD— French Broad River WRF Renewal French Broad
111
Outfall number. 001—see attached scans (Complete once for each outfall discharging effluent to waters of the United States.)
MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE
POLLUTANT Number ANALYTICAL MLIMDL
Conc. Units Mass Units Conc. Units Mass Units of METHOD
Samples
1,1,1-
TRICHLOROETHANE
1,1,2-
TRICHLOROETHANE
TRICHLOROETHYLENE
VINYL CHLORIDE
Use this space(or a separate sheet)to provide information on other volatile organic compounds requested by the permit writer
ACID-EXTRACTABLE COMPOUNDS
P-CHLORO-M-CRESOL
2-CHLOROPHENOL I'
2,4-DICHLOROPHENOL
2,4-DIMETHYLPHENOL
4,6-DINITRO-O-CRESOL I
2,4-DINITROPHENOL
2-NITROPHENOL 1
4-NITROPHENOL
PENTACHLOROPHENOL I
PHENOL
2,4,6-
TRICHLOROPHENOL
Use this space(or a separate sheet)to provide information on other acid-extractable compounds requested by the permit writer
BASE-NEUTRAL COMPOUNDS
ACENAPHTHENE
ACENAPHTHYLENE
ANTHRACENE
BENZIDINE '
BENZO(A)ANTHRACENE
BENZO(A)PYRENE
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 12 of 22

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD—French Broad River WRF Renewal French Broad
Outfall number. 001—see attached scans (Complete once for each outfall discharging effluent to waters of the United States.)
I MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE
POLLUTANT Number ANALYTICAL MUMDL
Conc. Units Mass Units Conc. Units Mass Units of METHOD
Samples
' 3,4 BENZO-
FLUORANTHENE
BENZO(GHI)PERYLENE
BENZO(K)
FLUORANTHENE
BIS(2-CHLOROETHOXY)
METHANE
BIS(2-CHLOROETHYL)-
ETHER
BIS(2-CHLOROISO-
PROPYL)ETHER
BIS(2-ETHYLHEXYL)
' PHTHALATE
4-BROMOPHENYL
PHENYL ETHER
BUTYL BENZYL
PHTHALATE
2-CHLORO-
NAPHTHALENE
4-CHLORPHENYL
PHENYL ETHER
CHRYSENE
DI-N-BUTYL PHTHALATE
DI-N-OCTYL PHTHALATE
DIBENZO(A,H)
ANTHRACENE
1,2-DICHLOROBENZENE
1,3-DICHLOROBENZENE
1,4-DICHLOROBENZENE
3,3-DICHLORO-
BENZIDINE
DIETHYL PHTHALATE
DIMETHYL PHTHALATE
2,4-DINITROTOLUENE
2,8-DINRROTOLUENE
1,2-DIPHENYL-
HYDRAZINE
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 13 of 22

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD—French Broad River WRF Renewal French Broad
Outfall number: 001—see attached scans (Complete once for each outfall discharging effluent to waters of the United States.)
MAXIMUM DAILY DISCHARGE AVERAGE DAILY DISCHARGE
POLLUTANT Number ANALYTICAL ML/MDL
Conc. Units Mass Units Conc. Units Mass Units of METHOD
Samples
FLUORANTHENE I
FLUORENE
HEXACHLOROBENZENE I
HEXACHLORO-
BUTADIENE
HEXACHLOROCYCLO-
PENTADIENE
HEXACHLOROETHANE
INDENO(1,2,3-CD)
PYRENE
ISOPHORONE I
NAPHTHALENE
NITROBENZENE '
N-NITROSODI-N-
PROPYLAMINE
N-NITROSODI-
METHYLAMINE
N-NITROSODI-
PHENYLAMINE
PHENANTHRENE
PYRENE
1,2,4-
TRICHLOROBENZENE
Use this space(or a separate sheet)to provide information on other base-neutral compounds requested by the permit writer
Use this space(or a separate sheet)to provide information on other pollutants(e.g.,pesticides)requested by the permit writer
END OF PART D.
REFER TO THE APPLICATION OVERVIEW(PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
I
I
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 14 of 22

r
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD—French Broad River WRF Renewal French Broad
SUPPLEMENTAL APPLICATION INFORMATION
PART E. TOXICITY TESTING DATA
POTWs meeting one or more of the following criteria must provide the results of whole effluent toxicity tests for acute or chronic toxicity for each of the
facility's discharge points: 1)POTWs with a design flow rate greater than or equal to 1.0 mgd;2)POTWs with a pretreatment program(or those that are
required to have one under 40 CFR Part 403);or 3)POTW5 required by the permitting authority to submit data for these parameters.
• At a minimum,these results must include quarterly testing for a 12-month period within the past 1 year using multiple species(minimum of two
species),or the results from four tests performed at least annually in the four and one-half years prior to the application,provided the results
show no appreciable toxicity,and testing for acute and/or chronic toxicity,depending on the range of receiving water dilution. Do not include
information on combined sewer overflows in this section. All information reported must be based on data collected through analysis conducted
using 40 CFR Part 136 methods. In addition,this data must comply with QA/QC requirements of 40 CFR Part 136 and other appropriate QA/QC
requirements for standard methods for analytes not addressed by 40 CFR Part 136.
• In addition,submit the results of any other whole effluent toxicity tests from the past four and one-half years. If a whole effluent toxicity test
conducted during the past four and one-half years revealed toxicity,provide any information on the cause of the toxicity or any results of a
toxicity reduction evaluation,if one was conducted.
• If you have already submitted any of the information requested in Part E,you need not submit it again. Rather,provide the information
requested in question E.4 for previously submitted information. If EPA methods were not used,report the reasons for using alternate methods.
If test summaries are available that contain all of the information requested below,they may be submitted in place of Part E.
If no biomonitoring data is required,do not complete Part E. Refer to the Application Overview for directions on which other sections of the form to
complete.
E.1. Required Tests.
Indicate the number of whole effluent toxicity tests conducted in the past four and one-half years.
®chronic 0 acute *See attached data summaries
E.2. Individual Teat Data. Complete the following chart for each whole effluent toxicity test conducted in the last four and one-half years. Allow one
column per test(where each species constitutes a test). Copy this page if more than three tests are being reported.
Test number: Test number: Test number.
a. Test information.
Test Species&test method number
111 Age at initiation of test
Outfall number
Dates sample collected
Date test started
Duration
b. Give toxicity test methods followed.
Manual title
Edition number and year of publication
Page number(s)
c. Give the sample collection method(s)used. For multiple grab samples,indicate the number of grab samples used.
24-Hour composite
Grab
d. Indicate where the sample was taken in relation to disinfection. (Check all that apply for each.
Before disinfection
After disinfection
After dechlorination
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 15 of 22

I
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD— French Broad River WRF Renewal French Broad I
Test number: Test number: Test number:
e. Describe the point in the treatment process at which the sample was collected. '
Sample was collected:
f. For each test,include whether the test was intended to assess chronic toxicity,acute toxicity,or both I
Chronic toxicity
Acute toxicity I
g. Provide the type of test performed.
Static I
Static-renewal
Flow-through I
h. Source of dilution water. If laboratory water,specify type;if receiving water,specify source.
Laboratory water I
Receiving water
i. Type of dilution water. If salt water,specify"natural"or type of artificial sea salts or brine used. ,
Fresh water
Salt water 1
j. Give the percentage effluent used for all concentrations in the test series.
1
I
k. Parameters measured during the test. (State whether parameter meets test method specifications)
pH i 1
Salinity
Temperature
Ammonia
Dissolved oxygen 1
I. Test Results.
Acute:
Percent survival in 100% % o�
effluent
LC5 ,
95%C.I.
Control percent survival
Other(describe)
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 16 of 22

I
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
INC0024911, MSD— French Broad River WRF Renewal French Broad
Chronic:
INOEC % %
IC25
' Control percent survival % % %
Other(describe)
Im. Quality Control/Quality Assurance.
Is reference toxicant data available?
I Was reference toxicant test within
acceptable bounds?
What date was reference toxicant test I I I I I 1
run(MM/DD/YYYY)?
IOther(describe)
E.3. Toxicity Reduction Evaluation. Is the treatment works involved in a Toxicity Reduction Evaluation?
I ❑ Yes ®No If yes,describe:
I
E.4. Summary of Submitted Biomonitoring Teat Information. If you have submitted biomonitoring test information,or information regarding the
I cause of toxicity,within the past four and one-half years,provide the dates the information was submitted to the permitting authority and a summary
of the results.
Date submitted: / / (MM/DD/YYYY)N/A
ISummary of results: (see instructions)
I
END OF PART E.
I REFER TO THE APPLICATION OVERVIEW(PAGE 1)TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE.
I
I
1
I
I
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 17 of 22

I
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD— French Broad River WRF Renewal French Broad
SUPPLEMENTAL APPLICATION INFORMATION
PART F.INDUSTRIAL USER DISCHARGES AND RCRA/CERCLA WASTES I
All treatment works receiving discharges from significant Industrial users or which receive RCRA,CERCLA,or other remedial wastes must
complete part F.
GENERAL INFORMATION: ,
F.1. Pretreatment program. Does the treatment works have,or is subject ot,an approved pretreatment program?
N Yes ❑ No '
F.2. Number of Significant Industrial Users(SIUs)and Categorical Industrial Users(CIUs). Provide the number of each of the following types of
industrial users that discharge to the treatment works.
a. Number of non-categorical Sills. 5 1
b. Number of CIUs. 14
SIGNIFICANT INDUSTRIAL USER INFORMATION:
Supply the following information for each SIU. If more than one SIU discharges to the treatment works,copy questions F.3 through F.8 and
provide the information requested for each SIU.
F.3. Significant Industrial User Information. Provide the name and address of each SIU discharging to the treatment works. Submit additional pages
as necessary.
Name: *see attached Pretreatment Program summary
Mailing Address:
i
F.4. Industrial Processes. Describe all the industrial processes that affect or contribute to the SIU's discharge.
F.5. Principal Product(s)and Raw Material(s). Describe all of the principal processes and raw materials that affect or contribute to the SIU's
discharge.
Principal product(s):
Raw material(s):
F.6. Flow Rate.
a. Process wastewater flow rate. Indicate the average daily volume of process wastewater discharge into the collection system in gallons per
day(gpd)and whether the discharge is continuous or intermittent.
gpd ( continuous or intermittent)
b. Non-process wastewater flow rate. Indicate the average daily volume of non-process wastewater flow discharged into the collection system
in gallons per day(gpd)and whether the discharge is continuous or intermittent.
gpd ( continuous or intermittent)
F.7. Pretreatment Standards. Indicate whether the SIU is subject to the following:
a. Local limits ❑ Yes 0 No
b. Categorical pretreatment standards 0 Yes 0 No
If subject to categorical pretreatment standards,which category and subcategory? ,
I
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 18 of 22111

I
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD— French Broad River WRF Renewal French Broad
F.8. Problems at the Treatment Works Attributed to Waste Discharge by the SIU. Has the SIU caused or contributed to any problems(e.g.,
upsets,interference)at the treatment works in the past three years?
�. 0 Yes ® No If yes,describe each episode.
RCRA HAZARDOUS WASTE RECEIVED BY TRUCK, RAIL,OR DEDICATED PIPELINE: '
F.9. RCRA Waste. Does the treatment works receive or has it in the past three years received RCRA hazardous waste by truck,rail or dedicated pipe?
0 Yes ® No(go to F.12) 1.1
F.10. Waste transport. Method by which RCRA waste is received(check all that apply): RECEIVEDIDENRIDWR
1 0 Truck 0 Rail 0 Dedicated Pipe MAY - 8 2015
F.11. Waste Description. Give EPA hazardous waste number and amount(volume or mass,specify units).
EPA Hazardous Waste Number Amount niPermitting Sections Water g Sec i
111
CERCLA(SUPERFUND)WASTEWATER, RCRA REMEDIATION/CORRECTIVE ACTION
WASTEWATER,AND OTHER REMEDIAL ACTIVITY WASTEWATER:
F.12. Remediation Waste. Does the treatment works currently(or has it been notified that it will)receive waste from remedial activities?
' ® Yes(complete F.13 through F.15.) 0 No
F.13. Waste Origin. Describe the site and type of facility at which the CERCLA/RCRA/or other remedial waste originates(or is excepted to originate in
the next five years).
The original industry was Chemtronics:a manufacturer of explosives.Ground water remediation came from several wells to two areas:Front Valley
and Back Valley. The each well has its own pretreatment facility.Pretreated around waters converge at one location before flowing into MSD
sewer lines.
' F.14. Pollutants. List the hazardous constituents that are received(or are expected to be received). Include data on volume and concentration,if
known. (Attach additional sheets if necessary.)
Since late September 2014,little to no discharge has been released to MSD.Operations will be shut down for approximately one year for
observation.Prior to September average flows from Front Valley were approximately 3.000 gad and from the Back Valley location were about 9,000
gpd.Historical data is on attached sheets.
F.15. Waste Treatment.
a. Is this waste treated(or will be treated)prior to entering the treatment works?
® Yes ❑ No
If yes,describe the treatment(provide information about the removal efficiency):
Pretreatment for both valley locations consists of flow equalization tanks and air strippers.At the Front Valley location there is tertiary
treatment utilizing drum carbon filters. At the Back Valley location a settling tank is used for tertiary treatment.
b. Is the discharge(or will the discharge be)continuous or intermittent?
Continuous 0 Intermittent If intermittent,describe discharge schedule.
END OF PART F.
REFER TO THE APPLICATION OVERVIEW(PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 19 of 22

I
FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD— French Broad River WRF Renewal French Broad
SUPPLEMENTAL APPLICATION INFORMATION
PART G. COMBINED SEWER SYSTEMS '
If the treatment works has a combined sewer system,complete Part G.
G.1. System Map. Provide a map indicating the following: (may be included with Basic Application Information) N/A ,
a. All CSO discharge points.
b. Sensitive use areas potentially affected by CSOs(e.g.,beaches,drinking water supplies,shellfish beds,sensitive aquatic ecosystems,and
outstanding natural resource waters).
c. Waters that support threatened and endangered species potentially affected by CSOs.
G.2. System Diagram. Provide a diagram,either in the map provided in G.1 or on a separate drawing,of the combined sewer collection system that
includes the following information.
a. Location of major sewer trunk lines,both combined and separate sanitary.
b. Locations of points where separate sanitary sewers feed into the combined sewer system.
c. Locations of in-line and off-line storage structures.
d. Locations of flow-regulating devices.
e. Locations of pump stations.
CSO OUTFALLS: I '
Complete questions G.3 through G.6 once for each CSO discharge point
I
1
I
I
I
I
I
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 20 of 22

1
' G.3. Description of Outfall.
a. Outfall number N/A
b. Location
(City or town,if applicable) (Zip Code)
' (County) (State)
(Latitude) (Longitude)
c. Distance from shore(if applicable) ft.
d. Depth below surface(if applicable) ft.
l
e. Which of the following were monitored during the last year for this CSO?
0 Rainfall 0 CSO pollutant concentrations 0 CSO frequency
ID CSO flow volume 0 Receiving water quality
f. How many storm events were monitored during the last year?
' G.4. CSO Events.
a. Give the number of CSO events in the last year.
N/A events (0 actual or 0 approx.)
b. Give the average duration per CSO event.
hours (0 actual or 0 approx.)
I
I
I
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 21 of 22

FACILITY NAME AND PERMIT NUMBER: PERMIT ACTION REQUESTED: RIVER BASIN:
NC0024911, MSD— French Broad River WRF Renewal French Broad
c. Give the average volume per CSO event.
million gallons(0 actual or 0 approx.)
d. Give the minimum rainfall that caused a CSO event in the last year ,
Inches of rainfall
G.5. Description of Receiving Waters. ,
a. Name of receiving water: N/A
b. Name of watershed/river/stream system: I
United State Soil Conservation Service 14-digit watershed code(if known):
c. Name of State Management/River Basin:
111
United States Geological Survey 8-digit hydrologic cataloging unit code(if known):
G.6. CSO Operations.
Describe any known water quality impacts on the receiving water caused by this CSO(e.g.,permanent or intermittent beach closings,permanent or
intermittent shell fish bed closings,fish kills,fish advisories,other recreational loss,or violation of any applicable State water quality standard).
END OF PART G.
REFER TO THE APPLICATION OVERVIEW(PAGE 1) TO DETERMINE WHICH OTHER PARTS
OF FORM 2A YOU MUST COMPLETE.
1
1
1
1
1
EPA Form 3510-2A(Rev.1-99). Replaces EPA forms 7550-6&7550-22. Page 22 of 22

1
� 2
I I
1
1
1
1
1
1
1
r

II 1
J
�s 1
1
I
I
IN
I
I
I
I
I
I
1 1
I

I
NPDES RENEWAL
2015
111
Facility Description:
The present reclamation facility is a 40MGD secondary plant serving Buncombe County
(specifically—Asheville,Biltmore Forest,Black Mountain,Montreat,Weaverville,Woodfin
I and Buncombe County at large). The facility treats a current average daily flow of 21.5
MGD. The reclamation facility is an attached growth design,comprised of 152 rotating
biological contactors (RBC's). These RBC's provide approximately 400 acres of surface
I area for biological growth. It has been said that MSD's facility is the largest RBC plant in
the world. The plant consists of:
I Preliminary Treatment Components
IDI Barscreens(2 units)w/screenings compactor and shaftless screw conveyer
Influent Pumps(3 units)—35 MGD rated capacity each
Aerated Grit Chambers(3 units)w/associated grease removal
Primary Treatment Components
Primary Micro-Screens(7 units)—250 micron screens—(mothballed—no longer in service)
Secondary Treatment Components
1st Stage RBC's(44 units)
I 2°d Stage RBC's(72 units)
3"d Stage RBC's(36 units)
Intermediate Pumps(3 units)—pump water to clarifier from 3'd RBC stage
I Intermediate Clarifier(4 cells—total volume 2 MG)
Final Disk Filtration(18 units)—10 micron particle
I Disinfection& De-Chlorination Components
Liquid Chlorine(Sodium Hypochlorite)
Liquid De-Chlorination (Sodium Bi-Sulfite)
IResiduals Handling Components
Gravity Thickeners(2 units)—100 foot diameter each
I 2.5 Meter Belt Filter Presses(2 units)
Anaerobic Digesters(2 units)—100 foot diameter each—(mothballed—no longer in service)
Fluidized Bed Incinerator(40DT/day rated)
Alkaline Stabilization Facility(40DT/day rated)(mothballed—no longer in service)
IEnergy Management Components
4 Megawatts of diesel powered Generators(full back-up/emergency power for WRF)
I850 Kilowatt Hydro Turbines(3 units)—induction units(French Broad River source)
Automation Components
I
SCADA—PC/PLC Control System—full automated control of WRF
I
I

The reclamation facility is permitted for up to 40 MGD,with discharge limits of 25mg/l
CBOD(monthly average)and 30mg/1 TSS(monthly average). The current average removal
efficiency for these two parameters is approx.92-93% respectively,compliance has been
consistent. Since the last permit renewal,the plant has undergone various improvements.
WWTP Improvements
Replacement of one Influent Pump with second unit scheduled before July 2015
Replacement of secondary Microscreens with AquaAerobics disk filtration units
Replacement of Air Pollution Control systems to meet new MACT standards(completion in
early 2016)
Replacement of Heat Exchanger and associated high temperature ductwork at Incinerator
Replacement of failed RBC's throughout system (30 in all)
Replacement of aluminum slide gates controlling flows throughout RBC basins
Replacement of Adjustable Frequency Drives for Influent Pumps in controlled air
environment
Creation of standby diesel powered Bypass Pumping at Plant Influent
Completion of Facility Master Plan with 20-year horizon
In addition to the items listed above,numerous operational modifications have been made '
to improve the overall efficiency of the treatment operation. All of which have significantly
improved the quality of the plant effluent.
It should also be noted that MSD maintains ISO-14001 certification and continues to be one
of the largest utility organizations in NC to achieve certification for the entire utility.
MSD also maintains an excellent web site,which includes a tour of the treatment facility—
access the site via www.msdbc.org
Sludge Management Plan
MSD utilizes its fluidized bed incinerator as its primary residuals management option,with
alkaline stabilization as a secondary management option—as well as maintains an
arrangement with the Buncombe County landfill(lined) for emergencies. Presently the
facility is managing approx. 14 DT's per day of residuals. The facilities are designed for
40DT's per day. Due to the lack of true primary clarifiers,most of the sludge generated at
the facility is secondary in nature(i.e.sloughings from the RBC's). Sludge is thickened in
on-site gravity thickeners to a consistency of 2-5% solids at which time it is then pumped to
the 2.5-meter belt presses. These units dewater the sludge to 24+% solids and then it is
pumped to the incinerator. The facility maintains gravity belt thickeners and anaerobic
digesters,however these units are presently not being utilized. Air emissions from the
incinerator are of excellent quality. Recent air emissions testing place removal efficiency of
the air scrubbers at 99+% for regulated parameters. Incinerator ash is thickened on-site
via a gravity ash thickener and then pumped to an on-site lagoon. Groundwater is
monitored in accordance with NCDENR requirements(up& down gradient). Alkaline
stabilization operations no longer in service,
I

I
1 g �, \S�R1CT • ",4,,o,
�X.__ j S, e•,,
s
44
y
�
W 1 �i N =
f�/ yV.
_3 YANpN r
�_ t '�_ SN OdodLiW 6\k`0
,� ` �'
,,\
1 52[2 .h ti s•_
! S<22 eV,y, n 'Q 7�
1 c� '' n: h-, y
q M �
W 4,-
g ^ c„,,,,, f
r , /
y N \
•\\\\\\\
I
U
I
\er S
\ / ° i?
, •'' /9 , s' ''. \
' _______/.1 . .\-_"
Ss
y --4' / \--
'=i N ,p 2625 '. �' 0
•
f..1-7 6- '1.,:,,' . ____,....r.-;:;:.::::.' -:::: .-:
ER
I o FRENCH g °pO 1 — I 0
— 2.000
's t�
zoz
I g
ton
�__ 2''''' — — — 3 4

It..
' •••& -.
'-
-- . 1 I
'7
I\ .
'. b1.1:
I
' .
''lTt
, ifit' 4-
16
c4e,:.:.:,,:vir.,,,,,,-• 1 17. 7..w: ilm \,:\.,..., ,,
11111, 11
1cL)
_.)
cn
0
,.,.,
. _
-t.e,_ •
et Lo
I j
rt a 'Z'
111.1111i,, ,
t.. i
1111\1 RUc
'----7- 1. 0\ le c.5
11\:10\' iiiir t ww
114
, z
EL
1 ..)
, a
.,..•
."7611111111 C..
,...
c ,
• r•-?. '----:.
0
,--
__ ---wimisol,-
,
7, 1.-
....,L,
Ex Ei-
6i i ED
F.5 vl
L.
..... _....13
/
/

I
I
I
RECEIVED/DENR/DWR
,,,,4{ a 8 2015
1 Water Quality
Permitting Section
I
I
I
��\��SEWEpgCe n '(\O d
• /
I ,,
_, ...„,_., __.
....„--- ,_,_.
• _ ,-..,_ ,...,,_ . \ - __________j , .7
, ,
/.,,,
ti. oat----,-,;---,c=7 z _........,.._
, 0,,,,, 7-, .,,,
q 9. sc,„ ,,
1 4, ,,,
cobNTY,NORj Y
`\ :ism:. _ it4..
s"�s
i - gli_.....4.%--,.....4*. i..._'1__:-..--=--,-----P-47.-n-yq
It 1111 Ir
511.1 1111 4. V
��� �lir7��' i
i how •-1 ,�
I
FRENCH BROAD RI ., 411
I
MSD WASTEWATETREATMENT PLANT SITE
1 NOT TO SCALE
1
I
I
I
I

I
I.
I
I
I
3
II
I
I
M
I
I
I
I
I
lilo
1

I
•0
I
I
I
W
I
I
I
I
4
I
I
I
I
1
•
1
1

IEFFLUENT
NPDES PERMIT NO.NC0024911 • DISCHARGE NO. 103 MONTH:January YEAR: 2012
I '"AGILITY NAME:Metr000litan Seweraae District CLASS 4 COUNTY:Buncombe
,PERATOR IN RESPONSIBLE CHARGE(ORC):John Kiviniem GRADE 4 Certification No. 107.73
CERTIFIED LABORATORIES(1)Pace Analytical Services. Inc. Certification No. 40
(List additional laboratories on the backsIde/page 2 of this form) '
ICHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY
Mel ORIGINAL and ONE COPY to:
ATTN:CENTRAL FLES X - Z/2A! Z
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
1817 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699.1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60050 00010 00400 50000 00310 80082 00810 00590 31816 00300 00095 00720
i 1Y�f •
FLOW m -
1 m$ h ,FFF m b
a o INF m w a o
e g
V t `m m 2 m m m u m
Q C c ^ oo n po i E c$9 . VB w to =•
a Iii � ry Ig ii,
mN 0 tSN O ` O ~4K Q ,g o GsCCC o ti 0
HR8 HMI Y9 MOD C UtRis up&L MOL MGA. MOA.. MOIL fri00kt MGs. 118/CM WM.
;:::i:.::'.:::zxdd:::•::•:•:24:••:.:.:is:::::.:.::..:'ti .•.•.•.•.t4e::::'..... .....::..;.;..:....•:r.• ;' ... ..::......i....... ............ ................::.9:4Q:::::::::::.i.......::..:::.i'.......:::::;:::::.
2 2400 24 B 17.3 13.9 Holiday 9.60
:::Y::: :�.::;:.;:�::;::;•:1'4i���� �$.;.:...:•"•:•:•%".•,.� :'......... ..... ..:•:•:•:;::k164:::'�b i''a�'��" .:�:9.0:�:�:-�:�:��.:�:i1,fi9:�:�.:::•'77t:k:_::.:•:::;:::::::
4 2400 24 Y 17.6.......14.0.......7.3..„<24,0 20.6 16.6 22.7 e. .....9.0... 8,26 492.0
\
�:�::.:.5:.::, :: .(j
� 0}:•:b:•:'�'�' ::::::::**:::,:i:':::'r.i.i.::::::*i::::'r}�:i:;'r'r};4... 4
. •::.... .. ....9}::::. ,:?iy,.. .•:v:•:•:•ii0:::}::Q:::•.:}9*::Y}'::i::::*(ii::.:::::{ii(tiQY':}}::::r:'t
6 • 2400 24 Y 17.7 14.6 7.2 <24.0 16.8 18.1 23.3 a 1.0 9.22 608.0
�:�7 ::v:��&00:�.•..•.•.24�}�: :;:$ }:•:\•:•:16-0�'�''�'�54.�6 ::•. -- -- � ..... ........ ........... .......... _ ..::�9:4Q�: %�' - -- - ..... •
8 2400 24 B 17.8 14.4 9.60
d.,..• :'�89:�� . ::13:5���'�:i[ill::::•'•'245:��:�::�:� :�:::.\•:.\•:�:'ITa'1�:�::�.. :�:t8 :�:'�b ....iT:a':':':�b:��::�:B:U:�:�:��:. .:�:9:08:�:: :8831}�'��: ...
i �. .:�:II4Gil�:•:r:•:2 ..... �1f.�:�:�:�':. fl•:�':. .a•:•fs ... ... ..
10 2400 24 Y 19.4 14.9 7.3 <24.0 16.9 19.0 s 24.0 12.0 6.76 622.0
..r•.•.,..
:i14:.:•::::0400:::•::•::A4::: ...::lt::... :;iti>:P:, ::::04:::::::031::::::: k44:•;,:-:-s -.:�io... ::a.:�::i{i:�:::•:a•.•.•.•.•as...• ....::i4'o:•::::....::d..2:::::'.:;tiittao;'::.,•..•,•.•.
12 2400 24 Y 31.4 13.2 7.1 <24.0 19.9 7.1 47.6 16.0 9.21 318.0
:::< : '' { .\:::::
!' ::if$:: :::x4QQ::•:•i:•:•ir4.•::.•...... .xx,. .f�,.. ...A:::;:::40.::1,::::,::::-:::::::::::::::.....�::::. : :'�.,6:{:�s:,•.•.•:�.•4:?::... ...0.4•:::''.. .:::ti:;t8:::::::::40O.::::.......
14 2400 24 B 20.9 12.9 9.30
4..\•.: 8:::;:;::• !9'6 • 13•: •.•.•..•..• 9:80 ::::::::::::::::::
16_ 2400 24 B 19.7 13.4 Holiday. '9.70
.•
':92�:•.•:'21100:�:•..\•\•.•�t......Y::•::••:':,2Oc6:•:••:•:S3.S:•::::7:8*::':Cts.4:•::•:•: ... ....*18:4::'':d•i:•:•:•24J9:•:•:•:: ...:::Il:ll*:::'....::'9:22::::'::49<.0::::':::::::'r:::
18 2400 24 Y 20.4 13.8 ,...7:2......<.2.4..6................. 18.0 2 17.6 c 26.3 6.0 s 9.12 455.0
I :1$::•.:::24b4.::....ii:::::.. �:(!=:- :::::::i$ :::;:43:$::::::: ;g.:. 24,.......... ..:�"it:M1:::?: :::3>.:d::::..6...•,•;4bo:*:,: •:: .::4:1 :-:.. :$:$8:::i:::::48d8::-:::::::;::*
20 2400 24 Y 18.9 13.6 7.3 <24.0 16.4 18.4 c 22.0 3.0 8.88 494.0
22 2400 24 B 21.4 13.9 9.70
�:¢3':'�:}200} ..24�:�;' .:��'�''.•.�•._,24:2'r:;:}:5�.3�}::.>7:0. Y4A• , �. �. ... �.'••78:5�:��s .19�:�:�:��;s:::•:;:31:0"�'�::;:�:'•�'�9:84:. :::�:4Y40:�:'� - ..
I
24 2400 24 B 22.6 13.8 7.4 <24.0 19.0 16.2 a 27.7 17.0 8.98 424.0
::i±,8 ::
::3$:::::::Q4CC::•:r:•:2 ...•:•:. ... ::: ii::.:�:? .. t .• :b:::::::± o::::::.. .::2 .0•:::::: :9,GC:::::i:i39.'6:::i: .....
I 28 2400 24 Y 21.3 14.3 7.1 <24.0 13.6 16.0 23.3 9.0 8.91 441.0
}i:•: •:•i:i::. 4:':' k:�5:: . :#_•.
�:�Z�:.'::•RdO�:�..,.:���:�r:�:�:�:Y:�:�.. ..��:�:�:�.�:�:3�:8:��:;����>���:�Lo:� ..... „_:�;;�'�73... ...,�:�fdit���:4 •..•28�:�,�:��:......,k•:::::::,.::::::0;04:::::::'.:4t14::;'•..... ,
28 2400 24 B 20.7 13.7 9.20
I
30 2400 24 Y 19.2 13.6 7.3 <24.0 12.1 .14.7 a 22.0 ' a <1.0 9.05 437.0
::9l:::::�:ft4GC::•:•r::•24 .Y.
:•:...•:• •::•:•:••::: (:::::•:18:EI:::::::iii:::'�:424VJ6t•'. - '•'t/�0::::::}•.•.•Z6.:3:::::•::'e:::::::9c0::::::::. .:::8c98:::::::::A88i::::......
•••16.8•• ................
AVERAGE 20.9 / 1.2 •1 24.4 ,0' 9.1
I
.!• �... .18. .'4670•
4:
0:
MINIMUM 17.3 12.9 8.8 <24.0 7.9 7.1 18.7 1.0 8.26 318.0
IMonthly Limit l 40 MCD, 26uGIL 25mg1L , 3nm/i 200d100mI
IDEM Form MR-1(B/93) .

EFFLUENT I
I
NPDES PERMIT NO.NC0024911 . DISCHARGE NO.103 MONTH:February YEAR: 2012
FACILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
)PERATOR IN RESPONSIBLE CHARGE(ORC):John Kiviniemi GRADES Certification No. 10773
I
CERTIFIED LABORATORIES(1)Pace Analytical Services,Inc.Certification No.40 (2)Meritech Certification No. 165
(List additional laboratories on the backside/page 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTINGS PLES: OPERATORS/PACE LABORATORY
Mall ORIGINAL and ONE COPY to: ` 3/al/'2
ATTN:CENTRAL FILES X
DIVISION OF WATER QUALITY (SIG RE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
1817 MAIL SERVICE CENTER • BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
50050 00010 00400 50080 00310 80082 001110 00530 31818 00300 00096 00720
��ee i FLOW 2 a
U FFF ITT C V �' b C
` _ C y INF 0 @ 'FC I. N ` oN i 16 b o C.� ` ig
�,'ppN U lVao IZ7Y
is M i 13
O i 5i c 7 Q N o y K �t CT
$ O m0 E Eg o S
O n . ~ a F° LL •
x I
rota t M YA3 MOD C Wife mit MOIL Mot MOIL MOA. MOMML .` MOA. uSICU WA.
. ................�'3'•'..:'i::::iFBj(::::'s'r::::::i0:::::::b:::.:::�.G::::::•.....8:66:::::::::466c0::::'.......
:�:'1�:� :l:4CU�:�:•i:•:�23:�::•:�:1C�:�:��:�:QO:t:' �:�:[4r2:�::� ?':U�:�-:'<Y4U'�•' �"J .1•'�' A
2 2400 24 Y 19.8 14.1 7.2 <24.0 12.4 18.1 s 18.3 17.0 9.09 464.0
I..-
$:::'::i4G0:.•.,::::i4::: :::Y::::::.15:6:::.::::iii: ::C.3:: .424 b ::.. ::::44;i:::: :ii .:1
.. . .d•::•::2 iI:: ::::::_o:::: .. ... s1t::: 7i
4 2400 24 B 19.3 14.0 9,10
::(:::• ::: : ::•::;::•:•::•:•:•::
6 2400 24 Y 19.1 14.4 7.0 <24.0 13.6 17.1 20.3 a 19.0 9.02 466.0
: '•::•::..;.:.:.•.• :.:`.:•:•%
:•:•••:.:4•:�•:•:•:•••••••••:•:.
:....2D� ��8���:� 69:�:��:�:t4F:� �:�7 �:�•:�:lY4Q:� '�'98'�:� • .'��1�8!Dl .. ..•.2f�:�:� :e.:••:•:g0:_:�:'• � .•H:8•.;.;..;•476C'.''•
8 2400 24 Y 18.8 14.0 7.2 <24.0 14.1 18.4 s 24.7 a 17.0 5.61 456.0
....
:..•.•.•'•';::.:;: ::::•:•:•.•.
j 9:::::.::'i)tUU::•..•.•.24...:Y�:�::�:�l9:6•:�::�:�}{��:��:�:i<:'�: �:�#20:��: �.. �:�.'tS6:��:. ::�8:9�:�:��:. � :1T8:::d•:.'.�:�27.$�: '•.. .�:�:I�O:�:��:. ...6.98:::;*]I82:U:::::::i:5.ix--
10 2400 24 Y 18.8 13.9 7.3 <24.0 8.6 18.0 23.0 a 12.0 8.98 621.0
I
.:.v.:. :::v:::: :i::•
;�11:�'.:�:34b0�:�:�::�:�1�¢.•..•.•.8:�:':�:t$... .�:t4:G:�::�..... ..... . .......... ..... ..�.�:�::�'i .:a :::::iii::::: .•.•9:6 ,..........?:::::::::.::.iiii
12 2400 24 B 17.8 11.8 24.9 18.6 6,6 20.3 10.00
:•J
:d•
14 2400 24 Y 18.2 13.9 7.2 <24.0 . 13.8 19.6 s,s 24.0 a 6.0 8.86 614.0 '
�:96�:::�:�2g88:�:•:y•:•:24. , .H•:•::�:�l7:B�:�::�:�?3:Y�:�;:�:7;d:�: �:�28:q': ' .... .. :�:77:l:�:��;'Tr�:�:t9L6•.•:.•.•..•.�:�2fl�t�:�:��:e��:.�:7•��:�:��:. ...bi18�:�:��:�b2S:0:��:. ..
18 2400 24 B 18.7 13.9 7.4 <24.0 12.6 20.4 as 24.3 3.0
i . , � i.::::. ): �
8.94 530.0
:�:ii; �::�:eoo�:::..• 2:.•:..•..•.�r:�:�':�:iii �:'�:�:i<s:�::� i:s�:� :�: zio:� :.............�:�:ie;i�: :'...�:�t �.. iti:.::fr#i:::.:::::::::::ito::::::'.::.:.:: b ....
..::.iii:i.i.d :.::.::.::.:: ::. i
18 2400 24 B 17.7 14.3 9.40
20 2400 24 Y 18.4 . . 13.8 7.3. 24.0. .a 21.8 . . 19.9 sa 32.0.. .a. . 138.0 8.97 469.0
:41::'. :i144::•:,•::::i44:::•::::*::::::::i7.:6::::::::i10::::::4;4::: ::•Ai4;0:: :::•:,:•:.:.:•:.:::;::::•:::i6,i:::;' ,:::14,..... .....*::::: ::';::::40.::::..•.>•....1.. ,. 34>2:4::::'.......
22 2400 24 Y 17.7 14.4 7.4 <24.0 21.6 a 20.6 a 32.0 82.0 5.99 528.0
::::: ::.:':1'::• ...,...
.. ... �:�!16:4�:;::' ::�211�•:��:. �:�:f8ab :�::�e:'�.�:GO,D:::;::• 8;69•:•'•'::'648�G::;:.
:�2�}�:?:2400'}}:}::2#::�::Y:�:��}:79:1:{ :14at}:'�'�7:Y�:�•'�'�24JC•:• ' ` � , i
24 2400 24 Y 18.0 15.4 7.4 <24.0 13.5 s 19.6 36.2 36.0 8.72 510.0
::Qff.: ::::271U0: •. .34•:••:::.EI:::::*St:B::•i:• }37:::::..... ....... .. :::.:::::::.:i: ::::::::.:.:::•::.: ........ .. ........ .. ... 9
28 2400 24 B v v 17.1 _ 13.9 8.80
?: .r: 4$$:,. }: :: , r,4..,. r:4 5:..:::.:M::: .. .$i$`" r � ....A:'..... 4,9 $d::, 1
28 2400 24 Y 17.1 14.6 7.4 <24.0 17.6 20.1 a 26.6 92.0 9.00 602.0
• .r.
•':�:• •••:•••••'•:•::•:•••:•••:. ..a�;a�- ''..
...................... .................. .. ... .
.... ...................... ....... ........ .........,..... ..... ...... ............. .. ..9,• ••499.8. •.0.0•
:�:9�: � fi :'•19.1•• .03�:
AVERAGE. .18.4.. • 14.2 3.4. .18.9 14.8 . . 1 .1 2 .7
� � I
:: :•:
....... :ilAAsii�iiiM:::�:�:�:�:�:�:�:��:�:�ii:a�:�::�::i5c�i;i :::z;b::::,.i4,.. .. ....�•::.;:;:::�:z4;�:::::::;:::�: �:�::...:�:a5�i:i:��:. .�:�ia,.. .. .....0 .. .6. $ii ...
MINIMUM 17.1 11.8 6.8 <24.0 ......18.9.............8:8.... 17.1 16.3 1.0 8.46 464.0 0.0
:•r:•:•:•: ::::::4•;:::':
Monthly Limit 40 MOD 26u0/L ....2bmglL •••• 3OmglL •.•200d100ml 22uGILJD
DEM Form MR-1(8/93) 1

IEFFLUENT
1v).
1
NPDES PERMIT NO.NC0024911 DISCHARGE NO. 103 MONTH: /YEAR: 2012
FACILITY NAME:Metropolitan Seweraoe District CLASS k COUNTY:Buncombe
I i OPERATOR IN RESPONSIBLE CHARGE(ORC):John Kiviniemi GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services,Inc.Certification No.,4Q (2)_Certification No.
(List additional laboratories on the backside/page 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY
Mall ORIGINAL and ONE COPY to:
ATTN:CENTRAL FILES VAIX DIVISION OF WATER QUALITY I R(SI RE OF OPERATOR ESPONSIBLEiCHARGE) TE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
50050 00010 '00400 50080 00310 80082 00810 00630 3181e 00300 00095 00720
I
FLOW/' g c
I Wgg 8 INfE 0 mpp� $ C•
F N N t> t N `� m Z 3i El
g
u 3 V aq v . 1 OC g O !a a a Nag' 3 II
9
M.ill
HRS lila Yle MOD C 1181.8 edL MAIL
4 : ::MO& MOI MOO. a0MMOIL uSICLl 50a
:ti�: ::::.: .::::.: .i.::::: �:44-:� :. ��:��:� :�274'.:�!li{:8:::�::7: :::::� ZO::� ...•.:.•.•..•::1158�:�; .. �:�2G4:_d�::':�:YBA:���:...:�:Q800::::J�.•:::.:•��8:8C�:�:���:8880'i::J.•r::•:::::•.••.
2 2400 24 Y 18.0 15.0_ 7.5 <24.0 14.6 a 20.2 28.0 70.0 8.89 540.0
:.4•:::... _ "
:: •:::: 7,
'''5150'''''.' ... •:•:•:•:•:.:•:•:.
• 4 2400 24 B 18.3 13.8 9.00
I t:::• '0'
:::-.0:: :::::24-00::::::::::44::::�.:::Y :: :..913 ':::12-.5::::;� .� .
6 2400 24 Y 17.7 14.2 7 <24.0 12.1 19.1 s 20.7 78.0 9.16 518.0
.. .. '..a:;•' ... ..:�:'178:�::' •:•:'19:8•: �:�::�:-:ie:3:�:��:..:�:fiY48:0:::.• ,:::8.'87'::'':�:64L0:�:''....
8 2400 24 Y 18.3 15.3 7.3 <24.0 16.8 20.6 a 28.4 , 8.0 9.05 690.0
I •.•J:.•..• :gi: ::•s::: :2t7:::':' :::3EA: .:::9 6::::::..::C64.b:•:••:.....:.
:�:9:� :.:24G4:�:�::�:�21{�:��:.�:�Y:�:�:��:¢¢:2: �:1'a:e��:�:7'03:�::�:1i24ti.9:�;: �:�:�:�.. ,.::%1:3:.x::::..:.4 .. .. ..
I 10 2400 24 B 18.6 14.9 9.00
::. : ::.: ':v:
12 2400 24 Y 18.8 14.9 7.2 <24.0 14.4 17.7 6 24.0 8.0 8.97 486.0
;a3: .�:�lQIP}•r:}}RA:{:',:;:k3: :•'�:�::4114:-::1$:4::::.7:4:•::;:;�. ;::::::::,:,:/..... .:::1L'•�:::..5: 8:�:
�..�:1 ::, •:;_•.:26;A::••,
4:-':
14 2400 24 Y 17.8 15.3 7.6 <24.0 13.0 >p 18.8 a 22.7 70.0 8.85 618.0
...:•!.:.:..:•:1S.' .:-:9'l'' .:•257-:::: :'p;': .:::&911 ::.::622.•:••'.......
}:18' :?:240?:� ::�}y�;?:::.:;:Y::::::::a8;14:��:16;'�:::;:�F.3:�::�:�2#��'• +�'.•' ,R.•::•4 ; .. �J! 4•'•Y•'•�• .
16 2400 24 Y 19.0 15.7 7.4 <24.0 12.1 18.2 s 25.0 42.0 L95 633.0
i:i:•.
::':v:•:•:•:•:
-:fF7•: :.::-2�9:-: ":::024:::::.: 9'r:�:�::f297:::::l6:if:::'..... ....... :i::::::::.:?:J.•.•.:.:• ::::•:::::.:i::.:::.::::: •:'i
......... ........ .......... -
I 18 .....?"9.:•::,"...-24 8 20.4 16.6
:.:v.•.'
:.:t.i. :,.i4ti'd:•:::::ii:=::::.•:•r•:•:•::.:ati: ::::ib;d::':::t;a:::...24i:;::....,. . .
20 2400 24 Y 19.5 16.1 7.2 <24.0 16.2 19.0 6 25.0 100.0 8.78 489.0
':
22 2400 24 Y 20.0 16.2 7.2 L <24.0 16.6 1 6 25.0 52.0 a 8.79 604.0
: ....:.• •.•..•..:'.ci"::: :.i1' . ::i::: •.:9: ..:.26iGi:::: '...... 6:88' : : QC0:•J:•:•:•::'::':•:
::.ia: '..ix::�:- ::44.::::'.:::ii:::�:::::xy:t•.:y5:e•. = :u:: �:�o•::• :1 >°<2': :R;s , ,
24 2400• 24 B 21.0 16.1 9.20
:..ii: ::2900::::::'::2ii:•::::r::9:::*::it8:2:•::4609::':.... ...........
•'8'10:'''::• .. ........
I 26 2400 24 Y 19.4 16.5 7.1 <24.0 12.6 17.3 5 21.7 a 82.0 8.66 449.0
�
\. .
::�f: :::::A440.:::::�:�:34•:�::.:�:1':�:�:�;:��9;$�::�:Il;:��::�:�)<;y:;::::;c�.�:��:..�..,.•...:•:•:•10::::•:•:••:•1
9;1:::::•:•:: ::2$4:::. 'a::' :4 ..::::::04:::::::::1$16.4:::,•:•:•:•:•:•:•:•:-,
28 2400 24 Y 18.9 16.3 7.4 <24.0 18.6 18.7 s 22.8 a 106.0 8.96 507.0
,'J:.•,: fi:• ..i.• : ::y:: p:..•::.•:...•:
;29: .:;�0�}:..::�Rd'�}:::::::Y.::;::::,:-.44A..:44:7::'XT:,15:::'1�+o-�:�... ....�:�I'�65:�'...:::�,6.•:::::e:}:''•.�u1 •�.,.,_,�••::;4,4•0:1:_:; .:�:$:BU::::::�:��..v:.•:.:•.•:•
I30 2400 24 Y 19.1 16.9 7.4 <24.0 12.7 18.8 24.7 a 35.0 8.77 499.0
::.it: ::::Y4i0R::::::':*.2iF::;:::,:;4:;5::::•9809'::1 .6::' _
.... .. .::9'10:.. ....... ......
9.02 508.4
.... ................... .
..... .......... '...... .... . . •2 . . • ,•
. . .:'AVERAGE .19.2 16.4 [ 1 0,0 16.1 18.8 4.3 48.7
1 •
...,....,:4IAXllklidt::..•....., ::‘iii ':1>i;$;: . .T'• :::.4.4::.i:•:•.. i:,_•.:::
MINIMUM 16.6 13.5 7.0 <24.0 11.0 16.7 10.0 I8.0 8.86 412.0
::i.•::.
Monthly Limit I 40 MOD 28u0/L 25myL 30myL 200c/100ml
IDEM Fore MR-1(8/93)

EFFLUENT I
NPDES PERMIT NO.NC0024911 DISCHARGE NO. 103 MONTH:April YEAR: 2012 i
FACILITY NAME:Metropolitan Sewerage District ' CLASS 4 COUNTY:Buncombe
( ERATOR IN RESPONSIBLE CHARGE(ORC):Dennis Lance_ GRADE 4 Certification No. 10773
I
..iRTIFIED LABORATORIES(1)Pace Analytical Services Inc.Certification No.40 (2)Meritech Certification No. 165
(List eddilonal laboratories on the backsfdofpage 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY
Mall ORIGINAL and ONE COPY to: c r 4% 7//.'_
I
ATTN:CENTRAL FILES X C 1 ��%
DIVISION OF WATER QUALITY (SIG TORE OF OPERA •R IN R IBL CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY REPORT IS ACCURATE
RALEIGH,NC 27899-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60060 00010 00400 60080 00310 60082 00810 00530 31818 00300 00096 00720
i s FLOW
w slI
o o i INF p8r c H ' ` € `
0
u a °m z a o� 11 0
o _ a 1- • '
NRe Nab YIB MGO C UNtTB BA MOIL MOIL MOA. MO& 1110041. MOB. BMW 508.
.. ':i.::::'1$:2:::'..... ....... •::::::::.::i::................ ......:::: ............ ........ .. .:::9c(li::::::....... ......:
:�:q�:��.:-:24U0�::�'::'271':::::::::::::i.:::.**:'�'IB
2 2400 24 Y 18.4 18.9 7.3 <24.0 13.8 17.4 6 24.0 6 27.0 8.40 471.0
. . .. . ;: .;.
........... ... . .. .. . .......
4 2400 24 Y 17.8 17.2 7.3 <24.0 13.9 zs 17.4 23.7 a 40.0 8.19 498.0
: �
:::*:::.:::*400:: :::::P... �N�:
....▪ Y•:�:�:�::2..4•,.. . :::::*ii::.: . .�:d :�:::�:::�::;:::::::::::::":4,1i::::, :::�::�:::;t9:�:::::..:
, ..•.1ti1'..•.... .. .. .a::::::B:Ad:*::::*i... .. ....
8 2400 24 B 34.6 Holiday
:'l•' 44• 00: s'
8 2400 24 B 20.5 16.5 8.80
: :•'•:
..:::2ia$U :::••:::24:::: :::::�Y:� :: ::4Ya}':: '1'1t;2::' :;<+3:•::::i+24:�:: '......] ... :::44:7::}::... :::i :a::: .... I
2400 24 Y 20.0 18.3 7.3 <24.0 17.6 18.2 a 23.0 8.0 8.81 477.0
:i:(:: .::?Aiiii�:...:�Ad:. ..:•:t• f�:.....$.4�:..6.��:.:�f:4�: ::4C'�.8:� .....:�3:•:•:-:...3.$�:'�'•... .�:�l'0:�::�>. .. •:-:-:5411:•:•:
12 2400 24 Y 18.7 16.1 7.1 24.6 13.2 17.6 s 23.0 a 12.0 8.77 439.0
::1
14 2400 24 B 18.2 17.0 8.48
...... .... ..... :: : ............
18 2400 24 Y 18.6 17.3 7.3 33.0 11.8 16.3 20.5 164.0 8.82 468.0
:4r: :::4t4G'ti•:::::::::iii ::.::::ii: :::i:;:ii:uf::::ir.;t:: :ira::• ::: i. :: ...........r :i><A:':::'... :::48c3:i:::b. •.::.rl2.O: :::Se::::::444. .. ..
18 2400 24 Y 60.2 15.8 7.0 <24.0 19.4 10.3 6 47.0 >240.0 8.06 280.0
::lli�:::::::2400::::::::::k4::::::::::::/:::::•::::284:: :�4.. .::'�� . :::04,0,:: ...... ... .::'4il.., .... .::t(:�1 ::•. 3:::::::i0::::. •y:
:'i
20 2400 24 Y 22.7 16.9 7.3 <24.0 11.5 11.4 6 27.0 0 12.0 8.63 432.0
22 2400 24 B 20.3 17.1 8.62
}73:.: ;::2400::::-::*:}26f::::::%:*:*:-:::i8a<'::•:t0:;i::::::7:4'::•.. Y4.0:_.. .. .. 'MOA::.::• '•'75A::: '-:Ygi{ '..4;..•r.i10. . :::Il Q':..
24 2400 24 Y 19.5 18.0 7.3 <24.0 12.8 16.7 s 23.16 42.0 8.68 460.0
:::::
::26::'::.2'AUO:: ::P.4'::::'..fiY:� ::::::2b:$::::49c9:: ::iri2::: :::#24a3f::•::....:..': �:::44;9: ::....)::i$:i:::::....•:2AT.•: .:...:•.1 ..
28 2400 24 Y 23.5 17.1 7.3 <24.0 13.4 18.9 a 31.4118.0 8.68 435.5
:j:' :::. .;
• .::..:::::.
28 2400 24 B 20.1 17.3
960
30 2400 24 Y 20.3 18.1 7.3 <24.0 13.1 15.8 26.0 27.0 8.27 467.0
I
AVERAGE ' -.22.1 16.9 6.6 15.0 15.7 27.1 3 .1
-•'8.88'. 458.6 1
.
•
•
....,:�:tNAjcla►(4M:i.;i:..i* ..b4:��i16:x.:.:z;a::::::ii:o:i: '...... ... :::;:$... .....:::-i8:3i:.;i::::;:::::_SBA::.::::...:::Ai
MINIMUM 17.8 16.8 7.0 24.6 9.2 8.4 .18.7 8.0 6.06 280.0
MontMy Limit I 40 MOD 28u0I1. .•.26491L .•30498- 200d100ml Il
DEM Form MR-1(8/93)

I ✓' EFFLUENT
1
NPDES PERMIT NO.NC0024911 DISCHARGE NO. 103 MONTH:May YEAR: 2012
FACILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
I ( /PERATOR IN RESPONSIBLE CHARGE(ORC):Dennis Lance_ GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No. 165
(List additional laboratories on the backside/page 2 of this form) 1
I CHECK BOX IF ORC HAS CHANGED
PERSON(S)COLLECT!i, . ' 14 PLES: OPERATORS/PACE LABORATORY i
Mao ORIGINAL and ONE COPY to: ��
ATTN:CENTRAL FILES X P4 L. /� , ,
DIVISION OF WATER QUALITY (SI _;, s F OPERATOR IN RESPONSIBLE CHARGE) DATE
I 1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699.1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60050 00010 00400 60060 00310 80082 00610 00530 31916 00900 00085 00720
II >< FLOW N
In. 1�1 dt
o INf o c .- •G c c m ` g- c k
8 E y �,,u E = 0 N 5 0 U !E o ¢m E a g g_ c P 4 2 m
p g $ o a a 9 re m c1N `�•�• k O ,� E p�` i
I c
i •
HRS HRS YID MOD F c UNITS ug1. MOIL MGIL MOI& Mon. 10100ML MOIL uSIGM AGA.
•'•B'' : .. ::. •6' .::.:.7i89:e:::......
:::�::�' �:2400::::�::: 27i:�::::::�:lf�:�::::::::19:i:::::18:4':•::::7:$:::�:::�Y4.U:•r:•:•;•:•::•::....::�.'IL:7�:�::: .. :•:'I$r2::::�....:::24:6 ::'::.. .. B.U�:�'�' '''$.71 .
I2 • 2400 24 Y 19.2 18.0 7.3 <24.0 14.7 17.7.3: s 28.1 40.0 8.39 613.0
• ;:}
�:� �::�r:��lfd:�:�:� �:34��::'..�:�Y:�:�:�:�::.46':1:�:46:4:-':�:`�;>.I'�' 24:$�::�...... ... :�:98;.{:�:��:...r:�36:$�:�'...... .1:::::::.. ::.4 .. .. .. t .....
4 2400 24 Y 18.4 18.8 7.3 <24.0 12.2 17.2 27.2 33.0 8.43 600.0
.r.
6 2400 24 B 17.9 19.2 7.98
:.-..2413.0..:,' ..
:�:9-}-'-'-'0-'-'-'•:-:-::¢ : '-'0•'-'-'":-:-:-'-'-:-:-:•:}Z�:•}•:?{•Y•:•::•: '�6:8•:}:�8:0-:'�:�7:8�:�;.. Y4.0}.' - ;:y2:B�}':�'e 17;11:::• .,.�;gr:;::• �' `. :?$pY71:�:�::-'.'-'-'-'-'.'•-'-:•:•:-:-:-:-
...T.- �' .... ,
8 2400 24 V 20.0 19.1 7.3 <24.0 11.1 8 17.7 26.2 a 73.0 8.21 626.0
... ;:;••i':p:;::
I
.''4;3•:�::�:b :�:�'�lf:6��'�:-i'-:•'�2fi:4::::::::;3•:::-:43;0 : :•..:.:....):iii.:::. ..4 $. ..........
( 9:�:'r:�3AOOr:•:"'r:it4�}::..�:��:�: �:��:3:0;3:_:19;'I} �:i!�0' 24:9:?:::;:;:;:;�:; :;::�:.1 ..
10 2400 24 Y 18.8 18.4 7.3 <24.0 16.6 17.3 27.2 3.0 7.96 606.0
.•r.•
i 'rii::-:-:::4499:::::::'34'. ...::Y:..,:::19:4:::::$ :.::t4:: .::51.4::•...... ....:::::10:::::•:•:•::•:::kigi... $ :
0::',•,•..•,.
I12 2400 24 B 17.6 18.8 8.20
O ..:::: :::8;94:::::::..... .
14 2400 24 Y 28.6 18.4 7.3 <24.0 14.0 16.7 24.6 112.0 8.27 410.0
I
:•:x ::m6:::. ..•:33.. .. ::•33:Q .:.:6UU:::.:::.... ':49•::: :42 0::::.
�:1fr::'.;'r246D:;:-::::�:24`'',..;ii.. ';{22;3: :16:4}-:�'q:7:�: _ 24J(C�' .. .. 'T:•: �::;'.' . . '�'$
.::::i
' 16 2400 24 Y 20.6 18.6 7.0 <24.0 16.6 14.7 23.0 27.0 8.10 485.0
:*.:It.:'.. :24U: :::::::211::::i: :::Y::::::::::20:$:::4k?::i:e.::'.:::<zid::::.:::::?::::::.... ::i:ii:¢.:.::'... :::as;t::::' . :•:24.0:•:•::::e::: .. ... . .. . ..
18 2400 24 Y 23.6 18.7 7.0 <24.0 14.2 a 16.7 5 28.7 1.0 8.05 458.0
...•..:..•.:•::.
:1 '
20 2400 24 B 18.9' 18.9 7.93I
� :'''
::: :e:::::::tf,20:::::;:::$410.::::::::::::::::::
22 2400 24 Y 20.6 19.0 7.2 <24.0 14.4 16.1 26.0 a 28.0 8.08 480.0
:
:•:46: : :.:.:>.:-:.:21.4:•:.:"��'� 362.0 :':7:91:'::'. 600:0•:••:::•::::::::::
I
:-73:::: :2400.:::�...:44:•::-:•:-:•*-:::::-:}28:8_:??�9:2.:�'r7:'[.:-; .-Y44}::::•:::::•:•::•:•:-: �'�Yi1:9•�:,� 7�' •�
24 2400 24 Y 22.6 18.9 7.0 <24.0 >37.9 20.9 13.6 5 34.6 36.0 8.28 344.3 <6.0
::.:: 4••;d::::
''.:**ii::.:.�:i7.AU :Y.4
U: :��:� i:i:: �:::�Y:::i::::':20;ai:::4
: 9;i{: i:2;2=:r:�Y4&::�::i:::i 'i' i:::::.: :i:94;6 :�'e
:::�: '�: ::lA. .. .. :.p :• :::8
2400 24 B 19.0 20.1 7.87
:. ,.,.
126
. 411 .�.-
28 2400 24 B 18.6 Holiday 1
::44::::::::2400:::::::.::24::,:•::::::11:::::::::::M:::I0:?:: •:_74;;;•••414,0.L•••:•:•:•:•:,:•:•:.::::14:7:::::::•::;_::::•1B,.. v... .. ••••:11253•X• ,: >B.2 .. ..24. p::; ,
I30 2400 24 Y 20.4 19.9 7.2 <24.0 12.9 18.0 25.0 24.0 7.91 469.0
::Si%I::::.::4,1UU::?:::: 4::'.::::::::4:::::*::9$:8:;::%J9:3::;:::i:2::::;:ii24:,.•:•..... .. :::4ff:Z:: *..•?:;:h6:8:?...:sfy:::20:Er:?':;' 2 .04':
.... .................... ................ ......,... '• . 16.3 26.4 30.18.16480.60.0
• • • •. . .• . '• • •. •
I
i AVERAGE 20.2 19.0 r 1 37.914.2
;'
•.........:::Mi47udtUM:::::��:•:•: .:•::::::40::::'21:1;:1:: .
. . _ .�4��,..3.9; x:_::::t'0'6:: •:,i::411c4: •:.•:.•:.•34... :•:•:-:::02;0::::.. ..: W.:•':•':-:ii4.0:::::..biil::::
MINIMUM 17.8 18.0 7.0 <24.0 >37.9 11.1 13.6 17.6 1.0 7.66 344.3 <6.0
:. :::.:
I
Monthly Limit I 40 MGD 28uG/L 25m9/L 30ngIL 200cl100mI 22uG/UD
IDEM Form MR4(8/83) .

EFFLUENT I
NPDES PERMIT NO.NC0024911 DISCHARGE NO.103 MONTH:June YEAR: 2012
FACILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
'ERATOR IN RESPONSIBLE CHARGE(CRC):Peter Weed_ GRADE 4 Certification No. 10773
.,IRTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.4Q (2)Meritech Certification No. 165
(Usk additional laboratories on the bedside/page 2 of this form)
CHECK BOX IF ORC HAS CHANGED 17 PERSON(S)COLLECTING LES: OPERATORS/PACE LABORATORY
TORIGINAL
ATX • 7 mss/2'
ATTN:CENTRAL FILES
DIVISION OF WATER QUALITY (SIG TUR OF OPERATOR IN RESPONSIBLE CHARGE) DATE
1817 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27899-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60050 00010 00400 60060 00310 60062 00610 00530 31616 00300 00095 00720
FLOW g
U c to INF ❑ 3y s pV ` . € a I
e C' S i N 0 CoIF, gill: O OS g C
0 ao n e a 1 0 gt3 g E1 .9 g V $ 2 V U
c c > � ysm g co d a ase a ox coil Q i a c c�
o g P. d;�
1
14R8 a Yal MOD C 8 MGA MOA 140& e/100ML MILL r&CM WM.
MI ::2400•:•:••::::2ii::: :::$:::::::::273:4•® :::i. : 111�.:.•'::Q:.:•:®:•:92:•:1 1•..:. 3..0.:• :X98.•3:3 :: 3 i : ::.:::: .
2400 24 B 19.8
:::3::::.:::2.006:::::• :'i4::: :..:;�:::::::::16,0: ::49 4: ...... ....... ... 4 :.: ' i
:::: ::::::: :::::::: •7.4 :':':':':.
1111
4 2400 24 Y 18.4 19.5 7.3 <24.0 11.8 17.7 18.4 n 398.0 II 8.32 688.0
:a�:•.:::44D4:::'••:•:$4::. ::Y::•:•:..:40:0:::fix:::: 4:•: ;i:544:0•: :..... ::..43:3 • '.:184 :::�
8 2400 24 Y 18.8 19.9 7.2 <24.0 17.0 18.2 23.8 112.0 8.12 629.0
:7::::::::4400•::• :::•24:: •..•:•:lr:::::::::18:4:::•19:8:::::7:4::: ::: Y4.Q:: :.... .::!(3:2:::::-.:: :::i i::: ::::29e::?:: :::68:0::::: :::8;70:.:::.:::679:0:: ....
8 2400 24 Y 17.7 19.8 7.3 <24.0 10.3 18.2 24.4 8.0 8.06 662.0
.:::2 400::::: ::::44: .:::::8:: ::::::9 Zc9 ::49:8::::....:..
...... ..... ...... .......... ....... ....... .:::7:98::::: :............
2400 24 B 17.6 20.0 7.58
:ii:::•:::244ti:::: . :4::: :..::€::::::i9;
.. .q•:::2!)�i::::�:t:••:�: ::ix4.o:: :•:::::::::: ::::ii:3::::�' :::QA;6::: ::::i2:4::::: :�:i•:�:�:�: ::'9:�� :::064;4:::''
2400 24 Y 21.6 20.3 6.9 <24.0 16.1 - 19.5 ■ 29.2 a 29.0 ■ 8.22 . 439.0
:::24.06:::::• . ..:::Y::;•.'.::: s;6:::: :::y..' :::t'."o:: .. .....
:: .. : ': : 1 :1::: . :::164::: :::41,$: ': :::9 :: :::6; i:
.•. ••: ::•:444.91:..•:•:•:•:•:•::
2400 24 Y 18.13 20.3 7.4 <24.0 . 12.3 18.8 22.0 19.0 III 8.10 636.0
::16::':::23)00: ::'::::Si'..::: ::18;7:::¢0.19:: ::-b24 39:0:: :::'•22.4:}: ::%16:0::::' :::7:88:>:: :::8200:::'
18 2400 24 17.9 20.9 7.80
:'IT:: :::240ii*:.::::::24:::. Aix:..:16:4:: :::*:::.:?....:':::: :::::: :' ' :•:• :::�r39:•::•: ':''''''' '•
'• •.:..: .111 :.
2400 • Y MI 20.8 ® <24.0 _. 11.8 - 19.9 III 21.8 ■ 13.0 1 8.12 660.0
:41I::':::::A400:::::. zY::.. ::8 :0: :.20:0'::::i:d:::.::K?/{' :: 11.::88;9::::111::::201.::: ::23 . :11:.
: :::f:if:::: •:7;88::::::;4f3A::
20 2400 24 Y 17.8 20.8 7.3 <24.0 18.1 20.7' :: 26.2 7.0 8.16 642.0
1'•::::2402:: ::::$4:: .
" :::3'•::::`•':10;3:'::$:IYL : c24.4:: :::i$::::: :'};'
:: 4:61:: ::: .x.:::: :::iq;4::::: :::6:Ui::::: :::668;4:::*i::::::::::::
22 2400 24 Y 20.4 21.1 7.1 <24.0 18.6 20.1 23.2 40.0 8.35 545.0
::23:::':::'!1UG:::::::271::: . :::9: :::::.'9:: ::20:0:::: ...X......*:.:::.:.: .
.
� R' - - ... ..... ... :::¢;117::::: :....... . ..... II
24 2400 24 8 17.9 21.7 7.98
::4::.:::id96::•:••:::ort::: ...:::8:::::::::1'4ie::::443.:1::.::'{i5.::.:::fs24Jih: .:::$:4:::: :iii::: ::::22:9::::: r::7:U: : ::::8:88::::::::649-0:::::.......
28 2400 24 B 17.4 21.1 7.2 <24.0 20.2 19.9 21.0 8.0 7.93 663.0
:i:: ..::$ao4::, I4::. .,:*:,. •::I7;8::4o;8:: :: A:. ::: 4.o:: ...,. :14;4:: :20;$::.,:d: :::::.2.24::::: .. .::1$;4;:: •:063:4::
28 2400 24 B 17.2 20.8 7.4 <24.0 18.0 21.1 s 26.2 6.0 7.98 830.0
:7:1:: ::: •'••••••••••
:2::•: : o:: :::$61. :':108;4:::' :::x;a9::::: :::44#:0�':•:•:-:•:•:•:••
30 2400 24 8 17.2 21.8 7.98
AVERAGE ••18.62. .•
• 0.6
0.0 •••14.0.. .•.19.4,•• •..23.2•. ..•21.7•. •..8.00.•' ...643.3•.•
III
........,:::MAXIMUM::::::::;:::: :::::34:P::::**1;1:: :.:y:4:::::: $40:: :::20:$;::: :::df;4::: .::::::iio...:* ::::.0.00:::: .:::0'34:Z. :::4x4:0:::
MINIMUM 17.1 19.2 5.9 <24.0 9.4 16.6 18.4 6.0 7.39 437.0
CO %ci.• ... ......... :::::::::: .:;'i::::::::c::::::,::::r:::::
Monthly Umlt 40 MG. 28uG/L 26moJL 30m0/1. 200c/100m1
OEM Form MR-1(8/63) 1
i

I
EFFLUENT
I .
NPDES PERMIT NO,NC0024911 • DISCHARGE NO. 103 MONTH:July YEAR: 2012
CILITY NAME:Metrorolitan Sewerage District CLASS 4 COUNTY:Buncombe
ERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773 •
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No. 165
psi additional laboratories on the backside/page 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY
Mab ORIGINAL end ONE COPY to: ,rI. -2 -,e-
ATTN:CENTRAL FILES XI
DMSION OF WATER QUALITY (SIGN LK
OF OPERATOR IN RESPONSIBLE CHARGE) DATE.
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
I F550F06❑0 00010 00400 50090 00310 8‘00082 00610 • 00530 31016 ` 00300 00095 00720
FLOW 9
n' ItJ a o A a € '$ i±
go cEFi 1u U = o u m i m `. d I 10 u o v
Q `y F O ~ s3 n O O ,it N S E y �l U '" 13
Co V
Im d2 Q �0: Q $ o 0� U
•
HRS FM YA MOD C UMTS uSA. MOIL MOA. MGA. MOIL 0/100ML ...MOA......u&CM.. uGe.
.. ......... ....... .. .:•:8:30::.;..•
I :�:1::: :::2400:�:�:::::28:::;'::�:::�:[3�:::-:�::�:18:7:'. 2. �.;;.;., r :;.;.;. ;.;.;.; .;:;:;. :•:•
2 2400 24 Y .1.26.0 ..21:0......7..0.......<24.0............<24.0. 16.2. ...20.6...5 31.2 74.0 8.03 368.0
:•.•.
•'>i�d•::�;:2;d•:':::#•3.;.:.;�4:k:::�...... .... :%I'3;1(:: '.....:::ld:4:::�:d....i3:k:::::::
III 4 2400 24 B 17.7 23.0 Holltln 7.90
r:::::
6 2400 24 Y 19.0 21.3 7.3 <24.0 11.6 21.1 24.0 11.0 7.94 629.0
.4,''....*::.*::J:44:::..::::.:.24:.:':•:::a::.:::::17:8:: 4 •::::::::::.:i::::. _
.:•:•:'•:::•:•:::::. ......*:::::::::::::i$6:::::::
8 2400 24 B 17.3 23.2 8.30 _
, .
.'..::::..:±4.5.9::::::•:::24::�::::�::::Y::::::::::'I#:0 ::22:3::::::#if:::::::�24��::'.... :::�2:8::::::...::�2f:9:::::d•,:r:.:.,..22.11t::. .. r:9:6::::..:.::.::.:)'•.55::::.:
10 2400 24 Y 17.9 21.8 7.2 <24.0 12.3 22.4 a 21.3 42.0 7.82 605.0
:.,•::::
I :�i:l:::::::34ub: ::��:•:••:.::Y:•:•:::�i4:$::::4xi:::::��:3:::':::52t:o. ........•;:'v: .. ,
12 2400 24 Y 24.9 21.6 6.9 <24.0 17.6 s 13.6 a 40.8 16.0 _ 8.12 406.0
::12:;;:*09:::::::*•:•,•:•::::Y::;.'•:;:::z$:,f::::*j:9::::::7.:4 :: 49•.,• ..... ... ::::$;8::::: ..... ..,#•:.::c:\:::::: 4,*:::::•.x•::'::11..... .:::::: ; t::::• ,
14 2400 24 B 22.1 21.8 7.86
::::-.4.66::,::::i*::::::::::::::::::-
•'
I
16 2400 24 Y 20.6 22.1 7.1.. ••.<24.0 ..r,., ..13.8. •..14:0 • 28.0, 392.0 7.69 437.0
�� dA�'�::•... ::16,8::`�:��:�:�2Z:0:�:�::�.. .�:�36:U�:�:��:. .:�:#:88:� ::.
;:iii.::.:::440G:: :::::271::::::.:�:1r�::::':':�39:8::::Y'15:9::::::7:8•:••:•: 24:b.• ...... .....'..'i
18 2400 24 Y 19.3 21.8 7.2 <24.0 14.7 18.0 24.0a 7.0 7.90 509.0
�:i✓l<: ::�dd::.. ::::ii:::; ..::Y::... ::9$:7: 32•'�::::::i.:1::.:
.::�4:$:::...... ... .::4%k$:::::... ,::l8:() :::41i:1:�::x4:�:::".... .
20 2400 24 Y 23.3 21.6 7.0 <24.0 15.3 17.8 s 27.6 15.0 s 7.72 452.0
22 2400 24 8 18.7 22.4 7.90
I ,;.;.;:
.... �.3:1� ::� :�:'f 9:�::�e. .540: ;::•
}73�•'...-.2400......:•:•24:{;::::..::K.....:.:•!19:1!x:{22:4':}}7:2.:•;:•:<Y4.4:•�:•:.... '�'i.... .0,. ... :.:.:88.0..-:;:...:;:,:•:7A4:::.:::.:6144::.:'.
24 2400 24 Y 19.6 22.5 7.2 <24.0 14.9 17.9 s 28.0 7.79 660.0
: :::::•.•.• :.,::: ':•633,0• • ...
'•9:2:�::ii:::.:�:�:#:3:�:�:44�•..•...... :�:92c3:�:��:...~:�38:4�:••......2210•:•:••:..:�:iF:24b:0:�::�:�::�.�:�7:#t�:�:'�.. ......
26 2400 24 Y 18.9 23.0 7.1 <24.0 13.1 17.9 a 24.4 108.0 7.78 536.0
:•:
}�;::::::2441?:''r:•:::::9d;:: :-lf;;$�:}'�3
.. :�:�:�:�: ;�::::}f:3::-::::424A:•e'r'r}::::::;>:•:: .:, • , ;�$!�':''� ,:;,.• ,t:4r}:'•, �:�T4
28 2400 24 B 18.6 23.0 7.3 80.0 7.70 677.0
30 2400 24 Y 18.0 22.6 7.2 <24.0 12.8 19.0 22.8 12.0 7.10 417.0
::39::::.::2i{dd ::::24•:•.:•.,•:•Y'.•:•:•:••:22:3.:22:4': :•l. ::• .-i24.9:::::: : . ..: :::41:2 18:7 ::d•\•::•22 E::•:••:.. 348.0 .-..:::8:96•:•:•.:66L.0::::.......
'
AVERAGE 20.1 22.3 0.0 13.3 18.0 26.0 28.9 7.88 616.8
,•........::N1AX(M4M::......,.., :;324::%Ol7:: .:?,4::..,.x4*.:::•:•,•..:•;1;•:-�X .. ��•:�. '�'''•:•:4 d8:•: '• , ,
MINIMUM 18.7 21.0 6.9 <24.0 8.6 13.6 -21.3 4.0 8.95 366.0
''.6%..iiiiii:,kiiiiiit:.:.:*:::i:.:.,::::.'...::::::::.?..:.:.:.::.:.*:?..?.....*:iii: :::::.4.;:.?:;....•.?...6.:.:::.I
:•:v::•:•::• :::::•::•:'
Monthly Limit 40 MGD 2800/1 2.5159/L 30m9IL 2005/100n5 - -
IDEM Form MR-1(8193) . •

vas t
,a c? EFFLUENT
I
NPDES PERMIT NO.NC0024911 DISCHARGE NO.103 MONTH:August YEAR: 2012
f -AGILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
PERATOR IN RESPONSIBLE CHARGE(ORC):Dennis LanceGRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services. Inc.Certification No.40 (2)Meritech Certification No. 165
(List additional laboratories on the badcsIde/paye 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY
Mao ORIGINAL and ONE COPY to: //
ATTN:CENTRAL FILES X ti. 7-2/ - /7-----
DIVISION
Z�
DIVISION OF WATER QUALITY (SIGNATURE OPERATOR IN RES SIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
•
-r 50050 00010 00400 50060 00310 • 60092 00610 00530 31616 00300 00065 00720
Y FLOW N
Q LS FFF M C
u INF•O m o U 3
U N .0` C c . •• j
9 c E V N 0 !� o m ce a3 u p d
a e.. O o. �, o a f0°co a E % 19 a ag a ,,,° A; v
O s a,
C
gE O o v m (Y v d Rk Q 9a !Fg G� V
O u S F LL7
t-
.
NRS Ma Via 100 C UMTS ua&. MOA. MOA. MOIL MOIL e/1O0Ai MOIL 551CM uCA.
:-:9-:-•.:•:2400-:-:.::-:-2A:•:• :-Y-:•:• ::-'19:9-::.:iii::::-6:g•:-::*::' .o::':.:::::::*:?::::,,:%:.::*:-:
.::2a:e':::::'... :*[i!:li:::::1r:,•:•:3'6.8:•:•::: :: 220.0 .. .:::;rc20:::i::::715T:Q:::::......
2 2400 24 Y 18.5 22.8 6.9 <24.0 0.... 13.5 15.3 21.6 33.0 7.77 472.0
:.:3.::.• •
:::1 .. .....:;:1$:'6:::::6:•:.:::22.ii:::::::...:..:31h6:::::::....::-1:$$:?:::::::4liZA:::::....
4 2400 24 B 22.7 23.0 7.90
111
::::.04:::
.4::
6 2400 24 Y 18.4 23.0 7.1 <24.0 4 9.9 18.1 21.6 27.0 7.51 502.0
:•:7•:••':•:2400•:.:•::•:•2': :. .;.1 .
::Y�'r'� ::�.'9:8;::;22:3�::�:�i:T� � . 240: :' .. ....
... .-. 4'� - - -... .1. .. .... _�•14:8�:; :• .. :::179Y::e:":,:_44:6}}::' ::::: 1:b:::::::::::::::::: 04::_::.:::::A88:Q:},' .....
8 2400 24 Y 18.9 23.0 7.1 <24.0 _ 11.3 18.1 a 16.3 32.0 7.66 510.0
Y;::• .:::i::•:•'.•
.. 4: ..:.•]r:*;::•:49:8: ::22c7::*::::'Si7:::.:::i248f: ::If9:fi:::'.:.. :::%14ci:::: ....:::l6:6:::::E: :::::2i;ii::::::..:::tt't3tOcU:::?:::::•.:::7:6U: ::•:::6iS9+U::::::55:00:•. I
10 2400 24 Y 19.6 22.8 7.3 <24.0 18.2 18.9 a 23.6 204.0 7.45 535.0
::1i::
12 2400 24 B 17.2 22.7 >47.0 2,4 17.4 a 21.0 7.80
G''
;:::.:**01:.::.:'..... :�.�:;:�:::::Y:::�::� ::ii.: :.:::ix:;;::::::i.:1:.::.:::.:4;0;.::Z4.. ..... :::•:::.:3.41.,t1:::?,R:::' ::::rd;ti:::::i:_,::::;.4$,i.:::;:'; :;::hao;4...;•.::d:::::A49::.:: ::42+t:4:::::.......
14 2400 24Y 17.6 22.6 7.2 <24.0 11.6 18.0 22.0 46.0 a 7.68 530.0 _
's.:.'
':�4:.;.: .4Yee::'.:222c3'::;:;gc7::: *:::.E3•lt:. . .. .. :':98c6:::%:'.. ':�78:8'::::d' ' ':42:4':': :...:::20'U:::�::� ::�7:6l3':�:� :. ..
_ '' .. •'928:0''':' --
16 2400 24 Y 17.4 22.4 7.2 <24.0 14.8 a 17.4 a 23.2 17.0 7.77 676.0
:.`17::•::;: 4'b;:: ::
0 .. •:211::" ::; ;:;:;::
.... ....::i7:Z:::'22:6:::::: :8i:: :•:�Y4.0::`.::.... ....:: i : :::::li::.:':t7:6::::•. :::;?4.1:' : '.. .:::'9nU::::::::. .:•:2c68:::•: •:•570:Q::••:......
18 2400 24 B 17.1 22.7 7.45
a'
2400
24 Y 17.3 21.4 ..7.0. <24.0' ...12.6••• ••17.7. •.6.. •22.4 . 40.0 . 7.60 .'538.0.
4 :"..::::::\;:i::.::.::, :x':
'r:i4'.
..ll,�{:�RR,4�::�:�x;��:� ..R.•4'�. �: �:�:�:�:'•.�:�y;...,$�::,''..::_i:•1.i_:;;::.. ::::::: :ii.:::::.,:::',•.:::::::i4:,0::.::.::••.:•:: .:::>':46:::::;:::ay.i0:::::::::::::;:::;:
22 2400 24 Y 17.6 22.6 7.2 <24.0 12.6 18.7 a 23.2 >320.0 7.47 537.0
: 400:;:;: :�:- ' 'Y'�'�'�::�
�:� •';:2 :;�:24 � �� .'.IB:6_:::22:9•a:;7a•'• i..... iii.)::.:.i:::::::_:::::.....:}:j5:¢;:::.;.:v::•:::1i6}:::e.•::x:43.8:?:::• 273.0 -- :::vTg93::?:}:_7x,78:4.;,::::::::.}:.::
24 2400 24 Y 17.5 22.7 7.2 <24.0 18.1 17.9 a 24.4 <1.0 7.72 682.0
:2Cr::::::27i00':•:•::•:•p4:'::'' .
26 2400 24 B 16.5 26.1 6.72
28 2400 24 Y 15.8 22.3 7.2 <24.0 14.3 18.4 a 23.2 1.0 7.89 640.0
,:2* 2..... .;:Z4:.::v;.:::. .... •.1.R.•.• ..i.R:.:,:::,:.iii*.....:*
i<:..::...4 .... ... ::13:d;:;::; :•:1873:;:::q::''.�:�1�$i8:�•�� ....:�:4$�b:�:�;;::::::: )t;t(�::.•....$$$:4:�::'...
5 �•
30 2400 24 Y 17.7 22.1 7.1 <24.0 _ 12.3 a 18.9 a,e 16.8 <1.0 v 7.40 550.0
•:•.I.•:•:.:•
1' ::�2Atiti•:;:;::::'it4::::•'..�:�r:�:�:�:��:%i;::T:��:42:9:��:�:�:o:�::�:�t23A•: • .... .�:�ii:d: ��::;; :';•• '''i:'::� •�:;::*:::�:�:':*
y•:: :• •��ye. .e�::�.�:�sea� :��:....�:�:i:o�:�:�::�....�:�i:iib�:�:��:�:issuo..........
AVERAGE .
17.9. 22.
9.6. :..
••'• •:•.•.•.•.•.•.•.•.•.•..•.•.•.•.•...•.•.•. ..•.•.•....•...16.6
.•..•.•.•. .•.•.•.•.•.
' 1 1 17.9•..•.•. 22.2• •.•22.3 7.61: •••530.1 0.0 .
•, ,.;:IMAk NtQ1N::;::: :::•:•:•:•:•:.::ii:x:.i:3e.. .. ::::..X44• . • $c�• �•'d: ;:; :.•.
• •,f tt:�� .. �'�.�•U;��:,. .�'��dcR�•�'. ..�e;a:�:�:��:.... 3�O.:d::;'.:::::'..:.6:Riii:i:':::::$#RA::::::$$:dd:�:
MINIMUM 15.0 21.4 6.9 <24.0 19.6 9.9 15.3 18.3 <1.0 6.72 487.0 <5.00
....:
ii.....iiiiiiii.:i6:1..f.P.ta0Y::::::::1::::::::::::::::::,:::::::::::::::A::!: ::::0;::::::::::0::::::;:::::: ::::;:::::::::::::P:::::;::::::::::::::!:::::.::::::;::::::::4:;::::::;::::::::::::9::::::::::::::::::::1:::::::::::::0::::::::::::0:::::: i
Monthly Limit I 40 MOD 28u3/L 25mg/I 30001. 2oec/1Domt 2203/1/0
DEM Form MR-1(8/93)

>a E. j EFFLUENT
Y.
r NPDES PERMIT NO.JVC0024911 DISCHARGE NO. 103 MONTH:September YEAR: 2012
I '` rACILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
( ,PERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No. 165
(Ust additional laboratories on the backside&page 2 of this form)
CHECK BOX IF ORC HAS CHANGEDI
PERSON(S)COLLECTIN SA�PLES: OPERATORS/PACE LABORATORY
Mel ORIGINAL and ONE COPY to:
ATTN:CENTRAL FILES X 1 iJ� __. `tJ�Zy/J Z
DIVISION OF WATER QUALITY (SIG Hr4m I IRE OF OPERATOR IN RESPONSIBLE CHARGE) ATE
I1817 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27899.1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60050 00010 00400 60080 00310 80082 00610 . 00630 31816 00300 03095 00720
I FLOWf , a
N FFFE C
V WF ❑ 3 c » !_ c a m 21 m a k.
CC C v N !E 0 O O °r !E a' rte-. u a Z
a o i. oo ', a '3' A 3 °Ag v
CC IL.fp
F1.!,"
ce
y ;O O �N a ig a HK d 1 p a V
Q ESE m O
,
HRS HAS YA! _.MGD C UMTS usA.....MG/L. Mbit MOA MOA. MPW100M. MOA ue/CM uGA
::•}. . • 2A00.•.•.. •7d:':•.•.•.B:•::.:.16.$•..•.YY:6.;:::.:.:.:::.:•:::.i:i:i:i:i::::::::::.::::::: .•.\'.'.'.'.'.'.'.\':':'.':?............:::.:.:::::.:.::•:::::::::::::.........:::.:••.:.:•:::.i.:;::::.::.:: ::: .7.66'.'.'..'...............
2 2400 24 B 17.2 23.1 7.37
4 2400 24 Y 18.2 23.0 7.3 <24.0 12.1 18.1 17.6 2.0 a 7.86 634.0
:./•'
..
4d01::. ��: ...::Y::.. . i:�:3�%S:::...�':" 3'4.0::• .... .. %4:::: 'i :;:i.•. ;:;y.•.
8 2400 24 Y 17.8 22.7 7.3 <24.0 11.7 16.1 a 14.7 3.0 s 7.89 570.0
I
:::7:•::: :::'9'::•'•:::56.9:':'YY ::...........4.4.:::•:;:i:44:::: ... :r
.... ':'��00:•. ..•?+f.•.��' .. :: :�ai{2'.. :?j9:&:0a::':;..i8:0::}:}....{:eL'6:}:}.. .:}74:}}:}:487c0Y}i::::::::::::
I8 2400 24 B 16.9 23.5 7.50
%1:•..•
,: :i iii .'24':':'. :::9:::::'::•':i:6.1K::::22:Y:::•
tI':. .. . ..... ....... ...... ... ....... .............. ......... .. ........ .. ..:5.9'.1::
10 2400 24 Y 16.2 22.2 7.4 <24.0 14.3 20.6 15.0 <1.0 s 7.82 563.0
:::
'::113::•:':'�od•::. �::::�:�:�::.': ' �%s•
... ....:� ....Y:...:::mss: :.� ..a::..::'544;d::.....,. .... .::3A%7:. ... ::iA:4:: .....>36;i:>:'':.. .::.:gf,ti.:': .. .::fia4:::?:•:'eo3:d::::.......
I12 2400 24Y 18.3 22.6 7.4 <24.0 13.9 18.5 a 15.2 1.0 7.24 570.0
:E:::''':::::::..: :' :::.
14 2400 24 Y 18.3 22.1 7.4 <24.0 10.3 s 17.2 16.7 <1.0 7.49 648.0
v
I
18 2400 24 B 17.3 21.0 7.60
I:
•.E .. .:2 ... ...•.{ 4. ............. :::tG}::: '•... ::::19:'x2::..:3:::.::::Ill:a:::::::'.. .:::io:::•:::.. :::z3'1:::::•:::'s'aao:::•:.......
18 2400 24 Y 46.0 21.2 7.2 <24.0 17.7 18.1 a 18.3 >240.0 6.19 340.0
;::
:: �:: 444 ,•• 4:.
I
20 2400 24 Y 20.2 21.2 7.2 <24.0 6.7 11.8 9.8 <2.0 7.82 459.0
:I
22 2400 24 B 17.7 21.8 7.70
.. ':'R10. t=T<:>:::::; :'• .. •• - --- - - -• _ .. - ...... :}SOP::::;' .......
24 2400 24 Y 18.7 21.0 7.3 <24.0 8.6 18.7 9.8 a 1.0 7.60 530.0
r•I ;;.
28 2400 24 Y 17.2 21.2 7.2 <24.0 16.0 17.4 9.6 19.7 7.59 619.0
•.\•
28 2400 24 Y 17.7 21.7 7.3 <24.0 9.1 17.8 10.8 <1.0 7.88 621.0
130 2400 24 B 16.9 20.6 7.Y0
•:,' :•i:
......:'•AVERAGE::.......... ••18A- ::22:0::.. .... .........................
[['' •••0.0•: •.•11.8.• .•17.2•.
L 14.2 1.7 7.63 , .834.7
MINIMUM 16.8 20.6 7.1 <24.0 6.7 96 9.2 1.0 6.19 340.0 .
Monthly Umk 140 MGD 28u0/L 26mgA 30mg/L 200d100m1 22uGAlD
iDEM Form MR-1(8/93) • .

s EFFLUENT
I
E CO
: 1
-ES PERMIT NO.NC0024911 DISCHARGE NO.103 MONTH:October YEAR: 2012
.CI"TY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
'E :OR IN RESPONSIBLE CHARGE(ORC):peter Weed GRADE 4 Certification No. 10773
:RTIFIED LABORATORIES(1)Pace Analytical Services,Inc.Certification No.40 (2)Meritech Certification No. 165
additional laboratories on the backside/page 2 of this form)
ECK BOX IF ORC HAS CHANGED PERSON(S)COLLECT)N S PLES: OPERATORS� /PACE LABORATORY
I ORIGINAL and ONE COPY to: (' / (/ ///2.71y��
fit:CENTRAL FILES X l - 11//�U`•
ISION OF WATER QUALITY (SIGi7ATURE OF OPERATOR IN RESPONSIBLE CHARGE) DA
7 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
.EIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
50050 00010_ 00400 60080 00310 80082 00310_ 00530 91815 00300 00095 00720
FLOW
0 a F B 2 ,1 d 8 5
g.
O
INF m 0 - in ,gf C c i '�
N w E = c.) H 'E G v i o p0 IE all mm o h o 1 _
E.. F S 0. o �N E8 '� H 3 _v 3 -0 o
o TI o o z of r3 8 ° ra
Q igmo
IT
,
HRS MR8 WO MOD C UNITS ug& MOIL MU. MOIL MOA. k 5V100ML MG& uS/CM 901L
::::::::i466*.:::.:::::i.4:::--:.:-:8-:-:: ::-h9:7-:....2.'1:6-::-:-7:8::-::::<YS.O:•::::::::.:::i::......:.:a.'-"' ::1 0'-':":
'-9':.::-:-50 '0-:•-:......
2400 24 B 34.6 20.6 7.2 <24.0 11.7 16.6 12.0 105.0 8.13 351.0
....-:-2iidd:- :-::::14::•::::::::41::::::::::'2U:,:::1041::-:-:;!4 ::-:qtr.::....... ... ::4441:-::::•::::::::::04:•:••:•:-::•::::fiztt:::::::•:•:::::::ib::•:•::::::::::::1:FA::::••:•Ak;tid::::::•:•:•::::::: I/
2400 24 Y 19.1 21.0 7.4 <24.0 6.6 11.5 8.2 4.1 7.25 623.0
• •1 :•:•:•:•::1:124:::::16:,..._:•::::9A::::•:" . -•x43•-:':::-64s�:R :•.......
. ..�:�M1t)�:...:-a4.•.,•..:.Y•:....:.8:4-:;-�:0-:,:-�:3-: ;-:534:4........... � ,-;7,.,.. ' ... ....��:•� .
2400 24 B 18.0 21.0 7.10
}2400'' .-:2t4�:, ... - �• _ .... ... _. _ -
2400 24 Y 18.6 20.6 7.3 <24.0 8.8 16.6 9.8 4.1 a 7.22 618.0
-:•i:•'r:':...
'�90:-:�:�-:-:l24•.•.:..•.•11 -:-:-•:4Bi2:--:00cti:•-:•:'•2• -:-•24�-::....... ... x:44:9:-:--:....�:-78: •} .. }p•g:;::: i1 ..
• ':-fiitBO-•".'
2400 24 Y 17.7 20.6 7.3 <24.0 12.4 15.8 10.5 1.0 7.18 556.0 I
:•
(.::::::;i4uii:::::::::44:::;:::`:::1C:::: :A7:y::::144::::=i,3:::•:::4t44:.• :
:.... •.:•:•:•::i:-,.•::•;:..t........ :::0'e::::•a.....32.4::::::•.. .:::a.... .
2 2400 24 Y 17.6 20.7 7.3 <24.0 13.3 17.0 11.6 3.1 7.16 684.0
:-1-: ....::6@4-:. ...... .......
4 2400 24 B 17.4 20.0 7.10
'e•g:;::• .. '-ir::'-:-7:48::•:
S-:::::-�QR:�:�:;::,:¢4•.•:,•.•{.•Y-.:-:•:•:230'{:x:21:0'`:-:4,9:-::-:-c24�f-::•...... --:>.42;0}.�:':'•:''�:-�� - 'fi•,' }:�'$:•'•'•'-- -=:•q:4•'-'•' .... .- ':::.:144:::. - ---
3 2400 24 Y 18.6 20.2 7.3 <24.0 13.6 14.7 s 12.6 >7.4 7.14 628.0
'-'1`022'-:�':.1199:0 :'.......
l:~::�:240G::::�::.:.:ii.:...: .�
•. ::$:::*::�:i$3:: 2b:4:: 7: :�
8�:�� :<14.0:••:.... .......:::9:D:*::::8::::�:16:9::::�§:':.:�:i[U::::::'.. .:� :4:D:: ::::. ...
: i
B 2400 24 B 18.3 20.5 7.2 <24.0 8.3 21.7 s 10.8 2.0 7.01 636.0
-x' : :
::i.ii-':'-:::iii24A:-::-.. .
9-:..:-�lbl):�.. .�:�4-:..,.:�e9 ... -:4��3:- :;zb;d:- •-:x; '� 34th:....... ... :��. .. ...
3 2400 24 B 17.1 19.6 6.80
:.
i
•
2 2400 • 24 B 17.2 19.6 7.3 <24.0 9.6 18.4 9.4 4.1 6.96 693.0
. •:::•:7;14:•:•::•:•5150:0-::,•'.
3:-�' .. :�17:6�::�40:0-: :�B:i!-:--:-:tY4U:••......:•:•:•:•::•.......::12:2::.:� - ' :-:t9�6:-:.....;.:.:.40:2:•:.: ::2;Q}: •:::ii'
:-'2400::::`:-24':•.:• :;:�:;:;:�:� .. .. .::•
4' 2400 24 B 17.4 20.0 7.3 <24.0 9.0 e 19.1 10.2 2.0 7.02 611.0
.,... ..: .r...
5-::-:-::iiii0:-: --:-:124:`:: :•:$•:•:•:• 4C6:--:'120:71:-•:.:7,2:-::-:-1+2CEI.::'...... ... :-:QOce::••:.,.,...•:-]9:8-:--:•.•::::}0l::-:-:....-:-3:0-:•:-:'rti::-.. :•:•:•:•:•:•:•:
6 2400 24 B 17.7 20.3 7.2 <24.0 7.8 8 19.3 10.2 2.0 a 7.07 615.0
-:341211-: ::2... :;:::::%•:::::::.
:,:',z/.00 ;•:•:•:•:•:•:•:••:•:•:•:•:•:•:.
8 2400 24 B '17.7 18.8 8.10
'.:'-:•:•:. .
:-;' :'4b'o•:-:;:: -.•7:': ::-7:�• :-:t'�'�u:-*::::::::::::::.:::._:.::::::::-f, :�:11:R-::::• :tg:g::::• 6�•:.,.: 1.8:;:::• :-:�c�1-:-:--:�:4a13A--'�'
0 2400 24 Y 18.6 18.2 7.3 <24.0 9.4 a 18.2 10.4 1.0 a 7.63 553.0
1-::•.-:27109::-:--:-:Q4•.•..•..•.•Y:-:..:-::-:9'itOS::-:48:11:-:::;i<:71::::-:-7i2431f•. •.•:.•.•.•••'
:-9:6-:-: 4::: -y7:s-:--::1:::•:9.0:•:: :....:-2:0.:.:.::.....:7:18:;:: :624A:-::-.......
. . '.. .
AVERAGE 18.7 20.2 0.0
1 ..:....17..:I0
:•i::::•:
1
::.1 ... :6• :::-34:4: .�:Z;4::,• �::- -: '•i
MINIMUM 16.7 18.2 6.7 0.0 6.6 9.9 8.2 1.0 6.21 351.0
:•:•:•:•••••:•:•:- ._
rally limit 40 MGD 280G/L 26mglL 30mglL 2008/10089
DEM Form MR-1(8/93)
I ,

a EFFLUENT
0
NPDES PERMIT NO.NC0024911 DISCHARGE NO. 103 MONTH:November YEAR: 2012
'AGILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
JPERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE6 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services,Inc.Certification No.40 (2)Meritech Certification No. 165
(List additional laboratories on the backside/page 2 of this form) . .
CHECK BOX IF ORC HAS CHANGEDI
PERSON(S)COLLECTING - ' • '- S: OPE' 'TORS PACE LABORATORY
Mab ORIGINAL end ONE COPY lo: Z8 ��
�
ATTN:CENTRAL FILES x /P Tr/ OP �
DIVISION OF WATER QUALITY (SIGNA RE OF OPERATOR IN R�€SPONSI: - : ATE
I1817 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699.1817 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
tt77 60060 00010 00400 60060 00310 80082 00610 ' 00530 31815 00300 00095 00720
• O FFF 7 C c
U INF oI
d 0 - o y ,@ m E cA4a QrCi Vo r ii'
�v '`'E uX '�4 0 o�� I 0
K Ja N O 1K QSm+ a �O f�
H .
Has HRa YIB MOD 1 C UNITS mil MOIL 1104. 1.101. MDA- MPNI10099. MA. 911,0M u06.
I •:•r::.....• .:•:T:><6:•:•.::•620:0•:•:......
:4�:�:::::2400::: ::::�2A:: ::::::1f�:::�:�: :�'18:9::::'IE.8::�::7:9:::: :<YS.U::r:::�:�: �:::i:.::::::.:�:ic7::: :•... :::'[7:5::::•.. •8 •:•:•': .:CI:O:�:`:
2 2400 24 Y 17.2 18.5 7.3 <24.0 6.9 18.1 9.6 3.0 7.37 605.0
16::•' .
4 2400 24 B 17.7 18.98A0
8 2400 24 Y 17.2 18.6 7.4 <24.0 10.2 17.2 10.0 2.0 6.88 609.0
..:.......:...:..........:.f..:91:•:-:• ••••' ::::::.•:.:6;98:-:-::•:585:a•:••'
... � ;:'7:6�:.. .:8•:'�}7:¢� v:j44A.• :. ,;'a6 T}:::•:,•:•:•:10.0::•: .-
.�:fi; •:2400'' ...:- 4:::3::::-:-:!(::::::::c 1 ._••'t$
8 2400 24 Y 17.0 182 7.2 <24.0 7.3 18.7 10.2 3.0 a 7.03 486.0
t ( B::::::::Zi4f)C::::'•::::24::.:::.:A ::::.•:48,9:.•:98,6::c:::Z,3'•''••:it24J0f•:C•::•::•:•:••:.. ..:.$:8.:•'r•:... ::ft:ti:::::S....10:i:::::::d::::.:::2:0:::::. ....
10 2400 24 B 17.1 18.2 7.30
;3d'::::
I
12 2400 24 B 17.3 19.1 7.2 <24.0 12.1 17.1 a 9.8 <1.0 7.02 576.0
'•::•:
'..::.ii:::
.'• �A:
:�:� :::::::�:�4�:�;''.:.:4�:•:•:•:••:14:4::::1>Ii9::':.:7� :[�:��!�!,?�':= :�:: :•:
••: :�:11� :�: .�:18,.
� �i:::..iii: .:.ti_.. ...6:i:::::: ., .Wi;:..::::'..
14 2400 24 Y 16.7 17.8 7.3 <24.0 9.6 18.3 6 11.4 1.0 8 7.01 609.0
r:.:•..
••J9[�:�:�Y0:4. _ �::7:6�:�'��' ::�7f:9: ::d::::r9 :_: �• -_:�3:1::;:�::�h:::�::;7'•;f .$I2,- ..;:'4..b::::
I
�:'I{r::��::ZS{flU:�:�:�::::¢4';:;�'.:�Y:;:;:::::7R;4:::''19:D':::::R;Z:�:k�:x28 �•. .....
16 2400 24 _ Y 16.9 17.8 7.2 <24.0 8.2 17.7 s 10.4 2.0 6 8.60 622.0
t
18 2400 24 B 18.6 16.4 7.60
::{.
•:1�:::.'::iddb: :��:�:i4�:.:::. :11:�:�:�:� :
�4i;6:�.:��;f::�:::i;:3:•.p4:..24,>}�::',...,..... .:::d .. _
20 2400 24 Y 17.1 18.6 7.3 <24.0 10.5 19.4 11.2 3.0 7.80 604.0
1.:.:::::::::..• y .•:.•:''
:iikl:i.:�:.:i4I1>i:;:i'�.:;:Z4;:::::.:::;C:::::::�:I�i�:::��7;8:,�:�Y�: �...24:4.-•..... ... ....�:�::'. -�:i��8:�::�..,...�1:%�`:� :'.•;:'::' .. ,
I22 2400 24 B 18.3 16.6 Holiday. 9.40
;.:•:::::.i.4...0.6::•:.:•::.:• :{B:::}}::..iff:9::::'(7.4:::..... .Hgl[d Y i. ::•..]:::::_::::::: ... ... ..- ,
24 2400 24 B 18.3 17.6 8.00
_ .;.i;.:.:.:-:.:.:.:•:..•
26 2400 24 Y 16.5 16.3 7.1 <24.0 9.2 18.9 10.4 <1.0 8.37 530.0
:::::
28 2400 24 Y 18.7 11).4 7.3 <24.0 9.0 19.4 11.4 3.1 a 8.31 661.0
:;7$::•::::¢406;:;:;::AV:::::::::::Y::::::::::444:':AO:::...4:::;:::40):;• >
::25
30 2400 24 Y 16.7 18.3 7.3 <24.0 9.8 19.2 12.2 1.0 8.80 692.0
... .................................... 1.7...... .... ............... ...................... - ...... .. '''''•7 86. ::''•681.6,..•••••0.0••••
.4
••••••••...'.'..•...•.
• : ..•.•.•..........
:
AVERAGE 16.9,,17.8 0.0 20.4 9.1 18.1 10
..........::),IMIt(tM::....,... .:1iw�:%::40:: .�4A
.•:?;4::... :::a: Q:4...j:. .:13.4.:
.411:;' ..... ':i :; ,
MINIMUM 16.9 16.1 6.9 <24.0 20.4 6.8 _ 16.3 9.0 1.0 6.75 464.0 <5.0
....................... .::::::::0:::::::... . ::::::::0::::::.:::::::0::::::
Monthly L1mk I :.
40 MOO 28uGA_ 25mWL • _ _ 30m4L _200c1100m1 22uGAJD
iDEM Form MR-1(8/93)

a IN
EFFLUENT
I
NPDES PERMIT NO.NC0024911 DISCHARGE NO. 103 MONTH:_December YEAR: 2012
;ILITY NAME:Metropolitan Seweraae District CLASS 4 COUNTY:Buncombe
vr'ERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No.165
pat addNbnal laboratories on the backside/page 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS I PACE LABORATORY
MaII ORIGINAL and ONE COPY to: •
/,��(7` //1
ATTN:CENTRAL FILES X fJ
DIVISION OF WATER QUALITY (SIG TORE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
1817 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60060 00010 00400 60080 00310 80082 00810 00530 31815 00300 00005 00720
16 FLOW
0 a n EE ® C vd € N
e 1N� = V N a °0 E o s iE0 co a v E a G a' _
c c;; o a ce o o° a dN v a h� 8 3 el .1 g
'
HRS MRS YM MOD C UNITS ua5L MO& MOA. MO& MOIL /AMM & MOA. u81CM uGA.
8:911:�:�::�... ... .......
...B•:•:•:•::::19:0r: '18:9::�..... ....... *::::%::::.::.::i::::. ......... .......:•:: ............ ........ .
i
2 2400 24 B 18.2 16.3 7.40
.`
:::$:$i'i'•: ..::�18:$i::::. i'i1it
ei'i':i' .'i' 0�:�:'s1 :...r:�7. .,.::..i .. 44 ..........
4 2400 24 Y 16.9 16.6 7.3 <24.0 •8.2 a 20.3 5 10.6 1.0 s 7.72 605.0
::'C
8 2400 24 Y 18.9 18.6 7.3 <24.0 9.2 18.8 ee 11.6 <1.0 7.53 804.0
•.•J.•.•.•.
};t:. 7 . 672..
.�:7�:�::•::::2408:::::::_ 2A.., _Y• :,:•:}1j9:0}}'�7:8;::_}7:$:;::.. 2¢O:.;' .. .'�90:1.}:�:e.'•:•:44dF}:,Se' • '.'t06}{.. •:•:•:0;1:•::::s::•••'�R #:• 0'•,' •
2400 24 B 17.0 17.1 8.10
10 2400 24 Y 17.7 17.9 7.2 <24.0 9.2 24.0 a 9.0 2.0 a 7.80 657.0
A:I;::.:::.2%{bC:::::::::44::•:•:::::Y•::::::::::f:4::..AO:::::/:2:::,:_:::k24:4::•...... .......10::::::•, fr':•::. ... .,..
$'
12 2400 24 Y 16.8 16.9 7.0 <24.0 10.1 22.0 5 10.6 <1.0 8.07 696.0
::14:: ::::0$0:::::-':::%4•:•.:..•.1:::::•::::14:R ::1$:9:::....f::::..:•:44,0.:: ..... •... .:::1;4:::.:.... r::Rx;Z:::::::•.:•:::::44:::::••:•:•:;•::..t ..•i:;:::::0;44::::: ,
14 2400 24 Y 18.2 18.7 7.2 <24.0 8.8 22.9 s 7.8 2.0 a 8.02 864.0
•••••::::.•.................. •:-:•,..........:.::::::.:.: ...:.7:80•:.:.
18 2400 24 B 19.0 15.9 7.80
•'2?• :::4:0':' ::d^'•:•:1346: : :a6'
:::ii:: :•:aao'o•:•:•::•:•i4:•:-•:•'::;f�:::• ::•id:b.::�:i�:i::::::i:¢:::,`::: io:: ............: :ii. ...... .. ... . .
18 2400 24 Y 17.8 16.4 7.2 <24.0 8.8 18.7 9.6 2.0 8.42 643.0
•:9&::'.::2dAd:::: ::::k4::.::•:::::4:::.:•::::;14;9:::::I10::::::/.;S:.:..4431.: '•...... ... .:::8:§::::::::2;3.::•: i.a:::•:•: :•:::::10%:•:•:•.:•:•: .. ..
20 2400 24 Y 19.5 18.6 7.4 <24.0 8.9 20.3 6 9.2 1.0 8.33 582.0
:c ::i :•:4.4;0::::
1�
22 2400 24 B 18.9 14.8 8.10
;.;..;.
:;�;�"�2400;:;{::;:;�
24 2400 24 B 20.6 14.9Holiday 8.70
::.7:•.
26 2400 24 B 42.9 12.6 7.1 <24.0 16.2 a 16.2 17.8 1410.0 8.41 264.0
}'fir•?r:i41)ti:i'r,'�'rj4.•. ...:Y:::'r:'ri6i4i:.:6:ii::: ii$i:.;:42(A:•: ii'.......**::::.::::::'...... 6,6i:::':,,, , .. •.
28 2400 24 B 21.3 18.0 7.6 <24.0 7.6 11.9 a 8.4 2.0 9.07 375.0
:•'0;
30 2400 24 B 18.7 13.1 9.50 I
....:.:i .:....:.:r7'8Y :44t:t•:.::::::::.
:C11::.:tidD9::: ::!4:::.::B::: :96:8:; :96:5 :r!o0:: 23 9 : .... .. :::::..ii:::....:. ... :98 4: T S::: 1.0:;:;::;:;::•
AVERAGE 18.8 18.0 r l 0.0 9.8 19.4 11.6 2.2 8.01 530.8
.
.'19;6•. 1h: .... ..:�9;t��:�:�::::10.A4:::.......
..•,•.....:::1V)7�lal(JM:::::•: :•:•'r'r::::�:4'1:$::�:17;0>::.:7.•5:.:::..�4.......... •:•:•:: .... �:�2.,4� �:. •.•1 0`:' .
MINIMUM 16.2 12.5 7.0 <24.0 7.4 9.3 <1.0 6.03 264.0
..q►P.t.1.ttf4t)0}:::::•:••:...... ... , ::�Q:::;:::;r�;:: : :;:Q:;:;:::.....�,.._., .. . ... ... ..:::1'c::':'•:'• :::::::ii. ... .. ..Gt`.�:�::::..
Monthly lin* I 40 MGD 28uGIL 25mghL 30mg/I. , 200d100m1
DEM Form MR-1(8/93)
1

