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HomeMy WebLinkAboutNC0086819_Issuance of Permit_20110809NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins Dee Freeman Governor Director Secretary August 9, 2011 Mr. Bruce Biehl Director of Engineering and Regulatory Affairs Brenntag Southeast, Inc. 2000 East Pettigrew Street Durham, NC 27703 Subject: Issuance of NPDES Permit Permit NCO086827 Brenntag Southeast, Inc. Groundwater Remediation System Facility Class I Durham County Dear Mr. Biehl: Division personnel have reviewed and approved your application for renewal of the subject permit. Accordingly, we are forwarding the attached NPDES discharge permit. This permit is issued pursuant to the requirements of North Carolina General Statute 143-215.1 and the Memorandum of Agreement between North Carolina and the U.S. Environmental Protection Agency dated October 15, 2007 (or as subsequently amended). Summary of Changes in Renewal Permit from ExistingPermit 1) Total manganese monthly average and daily limits were added. 2) Acetone and cis -1,2 dichloroethylene quarterly monitoring were added. 3) Total zinc and pH quarterly monitoring were added. 4) Narrative condition was added to bis (2-ethylhexyl) phthalate to require minimum detection limit of 1.0 µg/1. 5) Total nitrogen monitoring was removed. 6) Total iron monitoring was reduced to quarterly. 7) Chronic toxicity special condition narrative was updated to current narrative. 8) Narrative condition restricting an oily sheen in the discharge was added. 9) Supplemental page treatment system list was updated. 10) Stream classification was changed from C, NSW to WS -IV, NSW; to reflect 2009 stream reclassification. Page 1 of 2 1617 Mail Service Center, Raleigh, North Carolina 27699-1617 Location: 512 N. Salisbury St. Raleigh, North Caroli, a 27604 One Phone: 919-807-63001 FAX: 919-807.64921 Customer Service: 1-877-623.6748 North Carolina Internet: www.ncwaterquality.org An Equal opportunely 1, Affinnabve Action Employer Nat to /d g ` ytj�!/ y a Yti In the final permit, acetone and cis -1,2 dichloroethlyene monitoring frequencies were amended to quarterly with no conditional petition to better document the treatment system removal efficiency. Also, the final permit was not issued until the cation filters system was installed providing the manganese removal needed to obtain compliance. Please note that your discharge is into a receiving stream that is listed as an impaired waterbody on the North Carolina 303(d) Impaired Waters List. Addressing impaired waters is a high priority with the Division, and instream data will continue to be evaluated. If there is noncompliance with permitted effluent limits and stream impairment can be attributed to your facility, then mitigative measures may be required. If any parts, measurement frequencies or sampling requirements contained in this permit are unacceptable to you, you have the right to an adjudicatory hearing upon written request within thirty (30) days following receipt of this letter. This request must be in the form of a written petition, conforming to Chapter 150B of the North Carolina General Statutes, and filed with the Office of Administrative Hearings (6714 Mail Service Center, Raleigh, North Carolina 27699-6714). Unless such demand is made, this decision shall be final and binding. Please note that this permit is not transferable except after notice to the Division. The Division may require modification or revocation and reissuance of the permit. This permit does not affect the legal requirements to obtain other permits which may be required by the Division of Water Quality or permits required by the Division of Land Resources, the Coastal Area Management Act or any other federal or local governmental permits that may be required. If you have any questions concerning this permit, please contact Ron Berry at telephone number (919) 807-6396 or at email ron.berry@ncdenr.gov. Sincerely, 2oleen H. Sullins Attachments Cc: Raleigh Regional Office/Surface Water Protection Section Environmental Sciences Section/Aquatic Toxicology Unit/Susan Meadows (email) David Schwartz (email:dcschwartz@hotmail.com) Central Files NPDES Unit Page 2 of 2 Permit NCO086827 STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WATER QUALITY PERMIT TO DISCHARGE WASTEWATER UNDER THE NATIONAL POLLUTANT DISCHARGE ELIMINATION SYSTEM In compliance with the provision of North Carolina General Statute 143-215.1, other lawful standards and regulations promulgated and adopted by the North Carolina Environmental Management Commission, and the Federal Water Pollution Control Act, as amended, Brenntag Southeast, Inc. is hereby authorized to discharge wastewater from a facility located at Brenntag Southeast, Inc. Groundwater Remediation System 2000 East Pettigrew Street Durham County to receiving waters designated as Unnamed Tributary to Third Fork Creek in the Cape Fear River Basin in accordance with effluent limitations, monitoring requirements, and other conditions set forth in Parts I, II, III and IV hereof. This permit shall become effective September 1, 2011. This permit and authorization to discharge shall expire at midnight on April 30, 2016. Signed this day August 9, 2011. een H. Sullins, Director /Division of Water Quality By Authority of the Environmental Management Commission Permit NC0086827 SUPPLEMENT TO PERMIT COVER SHEET All previous NPDES Permits issued to this facility, whether for operation or discharge are hereby revoked. As of this permit issuance, any previously issued permit bearing this number is no longer effective. Therefore, the exclusive authority to operate and discharge from this facility arises under the permit conditions, requirements, terms, and provisions included herein. Brenntag Southeast, Inc. is hereby authorized to: Continue to operate a groundwater remediation treatment system consisting of: o Influent meter o Bag filter o Air stripper unit with collection sump and blower o Transfer pump o Two (2) GAC disposable filters a Two (2) cation disposable filters o Effluent flow meter with totalizer This facility is located at Brenntag Southeast, Inc., 2000 East Pettigrew Street in Durham County. 2. Discharge from said treatment works at the location specified on the attached map through outfall 001, into an unnamed tributary to Third Fork Creek, classified WS -V, NSW waters in the Cape Fear River Basin. 0 ' «W��'�" "�.: .''''�- , -.&.. cif � r -�ti �• y . �' �+ t �� `' fr t . � ej� Q. �I , I •� K l TMJ � � � i GVa Facihtj s z _ 'Ji it ' ��..- '`. �I .+ S f �. � 1':o•it jJ�i IT �- - r�� I �4 � • -- / u � - r may. �Rl r �' ► ' �; '� �`' � `- _fig- � � t. �1 , k z. - err; �,• r c e w- ti ' DIS charge'' p!; j1 a - �+{f ' `. �' AT. �' �: 1 `, is �, y _ / •� � ,.• 'F � j �_ �,+ �• �'�~ t tr- �.( fi tie ��+I�ICr - t �_ I r• + ��"� ?. _ pI� \\IIIL1f s a r , .} 47. �• '-, �'�,- ,`1 Kimp1. ' _ �� 1 ;� -M Y 5, Irl 1 - '� I �� 4 � i i ', �'r , ir Al ji i r.+ ti ,. .. • 3 j F .. USGS Quad: D23NW Southwest Durham, NC Outfall Facility Latitude: 35° 58'45.3" N 350 58'43.9" N A Longitude: 78° 52'58.3" W 780 52'54.2" W Stream Class: WS -V, NSW Facility Location North Subbasin: 03-06-05 HUC: 03030002 Brenntag Southeast, Inc. GWR NCO086827 Receiving Stream: UT to Third Fork Creek Durham County Permit NCO086827 A. (1) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS Beginning on the effective date of this permit and lasting until expiration, the Permittee is authorized to discharge treated groundwater from Outfall 001. Such discharges shall be limited and monitored by the Permittee as specified below: EFFLUENT LIMITS MONITORING REQUIREMENTS CHARACTERISTICS Monthly Daily Measurement Sample Sample PARAMETER CODES Average Maximum Frequency Type Location Flow 0.0144 MGD Instantaneous Recorder Effluent 50050 Total Suspended Solids (TSS) 30.0 mg/1 30.0 mg/1 Monthly Grab Effluent 00530 Total Manganese 200 µg/1 200 µg/1 Monthly Grab Effluent 01055 Oil and Grease', mg/1 Monthly Grab Effluent 00556 Acetone, µg/1 Quarterly Grab Effluent 81552 cis 1,2 dichloroethylene, µg/1 Quarterly Grab Effluent 81686 pH, S.U. Quarterly Grab Effluent 00400 Benzene, µg/1 Quarterly Grab Effluent 34030 bis (2-ethylhexyl) phthalate , µg/1 Quarterly Grab Effluent 39100 1,1 dichloroethylene, µg/1 Quarterly Grab Effluent 34501 Tetrachloroethylene (PCE), µg/1 Quarterly Grab Effluent 78389 Toluene, µg/1 Quarterly Grab Effluent 34010 Total Iron, mg/1 Quarterly Grab Effluent 01045 Total Zinc, µg/1 Quarterly Grab Effluent 01092 Trichloroethylene (TCE), µg/1 Quarterly Grab Effluent 39180 Vinyl chloride, µg/1 Quarterly Grab Effluent 39175 Total xylenes, 1,Lg/1 Quarterly Grab Effluent 81551 Chronic Toxicity Quarterly Grab Effluent TGP3B EPA Method 624/625 (Full Suite) Annually See Effluent 76029176028 Method Permit NCO086827 (Continued A. (1) EFFLUENT LIMITATIONS AND MONITORING REQUIREMENTS) Footnotes: 1. Sample should be skimmed from liquid surface in a quiescent zone, such as from liquid surface in a holding tank, if possible. 2. A minimum detection limit of 1.0 jig/] is required. 3. Chronic Toxicity (Ceriodaphnia), P/F at 90 %, January, April, July, and October, See Special Condition A.