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HomeMy WebLinkAboutWQ0006594_2022 Residual Annual Report_20230228 (2)Initial Review Reviewer Nathaniel.Thornburg Is this submittal an application? (Excluding additional information.) * Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2022 Permit Number (IR) * WQ0006594 Applicant/Permittee Unifi Manufacturing, Inc. Email Notifications Does this need review by the hydrogeologist? * Yes U No Regional Office Winston-Salem CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. Name* Brent Collins Email Address* brent.collins@emaresourcesinc.com Project Information ......................... Application/Document Type* New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Phone Number* 336-399-3646 Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, N DAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High -Rate Infiltration Other Wastewater Reclaimed Water Closed -Loop Recycle Residuals Single -Family Residence Wastewater Other Irrigation Permit Number:* WQ0006594 Has Current Existing permit number Applicant/Permittee Address* PO Box 1437, Reidsville, NC 27323 Facility Name* Unifi Manufacturing Class A Residuals Program Please provide comments/notes on your current submittal below. At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. (Application Form, Engineering Plans, Specifications, Calculations, Etc.) 2022 Unifi Annual Report - WQ0006594.pdf 11.41 MB Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/28/2023 February 28, 2023 DENR/Water Quality Section Non -Discharge Compliance Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2022 Annual Report — Unifi, Incorporated Treatment and Land Application of Residuals Permit No. WQ0006594 Dear Sir or Madam: Enclosed is the 2022 Annual Report for the above referenced land application permit. During 2022 EMA Resources, Inc. land applied 182.61 dry tons of wastewater residuals to 139.95 acres of private farmland. Please contact Brent Collins - Director of Technical Services if you have any further questions regarding this report. Sincerely, Z.-e4:241- Brent Collins Director of Technical Services brent.collins&emaresourcesinc.com Phone 336975191441 — Fax 336975191442 755 Yadkinville Rd — Mocksville, NC 27028 --Resources, Inc. Unifi, Incorporated 2022 Annual Report Residuals Land Application Permit No. WQ0006594 Prepared By: EMA Resources, Inc. Phone 336975191441 — Fax 336975191442 755 Yadkinville Rd — Mocksville, NC 27028 CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM WQ PERMIT #: WQ0006594 FACILITY NAME: IWOWell X Unifi, Incorporated COUNTY: Rockingham OPERATOR: Unifi, Inc. FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A (Source(s) and "Residual In" Volume only) and Part C) ❑ Distribution and Marketing (complete Parts A, B, and C) Was the facility in operation during the past calendar year? Yes E No ❑ —op- If No skip parts A, B, C and certify form below Part A*: Part B*: Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) January February March April May June July August September October November December Total from FORM DMSDF (sup) 0 182.61 182.61 1 182.61 Totals: Annual (dry tons): 0 182.61 182.61 182.61 Amendment(s) used: I I Bulking Agent(s) used: * If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)l 1 Part C: Facility was compliant during the past calendar year with all conditions of the land application permit ® Yes (including but not limited to items 1-3 below) issued by the Division of Water Quality: ❑ No 1, If No, Explain in Narritive 1. All monitoring was done in accordance with the permit and reported for the year as required and three (3) copies of certified laboratory results are attached. 2. All operation and maintenance requirements were compiled with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. No contravention of Ground Water Quality Standards occurred at a monitoring well. "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Lisa Haynes (Fe6 9, 202308:11 EST) Signature of Permittee Feb 9, 2023 Date Signature of Preparer** (if different from Permittee) **Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) Date DENR FORM DMSDF (12/2006) CLASS A ANNUAL DISTRIBUTION AND MARKETING/ SURFACE DISPOSAL CERTIFICATION AND SUMMARY FORM WQ PERMIT #: WQ0006594 FACILITY NAME: PHONE: Supplemental Information COUNTY: Rockingham Unifi, Incorporated OPERATOR: Unifi, Inc. FACILITY TYPE (please check one): ❑ Surface Disposal (complete Part A - "Month", "Source(s)" and "Residual In" columns only) ❑� Distribution and Marketing (complete Parts A, and B) Part A*: Part B*: Month Sources(s) (include NPDES # if applicable) Volume (dry tons) Recipient Information Amendment/ Bulking Agent Residual In Product Out Name(s) Volume (dry tons) Intended use(s) March Unifi Inc. Plant No. 2 Reidsville 12.94 12.94 Shane Shelton 12.94 Soil Amendment March Unifi Inc. Plant No. 2 Reidsville 10.59 10.59 Whitney Roger 10.59 Soil Amendment March Unifi Inc. Plant No. 2 Reidsville 8.85 8.85 Bennett Farms LLC 8.85 Soil Amendment April Unifi Inc. Plant No. 2 Reidsville 25.13 25.13 Bennett Farms LLC 25.13 Soil Amendment May Unifi Inc. Plant No. 2 Reidsville 46.07 46.07 James Blackwell 46.07 Soil Amendment June Unifi Inc. Plant No. 2 Reidsville 31.83 31.83 James Blackwell 31.83 Soil Amendment August Unifi Inc. Plant No. 2 Reidsville 39.62 39.62 Lofton Lovelace 39.62 Soil Amendment September Unifi Inc. Plant No. 2 Reidsville 7.58 7.58 Lofton Lovelace 7.58 Soil Amendment Totals: Annual (dry tons): 0 182.61 182.61 182.61 Amendments used: Bulking Agent(s) used: * If more space is required, attach additional information sheets (FORM DMSDF (supp)): Total Number of Form DMSDF (Supp)l 1 DENR FORM DMSDF (Supp) (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: Facility Name: Residual Source WQ # or NPDES #: WQ0006594 Laboratory: Unifi, Incorporated M-0104 WWTP Name: Unifi, Inc. Plant No.2 Reidsville Recidnal AnAvcic Data 1) 2) 3) 4) 5) Waypoint Analytical Parameter (mg/kg) Conc. Limit (mg/ka Sample or Composite Date 3/28/22 6/2/22 7/25/22 10/17/22 Percent Solids (%) NA 2.17 3.09 2.15 2.3 Arsenic 75 10.9 7.77 15.2 10.4 Cadmium 85 0.909 1.03 0.952 1.03 Copper 4,300 152 183 171 168 Chromium NA 48.6 68.3 57.6 62.2 Lead 840 77.3 85.8 82.4 78.7 Mercury 57 7.5 1.43 0.58 0.261 Molybdenum 75 6.14 4.37 6.43 5.87 Nickel 420 17.6 24.1 23.90 21 Selenium 100 14.5 10.4 15.2 13.9 Zinc 7,500 623 735 671 730 Total Phosphorus NA 3860 4170 3790 3440 TKN NA 37500 79600 33800 10500 Ammonia -Nitrogen NA 1260 3430 2120 2410 Nitrate and Nitrite NA 214 149 7240 217 a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Lire LL��f Feb 9, 2023 Lisa Haynes (Fe6 9, 2023 08:11 EST) Signature of Preparer * Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0006594 Facility Name: Unifi, Incorporated Residual Source NPDES # or WQ#: M-0104 WWTP Name: Unifi, Inc. Plant No.2 Reidsville Residual Analvsis Data Laboratory: 1) Waypoint Analytical 2) 3) 4) 5) Parameter Sample or Composite Date 11 11 11 11 -------- :11 1.11 :•11 •11 -------- • 11 •11 111 1.11 -------- ------------ ------------ ------------ ------------ ------------ ------------ "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Lrfg yjg� f Lisa Haynes (Fe 9, 2023 08:11 EST) Signature of Preparer * *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) Feb 9, 2023 Date DENR FORM RSSF - B (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Unifi, Inc. WQ0006594 James Blackwell Owner: 20.7 Acres Permitted: Total Dry Tons Applied (Annual): Cation Exchange Capacity (non 503 only): James Blackwell Predominant Soil Series: 20.7 Site #: CS06 Field #: 29.31 FaB3 3 Residual Analvsis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): 610AMM Com- posite Date ME an no no Bonn an Boa OEM no 0 Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total M E •�e NEEMBEEMMT/Ac./ os Event 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 ® 1 11 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 11 ® 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1• 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1• ®� 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 ® 1 11 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 11 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 ® 1 1•: 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1•: ® 1 1 • 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 • ® 1: 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1: Total Phos- :1• 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 :1• "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�ZZ4;2:� Signature of Land Applier 2/7/2023 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Unifi, Inc. WQ Permit #: WQ0006594 Field #: 3 Acres Utilized: 20.7 Land Owner: James Blackwell Annual Dry Tons Applied: 29.31 Site #: CS06 Acres Permitted: 20.7 Operator: James Blackwell Predominant Soil Series: FaB3 Cation Exchange Capacity (non 503): 0 Crop 1 Name: Fescue -Pasture Crop 1 Max. PAN: 145.5 Crop 2 Name: Crop 2 Max. PAN: o Volume applied enter one Solids/ Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#. Fert., Animal Waste, etc) Soil Cond. (Dry, Wet Moist) Precip. past 24 Hrs. inches a o 0 w o o ?: 0 ��, = N ?: 0 TKN mg/kg Z a o � ° mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 5/23 78000 3.09 0.486 Unifi, Inc. Dry <.5" S 0.5 0.3 79600 3430 149 24.000 NA Fescue 5/26 149500 3.09 0.931 Unifi, Inc. Dry <.5" S 0.5 0.3 79600 3430 149 46.000 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 227500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 70.000 0.00o Lime Applied Annuallbs/acre 0.022 0.003 0.518 0.193 0.243 0.004 0.012 0.068 0.029 2.082 11.809 Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 0 0 0 Current Cumulative lbs/ac 0.022 0.003 0.518 0.193 0.243 0.004 0.012 0.068 0.029 2.082 Permitted C. P. L. R.