I
• EFFLUENT
I
"IPDES PERMIT NO.)•IC0024911 DISCHARGE NO.103_ MONTH:January YEAR: 2013
II ,CILITY NAME:Metropolltan Sewerage District CLASS 4 COUNTY:Buncombe
OPERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services,Inc.Certification No.40 (2)Meritech Certification No. 165
' , (List additional laboratories on the backsidefpage 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING -,J PLES: OPERATORS/PACE LABORATORY
MeM ORIGINAL and ONE COPY to: ��,,,�� n
ATTN:CENTRAL FILES X ir /1(/J�t�'(}C �'I / I
DIVISION OF WATER QUALITY (SIGNATURE OF OPERA R IN RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27889-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60060 00010 00400 50060 00310 90062 00610 00530 31615 e 00300 00095 00720
3 I G FLOW e o
V INF ❑ V o V io • 9e C 3o a m °
EeE ti) (t.1 N ! O V g O Oei C °..3° ° I > Or i Z
+ F O a To '° a oR�Qp A A E p a g N 3 lg.
v
C O J Q O d U C7 C= d �w d ' d V V
�r a m
0 i 1i K LL r
Fat. ` HRS YR MOO C UNITS ae& Mart. MOA. MOIL MOA. MPW10M4 MOA_ uBIOM uUIL
:::*::* :24U0: :::'::YIi::: ::.::::k*:::hB:U:::.`I3:8:::..... ......:.Ffo1 deY:.
2 2400 24 B 20.3 14.9 7.3 <24.0 7.7 . ..16.0. . 8.6. 2.0a 8.30 460.0.
t::
;.; - -
�:�3:•..•::•fi1Ad:�:�:��:�:84�:�::�..�:��:�:�:�:��:%lili�:��:46::i:��:�:'7i3':' 24:d[•. :.•.•.•.•. •... :�:44 .. .....�:� .$•:��:E�::::::::iii::::::::::*::.... ..
4 2400 24 Y 18.514.7 7.2 <24.0 • 12.3 s 17.6 6 8.0 <1.0 8.70 626.0
III
:: ; •.
6 2400 24 B 17.6 14.6 6.00
.. }:i: :i:9:60:ir..::•678. •
:'l::;'?:2400:�:�: �T7{::}::::::::::4::::::::::��7:4_::�ai}:,4•:' :7:8::�; 2,4.0 4':;::•:•:::i.:::::40;1:::::-...:1;:. - ... ... ..- --- -'¢'• - --
I
' 2400 24 Y 17.8 14.6 7.3 <24.0 10.0 18.5 a 9.6 <1:0 8.10 641.0
:10:'
._ d�::•.':'7d0U:�:':��r:R4�:�::•.::�11:�:�:�:��:9�,Ti6{:�:::.4.4•::�:�:i!i2:�::�:�24:Q7:
�:E�:�:':':�:': ... .�:' �iT�:�:'':....�:'7$:t:� .•::9.$
. • :•:•:•:..... .. .. :. 6Q. ' ..
10 , 2400 24 Y 17.6 16.2 7.0 <24.0 9.417.4 11.8 <1.0 7.90 638.0
::E
12 2400 24 B r 17.9 18.0 .'.1.0 7.90
,;:
h:
.:::*:: ::::::1.9:• :1$•.. ::::::•:•:.: ............. ... ....... ........... .. ......... ..... ..
14 2400 24 Y 30.6 18.3 7.2 <24.0 8.6 18.0 10.0 3.1 7.70 600.0
I .. ::::>?::: :.i 6 i ::14a: ' i'0'r:}::i2A!Of1&8}}:'-':':": •'Tr'r:::::i::::: 92i:}';;: :::18 r 4
16 2400 24 Y 44.4 13.2 7.1 <24.0 18.7 6.1 s 44.0 21.3 8.70 281.0
.
:�it ::.:::aabb:� iii
:�::::: .:: :
.
. ..:ir:::?.:::::ai:a:::::id:b:7::::i:z:::::::it4:e.'..... .....:::;ii3::::::::::::: ::::ii:::.,:... :isi::::::.. :.:::: ;o::::.:
.......
18 2400 24 Y 60.5 11.7 7.0 <24.0 18.3 9.0 66.0 1200.0 a 9.20 288.0
:$•:•:•:•••:•••••••*4
•
20 2400 24 B 27.1 12.8 8.70
:19• '
I22 2400 24 Y 22.0 13.3 7.2 <24.0 8.1 7.3 11.1 7.8 2.0 9.10 453.0
:�7�:�;:_:�:2400::�}:}}ylj:�:�,' ::::y:.::?}20:8�::�'12:8':�:�7:1}::}:�A}�' - :::7;4:: ::���:' ., :::Tg;:;:;:.• ,1 ,., � �� -'�-',•' - -
24 2400 24 Y 20.4 13.7 7.2 <24.0 7.1 12.5 6.5 s <1:0 8.60 466.0
�:2s'::•::::.iiAO::::::::::P4:::::•.::::Y::::::::::it0i0 i:13iti}::::iia i:::::fi243`<:: ::..... ... .. .. .::::76::?:::::..... .. . . .. ,........
28 2400 24 B 19.2 13.3 8.70
I
•••••••••:•:.:•:•••••••••••••••
:41:::.:::44i) •rte.•, •': ;: ':'::19;4::::1A:4:::::•:•:•:•:••:•:•:•:•:•:•:••:•:•:•:•:•:• :•:;,-;;;•:•:•:•:•::•:.:•:. :•:•:•:•:•:•;:••••••••:•:•:•:•:•:.:•:.:,
28 2400 24 Y 18.7 14.3 7.0 <24.0 7.4 13.9 7.2 <1.0 8.50 486.0
:,:: :•:< -...:18-o:-:Ye..........:.84.:•:•: :0 : .•;4 . 78:
30 2400 24 Y 38.1 16.2 7.2 <24.0 10.6 18.1 8.2 1.0 8.10 626.0
41::.'.:::2AD0}::r::::24:}::•::•: ::::::68il {19i8::::::BcB}:::::N2iJOf.•: :....
:::::28. .. .l0:e.:::::::i:::::Sti:6*:: :::::::::4ai6::::: lr::::: 8:00::,:: :':ii6t0::;::::::::*:::
•
I :•I
AVERAGE 26.3 14.2 t 4 0.0 10.7 13.7 16.8 2.9 8.29 438.0
:IIMWdtGM:.......... ::$(id ::7$;d:: .;7; ::.:< ,0. .•...... ... .. $:A:. .....:ldc$;!.: ::d,iki ..:t34h:0 ::....:40i$0:;:::86 .......
I
MINIMUM 17.4 11.7 8.8 <24.0 6.1 3.0 8.2 1.0 6.00 245.0
O
Monthly Limit I 40 MGD 28u0/L 25m9M1. 30mp!L 200d100mt
iDEM Form MR-1 03/93)

Io EFFLUENT ' •
3 m
? 3i a
g ;AP DES PERMIT NO.NC0024911 DISCHARGE NO. 103 MONTH:February_ YEAR: 2013
' FACILITY NAME:Metr000litan Sewerage District CLASS 4 COUNTY:Buncombe
OPERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE] Certification No. 10773
I
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No. 165
(List additional laboratories on the bedside/page 2 of this form) --
CHECK BOX IF ORC HAS CHANGED I I PERSON(S)COLLECTING a I/PLES: OPERATORS/PACE LABORATORY
Mag ORIGINAL end ONE COPY to:
eli,
/,1/ 3� /
ATTN:CENTRAL FILES X
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RES-•' IBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699.1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
50050 00010 00400 50080 00310 80062 00810 . 00530 31615 00300 00095
a F'pow 6 00720
c
U1 o U ts. O m to m .9 c C m k .P a t.
! Q6 O 0 K i o• Ts' O 1 gN 'S E g.7, ; 3g IC A , .g G
g' re
(,,, O d F - m C7 Q ' f� (y� U
o g
.. HRe•.•_ fiRs YA6 MOD ,' C L301'8 BOIL ,. MOIL MOA. MOA. MOIL MPfYtOOML MOA. U$dCM uWA-
::4:• ::2400•: .:}}2i1:•:'•::::'y:•:•:•::•3.1:1•::I2:4:::•:•7:0•:•::<24.o:::•.•.::::•
............:::`Iit:B::::::... .::: 9i:•:�::�:::::30r3::::::.. .:::'16:0::::'.. .:::917t):.:::::-::3A9:Q::::'
2 2400 24 B 28.0 12.1 """"
9.10
:::i.::.:::::446::::::
4 2400 24 Y 22.4 12.9 6.8 <24.0 7.6 10.4 'e.' 4.1' ..e.' 9.00 392.0..
:'q;p: •:•:•'•`•:•::•:•:•:•••••:•:•:,.... •:•{•9 •:i••:1::.•:•••• • ,J , •:i'; :. ::<::
8 2400 24 Y 20.5 13.7 7.1 <24.0 8.3 12.9 6.6 1.0 8.40 462.0
:7: ::::::2400::•::•:.:..2.4:.::. :::YY :::22:9:::.'3:6:: ::7:Y' <24.:.:::::15 9: :....::..23:2*::::•
... }:192?:}ir: :::::4'..0....:::.*::::.?:1f.'::? *::_ :{if97}}: :.1(9ti: :::400:::
8 2400 24 Y 23.6 13.9 8.9 <24.0 ' 11.6 13.9 12.2 8 <1.0 7.74 304.0
III
it.::::::•2itOd:.:•:. :24::: ..:•::t3:•:•:• .:201:•::1219:.':....:::::.
1 • :9:70:: :•:•:•:.:•:•:•:}: ::::
.0 2400 24 8 21.2 13.8 8.20
::ii:: :::;24bb::::::::::i4::: ::::::::i:::::::: i;8:::i
Id,b::::::i:1:::'::: 244::•...... ....:::*.§::::::... :::18;4::::'.. .::::4::::::'.. .::Ab:::::::. .:::45:::::.:::40:A:::::.:.::.::i':::.:::.:
12 2400 24 Y 21.8 13.3 7.3 <24.0 11.4 12.8 9.2 6.2 6 7.64
445.0
7"r::'. '8: I
14 2400 24 Y 21.3 13.2 7.3 <24.0 9.3 12.9 6.9 2.0 a 7.71 441.0
1{r::•••••••••••••:•:•:.•:•:•••••:- . ;Y:•:•:`;•:gi;7 •:•••••••:--}:4.2}:'•:•:•••••••'::
•.:•_:�:::;: :;:8:4:::;:'... :;371:0:':' :'i.2:..:*•:. :•::t9;9:::•::::. ':f7:59;::'; :::4i60::::•
16 2400 24 B 20.6 13.6 u 8.30
::1T .::2400::-"::27(:: •..: B:::::19:7::11:4::..... % .•^� T,-.•,
,
18 2400 24 Y 19.9 13.2 7.1 <24.0 12.2 16.7 7.4 a. <1.0 7.69 470.0
::4b:: :244d ::•:24: :. :Y::::::AS;. ::bb:B:: :y;b
�t:Ci:: '...... ... :::;ia;$:��' ... •:•lli:ti::•::'s: ..Aa::::::•. �::;I;b::.:�::::'.:::f:9b::::: :::4$tt:G :::
20 2400 24 Y 19.1 ..13.4......7..2.......<24.0.. ...........19..1................17:8..; s 6.8 ,e•. 1.0 7.74 603.0 ,......
r.:..2:1:::: : 49Q: ::.::Irk:: 1 4 ::1g;ti:. ::iti44,:.•;:::: ::: :•:a '... ......
22 2400 24 3 13.2 7.2 <24.0` 12.8 15.6 6 7.8 <1.0 8.01 434.0
:.u..:.:.:2400.:,:.::.:.24..: :.:::.:4?.::.:::.::iiii::.ii.:4:: ..
24 2400 24 B 20.3 13.4 "'
8.60
::26:;:::::ADO :;::24: :'..::WY:::: ::20,t1 :A.5.:: :::1T;2::: :4i2G:4::::..... : : .:::9:8:::::
.. .....:::13:8:::::d: :.::::7,}::?::::...:::i419:::::::....:::7:24::*•:::602c11:::::
28 2400 24 Y 37A 12.9 7.2 <24.0 10.8 14.6 6 8.6 7.3 a 7.86 484.0
::. bb::::: :::7;4':•:•:......::.::•:11:4.•::. :::$4 ,
28 2400 24 Y 24.4 12.7 7.0 <24.0 6.4 a 10.36.1 4.1 e 8.11 384.0
_
I
.... .....•• ::........................ . .. .....
AVERAGEI 23.0 13.1 0.0
15.9 12.9 13A 9.8
1.9 8.00
...•:b) c(Nt4M:•......... ::3•;4:: .7: ::• 439.6 0,0
x.. 14;0 .. :�::..�f��:.:�76$:;�;;:; �3�:�:�� �:S :•>:•:•:•••
rt;b�:��:�:...•.•.•36:3: �:.T' 1a0:�:�:�'. , 9;14J639 'sb:04:�:
MINIMUM 18.8 11.4 6.6 <24.0 15.9 6.4 ....6.9.................6.5..................1:0.....
•'•'•''-••••••••v.• .....6:50.........304..0......<6.00...
QoiliP.:i4iiif81T f•::::t: :::::?:::: '::G
Monthly Limit / 40 MOD:• ......:.4::::::: '.. :Q:;:;:;::;. ..:: ::::';' :'�? : .::G:::•
28u0lL 26m67L
- 30mpIL 200r1100m1 22u0/UD
DEM Form MR-1(&93) _ I

I
EFFLUENT
ill /
NPDES PERMIT NO.NC0024911 DISCHARGE NO.103 MONTH:_March_ YEAR: 2013
I
4CILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
l ,PERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc,Certification No,42 (2)Merltech Certification No.N5
(Llstadditional laboratories onthe backside/page 2�this form) PERSON(S)COLLECTING 'uPLES: OPERAT RS/PACE LABORATORY
CHECK BOX IF ORC HAS CHANGED
Mail ORIGINAL and ONE COPY to: 4//://3
LES X �s CHARGE)
DTTSICENTRALNE (SIGNATURE OF OPERATOR IN RESPONSIBLE
DIVISION SERVICE WATER QUALITY BY THIS SIGNATURE,1 CERTIFY THIS REPORT IS ACCURATE
1817 MAIL CENTER AND COMPLETE TO THE BEST OF MY KNOWLEDGE
RALEIGH,NC 27698.1817
60050 00010 _00400 60080 _00310 80082
00810 00530 31815 00300 00098 00720 _
FLOW
1 •
C Is' N B 3N O 0
�o Cy F Y m H
g 1111) !'�G 1
R C 17
MOA. MOIL MOR t.wwIOC.L MG& uatat KUL
IiRS _rtRa YR MOD C UMTS vat- MGA. .; ...,...:.. ..;.. .,•.•,•,. '' .......
::::::::: 6:7:::•:'... -::::i1153::: : ::::::•6:6• ::::'.. .:::4:11::'r :: :ii:7f:::: :83O:•:'r
1:��: :2%1U0::�: 2A:�:��:::�'1f�'r:�:':�Y3:6 :�yZ6�::�:�7:lt� �:�:<s4.0:� .. 9.40
2 2400 24 B 21.2 13.0 •.•.
i:c�:�::'' :�Itti;�:��.4 ai:i�:
�::.•.•:bbd '�' :za�:�::� ::��:�:�:':' . ::�•i
.<24.0, 10.3 2 14.8 a 6.8 <1.0 8.06 460.0 .,,
4 2400 24 Y 20.4 12.7 7.2 • '''' #$��:: •,•..••
.::�:��'r.�:$41?$: }id'r. ..r:i'r. i$i: .r1:1'. 17.7 •18.9 •.e. 2.0 7.96 388.0
6 2400 24 Y 26.9 12.0 7.2 <24.0 2 14.8 8
:iqi::::i:;:2'a'lip::�: :.:::.i4:.::.;"::::::.W.:::.�zzs;:::�z:a:.::;i's': :;:<s4 .. '
16.2 13.8 18.7 a 1,0 8.32 436:0
8` 2400 24 Y 21.6 12.7 7.2 <24.0 • • ••'•••••••• •••••
::::::::::::..... 8:911::. if::::::::::::::*::::
i.:::::::::�1I':f...::ZIOl1 .. r:64::.... 8.90
10 2400 24 B 19.9 14.2 •'•'•
.d•. ... : :Sj; :y;$o:'• : :: $r;:tt: .......
;:11:' :�:;ZM1tli?•:��: �d;:�:::.:�:Y•:�:�:�::-�3:$�:..�. 8.23 330.0
24 Y 36:4 12:1 7.0 <24.0 24.6 16.7 6 17.6 a 10.6 •, •., ,
12 2400 :¢:: $:$$:: ?$$r. $ ,
�:13'y�:�:�24AA::':��':24�:�;;• '':'�':''''' 2.0 a 8.38 273.0 ... ,
14 2400 24 V 24.7 12.6 7.4 <24.0 8.6 12.4 6.4 ..• ,,,
ti •:i i:• .:•:io;Z:::::.. :::8:0•:: ::7:06•::..:::4LIsi0:•: ::•:::: :
�:18;::��::29RR�':'�;':':�::::' ::Y::�:::�::g;1;7:��:1''�;9:��:�:R;t : ��fiY0J9[�: . . ..:x:41.... .. .
7.90
18 2400 24 B 21.4 13.4 •.
:'iTi::.:41.0:0::.::.:-:.�::sai:�: �:�:�:�:f3�:i: ::. •••.••. •, •' �r00::::....... .......
486.0
18 2400 24 Y 22.8 14.0 7.3 <24.0 13.3 16.6 6.8 1.0 7.4„0 • . ,
:.:0::.......::f,ti5:: ;4ti$;d::,
1 ::::::.:0::::::
20.9 13.6 7.2 <24.0 10.4 2,4 16.0 s 6.8 6.2 a 7.84 492.0
20 2400 24 Y . g ::* ::4: ,::7,$0::,,::.$0:O:. .......
r?,�:�'.:�:`�4i?G�:�:�,:�:�2.4:�:{�:�:�:�:3C:�:�'r:'rA9i�:. ::I:♦i�::':�Fi$�:��..R�EaP:�:�;; ;�.: {
<24.0 12.3 16.9 6 8.2 2.0 6 _ 7.72 608.0
22 2400 24 Y 19.9 13.3 7.3 •:••:
}`13
73 :2400:}:::::i4::::'::...... 8.80
24 2400 24 B 25.8 14.2 :;:8.86:: ::8117:0:::
:•i:::::::" .-024/31::.....: :••:44;3:•:••:::•:••::x13:8•::•:il: :.::8:6:' : 1313•::•::•.... :
•:46:: :•±OA:•:•:.-:•:E4•.•.: :.•11:�:�:�:��:i26;8:�x:43;0:��:�:;<;2:�: ::.:.
9.0 13.7 a 6.8 a 5.2 a 8.06 484.0
262400 24 Y 21.513.1 7.3 <24.0_ ..•�.•, ,• ..��$�,;:.•••.•
•:::::: 4:: ::;::.:X:.•,: �:�::::'.:. .::)1'Q::'r::'.. •'r:$ ':
10.9 14.7 7.6 a 1,0 8.12 470.0
28 2400 24 Y 20.2 13.2 7.2 <24.0 •:••:.• •••• : .......••'•'•':.::
:�a: ' :-s:• :.2:ti:: : :1,92 :' :�6�:0 ::`:
::• .,; :::*'r:::v::xQ:t::::1i�y:::; 7:;[;:. .:1}4Q:_�r : ;:;:::.:::�:9z4:•i;::..... 14.0i.:::iti•� ._ ..�.�:���:��.:�:
�:�::::::..-.1.40:.::::.: �'=�'�'��'• Iso
30 2400 24 B 22.2 13.6 •.•
41::: 7AGU:::� :l 4:�::::B: :22c7: :44:I: :.................... ...
..r:.7:66•:•:•;•
.... .......•. ........•
..........••.... ..
. :
.....,
. .............•....•..
..... .•.....•.... ...•... .::.,...••
.•
.•. .• ::
AVERAGE 22.413.2 � 0.012.114.69.0 2.02438.8
:9441:. .::$iRu:_
......,
19.9 12.0 7.0 <24.0 8.6 11.0 6.8 1.0 7.00 273.0•
I iiiiiiiiiiAiialtia:::::.i:i*.:: :::::.*::::.::::MINIMUM :O: :. :.. ..:Q*: ......
: fix:::: ..... ...�.._. _.
40 MOD. •..•28u0/L 25m9IL_ 30mg/L 200c/100m1
Monthly Limit '
i .
DEM Form MR-1(8/93)

EFFLUENT I
•
I
NPDES PERMIT NO. NC0024911 DISCHARGE NO. 103 MONTH: April_ YEAR: 2013
I
'CILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
.iERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773 I
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No. 165
(List additional laboratories on the backelde/psge 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING ES: OPERATORS/PACE LABORATORY
MailONE COPY to: `r1� S/2`Z/-
ATTN:CENTRAL
ALL ONE
X
3 i
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSI:LE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699.1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60060 00010 00400 60060 00310 80062 00610 .00530 31616 00300 00095 00720
FLOW s m o
0mi
0 8 ,ti fel- 8 'op o € .$
I
rn Itg. p�u• 2 2 z
$0 a iii Tr
v a' a m o c5 a z a g o! d E c1 c°�
o� S5 O - ° w ce u
'
HRS HRS YA7 MOD C UMTS toll MOIL MCA. MOA. MG& MPI4100ML MOI (ACM uGIL
. 3:a.:: ,.....
:4;::�::::24U0:::::::�:�271:::•�'.::::1r•:•::•::•23:8::::'1i1:9:::�::T:4•::::�:<YS.O::�:.....
.. ... �'10:8:::: ... :�:44-0 $:EI
:�::�:•:.•:•:�: •:•:•::•.. ..*:::;: i. :U:::::::. : ii;a: ::'7133.
2 2400 24 Y 20.9 13.8 7.3 <24.0 10.0 . 14.6 7.9 <1.0 7.68 492.0
:i}:::.:::3460}}:::}:'44......11::::'•:••:it0;0: •:'13:9}:}:ri;3'•' 24S.f::.•:•:•:••••:•;:,•••••••:..
4 2400 24 Y 23.3 14.1 7.2 <24.0 '• • 13.0 a 15.9 10.8 1.0 7.62 496.0
. :::
6 2400 24 B 21.4 16.7 7.00
:::8;90:..:::.:::..:::::•:. : ......
8 2400 24 Y 28.5 14.7 7.0 <24.0 7.3 16.9 6.7 689.0 _ 6 7.58 484.0
•:•i:•:•::•'' •.i:•:•:•. .
f ...�:�7AU0:�:� �:�:it4•.•.:..•.•Y:�:•:�:••:p2r0:��:%14t$:�•:�:i!:0:�::�:�241Ji(�::•...... ... :ti20c8:�:��:....�:�}f:8�:��:•.•:.•.•.•17.•$�:�:��....:�:f1t0:�'r::..
10 2400 24 Y 20.1 16.8 7.2 <24.0 13.9 2,4 16.8 9.4 1.0 7.48 626.0
•:•i:•:•:•:•'•' :•:'•:•:•:•:•t:..
::ii;::.:•:240b::::•:::::2d:•:.•:•:•:•:Y��:•:•::•10:11,„:•1$;4•::•:•/;1::•:::::044:.•:........... :�'•$•�::•... :.:4$�y:-::•6:,•:•::::7•:b::: : .. ...CO:::::.-............._1.11:::
12 2400 24 Y 63.7 14.1 8.8 <24.0 26.5 14.6 61.0 a 138.0 s 7.80 268.0
14 2400 24 B 24.2 14.6 8.40
::15: ... •:::24•:-.,..:••••:•B:•:•••::.•:24:4:•,':16:.}•}:89}:}:•0244{7 :943::: ••ra2:3•:� :•'b0`.:•':';011:.:::::•)1.P••••• •••••••••••••••••
16 2400 24 B 22.0 16.6 7.1 <24.0 11.9 13.7 7.0 <1.0 7.82 452.0
A7:.•:.•:2400.:•:.::•:'241:•:-.:.•:.:1r.:•:•:.:r23:4:ASA::•:•7:U-:. •:<24.0:•.:...........•:•26:i2•:•::•...
18 2400 24 Y 23.3 16.0 7.0 <24.0 27.9 a 16.6 6 18.6 1.0 7.46 484.0
•:18::::r::1ddd:::::::: $4:r::::::A ::•::::210r::410::'r:Z;2'r:•..424tI:.•.•.•.•.:•:::,•::.. .:::9:1::::::.....:::1d:4:>::6•..•...,d:?: ' .... .b::::: •... .
20 2400 24 B 24.7 16.0 8.00
;:;f:::
22 2400 24 Y 21.3 15.8 7.1 <24.0 8.3 13.3 5.6 2.0 7.62 483.0
• •
:•23...;'}:2400;:•:.::•:�24:-:`:.:.:•:Y.:•:.:•:::2'.1:4;:}:p6:d.:}:_7:¢_:.;'r:<Y4A:�;' ... :::.:9;5:::::: • ;:.:15.18:•: 1� .:s_,- .:.::.:7:19:.:•:,:•:•492:0•:;_;::••••••••,...:
24 2400 24 V 21.3 16.8 7.2 <24.0 12.1 14.3 s 8.0 <1.0 a 7.38 487.0
....•..
:4fr::•.•:•7�9D::;:;: ::P4:.::..•:�Y:•:•:.:..:20:4:-•:4614:.•:•:2i1:•::•:-924.11.::...... ... .• 6:8.:• -.......:•::•:•14:6•:••:d.::.:•:• :54:.: .:•
26 2400 24 Y 20.2 16.5 7.4 <24.0 7.8 14.6 s 9.2 1.0 7.31 442.0 •
::0::::::::**41iti::::::,::::.14::::::::::::4:::::::',:4$;i:::::(11;Z::•:•:•:•:•..........:•::::::::•::::::::::::::•;•:•:,:•:•: :•:•:;•_:•:•:.-:::: •.•:•::•:•::.•:•;•;•:•:•:•:•:•;:::•;•--.....:•:•:•;•:•:.•:•:.•::::00:::::;•:•:•:•:•;•;•:.-:•:.:•:•;•:.:. i
28 2400 24 B 41.0 16.9 8.41
•13:2•: . :-.7: ::e. :•.4 T::
30 2400 24 Y 33.6 16.8 6.7 <24.0 10.3 7.0 6 12.0 6.2 a 6.24 342.0
;.;,;.
.. ..................................... ............... ••.7.83•• •'•449.3•-:
•••13.0•• '••14.3••
1�. ••Y.4•.
•••6.2•::•16.2• •.•0.0•• •.•12.7•:
AVERAGE: :2 ` ' 1
::::.:::::::::.:::::::10#04161:::::.............:.:......:::d3;it:: :$8;9> :7.4>.•...X4O.:.., ... . ::•:•V;0•:• ..::1 :@:: •.r.•.•.•9x,.. ..... $$: ;::
MINIMUM 20.1 13.8 8.7 <24.0 8.6 7.0 6.6 1.0 6.24 253.0
•
•,• .. :•:O:•::•::• }y
Monthly limit 40 MGD': .•:28tC91L: ..25mg5- 30mppL 200r/100mI
•
OEM Form MR-1(8/93) 1

IEFFLUENT
I
' NPDES PERMIT NO.NC0024911 DISCHARGE NO.103 MONTH:_May YEAR: 2013
IcACILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
I iPERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)pace Analytical Services,Inc.Certification No.40 (2)Meritech Certification No. 165
(Ual additional laboratories on the backside/page 2 of this form)
CHECK BOX IF ORC HAS CHANGED111
PERSON(S)COLLECTING SAMPLES: OPE TORS/PACE LABORATORY
Mai ORIGINAL and ONE COPY to: X td-Z9 J s
ATTN:CENTRAL FOES
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60060 00010 00400 60060 00310 00082 00010 00530 31616 00300 00095 00720
a[ FLOW a
O FFF IJ ti m
co
p c
0 21
ta
0 INF ❑ o c) r a d4 c c m cgs o c
P w a a 8" a s 3' a ISS 0
Q �el a 6 n{
p 4'a�' K �O d <1N C! a CS oK O p U
a as
HR8 HRB Vie Moo •
, C UN T8 ugl. - MOL MOIL Mal MOIL MMJIMOM. Mat. IOW u011-
::::43
0n.
:•:i•:
: :: 2400:: :.::::iii::::✓.;.:;.Y.:::::•26:9:: 1b'8::•:6:8: <Z4A: ..... ... . : IU:4 '... ::9:4: :b::..:• 8 3 :'.
•:: 3:2:•: :::B;ia:::::::::ai7:8•:::...:.
2 2400 24 Y 24.1 16.1 7.0 <24.0 7.1 10.9 a 6.1 1.0 7.37 448.0
1 A':: ......
:::9::::�.�:��iGd�::�:�:aa�::>:� �i�:�:�:�::�:;i;2;���:�ss2:�:�:k�o:�::�:�cz4i�:�::'...... ... .::��:D�:�:��:...
4
7.40
2400 24 B Y 66 25.6 13.6.6 18.2 6,0 <24.0 32.6 . . 4.6 a 125.0• ' .. .;218.0 8,97 238.0
6 2400 24 ✓•:::•:::..
...'....'..7:f.•�'•:•:¢d00? :y:-:•24}:.:}:::::Y:}}:::{578:}hp8:':::9:'v.:•:1O...:' -•- -- •'•i5:S:::•:::::. :.1e.,,:-:•::::(4,76:•:•::• 411.0 :::6;59 r'245:0::,:'..:..
2400 24 Y 46.7 14,6 6.6 <24.0 9,5 :::::::i1::::
.1 11.7 8.84 268.0
.✓..
.08:::: :.� �it0o:�:::�: it4 : �:y,:::::: ;830298;2::�:::8;9::;:;�y24�6r� •....... � a:5� : b6:8 - :� 2'}:fi �:...
::::::•:::::::: ::9:t8:• :BPB-0 :......
4.6 s 8.7 5.8 1.0 7.98 386.0
10 2400 24 Y 30.2 16.6 6.8 <24.0 ...
tiv:
i2
is .::i�:I£:::i:ti:�:...... ....... ......... : ,_,_•
'r:l:l: . :;:4bb•: :Ali:. ..::�:•..
12 2400 24 B 21.0 15.8 9.4 6 8.8 8.80
�:;: ::: ::26:,4:: :1O.: .::9:8: :::400:� ..... ... ....9::::••... . ::14:::•::a• ....
14 2400 24 Y 17.0 15.9 6.8 <24.0 10.8 10.2 a 6.9 1.0 7.94 434.0
•' :•::• :' :::7:62::::: :40(1 0
::95:. 2:{•:• D:•'..
r. :24:::::: :::p::::i:::. :46:.::9& 8 •aYh3Bi•:.: :: :. .. -:::9:0::::0:::s:•:::::i.•:•.:::::::::,::::: ..:.:::......4.::•::::.•:6::::::..,.
16 2400 24 Y 24.8 16.7 6.9 <24.0 28.0 10.0 11.0 7.7 3.1 7.26 630.0 <8.0
_ :•:Y•:•:•:•:'rYa:B�::-`iTO:•:....:•.-.......:•:•:•:-...-.-.............:-
::::�6:8:::::::<Z4.0::•:..... ....::::iti:6:::::�... :::tt;7'::.......8:8•::::: :::^::::2;0:�:�': ..
18 2400 24 B 32.1 17.0 11.6 6 6.70
z8ia i:%16.. ......
�:�f, as::. ...
20 2400 24 Y 26.3 17.2 6.8 <24.0 6.0 11.9 .,.6 5.3 a •.11.3. ....7:29.........410.0............... .
•
:f21::�':::i40R�: :::� 9::✓•:•::•;Y:::::•::�24�4:,;:17:4:;� l3cQ':: ., z� ;.:��::�:' ::
22 2400 24 Y 28.8 17.6 7.0 <24.0 7.8 12.5 7.1 a <1.0 a 7.29 435.0
' ••i2:: :::3ii:0::::'
:_23:` :}¢400:}:�:?}2a.:;••;{:Y: �:�:•::$'��1T::��`I:O::::}7:¢:{ �:1Y4.4::�• ...... _ ., .. ._.. _ .r�•-_.- ...
24 2400 24 Y 26.1 17.6 7.3 <24.0 6.0 11.2 s 5.9 6.2 7.18 374.0
::2&:::.•::2i{OU:::::::::.:0:;i::::.:::::.::.:ii:.:::,:::•:ita:6::::4T:i::::::::.::•:?...,:::::.:.:::,::::,:i :.;:i:i:::.:::: .
:.:.:.:::::.*:.:.;:;.::•::,*:,::::.:.::,:: 60*:) ::;::::::::::::...:: :.
26 2400 24 B 30.0 17.1 .. ..,. 6.30
,1�l ✓. ,r
28 2400 24 Y 22.8 17.8 7.0 <24.0 5.4 a 10.9 6.6 s 1.0 7.21 420.0
:: '
30 2400 24 Y 23.2 18.7 7.0 <24.0 8.9 10.9 6.8 <1.0 7.19 469.0
' ;i::::'18;3::::::6;7:: :: i;a:::::... :7s:;:;:::.,.: it):8:::::...:::76::: :44;0::::;::..::::::::1; i:::::::::406 0::::.......
' •.• *:::::::.::::::::::::::::.*.iii:
•• •.
.••
AVERAGE 29.3 18.6 0.0 28A 7.62 381.
'•9:1bbiyg ..
MINIMUM 17.0 13.5 6.0 0.0 28.0 4.6 4.1 6.0 1.0 8.30 0.0 . <8.0
.6.1iiiiii::i4ii.*lifir....::.:.:1:-::.::'•.:.::.:*:.:::::i::::)..:.::.:.::..:.::::!ti.::::::.:'•..:**.ii:.*::..: .:.:**.....::6.:.:iii.::_:.::::.:...:::::'::-:::::':':':ii:::::•:''.::.::%:::.7:::.::::.e:i.::::.::::::::::::::::.:: :::.::::**...:::::::.:iii.'.....:iiii::::.::-::1:.:*.:::.::.:::: .:::::::::::::4::::::::-i.:.•-:.:::ii:::::::i
I200d100rr l G4JD
Monthly limit 40 MOD •28uG/L _ Molt L 3at1yL
iDEM Form MR-1(8/99)

i I
EFFLUENT
I
NPDES PERMIT NO.NC0024911 DISCHARGE NO.103 MONTH:_June_ YEAR: 2013
^.ILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
ERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No. 165
(Ust additional laboratories on the backside/page 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SA r PLES: OPERATORSlear(Z
/PACE LABORATORY
MaN ORIGINAL and ONE COPY to: 4: 7--/C
//- )3
ATTN:CENTRAL FILES X4101L' TDIVISION OF WATER QUALITY (Sl OF OPERATOR IN RESPLSCHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60050 00010 00400 60080 00310 80082 00810 .00530 31615 00300 00096 00720
s FLOW
oc S8 o INFFF O J co
o I
o y
c
m o m g g
m e Z
F c E v el IE Op
in Ort 9111 iVg i3a p va w m V O O g CJ
cc 12
Fg o
HRS HRS Via MOD C UMTS up&. MOIL MOa- M0. MOIL MPNl100M1A. MOIL aB/CM uUIL
:::,.f.:::::::2aiib:::::::=::za:::='::.:4:::.::::.zi:6...:.tir4:::•.. .. :::.•:::::::::.*:::... : .
2 2400 24 B 25.6 21.1 7.80
• '
:::I:::•::::tidd:::•: %:%::::k4::•::•:•:•:4:::::::.-:24 .4 .. .. '4 ......... .. ...
4 2400 24 Y 22.8 . 18.6 8.8 <24.0 10.1 12.4 10.6 2.0 7.40 438.0
•
.�,..
:�:»::=:%:::;x4aa�:::�::� i:::•::::::. ::::::::::.�4:%:� ::R�:�:;:::19;��:,'•:i8;�%:::...Z4A:•:.... ,,.. ,:::>s........ :::::*(i4::::
:'.. :•:$i ..k::':. ....3a:%:%:; .AOi:::.....,,
6 2400 24 Y 25.3 19.0 8.9 <24.0 6.9 12.9 s 9.7 <1.0 7.26 412.0
•.J_
.:•:•631.:•.:.X24.0-:.�:�:::::::•.•.: :-:•:9:5:•:-::�.. : 4. 6•:•:•:: •�0:�:�:�•:d••'•::4:38:%:�:......40:6•:•::•:•:•:•:.::::
:�:?�:: :%:2400{:;:}}27{}:�•'.::Y•:_:;?: 2q:6:::;'�8:8% ... _.. ,:�1 ,7:::�.. .•6. •e:,•'-•:1,--. _
A 2400 24 B 36.4 18.47.60
.•.i:i2d00:::.::::.:Y4::::::.:::$::::::::::$9•L2:..::320i'I::•......................... ....... ... i:::::::::::::: :: .•.•.•: •:....... ::::::::::.::.::.:i.::. 1
10 2400 24 B 62.1 18.4 8.9 <24.0 15.1 9.8 52.0 1550.0 s 7.44 261.0
%11:%'.:%:;z$ub::::%:::::14:::::..:::Y::::::::::'$8:3::::16:4:::;:f:6:::::::.. 4:i::.::::::::::::.::::::::::::A.i %:::.. ,d,$::%;::s. ...Ir4Y: ::::::::::::::i4.1::::::::d::.. ...
12 2400 24 Y 28.8 18.8 6.9 <24.0 29.6 7.8 6.6 2.0 7.24 364.0
O :'s
::ii:'':':::i4.00::::::%:%:x4•:•,•:•.::=:Y:::::::::-. Y.::1::,�$:l3::::::7%P::::..�.. ..... .�. .�:1a%!3:%:��:.. .:%:$%1!:�:� ..r.•.•..4:::%:%•.......A:%::::%o;;•:%::M!!%:%:%::%:411%G:%;:•:•:•:%:•:•;%;
14 2400 24 Y 24.9 19.0 6.9 <24.0 8.6 10.7 7.5 5.2 a 7.30 422.0
':16::;::%3ii00:*}:}:44::;::• :::g:::: ::;2 .- ,.18:8':% - . •-• -- •,i..]:',::: : :•:::'::::i - ----- - $Q::::';::'•::'•::':::'•?.
18 2400 24 B 22.6 19.6 8.60
J.
:%:tT:•::%:24AU::::::::::271:::••..•:::lt:•:•:::::2r(:,2:::.:19:6.:x4:9E:::::<24.6:..:...........:•:8. .. .... .. ..... ... 9•:•:•::•.. ::::: :b::::: ... ::•:•:•:•:•::::
18 2400 24 Y 24.6 19.8 7.0 <24.0 26.3 12.4 12.0 1.0 a 6.79 434.0
::Ts:::•.:::x4Ad:::::'::::k4:::::::::::$::::::::::k4:$::::40:::::$:>f•:••:•44b•..•:.•.•:.•.••:.. : 4b%d:::::::i:•:::::la... .....::=01::::::......01 d::::::::::::..
20 2400 24 Y 23.3 19.8 7.1 <24.0 9.9 15.0 a 9.4 s 2.0 7.32 462.0
< .
:}1::::�:�4$a�::?::::24.., ...Y•:::::,::e3$:4::%'�1�§�'::::x;1%::•. t:P::',:•:•:•:•::::;::...:::::T.4:::::...•. :�:$i14::;;:i:•.•.•.•5�:::::%• . ..'...,a�:::.•:. ....Ir;e:%:::;:::44(0:::,::•:•:•:•:•:•:.
22 2400 24 B 22.0 19.5 6.10
'•23:': ':2400;:;{::};2�•:,':::' .. .. ... • ..�
24 2400 24 Y 22.5 19.9 7.1 <24.0 13.0 16.8 5 9.8 s 1.0 7.48 480.0
::id:-:�zarid::::::::%:iia:::::::::::4:::::::::;ia:z:%::iiod:%::::;<;i:::::::i4:0::::'...... ... ::::46:::: 7
;24 ::::::%4 .. .
20 2400 24 Y 22.7 20.2 8.9 <24.0 28.5 2.3 19.1 11.3 <1.0 7.18 456.0
4.:::.:::414::::::%:%24:::•.:.:%;tC:::%;%::%0$,4::;40;4:::::7,3%:%':%;4tk0::::....•.•......:::10�.�:%x. .:.4..tt:::..s, •,.•.V.......:::::: :1;4:::::...... .145•:•::;:::4$0;4::: ,. ..
28 2400 24 Y 22.0 20.7 7.1 <24.0 6.8 zs 15.3 8.4 <1:0 6.88 463.0
:..•.•.•.•.•.•.••'
.'400':........24...........y
.'• 4: Q:3:.. ..... ..... .... .. .... ... ..... ........ ..._ ..�. .
30 2400 24 B 21.7 21.0 6.80
..
:•:•:::•:•:
.
••. •, ••. •, .,
AVERAGE 26.0 19.5 [ 1.2 12.2 13.0 11.6
1.
:J
•
.........,::1NHCkINtQM::.........., ':�2:l::41,1-......:74:.:
.:::2aE.O:•..,.J...... ... .:49%6::. .... $$;It:::-:•:.
....:1b
MINIMUM 21.1 17.1 6.6 <24.0 5.3 6.9 8.6 1.0 6.10 251.0
•:O
Monthly Limit I 40 MGD 28uG/L 25m9IL SOmglL 200e/100m1
•
DEM Form MR-1(8/93) 1

I
1 , EFFLUENT •
ID
1
' NPDES PERMIT NO.NC0024911 DISCHARGE NO. 103 MONTH: July YEAR: 2013
II CILITY NAME:Metropolitan Seweraae District CLASS 4 COUNTY:Buncombe
..rERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc,Certification No.40 (2)Meritech Certification No. 165
Nat additional laboratories on the bad sIdelpage 2 of this ram)
ICHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY
Md ORIGINAL and ONE COPY to: -.2/-I
ATTN:CENTRAL FILES x
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPO 181E CHARGE) DATE
1517 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
I50060 00010 00400 60080 _00310 80082 00610 00530 31515 00300 00095 00720
FLOW g • a
oINF C Oo .. q `m A c `m o o ro 2 g o .8 c
«r t$ o N E = a 4 ov 4 o a ag 4 o ° o ' z
Q �t F aF a n w tQ 0. . E '@ g O y : 9 V
ll Q O1.
� O v m d U (7 1z d ' (J -g� 09p tg
FFEE-- o i F gir
MS HRS VID MOD C UNTO ud1. MGA. MOIL MOA. MGA. MPWI0014L MOO. uSioM uOIL
.;r.:;:;;.9.z•:.::•.•.•.. :'36:Q ...:::::::.:i::::::
:�:<'40:�i ...........�:9cY::::::'... :::'[6r2:::::b.....•9:Z•:•:•::•b:••::�9c0::::::ti. .:::$:66'•'•';•:A
:�:4�:��::�:240U�:�:�::�:�Y71:� '�:�:� �::�P6:9�: 2G:8�::�:�I:i� � Y . ,
I
2 2400 24 Y 27.2 20.3 6.9 <24.0 10.6 13.4 10.8 e 1.0 6.65 394.0
$ ;
4 2400 24 B 74.6 19.3 Holiday 7.30
ti•i.•.•. .-::: A44::>•:•:•:•:•:• ::
249.0
::: .:�11>1•' '':11k,.4.:' 'rd;il�:� .'�:$:11u;�7A:�:,::::$A:::::�F:;�;�:�:$$A:�:'::.. ,•:,•:- d ,
8 2400 24 B 68.6 19.7 7.50
IA 2400 24 Y 61.6 19.7 6.9 <24.0 7.8 4.8 6 28.7 102.0 7.68 235.0
:r:: .
..::•., :::::::-:::aai:i::* :4;:;:::::::aoie::::%iaa::::::zo:;:::;;izdi::::'...... ... :::;i;ia:::::....:.:s7i:•:: :::::'.:::4 :::::'.....:::s
10 2400 24 Y 42.3 20.0 7.0 <24.0 9.4 7.0 6 7.0 1.0 7.28 326.0
:
::;if '.::: 40: :::::::g4.• ..::Y:::::.:::dg:8::;:i9;�::::::8 :':::<U0::•:•:•:•:•:•:•:,:•:•:::::::11:4:::: / J648.0 '�'$l$':::.: dd4�:��....
...
I
12 2400 24 Y 36.5 19.7 7.0 <24.0 7.6 8.6 s 18.3 2.0 7.64 318.0
41411•:. ::::::::::::::.::::::i.:::::::.:,:.ii.:::::::
14 2400 24 B 48.2 20.9 7.50
7:59-:: ::Y.6 0
_ ... :�:45:3::::-' :::9:6:::��.. •.•23:3�:�::-:e::"i 97:4;::::. .i .. .
:'IQ•::�:�:_7i}GO: :::::�:24�:�::'..�: .�:�:� d9;2:;�:19:7':::�:8c9:�::::�?,8�:�:'� ,_. ..�:�✓' ... -..
I
16 2400 24 Y 32.7 20.2 7.1 <24.0 :: ; 7.2 7.2 7.1 a <1.0 7.25 360.0
.....
-Ay:::.:::24UU�:-:-: : :���271:� .::::Sf: ::::::32:7::::2d:4::::�7:4:::::� : 4.0�2 . ......:.•:•:•::::::$s7:::::::..
I 18 2400 24 B 31.1 20.6 7.0 <24.0 5.2 8.4 6.2 1.0 7.38 368.0
:;til:;:'.:::000:::::='::k4:::•:: ::::0:::::•:-::2$;3:'::kii.d::::::to1:::::::00::<::::•:•:•:. •..•• :::9:4:::::•:....::;4;d: :......-:',.:•:::•:44:•:•:.•.
20 2400 24 B 27.1 20.1 7.20
'v:•:•::•:::
I 22 2400 24 Y 28.2 20.7 7.0 <24.0 8.8 10.1 6.8 1.0 7.78 391.0
-•'-•.-:.
• ':r':' ......74.....:... :!10.7}:} ...•6.8:?{}e:••'•}:1:0'{: } {:4,._ ..0.: '..---
};�j:::.::::p400-.:.:.:-::24...,........x..:•-•:.:_28:6�: 21:9;:{ 8:9::�;:�:<Y4A. ... _ '' '•'• .:. _ -
24 2400 24 Y 26.2 20.5 7.2 <24.0 7.8 2.0 10.9 6.7 2.0 7.10 413.0
•
::23:'r.:r2ii!66i}:::}:E4:}:::::::::1::::::::::i4;1: ::494'r ti::Z:3}:�::4t24Vk:}...... ... .:}6:0::•}'3#•::. ...
:::.46o::.. .
I28 2400 24 Y 23.9 19.4 7.4 <24.0 10.1 12.5 6 6.7 <1.0 7.23 421.0
28 2400 24 B 28.2 . 20.8 6.10
.. :: . : :::g4:.
::�::'.:::��:�:� '}:Z4.: •.•.•. `;::;';'B:G':�3¢:.6::?:7.: :i_i1�4 �:.. :::�:�:_�'r:•' '.�.-.6}$ :: .... •:��:i� ._.. �.. .::9::'.. .�:�� >..._..,
30 2400 24 Y 24.3 20.7 7.0 <24.0 11.1 2 12.8 10.0 a <1.0 8.67 456.0
I
•:•i:::.•' .:77:11::::......•
..... :42:8:�:��:. � i3:4�:��' •i: .•.8:6:�:�:��:....�:�y:U�:�:�::�....�:�8:44:;:�:'r:4
�:{41�::�.�:�2AD11:�:�:��:�:¢4:�:�:�:�:�:�Y:�:�:�:��:29:9:�:29,2:��:�:''1713:�::�:•1�36J0:•;;.•r'•'•'•'•'-•' '�'1
. ........•............................ I ...... ... - l ••.389.8::
:';: ::'3.6': ::'7.14':
. 20.2 0.0
8.6 9.5 2.0
111
AVERAGE 37.7 r •,�•' ,
.:•.
'7
IMINIMUM 23.9 19.3 6.7 <24.0 6.2 3.44.9 I 1.0 8.10 229.0
•.,:iiiiiiii:44..i.iiiiiit:::::::.:.:....i:.....::::-a:a....".....:.:::::: :....:.-..:.:::-..4:.:.;.:...:.:::::::.:.4.:.:::ii:::.:.:.::::.:.:.i:....:.../.:::.:.:.ii:.::::.:.i'... .........::::*::::::::::::: :::::::::::..: :::::•.....:.......•.:.:•:.:.::::::...i:i.::::,.....:......::::::::::::::::::::::::::::.,.:.::::_iiiiiiii:.::::::::::::::.::.
Monthly Lima 40 MOD 28u011. 25mplL _ _ 30mgl_ 200d100m1
DEM Form MR-1(6193) •

I !y . I
m i i EFFLUENT
o
Eyi
NPDES PERMIT NO.NC0024911 DISCHARGE NO. 103 MONTH:August YEAR: 2013
( CILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
.'ERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773 '
CERTIFIED LABORATORIES(1)Pace Analytical Services, Inc.Certification No.40 (2)Meritech Certification No. 165
(List additional laboratories on the bsdcside/page 2 of this form)
CHECK BOX IF ORC HAS CHANGED 1 PERSON(S)COLLECTING S' u PLES: OPERATORS I PACE LABORATORY
Mail ORIGINAL and ONE COPY to: 9-Z3-1
ATTN:CENTRAL FILES X J i��
DIVISION OF WATER QUALITY of
(SIG =-E 2F OPERATOR IN RESPONSIB•-'-I,,-1_,_,..//:"..tgt,c(2 GE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1017 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60060 00010 00400 60060 00910 90082 00610 .00530 31016 00300 00095 00720
FLOW u3
U 8 1 INF O U p U in r ii
•• c m$ o c tyQ V t� G C1 rE a v H 8 eS E c aF $ . m a0� 'a m w rcm 9 m d O C! �� O Ote
O EI
H
Hes HRa YB MOD , C _ UNIra um. MGIL MOIL MOIL MOAM- MPNROOML MOIL uS/CeM.
^:4:::-:�: ::2400::�;:::: 271::•::::::....4e.1::::: ::-Y8:8::::2'1:3 :�:.7:T..:::: 4.0::..:...........::::13:7::::::... :::. à .:.:•.. ...•9:H::::::•:..b:::: :'1:0:::*::.:i:
:s:ts:: :::•: 6j1:::•:::.:i:*:::.:*:::.:
2 2400 24 Y 26.0 21.2 7.2 <24.0 12.7 7.9 9.0 1.0 8.60 476.0
4 2400 24 0 23.2 22.6 6.80
..-:4`'r::::::4441)::::::::::24:•:. ...::Y::. Z$;t<{;41;3::•'r1;x:: :::: t4;0:: .............::Z;$':':':•:•:::. , •. _
�:44�
6 2400 24 Y 24.1 21.6 7.3 <24.0 7.2 2 16.4 ,,6 8.8 <1.0 7.39 528.0 ,
,..:•:•:SS.O:•:•:: :.:'Iso:: - ::6;89:•::::::,4!79:1•:.
}:4:::-:�}:2400�'rX::::2A:•: •.•:.•:Y�:*::•::�26:0.::.2Y:8::?:�7a:::•:::<g4;0:.:'......:•:•.......:.:12:8.::.:;:?•:;:•a82:.::.9.• --... •:•, .•.•.;.
8 2400 24 Y 26,0 21,6 7.2 <24,0 24.8 10.3 14,3e a 9.8 1.0 a 7,13 455.0 <6,0
':'it:::...i• i::.::.::.::.*:. •.•.•.••' ,.:•:S4c0:: ::•...:::..7:itb:::::::466,9:::.;'•....;:i::.::.::.::. II
...:�ZADD:�: ^:�:R4•.•J::.•: :�:':��:it4c9:��:s24.9:��:�:;s�::::is24:d!': •.•.•:.••:�:•7:7�:�:^ ....':'93:7�:••:•:'i:�:�:�:602��:��'.
10 2400_ 24 B 26.6 21.9 6.10
12 2400 24 Y 25.7 21.7 7.0 <24.0 6.9 13.2 8.6 1.0 a 7.00 464.0
--:13::;::::$DQ:: ::::::24•.•,.•.•.•.:Y:•:•:•:•::411:$::..:M:a:::::%$::::::40::;::::•:•:•:.:. .,. .:::7;1: :.•:.. .3,t.:. . ....f::::::••...... .
14 2400 24 Y 23.9 21.0 7.2 <24,0 10.9 12.9 8.3 s 4.1 6.94 453.0
•:1ty::•..:::74}QD:::::••44•:..?:: ;::1f::::::i:::20;3:;;:90:8::::::i<:2::::::- 24:0(::::... . --::8:9::'':''•.. •'•171:2•'• . ::::::: :.:Ii::::
:.:.:.7:1g::::. :::4B5:D:::' :::.::
16 2400 24 V 24.0 20.8 7.3 <24.0 9.9 16.8 a 9.3 s 1.0 7.01 478.0
i
:. .:.
A '•.:•:;teba:•:•::•:•iii:•:.•:.•:•s::•:•:•::•ii:sz.:::±i:;s:: ..... ....... ....................... ....................... ........ .. .
18 2400 24 B 23.2 21.16.70
::1 �.4p
> ::'•:� p::::'•':::$4:::::::•::::Y::::::::::4k4: ::41:2::,:::$:$::::.44:0:::::....:•:.•:•:•:••::::f. J
20 2400 24 Y 28.2 20.9 7.2 <24.0 9.6 12.2 10.0 3.0 7.21 390.0
•,•J,•,•.•.. ...7: ::•:•:•:•:•:•:.
22 2400 24 Y 24.1 21.6 7.1 <24.0 7.7 a 13.5 8.0 <1.0 6.97 512.0
:!'•'' '0:::: :1sD:.r: , :1.1E•:•::•:•488:o: -:...
::�;.••: ¢4bU;:�:�::::�Y71:�:;�:::�:�:Y;:::�'�::�ZY:9�::�2'j:9�::�:�7:Y:�.�:�:2Y4.Q::�'. ,;:;J:;:•:•::� :6:8:�:�::�:��:�::�:'[4;3:�:'�e - .8. .. ..
24 2400 24 B 22.0 21.8 6.10
:•:<::::::::::::: ••J:•:•:•:•:•:-:•:-...•••••:::••' ::•s:bb::•:•.:•:•:• :•:•:•::•......:
26::•.•:•Z'aUO:•:• •:•:Z4-:•.J :.•::t3:• :::.•:Q4:8:.•:�4s7:�^:...................•.-.• :� •:•:•:•:•:•:•:.,•:•:•:•::-...:•:•:•:•:•.:•:.J •:.................
28 2400 24 Y 21.8 21.0 7.2 <24.0 6.7 16.9 9 7.1 <1.0 7.20 494.0
28 2400 24 Y 21.8 21.8 7.1 <24.0 12.2 2 14.9 is 7.7 a 2.0 7.18 487.0
:•%,•::•: :•:•::::•••6;91.:•::•:•:111.44:•;_:•:•:•:•:•:•:•:
30 2400 24 Y 22.1 22.1 7.1 <24.0 7.9 15.2 8.0 1.0 6.84 496.0
•:39• •.•:•24D0:•:•:•••:24•:-:•:••:•:•t3:•:•:•:••:S29 ••:2• 3:••:.......................� ..... .......... - ...
:•:•:•••:•'•••:•:-:•:•:•:•:•:•:•:................
:•.:•
.8.7 • •.•14.0•. .8.7 •1.4 . .•8.84 .
.
( AVERAGE 24.1 21.6 i 1 0.0 24.8 471.2
::::::::::::::::::::::41#0,01::::::::::::::::::::::::$2;9'r::;z;Z:G::::.:7.;3::. :�:c,¢0:. ..:•.•24:$:'r>; ::: :144::::.....,;i::::$0;8:::
MINIMUM 21.6 20.8 6.9 <24.0 24.8 6.6 7.9 7.1 <1.0 6.00 390.0 <6.0
•:•i::•:•:•:•:.;.;.;.
Monthly Limit .......: 40 MOD• 28uG/l. 25mg8.
30mgM1. 200eA00m1 22u0M110
DEM Foran MR-1(8/93)
1

A EFFLUENT
I I
: NPDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH:_September YEAR: 2013
i NCILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
.,ERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services,Inc.Certification No.40 (2)Meritech Certification No.165
(LIs1 additional laboratories on the badcside/page 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY
Mall ORIGINAL end ONE COPY to: --77��//�
ATTN:CENTRAL FILES X / IF /JD'G�T-13
5'/
DIVISION OF WATER QUALITY (SI i •E OF OPERAT••IN RESPONSIBLE CHARGE) DATE
I1817 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27889.1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
50050 00010 _00400 50000 00310 80062 00610 • 00530 91615 00300 00095 00720
1 _Y FLOW •p
g FFF p C b G
8 0 v r o '° d � . m m ; m g! O Vg k
I
C E s V H E p V rE o g a 9,v g o I p 6. a
o ag i a 3 0 1 ?Pg ii i$ 3'� u 9 v
V m v 0 o V C aztO
71am' a E o il o
i Em- ix: f"
MRS NRS YID MOD 0 UNITS uall, MOR.l MOIL MGR. MOIL ...' MPW100ML MOR. uBICM u011_.
...
r2 2400 24 B 22.0 22,3 Holiday / 6.70
�:��:•:.::•fid$li�:�:-�:�:'14:�::•..�:�1f:�:�:�::::it2�2:�•:2,1‘6:.•:•:7.3%*�:::Z;3'�'' 24��::'...... •.
4 2400 24 Y 21.0 21.3 7.3 <24.0 6.7 13.3 7.3 s 1.0 7.00 610.0
: ::::::::::::::::::Z0::::::::::: • :::::
:�:�:•::�:;t4D0•:•:•::� $9:.., �;il'::::::;trt•:••:�:5$4A:•;::•:•:•:•:•:..::; ::::.:"4:::•:::i4;$ ;�'::. ..::y..... :::•
6 2400 24 Y 20.2 21.6 7.0 <24.0 7.3 16.1 s 7.3 <1.0 8.98 489.2
.9'8{:'22:8•:' .... .. ... ::•::::.................::•:-:•:•.::•:•:.:.!.:;...........:.•:.:::........:600:.:•..-...-........:-..............
8 2400 24 B 19.8 22.06.80
:: ..:: 2'iS$0:' :'ti::1:4•:•✓:•:•:})1 :':':••:49:$::::,2;hid::' :C7 :::::4t241:(1f:::'...... -
10 2400 24 Y 20.21 22.2 7.0 <24.0 6.8 14.3 7.3 <1.0 15.37 493.8
:41:4::*AU: :'•71:1):.: ::423.0:::... •:,:•:•>:?::20:3;;::: ::k86::.:::<::::::0R:•:•:' •.
$ '
I 12 2400 24 Y 25.9 22.7 7.0 <24.0 6.9 15.4 7.7 <1.0 5.68 478.2
7;;:;::
14 2400 24 B 19.0 21.7 7.50
6. 0:
I
16 2400 24 B 18.0 21.2 7.4 <24.0.• 6,13...• •..15.9 .s 8.3 .<1.0• 6.77 .500.0
>.:•.
:�:i7:::::::,240G::�::::�:�2$::••:.:::13:::::::::::19:4::::ii:ii:::':::7:if:::::::C44,0:.::.............
18 2400 24 B 19.4 20.9 7.4 <24.0 8.2 14.9 5.7 <1.0 7.20 535.0
:;1,.. •:4.$A:::: .
I
x:18::::x4�il::;:;::;:;�: ::'..�:`�: �: � i.. �;ia6: .:i'$••' 141. .. .
20 2400 24 B 19.4 21.6 7.3 <24.0 7.0 14.9 s SA <1.0 6.61 683.0
::.::.::.i.*::::::
2400 24 B 22.2 19.6 7.20
..... :.:.:_::-...6i94.-.:<:-.-50441..7.........•...-
.7.24..
:•:8.9 04:0•:••'
. ,.1.. ... ::4:8:�:'::• :�:'ff!ct:�::�b:��' �:�07'''•"•:d'�•':i21:G:�:� ....
In
:•23::;:-:-:g400.:•:-:�}271:•:-...:::•:Y.:::.:-::_�8:��::�2'1:4�::�}7:2'� .. Y4Q::v{?{:}. .-- - _.... .� - - - ,.
_24 2400 24 Y 19.4 20.4 7.3 <24.0 6.6 13.6 s 6.7 2.0 8.78 659.0
:'..42i::::.:44.9.6:::::.:::::44 .2'.:'.*:::1i".::::::::: 'iti9::':24t2::::i:Zc3:::::::4s2ti.fi:•: .... _ .. ..
$:99 ::::::SEB 0'::''.....
I 26 2400 24 Y 22.5 20.4 7.3 <24.0 11.9 11.8 s 8.7 3.1 7.21 443.0
:: : ::2400:. r:14: :i :IC:::::.i: 0:9:::fiti$::;:;: ::, :::•40::.::::::::: •_.::::11;U :::zy:••:::%9:::' ::::;2:::':.;:p:.: ::.*:00$:: ": 4$$:4:::.
28 2400 24 B 19.6 20.2 7.50
30 2400 24 Y 19.3 21.8 7.4 <24.0 9.3 16.4 8.8' <1.0 6.84 457.0
I
•.•14.8•. •..1.
I •:::::•::::::::::::::::-::::::::::::::::•:•!,:•:•:•:•:•:•:•:.:.
.•7.9•. ..7.6..
S 10.0':
AVERAGE 20.8 Y1 1
3 6.68 497.6
.........''r:QtiWl4M:::::.:;::> r
'rr:: 'i( :':iiia:-.....:z;4:::',.::_.%�4.:,.:<...:..::.••:., .. L ., :::f0 .:.:.:::::::a::: ::: .
MINIMUM 16.0 19.6 7.0 <24.0 4.6 11.8 5.7 1.0 5.37 404.7
is
'l:
:.:•:.::::: ::::::':•:.'..' ►fit }}yy:
I
Monthly Umit 40 MOO 2Bu01L 25mg/I._ _ • 30mg I. 200d100m1
IDEM Form MR-1(8/93)

c I pp
f �Z I I EFFLUENT
V
o
c
NPDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH:October YEAR: 2013
"ACILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
JPERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No.L
(List additional laboratories on the backsidefpage 2 aft form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: O-ERATORS/PACE LABORATORY
Mall ORIGINAL and ONE COPY to:
ATTN:CENTRAL FILES X -.7.'-..-7 ‘Of
yI
DIVISION OF WATER QUALITY (SIGNA I E o OPERATOR IN RESPONSIB ..--E) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
50050 00010 00400 50080 00310 80082 00810 ' 00530 31815 00300 00095 00720
N
U •
,a ' . V .
goI. s ° c o . n c v A'
S E o y!3 a C> y g n !E o p rn a 9 0 re Z II
C iU 1 0 w v O O O 3 if U d Q 1 i U
I O - CO qt dZ d � O '� d o0 U
0 C� I-
11R8 FRa18
Y .•• C UNITS • MOM M08. W07_ MOIL - OOhi MOA. us/CM VOA.
:.2400 .. .:. ...:.:X:::.:.::::..R.4.' .... ":::9:'`•: ::::<'•':a:: •.
2400 24 Y 19.1 20.8 7.3 40.00 6.9 16.1III 8.1 <1.0 8.78 648.0 i
:.2ii00 . :24.:: ' ::Y::: : ::14;3: ::21:0 ::.:7;4:::.:'<24:11::...... :7:4:' : 1f67::: ::9.4
'' •'!:0•''.•: :.•8:94•::•::8660:::} .
2400 24 V 19.2 21.6 7.3 <24.0 8.6 16.1 a. 10.6 a 1.0 III 6.80 601.0
:g: ::i:ii:i00:i: .:::2i::: ;:i f;:i ::19:9: 21:6::i:i... ... ...::1 i:iii;li0::
6 2400 24 B 18.8 21.9 .. 6.30
�:Iiiii::.:?2400 : :: 4: :.::: :::::'::ii;ii ::.iti j:�:?....i.; ::::s ::i*i40:::..... ::.:::4:6:i::. .:sae::' . .. 4*2,:::::: : ;k
8 2400 24 B 21.9 19.6 7.3 <24.0 8.2 11.8 s 12.3 1.0 7.08 479.0
. .:::240Q : :::24•:• :.:•:8:•:•:•:•.:20 .".: :•.....-3.:....<24,.... • . •.8•
10 2400 24 Y 19.6 19.9 7.3 . <24.0 6.6 15.2 se 8.2 1.0 7.06 524.0
:i i:: :240U: :•:•2i : •:::• ::.:i::•'::2o:S. :.19;6: :7:8- *::::i :• ::::: ::iii::-:.
t *:ts;2:::.. .*:$.11;' :::::. :::ail:6:::: :::6:9U:::::::::6'Ft►:Q::•::......
12 2400 24 B 18.9 21.0 7.20
:4$::::.:if ilOd:.. ::.... i::: ...44;1:..f:i4;1: :::
. :::'' •:•d:4fi
14 2400 24 21.1 20.7 <24.0 43.7 9.0 1111 <1.0 7.01 474.0
::::.i:4K.:::::::.*KO:::MN
16 2400 24 19.9R,:,,,,,::,:.. ..
7.4 <24.0 . 10.1 16.4 10.3 . ..<1.0 7.03 621.0
::'•17.:: :•'i! •:.. i:�4.: :2D: • 'O: ;5:. :5::;
:..M :::::::.0::.:?: 99::::::::alba :; :...
18 2400. 24 Y 19.5 20.1 <24.0 9.8 <1.0 7.03 648.0
:99•:::::27{00 :::44::: :.::9::::*::::44;11 ::1e;6 .. ' .::?::4;i6::::::*:.:*:*:.::.:::::::III
20 . 2400 24 B 18.3 19.6
® ® 6.60
:::2400: ::24:: ::19:Q:.:.:11.69:161:":::.7i.44
:19:1:: ::t:8: :: c b:: :::13; :: :::t8;i::' :::::ió::::::�:;:::ri:6:::: ::ssair::•
2400 24 18.8 198 7.4 <24.0 10.7 18.4 6.7 <1.0 8.77 595.D
4 ::i4:: '*0;1' .:::.4:,.....:.:::.:i7; :i: i: 4.A:. . ',9 . ;3:r:� n' ;q: ...: 0.•s 2400 18.8 17.3 F <24.0IIIIII 10.9 16.7 II 10.2 III 1.0 II 7.39 602.0
NMI
rii:i:i:.:iiiii:::.:*:NI ::1i11i: 1*::•:: :':•_ :::': •::::y::.:.• Migi :'1C:::'.::El:::::21:U:::111 :C
28 2400 24 B 18.4 18.8 6.10 I
::27: f... ::a4bo::. .::21f:•. ..:: ::: ::::16:: ::38;4::...... ...... . ..,.,.
28 2400 24 Y 18.8 19.6 7.2 <24.0 7.1 17.5 9.4 2.0 7.30 683.0
::ili:'.
: :ia: :.4..:•::: ::t8;a:'::ali;i1 ' :r.;i::: ::cil :•:+i:k:::: :i41 : o:::•: :•:sit;d ::/;t4: :' :64S.o
::Ill
18.7 19.4 <24.0Ell 10.0 20.4 1511111 <1.0 7.18 559.0
11,:,:,:?...,7!,:,:,11. 1 ..........
:1:fi:• :1 •'• d'.' .....,....... :.: ;• :. .,C .inis
IAVERAGE en 20.1 1.7 _■ 10.6 I. 18.7 . 9.6 ■ 1.1 . 6.96 644.7
......:4.iii'iniiiigi::::.:X:.:,:::: C:8t;5: ::09;9::•::.7:4:•::•:::Aiii•:•;::...... ... :::4iS;}: ::.:: ::::22:x::' :::+1:2•.]::' :-:
. .o:.:.:: .::7;9[: :6fiG.4::
lil
MINIMUM 18.3 17.3 7.1 <24.0 6.6 11.8 8.0 ® 1.0 5.30 411.0
'aiiiiiP'{ i. rob ):..•.,•.............. ?lG
. �:...�:c. ::'{�'::
Monthly Limit � 40 MG* .• •:•:•:•:d:•:•:•:..:•:t-s:•:•:••...,...
28UG/L 25mg/L 30myL 200d100m1
DEM Form MR-1(8/93) - I

I ...-. EFFLUENT
NPDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH:November YEAR: 2013
IFACILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
JPERATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.9Q (2)Meritech Certification No. 165
(List additional laboratories on the backside/page 2 of this form)
ICHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY
Mab ORIGINAL end ONE COPY to:
ATTN:CENTRAL FILES X
DIVISION OF WATER QUALITY (SIGNA /2�/�r/3
URE OF OPERATOR IN RESPONSIBLE CHARGE) DATE j
I1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60060 00010 00400 60060 00310 80082 00810 00530 31615 00300 00095 00720
II I Y ri P• F ta
O Cp E C
INF ❑ p ° .- 71 $ em �M y de
N 7 L > 41
a CSS F 0 E a p E ti ' ° t0t
o v' m a ° or az Oi N9: a o t7 a 0
1 °i' re
° i m $ it
FR8 las Y65 MOD C UNITS ug*. MOA. MOIL MOA MOA WNn00ML MOA e8/CM WA.
i::*:: .:::'saou.:.:.::�:.zri:.: .:.. :ir.:.:.:.::.:is:e.:::>-.u:a:::•:•i:a•:-•:•:iY<.o:�=•......,•....:•:e:s:•:•::•.. :•:ttai:=: _ ...9.a•:•:•::.. .•:•ky:'o•:•:.•:.
/ 2 2400 24 B 18.4 20.2 <24.06.32
ai
'J: i
4 2400 24 Y 18.2 183 7.2 x24.0 8,8 18.1 6 8.8 <1.0 7,62 588.0
I 'r:*::::::::441i6::::::::::'24::: :r'r4'::.::..$;t1::,.4:::J;4:'::'::4'S 41::.'r ;:
:
8 2400 24 Y 18.8 19.8 7.2 <24.0 7.1 16.4 7.1 <1.0 7.39 629.0
..3:•::.s:r.•:.:•8: :0•:: ::4•�2'r ':...:ii:a:'r.:•:4,6:•:•
:::7::*:'::: 0G�:�:::':�21F:_:••'::•Y::•:':':��6:9:::�:19:8::::::i:i4•:�;:�:1f4:0:`�:::f4c7:`.`::�...�:�'.I$:6; ::::e:::�:�:t1T:._ . ••- ..��' - :�:�1 ...�.
8 2400_ 24 Y 18.6 17.2 7.2 <24.0 11.1 16.4 s 9.4 <1.0 7.40 660.0
�
( • :::'.: 2'Adt):�::-:::¢4•:•..•: •B:
,•. :::::::;1.6;i:.:::..4.6::±:.....::''1s28:�� ::'...... ... ......
I
10 2400 24 B 17.6 18.2 <24.0 8.43
11;: ..::;iati0::,..::g4::...�:::13: ....:1ty::::it:7::.5fi3:: .::s#ato:• ..... - .•:8:2:: :::::::::::::k10::::4:'.•::::::/•A::::::
I12 2400 24 B 17.8 17.7 7.3 <24.0 7.8 17.6 6 7.8 2.0 s 7.62 559.0
14 2400 24. Y 18.0 18.1 7.2 <24.0 7.8 17.2 8.2 1.0 a 7.81 551.0
• :.•,•. : :.:.ii:o• : :'......::i:68 .:s6ro:.: .
I ::'Ib::'::�?iJRG:�:�:••:•:g4:::: ::�;:y'•;:;:;:;::;19;Z:;: IBc6::::::;c3:•:: :a24: •:. .. :•:'19E8:':;. .. .;:I�?:�:;::;d.. 8 :::i; .... --
16 2400 24 B 18.3 18.4 <24.0 6.46
18 2400 24 Y 19.2 17.9 7.0 <24.0 7.2 19.8 7.8 1.0 7.40 620.0
i. .J,.:,.
:%18�::',�::i4d0:�:�:" :$4•:..•..•:�:i:�:�::::%I$;1 i:4$:d:�::x;�.�::�:xti ...
f�f•.... . ... .�:�d:$::� i:....�:if$:it�:-i:6•J.•.•.•.'/ati:::: ....:4ii,]:,:'•,.. s.• ,, ,
11
20 2400 24 Y 18.1 18.2 7.2 ` <24.0 9.3 16.0 7.4 a <1.0 7.23 682.0
•.'J:.•.'.: . . :••.
:•:.1
7:' .n•::::::. .:::a:0a::::: ::ase A::
22 2400 24 Y 18.6 19.1 7.4 <24.0 8.3 18.5 9.8 <1.0 8.67 546.1 •
II
:S:'6 :' ::*: :::: :: :: :...
24 2400 24 B 17.1 18.7 <24.0 7.95
•:26::'.•:•241:11):•::'-:-:24.:•::•:•:•:•Y:•:•:•:--:98;11:-.:44:11:•.:.:7;2:.::•:4424:H.:•:...... ... :..1 s11:•:.
:•7:80 . :ii4(IA':: :
26 2400 24 Y 36.8 16.1 6.8 <24.0 8.0 18.0 s 9.9 s <1.0 7.78 666.0
I
:-.0:::::::$4DR: ::;'::id::::::.:::iC:::::�::-3gii:::�;Id 1:::: x:'t�::�:::5t3.:Py.
.9,$:::::.... :::1h3::;;::.."..::::::($:i:::::,'• >
.. ..
28 2400 24 B 21.9 15.0 <24.0 Holiday 8.10
::44:...)::::$90::::::::::%11::•;;•::::::0.:::::::::41141:::14:4:::: ,•. ,•::?14,.. Ho'Udliv•:. , . .,.
I
30 2400 24 B 19.8 16.9 <24.0 7.72
. .
_ ......... ........................ ::.::::.::).:::."....:.;:i :;:6•2.9• .0.0
I •
AVERAGE 19.5..'17.5 r 1 0.0. 22.7 10.3
18.7: :.B.9 1A 7.25 642A
:::.:.i:i::.i:i:i::i:ii.:i.:ii‘i.:::i:i::i::t:,i:iiiiivi6iiiiiini:i:::::%.:•••::.:::::::.:::::::::....ii:iii ii i'...4::.: ::4: ::t1.
: 41.....
t:: :1$:9: ..;$:::: ::;•ii. ..::••..... x',11: : ', :'11 :•$ li-MINIMUM1711418.8 <2407 6.6 10.1 J 7.1 <1.0 6.30 319.0 <5,0
IIi0 ::ii6:::::::.:i:i
Monthly Unit 40 MOD .28uGA. _ 25mg1L 30mg& 200d100mi 22u0/UD
1 DEM Form MR-1(8/93) .

EFFLUENT I
••
I
NPDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH:_December_ YEAR: 2013
FACILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
I =BATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
I
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc,Certification No.40 (2)Meritech Certification No.165
(List additional Iaboretortes on the backside/page 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY
Mat ORIGINAL and ONE COPY to: LC/ _x n /
ATTN:CENTRAL FILES X � C -/t'
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RESPONSI8t CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE •
50050 00010 00400 50080 00310 80082 00610 00530 31815 00300 00095 00720
g FLOW to
t.1 A h FFF .g o m p 2 `
i O p A INF 0 o 0p ' �€€ o
Cn 1J F R b N m C m 0 m • O S m O O C
F O n U ^ m O EO1 as ° fo ur Z
D ei V G a O a E.a a cn 1 !LI .s V
of o m °m d 2 v as a ve ci gU..2 0 0 3
6
I- K H
I-
.
HR8 HR8 178 MOO 0 UNITE uqf. Max MOA. MOIL MOA. MPW100.8. MOIL uSIOM uO&
2 2400 24 B 19.4 16.2 7.2 <24.0 7.6 16.2 7.2 a 14.8 8.22 482.0 w
:::3::: 1): ::'a• :::::: b;4:. ;:.a;2.:::.::.: 1;S:6::.:
. ::��d4 .. .. a:�::'... .... .1 .. .%16��:��... .. :::::*::::::::':... :::aa;i::::::....*:::le:z::::.. ..::ta:a:::::'.....:::iii:::::::a::'.:::A:4is:::::::::iskto::::'.......
4 2400 24 Y 19.7 18.4 7.3 <24.0 9.9 16.7 9.0 <1.0 7.97 830.0
:: ::
::*•..:24:::: .:::4::::.::.::. ��i �:r•
1:.
6 2400 24 Y 21.8 18.0 7.2 <24.0 27.9 18.9 10.3 <1.0 7.60 882.0
:::7::.......2400:::::: :•1113.: :-:1•
8 2400 24 B 20.2 16.8 <24.0 6.07
:;:
2?tUD::: •::P4:•::..: ::: :24:U: :16:9 ::<:3:: ..23Ef: .. 2 e..
_ ... ... .. 0.1(:�:��:... �:�7t:4�:`�:. .::�:'l.:U :�:�•:i�:::�:�2:0:�:�::�b::•.�:�8:04:�:��:�.6 B:U:•::.......
2400 24 Y 25.1 16.2 7.2 <24.0 10.4 16.4 7.5 a 6.2 a 8.64 476.0
:::.
9... . ..Y:::::219 ....z: :3: : 2A:. ;:
12 2400 24 Y 20.4 14.6 7.3 <24.0 10.7 13.8 6.2 <1.0 8.35 520.0
:
::1�:''::•�Ap:::::'::::24:::::::::::$::::::::24�::::•.:�:Y:�:�:�:�::04::::14.4:••:.:/.0.1:•: ::1.�4,.. ... .. rt:::'•
14 2400 24 B 26.8 18.0 <24.0 7.16
:�15&: : 0 ::': :•4: :::a::::::•: 0 :•BA .*:::.04::
':'x40. 7r�1 .. .. ... :}T;413:}:"''
16 2400 24 V 21.1 16.5 7.3 <24.0 6.9 14.4 a 8.7 1,0 8.61 438.0
:::IT:::.:....:4466:.::.:: 'r}2i{::?:::':lC:}'�'::J•�0:8::': 3:9'}'�7:Y�'�).::. iii. :.:4
, ., . I .'
...........::5:7:•:•:::... :•:4$,6:•:::b:••..::•B.'8::::::::.. .•:W.0:?:::::. .:::8:30:::::AUB:Q:::'::......
18 2400 24 Y 19.7 13.3 7.2 <24.0 28.9 23 14.7 5 6.6 <1.0 8.40 585.0
::i.9::::::::.246:::::.::::iii:::!:::::::**::::::::::iIt'8:-::iii::::::y' ':' 24. ...... ... :::>L:b:::::::... :::ld:$:::::::: .....A ::::::::::::::::.*.ti:::::::::::::::::if4i:::::::-:ki$9'ti::::'.....
20 2400 24 V 19.9 15.8 7.2 <24.0 10.4 15:6 6 6.6 <1.0 8.14 632.0
4:
::3 ::<'
22 2400 24 B 47.0 16.8 <24.0 6.05
:1•.
:-:2400•:�:�'•�'11.. •:•Y•:•:•:•:::59:0:-. :�.'4:9�::�:�8:9�:�. Y4A:� ' '':6::... :::8;:. •.:�:::::: ... •:::•:::::•:•:-
-•�:•:. :;3 .. ---.. � - .::�:: '�: ... �:y{... .... .:!•::}•.:::7:::::?�,... ''6t2:'r:��' ,:r:B;BA'r::::;::265:Q�:�
24 2400 24 B 32.3 13.8 <24.0 Holiday 7.96
: 2..
�:4fr:::.:::�d0::::::::�:>t4:::3::::::�9: '::'� ::
�:24:8:��:43:6:��:..... . 4J1X::•EldllllA� .. 8'6i:
28 2400 24 B 23.3 13.9 524.0 Holiday 8,27 d
4:: :;�.
Xl .,::M1Otf:...:�... ...:Y:. R�r}:.. ;h:::.:"4:,i::: : 52P: ::�;.
28 2400 24 B 22.1 13.9 <24.0 8.69
:::1 _
30 2400 24 Y 26.3 13.0 7.2_ <24.0 6.8 10.9 6.2 <1.0 8.76 378.0
::t11:..•;.;2iFGU':'::: ::24* .::Y ::,:::::l10c8•::'96. ii:::...i...::::::::::.::::::::%. ::::6:4:::::::....: l2:Y:::......:i8:::::.•::•:.:::{iU:::::::.
.''.AVERAGE:...........:•24:3•::.16.0- ! ..•0,0 ....................... .......... .........:•:•:........:•:•:,.....:........ ......... ....... •:•:•:•:•:.:.:.
•.12.6••• •••14.7•. .'•9.0•• .•• •• •••93.8..
L 1 1.57.934
I
......,...�: NtQ ;�.,........ ::9a.:::...i9.¢:: ........xs.......... ... ::29:13: .. ..:�48;1i�:�:. . .i4 ::::.'.... :14�6:..:'i'....:�9;ti@::i ..$Li9A:'::... ...
MINIMUM 18.7 12.9 6.9 <24.0 6.2 8.6 6.6 1.0 6.05 255.0
•iiiiiiiiii...i4iiiWi.:0)......:•:::1.... ....::.:. ...:::.::,:.:::::::-::.i:i...:.:'..ii.::...:.....'4..............iii:4•:::.:::.,:'....:.•.:.::::.....:::::::::::::•'....•::::.::.: ::::::...::.:::::::::::..::::: :•.: :.:.-...:: :.•.•.....: ::.:::......7;:i:::..........iii.:ii.:.:::.:.::::•:-::::::::::'6::::.::.:.:::.:....:::‘::.::.::."....."..-::.•::::.:.:::::.: • i
Monthly LImIt 40 MOD 28u01L 25mg/L 30mg/L 200c/100ml
DEM Form MR-1(893) 1

EFFLUENT
NPDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH: January_ YEAR: 2014
FACILITY NAME:MetroDolitan Sewerage District CLASS 4 COUNTY:Buncombe
I ( 'RATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
t.,-,<TIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No. 165
(List additional laboratories on the backside/page 2 or this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY
MLIII ATTN ORIGINAL
NTRAL FILES COPY to: XQ -leagr(2__ 2_I p/,/T
DIVISION OF WATER QUALITY (SIGNATURE OF 0 TOR IN RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER • BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27899.1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE •
60060 00010 00400 60060 00310 80082 00610 00330 91016 00300 00095 00720
FLOW g
0 c
aU v ,S o o N `o `so m • `uoM o` me Z
a C l 1 o E1 9o
a d m° ° ° az $o � ° o° cR
ei
12
,
Fite t4R8 V. Moo C arum us/L Awn. MW. Mail MAIL MPWIaoAi Mon. u8/CM WA_
• :::9: - :::21b0::::::::2i.•:•..:.B•:::::f: 22:0 ::3a:8::'• .... :.' 4.O::fF1a'flilay::::;:::• ...
2 2400 24 Y 22.0 15.2 6.9 <24.0 8.8 .13.1 . :.6.2 :1.0 7.97 408.3
:•::::.•.
:::3:::::::::106:::::.::::$4•.::.:•.•.4:::::.:.•:44.1:...4 0..:::: ;2.:. 4:([::.•...... ... :::$:6::::^.:.:e::::::! ..
4 2400 24 B 21.2 13.2 <24.0 7.93
;� '.
I
6 2400 24 . Y 20.2 12.7 .7.2 <24.0 •.7.6 16.2 6 6.6 <1.0 8.89 498.0
:: :: .. . .. .. 8.,.
}:7}::'•::;�400�::X::::24:::: :::::::::4. �'�:�:::}29:4::::'19:5 �'�7:1�'�� 4d.0} ' '•'Bc9: �:'� .::::44:::. :•'•6T'��'• '•'+�I. - -.. •)4 .�:•,'._,. ..
8 2400 24 Y 21.4 10.0 7.3 <24.0 12.8 s 13.8 s 5.7 1.0 9.13 442.0
.;.
40'
-�izo;s:.:�a;i', :.:ail:.: .::iii.*:: ................4
. 11::::.....x.: :ii: ..:::a:es: : �:...:::{%i:d::::::i
� ::'.�:�a �tii::� i . .."..... .
2400 24 Y 22.0 13.4 7.3 <24.0 10.1 14.1 7.5 1.0 8.67 611.0
::;
II 12 2400 24 B 31.3 12.3 <24.0 7.97
::.
14 2400 24 Y 23.6 12.2 7.3 <24.0 7.7 12.1 5.7 1.0 8.86 438.0
:42.•: ::•i7o3:: 2• :13 7 •.s• 8::' :.... .•:U::' :9:58:: ::465;0::
�4a�::�'�ti4RR�: �::;:;g4,;:�;:;:;:�:y:v:�,:::114: •2:' -- - ��:- ... .':�9:1�::•'; .. -:�:•6, ':'1 .�•:�'��'
16 2400 24 Y 21.6 11.3 7.2 <24.0 14.9 2 13.0 6.7 a 1.0 9.03 601.0
1 •
:.5:,; 4.. .'Viii•:':' ::48:i::: :::71:2:'::::::.. •:::::::,6:.*:.:::::::::: 9clti::::::::iiiti:rt::-
:�iT��::�:a'abo�:�:�::�:�iii:���:.�:�:��:�:�:�::�2i:a��:�:IZ ::�:7 .�:<2 .a:� :.......... .. . ... .. ..
18 2400 24 B 20.9 12.4 <24.0 8.09
:;:?
I
20 2400 24 B......,...20.7....13:2.............<24.0 Holday 8.79
•:.' .
:�R1::::�:�:�M1Ot�::�::;'�:$... ....... ,.•RA�4�: .R;x�::�:�x:4�:��...�dA:� i::::::::::::**,:::::::::.:�:�:6;R:�:�;�'... :�:�@:6:�;:�s:�::�:�:�y:��:�:�:... .....0�:�:�'.. .:�:$��5�:�:�::�..9f:4�:�•..,....
22 2400 24 Y 20.1 11.2 7.3 <24.0 14.4 2 16.4 7.8 a <1.0 9.23 499.0
•UC�:�:�::::...../.4:.::.:;::.*::.::.:: .Y:•:•:•:::YO:t:::�.�i:4•:':'•7:2::�� 240: •:ti�::::::d:::::::i86:::::e: :7`.• .0�:�:��' '�:8.9 ��09:
'•7.3:�;}:R4 ----- - -'I. ..- - - '�:•'I� - ... , j':''.. ��:�:;:: 1. ,.i11� :�.� .SI::'::::::::::::::::::_ii
24 2400 24 B 20.0 12.2 7.2 <24.0 9.0 15.3 7.1 <1.0 9.45 497.0
r.
:'Qbeti'::•g2s3:: ..:.i:iii4:0f::: .. ....... ........... :::::.: .:.:i:::::::::".:.:::::.:
.................:::8:4i1:::::::...............
26 2400 24 B 20.3 12.7 <24.0 6.76
28 2400 24 Y 19.6 10.2 7.3 <24.0 33.0 18.4 8.3 1.0 9.04 526.0
::1 :Sc'
:2�' *40 •:6�:::7:4�:�• d0: • ::::114::::...4.... 8:::::a: . ;,r,.. '0::,:;, ..g:.
..$•::� :R..D�:�:��:�_x�•:,.•..•.7: :::::::�R:R:��:10.. ..... .$.. ......••���:� :�:1�... .�a:�::�:�14,.. ..•j:�.....�:�:�:�:......1.. ....�:�8c�4�:��:�:�:$$.0::;:.:.:.:::._::;
I
30 2400 24 Y 20.2 13.0 7.2 <24.0 9.8 2 17.1 6.3 <1.0 8.20 507.7
9c9: :Ific6: ::T:O ':4 218: ::94c 1::- .....:31:9: :ii:]::::617::: (:0::::....:8:6b:: ::47.616:::.......
4 0, 148 B, 847 480.8
,
......:.:•:•::•:•:•:.:.:
•9. •.,2. .0.• ,.12.0,•. •.'6. ••1.1.••
II
AVERAGE 21. 1 r
.....::::•::::::: 011::::::::::::::::::::::::8$ a:::41;0::::::Z4:::;:::46.:: ...... ... .. 0 . ., ::$x:i:::; .,>.•.•:.' .::::::4;4:::::.,:::::::::::0 .. .:$z$ , ,. .,.
MINIMUM 19.2 10.0 6.9 <24.0 8.6 10.0 5.6 1.0 6.76 368.0
;'C7 fid : :
Monthly Limit 40 MGO 4.I . 28uGIL 26myL 30m9IL 200000n1 _22uOND
IDEM Form MR-1(8/93)

EFFLUENT I
•
I
NPDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH:February_ YEAR: 2014
FACILITY NAME:Metroaolitan Sewerage District CLASS 4 COUNTY:Buncombe •
.RATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
GaRTIFIED LABORATORIES(1)Pace Analytical Services,Inc.Certification No.40 (2)Meritech Certification No. 165
(Ust additional laboratories on the backside/page 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SA PLES: OPERATORS/PACE LABORATORY
i
Mai ORIGINAL and ONE COPY to: r
ATTN:CENTRAL FILES X , / -ZS-1
DIVISION OF WATER QUALITY (SIGNA OF OPERATOR IN RESPONSIBLE CHARGE) DATE
1817 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE .
60050 00010 00400 60080 00310 80082 00810 00530 31815 00300 00095 00720 -
FLOW
gds FFFg C C
W C ' C 0 oI
fijl
OY S x V nZ
Q i3 a p 7 GE3qg 9 t1 a aE•
c I m d to°o �J z o d �J '� la 0
IF.
Ht8 HR8 y6 MOO C UNIT8 wit MOIL MG& MGA. MOA. MPN110051L MOA. uSrCM uOdL
.............. ............... ..... ..... ....... ........... .. ......... ................
:•:1:• ::•:4400•:•:•::•:•24:•:••:•::•:B•:•:•::•20:0::.124::•..... :•:t24.o:• :..... ................ ....................... ........ .. ::•:161:•:•::.....:: :•::•::•::
2 2400 24 B 19.6 13.1 <24.0 6.37
:1:::'•:::',cd a'::::�:�8q.. :'k$;D'::•4 :::::•`,r;3'.'...-424:4:::::•:•:•:•:•:. '.'85;d' :•g�q:�:::6• •'•:74':•:•::•A-::•:•:5%I;O:•:•:: ..•r:•9:4$:::: •:::6$$,G::::......•.
4 2400 24 Y 21.3 11.2 7.3 <24.0 36.0 • 14.6 6 9.3 <1.0 8.40 626.0
6 2400 24 .Y 20.6 11.1 7.3 1 <24,0 10.8 •2.•. 16.6 a 8.8 a 1.0 .6 9.02 609.0 I
;:•q.;::•,:;:¢40 ::'::':271:::�:::�:�Y:�:::::':4U:4::::?j!1:8�:::::7:i:':: 24.0: -: --::;a:;:::::::::'j3:8 ::.;:4,:;;.;:4�:3:;:::s 8:f:':':::� :x:4:0:;: :::,' ----
8 2400 24 B 19.9 13.0 <24.0 7.51
.•..•.•.•.•.•.•:.•:•::•
..�::3'4 .. ::E4•:?:•:•:•:•B:•:•:•:••:4806:'.1 ........•!r 4 ......... ... ..:::::.. ......:•:•:•: .. .. .. .:: •'•'•:•...
2400 24 V 20.1 11.9 7.4 <24.0 9.7 18.6 6 6.6 a <1.0 8.44 493.0
: 1• ' .
�•4 �1 ' '1 i':d33.
12 2400 24 Y 19.4 12.2 7.3 <24.0 9.6 18.1 6 7.8 <1.0 8.86 631.0
:13 ...........i:ii::::. . d... :'t '....9::: :......1.. :824:: :: tA:::...,...
111
14 2400 24 Y 21.8 12.2 - 7.2 <24.0 6.6 18A s 6.3 1.0 8.93 690.0
•:� :•:•:•::.: •• :•:':•:•::::..
:'S•::�:::7.:4D0:::::::'. .. :'6i6::::92:R:::;:;:;:;: :'::�Y#J9!•. •... ..... ...... ......... .... ....:::9:84:;:�: :�::::::::*::::::.
16 2400 24 B 22.4 12.4 <24.0 6.66
' 8;::::;i:Q:::.:::::....8.; . .;.44:6• '• r •�•�z�'��':' �:ti:�'�•��'. .:�:$0s6.'•:�::�:ai�u�l�:� ......
I
:::1T::::::�24bG:::::::�2ii::::::::::::.i.:::::::::�:6:::::i3 ... ..<14. . ............�:�:f3:{�:�::•... .. ..:b:i•::.. .. •b:��: :9 .. .
18 2400 24 Y 21.6 11.7 7.3 <24.0 12.8 14.6 5 8.4 a <1.0 8.62 635.0
::.41)::;:::::Z160::;:::::::`44:::::..:::Y::::::::::24;0;:::412:0::::..3:::.::•50*:::z4*::::::•:•:•:•:,•:•:•:•::::4S:1:::: .,•.. •:4•':'.,. ,,.. 1 '.':'•'
20 2400 24 Y 22.4 13.4 7.2 <24.0 26.2 2 11.6 16.0 10.3 1.0 8.78 473.0 <6.0 I
�.. ..:04 •:::::11:00:::::;:::4110.:::•:•:•:•::::::::
'..4:1::,::::::4400:::::;:::g... ..:::3C:::::��:;♦lsi9:;:::1M::::::Y:4:::•.::...R.•4::'..... . .:::;:....4 :;''... ::.1.g.:;:�d:-•.:::$........ .:::7..:::::..::.:b.: :
22 2400 24 B 25.9 12.6 <24.0 7.26
:•:1 :•:693:•:•:
.. .... :13:4::� 240:
: 400:}: � 4'�•••'�'�'�'B�'•:�}::�2 :7.•:
24 2400 24 Y .22.1 12.7 7.2 <24.0 7.9 14.6 a 6.4 <1.0 8.63 444.0 _
�:it$::::.: YA00::::::::i:¢4:::::..::Y::::::::::¢406::::4408::*.:*.:i0 :.::::asY4:ll(::•:...... ... :.:44:z::::::....•:•46. . .•.•108•.•.••:...... ....
26 2400 24 Y 21.0 12.6 7.3 <24.0 10.4 16.0 6 9.0 a <1.0 8.87 477.0
28 2400 24 Y 20.6 11.4 7.2 <24.0 12.6 17.1 8.9 1.0 8.64 487.0
: ✓.
8.318.29 04.8
••AVERAGE•. •21. .12.3.,:•:::::::::L.. 1 0' ..26.2.. 13.6' :•:.:.:.:•:•:
•:-:•:•:•:•:.;•:, ••, .•• ..
}:\.:: }:r
.........:::1yyg1(N(4M::: :::::::::::::::::::gia;0::�:13.. .... . •:.�t4.... �,� . b
.� . .. .�:� ;¢ :�
:�:��:.� v::�18... .....:.10,... ....::�y:4� :�::�....�:�6:44�:�:��.. @R:V ::..�.4:::;
MINIMUM 13.6 11.1 7.0 <24.0 26.2 6.6 14.6 6.2 1.0 6.31 444.0 <6:0
Q. i..iiiiii:.(4/:*.fifir:i::.::1::;:::.*.i'..::.:::.::.:•::::.::.:•::::.:, •..•.•.• ' •:::::::6:::::::•.:•IS•:•:•:
Monthly Utak 40 MOD' •28uO/L 25mg1L 30mgrt. .,200c1100m1 22uGND
OEM Form MR-1(8193) 1