(2). Toxicity sample to be collected at same time as monitored pollutants samples. There shall be no discharge of floating solids or visible foam in other than trace amounts. There shall be no oily sheen in the discharge or in the receiving stream traceable to the discharge. A. (2) CHRONIC TOXICITY PERMIT LIMIT (QRTRLY) The effluent discharge shall at no time exhibit observable inhibition of reproduction or significant mortality to Ceriodaphnia dubia at an effluent concentration of 90%. The permit holder shall perform at a minimum, quarterly monitoring using test procedures outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised February 1998, or subsequent versions or "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. The tests will be performed during the months of January, April, July, and October. Effluent sampling for this testing shall be performed at the NPDES permitted final effluent discharge below all treatment processes. If the test procedure performed as the first test of any single quarter results in a failure or ChV below the permit limit, then multiple -concentration testing shall be performed at a minimum, in each of the two following months as described in "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised -February 1998) or subsequent versions. The chronic value for multiple concentration tests will be determined using the geometric mean of the highest concentration having no detectable impairment of reproduction or survival and the lowest concentration that does have a detectable impairment of reproduction or survival. The definition of "detectable impairment," collection methods, exposure regimes, and further statistical methods are specified in the "North Carolina Phase II Chronic Whole Effluent Toxicity Test Procedure" (Revised - February 1998) or subsequent versions. All toxicity testing results required as part of this permit condition will be entered on the Effluent Discharge Monitoring Form (MR -1) for the months in which tests were performed. If reporting pass/fail results using the parameter code TGP3B, DWQ Form AT -1 (original) is sent to the below address. If reporting Chronic Value results using the parameter code THP3B, DWQ Form AT -3 (original) is to be sent to the following address: Attention: NC DENR / DWQ / Environmental Sciences Section 1621 Mail Service Center Raleigh, North Carolina 27699-1621 Permit NCO086827 (Continued A. (2) CHRONIC TOXICITY PERMIT LIMIT (QRTRLY)) Completed Aquatic Toxicity Test Forms shall be filed with the Environmental Sciences Section no later than 30 days after the end of the reporting period for which the report is made. Test data shall be complete, accurate, include all supporting chemical/physical measurements and all concentration/response data, and be certified by laboratory supervisor and ORC or approved designate signature. Total residual chlorine of the effluent toxicity sample must be measured and reported if chlorine is employed for disinfection of the waste stream. Should there be no discharge of flow from the facility during a month in which toxicity monitoring is required, the permittee will complete the information located at the top of the aquatic toxicity (AT) test form indicating the facility name, permit number, pipe number, county, and the month/year of the report with the notation of "No Flow" in the comment area of the form. The report shall be submitted to the Environmental Sciences Section at the address cited above. Should the permittee fail to monitor during a month in which toxicity monitoring is required, monitoring will be required during the following month. Should any test data from this monitoring requirement or tests performed by the North Carolina Division of Water Quality indicate potential impacts to the receiving stream, this permit may be re -opened and modified to include alternate monitoring requirements or limits. If the Permittee monitors any pollutant more frequently then required by this permit, the results of such monitoring shall be included in the calculation and reporting of the data submitted on the DMR and all AT Forms submitted. NOTE: Failure to achieve test conditions as specified in the cited document, such as minimum control organism survival, minimum control organism reproduction, and appropriate environmental controls, shall constitute an invalid test and will require immediate follow-up testing to be completed no later than the last day of the month following the month of the initial monitoring. DENR/DWQ FACT SHEET FOR NPDES PERMIT DEVELOPMENT NPDES Permit NC0086827 Revised. 814111 History Brenntag Southeast, Inc. has applied for renewal of its NPDES permit to discharge treated remediated groundwater into a storm drain located in Durham County from its industrial/commercial operation. The only viable option, other than discharge to surface water, is to discharge to the City of Durham. However, the City of Durham is unwilling to accept the remediated groundwater continuing to make this permitted discharge the most economical viable option. Groundwater data from 1996 to 2000 was used to establish the original owners, Southchem, Inc., 2000 GWR permits requirements, and included 32 effluent characteristics (see Table A). In addition to solvent contaminated groundwater, samples indicate contaminates from petroleum sources. Therefore, the conditions of the general permit for groundwater remediation systems were incorporated into the original permit. The discharge is to a zero flow stream. In 2001, the ownership changed to Brenntag Southeast, Inc. A major permit modification was issued in 2004 that reduced the monitored effluent characteristics to 18 parameters (see Table A). After reviewing the DMR data and petition request, the 2005 permit renewal reduced the effluent characteristics requirements to 16 (see Table A). As these permit amendments were implemented the permit limits and monitoring frequency were also amended. Fact Sheet NPDES NC0086827 Page 1 of 5 Facility Information Applicant/Facility Name: Brenntag Southeast, Inc. Applicant Address: 2000 East Pettigrew Street; Durham, NC 27702 Facility Address: 2000 East Pettigrew Street; Durham, NC 27702 Permitted Flow 0.0144 MGD Type of Waste: GWR treated waste Facility/Permit Status: Class I /Active; Renewal with stream re -class County: Durham Count Miscellaneous Receiving Stream: UT to Third Fork Creek Stream Classification: WS -V, NSW (re -classed 2009) Subbasin: 03-06-05 Index No. 16-41-1-12-(1) Drainage Area (mi): <0.1 HUC: 03030002 Summer 7Q10 (cfs) 0 303(d) Listed? Yes, Low DO, Zinc, Fecal, Biological Integrity Winter 7Q10 (cfs): 0 Regional Office: Raleigh 30Q2 (cfs) 0 State Grid / USGS Quad: D23NW SW Durham, NC Average Flow (cfs): <0.1 Permit Writer: Ron Berry IWC (%): 100 Date: Revised 1814111 History Brenntag Southeast, Inc. has applied for renewal of its NPDES permit to discharge treated remediated groundwater into a storm drain located in Durham County from its industrial/commercial operation. The only viable option, other than discharge to surface water, is to discharge to the City of Durham. However, the City of Durham is unwilling to accept the remediated groundwater continuing to make this permitted discharge the most economical viable option. Groundwater data from 1996 to 2000 was used to establish the original owners, Southchem, Inc., 2000 GWR permits requirements, and included 32 effluent characteristics (see Table A). In addition to solvent contaminated groundwater, samples indicate contaminates from petroleum sources. Therefore, the conditions of the general permit for groundwater remediation systems were incorporated into the original permit. The discharge is to a zero flow stream. In 2001, the ownership changed to Brenntag Southeast, Inc. A major permit modification was issued in 2004 that reduced the monitored effluent characteristics to 18 parameters (see Table A). After reviewing the DMR data and petition request, the 2005 permit renewal reduced the effluent characteristics requirements to 16 (see Table A). As these permit amendments were implemented the permit limits and monitoring frequency were also amended. Fact Sheet NPDES NC0086827 Page 1 of 5 The discharge is to an unnamed tributary to Third Fork Creek. Prior to 2009 this section of Third Fork Creek was classified as C, NSW. But in 2009 this stream was reclassified as a WS -V stream, as it is tributary to Jordan Lake. Though the unnamed tributary is not directly listed as impaired it is considered part of Third Fork Creek which is impaired. The approved 2010 303(d) list Third Fork Creek impaired for low dissolved oxygen, zinc, fecal, and biological integrity. The cause of impairment is uncertain but urbanization is suspected. Process The GWR system consist of 10 capture wells, estimated to extract 10 gpm each, that connect to a common manifold which then passes the combined flow through an influent meter and then a bag filter which removes particulate and other solids. The bag filter is routinely replaced. The filtered flow continues to the stripper air column and collects in the stripper sump. The sump is pumped intermittently through two in series GAC filters and then through the effluent meter before discharging to the outfall. The GAC filters are routinely replaced and disposed of by a contractor service. The system may be shutdown in severe weather, there are on site personnel that routinely check and maintain the system. A new cation replaceable filter was added to reduce the manganese and met the new effluent manganese wqs limits. The owner is required to collect data from various monitoring wells and the capture wells on an annual bases, and submit this data with a report to Aquifer Protection. A copy of the most recent report, 2009, was requested and has been received Table A: Effluent Characteristics Monitoring History Parameters Isopropyl ether 1 Benzene Carbon disulfide 2 Chloroethane Chloroform 1 1, 1 -Dichloroethane ' 1,1-Dichloroethene 1,2-Dichloroethane(total) 1 1,3,5-Trimethylbenzene ' tert-butylbenzene 1 1,2,4-Trimethlybenzene 1 sec-butylbenzene ethylbenzene 1 Methlyene chloride 1 Tetrachloroethene Toluene 1,1,1-Trichlorethane 1 Trichloroethene Vinyl chloride Xylenes(total) Bis(2ethylhexyl) phthalate Naphthalene 1 Phenol 2 Methyl isobutyl ketone 1 2000 Permit X X X X X X X X X X X X X X X X X X X X X X X X 2004 2005 Permit Permit X X X X X X X X X X X X X X X X X :4 Fact Sheet NPDES NCO086827 Page 2 of 5 Footnote: 1. Based on the fact that these constituents were not found at detectable levels in the effluent for at least 12 months, a Major Modification for the permit was granted and issued in 2004, and these parameters monitoring requirements were removed. 