**** 36 34 1 1338 1 267 1 15 F 374 1 89 2498 Permit PAN Limit 1 st/2nd Crop 145.5 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of tines and imprisonment for knowing violations." Z�/_"- *Application Method: S - Surface, IN - Injection, INC - Incorporation `��2/7/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Unifi, Inc. WQ0006594 James Blackwell Owner: 25.67 Acres Permitted: Total Dry Tons Applied (Annual): Cation Exchange Capacity (non 503 only): James Blackwell Predominant Soil Series: 25.67 Site #: CS06 Field #: 48.57 CmB 4 Residual Analvsis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): 610AMM Com- posite Date man no no Bonn an Bonn on mom Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total o © 0 •�e NEEMBEEMMT/Ac./ os Event 1 1 • 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 • ® 1 11 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 11 ® 1 •• 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 •• 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 ®� 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 ® 1 11 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 11 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 ® 1 1• 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1• ® 1 1 • 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 • ® 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 Total Phos- • 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 • "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�ZZ4;2:� Signature of Land Applier 2/7/2023 Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Unifi, Inc. James Blackwell Operator: James Blackwell Crop 1 Name: Fescue -Hay WQ Permit #: WQ0006594 Field #: Annual Dry Tons Applied: 48.57 Site #: Predominant Soil Series: CmB Crop 1 Max. PAN: 194 Crop 2 Name: 4 CS06 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503) Crop 2 Max. PAN: 25.67 25.67 0 o Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#. Fert., Animal Waste, etc) Soil Cond. (Dry, Wet Moist) Precip. past 24 Hrs. inches a o 0 w o o ?: 0 ��, = N ?: 0 TKN mg/kg Z a o � ° mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 5/31 130000 3.09 0.653 Unifi, Inc. Dry <.5" S 0.5 0.3 79600 3430 149 32.255 NA Fescue 6/1 175500 3.09 0.881 Unifi, Inc. Dry <.5" S 0.5 0.3 79600 3430 149 43.545 NA Fescue 6/2 71500 3.09 0.359 Unifi, Inc. Dry <.5" S 0.5 0.3 79600 3430 149 17.740 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 377000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 93.541 0.000 Lime Applied Annuallbs/acre 0.029 0.004 0.692 0.258 0.325 0.005 0.017 0.091 0.039 2.781 15.779 Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 0 0 0 Current Cumulative lbs/ac 0.029 0.004 0.692 0.258 0.325 0.005 0.017 0.091 0.039 2.781 Permitted C. P. L. R.**** 36 34 1 1338 1 1 267 15 374 89 1 2498 Permit PAN Limit 1 st/2nd Crop 194 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of tines and imprisonment for knowing violations." Z�/_"- *Application Method: S - Surface, IN - Injection, INC - Incorporation `��2/7/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Unifi, Inc. WQ0006594 Bennett Farm Owner: 59.4 Acres Permitted: Total Dry Tons Applied (Annual): 63.32 Cation Exchange Capacity (non 503 only): Bennett Farm Predominant Soil Series: CgB2 59.4 Site #: RC015 Field #: 1 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 Unifi 3/28/22 2 Unifi 6/2/22 3 Reidsville4 /6/22 4 5 6 7 8 9 10 11 12 % Solids 2.17 3.09 1.72 Arsenic 109 7.77 29.4 Cadmium 0.909 1.03 5.88 Copper 152 183 224 Chromium 48.6 68.3 39.5 Lead 77.3 85.8 55.4 Mercury 7.5 1.43 0.382 Molyb- denum 6.14 4.37 14.7 Nickel 17.6 24.1 16.6 Selenium 14.5 10.4 29.4 Zinc 623 735 706 Total Phos- horus 3860 4170 20600 Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5j 6j 7 8 9 10 11 12 DT/Ac./ App. .fir Event 0.15 0.42 0.49 Arsenic 0.003 0.007 0.029 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.039 Cadmium 0.000 0.001 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Copper 0.045 0.155 0.221 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.421 Chromium 0.014 0.058 0.039 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.111 Lead 0.023 0.073 0.055 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.150 Mercury 0.002 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.002 0.004 0.015 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 denum Nickel 0.005 0.020 0.016 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.042 Selenium 0.004 0.009 0.029 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.042 Zinc 0.186 0.622 0.698 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.505 Total Phos- 1.150 3.528 20.353 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 25.031 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". 1 9 0 W(R -1 MR Signature of Land Applier 2/7/2023 Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Unifi, Inc. Bennett Farm Operator: Bennett Farm Crop 1 Name: Fescue -Pasture WQ Permit #: WQ0006594 Field #: Annual Dry Tons Applied: 63.32 Site #: Predominant Soil Series: CgB2 Crop 1 Max. PAN: 209 Crop 2 Name: Acres Utilized: RC015 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 59.4 59.4 0 ° ° ° Q Volume applied (enter one) Solids/ Liquid Cu_ Yds Gallons % Solids Volume Applied per PP P Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a F'5 c� w *o• o ;� K # ;d w ?j * N *� TKN mg/kg Z �o o �• mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/30 97500 2.17 0.149 Unifi, Inc. Dry <.5" S 0.5 1 0.3 37500 1260 214 3.480 NA Fescue 4/4 65000 3.09 0.141 Unifi, Inc. Dry <.5" S 0.5 0.3 79600 3430 149 6.970 NA Fescue 4/5 130000 3.09 0.282 Unifi, Inc. Dry <.5" S 0.5 0.3 79600 3430 149 13.939 NA Fescue 5/6 65000 1.72 0.078 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 4.474 NA Fescue 5/10 1 136500 1.72 0.165 Reidsville WWTP Dry <.5" S 1 0.5 0.3 84700 14100 275 9.396 NA Fescue 5/11 130000 1.72 0.157 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 8.949 NA Fescue 5/12 78000 1.72 0.094 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 5.369 NA Fescue 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 702000 As Cd Cu Cr Pb Hg Mo Ni Se Zn 7-1-52.5791 0.000 Lime Applied Annuallbs/acre 0.039 0.007 0.421 0.111 0.150 0.004 0.020 0.042 0.042 1.505 25.031 Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 0 0 0 Current Cumulative lbs/ac 0.039 1 0.007 0.421 0.111 0.150 0.004 0.020 0.042 0.042 1.505 Permitted C. P. L. R.**** 1 36 1 34 1 1338 1 267 1 15 1 1 374 1 89 1 2498 Permit PAN Limit Ist/2nd Crop 1 209 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/7/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Unifi, Inc. WQ0006594 Donald Lovelace Owner: 8.81 Acres Permitted: Total Dry Tons Applied (Annual): Cation Exchange Capacity (non 503 only): Lofton Lovelace Predominant Soil Series: 8.81 Site #: RC041 Field #: 21.10 CdB2 2 Residual Analvsis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 1 Reidsville 4/6/22 _2j Unifi 7/25/22 3j 4j 5j 6j 7j 8j 9j 10 J 11j 12 % Solids 1.72 2.15 Arsenic 1 29.4 15.2 Cadmium 5.88 0.952 Copper 224 171 Chromium 39.5 57.6 Lead 55.4 82.4 Mercury 0.382 0.576 Molyb- denum 14.7 6.43 Nickel 16.6 23.9 Selenium 29.4 15.2 Zinc 706 671 Total Phos- horus 20600 3790 Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total E •�e NEW NEEMBEEMBT/Ac./ os Event 1 1 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1• ® 1 1 1 11 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 ® 1•• 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1• 1 11 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 ®� 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 • ® 1 11 1 11 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 11 1 1 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 ® 1 1 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1•• ® 1 1 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1• ®�� 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 Total Phos- 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 •1 -I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". 