- EFFLUENT
I
4PDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH:_MarchYEAR: 2014 '
I
F 'TY NAME:MetroDolitao Sewerage District CLASS 4 COUNTY:Buncombe
DI-_ .,ATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
•
)ERTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No.165
List additional laboratories on the backside/page 2 of this form)
ICHECK BOX IF ORC HAS CHANGED I I PERSON(S)COLLECTING SAMPLES: OPERATORS I PACE LABORATORY
Mal ORIGINAL and ONE COPY to:
ATTN:CENTRAL FILES X -...-liM < iii,,
DIVISION OF WATER QUALITY (SIGNAT R 0F OPERATOR IN RES •NSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
•
I50050 00010 00400 50060 00310 60082 00610 00630 31615 00300 00095 00720
_ FLOWpp p m ro
a FFF
r' INF l7 .0 o o . 'se cy .�0 $ e
as N Est
N i 0a i g� ••°°� i i Z
P i$ p CO
P o w o 0 E is y` a V Ts iv ° p
N v
Al 1
op
o E : to O F a n
FFta HEW Y8 MOO C U7iTe uwL MOIL MOIL MOIL Mo&• MPNNO@.t MOA.
:-:4-:-'-:-:2400::::::-:-2i1:-: :.::-:8---:-.:-$0:4-::-:13:4-"'
:: .:•:12:89::•:'•....... ::::*i:::::::.:
2
400
24
B 20.1 13.8 <24.0 6.11
•
�;:$:::'•:::rAdO:�:: ' :34 ...� lfi::-:-:--:i14:0:--:4a:1♦:--:::�:3 :-:--t24�-: '•...... ... :-:1�:3::::•:•:•:.:
:•:•:•8:11b.:•::•:•:484:0:•::•.......
I4 2400 24 Y 20.1 11.8 7.4 <24.0 13.2 18.1 6 9.1 a <1.0 8.63 497.0
::::::i$::::::::- :• 0:: ::::$09;4::.- ....,.
6 2400 24 Y 20.2 12.5 7.3 <24.0 14.2 e 21.8 6 12.3 12.2 e 8.61 622.0
.-:'7•:*•'••::¢499::::- :.:•••••:.:4.. '..:.:.:•••••:.:•:•::Y:••••:•••:•:•••:3:42:9::::.:7:8:::•:::1240.'••. :.'Z1:9•:•:::z•:;•:;:•:•:•••••••:-:7 ..
•7':4-:-:-::'.. :::2:U:::::-•:. ::-:8;68:•:•: .::7.76:8•:•-:.....•.•
IP 2400 24 B 21.1 13.4 <24.0 7.70
:( .:::•±.Alda::: :
10 2400 24 Y 20.2 13.1 7.2 <24.0 7.1 2 16.4 6.8 2.0 8.84 460.0
.-;11:- .:::Z4QQ-:...:-1t1::. ,.,-:Y-:....-1ti:$-::-1�:4-:.:�;4-: ::424.0:: ...... .:10:i1-:'::... .::i1$:4:-' .•:-a:•:':
:'4:1:::::- ::::800::::: :0O8;t::-::,.,...
I
12 2400 24 Y 20.3 14.5 7.3 <24.0 12.2 18.0 7.2 1.0 8.42 503.0
:8:•:•.:•:•:•:•-'11 -•- :.:.:•14:::::. .,Q•
:1�:�' :��0:-:-:'::::x�: :::::::1:::::•::::19:0.'::111141•.'�:�:z:a :•.:••20.:. �..... �:�9
14 2400 24 Y 19.4 12.5 7.3 <24.0 17.8 2 19.3 12.2 <1.0 8.48 519.0
-:..4::.-.':240Q :_'--:::g4::: ' ::-8:::::: ::1976::::44.2::-:..... -:<20:: '.. -
111 18 2400 24 B 21.6 14.7 <24.0 .. -:-::: 6.89
:`i2:6:::.::.:iii::: :::: :iii:.:':::::: ::9:it::::::'::: :i
:: 8a6::: r:-B:Q :%I:D:::::: :::6:iltl::-: :::60U:(I :-:.....
.'..i).::•::-:24U0 :- :-:-271:-: ...:.::::::i.6.:*.:....::?..1:Y. ..
18 2400 24 Y 21.4 12.2 7.3 <24.0 11.1 17.1 8.4 1.0 8.61. 608,0
I
. :8:::::: :::ri:0:::: :::8:30:::::. ;bi0A:::::......,
-:%I§-:'.-:-�rt00:-:-:- ::34-:- :.::-Y:-:-:-:--:iO:d:'-:%IQ;� -:-:i:0'-'�'xz�itr-:.-..... *:::::9;i:::.::*::*:*::::: '-:-f>':4-� .-.:'7..
20 2400 24 Y 20.3 13.6 7.3 <24.0 13.0 17.9 10.0. 1.0 8.34 629.0
•i: : :4$ :: :i:o:: :::8:x0: :: ::::00 :::: _....
22 2400 24 B 20.0 14.4 <24.0 7.29 .,.
_ . ... .... :::6;69 :::i::::::::::::::::::: - ..
' ::�3:: :-:2409-:::: ':-'27(:•: :::.::.::iii.:::.::.:::20:12'- 4 - :.::.:*:::*:*::•.::: :-:- :-:-:
24 2400 24 Y 19.8 13.1 7.3 <24.0 8.1 17.8 8.2 1.0 8.84 497.0
-:2Cr::- 2'ADU:-:-:--:::Z4::: :..-:ii:-:-:-::-;lZO:U:- 42:a:--:-:8:3:-: :-824:6[:: :.....
:::4b:U:::-::....::-1717::- .:::107-:::: .- 'i:0•::::: :::8:4it:::::_::4b_ ::::::::,...
I
26 2410 24 Y 19.6 11.7 7.4 <24.0 10.3 18.3 8.1 2.0 8.61 614.0
:•: '::�I:O::: ' :�9:1Q_::::
::::94::::' :-:X- ::-::-�O:Q-'::I�;Q-::-:-X70::-':-:44'''-'...... :::�R:y ::4 ::::.iii*::: ::::4.:4::::::::
28 2400 24 Y 20.1 14.6 7.2 <24.0 23.5 19.3 11.4 <1.0 8.66 620.0
. . ,..... ::.-66 :-::•:•:•::•::-:• .......
30 2400 24 B., .•.. ...21.1 13.9 <24.0 6.92
::31::::::::7AUD:::;:::::94:: :.::-B-:::::::ltb:U:--:4SJ1::-:::8:71::: -:ii20J6-:.:..... -:Til-:-:: :::9:6':- :-:{4oU:-:-: i:i::-8:68-:::-:-:489 0:-::'.......
.3,
1.3
•••8.0
•••6•••13.3. •..0.0.•.•_....•12.6..•-••,17.9•.•■ 8.7 ■ ■:.....
.• '• '' •
505.0
AVERAGE 20. .;@.-:- ;, ... :-9; ..
:::) iii/14M:::::-::::: :::::-::-:84:0:-::14:1;::::;7,4:::-:494;0:: :-: Q*::- : :t1 ,:::fi1,'k::::- ,-'1 :2:: : : 4Q 5 .0
MINIMUM 19.4 11.2 7.2 <24.0 7.1 9.6 8.6ICo1.0 5.69 480.0
'•:.:'a y': '/b'i
. ''.,. ... ::G:-:- :-c::-::-.:-:G:: :-:0:-:::- •:-::I -:-::'- ::-:-:'.:-::::: .:::::::-..C.::::::.::::::.:::.C....:::::
Monthly Limit 40 e. 28uGl1. 26mglL 30mgIL 200r170OmI
I

EFFLUENT I
I; _
i/4PDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH: April_ YEAR: 2014
FACILITY NAME:MetroDolitan Sewerage District CLASS 4 COUNTY:Buncombe •
-RATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
.._e(TIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No.165
(Ust additional laboratories on the bad side/page 2 of This form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECT! - •1 PLES: OPERATORS/P'C LABO- ' S;Y
Mai ORIGINAL and ONE COPY lo: �� ' 2 7--1 1
ATTN:CENTRAL FILES X ='j `-- _1/�
DIVISION OF WATER QUAIJTY (SIGNATUR OF OPERATOR IN RESPONSIBLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60050 00010 00400 60060 00310 80082 00610 00530 31616 00300 00095 00720
FLOW
u _ H
VFFFD _ A''E,opoc INF U U N YRem ; tl oASVEC Y S .° Ca9 p EO c aO , 0e a U
c r
'
-6 MRS YOB MOD C UNITS • MOA. MOA. MOIL MOIL MPNIIOWAL MU. uSACM WA.
:9:::::-:24G0::::::::Y7►.......Y•:::*::f20:G: 'Ib:2:::-:-7;4-:-::::1ii4:--:::•:•:: :: :: ::-:•:6:7 ::::-... ::'4:B:::: .. .:::73-:;:;::;-0;;: �
.......
2 2400 24 Y 20.3 14.4 7.3 <24.0 12.6 18.8 9.8 a <1.0 8.39 526.0
::: '' '•;o:::::• ::::::03t:::::::::60;6::::•.......
-:��:�::�:� �d00:�:�'� :24. ...Y.�:�:� -:%19,8: 46�:� :�:���'` 2{b�:::� � :��:.. �:9tr.$:�:�;:�2i�:::�l9:$�:��:...::�72��:�:- .... :i1 ......
4 2400 24 Y 20.0 16.8 7.3 <24.0 13.2 19.6 a 9.7 1.0 7.83 680.0
6 2400 24 B 19.0 16.3 <24.0 5.40
:•:7-:: :2400•::::: ::21t......Y•::•:•::'•;:i::::?I3:8•: ::7:'I.::-- : YS.O::.*::.`::::...r 9D.4: :: { :: :QOW::: b::::: i�'2':::::f...;::::'d2bi0'::: ::;'Yc110'::' '•713
8 2400 24 Y 29.2 12.9 7.3 <24.0 28.0 12.8 CO 21.5 4.1 8.69 378.0
:•�::•:.. .::•::::•::-
:•.'.::: �:9.All�::��:::¢4:•::.:•.•�::: :::it4s{:- 4if;9:::::icl{:�: :#24S•. •.•:•:::•:.. :':40;8::-':.i9-::: :à: ....
2400 24 Y 22.6 13.7 7.3 <24.0 13.6 14.8 10.1 1.0 8.90 480.0
1
:= 1::�: ::iM1b1F:�: :: 4;. -..::K::::: ::=41:3::;:idb::��y:0:::::.::•44:6:-:: .............:*.:>i;b: '::::'a•::: :iti' .1 :::::: :: :j:::: '3...•:.
12 2400 24 B 21.3 16.2 <24.0 7.71
• 7
14 2400 24 Y 21.6 16.7 72 <24.0 10.9 18.8 7.2 a 3.1 a 6.62 472.0
: '•:..:-; .::•'• •:is ::•:.;.;:.: ..
16•.:::7AD0:::••::24•:..•.:.•Y.•::.•:24,3::1d;9}•:••if;,t':::x2iic-: }:v:- :•-:-: v:14:0' --: '40:8'-'d 8:-':-1;-'-: PTz •.
18 2400 24 Y 21.9 13.7 7.2 <24.0 12.2 16.3 12.2 a 4.1 8.42 479.0
.18.........2400....7...
:i7:••:::2400::•::�::Yt(::•.:•:::{r-:•::•::2y:k•::fit:i3:::::-7:4:: :•:SZS.O:•::::•:::•:•::•....ti:::ID:B:f::•... :::48:8:::•b.':•:Y0.8::•::-e::-::::Bc3::::.:-:d:-:: :8cibr::::::::2{82•:C::-::...... ,
18 2400 24 B 21.0 15.3 <24.0 Holiday 7.38
.:41).:;•:•:44011:::::: ::24•..i,...:0:::.. ".:`i6:0::::41f4 .........24:4:::...... ... ....... ...:•:• ..... .•.:•:-:::-:-:•:-:-:•,-:-:-::-:-:-:.
20 2400 24 B 26.4 16.1 <24.0 6.28
:.:.g..1:.:::-:ili1fC:::•:::.14:::.::. :Y::: :; ia::::1 tti:::�:f1;2:::::::-...i4.*:.: ...... :::• :..,.,i::::... :::i $::::::::..:::::::0::::::::::: '4ti
22 2400 24 Y 23.2 16.4 7.4 <24.0 11.6 15.9 8.3 a <1.0 8.27 494.0
'.:.:::: - 5::::104:::-: 486:Q •:......
:4.5'..-:-::2400:=:}:-21:-:.•:::Y•:•::::-22:2.::.'�b:0:::-:-7A•:•::dY40::..........r:-'IA:6• ::.•.. }:4ir2:-::;Ts .8.4; :-::�e:•�� ic'I:O::: -• ll
24 2400 24 Y 22.0 14.6 7.4 <24.0 12.3 17.2 a 8.7 a 2.0 8,23 544.0
S4.:
I
�•: �7:96 - {•.4 . ..
�:'tfr::•::��'AI]O r �::::ii::::,:::::::*::::::'•...:�':�Y:�'r`�:�:it4t8:^:4&.�:�•�:�:�sY:-:':�24.��: ��:�:�:•:•::•.. _:4?;3 :��:...::�78:3:�:- .::�Z.•4:� ';'... :;4;0:-:-::....
26 2400 24 B 20.6 16.8 <24.0..... 8.79
}:i •:•:•:::: a •
28 2400 24 Y 20.9 17.3 7,4 <24.0 10.9 19.6 9.2 a 1.0 8.01 497.0
00>
::*•: �::gdpp::: ::24:::1:`:;::ir::;: ;:::44:9��:y>i:��::::14:::; .�o:�:=:.:.:;;>::. -:�:�1. .. -R,•- •- :::::::;c0.::::::•:4:: :�.� ,
30 2400 24 Y 31.8 18.1 7.2 <24.0 16.9 a 7.2 33.3 6 69.4 8.62 372.0
AVERAGE 24.2 16.1 7 1 0.0 13.4 16.2 13.4. 4.4 7.62 488.8
•.......::N+i1X(dt4M::.......... ::58:$:: :17:0:: ...4:-:::::40:-::::,...,.... .::3>F:A::. ...,. i4,.. .. ...46;lt:::: ..., O
MINIMUM 19.0 12.9 8,6 <24.0 8.7 8.8 7.2 - 1.0 5.27 248.7
:::r `:•:
Monthly Limit I 40 MGO. .2auG/L .•.25mg/l. 30mg/. 200c/100ml
OEM Form MR-1(8/93)
,1

EFFLUENT
LYEAR: 2014
DISCHARGE NO.001 MONTH:May
_t 'S PERMIT NO. C0024911 CLASS 4 COUNTY:Bu c be --
-- . _ITY NAME:(Lletropoliten Sewerage Distrix
er Weed GRADE 4 Certification No. 10 3
-==BATOR IN RESPONSIBLE CHARGE(OBC): - M tech Certification No. 165
7.
RTIFIED LABORATORIES(1)PaceA;alytical ervices,Inc.Certification No.40 (2) i
-s aldltional laboratories on thebackside/page 2 0l )
I
Y
CHECK BOX
WORC HAS CHANGED
�
PERSON(S)COLLECTING SAMPLES: OP TORS/P:C LABO- TOR
Van.
/J
Na".ORIGINAL end ONE COPY to: X / DATE
ATTN:CENTRAL FILES (SIGNA .--E 0F OPERATOR IN RESPONSIBLE CHARGE)
I 'DIVISION OF WATER QUALITY BY THIS SIGNATURE,I CERTIFY HIS REPORT IS ACCURATE
RALE MAIL SERVICE CENTER AND COMPLETE TO THE BEST OF MY KNOWLEDGE
RALEIGH,NC 27699-1817
50050 00010 00400 50060 00310 - 80082 - 00610 - 00530 _�- 00300 00095 00720
x FLOW? •$ @ m z
1.6 8 1 It N F it1i1tIflhit
811ISAu.a p g
III - ti
HR6 ����©� � � � � � ® •:�:0:68� :::::A6::::. :
I-
I ....:: EE::iiia: :::tZ4.o -� . <1.0 Q.S 8,67 464.0
:1: ::2 2400:::'400 ©�� _■ 13.1 11111151,1 13,8
® <24.0 � ,
2440 :: = �III __SSS ■ 6.03 --
IIIIMBI
I 4 2400 8 ® p <24.0 �::: •0::,.� , tie�,
��ipM�r�ql flfOIM ' 822 499.0
anitl
•'i"'^°fI50': 11 12.1 - 15,3 {- 10,2 - 1,0
8 2400 Y m�� <Z4.0' 61 � 1l•::::tii:7:: :•:1:0:• :-
EMEMIngi
<Y�LO' ■ <1.0 ■ 7.33 501.0
:':2400- _■ 16.0 © 18.8 a 12.1 5
Y. ��n i<24.0iiii -� � ;;{4 :i:i- :'490;0::
2400 � � �!;: ::::: ,
:',20;8:: ::424 II ■ 8.74
11111111
© <24.0 III IIII II-
10• ,• 2400 , lliillr�4l�ili1L01 :Sl'4.0:: 41 ■
I �1QqQ�gg 21.1 - 10.0 1.0 7.85 ,�617.0
;:i{:' :' abb llss9s �® <24.0 �. 11.9 a BtfCLLE'l�
12 2400 Ill 8 �20.1
11i iS30 5 7.85 640.0
4 0 0 r M® -■ 15.3 - 20.7 e 10.4 a 1.0
IIIN
�a e24.0
I 14 2400 20.6 -- - :•7:08 •IMAM
:15::.. '00:• : ■ III 11A ■ 16.2 ■ 5.2 e 8.39.: 415.0
�� ® <24.0 187
1. 2400 _::: :;:30::'
p� •:124.0:
::'i7: .`:2400: _ :17.0 ?NI <24. ._-_■_■_5 6.28 --
SSESSI
INI 17,0 <24.0
I 18 2400 Iffl •:6;0';: ..:•.>j'4.:..:::40::::
i�L0�9I:'F $:: 1.0 ■ 7.84 A48.0
: 8:..:.: 4,0;: 1151 Y 20.7 111111711 <24.0 _■ 13.5 - 19.1 a 8.7 - ..:.
20 2400
' 7.66 638.0 -
_ 19.9 - 11.2 - 1.0 ......
�® <24.0 14.7 �:860't[�
22 2400 20.8 , 2.0:_•:
::'1400
- ® 4 .0 :=i ■_■rM 6.61
•• <24A -
•24• 2400 n1 •
:2d: :*i400::• �- dA: 116N . _Is.3,
28 2400 in B ff - <24.0Mp., I
a 24.7 - 17.7 8,8 <1.0 - 7.86 554.0
28 2400•: •::-
•40:.. 2 .0 19,7 ■ 14.8 a 1.0 - 7.09 611.0 <6,0
<24.0 25.1 © 28.4
gI
••30• 2400 N Y T ® .. .•:5 M ® ®::::8'06::.
Won
111111111,111 NNE III III III II
111 ( ... 5 1A 7.29 504.3 0.0
:AVERAGE 0.0 25,1 - 16.7 - 17.7 5 12.1 ■
..... ® :<' :: M IM ,.
- ■ 5 1.0 5 5.28 377.0 <5.0
5.8 8.6
li u ��� <24.0 25.1 ■ 9.6 ::�;:::
MINIMUM :1':- _
� ::::¢::: ° MIMI 200,100.1■ 22uGrUD

I. EFFLUENT
i,'
r
•
I
;VPDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH:June YEAR: 2014
r--11LITY NAME:Metropolitan Seweraae District CLASS 4 COUNTY:Buncombe
I
1 _RATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services,Inc.Certification No.40 (2)Meritech Certification No.ME
(List additional laboratories on the backside/page 2 of this forth)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS 1 PACE LABORATORY Iii
ATM: ENTRAMall ORIGINAL L and
ONE COPY Io. X ! ' f 22�1
DIVISION-OF WATER QUALITY (SIG FIE•F OPERAT�RESPONS CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27899.1817 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60050 00010 00400 60060 00310 80052 00610 00530 31615 00300 00095 00720
44
NFLOW Hot
0. Fee ]4F
yep = r
22
ZNc t
WS lE Q d ` o h g3 • Is
OC Qs aAn w ] p E IP . N B ° a0 .. U od t�Or OaCc
O p p
F te >- E F U
0 r
.
HRS FIRS Y5 MCO C urcrs otic. MOA. MCMI. MOA. M04. MPNfl00ML MGL -uSOCM uOrL
:::I:: ... . .: .... ... ... -.......::: ............ .......
24U8�:.... ... ''6:. .. 24.0:: :��:- .. .......... ......
::Y1i'r :::: ::�::: '�:::19:9 ':`19. •::• � :� ::•:: :•:•:•: � :•:� :•::•: :::-
2 . 2400 24 B 19.2 19.0 •7.4 :: <24.0 ::20.8 • 20.3 10.3 <1.0 : ..-7.74'- :.526.0 I
':*--ii
..ti.-:.:'�:�a106:}:-'�::z. ::..iiiii::'R6�2 `{�$':' 241::::' ::::: ::�'=:�$:0: ::'. ..::ddb::::...:..-.:**•.14:.::.:::. ..1".-'''''...:?:::f:$§': ::$$$A::::'... .
4 2400 24 Y 18.9 19.0 7.3 .<24.0. 11.0 as. 20.4 10.0 <1.0 7.23 561.0
•
:::v::::::::400::::: 'r� :4� .:r....•::.:;C•:•:':; .i=• >3;
. i:::: itii::: :.*:4:::::::�
- :: ...�
..... •r':: :::: :.2 7:::'.. .:::a:f1•:::'� ::::::::4:0:: ::::::f*::::::�... ... By;Q:':'.,.....
6 2400. 24 Y 19.2 19.8 7.3 <24.0 13.6 20.3 9.4 <1.0 7.66 581.0
.:•:-.:24:0b.:•:•: ':214'• . :•ti.: M9:8.:':0:3' 4•' ...... ... .. . .. ..•:::::::-:•::::.
8 2400 24 B 19.1 20.1 <24.0 •
.. : v::_:•:•_::::•=�db9•::•:: :e:='o:s::::=:14:::::::iz4k:::::::'�: = .. 4i::i:::=' ..:::zf:if:=::s:: :::::ii:t : : ` :t'ti::::::::...::=i:;<e' :':::6a34::::'.......
10 2400 24 Y 18.6 20.1 7.2 <24.0 17.2 21.3 11.8 <1.0 7.12 681.0
.... .:.240:::: •:=g .••:::•• >i.a::::10;t::::::1;4:::•::::d4.4:--:•::::::::::: : .:::fib:;:::•:::: ::i43::::'.. .::iliY::: : �.:::k:t►:::�,=:•:-::. .dd::::::::*2d:Q=::'..... .
..:i ........!100.......24 Y 19.6 20.1 7.3 <24.0 11.7 18.9 7.8 a 2.0 7.48 566.0
:J:
14 2400 24 B 18.9 20.1 <24.0
:4:::. :?q99':::': g4_.....4•:•::,•:1Y,l�;•:'��'Oc8':}:.:*{•::�::e2kA: , i:::::•:::: :::;:; i;i:::::::.:"::::::
li
16 2400 24 Y 18.7 21.1 7.5 <24.0 8.0 19.7 8.6 1.0 7.60 518.0
•:v::•: : •:• '
T:: :::2 ::Fit::: p::::•'•::. :::::ht.*::::,::::::: ::4ii:9:::.•.....i1'• ::::: :ii:::::::::: ::''&:•:::::::iiiii : :-:•:: ::::
Ai.:. ... alio:::�:: sx :::::::ti: �::::::id:b:::�id:'e';:. :i24. . ........... . ... �1- :::'e'.:
18 2400 24 Y 18.9 21.1 7.4 <24.0 17.9 18.2 6 12.0 e 1.0 a 7.23 638.0
:•J:::
20 2400 24 Y 19.1 21.2 7.2 <24.0. 14.0 2 19.2 9.8 >2420.0 e 7.60 502.0
•:•:•`,•:-:.:-:•:•:•:•:.
22 2400 24 B 17.6 22.0 <24.0 - - •
::79:::::::2480•:::::':'1i...... ..:19:6::::2'1:8•:::7:4::: . 24.Q::*' ... :i:::: ::: '.19:6:'r:'' •::28:1:':' 9i:::':: �:':h iCI:U: ::: :: :::q:'i•�:-• i ;q ::; •::::::::
24 2400 24 . Y 20.4 21.2 7.6 <24.0 13.7 19.0 9.8 2.0 7.06 507.0
:2 :Z1090:::::: 24•:r.•::. ••••••••••••••••••••••ti: ii :'-24(I[ :':•:•:-:-:-:-:,..:•:•::•... 'r:499: - :: j:::...:::70:4 :•:...:::28-:::: ....
26 2400 24 Y 18.6 20.9 7.5 <24.0 29.7 e 17.7 8.6 <1.0 7.22 521.0
iy:.'
....O.::, ..::i40A:: . ��4 ::::.::X:::. �
. .$:Z::R2:0::.::7�;�?:' : '�/E:�'r ..... 8
. ,i:::;:.,. B .� .. .::�:3 :::.. .::.:,. 11• .. ..
28 2400 24 B 19.1 21.3 <24.0
::� _
.ti.
30 2400 24 Y 22.6 20.8 7.4 <24.0 12.8 17.6 11.7 6.3 7.31 428.0 J
v: :•
*.• I
:•i: :is .:
•r:
:i: __
.... ..................................... ....... .........,............. -:-:-:•:•:-:•:... .......,. .. .632.5•
7.30
.••5. .•.0.0.• ••16.8.• 1 .7.:
..AVERAGE• •.19.1• ,20. :.�: •:-:•:,:-:.:-:•:•:-;-:,:77.7".-7.7. .-:-;•:-:•:
::: '
•.•,..,..,. :Mi1�c(N
: tQM ......... ::i3:ik:::;x3:d:: .;V.:0::....24,.......:..•. . ::410::::'..::; ::0.A:::'. :: 3 ,.. ,: .::i4i4:P ;�.:,::::1A::::::::1110:4::',:::::::::::::::
MINIMUM 17.8 19.0 6.9 <24.0 8.0 17.3 8.6 1.0 6.60 428.0
Monthly Limit 40 MOO 28u13& 25mg/L 30mg/L 200c/100m1 ,
ncu c.,....M13_1/Prom ' I

• EFFLUENT
I •
NPDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH: July_ YEAR: 2014
IF"^•ILITY NAME:Metropolitan'Sewerage District CLASS 4 COUNTY:Buncombe
I• .RATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No. 165
(List additional laboratories on the backside/page 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING S' u'LES: OPERATORS/PACE LABORATORY
Mal ORIGINAL and ONE COPY to:
ATTN:CENTRAL FILES X = . 7 ,
DIVISION OF WATER QUALITY (SIGNA URE OF OPERATOR IN RESPONSIBLE CHARGE) DATE
I1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27899-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
50050 00010 00400 l 60080 00310 80082 00810 00530 31815 00300 00095 _00720
Y 6 FLOW m e
U N INF FF g u F va � 0 me
«<<`Q�' y W m` m Cm
G •{� C 1Q-• e Z u a 4 N i o OI 4 N v i O C p 00 i Z
o F O K i a 5 O = E= o H a U a U
R O v O d d aZ d1. Leo C Q
O p �+ m U u.f9 V
F 1 F
HR8 HR8 Y/8 5100 C
U9118 u2L 60,1 MQIL MOA. MOA. MP41006C MGL uSICM uGA.
• ;:;�:;: :.•.•.•.•.• i:�':::823:0•:.::......
'�'<� .. ........::'18:8:�::�... :�:20,U:�::•......t6A:•:•:: i��::�:8:7:�:�:��:. .:�:i:88:�..
:.:4�:..::�:2400•:�:�::�:�27i:�:��:.�:�:Il�:�:�:�::�98:8�::�2.'1:4�::::�7:4::::.. Y40:��' �.
2 2400 24 Y 18.9 21.4 7.4 <24.0 11.6 17.1 6 8.7 6.3 6.88 618.0
':•�:•:• •:•i:•: •:r.•,::
•::3::::'.::��;di66::::::•:•:24.:•;':•..•::X::::::::::4e;ti:-.:;z4;d::::•:��d:::�:x24ir•:..•:•:•:•:•:•:,•:•:•:.::::4b;:i>::.:....•:•:Id:S.:• •.•.,:.•.:..
... . 7::::.:.iSQti ......
4 2400 24 B 17.9 21.1 <24.0 Holiday 6.14
6 2400 24 B ' t6.9 20.6 <24.0 6.86
.:;•:••'•' •:.`... .• ::•:•'• ,.,. :0':'r'•'• ':883 • 9e.a.:::•:•••••••••••••
:�:7•:�••••••2490::•••:' :�:�Y�:•:••:.•:•Y•:•::;':�g7:8_::_2:1:4:'�::7:0•.;,:.12¢:0.. ... .. ;:9;7:::;:'•... :�:td;9:�:'•e.,. .•9:Y•.,.•..• :;:�1....••¢'� .: '�•$ ,
8 2400 24 Y 17.9 21.9 7.6 <24.0 12.0 18.6 s 8.4 1.0 7.47 618.0
::i:ti : ::::: 'ib:::::: :68b,0 ::•......:
i .':'Z�BD:�:�:•'':st4•.•r.•:.•.Y•:.•.••:48;7i:��:$4c3:�':':i:8'�'�':Ai24][�::�...... ... :�:96:8:�:��:....�:�l8:8�:��:d•::•::•10:4•:•:••:....':':I:O�:�:�::�ar::•. �2. ..
1,. 2400 24 Y 23.7 21.1 7.6 <24.0 9.6 s 17.4 7.4 7.4 7.04 575.0
•
;::li ..::;Z'4011::...r8d::. ..::::tl::...:::19:ti::::2.icb::.::1:ti:: .::S24A:••.......... .. v•.:
111
12 2400 24 B 18.3 <24.0
.1 ;:::::0;7.4::::.
14 2400 24 Y 18.4 22.1 7.6 <24.0 10.9 18.1 9.0 _ <1.0 7.14 625.0
w.•:. :18 9:•....244: :a 6c 4. • :184
: :} :}18:0} ...•.•.•.ti1}:: :;a4d1}:
::•7:02 -:.:6180:::
•
18 2400 24 Y 17.8 21.2 7.4 <24.0 13.7 2 17.8 a 9.0 a <1.0 7.03 662.0
'.'SZ4.0'..: ........ ^:•:iA3::::: :�:'IieF:-::�b:::::::•8:�:�:::::.7e:•::::::;i16:::•::.:•::
:•552..Q :•:::::•:::::.*
:��T�-:�:�:3t4bb�:��::�:�2i1:: ::.�:{lr�:�:�:�::�'17:8�:�2U:8�: :�7:4�:��..
18 2400 24 Y 23.5_ 21.7 7.4 <24.0 16.8 19.4 a 10.0 1.0 6.80 692.0
I
, .......:441,....... ..
20 2400 24 B 21.0 21.2 <24.0 6.77
:•:�::
::1.1::::1.1:: ..•:Z4R$}� }$¢}. %�'r
.. ... 2Qi7;'r4:1:>f::,::M:: '1.�
... X::-.....:•r:•:•:•:.::AR:::::..'r,''r:1$•6:{':6. ...40... ....,$: :�:4
22 2400 24 Y 20.5 21.9 7.5 <24.0 12.8 17.3 a 10,6 2.0 a 6.78 529.0
I
-: ,:,:.:y-::-:: •:fJ ;:
... ;:::.:**(4: ::::� :�:820.
::::ii: ::::.6 }. :�a59:�::� :�:9:E•:�:�:i }'0:1'7::} .-•- - --
:�7�::::;:�:¢400:::}::�:�$l4:•:�::•:;Y•::•';':�'�8:a::_7.R:4{:�:�7:6•};:�:194A:::::::::::::::::::-..i::::::: = .. ., �'• .--- ---- -
24 2400 24 Y 20.2 21.9 7.3 <24.0 3.8 a 16.6 6 7.6 3.1 6.08 539.0
.:46::•.•:•zriioo:•:•:-•:•:ii4. : .::1r,•:.:•:•.:20,0:••:21:8:.•:.:;<i2:.::•:4124:6.::•...... ... :.:42;7:•:.•:....•:•aii:s.:-•:•:•::•:•:•7,9:•:•:•.:+:
I26 2400 24 B 19.0
28 2400 24 Y 24.2 21.8 7.3 <24.0 12.0 18.1 14.2 e - 7.4 7.58 411.0
; :::'•:
•:•:5494:-.......:•:•:•:•:•
'�$::;::;:2.4'7A: �:�::::24::•;:•:::•::Y:•:::•::::x8:9:��:�9:3:: ::7.:�:�:;•:-..d24.9:::,:::•:•:•:•:•:••:.:•:••:•:111.2:::: ... .5,$�:��.•.•..•.•:.$.�:�:�:��:4�::�... ...
I
30 2400 24 Y 18.6 20.6 7.6 <24.0 17.8 17.8 5 10.8 2.0 a 6.80 580.0
•.�•. :•i:•:::.
::04:::*.,:::2;188 : :E4:•::•:::::jr, :::::::49c0::::21:2:: :Q:Ii::::::0240::::...... ... ::i'..j::.::;... lB:Y::: ,..,•,•YFJG :::4••••::.::.:I:6::: _ :7:Oi:7:.::.:a.a.•..'.......
_ :v:
- ................... ......... ...... ....................... .......... ............ ........ .. ..........''•629.3•:•.......
AVERAGE ;1
95 21.4. .0.0
••.12.8.•• _17.6.•.•
••882•••
.....
:•:
$$
I
..........�:b1i4KkatUM'r.......... ::'�7:s::::ii;2:� ..5:: .p4,, ,,..... ... .:1$:p7; '.....�� , ::f
MINIMUM 16.9 20.8 7.0 <24.0 0.0 14.6 7.4 1.0 6.80 411.0
I
:Y ,
Monthly Limit 40 40 MOD•: •.•28uGIL, .•2&898.•• :•..30ngIL.•: ..200d100r0i
•
I
OEM Form MR-1(8/93)

• EFFLUENT I
I
NPDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH:August YEAR: 2014
FACILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
( 'RATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
I
(.aRTIFIED LABORATORIES(1)Pace Analytical Services,Inc.Certification No.40 (2)Meritech Certification No.165
(Ust additional laboratories on the backside/page 2 of this farm)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY'
Mail ORIGINAL and ONE COPY to: c _ / 2� ,
M O CENTRAL FILES 7( ]
%/
DIVISION OF WATER QUALITY (SIGNATURE 0 OPERATOR IN SPON E CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE •
50050 00010 00400 50080 00910 80082 00810 00530 91815 00300 00096 00720
.Y FLOW Yr
/al I , 4' FFFW O N c t1 11 E II k
2 6 N INF an o N 1 N ;E c Y .4 O , t g s t 2 Y
q oat n4 a z
a F O < 3 a. a o�Op m E g ^ tg V
o gE a ce m O ce a <_ a It a SE a ig
F O E g LLro
19 8
HR8 HRS We MOO C UNRS wit. MOA. NOR. MOA. MOA. MpNhI00ML NOR. us/CM um1.
:::4+ :2400-:-:-::-:-s4:-:":::::::::i.:::::::::-!19:6•::-21:4-::-::7:4.:- <24.o:-
.. :-:0:3:�::: :::'lOc1:�: :-:tOr7•:�:-: :-:2:d:-: �:- :-:8:74:-:�::�:-661:Q-::::......
2 2400 24 B 18.8 <24.0
4 2400 24 Y 18.4 21.5 7.6 <24.0 6.3 19.0 9.4 <1.0 7.33 552.0
:-:.S': :g4:::. • ;: •;
... ., ,a.:::- A, ..•:-7:$: •::: kdA:- ..... -:-iRk' :-:2$:f:•: ::::1Q:d:;::: :::3.4U :-:x:il:-:-:.;;dxd;Q•::•:....�.
6 2400 24 Y 18.2 21.3 7.6 <24.0 6.8 19.4 10.9 <1.0 7.70 576.0
4:-:::-:2400-:-:-::-:-2 :::::::::ii::::::-: :
: :48:0• :-2
: :2-::-:-7:8-:-- :<Y4.o:-•:..
�': 1 :0:7:-:-: :-:t8:8:.: .::*9:2-:- : :-:2q.:�:- :-:8:93:-:-: -:-t;44:b.:--:......
8 2400 24 Y 22.3 21.0 7.3 <24.0 11.0 19.9 11.3 <1.0 7.31 686.0
• .-:-tido:-:.: ::::24. .:4 • • ...•..•.
(' 2400 24 B 20.4 <24.0
:.i.i::..
... ..•::7:ti::: :::524.8:: :..... ::$;$:�:?: :-:4A:2:-: :•:i1:.Z :-: :-:6.3:::::: :-:5;$8:-:-: -:..1i39:k-:-:::::::•:::•.:.:.:::.:::
12 2400 24 Y 19.4 22.3 7.5 <24.0 12.0 18.9 12.0 1.0 7.12 670.0
::::::2400::::::::::t4.::
:.:-:-Y:-:-:-:-:14:0: ::"4.11:: ::-.7.:5:::...z4,.. .: z:0:::� .:.se;a.:. .•:�sv$•:•:. :::Ri:0::::: .:::x;2a-:•:: :::4gA:a:••:....... '
14 2400 24 Y 18.3 20.8 7.6 <24.0 16.9 10.3 19.3 11.8 <1.0 7.64 671.0 <6.0
•:1I5-::-:::2400:::::-::-:24•:: ::::::::•4:::::::.i4i.i.:::::ii-..a.: ::7:8:::.::<e2;a:: '..,. :::8''' :;:i '
16 2400 24 B 18.1 <24.0
:

I
!'"F' EFFLUENT ,
1
NPDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH:_September YEAR: 2014.
I ` '•ILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
... *RATOR IN RESPONSIBLE CHARGE(CRC):Peter Weed GRADE 4 Certification No. 10773
CERTIFIED LABORATORIES(1)Pace Analytical Services,Inc.Certification No.40 (2)Meritech Certification No. 165
(Het.additional Laboratories on the backside/page 2 dells form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY
Mall ORIGINAL and ONE COPY to: /0"/�j-I/ '
ATTN:CENTRAL FILES XI ,,
DIVISION OF WATER QUALITY (SIG R OPERATOR RESPO RAROE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27698.1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE •
I 50060 00010 00400 60080 00310 00082 00810 00530 _ 31816 00300 00095 00720
1,1
FLOW a
EFF❑ C O o ,�.
MINF ❑ 8 o n . o . A c c m M ' c
N L N m n m O ED m II'
S m G t1 > m Z
p awa e a w a a ,& i y V 1 es C v' v
D O m C et
v m O m 0'1 2 a 3 K O g 2 d p 0
O I2 IL ipF-
reta HRI1 Yla MOD C UNITS eelL MCA MGA- M05. •MOO. MPW100M1. MOA. uwCM • eGO.
'• '•'•'• •'' >• ::•:-......:•:•:•:••:•:.:•:•:•:•:.
:%1::::.:�:24pG�:�:�::�:�Y11:�:��:.:�'9�:�:�:�::�'17:8�::�.....:.:•:•:•:•:•.:.:a4:6:•••:•:•:•:.:•:•::•:•:•:
24 Y 17.9 22.7 7.6 <24.0 18.1 22.9 6 17.7 2.0 a 7.41. 652.0
2 2400 :r...•:. ..
:::4::::•.:::tirid '::�:�:�':�:84�:�:'. *::::::::49;2::•'..22 :.::::t;G:::,:::4243$•..•...... .., :::9$;8::::::::::::::::11:4:::::k:: •:.
••6$,U'•::......:
4 2400 24 Y 20.7 22.3 7.2 <24.0 • 12.6 19.9 8.8 1.0 e 7.51 479.0
:: 3t(:::4.
I
8 2400 24 B 18.8 <24.0
• ::::::::::• :...
:�:7•:•':•:�400•:;:•:::•21F:':;�:•:_:Q•:�:•:•':;22:1•::.. - ..... :�:< :•'::::
•• •: •'::•: ••:•.;
2400 24 ' 37.4 21.7 7.2 <24.0 22.4 16.4 12.6 88.3 a 7.63 303.0
:::::i:ii' :•;7:44::•::,::448:0::: ,.,..,
� .:.::�zi56:�:�:�� :;:3�:�::�..�:r�:�:�:��:Q��s:��:a4;�:��:�:i::ri.•.:.•n26��::'...... ...
:�:42;t1:�:�•:�3:�:�:�'10:8�:��:d�::�.>r4'17�:•:��:...�:<%1;0:�:�::'.....
10 2400 24 Y 19.7 22.3 7.4 <24.0 11.9 15.4 7.2 4.1 e 7.38 495.0
;••.:. :: ::::......
12 2400 24 B 21.9 22.7 7.8 <24.0 12.4 17.8 6 7.4 178.0 6.60 471.0
-,.....?1,0..:;•:•:•:•:•:•:- ..... ........ ; ,....., a :•:•:•:•:•:•:•:•:••:.:.:•:•:•:•:•::•:•:•:•:•:•:.
14 2400 24 B 20.1 <24.0
,':0.:•::::•.. .......................................
:.7:68.:•:.::4870:•::'
��:22:'I:��:�:7: : �:�i20]a�:'' ::�7;3�:�:��:3,s•::�:�'16:9 ��'� i:...................................
:�:_'YF:2::::;;:a:;�::;:+�
I
;:16:'r:}7AQQ:'�',•:•:g4�:�:'' �:_Y:�'�'� •:.9.1;i::. ..4'•r ...
16 2400 24 Y 25.6 21.8 7.2 <24.0 15.3 2,e 16.1 11.0 816.0 7.17 398.0
.•:•:43:7:•:: •• :•i,•:•:•7:•:•:•: :.;•469:t1-:
:•:19:••:•:•:2400•:•:-::•:-24:•:.•:.:•:�.:•:•:•::.2U:8.::•,'e.`I:6.::•:•7:4:••:•:<24.0:.•:...........•:•:IS:4:•::.:Q•:• :.. ..•:•77•:•:•::•.. ..•:83:•:•:••:. •:•:•:7152:•:•:
18 2400 24 Y 19.6 21:8 ;4 <24.0 5.8 17.0 7.8 2,6 3.8 a 7.02 492.0
I
4:..::2,44d::.. :::it4::....::9::.., ::4i>id::::62;0: : ;d::... 24a......... ..
1' ,,
20 2400 24 B 18.7 <24.0 •
:;�1:;::'•'•'•'-'-'•'•'-'•:::44tNl�::;: :;:;Z.4::::•..:{�::'r:•:,•.$;x;::'r 'r:•:•a•:r:•'r:'.
22 2400 24 Y 18.3 22.0 7.4 <24.0 9.8 2 19.2 5 7.2 <1.0 8.02 497.0
I
:: :: ' ?:1:0::;:;,r.\,•.:::4;63::•::•:•628:a•:
:.:ii.:•:}: 400}::}}24:'`::::::*ii::.:::::::.:;l8:0:}70:2:>:7:ii.•. . 240: ;\':::}ti: :::::iii:: i:�: :¢8 :}:e:; ' :::6 g:: _:
24 2409 24 Y 17.2 21.4 7.4 <24.0 10.3 18.1 6 6.3 <1.0 7.28 520.0
:�:••.•,••.::.;: •:i:. :::>:::::;•'' :::7:8i:::::•:::6484:•::......:
�:4&::�.� 2it0U:�:�:�� :Q4:;:;•;:;{:;:�;:;:;:;:::48c#:� 'i29;9:��:�:i:6':,•:•1�24:�t•.\•::�:�:�:•:\•:•:�:��:�:�9:4�:•:��'d,e•::�:�i7:6�:��:•:r.•.•..6A•:�:�:��:...::i4;D:�:�::�.....
28 2400 24 Y 18.2 21.5 7.6 <24.0 16.6 2 19.8 7.5 <1.0 7.29 623.0
28 2400 24 B 17.6 <24.0
I30 2400 24 B 17.6 22.1 7.4 <24.0 12.7 2 21.6 7.8 2.0 7.21 653.0
I 9
AVERAGE 20.4 22.0 r 1 0.0 12.4 17.9 8.2 ^ 3.3 7.33 4 1.1
MINIMUM 17.2 20.7 7.2 <24.0 5.8 10.8 6.9 1.0 6.28 _ 303.0
Monthly Limit I 40 MGD 28uG/1_ 25mg8. _ 30mg/L 200d100ml
InCH Cnrn.UR.1/6/611 •

" ' f EFFLUENT I
•
I
NPDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH:_October YEAR: 2014
FACILITY NAME:Metropolitan Sewerage District CLASS 4 COUNTY:Buncombe
i iRATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
I
CERTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No. 165
(List additional laboratories on the backside/pege 2 of this form) •
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY
Mall ORIGINAL and ONE COPY to: //..-- I��/
ATTN:CENTRAL FILES X
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN RE BLE CHARGE) DATE
1817 MAIL SERVICE CENTER BY THIS SIGNATURE,!CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699-1817 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
60050 00010 00400 60080 00310 80082 00810 00530 31815 00300 00095 00720
a ROW § p
,FFF C • Cal
V c INF '= C 0 a
I
u1 30 0 o '�} E = V aIInnIHIPD
m v oUK
H28 1428 YA2 MOP C UNITS mgl MGL MO& MOA. MOA. APNI100ML MO& U&CM MOL.
:::%I::::::::R40U:} :::::2i{:.;.:::.:::V i:::•:::'17:11:'::2.'1:4::?.:..7:6:::::::<Z4.1j::.:............::9c8::::::'... :::28:i1::::�e.....8r'•:•::"•;'••::::iCI:U:;:;:
2 2400 24 Y 17.3 21.6 7.4 <24.0 15.0 •2• 21.7 6 7.0 <1.0 7.13 579.0
...4........2400... 24 B 17.2 <24.0
. - - 689.0
8 2400 24 B 17.7 20.1 7.4, <24.0 11.7 . ••2 22.5 5 8.1 . ... '.. •
a 3.0 2 7,42
0
:�:9C:.':::.400:_:;::.:'.:*.ii.::::::.:'.:*.ii.::::: >:�:8
� :}
. ?::��t13� : 71):9�:
:� :;:�7:9.{:::::.4a.:�: }
....�:�� :�}:}:_'j0:8;: :}��::; . f:' �'�
A•' ; :�:;:'. . . :::52.lY:;'i::::'::::::::'
8 2400 24 B 18.3 21.1 7.4 <24.0 13.5 19.7 s 7.4 <1.9 _ 7.33 626.0
2400 24 8 17.9 21.0 7.3 <24.0 14.3 2 22.0 6.e 8.8 1.0 7.26 662.0
:•:J•:
12 2400 24 B 18.5 <24.0
14 2400 24 Y 29.6 21.4 7.6 <24.0 18.4 22.9 5 8.8 <1.0 7.37 634.0
::46::;.. „66:::*:r:P4'::::'.r:Y: :;:::{if1fU:.::1fr3••:.:8:9:::'::�Y4JI►:::...... ... :::2i: ::::x:.::::.9.':1':::' ::.:::.:4%.::::: :;:;i•rti:;:;:
.. :::8''d:•::::..:. ..
18 2400 24 Y 24.8 20.1 7.2 <24.0 12.8 a 9.9 6 6.6 3.1 7.34 437.0
'� :'
:�:I7:::.:-:,24GU ":?::::::4.
�:�:�::�:�2i1:�:� ::�::�:
� :�2i:8'::19:87:2� :�
�::�:� •::: P40:�. :...........�:::I'1:4::�::'... :�:48:4♦;^:. :3i:�:::;�
' :: :::: ::::.. '(.:::::::d::}:'dry ...
18 2400 24 B 19.8 <24.0
:•:C ................. :::•:•:•:•:•:-::•:•:•:•:•:•:::
20 2400 24 Y 19.1 20.0 7.3 <24.0 11.0 2 20.2 7.4 2.0 a 7.15 608.0 I
;21:::.:::4400::::{•:::R4:::::::::::Y::::::::::.:1k9:: 40;4::G:::7;2?: ...24:4:: •:•:•:•:•:•,:•....:::10;$:::::::a:::=:::411:4::-,:::::.:::::1........ .....0•::::::. ....1... •:$ ::::•:•:•:•:•:.
22 2400 24 Y 18.9 19.8 7.2 <24.0 18.4 20.9 5 8.6 4.1 6 7.42 639.0
'•'J•'•'•' ..
_ ... ... :�:1Y4.0:�..'.::::::::::.:::.:_i ... �::'13:4�::::::��::•:::FY�'' ..1 U:•:�"�:� �' :¢c0:�:::*::d::':::p,3 _
}�;:�':_:�2�4N00;:.}:'� 28.•. •..�:�:Y'�:�?::-98:8::::'19:0:::�:7:4�`- .... :: �:�• ..... .. �/4•'��: .. �-... .. I
24 2400 24 Y 18.3 18.7 7.4 <24.0 18.8 13.6 10.6 1.0 6 7.25 683.0
•:48::.: G:::"::::14::•:,:•:•:•::6,•:•:::.':4t:7: :fsP49:....... •... ....... .... ...•.
26 2400 24 B 17.4 <24.0
28 2400 24 Y 18.0 19.3 7.1 <24.0 19.7 6 22.7 9.5 <1.0 7.39 802.0
:*21):*':":*:2400*:':*::}:14:::'.".":':Y::;:':*:::'t$:4::::4114)::•:•:7:1}:...x0:: ::•:•:.:•:•:••:•:•:.::::*14:4:::.•:•:11:::_:::21;0.::: ......0::_:`P.,::::•...:4.5:.::...::::::1;24•:•::
30 2400 24 Y 17.7 18.2 7.6 <24.0 9.9 sa 22,8 6 8.0 <1.0 7.86 662.0
,::.•
.�:�22:8�:��:d. ..•u3�•:•:••:...r:�2:0�:�:�::�.... �7:>t8�:•:•:•:682A:•::.......
::Si1:::•.�::Yi{Gll::::::::�:Q4:::'_''..�Y:: :::::'I�iT:6::::996::::�:icA::: :::#YkXlf:•::::::::�:::�::.. .� 8:8:�::::s�i::' ,
....• :•:•:•:•:•:•:•:•:•:•:•:•:•:•;•:•:•:.:.:•:•:•:•:•:•::•:•:•:•:•::•:•:•; ••. .• •' .-
• ,•. ..•
•:•:•:•:•:•:.:.:-:
:•:•:•:•:•:•:-:.
•. •.
I
AVERAGE 19.620.2 p 00 13.8 20.8 7. 7.37 634.0
::i
AI :�:� :Z;5::::..x40:: : .... ... .
6 . �:;;a:9:: ... :��... :J:..•fd,.. ...:::,fi. ,
MINIMUM 18.6 18.2 8.9 <24.0 8.3 9.9 0.0 1.0 6.94 338.0
Monthly Limit I 40 MGD 28u0A. 25mg7L 3Omg/L 200e/100mi
DEM Form MR-1(8/93) 1

EFFLUENT
1
NPDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH:_November YEAR: 2014
FACILITY NAME:Metropolitan Seweracie District CLASS 4 COUNTY:Buncombe
I
, :RATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
Ln.:.RTIFIED LABORATORIES(1)Pace Analytical Services.Inc.Certification No.40 (2)Meritech Certification No. 165
(List additional laboratories on the backsIde/page 2 of this rcnn)
CHECK BOX IF ORC HAS CHANGED _ PERSON(S)COLLECTING SADA'LES: OPERATORS/PACE LABORATORY
Mai ORIGINAL and ONE COPY b:
ATTN:CENTRAL FILES X 4.--.;) '7/ /2-/J
DIVISION OF WATER QUALITY (SIGNATORE OF OPERATO RESPONSIBLE CHARGE) DATE
I1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699.1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE
50050 00010 00400 50080 00310 80082 00010 00530 31815 00300 00095 00720
FLOW g
2 e C
I 4° 8 ri IFFo V c c N � . g '
' " ' j' '
ffi a s$Q °' .9� 9 d n ccc V
FRS is s Y/8 MCO C UMTS ue1L MC& WA- MOIL MQ,L MPW100AM. MAIL ualCM unit
:::4::::::::2400:::::::•::YB:::: ::::H::::::::::'18:8;::::::::::::: :::<2j.0:::.....: ...........::::: ......:::: ...... :: ........ .. i.:::::......:::.:.::•:::::::::::::::]::.:
2 2400 24 B 18.6 <24.0
:4::::.::44dd::::::::::it4•.•J.•.•.•.•Y::::::::::ai;s:: a7;i::::::'z;i:::' 2dii:::...... ... :::;iaiii::::::..... .s•:: ..::::94:::::::: :::'.:::i ....•1;:::..
4 2400 24 Y 17.6 18.4 7.4 <24.0 14.5 4.6 6 7.8 <1.0 8.17 669.0
1••
:::�:::::::�4Dh:::�;:::i... ..:•:Y::::: :..7,@:•..6.6::::::i:i:::::::Si4�o ;� ............1Q�x:::::::::: :::zi:e;::;;:;:; •,•:::y:�:;::::;:;:;::: 4 ,Q;::'
1 6 2400 24 Y 17.5 18.9 7.4 <24.0 16.4 22.8 8.2 <1.0 8.21 618.0
:•:7:;....:•:2400:::::. :::x•:::::::::17:8•':::16:0•:.......7:8•::•...424:0:.: :' ::-21:8.; :S:;:.:::251)::::: 6Q'•'•'' 1.0•:::::' ':'8:00'•'•:-
8 2400 24 B 17.6 <24.0
'•.i::^:'.... ......:::1249:::•.....: ... ....... ...:::::::: .. ::::::::: ..::::::...:::::: ....... ..............
2400 24 B 17.6 17.7 7.5 <24.0 12.4 , :;:e.•. 23.6....x. .7.3 1.0 • 8.14 638.0
1
12 2400 24 B 17.8 18.2 7.4 <24.0 24.2 s 23.0 s 12.6 1.0 7.76 642.0
::14:::,:::::2400:::::: . ::1$.. .. .. .;`4.. :::26;0:::::::i::::::4.,@•::...k.':•::::14*.:::::::::::::::::5:14:: ....:::1;44::::::: 842:0:: .....
14 2400 24 Y 17.4 15.6 7.4 <24.0 22.6 24.3 12.4 <1.0 8.09 580.3
111 16 2400 24 B 17.6 <24.0
•: ::::,.•.
::`i7::.:::2400::::::::::28:::::..::::8::::::::::23:8:::::i8:4::�::7:?::: :::<l4.0:: '..........r::'18:I::::::::te::-.. ):
.. ..:11.0:•:•:-Si. ....:13.A.:.:••:0:- .::'8
18 2400 24 Y 18.6 18.7 7.1 <24.0 29.0 ae 21.9 6 11.8 6.2 e 8.61 507.0
:;:i:::: '::::::•::•
I ::%ia: .'::TWO::: ::�:;2a•.•..•.::•Y.•.•,•:••:4b,d::::%i$d. ...d.:: ..u.4: :::::::•:. .. :::244:::: 4::::J ..:•::::1%;0:::::::-:::::::::1:11.:::::.: . :::8 8 :•:•:•:•:•:•:•:
20 2400 24 Y 16.9 17.1 7.0 <24.0 26.1 23.6 23.6 9.8 • <1.0 8.42 572.0 <6.0
::i1::::::::4400:::::::::.:24::::::::::::t:::::::;::0;7:;:::16:0::::::7 4::: ::A4:G:: :: :: ::::::•:•:•::•:s3$;6:::;:;.:.:..;.-144:::':: :::•:•:•a�.:•:::,: :::::;:<1;Q':::..:.:..:.:::r•64:•:•::•:6x8;4::::.:.;::::.:.
22 2400 24 B 17.1 <24.0
.:.29:7.::•:•:•:•:.: • ..•.•.•.•.•.•..•.•.•..•.•.•.•.•.•. ::
;•7 : 400•::::::•:•24:•:••' ::6•:•'•:'
.. :•:<Y4.0;:
24 2400 24 Y 29.7 16A 7.2 <24.0 19.3 . ::•x.. 17.6 16.0 • 6.2 . ..6.08 348.0
>::::•:••.
'•0:•' �.6::::::Z:2::: ::asY4H:' •. ':'40:3:::^::x::::::771:2:::•:•:•::•:•:•:e4:•::::::::::::.:::3:4:'::::::ii::::::7:y6:::::::::4$4A::::......•.
:X26::�.�:�2i188::::::::::Q4�.•..•..•.•Y:::::::::.Y .8r::48• ..... ... ..
..26.:.....2400..........24...., Y..........23..9....16:9......7..2........<24.0.. 19.0 s 19.2 6 6.7 1:0 8.00 618.0 '
I ::7
28 2400 24 B 17.9 <24.0 Holiday
d0 •:J:•:•:.• :
30 2400 24 0 17.9 <24.0
.... .....''•AVERAGE::. ..... .. •19.0•::•17.3•. •'•0.0.• •.•28.1::......''•19.6:..... :':20.8 .... . ''•9.8• ..... . '1.7. •8.08 :..'•636.8• '•0.0 .
I f '
.,....:::IMAXre1i4M:::::::::::::::::::::::i9iX::::18�9: . .s.:..44....•::9d:i:::'... :::36:ii:::: Wi:•:;::•.•..•.•.•f5.... ....:::iii;d:::::::....:::8;iii:::::::::RiRA ;ii::kii0::::
MINIMUM 16.9 16.1 7.0 <24.0 26.1 0.0 4.6 0.0 1.0 7.60 348.0 <6.0
.iiii ;'d'y•' :::Lx.:::::•:::i:::::: ..
Monthly Limit 40 MOD .2800IL .••••2bmg/L 3Omg& 200c1100n4 22uGIIJD
1 DEM Form MR-1(8/93)

1
EFFLUENT
I
NPDES PERMIT NO.NC0024911 DISCHARGE NO.001 MONTH:_December YEAR: 2014
I• 71LITY NAME:Metroaolitan Sewerage District CLASS 4 COUNTY:Buncombe
zRATOR IN RESPONSIBLE CHARGE(ORC):Peter Weed GRADE 4 Certification No. 10773
111
CERTIFIED LABORATORIES(1)Pace Analytical Services,Inc.Certification No.40 (2)Meritech Certification No. 165
(List additional laboratories on the badtside/page 2 of this form)
CHECK BOX IF ORC HAS CHANGED PERSON(S)COLLECTING SAMPLES: OPERATORS/PACE LABORATORY
Mall ORIGINAL and ONE COPY to: / J ^/�
ATTN:CENTRAL FILES X %G
DIVISION OF WATER QUALITY (SIGNATURE OF OPERATOR IN R ISLE CHARGE) DATE
1617 MAIL SERVICE CENTER BY THIS SIGNATURE,I CERTIFY THIS REPORT IS ACCURATE
RALEIGH,NC 27699.1617 AND COMPLETE TO THE BEST OF MY KNOWLEDGE -
60060 00010 00400 50060 00310 80082 00810 00530 31815 00300 00095 00720
o A
O O FLOW
fe
_a ■
C a
e
.. C ks • O m N 1 C d � m OV p rniF EPe EZ V
co
m a ro o yp
1OE3 3p�.
ZU
X b so
a� 7 � Ov O fJ & �+ pV
3 co
HRe HRS Ws MGD C UNITS ,�,,L MWLMGA. MOA. MPN/1001 •Ma81oM urLl
:.:1::.::::2400..•.::::Zi{::::•.::: V: -:-::-98:8-::-16:6-::':..7:1-:- <24.o: -:-'17:8:•' :•:lti.a:-: :-:tto:-:-:III :::4c0:::: :•:8:27:•:•: :::166:6:: ......
2 2400 24 Y 18.9 16.7 7.2 <24.0 21.7 22.6 9.8 1.0 8.18 622.0-MCAi�
:::3:::•::::i46O::::: ::::24::: ..:*::::::::48:d ::48:.7::::::i;?1::: : 2+4b.::-:.: :: ::.:::i4:::.::: ::c21:8::: ::::114::::: :::'L:b:: ::::i:9t..::::::::8fi8,0::::•.... ..
4 2400 24 ' Y 18.7 16.1 7.0 <24.0 16.2 22.5 8.4 3.1 8.16 679.0
:fig:'•:
....:.i.:.::::::44b4: :: �:�...• ..:::Y:::�:::..It;i:: . ,$•:::::x:i::: .,Y,. i4:Z:..... :::RAi': :::aY::' :::::6l:::::; :::i0:::::: :::$;4i:::::.:::d¢7',.. ::::::::::::::::::::i
I
6 2400 24 B 18.6 <24.0
:::?::::::::2400::::: ' :::73:::::::'::97:4: :........ 24O-:-:- . :- -: :. .:- :::::::..........i:i:::
0 2400 -24 ' Y 17.6 15.5 7.3 <24.0 14.7 23.9 12.7 <1.0 8.76 548.0
( 4 bo:::::: i.i.• :::i•.. :sii::i::: ::sdroi::.* ::tiib:::::: :::e:ia::.::':::sat:6:::'...:..:
:::fit ... ::24::: :..:: : :: ::48:9:::.4 . .• .. ,ai::.::x24 :: :... . :>35 4:: I
10 2400 24 Y 18.4 16.7 7.3 <24.0 34.6 22.3 12.2 1.0 8.14 638.0
:::11:::.:::24bb:::::::::24::: :..:::'.:::::::::11;3:.:::14; ::: :1;k::: ::Sd4A:: :..:.. ::::.3.2:4:::. : a;2.:: :tR.o.: ::%i:6:::::: :i;716... .dd3:Q::: .......
12 2400 24 Y 17.3 14.4 7.3 <24.0 24.7 21.9 8.8 2.0 8.60 681.0II
14 2400 24 B 16.8 <24.0
•;::' �i •..... ....
::46::::.:::7•.it00�::::::::24::: ...:::Y:•::: : 4i!'7::::46:0::::.�:2::::::x24. :::44:9:::: :::26:3::� .:::4'F� . :::14:0::::' :::7:8�i7.:::': :::82 0':":
16 2400 24 Y 17.4 18.2 7.6 <24.0 34.0 31.6 15.0 <1.0 7.94 616.0 '
: t:::.:::2400::::. :::211::: ::::::::it::::::::::17:P:::::16:0:::::7:4:: ::<24.0:: :::Y6 : ::28:5::: :::3:0:::::: :::.:: i..6*::::: :::163::::: :ti79:f2::•::......
18 2400 24 Y 17.5 14.9 7.3 <24.0 15.6 24.0 8.3 2.0 8.86 682.0
.::- z
::4i}:::•:::�.di)if::•'••'•:•;:'::•.:•••:•:44:•••:•:••:1164:••:110:.®®• .t 3.. 24�i.: :::4b... .:-.'14A::: ::::::14:::::: ..b::::- :cif:#i:::::•::$
:':•:•?488:::.:' ':18'9:'1111 ::x24.0.•
17.4146 7.4 <24.0 16 0 l::24.2 1 0 8.69 630.0 gill
p240024
::::::2400::::: ::2A::: :'88: :..1ti'.z::::::7:8:::•::<Y40:: N:::1i44 : •:::23'': I:::4.0::.1:;:8:78:: •::667:8::: 1
24 2400 24 B 31.2 • <24.0 Holiday
:'2&"•.:::2A66::::'::':'24': :-:-:-: •:-:-:-::49:8::::•:•:.:--• ...... •..24 U::'F]OIIf19
26 2400 24 B 18.0 <24.0 Holiday
28 2400 24 B 18.4 <24.0
' •:::::%1::::• ::: :.•.
:::40::'::::k9Aa::::::'::::24::: :.::�'Y::::::::::Z1:l3:�::19:�::::::y:;e::: .x.ego:: ..... �'x�:�:::� ....•;'R9,. ....� �' ...e,44:::::•:::464:0::.:::•:•:•:•:•:••
30 2400 24 Y 19.8 14.9 7.4 <24.0 33.3 a 18.4 7.5 1.0 s 8.80 432.0 I
. ::8:6 5:::::::480:8::::•......:
::34::':.::21400::::: :::2a:::.::.. :Y:::::{: 49:0::::4Cr.2::::::8a9::::::x28J0f::::..... :::43:8::::::... :::711:8::: .:::7la'F::::: .:::7:0::::::'.. .6
.. ................................... .. ..... ..... . ..... :'•8.30.:..'-.642.1: .......
... .. •••23.3•,• •..11.2•: 1.3•
AVERAGE 18.5 16.60.0 21.8
1
:•:C
.........:::�1A1((MtI(yl::;:::::;:::::;:::::::::b1:�::::18:$:: ..$.::.:::40.::X4.4.:: '..... .,. ::.`atl... ....•::.:3 ;(1::::::. ::::::$0;4::::: .....::0:1:::::':'....:::i#:$$:;::'..
MINIMUM 16.8 14.4 6.9 <24.0 11.3 18.4 6.11.0 7.78 432.0
:fi::: .:.0:::::::': :::::::.0::::•:.:: .. III
Monthly Limit I 40 MG• 28uG/L 25mg/L 30mgA. 200d100m1
DEM Form MR-1(8/931 I

I MI MI 111111 UM MN En NM 11111 11111 NM N 1111111 111111 NM M i 111111 N
Plant Effluent Metals
Date Arsenic Beryllium Cadmium Chromium Copper Cyanide Lead Mercury Nickel Silver Zinc
2/9/2012 0.0005 0.0005 0.0005 0.0025 0.0170 0.0025 0.0025 20.20 0.0025 0.0025 0.0800
5/24/2012 0.0005 0.0005 0.0005 0.0025 0.0160 0.0025 0.0025 24.70 0.0025 0.0025 0.0760
8/9/2012 0.0005 0.0005 0.0005 0.0025 0.0140 0.0025 0.0025 19.40 0.0025 0.0025 0.0670
11/15/2012 0.0005 0.0005 0.0005 0.0025 0.0110 0.0025 0.0025 18.20 0.0025 0.0025 0.0620
11/29/2012 0.0005 0.0005 0.0005 0.0025 0.0149 0.0025 0.0025 12.90 0.0063 0.0025 0.0743
2/7/2013 0.0005 0.0005 0.0005 0.0025 0.0140 0.0025 0.0025 19.00 0.0025 0.0025 0.0640
2/8/2013 12.70
5/16/2013 0.0005 0.0005 0.0005 0.0025 0.0110 0.0025 0.0025 9.08 0.0025 0.0025 0.0570
8/8/2013 0.0005 0.0005 0.0005 0.0025 0.0099 0.0025 0.0025 14.70 0.0025 0.0025 0.0500
11/7/2013 0.0005 0.0005 0.0005 0.0025 0.0130 0.0025 0.0025 17.70 0.0025 0.0025 0.0660
2/20/2014 0.0005 0.0005 0.0005 0.0025 0.0065 0.0025 0.0025 6.11 0.0025 0.0025 0.0510
5/19/2014 0.0005 0.0005 0.0005 0.0025 0.0089 0.0025 0.0025 7.91 0.0025 0.0025 0.0484
5/30/2014 0.0005 0.0005 0.0005 0.0025 0.0160 0.0025 0.0025 18.20 0.0052 0.0025 0.0770
8/14/2014 0.0005 0.0005 0.0005 0.0025 0.0160 0.0025 0.0025 0.0025 0.0025 0.0600
11/20/2014 0.0005 0.0005 0.0005 0.0025 0.0140 0.0025 0.0025 18.70 0.0025 0.0025 0.0660
Average 0.0005 0.0005 0.0005 0.0025 0.013014 0.0025 0.0025 15.68 0.002964 0.0025 0.064193
Max 0.0005 0.0005 0.0005 0.0025 0.017 0.0025 0.0025 24.70 0.0063 0.0025 0.08
Analysis
(Minimum)
Report 0.01 0.001 0.001 0.005 0.001 0.005 0.005 2.00 0.005 0.005 0.001
Limit
Results are in mg/I except Hg ug/I

al
1
n ® Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Mc.
• aCEAnalyfiCa� 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
www.pacelabscnm Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
[phone] [phone] [phone]
ANALYTICAL RESULTS
Project: EFF PPA 11/29 ,
Pace Project No.: 92140209 'j
Sample: PE Lab ID: 92140209001 Collected: 11/29/12 16:00 Received: 11/29/12 16:25 Matrix:Water
r
Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
0 2225 Riverside Dr. 9800 Kinsey Ave. Suite 100
aCU/I/��It 7};/��r 205 East Meadow Road-Suite A Huntersvllle,NC 28078 I•
UI'Ur I,j'�l� I Eden,NC 27288 Asheville,NC 28804
i4ww.pacelabs.com 828 254-7178 [phone]
[phone] ( ) -
I
QUALITY CONTROL DATA
Project: EFF PPA 11/29
Pace Project No.: 92140209
QC Batch: GCSV/13505 Analysis Method: EPA 1664A
y
QC Batch Method: EPA 1664A
Analysis Description: 1664 HEM,Oil and Grease
Associated Lab Samples: 92140209001
METHOD BLANK: 887609 Matrix: Water
Associated Lab Samples: 92140209001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 12/12/12 09:17 um
LABORATORY CONTROL SAMPLE: 887610
Spike LCS LCS %Rec
• Parameter Units Conc. Result %Rec Limits Qualifiers I_ ,
Oil and Grease mg/L 40 33.5 84 78-114
MI
MATRIX SPIKE SAMPLE: 887611
92140941001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Oil and Grease
mg/L ND 41.7 36.2 87 78-114 Its
a
a
a
r
Ilr
• I
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS
Page 10 of 31 ( I
This report shall not be reproduced,except In full,
I
without the written consent of Pace Analytical Services,Inc..

lo
I 0
lel

1
1
A
I

n/�.�e �j,(• 0 Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
I aceAnalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Klncey Ave. Suite 100
xnnvpacrlobxcom Eden,NC 27288 Asheville,NC 28804 HunterevlMe,NC 28078
[phone] [phone] [phone]
December 17, 2012
IMr.Wayne Tipton
Metropolitan Sewerage District
I 2028 Riverside Drive
Asheville, NC 28804
I
RE: Project: EFF PPA 11/29
I
Pace Project No.: 92140209
Dear Mr.Tipton:
I Enclosed are the analytical results for sample(s)received by the laboratory on November 29,2012.
The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual,where applicable, unless
otherwise noted in the body of the report.
1 .
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
IIIpage for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
I
Sincerely,
Y
ILorri Patton
[e-mail]
Project Manager
IEnclosures
I
f L REPORT OF LABORATORY ANALYSIS Page 1 of 31
!i _; lt
This report shall not be reproduced,except In full,
I 1 without the written consent of Pace Analytical Services,Inc..
J,

1
Q/{y, .y Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
aceAnallytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
wwiYprtnhb:cam Eden,NC 27288 Asheville,NC 28804 Huntersvlde,NC 28078
[phone] [phone] [phone]
CERTIFICATIONS
Project: EFF PPA 11/29
Pace Project No.: 92140209
Charlotte Certification IDs
9800 Kincey Ave.Ste 100,Huntersvlile,NC 28078 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 West Virginia Certification#:357
North Carolina Wastewater Certification#:12 VirginiaNELAP Certification#:460221
South Carolina Certification#:99006001
Asheville Certification IDs
2225 Riverside Dr.,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florlda/NELAP Certification#:E87648 South Carolina Certification#:99030001
Massachusetts Certification#:M-NC030 West Virginia Certification#:356
North Carolina Drinking Water Certification#:37712 VirginiaNELAP Certification#:460222
1
1
1
1
1
1
REPORT OF LABORATORY ANALYSIS Page 2 of 31 I '
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..

e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
' aceA!Jalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 98004(InceyAve. Suite 100
wwwpecelabs.com Eden.NC 27288 Asheville,NC 28804 Hunteravllle,NC 28078
[phone] [phone] [phone]
SAMPLE SUMMARY
1 Project: EFF PPA 11/29
Pace Project No.: 92140209
Lab ID Sample ID Matrix Date Collected Date Received
92140209001 PE Water
11/29/12 16:00 11/29/12 16:25
92140209002 FIELD BLANK EFF Water 11/29/12 16:10 11/29/12 16:25
F
i
•
1
1
i
1
1
1
1
1
REPORT OF LABORATORY ANALYSIS Page 3 of 31
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..
1

I
Q/� I e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc. •
ace,4 alytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Klncey Ave. Suite 100
wwepecskbaeom Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
[phone] [phone] [phone]
1
ISAMPLE ANALYTE COUNT
Project: EFF PPA 11/29
I
Pace Project No.: 92140209
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92140209001 PE EPA 1664A CLW 1 PASI-C
EPA200.7 JMW 15 PASI-A
EPA 1631E SH1 1 PASI-A
EPA 625 PPM 63 PASI-C
EPA 624 CAH 33 PASI-C
SM 2540C LMD 1 PASI-A
EPA 350.1 SAE 1 PASI-A
EPA351.2 JDA 1 PASI-A
EPA 353.2 DMN 1 PASI-A 1
EPA365.1 JDA 1 PASI-A
EPA 420.4 SAE 1 PASI-A
SM 4500-CN-E JDA 1 PASI-A 1
92140209002 FIELD BLANK EFF EPA 1631E SH1 1 PASI-A
1
I
I
I
I
I
• 1
REPORT OF LABORATORY ANALYSIS Page 4 of 31 ( 1
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..
•
I

I
I
pp.�.,, // e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
aceAna1ytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
tfora Eden,NC 27288 Asheville,NC 28804 Huntersvtle,NC 28078
[phone] [phone] [phone]
ANALYTICAL RESULTS
I Project: EFF PPA 11/29
Pace Project No.: 92140209
Sample: PE Lab ID: 92140209001 Collected: 11/29/12 16:00 Received: 11/29/12 16:25 Matrix:Water
I
Report Reg.
Parameters Results Units Limit Limit' DF Prepared Analyzed CAS No. Qual
HEM,Oil and Grease Analytical Method:EPA 1664A
I Oil and Grease ND mglL 5.0 1 12/12/12 09:20
200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7
Antimony ND ug/L 5.0 1 11/30/1220:30 12/05/1218:25 7440-36-0
Arsenic ND ug/L 10.0 1 11/30/12 20:30 12/04/12 19:57 7440-38-2
Beryllium ND ug/L 1.0 1 11/3011220:30 12/04/1219:57 7440-41-7
Cadmium ND ug/L 1.0 1 11/30112 20:30 12/04112 19:57 7440-43-9
Calcium 11000 ug/L 100 1 11/30/12 20:30 12/04/12 19:57 7440-70-2
Chromium ND ug/L5.0 1 11/30/12 20:30 12/04/12 19:57 7440-47-3
Copper 14.9 ug/L 5.0 1 11/30/12 20:30 12/04/12 19:57 7440-50-8
Lead ND ugh 5.0 1 11/30/12 20:30 12/04/12 19:57 7439-92-1
Magnesium 2720 ugh 100 1 11/30/12 20:30 12/04/12 19:57 7439-954
I
Nickel 6.3 ug/L
ND ug/L 5.0 1 11/30/12 20:30 12/04/12 19:67 7440-02-0
Selenium 10.0 1 11/30/12 20:30 12/04/12 19:57 7782-49-2
Silver ND ug/L 5.0 1 11/30/12 20:30 12/04/12 19:57 7440-22-4
Thallium ND ug/L 10.0 1 11/30/12 20:30 12/04/12 19:57 7440-28-0
Total Hardness 38700 ug/L 662 1 11/30/12 20:30 12/04/12 19:57
Zinc 74.3 ug/L 10.0 1 11/30/12 20:30 12/04/12 19:57 7440-66-6
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1831E
Mercury 12.9 nglL 0.50 E1
12/12/1215:30 12/13/1213:54 7439-97-6
825 MSSV Analytical Method:EPA 625 Preparation Method:EPA 625
Acenaphthene ND ug/L • 5.1 1 12/03/12 09:10 12/06/12 07:23 83-32-9
I
Acenaphthylene ND ug/L 5.1 1 12/03/12 09:10 12!06/12 07:23 208-96-8
Anthracene ND ug/L 5.1 1 12/0311209:10 12/06/12 07:23 120-12-7
Benzidine ND ug/L 50.5 1 12/03/12 09:10 12/06/12 07:23 92-87-5
Benzo(a)anthracene ND ugh 5.1 1 12/03/12 09:10 12/06/12 07:23 56-55-3
I
Benzo(a)pyrene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 0723 50-32-8
Benzo(b)fluoranthene ND ugh 5.1 1 12/03/12 09:10 12/08/12 07:23 205-99-2
Benzo(g,h,l)perylene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 191-24-2
Benzo(k)fluoranthene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 207-08-9
I 4 Bromophenylphenyl ether ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 101-55-3
Butylbenzyiphthalate ND ug/L 5.1 1 12/03/12 09:10 12/08/12 07:23 85-68-7
bis(2-Chloroethoxy)methane ND ug/L 10.1 1 12/03/12 09:10 12/06/12 07:23 111-91-1
bis(2-Chloroethyl)ether ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 111-44-4
I bis(2-Chlorolsopropyl)ether ND ugh 5.1 1 12/03/12 09:10 12/06/12 07:23 108-60-1
2-Chloronaphthalene ND ug/L 5.1 1 !2/03112 09:10 12/08/12 07:23 91-58-7
2-Chlorophenol ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 95-57-8
4-Chiorophenyiphenyl ether ND ug/L 5.1- 1 12/03/12 09:10 12/06/12 07:23 7005-72-3
Chrysene ND ug/L 5.1 1 12/03/12 09:10 12106/12 07:23 218-01-9
I
Dibenz(a,h)anthracene
1,2-Dichlorobenzene ND ugh 5.1 1 12/03112 09:10 '12/06/12 07:23 53-70-3
ND ugh. 5.1
1 12/03/12 09:10 12/06/12 07:23 95-50-1
1,3-Dichlorobenzene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 541-73-1
1,4-Dichlorobenzene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 106-46-7
3,3'-Dichlorobenzidlne ND ug/L 25.3 1 12/03/12 09:10 12/06/12 07:23 91-94-1
I Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 5 of 31
• This report shall not be reproduced,except In full,
Iwithout the written consent of Pace Analytical Services,Inc..

I
n/�� a.
205Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
c?CE�U f_�IJ ICaEast Meadow Road-Suite A 2225 Riverside Dr. 9800 Kinsey Ave. Suite 100 •
Eden,NC 27288 Asheville,NC 28804 HuniersvlNe,NC 28078
[phone] [phone] [phone]
• ANALYTICAL RESULTS
Project: EFF PPA 11/29
Pace Project No.: 92140209
Sample: PE Lab ID: 92140209001 Collected: 11/29/12 16:00 Received: 11/29/12 16:25 Matrix:Water .
Report Reg.
Parameters Results Units Limit Limit DF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Method:EPA 825 Preparation Method:EPA 625
2,4-Dichlorophenol ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 120-83-2
Diethylphthalate ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 84-68-2
2,4-Dimethylphenol ND ug/L 10.1 1 12/03/12 09:10 12/06/12 07:23 105-67-9
Dimethylphthalate ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 131-11-3
Di-n-butylphthalate ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 84-74-2
4,6-Dinitro-2-methylphenol ND ug/L 20.2 1 12/03/12 09:10 12/06/12 07:23 534-52-1
2,4-Dinitrophenol ND ug/L 50.5 1 12/03/12 09:10 12/06/12 07:23 51-28-5
2,4-Dinitrotoluene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 121-14-2
2,6-DInitrotoluene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 606-20-2
Di-n-octylphthalate ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 117-84-0
1,2-Diphenylhydrazine ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 122-66-7
bls(2-Ethyihexyl)phthalate ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 117-81-7
Fluoranthene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 206-44-0
Fluorene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 86-73-7
Hexachloro-1,3-butadiene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 87-68-3
Hexachlorobenzene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 118-74-1 '
Hexachlorocyclopentadiene ND ug/L 10.1 1 12/03/12 09:10 12/06/12 07:23 77-47-4
Hexachloroethane ND ug/L 5.1 1 12/03/12 09:10 12106/12 07:23 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 5.1 1 12/03/1209:10 12/06/1207:23 193-39-5
Isophorone ND ug/L 10.1 1 12/03/12 09:10 12/06/12 07:23 78-59-1
3&4-Methylphenol(m&p Cresol) ND ug/L 10.1 1 12/03/12 09:10 12/06/12 07:23
Naphthalene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 91-20-3
Nitrobenzene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 98-95-3
2-Nitrophenol ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 88-75-5
4-Nitrophenol ND ug/L 50.5 1 12/03/12 09:10 12/06/12 07:23 100-02-7
I
N-Nitrosodimethylamine ND ug/L 5.1 1 12/03/12 09:10 12/08/12 07:23 62-75-9
N-Nitroso-di-n-propylamine ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 621-64-7
N-Nitrosodiphenylamine ND ug/L 10.1 1 12/03/12 09:10 12/06/12 07:23 86-30-6
Pentachlorophenol ND ug/L 25.3 1 12/03/12 09:10 12/06/12 07:23 87-86-5
Phenanthrene ND ug/L 5.1 1 12103/12 09:10 12/06/12 07:23 85-01-8
Phenol ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 108-95-2
Pyrene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 129-00-0
1,2,4-Trlchlorobenzene ND ug/L 5.1 1 12/03/12 09:10 12/06/12 07:23 120-82-1
2,4,6-Trichlorophenol ND ug/L 10.1 1 12/03/12 09:10 12/06/12 07:23 88-06-2
I
Surrogates
Nitrobenzene-d5(S) 32% 10-120 1 12/03/12 09:10 12/06/12 07:23 4165-60-0
2-Fluorobiphenyl(S) 32% 15-120 1 12/03/12 09:10 12/06/12 07:23 321-60-8 '
Terphenyl-d14(S) 53% 11-131 1 12/03/12 09:10 12/06/12 07:23 1718-51-0 I
Phenol-d6(S) 12% 10-120 1 12/03/12 09:10 12/06/12 07:23 13127-88-3
2-Fluorophenol(S) 18 % 10-120 1 12/03/12 09:10 12/06/12 07:23 367-12-4
2,4,6-Tribromophenol(S) 47 % 10-137 1 12/03/12 09:10 12/06/12 07:23 118-79-6
624 Volatile Organics Analytical Method:EPA 624
I
Acrolein ND ug/L 100 1 12/05/12 22:09 107-02-8
Acrylonitrile ND ug/L 50.0 1 12/05/12 22:09 107-13-1
Benzene ND ug/L 6.0 1 12/05/12 22:09 71-43-2
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 6 of 31 (
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc.. 1

I •
/{ / • Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
aCeAn8lytiCal 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 wncey Ave. Suite 100
xwxtpacef.bs com Eden,NC 27288 AshevIlle,NC 28804 Hunteravllle,NC 28078
[phone] (828)2547176 [phone]
I (
ANALYTICAL RESULTS
I Project: EFF PPA 11/29
Pace Project No.: 92140209
Sample: PE Lab ID: 92140209001 Collected: 11/29/12 16:00 Received: 11/29/12 16:25 Matrix:Water
Report Reg.
IParameters Results Units Limit Limit DF Prepared Analyzed CAS No. Qua!
824 Volatile Organics Analytical Method:EPA 624
I Bromodichloromethane ND ug/L 5.0 1 12/05/12 22:09 75-27-4
Bromoform ND ug/L 5.0 1 12105/12 22:09 75-25-2
Bromomethane ND ug/L 10.0 1 12/05/12 22:09 74-83-9
Carbon tetrachloride ND ug/L 5.0 1 12105/12 22:09 56-23-5
Chlorobenzene ND ug/L 5.0 1 12/05/12 22:09 108-90-7
I Chloroethane ND ug/L 10.0 1 12/05/12 22:09 75-00-3
2-Chioroethylvinyl ether ND ug/L 10.0 1 12/05/12 22:09 110-75-8
Chloroform ND ugh 5.0 1 12/05/12 22:09 67-66-3
I Chloromethane ND ug/L 5.0 1 12/05/12 22:09 74-87-3
Dibromochloromethane ND ugh 5.0 1 12/05/12 22:09 124-48-1
1,1-Dichloroelhane ND ug/L 5.0 1 12/05/12 22:09 75-34-3
1,2-Dichloroethene ND ug/L 6.0 1 12/05/12 22:09 107-08-2
I 1,1-Dichloroethene ND ug/L 5.0 1 12/05/12 22:09 75-35-4
trans-1,2-Dlchloroethene ND ug/L 5.0 1 12/05/12 22:09 156-60-5
1,2 Dichioropropane ND ug/L 5.0 1 12/05/1222:09 78-87-5
cls-1,3-Dichioropropene ND ug/L 5.0 1 12/05/12 22:09 10061-01-5
trans-1,3-Dichloropropene ND ug/L 5.0 1 12/05/12 22:09 10081-02-6
Ethylbenzene ND ug/L 5.0 1 12/05/12 22:09 10041-4
Methylene Chloride ND ug/L 5.0 1 12105/12 22:09 75-09-2
1,1,2,2-Tetrachloroethane ND ug/L 5.0 1 12/05/12 22:09 79-34-5
Tetrachloroethene ND ug/L 5.0 1 12/05/12 22:09 127-18-4
I
Toluene ND ug/L 5.0 1 12/05/12 22:09 108-88-3
1,1,1-Trichloroethane ND ug/L 6.0 1 12/05/12 22:09 71-55-6
1,1,2-Trichloroethane ND ugh 5.0 1 12/05/12 22:09 79-00-5
Trichloroethene ND ug/L 5.0 1 12/05/1222:09 79-01-6
I
Vinyl chloride ND ugh 5.0 1 12/05/12 22:09 75-014 .
Surrogates
Dibromofluoromethane(S) 97 % 70-130 1 12/05/12 22:09 186853-7
4-Bromofluorobenzene(S) 98 % 70-130 1 12/05/12 22:09 460-00-4
I
Toluene-d8(S) 95 % 70-130 1 12105/12 22:09 2037-26-5
1,2-Dichloroethane-d4(S) 106 % 70-130 1 12/05/12 22:09 17060-07-0
2540C Total Dissolved Solids Analytical Method:SM 2540C •
I Total Dissolved Solids 294 mg/L 25.0 1 11/30/12 20:25
350.1 Ammonia Analytical Method:EPA 350.1
Nitrogen,Ammonia 18.6 mg/L 0.50 5 12/07/1216:07 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2
Nitrogen,Kjeldahl,Total 19.3 mg/L 0.50 . 1 12/11/12 13:50 7727-37-9
I 353.2 Nitrogen,NO2/NO3 pros. Analytical Method:EPA 3532
Nitrogen,NO2 plus NO3 5.8 mg/L 0.040 2 12112/12 22:05 M1
II Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 7 of 31
This report shell not be reproduced,except In full,
Iwithout the written consent of Pace Analytical Services,Ino..

Q/�.y )® Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,ihc.
�CG/V I�IIC�I 205 East Meadow Road-Suite A 2225 Riverside Dr. 9900 IQncey Ave, 3ulte 100 i
Eden,NC 27288 Asheville,NC 28804 Huntersvlta,NC 28078
[phone] [phone] [phone]
1 ANALYTICAL RESULTS
Project: EFF PPA 11/29
Pace Project No.: 92140209 1
Sample: PE Lab ID: 92140209001 Collected: 11/29/12 16:00 Received: 11/29/12 16:25 Matrix:Water
Report Reg.
Parameters Results Units Limit Limit DF Prepared Analyzed CAS No. Qual
365.1 Phosphorus,Total Analytical Method:EPA 365.1
till
Phosphorus 5.3 mg/L 0.25 5 12/10/1215:41 7723-14-0
420.4 Phenolics,Total Analytical Method:EPA 420.4
Phenol 0.087 mg/L 0.050 10 12/07/1211:41 108-95-2
4500CNE Cyanide,Total Analytical Method:SM 4500-CN-E
Cyanide ND mg/L 0.0050 1 12/11/12 10:01 57-12-5
1
. 1
I
- i
• I
I
1
1
f 11 Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 8 of 31
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..
• I

p M a Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
I
••aCOAnalytiCa/ 205 East Meadow Road-Suite A 2226 Riverside Dr. 98001ancey Ave. Suite 100
N Eden,NC 27288 Asheville,NC 28804 Hunteraville,NC 28078
vno [phone] [phone] [phone]
ANALYTICAL RESULTS
I Project: EFF PPA 11/29
Pace Project No.: 92140209
Sample: FIELD BLANK EFF Lab ID: 92140209002 Collected: 11/29/12 16:10 Received: 11129/12 16:25 Matrix:Water
Report Reg. •
IParameters Results Units Limit Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631E
IMercury ND ng/L 0.50 1 12/12/12 15:30 12/13/12 14:02 7439-97-6
I
I .
•I
111 l
I
I
I
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 9 of 31
This report shall not be reproduced,except in full,
Iwithout the written consent of Pace Analytical Services,Inc..

I
Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc. •
ace Analytical•
a 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kinsey Ave. Suite 100 ,
wwixP+ e6acom Eden,NC 27288 Asheville,NC 28804 HuntersNNe,NC 28078
[phone] [phone] [phone]
1 QUALITY CONTROL DATA
Project: EFF PPA 11/29
Pace Project No.: 92140209
QC Batch: GCSV/13505 Analysis Method: EPA 1664A
QC Batch Method: EPA 1664A Analysis Description: 1664 HEM,Oil and Grease •
Associated Lab Samples: 92140209001
METHOD BLANK: 887609 Matrix: Water
Associated Lab Samples: 92140209001
Blank Reporting
I
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 12112/12 09:17
LABORATORY CONTROL SAMPLE: 887610
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 40 33.5 84 78-114
MATRIX SPIKE SAMPLE: 887611
92140941001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L ND 41.7 36.2 87 78-114
(
I
I
•
. ,I
t
I
t
•
I
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 10 of 31
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..
I

I/++d�//����yy�e�/ jjh�ee��/a Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
av�i/711Q1 ical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 IOnoey Ave.Suite 100
Eden,NC 27288 Asheville,NC 28804 Huntersvl8e,NC 28078
[phone] [phone] [phone]
I (
QUALITY CONTROL DATA.
•
I Project: EFF PPA 11/29
Pace Project No.: 92140209
QC Batch: MERP/4758 Analysis Method: EPA 1631E
I QC Batch Method: EPA 1831E Analysis Description: 1631 E Mercury,Low Level
Associated Lab Samples: 92140209001,92140209002
METHOD BLANK: 888835 Matrix: Water
I Associated Lab Samples: 92140209001,92140209002
Blank Reporting
Parameter Units Result Umit Analyzed Qualifiers
•
Mercury ng/L ND 0.50 12/13/12 13:05
I .
METHQD BLANK: 888836Matrix: Water
Associated Lab Samples: 92140209001,92140209002
I Blank . Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 12/13/12 14:25
IMETHOD BLANK: 888837 Matrix: Water
Associated Lab Samples: 92140209001,92140209002
I
Blank Reporting
Parameter Units Result Umit Analyzed Qualifiers
Mercury ng/L ND 0.50 12/13/12 15:50
iLABORATORY CONTROL SAMPLE: 888838
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
IMercury ng/L 5 5.21 104 80-120
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 888839 888840
I MS MSD
92139291001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Mercury ng/L 1.44 25 25 24.7 25.0 93 94 71-125 1 20
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 888947 888948,
I MS MSD
92140757002 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Mercury ng/L 0.522 25 25 22.0 22.3 . 86 87 71-125 1 20
1
II Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 11 of 31
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..

I
r� //��� / j /R Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,lhc.
aceAnalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100II
snnxPbacam Eden,NC 27288 Asheville,NC 28804 Huntersvite,NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
1
Project: EFF PPA 11/29
Pace Project No.: 92140209
QC Batch: • MPRP112087 Analysis.Method: EPA 200.7
QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET
Associated Lab Samples: 92140209001
METHOD BLANK: 882075 Matrix: Water
Associated Lab Samples: 92140209001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Antimony ug/L ND 5.0 12/04/12 18:49
Arsenic ug/L ND 10.0 12/04/12 18:49
Beryllium ug/L ND 1.0 12/04/12 18:49
• Cadmium ug/L ND 1.0 12/04/12 18:49
Calcium ug/L ND 100 12/04/12 18:49
Chromium ug/L ND 5.0 12/04/12 18:49
Copper ug/L ND 5.0 12/04/12 18:49
Lead ug/L ND 6.0 12/04/12 18:49
Magnesium ug/L ND 100 12/04/12 18:49
Nickel ug/L ND 6.0 12104/1218:49
Selenium ug/L ND 10.0 12/04/12 18:49
Silver ug/L ND 5.0 12/04/12 18:49
Thallium ug/L ND 10.0 12/04/12 18:49
Total Hardness ug/L ND 662 12/04/12 18:49
Zinc ug/L ND 10.0 12/04/12 18:49 f
LABORATORY CONTROL SAMPLE: 882076
I
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Antimony ug/L 500 523 105 85-115
Arsenic ug/L 500 515 103 85-115
Beryllium ug/L 500 511 102 85-115
Cadmium ug/L 500 511 102 85-115
Calcium ug/L 5000 5060 101 85-116
Chromium ug/L 500 492 98 85-115
Copper ugh 500 518 104 85-115
Lead + ug/L 500 509 102 85-116
Magnesium ug/L 5000 4940 99 85-115
Nickel ug/L 500 510 102 85-115
I
Selenium ug/L 500 525 105 85-116
Silver ug/L 260 250 100 85-115
Thallium ug/L 500 504 101 85-115
Total Hardness ug/L 33000
Zinc ug/L 600 497 99 85-115
MATRIX SPIKE SAMPLE: 882106 I
92139835012 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
•
Antimony ug/L 253 500 788 107 70-130
Arsenic ug/L ND 500 549 110 70-130
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 12 of 31
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..
•
I

I •
/��� f a Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
I ace,4 IQII yb al 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Klncey Ave. Suite 100
Irs • Eden,NC 27288 Asheville,NC 28804 Hunteravllle,NC 28078
[phone] [phone] [phone]
I (
QUALITY CONTROL DATA
I
I Project: EFF PPA 11/29
Pace Project No.: 92140209
•
MATRIX SPIKE SAMPLE: 882106 • •
92139835012 Spike MS MS %Rec .
Parameter Units Result Conc. Result
%Rec Limits • Qualifiers
Beryllium ug/L ND 500 515 103 70-130
Cadmium ug/L 22.7 500 542 104 70-130
Calcium ug/L 12700 5000 17800 103 70-130
Chromium ug/L ND 500 511 100 70-130
Copper ug/L 482 500 1030 109 70-130
Lead ug/L 7900 500 8830 185 70-130 M1
I Magnesium ug/L 13400 5000 19400 119 70-130
Nickel ug/L 52.6 500 560 101 70-130
Selenium ug/L ND _ 500 578 113 70-130
Silver • ug/L ND • 250 244 98 70-130
I Thallium ug/L ND 500 445 89 70-130
Total Hardness ug/L 86800 124000
Zinc ug/L 2060 500 2640 115 70-130
•
I MATRIX SPIKE SAMPLE: 882108
92139913001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Antimony ug/L ND 500 579 115 70-130
I ( Arsenic ug/L ND 500 568 114 70-130
Beryllium ug/L ND 500 554 111 70-130
Cadmium ug/L ND 500 556 111 70-130
I
Calcium ug/L
ug/L 1290 5000 6780 110 70-130
Chromium ND 500 534 107 70-130
Copper ug/L 56.6 500 624 114 70-130
Lead ug/L ND 500 548 109 70-130
I Magnesium ug/L 398 5000 5740 107 70-130
Nickel ug/L 29.0 500 583 111 70-130 •
Selenium 41 ND 500 571 114 70-130
Sliver ug/L ND 250 269 108 70-130
I
Thallium ug/L ND 500 635 107 70-130
Total Hardness ug/L 4870 40600
Zinc ug/L 0.088 rn92 500 631 109 70-130
I SAMPLE DUPLICATE: 882107
92140243001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
I Antimony ug/L ND ND 20
Arsenic ug/L ND ND, 20
Beryllium ug/L ND ND 20
Cadmium ug/L ND ND 20
I Calcium ug/L 8.4 mg/I 8620 3 20
Chromium ug/L ND ND 20
Copper ug/L ND 2.8J • 20.
Lead ug/L ND ND 20
Magnesium ug/L 1.7 mg/L 1680 1 20
II ( Date:12/17/2012 02:63 PM REPORT OF LABORATORY ANALYSIS Page 13 of 31
This report shall not be reproduced,except In full,
Iwithout the written consent of Pace Analytical Services,Inc..

I
e• Pace Analytical Services,Inc. Pace Analytical Services,Inc.
Pace Analytical Services,Inc.I/��C ' 205 East Meadow Road-Suite A 2225 Riverside Dr. 980014noey.Ave. Suite 100
ceAnal
J*� ra Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
[phone] [phone] [phone] ill
QUALITY CONTROL DATA
Project: EFF PPA 11/29 I Pace Project No.: 92140209
SAMPLE DUPLICATE: 882107 •
92140243001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Nickel ug/L ND ND 20
Selenium ugA- ND ND 20 I Silver ugh ND ND 20 .
Thallium ug/L ND ND 20
Total Hardness ug/L 27.7 mg/L 28400 2 20
Zinc ug/L 0.015 mg/L. 14.9 1 20
I
SAMPLE DUPLICATE: 882109
92140126002 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Antimony ug/L ND 4.6J 20
Arsenic ug/L ND ND 20
Beryllium ug/L ND ND 20
' Cadmium ug/L ND ND 20
Calcium ug/L 26700 26000 3 20
Chromium ug/L 125 121 3 20
Copper ug/L 14.0 12.9 8 20
Lead ug/L ND ND 20
Magnesium ug/L 2520 2480 2 20 ( i
Nickel ug/L ND 4J 20
Selenium ug/L _ ND ND 20
Silver ug/L ND ND 20
I
Thallium ug/L ND ND 20
Total Hardness ug/L 77000 75000 3 20
Zinc ug/L 861 645 3 20
I
1
• I
I
1
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 14 of 31 ( II
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..
I

i
Pace Analytical Services,Inc. Pace Analytical Services,Inc. Inc.
Pace Analytical Services,In
• + ,��1/�Y/r�l 205 East Meadow Road-Suite A 2226 Riverside Dr. 9800 Klncey Ave. Suite 100
�w�rwPaciabtbom Eden,NC 27288 Asheville,NC 28804 Hunteraville,NC 28078
[phone] [phone] [phone]
Il (
QUALITY CONTROL DATA
Project: EFF PPA 11129
Pace Project No.: 92140209
QC Batch: MSV/21331 Analysis Method: EPA 624
QC Batch Method: EPA 624 Analysis Description: 824 MSV
Associated Lab Samples: 92140209001
METHOD BLANK: 884403 Matrix: Water
I
Associated Lab Samples: 92140209001
Blank Reporting
Parameter Units Result Limit ' Analyzed Qualifiers
1,1,1-Trichloroethane ug/L ND 5.0 12/05/1214:06
1,1,2,2-Tetrachloroethane ug/L ND 5.0 12/05/12 14:06
1,1,2-Trichloroethane ug/L ND 5.0 12/05/12 14:06
1,1-Dlchloroethane ug/L ND 5.0 .12/05/1214:06 •
1,1-Dlchloroethene ug/L ND 5.0 12/05/12 14:06
' 1,2-Didiloroethane ug/L ND 5.0 12/05/12 14:06
1,2-Dichloropropane ug/L ND 5.0 12/0511214:06
2-Chioroethyivinyi ether ug/L ND 10.0 12/05/12 14:06
Acrolein ug/L ND 100 12/05/12 14:06
II Acrylonitrile
ugh ND 50.0 12/05/12 14:06
Benzene ug/l ND 5.0 12/05/1214:06
Bromodichloromethane ug/L ND 5.0 12/05/12 14:06
Bromoform ug/L ND 5.0 12/05/12 14:06
Bromomethane ug/L ND 10.0 12/05/12 14:06
( Carbon tetrachloride ug/L ND 5.0 12/05/12 14:06
Chkxobenzene ug/L ND 5.0 12/05/12 14:06
Chloroethane ug/L ND 10.0 12/05/12 14:06
' Chloroform ug/L
ug/L ND 5.0 12/05/12 14:06
Chloromethane ND 5.0 12/05/12 14:06
cls-1,3-Dichloropropene ug/L ND 5.0 12/05/12 14:06
Dibromochloromethane ug/L ND 5.0 12/05/12 14:06
Ethylbenzene ugh ND 5.0 12/05/12 14:06
Methylene Chloride ug/L ND 5.0 12105/1214:06
Tetrachloroethene ug/L ND 5.0 12/05/12 14:06
Toluene ugh ND 5.0 12/05/12 14:06 •
i
trans-1,2-Dichloroethene ug/L ND 5.0 12/05/12 14:06
trans-1,3-Dichloropropene ug/L ND 5.0 12/05/12 14:06
Trichloroethene ug/L ND 5.0 12/05/1214:06
Vinyl chloride ug/L ND 5.0 12/05/12 14:06
1 1,2-Dichloroethane d4(S) % 110 70-130 12/05/12 14:06
4 Bromofluorobenzene(S) % 100 70-130 12/05/12 14:06
Dibromofluoromethane(S) °k 101 70-130 12/05/12 14:06
Toluene-d8(S) % 99 70-130 12/05/12 14:06
ILABORATORY CONTROL SAMPLE: 884404
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,1,1-Trichloroethane ug/L 20 23.1 116 52-162
1,1,2,2-Tetrachloroethane ug/L 20 19.9 100 46-157
1,1,2-Trichloroethane ugh 20 23.1 118 52-150
1,1-Dichloroethane ug/L • 20 21.8 109 59-155
( Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 15 of 31
This report shall not be reproduced,except In full,
' without the written consent of Pace Analytical Services,Inc..
I

1
AnalyticalPace Services, Pace AnalyticalPa nu
Ce/ya na!6 205 East Meadow Road Suite A 5 Riverside Dr. 9800 Kicey Ave. Suite 100
rYwirpswfsDacom ' Eden,NC 27288 Asheville,NC 28804 Huntersvllle,NC 28078
[phone] [phone] [phone]
11
QUALITY CONTROL DATA
•
Project: EFF PPA 11/29
Pace Project No.: 92140209
LABORATORY CONTROL SAMPLE: 884404
Spike LCS LCS %Rec
• Parameter Units Conc. Result %Rec Limits Qualifiers
1,1-Dichioroethene ug/L 20 21.0 105 1-234
1,2-Dkctbroethane ug/L 20 22.4 112 49-155
1,2-Dlchloropropane ug/L 20 22.1 110 1-210
2-Chbroethyivinyl ether ug/L 40 37.6 94 1-305 1
Acroleln ug/L 100 104 104 15-152
Acrylonitrile ug/L 100 107 107 75-132
Benzene ugh 20 22.1 111 37-151
Bromodichloromethane ug/L 20 22.5 113 35-155
Bromoform ug/L 20 22.8 114 45-169
Bromomethane ug/L 20 14.0 70 1-242
Carbon tetrachloride ug/L 20 25.5 128 70-140
Chlorobenzene ug/L 20 21.1 105 37-160 •
Chloroethane ugh 20 24.2 121 14-230•
Chloroform ugh 20 22.6 113 51-138
Chloromethane ug/L 20 20.3 102 1-273
cis-1,3-Dlchloropropene ug/L 20 23.4 117 1-227
Dibromochloromethane ug/L 20 22.2 111 53-149
Ethylbenzene ug/L 20 21.2 108 37-162
Methylene Chloride ug/L 20 22.2 111 1-221
Tetrachloroethene ug/L 20 21,5 107 64-148
Toluene ug/L 20 22.4 112 47-150 ( /
trans-1,2-Dlchloroethene ug/L 20 20.9 105 54-156
trans-1,3-Dichloropropene ug/L 20 22.7 114 17-183 I Trichloroethene ug/L 20 22.9 115 71-157
Vinyl chloride ug/L 20 21.3 106 1-251
1,2-Dichbroethane-d4(S) % 106 70-130
4-Bromofluorobenzene(S) %, 99 70-130
i
Dibromofluoromethane(S) °k 105 70-130
Toluene-d8(S) °,6 100 70-130
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 884405 884406 I MS MSD
92139991001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
1,1,1-Trichloroethane ug/L ND 20 20 11.1 12.3 56 62 46-171 10 30 i'
1,1,2,2 Tetrachloroethane ug/L ND 20 20 12.1 14.3 81 71 73-159 18 30 M1
1,1,2-Trichloroethane ug/L ND 20 20 13.5 14.7 67 73 64-152 8 30
1,1-Dichloroethane ugh ND 20 20 11.6 12.9 58 64 43-172 11 30
1,1-Dichioroethene ugh. ND 20 20 11.3 12.1 56 61 48-189 7 30
1,2-Dichloroethane ug/L ND 20 20 11.6 12.7 58 64 42-171 9 30
1,2-DIchloropropane ug/L ND 20 20 10.3 12.7 51 64 55-157 21 30 M1
2-ChloroethyMnyl ether ug/L ND . 40 40 ND ND 0 0 70-130 30 P5
Acroleln ug/L ND 100 100 65J 74.4J 65 74 70-130 30 M1 '
Acrylonitrile ug/L ND 100 100 68.7 76.4 69 76 70-130 11 30 M1
Benzene ug/L ND 20 20 11.7 13.0 58 85 54-183 11 30
Bromodichloromethane ug/L ND 20 20 11.5 13.8 58 69 56-152 18 30
Bromoform ug/L ND 20 20 13.5 14.5 67 72 53-151 7 30 '
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 16 of 31
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services.Inc..