2. With no detection for 12 previous months, the Permittee petitioned for the removal of these parameters. The removal was granted and include in the 2005 permit. Permitting Strategy To verify an acceptable cross-section of effluent -based pollutants are monitored to validate the treatment process, the 2009 well data was evaluated. It was noted the wells contained several pollutants in concentrations in excess of the WS water quality standard (see Table B). Table B: Pollutants in Wells in Excess of Water Quality Standards Not currently monitored in effluent except for annual EPA Method 624/625 Acetone Aquatic Life Standard = 2.0 mg/1 wells data maximum = 44.0 mg/1 Chloroethane 1 Water Supply Standard = 12 µg/1 well data maximum = 9100 µg/1 Chloroform 1 Water Supply Standard = 5.6 µg/1 well data maximum = (est) 70 µg/1 cis 1,2 dichloroethylene 1 Water Supply Standard = 0.33 mg/1 well data maximum = 59.0 mg/1 1,1 dichloroethane 1 Water Supply Standard = 6.7 mg/l well data maximum = 8.9 mg/1 Ethylbenzene 1 Aquatic Life Standard = 97 µg/1 well data maximum = 1600 µg/1 Methylene chloride 1 Water Supply Standard = 4.6 µg/1 well data maximum = 33000 µg/1 1,1,1 trichloroethane 1 Aquatic Life Standard = 2.5 mg/1 well data maximum = 24.0 mg/1 1 Monitored in 2000, removed from permit 2004 Currently monitored in effluent Benzene Water Supply Standard = 1.19 µg/1 1,1 dichloroethylene Water Supply Standard = 0.33 mg/1 Tetrachloroethylene Water Supply Standard = 0.7 µg/1 Toluene Aquatic Life Standard = 11 µg/1 Trichloroethylene Water Supply Standard = 2.5 µg/1 Vinyl chloride Water Supply Standard = 0.025 µg/1 Total xylenes Aquatic Life Standard = 0.67 mg/l well data maximum = 120 µg/1 well data maximum = 5.4 mg/l well data maximum = 2300 µg/1 well data maximum = 32000 µg/1 well data maximum = 5700 µg/1 well data maximum = 6100 µg/1 well data maximum = 9.0 mg/1 Fact Sheet NPDES NCO086827 Page 3 of 5 The 2008- 2010 DMR data including the annual EPA Method 624/625 (Full suite) was reviewed. Pollutants of interest, solvents and chlorinated compounds, were reported as no detects indicating the treatment system was performing satisfactory. No changes to the 624/625 annual monitoring requirement is recommended. The Permittee has requested removal of bis (2-ethylhexyl) phthalate monitoring. The reported values are less than values but are not consistent repeated values. The newly required Water Supply water quality standard, 1.2 14g/1, and previous Human Health water quality standard, 2.2 µg/1, could not be reconciled against the reported data. In discussions with the Permittee, it was determined that the lab inconsistency was the primary cause. The lab has agreed to provide future values following a minimum detection limit of 1.0 µg/1. Monitoring will remain unchanged in this permit with a minimum detection requirement of 1.0 µg/1. An RPA was performed for iron and manganese, and all organic parameters, using 2008 - 2010 DMR data and applying the applicable water supply standards. Since iron is an action level parameter, and all the toxicity tests were passed, monitoring was reduced to quarterly. The less than detects for the monitored organics by default yielded no justification to add limits. However, 8 of the reported manganese values were above its newly defined Water Supply water quality standard so a chronic limit will be added. To be consistent with EPA policy, both a monthly and daily limit of 200 µg/1 will be applied. Since this is a new limit as a result of the stream reclassification to WS -V in 2009, the Permittee consultant was contacted about the new manganese limits. The consultant responded that a new filter canister (disposable cation media) installation would be required to meet the new limits with a June 2011 completion date. Based on comments from CG&L, no A to C required, and the anticipated effective date on the renewed permit the Division foresee on compliance concerns. A review of the latest well data, influent to the treatment works, continue to show the existing monitored organic parameters as the pollutants of concern. No changes are recommended for the existing organic parameters monitoring. Two additional organic parameters, not previously monitored in the effluent, and in significant excess above water quality standards in the well data were noted, acetone and cis-1,2dichloroethlyene. However, acetone and cis -1,2 dichloroethylene should be easily reduced to below WQS by the current treatment process so quarterly monitoring will be added to the permit as validation. To be consistent with EPA policy, TSS will receive both a monthly and daily limit of 30 mg/l. Based on the current NSW Jordan Rules this facility is not required to monitor nutrients so Total Nitrogen monitoring will be removed. Oil and Grease monitoring will continue and a new narrative statement about oily sheen in the discharge will be added. Quarterly pH monitoring will be added to validate no issues. The receiving stream is impaired for zinc so quarterly zinc monitoring will be added. Toxiary TESTING: Since 2005 the Permittee has conducted 19 chronic toxicity tests and had no failures. No changes are recommended. The narrative will be updated to the current version. Fact Sheet NPDES NC0086827 Page 4 of 5 SUMMARY OF PROPOSED CHANGES In keeping with Division policies the following will be incorporated into the permit: • Monthly and daily limits for manganese will be added. • Quarterly acetone and cis-1,2dichloroethylene monitoring will be added. • Total nitrogen monitoring will be removed. • Total iron monitoring will be reduced to quarterly. • Quarterly pH and zinc monitoring will be added • Monthly TSS limit will be added. • A footnote narrative defining the minimum report limit of 1.0 µg/1 for bis (2- ethylhexyl) phthalate will be added. • The chronic toxicity special condition narrative will be updated. • A narrative condition not allowing an oily sheen to be visible or traceable to the discharge will be added. • Supplement page treatment system list will be updated. PROPOSED SCHEDULE FOR PERMIT ISSUANCE Draft Permit to Public Notice: April 27, 2011 Permit Scheduled to Issue: August 2011 NPDES DIVISION CONTACT If you have questions regarding any of the above information or on the attached permit, please contact Ron Berry at (919) 807-6396 or email ron.berryp@� ncdde�nr.go/v. NAME: DATE:al o ` REGIONAL OFFICE C0MN[ENTS NAME: DATE: SUPERVISOR: DA Fact Sheet NPDES NCO086827 Page 5 of 5 NCDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins Dee Freeman Governor Director Secretary April 29, 2011 MEMORANDUM To: Michael Douglas NCDENR / DEH / Regional Engineer Raleigh Regional Office From: Ron Berry NCDENR / DWQ / NPDES – Complex Group Central Raleigh Office Subject: Review of draft NPDES Permit NCO086827 Brenntag Southeast, Inc. GWR Durham County Please complete this form to indicate your agency's position or viewpoint on this draft permit and return to me by May 18, 2011. If you have any questions on the draft permit, please contact me at telephone number (919) 807-6396 or via e-mail at ron.berry@ncdenr.gov. RESPONSE: (Check one) Concur with the issuance of this permit provided the facility is operated and maintained properly, the FYI stated effluent limits are met prior to discharge, and the discharge does not contravene the designated water quality standards. ❑ Concurs with issuance of this permit, provided the following conditions are met: 1-1 Opposes the issuance of this permit, based on reasons stated below, or attached: Signed MDate: 1617 Mail Service Center, Raleigh, North Carolina 27699-1617 Location: 512 N. Salisbury St. Raleigh, North Carolina 27604 One Phone: 919-807-63001 FAX: 919-807-64921 Customer Service: 1-877-623-6748 North (Carolina Internet: www.ncwaterquality.org ��atitra!!