4; 2/7/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Unifi, Inc. WQ Permit #: WQ0006594 Field #: 2 Acres Utilized: 8.81 Land Owner: Lofton Lovelace Annual Dry Tons Applied: 21.10 Site #: RC041 Acres Permitted: 8.81 Operator: Donald Lovelace Predominant Soil Series: CdB2 Cation Exchange Capacity (non 503): 0 Crop 1 Name: Fescue -Pasture Crop 1 Max. PAN: 156 Crop 2 Name: Crop 2 Max. PAN: o Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#. Fert., Animal Waste, etc) Soil Cond. (Dry, Wet Moist) Precip. past 24 Hrs. inches a o 0 w o o ?: 0 ��, = N ?: 0 TKN mg/kg 84700 Z a o � ° mg/kg 14100 Nitrate and Nitrite mg/kg 275 PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 4/21 156000 1.72 1.270 Reidsville WWTP Dry <.5" S 0.5 0.3 72.404 NA Fescue 8/31 26000 2.15 0.265 Unifi Dry <.5" S 0.5 0.3 33800 2120 7240 9.421 NA Fescue 9/1 84500 2.15 0.860 Unifi Dry <.5" S 0.5 0.3 33800 2120 7240 30.620 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 266500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 112.4461 0.000 Lime Applied Annuallbs/acre 0.109 0.017 0.954 0.230 0.326 0.002 0.052 0.096 0.109 3.303 60.852 Date lbs/ac Prior Years Cumulative lbs/ac 0.223 0.244 8.373 0.762 1.792 0.04 0.399 1.151 0.311 16.688 Current Cumulative lbs/ac 0.332 0.261 9.327 0.992 2.118 0.042 0.451 1.247 0.420 19.991 Permitted C. P. L. R.**** 36 34 1 1338 267 1 15 1 1 374 89 1 2498 Permit PAN Limit 1 st/2nd Crop 156 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of tines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/7/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Unifi, Inc. WQ0006594 Donald Lovelace Owner: 17.2 Acres Permitted: Total Dry Tons Applied (Annual): Cation Exchange Capacity (non 503 only): Lofton Lovelace Predominant Soil Series: 17.2 Site #: RC041 Field #: 58.93 CdB2 4 Residual Analvsis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 1 Reidsville 1/12/22 2 Reidsville 4/6/22 3 j Unifi 7/25/22 4 j 5 6 7 8 j 9 10 J 11 12 % Solids 1.68 1.72 2.15 Arsenic 1 14.3 29.4 15.2 Cadmium 1.19 5.88 0.952 Copper 234 224 171 Chromium 38.7 39.5 57.6 Lead 53.9 55.4 82.4 Mercury 0.595 0.382 0.576 Molyb- denum 8.04 14.7 6.43 Nickel 15.8 16.6 23.9 Selenium 19 29.4 15.2 Zinc 798 706 671 Total Phos- horus 22800 20600 3790 Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 j 5 6 7 8 j 10 11 12 DT/Ac./ -91 App . Event 0.64 0.62 2.17 Arsenic 0.018 0.037 0.066 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.121 Cadmium 0.002 0.007 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.013 Copper 0.297 0.279 0.741 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.318 Chromium 0.049 0.049 0.250 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.348 Lead 0.068 0.069 0.357 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.495 Mercury 0.001 0.000 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.010 0.018 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.056 denum Nickel 0.020 0.021 0.104 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.144 Selenium 0.024 0.037 0.066 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.127 Zinc 1.013 0.880 2.909 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.803 Total Phos- 28.956 25.668 16.433 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 71.057 horus -I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". 4;:241- 2/7/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Unifi, Inc. WQ Permit #: WQ0006594 Field #: 4 Acres Utilized: 17.2 Land Owner: Lofton Lovelace Annual Dry Tons Applied: 58.93 Site #: RC041 Acres Permitted: 17.2 Operator: Donald Lovelace Predominant Soil Series: CdB2 Cation Exchange Capacity (non 503): 0 Crop 1 Name: Fescue -Pasture Crop 1 Max. PAN: 156 Crop 2 Name: Crop 2 Max. PAN: o Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#. Fert., Animal Waste, etc) Soil Cond. (Dry, Wet Moist) Precip. past 24 Hrs. inches a o 0 w o o ?: 0 ��, = N ?: 0 TKN mg/kg Z a o � ° mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/5 32500 1.68 0.132 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 7.878 NA Fescue 3/7 123500 1.68 0.503 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 29.938 NA Fescue 4/23 39000 1.72 0.163 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 9.272 NA Fescue 4/25 110500 1.72 0.461 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 26.269 NA Fescue 8/29 1 123500 2.15 0.644 Unifi Dry <.5" S 0.5 1 0.3 33800 2120 1 7240 22.922 NA Fescue 8/30 182000 2.15 0.949 Unifi Dry <.5" S 0.5 0.3 33800 2120 7240 33.780 NA Fescue 8/31 110500 2.15 0.576 Unifi Dry <.5" S 0.5 0.3 33800 2120 7240 20.510 NA Fescue 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 721500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 150.5691 0.000 Lime Applied Annuallbs/acre 0.121 0.013 1.318 0.348 0.495 0.004 0.056 0.144 0.127 4.803 71.057 Date lbs/ac Prior Years Cumulative lbs/ac 0.456 0.291 12.952 2.431 2.697 0.064 0.619 1.686 0.603 28.255 Current Cumulative lbs/ac 0.577 0.304 14.270 2.779 3.192 0.068 0.675 1.830 0.730 33.058 Permitted C. P. L. R.**** 1 36 34 1 1338 267 1 15 1 1 374 1 89 1 2498 Permit PAN Limit 1 st/2nd Crop 1156 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of tines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/7/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Unifi, Inc. WQ0006594 Shane Shelton Owner: 8.43 Acres Permitted: Total Dry Tons Applied (Annual): 12.94 Cation Exchange Capacity (non 503 only): Shane Shelton Predominant Soil Series: Cgl32 8.43 Site #: RC132 Field #: 1 Residual Analvsis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): 610AMM Com- posite Date Ian no no Bonn an Bonn on mom Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total E E�oose NEEMBEEMMT/Ac./ Event 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 ® 1 11 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 11 ® 1• 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1• 1 • 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 • ®� 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 ® 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 1 1 • 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 • ® 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 ® 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 ®� 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 Total Phos- 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/7/2023 Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Unifi, Inc. Shane Shelton Operator: Shane Shelton Crop 1 Name: Fescue -Pasture WQ Permit #: WQ0006594 Field #: Annual Dry Tons Applied: 12.94 Site #: Predominant Soil Series: Cg132 Crop 1 Max. PAN: 145 Crop 2 Name: Acres Utilized RC132 Acres Permitted: Cation Exchange Capacity (non 503) Crop 2 Max. PAN: 8.43 8.43 0 0 o Volume applied enter one Solids/ Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#. Fert., Animal Waste, etc) Soil Cond. (Dry, Wet Moist) Precip. Past Hrs. inches a 5 o 0 w o o %� ?3 ��, = N ?: 0 TKN mg/kg Z a o ° mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/28 143000 2.17 1.535 Unifi, Inc. Dry <.5" S 0.5 0.3 37500 1260 214 35.968 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 143000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 35.968 0.000 Lime Applied Annuallbs/acre 0.033 0.003 0.467 0.149 0.237 0.023 0.019 0.054 0.045 1.913 11.850 Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 0 0 0 Current Cumulative lbs/ac 0.033 0.003 0.467 0.149 0.237 0.023 0.019 0.054 0.045 1.913 Permitted C. P. L. R.