1
/�
., 1® Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
1 I ac+eAn ar 205 East Meadow Road-Suite A • 2225 Riverside Dr. 9800 Idncey Ave. Suite 100
oorrr Eden,NC 27288 Asheville,NC 28804 Huntersvllle,NC 28078
[phone] [phone] [phone]
I (
QUALITY CONTROL DATA
Project: EFF PPA 11/29
Pace Project No.: 92140209 •
•
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 884405 884406
I MS MSD
92139991001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Bromomethane ug/L ND 20 20 8.7J 8.7J 43 43 10-200 30
I Carbon tetrachloride ug/L ND 20 20 11.3 13.3 56 66 41-175 16 30
Chlorobenzene ug/L ND 20 20 11.3 12.9 57 65 67-152 13 ' 30 M1
Chloroethane ug/L ND 20 20 13.4 13.1 67 66 23-200 2 30
Chloroform ug/L ND 20 20 14.7 15.8 62 68 51-166 8 30
I Chloromethane ug/L ND 20 20 10.0 9.6 50 48 40-175 5 30
cls-1,3-Dlchloropropene ug/L ND • 20 20 11.5 13.0 58 65 38-146 12 30
Dibromochloromethane ug/L ND 20 20 12.2 12.7 61 63 65-144 4 30 M1
Ethylbenzene ug/L ND 20 20 10.3 12.0 61 60 57-152 16 30 M1
I Methylene Chloride ug/L ND 20 20 12.1 12.9 61 65 40-167 7 30
Tetrachloroethene ug/L ND 20 20 10.5 12.8 52 64 59 155 20 30 Mt
Toluene ug/L ND 20 20 10.9 12.8 54 62 47-162 15 30
trans-1,2-Dichloroethene ug/L ND 20 20 11.1 12.7 56 63 47-178 13 30
trans-1,3-Dlchioropropene ug/L ND 20 20 11.9 14.0 60 70 39-148 16 30
I Trichloroethene ug/L ND 20 20 12.0 13.1 60 66 60-153 8 30
Vinyl chloride ug/L ND 20 20 9.9 11.1 50 55 46-176 11 30
1,2-Dlchloroethane-d4(S) % 98 99 70-130
4-Bromofluorobenzene(S) % 108 102 70-130
Dlbromofluoromethane(S) % 102 104 70-130
I Toluene-d8(S) % 98 95 70-130
I
I
r
•1
I .
I .
I Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 17 of 31
This report shall not be reproduced,except In full,
Iwithout the written consent of Pace Analytical Services,Inc..

n �t a Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,18c.
aV BAI I.�� ICaI 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Sults 100
Eden,NC 27288 Asheville,NC 28804 Hunterevllle,NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
1
Project: EFF PPA 11/29 •
111
Pace Project No.: 92140209
QC Batch: OEXT/19941 Analysis Method: EPA 625
QC Batch Method: EPA 625 Analysis Description: 625 MSS
Associated Lab Samples: 92140209001
METHOD BLANK: 882389 Matrix: Water . •
Associated Lab Samples: 92140209001 I Blank Reporting
. Parameter Units . Result Limit Analyzed Qualifiers
1,2,4-Trichlorobenzene ug/L ND 5.0 12/06112 00:34
1,2-Dichtorobenzene ug/L ND 5.0 12/06/12 00:34
1,2-Diphenylhydrazine ug/L ND 6.0 12/06/12 00:34
1,3-Dichlorobenzene • ug/L ND 5.0 12/06/12 00:34
1,4-Dichlorobenzene ug/L ND 5.0 12/06/12 00:34
2,4,6-Trichlorophenol ug/L • ND 10.0 12/06/12 00:34 •
2,4-Dichlorophenol ug/L • ND . 6.0 12/06/12 00:34
•
2,4-Dimethylphenol ug/L ND 10.0 12/06/12 00:34
2,4-Dlnitrophanoi ug/L ND 50.0 12/06/12 00:34
2,4-Dinitrotoluene ug/L ND 5.0 12/06/12 00:34
2,6-Dinitrotoiuene ug/L ND 6.0 12/06/12 00:34
2-Chloronaphthalene ug/L ND 5.0 12/06/12 00:34
2-Chlorophenol ug/L ND 6.0 12/06/12 00:34
2-Nitrophenol ug/L ND 6.0 12/06/12 00:34 I 3&4 &p-Methyiphenol(m Cresol) ug/L ND 10.0 12/08/12 00:34
3,3'-Dlchlorobenzidine ug/L ND 25.0 12/06/12 00:34
4,6-Dinitro-2-methylphenol ug/L ND . 20.0 12/08/12 00:34
4-Bromophenylphenyl ether ug/L ND 5.0 12/06/12 00:34
4-Chiorophenyiphenyl ether ug/L ND 5.0 12/06/12 00:34
4-Nitrophenol ug/L ND 50.0 12/06/1200:34
Acenaphthene ug/L ND 5.0 12/06/12 00:34
Acenaphthylene ug/L ND 5.0 12/06/12 00:34 '
Anthracene ug/L ND 6.0 12/06/12 00:34
Benzidine ug/L ND 50.0 12/06/12 00:34
Benzo(a)anthracene ug/L ND 5.0 12/06/12 00:34
Benzo(a)pyrene ug/L ND 5.0 12/06/12 00:34 IIBenzo(b)fluoranthene ug/L ND 5.0 12/06/12 00:34
Benzo(g,h,i)perylene ug/L ND 5.0 12/06/12 00:34
Benzo(k)fluoranthene ug/L ND 5.0 12/06/12 00:34
bls(2-Chloroethoxy)methane ug/L ND 10.0 12/06/12 00:34 1
bis(2-Chloroethyl)ether ug/L ND 5.0 12/08/12 00:34
bis(2-Chloroisopropyl)ether ug/L ND 5.0 12/06/12 00:34
bls(2-Ethylhexyl)phthalate ug/L ND 5.0 12/06/12 00:34
Butylbenzylphthalate ug/L ND 5.0 12/06/12 00:34 '
Chrysene ug/L ND 5.0 12/06/12 00:34
Di-n-butylphthalate ug/L ND 5.0 12/06/12 00:34
Dl-n-octylphthalate ug/L ND 5.0 12/06/12 00:34
Dibenz(a,h)anthracene ug/L ND 5.0 12/06/12 00:34
Diethylphthalate ug/L ND 5.0 12/08/12 00:34
Dimethylphthaiate ug/L ND 5.0 12/06/12 00:34
Fluoranthene ug/L ND 5.0 12/06/12 00:34
Fluorene ug/L ND 5.0 12/06/12 00:34
Hexachloro-1,3-butadiene ug/L ND 5.0 12/06/12 00:34 •
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 18 of 31 (.
This report shall not be reproduced,except In full,
• without the written consent of Pace Analytical Services,Inc..
I

II
�n' a Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
I ... ceA is t/} I ' 205 East Meadow Road-Suite A 2225 Riveralde Dr. 9800 tdncey Ave. Suite 100
��` Eden,NC 27288 'Asheville,NC 28804 Huntersvilie,NC 28078
Wm
1 [phone] [phone] [phone]
QUALITY CONTROL DATA
I Project: EFF PPA 11/29
Pace Project No.: 92140209
METHOD BLANK: 882389 Matrix: Water
I Associated Lab Samples: 92140209001
Blank • Reporting
Parameter Units _ Result Limit • Analyzed Qualifiers
I Hexachlorobenzene ug/L ND 5.0 12/06/12 00:34
Hexachlorocyclopentadiene ugh ND 10.0 12/06/12 00:34
Hexachloroethane ug/L ND 5.0 12/06/12 00:34
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 12/06/12 00:34
isophorone ug/L ND 10.0 12/06/12 00:34
N Nitroso di-n-propylamine ug/L
ND 5.0 12/06/12 00:34
N-Nitrosodimethylamine ug/L ND 5.0 12!08112 00:34
N-Nitrosodiphenylamine ug/L ND 10.0 12/06/12 00:34 •
Naphthalene ug/L •ND 5.0 12/06/12 00:34
I Nitrobenzene ug/L ND 5.0 12/06/12 00:34
Pentachlorophenol ug/L ND 25.0 12/06/12 00:34
Phenanthrene ug/L ND 5.0 12/06/12 00:34
Phenol ug/L ND 5.0 12/06/12 00:34
I Pyrene
ug/L ND 5.0 12/06/12 00:34
2,4,6-Tribromophenol(S) .% 77 10-137 12/06/12 00:34
2-Fluorobiphenyl(S) % 67 15-120 12/06/12 00:34
2-Fkwrophenol(S) % 37 10-120 12/06/12 00:34
Nitrobenzene-d5(S) % 66 10-120 12/06/12 00:34
I ( Phenol-d6(S) % 24 10-120 12/08/12 00:34
Terphenyl-d14(S) % 93 11-131 12/06/1200:34
I
LABORATORY CONTROL SAMPLE: 882390
Spike LCS LCS %Rec
Parameter' Units Conc. Result %Rec Limits Qualifiers
I 1,2,4-Trlchlorobenzene ug/L 50 35.5 71 44-142
1,2-Dlohlorobenzene ug/L 50 32.8 68 32-129
1,2-Diphenyihydrazine ug/L 50 38.0 76 25-150
• 1,3-Dichlorobenzene ug/L 50 31.6 63 1-172
1,4 Dichlorobenzene ugh 50 31.8 64 20-124
2,4,6-Trichlorophenol ug/L 50 38.2 76 37-144
2,4-Dichlorophen/ ugh 50 36.5 73 1-191
2,4-Dimethylphenol ug/L 50 36.4 73 32-119
I
2,4-Dlnitrophenol
ugh 250 223 89 1-181
2,4-Dinitrotoluene ug/L 50 37.7 75 39-139
2,6-Dinitrotoiuene ugh 50 35.1 70 50-158
2-Chioronaphthalene ugh 50 38.9 78 60-118
I 2-Chlorophenol ugh 50 32.6 65 23-134
2-Nitrophenol ugiL 50 37.3 75 29-182
38<4-Methylphenol(m&p Cresol) ug/L 50 27.9 56 25-150
3,3'-Dichlorobenzldine ug/L 100 94.5 95 1-262
I 4,6-Dlnitro-2-methylphenol ugh 100 89.4 89 1-181
4-Bromophenylphenyl ether ug/L 50 40.0 80 53-127
4-Chlorophenylphenyl ether ug/L 50 40.8 82 25-158
4-Nitrophenol ughL 250 96.0 38 1-132
l
Acenaphthene
ug/L 50 39.7 79 47-145
f Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 19 of 31
•
This report shad not be reproduced,except In full,
Iwithout the written consent of Pace Analytical Services,Inc..

I
4
• n �y j /e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc. ,
• aceAnalytICal 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Klncey Ave. Suite 100
wn,a,pacelabuom Eden,NC 27288 Asheville,NC 28804 Huntersvile,NC 28078 II
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: EFF PPA 11/29 • I
Pace Project No.: 92140209 •
LABORATORY CONTROL SAMPLE: 882390
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Acenaphthylene ug/L 50 39.1 78 33-145
Anthracene ug/L 50 41.8 84 1-166
Benzidine ug/L 100 25.6J 26 25-150
Benzo(a)anthracene ug/L 50 43.7. 87 33-143
Benzo(a)pyrene ug/L 50 44.1 88 17-163
- ' Benzo(b)fluoranthene ug/L 50 39.7 79 24-159
Benzo(g,h,i)perylene ug/L 50 42.2 84 1-219
Benzo(k)fluoranthene ug/L 50 39.4 79 11-162
bls(2-Chioroethoxy)methane ug/L 50 38.1 76 33-184 •
bls(2-Chloroethyl)ether ug/L 50 37.6 75 12-158
bis(2-Chlorolsopropyl)ether ug/L 50 34.6 69 36-166
bls(2-Ethylhexyl)phthalate ug/L 50 43.5 87 8-158
Butylbenzylphthalate ug/L 50 42.6 85 1-152
Chrysene ug/L 50 40.5 81 17-168
Dl-n-butylphthalate ug/L 50 41.5 83 1-118
Di-n-octylphthalate ug/L 50 44.9 90 4-146
Dibenz(a,h)anthracene ug/L 50 42.6 85 1-227
Diethylphthalate ug/L 50 37.8 76 1-114
DImethylphthalate ug/L 50 37.2 74 1-112 '
Fluoranthene ug/L 50 47.5 95 26-137
Fluorene ug/L 50 40.3 81 59-121
Hexachbro-1,3-butadiene ug/L 50 33.4 67 24-116
Hexachlorobenzene ug/L 50 41.1 82 • 1-152
Hexachlorocyclopentadlene ug/L 50 39.7 79 25-150
Hexachbroethane ug/L 50 31.2 62 40-113
Indeno(1,2,3-cd)pyrene ug/L 50 43.1 86 1-171
Isophorone ug/L 50 31.9 64 21-196
N-Nitroso-dl-n-propylamine ug/L 50 37.7 75 1-230
N-Nitrosodimethylamine ug/L 50 24.1 48 25-150
N-Nitrosodiphenylamine ug/L 50 38.8 78 25-150
Naphthalene ug/L 50 34.7 69 21-133
Nitrobenzene ug/L 50 29.9 60 35-180 '
Pentachlorophenol ug/L 100 85.3 85 14-176
Phenanthrene ug/L 50 39.9 80 54-120
Phenol ug/L 50 17.3 35 5-112
Pyrene ug/L 50 43.8 88 52-115
2,4,6-Tribromophenol(S) % 88 10-137
2-Fluorobiphenyl(S) % 73 15-120 •
2-Fluorophenol(S) % 42 10-120
Nitrobenzene-d5(S) % 72 10-120
Phenol-d6(S) % 29 10-120
Terphenyl-d14(S) % 92 11-131
I
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 20 of 31 ( I
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc.. '
I

1
Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
•
COAnalytfcal a 206 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Eden,NC 27288 Asheville,NC 28804 Hunterovlib,NC 28078
[phone] [phone] [phone]
I ( •
QUALITY CONTROL DATA.
I Project: EFF PPA 11/29
Pace Project No.: 92140209
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 882391 882392 •
MS MSD
92140279009 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units• Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
1,2,4-TrIchlorobenzene ug/L ND 100 100 40.2 47.0 40 47 44-142 16 30 M0,M1
I 1,2-D1chlorobenzene ug/L ND 100 100 37.5 43.7 38 44 32-129 15 30
1,2-Dlphenythydrazine ug1L ND 100 100 52.0 57.8 52 58 25150 10 30
1,3-Dichlorobenzene ug/L ND 100 100 36.9 41.9 37 42 1-172 13. 30 •
1,4-Dichlorobenzene ug/L ND 100 100 36.4 42.2 36 42 20-124 15 30
' 2,4,6-Trichlorophenol
2,4-Dichlorophenol ug/L ND 100 100 34.9 41.0 35 41 37-144 16 30 MO,M1
•
ug/L ND 100 100 • 32.6 39.1 33 39 1-191 18 30 •
2,4-Dimethylphenol ug/L ND 100 100 13.8J 19.5J 14 19 32-119 30 MO,M1.
2,4-Dinitrophenol ug/L . ND 500 500 330 436 66 87 1-181 28 30
I 2,4 Dlnitrotoluene
ug/L ND 100 , 100 62.9 68.4 63 68 39-139 8 30
2,6-Dlnitrotoluene ug/L ND 100. 100 49.5 57.5 50 57 50-158 15 30
•
2-Chloronaphthalene ug/L ND 100 100 42.1 49.2 42 49 60-118 16 30 M0,M1
2-Chlorophenol ug/L ND . 100 . • 100 32.4 38.2 32 38 23-134 16 30
2-Nltrophenol ug/L • ND 100 100 39.5 46.7 40 47 29-182 17 30
3&4-Methylphenol(m&p ug/L ND 100 100 23.0 24.1 23 24 25-150 5 30 M0,M1
Cresol)
3,3'-Dichiorobenzidine ug/L ND 200 200 9.9J 8J 5 4 1-262 30
4,6-Dlnitro-2-methylphenol ug/L ND 200 200 149 189 74 85 1-181 13 30
4-Bromophenylphenyl ether ug/L ND 100 100 58.7 65.0 59 65 53-127 10 30
4-Chlorophenylphenyl ether ug/L ND 100 100 50.9 59.4 51 59 25-158 15 30
4-Nitrophenol ug/L ND 500 500 256 293 51 59 1-132 13 30
Acenaphthene ugh ND 100 100 44.0 50.6 44 51 47-145 14 30 M0,M1
Acenaphthylene ugh ND 100 100 43.7 51.0 44 51 33-145 15 30
Anthracene ugh ND 100 100 89.3 75.9 69 76 1-166 9 30
Benzldlne ug/L ND. 200 200 ND ND 0 0 25-150 30 MO,M1
Benzo(a)anthraoene ug/L ND 100 100 78.2 85.0 78 85 33-143 8 30
I Benzo(a)pyrene ug/L ND 100 100 79.7 84.6 80 85 17-163 6 30
Benzo(b)fluoranthene ug/L ND 100 100 74.6 80.3 75 80 24-159 7. 30
Benzo(g,h,i)perylene ug/L ND 100 100 71.9 75.1 72 75 1-219 4 30
Benzo(k)fluoranthene ug/L ND 100 100 68.7 76.5 69 77 11-162 11 30
I bls(2-Chloroethoxy)methane ug/L ND 100 100 39.3 45.8 39 46 33-184 15 30
bls(2-Chloroethyl)ether' ug/L ND 100 100 39.0 48.1 39 46 12-158 17 30
bis(2-Chlorolsopropyl)ether ug/L ND 100 100 36.8 44.5 37 45 36-1:66 19 30
bis(2-Ethyihexyl)phthalate ug/L ND 100 100 80.2 85.6 80 86 8-158 7 30
I Bulylbenzylphihalate ug/L ND 100 100 78.8 84.3 79 84 1-152 7 30
Chrysene ug/L ND 100 100 74.0 80.1 74 80 17-168 8 30
Dl-n-butylphthalate ug/L ND 100 100 73.4 77.7 73 78 1-118 6 30
DI-n-octylphthalate ug/L ND 100 100 81.6 89.2 82 89 4-146 9 30
Dlbenz(a,h)anthracene
ug/L ND 100 100 73.0 76.5 73 76 1-227 5 30
Dlethylphthalate ug/L ND 100 100 62.2 89.0 62 69 1-114 10 30
Dimethylphthalate ug/L ND 100 100 52.3 59.6 52 60 1-112 13 30
Fluoranthene ug/L ND ' 100 100 82.8 92.1 83 . 92 26-137 11 30
I Fluorene ug/L• ND 100 100 52.9 61.0 b3 61 59-121 14 •30 MO,M1
Hexachloro-1,3-buiadlene
ug/L ND 100 100 38.2 .43.7 38 44 24-116 13 . 30
Hexachlorobenzene ug/L ND 100 100 62.4 67.8 62 68 1-152 8 • 30
Hexachiorocyclopentadiene ug/L ND 100 100 42.6 .55.4 43 55 25-150 26 30
I Hexachloroethane ug/L ND 100 100 35.6 40.7 36• 41 40-113 13 30 MO,M1
Date:12117/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 21 of 31
This report ahaN not be reproduced,except In full,
Iwithout the written consent of Pace Analytical Services,Inc..
I

I
s Pace Analytical 8ervlces,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc. •
• ace I 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Klncey Ave. Sults 100 •
Eden,NC 27288 Asheville,NC 28804 Huntetsvitle,NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
1
Project: EFF PPA 11/29 • I Pace Project No.: 92140209
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 882391 882392 •
MS MSD
92140279009 Spike Spike MS MSD MS MSD %Rec Max
Parameter . Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Indeno(1,2,3-cd)pyrene ug/L ND 100 100 74.2 78.4 74 78 1-171 5 30
Isophorone ug/L ND 100 100 33.0 37.9 33 38 21-196 14 30
N-Nitroso-dl-n-propylamine ug/L ND 100 100 39.0 46.6 39 47 1-230 18 30
N-Nitrosodimethylamine ug/L ND 100 100 33.3 40.2 33 40 25-150 19 30
N-Nitrosodiphenylamine ug/L ND 100 100 32.2 30.0 32 30 25-150 7 30
Naphthalene ug/L ND 100 100 39.6 45.9 40 46 21-133 15 30
Nitrobenzene ug/L ND 100 100 32.3 37.2 32 37 35-180 14 30 MO,M1
Pentachlorophenol ugh ND . 200 200 142 159 71 79 14-176 11 30
Phenanthrene • ug/L ND 100 100 67.5 73.3 67 73 54-120 8 30
• Phenol ugh ND 100 100 20.4 18.5 20 18 5-112 10 30
I
• Pyrene ug/L ND 100 100 83.6 86.3 84 86 52-115 3 30
2,4,6-Trlbromophenol(S) % 48 57 10-137
2-Fiuorobiphenyl(S) % 38 44 15-120
2-Fluorophenol(S) % 23 24 10-120
Nitrobenzene-d5(S) % 38 44 10-120
Phenol-d6(S) % 19 17 10-120
Terphenyl-d14(S) % 87 86 11-131
I
1
I
I
I
I
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 22 of 31 ( 1
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..
I

I
•
e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
I .
• aceAnalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 KinceyAve. Suite 100
WaMRpgom Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
[phone] [phone] [phone]
1l .
QUALITY CONTROL DATA .
Project: EFF PPA 11/29
Pace Project No.: 92140209 •
QC Batch: WET/23316 ' Analysis Method: SM 2640C •
I
QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92140209001
METHOD BLANK: 882051 Matrix: Water
II Associated Lab Samples: 92140209001 •
Blank Reporting
Parameter Units Result Limit • Analyzed Qualifiers
ITotal Dissolved Solids mg/L ND 25.0 11/30/12 20:22
LABORATORY CONTROL SAMPLE: 882052 .
Spike LCS LCS %Rec
. Parameter Units Conc. Result %Rec Limits Qualifiers
•
Total Dissolved Solids mg/L . 250 244 98 80-120
SAMPLE DUPLICATE: 882053 ,
92139754001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
1 Total Dissolved Solids mg/L 96.0 111 14 20
I
I
•
I '
I •
•
I
•
1 .
I •
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 23 of 31
This report shall not be reproduced,except In full,
Iwithout the written consent of Pace Analytical Services,Inc..
I

I
s Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,inc. .
aCEAnalytical 205 East Meadow Road-Suite A 2226 Riverside Dr. 9800 MnceyAve. Suite 100 .
wwwpiatabuvmEden,NC 27288 Asheville,NC 28804 HuntersviNe,NC 28078
[phone] [phone] [phone]
I. 1
QUALITY CONTROL DATA
Project: EFF PPA 11/29
I
. Pace Project No.: 92140209
QC Batch: WETA/13992 Analysis Method: EPA 353.2 '
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate+Nitrite,preserved I Associated Lab Samples: 92140209001
METHOD BLANK: 889376 Matrix: Water
Associated Lab Samples: 92140209001 I
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,NO2 plus NO3 mg/L ND 0.020 12/12/12 21:30
LABORATORY CONTROL SAMPLE: 889377 .
Spike LCS LCS %Rec I
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 2.5 2.5 98 90-110
MATRIX SPIKE SAMPLE: 889378 • 11
92140209001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 5.8 2.5 8.0 85 90-110 M1
MATRIX SPIKE SAMPLE: 889380
92140210001 Spike MS MS %Rec
3
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 0.029 2.5 2.5 97 90-110
SAMPLE DUPLICATE: 889379 3
92140209001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Nitrogen,NO2 plus NO3 mg/L 5.8 5.8 0 20
3
SAMPLE DUPLICATE: 889381
92140210001 Dup Max
3
Parameter Units Result Result RPD RPD Qualifiers
Nitrogen,NO2 plus NO3 mg/L 0.029 0.034 13 20
I
3
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 26 of 31
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..
I

•
o Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
I , 2c. eAnal,ytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
[phone] [phone] [phone]
/
QUALITY CONTROL DATA
Project: EFF PPA 11/29
Pace Project No.: 92140209
•
QC Batch: WETA/13957 Analysis Method: EPA 365.1
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus,Total
Associated Lab Samples: 92140209001
METHOD BLANK: 887004 • Matrix: Water
I Associated Lab Samples: 92140209001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 12/10/12 13:59
• LABORATORY CONTROL SAMPLE: 887005 . '
Spike LCS LCS %Rec
Parameter ' Units Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.6 102 90-110
I MATRIX SPIKE SAMPLE: 887006
92140761001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 2.8 2.5 4.9 88 90-110 M1
MATRIX SPIKE SAMPLE: 887008
I
92140151002 Spike MS MS %Rec
Parameter Units Result Conc. Result
%Rec Limits Qualifiers
Phosphorus • mg/L 0.40 2.5 2.8 96 90-110
ISAMPLE DUPLICATE: 887007
92140628003 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Phosphorus mg/L 1.4 1.4 1 20
' SAMPLE DUPLICATE: 887009
92140162001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Phosphorus mg/L " 0.26 0.28 2 20
I •
•
I '
I { Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 27 of 31
I This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..
•
I

I
ne
/��, / Pace Analytical Services,inc. Pace Analytical Services,Inc. Pace Analytical Services,inc. I
ace naI kaI 206 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 ,
rhlMtpeceiebagom Eden,NC 27288 Asheville,NC 28804 Huntersvllle,NC 28078
[phone] [phone] [phone]
1
• QUALITY CONTROL DATA •
•
Project: EFF PPA 11/29 '
• Pace Project No.: 92140209
QC Batch: .WETA/13906 Analysis Method: EPA 420.4
QC Batch Method: EPA420.4 Analysts Description: 420.4 Phenolics
•
Associated Lab Samples: 92140209001
METHOD BLANK: 883.142 Matrix: Water
Associated Lab Samples: 92140209001
Blank Reporting
Parameter Units • Result Limit Analyzed Qualifiers
Phenol mg/L ND 0.0050 12/07/1211:16 •
LABORATORY CONTROL SAMPLE: 883143 •
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Phenol mg/L .05 0.047 94 90-110
MATRIX SPIKE SAMPLE: 883144 a
92139396002 • Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Phenol mg/L 0.0087 .05 0.072 ' 126 90-110 M1
3
MATRIX SPIKE SAMPLE: 883146
92139991001 Spike MS MS %Rec a
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Phenol mg/L 0.014 .05 0.067 106 90-110
SAMPLE DUPLICATE: 883145 3
92139724003 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Phenol mg/L 0.038 0.039 2 203
SAMPLE DUPLICATE: 883147
92140169001 Dup Max3
Parameter Units Result Result RPD RPD Qualifiers
Phenol mg/L 0.012 0.014 19 20
•
II
3
3
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 28 of 31 I.
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..
I

I 'II ' .
�y,,Vicar
Pace Analytical Services,Inc. Pace Analytical Services,Inc. PaceAnalytical Services,Inc.
aC@Ana205 East Meadow Road-Suite A 2225 Riverside Dr. 98001ancey Ave. Sidle 100
•
Eden,NC 27288 Asheville,NC 28804 Hunteravllle,NC 28078
[phone] [phone] [phone]
I (
.
QUALITY CONTROL DATA .
•
I Project: EFF PPA 11/29
Pace Project No.: 92140209
QC Batch: WETA/13959 Analysis Method: SM 4500-CN-E
I QC Batch Method: SM 4500-CN-E •
Analysis Description: 4500CNE Cyanide,Total
Associated Lab Samples: 92140209001
METHOD BLANK: 887263 Matrix: Water
I Associated Lab Samples: 92140209001
' Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Cyanide mg/L ND 0.0050 12/11/12 09:45
LABORATORY CONTROL SAMPLE: 887264'
Spike LCS LCS %Rec
I Parameter Units Conc. Result %Rec Limits' Qualifiers
Cyanide mg/L .1 0.11 112 80-120
•
I MATRIX SPIKE SAMPLE: • 887265
92139833004 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Cyanide mg/L ND .1 0.094 91 75-125
f
SAMPLE DUPLICATE: 887266
I 92140016002 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Cyanide mg/L ND ND 20 '
I
1
I
I
111 ( Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 29 of 31
This report shall not be reproduced,except In full,
Iwithout the written consent of Pace Analytical Services,Inc..
I

I
• Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
aceAnalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Idncey Ave. Suite 100
yatwn Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
[phone] [phone] [phone]
QUALIFIERS
•
Project: EFF PPA 11/29
Pace Project No.: 92140209
•
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to changes in sample preparation,dilution of
the sample aliquot,or moisture content.
ND-Not Detected at or above adjusted reporting limit.
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PRL-Pace Reporting Limit. •
RL-Reporting Limit.
S-Surrogate •
1,2-Diphenyihydrazine(8270 listed analyte)decomposes to Azobenzene.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values. •
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-indicates the compound was analyzed for,but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte Is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether,Styrene,and Vinyl chloride.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services-Asheville
PASI-C Pace Analytical Services-Charlotte
ANALYTE QUALIFIERS
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
P5 The EPA or method required sample preservation degrades this compound,therefore acceptable recoveries may not be
achieved in sample matrix spikes.
1
I
Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 30 of 31
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..

f
.. ..
A
• Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
aceAnaly ical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave: Suite 100
wiespacelabscom
Eden,NC 27288 Asheville,NC 28804 Huntersvllie,NC 28078
[phone] [phone] [phone]
Ii
QUALITY CONTROL DATA CROSS REFERENCE TABLE
I Project EFF PPA 11/29
Pace Project No.: 92140209
Analytical
I Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92140209001 PE EPA 1664A GCSV/13505
92140209001 PE EPA 200.7 MPRP/12087 EPA 200.7 ICP/11052
I 92140209001 PE EPA 1631E MERP/4758 EPA 1631E MERC/4648
92140209002 FIELD BLANK EFF EPA 1631E
MERP/4758 EPA 1631E MERC14648
92140209001 PE EPA 625 0EX1/19941 EPA 625 MSSV/7067
I 92140209001 PE EPA 624 MSV/21331
92140209001 PE SM 2540C WET/23316
92140209001 PE • EPA 350.1 WETA/13933
1 92140209001 PE EPA 351.2 WETA/13951
92140209001 PE EPA 353.2 WETA/13992
92140209001 PE EPA365.1 WETA/13957
1 92140209001 PE EPA420.4 WETA/13906
92140209001 PE SM 4500-CN-E WETA/13959
111 i
I
I .
I
I
1
I
II Date:12/17/2012 02:53 PM REPORT OF LABORATORY ANALYSIS Page 31 of 31
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..
I

CHAIN-OF-CUSTODY/Analytical Request Document
ae Analytical• The Chain-of-Custody is a LEGAL DOCUMENT.All relevant ftelds must be completed accurately.
www.DacelaBs.com
Section A Section B Section C Page of /
Required Client Information: ' Required Project Information: invoice Information.
1613424
Company"14 S\ Report To: 1� 1-A,
Menton:
Address: n Copy To: �!.
?- /I, 1 `J2 Company Name: �jf } R #trf "' 4> F °;5'.
Address:
( r r F NPDES •r GROUND WATER .r DRINKING WATER
Email To: Purchase Order No.: Pan Quote - •
r. UST r RCRA [; OTHER
Phone: Fac Project Name e /t Pace Plea ,,,a.,;r. _
FLG r Iy
Manager Sta at Geon 1:*sG1"; `.ri 9�.�'x �:
Requested Due Data/TAT: .. Project Number. Pam PrtYli a �: ,#^ 'r•�-'�. 1 % � y' .it -ii
-*iife.ed'r�1os??(9' ..,s(!!`/.'.�.ti_'` a .�'Eti` tr a' 51�.�". al,
Section D 'K � .!1 s3.�?tw'Yaa }i-A
Matrix Codes ' goir z4+•ra:,.}
Required Client Information MATRIX/C UW s COLLECTED Preservatives .• � 4 : � 4 �
Drinks Water OW t0i 4r:. �'�vsYK.:x�T?
Water WI U COMPOSITECOMPOSITE
Waste Water W W
Product P s mSTART t7acaia v
SAMPLE ID oil oL o v
vett
(A-Z.0-9/,) Wipe WP w 2 < \� z
AR -:
• Sample IDs MUST BE UNIQUE Tissue TS O a tu Fa— ' �` ct
Other OT U P , r Z SiZ al \ 1 ' `� V .
x U H O e �' .T IT
eZ.fit " o t�
M a' a- .u. 2 O -Z n ?a; I, 1 .l J y 1 1
o =�z " ° {mL �a�411 '2_i • to y 0
DATE TIME DATE- TIME m ak m Z S Z Z Z m O `-
_ Pace Project NoJ Lab W.
C Geri_✓..7 l(•,.� /6 o o t'P tI' > t 13 "41 t K t-•1c f X '' r K o041.-00 I
r10 I �J„..1"I O.+ OoZ,
:: pQ.
4
ot
1
i .e+c, ..4
7CE
.0yW s< r ze�.il w�, ;.a.•TS.D �. r*R •-W5E TI \ " ,r,�_"pBIEFIIIA�O� �� s � , � SAMPLE CONDTONS
' - . Ij—L- f' `I L` e.. ,ti 1 }4. 7.0
Er22:.4fi
l�N. 6/.- i/ Y`f=!J-. AL/ 1,4 el. (L.:a 5 3f1. 7' --\---c Y
•
? fe Gb1A7 Yes€ �.'°"1..s,K• T:*e :. ...
ORIGINAL PRR1T Name of SAMPLER: y $U Z_ h Z_
,/� a
SIGNATURE of SAM /PLER: 2 L N n /�ir DATE Signed. `/ 11 m ` _ e, ,—m, E
'Importer'.'-le:By signing gds form you are accepting Pace's NET,30 day payment Tarns and agreeing to late charges 0115%per month for• W.not days.•, (M WDDNY): / - d•y'/� ~ d' h cu
F-AL.L-Q-020rev.07,15 007
111111 11111I 11111 M NM 111111 — w r MI — MN 11111 11111 r — — — —

i
Document Name:Sample Condition Upon Document Revised:May 30,2012 1
aceAnal ical� Receipt(SCUR) Page 1 of 2
- •P■o'+e rom • Document No.:" Issuing Authorities: j
F-ASV-CS-003=rev.08 Pace Asheville Quality Office
Client Name: /�15� Project# �/:� /inzo cc
Where Received: 0 .Huntersvllle sheville 0 Eden . • 0 Raleigh • •
Courier(Circle): Fed Ex UPS USPS Client Commercial ace Other r
Custody Seal on Cooler/Box Present 0 yes a no Seals Intact 0 yes 0Jno Ia+I 1 t11 ,�� ` =
X1.1:.
Packing Material: fl Bubble Wrap o Bubble Bags'None Other l •
Circle Thermometer Used:�tio3 s Type of ice' W t Blue None 12-Samples on Ice,cooling process has begun
IR Gun Back Up-111585135
•
• Temp Correction Factor: Add/ trot p. / C I
Corrected Cooler Temp.: 3.1 C Biological Tissue is Frozen: Yes No N/A • Date and.lnitlals o Pers rl"ex mining
Temp should be above freezing to 6'C Comments: contents: �f,+� 7
Chain of Custody Present: pill; ❑No ON/A 1. �,
Chain of Custody Filled Out: �les ONo ON/A 2.
Chain of Custody Relinquished: . es ONo ON/A 3.
Sampler Name&Signature on COC: res DNo ON/A 4.
Samples Arrived within Hold Time: . ,es ONo ON/A 5.
Short Hold Time Analysis(<72hr): ❑Yesio ON/A 6. .
Rush Turn Around Time Requested: Oyes ido ON/A 7. - '
Sufficient Volume: esONo ON/A 8. " ' •
Correct Containers Used: ,e es ONo ON/A 9:
-Pace Containers Used: • zerYes ONo ON/A '
Containers Intact: �es ONo ON/A 10. . '
Filtered volume received for Dissolved tests )es.ONo ON/A 11.
Sample Labels match COC: ' des ONo ON/A 12. V _
-Includes date/time/ID/Analysis. Matrix: L"
All containers needing preservation have been checked.
/Dyes ❑No ❑WA 13.
All containers needing preservation are found to be In .
V ! I
compliance with EPA recommendation. Yes ❑No ❑NIA�+�'e. I
I
�)
ex
ceptions:�collform,70G,S,0�8;W I-DRO(water) i Yes ONo Initial when completed • l !
Samples checked for dechlorination: , ONo ON/A 14.
Headspace in VOA Vials(>6mm): .OFes "ONo ON/A 15: _
Trip Blank Present: Dees ❑NoN/A 16.
ITrip Blank Custody Seals Present ❑Yes ONo 8 A •
Pace Trip Blank Lot#(if purchased):
Client Notification/Resolution: Field Data Required? Y / N
I
•
Person Contacted: Date/Time: • V .
Comments/Resolution: '
•
1
.SCURF Review:^ (Date: (i D SRF Review:I tpep 'Date: Il q
Note: Whenever there is a discrepancy affecting North Carolina compliance samples,a copy of this form will be sent to the North Carolina DEHNR
Certification Office(I.e out of hold,Incorrect preservative,out of temp,incorrect containers) I
— 1

I
Q I7 �+ l® Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
I accAnafytica 205 East Meadow Road-SuiteA 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
s.corn Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
y wwwpacelab [phone] [phone] [phone]
II I
IMarch 08, 2013
' r. Wayne
MTipton
Metropolitan Sewerage District
2028 Riverside Drive
Asheville, NC 28804
I
RE: Project: PE PPA 2/7
IPace Project No.: 92147363
Dear Mr. Tipton:
Enclosed are the analytical results for sample(s) received by the laboratory on February 07, 2013.
I The results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual, where applicable, unless
otherwise noted in the body of the report. .
I ,
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
Ipage for analysis unless otherwise footnoted.
Revised Report. TKN re-analyzed and data was revised. There was an unknown error in the first
ITKN analysis.
If you have any questions concerning this report, please feel free to contact me.
ISincerely,
-..._.
Lorri Patton
[e-mail]
Project Manager
IEnclosures
I ! a REPORT OF LABORATORY ANALYSIS Page 1 of 29
x.111 This report shall not be reproduced,except In full,
I
without the written consent of Pace Analytcal Services,Inc..
I

1
Pace Analytical Services,inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
aceAnalytical 205 East Meadow Road-SuiteA 2226 Riverside Dr. 9800 Klncey Ave. Suite 100
e wpece>sbacom Eden,NC 27288 Asheville,NC 28804 Huntersvilte,NC.41078
[phone] [phone] [phone]
CERTIFICATIONS
Project: PE PPA 2/7
Pace Project No.: 92147363
Charlotte Certification IDs
9800 KlnceyAve.Ste 100,Huntersvllle,NC 28078 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 West Virginia Certification#:357
North Carolina Wastewater Certification#:12 VlrginiaNELAP Certification#:460221
South Carolina Certification#:99006001
Asheville Certification IDs
2225 Riverside Dr.,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001
Massachusetts Certification#:M-NC030 West Virginia Certification#:356
North Carolina Drinking Water Certification#:37712 VirginiaNELAP Certification#:460222
I
1
( 1
1
I
1
1
i
REPORT OF LABORATORY ANALYSIS Page 2 of 29 (
This report shaU not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..
1

aceAnmlytical
® 2 5Pa East Meadow Ro dce Analytical l-Suite A Inc. Pace Analyt225 Riverside Dr.Services,Inc. Pace9800 Kincey Ave. Suite 100
I
Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
[phone] [phone] [phone]
SAMPLE SUMMARY
Project: PE PPA 2/7
' Pace Project No.: 92147363
Lab ID Sample ID Matrix Date Collected Date Received
' 92147383001 PE PPA GRAB
92147383002 PE PPA COMP Water 02/07/13 09:45 02/07/13 10:20
Water 02/07/13 09:20 02/07/13 10:20
1
1
1
(
1
1
1
i
1 I, REPORT OF LABORATORY ANALYSIS Page 3 of 29
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..
1 /

1
e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Serviced Inc:
aceAnalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 I
Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078 .,
xww.pacelabs.can
[phone] [phone] [phone]
SAMPLE ANALYTE COUNT
Project: PE PPA 2/7
Pace Project No.: 92147383
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
I
92147363001 PE PPA GRAB EPA 16648 CLW 1 PASI-C
EPA 625 RES 63 PASI-C
EPA 624 CAH 33 PAST-C
EPA 420.4 SAE 1 PAST-A
SM 4500-CN-E JDA 1 PASI-A
92147363002 PE PPA COMP EPA 200.7 JDA 15 PAST-A
SM 2540C JTM 1 PASI-A
EPA 350.1 SAE 1 PASI-A
EPA351.2 JDA 1 PASI-A
EPA 353.2 DMN 1 PASI-A
EPA 365.1 JDA 1 PASI-A !
I
1
I
I
i
I
I
REPORT OF LABORATORY ANALYSIS Page 4 of 29 ( l
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..
I

I
• Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
aceQnalyfical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Eden,NC 27288 Ashevlie,NC 28804 Huntersvile,NC 28078
[phone] [phone] [phone]
I (
ANALYTICAL RESULTS
I Project PE PPA 2/7
Pace Project No.: 92147363
Sample: PE PPA GRAB Lab ID: 92147363001 Collected: 02/07/13 09:45 Received: 02/07/13 10:20 Matrix:Water
Report Reg.
I
Parameters Results Units Limit Limit OF Prepared Analyzed CAS No. Qual
HEM,011 and Grease Analytical Method:EPA 1664B
I Oil and Grease ND mg/L 5.0 1
Analytical02/11/1312:17
625 MSSV Method:EPA 625 Preparation Method:EPA 625
Acenaphthene ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 83-32-9
I
Acenaphthylene ND ugh
ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 208-96-8
Anthracene 5 2 1 02/12/1310:15 02/13/13 00:20 120-12-7
Benzidine ND ug/L 51.5 1 02/12/1310:15 02/13/13 00:20 92-87-5
Benzo(a)anthracene ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 56-55-3
I Benzo(a)pyrene ND ug/L 1 02/12/13 10:15 02/13/13 00:20 50-32-8
Benzo(b)fluoranthene ND ug/L 5.2 1 02/12/1310:15 02/13/13 00:20 205.99-2
Benzo(g,h,l)perylene ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 191-24-2
Benzo(k)fluoranthene ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 207-08-9
I
4 Bromophenylphenyl ether ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 101-55-3
Butylbenzylphthalate ND ug/L 6.2 1 02/12/13 10:15 02/13/13 00:20 85-68-7
bis(2-Chbroethoxy)methane ND ug/L 10.3 1 02/12/13 10:15 02/13/13 00:20 111-91-1
bis(2-Chloroethyl)ether ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 111-44-4
bls(2-Chlorolsopropyl)ether ND ug/L 5.2 1 02/12/1310:16 02/13/13 00:20 108-80-1
2-Chloronaphthalene ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 91-58-7
2-Chlorophenol ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 95-57-8
4-Chlorophenylphenyl ether ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 7005-72-3
I
Chrysene ND ug/L 5.2 1 02/12/1310:15 02/13/13 00:20 218-01-9
Olbenz(a,h)anthracene ND ug/L 5.2 1 02/1211310:15 02!13/13 00:20 53-70-3
1,2-Dichlorobenzene ND ug/L 5.2 1 02/12/1310:15 02/13/13 00:20 95-50-1
1,3-Dichlorobenzene ND ug/L 5.2 1 02/1211310:15 02/13/13 00:20 541-73-1
1,4-Dichlorobenzene ND ug/L 5.2 1 02/12/1310:15 02/13/13 00:20 106-46-7
3,3'-Dichbrobenzldine ND ug/L 25.8 1 02/12/13 10:15 02/13/13 00:20 91-94-1
2,4-Dichlorophenol ND ug/L 6.2 1 02/12/13 10:15 02/13/13 00:20 120-83-2
Diethylphthalate ND ug/L 5.2 1 02/12/13 10:16 02/13/13 00:20 84-66-2
2,4-Dimethylphenol ND ug/L 10.3 1 02/12/13 10:16 02/13/13 00:20 105-67-9
I Dimethylphthalate ND ug/L 5.2 1 02/12/13 10:15 02/13/1300:20 131-11-3
Dl-n butylphthelate ND ug/L 5.2 1 02/12/1310:15 02/13/13 00:20 84-74-2
4,6-Dlnitro-2-methylphenol ND ug/L 20.6 1 02/12/1310:15 02/13/13 00:20 534-52-1
2,4-Dinitrophenol ND ug/L 51.5 1 02/12/13 10:15 02/13/13 00:20 51-28-5
I 2,4-Dinitrotoluene ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 121-14-2
2,6-Dinitrotoluene ND ug/L 5.2 1 02/12/1310:15 02/13/13 00:20 606-20-2
Dl-n-octylphthalate ND ug/L 5.2 1 02/12/1310:15 02/13/13 00:20 117-84-0
1,2-Diphenylhydrazine ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 122-66-7
bis(2-Ethylhexyl)phthalate ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 117-81-7
Fluoranthene ND ug/L 5.2 1 02/12/1310:15 02/13/13 00:20 208-44-0
Fluorene ND ug/L 5.2 1 02!12/1310:15 02/13/13 00:20 86-73-7
Hexachloro-1,3-butadiene ND ug/L 5.2 1 02/12/1310:15 02/13/1300:20 87-68-3
I Hexachlorobenzene ND ug/L 5.2 1 02/12/1310:15 02/13/13 00:20 118-74-1
HexacMoracyclopentadiene ND ug/L 10.3 1 02112/1310:16 02/1311300:20 77-47-4
Hexachloroethane ND ug/L 5.2 1 02/12/1310:15 02/13/13 00:20 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 5.2 1 02/12/13 10:15 02/13/13 00:20 193-39-5
Isophorone ND ug/L 10.3 - 1 02/12/1310:15 02/13/13 00:20 78-59-1
I ( Jate:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 5 of 29
This report shall not be reproduced,except In full,
Iwithout the written consent of Pace Analytical Services,Inc..
I

I
e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc:
aceAnalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Klncey Ave. Suite 100
vAwepeseleks.com Eden,NC 27288 Asheville,NC 28804 Huntersvi8e,NC 28078 5
[phone] [phone] [phone]
ANALYTICAL RESULTS •
( II
Project: PE PPA 217 I Pace Project No.: 92147363
Sample: PE PPA GRAB Lab ID: 92147363001 Collected: 02/07/13 09:45 Received: 02/07/13 10:20 Matrix:Water
Report Reg.
I
Parameters Results Units Limit Limit DF Prepared Analyzed CAS No. Qual
626 MSSV Analytical Method:EPA625 Preparation Method:EPA625
3&4-Methylphenol(m&p Cresol) ND ug/L 10.3 1 02/12/13 10:15 02/13/13 00:20 I Naphthalene ND ug/L 5.2 1 02/12/13 10:15 02/13/1300:20 91-20-3
Nitrobenzene ND ug/L 52 1 02/12/1310:15 02/13/13 00:20 98-95-3
2-Nltrophenol ND ugh 6.2 1 02112/1310:15 02/13/13 00:20 88-75-5
4-Nltrophenol ND ug/L 51.5 1 02/12/1310:15 02/13/13 00:20 100-02-7
N-Nitrosodimethylamine ND ug/L 6.2 1 02/12/13 10:15 02/13/13 00:20 82-75-9
N-Nitroso-di-n-propylamine ND ug/L 6.2 1 02/12/13 10:15 02/13/13 00:20 821-64-7
N-Nltrosodiphenylamine ND ugh 10.3 1 02/12/1310:15 02/13/13 00:20 86-30-6
Pentachlorophenol ND ug/L 25.8 1 02112/1310:15 02/13/13 00:20 87-86-5
Phenanthrene ND ugh 5.2 1 02/12/13 10:15 02/13/13 00:20 85-01-8
Phenol ND ugh 5.2 1 02/12/1310:15 02/13/13 00:20 108-95-2
Pyrene ND ug/L 52 1 02/12/1310:15 02/13/13 00:20 129-00-0
1,2,4-Trichlorobenzene ND ug/L 6.2 1 02/12/13 10:15 02/13/1300:20 120-82-1
2,4,6-Trichlorophenol ND ugh 10.3 1 02/12/1310:15 02/13/13 00:20 88-08-2
Surrogates
Nitrobenzene-d5(S) 49 % 10-120 1 02/12/1310:15 02/13/13 00:20 4165-60-0
2-Fluoroblphenyl(S) 60% 15-120 1 02/12/1310:15 02/13/13 00:20 321-60-8
Terphenyl-d14(S) 52 % 11-131 1 02/12/13 10:15 02/13/13 00:20 1718-51-0 f
Phenol-d6(S) 17 % 10-120 1 02/12/13 10:15 02/13/13 00:20 13127-88-3
2-Fluorophenol(S) 26 % 10-120 1 02/12/1310:15 02/13/13 00:20 367-12-4
2,4,6-Tribromophenol(S) 68% 10-137 1 02/12/1310:15 02/13/13 00:20 118-79-6
624 Volatile Organics Analytical Method:EPA 624
Acrolein ND ug/L 100 1 02/16/1315:07 107-02-8
Acrylonitrile ND ug/L 50.0 1 02/16/1315:07 107-13-1
Benzene ND ug/L 5.0 1 02/16/1315:07 71-43-2
3
Bromodichloromethane ND ug/L 5.0 1 02/16/13 15:07 75-27-4
Bromoform ND ug/L 5.0 1 02/16/13 15:07 75-25-2
Bromomethane ND ug/L 10.0 1 02/16/13 15:07 74-83-9
Carbon tetrachloride ND ug/L 5.0 1 02/16/1316:07 56-23-5
Chlorobenzene ND ug/L 5.0 1 02/16/1316:07 108-90-7
Chloroethane ND ug/L 10.0 1 02/16/13 15:07 75-00-3
2-Chioroethylvinyl ether ND ug/L 10.0 1 02/16/1315:07 110-76-8
Chloroform ND ug/L 5.0 1 02/16/1315:07 67-66-3
Chloromethane ND ug/L 5.0 1 02/16/1315:07 74-87-3 II
DIbromochloromethane ND ug/L 5.0 1 02/16/1315:07 124-48-1
1,1-Dichloroethane ND ug/L 5.0 1 02/16/1315:07 76-34-3
1,2-Dichioroethane ND ug/L 5.0 1 02/16/1315:07 107-06-2
1,1-Dichloroethene ND ug/L 5.0 1 02/18/1315:07 75-35-4
trans-1,2-Dichioroethene ND ug/L 5.0 1 02/16/1315:07 156-60-5 3
1,2-DIchtoropropane ND ug/L 6.0 1 02/18/1315:07 78-87-5
cls-1,3-Dlchloropropene ND ug/L 6.0 1 02/16/13 15:07 10061-01-5
trans-1,3-Dichloropropene ND ugh 5.0 1 02/16/1315:07 10061-02-6
Ethyibenzene ND ug/L 6.0 1 02/18/1315:07 100-41-4 11
Methylene Chloride ND ug/L 6.0 1 02/16/1315:07 75-09-2
1,1,2,2-Tetrachloroethane ND ug/L 5.0 1 02/16/13 15:07 79-34-5
Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS . Page 6 of 29 I 3
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..

1
Pace Analytical Services,inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
aACla� ical 205 East Meadow Road-Suite A 2226 Riverside Dr. 9800 Kincey Ave. Suite 100
Eden,NC 27288 Asheville,NC 28804 Ituntersville,NC 28078
com
[phone] [phone] [phone]
1 ANALYTICAL RESULTS
I Project: PE PPA 2/7
Pace Project No.: 92147363
Sample: PE PPA GRAB Lab ID: 92147363001 Collected: 02/07/13 09:45 Received: 02/07/1310:20 Matrix:Water
I
Report Reg.
Parameters Results Units Limit Limit DF Prepared • Analyzed CAS No. Qual
624 Volatile Organics Analytical Method:EPA 624
I
Tetrachloroethane ND ug/L 5.0 1 02/16/13 15:07 127-18-4
Toluene ND ug/L 5.0 1
02/16/13 15:07 108-88-3
1,1,1-Trichloroethane ND ugh 5.0 1 02/16/1315:07 71-55-6
1,1,2-Trichloroethane ND ug/L 5.0 1 02/16/13 15:07 79-00-5
I Trichloroethene ND ug/L 5.0 1 02/16/13 15:07 79-01-6
Vinyl chloride ND ug/L 5.0 1 02/16/1316:07 75-01-4
Surrogates
Dibromofluoromethane(S) 94% 70-130 1 02/16/13 15:07 1868-53-7
4-Bromofluorobenzene(S) 93% 70-130 1 02/16/13 15:07 460-00-4
I
Toluene d8(S)
1,2-Dlchloroethane d4(S) 100% 70-130 1 02/18/13 15:07 2037-26-5
99% 70-130 1 02/16/13 15:07 17060-07-0
420.4 Phenolics,Total Analytical Method:EPA420.4
IPhenol 0.013 mg/L 0.0050 1 02/13/13 13:14 108-95-2 M1
4500CNE Cyanide,Total Analytical Method:SM 4500-CN-E
Cyanide ND mg/L 0.0050 1 02/15/13 14:18 57-12-5
I
I
I
I
II: Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 7 of 29
This report shall not be reproduced,except in full,
I
without the written consent of Pace Analytical Services,Inc..

Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc:
aceAnalytical 0 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Klncey Ave. Suite 100
I Eden,NC 27288 Asheville,NC 28804 HuntersvNle,NC 28078
[phone] [phone] [phone]
I 1 ANALYTICAL RESULTS
Project: PE PPA217
I
Pace Project No.: 92147363
Sample: PE PPA COMP Lab ID: 92147363002 Collected: 02/07/13 09:20 Rec elved: 02/07/13 10:20 Matrix:Water
Report Reg.
I
Parameters Results Units Limit Limit DF Prepared Analyzed CAS No. Qual
200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7
Antimony ND ug/L 5.0 1 02/09/1300:00 02/15/13 19:01 7440-36-0 I Arsenic ND ug/L 10.0 1 02/09/13 00:00 02/15/13 19:01 7440-38-2
Beryllium ND ug/L 1.0 1 02/09/13 00:00 02/15/1319:01 7440-41-7
Cadmium ND ug/L 1.0 1 02/09/13 00:00 02/15/13 19:01 7440-43-9
Calcium 10700 ug/L 100 1 02/09/13 00:00 02/15/1319:01 7440-70-2
I
Chromium ND ug/L 5.0 1 02/09/13 00:00 02/15/1319:01 7440-47-3
Copper 13.6 ug/L 5.0 1 02/09/13 00:00 02/15/13 19:01 7440-50-8
Lead ND ug/L 5,0 1 02/09/13 00:00 02/15/13 19:01 7439-92-1
Magnesium 3640 ug/L 100 1 02/09/13 00:00 02/15/1319:01 7439-95-4 I Nickel ND ug/L 5.0 1 02/09/13 00:00 02/15/1319:01 7440-02-0
Selenium ND ug/L 10.0 1 02/09/13 00:00 02/16/1315:52 7782-49-2
Silver ND ug/L 5.0 1 02/09/13 00:00 02/15/13 19:01 7440-22-4
Thallium ND ug/L 10.0 1 02/09/13 00:00 02/16/13 15:52 7440-28-0
Total Hardness 41800 ug/L 682 1 02/09/13 00:00 02/15/1319:01 I
Zinc 67.1 ug/L 10.0 1 02/09/13 00:00 02/15/13 19:01 7440-66-6
2540C Total Dissolved Solids Analytical Method:SM 2540C
Total Dissolved Solids 223 mg/L 25.0 1 02/08/13 14:50 (
I
Analytical Method:40CFR PART 432.2
Total Nitrogen 19.6 mg/L 1 02/21/13 10:16 I 360.1 Ammonia Analytical Method:EPA 350.1
Nitrogen,Ammonia 13.3 mg/L 0.50 5 02/13/13 02:36 7664-41-7
351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2 t
Nitrogen,Kjeldahl,Total 15.8 mg/L 0.50 1 02/17/1314:21 7727-37-9
•
353.2 Nitrogen,NO21NO3 pros. Analytical Method:EPA 353.2
Nitrogen,NO2 plus NO3 3.8 mg/L 0.020 1 03/07/1314:21 0
366.1 Phosphorus,Total Analytical Method:EPA 365.1
Phosphorus 2.3 mg/L 0.050 1 02/16/1310:41 7723-14-0
I
•
I
aDate:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 8 of 29
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..
3
II

1
e P205ace Analytical Services,Inc.East Meadow Road-Suite A Pace Analytical
Riverside Dr. Pace9800 Klncey Ave. Suite 100
aceAnalyti�al
paceleb& Eden,NC 27288 Asheville,NC 28804 HunterovlNe,NC 28078
(/ wm
[phone] [phone] [phone]
(
QUALITY CONTROL DATA
I Project: PE PPA 2/7
Pace Project No.: 92147363
QC Batch: GCSV/13908 Analysis Method: EPA 1664B
I QC Batch Method: EPA 1664B Analysts Description: 1664 HEM,Oil and Grease
Associated Lab Samples: 92147363001
METHOD BLANK: 919127 Matrix: Water
I Associated Lab Samples: 92147363001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
011 and Grease mg/L ND 5.0 02/11/13 12:11
' LABORATORY CONTROL SAMPLE: 919128
Spike LCS LCS %Rec
I
Parameter Units Conc. Result
%Rec
Limits Qualifiers
Oil and Grease mg/L 40 37.2 93 78-114
l MATRIX SPIKE SAMPLE: 919129
92147426001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
IOII and Grease mg/L ND 40 33.2 83 78-114
I •
I
I
I
I
I ( Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 9 of 29
This report shall not be reproduced,except In full,
1
without the written consent of Pace Analytical Services,Inc..

1
• e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services Inc:
aceAnalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100 I rnrwpacelabacom Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
[phone] [phone] [phone]
i
QUALITY CONTROL DATA
Project: PE PPA 2/7
Pace Project No.: 92147363
QC Batch: MPRP/12576 Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET
Associated Lab Samples: 92147363002
METHOD BLANK: 919502 Matrix: Water
Associated Lab Samples: 92147363002 I
Blank Reporting
Parameter Units• Result Limit Analyzed Qualifiers
Antimony ug/L ND 5.0 02/15/13 18:18
Arsenic ug/L ND 10.0 0215/1318:18
I
Beryllium ug/L ND 1.0 02/15/13 18:18
Cadmium ug/L ND 1.0 02/15/13 18:18
Calcium ug/L ND 100 02/15/1318:18
Chromium ug/L ND 5.0 02/15/13 18:18
Copper ug/L ND 5.0 02/15/1318:18
Lead ug/L ND 5.0 02/15/1318:18
Magnesium ug/L ND 100 02/15/1318:18
Nickel ug/L ND 5.0 02/15/1318:18
I
Selenium ug/L ND 10.0 02/16/1315:46
Silver ug/L ND 5.0 02/15/1318:18
Thallium ug/L ND 10.0 02/16/1315:46
Total Hardness ug/L ND 662 02/15/13 18:18
I
Zinc ug/L ND 10.0 02/15/13 18:18
LABORATORY CONTROL SAMPLE: 919503
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Antimony ug/L 500 473 95 85-115
Arsenic ug/L 500 466 93 85-115
I
Beryllium ug/L 500 456 91 85-115
Cadmium ug/L 500 458 92 85-115
Calcium ug/L 5000 4590 92 85-115
Chromium ug/L 500 477 95 85-115
I
Copper ug/L 500 474 95 85-115
Lead ug/L 500 467 93 85-115
Magnesium ug/L 5000 4910 98 85-115
Nickel ug/L 600 469 94 85-115
I
Selenium ug/L 500 490 98 85-115
Silver ug/L 250 235 94 85-115
Thallium ug/L 500 473 95 85-115
Total Hardness ug/L 31700
I
Zinc ug/L 500 459 92 85-115
MATRIX SPIKE SAMPLE: 919504
I
92147295003 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Units Qualifiers
Antimony ug/L ND 500 490 98 70-130
Arsenic ug/L ND 500 490 98 70-130 I Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 10 of 29
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..
I
I

e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
I . ceAnalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kinsey Ave. Suite 100
Eden,NC 27288 Asheville,NC 28804 Huntersvlle,NC 28078
[phone] [phone] [phone]
i l
QUALITY CONTROL DATA
I Project: PE PPA 2/7
Pace Project No.: 92147363
MATRIX SPIKE SAMPLE: 919504
I
92147295003 Spike MS MS %Rec
Parameter Units Result Conc, Result
%Rec Limits Qualifiers
Beryllium ug/L ND 500 477 95 70-130
Cadmium ug/L ND 500 480 92 70-130
I
Calcium ug/L 12.4 mg/L 5000 17200 96 70-130
Chromium ug/L 0.0088 mg/L 500 494 97 70 130
Copper ug/L 0.068 mg/i. 500 560 98 70-130
Lead ug/L ND 600 458 91 70-130
Magnesium ug/L 4.0 mg/L 6000 8730 95 70-130
Nickel
ug/L
0.0084 mg/L 600 476 94 70-130
Selenium ug/L ND 500 493 98 70-130
Sliver ug/L ND 250 240 96 70-130
' Thallium ug/L ND 500 438 87 70-130
Total Hardness ug/L 47.5 mg/L 78900
Zinc ug/L 0.26 mg/L 500 746 98 70-130
I MATRIX SPIKE SAMPLE: 919506
92147373003 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
I
Antimony ug/L ND 500 492 98 70-130
( Arsenic ug/L ND 500 488 98 70-130
Beryllium ug/L ND 500 479 96 70-130
Cadmium ug/L ND 500 489 94 70-130
I Calcium ug/L 6220 5000 10900 94 70-130
Chromium ug/L ND 500 490 98 70-130
Copper ug/L 43.2 500 532 98 70-130
Lead ug/L ND 500 469 94 70-130
I
Magnesium
ug/L 2420 5000 7290 97 70-130
Nickel ug/L ND 500 480 96 70-130
Selenium ug/L ND 500 483 96 70-130
Silver ug/L ND 250 242 97 70-130
I Thallium ug/L ND 500 469 91 70-130
Total Hardness ug/L 25500
57300
Zinc ug/L 491 500 982 98 70-130
I SAMPLE DUPLICATE: 919505
92147295008 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
I Antimony ug/L ND ND 20
Arsenic ug/L ND ND 20
Beryllium ug/L ND ND 20
Cadmium ug/L ND ND 20
I
Calcium ug/L 10.8 mg/L 11000 2 20
Chromium ug/L ND ND 20
Copper ug/L 0.014 mg/L 13.4 1 20
Lead ug/L ND ND 20
IMagnesium ug/L 3.8 mg/L 3620 1 20
f Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 11 of 29
This report shall not be reproduced,except in full,
I
without the written consent of Pace Analytical Services,Inc..

I
e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc:
aceAnalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 KIncey Ave. Suite 100
Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
1
Project: PE PPA 2/7
I
Pace Project No.: 92147363
SAMPLE DUPLICATE: 919505
92147295006 Dup Max
I
Parameter Units Result Result RPD RPD Qualifiers
Nickel ug/L ND 3.4J 20
Selenium ug/L ND ND 20
Silver ug/L ND .4J 20
Thallium ug/L ND ND 20
Total Hardness • ug/L 41.7 mg/L 42300 1 20
Zinc ug/L 0.064 mg/L 65.2 1 20
SAMPLE DUPLICATE: 919507
II
92147373004 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Antimony ug/L ND ND 20 I
Arsenic ug/L ND ND 20
Beryllium ug/L ND ND 20
Cadmium ug/L ND ND 20
Calcium ug/L 6060 6110 1 20 1
Chromium ug/L ND ND 20
Copper ug/L 8.0 8.2 3 20
Lead ug/L ND ND 20
•
Magnesium ug/L 2350 2400 2 20
Nickel ug/L ND ND 20
Selenium ug/L ND ND 20
Sliver ug/L ND .26J 20
I
Thallium ug/L 11.3 ND 20
Total Hardness ug/L 24800 25100 1 20
Zinc ug/L 461 467 1 20
I
I
I
I
I
Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 12 of 29 ( I
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..
I
I

ical Services,Inc.
I ., aceAnalytical
205 PaEast Meadow Road--Suite A ce Analytical Services,Inc. Pace Analytical5 Riverside Dr. Pace9800 Klncey Ave. Suite 100
Eden,NC 27288 Asheville,NC 28804 Hunteravlile,NC 28078
[phone] [phone] [phone]
I I
QUALITY CONTROL DATA
I Project: PE PPA 217
Pace Project No.: 92147363
QC Batch: MSV/22032 Analysis Method: EPA 624
I QC Batch Method: EPA 624 Analysis Description: 624 MSV
Associated Lab Samples: 92147363001
METHOD BLANK 923179 Matrix: Water
I Associated Lab Samples: 92147363001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1-Trichloroethane ug/L ND 5.0 02/16/13 05:67
' 1,1,2,2-Tetrachloroethane ug/L ND 5.0 02/16/13 05:57
1,1,2-Trichloroethane ug/L ND 5.0 02/16/13 05:57
1,1-Dichloroethane ug/L ND 5.0 02/16/13 05:57
1,1-D1chloroethene ug/L ND 5.0 02/16/13 05:57
I
1,2-Dichloroethane ug/L ND 5.0 02/16/13 05:57
1,2-Dtchloropropane ug/L ND 5.0 02/16/13 05:57
2-Chloroethylvinyl ether ug/L ND 10.0 02/16/13 05:67
Acrolein ug/L ND 100 02/16/13 05:57
111 Acrylonitrile ug/L ND 50.0 02/16/13 05:67
Benzene ug/L ND 5.0 02/16//13 05:57
Bromodichloromethane ug/L ND 5.0 02/16/13 05:57
Bromoform ug/L ND 5.0 02/16/13 05:57
I
Bromomethane ug/L ND 10.0 02/16/13 05:57
Carbon tetrachloride ug/L ND 5.0 02/16/13 05:57
Chiorobenzene ug/L ND 5.0 02/16/13 05:67
Chloroethane ug/L ND 10.0 02/16/13 05:57
I Chloroform ug/L ND 5.0 02/16/13 05:57
Chloromethane ug/L ND 6.0 02/16/13 05:67
cis-1,3 Dlchioropropene ughL ND 5.0 02/16/13 05:57
Dlbromochioromethane ug/L ND 6.0 02/16/13 05:57
I
Ethylbenzene ug/L ND 5.0 02/16/13 05:57
Methylene Chloride ug/L ND 5.0 02/16/13 05:67
Tetrachloroethane ug/L ND 5.0 02/16/13 06:57
Toluene ug/L ND 5.0 02/16/13 05:57
trans-1,2-Dichloroethene ug/L ND 5.0 02/16/13 05:57
I trans-1,3-Dtchloropropene ug/L ND 5.0 02/16/13 05:57
Trichloroethene ug/L ND 6.0 02/16/13 05:57
Vinyl chloride ug/L ND 6.0 02/16/13 05:57
1,2-Dichloroethane-d4(S) % 105 70-130 02/16/13 05:57
I4-Bromofluorobenzene(S) % 96 70-130 02/16/13 05:57
Dlbromofluoromethane(S) % 96 70-130 02/16/13 05:57
Toluene-d8(S) % 100 70-130 02/16/13 05:57
' LABORATORY CONTROL SAMPLE: 923180
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
I
1,1,1-Trichloroethane
ug/L 20 19.3 97 62-182
1,1,2,2-Tetrachloroethane ug/L 20 18.9 94 46-157
1,1,2-Trichloroethane ug/L 20 21.7 108 52-150
1,1-Dlchloroethane ug/L 20 19.3 96 59-155
Ii Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 13 of 29
This report shall not be reproduced,except In full,
1 without the written consent of Pace Analytical Services,Inc..

1
s •
•
Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc:
aceAnalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 KlnceyAve. Suite 100 . I
wweepad�bs.txea Eden,NC 27288 Asheville,NC 28804 Huntersvife,NC 28078
•
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: PE PPA2/7
I
Pace Project No.: 92147363
LABORATORY CONTROL SAMPLE: 923180
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,1-DIchioroethene ug/L 20 19.4 97 1-234
1,2-Dichloroethane ug/L 20 19.8 99 49-165
1,2-Dlchloropropane ug/L 20 19.8 99 1-210
I
2-Chioroethyivinyl ether ug/L 40 43.9 110 1-305
Acroleln ug/L 100 106 106 15-152
Acrylonitrile ug/L 100 106 106 75-132
Benzene ug/L 20 20.1 100 37-151 .
I
Bromodlchloromethane ug/L 20 18.9 95 35-155
Bromoform ug/L 20 15.2 76 45-169
Bromomethane ug/L 20 20.6 103 1-242
Carbon tetrachloride ug/L 20 18.9 94 70-140 I Chlorobenzene ug/L 20 20.3 102 37-160
Chloroethane ug/L 20 19.2 98 14-230
Chloroform ug/L 20 19.6 98 51-138
Chloromethane ug/L 20 21.2 106 1-273 I cls-1,3-Dichloropropene ug/L 20 19.0 95 1-227m
Dibroochloromethane ug/L 20 18.4 92 53-149
Ethylbenzene ug/L 20 19.9 100 37-182
Methylene Chloride ug/L 20 20.9 105 1-221
Tetrachloroethene ug/L 20 20.4 102 64-148 (
I Toluene ug/L 20 20.1 101 47-160
trans-1,2-DIchloroethene ug/L 20 18.2 91 54-156
trans-1,3-Dichloropropene ug/L 20 18.8 94 17-183
Trichloroethene ug/L 20 19.6 98 71-157 I Vinyl chloride ug/L 20 17.8 89 1-251
1,2-Dichloroethane-d4(S) % 102 70-130
4-Bromofluorobenzene(S) % 97 70-130
Dibromofluoromethane(S) % 99 70-130
I
Toluene-d8(S) % 101 70-130
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 924290 924291
I
MS MSD
92147965001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
1,1,1-Trichloroethane ug/L ND 20 20 25.0 24.9 125 124 46-171 1 30
I
1,1,2,2-Tetrachloroethane ug/L ND 20 20 20.6 21.0 102 105 73-159 3 30
1,1,2-Trichloroethane ug/L ND 20 20 22.7 22.9 114 114 64-152 1 30
1,1-Dichloroethane ug/L ND 20 20 23.4 23.6 117 118 43-172 1 30
1,1-Dichloroethene ug/L ND 20 20 24.1 23.7 121 119 48-189 2 30
I
1,2-Dichloroethane ug/L ND 20 20 22.6 23.1 113 116 42-171 2 30
1,2-Dichloropropane ug/L ND 20 20 22.4 23.1 112 115 55-157 3 30
2-ChloroethyMnyl ether ug/L ND 40 40 ND ND 0 0 70-130 30 P5
Acrolein ug/L ND 100 100 135 136 135 136 70-130 0 30 MO
I
Acrylonitrile ug/L ND 100 100 111 111 111 111 70-130 1 30
Benzene ug/L ND 20 20 22.8 23.2 114 116 54-163 1 30
Bromodichloromethane ug/L ND 20 20 22.1 22.1 111 110 56-162 0 30
Bromoform ug/L ND 20 20 17.7 17.9 88 89 53-151 1 30
Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 14 of 2911
This report shall not be reproduced,except In fuN,
without the written consent of Pace Analytical Services,Inc.. 1
1

I
o q., I • Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
I • id/Anal �CaI 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
wwwpacelebs com
Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
[phone] [phone] [phone]
i
QUALITY CONTROL DATA
I Project: PE PPA2/7
Pace Project No.: 92147363
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 924290 924291
I
MS MSD
92147965001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Bromomethane ug/L ND 20 20 29.4 30.3 147 152 10-200 3 30
I
Carbon tetrachloride ug/L ND 20 20 23.7 23.6 118 118 41-175 0 30
Chlorobenzene ug/L ND 20 20 21.6 22.2 108 111 67-152 3 30
Chloroethane
ug/L ND 20 20 23.1 23.0 116 116 23-200 1 30
Chloroform ug/L ND 20 20 23.4 23.7 117 119 61-166 1 30
I
Chloromethane ug/L Ni) 20 20 23.4 23.5 117 118 40-175 1 30
cls 1,3-Dichloropropene ug/L ND 20 20 22.9 23.7 115 118 38-146 3 30
Dibromochloromethane ug/L ND 20 20 20.4 20.9 102 105 65-144 3 30
Ethylbenzene ug/L ND 20 20 21.7 21.9 109 109 57-152 1 30
I
Methylene Chloride ug/L ND 20 20 21.3 21.1 105 104 40-167 1 30
Tetrachloroethene ug/L ND 20 20 22.2 22.4 111 112 59-155 1 30
Toluene ug/L ND 20 20 23.2 23.2 116 116 47-162 0 30
trans-1,2-Dichloroethene ug/L ND 20 20 23.8 23.4 119 117 47-178 1 30
trans-1,3-Dlchloropropene ug/L ND 20 20 23.4 23.7 117 119 39-148 1 30
I Trichloroethene ug/L ND 20 20 22.9 23.5 114 118 60-153 3 30
Vinyl chloride ug/L ND 20 20 21.3 21.4 106 107 48-176 0 30
1,2-Dlchioroethane-d4(S) % 100 100 70-130
4-Bromofluorobenzene(S) % 98 98 70-130
Dibromofiuoromethane(S) % 104 102 70-130
Toluene-d8(S) % 101 102 70-130
I
I
I
I
I
I •
II Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 15 of 29
This report shah not be reproduced,except in ful,
I
without the written consent of Pace Analytical Services,Inc..

I
o Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services?Inc:
- aceAnalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Klncey Ave. Suite 100 I Eden,NC 27288 Asheville,NC 28804 Hunterevite,NC 28078 t.
ww epecele6acom
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: PE PPA 217 111Pace Project No.: 92147363
QC Batch: OEXT/20753 Analysis Method: EPA 625
QC Batch Method: EPA 625 Analysis Description: 625 MSS IIIAssociated Lab Samples: 92147363001
METHOD BLANK 920171 Matrix:Water
Associated Lab Samples: 92147363001 I
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,2,4-Trichlorobenzene ug/L ND 5.0 02/12/13 22:42
1,2-Dichlorobenzene ug/L ND 5.0 02/12/13 22:42
1,2-Diphenyihydrazine ug/L ND 5.0 02/12/13 22:42
1,3-Dichlorobenzene ug/L ND 5.0 02/12/13 22:42
1,4-Dichlorobenzene ug/L ND 5.0 02/12/13 22:42
2,4,6-Trichlorophenol ug/L ND 10.0 02/12/13 22:42
I
2,4-Dichlorophenol ug/L ND 5.0 02/12/13 22:42
2,4-Dimethylphenol ug/L ND 10.0 02/12/13 22:42
2,4-Dinitrophenol ug/L ND 60.0 02/12/13 22:42
2,4-DInitrotoluene ug/L ND 5.0 02/12/13 22:42
2,6-Dinitrotoluene ug/L ND 5.0 02/12/13 22:42
2-Chloronaphthalene ug/L ND 5.0 02/12/13 22:42
2-Chlorophenol ug/L ND 5.0 02/12/13 22:42
2-Nitrophenol ug/L ND 5.0 02/12/13 22:42
I
38,4-Methylphenol(m&p Cresol) ug/L ND 10.0 02/12/13 22:42
3,3'-Dichlorobenzldine ug/L ND 25.0 02/12/13 22:42
4,6-Dinitro-2-methylphenol ug/L ND 20.0 02/12/13 22:42
4-Bromophenyiphenyl ether ug/L ND 5.0 02/12/13 22:42
I
4-Chlorophenylphenyl ether ug/L ND 5.0 02/12/13 22:42
4-Nitrophenol ug/L ND 50.0 02/12/13 22:42
Acenaphthene ug/L ND 5.0 02/12/13 22:42
Acenaphthylene ug/L ND 5.0 02/12/13 22:42
Anthracene i ug/L ND 5.0 02/12/13 22:42
Benzldine ugIL ND 50.0 02/12/13 22:42
Benzo(a)anthracene ug/L ND 5.0 02/12/13 22:42
Benzo(a)pyrene ug/L ND 5.0 02/12/13 22:42
Benzo(b)fluoranthene ug/L ND 5.0 02/12/13 22:42 ,
Benzo(g,h,Qperylene ug/L ND 6.0 02/12/13 22:42
Benzo(k)fluoranthene ug/L ND 5.0 02/12/13 22:42
bls(2-Chioroethoxy)methane ug/L ND 10.0 02/12/13 22:42
bls(2-Chloroethyl)ether ug/L ND 5.0 02/12/13 22:42
I
bls(2-Chloroisopropyl)ether ug/L ND 5.0 02/12/13 22:42
bls(2-Ethylhexyl)phthalate ug/L ND 5.0 02/12/13 22:42
Butylbenzylphthalate ug/L ND 5.0 02/12/13 22:42
Chrysene ug/L ND 5.0 02/12/13 22:42
I
Dl-n-butylphthalate ug/L ND 5.0 02/12/13 22:42
DI-n-octylphthalate ug/L ND 5.0 02/12/13 22:42
Dibenz(a,h)anthracene ug/L ND 5.0 02/12/13 22:42
Dlethylphthalate ug/L ND 5.0 02/12/13 22:42
Dlmethylphthalate ug/L ND 5.0 02/12/13 22:42
Fluoranthene ug/L ND 6.0 02/12/13 22:42
Fluorene ug/L ND 5.0 02/12/13 22:42
Hexachloro-1,3-butadlene ug/L ND 5.0 02/12/13 22:42 I Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 16 of 29
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..
I
I

a Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
I . •aceAnalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 KlnceyAve. Suite 100
Eden,NC 27288 Asheville,NC 28804 Hunteraville,NC 28078
[phone] [phone] [phone]
I 1
QUALITY CONTROL DATA
I Project: PE PPA 2/7
Pace Project No.: 92147363
METHOD BLANK: 920171 Matrix: Water
I Associated Lab Samples: 92147363001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Hexachlorobenzene ug/L ND 5.0 02/12/13 22:42
I Hexachlorocydopenladlene ug/L ND 10.0 02/12/13 22:42
Hexachloroethane ug/L ND 5.0 02/12/13 22:42
Indeno(1,2,3-cd)pyrene ug/L ND 5.0 02/12/13 22:42
Isophorone ug/L ND 10.0 02/12/13 22:42
I
N-Nitroso-di-n-propylamine ug/L ND 5.0 02/12/13 22:42
M-Nltrosodimethylamine ug/L ND 5.0 02/12/13 22:42
N-Nitrosodiphenylamine ug/L ND 10.0 02/12/13 22:42
Naphthalene ug/L ND 5.0 02/12/13 22:42
I
Nitrobenzene
Pentachlorophenol ug/L ND 5.0 02/12/13 22:42
ug/L ND 25.0 02/12/13 22:42
Phenanthrene ug/L ND 5.0 02/12/13 22:42
Phenol ug/L ND 5.0 02/12/1322:42 •
I Pyrene ug/L ND 5.0 02/12/13 22:42
2,4,6 Trlbromophenol(S) % 44 10-137 02/12/13 22:42
2-Fluorobiphenyl(S) % 71 16-120 02/12/13 22:42
2-Fluorophenol(S) % 38 10-120 02/12/13 22:42
l Nilrobenzene-d5
(S) % 72 10-120 02/12/13 22:42
Phenol-d6(S) % 25 10-120 02/12/13 22:42
Terphenyl-d14(S) % 87 11-131 02/12/13 22:42
I
LABORATORY CONTROL SAMPLE: 920172
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
I 1,2,4 Trichlorobenzene ug/L 50 31.9 84 44-142
1,2-Dichlorobenzene ug/L 50 31.3 63 32-129
1,2-Dlphenyihydrazine ug/L 50 35.3 71 25-150
1,3-Dichlorobenzene ug/L 50 29.9 80 1-172
I 1,4-Dichlorobenzene ug/L 50 30.8 61 20-124
2,4,6 Trichlorophenol ug/L 50 32.8 66 37-144
2,4 Dlchlorophenol u9/1- 50 37.6 75 1-191
2,4-Dimethylphenol ug/L 50 40.2 80 32-119
I 2,4-Dinitrophenol ug/L 250 87.9 35 1-181
2,4-Dlnitrotoluene ug/L 50 35.1 70 39139
2,6-Dlnitrotduene ug/L 50 32.6 65 50-158
2-Chloronaphthalene ug/L 50 34.4 89 60-118
I 2-Chlorophenol ug/L 50 33.0 66 23-134
2-Nitrophend ug/L 60 33.8 67 29-182
3&4 Methylphencl(m&p Cresol) ug/L 60 29.2 68 25-150
3,3'-Dichiorobenzldlne ug/L 100 79.7 80 1-262
4,6-Dinitro-2-methylphenol ug/L 100 72.7 73 1-181
I
4-Bromophenyiphenyl ether ug/L 50 39.7 79 53 127
4-Chlorophenylphenyl ether ug/L
50 43.7 87 25-158
4-Nitrophenol ug/L 250 98.3 39 1-132
Acenaphthene ug1L 50 41.4 83 47-145
I ( Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 17 of 29
This report shall not be reproduced,except in full,
1 without the written consent of Pace Analytical Services,Inc..

I
e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services Inc:
aceAnalytical 205 East Meadow Road-Suite A 2226 Riverside Dr. 9800 Klncey Ave. Suite 100 . I
wamyaoe►abamm Eden,NC 27288 Asheville,NC 28804 Hunteravile,NC 28078
•[phone] [phone] [phone]
QUALITY CONTROL DATA
1
Project: PE PPA 2/7
I
Pace Project No.: 92147363
LABORATORY CONTROL SAMPLE: 920172
Spike LCS LCS %Rec
I
Parameter Units Conc. Result %Rec Limits Qualifiers
Acenaphthylene ug/L 50 39.8 80 33-145
Anthracene ug/L 60 40.8 82 1-166
Benzidine ug/L 100 21.8J 22 26-150 L2
Benzo(a)anthracene ug/L 60 43.6 87 33-143
Benzo(a)pyrene ug/L 50 44.4 89 17-163
Benzo(b)fluoranthene ug/L 50 42.9 86 24-159
Benzo(g,h,i)perylene ug/L . 50 42.4 85 1-219
Benzo(k)fluoranthene ug/L 60 40.9 82 11-162
bls(2-Chloroethoxy)methane ug/L 60 38.6 77 33-184
bls(2-Chloroethyl)ether ug/L 50 37.9 76 12-158
bis(2-Chloroisopropyl)ether ug/L 50 32.9 66 36-166
I
bis(2-Ethylhexyl)phthalate ug/L 60 38.4 73 8-158
Butylbenzylphthalate ug/L 60 35.0 70 1-152
Chrysene ug/L 50 40.7 81 17-168
Di-n-butyiphthalate ug/L 50 35.1 70 1-118
Dl-n-octyiphlhalate ug/L 50 35.6 71 4-146
Dibenz(a,h)anthracene ug/L 50 42.4 85 1-227
Diethylphthatate ug/L 50 37.1 74 1-114
Dimethylphthalate ug/L 50 35.4 71 1-112
I
Fluoranthene ug/L 50 46.2 92 26-137
Fluorene ug/L 50 43.3 87 59-121
Hexachloro-1,3-butadiene ug/L 50 31.1 62 24-118
Hexachlorobenzene ug/L 50 35.3 71 1-152
Hexachiorocydopentadlene ug/L 50 28.7 57 25-150
I
Hexachloroethane ug/L 50 28.5 57 40-113 .
indeno(1,2,3-cd)pyrene ug/L 50 43.5 87 1-171
Isophorone ug/L 60 31.6 63 21-196
N-Nltroso-dl-n-propylamine ug/L 60 40.3 81 1-230
N-Nltrosodlmethyiamine ug/L 50 22.4 45 25-150
N-Nltrosodiphenylamine ug/L 60 38.1 76 25-150
Naphthalene ug/L 50 38.2 72 21-133
Nitrobenzene ug/L 50 29.6 59 35-180 '
Pentachlorophenol ug/L 100 36.2 38 14-176
Phenanthrene ug/L 50 39.6 79 54-120
Phenol ug/L 50 18.0 36 5-112
Pyrene ug/L 50 42.6 85 52-115
2,4,6-Tribromophenol(S) % 81 10-137
2-Fluorobiphenyl(S) % 78 15-120
2-Fluorophenol(S) % 40 10-120
Nitrobenzene-d5(S) e/, 76 10-120
Phenol-d6(S) % 28 10-120
Terphenyl-d14(S) % 83 11-131
I
Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 18 of 29 ( I
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..
I

e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
I aceAnlytial 208 East Meadow Road-Suite A
Eden,NC 27288 2225 Riverside Dr. 9800 Klncey Ave. Suite 100
Asheville,NC 28804 Huntersvllle,NC 28078
[phone] [phone] [phone]
I 1
QUALITY CONTROL DATA
I Project: PE PPA 217
Pace Project No.: 92147363
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 920173 920174
I
92147465001 Spike Spike MS MSD MS MSD %Rec Max
Parameter MS MSD
Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
1,2,4-Trlchlorobenzene ug/L ND 100 100 61.6 72.8 62 73 44-142 17 30
I 1,2-Dichlorobenzene ug/L ND 100 100 59.7 70.6 60 71 32-129 17 30
1,2-Diphenyihydrazine ug/L ND 100 100 64.5 71.4 64 71 25150 10 30
1,3-Dichlorobenzene ug/L ND 100 100 56.5 87.6 56 68 1-172 18 30
1,4-Dichlorobenzene ug/L ND 100 100 57.9 88.7 58 69 20-124 17 30
111 2,4,8 Trichlorophenol ug/L ND 100 100 64.8 79.4 65 79 37-144 20 30
2,4-Dkittlorophenol ug/L ND 100 100 68.8 82.6 69 83 1-191 18 30
2,4-Dimethylphenol ug/L ND 100 100 72.6 87.6 73 88 32-119 19 30
2,4-Dinitrophenol ug/L ND 500 500 161 394 32 79 1-181 84 30 R1
I 2,4-DINtrotoluene ug/L ND 100 100 60.2 72.4 60 72 39-139 18 30
2,6 Dktltrololuene ug/L ND 100 100 56.0 69.6 56 70 50-158 22 30
2-Chioronaphthalene ug/L ND 100 100 63.7 74.6 64 75 60118 16 30
2-Chlorophenol ug/L ND 100 100 61.6 78.6 62 77 23-134 22 30
I 2-Nltrophenol ug/L ND 100 100 63.4 78.5 63 78 29-182 21 30
3&4-Methylphenol(m&p ug/L ND 100 100 68.6 77.4 59 77 25-150 28 30
Cresol)
3,3'-DIchlorobenzidine ug/L ND 200 200 133 159 66 79 1-262 18 30
4,8-Dlnitro-2-methylphenol ug/L ND 200 200 120 167 60 83 1-181 33 30 R1
4 Brontophenylphenyl ether ug/L ND 100 100 72.4 81.2 72 81 53-127 11 30
I ( 4-Chlorophenylphenyl ether ug/L ND 100 100 76.7 88.6 77 89 25 158 14 30
4-Nitrophenol ug/L ND 500 500 231 346 46 69 1-132 40 30 R1
Acenaphthene ug/L ND 100 100 73.5 85.7 74 86 47-145 15 30
I
Acenaphthylene ug/L
ug/L ND 100 100 70.4 83.4 70 83 33-145 17 30
Anthracene ND 100 100 71.1 80.9 71 81 1-166 13 30
Benzidine ug/L ND 200 200 17.9J 11J 9 5 25-150 30 MO
Benzo(a)anthracene ug/L ND 100 100 76.0 87.4 76 87 33-143 14 30
' Benzo(a)pyrene ug/L ND 100 100 75.8 89.7 76 90 17-163 17 30
Benzo(b)fluoranthene ug/L ND 100 100 71.0 84.7 71 85 24159 18 30
Benzo(g,h,i)perylene ug/L ND 100 100 74.6 85.0 75 85 1-219 13 30
Benzo(k)fluoranthene ug/L ND 100 100 72.4 83.0 72 83 11-162 14 30
I
bis(2 Chlofoethoxy)melhane ug/L ND 100 100 67.9 79.9 68 80 33-184 16 30
bis(2 Chloroethyl)ether ug1L ND 100 100 66.9 81.2 67 81 12-158 19 30
bls(2-Chlorolsopropyl)ether ug/L ND 100 100 59.6 72.3 60 72 36-166 19 30
bis(2-Ethylhexyl)phthalate ug/L ND 100 100 87.6 78.6 68 79 8-158 15 30
Butylbenzylphthalate ug/L ND 100 100 64.4 74.8 64 75 1-152 15 30
Chrysene ug/L ND 100 100 71.0 81.8 71 82 17-168 14 30
Dl n bulylphthalate ug/L ND 100 100 62.5 72.0 63 72 1-118 14 30
Dl-n-octylphthalate ug/L ND 100 100 87.1 83.8 67 84 4-148 22 30
Dibenz(a,h)anthracene ug/L ND 100 100 73.7 88.7 74 87 1-227 16 30
I
Dlethylphthalate ug/L ND 100 100 63.7 74.0 64 74 1-114 15 30
Dimethyiphthalate
ug/L
ND 100 100 62.0 72.9 62 73 1-112 16 30
Fluoranthene ug/L ND 100 100 77.5 92.0 78 92 26-137 17 30
Fluorene ug/L ND 100 100 75.5 87.0 75 87 59-121 14 30
I
Hexachloro-1,3-butadlene ug/L ND 100 100 62.13 71.0 83 71 24-118 12 30
Hexachlorobenzene ug/L ND 100 100 134.7 71.7 65 72 1-152 10 30
Hexachlorocyclopentadiene ug/L ND 100 100 54.9 78.1 55 78 25-150 35 30 R1
Hexachloroethane ug/L ND 100 100 55.5 66.2 55 66 40-113 18 30
II Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 19 of 29
This report shell not be reproduced,except In full,
Iwithout the written consent of Pace Analytical Services,Inc..

I
b
O G n ® Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc:
ac Ana!ytICaIj•
205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Eden,NC 27288 Asheville,NC 28804 Huntersvile,NC 28078 •
[phone] [phone] [phone]
I 1 QUALITY CONTROL DATA
Project: PE PPA 2/7
Pace Project No.: 92147363
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 920173 920174
MS MSD
92147465001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Units RPD RPD Dual
Indeno(1,2,3-cd)pyrene ug/L ND 100 100 74.9 87.8 75 88 1-171 16 30
Isophorone ug/L ND 100 100 64.3 65.0 54 65 21-196 18 30
N-Nltroso-dl-n-propylamlne ug/L ND 100 100 68.6 85.4 69 85 1-230 22 30
N-Nltrosodlmethylamlne ug/L ND 100 100 50.4 65.2 60 65 25-150 26 30
N-Nitrosodlphenylamine ug/L ND 100 100 69.0 76.6 69 77 26-150 10 30
Naphthalene ug/L ND 100 100 66.9 79.2 67 79 21-133 17 30
Nitrobenzene ug/L ND 100 100 53.2 62.3 53 82 35-180 16 30
Pentachlorophenol ug/L ND 200 200 72.1 126 36 63 14-176 54 30 R1
Phenanthrene ug/L ND 100 100 69.2 78.4 69 78 54-120 13 30
Phenol ug/L ND 100 100 42.1 59.2 42 59 5-112 34 30 R1
I
Pyrene ug/L ND 100 100 75.9 85.3 76 85 52-115 12 30
2,4,6-Tribromophenol(S) % 68 85 10-137
2-Fluoroblphenyl(8) % 67 76 15-120
2-Fluorophenol(S) % 43 66 10-120 I Nitrobenzene-d5(S) % 64 76 10-120
Phenol-d6(5) % 34 47 10-120
Terphenyl-d14(S) % 71 82 11-131
1
I
1
I
I
I
I
Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 20 of 29 ( I
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..
Il
I

e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
I . •aCeAnalytical 205 East Meadow Road-Suite A 2226 Riverside Dr. 9800 Macey Ave. Suite 100
www.paceiabs.com NC 27288 Asheville,NC 28804 Huntersvllle,NC 28078
[phone] [phone] [phone]
I (
QUALITY CONTROL DATA
1111Project: PE PPA 2/7
Pace Project No.: 92147363
QC Batch: WET/24115 Analysis Method: SM 2640C
QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids
II
Associated Lab Samples: 92147363002
METHOD BLANK: 919099 Matrix: Water
II
Associated Lab Samples: 92147363002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 26.0 02/08/13 14:41
II
LABORATORY CONTROL SAMPLE: 919100
Spike LCS LCS %Rec
IaParameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 234
94
80-120
'I SAMPLE DUPLICATE: 919101
92148983001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
'I Total Dissolved Solids mg/L 263 270 3 20
1
SAMPLE DUPLICATE: 919102
92147252007 Dup Max
I
`
r Parameter Units Result Result RPD RPD Qualifiers
Total Dissolved Solids mg/L 366 372 2 20
II
Il
I
I
I
II Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 21 of 29
This report shall not be reproduced,except In full,
1 without the written consent of Pace Analytical Services,Inc..
I

I
,
a Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc:
aceAnalytiical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kinney Ave. Suite 100
twm Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
1
Project: PE PPA 2/7 I Pace Project No.: 92147363
QC Batch: WETA/14499 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia I Associated Lab Samples: 92147363002
METHOD BLANK 920941 Matrix: Water
Associated Lab Samples: 92147383002 '
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 02/13/13 01:28
LABORATORY CONTROL SAMPLE: 920942
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 4.9 97 90-110
MATRIX SPIKE SAMPLE: 920943
92147695001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5.5 5 9.7 83 90-110 M1
MATRIX SPIKE SAMPLE: 920945
92147337001 Spike MS MS %Rec I Parameter Units Result Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 2.8 5 5.4 55 90-110 M1
SAMPLE DUPLICATE: 920944 I
92147695001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Nitrogen,Ammonia mg/L 5.5 5.5 0 20
1
SAMPLE DUPLICATE: 920946
92147337001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers III
Nitrogen,Ammonia mg/L 2.6 2.6 1 20
I
. I
Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 22 of 29 f I
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..
I
I

1
e 2 5aEast Meadow Ro di-Suite A Pace Analytical
Riverside Dr. PaAnalytical
I , Kincey aceAnalytical
� �rwmcelecom
Eden,NC 27288 AahevN9800 Ave. Sute 100le,NC 28804 Huntersville,NC 28078
[phone] [phone] [phone]
I f
QUALITY CONTROL DATA
I Project: PE PPA 2/7
Pace Project No.: 92147363
QC Batch: WETA/14512 Analysis Method: EPA 351.2
I QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN
Associated Lab Samples: 92147363002
METHOD BLANK: 921803 Matrix: Water
I Associated Lab Samples: 92147383002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
' Nitrogen,Kjeldahl,Total mg/L ND 0.50 02/17113 14:49
LABORATORY CONTROL SAMPLE: 921804
Spike LCS LCS %Rec
I
ParameterUnits Conc. Result %Rec Limits Qualifiers
Nitrogen,Kjeldahl,Total mg/L 10 10.1 101 90-110
1 MATRIX SPIKE SAMPLE: 921805
92147815001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Nitrogen,Kjeldahl,Total mg/L 193 50 287 150 90-110 M1
MATRIX SPIKE SAMPLE: 921808
I
92147406003 Spike MS MS %Rec
Parameter Unfts
Result Conc. Result
%Rec Limits Qualifiers
Nitrogen,Kjeldahl,Total mg/L 1.7 10 14.2 125 90-110 M1
ISAMPLE DUPLICATE 921806
92147815002 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Nitrogen,Kjeldahl,Total mg/L 1990 1990 0 20
SAMPLE DUPLICATE: 921807
I
92147406002 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Nitrogen,Kjeldahl,Total mg/L 6.9 7.5 9 20
I
I
t4 Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 23 of 29
This report shaft not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..
I

a
e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,inc
a�eAnalytical 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 IQnceyAve. Suite 100
Wavypscelabscom Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
[phone] [phone] [phone]
QUALITY CONTROL DATA
1
Project: PEPPA 277
Pace Project No.: 92147363
QC Batch: WETA/14571 Analysis Method: EPA 353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate+Nitrite,preserved
Associated Lab Samples: 92147363002
METHOD BLANK: 925923 Matrix: Water
Associated Lab Samples: 92147363002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,NO2 plus NO3 mg/L ND 0.020 02/20/13 18:02
I
LABORATORY CONTROL SAMPLE: 925924
Spike LCS LCS %Rec • I
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 2.5 2.5 98 90-110
MATRIX SPIKE SAMPLE: 925976
I
92147287001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 20.6 2.5 24.8 168 75-125 M1
(
MATRIX SPIKE SAMPLE: 925978
92147295006 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 3.8 2.5 6.0 87 75-125
SAMPLE DUPLICATE: 925977 1
92147287001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Nitrogen,NO2 plus NO3 mg/L 20.6 20.6 0 20 1
SAMPLE DUPLICATE: 925979
92147295006 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Nitrogen,NO2 plus NO3 mg/L 3.8 3.9 1 20
I
I
Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 24 of 29 ( 1
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc..
I

ti e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
aceAnalytrcal 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 KlnceyAve. Suite 100
Eden,NC 27288 Asheville,NC 28804 Hunteraville,NC 28078
[phone] [phone] [phone]
(
QUALITY CONTROL DATA
I Project: PEPPA 2/7
Pace Project No.: 92147363
QC Batch: WETN14526 Analysis Method: EPA 365.1
I QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus,Total
Associated Lab Samples: 92147363002
METHOD BLANK 922733 Matrix: Water
I Associated Lab Samples: 92147363002
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phosphorus mg/L ND 0.050 02/16/13 10:27
1
LABORATORY CONTROL SAMPLE: 922734
I Spike LCS LCS %Rec
Parameter Units Conc. Result
%Rec Umits Qualifiers
Phosphorus mg/L 2.5 2.6 103 90-110
I
MATRIX SPIKE SAMPLE: 922736
92148104001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Phosphorus mg/L 0.11 2.6 3.0 116 90-110 M1
MATRIX SPIKE SAMPLE: 922888
I
92148104004 Spike MS MS %Rec
Parameter Units
Result Conc. Result
%Rec Limits Qualifiers
Phosphorus mg/L 0.065 2.5 2.8 108 90-110
1 SAMPLE DUPLICATE: 922735
92148104001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
IPhosphorus mg/L 0.11 0.11 6 20
I SAMPLE DUPLICATE 922887
92148104004 Dup Max
Parameter Units
Result Result RPD RPD Qualifiers
Phosphorus mg/L 0.085 0.063 4 20
I
I
II Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 25 of 29
This report ahal not be reproduced,except In full,
Iwithout the written consent of Pace Analytical Services,Inc..
I

I
a
Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc:
aCeAmovatieleowinnalytIcal 205 East Meadow Road-Suite A 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Eden,NC 27288 Asheville,NC 28804 Hunteravtlle,NC 28078 '
[phone] [phone] [phone]
QUALITY CONTROL DATA
Project: PE PPA 2/7
Pace Project No.: 92147363
QC Batch: WETA/14493 Analysis Method: EPA 420.4
QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics
Associated Lab Samples: 92147363001
METHOD BLANK: 920294 Matrix: Water
Associated Lab Samples: 92147363001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Phenol mg/L ND 0.0050 02/13/13 13:01
I
LABORATORY CONTROL SAMPLE: 920295
Spike LCS LCS %Rec
I
Parameter Units Conc. Result %Rec Limits Qualifiers
Phenol mg/L .05 0.052 105 90-110
MATRIX SPIKE SAMPLE: 920296111
92146762001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Phenol mg/L 0.011 .05 0.058 95 90-110
• i
MATRIX SPIKE SAMPLE: 920298
92147363001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Phenol mg/L 0.013 .05 0.058 89 90-110 M1
SAMPLE DUPLICATE: 920297
92147169002 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Phenol mg/L 0.050 0.062 21 20 D6 D
SAMPLE DUPLICATE: 920299
92147368002 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
Phenol mg/L 0.063 0.056 11 20
3
3
Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 26 of 29 ( 0
This report shall not be reproduced,except In full,
without the written consent of Pace Analyilcal Services,Inc..
II
�3

p p,�� a Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
I i • •
eeAnalytic I 205 East Meadow Road-Suite A 2225 Riverside Dc 9800 Klncey Ave. Suite 100
Ww"licelebs
Eden,NC 27288 Asheville,NC 28804 HuntersvWe,NC 28078
[phone] [phone] [phone]
i ‘
QUALITY CONTROL DATA
1 I Project: PE PPA 217
Pace Project No.: 92147363
QC Batch: WETA/14531 Analysis Method: SM 4500-CN-E
I QC Batch Method: SM 4500-CN-E Analysis Description: 4500CNE Cyanide,Total
Associated Lab Samples: 92147383001
METHOD BLANK: 922761 Matrix: Water •
I Associated Lab Samples: 92147363001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Cyanide mg/L ND 0.0050 02/15113 14:09
I
LABORATORY CONTROL SAMPLE: 922782
Spike LCS LCS %Rec
I Parameter Units Conc. Result
%Rec
Limits Qualifiers
Cyanide mg/L .1 0.11 111 80-120
I MATRIX SPIKE SAMPLE: 922763
92147295002 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Cyanide mg/L ND .1 0.12 113 75-125
I
SAMPLE DUPLICATE: 922764
I
921 Result 04 Dup Max
Parameter Units 47295Result Result RPD RPD Qualifiers
Cyanide mg/L ND ND 20
I
I
I
I
Il Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS Page 27 of 29
This report shall not be reproduced,except to full,
1 without the written consent of Pace Analytical Services,Inc..
I

,Inc.
Services,Inc.
aceAnalytical 6 205aEast Meadow Road o Suite A Pace Analytical
Riverside Dr.
Pace 800 KinceyAve. Suite 160
.. wwilepaceiebacom
Eden,NC 27288 Asheville,NC 28804 Huntersville,NC 28078
Analytical
[phone] [phone]
[phone] , i
QUALIFIERS
I
Project: PE PPA 2/7
I
Pace Project No.: 92147363
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to changes In sample preparation,dilution of
the sample aliquot,or moisture content.
ND-Not Detected at or above adjusted reporting limit.
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PRL-Pace Reporting Limit.
RL-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazine(8270 listed analyte)decomposes to Azobenzene.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable.
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether,Styrene,and Vinyl chloride.
Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES I
PASI-A Pace Analytical Services-Asheville
PAST-C Pace Analytical Services-Charlotte
ANALYTE QUALIFIERS
D6 The relative percent difference(RPD)between the sample and sample duplicate exceeded laboratory control limits.
L2 Analyte recovery in the laboratory control sample(LCS)was below QC limits. Results for this analyte in associated '
samples may be biased low.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
-M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
Pb The EPA or method required sample preservation degrades this compound,therefore acceptable recoveries may not be
achieved in sample matrix spikes.
R1 RPD value was outside control limits.
I
I
Date:03/08/2013 08:42 AM REPORT OF LABORATORY ANALYSIS
Page 28 of 29
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc..
FI

I
I /� I r
�CB/Illal ica e Pace Analytical Services,Inc. Pace Analytical Services,Inc. Pace Analytical Services,Inc.
205 East Meadow Road-SuileA 2225 Riverside Dr. 9800 Kincey Ave. Suite 100
Eden,NC 27288 Asheville,NC 28804 Hunteravi ie,NC 28078
[phone] [phone] [phone]
I l
QUALITY CONTROL DATA CROSS REFERENCE TABLE
I Project: PE PPA 2/7
Pace Project No.: 92147363
Analytical
I
Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92147363001 PE PPA GRAB EPA 16648 GCSV/13908
92147363002 PE PPA COMP EPA 200.7 MPRP/12576 EPA 200.7 ICP/11480
1 92147363001 PE PPA GRAB EPA 625 OT/20753 EPA 625 MSSV/7339
92147363001 PE PPA GRAB EPA 624 MSV/22032
92147383002 PE PPA COMP SM 2540C WET/24115
I92147363002 PE PPA COMP EPA 350.1 WETN14499
92147363002 PE PPA COMP EPA 351.2 WETN14512
92147363002 PE PPA COMP EPA 353.2 WETA/14571
92147363002 PE PPA COMP EPA 365.1 WETA/14526
92147363001 PE PPA GRAB EPA 420.4 WETN14493
I92147363001 PE PPA GRAB SM 4500-CN-E WETN14531
1f
I
I
I
I
I
I
IDate:03/08/2013 08:42AM REPORT OF LABORATORY ANALYSIS Page 29 of 29
This report shall not be reproduced,except In full,
Iwithout the written consent of Pace Analytical Services,Inc..