� An Equal Opportunity 1 Affirmative Action Employer Pudic Notice Nath Cardin Environmental Management Co mmis®aNJPDES Unit 1617 Mail Service Center • Raleigh. NC 27699.1617 Notice of Intent to Issue a NPDES Wastewater Permit The Nath Carolina Environ, mental Maregsmert Commis e era un Blow Written comments regarding I �I� the ted until permit will be as l}Gv�l ac- cepted until 30 days after the publish date of this not! The Director of the NC Division of Water Quality (E)WO) may hold a public hearing should there be a significant degree of pubic interest. Please mall Affidavit of Publication comments andlor information requests to DWQ at the above address Interested perms may visit the DWQ at 512 N. Salisbury Street. Raleigh. NC State of North Carolina, to review information at file Additional information on Durham Count NPDES permits and this notice Y may be found on our website: hftp://portW.node v. orghrabAwq /swpips/npdeshalendar. or by telling (919) W7-6UX. To Whom It May Concern: Brenntag Southeast Inc. has requested renewal of permit This is to certif the NC 27 for the Branntag Y facility in Durham County; this Advertisement attached ground aterr ttogan 'unr6eedd tributary to Third Fork Creak in Hereto has been published the Cape Feer River Basin in - The Herald Sun on the following dates: S�- Sworn o on this day of —72011 0-0 -a &4:�" Herald Sun Representa4ve Sworn to and Subscribed Before me this ;1 day of C In ►� f- , 2011 Nbtak!� Public �,0 whuvu i� p,�Ptw, 7Ia0l I Brenntag Southeast, Inc. REASONABLE POTENTIAL ANALYSIS NCO086827 H REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION Qw (MGD) = 0.01 WWTP/WTP Class: I 1Q10S (cfs) = 0.00 IWC 1Q10S = 100.00% 7Q10S (cfs) = 0.00 IWC 7Q10S = 100.00% 7Q10W (cfs) = 0.00 IWC 7Q IOW = 100.00% 3OQ2 (Cfs) = 0.00 IWC ® 30Q2 = 100.00•/6 Avg. Stream Flow, QA (cfs) = 0.00 IWC @ QA = 100.00% Receiving Stream: UT to Third Fork Creek Stream Class: WS -V, NSW Outfall 001 Qw=0.0144 MGD PARAMETER STANDARDS & CRITERIA (2) H REASONABLE POTENTIAL RESULTS RECOMMENDED ACTION TYPE -J F NC WQS / Applied `/2 FAV / I1 #Det Max Pred Allowable Cw (1) � Chronic Standard Acute Cw Acute: NO WQS Iron (AL) NC 1 FW(7QIOs) mg/I 23 17 1.1 Chronic: - ^ 1.00 RPA for AL(Cu,Zn,Ag,Fe,CI) - apply Quarterly No value > Allo"able Cw Monitoring in conjunction with TOX Test Acute: NO WQS Manganese NC 0.2 FW(7QIOs) mg/i 23 22 4.8 _ _ ronic _ _ Ch0.20 RPA for non -AL - apply Monthly Monitoring with Limit 8 \alue(s) > Allowable Cw may add compliance table Acute: NO WQS Benzene C 1.19 WS(Qavg) pg/l 10 0 0.5 _ _ _ _ _ Chronic 1.14 No RPA, Influent exceeds Allowable Cw - apply No value > Allowable Cw Quarterly Monitoring Acute: NO WQS B19(2-ethylhexyl) phthalate C 1.2 WS(Qavg) pg/1 10 0 7.4 _ _ _nic _ Chro1.20 RPA for non -AL - but vailues Athan WQS and 10 val uc(s) > Al lowahle C%� variable detect- apply special condition Acute: NO WQS 1,1-dlchloroethylene NC 330 WS(7QIOs) pg/l 10 0 0.5 _ _ Chronic 330.00 No RPA , influent exceeds Allowable Cw - apply No value > Allowable C'w Quarterly Monitoring Acute: NO WQS Tetrachloroethylene C 0.7 WS(Qavg) pgA 10 0 0.5 _ _ hronic _ _ C 0.70 No RPA, Influent exceeds Allowable Cw - apply 10 value(S)> Allowable C%% Quarterly Monitoring Acute: NO WQS Toluene NC 11 FW(7QIOs) pgA 10 0 0.5 _ _ _ _ _ -------- _ -W Chronic 11.00 _ _ _ No RPA , Intluent exceeds Allowable Cw -apply No value > AlkMable Cw Quarterly Monitoring Acute: NO WQS Trichloroethylene C 2.5 WS(Qavg) pg/l 10 0 0.5 _ _hronic _ _ C 2.50 No RPA, Influent exceeds Allowable Cw - apply No value > Allowable C'w Quarterly Monitoring Acute: NO WQS Vinyl chloride C 0.025 WS(Qavg) µg/l 10 0 0.5 _ Chronic 0.03 _ _ _ RPA but all values < than detect & applicable PQL - 10 caluc(S) > Allo apply Quarterly Monitoring influnet high Acute: NO WQS lNo Total xylenes NC 670 FW(7QIOs) pgA 10 0 1.0 _nic _ _ _ Chro670.00 RPA , Influent exceeds Allowable Cw - apply No value > Allowable Cw Quarterly Monftoring; 2011 RPA, rpe Page 1 of 1 2!22/2011 REASONABLE POTENTIAL ANALYSIS . 1 02531 1.2155 23 3.8500 1.3 mg/ 4.8 m9ll + : 2011 RP& data 2222011 Iron (AL) l Manganese Date Dalt BDL=1/2DL Results • - Date Data 6DL=I2DL Results 1 10282008 0.0989 0.0989 Std Dev 0.1188 1 10282008 00233 0.0233 Std Dev_ 2 12/32008 0.42 0.42 Mean 0.1535 2 12/32008 0.265 0.265 Mean 3 1272009 0.38 1 0.38 C. V. 0.7738 3 1272009 0.0798 0.0798 CV 4 2272009 0.347 0.347 n 23 4 2272009 0.286 0.286 n 5 3262009 0.05 0.025 5 3262009 0.135 0.135 6 4282009 0.268 0.268 Muft Factor = 2.6300 6 428/1009 0.219 0.219 Mutt Factor = 7 5282009 0.107 0.107 Max Value 04 m9A 7 5282" 1.25 1.25 Max. Value 8 6/182009 0.0578 0.0578 Max Pred Cw 1.1 mgA 8 6/18/2009. 0.0345 0.0345 Max. Pred Cw 9 7282009 0.116 0.116 9 7282009 0.0241 0.0241 10 8242009 0.05 0.025 �� ; 10 8242009 0.015 0.0075 11 9292009 0.1 0.1 11 9292009 0.0241 00241 12 10/202009 0.0914 0.0914 12 10202009 0.0535 0-0535 13 12/12009 13 12/12009 14 12/212009 14 1222009 15 12/32009 15 12/32009 16 12/42009 ' 16 12/42009 17 12/52009 17 12)52009 18 1262009 18 12162009 19 12!72009 19 12/72009 20 12/82009 20 12/8/2009 21 12192009 t41 21 12/92009 22 23 12/102009 12/112009 , , • ° 22 12/102009 23 12/112009 24 12/122009 24 12/12/2009 25 12/13/2009 25 12/132009 26 12/142009 0.05 0.025 26 12/142009 0.0878 0.0878 27 12/192009 27 12/192009 28 12202009 28 12202009 29 12212009 1 29 1221/2009 30 12222009 30 12222009 31 12232009 31 1223/2009 32 12242009 32 12242009 33 12252009 , 33 12252009 34 12262009 1 34 12262009 35 12272009 35 12272009 ,.. y .. 36 12282009 12/28/2009 37 12292009 37 12292009 r 38 121302009 38 12/302009 39 12x312009 39 12/'312009 40 1112010 40 1/12010 41 122010 41 122010 42 1132010 42 1 /3/2010 43 1/4/2010 43 1/4/2010 44 1/5/2010 44 1 /512010 45 1/612010 45 116/2010 46 1t712010 46 1172010 47 1/8/2010 47 1 /32010 48 1/92010 48 1/9/2010 49 1 /102010 49 1/10/2010 50 1n 12010 50 1/112010 51 1/12/2010 51 1/122010 52 V13/2010 52 1/132010 53 11152010 53 1/152010 54 1 M 62010 54 1/1612010 55 1/17/2010 55 1/17/2010 56 1 n 82010 56 1118/2010 57 1/192010 57 1/19/2010 58 1262010 0.1 0.05 58 1262010 0.13 0.13 59 2/1/2010 59 2112010 60 22/2010 60 2/7/2010 61 2162010 61 2/62010 62 2!72010 62 2!72010 63 2/82010 63 2/6/2010 64 2192010 - - - _ - - 64 Z9/2010- 192010-65 65 2/102010 t i 65 2/10/2010 66 67 2/112010 2/122010 l�� i {Q„�t�1 ' �+ 66 67 2/112010 , 2/122010 SS, 68 2/132010 PP 1111T ", I 68 2/132010 { 't 69 21142010 69 2/14/2010 02531 1.2155 23 3.8500 1.3 mg/ 4.8 m9ll + : 2011 RP& data 2222011 SUMMER HILLSBOROUGH WWTP 3.0 MGD SUMMER 7Q10 = 0.4 CFS ---------- MODEL RESULTS ---------- Discharger : HILLSBOROUGH WWTP Receiving Stream : ENO RIVER ------- The End ------ D.O. ---------- -----------_-------- i s 7.84 mg/ 1. - � � --- ----------------------------- --�- - -- - --- -� -- -- • The End CBOD is 1..41 mg/1. The End -------------------- NBOD is 0. 6 mg/1. -------------- ---------------------------------- WLA WLA WLA DO Min CBOD NBOD DO Waste Flow (mg/1) M lepoi Reach # (mg/1) (mg/1) (mg/1) (mgd) Segment 1 ------ -- ----- 5.13 0 ------- 1 ---- ---- -- ---------- Reach 1 7.50 9.00 5.00 3.00000 Reach 2 0.00 0.00 0.00 0.00000 Reach 3 $ tom- 0.00 0.00 0.00 0.00000 Reach 4 0.00 0.00 0.00 0.00000 Reach 5 r 2 � 3 0.00. 0.00 0.00 0.00000 rT.T-.. r~t' WI A v. j ,..�. -L-�JDji, .. ;v,.-AOD . . (mq r U.Ui; JC I REASONABLE POTENTIAL ANALYSIS 70 2!152010 70 2/152010 71 2/162010 71 2/162010 72 2/172010 :,�, i 72 2/172010 err i ; r 73 2242010 0.11 0.11 73 224!2010 0.19 0.19 74 3/52010 74 3152010 75 3/672010 � 75 3/6/2010 76 3/72010 76 3/72010 77 3182010 77 3!82010 11..1 (.�•hi '�i : •! 78 3/92010 78 3/92010 79 3!102010 79 3/102010 s 80 3/112010 80 3/112010 ,. 81 3/122010 2011 RPA, data r 81 3/122010 82 3/132010 82 3/132010 83 3/142010 83 3/142010 84 3/152010 84 3/152010 85 3/1612010 85 3/162010 86 3/172010 86 3/17/2010 87 3/182010 87 3/182010 88 3/192010 88 3/192010 69 3202010 89 3202010 90 3212010 90 3212010 91 3222010 91 322/2010 92 3242010 0.1 0.05 92 3242010 0.18 0.18 93 4/132010 93 4/132010 94 4/142010 94 4/142010 95 47152010 95 4/152010 96 4/16201096 . 4/162010 _ �. 97 4/172010 97 4/172010 f 98 47182010 98 4/182010 99 4/192010 99 4/192010 100 4202010 100 4/202010 101 4212010 F 101 4/212010 102 4222010 r .; �o , _ t. 102 41222010. :y 103 4272010 0.23 0.23 103 4272010 0.17 0.17 104 5272010 z'' 0.11 0.11 ; 104 5272010 0.092 0.092 105 6242010 '' 0.1 0.05 105 6242010 0.069 0 069 106 7272010 0.27 0.27 106 7272010 044 0-44 107 8232010 ';I? 0.22 0.22 107 8232010 0.6 0.6 108 9272010 " 0.23 0.23 108 9272010 0.79 0.79 109 10/192010 0.15 0.15 , 109 10/192010 0.67 0.67 1 2 110 110 :,�, i • ��, ��. r err i ; r � �'., 1� ra tF i { ,�� �ry: �. , � iii Yt ::, t{ :I. 11..1 (.�•hi '�i : •! k .,a `'1 ' I! T(rl . R, T ', ��F 1j1 ar�. lt.' �f�.y . ��'`' _'may.(• { 1 s i t ,. t 2011 RPA, data r -2- 2/22/2001 A14!ice fxj;;i x,786`'8 0.5; '�<S 46 1 5 13.7 ►„�` $ .46 84� Seg # Reach • # . Seg 'Mi 1;1.a). . +' , �, Q iJ D •i REASONABLE POTENTIAL ANALYSIS 2011 RPA� data -2- ' 2222041 Benzene Bis(2-ethylhexyl) phthalate Date Data BDL=112DL Results• - Date Dale BDL--Ir2DL Results • ' 1 7/22/2008 4 1 05 Std Dev. 0.0000 1 7/2212008 c 11.1 5.55 Std Dev_ 0.4490 2 101282006 4 1 0.5 Mean 0.5000 2 102820w 11.1 5.55 Mean 5.2365 3 1272009 �; 1 0.5 C.V. 0.0000 3 1272009 oi; 9.43 4.715 C. V 0.0857 4 4282009 -6 1 0.5 n 10 4 4282009 a":; 10.5 5.25 n 10 5 7282009 :. 