**** 36 1 34 1 1338 1 1 267 1 15 1 1 374 89 1 2498 Permit PAN Limit 1 st/2nd Crop 145 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of tines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/7/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: Unifi, Inc. WQ0006594 Shane Shelton Owner: 6.39 Acres Permitted: Total Dry Tons Applied (Annual): Cation Exchange Capacity (non 503 only): Shane Shelton Predominant Soil Series: 6.39 Site #: RC133 Field #: 10.59 FrD2 1 Residual Analvsis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): 610AMM Com- posite Date Ian no no Bonn an Bonn on mom Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total o © 0�oose NEEMBEEMMT/Ac./ Event 1 1 • 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 • ® 1 11 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 11 ® 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 1• 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1• ® 1 • 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 • ® 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 1 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 1 ® 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 ® 1 1 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 1 ® 1• 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1• Total Phos- • 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 1 111 • "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Signature of Land Applier 2/7/2023 Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: Unifi, Inc. WQ Permit #: WQ0006594 Field #: I Acres Utilized: 6.39 Land Owner: Shane Shelton Annual Dry Tons Applied: 10.59 Site #: RC133 Acres Permitted: 6.39 Operator: Shane Shelton Predominant Soil Series: FrD2 Cation Exchange Capacity (non 503): 0 Crop 1 Name: Fescue -Pasture Crop 1 Max. PAN: 154 Crop 2 Name: Crop 2 Max. PAN: o Volume applied enter one Solids/ Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#. Fert., Animal Waste, etc) Soil Cond. (Dry, Wet Moist) Precip. Past Hrs. inches a o 0 w o o %� ?3 0 ��, = N ?: 0 TKN mg/kg Z a o � ° mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/29 117000 2.17 1.657 Unifi, Inc. Dry <.5" S 0.5 0.3 37500 1260 214 38.823 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 117000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 38.823 0.000 Lime Applied Annuallbs/acre 0.036 0.003 0.504 0.161 0.256 0.025 0.020 0.058 0.048 2.065 12.792 Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 0 0 0 Current Cumulative lbs/ac 0.036 0.003 0.504 0.161 0.256 0.025 0.020 0.058 0.048 2.065 Permitted C. P. L. R.**** 36 34 1 1338 1 1 267 15 374 89 1 2498 Permit PAN Limit 1 st/2nd Crop 154 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of tines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/7/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) Waypointo ANALYTICAL 4/7/2022 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Road Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 22-088-0011 Client Project Description: Reidsville, NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Mr. Brent Collins: Waypoint Analytical, LLC. received sample(s) on 3/29/2022 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a' -'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Connie Cook Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 7 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901,213,2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2023 Arkansas State Program 88-0650 02/07/2023 California State Program 2904 06/30/2022 Florida State Program - NELAP E871157 06/30/2022 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2022 Illinois State Program - NELAP 200078 10/10/2022 Kentucky State Program 80215 06/30/2022 Kentucky State Program KY90047 12/31/2022 Louisiana State Program - NELAP LA037 12/31/2022 Louisiana State Program - NELAP 04015 06/30/2022 Mississippi State Program MS 02/11/2023 North Carolina State Program 415 12/31/2022 Pennsylvania State Program - NELAP 68-03195 05/31/2022 South Carolina State Program 84002 06/30/2022 South Carolina State Program 84002 06/30/2022 Tennessee State Program 02027 02/11/2023 Texas State Program - NELAP T104704180 09/30/2022 Virginia State Program 00106 06/30/2022 Virginia State Program - NELAP 460181 09/14/2022 Page 1 of 1 00001 /22-088-0011 Page 2 of 7 Waypoint 27(2) 90 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 22-088-0011 Client Project Description: Reidsville, NC Lab No Client Sample ID 96311 Unifi Matrix Date Collected Solids 03/28/2022 09:30 Date Received 03/29/2022 Page 3 of 7 Waypointo ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Road Mocksville , NC 27028 Project Reidsville, NC Information : 2790 Whitten Road, Memphis, TN 38133 Main 901,213,2400 0 Fax 901.213.2440 www.waypointanalytical.com Report Date : 04/07/2022 Received03/29/2022 &%4- Connie Cook Report Number :22-088-0011 REPORT OFANAL YSIS Project Manager Lab No : 96311 Matrix: Solids Sample ID : Unifi Sampled: 3/28/2022 9:30 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 97.8 % 1 03/30/22 15:35 FMM SW-DRYWT Ammonia Nitrogen 12603 mg/Kg - dry 727 4550 1 04/05/22 14:30 JPJ 4500NH3C-2011 Nitrate+Nitrite-N <214 mg/Kg - dry 214 214 1 04/05/22 15:41 ZBD 4500NO3F-2016 Organic N 361903 mg/Kg - dry 727.3 4545 1 04/05/22 14:00 CALCULATION pH 6.7 S.U. 1 04/04/2215:00 DRS 9045D Total Solids 2.17 % 0.010 0.010 1 03/30/22 15:35 FMM 2540G-2011 Total Volatile Solids 77.4 % 0.010 0.010 1 03/30/22 15:35 FMM 2540G-2011 Total Kjeldahl Nitrogen 37500 mg/Kg - dry 455 11400 1 04/05/22 14:00 JPJ iM-4500-NH3C-TKP Phosphorus 3860 mg/Kg - dry 125 227 1 04/05/22 01:07 TJS 6010D Aluminum 11200 mg/Kg - dry 210 227 1 04/05/22 17:21 EAL 6010D Arsenic <10.9 mg/Kg - dry 10.9 22.7 1 04/05/22 01:07 TJS 6010D Cadmium <0.909 mg/Kg - dry 0.909 4.55 1 04/05/22 01:07 TJS 6010D Calcium 23800 mg/Kg - dry 1760 2270 1 04/05/22 01:07 TJS 6010D Chromium 48.6 mg/Kg - dry 10.7 11.4 1 04/05/22 17:21 EAL 6010D Copper 152 mg/Kg - dry 14.1 22.7 1 04/05/22 01:07 TJS 6010D Iron 5180 mg/Kg - dry 387 455 1 04/05/22 01:07 TJS 6010D Lead 77.3 mg/Kg - dry 8.18 13.6 1 04/05/22 01:07 TJS 6010D Magnesium 3850 mg/Kg - dry 117 227 1 04/05/22 01:07 TJS 6010D Manganese 145 mg/Kg - dry 14.8 22.7 1 04/05/22 17:21 EAL 6010D Mercury 7.50 mg/Kg - dry 0.291 0.668 1 04/06/22 18:51 ZMT 7471A Molybdenum <6.14 mg/Kg - dry 6.14 11.4 1 04/05/22 01:07 TJS 6010D Nickel 17.6 mg/Kg - dry 5.45 11.4 1 04/05/22 01:07 TJS 6010D Potassium 2560 mg/Kg - dry 281 455 1 04/05/22 17:21 EAL 6010D Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 4 of 7 0 Waypoint 2790 Whitten Road, Memphis, TN 38133 Main 901,213,2400 0 Fax 901.213.2440 ANALYTICAL www.waypointanalytical.com 46245 EMA Resources Inc Project Reidsville, NC Mr. Brent Collins Report Date : 04/07/2022 755 Yadkinville Road Information : Received : 03/29/2022 Mocksville , NC 27028 Connie Cook Report Number :22-088-0011 REPORT OFANAL YSIS Project Manager Lab No : 96311 Matrix: Solids Sample ID : Unifi Sampled: 3/28/2022 9:30 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <14.5 mg/Kg - dry 14.5 22.7 1 04/05/22 01:07 TJS 6010D Sodium 25500 mg/Kg - dry 591 1140 1 04/05/22 01:07 TJS 6010D Zinc 623 mg/Kg - dry 36.8 56.8 1 04/05/22 01:07 TJS 6010D Sulfur 9770 mg/Kg - dry 235 455 1 04/05/22 01:07 TJS 6010D Sodium Absorption Ratio 5.99 Ratio 0.01 0.01 1 04/05/22 01:07 CALCULATION Qualifiers/ DF Dilution Factor Definitions J Estimated value Page 5 of 7 (D p�i ��,. 2790 Whitten Road, Memphis, TN 38133 Wayl? Main 901.213.2400 ° Fax 901.213.2440 NALYTICAL www.waypointanaIytica1.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 22-088-0011 Shipping Method Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: T135 Shipping container/cooler uncompromised? # Yes 0 No Number of coolers/boxes received I ' Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? Yes 0 No COC agrees with sample label(s)? Yes 0 No COC properly completed Yes 0 No Samples in proper containers? Yes 0 No Sample containers intact? Yes 0 No Sufficient sample volume for indicated test(s)? Yes 0 No All samples received within holding time? Yes 0 No Cooler temperature in compliance? Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes 0 No 0 N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A High concentration container (48 hr) [_ Low concentration EnCore samplers (48 hr) High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes 0 No Comments: Signature: jEmily M. Peterson Date & Time: 03/29/2022 08:57:31 Page 6 of 7 a j c a L3 Z M r' � � V4 N NLIN V _ N 01.n[��pp C N �n ry a d x r a �1 V '�' +4 ie v qC a p' I Q V �' E O 3 d ^� m o V CC. C Q ❑❑ ❑O N❑, 2 �, G pO C tf u T �, V c.+ m 2 2 2 x x V Q C S }}� i �� ❑a �n amu❑u,LL�x_ � � � � � NA� J C7 R in C2 in y L 0. n W �[ ■ V U u U a+ a r�u 1J V E CIa � � � a- SAi 2 � ro � 4R o W v `a �� w .� E _� v n r c � a o H R a a y l ld � � Sp!lOs Ielol 7, v {Jj ❑� O ❑ U � 7 a a N [❑i a m a N OW126JO01ela{N en eiuOWWV/NNi u •� m 0 4 m E o s= m R a (cm0g) sle}an z a z = L] a iLi h7 47 ❑ 7) R ji' a a1lsodw❑j3J eo ga iI�]1 z Y r a a b v N {AaH oy aayaaI xiayeVy w Ah G C a or siauie3uo� yo aaquinry (-IN a� m U 4 R L N � w u n v � V � d G ❑ I E a m c LL a N rCo C t: o v -M 1' r d a u 4 a71.vm m p a d ro C cy) p m C v a C c ro C a � a .