I E I. I
CHAIN-OF-CUSTODY/Analytical Request Document
aeArialyticarThe Chain•of-Custody is a LEGAL DOCUMENT.All relevant fields must be completed accurately.r wrr.pacelabscom
Section A Section B -. Section C Page: + of f
Required Client Information: Required Project Information: Invoice Information:
Compan 14 ^ Report To: LiQ .J�1 j , r' Attention: .
Address: Y/ G� To: CompanyName: "r � � "" ;
Copy �tEG IJ GEd.` 0.4:c ... _d ,,,.,
Address: t—1 P
DES 1 GROUND WATER r DRINKING WATER
Email To: Purchase Order No.: Pace Quote
Reference: r .UST r ROM OTHER
Phone: Fax Project Namep/� Pace Project ;;;
lrat � 1` ' M'g �k z'�'
/ C �'r Manager.RequestedDueDate/TAT: �`'r' may-. ...Ix.'-r. 'i' `�'°' ,,,yt-\-.i
-�-` Q4 _. . _�S �� };mss t''�' '� . -s
1 rz " ,pr .'e -r v -fir
Section D Matrix Codes + _.n
Required Client Infomation MATRIX r cooe a COLLECTED - Preservatives �.�,`^ �jfi,- _ x;ti,,
Drinking Water DW o
Z. �.
Water w'r
Waste Water WW g m COMPOSITE COMPOSRE tu r C
Product P qg START ENor6RA9 w - Z
SoiliSotd SL r, . - p S } ~. .
SAMPLE ID ou OL 0 ' ` -I
VVIpe VVP I- la
( ) Air AR ❑ w a .. ,, • \ Z _ :4 lei,/ �.
Sample IDs MUST BE UNIQUE Tissue TS ' 0 o- w a ami ;',g=a, ¢ 4.. 1 ; ` t
Other • OT U r0
Z m o • m3 4 ` .. `.Tr -
w ,• ', a LLO- aN � =Ocn r � .�. j c� Q F ; o`c m ‘t:,; -173L,
us N c z U.to (o ar ._:ai V O, `\ k N
/!/J /� A DATE •TIME DATE TIME ' w a 7•S 2 2 z-z .e o �;•/ C-� 1' CE - Pace Project NoJ Lab 1.D.
A.
('./ Ccn,e0 - 1-3,)3 ,=”--P .. h / /P ! � /s.,�r- .- 40,62
0
04
g
Z
3-
BIZ: . i..
•"�"''° ITO-O :EO EN7S r" ,p T�i`ttz .�'^e+ QUISFff�-ift * i.�na 1.7ie -'..'"'''r '7 "s' •'`fr# I: `y;',F"'.:."ti _
e '4' �- L.•.•,v.� ,+� s� -_sr `i* + -t4 - _ '..war.:; e'��_.r. _ r. ' r.--C--ar,. ,.. 3 _n��±.: `3�iAA Er' „.;-1/1; SAMPLE CONDITIONS
. - )^?_15 -lal3' :/rLr .A i..• 9J-ri rad
"I'LL/,' 4 1i x:,,-,, I D ? .1,7:-.10 2.5 Y v-
1 �3:eeEr "y?ar c *i M. ^l-. si ,�? ct G
o .
ORIGINAL PRINT Name of SAMPLER: 4-2K ({ SW1-„.,„j a m L ' m E. *,'.8
SIGNATURE ofSAMPLERY I n!C DATE Signod )_ � .l ) I U m
J (MWDDlYY) b 1 m co
.
btu 'e:By slgoing this form you are accepting Pace's NET 30 day payment terms and agreeing to late charges of 1.5%per month for does not geld within 30 days • F-ALL-Q-020rev.07,15 1.007
- NB - 1111 MI MO M 111111 all 111111 MN - M - r M all MI an

I
Document Name:Sample Condition Upon Document Revised:May 30,2012 -
ace,Anal,teal A Receipt(SCUR) Page 1 of 2 •
i,M1iw.ba�ea "o , Document No.: Issuing Authorities:
F-ASV-CS-003-rev.08 Pace Asheville Quality Office
Client Name: /145,0 Project # 12 iY?3 G
Where Received: f Huntersville./Ei--Xsheville •fl Eden Ei Raleigh -
Courier(Circle): Fed Ex UPS USPS raCommercial, Pace Other I—t
FL,—s�
Custody Seal on Cooler/Box Present: 0 yes ,moo Seals Intact: 0 yes 0--no e'' ' c 1 " ,3 —
Packing Material: 0•Bobbie Wrap Q—gUbble Bags None Ei Other x
Circle Thermometer Used:IR- n#2.80344039 Type of Ice: et Blue None ___ Samples on Ice,cooling process has begun
IR gun Back'Up-111565135
Temp Correction Factor: Add/ trot ,v.- - ) C
Corrected Cooler Temp.: .. 3 c Biological Tissue is Frozen: Yes No N/A Date and Initials of person ex•mining 1
contents: .2_, .e./
Temp should be above freezing to 6°C Comments: .
Chain of Custody Present: es' ❑No ON/A 1.
Chain of Custody Filled Out: 4.21 s ONo ON/A 2. i
Chain of Custody Relinquished: ,J]e ONo ON/A 3. •
Sampler Name&Signature on COC: ,,0 rtes ONo ON/A 4. .
Samples Arrived within Hold Time: Yes ONo ON/A 5.
Short Hold Time Analysis(<72hr): Ores L2io ON/A 6. ,
•
Rush Turn Around Time Requested: Dyes TKO ❑N/A,7. y
Sufficient Volume: ONo ❑N/A 8. ' . • •
•
Correct Containers Used: ,y Yes ONo ON/A 9: . .
-Pace Containers Used: • . 4Yes ONo ON/A • •
Containers Intact: /6Yes ONo ON/A 10. .
•
Filtered volume received for Dissolved tests �es.ONo ON/A 11. •
Sample Labels match COC: Yes ONo ❑N/A 12.
i j -
1
-Includes date/time/ID/Analysis. Matrix: 4..- - 1
All containers needing preservation have been checked.
°Yes ONo ❑N/A 13. •
At containers needing preservation are found to be In I
Yes ONo ❑N/A
compliancewithEPA recommendation.
exceptlbne. _, c ,t,
�(. Ooliform,TOCOO I-DRO(water) if/Yes ONo Initial when completed
1
Samples checked for dechlorination: es ❑No .❑N/A 14.
Headspace In VOA Vials(>6mm): ---1: s ❑W ON/A 15.
Trip Blank Present: ❑Yes DNo /A 16.
Trip Blank Custody Seals Present ❑Yes ❑No N? '
Pace Trip Blank Lot#(if purchased):
Client Notification/Resolution: Field Data Required? Y I N111
Person Contacted: Date/Time: .
Comments/Resolution: i
SCURF Review: VC . Date: 02 `K SRF Review: A Date: p` t3
Note: Whenever there Is a discrepancy affecting North Carolina compliance samples,a copy of this form will be sent to the North Carolina DEHNR
• Certification Office(I.e out of hold,incorrect preservative,out of temp,Incorrect containers)
,
•
• r
1

i
• Pace Analytical Services,Inc.
I ` acen'
Aa !6 2225 Riverside Dr.
Asheville,NC 28804
itivriPauflalyticab u [phone]
•
I
June 04,2014
I
Mr. Wayne Tipton
Metropolitan Sewerage District
2028 Riverside Drive
Asheville, NC 28804
RE: Project: P PPA 5/19/14
Pace Project No.: 92201869
Dear Mr.Tipton:
Enclosed are the analytical results for sample(s) received bythe laboratory on May 19, 2014, The
Yt
results relate only to the samples included in this report. Results reported herein conform to the
most current TNI standards and the laboratory's Quality Assurance Manual,where applicable, unless
otherwise noted in the body of the report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
' [e-mail]
Project Manager
Enclosures
I
REPORT OF LABORATORY ANALYSIS
This report shag not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc.. Page 1 of 33
I

I
Pace Analytical Services:Mc.
2226 Riverside Dr.•
aceAnalytical
Asheville,NC 28804
pwtv:peoelabatom [phone]
CERTIFICATIONS
Project: P PPA 5/19/14
Pace Project No.: 92201869
Charlotte Certification IDs
9800 Kincey Ave.Ste 100,Huntersvllle,NC 28078 Florida/NELAP Certification#:E87627
North Carolina Drinking Water Certification#:37706 Kentucky UST Certification#:84
North Carolina Field Services Certification#:5342 West Virginia Certification#:357
North Carolina Wastewater Certification#:12 VlrginiaNELAP Certification#:460221
South Carolina Certification#:99006001
Asheville Certification IDs
2225 Riverside Dr.,Asheville,NC 28804 North Carolina Wastewater Certification#:40
Florlda/NELAP Certification#:E87648 South Carolina Certification#:99030001
MassachusettsCertificationCrC030 _ —� - - West Virginia Certification#:356
North Carolina Drinking Water Certification#:37712 VrginlaNEIAP Certification
#:460222
I
( t
I
I
r
1
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc.. Page 2 of 33

Pace Analytical Services,Inc.
•0 2225 Riverside Dr.
ace jialyhcal Asheville,Nc 28804
wx+xpsoelenadarr [phone]
111 I
SAMPLE SUMMARY
Project: P PPA 5/19/14
Pace Project No.: 92201869
Lab ID Sample ID Matrix Date Collected Date Received
92201869001 PE Water
05/19/14 10:15 05/19/14 10:45
92201869002 PE LLHG Water 05/19/14 10:10 05/19/1410:45
92201869003 Field Blank PE LLHG Water 05/19/14 10:00 05/19/14 10:45
92201869004 TRIP BLANK Water 05/19/14 00:00 05/19/14 10:45
•
•
•I
i
L
1
i
I
I
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Inc.. Page 3 of 33
I

Pace Analytical Services,thc.
2225 Riverside Dr.•
•aceAna1ytifcal Asheville,NC 28804
y pyps (828)254=7176
III
SAMPLE ANALYTE COUNT
I
Project: P PPA 5/19/14
Pace Project No.: 92201869 11
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92201869001 PE EPA 16648 CLW 1 PASI-C
EPA 200.7 JMW 15 PASI-A
. EPA 625 RES 63 PASI-C
EPA 624 GAW 32 PASI-C
SM 2540C JTJ 1 PASI-A
EPA 350.1 AES2 1 PASI-A
EPA 351.2 JDA 1 PASI-A
111
EPA 353.2 DMN 1 PASI-A•
EPA 365.1 JDA 1 PASI-A -
EPA 420.4 DMN 1 PASI-A
II
SM 4500-CN-E JDA 1 PASI-A
92201869002 PE LLHG EPA 1631E SH1 1 PASI-A
92201869003 Field Blank PE LLHG EPA 1631E SH1 1 PASI-A
92201869004 TRIP BLANK EPA 624 GAW 32 PASI-C
I
I
1
I
I
I
. I 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc.. Page 4 of 33
•
I

I
Pace Analytical Services,Inc.
• e 2225 Riverside Dr.
aceAnalyticar Asheville,NC 28804
818W8P41464#40 [phone]
I I
ANALYTICAL RESULTS
I Project: P PPA 5/19/14
Pace Project No.: 92201869 •
Sample: PE Lab ID: 92201869001 Collected: 05/19/14 10:15 •Received: 05/19/14 10:45 Matrix:Water
I
Report Reg.
Parameters Results Units Limit Limit DF Prepared Analyzed CAS No. Qua!
• HEM,011 and Grease Analytical Method:EPA 1864B
I Oil and Grease ND mg/L 5.0 1 05/20/1414:57
200.7 MET ICP Analytical Method:EPA 200.7 Preparation Method:EPA 200.7
Antimony ND ugh 5.0 1 05/20/14 16:45 05/21/14 18:12 7440-36-0
I Arsenic ND ugh 10.0 1 05/20/14 16:45 05/21/14 18:12 7440-38-2
Beryllium ND ug/L 1.0 1 05/20/1418:45 05/21/1418:12 7440 41-7 1
Cadmium ND ug/L 1.0 1 05/20/1416:45 05/21/14 18:12 7440-43-9
Calcium 12000 ug/L 100 1 05/20/1416:45 05/21/14 18:12 7440-70-2
I
Chromium ND ug/L 5.0 1 05/20/14 16:45 05/21/14 18:12 7440-47-3
Copper 8.9 ug/L 5.0 1 05/20/14 16:45 05/21/14 18:12 7440-50-8
Lead ND ug/L 6.0 1 05/20/1416:45 05121/14 18:12 7439-92-1
Magnesium 3640 ug/L 100 1 05/20/1416:45 05/21/14 18:12 7439-95-4
INickel ND ug/L 5.0 . 1 05/20/14 16:45 05/21/14 18:12 7440-02-0
Selenium ND ug/L 10.0 1 05/20/14 18:45 05/21/14 18:12 7782-49-2
Sliver . ND ug/L 5.0 1 05/20/14 16:45 05/21/14 18:12 7440-22-4
Thallium ND ugh 10.0 1 05/20/14 18:45 05/21/14 18:12 7440-28-0
Hardness,Total(SM 2340B) 45000 ug/L 682 1 05/20/14 16:45 05/21/14 18:12
Zinc 48.4 ug/L 10.0 1 05/20/1416:45 05/21/14 18:12 7440-66-6
826 MSSV Analytical Method:EPA625 Preparation Method:EPA625
I Acenaphthene ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 83-32-9
Acenaphthylene ND ug/L 6.0 1 05/22/14 13:00 06/03/14 01:62 208-98-8
Anthracene ND ugh 5.0 1 05/22/1413:00 06/03/14 01:52 120-12-7
Benzkline ND ugh 50.0 1 05122/14 13:00 06/03/14 01:52 92-87-5
Benzo(a)anthracene ND ug/L 6.0 1 05/22/14 13:00 06/03/14 01:52 56-55-3
Benzo(a)pyrene ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 60-32-8
Benzo(b)fluoranthene ND ugh 5.0 1 05/22/14 13:00 06/03/14 01:52 205-99-2
Benzo(g,h,gperyiene ND ug/L 5.0 1 05/22/1413:00 06/03/14 01:52 191-24-2
I Benzo(k)fluoranthene ND ug/L 5.0 1 05/22/1413:00 06/03/14 01:52 207-08-9
4-Bromophenylphenyl ether ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 101-55-3
Sutylbenzylphthalate ND ug/L 5.0 1 05/22/1413:00 06/03/14 01:52 85-68-7
bis(2-Chioroethoxy)methane ND ug/L 10.0 ' 1 05/22/1413:00 06/03/14 01:52 111-91-1
bis(2-Chloroethyl ether ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 111-44-4
I bls(2-Chlorolsopropyi)ether ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 108-80-1
2 Chloronaphthalene ND ug/L 5.0 • 1 05/22/1413:00 06/03/14 01:52 91-58-7
2-Chlorophenol ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 95-57-8
4-Chlorophenylphenyl ether ND ug/L 5.0 ' 1 05/22/1413:00 08/03/14 01:52 7005-72-3
I
Chrysene
Dibenz(a,h)anthracerte ND ug/L 5.0 1 05/22/1413:00 06/03/14 01:52 218-01-9
ND ug/L 6.0 1 05/22/14 13:00 08/03/14 01:52 63-70-3
1,2-Dichlorobenzene ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 95-60-1
1,3-Dichlorobenzene ND ug/L 5.0 1 05/22/14 13:00 08/03/14 01:62 641-73-1
I 1,4 Dichlorobenzene ND ug/L 6.0 1 05/22/14 13:00 06/03/14 01:52 106-46-7
3,3'-Dichlorobenzidine ND ug/L 26.0 1 05/22/1413:00 08/03/14 01:52 91-94-1
2,4-Dichlorophenol ND ug/L 6.0 1 05/22/14 13:00 06/03/14 01:52 120-83-2
Dlethylphthalate ND ug/L 6.0 1 05/22/14 13:00 08/03/14 01:52 84-66-2
2,4-Dimethylphenol ND ug/L 10.0 1 05/22/1413:00 06/03/14 01:52 105-67-9
•I
REPORT OF LABORATORY ANALYSIS ' '
I
I .
This report shall not be reproduced,except in full, ' •
Date:06/04/201410:37 AM without the written consent of Pace Analytical Services,Inc.. Page 6 of 33
I

Pace Analytical Services?thc.
/�w • 2225 ervice 7 Dc
aceAnalytical
Asheville,NC 28804
)rwrypaaf¢Qr spm (828)25447176
ANALYTICAL RESULTS
Project: - P PPA 5/19/14
Pace Project No.: 92201869 .
Sample: PE Lab ID: 92201869001 Collected: 05/19/14 10:15 Received: 05/19/14 10:45 Matrix:Water
Report Reg.
Parameters Results Units Limit Limit DF Prepared Analyzed CAS No. Qual
625 MSSV Analytical Method:EPA 625 Preparation Method:EPA625
Dimethylphthalate ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 131-11-3
DI-n-butylphthalate ND ug/L 5.0 1 05122/14 13:00 06/03/14 01:52 84-74-2
4,6-Dlnitro-2-methylphenol ND ug/L 20.0 1 05/22/14 13:00 06/03/14 01:52 634-52-1
2,4-Dlnitrophenol ND ug/L 50.0 1 05/22/14 13:00 06/03/14 01:52 51-28-5
2,4-Dinitrotoluene ND ug/L 5.0 1 05/22/1413:00 06/03/14 01:62 121-14-2
2,6-Dinitrotoluene ' ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 606-20-2
Di-n-octylphthalate ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 117-84-0
1,2-Diphenylhydrazine ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 122-66-7
bis(2-Ethylhexyl)phthalate ND ug/L 5.0 1 06/22/14 13:00 06/03/14 01:52 117-81-7
Fluoranthene ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 206-44-0
Fluorene ND ug/L 6.0 1 05/22/14 13:00 06/03/14 01:52 86-73-7
Hexachloro-1,3-butadiene ND ug/L 6.0 1 05/22/14 13:00 06/03/1401:52 87-68-3
Hexachlorobenzene ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 118-74-1
Hexachlorocyclopentadiene ND ug/L 10.0 1 05/22/14 13:00 06/03/14 01:52 77-47-4
Hexachloroethane ND ug/L 6.0 1 05/22/14 13:00 06/03/14 01:52 67-72-1
Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 193-39-5
Isophorone ' ND ug/L 10.0 1 06/22/14 13:00 06/03/14 01:52 78-59-1
3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1 05/22/14 13:00 06/03/14 01:52
Naphthalene ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 91-20-3
Nitrobenzene ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 98-95-3
2-Nttrophenol ND ug/L 5.0 1 05/22/1413:00 06/03/14 01:52 88-75-5
4-Nttrophenol ND ug/L 50.0 1 05/22/1413:00 06/03/14 01:52 100-02-7
N-Nitrosodimethylamine ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 62-75-9
N-Nitroso-dl-n-propylamine ND ug/L 5.0 1 05/22/1413:00 08/03/14 01:52 821-64-7
N-Nltrosodiphenylamine ND ug/L 10.0 1 05/22/14 13:00 06/03/14 01:52 86-30-6
Pentachlorophenol ND ug/L 10.0 1 05/22/14 13:00 08/03/14 01:62 87-86-6
Phenanthrene ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:62 85-01-8
Phenol ND ug/L 5.0 1 05/22/14 13:00 06/03/14 01:52 108-95-2
Pyrene ND uglL 5.0 1 05122/1413:00 06/03/14 01:52 129-00-0
1,2,4-Trichlorobenzene ND ug/L 5.0 1 05/22/1413:00 08/03/14 01:52 120-82-1
2,4,6-Trichlorophenol ND ugh.' 10.0 1 05/22/14 13:00 08/03/14 01:52 88-06-2
Surrogates
Nitrobenzene-d6(S) 37 % 10-120 1 05/22/14 13:00 06/03/14 01:52 4165-60-0
2-Fluorobiphenyl(S) 36 % 15-120 1 05/22/14 13:00 06/03/14 01:52 321-80-8
Terphenyl-d14(S) 59 % 11-131 1 05/22/1413:00 06/03/14 01:52 1718-51-0
Phenol-d6(S) 16 % 10-120 1 05/22/14 13:00 06/03/14 01:52 13127-88-3
2-Fluorophenol(S) 22 % 10-120 1 05/22/14 13:00 06/03/14 01:52 367-12-4
2,4,6-Tribromophenol(S) 64 % 10-137 1 05/22/1413:00 06/03/14 01:52 118-79-6
624 Volatile Organics Analytical Method:EPA 624 •
Acrolein ND ug/L 5.0 1 05/24/14 01:35 107-02-8
Acrylonitrile ND ug/L 50.0 1 06/24/14 01:35 107-13-1
Benzene ND ug/L 2.0 1 05/24/14 01:36 71-43-2
Bromodichioromethane ND ug/L 2.0 1 05/24/14 01:35 76-27-4
Bromoform ND ug/L 2.0 1 05/24/14 01:35 76-25-2
Bromomethane ND ug/L 2.0 1 05/24/14 01:35 74-83-9
1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In futi,
Date:06/04/2014 10:37AM without the written consent of Pace Analytical Services,Inc.. Page 6 of 33
�I

i
I
, ,
Pace Analytical Services,Inc.
I 's i 2226 Riverside Dr.
� / ICBj{ Asheville,NC 28804
w►NypeodaQaam [phone]
IIANALYTICAL RESULTS
I Project: P PPA 5/19/14
Pace Project No.: 92201869
Sample: PE Lab ID: 92201869001 Collected: 05/19/14 10:15 Received: 05/19/14 10:45 Matrix:Water
I
Report Reg.
Parameters Results Units Limit Limit DF Prepared Analyzed CAS No. Qua!
•
624 Volatile Organics Analytical Method:EPA 624
I Carbon tetrachloride • ND ug/L 2.0 1 05/24/14 01:35 56-23-5
Chlorobenzene ND ug/L 2.0 1 05/24/14 01:35 108-90-7
Chloroethane ND ug/L 2.0 1 05/24/14 01:35 75-00-3
2-Chloroethyivinyl ether ND ug/L 5.0 1 05/24/14 01:35 110-75-8
I Chloroform ND ug/L 2.0 1 05/24/14 01:35 67-66-3
Chloromethane ND ug/L 2.0 1 05/24/14 01:35 74-87-3
Dibromochloromethane ND ug/L 2.0 1 05/24/14 01:35 124-48-1
1,1-Dichloroethane ND ug/L 2.0 1 05/24/14 01:35 75-34-3
1,2-Dichloroethane ND ug/L 2.0 1 05/24/14 01:35 107-06-2
I 1,1-Dichloroethene ND ug/L 2.0 1 05/24/14 01:35 75-35-4
trans-1,2-DIchloroethene ND ug/L 2.0 1 05/24/14 01:35 156-60-5
1,2-Dichloropropane ND ug/L 2.0 1 05/24/14 01:35 78-87-5
cls-1,3-Dichloropropene ND ug/L 2.0 1 05/24/14 01:35 10061-01-5
I trans-1,3-Dlchioropropene ND ug/L 2.0 1 05/24/14 01:35 10061-02-6
Ethyibenzene ND ug/L 2.0 1 05/24/14 01:35 100-41-4
Methylene Chloride ND ug/L 2.0 1 05/24/14 01:35 75-09-2
1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 05/24/14 01:35 79-34-5
I Tetrachloroethene ND ug/L 2.0 1 05/24/14 01:35 127-18-4
(. Toluene ND ug/L 2.0 1 05/24/14 01:35 108-88-3
1,1,1-Trichloroethane ND ug/L 2.0 1 05/24/14 01:36 71-55-6
I 1,1,2-Trichloroethane ND ug/L 2.0 1 05/24/14 01:35 79-00-5 '
Trichloroethene ND ug/L 2.0 1 05/24/14 01:35 79-01-6
Vinyl chloride ND ug/L 2.0 1 05/24/14 01:35 75-01-4
Surrogates
4-Bromofluorobenzene(S) 89% 70-130 1 05/24/14 01:35 460-00-4
I Toluene d8(S) 98% 70-130 1 05/24/14 01:35 2037-28-5
1,2-Dlchtoroethane-d4(S) 103 %
70-130 1 05/24/14 01:35 17060-07-0
2640C Total Dissolved Solids Analytical Method:SM 2540C
ITotal Dissolved Solids 227 mg/L/ 25.0 1 05/23/14 02:46
350.1 Ammonia Analytical Method:EPA 350.1
Nitrogen,Ammonia 17.6 mg/L`/ 0.50 5 05/21/14 16:23 7664-41-7
I351.2 Total Kjeldahl Nitrogen Analytical Method:EPA 351.2
Nitrogen,Kjeldahl,Total 21.9 mg/L/ 2.5 5 06/02/14 16:54 7727-37-9
I 353.2 Nitrogen,NO2/NO3 pres. Analytical Method:EPA 353.2
Nitrogen,NO2 plus NO3 1.1 mg/L ./ 0.020 1 05/30/14 18:09
' 366.1 Phosphorus,Total Analytical MethodPA 365.1 •
IPhosphorus 2.7 mg/L/ 0.050 1 06/02/14 09:68 7723-14-0 M1
420.4 Phenolics,Total Analytical Method:EPA 420.4
Phenol 0.14 mghL/" 0.015 3 06/03/14 22:08 108-95-2
I i •
REPORT OF LABORATORY ANALYSIS
I This report shall not be reproduced,except In full,
Date:08/04/2014 10:37 AM without the written consent of Pace Analytical Services,Inc.. Page 7 of 33
I

I
Pace Analytical Services]tnc.
e 2225 Riverside Dr:
•aceAnalyticjl Asheville,NC 28804
wwwpecelabacom [phone]
ANALYTICAL RESULTS
I
Project: P PPA 5/19/14 •
Pace Project No.: 92201889
Sample: PE Lab ID: 92201869001 Collected: 05/19/14 10:15 Received: 05/19/14 10:45 Matrix:Water
Report Reg.
Parameters Results Units Limit Limit DF Prepared Analyzed CAS No. Qual
4500CNE Cyanide,Total Analytical Method:SM 4500-CN-E
Cyanide ND mg/L 0.0050 1 08/01/14 12:55 57-12-5
••
i
I
I
I
I
I
1
i i
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full, I
Date:08/04/2014 10:37 AM without the written consent of Pace Analytical Services,Inc.. Page 8 of 33
r

I
' Pace Analytical Services,Inc.
1 'm 2225 Riverside Dr.
=AnalyticalAsheville,NC 28804
W lmfrcc 8b&orn [phone]
II I
ANALYTICAL RESULTS
IProject: P PPA 5/19/14 •.
Pace Project No.: 92201869
Sample: PE LLHO Lab ID: •92201869002 Collected: 05/19/14 10:10 Received: 05/19/14 10:45 Matrix:Water
1 Parameters Results Units Report Reg.
Umit Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631E
Mercury 7.91 ng/L 0.60 1 05/28/14 17:30 05/29/14 16:14 7439-97-6
I
I
I
I ( •
I
I
I
1
I
I
I
REPORT OF LABORATORY ANALYSIS
I This report shell not be reproduced,except In full,
Date:06/04/201410:37 AM without the written consent of Pace Analytical Services,Inc.. Page 9 of 33
I

Pace Analytical Services`}'thc.
2225 Riverside Dr.
=AnalyticalAsheville,NC 28804
wwncnsne►epscanr [phone]
ANALYTICAL RESULTS
Project: P PPA 5/19/14
Pace Project No.: 92201869
Sample: Field Blank PE LLHG Lab ID: 92201869003 Collected: 05/19/14 10:00 Received: 05/19/1410:45 Matrix:Water
Report Reg.
Parameters Results Units Limit Limit DF Prepared Analyzed CAS No. Qual
1631E Mercury,Low Level Analytical Method:EPA 1631E Preparation Method:EPA 1631E
Mercury ND ng/L 0.50 1 05/28/14 17:30 05/29/14 16:21 7439-97-6
•
{
•
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
Date:06/04/2014 10:37 AM without the written consent of Pace Analytical Services,Inc.. Page 10 of 33

I •
Pace Analytical Services,Inc.
ide Dr.
RCB/V 101tiQ/aAsheville,NC N28804
01,04000101.00m [phone]
II
ANALYTICAL RESULTS
I Project: P PPA 5/19/14
Pace Project No.: 92201869
Sample: TRIP BLANK Lab ID: 92201869004 •Collected: 05/19/14 00:00 Received: 05/19/14 10:45 Matrix:Water
I
Parameters Results Units Report Reg.Limit Limit DF Prepared Analyzed CAS No. Qual
624 Volatile Organics Analytical Method:EPA 624
I Acrolein ND ug/L 5.0 1 05/24/14 01:51 107-02-8
Acrylonitrile ND ug/L 50.0 1 05/24/14 01:51 107-13-1
Benzene ND ug/L 2.0 1 05/24/14 01:51 71-43-2
Bromodichloromethane ND ug/L 2.0 1 05/24/14 01:51 75-27-4
I Bromoform ND ug/L 2.0 1 05/24/14 01:51 75-25-2
Bromomethane ND ug/L 2.0 1 05/24/14 01:51 74-83-9
Carbon tetrachloride ND ug/L 2.0 1 05/24/14 01:51 56-23-5 .
Chlorobenzene ND ug/L 2.0 1 05/24/14 01:51 108-90-7
I Chloroethane ND ug/L 2.0 1 05/24/14 01:51 75-00-3
2-Chloroethylvinyl ether ND ug/L
5.0 1 05/24/14 01:51 110-75-8
Chloroform ND ug/L 2.0 1 05/24/14 01:51 67-66-3
Chloromethane ND ug/L 2.0 1 05/24/14 01:51 74-87-3
IDibromochloromethane ND ug/L 2.0 1 05/24/14 01:51 124-48-1
1,1-Dichloroethane ND ug/L 2.0 1 05/24/14 01:51 76-34-3
1,2-Dichloroeihane ND ug/L 2.0 1 05/24/14 01:51 107-08-2
1,1-DIchloroethene ND ug/L 2.0 1 05/24/14 01:51 75-35-4
trans-1,2-Dlchloroethene ND ug/L 2.0 1 06/24/14 01:51 156-60-5
1,2-Dlchloropropane ND ug/L 2.0 1 ' 05/24/14 01:61 78-87-5
cls-1,3-Dlchloropropene ND ug/L 2.0 1 05/24/14 01:51 10061-01-5
trans-1,3-Dlchloropropene ND ug/L 2.0 1 05/24/14 01:51 10061-02-6
I Ethylbenzene ND ug/L 2.0 1 05/24/14 01:51 100-41-4
Methylene Chloride ND ug/L 2.0 1 05/24/14 01:51 75-09-2
1,1,2,2-Tetrachloroethane ND ug/L 2.0 1 05/24/14 01:51 79-34-5
Tetrachloroethene ND ug/L 2.0 1 05/24/14 01:51 127-18-4
Toluene ND ug/L 2.0 1 05/24/14 01:51 108-88-3
1,1,1-Trichloroethane ND ug/L 2.0 1 05/24/14 01:51 71-55-6
1,1,2-Trichloroethane ND ug/L 2.0 1 05/24/14 01:51 79-00-5
Trichloroethene ND ug/L 2.0 1 05/24/14 01:51 79-01-6
Vinyl chloride ND ug/L 2.0 1 05/24/14 01:51 75-01-4
I
Surrogates
4-Bromofluorobenzene(S) 89% 70-130 1 05/24/14 01:51 460-00-4
Toluene-d8(S) 97% 70-130 1 05/24/14 01:51 2037-28-5
1,2-Dichloroethane-d4(S) 104 % 70-130 1 05/24/14 01:51 17060-07-0
I
I •
I
111 j '
REPORT OF LABORATORY ANALYSIS
I This report shall not be reproduced,except In full,
Date:06/04/201410:37 AM without the written consent of Pace Analytical Services,Inc.. Page 11 of 33
I

I
Pace Analytical Servicee7tnc.
n q., r e 2225 Riverside Dr.•
.c?CeAnigl licai Asheville,NC 28804
• �y v.paPefeb& [phone]
1
QUALITY CONTROL DATA
Project: P PPA 5/19/14
Pace Project No.: 92201869
QC Batch: GCSV/17663 Analysis Method: EPA 1664B
QC Batch Method: EPA 1664B Analysis Description: 1684 HEM,Oil and Grease
Associated Lab Samples: 92201869001
METHOD BLANK: 1202826 Matrix: Water
Associated Lab Samples: 92201869001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Oil and Grease mg/L ND 5.0 05/20/14 14:51
I
LABORATORY CONTROL SAMPLE:' 1202827
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L 40 37.5 94 78-114
MATRIX SPIKE SAMPLE: • 1202828
92201875001 Spike MS MS %Rec
Parameter Units Result Conc. Result %Rec Limits Qualifiers
Oil and Grease mg/L ND 40 37.1 93 78-114
•
i
. I
1
I
Results presented on this page ars in the units Indicated by the"Units'column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Dale:06/04/2014 10:37 AM without the written consent or Pace Analytical Services,Inc.. Page 12 of 33

I
Pace Analytical Services,Inc.
I
/+p/�lI )'s • 2226 Riverside Dr.
aVvl•
AshevMe,NC 28804
[phone]
I I,
QUALITY CONTROL DATA •
I Project: P PPA 5119/14
Pace Project No.: 92201889 •
' QC Batch: MERP/6677 Analysis Method: EPA 1631E
I QC Batch Method: EPA 1631E Analysis Description: 1631 E Mercury,Low Level
Associated Lab Samples: 92201869002,92201869003
METHOD BLANK: 1208873 Matrix: Water •
I
Associated Lab Samples: 92201869002,92201869003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
IMercury ng/L ND 0.50 05/29/14 13:25
METHOD BLANK: 1208674 Matrix: Water
I
Associated Lab Samples: 92201869002,92201869003
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 05/29/14 15:05
METHOD BLANK: 1208875 Matrix: Water
Associated Lab Samples: 92201869002,92201869003
I Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury ng/L ND 0.50 05/29/14 16:37
I
LABORATORY CONTROL SAMPLE: 1208676
Spike LCS LCS %Rec
I Parameter Units Conc. Result
%Rec
Limits Qualifiers
Mercury ng/L 5 4.49 90 80-120
I MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1208677 1208678
MS MSD
92201808005 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
IMercury ng/L 2.30 25 25 26.4 26.4 96 96 71-125 0 24
II MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1208679 1208680
MS MSD
92202054001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
111 Mercury ng/L 5.36 25 25 29.8 29.8 98 98 71-125 0 24
I
Results presented on this page are in the unite Indicated by the"Units"column except where en alternate unit Is presented to the right of the result.
1
REPORT OF LABORATORY ANALYSIS
I This report shall not be reproduced,except in full,
Date:06104/201410:37 AM without the written consent of Pace Analytical Services,Inc.. Page 13 of 33
I

I
Pace Analytical Services;Ihc.
e 2225 Riverside Dr.•
•aceAnalytica! Asheville,NC 28804 I tyigps (828)254'-7176
I111
• QUALITY CONTROL DATA
Project: P PPA 5/19/14 .
Pace Project No.: 92201869
QC Batch: MPRP/16000 Analysis Method: EPA 200.7
QC Batch Method: EPA 200.7 Analysis Description: 200.7 MET
Associated Lab Samples: 92201869001
METHOD BLANK: 1202890 Matrix: Water
Associated Lab Samples: 92201869001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Antimony ug/L ND 5.0 05/21/14 16:59
I
Arsenic ug/L ND 10.0 05/21/14 16:59
Beryllium ug/L ND 1.0 05/21/14 16:59
Cadmium ug/L ND 1.0 05/21/14 16:59
Caidum ug/L ND 100 05/21/14 16:59
Chromium ug/L ND 5.0 05/21/14 16:59
Copper ug/L ND 5.0 05/21/14 16:59
Hardness,Total(SM 23406) ug/L ND 662 05/21/14 16:59
Lead ug/L ND 5.0 05/21/14 16:59
Magnesium ug/L ND 100 05/21114 16:59
Nickel ugh ND 5.0 05/21/14 16:59
Selenium ugh ND 10.0 05/21/14 16:59
Silver ug/L ND 5.0 05/21/14 16:59
Thallium ug/L ND 10.0 05/21/14 16:59
Zinc ug/L ND 10.0 05/21/14 16:59
LABORATORY CONTROL SAMPLE: 1202891 ,11
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Antimony ugh 500 478 96 85-115 •
Arsenic ugh 500 462 92 85-115
Beryllium ug/L 500 482 96 85-115
Cadmium ug/L 500 480 96 85-116
Calcium ug/L 6000 4780 96 85-115 I Chromium ug/L 500 479 96 85-115
Copper ug/L 500 463 93 85-115
Hardness,Total(SM 2340B) ug/L 32000 •
Lead ug/L 500 473 95 85-115
Magnesium ug/L 5000 4880 97 85-115
Nickel ug/L 500 481 96 85-115
Selenium ug/L 500 453 91 85-115
Silver ugh - 250 241 96 85-115
Thallium ug/L 500 455 91 85-115
I
Zinc ugh 500 475 95 85-115
I
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
i
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:06/04/2014 10:37 AM without the written consent of Pace Analytical Services,Inc.. Page 14 of 33
I

I
na Pace Analytical Services,Inc.
I
•e - 2225 Riverside Dr.
��/ jCc7/ Asheville,NC 28804
Int W.pe0.kts.001n [phone]
Ii
QUALITY CONTROL DATA
I Project: PPPA 5/19/14
Pace Project No.: 92201869 •
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1202892 1202893
I MS MSD
92200581002 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Antimony ug/L ND 600 500 475 477 95 95 70-130 0 20
I Arsenic ug/L ND 500 600 459 484 •91 92 70-130 1 20
Beryllium ug/L ND 500 600 467 472 93 94 70-130 1 20
Cadmium ug/L ND 600 500 470 474 94 95 70-130 1 20
Caldum ug/L 6170 5000 5000 10800 10800 93 94 70-130 0 20
I Chromium ug/L ND •500
500 472 474 94 95 70-130 0 20
Copper ugh ND 500 500 462 467 92 93 70-130 1 20
Hardness,Total(SM 2340B) ug/L 23600 54100 54400 1 20
Lead ug/L • ND 500 500 462 468 92 93 70-130 1 20
I
Magnesium ug/L
ug/L 2000 5000 5000 6570 6640 91 93 70-130 1 20
Nickel ND 500 500 473 477 94 95 70-130 1 20
Selenium ug/L ND 500 500 • 451 451 90 90 70-130 0 20
Silver ug/L ND 250 250 236 237 94 95 70-130 0 20
I Thallium ug/L ND 500 500 442 451 88 90 70-130 2 20
Zinc ug/L 23.8 500 500 482 485 92 92 70-130• 1 20
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1202894 1202895
MS MSD
92201869001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
I
Antimony ug/L
ug/L ND 500 500 480 481 96 96 70-130 0 20
Arsenic ND 500 500 467 473 93 95 70-130 1 20
Beryllium ug/L ND 500 500 476 477 95 95 70-130 0 20
Cadmium ug/L ND 600 500 472 474 94 95 70-130 0 20
I Calcium ug/L
ug/L 12000 5000 5000 16400 16700 89 93 70-130 1 20
Chromium ND 500 500 475 476 95 95 70-130 0 20
Copper ug/L 8.9 500 500 475 476 93 93 70-130 0 20
Hardness,Total(SM 2340B) ug/L 45000 74700 75800 1 20
I
Lead ug/L ND 500 500 460 459 92 92 70-130 0 20
Magnesium ug/L 3840 5000 5000 8190 8290 91
93 70-130 1 20
NIckel ug/L ND 500 500 473 473 94 94 70-130 0 20
' Selenium ug/L ND 500 500 469 460 93 91 70-130 2 20
I Silver ug/L ND 250 250 238 238 95 95 70-130 0 20
Thallium ug/L ND
500 500 436 441 87 88 70-130 1 20
Zinc ug/L 48.4 500 500 617 519 94 94 70-130 0 20
I
I
Results presented on this page are In the units indicated by the"Units"column except where an alternate unit Is presented to the right of UI.result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
without 06/04/2014 10:37AM the written consent of Pace Analytical Services,Inc.. Page 15 of 33

Pace Analytical Services?Inc.
e 2225 Rhrorside Dr.' I aceAnalytical Asheville,NC 28804
ttw pecelab&com (828)254'4176
QUALITY CONTROL DATA
I
Project: P PPA 6/19/14
Pace Project No.: 92201869
QC Batch: MSV/26942 Analysis Method: EPA 624
QC Batch Method: EPA 624 Analysis Description: 624 MSV
Associated Lab Samples: 92201869001,92201869004
METHOD BLANK: 1206118 Matrix: Water
Associated Lab Samples: 92201869001,92201869004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1,1-Trichloroethane ug/L ND 2.0. 05/24/1400:12
1,1,2,2-Tetrachloroethane ug/L ND 2.0 05/24/14 00:12
1,1,2-Trichloroethane ug/L ND 2.0 05/24/14 00:12
1,1-Dichloroethane ug/L ND. 2.0 05/24/1400:12.
1,1-Dichioroethene ug/L ND 2.0 05/24/14 00:12
1,2-Dichloroethane ug/L ND 2.0 05/24/14 00:12
1,2-Dichioropropane ug/L ND 2.0 05/24/14 00:12
2-ChtoroethyMnyl ether ug/L ND 5.0 05/24/14 00:12
Acroleln ug/L ND 5.0 05/24/14 00:12
Acrylonitrile ug/L ND 50.0 05/24/14 00:12
Benzene ug/L ND 2.0 06/24/14 00:12
Bromodichioromethane ug/L ND 2.0 05/24/14 00:12
Bromoform ug/L ND 2.0 05/24/14 00:12
Bromomethane ug/L ND 2.0 05/24/14 00:12
I
Carbon tetrachloride ug/L ND 2.0 05/24/14 00:12 (.
Chlorobenzene ug/L ND 2.0 05/24/14 00:12
Chloroethane ug/L ND 2.0 05/24/14 00:12
Chloroform ug/L ND 2.0 05/24/14 00:12
Chloromethane ug/L ND 2.0 05/24/14 00:12
cis-1,3-Dlchloropropene ug/L ND 2.0 05/24/14 00:12
Dibromochloromethane ug/L ND 2.0 05/24/14 00:12
Ethylbenzene ug/L ND 2.0 05/24/14 00:12
Methylene Chloride ug/L ND 2.0 05/24/14 00:12
Tetrachloroethene ug/L ND 2.0 05/24/14 00:12
Toluene ug/L ND 2.0 05/24/14 00:12
trans-1,2-Dichioroethene ug/L ND 2.0 05/24/14 00:12
trans-1,3-Dlchioropropene ug/L ND 2.0 05/24/1400:12
Trichloroethene ug/L ND 2.0 05/24/14 00:12
Vinyl chloride ug/L ND 2.0 05/24/14 00:12 .
1,2-Dichloroethane-d4(S) % 103 70-130 05/24/14 00:12
4-Bromofluorobenzene(S) % 98 70-130 05/24/14 00:12
Toluene-d8(S) % 97 70-130 05/24/14 00:12
LABORATORY CONTROL SAMPLE: 1206119
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
1,1,1-Trichloroethane ug/L 20 21.0 105 • 52-162
1,1,2,2-Tetrachloroethane ug/L 20 21.3 106 46-157
1,1,2-Trichloroethane ug/L 20 21.9 109 52-150
1,1-Dichloroethane ug/L 20 20.8 104 59-155
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit I.presented to the right or the result.
I
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
Date:06/04/2014 10:37 AM without the written consent of Pace Analytical Services,Inc.. Page 16 of 33

I
Pace Analytical Services,Inc.
aj /��y� 2225 Riverside Dr.
CBt+411c lytical Asheville,NC 28804
awltcpartgNbacom [phone]
I (
QUALITY CONTROL DATA
I Project: P PPA 5/19/14
Pace Project No.: 92201869
LABORATORY CONTROL SAMPLE: 1206119
I Spike LCS LCS %Rec •
Parameter Units Conc. Result
%Rec LimitsQualifiers •
1,1-Dlchloroethene ug/L 20 20.9 104 1-234
I 1,2-Dichloroethane ug/L 20 22.2 111 49-155
1,2-Dichloropropane ug/L 20 21.6 108 1-210
2 Chloroefhylvinyl ether ug/L 40 42.3 106 1-305
Acroleln ug/L 100 101 101 15-152
Acrylonitrile ug/L 100 108 108 76-132
I Benzene ug/L 20 23.0 •
115 37-151
Bromodichloromethane
ug/L20 20.8 104 35-155
Bromoform ug/L 20 18.3 92 45-189
Bromomethane ug/L - 20 25:5 127 1-242
Carbon tetrachloride ug/L 20 20.4 102 70-140
- Chiorobenzene ug/L 20 20.5 103 37-160
Chloroethane ug/L 20 22.4 112 14-230
Chloroform ug/L 20 21.4 107 51-138
I Chloromethane ug/L 20 17.5 88 1-273
ds-1,3 Dlchloropropetle ug/L 20 20.5 103 1-227
Dibromochloromethane ug/L 20 19.4 97 53-149
Ethylbenzene ug/L 20 20.7 104 37-162
IMethylene Chloride ug/L 20 21.8 109 1-221
{ Tetrachloroethene ug/L 20 21.0 105 64-148
Toluene ug/L 20 21.1 106 47-150
trans-1,2-Dichloroethene ug/L 20 21.1 106 54-158
trans-1,3-DIchioropropene ug/L 20 20.3 101 17-183
Trichloroethene ug/L 20 22.5 113 71-157
Vinyl chloride ug/L 20 21.8 109 1-251
1,2-Dichloroethane-d4(S) % 106 70-130
4-Bromofluorobenzene(S) % 98 70-130
I Toluene-d8(S) % 99 70-130
I
•I
I
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right or the result..
I
REPORT OF LABORATORY ANALYSIS
I This report shall not be reproduced,except in full,
without Date:06104/201410:37 AM the written consent of Pace Analytical Services,Inc.. Page 17 of 33
I

Pace Analytical Serviced;Inc.
I
a 2225 Riverside Dr.
(7
•aceAnalyhcal Asheville,NC 28804
ikwwcom [phone]
f f
QUALITY CONTROL DATA
Project: P PPA 5/19/14
Pace Project No.: 92201889
QC Batch: OEXT/27846 Analysis Method: EPA 825
QC Batch Method: EPA 625 Analysis Description: 625 MSS
Associated Lab Samples: 92201869001
METHOD BLANK: 1204687 Matrix: Water '
Associated Lab Samples: 92201869001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,2,4-Trichlorobenzene ug/L ND 5.0 05/27/14 20:33
1,2-Dichlorobenzene ug/L ND 5.0 05/27/14 20:33
1,2-Diphenylhydrazine ug/L ND 5.0 05/27/14 20:33 .
1,3-Dichlorobenzene ug/L ND 5.0 05/27/14 20:33
1,4-Dichlorobenzene ug/L ND 5.0 05/27/14 20:33
2,4,6-Trichlorophenol ug/L ND 10.0 05/27/14 20:33111
2,4-Dlchlorophenol ug/L ND 5.0 05/27/14 20:33
2,4-Dimethylphenol ug/L ND 10.0 05/27/14 20:33
2,4-Dinitrophenol ug/L ND 50.0 05/27/14 20:33
2,4-Dinitrotoluene ug/L ND 5.0 05/27/14 20:33
2,6-Dlnitrotoluene ug/L ND 5.0 05/27/14 20:33
2-Chloronaphthalene ug/L ND 5.0 05/27/14 20:33
2-Chlorophenol ug/L ND 5.0 05/27/1420:33
2-Nitrophenol ug/L ND 5.0 05/27/14 20:33
3&4-Methylphenol(m&p Cresol) ug/L ND 10.0 05/27/14 20:33 I
3,3'-Dlchlorobenzidine ug/L ND 25.0 05/27/14 20:33
4,6-Dlnitro-2-methylphenol ug/L ND 20.0 05/27/14 20:33
4-Bromophenylphenyl ether ug/L ND 5.0 05/27/14 20:33
4-Chlorophenytphenyl ether ug/L ND 5.0 05/27/14 20:33
4-Nitrophenol ug/L ND 50.0 05/27/14 20:33
Acenaphthene . ug/L ND 5.0 05/27/14 20:33
Acenaphthylene ug/L ND 5.0 05/27/14 20:33 •
Anthracene ug/L ND 5.0 05/27/14 20:33
Benzldlne ug/L ND 50.0 05/27/14 20:33
Benzo(a)anthracene ug/L ND 5.0 05/27/14 20:33
Benzo(a)pyrene ug/L ND 5.0 05/27/14 20:33
Benzo(b)fluoranthene ug/L ND 5.0 05/27/14 20:33
Benzo(g,h,l)perylene ug/L ND 5.0 05/27/14 20:33
Benzo(k)fluoranthene ug/L ND 5.0 05/27/14 20:33
bls(2-Chloroethoxy)methane ug/L ND 10.0 05/27/14 20:33
bis(2-Chloroelhyl)ether ug/L ND 5.0 05/27/14 20:33
bls(2-Chlorolsopropyl)ether ug/L ND 5.0 05/27/14 20:33
bis(2-Ethylhexyl)phthalate ug/L ND 5.0 05/27/14 20:33
Butylbenzylphthalate ug/L ND 5.0 05/27/14 20:33
Chrysene ug/L ND 5.0 05/27/14 20:33
Dl-n-butylphthalate ug/L ND 5.0 05/27/14 20:33
Dl-n-octylphthalate ug/L ND 5.0 05/27/14 20:33
Dibenz(a,h)anthracene ug/L ND 5.0 05/27/1420:33
Diethylphlhalate ug/L ND 5.0 05/27/14 20:33
Dimethylphthalate ug/L ND 5.0 05/27/14 20:33
Fluoranthene ug/L ND 5.0 05/27/14 20:33
Results presented on this page are In the unite Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full,
Date:06/04/2014 10:37 AM without the written consent of Pace Analytical Services,Inc.. Page 18 of 33

I
Pace Analytical Services,Inc.
2225 Riverside Dr.
ace Analytical AshevNle,NC 28804
wwwpaogbbaeom [phone]
' II
QUALITY CONTROL DATA
I Project: P PPA 5/19/14
Pace Project No.: 92201869
METHOD BLANK: 1204887 Matrix: Water .
I Associated Lab Samples: 92201869001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
I Fluorene ug/L ND 5.0 05127/14 20:33
HexacNoro-1,3-butadiene ug/L ND 5.0 05/27/14 20:33
Hexachlorobenzene ug/L ND 5.0 05/27/14 20:33 •
Hexachiorocyclopentadiene ug/L ND 10.0•05/27/14 20:33
I Hexachloroethane ug/L ND 5.0 05/27/1420:33
Indeno(1,2,3 cd)pyrene ug/L ND 5.0 05127/1420:33
Isophorone ugh ND 10.0 05/27/14 20:33
N-Nitroso-di-n-propylamine ugh ND 5.0 05127/14 20:33
N-Nitrosodimethylamine ug/L ND 5.0 05/27/14 20:33
I N-Nfirosodiphenytamine ug/L ND 10.0 05/27/14 20:33
Naphthalene ug/L ND 5.0 05/27/14 20:33
Nitrobenzene ug/L ND 5.0 05/27/14 20:33
Pentachlorophenol ug/L ND 10.0 05/27/14 20:33
I Phenanthrene
ug/L ND 5.0 05/27/14 20:33
Phenol ug/L ND 5.0 05/27/14 20:33
Pyrene ug/L ND 5.0 05/27/14 20:33
2,4,6-Tribromophenol(S) % 60 10-137 05/27/14 20:33
2-Fluoroblphenyl(5) % 44 15-120 05/27/14 20:33
( 2-Fluorophenol(S) % 24 10-120 05/27/14 20:33
Nitrobenzene-d5(S) % 51 10-120 05/27/14 20:33
Phenol-d6(S) % 15 10-120 05/27/14 20:33
Terphenyl-d14(S) % ' 84 11-131 05/27/1420:33
LABORATORY CONTROL SAMPLE: 1204688
I Spike LCS LCS %Rec
Parameter Units Conc. Result
%Rec Limits Qualifiers
1,2,4-Trlchlorobenzene ug/L 50 35.7 71 44-142
1,2-Dichlorobenzene ug/L 50 32.4 85 32-129
I
1,2-Diphenylhydrezine ug/L 50 33.4 67 25-160
1,3 Dichlorobenzene ug/L 50 32.1 64 1-172
1,4-Dichlorobenzene ug/L 50 33.4 67 20-124
2,4,6-Trichiorophenol ug/L 50 39.4 79 37-144
I 2,4-Dichiorophenol ug/L 50 38.5 77 1-191
2,4 Dimethylphenol
ug/L 50 34.4 69 .32-119
2,4-Dinitrophenol uglL 250 233 93 1-181
2,4-Dinitrotoluene ug/L 50 52.9 106 39-139
I 2,6-Dlydtrotoluene ug/L 60 50,5 101 50-158
2-Chloronaphthalene ug/L 50 35.2 70 60-118
2-Chlorophenol ug/L 50 31.0 62 23-134
2-Nitrophenol ug/L 50 44.3 89 29-182
I 3&4-Methytphenol(m&p Cresol) ug/L 50 25.0 50 25 150
3,3'-Dichiorobenzidine ug/L 100 77.1 77 1-262
4,8-DInIUo-2-methylphenoi ug/L 100 96.7 97 1-181
4-Bromophenyiphenyl ether ug/L 50 40.0 80 53-127
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right or the result.
I
REPORT OF LABORATORY ANALYSIS
I This report shall not be reproduced,except In tuft,
Date:06/04/201410:37 AM without the written consent of Pace Analytical Services,Inc.. Page 19 of 33

1
Pace Analytical Servlcei,Mc.
• 0 2226 Riverside Dr..
aceAnalytical Asheville,NC 28804
aww.pscelabacom [phone]
• QUALITY CONTROL DATA
I
Project: P PPA 5/19/14
I
Pace Project No.: 92201869
LABORATORY CONTROL SAMPLE: 1204688
Spike LCS LCS %Rec • I
Parameter Units Conc. Result %Rec Limits Qualifiers
4-Chlorophenylphenyl ether ug/L 50 40.2 80 25-158 •
4-Nitrophenoi ug/L 260 121 49 1-132 I Acenaphthene ugh 60 35.5 71 47-145
Acenaphthylene ugh 60 34.7 69 33-145
Anthracene ug/L 60 41.9 84 1-166
Benzldine ugh 100 30.3J 30 25-150
Benzo(a)anthracene ugh 60 39.8 80 33-143
I
Benzo(a)pyrene ug/L 60 40.8 82 17-163
Benzo(b)fluoranthene ug/L 50 40.9 82 24-159
Benzo(g,h,l)perylene ug/L 50 30.9 62 1-219
Benzo(k)fluoranthene ug/L 50 38.4 77 11-162
I
bls(2-Chloroethoxy)methane ug/L 50 38.2 76 33-184
bls(2-Chloroethyl)ether ug/L 50 35.4 71 12-158
bls(2-Chlorolsopropyl)ether ugh 50 36.0 72 36-166
bis(2-Ethylhexyl)phlhalate ug/L 50 41.2 82 8-158
Butylbenzylphthalate ugh 50 42.5 85 1-152
Chrysene ug/L 50 39.7 79 17-168
DI-n-butylphthalate ug/L 50 38.3 77 1-118
Dl-n-octylphthalate ugh 60 40.4 81 4-146
Dibenz(a,h)anthracene ug/L 50 32.2 64 1-227
D iethyiphthatate ug/L 50 38.2 76 1-114
D imethyiphthalate ug/L 50 40.8 82 1-112
Fluoranthene ug/L 50 45.1 90 26-137
Fluorene ug/L 50 40.6 81 59-121
Hexachloro-1,3-butadiene ugh 50 36.8 74 24-116 .
Hexachlorobenzene ug/L 50 40.3 81 1-152 •
Hexachlorocyclopentadlene ugh 50 31.7 63 25-150
Hexachloroethane ug/L 50 35.4 71 40-113
Indeno(1,2,3-cd)pyrene • ug/L 50 25.8 52 1-171
Isophorone ugh 50 49.4' 99 21-196
N-Nltroso-di-n-propyiamine ug/L 50 34.2 88 1-230
N-Nkrosodlmethylamine ug/L 50 21.6 43 25-150
N-Nitrosodlphenylamine ugh. 50 32.6 65 25-150
Naphthalene ugh 50 32.2 64 21-133
Nitrobenzene ug/L 50 50.6 101 35-180
Pentachlorophenol ug/L 100 77.2 77 14-176
Phenanthrene ug/L 50 41.0 82 54-120
Phenol ugh. 50 16.0 32 5-112
Pyrene ugh 50 41.4 83 52-115
2,4,6-Tribromophenol(S) % 100 10-137
2-Fluoroblphenyl(S) % 74 15-120
2-Fluorophenol(S) % 41 10-120
Nitrobenzene-d5(8) % 93 10-120
Phenol-d6(S) % 28 10-120
Terphenyl-d14(S) % 90 11-131
•
Results presented on this page are In the unite Indicated by the"Units"column except where an alternate unit Is presented to the fight or the result. 1
•
I
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:06/04/2014 10:37 AM without the written consent of Pace Analytical Services,Inc.. Page 20 of 33

Pace Analytical Services,Inc.
I
•
s • 2225 Riverside Dr.
aceAnalyticl Asheville,NC 28804
16144 [phone]
1 ( ..
QUALITY CONTROL DATA
A Project: P PPA 5/19/14
Pace Project No.: 92201869
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1204689 1204690
I
MS MSD
92201745002 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
1,2,4-Trichlorobenzene ug/L ND 100 100 51.9 37.5 52 38 44-142 32 30 MO,R1
I 1,2-Dichlorobenzene ug/L ND 100 100 47.3 34.9 47 35 32-129 30 3010
1,2-Dlphenyihydrazine ug1L ND 100 100 62.4 50.7 62 51 25150 2! 30
1,3-Dichlorobenzene tg/L ND 100 100 46.0 35.2 46 35 1-172 26 3010
1,4-Dichlorobenzene ug/L ND 100 100 49.2 37.0 49 37 20-124 28 3010
I
2,4,6-Trichlorophenol ug/L ND 100 100 66.2 53.2 66 53 37-144 22 30
2,4-Dlchlorophenol ug/L ND 100 100 48.8 35.3 49 35 1-191 32 30 R1
2,4-Dimethylphenol ug/L ND 100 100 44.5 29.9 44 30 32-119 39 30 M0,R1
2,4-DIr trophenoi ug/L ND 500 500 221 238 44 48 1-181 7 30
I
2,4-Dlnitrotoluene ug/L ND 100 100 82.6 78.9 83 79 39-139 5 30
2,6-Dlnitrotoluene ug/L ND 100 100 84.9 72.0 85 72 50.158 16 30
2-Chloronaphthalene ug/L ND 100 100 55.9 40.6 56 41 60-118 32 30 MO,R1
2-Chlorophenol ug/L ND 100 100 43.2 32.2 43 32 23-134 29 3010
I 2-Nltrophenol ug/L . ND 100 100 61.4 43.6 61 44 29-182 34' 30 R1
3&4-Methytphenol(m&p ug/L ND 100 100 34.8 25.8 35 26 25-150 30 3010
Cresol)
3,3'-Dlchlorobenzldlne ug/L . ND 200 200 73.8 70.0 37 35 1-262 5 30
4,6 Dlnitro-2-methylphenol tg/L ND 200 200 120 120 60 60 1-181 1 ' 30
4-Bromopheriylphenyl ether ugh ND 100 100 72.2 61.0 72 61 53 127 17 30
1 4-Chiorophenylphenyl ether ug/L ND !00 100 60.8 51.3 61 51 25-158 17 30
4-Nitrophenol ug/L ND 500 500 210 234 42 47 1-132 11 30
Acenaphthene ugh ND 100 100 51.6 39.5 51 40 47-145 26 30 MO •
I Acenaphthylene ug/L ND 100 100 53.2 40.7 63 41 33-145 27 30
Anthracene ug/L ND 100 100 74.8 68.2 75 68 1-166 9 30
Benzidine tg/L ND 200 200 ND ND 0 0 25-150 30 MO
1 Benzo(a)anthracene ugh ND 100 100 67.7 66.9 68 67 33-143 1 30
I
Benzo(a)pyrene ug/L ND 100 100 65.3 66.7 65 67 17-163 2 30
Benzo(b)fluoranthene ug/L ND 100 100 67.5 68.7 68 69 24169 2 30
Benzo(g,h,l)perylene ugh ND 100 100 47.1 50.6 47 51 1-219 7 30
Benzo(k)fluoranthene ugh ND 100 100 63.1 64.3 63 64 11-162 2 30
I
bls(2-Chloroethoxy)methane ug/L ND 100 100 50.9 34.6 51 35 33-184 38 30 R1
bis(2-Chloroethyl)ether ug/L ND 100 100 50.0 37.3 50 37 12-158 29 30 10
bis(2-Chloroisopropyi)ether ug/L ND 100 100 44.9 31.7 45 32 36-166 34 30 10,MO,
R1
bis(2-Efliyihexyl)phthalate
ug/L ND 100 100 77.6 .72.3 78 72 8-158 7 30
Butylbenzylphthalate ug/L ND 100 !OD 81.6 72.8 82 73 1-152 11 30
Chrysene ug/L ND 100 100 70.7 70.0 71 70 17-168 1 30
DI-n-butylphthalate ug/L ND 100 100 66.9 63.0 , 67 63 1-118 6 30
I Dl n octylphthalate ug/L ND 100 100 69.3 71.4 69 71 4-146 3 30
Dibenz(a,h)anthracene trglL ND 100 100 50.5 51.5 51 51 1-227 2 30
Diethylphthalate ugh ND
100 100 60.5 56.4 61 56 1-114 7 30
Dlmethylphthalate ug/L ND 100 100 68.8 58.4 89 58 1-112 16 30
Fluoranthene ug/L ND 100 100 72.2 76.1 72 78 26-137 5 30
I Fluorene
ug/L ND 100 100 81.3 53.7 61 54 59-121 13 30 MO
Hexachloro-1,3-butadlene ug/L ND 100 100 54.7 38.0 55 38 24 116 36 30 R1
Hexachlorobenzene ug/L ND 100 100 70.8 61.9 71 82 1-152 13 30
' 1 Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS •
I This report shall not be reproduced,except in full,
Date:06/04/2014 10:37 AM without the written consent of Pace Analytical Services,Inc.. Page 21 of 33
I

I
Pace Analytical Services;Inc.
I•e 2226 Riverside Dr.
aceAnalytica! Asheville,NC 28804
Nw.p
eaeafeba.com [phone]
QUALITY CONTROL DATA
Project: P PPA 5/19/14
Pace Project No.: 92201869
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1204889 1204690
MS MSD
92201745002 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Hexachlorocyciopentadiene ug/L ND 100 100 55.4 36.0 55 36 25-150 42 30 R1
Hexachloroethane ug/L ND 100 100 50.7 38.1 51 38 40-113 28 30 10,M0
Indeno(1,2,3-cd)pyrene ug/L ND 100 100 39.0 40.8 39 41 1-171 4 30
Isophorone ug/L ND 100 100 60.0 42.3 60 42 21-196 35 30 R1
N-Nitroso-di-n-propylamine ug/L ND 100 100 38.7 30.9 39 31 1-230 22 3010
N-Nitrosodimethylamine ug/L ND 100 100 39.6 30.3 40 30 25-150 27 3010
N-Nitrosodiphenylamine ug/L ND 100 100 61.2 53.3 61 53 25-150 14 30
Naphthalene . ug/L ND 100 100 46.5 33.7 46 34 21-133 .32 30 R1
Nitrobenzene ug/L ND 100 100 71.7 53.3 72 53 35-180 29 30
Pentachlorophenol ug/L ND 200 200 105 115 53 57 14-176 9 30
I
Phenanthrene ug/L ND 100 100 73.5 86.8 74 67 54-120 10 30
Phenol ug/L ND 100 100 31.0 21.1 31 21 5-112 38 3010,R1
Pyrene ug/L ND 100 100 84.6 69.7 85 70 52-115 19 30
2,4,6-Tribromophenol(S) % 79 75 10-137
I
2-Fluorobiphenyl(S) % 57 40 15-120
2-Fluorophenol(S) % 36 24 10-120 10
Nitrobenzene-d5(S) % • 64 47 10-120
Phenol-d6(S) % 27 18 10-120 10
Terphenyi-d14(S) % 85 72 11-131 i
• 1
I
• I
•
I
• I
I
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
I
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:06/04/2014 10:37AM without the written consent of Pace Analytical Services,Inc.. Page 22 of 33
I

1
Pace Analytical Services,Inc.
1 .aceAnalytical0 2225 Riverside Dr.
AshevBle,NC 28804
rnvNtpecels¢a gam [phone]
`
1 (
QUALITY CONTROL DATA
I
Project: P PPA 5/19/14
Pace Project No.: 92201869
QC Batch: WET/31168 Analysis Method: SM 2540C
I
QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids
Associated Lab Samples: 92201869001
METHOD BLANK: 1205440 Matrix: Water
I
Associated Lab Samples: 92201869001
Blank Reporting
Parameter , , Units Result Limit Analyzed Qualifiers
ITotal Dissolved Solids mg/L ND 25.0 05/23/14 02:45
. LABORATORY CONTROL SAMPLE: 1205441
I
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids mg/L • 250 238 95 80-120
I
SAMPLE DUPLICATE: 1205442
92201869001 Dup Max
Parameter Units Result Result RPD RPD Qualifiers
I
Total Dissolved Solids mg/L 227 204 11 20
I •
I
1
I
I
I
I
1 Results presented on this page are In the milts Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
I Date:06/04/2014 10:37 AM • This report shell not be reproduced,except In full,
without the written consent of Pace Analytical Services,Inc.. Page 23 of 33
I

Pace Analytical Services{;Iilc.
do a 2225 Serviced;
c.r.
aceAnalytt!cal Asheville,NC 28804
opm (828)2547176
QUALITY CONTROL DATA
1
Project: P PPA 5/19/14 I Pace Project No.: 92201869
QC Batch: WETA/19062 Analysis Method: EPA 350.1
QC Batch Method: EPA 350.1 Analysis Description: 350.1 Ammonia I Associated Lab Samples: 92201869001
METHOD BLANK 1203631 Matrix: Water
Associated Lab Samples: 92201869001
I
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,Ammonia mg/L ND 0.10 05/21/14 15:24 '
LABORATORY CONTROL SAMPLE: 1203632
Spike LCS LCS %Rec
I
Parameter Units Conc. Result %Rec Limits Qualifiers
Nitrogen,Ammonia mg/L 5 5.0 99 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1203633 1203634
I
MS MSD
92201857002 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
I
Nitrogen,Ammonia mg& • 18.6 5 5 23.7 22.7 102 83 90-110 4 20 M1 (
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1203635 1203636 I MS MSD
92201987001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Nitrogen,Ammonia mg/L ND 5 5 5.3 5.2 105 104 90-110 1 20
I
I
•
1
I
Results presented on this page are in the units indicated by the"Units"column except where an alternate unit Is presented to the right of the result. I
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full, I Date:06/04/2014 10:37 AM without the written consent of Pace Analytical Services,Inc.. Page 24 of 33

Pace Analytical Services,Inc.
I
q.. r /+,,f'e 2225 Riverside Dr.
CeAnaI�VQI Asheville,NC 28804
w i cpsaf.Mccm [phone]
i
1 ( .
QUALITY CONTROL DATA
I Project: P PPA 5/19/14
Pace Project No.: 92201869
QC Batch: WETA/19148 Analysis Method: EPA 351.2
I QC Batch Method: EPA 351.2 Analysis Description: 351.2 TKN
Associated Lab Samples: 92201869001
METHOD BLANK: 1210376 Matrix: Water
I Associated Lab Samples: 92201869001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
I
Nitrogen,Kjeldahl,Total 'mg/L ND 0.50 08/02/14 13:36
. LABORATORY CONTROL SAMPLE: 1210377 .
I Spike LCS LCS %Rec
Parameter Units Conc. Result
%Rec Llmtts Qualifiers
Nitrogen,Kjeldahl,Total mg/L 10 10.8 108 90-110
•
IMATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1210378 1210379
MS MSD
92202941001 Spike Spike MS MSD MS MSD %Rec Max
I
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Nitrogen,Kjeldahl,Total mg/L 7.1 10 10 17.1 18.9 101 119 90-110 10 20 M1
I MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1210380 1210381
MS MSD
92202741001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
1 Nitrogen,Kjeldahl,Total mg/L 1.0 10 10 11.8 11.1 108 101 90-110 6 20
I
I
I
I
I
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
I This report shell not be reproduced,except In full,
Date:06/04/201410:37 AM without the written consent of Pace Analytical Services,Inc.. Page 25 of 33

1
n
(4
Pace Analytical Services,Inc.
0 2228 Riverside Dr."
aceAnalytical Asheville,NC 28804
w►nyp9cebps aom [phone]
QUALITY CONTROL DATA
1
Project: P PPA 5/19/14
I
Pace Project No.: 92201869
QC Batch: WETA/19158 Analysis Method: EPA353.2
QC Batch Method: EPA 353.2 Analysis Description: 353.2 Nitrate+Nitrite,preserved I Associated Lab Samples: 92201889001
METHOD BLANK: 1210804 Matrix: Water •
Associated Lab Samples: 92201869001 1
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen,NO2 plus NO3 mg/L ND 0.020 06/30/14 17:45
I
LABORATORY CONTROL SAMPLE: 1210805 •
Spike LCS LCS %Rec
Parameter Units Conc. Result %Rec Umits Qualifiers
Nitrogen,NO2 plus NO3 mg/L 2.5 2.5 100 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1210806 1210807
MS MSD
92202530001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual I Nitrogen,NO2 plus NO3 mg/L 0.070 2.6 2.5 2.6 2.6 103 103 75-125 0 20
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1210808 1210809 I MS MSD
92202481002 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
. Nitrogen,NO2 plus NO3 mg/L 19.3 2.5 2.5 21.8 21.8 101 100 75-125 0 20
I
I
I
I
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result. I
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except In full, I Date:06/04/2014 10:37 AM without the written consent of Pace Analytical Sbrvlces,Inc.. Page 26 of 33

I
Pace AnalytI (
ical Services,Inc.
y 2225 Riverside Dr.
aceAnalytical Asheville,NC 28804
Win Pni*Co r [phone]
Ii
QUALITY CONTROL DATA
I
Project: P PPA 5/19/14
• Pace Project No.: 92201869
QC Batch: WETN19168 Analysis Method: EPA365.1
l
QC Batch Method: EPA 365.1 Analysis Description: 365.1 Phosphorus,Total
Associated Lab Samples: 92201869001
METHOD BLANK: 1211208 Matrix: Water
I
Associated Lab Samples: 92201869001
Blank Reporting
Parameter . Units Result Limit Analyzed Qualifiers
I
Phosphorus mg/L ND 0.050 06/02/14 09:46
LABORATORY CONTROL SAMPLE: 1211209
I Spike LCS LCS %Rec
Parameter Units Conc. Result
%Rec Limits Qualifiers
Phosphorus mg/L 2.5 2.3 93 90-110
IMATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1211210 1211211
MS MSD
- 92201563001 Spike Spike . MS MSD MS MSD %Rec Max
I
Parameter Units Result Conc. . Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Phosphorus mg/L ND 2.5 2.5 - 2.5 2.6 101 102 90-110 1 20
I MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1211212 1211213
MS MSD
92201869001 Spike Spike MS MSD MS MSD %Rec Max
I .
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
I
Phosphorus mg/L 2.7 2.5 2.5 6.6 5.5 114 111 90-110 1 20 M1
I
I
I
I
I
Results presented on ails page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
I
This report shall not be reproduced,except In full,
Date:06/04/201410:37 AM This
the written consent of Pace Analytical Services,Inc.. Page 27 of 33
I

I
Pace Analytical ServiceLOnc.
aceAnalyfical a 2225 Riverside Dr.
x+ pa�Ietaaom Asheville,NC 28804
[phone]
QUALITY CONTROL DATA
Project: P PPA 5/19/14 - I Pace Project No.: 92201869
QC Batch: WETN19194 Analysis Method: EPA 420.4
QC Batch Method: EPA 420.4 Analysis Description: 420.4 Phenolics
I
Associated Lab Samples: 92201869001
METHOD BLANK: 1212713 Matrix: Water
Associated Lab Samples: 92201869001
I
Blank Reporting
Parameter Units Result Limit Analyzed. Qualifiers
Phenol mg/L ND 0.0050 06/03/14 20:51
I
LABORATORY CONTROL SAMPLE: 1212714 •
Spike LCS LCS %Rec
I
Parameter Units Conc. Result %Rec Limits Qualifiers
Phenol mg/L .05 0.051 101 90-110
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1212715 1212716 ,
MS MSD
92201123002 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Umits RPD RPD Qual
Phenol mg/L 0.014 .05 .05 0.070 0.061 114 94 90-110 15 20 M1
MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1212717 1212718
I
MS MSD
92201642001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
Phenol mg/L 0.011 .05 .05 0.053 0.068 85 115 90-110 25 20 M1,R1
I
I
I
I
. 1
Results presented on this page ere In the unite indicated by the"Units"column except where an alternate unit Is presented to the right of the result I
REPORT OF LABORATORY ANALYSIS
This report shal not be reproduced,except in full,
III
Date:06/04/2014 10:37AM without the written consent of Pace Analytical Services,Inc.. Page 28 of 33

Pace Analytical Services,
I
I
e vInc.I Dr.
a(......4ceA�taly lcal Asheville,NC 28804
[phone]
III I
QUALITY CONTROL DATA
I
Project: P PPA 5/19/14
Pace Project No.: 92201869
QC Batch: WETA/19164 Analysis Method: SM 4500-CN-E
QC Batch Method: SM 4500-CN-E Analysis Description: 4500CNE Cyanide,Total
Associated Lab Samples: 92201869001
METHOD BLANK: 1211186 Matrix: Water
I Associated Lab Samples: 92201869001
Blank '
Reporting
Parameter Units Result Limit Analyzed Qualifiers
111
Cyanide mg/L ND 0.0050 06/01/14 12:43
LABORATORY CONTROL SAMPLE: 1211187
Spike LCS LCS %Rec
I Parameter Units Conc. Result
%Rec Limits Qualifiers
Cyanide mg/L .1 0.10 104 80-120
I MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1211188 1211189
MS MSD
92202530001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
I
( Cyanide mg/L ND .1 .1 0.090 0.090 86 86 75-125 0 20
I MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 1211190 1211191
MS MSD •
92201908001 Spike Spike MS MSD MS MSD %Rec Max
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual
I
Cyanide mg/L ND .1 .1 0.094 0.10 91 97 75-125 6 20
•I
I
I
I
I
Results presented on this page are In the units Indicated by the"Units"column except where an alternate unit Is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
I This report shall not be reproduced,except In full,
Date:06/0412014 10:37 AM without the written consent of Pace Analytical Services,Inc.. Page 29 of 33

Pace Analytical ServIcet$1hc.
• 2225 Riverside Dc .
Asheville,NC 28804 ,
aceAnalyflcal
Wwwpecsiabs.com [phone]
QUALIFIERS
Project: P PPA 5/19/14 •
Pace Project No.: 92201889
DEFINITIONS
DF-Dilution Factor,if reported,represents the factor applied to the reported data due to changes in sample preparation,dilution of
the sample aliquot,or moisture content.
ND-Not Detected at or above adjusted reporting limit.
J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PRL-Pace Reporting Limit. •
RL-Reporting Limit.
S-Surrogate
1,2-Diphenylhydrazlne(8270 listed analyte)decomposes to Azobenzene.
Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values.
LCS(D)-Laboratory Control Sample(Duplicate)
MS(D)-Matrix Spike(Duplicate)
DUP-Sample Duplicate
RPD-Relative Percent Difference
NC-Not Calculable. •
SG-Silica Gel-Clean-Up
U-Indicates the compound was analyzed for,but not detected.
N-Nitrosodlphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Acid preservation may not be appropriate for 2-Chloroethylvinyl ether,Styrene,and Vinyl chloride.
Pace Analytical Is TNI accredited.Contact your Pace PM for the current list of accredited analytes.
TNI-The NELAC Institute.
LABORATORIES ,
PASI-A Pace Analytical Services-Asheville
PASI-C Pace Analytical Services-Charlotte
ANALYTE QUALIFIERS
10 The Internal standard response was outside the laboratory acceptance limits confirmed by reanalysis.The results
reported are from the most QC compliant analysis.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery.
R1 RPD value was outside control limits.
i
•
I
I
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced,except in full,
Date:06/04/2014 10:37 AM without the written consent of Pace Analytical Services,Inc.. Page 30 of 33

I
Pace Analytical Services,Inc.
e 2225 Riverside Dr.
aceAnalytica! Asheville,NC 28804
.peQelebecom [phone]
l
QUALITY CONTROL DATA CROSS REFERENCE TABLE
•
I Project: P PPA 5/19/14
Pace Project No.: 92201869
Analytical
I Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch
92201869001 PE EPA 1664B GCSV/17863
92201889001 • PE EPA200.7 MPRP/16000 EPA200.7 1CP/14471
I
92201869002 PE LLHG EPA 1631E MERP/6677 EPA 1631E MERC/6436
92201869003 Field Blank PE LLHG EPA 1631E MERPl6877 EPA 1831E MERC/6436
92201869001 PE EPA 625 OEXT/27846 EPA 625 MSSV/9189
I
92201869001 PE EPA 624 MSV/26942
92201869004 TRIP BLANK EPA 624 MSV/26942
92201869001 PE SM 2540C 1NET/31168
I
92201868001 PE EPA 350.1 WETN19062
92201869001 PE EPA 351.2 WETA/19148
92201869001 PE EPA 353.2 WETN19158 .
1
92201869001 PE EPA 365.1 WETN19168
92201869001 PE EPA 420.4 WETN19194
92201889001 PE SM 4500-CN-E 1NETN19164 •
•
I
I
•I .
I
I , .
REPORT OF LABORATORY ANALYSIS
I .
Date:06/04/2014 10:37 AMThis report shall not be reproduced,except in full,
without the written consent of Pace Analytical Services,Ina. .Page 31 of 33

los iis min mg ow IIIII IIIIII IIIIIII MIN _ MO_ _ _ _11111111__ 1111111 111111 11111 INN MI 111111111 111111 11111
CHAIN-OF-CUSTODY/Analytical Request Document
m
• The Chain-of-Custody is a LEGAL DOCUMENT-Al!relevant fields must be completed accurately. os
ace Analytical..., -I•. . , „ •. ;t; . . - - , _ -
0
www.pacelabs.cam N
Page: (
of I cn
Required Client information: Required Project Infortn/a�tlon: Invoice Information: - " li
Company M s(7 • " Report To:/I�Q n 7� �ltiS�C , A ,tion~ 16976'6:5
Address: Copy To: �( Company Name:
,X.1✓u3 i co +6)4t.:4"1..._ ft.....•ORYJKGE .- ;;
Sfic i. //e �C'
Address: —17PNPDES 1- GROUNDWATER.:WATER,r DRINKING WATER
Email To: Purchase Order No.: Pace blot• .
Reference: .. ., r UST r RCRA • r OTHER
Phone: - Fax: Project Nam /a
Pace Protect Sit!".
Loao?-040}/y. ..- / �� Manager
IA,'Requested Dile DateITAT: : - . Project Num - Pace.Profte#:. . . -- •
. - a5x Re`qutyslt AnalyyIs.Flite'T.ed,•(.YIN)`, `; - - _ .
Section 0 Matrix Codes a 2 • • • •
• RequivodClient Information • '- - MATRIX I CODE -9 r - COLLECTED ' - ' PleSelvatives j - • _ ;• " _ ^•4,
Drinking Water DW IIo '
Water. WT 8 .. .. ;k;- .
Waste Water W . m �� • (:OM.POanE
W
Product P ,•g- START END/GRAB W ...^ C
SoiVaotd SL- ` .. .fat% •• G
SAMPLE ID wpe WP = d F re .4. 3 Y-A,
(A z as l,-J Afr AR....GI < z m: e °1•49.430[39
,�,,'(}
• Sample IDs MUST BE UNIQUE Tissue TS w • I. '� .. ' K'. C 'vl 0 l V•C 9 '
Other -OT. :U - f. Z .L .. t e U
•
Swit • a .w.i U e O O c. w•r:/�' O O �.T 10
• • • ft O= c'� Z'V W W m 1•-.ii�j``��\O q, `�j' J t 'C ..
. • . - • .` N' ' DATE. :TIME: '-DATE •TIME' :09, ,4e 7"7 2 2 Z Z -E,O y'•
L - '', �' —"� ��' Pace Project NoJ Lab I.D.
F.-- ft-tiF�Pr 'w a 3-44 /9,j (.s 3 zfr.l ci --1-..:* 1:(C x Y KKK K X-1- -CC 1
• `. /;---.7--,,--,.4.---,-- . . . • - kik, G . • s Is.. JO/0. - (. i .. . . . . . • Y • • _
1-y lis. Aa /3 /i ai G ,r-�s /oo� 1 _��`
: IC
.
•
. .....717,^-"''
TP,- 0O4-
. . .
•
6:
'_7._ • • .. -
•
•
r . •
,g7 ..
12'.
r.,...
? c . 3ADDPTIONA};CONIMEKTS- REIt'NQI1SNED BYI.AFF tikriO l �`•."ss.:-.444,0 ^ TIAE .+'{(.CC .D BYI AFERiAATtON z;_ I.••',DATE 3TimEgi SAMPLE CONDITIONS
' - s-Is-fes /0IF'2., 7.4"-*<7:41, s-/s./)< /0I1-. - "
.`A //- . e s•' 3-•/S=/*. to*— At —....r— ' •- ;(19/re I„•.4,s--°[.0 -\I. " N 1
SA**NAWE$NQSIGNATURF« ;:<i. '" `• .r fr-..
ter v Y.•,,. .':p ;1 • 2
PRINT Name of SAMPLER:.- 5. m z �`8 c^
ORIGINAL LI 472 �t= ,,� a mz s3Z ��
.✓/ DATE Signed T '• n
SIGNATURE of SAMP //�� !/ i' , V R
H S` (MMlDD1YY): S -/rl'"/ ~ cc h
co
"Important Note:By signing this Ions you are accepting Pace's NET 30 day payment terns and agreeing to late charges of 1.5%per month for any Invoices not paid within 30 days. F-ALL-Q-O20rev.07,15-May-2007

I '
'r'' ^
Document Name: Sample Condition UponDocument Revised:April 9,2014
I aceAnalcal' Receipt(SCUR) Page 1 of 2
�„.Paao,o =.aem Document No.: Issuing Authorities:
F-ASV-CS-003-rev.13 Pace Asheville Quality Office
1 Client Name: '7y2
ICourier(Circle): Fed Ex UPS USPS Clie Commercial aOther
Custody Seal on Cooler/Box Present: Fil yes p no Seals intact: D yes D
no
Packing Material: D Bubbl rap_ Bubble Bags , e _ Other
1 Thermometer Used:I /Gun#3-13. DI265963 Noni Type of Ice: Wet' Blue None © Samples on ice,cooling process has begun
Other;
Temp Correction Factor: Add I Subtract OD C
I Corrected Cooler Temp.: 4/. C Biological Tissue is Frozen: Yes No N/A Date and Initials of peon xamining
Temp should be above freezing to 6°C Comments: contents:POR 511q7,lf
Chain of Custody Present: ❑ es No ❑N/A 1.
I Chain of Custody Filled Out: f es ❑No ON/A 2.
Chain of Custody Relinquished: ©Y/DNo ON/A 3.
Sampler Name&Signature on COC: Yes No ON/A 4.
I Samples Arrived within Hold Time: ea ❑No ON/A 5.
Short Hold Time Analysis(<72hr): ❑Yes 12No,❑N/A 6.
Rush Turn Around Time Requested: ❑Yeses EIN ON/A 7.
I
Sufficient Volume: EOYe/E]No ON/A 8.
Correct Containers Used: ❑Y ❑No DN/A 9.
-Pace Containers Used: ElceszONo ON/A
IContainers Intact: ,I�Yes Ow ❑N/ 10.
Filtered volume received for Dissolved tests Over❑No ❑N/A 11.
Sample Labels match COC: Ei es ❑No ❑N/A 12.
I -Includes date/time/ID/Analysis Matrix: (x.X )
All containers needing preservation have been checked. 124 ❑No ON/A 13.
I All containers needing preservation are found to be In es ❑No ON/A
compliance with EPA recommendation.
i /
exceptions: VOA, coliform,TO,../.-"\-1
O`&�GjWI-DRO(water) glYeesu❑No
Samples checked for dechlorination: i=tires ❑NN9 ON/A 14.
1 Headspace in VOA Vials(>6mm): ❑Ye go o ❑N/A 15.
Trip Blank Present: l lyes ❑NN° ON/A 16.
' Trip Blank Custody Seals Present ❑Yes No ON/A
Pace Trip Blank Lot#(if purchased):
Client Notification/Resolution: Field Data Required? Y I N
IPerson Contacted: Date/Time:
Comments/Resolution:
r
SCURF Review: Date: rj ) ' 43.. eA�` `{�}//�� r ,�'��' ` ' i
V ) ?Al
� ly y��l 41 / / 5� !1`I L A 1 I
G. 4t`T,1 1. L� `Z �.rr' 1 ; - `5 i j.
SRF Review: Date: 5f l 1 )� - -/ y ,it '
Note: Whenever there Is a discrepancy affecting North Carolina I ` f; t
compliance samples,a copy of this form will be sent to the North L r' xr t i;'
1 I Carolina DEHNR Certification Office(I.e out of hold,Incorrect i, � k i.; )' ` , u,` .`-, r 1
preservative,out of temp,incorrect containers)
si. e'1„ .;:Ys ii 3} ?,r...�&.:1i c -. ua_,+ t!.H 4 k ,,Lr
1
Page 33 of 33
I

1
I
1
1 5
1
1
1
t
t
t

96uu AlnGey FIVCIIUG,OWrC hilt zzeu f1IVCIJIUG U/IVC I
7-- Nunt/tvut tie,NC 28078 Asheville,NC 28804
ace Anal Tical Phone:[phone] Phone:[phone]
Fax:[phone] Fax:[phone]
Iwww.pacelabs.corn
' cffIuent Aquatic Toxicity Report Form/Phase II Chronic Ceriodaphnia
I
Facility MSD NPDESff:NC 0024911 Pipeff 103 County Buncombe
Labor rforming Test PACE Analytical Services,Inc. 'Comments: ,
< l -- /1
r /l_.9-s1�n�.L,.,�,) V-11/C.c'�l i z-> ,/tit-
s: of Operator In Responsible Charge Signenre of Leh Supenns r
S1eM1DeloEnnam Start
Sample Information Sample 1 Sample 2 Control Test 11f3/1o Ili/to/to 110:3 =5 8:300
0:3End
Collection Start Date 11/1/10 11/4/10 IIIIIIIIIIIIIIIIIIIIIIIIIIIIIII Information' Sled Renewl Renew2 Start Renewl Renew2 I
Grab •
IIIIIIIIIIIIIIIIIIIIIIIIIIIIIII Treatment 36 36 % 36 % Control Control Control
Composite(Duration) 24.2 Hr 24.2 Hr IIIIIIIIIIIIIIIIIIIIIIIIIIIIIII pH Initial 7.3 7.3 7.2 7.1 7.7 7.2
Hardness(mg/L);ry!IIIIIIlphIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII 41 pH Final 7.5 7.3 7.2 7.2 7.4 7.4
1
Spec.Cond.(µmhos/cm) 466 505 132 D.O.Initial 7.7 7.9 8.1 7.8 8,0 7.4
Chlorine(mg/L) <0.1 <0.1 IIIIIIIIIIIIIIIIIIIIIIIIIIIIIII D.O.Final 8.0 8.0 8.2 7.8 7.8 8.3
Sample Temp.at Receipt 1.4 •C 1.3 'C IIIIIIIIIIIIIIIIIIIIIIIIIIIIIII Temp.Initial 25.6 25.6 25.7 25.5 26.3 25.7
Temp.Final 24.5 24.3 24.4 24.5 _24.3 24.4 I
Organism# Chronic Test Results
1 2 3 4 5 6 7 8 9 10 11 12 mean Final Control Mortality % 0'
Control #Young 22 22 17 21 9 20 19 22 18 22 NA NA 19.2 %Control with 3rd Brood 91.7
I
Adult
(Oive(D)ead LLLLL L LL L L NA NA Control Reproduction CV 20.9
1 2 3 4 5 6 7 8 9 10 11 12 mean 48 Hour Mortality
cnnLnl IW C
Effluent% #Young 32 24 28 25 25 25 21 15 21 24 NA NA 24.0 0
_ of 10 0 of 10
Adult %Red..
6 (L)Ive(0)ead LL L LLL L d L L NA NA 0.01 Significant? No
- Final Mortality Signllicant® nq corn I.
1 2 3 4 5 6 7 8 9 10 mean % xI
Effluent% #Younq 27 25 30 16 26 17 25 19 24 21 23.0 Reproduction Analysis:
' Adult %Red
/
9 (L)Ive(D)ead L L L L L L L L L L 0,0 Reproduction LOEC= >36 %; NOEL= 36.0 I
1 2 3 4 5 6 7 8 9 10 mean Method: Dunnetl's Test
Effluent% #Young 29 26 29 24 27 28 24 20 22 19 24.8 Normal Distrib? Yes Method: Kolmogorov D
Adult %Red I
12 (L)ive(Dlead LLLLLLLLLL o.o Statistic: 0.954 Critical: 1.035
1 2 3 4 5 6 7 8 9 10 mean Non-Parametric Analysis(if applicable):
#Younq I
Effluent°/ 36 24 35 17 23 22 5 23 21 26 23.2 Method:Adult %Rod
24 (L)Iveloiead L L L d L L d L L L o.o Eltluent% I-statistic Critical I
1 2 3 4 5 6 7 8 9 10 mean 6 -1.875 2.287
Effluent% #Young 32 8 25 13 23 29 24 19 22 21 21.6 9 -1.484 2.287
Adult %Red
36 (Ulve 101eod L d L L L L L L L L 0,01 12 -2.188 2.287
24 -1.563 2.287
MAIL ATT: Environmental Sciences Branch • Should use highest lest 36 0.938 2.287
concentration or highest
Div.of Water Quality
concentration wllhD.O.>5.0mgL Overall Analysis:
TO: N.C.DENR Result=PASS/FAIL or
1621 Mail Service Center " %Reduction from Control Test LOEC= >36 %; NOEC= 36.0 % I
Raleigh,NC 27699-1621 Reproducllon Mean Chronic Value= >36
I sheville Certification IDs REPORT OF LABORATORY ANALYSIS Charlotte Certification IDs i
IVC Wastewater 40 NC Wastewater 12
This report shall not be reproduced,except In full,
NC Drinking Water 37712 NC Drinking Water 37706
without the written consent of Pace Analytical Services,Inc.
SC 99030 SC 99006
1 .aCONO
FL NELAP E87648 E +, FL NELAP E87627
nelac
•

I
I
Wit.
I Effluent Aquatic Toxicity Report Form/Phase II Chronic Ceriodaphnia
Facility 1Y1SD NPDES#: NC 662'11' l Pipe#O01 County Bove".6140
ILabors my P-rforming Test kr\ .a- c- / (Th Comments
x it ' A_Lr x 11 kt-ati� 11-9 •' W \loo i(o
ature of O.R.C. _nature of L Supervisor
Test Start Date End Date Start Time End Time
Sample Information EMEIMEZEIZI Control Information' '/
ICollection Start Date Start Renewl Renew2 Start Renewl Rene
Grab Treatment 3( °"° 2(p °" ?(o°J° control control Control
ICompo•site MI N pH Initial q.?3 �•�9 Certo .SQ .7.80(Duration) 02 _ P6„
yam__ O. 0 pH Final 7 -4-37- qv° QTS 173 7-g`1
Hardness(mg/Ir ,
I Spec.Cond.(pmhos/cm. 66,3,6 an U D.O. Initial .3o 8•yto (Q63 3 jv (�
g �
i'77"---__:
D.O. Finalt.k
Chlor:ne(mg/I caa c.p,Lb :A-7
) 8.33 (4,..43_ (1?(i3 3q cs q 43
Temp. Initial 2N.� 25•a 252 . 25.0 as-.0 Di--.2._
ISample temp.at receipt t, Q °c as---- cV.:":":-..-.,-,::"..: Temp. Final t3 4 a l�R Zrt 24.1- 24. T-I+
Organism# Chronic Test Results
1 2 3 4 5 _6 7 8 9 10 11 12 Mean Final Control Mortality°n J o
IControl #Young `(o l9 1 q• acp 's t--4. 19 1 Li Ila 9 IP %Control 3rd Brood top
Control CV Repro
Adult P 38.S'ic
(L)ive (D)ead L (, L L t) 1. L. L. t-. D allConttrolourMortalitlWC
' 1 2 3 4 5 6 7 8 9 10 11 12 Mean
..... . ,Q5 of 10 Rs of t(--
Effluent% #Young Co a-0 aa 1g a5 a,laa. 19 )(o 5 18.q- Significant? Y M
Adult R°dt Final Mortality Significant .
(o,0 (L)ive (D)ead U 1._ L- - G L L D % or FPC777P
1 2 3 4 5 6 7 8 9 10 Mean
Reproduction Analysis:
' Effluent% #Young ld 90 az a� a1 6 x, 1Q� Ip )S Repro.LOEC=13(o %• N_OEC=.s %
Adult Y.Red Method: I•
et, 0 (L)ive (D)ead L L- L. L. L L. L L- t) L- Normal Distrib 4 Method:r �. ..
1 2 3 4 5 6 7 8 9 10 Mean Statistic:648 . I Critical: 1.63
I Equal Variances?1.d.- Method?o .Ii-
Effluent% #Young 30 ay ,31 )fO a3 2 q �S- 3�- o?S5' Statistic: (loci$ CriticaL:1S. 07�
x R
Adult �
e No Analysis(it applicable):
I a,O (L)ive (D)ead t, t- L, L- l./ l... L-llr L- C ethod:
1 1 2 3 4 5 6 7 8 9 10 ^te Effluent% Rank Sum Critical Sum
Effluent% #Young `( .21 ace al a,( 93 a9 28 2Z A_
Adult %Red
ILt (L)ive (D)ead L 1, t- L- U- L, L ti L
1 2 3 4 5 6 7 8 9 10 Mean
Overall Analysis:
Effluent% #Young 2,( it{ 22_, 3 ALA 9,5 oto a3 3,-7- 2( a Result=PASS/FAIL or
' Adult /Red Test LOEC='13t.o %;NOEC=3c %
3(c)•° (L)ive (D)ead - (- U L L L• (, 1, (.„ L- e Chronic Valuer )36 %
1 'Should use highest test concentration or
MAIL ATT: Environmental Sciences Branch highest concentration with D.O.>5.0 mg/1
Div.of Water Quality t°„Reduction from Control Reproduction Mean
TO: N.C. DENR
1621 Mail Service Center
I
Raleigh, N,C•27699-1621 DWQ form AT-3 (8/91)Rev. 11/95
1

I
I
I
Effluent Aquatic Toxicity Report Form/Phase II Chronic Ceriodaphnia
Facility MSD of Buncombe County NPDES#:NC
0024911 Pipe#001 County Buncombe
Laboratory Performing Test Pace Analytical ervices,Inc-Raleigh Comments
wo#szzo-osis
Cup#0 of 36%treatment dllullon was KIA,removed from stats ,
Signature of O.R.C. Signature of Lab Supervisor
Test Start Date End Date Start Time End Time
Sample information Sample 1 Sample 2 Control Information" 05/14/14 05/20/14. 1409 1638 '
ot -g- " I Start Renew/Renew2 Start Renew/Renew2
Collection Start Date 05/12/14 05/14/14 ,.. ` , `'-
°� 36 °/° 36 % Control Control Control
Grab I 1 I 1M Treatment 36
Composite 25
r1 ;r pH Initial 7.87 7.83 7.65 7.6$ 7.50 7.45
I 25 " ;;_,s
(Duration) -friy, n-t 39.0 pH Final 7.99 7.99 8.03 7.75 7.71 7.75
Hardness(mgll :r D.O.Initial 7.47' 7.12 7.49 .7.72 7.74 7.84 '
Spec.Cond.(flmhos/cITO 540 510 132.1 D.O.Final 7,50 7.61 7.92 7.80 7,92. 7.69
Chlorine(mg/l <0.1t p
<0.1 v, Tem initial 24.6 24.6 24.7 24.8 24.7 24.7
Sample temp.at receipt 1.3 °C 1.2 C . , L Temp,Final 24.5 24.8 24.8 24.9 24.9 24.7
1
• Organism# Chronic Test Results
1 2 3 4 5 6 7 8 , 9 10 11 12 Mean Final Control Mortality$) 10
30.8 %Control 3rd Brooc 10D '
Control #Young 29 20 34 28 32 30 32 34 32 37
Adult L D L L L L L L L L 4M Control Repro CV 14,990
48 Hour Mortality
x Control IWC
(L)ive (Mead �' -I
1 2 3 4 5 6 7 ;3 9 10 11 12 Mean o of to] f 0 of 10
32 34 33 39 39 38 36 34 33 33 / 35.1 Significant?' 7 1 1 N 10
Effluent% #Young -
•
f 6 �Raai Final Mortality Sl•nlficant •
% or No Conc.Adult ,3.98 1 (L)ive (D)ead L L L LL L L L L L
1 2 3 4 5 6 7 8 9 10 Mean
Reproduction Analysis: °
Effluent% #Young 41 33 38 35 38 36 37 42 36 40
IIIRepro•LOEC= >38 %; NOEL= 36 /°
- %Red Method:Bonferronl T Test
Adult L L L L L L L L L L n•ua Normal Dlstrib? Yes Method: Kolmogorov
l 9 (L)Ive (D)ead
1 2 3 4 5 6 7 8 9 10 Mean Statistic: 0.75348 Critical: 1.035
Yes Method: Bartlett's
IIIEqual Variances? 18.0883
Effluent% #Young
38 29 24 30 32 35 37 33 30 31 Statistic: 3.79341 Critical;
2 1 (L)ive (D)
%Rea Non-Parametric Analysis(If applicable):
Adult eadL L L L L L L L L L 35r Method:
1 2 3 4 5 6 7 8 9 10 Mean Effluent% Rank Sum Critical Sum I
Effluent% #Young
32 30 40 37 32 40 37 39 37 32
24 J
l (L)Ive (D)Adult ead L L L L L L L L L L %,6R.::
1 2 3 4 5 6 7 8 9 10 Meaa I
Effluent% #Young 27 35 36 38 31 29 36 35 KOverall Analysis:
tAk 37 30.4 Result= or
Red Test = >36 %;NOEL=__M___,%
36 Adultead L L L L L L L L « L 1.30'° ChroniLOECc Value= >36
1 (L)Ive (D) I.
'Should use highest test concentration or
highest concentration with >5.0 mg/I
ATT:Environmental Sciences Branch 1s from au°t RD.O.D. .>6.
MAIL Div.of Water Quality
N.C.DENR
oon
�� 1621 Mail Service Center DWQ form AT-3 (8/91)Rev. 11/95
Raleigh, N•C.27699-1621 i
i
1
1

I ,
A 1.
II
-.'E Effluent Toxicity
Report
FormChronic Pass/FailFail and Acute LC50 Date: 09/21/14
II (
= =_lity: MSD BUNCOMBE COUNTY NPDES#: NC0024911 Pipe#: 001 County: BUNCOMBE
- TICAL
_aborato forming Test: PACE ANALYTICAL
II
Laboratory,..Performing Comments:
l r
Y
x ���ttt.,,�: ,r������
Sig' ure of Operat r in Responsible Charge
Signature bf Laboratory Supervisor * PASSED: -3.72% Reduction *
II
Work Order: 9221-2868 Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center
Raleigh, North Carolina 27699-1621
North Carolina CeriodaphniaII
ronic Test Results
Chronic Pass/Fail Reproduction Toxicity Test CCChlroniced t -0.486
Tabular t = 2.508
II
ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 % Reduction = -3.72
% Mortality Avg.Reprod.
€ Young Produced 22 27 26 21 25 30 25 30 24 27 18 21
II 24.67
Control Control
Adult (L) ive (D)ead L L L L L L L L L L L L 8.33 25.58
Treatment 2 Treatment 2
IIEffluent %: 12%
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control PASS FAIL
# Young Produced 27 25 29 25 11 27 30 23 33 27 23 27 % control s X
3rd
producing
I ----
brood Check One
Adult (L)ive (D)ead LLLLDLLLLLLL 100%
1st sample 1st sample 2nd sample Complete This For Either Test
IIpH Test Start Date: 08/13/14
Control 7.65 7,70 7.69 7.90 7.59 7.51 Collection (Start) Date
Sample 1: 08/11/14 Sample 2: 08/13/14 2nd
Treatment 2 7.67 7.88 7.67 7.73 7.81 7.85 Sample Type/Duration 1st 22Pnd
IIs s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X 24 hrs L M M
r d r d r d
t t t Sample 2 X 23.3 hrs T P P
1st sample let sample 2nd sample
D.O. Hardness(mg/1) 40
Control 7.59 8.14 7.70 7.52 7.58 7.73 -
Spec. Cond. (µmhos) 146 583 574
II
Treatment 2 7.86 7.82 8.06 7.49 7.72 7.70 Chlorine(mg/1) <0.1 <0.1
LC50/Acute Toxicity Test Sample temp. at receipt(0C) 1.3 0.7
II (Mortality expressed as %, combining replicates)
Note: Please
% % % % % % % % % % Concentration I
Complete Section Also
% 4 % % % % % % % % Mortality
etart/end start/end
IILC50 = t Method of Determination Control
95% Confidence Limits Moving Average Probit _ High
% -- % Spearman Karber Other g
Conc.
pH D.O.
Organism Tested: Ceriodaphnia dubia Duration(hrs) :
II
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41)
I .