1 0.5 5 7282009 :: 10.4 5.2 6 10202009 1 0.5 Mult Factor = 1.0000 6 10/202009 9.7 4.85 Mutt Factor = 1.1900 7 1262010 1 0.5 Max. Value 0.5 NgA 7 1262010 10 5 Max Value 6.3 NgA 8 4272010 1 0.5 Max. Pred Cw 0.5 NgA 8 4/772010 10 5 Max Pred Cw 7.4 N9A 9 7272010 1 0.5 9 7272010 10 5 10 10/192010 1 0.5 10 10/192010 12.5 6.25 11 11 2011 RPA� data -2- ' 2222041 Seg # Reach # Seg Mi D.O. 1 1 0.00 5.18 1 1 0.28 5.14 1 1 0.57 5.13 1 1 0.85 5.15 1 1 1.13 5.19 1 1 1.42 5.25 1 1 1.70 5.32 1 1 1.98 5.39 1 1 2.27 5.48 1 1 2.55 5.56 1 1 2.84 5.65 1 1 3.12 5.74 1 1 3.40 5.83 1 1 3.69 5.92 1 1 3.97 6.00 1 1 4.25 6.09 1 1 4.54 6.17 1 1 4.82 6.25 1 1 5.10 6.33 1 1 5.39 6.40 1 1 5.6 6.47 1 2 5.67 6.47 1 2 5.93 7.13 1 2 6.19 7.45 1 2 6.45 .62 1 2 6.71 71 1 2 6.97 7.76 1 2 7.23 7. 9 1 2 7.49 7.8 1 3 7.49 7.8 1 3 7:74 7: 1 3 8:00 7. 7 1 3 8:25 7.48 1 3 8.51 .41 1 3 8.76 7.36 1 3 9.01 7.33 1 3 9.27 7.31 1 3 9.52 7.29 1 3 9.7 7.28 1 3 10: 3 7:28 1 3 10.28 7.29 1 3 .54 7.30 1 3 0.79 7.31 1 3 11:05 7.32 1 3 11.30 7:34 1 4 11.30 7.34 1 4 11.53 7.63 1 4 11.76 7:78 1 4 11,99 7:87 1 4 12:22 7.92 1 4 12.45 7..95 1 4 12.68 7.96 1 5 12.68 7:96 1 5 12.89 7.93 1 5 13.10 7.90 -1 a i 5 13.31 7.88 SUMMER HILLSBOROUGH WWTP 3.0 MGD SUMMER 7Q10 = 0.4 CFS CBOD NBOD Flow 7.06 8.37 5.05 6.83 7.92 5.06 6.61 7.49 5.07 6.39 7.09 5.08 6.18 6.71 5.08 5.98 6.35 5.09 5.78 6.01 5.10 5.59 5.69 5.11 5.41 5.38 5.12 5.23 5.09 5.13 5.06 4.82 5.14 4.89 4.56 5.14 4.73 4.32 5.15 4.58 4.0 5.16 4.43 3 7 5.17 4.28 .66 5.18 4.14 3.46 5.19 4.01 3.28 5.19 3.88 3.10 5.20 3.75 2.94. _ 5.21 3.6 2.:78:, 1--15.22 3. 2.78'', 5.22 -3' 3 2.62 5:23 .44 2.47 5.24 .35 2.32 5.24 3.27 2:19 5.25 3.18 2.06 5.26 3.10 1.94 5.27 3.02 1:83 5.27 3.02 �:83 5.27 2.93 1:73 5:28 2:83 1.64 5:29 2.74 1.56 5.30 2.66 1.47 5.31 2:57 1:40 5.31 .49 1.32 5.32 2 41 1.25 5.33 2. 4 1.19 5.34 2: 6 �.12 5.34 2.'1 1.06 5:35 2:1 1.01 5:36 2.06 0.96 5.37 1.99 0.91 5.37 1.93 0:86 5.38 1.87 0.81 5.39 1.87 0.81 5.39 1:83 0.'77 5.40 1:79 Q:73 5.40 1:74 0.'69 5:41 1:70 0.65 5:42 1.67 0.62 5.42 1.63 0.59 5.43 1.63 0.59 5.43 1.59 0:56 5.44 1.55 0.54 5.44 1:51 0.'52 5.45 REASONABLE POTENTIAL ANALYSIS 2011 RPA, data - 3 - 22220x11 1,1 -dichloroethylene Tetrachloroethylene Date Data BDL=IrML Results • . Date Data 6DL=I/2DL Results Values" MT,' • - 1 7222008 a 1 0.5 Std Dev 0.0 1 7222008 c 1 05 Std Dev 0.0000 2 1028200B ,,*', 1 0.5 Mean 0.5 2 10282008 ci 1 0.5 Mean 05000 3 1272009 1 0.5 C.V. 0.0 3 1272009 1 0,5 C V 0.0000 4 4282009 ;, 1 0.5 n 10.0 4 4282009 1 0.5 n 10 5 7282009 _ 1 0.5 5 7282009 1 0.5 6 10202009 `. 1 0.5 Muff Factor = 1.0 6 10202009 1 0.5 Mutt Factor = 1.0000 7 1262010 ;' 1 0.5 Max Value 0.5 NgA 7 1262010 1 0.5 Max_ Value 0.5 NgA 8 4272010 1 0.5 Max. Pred Cw 0.5 NgA 8 4272010 1 0.5 Max. Pred Cw 0.5 NgA 9 7272010 1 0.5 9 7272010 1 05 10 101192010 ,' 1 0.5 10 10/19/2010 1 0.5 11 11 2011 RPA, data - 3 - 22220x11 C 0000010 00'0 00'0 0010 c) �S 9 140eaH 00000'0 00'0 00'0 00'0 S goleaH 00000'0 00'0 00'0 00'0 uoleaH 00000'0 00'0 00'0 00' E uDleaH 00000'0 00'0 00'0 00 0 z uoleaH 00000'1 00'S 08'0 'z T uolegH T%9'T LT'S T :tuaw6as -- (Pf5m) --- WSW) (1/Sul) (1/Sul) # Kalea quTodalTw (1/6ui) Moja a:lsleM OQ MEN aOSO UTw OQ ------------ --------------------------------------------------------- *115W So'o ST aOE[N PUS aus ' 1/ btu 0 E' 0 S T aOSO Pus aT4i '1/6w E6•L ST 'O'a Pus aw, ---------------------------------------------------------------------- ------ -- — --- --- -- - - - - 2iSAI2i- OI�iS IUVQagS 6UTAT909H dIMM HJAOHOSS'IZIH : za6zleuasTa ---------- Ssznssu zsaow---------- oToz Os 600z sacmaAv uwa SOTOL SaD VO ' ,daw Ills ' REASONABLE POTENTIAL ANALYSIS Toluene. ; , , Trichloroethylene Date Data BDL=I2DL Results ,U Date Data BDL=I2DL Results SOMMOji " 1 7/2212008 < 1 05 Std Dev 00000 1 722/2008 1 05 Std Dev 0.0000 2 10/28/2008 + 1 0.5 Mean 0.5000 2 102811008 1 0.5 Mean 0.5000 3 1272009 t: 1 0.5 C.V. 0 0000 3 1/772009 1 0.5 C V. 0.0000 4 4282009 C, 1 0.5 n 10 4 4282009 1 0.5 n 10 5 7282009 :!4 1 0.5 5 7282009 1 0.5 6 10202009 < 1 0-5 Mult Factor = 10000 6 10202009 1 0.5 Mutt Factor = 1.0000 7 1262010 1 0-5 Max. Value 0.5 Ng/l 7 1262010 1 0.5 Max. Value 0.5 Ngll 8 4272010 1 0.5 Max. Pred Cw 0 5 Ng/I 8 4272010 1 0.5 Max- Prod Cw 0.5 Ngn 9 7272010; 1 0.5 9 7272010 1 0.5 10 10/192010 1 0.5 10 10/192010 1 0.5 11 11 , 2011 RPA, data - 4 - 2/22 Ql 1 ? 15 1 00000'0 00'0 00'0 00'0 9 -gova-d 00000,0 00*0 00*0 00.0 -G� f�� S T.jDLag 00000'0 00'0 00'0 00'0 00000' 0 0010 00' 0 00' £ 110'e;DH 00000.0 00.0 00' 0 00' z, uoleaH 00000'£ 00'S 00'6 0 'L T uoieaU T Ti9 ' T S S' T T quain6as (P6tu) WSW) (T/Sul) (T/btu) # rga2aH :IuiodaTTW (T/bw) Moja a:ISeM OQ QOEIN QOHO Urw OQ V IM v'IM vum ---------------------------------------------------------------------- ' T /6ul 9 S' 0 el QOHN puS 9'q L 'T/6u' TV'T ST QOHO PUH au,L --- - - - --- -- -. _.. _ ' T/bw VL G Si 'O'Q PUS auy ---------------------------------------------------------------------- 2iSAI2i ONS s Me;9.z'4S 6utAT909H dIMM HJAOHOHS'I'IIH : za6zEu�SiQ ---------- sirmsS?i 'ISaow ---------- TT/6Z/£ S.LIWI'I ZINHHd `NIISIXS SOTOL SaD rv' 0 damns REASONABLE POTENTIAL ANALYSIS Total xylenes Vinyl chloride Results 2 1 Std Dev 2 1 Mean Date Data C.V. BDL=l2M Results • - Date Data 1 71222008 e 1 05 Std Dev_ 0.0000 1 72212008 <. 2 10/282008 ± 1 0.5 Mean 0 5000 2 10282008 3 1272009 •, 1 0.5 C V. 0.0000 3 11272009 4 4282009 1 0.5 n 10 4 4282009 5 7282009 1 0.5 5 7282009 6 101202009 1 0.5 Mull Factor = 1.00 6 10202009 'cwi 7 1262010 1 0.5 Max. Value 0.5 Fg/I 7 1262010 8 4272010 1 0.5 Max. Pred Cw 0.5 pg/1 8 4272010 9 7272010 1 0.5 9 7272010 #' 10 10/192010 1 0.5 10 10/192010 11 11 Total xylenes BDL=120L Results 2 1 Std Dev 2 1 Mean 2 1 C.V. 2 1 n 2 1 2 1 Mutt Factor = 2 1 Max- Value 2 1 Max. Pred Cw 2 1 2 1 1.00 0.00 10 1.0000 1.0 Ngo 1.0 Ngrl 2011 RPA, data - 5 - 2/2212011 . Mot3 aosN a0w) 'O'Q Tw bag bas vZ' S LS' 0 E5, 1 ZL' L TS' E 9 T ilZ' S LS' 0 ED, T ZL' L Lri' £T 9 T tz, S 8S'0 :V:'T ZL'L EV ET 9 T tiZ' S 8S' 0 SVT ZL' L 6E' £T 9 T EZ'S 85'0 SVI ZL'L SUET 9 T EZ'S 6S'0 9V T ZL'L TE'ET 9 T EZ'S 6S'0 LV T TL'L LZ'ET 9 T EZ'S 0910 LV T TL'L EZ'ET 9 T EZ'S 09'0 8TIIT TL'L 6T' 9 T EZ'S 19'0 6VI TL'L SUET 9 T EZ'S 1910 6V T TL'L 'ET 9 T EZ'S Z9' OS'T TL'L LVET 9 T ZZ'S Z9'0 TS'T OL'L EO'ET 9 1 ZZ'S E9'0 ZS'T OL' 667ZT 9 T ZZ'S E9'0 ZS'T 0 'L S6'ZT 9 T ZZ'S t,9'0 ES'T 'L 16'ZT 9 T ZZ'S t,9'0 S'T OCL L8'ZT 9 T ZZ'S S9'0 'T OCL E8'ZT 9 T ZZ'S S9'0 S 'T 69'L 6L'ZT 9 T ZZ'S 99'0 95' 69'L SL'ZT 9 T ZZ'S 99'0 LS' 69'L TL'ZT 9 T TZ'S L9'0 'T 69'L L9'ZT 9 T TZ'S L9'0 8S'T 69'L E9'ZT 9 T TZ'S 89'0 6S'T 69'L 6S'ZT 9 T TZ'S 89'0 09'T 89'L SS'ZT 9 1 TZ'S 69' 09'T 9'L TS'ZT 9 T TZ'S 6 0 19'1 8 'L LVZT 9 T TZ'S L'0 Z91T 8 'L EV ZT 9 T TZ'S OL'0 E9'T 89 L 6E'ZT 9 T OZ'S TL'0 E9'1 89'L S£'ZT 9 T OZ'S ZL'0 fii9'T L9'L TE'ZT 9 T OZ' ZL'O S9'1 L9'L LZ'ZT 9 T 0 S EL'0 99'1 L9'L EZ'Z1 9 T 'S EL'0 L9'T L9'L 61'ZT 9 T OZ'S tL'O L9'T L9'L S1'ZT 9 T OZ'S tL'0 89'T L9'L TT'ZT 9 T OZ'S SL'0 69'1 L9'L LO'ZT 9 T 6T'S 9L'0 OCT L9'L EO'ZT 9 T 6T'S 9L'0 TL'T 99'L 66'11 9 T 6T'S LL'O TL'T 99'L S6'TT 9 T 6T'S LL'0 ZL'T 99'L T6'TT 9 T 6T'S 8L'0 EL'T 99'L L8'TT 9 T 6T'S 6L'0 TL'T 99'L E8'TT 9 T 6T'S 6L'0 SL'T 99'L 6L'TT 9 T 6T'S - 08'0 - SL'T -- -99'-L - SUIT 9 T 6T'S T8'0 9L'T 99'L TL'TT 9 1 8T'S T8'0 LCT 99'L L9'TT 9 T 8T'S Z8'0 8L'T 99'L E9'11 9 1 81'S Z8'0 6L'T 99'L 6S'TT 9 T 8T'S E8'0 08'T S9'L SS'TT 9 T 8T S. t8'Ci TO T' .�, 9.9`L TS'TT 9 '� f Verbal description of GWR treatment operation Brenntag Durham from phone call 1/19/11 with James O Shilliday. 9 active collection wells (pneumatic driven) tie to common manifold which passes the combined flow through a bag filter to remove particulate and other solids. The bag filter is routinely replaced. The filtered flow continues to the stripper column and collects in the stripper sump. The sump is pumped intermittently through two in series GAC filters and then through the effluent meter before discharging to the outfall. The GAC filters are routinely replaced and disposed of by a contractor service. The system may be shutdown in severe weather, there are on site personnel that check and maintain the system. Note: Requested a copy of the last groundwater well analysis report. Mr. Shilliday asked bout the removal of the Bis compound monitoring from the permit. x J v J TABLE 3 OF 503.13. POLLUTANT CONCENTRATIONS Pollutant Monthly average concentration (milligr per kilogram)' Arsenic................................................ Cadmium............................................. Copper................................................ Lead................................................... Mercury.............................................. Nickel............................ ................. Selenium.............................. ......... Zinc........................................... ... 41 39 1500 300 17 420 100 2800 Dry weight basis. TABLE 4 OF 503.13. ANN L POLLUTANT LOADING RATES Annual pollutant loading rate /pollutant (kilograms per hectare per 365 day period) Arsenic.... ......................................... 2.0 Cadmium... .......................................... 1.9 Copper................................................ 75 Lead................................................... 15 Mercury............................................... 0.85 — ._.._— Y---- --- - - 21 - Nickel...._ ...:. ............. ..,.- Selenium.............................................. 