❑ � CO O �d ¢ V a U m d C CO' J ' GCi n_ C C ❑ N in O �a `-T m C - �Q u r N N ❑ 2^i y b roLO Z Q' u c ❑ a r Wn:� a` I Page 7 of 7 3/28/2022 mg/kg mg/L Equiv Weight Milli Equiv Sodium 25500 553.35 23 24.0587 Calcium 23800 516.46 20 25.823 Magnesium 3850 83.545 12 6.962083 Percent Solids 2.17 SAR 5.94 SAR = Na+ 2 (Ca2+ + Mg2+) 24.05870 0.5( 25.823 2 + 6.96208 2 ) Waypointo ANALYTICAL 6/16/2022 EMA Resources Inc Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 22-154-0009 Client Project Description: Reidsville, NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Brent Collins: Waypoint Analytical, LLC. received sample(s) on 6/3/2022 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a' -'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Connie Cook Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 9 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901,213,2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2023 Arkansas State Program 88-0650 02/07/2023 California State Program 2904 06/30/2022 Florida State Program - NELAP E871157 06/30/2022 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2022 Illinois State Program - NELAP 200078 10/10/2022 Kentucky State Program 80215 06/30/2022 Kentucky State Program KY90047 12/31/2022 Louisiana State Program - NELAP LA037 12/31/2022 Louisiana State Program - NELAP 04015 06/30/2023 Mississippi State Program MS 02/11/2023 North Carolina State Program 415 12/31/2022 Pennsylvania State Program - NELAP 68-03195 05/31/2023 South Carolina State Program 84002 06/30/2022 South Carolina State Program 84002 06/30/2022 Tennessee State Program 02027 02/11/2023 Texas State Program - NELAP T104704180 09/30/2022 Virginia State Program 00106 06/30/2022 Virginia State Program - NELAP 460181 09/14/2022 Page 1 of 1 00001/22-154-0009 Page 2 of 9 Waypoint 27(2) 90 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 22-154-0009 Client Project Description: Reidsville, NC Lab No Client Sample ID 89863 Unifi Matrix Date Collected Solids 06/02/202210:30 Date Received 06/03/2022 Page 3 of 9 Waypointo ANALYTICAL Client: EMA Resources Inc Project: Reidsville, NC Lab Report Number: 22-154-0009 Date: 6/16/2022 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com CASE NARRATIVE Metals Analysis Method 6010D Sample 90192 (WRC Topsoil (June)) Analyte: Aluminum QC Batch No: L620235/L619916 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 90192 (WRC Topsoil (June)) Analyte: Aluminum QC Batch No: L620618/L619916 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 90192 (WRC Topsoil (June)) Analyte: Calcium QC Batch No: L620618/L619916 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 90192 (WRC Topsoil (June)) Analyte: Iron QC Batch No: L620618/L619916 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 90192 (WRC Topsoil (June)) Analyte: Potassium QC Batch No: L620618/L619916 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 90192 (WRC Topsoil (June)) Analyte: Magnesium QC Batch No: L620235/L619916 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 90192 (WRC Topsoil (June)) Analyte: Manganese QC Batch No: L620235/L619916 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 90192 (WRC Topsoil (June)) Page 4 of 9 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com Analyte: Phosphorus QC Batch No: 1-620235/1-619916 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 90192 (WRC Topsoil (June)) Analyte: Lead QC Batch No: 1-620235/1-619916 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 90192 (WRC Topsoil (June)) Analyte: Sulfur QC Batch No: 1-620235/1-619916 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 90192 (WRC Topsoil (June)) Analyte: Selenium QC Batch No: 1-620235/1-619916 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 5 of 9 Waypointo ANALYTICAL 46245 EMA Resources Inc Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Project Reidsville, NC Information : 2790 Whitten Road, Memphis, TN 38133 Main 901,213,2400 0 Fax 901.213.2440 www.waypointanalytical.com Report Date : 06/16/2022 Received06/03/2022 &%4- Connie Cook Report Number :22-154-0009 REPORT OFANAL YSIS Project Manager Lab No : 89863 Matrix: Solids Sample ID : Unifi Sampled: 6/2/2022 10:30 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 96.91 % 0.010 0.010 1 06/03/22 16:27 FMM SW-DRYWT Ammonia Nitrogen 3430 mg/Kg - dry 518 3240 1 06/16/22 14:00 JPJ 4500NH3C-2011 Nitrate+Nitrite-N <149 mg/Kg - dry 149 149 1 06/07/22 14:57 ZBD 4500NO3F-2016 Organic N 76180 mg/Kg - dry 517.8 3236 1 06/14/22 11:30 CALCULATION pH 7.9 S.U. 1 06/10/2216:00 DRS 9045D Total Solids 3.09 % 0.010 0.010 1 06/03/22 16:27 FMM 2540G-2011 Total Volatile Solids 74.9 % 0.010 0.010 1 06/03/22 16:27 FMM 2540G-2011 Total Kjeldahl Nitrogen 79600 mg/Kg - dry 324 8090 1 06/14/22 11:30 JPJ iM-4500-NH3C-TKP Phosphorus 4170 mg/Kg - dry 89.3 162 1 06/07/22 19:34 EAL 6010D Aluminum 13100 mg/Kg - dry 150 162 1 06/07/22 19:34 EAL 6010D Arsenic <7.77 mg/Kg - dry 7.77 16.2 1 06/07/22 19:34 EAL 6010D Cadmium 1.033 mg/Kg - dry 0.647 3.24 1 06/07/22 19:34 EAL 6010D Calcium 30600 mg/Kg - dry 1250 1620 1 06/07/22 19:34 TJS 6010D Chromium 68.3 mg/Kg - dry 7.64 8.09 1 06/07/22 19:34 EAL 6010D Copper 183 mg/Kg - dry 10.0 16.2 1 06/07/22 19:34 EAL 6010D Iron 5630 mg/Kg - dry 276 324 1 06/07/22 19:34 TJS 6010D Lead 85.8 mg/Kg - dry 5.83 9.71 1 06/07/22 19:34 EAL 6010D Magnesium 8190 mg/Kg - dry 83.5 162 1 06/07/22 19:34 EAL 6010D Manganese 177 mg/Kg - dry 10.5 16.2 1 06/07/22 19:34 EAL 6010D Mercury 1.433 mg/Kg - dry 0.213 4.89 1 06/07/22 16:40 ZMT 7471A Molybdenum <4.37 mg/Kg - dry 4.37 8.09 1 06/07/22 19:34 EAL 6010D Nickel 24.1 mg/Kg - dry 3.88 8.09 1 06/07/22 19:34 EAL 6010D Potassium 2370 mg/Kg - dry 200 324 1 06/07/22 19:34 TJS 6010D Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 6 of 9 0 Waypoint 2790 Whitten Road, Memphis, TN 38133 Main 901,213,2400 0 Fax 901.213.2440 ANALYTICAL www.waypointanalytical.com 46245 EMA Resources Inc Project Reidsville, NC Brent Collins Report Date : 06/16/2022 755 Yadkinville Rd Information : Received : 06/03/2022 Mocksville , NC 27028 Connie Cook Report Number :22-154-0009 REPORT OFANAL YSIS Project Manager Lab No : 89863 Matrix: Solids Sample ID : Unifi Sampled: 6/2/2022 10:30 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <10.4 mg/Kg - dry 10.4 16.2 1 06/07/22 19:34 EAL 6010D Sodium 19400 mg/Kg - dry 421 809 1 06/07/22 19:34 EAL 6010D Zinc 735 mg/Kg - dry 26.2 40.5 1 06/07/22 19:34 EAL 6010D Sulfur 8610 mg/Kg - dry 168 324 1 06/07/22 19:34 EAL 6010D Sodium Absorption Ratio 4.48 Ratio 0.01 0.01 1 06/07/22 19:34 CALCULATION Qualifiers/ DF Dilution Factor Definitions J Estimated value Page 7 of 9 (D p�i ��,. 2790 Whitten Road, Memphis, TN 38133 Wayl? Main 901.213.2400 ° Fax 901.213.2440 NALYTICAL www.waypointanaIytica1.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 22-154-0009 Shipping Method Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: T137 Shipping container/cooler uncompromised? # Yes 0 No Number of coolers/boxes received I ' Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? Yes 0 No COC agrees with sample label(s)? Yes 0 No COC properly completed Yes 0 No Samples in proper containers? Yes 0 No Sample containers intact? Yes 0 No Sufficient sample volume for indicated test(s)? Yes 0 No All samples received within holding time? Yes 0 No Cooler temperature in compliance? Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes 0 No 0 N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A High concentration container (48 hr) [_ Low concentration EnCore samplers (48 hr) High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes 0 No Comments: Signature: ISummer Harrison Date & Time: 06/03/2022 10:10:43 Page 8 of 9 ti O a D CY) F � c o U a - ? (] Z o l7 N D a a a N �' ate+ T Q 2 S M 6 rN C ca Z C� Ln ❑ v f0 fL V = C N T�7 Z l[7 V P y C v a as N a 2 u M p �p J 14 p L ,n O a. �• W m� 3 L3 a in 6 iD u n W LL u^ Z_ OS C 0 C' �L J ~ z 2 z _ N vnow W n v N Oa C (� Uer E •'+ E d -W W E® .� j yj V L c�i AI m Y w V y S C'] E E .0-0 7 .c 0 ( m w TY a h ~ Hd� ��c� LL� -- =r�`d�r a SPHOS lejol T rnw!m!