'I: .i."' , ,,,,..
..„. .. ., 4, / _ , . A
i fr.- t
fi
2Efluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 11/13/14
=a::1ity: MSD BUNCOMBE COUNTY NPDES#: NC0024911 Pipe#: 001 County: BUNCOMBE II
_eboratoxy Performi g Test: PACE ANALYTICAL
Comments:
Sig a 'Operator in Responsible Charge
-1_ ti .(
'� £, -- II
Signature oLaboratory Supervisor
* PASSED: -11.02% Reduction *
Work Order: 9222-4073 Environmental Sciences Branch
II
MAIL ORIGINAL TO: Div. of Water Quality
N.C. DENR
1621 Mail Service Center IIRaleigh, North Carolina 27699-1621
North Carolina Ceriodaphnia Chronic Teat Results
Chronic Pass/Fail Reproduction Toxicity Test calculated t = -1.728
Tabular t = 2.508 . IICONTROL ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 % Reduction = -11.02
% Mortality Avg.Reprod.
f Young Produced 19 21 24 17 26 25 25 19 19 22 17 20 0.00 21.17
Control Control IIAdult (L)ive (D)ead L L lL L L L L L L L L L
0.00 23.50
Treatment 2 Treatment 2
EffLuent %: 12%
II---: T 2 ORGANISMS 1 2 3 4 5 6 7 8 9 10 11 12 Control CV
-' ::.E 15.053% PASS FAIL
n Young Produced 123 20 24 29 26 25 23 19 19 27 27 20 %rcontrol gg
3rd
broodicing Check One IIAdult (L)ive (D)ead L L L L L L L L L L L L 100%
1st sample 1st sample 2nd sample Complete This For Either Test
pH Test Start Date: 11/05/14II
Control 7.82 7.61 7.66 7.84 7.64 7.97 Sampled Collection Date
11/03/14 Sample 2: 11/05/14
Treatment 2 7.77 7.79 7.77 7.89 7.74 7.86 Sample Type/Duration 2nd
1st P/F IIs s s Grab Comp. Duration D
t e t e t e I S S
a n a n a n Sample 1 X 24 hrs L A M
✓ d r d r d
t t t Sample 2 X 24 hrs T P P
I
1st sample lst sample 2nd sample
D.O. Hardness(mg/1) 38 "_
Control 7.67 7.34 7.46 8.02 7.82 7.29 Spec. Cond. (µmhos) 127 575 615
Treatment 2 7.82 7.31 7.23 7.84 7.64 7.62 -
Chlorine(mg/1) <0.1 <0.1
II
LC50/Acute Toxicity Test Sample temp. at receipt(°C) 2.7 0.7
I
(Mortality expressed as %, combining replicates) Note: Please I
% % % % % % % % % % Concentration Sect ete lso
This
% % % % % % % % % % Mortality
start/end start/end
LC50 = % Method of Determination -___-Control
II
95% Confidence Limits Moving Average -- Probit --% -- % Spearman Karber _ Other High
Cont.
pH D.O.
II
Organism Tested: Ceriodaphnia dubia Duration(hrs) :
Copied from DWQ form AT-1 (3/87) rev. 11/95 (DUBIA ver. 4.41) I
11

r
Effluent Toxicity Report Form - Chronic Pass/Fail and Acute LC50 Date: 02/23/15
Facility: MSD BUNCOMBE COUNTY NPDES#: NC00249114,ipe#: 001 County: BUNCOMBE
Laboratory.Performing Test: PACE ANALYTICAL -
• • Comments:
X -
Signat e o Operato in esponsible Charge _
II X '�,ll�
8lgnatu o Y,aa ry upervisor - • * PASSED: 9.32 Reduction
Work Order: 92236988 Environmental Sciences Branch
MAIL ORIGINAL TO: Div. of Water Quality
N.C. 'DENR '
16211Mail Service Center .
.IIRaleigh, North Carolina 27699-1621 -
.North Carolina Cerjodaphnia
Chronic Pass/Fail Reproduction Toxicity Teat Chronic Test Results
Calculated t . 1.466
Tabular t a 2.508
CONTROL ORGANISMS 1 2 3 4 5 6 7 8 ' 9. 10 11 12 t Reduction = 9.32
I _ __ ,
't Mortality Avg.Reprod.
# Young Produced 12 16 20 22 22 23 27 18 19 19 20 18
. 0.00 19.67
Control Control
I
Adult .(L)ive (D)ead L L L L L L L L • L L L L
0.00 • 17.83
Treatment 2 Treatment 2 .. ,,
Effluent t: 12% . __..
TREATMENT 2 ORGANISMS 1 2 3 4 5 6 7 8 :9 10 11 12 Control CV
1 19.067* PASS FAIL
# Young.Produced 16 14 19 17 18 21 21 18 18 20 16 16i t control orgs
producing 3rd
brood Check One '
Adult (L)ive (D)ead L L L L L L L L L L L L 100* -
•
let sample 1st sample 2nd sample Complete This For Either Test
pH . Test Start Date: 02/11/15
Control 8.04 7.79 7.84 7.85 7.75 7.70 -Collection (Start) Date
Sample .1: 02/09/15 Sample 2: 02/11/15
Treatment 2 7.85 7.82 7.77 8.03 7.85 7.84 Sample-Type/Duration 2nd
1st P/F
s a s Grab Comp. Duration D
t e t . e t e I S S
a n a n a n -Sample .1 •• X 23.8 hrs L A A
r d r d r d - U M M
• t t t ' ' Sample 2 X 24.2 hrs T P P
1st sample 1st sample 2nd sample
II D.O. Hardness{mg/1) 50 ::
Control 7.39 8.82 7.06 7.14 7.63 6.69
Spec. Cond.(pmhos) 251 523 519 •
Treatment 2 7.35 8.75 9.35 7.31 7.57 6.18
Chlorine(mg/1) <0.1 <0.1
LC50/Acute Toxicity Test Sample temp. at receipt(°C) 1.5 0.5
• (Mortality expressed as t, combining replicates) I
Note: Please
II %
% * itt * * * : % Concentration. Complete This
- Section Also
t t * * . t * * t * * Mortality
• start/end start/end
' LC50 ; * Method of Determination Control
95% Confidence Limits Moving Average Probit •
* -- * Spearman Kerber -" Other . Hi h
' ' Conc.
'' pH D.O.
Organism Tested: Ceriodaphnia dubia 'Duration(hrs) : ' •
Copied•from'DWQ form AT-1 (3/87) rev. 11/95 1DUBIA ver. 4,41)
•
•
I •

1
1.
I
I
I
I
I
I
I
1
1 6

Permit No.S-034-12
THE METROPOLITAN SEWERAGE DISTRICT
OF
BUNCOMBE COUNTY,NORTH CAROLINA '
�oQc),) SEWFg40S
°+.9e
COUNT
PERMIT RATIONALE
FOR '
Permit No. S-034-12
Effective Date: January 1,2012
Expiration Date: December 31,2016
A. Basic Information
1. Name and Address of User '
Arvato
108 Monticello Road
Weaverville, North Carolina 28787
Cr) 2. Description of User's Operation ,
i) SIC Code No. 3652: Mastering process and manufacturer of CDs, DVDs,
and BDs (Blu-ray disc) and Call Center.
ii) 40 CFR Category: 433.17
3. Name of WWTP Receiving Wastewater
Metropolitan Sewerage District of Buncombe County,NC
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911
I
I '

I
Permit No.S-034-12
B. Rationale For Limitations and Effluent Limits
The following pollutants were assigned numerical limits in this Industrial User
Permit for Monitoring Point 01 based on the categorical regulations and the MSD Sewer
Use Ordinance which-ever is more restrictive. These limits do not result in over
allocation the Maximum Allowable Industrial Loading determined with the Headworks
Analysis among all Users.
Daily
Pollutants Maximum Units
Cadmium 0.07 mg/I
Chromium 1.00 mg/I
Copper 1.00 mg/I
Lead 0.40 mg/I
' Nickel 1.00 mg/1
Silver 0.24 mg/I
Zinc 1.00 mg/1
Cyanide 0.65 mg/1
TTO 2.13 mg/1
' The Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating
the industrial waste it is receiving at this time. Permit limits are based on the current
Headworks Analysis, which considers most recent available industrial monitoring and
' analytical characterization of the MSD Wastewater System. Limits established in
Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
chemical inhibition.
C. Rationale For Other Pollutants
1. The following pollutants, which were detected in the discharge at Monitoring
Point 01, are monitored with the TTO monitoring. These parameters are
limited by the sum of the TTO.
Pollutants
_ Chloride
Trichloroethylene
2. The following pollutant is a Priority Pollutant known to be used in the
manufacturing process and can come in contact with process waste water
' minimally. Concentration levels are expected to be at or below domestic
concentrations.
' Pollutants
Aluminum
2
I

I
Permit No.S-003-12
THE METROPOLITAN SEWERAGE DISTRICT
OF
BUNCOMBE COUNTY,NORTH CAROLINA
� N SEWER40F
eoQ0•v
1
CQ P 1
+4.`own,
`own, M�""
PERMIT RATIONALE
FOR
Permit No. S-003-12 '
Effective Date: January 1,2012
Expiration Date: December 31,2016 '
A. Basic Information
1. Name and Address of User
Asheville Metal Finishing, Inc.
178 Clingman Avenue
Asheville,North Carolina 28801
2. Description of User's Operation 1
i) SIC Code No. 3471: Electroplating facility providing finishes in
anodizing, copper,nickel,chrome, zinc, silver, black oxide,chromate
conversion,tin and phosphating.
ii) 40 CFR Category: 413 '
3. Name of WWTP Receiving Wastewater
111
Metropolitan Sewerage District of Buncombe County,NC
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911 I
I

Permit No.S-003-12
B. Rationale For Limitations and Effluent Limits
The Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating
' the industrial waste it is receiving at this time. Permit limits are based on the current
Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
chemical inhibition.
1. The following pollutants from Monitoring Point 01 (40 CFR 413) were
assigned numerical limits in this Industrial User Permit based on the
categorical regulations and the MSD Sewer Use Ordinance which-ever is
more restrictive.
Daily
Pollutants Maximum Units
Cadmium 0.10 mg/I
' Chromium 1.00 mg/I
Copper 1.00 mg/1
Lead 0.40 mg/1
Nickel 1.00 mg/I
Silver .043 mg/1
' Zinc 1.00 mg/I
Tin 1.00 mg/1
Total Metals 4.50 mg/1
Cyanide 1.00 mg/l
TTO 2.13 mg/1
' These limits do not result in over allocation the Maximum Allowable Industrial
Loading determined with the Headworks Analysis among all Users.
C. Rationale For Other Pollutants
1. The following pollutants, which were detected in the discharge at Monitoring
Point 01, are monitored with the TTO monitoring. These parameters are
limited by the sum of the TTO.
Pollutants
N-nitrosodimethylam i ne
Antimony
Chloroform
Chloromethane
1
2

Permit No.S-070-12
THE METROPOLITAN SEWERAGE DISTRICT
OF
BUNCOMBE COUNTY,NORTH CAROLINA
Q o��
.
mL _ r
COUMi Y.
PERMIT SYNOPSIS ,
FOR
Permit No. S-070-12
Effective Date: January 1,2012 I
Expiration Date: December 31,2016
A. Basic Information I
1. Name and Address of User
Baldor Electric Company
70 Reems Creek Road
Weaverville,North Carolina 28787
2. Description of User's Operation
i) SIC Code Nos. 3568 and 3566: Manufacturer of industrial sized pulleys, '
couplings, bearings, and bushings used for power transmission.
ii) 40 CFR Categories: 433.15 and 471.104(e) • ,
3. Name of WWTP Receiving Wastewater
Metropolitan Sewerage District of Buncombe County,NC
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911 1
111
1 1

Permit No.S-070-12
B. Rationale For Limitations and Effluent Limits
The following pollutants for each of the Categorical Processes were assigned
numerical limits in this Industrial User Permit based on the categorical regulations and
the MSD Sewer Use Ordinance which-ever is more restrictive. These limits do not result
in over allocation the Maximum Allowable Industrial Loading determined with the
Headworks Analysis among all Users.
The discharge at MP 01 is regulated by 40 CFR 471.104(e)
Pollutants Daily Maximum(lb/day)
Copper 0.081
Lead 0.018
Cyanide 0.012
The discharge at MP 02 is regulated by 40 CFR 433.17(a)
Pollutants Daily Maximum(mg/1)
Cadmium 0.10
Chromium 1.00
Copper 1.00
Lead 0.40
Nickel 1.00
Silver 0.24
Zinc 1.00
Cyanide 0.65
TTO 2.13
The Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating
the industrial waste it is receiving at this time. Permit limits are based on the current
' Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
chemical inhibition.
I
I
2

Permit No.S-060-12
B. Rationale For Limitations and Effluent Limits
The following pollutants were assigned numerical limits in this Industrial User
Permit for Monitoring Point 01 based on the categorical regulations. These limits do
not result in over allocation the Maximum Allowable Industrial Loading determined with
the Headworks Analysis among all Users.
Daily Monthly
Pollutants Maximum Average Units
Lead 0.529 0.176 lbs/day
Zinc 1.040 0.235 lbs/day
The Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating
the industrial waste it is receiving at this time. Permit limits are based on the current
Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
chemical inhibition.
C. Rationale For Other Pollutants '
1. MSD had sampled the effluent from Blue Ridge Metals during the period for
Permit S-060-07. The following pollutants, which were detected in the
discharge at Monitoring Point 01, were not assigned numerical limits in this
Industrial User Permit. Their concentrations were at or below domestic
concentrations. I
Pollutants
Chromium
Copper
Nickel
Tin '
2. The following pollutant, which was detected in an analysis of the acid waste,
has not been detected in the discharge at Monitoring Point 01. 1
Pollutants
Cadmium i
2 I

I
tPermit No. S-060-12
3. The following pollutant is a Priority Pollutant known to be used in the
manufacturing process but does not come in contact with process waste water.
Pollutants
Toluene
1
I
p
I
I
I
I
3
I

Permit No. S-015-12
B. Rationale For Limitations and Effluent Limits
The following pollutants were assigned numerical limits in this Industrial User
Permit for Monitoring Point 01 based on the categorical regulations and the MSD Sewer
Use Ordinance whichever is more restrictive. These limits do not result in over
allocation the Maximum Allowable Industrial Loading determined with the Headworks
Analysis among all Users.
Daily '
Pollutants Maximum Units
Cadmium 0.07 mg/1
Chromium 1.00 mg/I
Copper 1.00 mg/I
Lead 0.40 mg/I
Nickel 1.00 mg/I
Silver 0.24 mg/1
Zinc 1.00 mg/I
Cyanide 0.65 mg/1 ,
TTO 2.13 mg/1
The Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating 1
industrial w st it is receivingat this time. Permit limits are based on the current
thewaste
Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without I
chemical inhibition.
C. Rationale For Other Pollutants
1. The following pollutants, which were detected in the discharge at Monitoring
Point 01, are monitored with the TTO monitoring. These parameters are
limited by the sum of the TTO.
Pollutants
Arsenic
Phenol I
I
1
2 i
I

I
Permit No.S-015-12
2. The following pollutant is a Priority Pollutant known to be used in the
manufacturing process and is known to be in the discharge at Monitoring
Point 01. This pollutant is monitored with the TTO monitoring. This
parameter is limited by the sum of the TTO.
• Pollutants
Chloride
I
3. The following pollutant is a Priority Pollutant known to be used in the
Imanufacturing process but does not come in contact with process waste water.
Pollutants
Naphthalene
1. The following pollutant is known to be used in the manufacturing process.
' Concentrations discharged not at Monitoring Point 01 are expected to be at or
below domestic concentrations.
Pollutants
Aluminum
1
I
1
1
I
I
3
1

1
Permit No.S-066-12
THE METROPOLITAN SEWERAGE DISTRICT
OF
BUNCOMBE COUNTY,NORTH CAROLINA
��oQo�\SPN SEWER,ice���
I
so P�
SOF�OMf r.On'�`'
PERMIT RATIONALE
FOR
Permit No. S-066-12 1
Effective Date: January 1,2012
Expiration Date: December 31,2016 '
A. Basic Information
1. Name and Address of User
Craggy Prison Laundry
1405 Riverside Drive
Asheville,North Carolina 28804
2. Description of User's Operation 1
i) SIC Code 7218: Industrial laundry: processing(washing)of uniforms and
linen for the North Carolina Prison System
ii) 40 CFR Category: N/A
3. Name of WWTP Receiving Wastewater
Metropolitan Sewerage District of Buncombe County,NC ,
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911
1 '
I

Permit No.S-066-12
B. Rationale For Limitations and Effluent Limits
' The following pollutants were assigned numerical limits in this Industrial User
Permit for Monitoring Point 01 based on the MSD Sewer Use Ordinance (SUO) or Best
Professional Judgment(BPJ).
Daily
Pollutants Maximum Units
BOD 700 mg/I
TSS 300 mg/I
These limits do not result in over allocation the Maximum Allowable Industrial
Loading determined with the Headworks Analysis among all Users.
' The MSD Sewerage Treatment Plant is experiencing no difficulty treating the
industrial waste it is receiving at this time. Permit limits are based on the current
' Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
chemical inhibition.
C. Significant Industrial User Application for Permit to Discharge and Wastewater
'
Survey
Attached.
D. Inspection Report
Attached.
I
I
I
1 2

1
Permit No.S-057-12
THE METROPOLITAN SEWERAGE DISTRICT
OF
BUNCOMBE COUNTY,NORTH CAROLINA
�eoQoep SEWFq,„_Q�.
9 '
PERMIT RATIONALE
FOR
Permit No. S-057-12 '
Effective Date: January 1,2012
Expiration Date: December 31,2016 I
A. Basic Information
1. Name and Address of User
Day International/Flint Group
95 Glenn Bridge Road
Arden,North Carolina 28704
2. Description of User's Operation i
i) SIC Code 3069: Manufacturer of fabricated rubber productse systems for missiles
and space vehicles.
ii) 40 CFR Category: 428.76
3. Name of WWTP Receiving Wastewater
Metropolitan Sewerage District of Buncombe County,NC ,
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911
I
1 1

I
Permit No.S-057-12
B. Rationale For Limitations and Effluent Limits
IThe Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating the
industrial waste it is receiving at this time. Permit limits are based on the current Headworks
I
Analysis, which considers most recent available industrial monitoring and analytical
characterization of the MSD Wastewater System. Limits established in Permits to Discharge
Industrial Waste were utilized in the Headworks Analysis to determine the capability of the
I
Wastewater Treatment Plant to operate within design and Permit Limits, pass-through and
receiving stream Water Quality Criteria, and without chemical inhibition.
1 1. The following pollutants from Monitoring Point 01 (40 CFR 428.76) were assigned
numerical limits in this Industrial User Permit based on the categorical regulations
and the MSD Sewer Use Ordinance which-ever is more restrictive.
I Daily
Pollutants Maximum Units
I TSS - mg/I
Oil&Grease 100 mg/I
I
2. The following pollutants from Monitoring Point 04 (total facility) were assigned
numerical limits in this Industrial User Permit based on the MSD Sewer Use
Ordinance(SUO) or Best Professional Judgment(BPJ).
I Daily
Pollutants Maximum Units
I BOD
TSS 2,500 mg/I
600 mg/1
Zinc 1.38 lb/day
I
MEK 1.00 mg/I
Toluene 1.00 mg/1
TTO - mg/1
IThese limits do not result in over allocation the Maximum Allowable Industrial Loading
determined with the Headworks Analysis among all Users.
IC. Rationale For Other Pollutants
1. The following pollutants, which were detected in the discharge at Monitoring Point
I 04, were not assigned numerical limits in this Industrial User Permit. Their
concentrations were at or below domestic concentrations.
I
Pollutants
Copper
Mercury
I
Nickel
1 2

1
Permit No. S-057-12
2. The following pollutant, which was detected in the discharge at Monitoring Point 04,
is monitored with the TTO monitoring. This parameter is limited by the sum of the
TTO.
Pollutants
Phenol
3. The following pollutants are Priority Pollutants known to be used in the
manufacturing process but do not come in contact with process waste water.
Pollutants
Di-n-butyl phthalate
Acrylonitrile
Ethylbenzene
Xylene
C. Significant Industrial User Application for Permit to Discharge and Wastewater Survey
Attached. '
D. Inspection Report
Attached.
1
1
1
1
1
3 1
1

i
Permit No.S-014-12
THE METROPOLITAN SEWERAGE DISTRICT
OF
BUNCOMBE COUNTY,NORTH CAROLINA
¢°eo�\SAN sEWER40,,,
oted' 9
sc 4!eg
��P N
CaNIY,io
PERMIT RATIONALE
FOR
Permit No. S-014-12
Effective Date: January 1,2012
Expiration Date: December 31,2016
A. Basic Information
1. Name and Address of User
' Eaton Corporation,Arden Plant
221 Heywood Road
Arden,North Carolina 28704
' 2. Description of User's Operation
i) NAICS Code No. 335313: Manufacturer of motor control devices, low
voltage switchgear and electronic control equipment. The panels built for
this equipment are pre-coated with phosphate before a protective powder
' coating is applied.
ii) 40 CFR Category: 433.17
3. Name of WWTP Receiving Wastewater
Metropolitan Sewerage District of Buncombe County,NC
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911
1

Permit No.S-014-12
B. Rationale For Limitations and Effluent Limits
The following pollutants were assigned numerical limits in this Industrial User
Permit for Monitoring Point 01 based on the categorical regulations and the MSD Sewer
Use Ordinance which-ever is more restrictive. These limits do not result in over
allocation the Maximum Allowable Industrial Loading determined with the Headworks
Analysis among all Users.
Daily
Pollutants Maximum Units
Cadmium 0.07 mg/1
Chromium 1.00 mg/1
Copper 1.00 mg/1 '
Lead 0.40 mg/1
Nickel 1.00 mg/1
Silver 0.24 mg/1
Zinc 1.00 mg/1
Cyanide 0.65 mg/1
TTO 2.13 mg/1
The Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating
the industrial waste it is receiving at this time. Permit limits are based on the current
Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
chemical inhibition.
C. Rationale For Other Pollutants
1. The following pollutants are Priority Pollutants known to be used in the
manufacturing process but do not come in contact with process waste water. '
Pollutants
Phenol
Di-n-butyl Phthalate
Di-n-octyl phthalate
Naphthalene
Antimony
Arsenic
Mercury
Benzene
Carbon tetrachloride
2 1

1
1 Permit No.S-014-12
1 Ethylbenzene
Tetrachloroethylene
Toluene
Itrans-i,2-Dichloroethylene
Trichloroethylene
Trichlorofluoromethane
1 Xylene
2. The following pollutant is known to be used in the manufacturing process.
Concentrations discharged at Monitoring Point 01 are expected to be at or
1 below domestic concentrations.
Pollutants
1 Aluminum
1
1
i
1
1
1
1
i
1
1
1 3
1

Permit No.S-067-12
THE METROPOLITAN SEWERAGE DISTRICT
OF
BUNCOMBE COUNTY,NORTH CAROLINA
�eoeo�oak
SEW4,0_4
9 '
VIE Na'M 4
COUNT,, S
PERMIT RATIONALE
FOR
Permit No. S-067-12 '
Effective Date: January 1,2012
Expiration Date: December 31,2016
A. Basic Information
1. Name and Address of User
Jacob Holm Industries(America),Inc.
1265 Sand Hill Road
Candler,North Carolina 28715
2. Description of User's Operation
i) SIC Code No.2299: Manufacturer non-woven hygiene products. High
pressure water causes the fibers to intertwine (hydro entanglement).
ii) 40 CFR Category: N/A '
3. Name of WWTP Receiving Wastewater
Metropolitan Sewerage District of Buncombe County,NC 1
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911
I 1

1
Permit No.S-067-12
B. Rationale For Limitations and Effluent Limits
1. The following pollutants were assigned numerical limits in this Industrial User
' Permit for Monitoring Point 01 based on the MSD Sewer Use Ordinance or
Best Professional Judgment(BPJ).
Daily
Pollutants Maximum Units
BOD 1,029 lbs/day
' TSS 2,285 lbs/day
These limits do not result in over allocation the Maximum Allowable Industrial
Loading determined with the Headworks Analysis among all Users.
The Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating
the industrial waste it is receiving at this time. Permit limits are based on the current
Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
' Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
chemical inhibition.
1
1
1
1 2

Permit No.S-066-12
THE METROPOLITAN SEWERAGE DISTRICT
OF
BUNCOMBE COUNTY,NORTH CAROLINA
_ 9 ,
r
o4,�f M 4r
COUNTY,
PERMIT RATIONALE
FOR
Permit No. S-009-12 '
Effective Date: January 1,2012
Expiration Date: December 31,2016
A. Basic Information
1. Name and Address of User
Kearfott Corporation, Motion Systems Division
2858 US Highway 70 W
Black Mountain,North Carolina 28711
2. Description of User's Operation
i) SIC Codes 3769, 3761, and 3764: Manufacturer of electronic guidance
systems for missiles and space vehicles.
ii) 40 CFR Category: 433.15
3. Name of WWTP Receiving Wastewater
Metropolitan Sewerage District of Buncombe County,NC '
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911
1 '

Permit No.S-066-12
B. Rationale For Limitations and Effluent Limits
The Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating
the industrial waste it is receiving at this time. Permit limits are based on the current
' Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
' determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
chemical inhibition.
1. The following pollutants were assigned numerical limits in this Industrial User
' Permit for Monitoring Point 01 (40 CFR 433.15) based on the categorical
regulations and the MSD Sewer Use Ordinance (SUO) which-ever is more
restrictive.
Daily
Pollutants Maximum Units
Cadmium 0.07 mg/I
Chromium 1.00 mg/I
Copper 1.00 mg/I
' Lead 0.40 mg/I
Nickel 1.00 mg/1
Silver 0.24 mg/1
' Zinc 1.00 mg/I
Cyanide 0.65 mg/I
TTO 2.13 mg/I
' These limits do not result in over allocation the Maximum Allowable Industrial
Loading determined with the Headworks Analysis among all Users.
C. Rationale For Other Pollutants
' 1. The following pollutant, which was detected in the discharge at Monitoring
Point 01, is monitored with the TTO monitoring. This parameter is limited by
the sum of the TTO.
' Pollutants
Chloroform
1 2

1
Permit No.S-066-12 ,
2. The following pollutants are Priority Pollutants known to be used in the
manufacturing process but do not come in contact with process waste water. '
Pollutants
Phenol ,
Naphthalene
Aluminum
Antimony '
Beryllium
Molybdenum
Methylene Chloride '
Toluene
Trans-l,2-Dichloroethylene
1
C. Significant Industrial User Application for Permit to Discharge and Wastewater
Survey '
Attached.
D. Inspection Report
Attached. ,
3 1

Permit No.S-061-12
THE METROPOLITAN SEWERAGE DISTRICT
OF
BUNCOMBE COUNTY,NORTH CAROLINA
•
' 9
•Lyra ./j74r�
41 �!
'ANT,I O
PERMIT RATIONALE
FOR
Permit No. S-061-12
' Effective Date: January 1,2012
Expiration Date: December 31,2016
A. Basic Information
1. Name and Address of User
' Meritor Heavy Vehicle Systems,LLC
1000 Rockwell Drive
Fletcher,North Carolina 28732
2. Description of User's Operation
' i) NAICS Code No. 336399: Machining, cleaning, and assembly of truck
axle components.
ii) 40 CFR Category: 433.17
3. Name of WWTP Receiving Wastewater
' Metropolitan Sewerage District of Buncombe County,NC
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911
1
1 1

I
Permit No.S-061-12
I
B. Rationale For Limitations and Effluent Limits
The following pollutants were assigned numerical limits in this Industrial User I
Permit for Monitoring Point 01 based on the Combined Waste Stream Formula for
categorical regulations and the MSD Sewer Use Ordinance whichever is more restrictive.
I
Some parameters may retain the originally assigned limit, but that limit must be equal to
or lower than the calculated CWS formula based on CFR Categorical Limits.
These limits do not result in over allocation the Maximum Allowable Industrial
Loading determined with the Headworks Analysis among all Users.
Daily 1
Pollutants Maximum Units
Cadmium 0.055 mg/1 I Chromium 0.781 mg/1 _
Copper 0.781 mg/1
Lead 0.313 mg/1 I Nickel 1.000 mg/I
Silver 0.188 mg/1
Zinc 1.000 mg/1 I Cyanide 0.508 mg/1
TTO 1.66 mg/1
The Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating I
the industrial waste it is receiving at this time. Permit limits are based on the current
Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
determine the capability of the Wastewater Treatment Plant to operate within design and
I
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
chemical inhibition.
C. Rationale For Other Pollutants I
1. The following pollutant, which was detected in the discharge at Monitoring
I
Point 01, is monitored with the TTO monitoring. This parameter is limited by
the sum of the TTO.
Pollutants I
Phenol
I
I
2 1
I

I
1 Permit No.S-061-12
1 2. The following pollutants are Priority Pollutants known to be used in the
manufacturing process. These parameters do not come in contact with process
waste water.
Pollutants
Aluminum
Antimony
1 Arsenic
Beryllium
Molybdenum
1 _ Selenium
■ Barium
Fluoride
1 Carbon tetrachloride
Ethylbenzene
Toluene
Xylene
1
1
i
1
1
1
1
1
' 3
1

I
Permit No.S-036-12
THE METROPOLITAN SEWERAGE DISTRICT
OF '
BUNCOMBE COUNTY,NORTH CAROLINA
�eoQo�`,�pµSEWfq,0_
I
'0%
0oLNT, to
PERMIT RATIONALE
FOR
Permit No. S-036-12 ,
Effective Date: January 1,2012
Expiration Date: December 31,2016
A. Basic Information
1. Name and Address of User
Milkco,Inc.
220 Deaverview Road
Asheville,North Carolina 28806
2. Description of User's Operation
i) SIC Code Nos.2026,2037 and 3085: Manufacturer of milk processing
with secondary process lines of bottled water, fruit flavored drinks and
orange juice and a secondary process of plastic injection mold.
ii) 40 CFR Category: N/A
3. Name of WWTP Receiving Wastewater
Metropolitan Sewerage District of Buncombe County,NC
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911
1 '

Permit No.S-036-12
B. Rationale For Limitations and Effluent Limits
The following pollutants were assigned numerical limits in this Industrial User
Permit for Monitoring Point 01 based on the MSD Sewer Use Ordinance (SUO) or Best
Professional Judgment(BPJ).
Daily
Pollutants Maximum Units
BOD 4500 mg/I
TSS 2000 mg/I
These limits do not result in over allocation the Maximum Allowable Industrial
' Loading determined with the Headworks Analysis among all Users.
The Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating
' the industrial waste it is receiving at this time. Permit limits are based on the current
Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
' Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
chemical inhibition.
I
1
1
I
I
' 2

I
Permit No.S-068-12
THE METROPOLITAN SEWERAGE DISTRICT
OF
BUNCOMBE COUNTY,NORTH CAROLINA
SEWEike4'4
•
tto
P
4.es Coolly
PERMIT RATIONALE
FOR
Permit No. S-068-12 ,
Effective Date: January 1,2012
Expiration Date: December 31,2016
A. Basic Information
1. Name and Address of User
Mission Hospital Laundry ,
345 Biltmore Avenue
Asheville,North Carolina 28801
2. Description of User's Operation
i) SIC Code No. 7213: Service laundry for 5 area hospitals and healthcare
facilities.
ii) 40 CFR Category:N/A
111
3. Name of WWTP Receiving Wastewater
Metropolitan Sewerage District of Buncombe County,NC '
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911
I
I
1 1

1
Permit No.S-068-12
B. Rationale For Limitations and Effluent Limits
The following pollutants were assigned numerical limits in this Industrial User
Permit for Monitoring Point 01 based on the MSD Sewer Use Ordinance (SUO) or Best
Professional Judgment(BPJ).
Daily
' Pollutants Maximum Units
BOD 350 mg/l
TSS 350 mg/1
These limits do not result in over allocation the Maximum Allowable Industrial
Loading determined with the Headworks Analysis among all Users.
' The MSD Sewerage Treatment Plant is experiencing no difficulty treating the
industrial waste it is receiving at this time. Permit limits are based on the current
' Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
chemical inhibition.
C. Rationale For Other Pollutants
1 1. The following pollutants are Priority Pollutants known to be used in the
manufacturing process and come in contact with wastewater discharged at
' Monitoring Point 01 but quantity usage is minimal. Expected concentrations
are at or below domestic levels.
Pollutants
Chloride
Fluoride
1
I
I
1
' 2

1
Permit No.S-065-12
THE METROPOLITAN SEWERAGE DISTRICT
1
OF
BUNCOMBE COUNTY,NORTH CAROLINA
,
s
0
,
µSEWFq40-4
%NTx NOPEN
PERMIT RATIONALE
FOR
Permit No. S-065-12 '
Effective Date: January 1,2012
Expiration Date: December 31,20161
A. Basic Information
1. Name and Address of User
Prince Manufacturing ,
209 Broadpointe Drive
Mills River,North Carolina 28759
2. Description of User's Operation
i) SIC Codes 3479, 3469, and 3471: Painting of prefabricated metal parts
using electro-paint deposition (E-coating)and powder paint operation.
ii) 40 CFR Category: 433.17 1
3. Name of WWTP Receiving Wastewater
Metropolitan Sewerage District of Buncombe County,NC '
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911
1 '
1

I
Permit No. S-065-12
B. Rationale For Limitations and Effluent Limits
The following pollutants were assigned numerical limits in this Industrial User
Permit for Monitoring Point 01 based on the categorical regulations and the MSD Sewer
Use Ordinance which-ever is more restrictive. These limits do not result in over
allocation the Maximum Allowable Industrial Loading determined with the Headworks
Analysis among all Users.
' Daily
Pollutants Maximum Units
' Cadmium 0.07 mg/1
Chromium 1.00 mg/1
Copper 1.00 mg/1
' Lead 0.40 mg/I
Nickel 1.00 mg/1
Silver 0.24 mg/1
Zinc 1.00 mg/I
Cyanide 0.65 mg/I
TTO 2.13 mg/I
' The Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating
the industrial waste it is receiving at this time. Permit limits are based on the current
Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
' determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
chemical inhibition.
C. Rationale For Other Pollutants
' 1. The following pollutant is known to be used in the manufacturing process.
Concentrations discharged at Monitoring Point 01 are expected to be at or
below domestic concentrations.
Pollutants
Aluminum
' 2. The followingpollutant, which was detected in the discharge at Monitoring
g
Point 01, is monitored with the TTO monitoring. This parameter is limited by
the sum of the TTO.
Pollutants
Fluoride
2

I
Permit No.S-073-13
THE METROPOLITAN SEWERAGE DISTRICT
OF
BUNCOMBE COUNTY,NORTH CAROLINA
�QoQo�0,1k SEWpqvF4
9 1
i
4°`,..,047. N4
,Ma's
PERMIT RATIONALE
FOR
Permit No. S-073-13 1
Effective Date: October 7,2013
Expiration Date: December 31,20161
A. Basic Information
1. Name and Address of User
Sierra Nevada Brewing Co.
100 Sierra Nevada Way
Mills River,North Carolina 28732
2. Description of User's Operation
i) NAICS Code No. 312120: Manufacturer of beer processing. 1
ii) 40 CFR Category: N/A
3. Name of WWTP Receiving Wastewater 1
Metropolitan Sewerage District of Buncombe County,NC
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911
1
i
1
1 1
1

Permit No.S-073-13
B. Rationale For Limitations and Effluent Limits
The following pollutants and associated flow limit were assigned numerical limits
in this Industrial User Permit for Monitoring Point 01 based on the MSD Sewer Use
' Ordinance (SUO)or Best Professional Judgment(BPJ).
Daily
Pollutants Maximum Units
BOD 9,200 lb/day
TSS 5,600 lb/day
Flow 0.100 MGD
These limits do not result in over allocation the Maximum Allowable Industrial
' Loading determined with the Headworks Analysis among all Users.
The Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating
the industrial waste it is receiving at this time. Permit limits are based on the current
Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
chemical inhibition.
I
1
I
1 2
I

Permit No. S-007-12
THE METROPOLITAN SEWERAGE DISTRICT
OF
BUNCOMBE COUNTY,NORTH CAROLINA
�QoQo�\�PN SEWfH40F4
9
oyF
c `'
�MTT MORN
PERMIT RATIONALE
FOR
Permit No. S-007-12 '
Effective Date: January 1,2012
Expiration Date: December 31,2016 1
A. Basic Information
1. Name and Address of User
Williams Plating Company,Inc.
6 Industrial Drive
Arden,North Carolina 28704
2. Description of User's Operation 1
i) SIC Code No. 3471: Electroplating of small parts(job shop)
ii) 40 CFR Category: 433.17
3. Name of WWTP Receiving Wastewater '
Metropolitan Sewerage District of Buncombe County,NC
French Broad River Water Reclamation Facility
NPDES Permit No.NC 0024911
I
1 t

I
Permit No.S-007-12
B. Rationale For Limitations and Effluent Limits
IThe following pollutants were assigned numerical limits in this Industrial User
Permit for Monitoring Point 01 based on the categorical regulations and the MSD Sewer
I Use Ordinance which-ever is more restrictive. These limits do not result in over
allocation the Maximum Allowable Industrial Loading determined with the Headworks
Analysis among all Users.
I Daily
Pollutants Maximum Units
I Cadmium 0.07 mg/1
Chromium 1.00 mg/1
Copper 1.00 mg/1
I Lead 0.40 mg/1
Nickel 1.00 mg/1
Silver 0.24 mg/I
I Zinc 1.00 mg/I
Tin 1.00 mg/1
Cyanide 0.65 mg/I
ITTO 2.13 mg/1
The Metropolitan Sewerage Treatment Plant is experiencing no difficulty treating
I the industrial waste it is receiving at this time. Permit limits are based on the current
Headworks Analysis, which considers most recent available industrial monitoring and
analytical characterization of the MSD Wastewater System. Limits established in
I Permits to Discharge Industrial Waste were utilized in the Headworks Analysis to
determine the capability of the Wastewater Treatment Plant to operate within design and
Permit Limits, pass-through and receiving stream Water Quality Criteria, and without
Ichemical inhibition.
IC. Rationale For Other Pollutants
1. The following pollutant, which was detected in the discharge at Monitoring
Point 01, is monitored with the TTO monitoring. This parameter is limited by
I
the sum of the TTO.
Pollutants
IChloroform
I
I
I 2

1
Permit No.S-007-12
2. The following pollutants are Priority Pollutants known to be used in the
manufacturing process and expected to be in the discharge of Monitoring
Point 01. These parameters are limited by the sum of the TTO.
Pollutants
Chloride
Fluoride
1. The following pollutant is known to be used in the manufacturing process.
Concentrations discharged at Monitoring Point 01 are expected to be at or
below domestic concentrations.
Pollutants
Aluminum
1
1
3 1

I
I Inspector: Jon H.van Hoff �q—_t Permit Number: S 4
t�'H 5EW -'fi
Date: 2/3/2014 �q as1 03
Permit expiration: 12/3112016
s s Date of Last Revised SCRP: 11/1/2013
r`
r
�*°apr. ..o'
IMETROPOLITAN SEWERAGE DISTRICT
INDUSTRIAL PRETREATMENT INSPECTION
1 A. General Information I
Facility Name: Arvato Entertainment LLC Phone Number: 1828)658-2000
I Industrial Category: CD.DVD Blue Ray Manufacturer and Call Center Fax Number: [phone]
Location Address: 108 Monticello Rd. Mailing Address:
Weaverville V )8787
I Responsible Official(title):
Peter Schaper. Vice President Qf Operations
Contact Person(title):
I ,Adam Karn.HR.EHS Supervisor.David Tunnel!.Facility& Compliance Supervisor
B. Work Information I
IAverage Number of Employees working 8 hours: 162 12 hours:
Average Number of Work Days: Mon.-Fri. (8 hr). 7 days(8 hr)
IWeeks Shut Down: LV(4
C Sources of Water I
I Surface water: gal
Well water. gal
Municipal water. 43.249 gal
ID. Water Usage,gpd I
I wash down: gal Metered-1 ❑
Cooling make-up: 38.893 gal Metered-2 ❑r
Boiler make-up: gal Metered-3 ❑
I Evaporation: gg( Metered-4 ❑
Sanitary: 3.258 gal Metered-5 ❑
Process: LIZ gal Metered-6 ❑
Pretreatment: EU Ed Metered-7
E. In-house Meters'
I
Meter Date Certified Used for Billing
Cooling Tower 5/9/14 WI
Pretreatment Effluent 19 Mar 14 ❑
❑
IEMSRP4.5.1 01
I

I
F. Pretreatment (
Type of pretreatment system: Metal Precipitation
Is the pretreatment facility properly maintained and operated? ❑ Yes ❑ No
Explain:
t
Is stand-by power necessary? ❑ Yes © No
Has the treatment system experienced any operational upsets? ❑ Yes ❑ No
Explain:
Type of Alarm system: Light and shut down alarm in thepretreatment room and an alarm at the computer in
g P
the office. The alarms for high level for influent holding tanks,tanks 1,2,sandflter
feed,&final pit,&low level for feed tanks,&for pH.
How often is the pH meter calibrated?: weekly
G. Monitoring
)
Parameter Sampling Analysis Performed by(Frequency) '
flow Metered in-house (daily)
pH Grab in-house (daily)
Zinc Composite Pace (twice a month)
Lead Composite Pace (twice a month)
Nickel Composite Pace (twice a month)
Silver Composite Pace (twice a month)
Cadmium Composite Pace (twice a month)
Chromium Composite Pace (twice a month) i
Copper Composite Pace (twice a month)
Cyanide Grab Pace (twice a month)
TTO Grab Pace(once per permit period) '
1
EMSRP4.5.101

I
I
H. Residual Solids I
I Quantity Date of Last Manifest
Solid Generated Source Method of Disposal (Quantity)
Pretreatment Sludge 2,288 lb/yr filter pressed and dried Nexeo Solutions 9/24/13 (1,716 lb)
I Grease not measured interceptor for kitchen CBP N/A
*extra liquid wastes
lacquer 1,356!b/yr Replication area Nexeo Solutions 6/12/12 (565 lb)
I
Ethyl Acetate 560 lb/ry Kiwo Wash Nexeo Solutions 9/24/13 (490!b)
I I. Liquid Waste I
Quantity Amount Storage Date of Last Manifest
Liquid Waste Generated Container Method of Disposal fQuantityl
I
Ink waste 813 lb/yr 55 gal drum
<500 gal/yr 55 gal drum Nexeo Solutions 6/12/12 (610 lb)
oilHolston Energy 2/4/13 (500 gal)
Aquapell 1,1401b4r 55 gal drum Nexeo Solutions 11/12/12 (285 lb)
I flammable(ink&isopro 547 lb/yr
55 gal drum Nexeo Solutions 6/12/12 (410 lb)
NaOH(caustic) 190 lb/yr 55 gal drum Nexeo Solutions 2/14/12 (190 lb)
propylene glycol&acetat 1,205 lb/yr 55 gal drum Nexeo Solutions 4/16/13 (1,004 lb)
INi Bath <1,000 lb/yr 55 gal drum Nexeo Solutions 9/24/13 (1,224 lb)
I
I
I
I
I
I
I
I
EMSRP4.5.1 01
I

I
Inspector: Jon H. van Hoff Permit Number: S-003 J.2I
EW
N SEg4„
y.
Date: 3/]8/20]4 14sr Permit expiration: 12/31/2016
A- t Date of Last Revised SCRP: 6/20/2012
ti4'. !T. .v.r
METROPOLITAN SEWERAGE DISTRICT
I
INDUSTRIAL PRETREATMENT INSPECTION
A. General Information'
I
Facility Name: Asheville Metal Finishing,Inc. Phone Number: [phone]
Industrial Category: Electroplating Fax Number: [phone]
I
Location Address: 178 Clingman Ave. Mailing Address: post Office Box 16237
Asheville 28801 Asheville Lc 28816
Responsible Official(title):
I
Thomas Finger.President
Contact Person(title):
Tom Israel.General Manager/Todd Israel.Plant Manager
B. Work Information I
Average Number of Employees working 8 hours: 22 12 hours:
I
Average Number of Work Days: Mon.-Fri.
Weeks Shut Down: VL.LA
I
C. Sources of Water
Surface water: gai
I
Well water: ad
Municipal water: 3009 gal
D. Water Usage,gpd I 1
wash down: gal Metered-1 ❑
I
Cooling make-up: gai Metered-2 111
Boiler make-up: gal Metered-3 ❑
Evaporation: jai gal Metered-4 ❑
I
Sanitary: SQ gal Metered-5 ❑
Process: )289 gal Metered-6 ❑r
Pretreatment: gal Metered-7 ❑
I
E. In-house Meters I
Meter Date Certified Used for Billing
I
Pretreatment meter 4 Mar 14 ❑
111
EMSRP4.5.1 01
I
I

I
1 F. Pretreatment I
Type of pretreatment system: Metal Precipitation
IIs the pretreatment facility properly maintained and operated? © Yes ❑ No
Explain:
I
Is stand-by power necessary? ❑ Yes No
I Has the treatment system experienced any operational upsets? 1=1 Yes ❑� No
Explain:
IType of Alarm system:
1 How often is the pH meter calibrated?: calibrated weekly
' G. Monitoring
IParameter Sampling Analysis Performed by(Frequency)
flow Metered in-house (monthly)
I
pH
Cadmium Metered in-house (daily)
Grab Pace(once a week)
Lead Grab In-house(prior to discharge) Pace(once a week)
I
Silver
Tin Grab In-house(prior to discharge) Pace(once a week)
Grab In-house(prior to discharge) Pace(once a week)
Chromium Grab In-house(prior to discharge) Pace(once a week)
I
Copper Grab In-house(prior to discharge) Pace(once a week)
Nickel Grab In-house(prior to discharge) Pace(once a week)
Zinc Grab In-house(prior to discharge) Pace(once a week)
I
Cyanide Grab In-house(prior to discharge) Pace(once a week)
TTO Grab Pace(once per permit)
I
EMSRP4.S.1 01

I
H. Residual Solids I
Quantity Date of Last Manifest
Solid Generated Source Method of Disposal (Quantity)
Filter cake 103,209 lb/yr pretreatment Envirite of PA 2/6/14 (13,262 lb)
i
i
L Liquid Waste
Quantity Amount Storage Date of Last Manifest
Liquid Waste Generated Container Method of Disposal (Quantity)
Nitric Acid 720 gal/yr 55 gal drum Advance Chem 5/31/13 (330 gal)
1
1
I
EMSRP4.5.1 01 ,
1

I
I
Inspector: ,Ion H. van Hoff E Permit Number. S-005
"A 14Gie
Date: 4/30/2014 X40' Permit
Permit expiration: j2/31/2016
s Date of Last Revised SCRP: 3/1/2013
I }°1 .11F
Y
I METROPOLITAN SEWERAGE DISTRICT
INDUSTRIAL PRETREATMENT INSPECTION
I
A. General Information I
Facility Name: Asheville Paint and Powder Coat. Inc. Phone Number [phone]
IIndustrial Category: Metal Finishing&Powder Coat Painting Fax Number 1828)299-1779
Location Address: J6 Old Charlotte Hwy. Mailing Address: post Office Box 25028
Asheville EC )8803 Asheville Q )8813
I Responsible Official(title):
Tom Finger.President
Contact Person(title):
I
Tom Finger.President
B. Work Information I
IAverage Number of Employees working 8 hours: is 12 hours:
Average Number of Work Days: Mon.-Fri.
Weeks Shut Down: jy(g
C. Sources of Water'
I Surface water gal
Well water: gal
Municipal water ilk gal
ID. Water Usage,gpd I
wash down: gal Metered-1 ❑
I
Cooling make-up: gal Metered-2 ❑
Boiler make-up: gal Metered-3 ❑
Evaporation: gal Metered-4 El'
Sanitary: 251 gal Metered-5 ❑
Process: ILO gal Metered-6 ❑
IPretreatment: gal Metered-7 ❑
E. In-house Meters I
I Meter Date Certified Used for Billing
N/A ❑
CI
In
El
❑
CI
1 EMSRP4.5.1 DI

I
F. Pretreatment I I
Type of pretreatment system: NM
Is the pretreatment facility properly maintained and operated? © Yes ❑ No I
Explain:
I
Is stand-by power necessary? ❑ Yes ❑� No
Has the treatment system experienced any operational upsets? © Yes ❑ No
I
Explain: Removal of process wastewater is unaccountable
Type of Alarm system: M I
How often is the pH meter calibrated?: at the time of the discharge. I
G. Monitoring I I
Parameter Sampling Analysis Performed by(Frequency) t
flow Continuous in-house-at time of discharge
pH Grab in-house-at time of discharge I Cadmium Grab Pace-at time of discharge
Chromium Grab Pace-at time of discharge
Copper _ Grab Pace-at time of discharge I Lead Grab Pace-at time of discharge
Nickel Grab Pace-at time of discharge
Silver Grab Pace-at time of discharge
I
Zinc Grab Pace-at time of discharge
Cyanide Grab Pace-at time of discharge
TTO Grab Pace-once per permit period
I
I
I
I
I
EMSRP4.5.1 01
I

I
H. Residual Solids
I
Quantity Date of Last Manifest
Solid Generated Source Method of Disposal (Quantity)
paint not measured powder coat bake it&landfill NM
Phosphate Sludge 3,000 164,r Phosphate wash Envirite of PA 3/29/11 (9,155 lb)
I. Liquid Waste,
' Quantity Amount Storage Pate of Last Manifest
Liquid Waste Generated Container Method of Disposal (Quantity)
1
1
EMSRP4.5.1 01
1

I
Inspector: Jon H.van Hoff Permit Number: 5-071I I
Date: J/24/2014 �4,4� 44:. Permit expiration: 12/31/2016
Date of Last Revised SCRP: 12/15/2014
Ih4 y�.t
METROPOLITAN SEWERAGE DISTRICT
I
INDUSTRIAL PRETREATMENT INSPECTION
A. General Informationi
I
Facility Name: Balcrank Corporation Phone Number: 028)645-4261
Industrial Category: Manufacturer of pumps and hoses Fax Number: 028)658-0840 I Location Address: 115 Reems Creek Road Mailing Address: szei
Weaverville aQ 28787
Responsible Official(title):
I
Vickie O'Shield.Controller. Vice President of Operations&Finance
Contact Person(title):
Roger Honevcutt. Plant Maintenance/Garr Mease.Production Manager
I
B. Work Information 1
Average Number of Employees working 8 hours: 4,i 12 hours:
I
Average Number of Work Days: Mon.-Fri.
Weeks Shut Down: VL/d
Sources of Water I
C.
Surface water: gal I Well water: gal
Municipal water: 1.511 gal
D. Water Usage,gpd l I
wash down: gal Metered-1 ❑
Cooling make-up: gal Metered-2 ❑ t
Boiler make-up: gal Metered-3 ❑
Evaporation: gal Metered-4 ❑
I
Sanitary: .1.91 gal Metered-5 ❑
Process: jQ gal Metered-6 ❑
Pretreatment: gg( Metered-7 ❑
I
E. In-house Meters
Meter Date Certified Used for Billing I
111
CI
❑❑
EMSRP4.5.1 01
I

I
F. Pretreatment ,
Type of pretreatment system: Metal Removal and OIL/Water Separator
IIs the pretreatment facility properly maintained and operated? ❑d Yes ❑ No
Explain:
I
Is stand-by power necessary? ❑ Yes Q No
IHas the treatment system experienced any operational upsets? ❑ Yes ❑� No
Explain:
I
Type of Alarm system: /A
IHow often is the pH meter calibrated?: each release of categorical wastestre
I
G. Monitoring
I
IParameter Sampling Analysis Performed by(Frequency)
flow Calculated in-house (monthly)
I
pH
Cadmium Grab Hand held pH meter(day of treatment)
Grab Pace(each discharge)
Chromium Grab Pace(each discharge)
I
Copper Grab Pace(each discharge)
Lead Grab Pace(each discharge)
Nickel Grab Pace(each discharge)
I
Silver Grab Pace(each discharge)
Zinc Grab Pace(each discharge)
Cyanide Grab Pace(each discharge)
I
TTO Grab Pace(once per permit period)
I
I
I
I
IEMSRP4.5.1 01

t
H. Residual Solids I I
1
Quantity Date of Last Manifest
lojid Generated Source Method of Disposal (Quantity)
Tumbler&pit sludge tumblers ABM-American
1
I. Liquid Waste'
Quantity Amount Storage Date of Last Manifest
Liquid Waste Generated Container Method of Disposal (Quantity)
washer water 173 gal/yr 36 gal container Crystal Clean _ 2/17/14 (60 gal)
Coolant and oil 2,451 gal/yr 55 gal drum ABM American 8/20/13 (1,430 gal)
i
EMSRP4.5.1 01 '

I
I
Inspector: Jon H. van Hoff Permit Number: $-070
Date: 4/15/2014 42.> Permit expiration: 12/31/2016
s t Date of Last Revised SCRP: 1/15/2012
I ‘.
METROPOLITAN SEWERAGE DISTRICT
INDUSTRIAL PRETREATMENT INSPECTION
' A. General Information'
Facility Name: Baldor Electric COmpani Phone Number: [phone]
' Industrial Category: Manufacture of Mechanical Drive Components Fax Number: 1828)645-5211
Location Address: 70 Reems Creek Rd. Mailing Address:
Weaverville 'YC 18787
I Responsible Official(title):
Pale Spivey. Plant Manager
Contact Person(title):
IGary Massey.Safety and Environmental Coordinator
B. Work Information '
Average Number of Employees working 8 hours: 111 12 hours:
I
,(¢Average Number of Work Days: M on.- Thurs./weekend
Weeks Shut Down: VLLB
I
C Sources of Water'
I Surface water: gii1
Well water. Pgj
Municipal water: 3.442 gal
D. Water Usage,gpd '
wash down: gal Metered-1 II]'
Cooling make-up: 2Z2 gal Metered-2 E1
Boiler make-up: gal Metered-3 ❑
I Evaporation:
gal Metered-4 ❑
Sanitary: 1.050 gal Metered-5 ❑
Process: IL1 gal Metered-6 ❑
I
Pretreatment: gal Metered-7 ❑
E. In-house Meters'
IMeter Date Certified Used for Billing
Primary Coolant Makeup 5/24/05
2ndary Coolant Makeup 4/6/06 0
I Furnace cooling 5/24/05
Pretreatment effluent 3/15/11 ❑
Black Oxide Meter 7 Nov 14 ❑
IEMSRP4.5.1 01

I
F. Pretreatment I I
Type of pretreatment system: N/A I Is the pretreatment facility properly maintained and operated? ❑ Yes ❑ No
Explain:
Is stand-by power necessary? ❑ Yes [] No
Has the treatment system experienced any operational upsets? ❑ Yes ❑ No I
Explain:
Type of Alarm system: 'An audible high flow alarm for the berm of the Black Oxide process.
How often is the pH meter calibrated?: monthly I
G. Monitoring
Parameter Sampling Analysis Performed by(Frequency) I
MP#01
flow Metered in-house (daily) '
pH Metered in-house (daily)
Copper Composite Environmental Testing Solution (monthly)
Lead Composite Environmental Testing Solution (monthly)
I
Cyanide Grab Environmental Testing Solution (monthly)
MP#02
flow Metered Environmental Testing Solution (monthly)
pH Grab Environmental Testing Solution (monthly)
Cadmium Composite Environmental Testing Solution (monthly) I
Chromium Composite Environmental Testing Solution (monthly)
Copper Composite Environmental Testing Solution (monthly)
Nickel Composite Environmental Testing Solution (monthly) I
Zinc Composite Environmental Testing Solution (monthly)
Cyanide Grab Environmental Testing Solution (monthly)
Lead Composite Environmental Testing Solution (monthly)
Silver Composite Environmental Testing Solution (monthly)
TTO Grab Environmental Testing Solution (once/S years)
I
I
EMSRP4.5.1 01
I

I
I
H. Residual Solids I
I
Quantity Date of Last Manifest
Solid Generated Source Method of Disposal (Quantity)
metal shavings 4,000,000 16.61r machining Omni N/A
Imetal sludge/oil dry 11,0001b6lr machining Clean Harbors NM
Liquid Waste
Iwashes& blk.Oxi 40,0001b6,r Black Oxide Safety Kleen 12/13/13 (5,000 lb)
I I. Liquid Waste I
Quantity Amount Storage Date of Last Manifest
Liquid Waste Generated Container Method of Disposal (Quantity!
I Non-haz Coolant&mop 454,000 lb/yr 5,000 gal tank
oil 20,7641b/yr 500 gal tank Clean Harbors 4/8/14 (5,000/b)
Safety Kleen 12/3/13 (1,075 gal)
Pb contaminated Coolant 36,000 lb/yr 55 gal drum Safety Kleen 3/7/14 (2,845 lb)
I Antecorit SV 5041b/yr
55 gal drum Clean Harbors 5/6/13 (156 lb)
Pb contaminated mop wa 2,000 lb/yr 55 gal drum Safety Kleen 4/4/14 (170 lb)
Zinc Chloride 1,295 lb/yr 55 gal drum Clean Harbors 4/10/13 (1,295 lb)
ITru Temp(NaOH) 10,096 1b67 55 gal drum Clean Harbors 10/4/13 (2,700 lb)
I
I
I
I
I
1
I
I
EMSRP4.5.101

I
Inspector: Jon H. van Hoff Permit Number. 3-060 di
'
Date: 2/17/2014 .g 4 Permit expiration: 12/31/2016
Date of Last Revised SCRP: 11/7/2012
I
`'•+,
,.JO.r• SIP'
METROPOLITAN SEWERAGE DISTRICT
I
INDUSTRIAL PRETREATMENT INSPECTION
A. General Information'
I
Facility Name: Blue Ridge Metals Corporation Phone Number: [phone]
Industrial Category: ffangfactuing of Cold Head Wire&Slugs Fax Number: [phone]
I
Location Address: 180 Mills Gap Rd. Mailing Address: post Office Box 189
Fletcher VLA 18732 Fletcher NQ 28732
Responsible Official(title):
I
l(vo Shiozawa.Senior Vice President
Contact Person(title):
Carroll Morgan.Production/Engineer Technician
I
B. Work Information I
Average Number of Employees working 8 hours: la 12 hours: I
Average Number of Work Days: Mon.-Fri
Weeks Shut Down: 4th of July and Christmas
C. Sources of Water'
Surface water: gal
I
Well water: gal
Municipal water: 92.958 gal
D. Water Usage,gpd I 111
wash down: gal Metered-1 ❑
I
Cooling make-up: gal Metered-2 El
Boiler make-up: gal Metered-3 ❑
Evaporation: gal Metered-4 ❑
I
Sanitary: ¢ El
gal Metered-5
Process: 35.141 gal Metered-6 ❑
Pretreatment: 57.195 gal Metered-7 ❑d I
E. In-house Meters,
Meter Date Certified Used for Billing
I
Effluent flow meter 5/9/13 lkl
Process flow meter(2") 9 Nov 12 W
Domestic meter(1 1/2") 12/30/07 W I
El
EMSRP4.5.1 01
I

i
F. Pretreatment I
Type of pretreatment system: Metal Precipitation
Is the pretreatment facility properly maintained and operated? © Yes ❑ No
Explain:
1
Is stand-by power necessary? ❑ Yes LI No
' Has the treatment system experienced any operational upsets? ❑ Yes No©
Explain:
Type of Alarm system: Effluent pH alarm shuts down pumps,triggers a portable beeper,visual alarm in the coil
area and an audible/visual alarm in the cafeteria.
How often is the pH meter calibrated?: checked weekly against hand-held/c
1 G. Monitoring I
Parameter Sampling Analysis Performed by(Frequency)
flow Metered in-house (daily)
pH Metered in-house (daily)
Lead Composite Pace(once a week)
Zinc Composite Pace(once a week)
1
i
1
i
1
1
1
EMSRP4.5.1 01
i

I
H. Residual Solids I I
Quantity Date of Last Manifest
I
Solid Generated Source Method of Disposal (Quantity)
Sludge-sulfuric acid 33,000 ib/yr barrel and coil line Envirite of Ohio 6/12/13 (16,500 lb)
Ferrous Sulfate 64,000 ton/yr acid recovery Add Iron Corp. weekly
cake 115 ton/yr er press from pretreatm Palmetto Landfill 1/31/14 (6.47 ton) i
I
I. Liquid Waste I
Quantity Amount Storage Pate of Last Manifest I
Liquid Waste Generated Container Method of Disposal (Quantity)
Sulfuric acid 6,000 gal/yr tank Envirite of Ohio 12/27/13 (3,000 gal) I Potassium Hydroxide 3,989 gal/yr tank Envirite of Ohio 10/11/13 (2,327 gal)
oily water(includes parts 34,650 gal/yr 55 gal drum FFC Enviro. 1/20/14 (5,775 gal)
Phosphate and water 5,600 gal/yr 55 gal drum VLS Recovery 12/22/13 (2,800 gal)
I
Water and soap 5,000 ga//yr 55 gal drum VLS Recovery 12/20/13 (5,000 gal)
I
I
I
I
I
I
I
I
EMSRP4.5.101 '
I

I
I Inspector: Jon H.van Hojf 40x sEviERve S Permit Number: 03011
Date: 1/16/2014 �o� Qs. Permit expiration: 12/31/2016
Date of Last Revised SCRP: 4/29/2013
I /
4.O_vr. .0r
I METROPOLITAN SEWERAGE DISTRICT
INDUSTRIAL PRETREATMENT INSPECTION
I
A. General Information I
Facility Name: Borg Warner Thermal Systems Phone Number: (8281684-3501
I Industrial Category: Manufacturer of Viscous and Plastic Fan Drivers Fax Number: (8281687-5338
Location Address: 40 Cane Creek Industrial Park Mailing Address: post Office Box 1509
Fletcher VLA )8732 Fletcher VLA 18732
I Responsible Official(title):
Todd Bennington.Plant Manager
Contact Person(title):
IGrover DeHart.EHS Engineer
B. Work Information I
IAverage Number of Employees working 8 hours: El 12 hours:
Average Number of Work Days: mom-Fri.
Weeks Shut Down: 4th of July and 12 dgvs at Christmas
C Sources of Water I
I Surface water: gal
Well water: gg(
Municipal water: 17.115 gal
D. Water Usage,gpd
wash down: gat Metered-1 ❑
ICooling make-up: gal Metered-2 ❑
Boiler make-up: gal Metered-3 ❑
I Evaporation: ggl Metered-4 ❑
Sanitary: 6.875 gal Metered-5 ❑
Process: ESQ gal Metered-6 ❑
Pretreatment: 9.790 gal Metered-7 W
E. In-house Meters'
I Meter Date Certified Used for Billing
Effluent flow meter 28 Feb 12 ❑
OF effluent to chem.nreci 2012 ❑
ICold rinse tank to chem.o 2012 ❑
IEMSRP4.5.1 01
I

I
F. Pretreatment I i
Type of pretreatment system: Ultrafiltration for Oils/Chemical Precipitation
Is the pretreatment facility properly maintained and operated? © Yes ❑ No
Explain:
I
Is stand-by power necessary? ❑ Yes [I No
Has the treatment system experienced any operational upsets? ❑ Yes W No I
Explain:
Type of Alarm system: igh level alarms on tank#1 in UF and#1& #10 in chemical precipitation treatment. '
rH alarms for T-2 and T-3 tanks. The alarms are audible and visual in the pretreatment
area.
How often is the pH meter calibrated?: monthly
G. Monitoring
I 111
Parameter Sampling Analysis Performed by(Frequency) I
flow Metered in-house (daily)
pH Grab in-house (daily)
I
Cadmium Grab in-house(weekly);Pace(twice a month)
Chromium Grab in-house(weekly);Pace(twice a month)
Copper Grab in-house(weekly);Pace(twice a month)
Lead Grab in-house(weekly);Pace(twice a month)
Nickel Grab in-house(weekly);Pace(twice a month)
Silver Grab Pace(twice a month)
Il
Zinc Grab in-house(daily);Pace(twice a month)
Cyanide Grab Pace(twice a month)
TTO Grab Pace(once per permit)
I
I
I
I
I
EMSRP4.5.101 '
I

I
I
H. Residual Solids I
I
Quantity Date of Last Manifest
Solid Generated Source Method of Disposal (Quantity)
Sludge 12.4 ton/yr rhes.Filter press,mopp, STAT 2/8/13 (12.4 tons)
I metal chips 504 tons/yr Henry Filter CRG monthly
grease and oil <150 gaUyr kitchen Blue Ridge Biofuel annually
I
II I. Liquid Waste I
Quantity Amount Storage Date of Last Manifest
Liquid Waste Generated Container Method of Disposal IQuantityl
I paint waste 406 lb/yr
1,473 gal/yr
gal drum STAT 12/13/13 (440 lb)
Oil tote FCC Enviro. 12/20/13 (255 gal)
Oily water&coolant 35,280 gal/yr 8,000 gal tank STAT,Inc. 12/20/13 (2,700 gal)
I
I
I
I
I
I
I
I
I
I
IEMSRP4.5.1 01
I

I
Inspector: Jon H.van Hoff Permit Number: 5-015 d2
Date: 3/6/2014 �q4� Qs. Permit expiration: 12/31/2016
a • Date of Last Revised SCRP: 11/11/2013
wit
Ci i�
4 # .
METROPOLITAN SEWERAGE DISTRICT
INDUSTRIAL PRETREATMENT INSPECTION
A. General InformationI I
Facility Name: Continental Automotive Systems. Inc. Phone Number: [phone]
Industrial Category: Manufacturer and Assembler of Brake Systems Fax Number: [phone]
Location Address: I Oualily Wqy Mailing Address:
Fletcher 28732
Responsible Official(title):
11
,teff Scott.Plant Manager
Contact Person(title):
Lisa Foster-Morrow.Senior EHS Administrator
I
B. Work Information I
Average Number of Employees working 8 hours: Lei 12 hours: 345 I
Average Number of Work Days: Mon.-Fri./7 days
Weeks Shut Down: Christmas
C. Sources of Water'
Surface water: Eel
Well water: Ent
Municipal water: 66.828 gal
D. Water Usage,gpd I S
wash down: gal Metered-1 ❑
Cooling make-up: 13.651 gal Metered-2 II]
Boiler make-up: gal Metered-3 ❑
Evaporation: gal Metered-4 ❑
Sanitary: 15.563 gal Metered-5 ❑
111
Process: 6501 gal Metered-6 ❑
Pretreatment: 31.113 gal Metered-7 ❑�
E. In-house Meters
Meter Date Certified Used for Billing
Cooling tower 19 Oct 12 W
Central Coolant system 10 Oct 12 0
Coolant Reclaim#1 Nov 2000 ❑r
Coolant Reclaim#2 May 2005 ❑i
Pretreatment 4 Jul 14 ❑
EMSRP4.5.1 01
II
I

I
IF. Pretreatment I
II Type of pretreatment system: Chemical Precipitation
Is the pretreatment facility properly maintained and operated? ❑ Yes ❑ No
Explain:
I
Is stand-by power necessary? ❑ Yes © No
IHas the treatment system experienced any operational upsets? ❑ Yes ❑ No
Explain:
Type of Alarm system: audible and visual alarm for high and low level and pH. It will also shut system down.
Alarm noticed in plating area and the unload/load station.
How often is the pH meter calibrated?: lab:daily,eff. Tank:weekly
1
G. Monitoring
IParameter Sampling Analysis Performed by(Frequency)
flow Metered in-house (daily)
I
pH Metered in-house (daily)
Cadmium Composite Pace(twice a month)
Chromium Composite Pace(twice a month)
I Copper Composite Pace(twice a month)
Lead Composite Pace(twice a month)
Nickel Composite Pace(twice a month)
ISilver Composite Pace(twice a month)
Zinc Composite Pace(twice a month)
Cyanide Grab Pace(twice a month)
ITTO Grab Pace(once per 5 years)
I
I
I
I
EMSRP4.5.1 01
I

I
H. Residual Solids
I
Ouantity Date of Last Manifest
I
Solid Generated Source Method of Disposal (Quantity)
Shavings&chips 1,600 tons/yr machining McDowell N/A
pretreatment solids 780 cu yd/yr plating Envirite of Ohio 5/4/14 (13 cu yd
I
I
I. Liquid Waste'
I
Quantity Amount Storage Date of Last Manifest
Liquid Waste Generated Container Method of Disposal (Quantity)
oily water 19,200 gal/yr 55 gal drum STAT 4/14/14 (2,100 gal)
Naphtha 86 gal/yr 55 gal drum Spectra 5/1/14 (86 gal)
Ink and solvent 125 lb/yr 55 gal drum STAT 12/20/13 (125 lb)
Sodium Hydroxide 1,9201b/yr tote Tradebe 3/21/14 (400 lb) I Waste Paint 6,000 lb/yr 55 gal drum Tradebe 5/6/14 (400 ib)
I
I
I
I
1
I
I
I
I
EMSRP4.5.1 01
I

I
Inspector: Jon H. van HQ ��PN Permit Number: S-066
Date: 3/26/2014 e� if'.., Permit expiration: 12/31/2016
t Date of Last Revised SCRP: 3/29/2012
II,� .`.i
t
I METROPOLITAN SEWERAGE DISTRICT
INDUSTRIAL PRETREATMENT INSPECTION
IA. General Information'
Facility Name: Craggy Prison Laundry Phone Number: [phone]
I Industrial Category: Laundry Fax Number: [phone]
Location Address: j405 Riverside Drive Mailing Address:
Asheville VLA 18804
I Responsible Official(title):
Michael Greene.Corrections Enterprise Manager II
Contact Person(title):
/Michael Greene.Corrections Enterprise Manager II
B. Work Information)
I
Average Number of Employees working 8 hours: 7 Staff/56 inmates 12 hours:
Average Number of Work Days: 'fon.-Thurs. (10 hour days)
Weeks Shut Down: VL1A
C. Sources of Water
I Surface water: gal
Well water: gal
Municipal water: 50.370 gal
ID. Water Usage,gpd ,
wash down: gal Metered-1 ❑
ICooling make-up: gal Metered-2 ❑
Boiler make-up: gal Metered-3 ❑ .
I Evaporation: ggl Metered-4 ❑
Sanitary: 1.575 gal Metered-5 ❑
Process: 48.795 gal Metered-6 ❑
1 Pretreatment: gal Metered-7 ❑
E. In-house Meters
I Meter Date Certified Used for Billing
N/A ❑
111
I 111
❑
CI
IEMSRP4.5.1 01
I

I
F. Pretreatment I
1
Type of pretreatment system: Lint Removal
Is the pretreatment facility properly maintained and operated? © Yes ❑ No
Explain:
I
Is stand-by power necessary? ❑ Yes © No
Has the treatment system experienced any operational upsets? ❑ Yes © No I
Explain:
Type of Alarm system: /A iii
How often is the pH meter calibrated?: Calibrate once or twice a month 1
G. Monitoring I
Parameter Sampling Analysis Performed by(Frequency)
I
flow Metered in-house (daily)
pH Grab in-house (daily)
111
BOD Composite Pace(once a month)
TSS Composite Pace(once a month)
I
I
I
I
I
I
I
EMSRP4.5.1 01 1

I
H. Residual Solids I
Quantity Date of Last Manifest
Solid Generated Source Method of Disposal (Quantity)
lint not measured hing and drying operati landfill NM
I
I
I. Liquid Waste I
Quantity Amount Storage Date of Last Manifest
Liquid Waste Generated Container Method of Disposal (Quantity)
oil <7 gaUyr 55 gal drum US Filter 2002
I
1
I
I
I
1
I
I
EMSRP4.5.1 01
I

I
Inspector Jon H.van Hoff Permit Number. 3-057,J.2
J,,'p SH4
Date: 5/2/2014 11 Asa Permit expiration: 12/31/2016
s Date of Last Revised SCRP: 7/1/2013
It
`l`4
r0.,yr. atY''
METROPOLITAN SEWERAGE DISTRICT
I
INDUSTRIAL PRETREATMENT INSPECTION
A. General Information I I
Facility Name: Day International. Inc. Phone Number: [phone]
Industrial Category: Manufacturer of rubber&plastic coaled products Fax Number: [phone]
Location Address: 95 Glenn Bridge Rd. Mailing Address: post Office Box 1077
Arden VLA 28704 Arden sc 18704
Responsible Official(title):
111
Ouentin Hopkins.Facility Manager
Contact Person(title):
John Hodges.Safety.Health and Environmental Manager I
B. Work Information I
Average Number of Employees working 8 hours: ja 12 hours:
I
Average Number of Work Days: Mon.-Fri.
Weeks Shut Down: NA
C. Sources of Water I
Surface water: gal
Well water: gal
Municipal water: 79.193 gal
D. Water Usage,gpd I I
wash down: gal Metered-1 ❑
Cooling make-up: ggl Metered-2 ❑ '
Boiler make-up: gal Metered-3 ❑
Evaporation: 40.505 gal Metered-4 ❑
I
Sanitary: 8.250 gal Metered-5 El
Process: 14.867 gal Metered-6 ❑
Pretreatment: j5.571 gal Metered-7 W
i
E. In-house Meters'
Meter Date Certified Used for Billing
Cooling Tower#1.2.3.4 not used ❑
Boiler#1.2 not used ❑
Effluent meter 6/5/13 ❑r
EMSRP4.5.1 011
1

I
IF. Pretreatment I
Type of pretreatment system: Filtration
IIs the pretreatment facility properly maintained and operated? © Yes ❑ No
Explain:
I
Is stand-by power necessary? ❑ Yes © No
I Has the treatment system experienced any operational upsets? 11Yes © No
Explain:
IType of Alarm system:
IHow often is the pH meter calibrated?: calibrated weekly
IG. Monitoring I
IParameter Sampling Analysis Performed by(Frequency)
flow Metered in-house (daily)
pH Metered in-house (daily)
Zinc Composite Pace (twice a month)
Toluene Grab Pace (quarterly)
I MBA" Grab Pace (quarterly)
BOD Composite Pace (once a month))
TSS Composite Pace (once a month)
I
TTO Grab Pace (Annually)
oil and grease Grab Pace (once a month)
I
I
I
I
I
IEMSRP4.5.1 01

I
H. Residual Solids I I
Quantity Date of Last Manifest
Solid Generated Source Method of Disposal (Quantity)
Solids 282 lb/yr pretreatment VLS Piedmont 1/3/13 (400 lb)
grinder waste 28,5601b/yr wet grinder VLS Piedmont 2/4/14 (5,950 lb)
I
I. Liquid Waste
Quantity Amount Storage Date of Last Manifest I
Liquid Waste Generated Container Method of Disposal (Quantity)
Heptane and Ethanol 5,375 lb/yr 55 gal drum Giant Resource 4/29/14 (921 lb) I
PUC Cleaner 1,925 lb/yr 55 gal drum VLS Piedmont 4/29/14 (600 lb)
Acetone Resin 4,245 lb/yr 55 gal drum Giant Resource 4/29/14 (921 lb)
Isopropanal/fetrahydrof 1,200 lb/yr 55 gal drum Giant Resource 11/19/13 (300 lb)
oil 514 lb/yr 55 gal drum VLS Piedmont 4/29/14 (300 lb)
Styrene 20,347 lb/yr 55 gal drum VLS Piedmont 4/29/14 (4,550 lb)
MEK/Toluene 250 lb/yr 55 gal drum Giant Resource 2/4/14 (2501b)
I
I
I
I
1
I
I
1
I
EMSRP4.5.101
I
1

I
I Inspector: Jon H. van Hoff `sip seke Permit Number: S 014
Date: 4/17/20144) Permit expiration: 12/31/2016
e 7 1
Date of Last Revised SCRP: 7/1/2012
I.e. ikatair-o-41e571
I
METROPOLITAN SEWERAGE DISTRICT
INDUSTRIAL PRETREATMENT INSPECTION
IA. General Information I
Facility Name: Eaton Phone Number: [phone]
I Industrial Category: Electronic Motor Facility Fax Number: [phone]
Location Address: 121 Heywood Rd. Mailing Address:
Arden NC 28704
I
Responsible Official(title):
Jon Wehrli.Plant Manager
Contact Person(title):
Ben Hale.Senior EHS Technician/Jason Morgan.EHS Manager
B. Work Information I
IAverage Number of Employees working 8 hours: J.000 12 hours:
Average Number of Work Days: Non.-Fri. and Sat. (25%)
Weeks Shut Down: yza
C. Sources of Water
2 Surface water: gal
1 II Well water gal
Municipal water: 9.837 g91
1111 D. Water Usage,gpd
wash down: gal Metered-1 ❑
ICooling make-up: gal Metered-2 ❑
Boiler make-up: gal Metered-3 ❑
I Evaporation: g91 Metered-4 ❑
Sanitary: 9.000 gal Metered-5 ❑
Process: $] gal Metered-6 ❑
Pretreatment: 1 gal Metered-7 ❑Q
I
E. In-house Meters,
I Meter Date Certified Used for Bigg
Paint line Mar 10
CI
ID El
111 EMSRP4.5.1 01

I
F. Pretreatment I I
Type of pretreatment system: N/A 111Is the pretreatment facility properly maintained and operated? ❑ Yes ❑ No
Explain:
I
Is stand-by power necessary? ❑ Yes ❑� No
Has the treatment system experienced any operational upsets? ❑ Yes ❑ No I
Explain:
Type of Alarm system:
How often is the pH meter calibrated?: every daily
Monitorin IlG
SI
Parameter Sampling Analysis Performed by(Frequency) 111
flow Metered in-house (daily)
pH Metered in-house (daily)
Cadmium Grab Pace (at time of discharge)
Chromium Grab Pace (at time of discharge)
Copper Grab Pace (at time of discharge)
I
Lead Grab Pace (at time of discharge)
Nickel Grab Pace (at time of discharge)
Silver Grab Pace (at time of discharge)
Zinc Grab Pace (at time of discharge)
Cyanide Grab Pace (at time of discharge)
TTO Grab Pace (once per permit period)
1
1
I
I
I
EMSRP4.5.101

I
1 H. Residual Solids I
Quantity Date of Last Manifest
Solid Generated Source Method of Disposal (Quantity)
Powder Paint 39,600 lb/yr Powder coat paint VLS Recovery 3/31/14 (2,200 lb)
I grease and oil not measured kitchen trap Valley Protein every 2 weeks
KOH/Iron Phosphate 16,800 114r paint sludge VLS Recovery 3/15/14 (1,600 ib)
I
Liquid Waste I
If.
Quantity Amount Storage Date of Last Manifest
Liquid Waste Generated Container Method of Disposal (Quantity)
Spent Cleaner 2,000 gal/yr hree 250 gal tank. VLS Recovery 1/11/14 (1,000 gal)
IParts Washer 336 gal/yr parts washer Crystal Clean 4/15/14 (56 gal)
Paint and Solvent 400 gal/yr 55 gal drum Nexeo 3/31/14 (400 gal)
I Coolant and oil
9,744 gal/yr 500 gal tank Holston Energy 4/10/14 (818 gal)
water jet 2,500 gal Yr 3,00 gal container VLS Recovery 3/18/14 (2,500 gal)
I
11
I
I
I
I
I
1
IIEMSRP4.5.1 01
I

I
Inspector: Jon H. van Hoff Permit Number: 3-067: 2
J,AH SEWEq„
Date: 5/28/2014 SOP 4, Permit expiration: 12/31/2016
- t Date of Last Revised SCRP: 5/31/2012
t
1
Ci
METROPOLITAN SEWERAGE DISTRICT
INDUSTRIAL PRETREATMENT INSPECTION
A. General Information
Facility Name: Jaocb Holm Industries (America)ilnc. Phone Number: [phone] I
Industrial Category: Manufacturing industrial cleaning towels Fax Number: [phone]
Location Address: 1265 Sand Hill Road Mailing Address:
Candler NC 28715
Responsible Official(title):
IcaSellers.Supply Chain& Operations Vice President America
Contact Person(title):
,Sammy Johnson.Quality Re-Engineering Manager
I
B. Work Information )
Average Number of Employees working 8 hours: Li 12 hours: j$
Average Number of Work Days: Mon-Fri/7 days/week
Weeks Shut Down: sa
C Sources of Water
Surface water: ggf
Well water: Ed
i
Municipal water: 66.071 gal
D. Water Usage,gpd I I
wash down: gal Metered-1 ❑
Cooling make-up: gal Metered-2 ❑ '
Boiler make-up: gaf Metered-3 ❑
Evaporation: gal Metered-4 ❑
Sanitary: L59.2 gal Metered-5 ❑l I
Process: )8.234 gaL Metered-6 ❑
Pretreatment: 36.288 gal Metered-7 ❑�
E. In-house Meters
1
Meter Date Certified Used for Billing
flume 13 Mar 14 ❑r
domestic(1-1/2") 6 AUL'14 ❑r
EMSRP4.5.101 1

F. Pretreatment I
Type of pretreatment system: DAF and filter
Is the pretreatment facility properly maintained and operated? © Yes ❑ No
Explain:
I
Is stand-by power necessary? ❑ Yes © No
Has the treatment system experienced any operational upsets? ❑ Yes © No
Explain:
Type of Alarm system: o
YP Y
How often is the pH meter calibrated?: monthy
G. Monitoring I
Parameter Sampling Analysis Performed by(Frequency)
flow Metered in-house (daily)
pH Metered in-house (daily)
BOD Composite Pace(monthly)
TSS Composite Pace(monthly)
I
I
i
1
1
1
EMSRP4.5.1 01
I

H. Residual SolidsI
I
Quantity Date of Last Manifest
Solid Generated Source Method of Disposal (Quantity)
lint not measured sweeping recycling companines NM
filter paper not measured dumpster landfill NM I
I
I. Liquid Waste I
Quantity Amount Storage Date of Last Manifest
Liquid Waste Generated Container Method of Disposal (Quantityl
oils 165 gaLyr 55 gal drum Universal Enviro. 13 Aug 13 (165 gal)
Naphtha 271 lb/yr 50 gal container Clean Harbors 14 Aug 14 (147 Ib)
I
I
I
1
i
I
I
I
I
I
EMSRP4.5.1 01
I

I
Inspector: Jon H.van Mgt,' \�^�sew Permit Number: 5-009- 2
Date: 5/8/2014 =e, '` � Permit expiration: 12/31/2016
Date of Last Revised SCRP: 4/23/2014
`v. '
IMETROPOLITAN SEWERAGE DISTRICT
INDUSTRIAL PRETREATMENT INSPECTION
A. General Information'
Facility Name: Kearfott Corporation. Motion Systems Div Phone Number: 18281686-3811
I Industrial Category: Guidance and Navigation Systems
LocationFax Number: (8281686-5764
Address: 1858 U.S. 70 West Mailing Address:
flack Mountain VLA 28711
I Responsible Official(title):
hark F. Trcffinger. Group Dir.Operations/Paul Schatteman.Director
Contact Person(title):
Dave Trout.Senior EHS Technician
B. Work Information I
IAverage Number of Employees working 8 hours: In 12 hours:
Average Number of Work Days: Mon.-Fri.
IWeeks Shut Down: Christmas
C. Sources of Water I
Surface water. gal
Well water. gal
Municipal water. 11.631 gal
D. Water Usage,gpd I
wash down: gal Metered-1 ❑
ICooling make-up: gill Metered-2 ❑
Boiler make-up: ggl Metered-3 ❑
1 Evaporation:
gal Metered-4 ❑
Sanitary: 8.750 gal Metered-5 ❑
Process: 1.848 gal Metered-6 ❑
Pretreatment: j.033 gal Metered-7 W
E. In-house Meters I
I Meter Date Certified Used for Bi11ing
effluent flow meter 1/6/14 ❑
El
IIEMSRP4.5.101

F. Pretreatment I
Type of pretreatment system: Metal Precipitation
Is the pretreatment facility properly maintained and operated? © Yes ❑ No 111
Explain:
1
Is stand-by power necessary? ❑ Yes © No
Has the treatment system experienced any operational upsets? ❑ Yes ❑d No I
Explain:
Type of Alarm system: Visual alarm for pH.Audible and visual alarms for high and low levels and for power
outages. PH alarm range it 7-9 and shut down with range 6-10.5.All alarms stop
pumping. I
How often is the pH meter calibrated?: checked weekly calibrated every 2 w
G. Monitoring I
Parameter Sampling Analysis Performed by(Frequency) I
flow Metered in-house (daily)
pH Metered in-house (daily)
Cadmium Composite Pace Analytical&ETS(twice a year)
Chromium Composite Pace Analytical&ETS(twice a month)
Copper Composite Pace Analytical&ETS(twice a month)
Lead Composite Pace Analytical&ETS(twice a year)
Nickel Composite Pace Analytical&ETS(twice a month)
Zinc Composite Pace Analytical&ETS(twice a month) '
Cyanide Grab Pace Analytical&ETS(twice a year)
TTO Grab Pace Analytical(once a permit)
1
I
I
EMSRP4.5.1 01
I

I
1
H. Residual Solids I
I Quantity Date of Last Manifest
Solid Generated Source Method of Disposal (Quantity)
sludge 1,9201b/yr pretreatment Envirite of PA 3/20/14 (4001b)
I Metal shavings not measured machining McDowell Recycle N/A
AK 225 still bottoms 68 lb/yr parts washers Clean Harbors 9/6/02 (1,200 lb)
Potassium CN 771 lb/yr plating Clean Harbors 3/13/14 (4501b)
IWhirklad Powder 343 1647 platine Univar 3/20/14 (100 Ib)
I. Liquid Waste'
Quantity Amount Storage Date of Last Manifest
Liquid Waste Generated Container Method of Disposal (Quantity)
I Acetone and Toluene 566 gal/yrSS gal drum Giant Resource 2/4/14 (110 gal)
Waste Oil 623 gal/yr gal drum Holston Energy 3/24/14 (623 gal)
Acetone and lsoproyl Alc 587 gal/yr 55 gal drum Giant Resource 2/4/14 (165 gal)
IChromic acid 377 gal/yr 55 gal drum EQ of Envirite 3/20/14 (220 gal)
Acetone and Sodium 165 gal/yr 55 gal drum Tradebe Treat. 2/4/14 (55 gal)
Electroless Nickel 739 lb/yr 55 gal drum Envirite of PA 2/4/14 (4001b)
Ebrite Cooper <20 gal/yr 55 gal drum EQ of Envirite 1/24/13 (20 gal)
I
I
I
I
11
11
I
II
•
EMSRP4.5.1 01
II

Inspector: ,ion H. van Huff Permit Number: 5-073:11
SEVEN,
Date: 6/18/2014 a� gss Permit expiration: 12/31/2016
Date of Last Revised SCRP: 7/31/2013
c 4 � I
°0,, ate:•
METROPOLITAN SEWERAGE DISTRICT
INDUSTRIAL PRETREATMENT INSPECTION
A. General InformationI I
Facility Name: Sierra Nevada Brewing Company Phone Number: 828-681-5300
Industrial Category: freer brewery Fax Number:
Location Address: 100 Sierra Nevada Way Mailing Address: t
/Hills River SC 28732
Responsible Official(title):
Stan Cooper.Director of Logistics/Co-Plant Manager
Contact Person(title):
Patrick Rogers.EHS Specialist.Jim Mellem.Quality Operations Manager
B. Work Information l
Average Number of Employees working 8 hours: 22 12 hours:
Average Number of Work Days: 7 days/week
Weeks Shut Down: VLA
C Sources of Water
Surface water: ga(
Well water: >65.067 gq(
Municipal water: 3.717 gal
D. Water Usage,gpd I I
wash down: gal Metered-1 ❑
Cooling make-up: gal Metered-2 ❑ ,
Boiler make-up: gal Metered-3 ❑
Evaporation: gal Metered-4 ❑
Sanitary: 1.300 gal Metered-5 ❑ I
Process: 1.417 gal Metered-6 ❑
Pretreatment: 65.067 gal Metered-7 ❑
E. In-house Meters'
Meter Date Certified Used for Billing
4 Cooling Tower Meters Jun 14 ❑r
Effluent Flume 15 Oct 13
L
EMSRP4.5.1 01
111

I
F. Pretreatment I
Type of pretreatment system: Equalization,anaerobic and aerobic digestion
IIs the pretreatment facility properly maintained and operated? ❑� Yes ❑ No
Explain:
I
Is stand-by power necessary? El Yes ❑ No
IHas the treatment system experienced any operational upsets? ❑ Yes 0 No
Explain:
Type of Alarm system: igh level alarms for each stage of retreatment Theytrigger messages sent to
computer and texting. pH alarm at flume is audible and visual
How often is the pH meter calibrated?: daily
G. Monitoring
1 Parameter Sampling Analysis Performed by(Frequency)
flow Metered in-house (daily)
II pH Metered in-house (daily)
BOD Composite ETS(twice a month)
TSS Composite ETS(twice a month)
I
I
I
I
I
I
I
IEMSRP4.5.1 01

I
H. Residual Solids
I
Quantity Date of Last Manifest
Solid Generated Source Method of Disposal (Quantity)
spent grain 73 million lbs/yr brewing Local Farmers about 1.4 million Ibs/w
hops 180,000 lb/yr brewing Daily's Dumpster May 2014 (16,180 lb)
I
I. Liquid Waste I
Quantity Amount Storage Date of Last Manifest
Liquid Waste Generated Container Method of Disposal (Quantity)
used oil 257 lb/yr 55 gal drum VLS Recovery 5/14/14 (150 Ib)
COD(Sulfuric Acid) 154 Ib/yr 55 gal drum Nexeo 5/14/14 (90 lb)
Solvent and Ink not yet hauled off 55 gal drum N/A NM
1
I
I
I
1
I
I
EMSRP4.5.101

I
I Inspector: Jon H. van Hoff s3.4.0sea Permit Number: S-00712
Date: 6/26/2014 4° 4
s,. Permit expiration: 12/31/2016
fie,
s ; t Date of Last Revised SCRP: 9/16,2011
I71
titr,,,, rd.,,
I METROPOLITAN SEWERAGE DISTRICT
INDUSTRIAL PRETREATMENT INSPECTION
A. General Information'
Facility Name: Williams Plating Company. Inc. Phone Number: [phone]
I Industrial Category: Metal Finisher Fax Number: [phone]
Mailing Address:
Location Address: 6 Industrial Dr. Post Office Box 3042
Arden VLA 28704 Asheville VLA 28802
I Responsible Official(title):
Michael E. Williams(Owner)
Contact Person(title):
Michael E. Williams(Owner)
B. Work Information I
I Average Number of Employees working 8 hours: 2Q 12 hours:
Average Number of Work Days: Mon.-Fri..
Weeks Shut Down: &A
iC Sources of Water
II Surface water. ggj
Well water: gal
Municipal water: L826 gal
ID. Water Usage,gpd I
wash down: gal Metered-1 ❑
ICooling make-up: gal Metered-2 ❑
Boiler make-up: gal Metered-3 ❑
Evaporation: gal Metered-4 ❑
ISanitary: 42q gal Metered-5 ❑
Process: 1.402 gal Metered-6 ❑r
Pretreatment: gal Metered-7 ❑
I
E. In-house Meters I
I Meter pate Certified Used for Billing
in-cominf process Jan 96 ❑
Cl
❑
CI
IEMSRP4.5.1 01

I
F. Pretreatment 1
Type of pretreatment system: Metal Precipitation
Is the pretreatment facility properly maintained and operated? © Yes ❑ No I
Explain:
I
Is stand-by power necessary? ❑ Yes ❑✓ No
Has the treatment system experienced any operational upsets? ❑ Yes © No
Explain:
Type of Alarm system: all tanks and sumps have an audible high level alarm. 111
How often is the pH meter calibrated?: daily I
G. Monitoring I I
Parameter Sampling Analysis Performed by(Frequency) I
flow Metered in-house(daily)
pH Grab in-house(daily) lis
Cadmium Grab Pace (monthly)
Chromium Grab Pace (monthly)
Copper Grab Pace (monthly)
Lead Grab Pace (monthly)
Nickel Grab Pace (monthly)
Silver Grab Pace (monthly)
I
Zinc Grab Pace (monthly)
Tin Grab Pace (monthly)
Cyanide Grab Pace (monthly) I
I
I
I
I
EMSRP4.5.101111
I

K Residual Solids I
Quantity Date of Last Manifest
Solid Generated Source Method of Disposal (Quantity)
pretreatment solids 4,000 lb/yr pretreatment EQ Detroit 3/10/14 (2,000 lb)
I 1
I
I. Liquid Waste I
Quantity Amount Storage Date of Last Manifest
Liquid Waste Generated Container Method of Disposal (Quantityl
' Electroless Nickel 450 gaUyr 55 gal drum
<1 gaUyr 1 gal container AMB America 4/24/14 (300 gal)
oil landfill NM
CN 3,300 lb/yr 55 gal drum EQ Detroit 3/10/14 (2,200 lb)
1
1
1
1
1
1
1
1
1
1
1 EMSRP4.5.1 01
1

I
16
I
I
I
I
I
I
I
N
I
I
71
I
I
1
I�
1
1

I
1
II
I
I
I
I
1N
1
IV
I
I
I
1

r
' ti�PN SEWERgGs
'° Metropolitan Sewerage District
.wJ = OF BUNCOMBE COUNTY, NORTH CAROLINA •
;t
OOUNT Y NOPS
a
March 2,2015
Ms. Sarah Bass,Environmental Engineer
' North Carolina Division of Water Resources
PERCS Unit
1617 Mail Service Center
Raleigh,North Carolina 27699-1617
' Subject: Pretreatment Annual Report for MSD of Buncombe County
Dear Ms. Bass:
Enclosed in this email is the Pretreatment Annual Report for the calendar year 2014. The
' report consists of the following parts:
1. Pretreatment Performance Summary(PPS)
2. Significant Non-Compliance Report(SNCR)
3. Narrative with accompanying enclosure
4. Pretreatment Program Information Database(PPID)
5. Industrial Data Summary Form(IDSF)
6. Allocation Table
' The Public Notice of Non-compliance is not included,because there were no industries in
Reportable Non-Compliance during this calendar year. Also not included is the Historical
Significant Non-Compliance Report. This report was not submitted by the PERCS Unit because
there have not been any Sills in SNC since 2006.
If you need any additional information pertaining to this report,please contact this office
' at(828)225-8230.
Sincerely,
Jon H. van Hoff
Industrial Pretreatment Coordinator
cc: Tom Hartye,P.E.,General Manager,MSD Buncombe Co.
Linda Wiggs,Environmental Senior Specialist,ARO
' Peter Weed,Director of Operations,MSD Buncombe Co.
William Clarke with Roberts&Stevens,P.A
Monty Payne, Field Operations Manager, MSD Buncombe Co.
-Protecting Our Natural Resources-
, 2028 RIVERSIDE DRIVE, ASHEVILLE,NORTH CAROLINA 28804 TELEPHONE:[phone] FAX:[phone] WEBSITE:www.msdbc.org

I
I
Chapter 9, PAR Guidance
Pretreatment Performance Summary (PPS)
I
i. Pretreatment Town Name: MSD of Buncombe County
2. "Primary"NPDES Number NC0024911 This
Column
or Non_Discharge Permit# if applicable=> for
office
I
use
3. PAR begin Date, please enter 01/01/yy or 07/0l/yy 3.=> 1/1/2014 PSSD
4. PAR end Date, please enter 06/30/yy or 12/31/yy 4.=> 12/31/2014 PSED
I
5. Total number of SIUs, includes CIUs 5.=> 19 slus
6. Number of CIUs 6.=> 14 CRUS
7. Enter the Higher Number, either (7a)or(7b)here=> 1* NOIN
I
7a. Number of SIUs not sampled by POTW 7a.=> 1*
7b. Number of SIUs not inspected by POTW 7b.=> 0
8. Number of SIUs with no IUP, or with an expired IUP 8.=> 0 NOCM
9. Total Number of SIUs in SNC due to either IU Reporting violations or
IUP Limit violations. To avoid double counting some SIUs I
Enter (9a+9b )- 9c here=> 0 PSNC
Enter the Number of SIUs in SNC for : I 9a. IU Reporting violations 9a._> 0 MSNC
9b. IUP Limit violations 9b.=> 0 SNPS
9c. Both IU Reporting& Limit violations 9c._> 0
to. Number of SIUs in SNC due to IU Reporting violations
that were not sampled or inspected by POTW 1o.=> 0 SNIN
11. Number of SIUs in SNC due to violation of 11.=> 0 SSNC
Compliance Schedule due dates
12. Number NOVs,NNCs,AOs, or similar assessed to SIUs 12.=> 14 FENF
13. Number Civil or Criminal Penalties assessed to SIUs 13.=> 2 JUDI
14. Number of SIUs included in public notice 14.=> 0 SVPU
I
15. Number of SIUs from which penalties collected 15.=> 2 IUPN
16. Total Amount of Civil Penalties Collected 16.=> $ 350
17. Total Number of SIUs on a compliance schedule 17.=> 0 socs
111
'Foot Notes: AO Administrative Order NOV Notice of Violation
CIU Categorical Industrial User PAR Pretreatment Annual Report
I
CO Consent Order POTW Public Operated Treatment Works
IUP Industrial User Pretreatment Permit SIU Significant Industrial User I NNC Notice of Non-Compliance SNC Significant Non-Compliance,formerly RNC I
*Baldor Electric Company-MPO1 did not discharge for the entire year.
Page 1 PPS.xlsx
1

1 r — MS M NS — 1 NM N - - M w a — E MI MN E
Pretreatment Annual Report (PAR) PAR covers this calendar year=> 2014
Significant Non-Compliance Report (SNCR) Control Authority=Program=Town Name => MSD of Buncombe County
WWTP= Wastewater Treatment Plant,use separate form for each WWTP. WWTP Name => French Broad WRF
SIU= Significant Industrial User NPDES # _> NC0024911
SNC = Significant Non-Compliance
A SNCR Form must be submitted with every PAR, please write "None" if you had No SIUs in SNC during calendar year
SNC ? (Yes/No)
IUP Pipe Industry Name Parameter for each 6-month period.
# # or"Reporting" Jan. -June July-Dec.
None
•
Attach a copy of the Division's "SIUs in SNC Historical Report" for your POTW's SIUs behind this page .
Is the database correct? Notify the Division of any errors ! Database indicates SNC history for previous years.
EVERY SNC MUST be explained in the Narrative, How was, is, or will it be resolved?
REPEAT SNCs are serious matters that MUST be explained in the Narrative.
Form name: PAR,SNCR,2001
Date Revised: 1/4/2001

I
I
2014 PAR Narrative
I
Metropolitan Sewerage District of Buncombe County(MSD)
NPDES#:NC0024911
General Information: I
On February 3,2015,the Metropolitan Sewerage District of Buncombe County(MSD)
I
was granted, by the North Carolina Division of Water Resources, PERCS Unit, an
extension to April 1, 2015 in submitting this Pretreatment Annual Report(PAR).
This year MSD had submitted the Headworks Analysis and it was approved by the I
PERCS Unit on June 26, 2014. In addition, MSD has submitted the Industrial Waste
Survey (IWS). This report was due on November 1, 2014. However, an extension to
December 31, 2014 was approved by the PERCS Unit on August 18, 2014. The
submitted IWS was reviewed and approved on February 20, 2015.
The number of permitted SIUs has not changed during the course of the year. However, I
from the IWS, one Categorical Industrial User was found. After careful evaluation and
discussion, the CIU, Black Mountain Machine & Tool, Inc. has agreed, on February 20,
2015, to be permitted as a Non-Significant Categorical Industrial User rather than have
the waste stream hauled off for proper disposal.
I
SIU Information
Asheville Metal Finishing,Inc. (S-003-12) I
On February 21, 2014, MSD received a 24 hour notification from Asheville Metal
Finishing, Inc.that their Self-Monitoring lab results reported a cyanide(CN) violation.
I
On February 25, 2014, MSD met with Asheville Metal Finishing, Inc. to discuss this 2"d
CN violation, which has occurred in the past 6 months. Upon arrival, MSD was told that
Asheville Metal Finishing, Inc.just became aware of yet another CN limit violation.
As a result of that meeting, it was decided that Asheville Metal Finishing, Inc. would be I issued a Civil Penalty for this third CN violation and that MSD and Asheville Metal
Finishing, Inc. would enter into a Consent Agreement. (The Civil Penalty for Limit
Violation and the Consent Agreement are enclosed with this report.)
I
During this meeting, Asheville Metal Finishing, Inc. also expressed a concerned that they
might experience Chromium violations while they were in the process of eliminating
hexavalent chrome plating in exchange for replacing it with trivalent chrome plating.
In the Consent Agreement, MSD increased the concentration limits for CN and for Cr for
I
the period of the agreement. Asheville Metal Finishing, Inc. agreed to remove hexavalent
chromium from the premises and to thoroughly clean the drain channels from the CN and
I
Page 1
I