5.0 Zinc.................................................... 140 Sludge sold or given away in a bag or container cannot exceed the ceiling concentrations illustrated in Table 1. Sludge land applied must either not exceed the cumulative loadings in Table 2 or must be less than the limits in Table 3 (high quality sludge). Sludge applied to a lawn or home garden must comply with the limits in Table 3. If sludge is sold or given away in a bag \\G-PC1\D805\FTL\2007\CL.201P06.TXT 37 NC 2010 Integrated Report Categories 4 and 5 Impaired Waters All 13,123 Waters in NC are in Category S -303(d) List for Mercury due to statewide fish consumption advice for several fish species AU Number AU_Name AU_Description LengthArea AU_Units Classification Category Parameter Reason for Rating Use Category Collection Year 303(d)year Cape Fear River Basin B Everett Jordan Lake -New Hope River Watershed 0303000206 Q 16-41-(0.5) New Hope River Arm From source at confluence of Morgan Creek 1,199.8 FW Acres WS - of B. Everett Jordan and New Hope Creek Arm of B. Everett IV,B;NSW,CA Lake (below normal Jordan Lake (a east -west line across the pool elevation) southern tip of the formed penisula) to Chatham Co 4t Chlorophyll a Standard Violation Aquatic Life 2008 2008 0` 0 5 Turbidity Standard Violation Aquatic Life 2008 2008 `V Q 16-41-1-17-(0.7)a Northeast Creek From US Hwy 55 to Durham Triangle WWTP 3.3 FW Miles WS-IV;NSW 5 Copper Standard Violation Aquatic Life 2008 2008 4t Fecal Coliform (recreation) Standard Violation Recreation 2008 1998 �n 5 Low Dissolved Oxygen Standard Violation Aquatic Life 2008 2008 5 Turbidity Standard Violation Aquatic Life 2008 2008 Q 16-41-1-17- Northeast Creek From Durham Triangle WWTP to Kit Creek 3.3 FW Miles WS-IV;NSW 3 (0.7)bl 5 Zinc Standard Violation Aquatic Life 2008 2008 v Q 16-41-1-17- Northeast Creek From Kit Creek to a point 0.5 mile 3.2 FW Miles WS-IV;NSW (0.7)b2 downstream of Panther Creek 5 Copper Standard Violation Aquatic Life 2008 2008 4t Fecal Coliform (recreation) Standard Violation Recreation 2008 1998 ✓j 5 Turbidity Standard Violation Aquatic Life 2008 2008 A 5 Zine Standard Violation Aquatic Life 2008 2008 v Q 16-41-1-12-(1) Third Fork Creek From source to a point 2.0 miles upstream 5.2 FW Miles C;NSW of NC Hwy. 54 4s EcologicaUbiologial Integrity Benthos Poor Bioclassification Aquatic Life 1993 2008 N 4t Fecal Coliform (recreation) Standard Violation Recreation 2008 1998 S Low Dissolved Oxygen Standard Violation Aquatic Life 2008 2008 5 Zinc Standard Violation Aquatic Life 2008 2008 Q 16-41-1-12-(2) Third Fork Creek From a point 2.0 miles upstream of NC 3.9 FW Miles WS-IV;NSW HWY. 54 to New Hope Creek 5 Copper Standard Violation Aquatic Life 2008 2008 4s Eeologial/blologial Integrity Benthos Poor Bioclassification Aquatic Life 1993 2008 4t Fecal Coliform (recreation) Standard Violation Recreation 2008 1998 S Low Dissolved Oxygen Standard Violation Aquatic Life 2008 2008 Cape Fear River Basin Roberson Creek -Haw River Watershed 0303000207 NC 2010 Integrated Report Category 4 and 5 303(d) List EPA Approved Aug 31, 201 9/20/2010 Page 8 of 145 RE Questions.about new limits in Brenntag southeast Inc. GWR NPDES Permit - NC00868272nd reply From: Berry, Ron Sent: Tuesday, March 15, 2011 2:40 PM To: 'shilliday, Jim' Subject: RE: Questions about new limits in Brenntag Southeast Inc. GWR NPDES Permit - NC0086827 Jim, Thanks for the information. For the manganese, prior to issuing the final permit I will send you a draft of the special condition text with a compliance date we will add to the permit. One thing to remember is to include time to obtain an Authorization to construct from the DWQ construction Grants and Loans section. I assume there is no additional waste streams being generated as the CG -8 resin will be replaced once spent. The bis (2-ethylhexyl) phthalate issue is ultimately going to be addressed by the lab ability to 1) provide viable data demonstrating no effluent exceedance of the limit or to 2) provide viable data demonstrating problems with measuring this parameter or to 3) provide viable data demonstrating effluent exceedance of the limit. In any case, we can not wait until the manganese treatment system is in place. Is there some concern about interaction from the treatment system? If there is an analytical problem then we need the lab to advise you on the cause and possible solution which in turn we will require formal documentation. If you have any questions let me know. Ron Ron Berry ron.berry@ncdenr.gov Engineer I DWQ/Point Source/NPDES Complex Permitting unit NCDENR Phone: (919) 807-6396 Fax: (919) 807-6495 office: Archdale Building Room 925N E-mail correspondence to and from this address may be subject to the North Carolina Public Records Law and may be disclosed to third parties. From: shilliday, Jim[mailto:Jim.shilliday@arcadis-us.com] Sent: Tuesday, March 15, 2011 9:49 AM To: Berryy, Ron Cc: BBiehl@brenntag.com; Twamley, David Subject: RE: Questions about new limits in Brenntag southeast Inc. GWR NPDES Permit - NC0086827 Mr. Berry, we have done some research regarding the two issues raised in your e-mail and the below text should address both issues. 1) Treatment of extracted groundwater to reduce manganese concentrations Based on the information that you have provided below and information from the DwQ Page 1 James & James Environmental Management, Inc. + 3801 Asheville Hwy., Hendersonville, N. C. 28791 OFFICE: (828) 697-0063 FAX: (828) 697-0065 April 9, 2010 N. C. Department of Environment and Natural Resources Division of Water Qua.lity/NPDES Unit 1617 Mail Service Center Raleigh, N. C. 27699-1617 \ Regarding All Waste Water Facilitie�\Operated by James & J To Whom It May Concern: This letter is to request the renewal for the Home Park, NPDES number NC0062634. Sincerely Juanita 2es James and James Environmental Mgt., Inc. facility of Wedgefield Acres Mobile 4AIA l/i/�f RE Questions about new limits in Brenntag Southeast Inc. GWR NPDES Permit - NC00868272nd reply website, we understand that Third Fork creek was reclassified to a water supply (ws) stream (actual classification being ws-Iv) on August 11, 2009. The classification of ws-Iv applies to Third Fork creek from its source to a point 2.0 miles upstream of N.C. Highway 54. Because of this reclassification a surface water Quality Standard of 200 micrograms per liter (µg/L) now applies for manganese for surface water in Third Fork creek and its tributaries. The treated groundwater for the groundwater remediation system at the Brenntag Durham facility currently discharges to an unnamed tributary to Third Fork creek; therefore, it appears that our new NPDES Permit will stipulate a discharge limit of 200 Ng/L for manganese. since activation of our groundwater remediation system in 2002, we have detected concentrations of manganese in our discharge at concentrations ranging from a high of around 3,000 Ng/L to a low of <50 Ng/L. The typical manganese concentration range that we have seen over the past 2 years has been <50 pg/L to 380 pg/L. Because the potential exists for our discharge to exceed the 200 pg/L limit for manganese that will be imposed in the new NPDES Permit, we will need to modify our current water treatment system to address manganese. we have engaged in discussions with one of our subcontractors regarding the type of equipment that would be best suited for removal of manganese from our effluent discharge. we supplied the subcontractor with a data summary table that lists the concentrations of manganese that have been detected in the effluent samples for the past several years. Based on our conversation with the subcontractor, they recommend using a strong acid cation resin called CG -8. Reportedly this type of resin is specifically designed to treat metals. To incorporate this technology we would add another vessel for the CG -8 resin after the two granular activated carbon (GAC) vessels. we are working with our subcontractor right now to determine how much resin we would need and how often it would need to be replaced. I anticipate having this data in the next week or so. we would like to have approximately a 3 month timeframe to purchase the new equipment, have it installed, and test it. So I think a realistic timeframe for having this additional equipment up and running is June 30. 2) Reporting limit and NPDES discharge limit for bis (2-ethylhexyl) phthalate As discussed above, it is understood that Third Fork creek and its headwater tributaries were reclassified to a water supply stream (ws-iv) in 2009. Because of this reclassification a surface water Quality standard of 1.2 Ng/L now applies for bis (2-ethylhexyl) phthalate. It is our understanding that our new NPDES Permit will stipulate a discharge limit of 1.2 Ng/L for bis (2- ethylhexyl) phthalate. The standard Method 625 analysis which we have been using Page 2 Permit NCO � 11 ' A. (2) CHRONIC TOXICITY MONITORING (QUARTERLY) -D T The permittee shall conduct uarterl chronic toxicity tests using test proZb outlined in the "North Carolina Ceriodaphnia Chronic Effluent Bioassay Procedure," Revised 1998, or subsequent versions. The effluent concentration defined as treatment two in the procedure d ument is 90 %. The testing shall be performed as a Ceriodaphnia dubia 7day pass/fail test. The to s will be performed during the months of February, May, August, and November. Effluent sampling or this testing shall be performed at the NPDES permitted final effluent discharge below all treatment cesses. All toxicity testing results required as part of this permit coon/on on will be entered on the Effluent Discharge Monitoring Form (MR -1) for the month in which it w performed, using the parameter code TGP3B. Additionally, DWQ Form AT-] (orig*) is to be sent the following address: Attention: NC DENR / Q / En ironmental Sciences Section 1621 Mail Servi Ce er Raleigh, N.C. 276 621 Completed Aquatic Toxicity Test Forms shall be filed :!c Environmental Sciences Section no later than 30 days after the end of the reporting period for w ch the port is made. Test data shall be complete and accurate and inclu all support" chemical/physical measurements performed in association with the toxicity tests, as 11 as all dose/res nse data. Total residual chlorine of the effluent toxicity sample must be measured d reported if chlorine " employed for disinfection of the waste stream. Should there be no discharge of flow: the acility during a month in which toxicity monitoring is required, the permittee will complete the info ation located at the top of the aquatic toxicity (AT) test form indicating the facility name, permit n r, pipe number, county, and the month/year of the report with the notation of "No Flow" in the co ent area of the form. The report shall be submitted to the Environmental Sciences Section at the ad dr ss cited above. Should the permittee fail to monitor d "ng a month in which toxicity monitoring is required, then monthly monitoring will begin imm ately. Upon submission of a valid test, this monthly test requirement will revert to quarterly in a months specified above. Should any test data from this monito ng requirement or tests performed by the North Carolina Division of Water Quality indicate potential " pacts to the receiving stream, this permit may be re -opened and modified to include alternate monit "ng requirements or limits. If the Permittee monitors any pol tant more frequently then required by this permit, the results of such monitoring shall be included in a calculation and reporting of the data submitted on the DMR and AT Forms. NOTE: Failure to achieve to t conditions as specified in the cited document, such as minimum control organism survival, minimu control organism reproduction, and appropriate environmental controls, shall constitute an invalid st and will require immediate follow-up testing to be completed no later than the last day of the mo; following the month of the initial monitoring. RE Questions about new limits in Brenntag southeast Inc. GWR NPDES Permit - NC00868272nd reply to analyze for bis (2-ethylhexyl) phthalate since we first started effluent sampling in 2002 provides a reporting limit (RL) of 10 Ng/L; therefore, we will need to utilize a different analytical procedure for testing for bis (2-ethylhexyl) phthalate that will provide a RL of 1.0 Ng/L. The analytical laboratory that we utilize on this project (Test America) has indicated that they can provide a consistent RL of 1.0 Ng/L for bis (2-ethylhexyl) phthalate using Method 8270 Low Level (LL). Test America will use the full liter of water collected for the analysis, concentrate it to 0.5 milliliters and analyze that extract. This will provide a RL of 1 Ng/L. The new NPDES Permit will need to stipulate use of EPA Method 8270 Low Level for analysis of bis (2-ethylhexyl) phthalate. Please note that because of the ubiquitous nature of bis (2-ethylhexyl) phthalate in all things made of plastic, there is a concern that detections of bis (2-ethylhexyl) phthalate could be associated with plastic piping associated with the groundwater extraction and treatment system. we would like to wait to implement this change in analytical procedures following completion of our installation and testing of the strong acid cation resin unit for treatment of manganese. so this new analytical procedure would be implemented after June 30. Please let us know if you would like to discuss these items in more detail. Thanks Jim From: Berry, Ron [mailto:ron.berrygncdenr.gov] sent: Tuesday, March 01, 2011 3:52 PM To: Shilliday, Jim subject: Questions about new limits in Brenntag Southeast Inc. GWR NPDES Permit - NC0086827 Mr. shilliday: This is a follow up to the a voice message I previously left. I would like to resolve some issues and pending items prior to issuing the draft permit for Brenntag southeast Inc. GWR. We have completed evaluation of all pertinent data for renewing the NPDES permit for Brenntag southeast Inc. GWR. Two significant items you need to be aware of, and we request your input for are: 1) The receiving stream classification was reclassified in 2009 to water supply (WS). As a result, several reported effluent manganese levels already exceed the WS water quality standard, 200 pg/1. our evaluation indicate this discharge will continue to violate the 200 pg/l water quality standard, and as such a limit will be applied in the new permit. we prefer to work with the Permittee to establish a compliance time line that is acceptable by the Page 3 000t•zx »yDs y1JON • • �laas� �anea8 Iwea»S SUTAI3aay 90£06 :Utseggnc d.LM • d xmiS QUI d Ino]y-3 :sszl:) wea»S 3N01a :# Penb Z 9 Z Z 8 0 0 J N ..e£so28 :aPw!$uo'i ..60,SS.S£ :aPrL)!Wj J / ` tr• � , �i � , � � ^moi. •� j�-����+ ' . � ., r ••ate �.! = / ` S•�"H:..� � • / � \\ � ;u_' Lila u w 1 ' � ♦ •\ ( - \� 'U43 lep Ad a q ' _ „ ,�• � j' 1/ !^���a'►• � � '•� t IP4l.�Sf. •� � . � __ � I -tel , i• r ! w�r. lace.:)4"a13 / •I .. ••v }'1 .� - / _'I •s •ter. A Ulu) 966 Oc 811w, 11H mQ j au IN Nk RM 0,19kf .,,L tri � 1, ,1• .J•.� .��� �, -)� I� . - -S•'-• o+t''s� �—. " (:�✓� � ��.- ��^Ff''�1 I SII 1 f �'� i`•; �' a••,` 1 ,! . • i "' I _�ri � ; I \ l�W '�. - II II• �` o I; —f.• j1.��+x i • 1 •).r ��.{�',I ..., �.' ,� t. �,•r'r i;l� ` ..99J�' •'� /�1; ' I,i 'Iau- At_ . \_ *" . _.1 \r1 '^ S Iti 1 I _�_- �'_•. �-, •I�•' (`��y`4' rl I '�•. 9 - RE Questions about new limits in Brenntag southeast Inc. GWR NPDES Permit - NC00868272nd reply Division to allow for design and installation of the necessary treatment equipment. we need to determine a tentative schedule and narrative for this permit. 2) The bis (2-ethylhexyl) phthalate pollutant is going to receive a limit, 1.2 pg/1, in the new permit. we recognize this is an on going issue and may be a lab issue. However, the data provided is not of sufficient detection to eliminate this concern. In the new permit a limit will be imposed. Recommend you discuss with the labyou use and see if they can succeed in providing consistent good data, detection to less than 1 Ng/1, and make changes in the sampling process to eliminate the cross contamination. we can discuss options based on what information your lab can provide. I am very interested in any information you can provide in regards to the above. Ron Berry ron.berry@ncdenr.gov Engineer I DWQ/Point Source/NPDES Complex Permitting Unit NCDENR Phone: (919) 807-6396 Fax: (919) 807-6495 office: Archdale Building Room 925N E-mail correspondence to and from this address may be subject to the North Carolina Public Records Law and may be disclosed to third parties. NOTICE: This e-mail and any files transmitted with it are the property of ARCADIS U.S., Inc. and its affiliates. All rights, including without limitation copyright, are reserved. The proprietary information contained in this e-mail message, and any files transmitted with it, is intended for the use of the recipient(s) named above. If the reader of this e-mail is not the intended recipient, you are hereby notified that you have received this e-mail in error and that any review, distribution or copying of this e-mail or any files transmitted with it is strictly prohibited. If you have received this e-mail in error, please notify the sender immediately and delete the original message and any files transmitted. The unauthorized use of this e-mail or any files transmitted with it is prohibited and disclaimed by ARCADIS U.S., Inc. and its affiliates. Nothing herein is intended to constitute the offering or performance of services where otherwise restricted by law. Page 4 S0/0 dIM-J • q0 �ajsd, . )•asuabo 11upLuis 9.10J gloq io 'saeaA S uegl ajow lou luawuosudwt so 000'SZ$ uegl a.iow lou Jo au!; is Xq luawgstund s sapinosd 100 uotlaaS 'O'S'n 8I) 'gloq Xq [o 'sgluow xis paaaxa of lou luawuosudw► Aq so 100019Z$ paaaxa of lou aug a Sq algegstund Joueawapsiw a;o ,411pn8 aq Ilegs 'apnjy Imp Suiluawaldwt uoissiwwoo luawa8eue Ieluawuonnu3 agl ;o suopeln8ai io I Z aptuy iapun paupnutew to palaiado aq of pamnbas poglaw jo atnap Suuoltuow .ao 8utp.1030a clue alemoogui slapuas SISutmomi io 'glinm s.iadwel 'saytsle,I ogM io 'apply egl Su. uawaldwt uotssiwwo3 luawaBeuelp lMuawuollnu3 agl Jo suotlelt Sal so 1z appiv sapun pautelu w aq of paunbal io salg luawnoop aaglo jo 'usld 'uodw 'p.ioaa.i 'uotleatldde Cue ut uotleat;T to 'uon uasaidai luawalels aspsj Cue sa)lew Al2utmoull ogM uosiad SUV :1eg1 sapinoid )Z))q) 9'SIZ-Ctl alnlelS I$ uaq eutloseo glaoH a113a ueatlddy 3o aln;euS S ailt,L sut uosi 3o auisu ud •a;ssnaas pas 'o;al#po:g 'asl aol;s�opq