I
I
I Hexavalent Chromium areas. In addition, the large pits in the pretreatment area would
also be cleaned. This was to eliminate all remaining residues of CN and Hexavalent Cr.
from the facility. Each step had a corresponding due date.
IThe Consent Agreement was issued on March 19, 2014 and was effective until June 30,
2014.
IOn May 28, 2014, Asheville Metal Finishing, Inc. requested an extension for completion
date to have the pits cleaned. They were having delays with the company contracted to
Ido the cleaning.
On May 29, 2014, Asheville Metal Finishing, Inc. was issued an amended Consent
Agreement that extended the completion of the project to July 31, 2014. (The Consent
IAgreement_Amended is enclosed in this report.)
On July 15, 2014, MSD issued a Notice of Violation and Civil Penalty due to a CN limit
I violation that exceeded the raised interim limit in the Consent Agreement. (The Civil
Penalty for Violation of Consent Agreement is enclosed in this report.)
I The conditions of the Consent Agreement have been completed and Asheville Metal
Finishing, Inc.has not experienced another effluent cyanide violation.
Asheville Paint and Powder (S-005-12)
On May 20th, MSD issued a Technical Notice of Violation to Asheville Paint and
I Powder. It was based on visual observation of the wastewater level in the holding tanks.
During an unannounced visit on August 12, 2013, a note in the report stated,"Both large
tanks were nearly full." During the annual inspection visit on April 30, 2014,a note in
I the report stated, "At the time of the inspection, the right tank was about half full and the
left tank was less than half full." Each tank holds a 2,500 gallon capacity. The last
recorded discharge was March 8, 2013.
IMSD required Asheville Paint and Powder to discharge before the end of 2014. Test
results reported Chromium and Zinc limit violations. The owner discharged batch
process wastewater every two weeks for the remainder of the year. MSD observed each
Idischarge release and their sampling procedures. The analytical sample results were all
compliant.
IThe owner informed MSD that he will initiate a policy procedure to discharge quarterly
to avoid future violations.
III
Baldor Electric Company(S-070-12)
In June of 2012, Baldor Electric Company discontinued discharging the Part 471
I categorical wastewater at Monitoring Point 01. This wastewater is hauled off site for
proper disposal.
I
Page 2
I

I
1
The pretreatment system was cleaned but the connection to the sewer remains intact. As I per requested by Baldor Electric Company, the effluent limits and monitoring
requirements for Monitoring Point 01 remain active in case the company decides to
restart the pretreatment system and discharge to MSD.
I
October 6, 2014, Baldor Electric Company notified MSD that the expansion of the Lead
Babbitt room will begin soon. The Lead Babbitt operation is confined and there is no
discharge to the sewer system from this area. I
The expansion will consist of a locker/restroom and a shower room. The washer and
drier, with which men working in Lead Babbitt room wash their clothes, are currently on I
the mezzanine and will be relocated to the new locker/restroom.
Baldor Electric Company informed MSD of the washer and dryer on April 15, 2013. In I
that year, MSD tested total plant discharge for the time period while the washer was used
but did not detect lead in the analysis.
I
BorgWarner Thermal Systems(S-030-12)
In a letter dated June 10,2014, MSD was notified that Mr.Todd Bennington replaced
I
Mr. Steve Racher as the Plant Manager,who is the primary Authorized Representative
for BorgWarner Thermal Systems.
I
Craggy Prison Laundry (S-066-12)
In a letter dated February 10, 2014, MSD was informed that Mr. Michael Greene I replaced Mr. Randall Cole as Corrections Enterprise Manager III, who is the primary
Authorized Representative for Craggy Prison Laundry.
On October 1, 2014, MSD received notification that due to being short-staffed,they did I
not collect the Self-Monitoring sample for the month of September as required by their
permit. On October 29, 2014, MSD issued Craggy Prison Laundry a Technical Notice of
I
Violation for failure to obtain a required sample. The reported corrective action was to
be fully staffed.
Day International,Inc.(S-057-12)
On August 15,2014,MSD sampled for Acetone at Monitoring Point(MP)#01. This is
not a parameter required by the permit. A detectable concentration was found. Since
I
then, Day International, Inc. has been testing for Acetone at MP#01 and have been
investigating how it could possibly get into the sewer system. There is only one area of
the plant that uses acetone and there is no connection to the sewer. They are now looking I
at the option of replacing acetone with a different chemical.
I
1
Page 3
I

t
Duke Energy (not yet permitted)
On October 29, 2014 Duke Energy Progress—Asheville Plant submitted a request for
MSD to consider acceptance of their pretreated scrubber blowdown wastewater into the
MSD sewer system.
MSD reviewed sampling data from the pretreatment system and conducted a follow-up
inspection. In addition, MSD retained the services of an engineering group,McGill
Associates,to review the information and comment on potential impacts to MSD sewer
system.
On December 31,2014, MSD submitted a letter of approval to Duke Energy Progress—
Asheville Plant's request and required Duke Energy Progress—Asheville Plant to
complete and submit an Application for Permit.
Jacob Holm Industries(America),Inc.(S-067-12)
On June 19, 2014, MSD reviewed plans for the Water Filtration System (Recovery Loop)
and the new pretreatment system.
A letter for Authorization to Construct was issued on August 5, 2014. (AtoC letter is
11 enclosed in this report.)
Mission Hospital Laundry (S-068-12)
From a TSS Self-Monitoring violation reported to MSD on July 21, 2014, Mission
Hospital Laundry reported that the violation was probably due to"sludge or particulate
floatation" in the acquired sample.
' In a follow-up conversation on July 22, 2014, MSD could not accept that explanation.
On July 28, 2014,MSD received an email from Mission Hospital Laundry expressing a
suspicion that the lab,which they contract out to do their sampling,had been sampling at
the older original monitoring point. With the issuance of the 2012 permit,the monitoring
point had been changed because of the installation of a new pretreatment system.
Mission Hospital Laundry's suspicion was verified and, beginning with the Self-
Monitoring in August,the contracted lab has begun sampling at the appropriate
monitoring point location.
New Belgium Brewery(not yet permitted)
New Belgium Brewery is currently still in the construction phase. However, in a letter
dated, January 8, 2014, MSD did issue them an Authorization to Construct letter for their
lift station and Equalization(EQ)Tank. (The AtoC_EQ letter is enclosed in this report.)
The lift station and EQ tank will be part of their pretreatment system during the first year
of operation.
r
i
Page 4

I
1
In a letter dated, September 17, 2014, MSD issued New Belgium Brewery an '
Authorization to Construct letter for the Monitoring Site. (the AtoC_MonitoringManhole
letter is enclosed in this report.)
Sierra Nevada Brewing Company (S-073-13) 1
During the early part of the year, Sierra Nevada Brewing Company was doing test
batches of beer. All process wastewater was sent through the pretreatment system.
It was not until February that regular full production began and the baseline monitoring I
was initiated. This was followed by the 90 Day Compliance Schedule which ran from
March to May. I
Sierra Nevada Brewing Company's pretreatment system has exceeded expectations and
on November 14, 2014, agreed to have their permit amended where the BOD and TSS
I
limits would become more stringent.
I
I
I
I
I
I
I
I
I
I
1
Page 5

- — — —
I . CONSENT AGREEMENT
IWITH
THE METROPOLITAN SEWERAGE DISTRICT
I OF
BUNCOMBE COUNTY,NORTH CAROLINA
tQOJtpN SRVE44, ��
Il
. y-04.,.,',�_i ' ,,t,
p mi.,_+
I THIS CONSENT AGREEMENT, entered into this 19`11 day of March 2014, by and between the
Metropolitan Sewerage District of Buncombe County (MSD) and Asheville Metal Finishing, Inc. in
Asheville,North Carolina.
IWHEREAS, MSD is a Publicly Owned Treatment Work responsible for the implementation and
administration of the Pretreatment Program for Industrial Waste mandated by the Clean Water Act;
I WHEREAS,MSD regulates the discharge of wastewater into the sewerage system through the issuance
of Permits to Discharge Industrial Waste and the MSD Sewer Use Ordinance(SUO);
1 WHEREAS,the MSD issued a Permit to Discharge Industrial Waste("the Permit")numbered S-003-12
to Asheville Metal Finishing,Inc.on January 1,2012(herein after referred to as the"Permit");
WHEREAS, the Permit establishes, inter alia, effluent limitations for the wastewater discharged by
IAsheville Metal Finishing, Inc. and requires certain self-monitoring and reporting requirements of
Asheville Metal Finishing,Inc.;
IWHEREAS,Asheville Metal Finishing,Inc.exceeded effluent limits on the following dates:
Date Analytical Result Parameter Monitoring Monitoring
I (me-) Point
11/20/13 1.4 Cyanide Self-Monitoring #01
1/24114 1.1 Cyanide Self-Monitoring . #01
2/7/14 1.7 Cyanide Self-Monitoring #01
WHEREAS,MSD issued Notices of Violation(NOVs)for the above violations on the following dates:
I Date of Violation Monitoring NOV
Issued
11/20/13 Self-Monitoring 12/31/13
I 1/24/14 Self-Monitoring 2/25/14
WHEREAS,Asheville Metal Finishing,Inc. met with MSD Industrial Waste Staff on February 25,2014,
regarding the violations:
WHEREAS, MSD issued a Notice of Violation (NOV) along with a Civil Penalty of$100.00 for the
Cyanide violation on February 27,2014:
I1

WHEREAS,Asheville Metal Finishing, Inc. anticipates potential increased effluent concentration levels
for Chromium during the transition period of removing the hexavalent chromium bath and replacing it
with a trivalent chromium bath. During the transition,the hexavalent chromium will be properly disposed
of and the bath tank,area,and associated drain channels will be washed down during the cleanup process:
WHEREAS,Asheville Metal Finishing,Inc.had undertaken the following actions in response to the first
Cyanide violation:
1. Checked for leaks from the Silver line to the Cyanide evaporator.
a. No leaks were detected.
2. Removed the Copper/Cyanide plating baths and corresponding rinses.
a. These tanks and the area where the tanks had been located were cleaned.
WHEREAS,Asheville Metal Finishing,Inc.has resolved to take the following additional actions:
1. Asheville Metal Finishing, Inc. has consented to thoroughly wash the channels connecting the
former Copper/Cyanide plating area to the pits in the pretreatment area.
2. Asheville Metal Finishing, Inc. has consented to pump out and haul off or evaporate the contents
of the hexavalent chromium tank. The tank, area, and the channels connecting the former
hexavalent chromium tank area to the pits in the pretreatment area will be thoroughly cleaned.
3. Asheville•Metal Finishing, Inc.has consented to pump out and haul off or evaporate the contents
of the pits in the pretreatment area in which Cyanide contaminated residue might have built up
over the years. The above mentioned pits will also be thoroughly washed to remove any
lingering Cyanide and Chromium.
IT IS NOW THEREFORE AGREED AS FOLLOWS:
Asheville Metal Finishing, Inc. will be in compliance with all requirements of the Permit and the MSD
Sewer Use Ordinance no later.than June 30,2014.
Asheville Metal Finishing,Inc.must meet the following due dates*:
1. On or before April 18, 2014, the contents of the hexavalent chromium tank will have been
pumped out and hauled off or evaporated.
2. On or before May 30,2014, the hexavalent chromium tank and area, along with the associated
drain channels connecting the former hexavalent chromium areato the pretreatment system will
have been properly and thoroughly cleaned.
•
3. On or before May 30, 2014, the drain channels connecting the former Copper/Cyanide plating
area with the pits in the pretreatment area will have been properly and thoroughly cleaned. In
addition,the contents of the pits in the pretreatment area in which Cyanide contaminated residue
might still be present will have been pumped out and hauled off or evaporated and,these same pits
will have been properly and thoroughly cleaned.
*Dates can be amended if unforeseen, legitimate problems arise.
2

From March 18, 2014 through June 30, 2014, Asheville Metal.Finishing, Inc. will comply with all
conditions of the Permit and Sewer Use Ordinance except for the interimeffluent concentration limits for
Cyanide and Chromium,which are to be modified as set forth below:
Parameter Daily Maximum(mg/L)
Cyanide 1:90
Chromium 3.00
The monitoring for Cyanide and Chromium shall be performed during each discharge batch event from
Monitoring Point # 01 as designated in the Permit. The reported analyses are to be performed by a
wastewater laboratory certified by the State on North Carolina. Copies of results and chain of custody
. must be attached with the monthly self-monitoring report.
If Asheville Metal Finishing, Inc. exceeds the interim effluent limit during the period of this Consent
Agreement, (both self-monitoring and MSD monitoring) or if Asheville Metal Finishing, Inc. fails to
conduct self-monitoring or report the results of self-monitoring, or if Asheville Metal Finishing,Inc.fails
to meet the milestone dates,the Metropolitan Sewerage District of.Buncombe County will impose a fine •
of$250.00 for each violation.
If Asheville Metal Finishing, Inc. cannot demonstrate compliance with the Permit and the Sewer Use
Ordinance by June 30, 2014,Asheville Metal Finishing, Inc. may be subject to additional civil penalties
in addition to penalties which may be assessed under this Consent Agreement.
This Consent Agreement is entered into on this 19th day of March,2014 by:
METROPOLITAN SEWERAGE DISTRICT OF
BUNCOMBE COUNTY,NORTH CAROLINA.
I
BY: 7.•
omas E.Hartye
• General Manager
•
ASHEVILLE'METAL FINISHING,INC.
BY: �" "zGf °J'r
•
Todd Israel
Plant Manager
I
1
1 3
1

issoN, SEWERgCe
Metropolitan:Sewerage District
= OF BUNCOMBE COUNTY, NORTH CAROLINA
Cot,Nr Y,NOPE
May 29,2014 I
Mr. Thomas L. Finger, Owner
Mr. Tom Israel, Manager
Mr. Todd Israel, Plant Manager
Asheville Metal Finishing,Inc. 1111
178 Clingman Avenue.
Asheville,North Carolina 28801
Re: Amended Consent Agreement
Dear Gentlemen:
Pursuant to your request for an extension on the Consent Agreement entered into
on March 19, 2014, the Metropolitan Sewerage District of Buncombe County (MSD) has
agreed to modify the due dates for the cleaning of the drain channels and the pumping of
the pits from on or before May 30, 2014 to on or before June 30,2014 and to demonstrate
Permit monitoring compliance by July 31,2014.
It is imperative that Asheville Metal Finishing, Inc. make every effort to comply I
with the conditions of this amended Consent Agreement. MSD deems the extension
date's as ample time for Asheville Metal Finishing, Inc. to complete the agreed upon goals
as outlined in the Consent Agreement. - -
Please note that all modifications made on the Amended Consent Agreement have
been highlighted in yellow.
Sincerely,
o 7. Hartye,P.E.
/ .eneral Manager
/Protecting Our Natural Resources-
2028 RIVERSIDE DRIVE, ASHEVILLE,NORTH CAROLINA 28804 TELEPHONE:[phone] FAX:[phone] WEBSITE:www.msdbc.org

I
I CONSENT AGREEMENT
IWITH
I THE METROPOLITAN SEWERAGE DISTRICT
OF
BUNCOMBE COUNTY,NORTH CAROLINA
Q,40.1%SEWEg40,4,
i .
9
I cy
v
I THIS CONSENT AGREEMENT, entered on the 19"' day of March 2014, by and between the
Metropolitan Sewerage District of Buncombe County (MSD) and Asheville Metal Finishing, Inc. in
Asheville,North Carolina is,as of this 29"'day of Mav 2014 being amended.
IWHEREAS, MSD is a Publicly Owned Treatment Work responsible for the implementation and
administration of the Pretreatment Program for Industrial Waste mandated by the Clean Water Act;
I WHEREAS, MSD regulates the discharge of wastewater into the sewerage system through the issuance
of Permits to Discharge Industrial Waste and the MSD Sewer Use Ordinance(SUO);
1 WHEREAS,the MSD issued a Permit to Discharge Industrial Waste("the Permit")numbered S-003-12
to Asheville Metal Finishing,Inc.on January 1,2012(herein after referred to as the"Permit");
I WHEREAS, the Permit establishes, inter alia, effluent limitations for the wastewater discharged by
Asheville Metal Finishing, Inc. and requires certain self-monitoring and reporting requirements of
Asheville Metal Finishing,Inc.;
IWHEREAS,Asheville Metal Finishing,Inc.exceeded effluent limits on the following dates:
' Date Analytical Result Parameter Monitoring Monitoring
I (mg/L) Point
11/20/13 1.4 Cyanide Self-Monitoring #01
1/24/14 1.1 Cyanide Self-Monitoring #01
I2/7/14 1.7 Cyanide Self-Monitoring #01
WHEREAS,MSD issued Notices of Violation(NOVs)for the above violations on the following dates:
I Date of Violation Monitoring NOV
Issued
11/20/13 Self-Monitoring 12/31/13
I 1/24/14 Self-Monitoring 2/25/14
WHEREAS,Asheville Metal Finishing, Inc.met with MSD Industrial Waste Staff on February 25,2014,
regarding the violations:
IWHEREAS, MSD issued a Notice of Violation (NOV) along with a Civil Penalty of$100.00 for the
Cyanide violation on February 27,2014:
I1
I
um

WHEREAS,Asheville Metal Finishing, Inc. anticipates potential increased effluent concentration levels
for Chromium during the transition period of removing the hexavalent chromium bath and replacing it
with a trivalent chromium bath. During the transition,the hexavalent chromium will be properly disposed
of and the bath tank, area,and associated drain channels will be washed down during the cleanup process:
WHEREAS,Asheville Metal Finishing, Inc. had undertaken the following actions in response to the first
Cyanide violation:
1. Checked for leaks from the Silver line to the Cyanide evaporator.
a. No leaks were detected.
2. Removed the Copper/Cyanide plating baths and corresponding rinses.
a. These tanks and the area where the tanks had been located were cleaned.
WHEREAS,Asheville Metal Finishing,Inc. has resolved to take the following additional actions:
1. Asheville Metal Finishing, Inc. has consented to thoroughly wash the channels connecting the
former Copper/Cyanide plating area to the pits in the pretreatment area.
2. Asheville Metal Finishing, Inc. has consented to pump out and haul off or evaporate the contents
of the hexavalent chromium tank. The tank, area, and the channels connecting the former
hexavalent chromium tank area to the pits in the pretreatment area will be thoroughly cleaned.
3. Asheville Metal Finishing, Inc. has consented to pump out and haul off or evaporate the contents
of the pits in the pretreatment area in which Cyanide contaminated residue might have built up
over the years. The above mentioned pits will also be thoroughly washed to remove any
lingering Cyanide and Chromium.
IT IS NOW THEREFORE AGREED AS FOLLOWS:
Asheville Metal Finishing, Inc. will be in compliance with all requirements of the Permit and the MSD
Sewer Use Ordinance no later than June 30,2014.
Asheville Metal Finishing,Inc.has met the following due dates:
1. On or before April 18, 2014, the contents of the hexavalent chromium tank will have been
pumped out and hauled off or evaporated.
Asheville Metal Finishing,Inc.must meet the following amended due dates*:
1. On or before June 30, 2014, the hexavalent chromium tank and area, along with the associated
drain channels connecting the former hexavalent chromium area to the pretreatment system will
have been properly and thoroughly cleaned.
2. On or before June 30, 2014, the drain channels connecting the former Copper/Cyanide plating
area with the pits in the pretreatment area will have been properly and thoroughly cleaned. In
addition,the contents of the pits in the pretreatment area in which Cyanide contaminated residue
might still be present will have been pumped out and hauled off or evaporated and these same pits
will have been properly and thoroughly cleaned.
*Dates can be amended if unforeseen, legitimate problems arise.
2

From March 18, 2014 through June 30, 2014, Asheville Metal Finishing, Inc. will comply with all
conditions of the Permit and Sewer Use Ordinance except for the interim effluent concentration limits for
Cyanide and Chromium,which are to be modified as set forth below:
Parameter Daily Maximum(mg/L)
Cyanide 1.90
Chromium 3.00
The monitoring for Cyanide and Chromium shall be performed during each discharge batch event from
Monitoring Point # 01 as designated in the Permit. The reported analyses are to be performed by a
wastewater laboratory certified by the State on North Carolina. Copies of results and chain of custody
must be attached with the monthly self-monitoring report.
If Asheville Metal Finishing, Inc. exceeds the interim effluent limit during the period of this Consent
Agreement, (both self-monitoring and MSD monitoring) or if Asheville Metal Finishing, Inc. fails to
conduct self-monitoring or report the results of self-monitoring, or if Asheville Metal Finishing, Inc. fails
to meet the milestone dates, the Metropolitan Sewerage District of Buncombe County will impose a fine
of$250.00 for each violation.
If Asheville Metal Finishing, Inc. cannot demonstrate compliance with the Permit and the Sewer Use
Ordinance by July 31,2014,Asheville Metal Finishing,Inc.may be subject to additional civil penalties in
addition to penalties which may be assessed under this Consent Agreement.
rThis amended Consent Agreement is entered into on this 29th day of May,2014 by:
111
METROPOLITAN SEWERAGE DISTRICT OF
BUNC I r E COUNTY,NORTH CAROLINA
BY: 1--1411,'M`
Thomas E.Hartye
General Manager
I
ASHEVILLE METAL FINISHING,INC.
BY: a4 931 4'43
Todd Israel
Plant Manager
1
I
1 3

`SAN 11
SE"ER9c
, -A Metropolitan Sewerage District
• �"t�t� OF BUNCOMBE COUNTY, NORTH CAROLINA
%4B �fp �.-a G!
Cat,rI r Y,r40
February 27,2014
Mr.Torn Finger,President
Mr.Tom Israel,General Manager
Mr.Todd Israel,Plant Manger
Asheville Metal Finishing,Inc.
Post Office Box 16237
Asheville,North Carolina 28816
Subject:NOV and Civil Penalty
Dear Gentlemen:
In a meeting on February 25,2014 with Asheville Metal Finishing, Inc.to discuss two recent Cyanide(CN)
violations,the Metropolitan Sewerage District of Buncombe County(MSD)was informed that there was another CN
violation from a Self-Monitoring effluent sampling event on February 7,2014. The reported result was 1.7 mg/I of
which it was not to exceed 1.0 mg/1 according to the Pennit Effluent Limitation for Cyanide.
This correspondence recognizes and constitutes an official Notice of Violation for this sampling event.
In that this was the third CN violation in the past four months,MSD is required to follow the administrative
penalty protocols as outlined in Sections V.A.1. and VI.A. of MSD's Enforcement Response Plan. Once a specific
parameter exceeds the pennitted effluent limit on three occasions within a one hundred and eighty(180)day period,
the violation results in a Tier 3 penalty. This includes; issuing a Notice of Violation(as noted above), assessing a
civil penalty fee from$100.00 to$500.00,and entering into a Consent Agreement.
During our meeting on February 25, 2014, MSD was informed that, after the second CN violation, efforts
had been taken by Asheville Metal Finishing to eliminate the source of the Cyanide. This consisted of removing the
Copper/Cyanide tanks and their rinse tanks and washing down that area.
While discussing possible causes of this last CN violation, Asheville Metal Finishing, Inc. realized that
there are additional actions that can be taken to further remove the potential for future CN violations from occurring.
This will include washing down the drain channels leading to pretreatment and pumping out and washing down the
pits that the channels drain into.
In that Asheville Metal Finishing,Inc.is actively involved in an effort to resolve this non-compliance status,
the Metropolitan Sewerage District of Buncombe County will impose the minimal civil penalty of $100.00.
Enclosed is an invoice addressing this fee. Please remit payment of this penalty to MSD by no later than March 28,
2014. The mailing address is as follows:
Metropolitan Sewerage District of Buncombe County
Attention:Accounts Receivable
2028 Riverside Drive
Asheville,North Carolina 28804
-Protecting Our Natural Resources-
2028 RIVERSIDE DRIVE, ASHEVILLE,NORTH CAROLINA 28804 TELEPHONE:[phone] FAX:[phone] WEBSITE:www.msdbc.org

1
I
February 27,2014
Page 2
With regard to the Consent Agreement,MSD is waiting for Asheville Metal Finishing,Inc. to address the
components needed to draw up the agreement.
If you have any questions,please contact Jon H.van Hoff at 225-8230 or this office.
' Sincerely;
1 dac
Thomas . ,P.E.
q-ne al Manager
1
•
1
1
1
I
i
1
i .
1 .
i
1

1
QO�,�PN SEwERA�,cc
Metropolitan Sewerage District of Buncombe County
2028 Riverside Drive
W. H. Mull Building
• Asheville, North Carolina 28804
00, a4;,d i+ � Phone: [phone] Invoice Number: SPINV043040
s`CD Irl ry tt°c<<j�G Fax: [phone]
immilimmsimmi Invoice
Invoice Date: 02/27/14
Asheville Metal Finishing Inc Acct. No: 6
Post Office Box 16237 178 Clingman Avenue Please include the
Asheville, NC 28816 account number on
your check.
Month: Invoice SINV001533
Item/Description Quantity Unit Price Total Price
Cyanide Effluent Violation 3rd occurence 1 100.00 100.00
Subtotal: 100.00
(Payments) Past Due: - 27.62
Finance Charges: , ;; ,� 0.00
Credits: • 0.00
Payment must be received in our office by the due date or interest Total Due: 727.62
charges will be assessed at a rate of 1.5%against the unpaid balance. Due Date: 03/24/14

I
` AN SEIY!R���
p
ct. °'cr Metropolitan Sewerage District
i ♦� OF BUNCOMBE COUNTY, NORTH CAROLINA
04BE •Iu, ♦..." 4�
II cooNTY. July 15,2014
Mr.Tom Finger,President
I Mr.Torn Israel,General Manager
Mr.Todd Israel,Plant Manger
Asheville Metal Finishing,Inc.
Post Office Box 16237
IAsheville,North Carolina 28816
Subject:NOV and Civil Penalty
IDear Gentlemen:
I On July 15,2014,Asheville Metal Finishing submitted a 24 Hour Notification of Effluent Violation Report
to the Metropolitan Sewerage District of Buncombe County (MSD), followed up with a phone call. The effluent
violation was for Cyanide(CN)which occurred on June 18,2014.
I According to Asheville Metal Finishing, it was determined that the violation was the result of pumping the
wastewater from pits 3 and 4 into pit 1, where the wastewater was treated. It was the intent of Asheville Metal
Finishing to treat as much wastewater as possible to reduce the amount of liquid and sludge to be pump and hauled
off site from the pits. Asheville Metal Finishing felt confident that after having used their ORP meter, the Cyanide
1 level would be below the raised interim effluent concentration limit allotted in the Consent Agreement,under which
Asheville Metal Finishing is currently subject.
MSD is aware that Asheville Metal Finishing has made sound efforts to comply with each condition of the
I
Consent Agreement and commends you for those efforts.
However the Metropolitan Sewerage District of Buncombe County (MSD) is required to follow the
I administrative penalty protocols according to the Consent Agreement with regard to the CN effluent violation on
June 18,2014.
This correspondence recognizes and constitutes an official Notice of Violation for this sampling event.
IIn addition, the Metropolitan Sewerage District of Buncombe County is required to impose a civil penalty
of$250.00 as per the Consent Agreement. Enclosed is an invoice addressing this fee. Please remit payment of this
I penalty to MSD by no later than August 15,2014. The mailing address is as follows:
Metropolitan Sewerage District of Buncombe County
Attention:Accounts Receivable
I 2028 Riverside Drive
Asheville,North Carolina 28804
If you have any questions,please contact Jon H.van Hoff at 225-8230 or this office.
ISincerely,
IF
GAJ
Thomas E. ,P i
Gen: . , anas-r
-Protecting Our Natural Resources-
2028 RIVERSIDE DRIVE, ASHEVILLE,NORTH CAROLINA 28804 TELEPHONE:[phone] FAX:[phone] WEBSITE:www.msdbc.org
t

QQo\SAN SEW/a`gtK,'O, Metropolitan Sewerage District of Buncombe County
14 13 2028 Riverside Drive
-- I W. H. Mull Building
• - Asheville, North Carolina 28804
`'o 0,h, ,„�n� Q�' Phone: [phone] Invoice Number: SPINV045029
�Sa C�UfIT Y,t1^v��~4l Fax: [phone]
11 Invoice
Invoice Date: 07/15/14
Asheville Metal Finishing Inc Acct.No: 6
Post Office Box 16237 178 Clingman Avenue
Asheville, NC 28816 Please include the
account number on
your check.
CIVIL PENALTY 071514
Item/Description Quantity Unit Price Total Price
CYANIDE EFFLUENT VIOLATION 1 250.00 250.00
Current Rates Subtotal: 250.00
Industrial: (Payments) Past Due: 0.00
Flow($/ccf): 3.439 Finance Charges: 0.00
BOD($/#)>220 .334 Payment must be received in our Credits: 0.00
TSS($/#)>220 .264 office by the due date or interest
Domestic: charges will be assessed at a rate Total Due: $ 250.00
Flow($/ccf): 4.18 of 1.5%against the unpaid
balance. Due Date: 08/09/14
a

I
I i c?q.c- AN SEWER",
. Metropolitan Sewerage District
'. :. OF BUNCOMBE COUNTY, NORTH CAROLINA
I 4'0+4-',iie,44°'- 04'
'
'.UNT V.SOC''''
August 5, 2014
I Mr. Jeff Sellers, Supply Chain& Operations Vice President America
Mr. Sammy Johnson, Quality Re-Engineering Manager
Jacob Holm Industries(America), Inc.
I 1265 Sand Hill Road
Candler,North Carolina 28715
Subject: Authorization to Construct Pretreatment System
I
Dear Gentlemen:
I The Metropolitan Sewerage District of Buncombe County (MSD) has reviewed the
information provided by Jacob Holm Industries with regard to the construction of the proposed
Main Water Filtration Loop and Retreatment Water Filtration Loop.
IFrom the schematics provided and the conversations regarding particular concerns •
expressed by MSD, Jacob Holm Industries has agreed to the following conditions and
Imodifications from the original design: .
1. In preparation for the cleaning cycles for the Main Water Filtration Loop and the
I
Retreatment Water Filtration Loop, Jacob Holm Industries will pump or gravity feed
as much of the process wastewater as feasibly possible from the tanks and the process
systems (such as the DAFs, Filter Gravity Strainer, etc.) through the remainder of the
treatment systems before discharging to Monitoring Point 01 (MP 01). 'The only
exceptions arc the pit,RT1,and RT2,which are addressed below.
I It is the understanding of MSD that not all the process water can be removed
from the tanks and some of the process systems. MSD will allow the residual
partially treated process water to be drained to MP 01.
1 2. As mentioned above, the contents of the pit, RT1, and RT2 will be handled
differently prior to cleaning these tanks. The process water from these areas are
I untreated and should not be released directly.to the sewer system. Therefore, the
process water in the pit will be pumped to RT1 and RT2. The drain and the overflow
from RT1 and RT2 tanks will not have the capability to discharge directly to the MP
01 but will be pumped to STA2, which is the beginning of the Retreatment Water
IFiltration Loop. Directing this wastewater to STA2 should provide adequate
treatment before discharging to the MP 01.
I
Protecting Our Natural Resources—
2028 RIVERSIDE DRIVE, ASHEVILLE,NORTH CAROLINA 28804 TELEPHONE:[phone] FAX:[phone] WEBSITE:www.msdbc.org

•
August 5,2014
Page.2 111
t
3. There is a sewer drain connection immediately following the pit, which receives the
recovered water from the Jetlace machine. The valve for this sewer drain will remain
closed when pumping the recovered water out of the pit. It can be opened to release
the wash down water,which is used to clean the pit.
4. MSD is aware that Jacob Holm Industries has the capability to by-pass three I
treatment sections of the Main Water Filtration Loop. These three sections are:
a. The DAF unit(FL 1)
b. The Sectioned filter unit(FLKLC)•
c. The Sand filters
In accordance to Part III, Section E of your permit, by-passes are permissible '
. provided conditions listed in that section are satisfied. MSD was informed
that each of the by-pass controls will be password protected and that only .
selected• individuals at Jacob Holm Industries will have the authority to
initiate such by-passes.
•
Upon the agreed conditions and modifications mentioned above and in accordance to Part
III, Section BB of your permit,this letter is issued as official Authorization to Construct and
operate the proposed Main Water Filtration Loop and the Retreatment Water Filtration Loop.
Please note that MSD's approval of the pretreatment systems is not a guarantee that the
process wastewater discharged to MP 01 will meet the Effluent Limit requirements as
established in Part II,Section B of your permit. Should Jacob Holm Industries exceed the permit
effluent limits,it may be necessary to modify or add addition treatment.
A copy of the authorized plans and specifications shall be•maintained on file at Jacob Holm
Industries(America),Inc.for the life of the systems.
If you have any questions or comments regarding the inspection, please contact me at
[phone].
Sincerely,
,GG• 4,-PA
Jon H.van Hoff •
Industrial Pretreatment Coordinator

o
Metropolitan Sewerage District
.. 'V OF BUNCOMBE COUNTY, NORTH CAROLINA •
F OOUNT Y.NOPta�
January 8,2014
Mr.Mark Fischer, Senior Plant Engineer
' New Belgium Brewery
500 Linden Street •
Fort Collins,CO 80524
Subject: Authorization to Construct •
Dear gentlemen: •
In accordance to Section 6.2 of the Metropolitan Sewerage District of Buncombe County, NC
(MSD) Sewer Use Ordinance, the industrial user is required to submit detailed plans of the pretreatment
' facilities and operating procedures and receive approval from MSD before construction of the facility
begins.
MSD has carefully reviewed the information provided during our conference call on January 6,
2014, along with an email received prior to the call. The topic was the proposed design and construction
of the lift station and the Equalization(EQ)Tank for the process wastewater. Below is a summary of that
information.
It is the understanding of MSD that the process wastewater will pass through a centrifuge to
remove yeast and hops prior to discharging to the lift station. From the lift station,the wastewater will be
' pumped to a 120,000 gallon EQ tank to allow for pH neutralization and any additional retention of
settable and floatable solids. This is considered Phase 1 of a two phase pretreatment construction.
Both the lift station and the EQ tank have overflow bypass capabilities,whereby if the pumps to
either system were to fail, the wastewater would bypass directly to the Monitoring Manhole (parshall
flume) and into the MSD sewer system. MSD was informed, during the conference call, that the
following conditions will be set in place and adhere to:
• There are two pumps for the lift station and two pumps for the EQ tank. New Belgium Brewery
will retain a replacement pump in stock for each system.
• Should both pumps for the lift station or the EQ tank fail, a high level alarm will be triggered,
alerting personnel prior to an actual bypass occurring.
' • At the onset of a bypass,manufacturing operations will be shut down until the bypass has ceased.
• The SCADA system will mark when the alarm has been triggered and when the alarm ceases, so
that the volume of wastewater and the time duration of the bypass can be measured.
• Should both pumps fail in the lift station, a temporary sump pump can be lowered into the wet
well to pump the contents to the EQ tank,until a replacement pump and be installed.
•
-Protecting Our Natural Resources-
•
2028 RIVERSIDE DRIVE, ASHEVILLE,NORTH CAROLINA 28804 TELEPHONE:[phone] FAX:[phone] WEBSITE:www.msdbc.org

— _ - I
, I
•
January 8,2014
Page 2 I
•
The Metropolitan Sewerage District of Buncombe County will-approve of the bypass structures
and the accompanying protocol. However,please be advised that approval of the system shall in no way
' relieve the user from the responsibility of modifying the pretreatment facility as necessary to produce an • .
effluent compliant with the conditions of the Sewer Use Ordinance and the permit that will be issued to
- this facility. .
With regard to the construction of the Equalization Tank, which constitutes the pretreatment .
system for Phase 1,this letter is issued as an official Authorization to Construct for the system as follows:
• ' The EQ tank will be of the capacity of 120,000 gallons. '
. • Piping for aeration within the tank will be installed but not used during Phase I. •
• The pumps pulling the wastewater out of the EQ tank will draw from a level of two (2) feet or '
higher from the bottom of the tank. This is to allow any settled'solids to "remain in the tank, .
• which will be periodically pumped out and properly disposed.
• There will be pH meters in the effluent piping of the EQ tank. If the pH exceeds the 6.5 to 10.0
range or if there is a differentiation of morn.than 0.2 pH standard units between the two pH
• meters,the discharge valves will be closed after a 15 minute delay and the system will be placed •
into a recirculation mode. Once the pH wastewater in the EQ tank returns to compliance, the
discharge valves will be opened after a 15 minute delay.
• All discharge from the EQ tank will be directed to the Metering•Manhole, of which MSD has
. previously issued ad Authorization to Construct letter submitted on September 17,2013.
Please note that a copy of.the approved plans and specifications shall be maintained on file at
New Belgium Brewery's facility in Asheville,North Carolina for the life of the system.
•
During the conference call,MSD was informed of the proposed timeline for the construction and
installation of the lift station and the Equalization Tank. Please advise this office of any changes to that '
timeline. .
Thank you for your cooperation and assistance. If you have any questions or comments
• concerning this letter,please contact me at(828)225-8225.
Sincerely - I
/if 1
• Jon,,H.van Hoff I
' Industrial Waste Coordinator
i
cc: Mr.Scott Lyon,Construction Manager/Project Supervisor .
I)
• 1
I

•SAN SEIVERgC,
4A, ` ' Metropolitan Sewerage District
L. r- OF BUNCOMBE COUNTY, NORTH CAROLINA
y �r
4'
°own.Y.MOPS
September 17,2013
' Mr.Mark Fischer,Senior Plant Engineer
Mr.Tim Rynders with CDM Smith
New Belgium
500 Linden Street
Fort Collins,CO 80524
Subject: Authorization to Construct Monitoring Site
I
Dear gentlemen:
The Metropolitan Sewerage District of Buncombe County,NC(MSD)has carefully reviewed the
information provided during our conference call on September 11,2013 along with a follow-up email on
September 13, 2013, regarding the proposed construction of the Metering Manhole and the Monitoring
' Enclosure. Below is a summary of that information.
• The Metering Manhole will only receive process wastewater. No domestic wastewater will
merge into the sewer lines upstream of this manhole.
• The Metering Manhole will not be placed in a high traffic area nor are there future expansion
plans to build over the manhole. Therefore, there will always be easy access to the manhole by
' New Belgium and by MSD.
• The Metering Manhole will consist of a Parshall Flume with a pH meter probe and an Ultrasonic
Flow Meter to respectively measure the pH and flow of the process wastewater discharge.
' • There shall be easy access to calibrate both meters.
• The pH meter will record a continuous log,which can be reviewed as needed.
• The flow meter will convey totalized readings.
• The piping connecting from the Monitoring Enclosure to the Metering Manhole will not have a
1 90° elbow but will consist of a "long sweeping elbow" to allow sampler tubing to be easily
changed out as needed.
Having approved these conditions and the schematics submitted to MSD, this letter is issued as
official Authorizes to Construct the proposed installation of the Metering Manhole and the Monitoring
Enclosure.
' Please note that a copy of the authorization plans and specifications shall be maintained on file at
New Belgium's facility for the life of the system.
The Metropolitan Sewerage District is requesting that this office be notified,when known,of the
timeline for the construction and startup of the Metering Manhole and the Monitoring Enclosure.
•1 .
-Protecting Our Natural Resources-
' 2028 RIVERSIDE DRIVE, ASHEVILLE,NORTH CAROLINA 28804 TELEPHONE:[phone] FAX:[phone] WEBSITE:www.msdbc.org

1
September 17,2013 ( ,
Page 2
With regard to the lift station,New Belgium and MSD have agreed to consider the use of the wet
well as a potential Equalization Tank should New Belgium be unable to comply with the limits or the
conditions of the Permit.
Thank you for your cooperation and assistance in this matter. If you have any questions or
comments concerning this letter,please contact me at(828)225-8225.
Sincerely,
N�
4P74.
2
•
Jon H.van Hoff I
Industrial Waste Coordinator
1
1
1
i
i
1
1
. ' 1
•
1
1

I
I
Pretreatment Program Info Database printed on: 12/8/2014
for Program Name Buncombe MSD
WWTP Name MSD Buncombe County
Stream Information IWC gra at 7Q10 11.73
I
Program Approval Date 07/01/1983 7Q10 Flow cfs/mgd 466 / 301.04
1Q10 Flow cfs/mgd 376.30 / 243.20L
Pretreatment StatusFull —
Stream Classification B
I Region ARO Basin Number FRB02
County Buncombe Receiving Stream Name FRENCH BROAD RIVER
NPDES Number NC0024911
Last PAR Rec 02/11/2014 PAR Due Date 03/01/2015 mercury
I NPDES Effective Date 04/01/2011 1631
NPDES Expire Date Current Fiscal required
P12/31/2015 Year PCI Done
POTW is Primary WWTP
TRUE Last Audit on 06/18/2014 Audit Year Next 18/19 yes
I Design Flow mgd 40.0000 %Design mgd is SIU permitted 2.72 Permitted SIU flow(mgd)(Pt_SIU) 1.088
WWTP SIU's 19 Program SIUs 19 --
WWTP CIU's 14 Program CIUs 14 HWA LTMP MS i SUO ERP
- - ---
date Inactive Date Next Due I 04/01/2019 11/01/2019 L
Date Received by DWQ r 03/25/2014] [ 08/11/2005 1 [ 12/01/2014 11/28/2011 L10/06/2004
I Date Approved 06/11/2014 [ 10/03/2005 ] I12/13/2011 05/02/2005
Adopt Date Required
Date Adopted 05/16/2012
r
Info in this Box from Pt Contacts Date Date Date
PT Pro Attended Attended Attended
Formal Name g.Prime Phone/ ext Fax HWA Wksp IUP Wksp PAR Wksp
IMr.Thomas Hartye,P.E. I 11(828)254-9646 I II I I I
[e-mail] General Manager 2028 Riverside Drive 28804
Mr.Monty Payne I 11(828)225-8225 1 1(828)232-5537 II 2/24/2009 ' 9/27/2011 ' 1/6/2005
[e-mail] Field Operations Manager 2028 Riverside Drive 28804
Mr.Jon van Hoff IPrim II(828)225-8230 1 1(828)232-5536 II 2/24/2011 I 4/7/2011 I 2/3/2011
' [e-mail] Industrial Pretreatment Coordinator 2028 Riverside Drive 28804
Mr.Peter Weed 1 11(828)225-8204 1 1(828)251-4767 II I I I
[e-mail] Director of Wastewater Treatment 2028 Riverside Drive 1128804
Pretreatment Related NOVs from DWQ ) DWQ Central Office Contact Sarah Bass
u
DWQ Regional Contact Linda Wiggs
I
IN o I-1 ts+ 1 LA-1 s N
I

Pretreatment Annual Report (PAR) Arvato Entertainment LLC Control Authority
Industrial Data Summary Form IUP#: S-034-12 Town Name: MSD Buncombe County
Pipe#: MPOI WWTP Name: French Broad WRF
1st 6 Months: January 1 to July 30,2014 NPDES#: NC0024911
2nd 6 Months: July 1 to December 31,20]4
Flow,MGD BOD TSS Cd Cr Cu
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months' 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max. Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 72 i 75 0 0 0 0 J 1 3 24 21 I 13 1 13
Maximum(mg/L): 1 0.00325 I I 0.00324 0.0005 0.0005 0.007 0.068 0.067 0.002
Maximum(Ib/d): I
6 Month Average(mg/L): I 0.0015 1 ' 0.0015 I 0.0005 0.0005 0.003 0.015 0.007 0.002
6 Month Average(lb/d):
%Violations,(Chronic SND is> 6%): 0.00% ' 0.00% N/A N/A N/A N/A 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
%TRC Violations(SNC is>=33%): 0.00% 0.00% N/A N/A N/A N/A 0.00% j 0.00% 0.00% 0.00% 0.00% 0.00%
Ni Zn Sn CN Pb Ag
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max. Daily Max ' Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 23 21 12 13 0 0 1 2 1 12 12 13
Maximum(mg/L): I 0.137 1 0.141 I 0.018 1 I 0.012 I I I I I I 0.009 I 0.006 I r 0.002 I I 0.018 I I 0.007 1 I 0.023 I
Maximum(lb/d): •
6 Month Average(mg/L): 0.091 0.088 0.007 0.006 0.009 0.0042 0.002 0.004 0.003 0.007
6 Month Average(lb/d): I 11 II I I - 1 I _ I I I I - - -I [ - - - II IF 1
%Violations,(Chronic SND is>�6%): 0.00% 1 0.00% ] I_0.00%J 0.00% I N/A I N/A J 0.00% 1 0.00% 0.00% 0.00% 0.00% 0.00%
%TRC Violations(SNC is>=33%): 0.00% 0.00% 0.00% 0.00% N/A N/A 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
Hg Total Metals Toluene MEK TTO Oil and Grease
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max. Daily Max Daily Max
Total#of Samples: 0 1 I 0 0 0 0 0 0 1 I 0 0 0 0 0
Maximum(mg/L): I 1 r
Maximum(lb/d): 1 I j
6 Month Average(mg/L):
6 Month Average(lb/d):
%Violations,(Chronic SND is> 66%): I N/A N/A I N/A I N/A I I N/A I I N/A N/A N/A 1 N/A I N/A N/A 1 N/A
%TRC Violations(SNC is>=33%): N/A 1 N/ N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Averages are determined using 1/2 BDL Page 1
1 I M M I = MN - ME M MI I - M - M M - - r

L e6ed lug U!Sewn paueuuatap alp sa tuaAY
VM V/N V/N _ V/N V/N V/N V/N V/N %00'0 %00'0 V/N j V/N :(%££_<s!DNS)suo!lelo!A 3/11%
V/N I I VM I I VM I VM 1 I VM I WN I I V/N 1 I V/N I I %00'0 I I %00'0 I I V/N I.. VM 1 :(%99 <s!(INS a!uolqD)`suo!lelo!A%
:(P/gl1 a2siany gluotnl 9
LL 1.'0 961.'0 :('I/Sw)agsiaAv gluow 9
1 :(P/91)wnw!xeyil
49£'0 I 6£'0 _ I :(1/2w)wnw!xeyq
0 0 0 0 0 0 0 0 91. a a o :saldwgs Jo#lwoi
w i1!aa -W,(!!aa xaw AMU 'NM filWI w AFC! 1031^4 kPua xvw AM! _ lull^1 AIM 1,1441 APO w Ta w i su xvs ,4Qa
s4luutu 9 P"Z s9uau 91sT s9uau 9 PuZ stPuaw 9 PI sip=9 PuZ s4tuow 9 is I swam 9 PuZ stpuow 901 s9uuw 9 PuZ s9uotu 91st sot=9 PuZ sliuo a 91s I
assat0 pee HO OJ L 3I3I11 aeaotol slelaIN 11101 SH
%00'0 %00'0 %00'0 %00'0 %00'0 %OL'£ %00'0 %00'0 %00'0 %00'0 %00'0 %00'0 :(%££=<s!RNs)suoueto!A DILL%
%00'0 %00'0 %00'0 %00'0 %00'0 %1.1.'l l %00'0 %001) I %00'0 %00'0 [ %00'0 %00'0 :(%99=<Si QNS o!uotgJ)•suolleto!A%
:(P/qI)a8utany 4luoynt 9
—
LOO E1.0'0 900'0 900'0 LOOL'0 960£'0 L00'0 600'0 ZOL'O ELL'0 LEO)) 940'0 :('U9w)amity glum 9
:(P/g1)umwfXoAJ
91.'0 I 90'0 I 600'0 £40'0 I 42'0 J L'Z 81.0'0 L£0'O I 62'0 1 I 92'•0 1 Ivo LL'0 I :Maul)umugxeLAI
91. a Z Z 91. a 91. a 91. a 91. j a aaldwes Jo#Rol
XSN ALreCI xvN dPva luINI Alva 'xaw'4"ci 'MN,tl!aa xaN AI!eu WI AIME xvN di!vu xvv dl!sa xvN AIM 'WN,t u , xvN AI!aa
WI=9 PuZ stllu=91sT stpuau 9 PuZ ER=910 1 alluow 9 PuZ S9utxu 91sT stPuau 9 PuZ s9tttxu 9151 s9uaut 9 PuZ siPuau 91sT slum 9 PuZ 0400L9 901
3V qd NO us uZ !N
%00'0 %00'0 _ %00'0 %00'0 %00'0 ; %0011 V/N V/N V/N V/N %00'0 1 %00'0 :(%££=<s!DNS)suo!lelo!A 3/LL%
%00'0 %00'0 %00'0 %00'0 %001) %00'0 V/N V/N V/N V/N %00'0 j %00'0 :(%99=<s!QHS o!uoig3)`suo!leto!A%
:(p/q0 2$e13AV giuoyi 9
400'0 £10'0 LOO £20'0 L900'0 9200'0 L I 9200'0 IZ00'0 :(7/1114)a8etanV gwoyg 9
I 1 I I I 1 I I I I I 1 I I I :(P/gl)wnu!xew
£40'0 £0'0 LLO'O 90'0 1.40'0 9200'0 1 I I I I 4900'0 I ZL00'0 I :(1111)wnw!xew
I 91 I I LZ I I 91 I I a I I _Z _ L I I 0 I I 0 1 0 _ 0 £4 LL :saldweSJo#Imu,
xaw CI!va xaw rSt!aa -raw,tt!aa _ xeN,ctwu 'xvN'CM xvN/VG_ xvn AI!va IMIAL XI!tta WN At!aa xvN A O xvN'CI!ua xaw/luta
s9utxu 9 PuZ s9uau 91s I stPuau 9 PuZ aluau 91s l stlluaw 9 PuZ s4luuut 91s I s4Nu u 9 PuZ s4wau 91s I s9atxtl 9 PuZ aqui=91s I stPuuw 9 PUZ RR=91s I
10 JD PO SS.L 0Oit 09W'M0121
FT6Z'1£tegwaoea 01 L Mnf:sgwoN[9 PuZ
[164Z000N :#S3QdN frOZ'oc Ant•of L nlenuef :sy3uop/9lst
32IM Pewit 113119JA :aweN dIAVA
[OdW :#aci!d `
,Clueo0 agwoaunit OST :aweN umoi Zi-£00-5 :#and 111.103 Aiguiwns nua iUia;snpuI
A uoginy Ioa;1103 2uiystui3 pug 'glow aiiinagsy (Hyd) ;.iodali ignuuy 4uaul4eaa4aad
INIIII MEI S IIIII N M r IIMI NM Mil MN MN NM MO I r M M NM

Pretreatment Annual Report (PAR) Asheville Paint & Powder Control Authority
Industrial Data Summary Form IUP#. S-005-12 Town Name: MSD Buncombe County
Pipe#: MPOI WWTP Name: French Broad WRF
1st 6 Months: January 1 to July 30,2014
NPDES#: NC0024911
2nd 6 Months: July 1 to December 31,21114
Flow,MGD BOD TSS Cd Cr Cu
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max. Daily Max Daily Max. Daily Max Daily Max . Daily Max
Total#of Samples: 0 4 0 0 I 0 0 I I 0 1 2 I 0 4 0 2
Maximum(mg/L): I I 0.0025 I 0.0029 9.76 0.426
Maximum(lb/d): I
6 Month Average(mg/L): I I 0.0025 I 0.0017 2.484 0.227
6 Month Average(Ib/d):
%Violations,(Chronic SND is> 6%): N/A I 0.00% N/A N/A N/A N/A N/A 0.00% N/A 25.00% N/A 0.00%
%TRC Violations(SNC is>=33%): N/A 0.00% N/A N/A N/A N/A N/A I 0.00% N/A 25.D0% N/A 0.00%
Ni Zn Sn CN Pb Ag
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max. Daily Max Daily Max Daily Max. Daily Max Daily Max. Daily Max Daily Max . Daily Max Daily Max Daily Max
Total#of Samples: 0 2 0 4 0 0 0 2 0 2 0 2
Maximum(mg/L): 1 , 0.665 I I I 2.67 I I 1 I I I I 0.0092 1 1 I I 0.047 I I I r 0.002 I
Maximum(lb/d):
6 Month Average(mg/L): ' 0.343 0.889 I 0.0066 0.025 0.002
6 Month Average(lb/d): I I I I I I I I I I I I I I I I I 1 I I I
%Violations,(Chronic SND is>56%): L N/A _ I 0.00% I N/A 25.00% N/A - N/A N/A 0.00% N/A L0.00% J N/A J 0.00%J
%TRC Violations(SNC is>=33%): N/A 0.00% N/A 25.00% N/A N/A N/A 0.00% N/A 0.00% N/A 0.00%
Hg Total Metals Toluene MEK TTO Oil and Grease
1st 6 months i 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 0 0 0 _ 0 0 0 0 0 0 _ 1 0 0
Maximum(mg/L): I r 0.078 I 1
Maximum(lb/d):
6 Month Average(mg/L): I 0.078
6 Month Average(1b/d):
%Violations,(Chronic SND is>=66%): N/A I N/A N/A N/A N/A N/A N/A I N/A J I N/A 1 I 0.00% I_ N/A N/A
%TRC Violations(SNC is>=33%): N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00% N/A N/A
Averages are determined using 1/2 BDL Page 1
MI I 11111. M - I - - ' - - - - NM MN - E

• NI I NI OM • NI - - IN - I I ■■i - EN ■l I 11111
Pretreatment Annual Report (PAR) Balcrank Corporation Control Authority
Industrial Data Summary Form IUP#: 5-071-12 Town Name: MSD Buncombe County
Pipe#: MPOI WWTP Name: French Broad WRF
1st 6 Months: January 1 to July 30,204 NPDES#: NC0024911
2nd 6 Months: July 1 to December 31,204
Flow,MGD BOD TSS Cd Cr Cu
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max. Daily Max ` Daily Max Daily Max. Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max. Daily Max Daily Max
Total#of Samples: 3 2 0 0 [ 0_ _ { _ 0 _ 3 _ I _ 2 _ _ 3 [ 2 I 3 I 2 -
Maximum(mg/L): I 0.0024 I 0.0024 I 0.003 I 0.0005 0.035 0.011 0.31 0.158
Maximum(1b/d): I _ - _ _ _ 1- --
6 Month Average(mg/L): I 0.0017 I I 0.0024 - 0.0018 I 0.0005 0.017 0.009 0.216 0.149
6 Month Average(lb/d): - --
-
%Violations,(Chronic SND is>- 36%): 0.00% I i 0.00% N/A N/A N/A N/A 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
%TRC Violations(SNC is>=33%): 0.00% I 0.00% WA N/A N/A N/A 0.00% I 0.00% 0.00% 0.00% 0.00% 0.00%
Ni Zn Sn CN Pb Ag
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months "-1st 6 months 2nd 6 months
Daily Max Daily Max. Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max. Daily Max Daily Max
Total#of Samples: 3 j 2 3 2 0 0 I 3 I 2 3 2 3 2
Maximum(mg/L): I 0.207 H 0.144 I 0.168 H I 0.135 I I H I I I 0.15 I 0.27 I I 0.146 -I I 0.002 I I 0.002 1 I 0.002 I
Maximum°b/d):
6 Month Average(mg/L): 0.159 I ' 0.129 0.11 0.117 0.0807 I 0.1455 [ 0.055 0.002 0.002 0.002
6 Month Average(lb/d): L i I I I I 1 I I I ( _ I I I I I I 1 I 1 I
%Violations,(Chronic SND is> 56%): L 0.00%L ` O.00% J 0.00% L 0.00% WA _I I_ WA L0.00% 0.00% 0.00% L0.00% J 0.00% J 0.00%
%TRC Violations(SNC is>=33%): 0.00% ' 0.00% 0.00% 0.00% N/A N/A I 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
Hg Total Metals Toluene MEK TTO Oil and Grease
I st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max. ' Daily Max Daily Max Daily Max. Daily Max Daily Max
Total#of Samples: 0 0 0 0 0 L 0 0 0 0 0 0 0
Maximum(mg/L): I 1 -1 [ -
Maximum(lb/di:
6 Month Average(mg/L): 1
6 Month Average(lb/d): �
%Violations,(Chronic SND is> 6%): I N/A I N/A N/A N/A I N/A I N/A N/A I WA I I N/A N/A I WA I WA
%TRC Violations(SNC is>=33%): N/A N/A I N/A N/A N/A N/A N/A �A N/A N/A N/A N/A
Averages are determined using 1/2 BDL Page 1

Pretreatment Annual Report (PAR) Borg Warner Thermal Systems Control Authority
Industrial Data Summary Form IUP#: S-030-12 Town Name: MSD Buncombe County
Pipe#: MP01 WWTP Name: French Broad WRF
1st 6 Months: January 1 to July 30,2Q14
NPDES#: NC0024911
2nd 6 Months: July 1 to December 31,2Q11
Flow,MGD BOD TSS Cd Cr Cu
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max. Daily Max. - Daily Max Daily Max Daily Max. Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max. Daily Max
Total#of Samples: 127 123 0 0 0 H I 0 1 1 _ 2 I- 1 _ _ 2 I 12 11 13
Maximum(mg/L): 0.0138 1 0.0146 0.0005 0.0005 0.002 0.002 _ .1 0.055 0.052
Maximum(1b/d): I I I I I
6 Month Average(mg/L): I 0.0100 1 0.0094 0.0005 ' 0.0005 0.002 0.002 0.029 0.024
6 Month Average(lb/d):
%Violations,(Chronic SND is>--56%): 0.00% li 0.00% N/A N/A N/A N/A 0.00% L 0.00% 0.00% 0.00% 0.00% 0.00%
%TRC Violations(SNC is>=33%): 0.00% 1 r 0.00% N/A N/A N/A N/A 0.00% 0.00% 0.00% 0.00% 0.00% j 0.00%
Ni Zn Su CN Pb Ag
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max. Daily Max Daily Max Daily Max. Daily Max. Daily Max Daily Max Daily Max Daily Max. Daily Max Daily Max
Total#of Samples: I 12 1 l 13 12 13 0 3 12 13 1 2 1 2
Maximum(mg/L): I 0.062 0.06 1 0.235 I I 0.528 I I H I 0.02 I 0.51 0.4 I I 0.002 I I 0.002 I I 0.002 I I 0.002
Maximum(lb/d): 1
6 Month Average(mg/L): 0.038 1 0.036 0.122 0.217 0.017 0.2147 0.1192 0.002 _ 0.002 0.002 0.002
6 Month Average(lb/d): I 1 , I I I I I I I 1 I I I I I I I I I
%Violations,(Chronic SND is>=66%): L 0.00% 1 0.00%_] 1. 0.00%J 0.00% N/A J L N/A 0.00% 0.00% L 0.00% J 0.00%] 0.00% L0.00%
%TRC Violations(SNC is>=33%): 0.00% 1 0.00% 0.00% 0.00% N/A N/A 0.00% 0.00% J 0.00% 0.00% 0.00% 0.00%
Hg Total Metals Toluene MEK TTO Oil and Grease
I st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max . Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 0 0 0 0 0 0 0 0 0 0 0 0 _
Maximum(mg/L): I I I 1 r i r 1 1 1
Maximum(lb/d): _ _
6 Month Average(mg/L): I
6 Month Average(lb/d):
%Violations,(Chronic SND is> 6%): N/A N/A I N/A I N/A I N/A I N/A I N/A N/A N/A N/A N/A N/A I
%TRC Violations(SNC is>=33%): N/A 1 N/A N/A N/A N/A N/A I N/A N/A N/A N/A N/A N/A
Averages are determined using 1/2 BDL Page 1
- - - i♦ NI - - NM MI III NIB III ON 11111 Ell NI 11111

1
1111 1111 1111 MI NI IN NI I NI - I - NI NE - - MO r IN
Pretreatment Annual Report (PAR) Continental Automotive Systems. Inc. Control Authority
Industrial Data Summary Form !up#: S-015-12 Town Name: MSD Buncombe County
Pipe#: MPO1 WWTP Name: French Broad WRF
1st 6 Months: January 1 to July 30,2Q14 NPDES#: NC0024911
2nd 6 Months: July 1 to December 31,2014 -
Flow,MGD BOD TSS Cd Cr Cu
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max. Daily Max Daily Max Daily Max Daily Max Daily Max. Daily Max Daily Max Daily Max
Total#of Samples: 178 h 168 0 0 0 0 12 13 I 12 L 13 12 13
Maximum(mg/L): I 0.061 I 0.055 I 0.0025 0.0005 0.023 0.027 0.013 0.008
Maximum(lb/d):
6 Month Average(mg/L): I 0.0311 I 0.0329 I 0.0007 0.0005 0.013 0.015 0.005 0.005
6 Month Average(Ib/d):
%Violations,(Chronic SND is>=66%): 0.00% I 1 0.00% N/A N/A N/A N/A 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
%TRC Violations(SNC is>=33%): 0.00% 1 1 0.D0% N/A N/A WA WA0.00% 0. 00 0.00% 0.00% 0.00% 0.00%
NI Zn Sn CN Pb Ag
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max. Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 12 13 12 13 0 0 12 13 12 13 12 13
Maximum(mg/L): I 0.226 I 0.329 I L 0.372 ] I 0.606 I I _1 I I I 0.012 j 0.011 I [ 0.013 I I 0.002 I I 0.013 1 I 0.002
Maximum(lb/d):
6 Month Average(mg/L): 0.15 I 0.16 0.233 0.244 0.0041 0.0065 0.003 0.002 0.003 0.002
6 Month Average(lb/d): I I I I i I I I I I I I - I I - I I_ 11 - - I I-- - I
%Violations,(Chronic SND is>�6%): 0.00% I I 0.00% J L 0.00% J 0.00% N/A _I L N/A 0.00% 0.00% 0.00% J I 0.00% J 0.00% J L 0.00%J
%TRC Violations(SNC is>=33%): 0.00% jI 0.00% 0.00% 0.00% N/A N/A 0.00% I 0.00% 0.00% 0.00% 0.00% 0.00%
Hg Total Metals Toluene MEK TTO Oil and Grease
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 0 0 0 0 0 0 I 0 0 _ 0 0 0 _ 0
Maximum(mg/L): 1 -1 L 1-
Maximum
Maximum(lb/d):
6 Month Average(mg/L): i
6 Month Average(lb/d):
%Violations,(Chronic SND is> 56%): _ N/A N/A N/A I N/A I N/A N/A I N/A I N/A N/A r N/A N/A I N/A
%TRC Violations(SNC is>=33%): N/A N/A N/A N/A N/A N/A N/A I N/A N/A N/A N/A N/A
Averages are determined using 1/2 BDL Page 1

Pretreatment Annual Report (PAR) Jacob Holm Industries (America). Inc. Control Authority
Industrial Data Summary Form IUP#: S-067-12 Town Name: MSD Buncombe County
Pipe#: MPOI WWTP Name: French Broad WRF
1st 6 Months: ,January 1 to July 30,2Q14
NPDES it: NC0024911
2nd 6 Months: ,July 1 to December 31,2114
Flow,MGD BOD TSS Cd Cr Cu
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max , Daily Max. Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 181 I 184 6 8 6 8 I 0 1 0 I 0 _ _ I 0 I 0 10 I
Maximum(mg/L): 0.10179 I 0.11937
Maximum(lb/d): 186.2 149.1 I 471.6 497.9 � I _ _ _ . I _ I I
6 Month Average(mg/L): 0.0308 i i 0.0408
6 Month Average°b/d): 60.7 29.1 209.8 118.4
%Violations,(Chronic SND is>=66%): 0.00% ' 0.00% 0.00% 0.00% 0.00% 0.00% N/A N/A N/A N/A N/A N/A
%TRC Violations(SNC is>=33%): 0.00% I, 0.00% 0.00% 0.00% 0.00% 0.00% N/A I N/A N/A N/A N/A N/A
Ni Zn Sn CN Pb Ag
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months ' 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max r Daily Max. Daily Max Daily Max Daily Max. Daily Max - Daily Max. Daily Max Daily Max Daily Max. Daily Max Daily Max
Total#of Samples: 0 0 0 0 0 0 0 0 0 0 0 0
Maximum(mg/L): I I I I I I I II I I I I II I I I I I
Maximum(lb/d): I _ -
6 Month Average(mg/L): _ I
6 Month Average(lb/d): I I I I I I I I I I I I II I I I ! I
%Violations,(Chronic SND is>�6%): N/A____! ___. WA _] L WA J N/A L WA _; L WA J L N/A N/A L N/A I_-N/A N/A J I N/A I
%TRC Violations(SNC is>=33%): N/A N/A _ N/A N/A N/A N/A N/A I N/A N/A N/A N/A N/A
Hg Total Metals Toluene MEK TTO Oil and Grease
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max. Daily Max Daily Max
Total#of Samples: 0 1 0 0 0 0 0 0 0 0 0 0 0
Maximum(mg/L): P Li _ L
Maximum(lb/d): _
6 Month Average(mg/L): I
_
6 Month Average(lb/d): __
%Violations,(Chronic SND is> 56%): N/A N/A I N/A I N/A I N/A I I N/A I I N/A N/A N/A I N/A I N/A WA
%TRC Violations(SNC is>=33%): I N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Averages are determined rinsing 1/2 BDL Page 1
MN MI MI MI IM - MI - - - - - - IN - - - 11111 ■N

I IMO
no EN I m - 1
Pretreatment Annual Report (PAR) Kearfott Corporation. Motion Systems Division Control Authority
Industrial Data Summary Form IUP#: S-009-12 Town Name: MSD Buncombe County
Pipe#: MPOI WWTP Name: French Broad WRF
1st6 Months: January 1 to July 30,2Q14
NPDES#: NC0024911
2nd 6 Months: July 1 to December 31,2Q14
Flow,MGD BOD TSS Cd Cr Cu
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max. Daily Max. Daily Max Daily Max Daily Max Daily Max. Daily Max Daily Max
Total#of Samples: 122 1 120 0 0 0 _ 0 1_ 1 2 I 12 13 [ 12 13
Maximum(mg/L): I 0.0093 I 0.002942 I 0.0005 i 0.0005 0.61 0.304 0.376 0.154
-
Maximum(Ib/d): I I I
6 Month Average(mg/L): I 0.0011 1 1 0.0007 I 0.0005 0.0005 0.101 0.052 0.071 0.036
6 Month Average(lb/d):
%Violations,(Chronic SND is> 66%): 0.00% 0.00% N/A N/A N/A N/A 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
%TRC Violations(SNC is>=33%): 0.00% . 0.00% N/A N/A N/A N/A 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
Ni Zn ) Sn CN Pb Ag
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max - Daily Max Daily Max Daily Max Daily Max Daily Max - Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 12 113 12 13 0 0 1 2 1 2 1 2
Maximum(mg/L): I 0.791 I 0.213 I I 0.25 H I 0.147 I I I I I l 0.025 0.009 1 I 0.002 11 0.002 11 0.002 I I 0.002 1
Maximum(lb/d): I
6 Month Average(mg/L): 0.199 I 0.059 0.046 0.03 0.025 0.0057 0.002 0.002 0.002 0.002
6 Month Average(lb/d): I 1 I I I I I I I I I I I 1 I I- I I I I I I 1
%Violations,(Chronic SND is>--56%): 0.00% 1 0.00% 1 L 0.00% L 0.00% N/A _J N/A L 0.00% 0.00% L 0.00% 1 0.00% 0.00% J 0.00%
%TRC Violations(SNC is>=33%): 0.00% 0.00% 0.00% 0.00% N/A N/A 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
Hg Total Metals Toluene MEK TTO Oil and Grease
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 0 1 0 0 0 0 0 0 1 0 0 0 0 0
Maximum(mg/L):
Maximum°b/d):
6 Month Average(mg/L): I
6 Month Average(lb/d): I j
/°Violations, Chronic SND is>=66/0: N/A N/A N/A N/A N/A N/A N/A N/AWA N/A N/A N/A
° ( ° ) I IIII I 1I 1 - i
%TRC Violations(SNC is>=33%): N/A I N/A N/A N/A N/A N/A N/A N/A N/A WA - N/A N/A
Averages are determined using 1/2 BDL Page 1

Jmum
Pretreatment Annual Report (PAR) Mission Hospital Laundry Control Authority
Industrial Data Summary Form IUP#: S-068-12 Town Name: MSD Buncombe County
Pipe#: MPOI WWTP Name: French Broad WRF
1st 6 Months: January 1 to July 30,2014 NPDES#: NC0024911
2nd 6 Months: July 1 to December 31.20.4
Flow,MGD BOD TSS Cd Cr Cu
i st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max . Daily Max Daily Max Daily Max. Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 181 j 1 184 1 6 7 6 7 0 1 0 I 0 _ I 0 0 I I 0
Maximum(mg/L): 10.064321 ' 0.068656 I 277 192 476 147
Maximum(lb/d): I I
6 Month Average(mg/L): I 0.0547 j 0.0543 I 131.4 61.2 298.2 37.7 i I
6 Month Average(lb/d): I -
%Violations,(Chronic SND is> 56%): 16.57% j ' 22.83% 0.00% 0.00% 16.67% 0.00% N/A I WA N/A N/A N/A N/A
%TRC Violations(SNC is>=33%): 0.00% I, 0.00% 0.00% 0.00% 0.00% 0.00% N/A I N/A N/A N/A N/A N/A
Ni Zn Sn CN Pb Ag
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max. Daily Max Daily Max Daily Max. Daily Max Daily Max. Daily Max Daily Max Daily Max. Daily Max Daily Max
Total#of Samples: 0 1 0 0 0 0 0 0 � 0 0 0 0 0
Maximum(mg/L): 1 I I I I I I I I I I I I I - - I I_ I I I
Maximum(lb/d): 1
6 Month Average(mg/L): _
6 Month Average(lb/d): I 1 I f I I I I I I I I I I I I I I I I
%Violations,(Chronic SND is>=66%): L__N/A I N/A I WA NIA [ _WA J I WA I N/A_ I N/A L N/A L N/A I L__N/A _I [- N/A _
%TRC Violations(SNC is>=33%): N/A 1 ' N/A N/A _ N/A N/A N/A N/A 1 N/A N/A N/A N/A N/A
Hg Total Metals Toluene MEK TTO Oil and Grease
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 0 j 0 0 0 0 0 0 j 0 0 0 0 0
Maximum(mg/L): I i 1 I I I 1— 1 L
Maximum(lb/d): _
6 Month Average(mg/L): I
6 Month Average(1b/d): 1
%Violations,(Chronic SND is> 56%): N/A N/A N/A N/A I N/A I N/A I N/A N/A I I N/A N/A I 1 N/A I WA I
%TRC Violations(SNC is>=33%): N/A I N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Averages are determined using 1/2 BDL Page 1
—
MIN1— N aaas �.. mal

111111 IIIIII - NM I - r - MN - M - N N MI - N l IIIIIII
Pretreatment Annual Report (PAR) prince Manufacturing Control Authority
Industrial Data Summary Form 111P#: 5.065-12 Town Name: MSD Buncombe County
Pipe#: MPO1 W WTP Name: French Broad WRF
1st 6 Months: January 1 to July 30,2Q14
NPDES#: NC0024911
2nd 6 Months: July 1 to December 31,2014
Flow,MGD BOD TSS Cd Cr Cu
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max. Daily Max. Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 155 I 151 0 0 0 0 I 1 3 12 C 13 2 I 3
Maximum(mg/L): I 0.0305 I I- 0.0306 I 0.0005 : 0.0005 0.019 0.035 0.002 0.002
Maximum(1b/d): I I
6 Month Average(mg/L): I 0.0187 11 0.0192 0.0005 0.0005 0.014 0.014 0.002 0.002
6 Month Average(lb/d):
%Violations,(Chronic SND is>�6%): 0.65% I 0.86% N/A N/A N/A N/A 0.00% I 0.00% 0.00% 0.00% 0.00% 0.00%
%TRC Violations(SNC is>=33%): 0.00% 0.00% N/A N/A N/A N/A 0.00% ' 0.00% 0.00% 0.00% 0.00% 0.00%
Ni Zn So CN Pb Ag
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 mouths 1st 6 months 2nd 6 months
-
Daily Max Daily Max. Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 12 13 12 13 0 0 1 I 2 1 3 1 2
Maximum(mg/L): I 0.095 I r 0.062 [ 0.44 1 I 0.571 1 I 1 I I 0.0025 0.0025 1 I 0.002 I F 0.002 I I 0.002 I I 0.002 I
Maximum(lb/d):
6 Month Average(mg/L): 0.015 0.016 0.125 - 0.134 0.0025 ' 0.0025 0.002 0.002 0.002 0.002
6 Month Average(113/d): I I I I I I I I I I I l I I l I I 1 I I
%Violations,(Chronic SND is> 56%): 0.00% 0.00% ] 0.00% 1 0.00% L N/A N/A - 0.00% 0.00% 0.00% 0.00% 0.00% J 0.00%
%TRC Violations(SNC is>=33%): 0.00% 0.00% 0.00% 0.00% N/A N/A 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
Hg Total Metals Toluene MEKTTO Oil and Grease
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 0 0 0 0 0 0 0 0 0 0 0 0
Maximum(mg/L): I
Maximum(1b/d): I
6 Month Average(mg/L): - l
6 Month Average(1b/d):
%Violations,(Chronic SND is>�6%): N/A N/A I N/A N/A N/A N/A N/A N/A I N/A I N/A N/A I N/A
%TRC Violations(SNC is>=33%): N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Averages are determined using 1/2 BDL Page 1

Pretreatment Annual Report (PAR) Sierra Nevada Brewing Co. Control Authority
Industrial Data Summary Form IUP#: S-073-13 Town Name: MSD Buncombe County
, Pipe#: MPO1 WWTP Name: French Broad WRF
1st 6 Months: January 1 to July 30,2Q14
NPDES#: NC0024911
2nd 6 Months: July 1 to December 31,2E114
Flow,MGD BOD TSS Cd Cr Cu
1st 6 months 2nd 6 months lot 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months '
Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max. Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 177 I 183 45 19 45 1 19 I 0 1 0 I 1 0 1 I 0 0 I 0 1
Maximum(mg/L): 10.130671 I 1 0.129219
Maximum(lb/d): 115.7 727.1 260.3 206.1 1I
6 Month Average(mg/L): I 0.06380.0
6 Month Average(lb/d): 47.5 133.6 89.6 82.7
%Violations,(Chronic SND is> 56%): 5.08% ' 7.10% 0.00% 0.00% 0.00% 0.00% N/A l N/A N/A N/A N/A N/A
%TRC Violations(SNC is>=33%): 1.69% 1.09% 0.00% 0.00% 0.00% 0.00% N/A i N/A N/A N/A N/A N/A
Ni Zn So CN Pb Ag
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max - Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max. Daily Max Daily Max
Total#of Samples: 0 I : 0 0 0 0 0 0 ' 0 0 0 0 0
Maximum(mg/L): I I I I I I I 1 I _ I I I I 11 I I 11
Maximum(lb/d): I I
—
6 Month Average(mg/L): 1
6 Month Average(lb/d): I 11 I I 11 I I I I I I I I 11 I I I I I
%Violations,(Chronic SND is>66%): N/A r N/A j N/A J N/A N/A N/A _I L N/A : N/A N/A N/A I__ N/A J N/A
%TRC Violations(SNC is>=33%): N/A N/A N/A N/A N/A N/A N/A 1 N/A N/A N/A N/A 1 N/A
Hg Total Metals Toluene MEK TTO Oil and Grease
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max ', Daily Max Daily Max
Total#of Samples: 0 0 0 0 0 0 0 0 0 0 _ 0 0
Maximum(mg/L):
Maximum(lb/d):
6 Month Average(mg/L):
6 Month Average(lb/d):
%Violations,(Chronic SND is> 56%): L N/A I N/A I N/A N/A N/A I WA 1 N/A I N/A I N/A N/A I N/A N/A 1
%TRC Violations(SNC is>=33%): N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Averages are determined using 1/2 BDL Page 1
INN M — — 11111 M w M MINI — I M N M M M M — N

1 M 1 E 1 M r - N E n - N - w ■w r EN N
Pretreatment Annual Report (PAR) Williams Plating Company. Inc, Control Authority
Industrial Data Summary Form 11./P#: S-007-12 Town Name: MSD Buncombe County
Pipe#: MP01 WWTP Name: French Broad WRF
1st 6 Months: January 1 to July 30,ZQ14
NPDES#: NC0024911
2nd 6 Months: July 1 to December 31,20.14
Flow,MGD BOD TSS Cd Cr Cu
1st 6 months 2nd 6 months 1st 6 months 2nd 6 nxmths 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max. Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 134 I 129 0 0 0_ I L 0 12 12 I I 12 12 12 12
Maximum(mg/L): L 0.0029 I 0.0028 0.0025 0.005 0.026 0.025 0.051 0.197
Maximum(]b/d): I I I 1 r I
6 Month Average(mg/L): I 0.0014 0.0014 0.0023 0.0025 0.013 0.013 0.019 0.051
6 Month Average(lb/d):
%Violations,(Chronic SND is>=66%): 0.00% I 0.00% N/A N/A N/A N/A 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
%TRC Violations(SNC is>=33%): 0.00% I 0.00% N/A N/A N/A N/A 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
Ni Zn Sn CN Pb Ag
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Mem Daily Max Daily Max
Total#of Samples: 12 12 12 12 12 12 12 12 12 12 12 12
Maximum(mg/L): I 0.88 0.65 I I 0.105 I I 0.269 I I 0.066 I I 0.277 I I 0.024 0.13 I I 0.013 I I 0.029 I I 0.013 1 I 0.025 1
Maximum(1b/d):
6 Month Average(mg/L): 0.397 j 0.225 0.05 0.062 0.035 0.073 0.0057 I 0.0205 0.012 0.015 0.012 0.013
6 Month Average(lb/d): I I I 11 I I I I I I I - I I Ill_ I I l
%Violations,(Chronic SND is> 6%): 0.00% x_0.00%J L 0.00%J I 0.00% I L_0.00% J [ 0.00%J 0.00% 0.00% 0.00% I 0.00% J 0.00%J 0.00%
%TRC Violations(SNC is>=33%): 0.00% I I 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00% 0.00%
Hg Total Metals Toluene MEK TM Oil and Grease
1st 6 months 2nd 6 months 1st 6 months 2nd 6 months lst 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months 1st 6 months 2nd 6 months
Daily Max Daily Max. Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max Daily Max
Total#of Samples: 0 0 0 0 0 0 0 0 0 0 0 0
Maximum(mg/L): 1
Maximum(lb/d):
6 Month Average(mg/L):
6 Month Average(1b/d):
%Violations,(Chronic SND is> 6%): N/A N/A N/A N/A N/A ] N/A N/A N/A N/A N/A N/A I N/A
%TRC Violations(SNC is>=33%): N/A , N/A N/A N/A N/A N/A N/A N/A N/AN/A N/A N/A
Averages are determined using 1/2 BDL Page 1

Allocation Table
Permit Limits in(mg/L)
Allcocation Table Last Updated:10/7/2013
Effecitve Expired
Company Flow BOD TSS Cd Cr Cu Pb Ni Ag Zn CN Hg C-BOD OG Date Date
Arvato Entertainment LLC 0.0050 0.070 1.000 1.000 0.400 1.000 0.240 1.000 0.650 1/1/2012 12/31/2016
Asheville Metal and Finishing 0.0200 0.100 1.000 1.000 0.400 1.000 0.430 1.000 1.000 7/1/2014 12/31/2016
Asheville Paint&Powder 0.0030 0.070 1.000 1.000 0.400 1.000 0.240 1.000 0.650 1/1/2012 12/31/2016
Balcrank Corporation 0.0030 0.070 1.000 1.000 0.400 1.000 0.240 1.000 0.650 1/1/2012 12/31/2016
BaldorElectricCompany-MPOI 0.0025 2.058 0.412 0.249 1/1/2012 12/31/2016
Baldor Electric Company-MPO2 0.0300 0.070 1.000 1.000 0.400 1.000 0.240 1.000 0.650 1/1/2012 12/31/2016
Blue Ridge Metals Corporation 0.1000 0.634 0.843 1/1/2012 12/31/2016
Borg Warner Thermal Systems 0.0200 0.067 0.960 0.960 0.384 1.000 0.230 1.000 0.624 1/1/2012 12/31/2016
Continental Automotive Systems,Inc. 0.0900 0.070 1.000 1.000 0.400 1.000 0.240 1.000 0.650 1/1/2012 12/31/2016
Craggy Prison Laundry 0.0800 700.00 300.00 1/1/2012 12/31/2016
Day International,Inc. 0.0700 2500.00 600.00 2.364 1/1/2012 12/31/2016
Day International,Inc.-1 0.0000 100.00 1/1/2012 12/31/2016
Eaton Corporation-Arden Plant 0.0050 0.070 1.000 1.000 0.400 1.000 0.240 1.000 0.650 1/1/2012 12/31/2016
Jacob Holm Industries(America),Inc. 0.2000 616.91 1369.90 1/1/2012 12/31/2016
Kearfott Corporation,Motion Systems Division 0.0300 0.070 1.000 1.000 0.400 1.000 0.240 1.000 0.650 1/1/2012 12/31/2016
Meritor Heavy Vehicle System,LLC 0.0350 0.055 0.781 0.781 0.313 1.000 0.188 1.000 0.508 1/1/2012 12/31/2016
Milkco,Inc. 0.2000 4500.00 2000.00 1/1/2012 12/31/2016
Mission Hospital Laundry 0.0600 350.00 350.00 1/1/2012 12/31/2016
Prince Manufacturing 0.0300 0.070 1.000 1.000 0.400 1.000 0.240 1.000 0.650 1/1/2012 12/31/2016
Sierra Nevada Brewing Co. 0.1000 11031.18 6714.63 10/7/2013 12/31/2016
Williams Plating Company,Inc. 0.0045 0.070 1.000 1.000 0.400 1.000 0.240 1.000 0.650 1/1/2012 12/31/2016
Domestic Averages
Average Plant Flow CY 2013 19.02
Average SIU Flow CY 2013 0.46
Average Domestic Flow CY 2013 18.56 219.99 195.08 0.001 0.003 0.050 0.004 0.004 0.002 0.197 0.0038 0.00014 218.02 page 1
S - w - M N N ■III ■■I MIN NM - E M NM N - - M

I ■N NE M - NM MN MN - MINI ■IIIE n N M = M M E - E
Allocation Table
Permit Limits in(mg/L)
Allcocation Table Last Updated:10/7/2013
Company Flow BOD TSS Cd Cr Cu Pb Ni Ag Zn CN Hg C-BOD
Arvato Entertainment LLC 0.0050 0.003 0.042 0.042 0.017 0.042 0.010 0.042 0.027
Asheville Metal and Finishing 0.0200 0.017 0.167 0.167 0.067 0.167 0.072 0.167 0.167
Asheville Paint&Powder 0.0030 0.002 0.025 0.025 0.010 0.025 0.006 0.025 0.016
Balcrank Corporation 0.0030 0.002 0.025 0.025 0.010 0.025 0.006 0.025 0.016
Baldor Electric Company-MPOI 0.0025 0.043 0.009 0.005
Baldor Electric Company-MPO2 0.0300 0.018 0.250 0.250 0.100 0.250 0.060 0.250 0.163
Blue Ridge Metals Corporation 0.1000 0.529 0.703
Borg Warner Thermal Systems 0.0200 0.011 0.160 0.160 0.064 0.167 0.038 0.167 0.104
Continental Automotive Systems,Inc. 0.0900 0.053 0.751 0.751 0.300 0.751 0.180 0.751 0.488
Craggy Prison Laundry 0.0800 467.04 200.16
Day International,Inc. 0.0700 1459.50 350.28 1.380
Day International,Inc.-1 0.0000
Eaton Corporation-Arden Plant 0.0050 0.003 0.042 0.042 0.017 0.042 0.010 0.042 0.027
Jacob Holm Industries(America),Inc. 0.2000 1029.00 2285.00
Kearfott Corporation,Motion Systems Division 0.0300 0.018 0.250 0.250 0.100 0.250 0.060 0.250 0.163
Meritor Heavy Vehicle System,LLC 0.0350 0.016 0.228 0.228 0.091 0.292 0.055 0.292 0.148
Milkco,Inc. 0.2000 7506.00 3336.00
Mission Hospital Laundry 0.0600 175.14 175.14
Prince Manufacturing 0.0300 0.018 0.250 0.250 0.100 0.250 0.060 0.250 0.163
Sierra Nevada Brewing Co. 0.1000 9200.00 5600.00
Williams Plating Company,Inc. 0.0045 0.003 0.038 0.038 0.015 0.038 0.009 0.038 0.024
Total Permitted Industrial(lbs/day) 1.0880 19837 11947 0.161 2.227 2.270 1.429 2.298 0.566 4.381 1.5113 0.000 17258 i
Average Domestic(lbs/day) 18.5562 34046 30190 0.091 0.502 7.756 0.624 0.546 0.387 30.416 0.5828 0.021 33741
Total(lbs/day) 19.6442 53883 42137 0.252 2.729 10.026 2.053 2.844 0.953 34.797 2.0941 0.021 50999
C-BOD for"Total Permited Industrial(lbs/day)"is a calculation of BOD•0.8,since it is not monitored by the Sills. page 2

Allocation Table
Permit Limits in(lbs/day
Allcocation Table Last Updated: 10/7/2013
Flow BOD TSS Cd Cr Cu Pb Ni Ag Zn CN Hg C-BOD
Total Allowed 40.00 80731 74726 16.681 296.551 158.619 148.275 158.619 39.655 158.619 32.548 0.1345 70390
Allowed With 10%Safety Factor 36.00 72658 67254 15.013 266.896 142.757 133.448 142.757 35.689 142.757 29.293 0.1210 63351
Industrial Total 1.09 19837 11947 0.161 2.227 2.270 1.429 2.298 0.566 4.381 1.511 0.0000 17258
Domestic Total 18.56 34046 30190 0.091 0.502 7.756 0.624 0.546 0.387 30.416 0.583 0.0210 33741
Total(Industrial and Domestic) 19.64 53883 42137 0.252 2.729 10.026 2.053 2.844 0.953 34.797 2.094 0.0210 50999
Pounds/Day Remaining 16.36 18775 25117 14.761 264.167 132.730 131.395 139.913 34.736 107.960 27.199 0.1000 12352
Percent Remaining 45.43% 25.84% 37.35% 98.32% 98.98% 92.98% 98.46% 98.01% 97.33% 75.63% 92.85% 82.62% 19.50%
page 3
M IIIIII MN M NM = IIIIII M N IIMI I N M MO MI I M MI MI

I
I
I
I
I
I
I
I
le
I
I
I
I $
I
I
1
1

I
•I
I
I
I
I
I
I
I
si
I
I
I
I
co
I
I
I
I
I

1
1
Chapter 9, PAR Guidance
I Pretreatment Performance Summary (PPS)
1. Pretreatment Town Name: MSD of Buncombe County
1
2. "Primary"NPDES Number NCOO 24911 This
Column
or Non_Discharge Permit# if applicable=> for
office
I use
3, PAR begin Date, please enter 01/01/yy or 07/01/yy 3.=> 1/1/2011 PSSD
I 4. PAR end Date, please enter 06/30/yy or 12/31/yy 4.=> 12/31/2011 PSED
g. Total number of SIUs, includes CIUs 5.=> 19 slur
6. Number of CIUs 6.=> 15 CIUS
1 7. Enter the Higher Number, either (7a)or(7b)here=> 1* NOIN
7a. Number of SIUs not sampled by POTW 7a._> 1*
7b. Number of SIUs not inspected by POTW 7b.=> 0
8. Number of SIUs with no IUP, or with an expired IUP 8.=> 0 NOCM
9. Total Number of SIUs in SNC due to either IU Reporting violations or
IUP Limit violations. To avoid double counting some SIUs
Enter ( 9a+9b)- 9c here=> 0 PSNC
IEnter the Number of SIUs in SNC for :
9a. IU Reporting violations 9a._> 0 MSNC
9b. IUP Limit violations 9b._> 0 SNPS
1 9c. Both IU Reporting& Limit violations 9c._> 0
to. Number of SIUs in SNC due to IU Reporting violations
I that were not sampled or inspected by POTW lo.=> 0 SNIN
11. Number of SIUs in SNC due to violation of 11.=> 0 SSNC
Compliance Schedule due dates
1 12. Number NOVs,NNCs, AOs, or similar assessed to SIUs 12.=> 9 FENF
13. Number Civil or Criminal Penalties assessed to SIUs 13.=> 0 .IUDI
14. Number of SIUs included in public notice 14.=> 0 svPu
15. Number of SIUs from which penalties collected 15.=> 0 IUPN
16. Total Amount of Civil Penalties Collected 16.=> $ 0
I 17. Total Number of SIUs on a compliance schedule 17.=> 0 socs
(Foot Notes: AO Administrative Order NOV Notice of Violation
CIU Categorical Industrial User PAR Pretreatment Annual Report
CO Consent Order POTW Public Operated Treatment Works
IIUP Industrial User Pretreatment Permit SIU Significant Industrial User
NNC Notice of Non-Compliance SNC Significant Non-Compliance,formerly RNC
. *Thermal Fisher Scientific USA LLC:was permitted during 2011 but there was no process discharge to monitor.
Page 1 PPS.xlsx
I

Industrial Summary
CY2012
SIU BOD TSS Cd Cr Cu Ni Zn CN Pb Ag Sn Hg Toluene MEK
Arvato Entertainment LLC
Average(mg/1) 0.0020 0.0066 0.0050 0.0590 0.0098 0.0042 0.0025 0.0105 0.0001 0.0025
Maximum (mg/1) 0.0050 0.0250 0.0250 0.1180 0.0500 0.0076 0.0025 0.0250 0.0001 0.0025
Asheville Metal and Finishing
Average(mg/1) 0.0033 0.0458 0.0121 0.1506 0.2765 0.3128 0.0112 0.0251 0.0129 0.0001 0.0025
Maximum (mg/I) 0.0050 0.2960 0.0280 0.4000 0.6200 1.4000 0.0250 0.1000 0.0330 0.0001 0.0025
Balcrank Corporation
Average(mg/I) 0.0018 0.0158 0.2725 0.1780 0.2273 0.2005 0.0050 0.0050 0.0001 0.0025
Maximum (mg/1) 0.0030 0.0410 0.4520 0.2210 0.3740 0.3900 0.0125 0.0125 0.0001 0.0025
Baldor Electric Company-MPO1
Average(mg/1) 0.0121 0.0041 0.2216
Maximum (mg/1) 0.0340 0.0097 0.6200'',
Baldor Electric Company-MP02
Average(mg/1) 0.0005 0.0061 0.0078 0.0056 0.0143 0.0112 0.0025 0.0025 0.1033 0.0025
Maximum (mg/1) 0.0005 0.0170 0.0220 0.0120 0.0231 0.0360 0.0025 0.0025 0.2700 0.0025
Blue Ridge Metals Corporation
Average(mg/I) 0.4025 0.0028
Maximum (mg/I) 3.0000 0.0160,
Blue Ridge Metals Corporation-Total Plant
Average(mg/I) 1.00 35.40
Maximum (mg/1) 1 47
Page 1
IN • Nu • No NI No NI EN no - um EN N. ma

MN Ell NM 11111 Ell INN 11111 NM INN MN NM an 11111 WM MI NI Ell all 11111
Industrial Summary
CY2012
SIU BOD TSS Cd Cr Cu Ni Zn CN Pb Ag Sn Hg Toluene MEK
'Borg Warner Thermal Systems j
Average(mg/I) 1
1, 0.0005, 0.002-51 0.0130 0.027311 0.03711 0.11161 0.0025 1 0.0025, 0.00251 0.0001 0--.-00251 1
Maximum(mg/I)L ;[ 1! 0.000_5 0.00251,1 0.0390jL 0.0551] 0.0580_11 0.3400][ 0.0025] 0.0025,E 0.0025 1_ 0.0001 0.0025]_
;Continental Automotive Systems,Inc.
Average(mg/1)L ,,
EL 0.0007 0.0169 0.00511 0.2045 ' 0.3982" 0.09L_°°°33 ' 0.0041 1 0.00011 0.0025
Maximum(mg/I)[ ,I 0.0025 0.0542, 00158 ] 0.5000';', 0.98301 0.01201, 00125] 0.0215 r 0.0067 0.00i5i
i,
'Craggy Prison Laundry
Average(mg/1)1 265.'9] 72.751[ , 1 II- 1
, !III 1 1 1
r
7 i i 1'
Maximum(mg/1) 42'7J L 14.6] ,E L ,,
. E , 1 I _I
, ..
Day International,Inc.
Average(mg/1)[ 1078.3311 120.651 0.0005 0.0025 0.28501 0.0054 , 1.0142 00025i 0.00251 0.0025 000501 0.0068 0.17291 0.2419
Maximum(mg/1)I 2190,1 268, 0.0005 0.0025 02850 ] 0 0054 , 3.7800 0.002511 0.00251 0.0025 0.0050 [ 0.0068 1.62001 0.9070]
Day International,Inc.-1
-- .
I
Average(mg/1)[ 1 17.83 r 1,
_____}1, I 11 1 1r 1' 1
Maximum(mg/1) 5411 H 11 1 11 i 1 ,
, 1
!Eaton Corporation-Arden Plant
Average(mg/I) 1 0.0005 0.0127 0.0200 0.05581r 0.0454 0.01381,1, 0.00251 0.0177 L 0.0001EE 0.0025!
Maximum(mg/1)111 0.0005 0.0330 0.03701[ 0.09201' 0.1020,, 0.0270 0.0025] 0.0390 0.0001, 0.00251 _1
,Jacob Holm Industries(America),Inc. I
_ ,
1[ 1 ,E 1 -
Average(mg/1)r 306.29! 620.2311 H
11 ,
/ h
,, , 1 11
-,--
1 11 1,--- ;t , ,,---
i' 1 i
Maximum(mg/1)I 82 [ 130011: 11 1P li
i I
Page 2 1

Industrial Summary
CY 2012
SIU BOD TSS Cd Cr Cu Ni Zn CN Pb Ag Sn Hg Toluene MEK
Kearfott Corporation,Motion Systems Division
Average(mg/I)[ 0.0005 0.0434 0.03741 0.0262, 0.0209 0.019011 0.0025] 0.0025 0.0001 0.0025
0.0005 0.3300 0.18001r 0.1100,r 0.0540 0.0256111 0.00251 0.0025 0.0001 0.0025
Maximum(mg/t [
Meritor Heavy Vehicle System,LLC
Average(mg/I)L ' :,_ 0.0038 0.00251: 0.3437 0.102811 0.12361 0.00631 0.0025 0.0025 ' 0.0001 0.00251
,
Maximum(mg/l) 1 0.0457 0.00231 4.73001r 0.20201 1.5006 0014011 0.00251 0.0025 1 ' 0.0001 0.00251,
Milkco,Inc.
Average(mg/1)[1928.00 562.10 _11
Maximum(mg/1) 2760 i 973 1 -11 7 1
Mission Hospital Laundry
___
Average(mg/1) 127.62 76.35' i 1 I- I 111-
Maximum(mg/I)I 3521 1351 7- I -,-
11 I --i-
1
Prince Manufacturing
Average(mg/1)[ 0.0005 0.0102 0.00461 0.0109, 0.1416 0.00351 0.00251 0.0025 0.0001 0.00251 _1
J l 1
i" -----
Maximum(mg/D r 0.0005 0.0261 0.0088 [ 0.1240 1.0900 0.06-51: 0.0025 0.0025 0.0001 0.0025,
Williams Plating Company,Inc. 1
Average 010/1)L I 0.0026 0.0133;1 0.05211[ 0.07131 0.1530, 0.1789] 0.0133] 0.0133 1 0.02831 0.0001,1 0.001511
Maximum(mg/1) ' ' 0.0050 0.02501; 0.625011 0.8250,1 2.5000,1 1.20001i 0.0250 0.02501 0.063311 0.00011,' 0.002511
Page 3
MS 11111 MN MIN 11111 NM Inn EN IMO 11111 111111 II1E MI 11.1 MIN Ell NEI 111111 111111

I
I
Chapter 9, PAR Guidance
IPretreatment Performance Summary (PPS)
1. Pretreatment Town Name: MSD of Buncombe County
f 2. "Primary" NPDES Number NC0024911 C.This
olumn
or Non Discharge Permit# if applicable=> for
office
I
use
3. PAR begin Date, please enter O1/O1/yy or 07/O1/yy 3.=> 1/1/2013 PSSD
4. PAR end Date, please enter 06/30/yy or 12/31/yy 4.=> 12/31/2013 PSED
I5. Total number of SIUs, includes CIUs 5.=> 19 slus
6. Number of CIUs 6.=> 14 cius
I 7, Enter the Higher Number, either (7a)or(7b)here=> 1* NOIN
7a. Number of SIUs not sampled by POTW 7a._> 1*
7b. Number of SIUs not inspected by POTW 7b.=> 0
8. Number of SIUs with no IUP,or with an expired IUP 8.=> 0 NOCM
9. Total Number of SIUs in SNC due to either IU Reporting violations or
IUP Limit violations. To avoid double counting some SIUs
I Enter ( 9a+9b)- 9c here=> 0 PSNC
Enter the Number of SIUs in SNC for :
I
9a. IU Reporting violations 9a._> 0 MSNC
9b. IUP Limit violations 9b._> 0 SNPS
I9c. Both IU Reporting& Limit violations 9c._> 0
to. Number of SIUs in SNC due to IU Reporting violations
I
that were not sampled or inspected by POTW 10.=> 0 SNIN
11. Number of SIUs in SNC due to violation of 11._> 0 SSNC
Compliance Schedule due dates
' 12. Number NOVs,NNCs, AOs,or similar assessed to SIUs 12.=> 7 FENF
13. Number Civil or Criminal Penalties assessed to SIUs 13.=> 0 JUDI
14. Number of SIUs included in public notice 14.=> 0 svPU
I15. Number of SIUs from which penalties collected 15.=> 0 NPN
16. Total Amount of Civil Penalties Collected 16.=> $ 0
I17. Total Number of SIUs on a compliance schedule 17.=> 0 socs
IFoot Notes: AO Administrative Order NOV Notice of Violation
ICIU Categorical Industrial User PAR Pretreatment Annual Report
CO Consent Order POTW Public Operated Treatment Works
I IUP Industrial User Pretreatment Permit SIU Significant Industrial User
NNC Notice of Non Compliance SNC Significant Non-Compliance,formerly RNC
*Baldor Electric Company-MPO1 did not discharge for the entire year.
IPage 1 PPS.xlsx
I

Pretreatment Annual Report (PAR) PAR covers this calendar year=> 2013
Significant Non-Compliance Report (SNCR) Control Authority=Program=Town Name => MSD of Buncombe County
WWTP= Wastewater Treatment Plant, use separate form for each WWTP. WWTP Name => French Broad WRF
S1U = Significant Industrial User NPDES # _> NC0024911
SNC = Significant Non-Compliance
A SNCR Form must be submitted with every PAR, please write "None" if you had No SIUs in SNC during calendar year
SNC ? (Yes/No)
1UP Pipe Industry Name Parameter for each 6-month period.
# # or"Reporting" Jan. -June July -Dec.
None
Attach a copy of the Division's "SIUs in SNC Historical Report" for your POTW's SIUs behind this page .
Is the database correct? Notify the Division of any errors ! Database indicates SNC history for previous years.
EVERY SNC MUST be explained in the Narrative, How was, is, or will it be resolved?
REPEAT SNCs are serious matters that MUST be explained in the Narrative.
Form name: PAR,SNCR,2001
Date Revised: 1/4/2001
Mil ■■■i N MI 1111111 M M — MI — M MI 1111111 M NM MI M N IIIIIII

MI NM M - I MI NM MN - - In MN M EN M -
- r
Industrial Summary
CY 2013
SIU BOD TSS Cd Cr Cu Ni Zn CN Pb Ag Sn Hg Toluene MEK
Arvato Entertainment LLC
Average(mg/I) 0.0012 0.0046 0.0049 0.0987 0.0081 0.0040 0.0058 0.0111
Maximum(mg/I) 0.0025 0.0125 0.0125 0.2710 0.0250 0.0070 0.0125 0.0220
Asheville Metal and Finishing
Average(mg/I) 0.0019 0.0294 0.0115 0.1028 0.0991 0.3850 0.0111 0.0123 0.0115
Maximum(mg/I) 0.0025 0.0700 0.0400 0.4600 0.4700 1.4000 0.0200 0.0620 0.0280
Asheville Paint&Powder
Average(mg/1) 0.0015 0.0536 0.0414 0.0738 0.2453 0.0512 0.0075 0.0278 0.0001 0.0003
Maximum(mg/I) 0.0015 0.0536 0.0414 0.0738 0.2453 0.0512 0.0075 0.0278 0.0001 0.0003
Balcrank Corporation
Average(mg/I) 0.0027 0.0177 0.2480 0.2247 0.2217 0.2767 0.0090 0.0090 0.0060
Maximum(mg/I) 0.0050 0.0380 0.2700 0.2860 0.3140 0.3700 0.0125 0.0125 0.0060
Baldor Electric Company-MPO1
Average(mg/1)
Maximum(mg/I)
Baldor Electric Company-MP02
Average(mg/I) 0.0005 0.0052 0.0099 0.0042 0.0092 0.0160 0.0025 0.0018
Maximum(mg/I) 0.0005 0.0100 0.0230 0.0050 0.0150 0.0870 0.0025 0.0025
Blue Ridge Metals Corporation
Average(mg/I) 0.0005 0.0360 0.0220 0.0920 0.1011 0.0025 0.0025 0.0025 0.0025
Maximum(mg/l) 0.0005 0.0360 0.0220 0.0920 0.6800 0.0025 0.0025 0.0025 0.0025
Page 1

Industrial Summary
CY 2013
SN BOD TSS Cd Cr Cu Ni Zn CN Pb Ag Sn Hg Toluene MEK
Blue Ridge Metals Corporation-Total Plant
Average(mg/1) 8.65 46.00
Maximum(mg/I) 12.40 58.00
Borg Warner Thermal Systems
Average(mg/1) 0.0005 0.0025 0.0154 0.0320 0.0583 0.1639 0.0025 0.0025 0.0001
Maximum(mg/1) 0.0005 0.0025 0.0400 0.0500 0.1090 0.4400 0.0025 0.0025 0.0001
Continental Automotive Systems,Inc.
Average(mg/I) 0.0008 0.0165 0.0054 0.1751 0.3404 0.0057 0.0041 0.0041
Maximum(mg/I) 0.0025 0.0400 0.0125 0.4470 0.6830 0.0170 0.0125 0.0125
Craggy Prison Laundry
Average(mg/1) 212.59 62.87
Maximum(mg/I) 424.00 104.00
Day International,Inc.
Average(mg/1) 1291.84 124.02 0.0005 0.0050 0.0430 0.0130 0.8486 0.0025 0.0025 0.0025 0.0034 0.0359 0.1945
Maximum(mg/I) 2550.00 607.00 0.0005 0.0050 0.0430 0.0130 3.1900 0.0025 0.0025 0.0025 0.0034 0.2500 0.5000
Day International,Inc.-1
Average(mg/1) 12.94
Maximum(mg/1) 26.70
Eaton Corporation-Arden Plant
Average(mg/I) 0.0005 0.0025 0.0528 0.0458 0.0673 0.0050 0.0025 0.0143 0.0090
Maximum(mg/I) 0.0005 0.0025 0.1510 0.0620 0.1740 0.0090 0.0025 0.0224 0.0090
Page 2