Rang Jo q pun aapolAoug La[ jo ;soq ag; o; ;sg; pus aol;salldds a;aoa sopsauo,;al otp Id rslllsas3 gas I 3sg4 Anizaa I uolT$aUT4303 ;usallddV 'LT s Salsn po;snla&o aq nsgs s;usld spotaso ON ❑ s*A ❑ d iauzo;sna MRS(ION aqT g4IM io;salP=ooa •slsalusaga;o ul s;ulod IIs ;s sazanloA ezoB apnlozq A;I ON •lopoza AIIlsnb solum pus asa axe uoI tao:3 sallisgan(I Q aepatua;lr 8alsaaalBu3 :a;s& oasnos 3o so*AI=V Q u20 aalwag aoaao;sno ag; ssm •:a;aa� aalesog ;as;aoo ;snuz s;asalldds AwN z -I all o; uou:ppn uz papaau uournu 0ful s;usallddV MZN '9T asld 2UHPUvH aPIIo9 Q ;o ;alod pas �ssoaoid ;nota;sari oq; glno:g3 ALOII 3 apsa:agos s aPIAOJd Q :aol;staiq;al TTUOPIPPV '91 ❑ $*A xaaya) d6r;anoa uslpal ao po;saoi AIiilas3 vm:J sI 'tiT •paliisgaslp aq o; Isl;ua;od aq; aAsq imp 's;aatgsar; uopaopgslP so spopnega Xalusolo I Mpnlaul 'soAplpps ;uouquar; sols& nu 39ll maid '£T shield luawleail lalem gltm palmaosse sa8mg3sip ioq dsJA - 3 WHod zxoHs - M011vaizddd siNHzd szadx Subject: Annual Report on Groundwater Remediation System O&M and Monitor Well Sampling — January through December 2009, Brenntag Southeast Facility (Former Southchem Facility), Durham, North Carolina. Data: 0 ARCADIS ARCADIS Infrastructure, environment, buildings 801 Corporate Center Drive ARCADIS is submitting the above -referenced report to your attention as per your Suite 300 verbal request made on January 19, 2011. As we discussed, you plan to review the Raleigh information in this report as part of your review process for the NPDES Permit North Carolina 27607 Renewal Application associated with the groundwater remediation system at the Tel 919.854.1282 Durham facility. The NPDES Permit Renewal Application (NPDES Permit Fax 919.854.5448 Mr. Ron Berry www.arcadis-us.com North Carolina Department of Environment and Natural Resources us.com Division of Water Quality (9`h Floor) Our ret: 512 North Salisbury Street NC000368.0020 Raleigh, North Carolina 27604 ENVIRONMENT Subject: Annual Report on Groundwater Remediation System O&M and Monitor Well Sampling — January through December 2009, Brenntag Southeast Facility (Former Southchem Facility), Durham, North Carolina. Data: January 20, 2011 Dear Mr. Berry: contaet: ARCADIS is submitting the above -referenced report to your attention as per your Jim Shilliday verbal request made on January 19, 2011. As we discussed, you plan to review the information in this report as part of your review process for the NPDES Permit 919 919 854-1282 Renewal Application associated with the groundwater remediation system at the Durham facility. The NPDES Permit Renewal Application (NPDES Permit E-mail: NC0086827) was submitted to the Division of Water Quality on April 30, 2010. jshilliday@arcadis- If you have any questions regarding the information presented in the report, please us.com contact me at (919) 854-1282. Our ret: NC000368.0020 Sincerely, ARCADIS G&M, Inc. ames E. Shilliday, III, L.G. ; Principal Scientist / Project Copies: Mr. Bruce Biehl — Brenntag Southeast G'.0020%DWQ-Ron Bary rover iatter.ao« page: 1/1 e v—*—z—x� LEGEND LJ BUILDING Mw -1 ---- PROPERTY LINE STORAGE —x—x— FENCE TANK RAILROAD I MONITOR WELL O (D RECOVERY WELL ® ABANDONED WEL SCALE IN FEET 0 00 1 1 T STT z x I I CAUSTIC r �I TANKS 1 1 1 I1 MWW-3 ' I 0 0 00 -----� 00 I00 I I 33 00 -100 O __�� MW -2• xx�x_MWW�4/ Ot ARCADIS ARCADIS C&M of North Carolina, Inc. 801 Corporate Center Drive, Suite 300 Raleigh, NC 27607 Tel: 919-854-1282 Fox: 919-854-5448 --orcodis—us.com IG -n- UNDERGROUND DIESEL OIL/WATER STORAGE SEPERATOR TANK 1 I LUBRICANT O PACKAGING I PLATFORM OO I t-- MWW-51D O I O 00 I _x0 � x � x x x + LUBRICANT TANK ANK TRUCK FARM UNLOADING AREA TAN K FARM MWW-571 .L AND RECOVERY WELL )CATION MAP FlGURE: 2-1 Date:2/22/11 WELL DATA FROM 2009 REPORT Brenntag Southeast, Inc. NCO086827 Stream re -classed as WS -V in 2009 methylene chloride Fri/1 NC/WS■4.6 4 methy 2 pentanone KA NC/WS■2800 tetracholoroethene N8J1 C/WS■0.7 tduene M4 NC/FW =11 trans 1,2 dichloroethene y&A NC/WS■140 1,1,1 tricholorethane WA N -2500 tricholorethene Wn CJWS=2.5 Wrild chloride WA C/WS=0.025 total xylenes Wn NOW ■670 34 940 13 210 18 1100 810 650 110 25 24 12W 410 37 15000 110 34000 47 19 2.4 98 120 8.7 1000 13 12 100 2200 590 89 21 590 16 60 11 <20 <10 <20 <50 8200 33000 18000 850 980 x <12 <20 _ <12 <100 1300 25W 1300 _ 96 96 150 1200 91 23 <10 48 2300 300 550 1200 x 8 _ <2 170 12000 12000 32000 17000 3500 2200 x x 8.7 <2 6.7 14 <30 <60 <150 16 16 _ - 910 <2 250 28 1500 24000 16000 1500 85 x _ 220 370 160 19 <10 <40 5700 1100 380 2000 x x 260 4.6 510 810 4800 4000 6100 1900 4000 x x <17 <4 120 1100 6000 9000 3000 1400 320 x x Date: 2/22/11 WELL DATA FROM 2009 REPORT - Brenntag Southeast, Inc. chloroethane p4A NC/WS =12 NC0086827 cls 1,2 dichloroethene N8/1 N - 330 1,1 dkhloroethane _ paill li s 6700 1,1 dicholorethene N8/1 NC/WS= 330 Stream re -classed as WS -V in 2009 MWW-4D 970 Pollutant: LI*M: WQS: acetone 1:n NC/FW - 2000 benzene 14A CAWS =1.19 2 buhnone V8A N - 20000 chloroethane p4A NC/WS =12 chloroform V8A1 NCAWS - 5.6 cls 1,2 dichloroethene N8/1 N - 330 1,1 dkhloroethane _ paill li s 6700 1,1 dicholorethene N8/1 NC/WS= 330 ethylben=ene PSA NC/FW ■ 97 MWW-4D 970 29 7.5 2000 210 110 180 MW W -IS D _ 21 2600 260 300 MWW-33 150 310 1100 MW W-34 IA MW W-37 2.1 87 17 43 MW W-38 1 MWW-40 3700 310 530 MW W-43 MWW45 - — 230 82 MW W-461 MWW-471 - -- MWW48 7.4 5.3 6.1 MWW49 D l W -SO D MW W-51 D MW W-52 -- MWW-53 - 8.7 75 14 75 MWW-571 — - li <100 <6.4 <12 22 24 3700 140 220 <2 RW -2 <50 <2 <20 <2 2.5 170 14 22 <6 RW4 2900 <6.4 <12 23 6.3 2000 79 80 26 RW -5 <250 <10 _ <100 210 <10 740 130 28 170 RW -6 12000 52 1800 3000 <29 9500 4000 2400 1000 RW -7 44000 120 8800 2300 <58 29000 8900 4000 1600 RW -8 26000 <160 4300 9100 <140 59000 8700 5400 360 Iii <250 25 <30 1100 <14 8400 5700 1400 320 RW -10 730 <16 <30 550 <14 6500 1300 350 74 In permit x x _ Ors parmlt x x x x x x Indicates well concentration exceeds WQS - 1 . go / o ReapwQ' 4 p", /,'- r - CO3 ARCADIS Infrastructure, environment, buildings Mrs. Dina Sprinkle NC DENR/DWQ/Point Source Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Subject: NPDES Permit Renewal Application (NPDES Permit NC0086827), Groundwater Remediation System, Brenntag Southeast, Inc., Durham, North Carolina. Dear Mrs. Sprinkle: On behalf of Brenntag Southeast, Inc. (Brenntag Southeast), ARCADIS G&M of North Carolina, Inc. (ARCADIS) has enclosed one original and two copies of the National Pollutant Discharge Elimination System (NPDES) permit renewal application for the continued discharge of effluent from a groundwater remediation system at the Brenntag Southeast facility (formerly Southchem) in Durham, North Carolina (NPDES Permit NC0086827). Treated groundwater from the remediation system is discharged to an on-site storm sewer that, in turn, discharges to a drainage ditch located along the southern boundary of the site. This drainage ditch conveys surface water to an unnamed tributary of Third Fork Creek. No changes have been implemented to the groundwater remediation system since the previous NPDES Permit Renewal Application was submitted in April 2005. Other items enclosed with this letter in support of the NPDES permit renewal application include the following: • Figure 1 - USGS topographic map of the project area that depicts the location of the system outfall; • Figure 2 - site map that depicts the route of the treated water to the discharge point; and • Attachment 1 - a copy of the March 2010 Discharge Monitoring Report which summarizes the most recent analytical data for the system effluent. Imagine the result ARCADIS G&M of North Carolina, Inc. 801 Corporate Center Drive Suite 300 Raleigh North Carolina 27607 Tel 919.854.1282 Fax 919.854.5448 www.arcadis-ua.com ENVIRONMENT Date: April 30, 2010 Contact: Jim Shilliday Phone: 919.854.1282 Email: Jim.Shilliday@arcadis-us.com Our ref: NC000368.0020.00006 ARCADIS Sludge is neither generated nor discharged by the groundwater remediation system; therefore, a sludge management plan has not been included with this application. Any solids (e.g. silt, iron and manganese precipitate) generated during the groundwater extraction and/or treatment processes are filtered from the treatment stream using bag filters and granular activated carbon units. The treated effluent is sampled on a monthly basis for total suspended solids in compliance with the monitoring requirements for the site (see Attachment 1). If you have any questions regarding the information presented in the NPDES permit application or any of the supporting material, please call me at (919) 854-1282. Sincerely, ARCADIS G&M of North Carolina, Inc. 20)--2t & Robert White, E.I.T Environmental Engineer II James E. Shilliday, III, Principal Scientist, Pr( des: Mr. Bruce Biehl (Brenntag Southeast, Inc.) NCDENR/DWQ/Point Source Branch File 0 Copy) (2 Copies) 0 Copy) Mrs. Dina Sprinkle April 30, 2010 Page: 2/2 A.,:5 lbwz 1f: m W DISCHARGE TO DRAJNAGE DITCH DIESEL -STORAGE TANK LUBRICANT - PACKAGING PLATFORM Q BUILDING — ^ • — FENCE — — — — PROPERTY LINE RAILROAD ® RECOVERY WELL SCALE IN FEET 0 100 200 VP ARCADIS FIGURE. ARCADIS G$M of North Carolina, Inc. S17 601 Corporate Center Drive, Suite 300 MAP Raleigh, NC 27607 Tel:919-854-1282 Fax: 919-854-5448 —.arcadis-us.com