M I - IIIIII IIIIII N I IIIIII MI = O IIMII MO I MI
Industrial Summary
CY 2013
SIU BOD TSS Cd Cr Cu Ni Zn CN Pb Ag Sn Hg Toluene MEK
Jacob Holm Industries(America),Inc.
Average(mg/I) 235.14 768.69
Maximum(mg/I) 726.00 2390.00
Kearfott Corporation,Motion Systems Division
Average(mg/1) 0.0005 0.1135 0.0445 0.0445 0.0639 0.0194 0.0025 0.0025
Maximum(mg/I) 0.0005 1.8700 0.1440 0.2600 0.4900 0.0250 0.0025 0.0025
Meritor Heavy Vehicle System, LLC
Average(mg/1) 0.0005 0.0025 0.0025 0.0961 0.0312 0.0036 0.0025 0.0025
Maximum(mg/I) 0.0005 0.0025 0.0025 0.2960 0.0880 0.0058 0.0025 0.0025
Milkco,Inc.
Average(mg/I) 1915.20 483.60
Maximum(mg/I) 2440.00 730.00
Mission Hospital Laundry
Average(mg/I) 183.25 171.22
Maximum(mg/I) 361.00 359.00
Prince Manufacturing
Average(mg/I) 0.0005 0.0090 0.0025 0.0170 0.1488 0.0025 0.0025 0.0025 0.0001
Maximum(mg/1) , 0.0005 0.0258 0.0025 0.1730 0.8870 0.0025 0.0025 0.0025 0.0001
Sierra Nevada Brewing Co.
Average(mg/I) 97.12 242.35
Maximum(mg/1) 260.00 420.00
Page 3

Industrial Summary
CY2013
SIU BOD TSS Cd Cr Cu Ni Zn CN Pb Ag Sn Hg Toluene MEK
Williams Plating Company,Inc.
Average(mg/I) 0.0026 0.0134 0.0555 0.2772 0.0508 0.1464 0.0132 0.0145 0.0221
Maximum(mg/I) 0.0050 0.0250 0.8950 1.0600 0.1560 1.2000 0.0250 0.0510 0.0800
Page 4
MN lid 16411 V V MIII N = MN I IIIIIII N IM M =

I
I
1
I
I
I
I
I
I
I
I
II 9
t
t

I
Table 2 I
MSD Semiannual Compliance Monitoring Results and Removal Rates
Front and Back Valley
September 16,2014 '
Chemtronics Site, Swannanoa,North Carolina
Front Valley(Pipe 01)
Parameter Influent Concentration Effluent Concentration Percentage
(if/l-,) (sg/L) Removal Rate
1,2-Dichloroethane 1.7 _ 0.0 100% _ I
1,2-Dichloropropane <0.1 U 0.0 100%
Benzene <0.1 U 0.0 100%
Bromobenzene <0.1 U 0.0 100% ,
Chloroform 1.0 0.0 100%
cis-1,2-Dichloroethene 0.4 J 0.0 100%
Cyclohexane <0.1 U 0.0 100% '
Ethylbenzene <0.1 U 0.0 100%
m,p-Xylenes <0.1 U 0.0 100%
Methylene Chloride <0.2 U 0.0 100% '
Methyl-tert-butyl ether <0.1 U 0.0 100%
Tetrachloroethene 1.0 0.0 100%
Toluene <0.1 U 0.0 100% ,
Trichloroethene 1.6 0.0 100%
Vinyl Chloride <0.1 U 0.0 100%
Back Valley(Pipe 02) ,
Parameter Influent Concentration Effluent Concentration Percentage
(sg/L) (µg/L) Removal Rate ,
1,2-Dichloroethane 16,000 29 99.8%
1,2-Dichloropropane 410 0.9 99.8%
Benzene 260 0.7 99.7% ,
Bromobenzene 13 J 0.1 J 99.2%
Chloroform 840 1.6 99.8%
cis-1,2-Dichloroethene 73 0.4 J 99.5% ,
Cyclohexane 3,100 3.2 99.9%
Ethylbenzene 11 J 0.0 100.0%
m,p-Xylenes 14 J 0.0 100.0% ,
Methylene Chloride 170 0.4 J 99.8%
Methyl-tert-butyl ether 330 1.4 99.6%
Tetrachloroethene 74 0.2 J 99.7% 1
' Toluene 12 J 0.0 100.0%
Trichloroethene 2,600 _ 5.4 99.8%
Vinyl Chloride <10 U 0.0 100.0%
Notes: I
i 1.MSD means Metropolitan Sewerage District.
) 2.Concentrations are in micrograms per liter(µg/L)for volatile organic compounds.
3."<"indicates a non-detectable result at the reported method detection limit.
4.EPA data qualifiers are indicated as"U"for compounds that were not detected and
"J"for compounds with estimated values.
5.Effluent concentrations indicated as"0.0"represent analytical data results below
the method detection limit as stated in Permit No.G-006-13. I
P:\Chemtronics-2134\Task 20-Compliance Reports\MSD Rpts\Semi-Annual\2014\Scptember\September Semiannual Rpt CY2014 Tables Page 1 of 1
I

tiff eurofins :.
Lancaster Laboratories Analysis Report
Environmental
' 2125 New Wand Pricy,tanes$ew.PA 17101•7174542100•fa:717411-2011•uwellancesaiLabs.corn
ANALYTICAL RESULTS
Prepared by: Prepared for.
' Eurofins Lancaster Laboratories Environmental Altamont Environmental
2425 New Holland Pike 231 Haywood Street
Lancaster,PA 17601 Asheville NC 28801
October 10,2014
Project: MSD Collection System
' Submittal Date: 09/17/2014
Group Number: 1504063
PO Number: 2134.20
State of Sample Origin: NC
Client Sample Description Lancaster Labs(LL)#
FV-EQT Grab Groundwater 7603005
FV-EFF Grab Groundwater 7603006
BV-EQT Grab Groundwater 7603007
BVAS-EFF Grab Groundwater 7603008
MMH Grab Groundwater 7603009
Trip Blank Water 7603010
The specific methodologies used in obtaining the enclosed analytical results are indicated on the
Laboratory Sample Analysis Record.
ELECTRONIC Altamont Environmental Attn:Amy Huffman
COPY TO
Respectfully Submitted,
1\4(k.;, (.t 4:Cfti�_ � l�liVI1 A. , )
( I
Nancy Jean Bomhcilm
Principal Specialist
i [phone]
I
■
Page 1 of 13
11

I
. eurofins
Lancaster Laboratories /�
Environmental Analysis Report
2425 New MoNand Pike,Lancaster,PA 17001 •717456-2300•fax:[phone] •www.LancastsrLabs.com I
1
Quality Control Summary
Client Name: Altamont Environmental Group Number: 1504063 ,
Reported: 10/10/14 at 09:24 AM
Sample Matrix Quality Control
Unspiked (UNSPK) - the sample used in conjunction with the matrix spike
Background (BKG) . the sample used in conjunction with the duplicate
NS MSD M8/MSD RPD BKO DUP DUP Dup RPD II
Analysis None &RBC +LAIC Limits AER MAX aims. Coac Nam
Batch number: 142610035A Sample number(s): 7603009 UNSPK: P601494
Perchlorate 108 99 80-120 9 20
Batch number: 142620024A Sample number(s): 7603009 UNSPK: P594445 ,
Methanol 103 96 84-116 8 20
Surrogate Quality Control 1
Surrogate recoveries which are outside of the QC window are confirmed
unless attributed to dilution or otherwise noted on the Analysis Report.
Analysis Name: GC/MS Volatiles
Batch number: C142621AA
Dbromoluoromethane 1,2-Dichloroethane-d4 Toluene-d8 4-Bromoluorobenzene
7603005 112 109 99 99
7603006 113 107 99 98
7603007 108 104 99 99 II7603010 113 105 99 98
Blank 109 106 99 99
DUP 110 105 99 100
LCS 106 104 102 105
LCSD 106 104 101 105
Limits: 77-114 74-113 77-110 78-110 1
Analysis Name: GC/MS Volatiles
Batch number: C142651AA 1
Dibromotiuwromethane 1,2-Dichloroethaned4 Toluene-d8 4-Brmwluorobenzene
7603008 109 108 99 99
7603009 110 101 99 9911
Blank 111 106 100 99
DUP 111 108 99 99
LCS 108 104 102 105
LCSD 105 101 102 104
Limits: 77-114 74-113 77-110 78-110 1
Analysis Name: Picric Acid -
Batch number: 142620022A
2-NMX
7603009 101
Blank 101 l
LCS 101
MS 101
MSD 102
Limits: 40-157
Analysis Name: Nitroaromatics/Amines 11
Batch number: 142630021A
2-Nitro-m-xy4ene
*-Outside of specification I.
**-This limit was used in the evaluation of the final result for the blank
(1)The result for one or both determinations was less than five times the LOQ.
(2)The unspiked result was more than four times the spike added.
a
I
Page 10 of 13
I
J

At: eurofins
Lancaster Laboratories Analysis Report
' Environmental
2425 New Holland Pike,Lancaster.PA 17601 •717450.2300 •Fax:[phone] •www.Lanc asterLebs.com
Quality Control Summary
' Client Name: Altamont Environmental Group Number: 1504063
Reported: 10/10/14 at 09:24 AM
Surrogate Quality Control
' 7603009 67
Blank 84
LCS 83
LCSD 83
Limits: 60-137
' Analysis Name: Methanol
Batch number: 242620024A
Acetone
7603009 111
Blank 100
' LCS 99
MS 110
MSD 111
Limits: 71-127
I
*-Outside of specification
**-This limit was used in the evaluation of the final result for the blank
' (1)The result for one or both determinations was less than five times the LOQ.
(2)The unspiked result was more than four times the spike added.
Page 11 of 13
I

ti. eurofins iEnvironmental Services Analysis Request/Chain of Custody Lancaster Environmental q
i.abcr atcries
Acct#: 12184 Group#: j S CHO CA Sample#:-.44O O xs- p COC#: 9944
Client: Altamont Environmental Matrix Analyses Requested For Lab Use Only
Project Name/#: MSD Collection System Site ID#: 0 0 ❑ Preservation Codes _SF#:117024 L.
Project Mana er: Amy Huffman P.O.#: 2134.20c 1 ='. H H SCR#:161123 •
u��,,, d Q t
Sampler: jfkook- E C7 u) Preservation Codes
Phone#: 221 3350 Quote#: 207662 N ❑ CJ el o^ , ' H=HCI T=Thlosulrate
State where sample(s)were collected: NC .n W °�,° N=HNO, B=NaOH •
0 G
m o a o N m r
,n
Collection o o ` c @ o s=Hso. P=H�PO� •
G. w N rn t , o..�. = 0=Other
E - m t :° P x o
Sample Identification Date Time t; 0 to 0 i-- 0 e. a �a 1) Remarks _
EFF VON (o0 )< )( 3 -S(
& --Fqr- gI6 ,l! 'loI3 X
EUS - FF et (Diq 1 o23 X K 3 )C
AMI eIrIN iogI x X -7 XXXXX
Turnaround Time Requested(TAT)(please check): Standard RUSH❑ Re I.quished by: Date Time Received by: Date Time
(RUSH TAT is subject to Lancaster Laboratories approval and surcharges.) /ad/A ?//2 /t/ 3 !L(0
Date results are needed: ; Time Rece ved by: Date Time
E-mail address to send RUSH results: �.�! q A:0 (L:co
Data Package Options(please check if required) Relinquished by: Date Time Receiv,d by: Date Time
Type I(Validation/non-CLP) ❑ MA MCP ❑ TX TRRP-13 ❑
Type III(Reduced non-CLP) ❑ CT RCP ❑ Relinquished by: Date Time Received ., : Date Time
Type IV(CLP SOW) 0 ASP Type A 0
Type VI(Raw Data Only) 0 ASP Type B ❑ Relinquished by: \ Date Time Rtfeive y: fa7-
EDD
Time
-I Format: ` 0 qC)-
Airbill No.:
If site-specific QC(MS/MSD/Dup)required, indicate QC samples and Relinq hed +y Commercial Carder:
submit tri•licate volume. UPS FedEx Other Temperature upon receipt Q 'C
Eurofins Lancaster Laboratories Environmental•2425 New Holland Pike,Lancaster,PA 17601 •717-656-2300 Issued by Dept.40 Management
Page 12 of 13 7045.01
I M - - w ■■■ MN - - M M M MI M X M MI N IIIIIII

I
0 eurofins
I mentl Laboratories Explanation of Symbols and Abbreviations
The following defines common symbols and abbreviations used in reporting technical data:
I
RL Reporting Limit BMQL Below Minimum Quantitation Level
N.D. none detected MPN Most Probable Number
TNTC Too Numerous To Count CP Units cobalt-chloroplatinate units
IU International Units NTU nephelometric turbidity units
I umhos/cm micromhos/cm ng nanogram(s)
C degrees Celsius F degrees Fahrenheit
meq milliequivalents lb. pound(s)
g gram(s) kg kilogram(s)
I
Ng microgram(s) mg milligram(s)
mL milliliter(s) L liter(s)
m3 cubic meter(s) pL microliter(s)
pg/L picogram/liter
I
< less than-The number following the sign is the limit of quantitation,the smallest amount of analyte which can be
reliably determined using this specific test.
> greater than
I
ppm parts per million-One ppm is equivalent to one milligram per kilogram(mg/kg),or one gram per million grams. For
aqueous liquids,ppm is usually taken to be equivalent to milligrams per liter(mg/I),because one liter of water has a
weight very close to a kilogram. For gases or vapors,one ppm is equivalent to one microliter per liter of gas.
I ppb parts per billion
Dry weight Results printed under this heading have been adjusted for moisture content. This increases the analyte weight
basis concentration to approximate the value present in a similar sample without moisture. All other results are reported
on an as-received basis.
Data Qualifiers:
C—result confirmed by reanalysis.
J-estimated value—The result is z the Method Detection Limit(MDL)and<the Limit of Quantitation(LOQ).
IU.S. EPA CLP Data Qualifiers:
Organic Qualifiers Inorganic Qualifiers
A TIC is a possible aldol-condensation product B Value is<CRDL,but ZIDL
I B Analyte was also detected in the blank E Estimated due to interference
C Pesticide result confirmed by GC/MS M Duplicate injection precision not met
D Compound quantitated on a diluted sample N Spike sample not within control limits
E Concentration exceeds the calibration range of S Method of standard additions(MSA)used
I the instrument for calculation
N Presumptive evidence of a compound(TICs only) U Compound was not detected
P Concentration difference between primary and W Post digestion spike out of control limits
confirmation columns>25% * Duplicate analysis not within control limits
IU Compound was not detected + Correlation coefficient for MSA<0.995
X,Y,Z Defined in case narrative
Analytical test results meet all requirements of NELAC unless otherwise noted under the individual analysis.
Measurement uncertainty values,as applicable,are available upon request.
ITests results relate only to the sample tested. Clients should be aware that a critical step in a chemical or microbiological
analysis is the collection of the sample. Unless the sample analyzed is truly representative of the bulk of material involved,the
test results will be meaningless. If you have questions regarding the proper techniques of collecting samples, please contact
I us. We cannot be held responsible for sample integrity, however,unless sampling has been performed by a member of our
staff. This report shall not be reproduced except in full,without the written approval of the laboratory.
Times are local to the area of activity. Parameters listed in the 40 CFR part 136 Table II as"analyze immediately"are not
performed within 15 minutes.
I
WARRANTY AND LIMITS OF LIABILITY-In accepting analytical work,we warrant the accuracy of test results for the sample as submitted. THE
FOREGOING EXPRESS WARRANTY IS EXCLUSIVE AND IS GIVEN IN LIEU OF ALL OTHER WARRANTIES,EXPRESSED OR IMPLIED. WE DISCLAIM
ANY OTHER WARRANTIES,EXPRESSED OR IMPLIED,INCLUDING A WARRANTY OF FITNESS FOR PARTICULAR PURPOSE AND WARRANTY OF
MERCHANTABILITY. IN NO EVENT SHALL EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL,LLC BE LIABLE FOR INDIRECT,SPECIAL,
ICONSEQUENTIAL,OR INCIDENTAL DAMAGES INCLUDING,BUT NOT LIMITED TO,DAMAGES FOR LOSS OF PROFIT OR GOODWILL REGARDLESS
OF(A)THE NEGLIGENCE(EITHER SOLE OR CONCURRENT)OF EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL AND(B)WHETHER
EUROFINS LANCASTER LABORATORIES ENVIRONMENTAL HAS BEEN INFORMED OF THE POSSIBILITY OF SUCH DAMAGES. We accept no legal
responsibility for the purposes for which the dient uses the test results. No purchase order or other order for work shall be accepted by Eurofins Lancaster
Laboratories Environmental which includes any conditions that vary from the Standard Terms and Conditions,and Eurofins Lancaster Laboratories
IEnvironmental hereby objects to any conflicting terms contained in any acceptance or order submitted by client
Pages130701313
I

I
I i 0
I
I
I
I
I
I
I
N
I
I
I
I
I
1•
1
1 0
1

1
o �

i
i
FYZ
,_: Ammonia Reduction
1 �� _ � r Evaluation
} Il6��1 FINAL DRAFT
Metropolitan Sewerage District of Buncombe County
1
April 8, 2015
1
1
1
1
1
1
1
1
1

I
Metropolitan Sewerage District of Buncombe CountyI ility PlaUpda ���
TABLE OF CONTENTS
te
TABLE OF CONTENTS
I
1.0 INTRODUCTION 1
2.0 EXISTING TREATMENT FACILITIES 3 I 3.0 EXISTING TREATMENT REQUIREMENTS AND SUMMARY OF CURRENT EFFLUENT
PERFORMANCE 6
3.1. Existing National Pollutant Discharge Elimination System (NPDES) Discharge Limits 6
I
3.2. Summary of Existing Treatment Performance 7
3.3. Quarterly Chronic Toxicity Performance 11
I
3.4. Ammonia Water Quality Data 11
4.0 EVALUATION OF EXISTING AMMONIA REMOVAL PERFORMANCE 13
I
4.1. Ammonia Study 13
4.2. Supplemental Sampling 14 I 4.3. Evaluation of Nitrification Capacity of RBC Process 22
4.4. Challenges in Achieving Additional Ammonia Reduction 22
4.4.1. Out of Service RBCs 22 I
4.4.2. Poor Grit Removal 23
4.4.3. Wet Weather Flow 23
I
4.4.4. High Loads to RBC process 24
4.4.5. Low Influent Alkalinity 25
I
4.5. Recommended Short Term Improvements 25
4.5.1. Replacement of Broken RBCs 25
I
4.5.2. Grit Removal Improvements 25
4.5.3. Equalization for Wet Weather Flow Management 26 I 4.5.4. Primary Treatment 26
5.0 OPTIMIZATION OF EXISTING TREATMENT SYSTEM 27 I 5.1. RBC Replacement and Optimization Program 27
5.2. Monitoring Program 29
6.0 EVALUATION OF BIOLOGICAL TREATMENT UPGRADES TO MEET NUMERICAL
I
AMMONIA REDUCTION TARGETS 30
6.1. Overview of Biological Treatment Upgrade Strategy 30
I
6.2. Approach for Evaluating Biological Treatment Upgrades 30
6.2.1. Biological Treatment Influent Flows and Loads 31 I 6.2.2. Effluent Objectives 34
1

Metropolitan Sewerage District of Buncombe County I Facility Plan Update
TABLE OF CONTENTS
6.2.3. Identification and Evaluation of Biological Treatment Alternatives 34
' 6.3. Conceptual Development of Long-Term Biological Treatment Alternatives 38
6.4. Cost Estimates for Long-Term Biological Treatment Upgrades 38
' 7.0 SUMMARY OF FINDINGS AND CONCLUSIONS 40
' List of Tables
Table 3-1: Summary of French Broad River WRF Existing NPDES Discharge Limits(NC
' 0024911) 6
Table 3-2: Summary of French Broad River WRF Quarterly Chronic Toxicity Results for 2011 —
May 2014 11
' Table 4-1: Summary of Ammonia Study Data for Treatment Process Performance 16
Table 4-2: Operational RBCs during Ammonia Study 16
Table 4-3: Summary of Supplemental Sampling Program Results(Averages of Five Samples
Collected 4/28/14—5/9/14) 17
Table 4-4: Summary of Supplemental Sampling Program Results(Averages of Five Samples
Collected 4/28/14—5/9/14, Excluding Outliers) 18
' Table 5-1: Actual and Estimated Costs for RBC Optimization 28
Table 5-2: Estimated Capital Costs(2014 dollars)for Phased Initial Improvements 29
Table 6-1: Baseline Flows and Loads Based on Historic Data Review 31
' Table 6-2: Summary of Wastewater Loads and Concentrations at 40 mgd permitted Capacity
(Year 2042) 32
Table 6-3: Primary Effluent Estimates at 40 mgd Permitted Capacity(Year 2042)with
Chemically Enhanced High Rate Primary Clarifiers Optimized for TSS Removal 33
Table 6-4: Summary Biological Treatment Alternatives Considered 35
Table 6-5: Feasible Alternatives for Meeting Ammonia Reduction Targets 37
' Table 6-6: Estimated Capital Costs(2014 dollars)for Biological Alternatives 39
Table A-1: Summary of Existing Unit Processes and Major Equipment at French Broad River
WRF 43
' Table A-2: Operational Status of RBCs as of April 2015 46
1
1
1
If

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update loin
TABLE OF CONTENTS
I
Table of Figures
Figure 2-1: French Broad River WRF- Existing Treatment Facility Process Flow Diagram 5
I
Figure 3-1: 30-Day Running Average Effluent CBOD Performance for 2009 through 2014 8
Figure 3-2: 30-Day Running Average Effluent TSS Performance for 2009 through 2014 8 I Figure 3-3: 30-Day Average Effluent NH3-N Performance for 2009 through 2014 Compared to
Monthly Average Targets for Ammonia Reduction Evaluation 9
Figure 3-4: 7-Day Average Effluent NH3-N Performance for 2009 through 2014 Compared to I Targets for Ammonia Reduction Evaluation 10
Figure 4-1: Ammonia Study Treatment Process Profile 19
Figure 4-2: Ammonia Study Intermediate Clarifier Effluent Nitrate+ Nitrite- Nitrogen for Each I Sampling Campaign 20
Figure 4-3: Ammonia Study Treatment Process Alkalinity Profile 20
Figure 4-4: Ammonia Study Treatment Process Profile 21 I Figure 4-5: 2008 through 2013 Effluent Flows and Rainfall 24
Appendices
I
APPENDIX A- SUMMARY OF EXISTING UNIT PROCESSES AND OPERATIONAL STATUS
OF RBCs
1
I
I
I
I
I
I
I
I
ill I

f
Metropolitan Sewerage District of Buncombe County I Facility Plan Update
' INTRODUCTION
1 .0 INTRODUCTION
The Metropolitan Sewerage District(MSD) of Buncombe County's French Broad River Water
' Reclamation Facility(hereafter referred to as French Broad River WRF)was placed into service
in 1967 with a capacity of 25 million gallons per day(mgd). Originally an activated sludge
facility, the biological treatment process was converted to Rotating Biological Contactors(RBCs)
in 1988 as part of a federal government initiative to promote"innovative technology". The RBCs
were retrofitted into existing primary and secondary clarifier basins, and activated sludge
aeration tanks. In the same footprint, the 25 mgd activated sludge plant was expanded to 40
' mgd using RBC technology.
Major treatment processes at the French Broad River WRF include Screening, Grit and Grease
• Removal, Biological Treatment via seven-stage RBCs, Intermediate Clarification, Cloth Media
Filtration, Chlorine Disinfection, Dechlorination, Gravity Thickening, Belt Filter Press
Dewatering, and Fluidized Bed Sludge Incineration. Treated effluent is discharged to the French
Broad River.
111
The French Broad River WRF was designed based on meeting secondary treatment
requirements(monthly average CBOD5 and TSS concentrations of 25 and 30 mg/L,
' respectively). The exiting French Broad River WRF NPDES permit(NC0024911) does not
include numerical discharge limits for ammonia-nitrogen (NH3-N). Compliance with NCDENR's
current ammonia policy is achieved through quarterly chronic toxicity monitoring.
As part of the French Broad River WRF 2011 NPDES permit renewal, Special Condition A. (7)
was added to the permit, which requires the French Broad River WRF to complete and submit
an Ammonia Reduction Evaluation to DWR within 4.5 years of the permit effective date of April
1, 2011. The evaluation shall consider the feasibility and cost for optimizing ammonia removal at
the current plant via operational improvements, and upgrading the plant to meet summer NH3-N
limits of 6.9 mg/L(monthly average) and 20.7 mg/L (weekly average), and winter limits of 17
mg/L(monthly average) and 35 mg/L(weekly average). Summer is defined as April 1 through
October 31. The study also includes monitoring of 36 monthly in-stream ammonia samples
collected approximately 3,000 feet downstream from the discharge.
This report documents findings from the Ammonia Reduction Evaluation completed to meet the
requirements of Special Condition A. (7) of the 2011 NPDES permit. This report presents an
evaluation of existing treatment plant performance data, including intensive intra-process data
collected by MSD specifically for the Ammonia Reduction Evaluation. In addition, this report
presents findings from an evaluation of the feasibility and cost of improvements for optimizing
ammonia removal via operational improvements and implementing upgrades to meet summer
NH3-N limits of 6.9 mg/L(monthly average) and 20.7 mg/L(weekly average), and winter limits of
17 mg/L(monthly average) and 35 mg/L(weekly average).
1
I

I
Metropolitan Serage District of Buncombe County I Facility Plan Update
EXISTING TREATMENT REQUIREMENTS AND SUMMARY OF CURRENT EFFLUENT PERFORMANCE
3.0 EXISTING TREATMENT
REQUIREMENTS AND SUMMARY OF
CURRENT EFFLUENT PERFORMANCE
3.1. Existing National Pollutant Discharge Elimination I
System (NPDES) Discharge Limits
The existing NPDES discharge limits for the French Broad River WRF, established under ,
NPDES Permit NC 0024911, are summarized in Table 3-1. The existing NPDES permit was
issued on February 25, 2011, became effective on April 1, 2011, and expires on December 31,
2015.
Table 3-1: Summary of French Broad River WRF Existing NPDES Discharge Limits(NC 0024911)
Parameter Monthly Average Weekly Average Daily Maximum '
Limit Limit Limit
Flow 40.0 mgd
CBOD51 25.0 mg/L 40.0 mg/L
TSS1 30.0 mg/L 45.0 mg/L
D.O. Daily Average > 5.0 mg/L
Fecal Coliform 200/100 ml 400/100 ml
Total Residual Chlorine 28 pg/L
pH Between 6.0 and 9.0 Standard Units
Chronic Toxicity Pass Quarterly Pass/Fail Chronic Toxicity test with Ceriodaphnia
at 12%waste concentration
'Monthly average removal of 85%of influent CBOD and TSS also required.
2Must also collect upstream and downstream in-stream fecal coliform grab samples three times per week during
June,July,August,and September,and once per week the remaining months of the year.
The current NPDES permit does not include discharge limits for ammonia-nitrogen (NH3-N),
total nitrogen (TN), and total phosphorus(TP) but does require daily monitoring for effluent NH3-
N and quarterly monitoring for effluent TN and TP. The current NPDES permit includes quarterly
chronic toxicity whole effluent toxicity monitoring using Ceriodaphnia as the test organism at
12%waste concentration. DWR's 1999 Ammonia Toxicity Policy allows permit holders for 1
existing flows to have the option to have ammonia limit(s) or to have quarterly chronic, WET
test, pass/fail at the instream waste concentration using Ceriodaphnia as the test organism or
an effluent ammonia-limit. ,
The current NPDES permit also includes a new Special Condition, A.(7.), entitled"Ammonia
Reduction Evaluation". This Special Condition requires MSD to complete and submit an '
Ammonia Reduction Evaluation to DWR within 4.5 years of the permit effective date of April 1,
2011, as described previously in Section 1.0.
111
6
I

I
EXISTING TREATMENT REQUIREMENTS AND Metropolitan Sewerage
UMMARY OF CU RENT EFFLUENT PERFORMANCE FyZ
County I Facility Plan Update
1
3.2. Summary of Existing Treatment Performance
The French Broad River WRF produces an effluent quality that routinely meets or performs
better than the current NPDES discharge limits. 30-day running average and calendar month
I average effluent CBOD concentration and percent removal results for 2009 through 2014 is
illustrated in Figure 3-1. Effluent CBOD is typically between 10 and 20 mg/L and removals
typically range from 85 to 95%with the lower removals occurring during wet-weather periods
Iwhen influent concentrations are diluted by wet-weather flows.
Similar data for effluent TSS is presented in Figure 3-2. Effluent TSS is typically 15 to 30 mg/L
I through September 2012 when the Cloth Media Filters were put into service. Effluent TSS has
ranged from 8 to 10 mg/L since the filters were brought online.TSS removal was 80 to 93%
prior to the filters and has been 90 to 97%since the filters were brought online.
I30-day running average and calendar month average effluent NH3-N concentration results for
2009 through 2014 is illustrated in Figure 3-3. Seven-day running average and calendar week
average effluent NH3-N performance over the same time period is illustrated in Figure 3-4.
I
Effluent NH3-N averaged 15.7 mg/L over this time period. Average effluent NH3-N
concentrations were similar during summer(April—October) and winter(November—March)
operation.I
As illustrated in Figure 3-3, between 2009 and 2014, the existing treatment process was not
achieving the summer(6.9 mg/L) or the winter(17 mg/L) monthly average effluent NH3-N
I targets identified for the Ammonia Reduction Evaluation. Figure 3-4 illustrates that the existing
treatment process currently meets the winter weekly average NH3-N target(35 mg/L) identified
in the Ammonia Reduction Evaluation, but does not meet the summer weekly average NH3-N
Itarget(20.7 mg/L).
I
I
I
I
I
I
1
I

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update En
EXISTING TREATMENT REQUIREMENTS AND SUMMARY OF CURRENT EFFLUENT PERFORMANCE
I
100 100%
I
90 90%
80 80%
1
70 70%
I60 60%
To
p o.
-30-Day Running Avg Effluent CBOD
co u 50 50% I
• Calendar Month Avg Effluent CBOD ce
G
3 40 .30-Day Rurnring Avg CBOD Reniuval 40%ig m
v
•30 Calendar Month Avg CBOD Removal 30%
I
20 20%
10 10% I
0 , 0% I 1/1/2009 1/1/2010 1/1/2011 1/1/2012 1/1/2013 1/1/2014 1/1/2015
Figure 3-1: 30-Day Running Average Effluent CBOD Performance for 2009 through 2014
100 100% 1
90 ♦ ♦ A 90%
I
80 80%
70 - 70%
1
60 30-Day Running Avg Effluent TSS 60%
E • Calendar Month Avg Effluent TSS i
I
5030-Day Running Avg TSS Removal 50% °
r m
C ♦ Calendar Month Avg TSS Removal °C
i40 40% II I
W
30 30%
20 20%
1
10 10%
1
1/1/2009 1/1/2010 1/1/2011 1/1/2012 1/1/2013 1/1/2014 1/1/2015
Figure 3-2: 30-Day Running Average Effluent TSS Performance for 2009 through 2014 1
III
8
I

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update FyZ
I
EXISTING TREATMENT REQUIREMENTS AND SUMMARY OF CURRENT EFFLUENT PERFORMANCE r
I 30
17.0 mg/L Monthly Ave Effluent NH3-N Winter
111Target for Ammonia Reduction Evaluation
25
1
I
ilk
20 !
1 .,
15
•••• , J1V /
1 a
0 10
1 0
„,
A6.9 mg/L Monthly Ave Effluent NH3 N Summer Target
for Ammonia Reduction Evaluation
I .•30-Day Running Avg-Winter •30-Day Running Avg-Summer Calendar Month Averages
0
1/1/2009 1/1/2010 1/1/2011 1/1/2012 1/1/2013 1/1/2014 1/1/2015
I Figure 3-3: 30-Day Average Effluent NH3-N Performance for 2009 through 2014 Compared to Monthly
Average Targets for Ammonia Reduction Evaluation
I
I
I
I
1
I
9
i

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update FyZ
EXISTING TREATMENT REQUIREMENTS AND SUMMARY OF CURRENT EFFLUENT PERFORMANCE r I
35 — a a. --a_a_ - 11i
35.0 mg/L Weekly Ave Effluent NH3 N Winter
Target for Ammonia Reduction Evaluation
30 — ! 1
25 20.7 mg/tw eklyAve-Effluent IP.` 1, I
Ammonia-N Summer Target for • •
m Ammonia Reduction Evaluation i 9 $�
l: 1
so, _ z_ .
i ::
%
II
$ — X k 111 .. II V
CU I
12 _ i.s • • 1
•
>. 10 ♦ '
co
I $ . .
5 ■♦
I
0 I 1 f I I
1/1/09 1/1/10 1/1/11 1/1/12 1/1/13 1/1/14 1/1/15
I
•7-Day Running Avg-Winter ■7-Day Running Avg-Summer A Calendar Week Averages
Figure 3-4: 7-Day Average Effluent NH3-N Performance for 2009 through 2014 Compared to Targets for '
Ammonia Reduction Evaluation
I
1
I
1
I
1
10
I

I
Metropolitan
County I Facility Plan Updats
EXISTING TREATMENT REQUIREMENTS AND SUMMARY OF CU RENT EFFLUENT PERFORMANCE Imn
I 3.3. Quarterly Chronic Toxicity Performance
Quarterly chronic toxicity test results for pass/fail tests completed with Cetiodaphnia from
February 2011 through May 2014 are summarized in Table 3-2. The NPDES permit requires a
I passing value at 12%waste concentration. The French Broad River WRF effluent consistently
complied with the quarterly chronic toxicity requirement. In addition, the chronic value is typically
greater than 36%. Passing results for chronic toxicity indicates no ammonia toxicity.
ITable 3-2: Summary of French Broad River WRF Quarterly Chronic Toxicity Results for 2011—May 2014
Sample Chronic LOEC NOEC
I Collection Value
Date
Nov-14
I Sept-14
May-14 >36% >36% >36%
Feb-14 >36% >36% j >36%
I Nov-13 29.4% 36% 24%
Aug-13 >36% >36% >36%
May-13 >36% >36% j >36%
I Feb-13 >36% >36% >36%
Nov-12 >36% I >36% >36%
Aug-12 >36% >36% >36%
IMay-12 >36% >36% >36%
Feb-12 >36% >36% >36%
Jan-12 >36% >36% >36%
IDec-11 >36% >36% >36%
Nov-11 10.4% 12% 9%
Aug-11 >36% >36% >36%
I
May-11 >36% >36% >36%
Feb-11 ! >36% >36% i >36%
I
3.4. Ammonia Water Quality Data
I As part of the preparation for the Ammonia Reduction Evaluation, MSD collected monthly in-
stream ammonia samples between April 2011 and May 2014, as well as during three week-long
intensive sampling campaigns in November 2011, February 2012, and August 2012. In addition
I to monthly samples, daily in-stream samples were also collected during the three one-week
intensive sample campaigns. Throughout the testing period, in-stream ammonia samples were
collected 3,000 feet down stream of the discharge, which is the monitoring point required per
I the NPDES Permit Special Condition. The ammonia water quality data collected between April
2011 and May 2014 is summarized in Table 3-3.
1
I
vi1

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update 14Z
EXISTING TREATMENT REQUIREMENTS AND SUMMARY OF CURRENT EFFLUENT PERFORMANCE
Table 3-3: Summary of NH3-N Water Quality Data Collected For Ammonia Reduction Evaluation
Date Downstream River Date Downstream River I
Sample(3,000 ft Sample(3,000-ft
downstream) downstream)
4/14/2011 0.69 8/10/2012 1 0.40
I
5/25/2011 0.65 8/11/2012 0.21
6/8/2011 j 0.65 8/12/2012 0.34
7/19/2011 0.46 9/14/2012 0.66
I
8/16/2011 0.40 10/12/2012 0.50
9/15/2011 1.30 11/8/2012 0.53
10/13/2011 0.48 12/13/2012 1 0.20
I
11/7/2011 2.60 1/8/2013 0.59
11/8/2011 0.72 2/13/2013 0.35
11/9/2011 0.80 3/18/2013 0.35
I
11/10/2011 0.83 4/11/2013 0.42
11/11/2011 0.74 5/14/2013 0.44
11/12/2011 0.53 6/19/2013 0.32
I
11/13/2011 0.49 7/19/2013 0.32
12/9/2011 0.45 8/9/2013 0.42
1/6/2012 0.43 9/10/2013 0.59
I
2/6/2012 0.50 10/2/2013 1.10
2/7/2012 0.50 11/11/2013 2.00
2/8/2012 0.43 12/4/2013 1.50
I
2/9/2012 0.47 1/16/2014 0.22
2/10/2012 0.61 2/19/2014 1 0.44
2/11/2012 1.20 3/24/2014 1.00
I
2/12/2012 ' 0.57 4/25/2014 0.53
3/12/2012 0.44 5/13/2014 0.53
4/17/2012 0.61 6/26/2014 0.66
I
5/21/2012 0.29 7/22/2014 0.44
6/8/2012 I 0.56 8/262014 0.73
7/6/2012 0.62 9/22/2014 0.60
I
8/6/2012 0.61 10/9/2014 0.69
8/7/2012 0.39 11/4/2014 0.67
8/8/2012 0.61 12/1/2014 j 0.78 '
8/9/2012 0.50
I
I
I
1
12

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update 11.01Z
I
EVALUATION OF EXISTING AMMONIA REMOVAL PERFORMANCE
1 4.0 EVALUATION OF EXISTING AMMONIA
REMOVAL PERFORMANCE
I MSD completed several intensive sampling campaigns between 2011 and 2014 to collect
additional wastewater characterization data and to estimate unit process treatment
performance. One of the primary goals was to document nitrification in the existing RBC
Iprocess. The following sections summarize findings from the supplemental sampling program.
4.1. Ammonia Study
IThe results of the intra-process sampling and the significant plant return streams(gravity
thickener overflow, incinerator return and ash lagoon overflow) are summarized in Table 4-1.
I These are averages of all the data produced during the special sampling program.
The data shown in Figure 4-1 presents BOD, NH3-N and nitrite plus nitrate-nitrogen profiles
through the treatment process. The top panel shows the fate of total and soluble BOD. Total
1 BOD is reduced through the RBCS, intermediate clarifier and finally through the cloth media
filters. Soluble BOD is primarily removed in RBC Basins 1 and 2 (Stages 1 through 5)to below
20 mg/L. RBC's will nitrify once soluble BOD is reduced to 15 to 20 mg/L. The middle panel of
I Figure 4-1 shows ammonia-nitrogen and TKN reductions occurring in RBC Basins 2 and 3
which occurs after soluble BOD is reduced to below 20 mg/L. The observed NH3-N reductions
are occurring because of nitrification in the latter RBC stages. This is confirmed in the bottom
Ipanel of Figure 4-1 which shows the production of approximately 5 mg/L of nitrate plus nitrite
nitrogen. This low level of nitrification occurs in the three sampling campaigns as shown in
Figure 4-2; however consistent nitrification performance cannot be assumed because the RBCs
Iare not designed for nitrification in any kind of predictable way and the level of nitrification
achieved in the existing system is not readily controllable and expected to be inconsistent in the
existing treatment system.I
A consequence of nitrification is a reduction in alkalinity which is shown in Figure 4-3. There is a
35 mg/L decrease in alkalinity in response to the production of 5.5 mg/L of nitrite plus nitrate
I nitrogen. This translates to 6.4 mg of alkalinity consumed per mg of nitrite plus nitrate nitrogen
produced which is close to the stoichiometric requirement of 7.14 mg of alkalinity consumed per
mg of nitrite plus nitrate nitrogen produced. The influent alkalinity was more than sufficient to
I accommodate nitrification achieved and was not limiting. The RBC pH was also within a
favorable range(between 7.3 and 7.5 su)for nitrification.
I Based on process ammonia data collected within the treatment process as part of the intensive
sampling campaigns, it is estimated that approximately 5 mg/L of NH3-N was nitrified in the
existing RBC process during those sampling campaigns. An additional 11 to 13 mg/L of influent
I nitrogen is removed through the treatment process. The additional nitrogen removal is primarily
attributed to biological assimilation of nutrients that occurs in the RBC process as a result of
biological oxidation of organics(i.e., removal of CBOD5). A small fraction of the nitrogen removal
I is likely attributed to particulate nitrogen removal removed through sedimentation and/or
adsorption to biomass in the RBCs.
1
13

1
District of Buncombe County I Facility Plan Update
Metropolitan
EVALUA ON OF EXISTING AMMONIA RE OVAL PERFORMANCE limn
1
The intra-process sampling data was used to estimate BOD and ammonia removal rates in the
RBC process. Unit removal rates were estimated based on operational RBC surface area at the
I
time of sampling. At the time of sampling, a total of 36 of the 152 units were inoperable,
removed, or had broken shafts that were not turning. The number of RBCs operational during
the time of the testing is summarized in Table 4-2. The observed removal rates are in
I
agreement with removal rates published in Wastewater Engineering Treatment and Reuse
(Metcalf and Eddy, Inc., 4th Edition, 2004, Table 9-8, pg 933).
4.2. Supplemental Sampling I
In addition to the Ammonia Study described above, additional supplemental sampling was '
completed in 2014 to capture additional information needed to support the Ammonia Reduction
Evaluation. The supplemental sampling program provided the following:
• Additional influent wastewater characterization data needed for process analysis.
I
• Expanded parameter list including volatile suspended solids, filtered TKN,
phosphorus and COD including floc filtered COD(ff-COD).
• Additional plant return sampling to characterize return loads.
I
Five sets of samples were collected between April 28, 2014 and May 9, 2014. The results of the
supplemental sampling data are summarized in Table 4-3. These are averages of all the data
produced during this sampling program. There were several abnormally high concentrations
noted during the sampling period. For example, on May 9, 2014, high recycle loads were noted
in the belt filter press filtrate and in the gravity thickener overflow. In addition, on April 28, 2014,
the influent TSS concentration was well above average. Averages were also estimated
excluding outlier data and are presented in Table 4-4. Considering variable conditions
encountered and limited time period for the supplemental sampling, prediction of future
I
performance cannot be made accurately.
The data shown in Figure 4-4 shows BOD, NH3-N and nitrite plus nitrate-nitrogen profiles
through the treatment process during the supplemental sampling. RBC performance during the
I
supplemental sampling was lower in comparison to during the Ammonia Study. The lower
treatment performance is likely attributed to the lower number of operational RBCs during the
Supplemental Sampling. MSD was completing gate replacement during the supplemental
I
sampling and had several basin trains out of service during the testing. On April 28, 2014,
Basins 2 and 3 of Train 3 were out of service. Between May 6 and May 9, 2014, Basins 2 and 3
of Train 4 were out of service. As a result, the operational surface area was approximately 20 1
percent lower in comparison to during the Ammonia Study.
As shown in the top panel of Figure 4-4, soluble BOD removal achieved in RBCs 1 and 2 is
I
lower in comparison to during Ammonia Study. This would be expected with the lower operating
RBC surface area. The observed SBOD removal rate based on the actual operating RBC was
slightly lower, but similar to the rate observed during the ammonia study. 1
As shown in the middle panel of Figure 4-1, lower ammonia-nitrogen and TKN reduction
occurred during the supplemental testing compared to the Ammonia Study. Nitrate plus nitrite
nitrogen production averaged approximately 2 mg/L during this testing. The observed
1
14
I

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update Imen
I
EVALUATION OF EXISTING AMMONIA REMOVAL PERFORMANCE
nitrification rate at the time of testing was lower in comparison to observed nitrification rates
Iduring the Ammonia Study. The lower ammonia removal rates are likely attributed to higher
soluble BOD concentrations in Basins 2 and 3 and lower operating RBC surface area in Basin 3
with a train out of service during each of the testing days. The lower ammonia removal rates
Imay also be partially attributed to Train 3 being out of service just prior to the testing which
would have had an adverse impact on the population of nitrifiers there.
I
In summary, the differences in ammonia removal performance between the Ammonia Study and
the Supplemental Sampling illustrate how increasing the number of RBCs in service improves
treatment performance by achieving lower soluble BOD concentrations earlier in the RBC
I process and provides additional surface area for nitrification to potentially occur in the
downstream RBCs. This conclusion makes technical sense and is consistent with the evaluation
of the data available. Improving ammonia reduction is something that will undoubtedly occur
Iwith a higher level of RBCs in operation; however prediction of future reliable performance
cannot be made accurately.
I
I
I
I
I
I
I
I
I
I
I
15

of Buncombe
ounty
MetropolitanEVALUATION OF EXISTING AMMONIAC RE OVAL PERFORMANCE EN
Table 4-1: Summary of Ammonia Study Data for Treatment Process Performance
Nitrogen Phosphorus
Process S-BOD i C-BOD TSS NH3-N TKN Nitrite+ Total Organic Total Ortho Organic MBAS pH j pH 1 Alkalinity
Nitrate- Grab 1 Comp
Headworks inf 66 168 200 22 40 0.18 40 17 5.5 2.6 2.8 1.97 7.07 6.98 j 180
Plant Influent 51 163 199 22 j 37 0.19 37 16 5.6 2.7 2.9 1.84 7.10 7.16 180
Primary Microscreen 62 161 207 22 38 0.18 38 16 6.0 2.9 3.1 1.77 7.06 7.09 183
Effluent
RBC1 Effluent 22 ! 144 209 20 37 0.18 37 j 16 5.9 2.6 3.3 1.20 7.32 7.38 177
RBC2 Effluent 8 67 179 21 34 1.33 35 13 6.1 3.6 2.5 0.30 7.36 7.48 149
RBC3 Effluent 7 58 171 17 30 5.49 35 ; 13 6.0 3.3 2.6 0.26 7.36 ' 7.51 142
Clarifier Effluent i 8 13 23 17 22 5.27 27 4 4.1 3.4 0.7 0.28 7.42 7.57 135
Filter Effluent 8 ! 13 21 17 l 22 5.21 27 E 4 4.1 3.4 0.6 0.24 7.47 7.69 116
Thickener Overflow 9 27 66 I 18 27 0.45 27 9 5.2 3.9 1.2 0.25 7.24 7.41 160
Incinerator Return 1 66 165 210 24 40 3.66 43 16 12.5 7.5 5 0.31 ' 7.23 6.75 135
Lagoon Overflow 3 3 6 27 29 0.17 29 2 6.1 6.2 - 0.26 7.39 7.45 138
Table 42: Operational RBCs during Ammonia Study
Basin No. RBC Number of Total Basin Surface
Stage units Area(ft=)
Operating
1 1 ' 16 4,335,000
1 2 i 18
2 3 12 7,717,500
2 4 23
2 5 21
3 6 14 4,030,000
3 7 ; 12
Total All 116 16,082,500
Basins
16
r N UN r I - MS NI MI MI - MN M M EN N NE I MN

En en N I Ma MI NM NS 11111 WE N On M NM 111111 NM 11111 MS 1
Metropolitan
EVALUATION OF EXISTrage ING AMMONIA of Buncombe CRE OVAL PERFORMANCE
ounty I Facility Flan Update ���
Table 4-3: Summary of Supplemental Sampling Program Results(Averages of Five Samples Collected 4/28/14-5/9/14)
Process T-COD F-COD ffCOD SCOD TCBOD FCBOD TSS VSS TKN FTKN NH3-N NOR-N TP Ortho-P FP Alkalin
-IY
Headworks inf 421 187 46 1 i 160 69 1 206 225 30.7 ' 24.4 19.1 5.4 f 3.0 i 134
Plant Influent 551 178 39 190 72 348 227 33.9 23.6 18.8 7.2 3.3 136
RBC1 Effluent' 438 ; 107 j 30 243 200 ; 21.7 18.3 0.1 139
RBC2 Effluent* 428 75 13 297 226 23.7 20.1 0.2 147
RBC3 Effluent' 300 66 ( j 13 198 152 30.2 ' 20.6 18.1 1.7 6.2 2.9 137
Clarifier Effluent
126 71 19 24 30 25 24.3 ' 22.6 19.1 1.3 3.6 3.1 137
Plant Effluent 110 83 76 18 11 12 17 22.8 22.0 18.6 1.9 3.3 3.0 ; 3.1 134
Thickener
Overflow 276 143 97 37 82 80 33.2 28.4 21.3 ; 6.6 3.9 157
Filter Backwash ** 14.1
6.8 **
880 ! 273 693 696 ! 64.3 I 0.0 158
Scrubber Water 95 83 22 18153 17 22.6 ! 22.7 19.4 13.5 4.9 66
Ash Clarifier !
92 73 21 i 16 238 20 ! 23.4 j 22.8 19.4 20.0 6.3 66
BFP Filtrate 544419 90 50 318 77 47.9 47.8 31.9 32.9 19.7 128
Lagoon Overflow l 33 I 6 ! 0 13 6 29.8 ; , 28.7 { 6.2 ! 5.0 146
*Train IV of RBC Basins No.2 and 3 were out of service during 4/28/14 sampling and Train III of Basins No.2 and 3 were out of service during 5/6/14-5/9/14
sampling.
**Filtered value.
17

ounty
MetropolitanEVALUATION OF EXISTING AMMONIAC RE OVAL PERFORMANCE lion
Table 4-4: Summary of Supplemental Sampling Program Results(Averages of Five Samples Collected 4/28/14-5/9/14,Excluding Outliers)
Process T-COD F-COD ffCOD SCOD TCBOD FCBOD TSS VSS TKN FTKN NH3-N NO:- TP Ortho FP Alkalinity
N -P
Headworks int 474 187 46 j 195 56 215 178 30.7 24.4 19.1 5.4 ; 3.0 134
Plant Influent
480 178 49 190 48 224 189 31.2 23.6 18.8 ! 6.6 3.3 136
RBC1 Effluent* 438 107 30 254 219 21.7 18.3 0.1 j 139
RBC2 Effluent* 428 75 13 272 235 23.7 20.1 0.2 147
RBC3 Effluent*
300 66 13 ! 207 i 176 302 20.6 18.1 1.7 , 6.2 2.9 137
Clarifier Effluent 126 71 19 8 31 28 24.3 22.6 19.1 1.3 3.6 3.1 137
Plant Effluent 110 72 fi9 18 11 14 13 21.3 22.0 18.6 1.9 3.3 3.0 3.1 134
Thickener
Overflow 256 129 65 28 82 80 33.2 28.4 21.3 6.6 3.9 157
Filter Backwash 880 ' I 273 664 595 i 64.3 0.0 6.8** 14.1 158„
Scrubber Water 95 83 22 18 153 17 22.6 22.7 19.4 13.5 4.9 66
Ash Clarifier 92 73 21 i 16 238 20 23.4 22.8 19.4 20.0 6.3 66
BFP Filtrate
90 76 i 13 13 277 18 21.9 22.5 19.2 i 25.6 7.3 60
Lagoon Overflow 41 j 6 0 13 6 29.8 I 28.7 6.2 ! 5.0 146
*Train IV of RBC Basins No.2 and 3 were out of service during 4/28/14 sampling and Train Ill of Basins No.2 and 3 were out of service during 5/6/14-5/9/14
sampling.
**Filtered value.
18

I
Metropolitan District
County I Facility
EVALUATION OF EXISTING AMMONIA REMOVAL PERFORMANCE 1 ��
I 180
160 —6-5BO)
140 fTBOU
I 120
100
o 80
1 0
co 60 .."*"'"''•.....J-4NsN..................„
40
I
20
0
1
40
—6—Ammonia-nitrogen
I 35 1
—1111
30
J
m 25
I E
z 20
~
c 15
I
z 10
m
= 5
z
1 0
I 40
35
O73 30
E 25
Z
00 20
z 15
+
p
I
10
z 5 4------ • •
0 --• • •
I
e'cs
a� ,.`\ oye` Otis C LF C,�F \e�F �zcF
mea Qua \ec �� Q� �� ac• k`
�� O\
I �a
Qc
Figure 4-1: Ammonia Study Treatment Process Profile
I
19

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update 1.)11Z
EVALUATION OF EXISTING AMMONIA REMOVAL PERFORMANCE
I
10.0 I 2 9.0
E 8.0 •
z
7.0I
•
z 6.0 •
N
z 5.0 • I
c • • •
•
3.0 • •
iu
s~ 2.0 I
u 1.0
0.0 1 I I I I I I I I I
ei e-1 a..1 a-1 ‘-i N N N N N N N N N NI
a-i e-i .-1 r-I a--I a-I ei R-l e I e-I I-1 e-I e-1 _l e-1 4--1
O O O O O O O O 0 0 O O 0 0 0 0
N N N N N N - CV
IN
- - N N N N N
\ \ \ \ \ \ \ \ \ \ \
u. N. Ol e-i M VI ll'1 N al e I M U1 N 01 e I M
\ \ \ ei N ei \ \ \ N eti \ \ \ N ei
I e-1 ei ei e\-1 a\-1 e\-1 N N N N N co 00 00 oo co
e-1 e-I e-I
Figure 4-2: Ammonia Study Intermediate Clarifier Effluent Nitrate+Nitrite-Nitrogen for Each Sampling
Campaign
I
200
I
O 180 •--
u 160
m 140
120 - -4F-- I
E 100
80
Z. 60
c 40
To
I
Y 20
Q 0 , ' , , I , , 1
Ieaa� mac`\ `osec OC.> O& 0C''l .e�Q. \`eke.
�. Q ��\` Q Q Q `-6• F�
�a '
.g
Figure 4-3: Ammonia Study Treatment Process Alkalinity Profile
I
I
I
1
20
I

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update FyZ
IEVALUATION OF EXISTING AMMONIA REMOVAL PERFORMANCE
200
I180 ` —�FrRnn
160
—i--FCOD
140
120
1 100
NL'%"%„................................i.
1 m 80
60
40
I 20 - . • .
0 —
1
40.0
—0—Ammonia-nitrogen
35.0 —f—Filtered TKN
1 30.0 • —1—TKN
m 25.0 •
E
I
Z 20.0
Z 15.0
1
10.0
5.0
0.0
40
1 35 •
30
E 25 •
I Z
0 20
? 15 •
N
I
010 '
5 •
0 •
I Cl
L�
IFigure 4-4: Ammonia Study Treatment Process Profile
I
21
I

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update EDIZ
EVALUATION OF EXISTING AMMONIA REMOVAL PERFORMANCE
4.3. Evaluation of Nitrification Capacity of RBC Process
The plant effluent monitoring data and results from the intensive sampling campaigns support I
that the RBC process has been providing effective CBOD removal and achieves a low level of
nitrification at current loadings, even with 36 units out of service during the Ammonia Study. The
results of the 2014 Supplemental Sampling indicate that decreased RBC surface area
negatively impacted nitrification performance. The evaluation clearly shows that RBC
improvement alone cannot achieve the ammonia reduction targets and that even with additional
RBC's in service, it is impossible to predict with accuracy ammonia reduction that would be
achieved in the RBC process.
4.4. Challenges in Achieving Additional Ammonia Reduction
The French Broad River WRF has several existing treatment challenges that impact treatment
performance achieved in the RBC process. These challenges need to be addressed for MSD to
I
recognize improved treatment and additional nitrification in the RBC process. These challenges
include the following:
• Number of RBCs out of service I
• Poor grit removal and accumulation of solids in RBCs
• High loads to RBCs(need for primary treatment)
• Wet Weather Flows
• Low influent alkalinity
• Limited ability to predict and control nitrification
I
The following subsections provide a brief description of each of these challenges.
4.4.1. Out of Service RBCs
I
There are a total of 152 RBCs installed. Many of the original RBC units have failed as the RBCs
are approaching the end of their useful life. As of September 2014, a total of 38 of the 152 units
were inoperable, removed, or had broken shafts that were not turning. These 38 units were
fairly equally divided between the three basins for a total of approximately 25%of the RBCs out
of service per basin. I The number of operational RBCs impacts the total RBC surface area available for biological
treatment. As illustrated by differences in nitrification performance differences between the
Ammonia Study and Supplemental Sampling, treatment performance and nitrification
I
capabilities decrease with less RBCs in service. To maximize nitrification capabilities of the RBC
process, the failed RBCs should be replaced.
In late 2014, MSD replaced 20 of the out of service RBCs with replacement RBCs from other
decommissioned RBC facilities. MSD anticipates replacing most of the broken and damaged
RBCs. Restoration of the RBC process is a transitional upgrade strategy to increase the number ,
of RBCs in service and to achieve as much ammonia reduction as possible without establishing
a specific interim level of specific performance at the French Broad WRF.
1
I
22

I
Metropolitan Sewerage District of Buncombe County Facility Plan Update EVALUATION OF EXISTING AMMONIA RE OVAL PERFORMANCE 11.011Z
' 4.4.2. Poor Grit Removal
Poor grit removal performance has been problematic at the French Broad River WRF,
particularly during wet-weather flow events. In 2008, MSD implemented a grit and grease
' removal upgrade project which included the following improvements:
• Replacement of two existing grit classifier units with three smaller units.
• Replacement of existing grease skimmers with fixed air lance system.
' • Installation of new air blowers.
• Replacement of existing grease screws.
Even with these improvements, pass through of grit continues to be an ongoing operational
issue. Grit performance testing was completed in 2011 by Grit Solutions. The girt performance
testing indicated that a significant portion of grit is not being removed by the Schreiber process
and also that a large portion of previously settled grit is being re-entrained in the wastewater
flow when the grit system is subjected to variable flows.
Poor grit removal and the lack of primary clarification results in collection of solids and grit
' throughout the downstream processes. Grit and solids accumulation in the RBC process has
several negative impacts on the biological treatment process. First, the grit and solids
accumulation reduces retention time in the RBC process. Second, the additional solids increase
' stress on the RBC equipment by increasing RBC operating weights and loads on the shafts.
This can be problematic in leading to shaft and bearing failures. Finally, the additional solids and
grit results in higher organic and solids loading rates to the RBC process. Because nitrification is
not typically achieved in an RBC process until most of the organic load has been oxidized, the
higher loading rates impacts nitrification performance.
Improved grit removal performance is a necessary step to improve existing RBC treatment
performance, as well as to provide an essential treatment step before adding enhanced
biological treatment.
4.4.3. Wet Weather Flow
Another challenge for the French Broad River WRF is high wet weather flow. Between 2009 and
2014, the French Broad River WRF experienced peak day/annual average flow peaking
factors of between 2.6 and 3.5. High peak day flows are attributed to Inflow and Infiltration (Ill)
during wet weather events. Historical effluent flow trends are presented in Figure 4-5. As
illustrated in Figure 4-5, higher peak flows events occurred during wetter years.
High wet weather flows create several challenges to biological treatment processes. One of the
' biggest challenges is increased hydraulic loads to the secondary clarifiers and the potential for
reduced TSS removal efficiency during these periods. Elevated secondary clarifier effluent TSS
can results in a reduction in the biological mass and can result in a washout of the nitrification
process, particularly during winter operations when nitrification growth rates are low.
Fixed film processes, such as the RBC process, are typically more resilient to washout events in
' comparison to suspended growth biological treatment processes since the largest portion of the
microorganisms are attached to the process. However, plant performance data does indicate
that French Broad River WRF performance is impacted during wet weather flows. Poorer
I
23

I
MetropolitanEVALUATION OF EEXISTING AMMONIA REMOVAL PERFORMANCE istrict of Buncombe County I Facility Plan Update 1 ��
1
intermediate clarifier performance is noted during high flow events. In addition, grit removal
performance deteriorates during wet weather event, exacerbating grit accumulation challenges
I
previously discussed in Section 4.4.2.
MSD currently has an extensive and aggressive program for the improvement of its collection
I
system. The CIP for I&I reduction is as expansive as funding will allow and continues to provide
benefits. In addition to the ongoing collection system maintenance program, wet weather flow
management at French Broad River WRF would provide additional benefits in reducing
I
treatment performance impacts during wet weather events.
100 — 100
Daily(MGD)
90 - - 90
7 Day Average(MGD)
I
80 - 80
30 Day Average(MGD)
70 70 �,
0 s al
L
LD 60 — - - r I 60 c
113
LL 50 I I If _ I 50 E
c I I II��- - — r I '°
cc
40 . I• In iI 40 70
`
I I I 1 I I C
30 i / I; ( I I I ' 1 1 , l 30 a
I IfII
is
oh I
20v. Ih .,�, ''UP`1T 'STIP - .� • 20
711H10 I 0 10
1
1/1/2008 1/1/2009 1/1/2010 1/1/2011 1/1/2012 1/1/2013 1/1/2014 I Figure 4-5: 2008 through 2013 Effluent Flows and Rainfall
4.4.4. High Loads to RBC process I
In an RBC process, nitrification does not occur until the majority of the organics have been
oxidized. One of the biggest challenges for the RBCs to achieve additional nitrification
I
performance is the high unit organic loads to the RBC process which limits potential for
improved nitrification achieved in Basin 2 as illustrated by the evaluation of the Ammonia Study
and Supplemental Sampling data.
I
The French Broad River WRF does not currently have a primary clarification process to reduce
influent loads to the RBC process. The lack of primary clarifiers has led to solids accumulation
I
in the RBCs which contributes to excessive biofilm growth and shaft failures. Any future
stabilization of the existing RBC process or upgrade to an alternative biological treatment
process should consider primary clarification to manage the loads to biological treatment.
I
I
24

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update 01
IEVALUATION OF EXISTING AMMONIA REMOVAL PERFORMANCE
I
The current average influent total CBOD is approximately 180 mg/L while the soluble BOD is
approximately 55 mg/L. This indicates a high particulate CBOD component and suggests that
primary treatment could provide an effective means of load reduction to the biological treatment
I process. Primary clarification will also extend the useful life of the RBCs and could potentially
improve their ability to nitrify.
4.4.5. Low Influent Alkalinity
1 The current influent alkalinity load is more than sufficient to support the current levels of
nitrification that are achieved in the RBC process. Alkalinity will potentially be deficient in the
future depending on the degree of nitrification. The optimum pH for nitrification is pH 7.5 to 8.
1
For these reasons, alkalinity addition may be needed to support ammonia removal reductions.
4.4.6. Limited Ability to Predict and Control Nitrification
I
The existing RBC process was not designed for nitrification, therefore the design RBC surface
area is based on organics removal and not nitrification. Unlike an activated sludge process,the
solids retention time(SRT) of an RBC process is not controlled. There are limited operational
I
process control parameters that can be made to improve nitrification performance in the existing
RBC process. The degree of nitrification performance achieved is a function of the organic load
to the RBC process and at what point within the RBC process the CBOD is sufficiently low to
I
support nitrification. The influent load to the RBC process is based on the influent load
variability, which is also not controllable. These factors make it difficult to predict and control the
level of nitrification in the existing RBC process.
I4.5. Recommended Initial Improvements
Improvements are necessary at the French Broad River WRF to address existing treatment
I
challenges described in Section 4.4 to improve existing treatment performance and nitrification
capabilities. The following subsections describe the improvements and anticipated costs for the
short-term (within 10 years) improvement elements. The recommended initial improvements
I
are the"highest priority actions" based on the evaluations performed and the most effective way
to prepare the facility for the successful implementation of longer term improvements.
I
4.5.1. Replacement of Broken RBCs
Replacing out of service RBCs is recommended to increase operational surface area for the
biological treatment process to maximize nitrification capabilities of the existing RBC process.
I
MSD began implementing an RBC replacement program in 2014 as part of an optimization
strategy to improve existing RBC performance. MSD also completed several improvements
earlier in 2014 in preparation for replacing the RBCS. This included a project to repair and
I
replace inoperable gates. The gate replacement project was required to allow isolation of
individual RBC trains to conduct maintenance and allow RBC replacement. Another project
included cleanout of grit and solids that had accumulated in the RBC basins.
I4.5.2. Grit Removal Improvements
Replacing the existing grit system with a better performing grit system is recommended in order
' to reduce the wear and performance impacts on downstream processes and improve RBC
performance. In order to significantly improve grit removal which has been a proven problem at
I
25

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update 1.)
EVALUATION OF EXISTING AMMONIA REMOVAL PERFORMANCE
I
the plant, it is recommended to replace the existing Schreiber process with a vortex-based grit
removal system. Proceeding with biological treatment improvements without these"headworks"
I
improvements is not an appropriate route to full facility upgrade.
4.5.3. Equalization for Wet Weather Flow Management
I
Surge/flow equalization is recommended as a strategy for the French Broad River WRF to trim
peak flows during wet-weather operations and reduce potential for adverse treatment process
impacts, such as nitrifier washout, associated with high flow events. The existing out of service
I
anaerobic sludge digester tanks should be considered for use as surge/flow equalization tanks.
The combined volume of these tanks is 4.2 MG which could be used to trim peak hourly and
daily flows. Peak flows that exceed 65 mgd can be routed to these tanks, and returned to the
I
plant at a controlled rate when flows drop below 65 mgd.
The goal of the surge/flow equalization system would be to mitigate peak flows such that the I maximum flow through the plant at any time is 65 mgd. Based on analysis of the last 4 years of
plant flow data the two existing digester tanks are sufficient to mitigate all the peak flows for
typical flow years. While not every wet weather event can be expected to be contained with this
I
volume, repurposing the anaerobic digesters to surge/equalization tanks will provide capacity to
manage peak flows during most wet weather periods.Wet weather flow management will
become an important aspect of plant operations. Relative to enhancing nitrification,
I
equalization, along with other wet weather operating strategies,would help to better promote
nitrification during wet weather periods.
4.5.4. Primary Treatment I
Primary treatment at the French Broad River WRF would provide significant benefits in reducing
TSS and CBOD loads to the biological treatment process. This will offload the RBCs of a I significant CBOD load and enhance nitrification performance through the RBCs.
The primary challenge in considering primary treatment for the French Broad River WRF is
I
existing site constraints and space required for other improvements, such as grit removal
improvements. The most readily available area is the existing space in the Primary
Microscreens area. I Multiple primary treatment alternatives were reviewed to determine the best approach for MSD
subject to the site constraints and future requirements. Conventional primary clarification was
eliminated as a viable alternative because it would require more area than is available. Based
I
on evaluation of high rate primary treatment alternatives, chemically enhanced high rate primary
treatment is recommended to accommodate French Broad River WRF site constraints.
Chemically enhanced high rate primary treatment systems typically achieve greater than 90% I
TSS removal. For the French Broad River WRF, the goal of high rate primary treatment is to
balance TSS removal rates while maintaining sufficient primary effluent ortho-P and CBOD to
support downstream biological processes. I
I
I
26

Metropolitan Sewerage District of Buncombe County I Facility Plan Update 1.)
OPTIMIZATION OF EXISTING TREATMENT SYSTEM
' 5.0 OPTIMIZATION OF EXISTING
TREATMENT SYSTEM
' This section considers the feasibility and cost of optimizing the existing treatment system
through operational improvements.
' Based on results from the Ammonia Study and Supplemental Sampling, there are limited
opportunities to recognize substantial additional ammonia reduction through operational
improvements alone. Capital improvements, as outlined in Section 4.4, identify the highest
priority objectives related to existing and future plant configurations and are important steps to
address existing treatment challenges and are expected to further improve nitrification
capabilities on the existing RBC process.
Several operational improvements have been identified to assist with maintaining operation and
life of the RBCs units. These operational improvements, combined with replacement of out of
' service RBCs, provide the best opportunity for maximizing nitrification capabilities of the existing
RBC process through optimization. As such, this section focuses on the feasibility and cost of
optimizing the existing RBC process. A monitoring plan is then suggested to assess the benefits
' of the RBC optimization program.
5.1. RBC Replacement and Optimization Program
' Restoration of the RBC process is a transitional upgrade strategy for biological treatment as well
as improved nitrification performance at the French Broad River WRF. In 2014, MSD initiated an
RBC replacement and proactive maintenance program. The goal of this program is to replace
' most of the out of service RBCs and to implement a proactive RBC maintenance program to
sustain a high percentage of operating RBCs. As discussed in Section 4.3, maximizing the
operating RBC surface area provides an opportunity for maximizing the nitrification capabilities
' of the existing RBCs.
MSD recently completed an RBC gate replacement program which helps to manage flows
through the RBCs and allow segments of RBC trains to be taken out of service for preventative
maintenance, including biofilm growth control which is done by"starving"or in-situ chemical
treatment to strip excessive growth. The intent of this program is to prevent excessive biofilm
growth, control shaft weights and reduce the frequency of RBC failures. Following completion of
the gate replacement, MSD also completed cleanout of grit and solids that had accumulated in
the RBC basins. This proactive maintenance is one component of MSD's ongoing RBC
' optimization program.
The second component of the RBC optimization program is restoring operation of out of service
' RBCs. MSD has been working to locate used RBCs in good condition to restore operation of the
out of service RBCs. The first stage of this restoration program was to replace the out of service
RBCs in Basin 1 and the east half of Basin 2 RBCs back into service. This will be followed by
' restoring RBCs in the west half of Basin 2 and most of Basin 3, substantially restoring the
remaining out of service RBCs.
I
27

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update En
OPTIMIZATION OF EXISTING TREATMENT SYSTEM
I
The current location of in service and out of service RBCs is illustrated in Table A-2, located in
the Appendix.
I
Actual and future estimated costs for gate repair and replacement, RBC replacement, and grit
and solids removal are summarized in Table 5-1. Over$1.8 million will be spent by MSD on
I
RBC replacement and optimization.
Table 5-1: Actual and Estimated Costs for RBC Optimization
I
RBC Improvements Cost
RBC Gate Repair and Replacement(2014) $455,000
RBC Replacement—20 RBCs in 2014 $674,000
I
RBC Replacement(for 95% Operational Target) $400,000
Grit and Solids Removal (2014) $136,000
Grit and Solids Removal (future) $200,000
I
With all of the planned replacements, there would be a total of 147 operational RBCs, or
I
approximately 97% of the total RBCs. Under current loading conditions with no primary
treatment, this action will provide greater general treatment process flexibility and increase the
potential for additional nitrification. Nitrification performance diminishes when current maximum
I
month loadings are considered. The potential for nitrification will improve when additional RBCs
are replaced, but RBCs are not designed to nitrify, therefore actual ammonia effluent reduction
cannot be accurately projected. Results are variable depending on conditions, and are not I
considered reliable for permit compliance for the levels identified in the ammonia reduction
evaluation targets or for establishing levels that may result from the planned RBC
improvements. Although necessary to extend the longevity of the RBCs, "starving" or in-situ
I
chemical treatment to strip excessive growth has a negative impact on nitrification.
Implementation of other recommended highest priority improvements outlined in Section 4.4 are
I
expected to further improve overall performance of the RBC process. For example,
implementation of effective primary treatment is anticipated to reduce organic load to the RBC
process which is expected to increase surface area available for nitrification by achieving a
soluble BOD of less than 20 mg/L earlier within the RBC train. Grit removal improvements are
also anticipated to reduce solids loads to the RBC process which will improve operating
conditions in the RBC basin and help to extend the life of the RBCs. Wet weather flow
I
attenuation will assist with maintaining nitrification during wet weather. The combination of these
improvements increases the potential for improved ammonia removal performance in the RBCs
in the future. It would be difficult to project additional ammonia removal that could be achieved
I
through these improvements. Therefore, an ongoing monitoring program to evaluate nitrification
changes that may result from improvements of the RBC system will be an effective way to track
potential improvement in effluent ammonia levels.
I
Cost estimates for initial improvements are summarized in Table 5-2. The upgrade of the facility
is a "stepwise" process and the initial highest priority actions are ones that are essential, and I required first, to an overall plant upgrade. The headworks and primary treatment improvements
I
28
1

1
Metropolitan Sewerage District of Buncombe County I Facility Plan Update Inn
OPTIMIZATION OF EXISTING TREATMENT SYSTEM
' are a part of the overall fully upgraded facility. Over$15.5 million will be spent by MSD in the
next 5 to 7 years on upgrade projects to the treatment facility and for improvement of the RBC
process.
' Table 5-2: Estimated Capital Costs(2014 dollars)for Phased Initial Improvements
Facility Cost
Fine Screening and Grit Removal Improvements $4,600,000
Surge Tank /Flow Equalization $2,000,000
Primary Treatment $9,000,000
5.2. Monitoring Program
This section outlines a proposed monitoring program for assessing the benefits of RBC
optimization alone and RBC optimization with implementation of initial upgrades. MSD
' completed initial RBC replacement in November and December 2014. It is anticipated that
additional RBC replacement will be completed over the next year. In addition to the ongoing
RBC optimization program, MSD plans to move forward with design and construction of grit
' removal and surge/flow equalization improvements to address the most critical treatment
challenges. Fine screening will also be installed as part of the grit removal project. It is
anticipated that these improvements could be complete and operational by 2018. Primary
' treatment improvements are expected to be completed over the next 5 to 7 years.
Because some of the RBC replacements were just recently completed, it is too early to assess
' benefits of increased RBC surface area. In addition, since the RBC replacement occurred
during winter operation,warmer operating temperatures will likely be required to allow time for
nitrification start-up in the replaced RBCs. It is recommended that sampling be initiated in
' Summer 2015 to allow time for nitrification start-up.
An intra-process monitoring program could be conducted similar to the protocol used for the
Ammonia Study. If possible, the sampling program should be conducted to estimate nitrification
' capacity of the most fully restored train. Process control of the RBCs is limited in relation to
nitrification. A reasonable approach is to continue monitoring and to do the very best possible
until a more reliable nitrification process can be implemented.
Following completion of baseline sampling for the RBC improvements alone, the intra-process
monitoring program could be repeated following completion of the grit removal improvements.
' Based on timing for RBC and grit removal improvements, the baseline ammonia removal
improvements monitoring could be conducted between Summer 2015 and Winter 2017 prior to
' completion of grit removal improvements. It is estimated that monitoring for additional ammonia
reduction improvements following completion of grit removal improvement project could begin in
Summer 2018. Similar monitoring can also be conducted following completion of high rate
' primary treatment improvements. Sampling of intermediate clarifier NOX N could also be
conducted to provide additional data for monitoring nitrification improvements.
I
29

Metropolitan Sewerage District of Buncombe County I Facility Plan Update
EVALUATION OF BIOLOGICAL TREATMENT UPGRADES TO MEET NUMERICAL AMMONIA REDUCTION 1.011Z
TARGETS
6.0 EVALUATION OF BIOLOGICAL
TREATMENT UPGRADES TO MEET
NUMERICAL AMMONIA REDUCTION
TARGETS
111
6.1. Overview of Biological Treatment Upgrade Strategy
The existing RBC process in Basins 1, 2 and 3 is effective in removing CBOD, and under
current conditions and loads is able to provide a low level of nitrification. The existing treatment
plant maintains consistent compliance with existing permit limits, including consistent
compliance with chronic toxicity permit limits. '
However, as discussed in Section 4.3, even with all RBCs in service, the existing RBC process
cannot be expected to provide a high degree of nitrification and cannot meet the monthly
average NH3-N targets for the Ammonia Reduction Evaluation. As discussed in Section 4.4, the
French Broad River WRF has several existing treatment challenges that limit the ability of the
existing RBC process to achieve additional nitrification and that must be addressed for overall
plant improvement. As described in Section 5, MSD has already initiated an RBC optimization
program to replace out of service RBCs and sustain the number of RBCs in operation through a
proactive RBC maintenance program. MSD plans to initiate a phased improvement program to
address the other existing treatment challenges. It is anticipated that grit removal and surge/
flow equalization improvements will be completed first with estimated completion in 2018.
Installation of high rate primary treatment is anticipated to be accomplished next over with
anticipated timing of 5 to 7 years.
MSD should continue with the option for quarterly chronic toxicity monitoring as the continued
option for compliance with DWR's existing ammonia toxicity policy. This will allow time needed
for MSD to complete the RBC optimization program and proposed initial improvements, conduct
a monitoring program to quantify additional ammonia removal achieved through optimization of
the RBCs alone, as well as with implementation of the initial improvements.
The following subsections present an evaluation of the feasibility and costs for biological
treatment upgrades to meet numerical ammonia targets for the Ammonia Reduction Evaluation.
As previously discussed, this is a phased transitional upgrade strategy, and the highest priority
improvements will be constructed first. The biological upgrade components can be completed
after these initial improvements are in operation. This phased approach is a logical, real-world
methodology for getting this large facility upgraded.
6.2. Approach for Evaluating Biological Treatment Upgrades
This section presents the overall approach for evaluating biological treatment upgrades required
to meet numerical ammonia targets fro the Ammonia Reduction Evaluation.
1
30
1

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update 1.)IZ
I EVALUATION OF BIOLOGICAL TREATMENT UPGRADES TO MEET NUMERICAL AMMONIA REDUCTION
TARGETS
6.2.1. Biological Treatment Influent Flows and Loads
Flow and load projections at permitted flow conditions served as the basis for conceptual sizing
and evaluation of both highest priority improvements presented in Section 4.4 and biological
treatment alternatives.
I
Flow and load projections were based on the historic data analysis as well as domestic and
industrial growth rates provided by MSD. Current baseline flows, loads and peaking factors are
I
presented in Table 6-1.
Table 6-1: Baseline Flows and Loads Based on Historic Data Review
ITotal Total MM/AA Max 7-
Parameter Average Industrial Peaking
Annual Component Factor Peaking
I
Factor
Flow(mgd) 19 0.71 1.6 ; 2.6
CBOD (lb/d) 28,685 3,960 1.2 1.7
I
TSS (lb/d) 41,165 1,502 1.4 2.3
INH3-N (Ib/d) 3,405 198(1) 1.3 1.8
TKN (lb/d) 5,618(2) 327(2) 1.3 i 1.8
II (1)Based on 5%of CBOD load
(2)Based on TKN/NH3-N=1.65 form ammonia study data.
I
No ammonia or TKN data was available for the industrial loads; therefore, the load was
assumed to be 5% of the industrial CBOD load.This was necessary because the growth rates
for domestic and industrial growth are different. The domestic flow and load growth rate is 1.0%
I
per year and the industrial growth rate is 1.2% per year.
Projected influent wastewater flows, loads, and concentrations at the maximum month permitted
I flow of 40 mgd are summarized in Table 6-2. Flows and loads in Table 6-2 were used for
conceptual sizing of the biological treatment alternatives, taking into account any additional
treatment that would be achieved with high rate primary clarification. High rate primary clarifier
effluent loads are summarized in Table 6-3.
I
I
I
I
31

I
MetrolitanSeweg!DisctofBuncomtounf-I FacilityPlDUPda
EVALUATION OF BIOLOGICAL TREATVENTupGacEstmEETNumrRALiNAMMONIA REDUCTION Fn
TARGETS
I
Table 6-2: Summary of Wastewater Loads and Concentrations at 40 mgd permitted Capacity(Year 2042)
Parameter Average Max Month Peak Week Max Day Peak Hour I
Annual
Flow(mgd) 25.4 40 65.0 75 80 I
CBOD(1b/d) 38,593 47,955 63,992
CBOD(mg/L) 182 144 118
TSS(1b/d) 55,053 76,511 127,011
TSS(mg/L) 259 231 234
I
NH3-N (Ib/d) 4,560 5,856 8,082
NH3-N (mg/L) 21 18 15
1
TKN (1b/d) 7,523 9,663 13,335
TKN (mg/L) 35 29 25
1
Total P(mg/L) Average 5.8, Range 4.0 to 6.9
Ortho P(mg/L) Range 2.4 to 2.9
I
pH(su) 6.5 to 7.5
Alkalinity(mg/L) Average 180, Range 135 to 250
1
Temperature(°C) Range 11 to 23
I
I
I
I
I
I
I
I
32
i

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update 1.)11Z
I EVALUATION OF BIOLOGICAL TREATMENT UPGRADES TO MEET NUMERICAL AMMONIA REDUCTION
TARGETS
Table 6-3: Primary Effluent Estimates at 40 mgd Permitted Capacity(Year 2042)with Chemically Enhanced
IHigh Rate Primary Clarifiers Optimized for TSS Removal
Average
Parameter Max Month Peak Week Max Day Peak Hour
Annual
I Flow(mgd) 25.4 40 65.0 75
1 80
CBOD (Ib/d) 21,221 33,192 54,174
ICBOD(mg/L)2 100 100 100
TSS(1b/d)1 5,505 7,651 25,402
1 TSS(mg/L) 26 23 47
NH3-N (1b/d)5 4,796 7,468 10,001
I NH3-N(mg/L)
23 23
TKN (lb/d)4
6,395
9,663 18
13,335
TKN(mg/L) 30 30 . 25
Total P (mg/L)5 2 mg/L
Ortho P(mg/L)5 1 mg/L
IpH(su) 6.5 to 7.5
Alkalinity(mg/L) Average 180, Range 135 to 250
I Temperature(°C) Range 11 to 23
190%TSS removal assumed at annual average and maximum month;80%TSS removal assumed at peak week.
2 Primary effluent CBOD was estimated assuming influent particulate CBODTTSS ratio of 0.6 and a soluble CBOD of
I 55 mg/L. If resulting estimate was less than 100 mg/L,then the primary CBOD was rounded up 100 mg/L.
3
NH3-N load estimated by multiplying primary effluent TKN load by typical primary effluent NH3-N/TKN ratio of 0.75.
4 Primary effluent TKN calculated assumed that 15%of influent TKN load(particulate TKN)would be removed in the
I primary clarifiers.
5Chemical addition to high rate primary clarifiers would be dosed to maintain a primary effluent ortho-P concentration
of at least 1 mg/L.
I
I
I
I
I
I
1 33

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update
EVALUATION OF BIOLOGICAL TREATMENT UPGRADES TO MEET NUMERICAL AMMONIA REDUCTION 1.)11Z
TARGETS I
6.2.2. Effluent Objectives
Biological upgrade alternatives were evaluated based on their ability to continue to meet
I
existing NPDES discharge requirements in addition to the ammonia reduction targets for the
Ammonia Reduction Evaluation.
The ammonia reduction targets include summer and winter effluent discharge targets; however, I
it is important to note that summer is defined as between April 1 through October 31. Hence, it
is important that the biological treatment process be sized to achieve year-round nitrification so
I
that nitrification is sustained during the winter and the lower summer ammonia-N target can be
achieved at the on-set of the summer compliance period when operating temperatures are still
low. This also provides additional flexibility for the biological system to accommodate a more
I
stringent ammonia-N discharge limit should it be required in the future.
Flexibility for partial denitrification for alkalinity recovery and reduced aeration demands were
I
also considered when feasible.
6.2.3. Identification and Evaluation of Biological Treatment Alternatives I Preliminary screening of potential biological treatment alternative was completed to identify
feasible alternatives that could comply with the ammonia reduction targets. One of the
overarching goals was to work within the existing biological treatment tanks(Basins 1, 2 and 3) I because the plant site is underlain with hard rock. This constraint limited some of the secondary
treatment alternatives that were considered.
Table 6-4 presents a summary of the potentially feasible treatment alternatives that were
I
considered along with their advantages and disadvantages. These technologies were assessed
for their ability to comply with the ammonia reduction targets. Through this initial screening the
alternatives listed in Table 6-5 were identified as being feasible to meet the ammonia reduction
I
targets.
I
I
I
I
I
I
I
34
i

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update Imn
I EVALUATION OF BIOLOGICAL TREATMENT UPGRADES TO MEET NUMERICAL AMMONIA REDUCTION
TARGETS
Table 6-4: Summary Biological Treatment Alternatives Considered
1 Treatment Alternative Advantages Disadvantages
Rotating Biological Contactors • Familiarity of operation • Limited degree and
I (RBC) • Most compatible with reliability of nitrification
existing facility • Availability of parts and
I
• Energy efficient replacement equipment
Conventional Activated • Reliable and well • Requires largest reactor
ISludge, BNR demonstrated volume
• Can be retrofitted into • Increased clarification area
I available tanks required
• Can be configured to • Large footprint
recover alkalinity • Construct deeper tanks for
I reduced footprint and
energy efficiency
Membrane Bioreactor(MBR) • Reliable and well • Capital cost
I demonstrated • New operator skill set
• Can be retrofitted into needed
available tanks • Membrane maintenance
I • High biomass process and eventual replacement
reduces tank volume • More energy intensive
requirements than other methods
I • Smallest footprint • Fine screening required
• Eliminates need for (2 to 3 mm)
I clarifiers
• Can be configured to
recover alkalinity
I
I
I
I
I
I
35
I

I
Metropolitan Sewerage District of Buncombe County l Facility Plan Update
EVALUATION OF BIOLOGICAL TREATMENT UPGRADES TO MEET NUMERICAL AMMONIA REDUCTION �)1Z
TARGETS
I
Treatment Alternative Advantages Disadvantages
Integrated Fixed Film • Reliable and well • Capital cost I
Activated Sludge(IFAS) or demonstrated • Media can clog
Moving Bed Biofilm reactor • Can be retrofitted into • Fine screening required (6
I
(MBBR) existing tanks mm with primary
• High biomass process clarification; 3—4 mm
reduces tank volume without primary
I
requirements clarification)
• Media and support
equipment offered by
I
several vendors
• Smaller footprint than
conventional activated
I
sludge
• Can be configured to
recover alkalinity
I
Step Feed BNR Process • Energy efficient • Increased clarification area
• Cost effective required
• Greatest ability to manage • Large footprint I
peak wet weather flows • Construct deeper tanks for
• Proven to remove nitrogen reduced footprint and I• Most process flexibility. energy efficiency
• Can be configured to
recover alkalinity I BioMag • Can be retrofitted into • Relatively new process
available tanks with limited installations
• High biomass process • Proprietary process
I
reduces tank volume
requirements
• Smaller footprint
III
• Enhances MLSS settling
characteristics and solids
capture
I
• Reduces clarifier area
requirements
• Can be configured to I
recover alkalinity
A-Stage • High rate CBOD removal • Must be coupled with
• Energy efficient second stage nitrification
I
• Cost effective process
• Small aeration tanks • Conventional clarification
I
area required
I
36

Metropolitan Sewerage District of Buncombe County l Facility Plan Update 11.)1Z
' EVALUATION OF BIOLOGICAL TREATMENT UPGRADES TO MEET NUMERICAL AMMONIA REDUCTION
TARGETS
' Treatment Alternative Advantages Disadvantages
Mainstream • Reduction in oxygen • Emerging technology
Deammonification demand (energy) • Ideal temperature is 30 to
' • Reduced alkalinity 35°C.
requirements • Mainstream
• Reduction in biomass deammonification is in the
' production investigative stage and
• Reduction in carbon should not be considered
demand for denitrification feasible at this time for full
• Can be part of an AIB scale application
Stage process
Table 6-5: Feasible Alternatives for Meeting Ammonia Reduction Targets
Process Description
High Rate Primary Treatment and Full Conversion to Conventional
Activated Sludge Nitrification (Basin 1 and 2)
High Rate Primary Treatment and Full Conversion to Conventional
Activated Sludge Nitrification (Basin 2 only)
' High Rate Primary Treatment with RBCs for CBOD Removal and Second
Stage Activated Sludge Nitrification
' High Rate Primary Treatment with Parallel RBC and Nitrifying Activated
Sludge Processes
Full MBR Process
' High Rate Primary Treatment with RBCs for CBOD Removal and Nitrifying
MBBR
High Rate Primary Treatment with full conversion to MBBRs
Full IFAS Process
1
1
37

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update
EVALUATION OF BIOLOGICAL TREATMENT UPGRADES TO MEET NUMERICAL AMMONIA REDUCTION 11.01Z
TARGETS I
6.3. Conceptual Development of Biological Treatment
Alternatives I
The feasible alternatives were considered in conceptual planning for upgrades to meet the
Ammonia Reduction Evaluation targets.
I
Pre-anoxic zones should be considered because of their ability to recover alkalinity and reduce
chemical consumption and O&M costs.
I
Construction sequencing and maintenance of plant operations for each of the biological options
is complicated because the existing structures must be modified and re-used inside their I existing footprint while the plant is kept sufficiently operational to continue to meet permit limits.
It was assumed based on the ongoing optimization program that the RBC process will be nearly
fully functional during the biological process upgrade. However, the plant will have very limited I or no ability to nitrify during construction, depending on high rate primary treatment
performance. Therefore, for construction sequencing, it was assumed that the plant would not
be required to comply with numerical ammonia limits until long term biological treatment I alternatives are constructed. This is a critical assumption for successful maintenance of plant
operations during construction and transition to a new biological treatment process.
All of the biological treatment alternatives incorporate the phased highest priority improvements
I
described in Section 4.4. It was assumed that new fine screening and grit removal, along with
high rate primary treatment would be constructed prior to upgrading the biological treatment
I
process. It is critical that the biological process conversion be completed after the high rate
primary treatment process in online and optimized to maximize TSS and particulate CBOD
removal. Additionally, at least three of the four existing biological trains must be kept operational
I
during construction to meet existing permit limits.
6.4. Cost Estimates for Biological Treatment Upgrades
New fine screening and grit removal, as well as high rate primary treatment, would need to be
I
constructed prior to upgrading the biological treatment process. High-level conceptual cost
ranges were prepared for the feasible biological treatment upgrade alternatives. Since the I biological upgrade cannot be completed first, it is assumed that the feasible alternatives may
change and other technologies may evolve. Costs were developed based on assumptions for
equipment, concrete, structures, infrastructure rehabilitation and demolition costs as well as I allowances as a percentage of construction for instrumentation and control, electrical and a 25%
overall contingency. Costs also include constructability and maintenance of plant operations
related items such as bypass pumping. Major equipment costs are based on vendor budgetary 111estimates and are marked up by 40%as an allowance for installation. Unit costs for items such
as concrete and piping are installed cost estimates.
A summary of the estimated capital costs for the biological treatment upgrades are summarized 1
in Table 6-6.
I
I
38

1
Metropolitan Sewerage District of Buncombe County I Facility Plan Update Inn
EVALUATION OF BIOLOGICAL TREATMENT UPGRADES TO MEET NUMERICAL AMMONIA REDUCTION
TARGETS
' Table 6-6: Estimated Capital Costs(2014 dollars)for Biological Alternatives
Facility Cost
Activated Sludge $35,000,000- $50,000,000
' MBBR $50,000,000- $70,000,000
IFAS $35,000,000- $50,000,000
' MBR >$250,000,000
1
I
i
1
39

Metropolitan Sewerage District of Buncombe County I Facility Plan Update lion
SUMMARY OF FINDINGS AND CONCLUSIONS
7.0 SUMMARY OF FINDINGS AND
CONCLUSIONS
Below is a summary of key findings and conclusions for the Ammonia Reduction Evaluation: ,
• The French Broad River WRF maintains consistent compliance with existing permit
limits and complies with DWR's existing ammonia policy through consistent compliance
with chronic toxicity permit limits.
• The existing RBC process is effective in removing CBOD, and under current conditions
and loads is able to provide variable low level of nitrification.
• The existing RBC process, even with the improvements in RBC operations, cannot
currently meet targets for the Ammonia Reduction Evaluation, and RBC nitrification
cannot accurately be estimated. 1
• The results of the intensive sampling support that some additional improvement of
nitrification can be expected with increased RBC surface.
• Based on observed current nitrification rates from intensive sampling events, even with '
all RBCs in service, the existing RBC process cannot provide a high degree of
predictable nitrification and cannot meet the monthly average NH3-N targets for the
Ammonia Reduction Evaluation. 111
• The French Broad River WRF has several existing treatment challenges that must be
addressed first in order to optimize the operation of the RBC system and provide an
appropriate treatment foundation for upgrading biological treatment at the facility. These
challenges include the following:
o Number of RBCs out of service
o Poor grit removal and accumulation of solids in RBCs
o High loads to RBCS
o Wet Weather Flows
o Limited influent alkalinity
o Limited ability to predict and control nitrification
• MSD has initiated an RBC optimization program to replace out of service RBCs and
sustain the number of RBCs in operation through a proactive RBC maintenance
program. By the end of this program, it is anticipated that 97% of the RBCs will be
operational.
• A monitoring program could quantify ammonia benefits of the RBC optimization.
• MSD intends to initiate a phased improvement program to address existing treatment
challenges, and to provide an overall upgrade of the WRF in accordance with an
appropriately scheduled and managed major treatment improvement project. It is
anticipated that grit removal and surge/flow equalization improvements will be
completed first with estimated completion in 2018. Installation of high rate primary
treatment is anticipated to be accomplished next over with anticipated timing of 5 to 7
years. It is anticipated that these improvements will further improve nitrification
capabilities of optimized RBC process.
40

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update 1.)11Z
I
SUMMARY OF FINDINGS AND CONCLUSIONS
' • A monitoring program could quantify additional ammonia removal benefits with
implementation of each of the phased initial upgrades.
• Significant and costly biological upgrades are required to achieve process control
' managed year-round enhanced nitrification at the French Broad River WRF. The
addition of these improvements is planned and is a part of the overall upgrade program
for this facility.
I
I . Feasible biological alternatives were identified and conceptually developed.
o The identified initial improvements are required prior to implementation of all
biological treatment alternatives.
Ia Initial phases are costly, complex and require time to design and construct and
initiate operation.
o Implementation of the biological alternatives will be complicated and require an
I
extensive maintenance of operations plan to transition to an alternative
biological treatment process.
• A phased biological implementation strategy is recommended. MSD should continue
I
with the option for quarterly chronic toxicity monitoring as the continued option for
compliance with the existing ammonia toxicity policy. This will allow time needed for
MSD to complete the RBC optimization program and proposed phased initial
I
improvements, as well as to conduct a monitoring program to quantify additional
nitrification achieved through optimization of the RBCs alone and with implementation of
the phased highest priority improvements.
I
I
I
1
I
I
I
I
I
41

Metropolitan Sewerage District of Buncombe County I Facility Plan Update 1.n
APPENDIX A-SUMMARY OF EXISTING UNIT PROCESSES AND OPERATIONAL STATUS OF RBCS
1
A1
4,, PN SEWEggCF.:,
O
• APPENDIX A —
se
coo„Tv, SUMMARY OF
EXISTING UNIT '
PROCESSES AND
OPERATIONAL STATUS
OF RBCs t
I
I
I
I
I

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update 011Z
I
APPENDIX A-SUMMARY OF EXISTING UNIT PROCESSES AND OPERATIONAL STATUS OF RBCS
Table A-1: Summary of Existing Unit Processes and Major Equipment at French Broad River WRF
ILocation/Process Parameter Design Criteria
Influent Screening Number of Units 2
l
Facility Opening of Screens,in. 3/4"
Width,ft 4
Height,ft 8
Depth,ft 30
I Hydraulic Capacity,each,mgd 40
Total Capacity,mgd 80
Grit and Grease Number of Units 3
I Removal System Type
Width,ft Schreiber Grit&Grease
17
Length,ft 76
I Depth,ft 18
Volume per Unit,gal 173,955
Unit Surface Area,ft2 1,292
HRT at Peak Hourly Flow(80 mgd with 1 OOS), 6
I
Min
Collector Speed,fpm 2
Grit Pump Capacity(each),gpm 175
I Influent Pumping I No.of Influent Pumps 3
Station
Unit Capacity,gpm 24,300
No.Typically in Service 1 or 2
I Type of Pumps
Control vertical centrifugal
level control w/VFDs
Firm capacity,gpm 55,555
Unit hp 400
TDH,ft 44
Primary Concrete tank 146 ft long,42 ft wide,
Microscreens and 13 ft deep(inside dimensions)
I Reinforced concrete building
23 ft high(Inside dear height)
Total area,ft'(outside dimensions) I 6,900
RBCs Number of Basins 3
l
Number of Original Stages 7
High Density Media Unit Area,ft2 155,000
Standard Density Media Unit Area,ft2 127,500
I Submergence,% 37%(1)
Basin 1 -Stage No. 1 Units(Standard Density) 24
Basin 1 -Stage No.2 Units (Standard Density) 20
I Basin 2-Stage No. 3 Units (Standard Density) 24
Basin 2-Stage No.4 Units (Standard Density) 24
Basin 2-Stage No.5 Units(High Density) 24
Basin 3-Stage No.6 Units(High Density) 20
I Basin 3-Stage No.7 Units(High Density) 16
Total RBCs 152
Basin 1 -Total Surface Area 5,610,000
I Basin 2-Total Surface Area 9,840,000
Basin 3-Total Surface Area 5,580,000
I
I

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update Fn
APPENDIX A-SUMMARY OF EXISTING UNIT PROCESSES AND OPERATIONAL STATUS OF RBCS
I
Location/Process Parameter Design Criteria
Total Surface area,ft2 21,030,000
I
Internal Recirculation Rate,gpm 0
Blowers Number of Units 5
I
hp,each 450
Unit capacity,scfm 10,755
Discharge pressure N/A
I
Intermediate Pumping No.of Influent Pumps 3
Unit Capacity,gpm 23,000
No.Typically in Service 1 or 2 '
Type of Pumps submersible
Control level control w/VFD
Firm capacity,gpm 46,000 I Unit hp 300
TDH,ft 27
Intermediate Clarifiers Number of Clarifiers 4
I
Number of Tanks per Clarifier 2
Width,ft 16.33
Length,ft 128.5
1
Average Depth,ft 12.3
Area per unit,ft2 4,197
Total Surface Area, ft2 16,787 '
Hydraulic Loading Rate,gpd/ft2 ,383
HRT, hrs 0.9
Cloth Media Filters No. of Units 16
I
Number of Quads 4
Disks per Unit 12
Area per unit,ft2 553
I
Max Month Design Flow 40
Peak Flow 65
Max Hydraulic Capacity 70
Total Area(two units out of service),ft2 7,742 I Hydraulic Loading Rate,gpm/ft2(2 OOS) 3.6
Hydraulic Loading Rate at 65 mgd,gpm/ft2(2 OOS) 5.8
Peak Hydraulic Loading Rate at 70 mgd,gpm/ft2(1 5.9
I
OOS)
Max Month Influent TSS,mg/L 20
Peak Day Influent TSS,mg/L 30
Max Solids Loading Rate,lb/d-ft2(2 OOS) 2.1
No.of Backwash Pumps 8(2 per Quad)
Current Backwash Flow Estimate,gpd 500,000
I
(2.5%of Plant Flow)
Chlorination/ No. of Chlorine Contact Tanks 1
Dechlorination
Width,ft 26.7
I
Length,ft 200
I
I

I
Metropolitan Sewerage District of Buncombe County I Facility Plan Update Inn
tAPPENDIX A-SUMMARY OF EXISTING UNIT PROCESSES AND OPERATIONAL STATUS OF RBCS
I Location/Process ParameterDepth,ft IDesign Criteria
, 8.6
j Unit Volume,gal 1 343,512
Inlet Volume,gal 55,876
I Additional Contact Volume in Filter Building,gal 243,310
Total Volume,gal 642,698
Min HRT,Min 14.2
I Clarifier Underflow No.of Pumps 6
Pumps
No.Typically in Service 4
Type of Pumps Vertical,centrifugal
Control Timer (7 min on/off typ)
Unit Capacity,gpm 500
Current Ave Flow Estimate,mgd 1.4
I
Gravity Thickeners i Number of Units 2
Diameter,ft 100
I
Depth,ft 12
Area per unit,ft2 7,854
Estimated Capture, % 95
Belt Filter Press Number of Units 2
Unit Size 2.5 m
Unit Hydraulic Capacity,gpm 100
I ! Unit Solids Capacity,lbs/hour/meter
Estimated Capture,% 95
Spray wash water,gpm 100-200
IIncinerator Permitted capacity,dtpd 40
Typical operating rate,dtpd 16
Iscrubber water,gpm 600
Ash Pond Total Storage Capacity,ac-ft 276
Surface Area,acres 13
ICurrent Ashpond Overflow Estimate,mgd 0.14
Sodium Hypochlorite Number of Storage Tanks 4
I Disinfection System
Tank Volume,gal 15,000
Concentration in Storage Tanks,% 7
I Number of Metering Pumps 4
Disinfection Pump Capacity,gph
Dechlorination Chemical Sodium Bisulfate
I
Polymer Feed System Current Dosage 4 lbs/dry ton

I
Metropolitan District of Buncombe County I Facility
Update
age
n
APPENDIX A-SUMMARY OF EXISTING UNITrPROCESSES AND OPERATIONAL STATUSaOF RBCS 11.01Z
I
Table A-2: Operational Status of RBCs as of April 2015
I
Train 1 Train 2 Basin 1 Train 3 Train 4
1 12 23 34 c I
Zt 2 13 24 35 Q
in 3 14 25 36 en
4 15 26 37
N 5 - 16 27 38 N
aa) 6 17 28 39 c)
7 18 29 40 0
T. _ 8 _ 19 30 41 a
c _— 9 20 31 42 c
ca 10 21 32 43 - I
11 22 33 44 N
_ Basin 2 I cr 1 19 k Shaft Ruined Shaft Ruined ct
a2 20 - 38 = 56 a
io 3 21 E[Shaft Ruiner El 57 eo
o 4 22 1.1 40 Shaft Ruined o
O 5 23 MIBroken Shaft I. 59 0
U) I 6 24 MI Shaft Ruined., M p;Shaft
ec 7 25 I. 43 M 61 cc
Q 8 26 M44 M 62 Q
v I
9 27 M 45 ruined v
10 28 M 46 MI 64 3
❑ 11 29 El 47 M 65 ❑
I-
12 30 MI 48 M 66 U)
ec 13 31 Ellt Broken Shaft NI 67 cc
I
Q 14 32 M 50 1. 68 Q
in _ 15 33 • 51 69 m
3 16 34 r Broken Shaft M 70 3
❑ 17 34 ME 53 M71 ❑
I
= 18 36 IIII 54 El 72 =
Basin 3
I
w m 1 Dead Unit = 19 28 cc
Q Dead Unit M 11 M 20 29 ' 7i-
:v Dead Unit Dead Unit Dead Unit 30 4
3 Dead Unit IIII 13 M 22 31 3I
' M 5 M14 E 23 32 _ 4'
Fn.c Dead Unit M 15 24 33 c
m Dead Unit Dead Unit 111. 25 34 m
❑ M 8 = 17 = 26 35 ❑ r I
_ M 9 Shaft Ruined M 27 36 I
Additional proposed replacements over next year.
I
I
I
I
I