` 0 7 a a N 3 N O{ue6Jfl/aleA!N c a � 0 N eluOWWVINNi N c a a a z z c Co m j i%r iw 7 w 7 a° S in a 1 (��F��) $�elaW lA � 2 z N q C] w l7 l7 C3 d C Val m Q a azisadw°[71 �o qe,[�1 z a s5 NZ m r L G C C C � D saau!eyua:)yaiagwnN N v g 0: V u A V L O t S V u ono c c o U) A � •� a LTTlJ u a J C1 A a+ .7 C co o E m CD p � 54 p � c N C a 0 m a a co d E m C d } ro a` a co uN d NON C •�Q a� u� Y U 2 o �1 jZJ�C:J g G m ,j. E M Q z�� D V zLO 13 n ❑ ° a 5 ° o 4 of 6/2/2022 mg/kg mg/L Equiv Weight Milli Equiv Sodium 19400 599.46 23 26.06348 Calcium 30600 945.54 20 47.277 Magnesium 8190 253.071 12 21.08925 Percent Solids 3.09 SAR 4.46 SAR = Na+ 2 (Ca2+ + Mg2+) 26.06348 0.5( 47.277 2 + 21.08925 2 ) Waypointo ANALYTICAL 8/3/2022 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Road Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 22-207-0024 Client Project Description: Unifi Reidsville, NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Mr. Brent Collins: Waypoint Analytical, LLC. received sample(s) on 7/26/2022 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a' -'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Connie Cook Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 8 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901,213,2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2023 Arkansas State Program 88-0650 02/07/2023 California State Program 2904 06/30/2023 Florida State Program - NELAP E871157 06/30/2023 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2023 Illinois State Program - NELAP 200078 10/10/2022 Kentucky State Program 80215 06/30/2023 Kentucky State Program KY90047 12/31/2022 Louisiana State Program - NELAP LA037 12/31/2022 Louisiana State Program - NELAP 04015 06/30/2023 Mississippi State Program MS 02/11/2023 North Carolina State Program 415 12/31/2022 Pennsylvania State Program - NELAP 68-03195 05/31/2023 South Carolina State Program 84002 06/30/2022 Tennessee State Program 02027 02/11/2023 Texas State Program - NELAP T104704180 09/30/2022 Virginia State Program 00106 06/30/2023 Virginia State Program - NELAP 460181 09/14/2022 Page 1 of 1 00001/22-207-0024 Page 2 of 8 Waypoint 27(2) 90 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 22-207-0024 Client Project Description: Unifi Reidsville, NC Lab No Client Sample ID Matrix Date Collected Date Received 91149 Unifi Solids 07/25/202210:40 07/26/2022 Page 3 of 8 Waypointo ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Road Mocksville , NC 27028 Project Unifi Information : Reidsville, NC 2790 Whitten Road, Memphis, TN 38133 Main 901,213,2400 0 Fax 901.213.2440 www.waypointanalytical.com Report Date : 08/03/2022 Received07/26/2022 &%4- Connie Cook Report Number :22-207-0024 REPORT OFANAL YSIS Project Manager Lab No : 91149 Matrix: Solids Sample ID : Unifi Sampled: 7/25/2022 10:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 97.9 % 1 07/29/22 15:56 FMM SW-DRYWT Ammonia Nitrogen 21203 mg/Kg - dry 762 4760 1 08/02/22 14:30 JPJ 4500NH3C-2011 Nitrate+Nitrite-N 7240 mg/Kg - dry 230 230 1 08/01/22 13:52 ZBD 4500NO3F-2016 Organic N 316903 mg/Kg - dry 761.9 4762 1 08/02/22 10:30 DH CALCULATION pH 6.9 S.U. 1 08/01/2216:03 DRS 9045D Total Solids 2.15 % 0.010 0.010 1 07/29/22 15:56 FMM 2540G-2011 Total Volatile Solids 74.8 % 0.010 0.010 1 07/29/22 15:56 FMM 2540G-2011 Total Kjeldahl Nitrogen 33800 mg/Kg - dry 476 11900 1 08/02/22 10:30 JPJ iM-4500-NH3C-TKP Phosphorus 3790 mg/Kg - dry 131 238 1 07/27/22 21:40 EAL 6010D Aluminum 13100 mg/Kg - dry 220 238 1 07/27/22 21:40 EAL 6010D Arsenic 15.2 J mg/Kg - dry 11.4 23.8 1 07/27/22 21:40 EAL 6010D Cadmium <0.952 mg/Kg - dry 0.952 4.76 1 07/27/22 21:40 EAL 6010D Calcium 28600 mg/Kg - dry 1840 2380 1 07/27/22 21:40 EAL 6010D Chromium 57.6 mg/Kg - dry 11.2 11.9 1 07/27/22 21:40 EAL 6010D Copper 171 mg/Kg - dry 14.8 23.8 1 07/27/22 21:40 EAL 6010D Iron 5240 mg/Kg - dry 406 476 1 07/27/22 21:40 EAL 6010D Lead 82.4 mg/Kg - dry 8.57 14.3 1 07/27/22 21:40 EAL 6010D Magnesium 2200 mg/Kg - dry 123 238 1 07/27/22 21:40 EAL 6010D Manganese 180 mg/Kg - dry 15.5 23.8 1 07/27/22 21:40 EAL 6010D Mercury 0.576 J mg/Kg - dry 0.324 7.43 1 07/27/22 12:30 TJS 7471A Molybdenum <6.43 mg/Kg - dry 6.43 11.9 1 07/27/22 21:40 EAL 6010D Nickel 23.9 mg/Kg - dry 5.71 11.9 1 07/27/22 21:40 EAL 6010D Potassium 2390 mg/Kg - dry 294 476 1 07/27/22 21:40 EAL 6010D Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 4 of 8 Waypointo ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Road Mocksville , NC 27028 Report Number : 22-207-0024 Lab No : 91149 Sample ID : Unifi Project Unifi Information : Reidsville, NC 2790 Whitten Road, Memphis, TN 38133 Main 901,213,2400 0 Fax 901.213.2440 www.waypointanalytical.com REPORT OFANALYSIS Report Date : 08/03/2022 Received07/26/2022 A 4 Connie Cook Project Manager Matrix: Solids Sampled: 7/ 25 / 2022 10:40 Test Results Units MDL MQL DF Date / Time Analyzed By Analytical Method Selenium <15.2 mg/Kg - dry 15.2 23.8 1 07/27/22 21:40 EAL 6010D Sodium 23000 mg/Kg - dry 619 1190 1 07/27/22 21:40 EAL 6010D Zinc 671 mg/Kg - dry 38.6 59.5 1 07/27/22 21:40 EAL 6010D Sulfur 9620 mg/Kg - dry 247 476 1 07/27/22 21:40 EAL 6010D Sodium Absorption Ratio 5.11 Ratio 0.01 0.01 1 07/27/22 21:40 CALCULATION Qualifiers/ DF Dilution Factor Definitions J Estimated value Page 5 of 8 (D p�i ��,. 2790 Whitten Road, Memphis, TN 38133 Wayl? Main 901.213.2400 ° Fax 901.213.2440 NALYTICAL www.waypointanaIytica1.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 22-207-0024 Shipping Method Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: T135 Shipping container/cooler uncompromised? # Yes 0 No Number of coolers/boxes received I ' Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? Yes 0 No COC agrees with sample label(s)? Yes 0 No COC properly completed Yes 0 No Samples in proper containers? Yes 0 No Sample containers intact? Yes 0 No Sufficient sample volume for indicated test(s)? Yes 0 No All samples received within holding time? Yes 0 No Cooler temperature in compliance? Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes 0 No 0 N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A High concentration container (48 hr) [_ Low concentration EnCore samplers (48 hr) High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes 0 No Comments: Signature: jEmily M. Peterson Date & Time: 07/26/2022 09:23:00 Page 6 of 8 � c 0 Ll # o C17 a CS7 E E C d V L @ •� y N � v0 m q O O a!"t3 C1 � N N ❑ ❑ U r�arn ❑ IQ n❑`o v Q nc G o 0D❑ �g�z=r=as Q ❑ 2 If — o Y 3 7 I ❑ G •m Ui C�7 G a ti 4 QY C �i r �.I 0 0 L7 LL � ❑ � U � 2! .O 7 T ?_ s� �M 7 � 2 E c ❑ u • E SAi O w a 6i ❑ 4 y E ; E p m E P E P u ❑ Mil � � N d a T m C [� a h o 0 2L CL a N aiue6J0/04eaaiN79 y " m m ` co o g z W v eiuowwdlNA-L 0 d yy ice' W W W +� Q❑ N m m 7 ❑ rrCIO nnn �n� 1 [] C 19 U ii L7 l7 Ppp C i.i cc �n C7 y C y t 'n ✓s `• an d 4 A aa!sadwo(�j �a gei(r�] CJ z a a T 4- �' � d �RaM ❑;away) x!1;eye � E c � - c saau!e;uo? }a iagwnN ct Lo C r a J m C __. 0 I a LOLL 1 O T m [J ] Q {) Y C CIO m O~ C O C Q _ I y a E C v v v4i c y~ c c 0 w o c a a C a m CL E = i7 ai a o xa W CD y 0 o o x� a C E 07 m S' �� Q d v d a N ca v W ti� rage i or 6 7/25/2022 mg/kg mg/L Equiv Weight Milli Equiv Sodium 23000 494.5 23 21.5 Calcium 28600 614.9 20 30.745 Magnesium 2200 47.3 12 3.941667 Percent Solids 2.15 SAR 5.16 SAR = Na+ 2 (Ca2+ + Mg2+) 21.50000 0.5( 30.745 2 + 3.94167 2 ) Waypointo ANALYTICAL 10/31 /2022 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 22-292-0019 Client Project Description: Unifi 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Mr. Brent Collins: Waypoint Analytical, LLC. received sample(s) on 10/19/2022 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a' -'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Connie Cook Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 9 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901,213,2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2023 Arkansas State Program 88-0650 02/07/2023 California State Program 2904 06/30/2023 Florida State Program - NELAP E871157 06/30/2023 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2023 Illinois State Program - NELAP 200078 10/10/2023 Kentucky State Program 80215 06/30/2023 Kentucky State Program KY90047 12/31/2022 Louisiana State Program - NELAP LA037 12/31/2022 Louisiana State Program - NELAP 04015 06/30/2023 Mississippi State Program MS 02/11/2023 North Carolina State Program 47701 07/31/2023 North Carolina State Program 415 12/31/2022 Pennsylvania State Program - NELAP 68-03195 05/31/2023 South Carolina State Program 84002 06/30/2022 Tennessee State Program 02027 02/11/2023 Texas State Program - NELAP T104704180 09/30/2022 Virginia State Program 00106 06/30/2023 Virginia State Program - NELAP 460181 09/14/2023 Page 1 of 1 00001/22-292-0019 Page 2 of 9 Waypoint 27(2) 90 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 ANALYTICAL www.waypointanalytical.com Sample Summary Table Report Number: 22-292-0019 Client Project Description: Unifi Lab No Client Sample ID Matrix Date Collected Date Received 98722 Unifi Solids 10/17/202210:45 10/19/2022 Page 3 of 9 Waypointo ANALYTICAL Client: EMA Resources Inc Project: Unifi Lab Report Number: 22-292-0019 Date: 10/31 /2022 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com CASE NARRATIVE Metals Analysis Method 6010D Sample 98996 (DG-4) Analyte: Aluminum QC Batch No: L645160/L644815 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 98996 (DG-4) Analyte: Arsenic QC Batch No: L645160/L644815 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 98996 (DG-4) Analyte: Calcium QC Batch No: L645160/L644815 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 98996 (DG-4) Analyte: Iron QC Batch No: L645365/L644815 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 98996 (DG-4) Analyte: Potassium QC Batch No: L645160/L644815 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 98996 (DG-4) Analyte: Manganese QC Batch No: L645365/L644815 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 98996 (DG-4) Analyte: Phosphorus QC Batch No: L645160/L644815 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 4 of 9 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com Sample 98996 (DG-4) Analyte: Lead QC Batch No: 1-645160/1-644815 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 5 of 9 Waypointo ANALYTICAL 46245 EMA Resources Inc Mr. Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Project Unifi Information : 2790 Whitten Road, Memphis, TN 38133 Main 901,213,2400 0 Fax 901.213.2440 www.waypointanalytical.com Report Date : 10/31/2022 Received10/19/2022 &%4- Connie Cook Report Number :22-292-0019 REPORT OFANAL YSIS Project Manager Lab No : 98722 Matrix: Solids Sample ID : Unifi Sampled: 10/17/2022 10:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 97.7 % 1 10/24/22 17:20 FMM SW-DRYWT Ammonia Nitrogen 24103 mg/Kg - dry 696 4350 1 10/26/22 15:00 JPJ 4500NH3C-2011 Nitrate+Nitrite-N <217 mg/Kg - dry 217 217 1 10/25/22 14:30 ZBD 4500NO3F-2016 Organic N 80703 mg/Kg - dry 4783 9609 1 10/24/22 16:02 DH CALCULATION pH 7.5 S.U. 1 10/26/2216:25 DRS 9045D Total Solids 2.30 % 0.010 0.010 1 10/24/22 17:20 FMM 2540G-2011 Total Volatile Solids 76.7 % 0.010 0.010 1 10/24/22 17:20 FMM 2540G-2011 Total Kjeldahl Nitrogen 10500 mg/Kg - dry 9610 1 10/24/22 16:02 ANH 4500NORGD-2011 Phosphorus 3440 mg/Kg - dry 120 217 1 10/25/22 18:11 TJS 6010D Aluminum 11200 mg/Kg - dry 201 217 1 10/25/22 18:11 TJS 6010D Arsenic <10.4 mg/Kg - dry 10.4 21.7 1 10/25/22 18:11 TJS 6010D Cadmium 1.033 mg/Kg - dry 0.870 4.35 1 10/25/22 18:11 TJS 6010D Calcium 25900 mg/Kg - dry 1680 2170 1 10/25/22 18:11 TJS 6010D Chromium 62.2 mg/Kg - dry 10.3 10.9 1 10/25/22 18:11 TJS 6010D Copper 168 mg/Kg - dry 13.5 21.7 1 10/25/22 18:11 TJS 6010D Iron 5520 mg/Kg - dry 370 435 1 10/25/22 18:11 TJS 6010D Lead 78.7 mg/Kg - dry 7.83 13.0 1 10/25/22 18:11 TJS 6010D Magnesium 8780 mg/Kg - dry 112 217 1 10/25/22 18:11 TJS 6010D Manganese 196 mg/Kg - dry 14.1 21.7 1 10/25/22 18:11 6010D Mercury <0.261 mg/Kg - dry 0.261 6.00 1 10/20/22 15:03 TJS 7471A Molybdenum <5.87 mg/Kg - dry 5.87 10.9 1 10/25/22 18:11 TJS 6010D Nickel 21.0 mg/Kg - dry 5.22 10.9 1 10/25/22 18:11 TJS 6010D Potassium 2190 mg/Kg - dry 269 435 1 10/25/22 18:11 TJS 6010D Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 6 of 9 0 Waypoint 2790 Whitten Road, Memphis, TN 38133 Main 901,213,2400 0 Fax 901.213.2440 ANALYTICAL www.waypointanalytical.com 46245 EMA Resources Inc Project Unifi Mr. Brent Collins Report Date : 10/31/2022 755 Yadkinville Rd Information : Received : 10/19/2022 Mocksville , NC 27028 Connie Cook Report Number :22-292-0019 REPORT OFANAL YSIS Project Manager Lab No : 98722 Matrix: Solids Sample ID : Unifi Sampled: 10/17/2022 10:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <13.9 mg/Kg - dry 13.9 21.7 1 10/25/22 18:11 TJS 6010D Sodium 20900 mg/Kg - dry 565 1090 1 10/25/22 18:11 TJS 6010D Zinc 730 mg/Kg - dry 35.2 54.3 1 10/25/22 18:11 TJS 6010D Sulfur 7260 mg/Kg - dry 225 435 1 10/25/22 18:11 TJS 6010D Sodium Absorption Ratio 4.33 Ratio 0.01 0.01 1 10/25/22 18:11 CALCULATION Qualifiers/ DF Dilution Factor Definitions J Estimated value Page 7 of 9 (D p�i ��,. 2790 Whitten Road, Memphis, TN 38133 Wayl? Main 901.213.2400 ° Fax 901.213.2440 NALYTICAL www.waypointanaIytica1.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 22-292-0019 Shipping Method Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: T135 Shipping container/cooler uncompromised? # Yes 0 No Number of coolers/boxes received I ' Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? Yes 0 No COC agrees with sample label(s)? Yes 0 No COC properly completed Yes 0 No Samples in proper containers? Yes 0 No Sample containers intact? Yes 0 No Sufficient sample volume for indicated test(s)? Yes 0 No All samples received within holding time? Yes 0 No Cooler temperature in compliance? Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No 0 N/A Water - VOA vials free of headspace 0 Yes 0 No 0 N/A Trip Blanks received with VOAs 0 Yes 0 No 0 N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A High concentration container (48 hr) [_ Low concentration EnCore samplers (48 hr) High concentration pre -weighed (methanol -14 d) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes 0 No Comments: Signature: jEmily M. Peterson Date & Time: 10/19/2022 09:15:30 Page 8 of 9 o Y a v vi r V] m 0 c 0 O U Cc CDE •v ''. p a a O C] m o c a � 'o p Q 2 W cNv :; "' cr aw E U Z� l[1 a _ ate= Ol = C =� ❑ O O i x 2 2 x 2 2 u Q - y N M, CL a M� ; v 0_ 0 o > a CO C27 L27 w T Lk,O N } -0 m a a El C o N d a s m a m a ^^jj c n o 7 E u w ¢ a V � ) 2 aa NSAiv a D •� E E E r �' c � _ ° Hd a g � _ rr'� n� p 4 ¢ a m ❑ a VJ spilos 16101 n } cn a m m.= Li N 3iueBJ0/a;ej;iN q a N I t17 eruact��ub'IN�Il d Cp p r CD 2 to G +, (CIOl09) slelaWLl < y N °n N 7 7 ❑ ¢ ro Lp G tD m ce n ❑ C ° \3 '. G Y U m ° aadwo{3) JD gej(F) t A a Q a A d Qc) siauieyuD:) }o J;3 LunN Cc u C • I ro Oa0 C D I C LL G � / ❑ � N t} a E C N C t,J u L CJ Cl)(J G '� 0. D y� a` c Q y � a d j a J � 6 R co U N Q C a F n w R O �U a Q �Z n /yam A� �x� T °o ❑ d o tl7 Y y �� .� •n ,r, o V W P— 2 d Page 9 of 9 10/17/2022 mg/kg mg/L Equiv Weight Milli Equiv Sodium 20900 480.7 23 20.9 Calcium 25900 595.7 20 29.785 Magnesium 8780 201.94 12 16.82833 Percent Solids 2.3 SAR 4.33 SAR = Na+ 2 (Ca2+ + Mg2+) ►EM 0.5( 29.785 2 + 16.82833 2 ) ' PaceAnalytical ANALYTICAL REPORT April 08, 2022 LEI Ss EMA Resources 3 Sample Delivery Group: L1476O24 [Cn] Samples Received: 03/29/2022 Project Number: Isr Description: Sludge 1QC1 E Report To: Mr. Brent Collins 755 Yadkinville Road CAI Mocksville, NC 27028 FSCI Entire Report Reviewed By: ce�'� Justin Carr Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received. � f ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: rMA Resources L1476024 04/08/2215:30 1 of20 TABLE OF CONTENTS Cp: Cover Page 1 1-CP1 Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 ISS] UNIFI L1476024-01 5 [Cn Qc: Quality Control Summary 7 Wet Chemistry by Method 9012 B 7 Isr Wet Chemistry by Method 9034-9030B 8 Wet Chemistry by Method 9045D 9 1QC1 Wet Chemistry by Method D93/1010A 10 GI Mercury by Method 7470A 11 Metals (ICP) by Method 6010D 12 CAI Volatile Organic Compounds (GC/MS) by Method 8260D 13 Chlorinated Acid Herbicides (GC) by Method 8151A 14 ISCI Pesticides (GC) by Method 8081B 15 Semi Volatile Organic Compounds (GC/MS) by Method 8270E 16 GI: Glossary of Terms 18 Al: Accreditations & Locations 19 Sc: Sample Chain of Custody 20 ACCOUNT: PROJECT: S DG: DATE /TIME: PAGE: EMA Resources L1476024 04/08/22 15:30 2 of 20 UNIFI L1476024-01 Waste Collected by Brent Collins Collected date/time 03/28/2209:30 Received date/time 03/29/2209:00 Cp Method Batch Dilution Preparation Analysis Analyst Location date/time date/time RC Preparation by Method 1311 WG1840072 1 03/30/2210:24 03/30/2210:24 JAV Mt. Juliet, TN Preparation by Method 1311 WG1842441 1 04/03/2210:20 04/03/2210:20 JAV Mt. Juliet, TN Wet Chemistry by Method 9012 B WG1839959 1 03/31/22 07:00 04/02/2213:59 LDT Mt. Juliet, TN Wet Chemistry by Method 9034-9030B WG1841495 1 04/03/22 09:00 04/04/22 20:00 CAG Mt. Juliet, TN Wet Chemistry by Method 9045D WG1840192 1 03/30/22 07:00 03/30/22 09:00 GI Mt. Juliet, TN Rn Wet Chemistry by Method D93/1010A WG1840227 1 03/30/22 00:00 03/30/22 00:00 WOS Mt. Juliet, TN Mercury by Method 7470A WG1841409 1 03/31/2214:18 04/03/2215:06 MRW Mt. Juliet, TN Metals (ICP) by Method 6010D WG1841436 1 03/31/2216:47 03/31/22 23:24 CCE Mt. Juliet, TN FSr Volatile Organic Compounds (GC/MS) by Method 8260D WG1842863 1 04/04/2214:39 04/04/2214:39 BMB Mt. Juliet, TN Chlorinated Acid Herbicides (GC) by Method 8151A WG1842932 1 04/05/22 04:17 04/06/2211:30 HLA Mt. Juliet, TN 1QC1 Pesticides (GC) by Method 8081B WG1841953 1 04/03/22 08:38 04/03/22 20:49 AO Mt. Juliet, TN Semi Volatile Organic Compounds (GC/MS) by Method 8270E WG1842908 1 04/04/2215:57 04/05/22 02:17 JNJ Mt. Juliet, TN F sAl FSCI ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: LMA Resources L1476024 04/08/22 15:30 3 of 20 CASE NARRATIVE All sample aliquots were received at the correct temperature, in the proper containers, with the [—CP] appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOO) values reported for environmental samples 17C have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my ISS] knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. I Sr 5 _QC] GI Justin Carr CAI Project Manager Project Narrative I _SC All Reactive Cyanide results reported in the attached report were determined as totals using method 9012 B. All Reactive Sulfide results reported in the attached report were determined as totals using method 9034-9030B. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1476024 04/08/22 15:30 4 of 20 SAMPLE RESULTS - 01 L1476024 UNIFI Collected date/time: 03/28/22 09:30 Preparation by Method 1311 Result Qualifier Prep Batch Analyte date / time TCLP Extraction 3/30/202210:24:12 AM WG1240072 TCLP ZHE Extraction - 4/3/202210:20:23 AM WG1342441 Fluid 1 3/30/202210:24:12 AM WG1340072 Initial pH 7.01 3/30/202210:24:12 AM WG1340072 Final pH 5.06 3/30/202210:24:12 AM WG1340072 Wet Chemistry by Method 9012 B Result Qualifier RDL Dilution Analysis Batch Analyte mg/kg mg/kg date / time Reactive Cyanide ND 0.250 1 04/02/202213:59 WG1839959 Wet Chemistry by Method 9034-9030B Result Qualifier RDL Dilution Analysis Batch Analyte mg/kg mg/kg date / time Reactive Sulfide ND 75.0 1 04/04/2022 20:00 WG1841495 Wet Chemistry by Method 9045D Result Qualifier Dilution Analysis Batch Analyte su date / time Corrosivity by pH 7.55 T8 1 03/30/2022 09:00 WG1840192 Sample Narrative: L1476024-01 WG1840192: 7.55 at 20.8C Wet Chemistry by Method D93/1010A Result Qualifier Dilution Analysis Batch Analyte Deg. F date / time Ignitability DNI at 170 1 03/30/2022 00:00 WG1840227 Mercury by Method 7470A Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date/time Mercury ND 0.0100 0.20 1 04/03/202215:06 WG1841409 Metals (ICP) by Method 6010D 1-CP1 ITC] ITS] [Cn] 5 QC GI CAI 9 Sc Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date/time Arsenic ND 0.100 5 1 03/31/2022 23:24 WG1841436 Barium ND 0.100 100 1 03/31/2022 23:24 WG1841436 Cadmium ND 0.100 1 1 03/31/2022 23:24 WG1841436 Chromium ND 0.100 5 1 03/31/2022 23:24 WG1841436 Lead ND 0.100 5 1 03/31/2022 23:24 WG1841436 Selenium ND 0.100 1 1 03/31/2022 23:24 WG1841436 Silver ND 0.100 5 1 03/31/2022 23:24 WG1841436 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date/time Benzene ND 0.0500 0.50 1 04/04/202214:39 WG1842863 Carbon tetrachloride ND 0.0500 0.50 1 04/04/202214:39 WG1842863 Chlorobenzene ND 0.0500 100 1 04/04/202214:39 WG1842863 Chloroform ND 0.250 6 1 04/04/202214:39 WG1842863 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: LIMA Resources L1476024 04/08/2215:30 5 of20 UNIFI SAMPLE RESULTS - 01 Collected date/time: 03/28/22 09:30 L1476024 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier RDL Limit Dilution Analysis Batch FP1 Analyte mg/l mg/l mg/1 date/time 1,2-Dichloroethane ND 0.0500 0.50 1 04/04/202214:39 WG1842863 Rc 1,1-Dichloroethene ND 0.0500 0.70 1 04/04/202214:39 WG1842863 2-Butanone (MEK) ND 0.500 200 1 04/04/202214:39 WG1842863 Tetrachloroethene ND 0.0500 0.70 1 04/04/202214:39 WG1842863 Rs Trichloroethene ND 0.0500 0.50 1 04/04/202214:39 WG1842863 Vinyl chloride ND 0.0500 0.20 1 04/04/202214:39 WG1842863 Rn (S) Toluene-d8 103 80.0-120 041041202214:39 WG1842863 (S)4-Bromofluorobenzene 99.4 77.0-126 041041202214:39 WG1842863 (S)1,2-Dichloroethane-d4 94.4 70.0-130 041041202214:39 WG1842863 Chlorinated Acid Herbicides (GC) by Method 8151A PC] Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/l mg/l mg/1 date/time GI 2,4,5-TP (Silvex) ND 0.00200 1 1 04/06/202211:30 WG1842932 2,4-D ND 0.00200 10 1 04/06/202211:30 WG1842932 8 (S) 2,4-Dichlorophenyl Acetic Acid 52.4 14.0-158 041061202211:30 WG1842932 AI Pesticides (GC) by Method 8081B FSCI Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/l mg/l mg/1 date/time Chlordane ND 0.00500 0.03 1 04/03/2022 20:49 WG1841953 Endrin ND 0.00500 0.02 1 04/03/2022 20:49 WG1841953 Heptachlor ND 0.00500 0.0080 1 04/03/2022 20:49 WG1841953 Heptachlor epoxide ND 0.00500 0.0080 1 04/03/2022 20:49 WG1841953 Lindane ND 0.00500 0.40 1 04/03/2022 20:49 WG1841953 Methoxychlor ND 0.00500 10 1 04/03/2022 20:49 WG1841953 Toxaphene ND 0.0100 0.50 1 04/03/2022 20:49 WG1841953 (S) Decachlorobiphenyl 93.1 10.0-128 0410312022 20:49 WG1841953 (S) Tetrochloro-m-xylene 71.5 10.0-127 0410312022 20:49 WG1841953 Semi Volatile Organic Compounds (GC/MS) by Method 8270E Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/l mg/l mg/1 date/time 1,4-Dichlorobenzene ND 0.100 7.50 1 04/05/2022 0217 WG1842908 2,4-Dinitrotoluene ND 0.100 0.13 1 04/05/2022 0217 WG1842908 Hexachlorobenzene ND 0.100 0.13 1 04/05/2022 0217 WG1842908 Hexachloro-1,3-butadiene ND 0.100 0.50 1 04/05/2022 0217 WG1842908 Hexachloroethane ND 0.100 3 1 04/05/2022 0217 WG1842908 Nitrobenzene ND 0.100 2 1 04/05/2022 0217 WG1842908 Pyridine ND J3 J4 J6 0.100 5 1 04/05/2022 02:17 WG1842908 3&4-Methyl Phenol ND 0.100 400 1 04/05/2022 0217 WG1842908 2-Methylphenol ND 0.100 200 1 04/05/2022 0217 WG1842908 Pentachlorophenol ND 0.100 100 1 04/05/2022 0217 WG1842908 2,4,5-Trichlorophenol ND 0.100 400 1 04/05/2022 0217 WG1842908 2,4,6-Trichlorophenol ND 0.100 2 1 04/05/2022 0217 WG1842908 (S) 2-Fluorophenol 46.9 10.0-120 0410512022 02:17 WG1842908 (S) Phenol-d5 33.0 10.0-120 0410512022 02:17 WG1842908 (S) Nitrobenzene-d5 86.9 10.0-127 0410512022 02:17 WG1842908 (S) 2-Fluorobiphenyl 80.4 10.0430 0410512022 02:17 WG1842908 (S)2,4,6-Tribromophenol 950 10.0-155 0410512022 02:17 WG1842908 (S) p-Terphenyl-d14 77.1 10.0-128 0410512022 02:17 WG1842908 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1476024 04/08/2215:30 6 of20 EEEEEMEEE � ry Q � 77 D Cf) I O § F 3 � 2 Z \_ O U � � � Q � � / IP J \ 9| \ 9| \ j ID a � � G c { a \ \ ƒ , (, i \ e j\ 2 j\ S \ > s _ ° \ \ / » 7 E j 2/ 5 § a= co/§ \ > j ) - 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O N O I� CON N c9 M of r M N — Ln m M Q E O O O O O O Z O O O O O O � o — � p p p p p p p p p p p p m O E z z z z z z z z z z z z Ln c 0 0 0 0 0 0 0 0 0 0 0 0 0 0 N — O O O O O O O O O O O O O D- p] LCJ LCJ LCJ LCJ LCJ LCJ LCJ LCJ LCJ LCJ LCJ LCJ In E O O O O O O O O O O O O N N O o � O G o o 4 — .. U J N �� t t t C O ¢ - N = = = 2 d M N GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not Intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions MDL Method Detection Limit. ND Not detected at the Reporting Limit (or MDL where applicable). RDL Reported Detection Limit. Rec. Recovery. RPD Relative Percent Difference. SDG Sample Delivery Group. Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and (S) Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. u Not detected at the Reporting Limit (or MDL where applicable). Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the Dilution standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal Limits for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. Original Sample The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section of the report includes the results of the laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description J The identification of the analyte is acceptable, the reported value is an estimate. J3 The associated batch QC was outside the established quality control range for precision. J4 The associated batch QC was outside the established quality control range for accuracy. J6 The sample matrix Interfered with the ability to make any accurate determination; spike value is low. T8 Sample(s) received past/too close to holding time expiration. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1476024 04/08/22 15:30 18 of 20 ACCREDITATIONS & LOCATIONS Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 Alabama 40660 Nebraska NE-05-15-05 Alaska 17-026 Nevada TN000032021-1 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TNO02 California 2932� New Mexico TN00003 Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky's KY90010 South Carolina 84004002 Kentucky 2 16 South Dakota n/a Louisiana AI30792 Tennessee 2006 Louisiana LA018 Texas T104704245-20-18 Maine TN00003 Texas' LAB0152 Maryland 324 Utah TN000032021-11 Massachusetts M-TNO03 Vermont VT2006 _ Michigan 9958 Virginia 110033 Minnesota 047-999-305 Washington _ C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 998093910 Montana CERT0086 Wyoming A2LA A2LA — 150 17025 1461.01 AIHA-LAP,LLC EMLAP 100789 A21-A — ISO 17025' 1461.02 DOD 1461.01 Canada 1461.01 USDA P330-15-00234 EPA—Crypto TN00003 Drinking Water 2 Underground Storage Tanks ' Aquatic Toxicity 4 Chemical/Microbiological ' Mold ' Wastewater n/a Accreditation not applicable Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical. ACCOUNT: PROJECT: SDG: DATE/TIME: LMA Resources L1476024 04/08/2215:30 PAGE: 19 of 20 xoa.x Rs 9 cc- '1i ,,, ^ •ryry x 1 'W J m � o u U Z LU a Ln C W ,..� Cn Z w d re 'op EE `0 'm o m CL ro r❑ NN u w E a is E a CL a a o u - _ c fj 1Y fJ ro S1 m '4 Ski 1 •+ •1N U P Qi w U N N y Up(p,7e-!.� rww 14 �G ci n u00 u V) a. px`, 2 S d � d 2 v a � a d 2 w °i E d E � F O ro ~ a V ffl d N m � w a i J sasdON-Jl?-Il Ilnb - dl:) l x saMON-}p-li RSba x a b ro A a m N = # d OaC a .n CC L U ro \ a d O a N 4 2' U aE+ io C a @J a ai hi c m r w .0 �� 2 ul uu sc p v x ro ro ° 27 O -- c � � L 3 L 7 r r C•i � LL L m sn oa a LL fA 3 m N U ,ti de VI a a m m m a L '^ C 3 a E y u, N $ a U = c .di o ro O Z o -4Ln m ro ro a n s VY 7 d t u a n �� y 3 aL, v v n z 'a cm N c Q �a E mv°LDQ u Ln LLI r, 2 m a ,-'^ cr 2 -C a a u o ro u E 0- cc oc x 2022 Unifi Annual Report - WQ0006594 Final Audit Report 2023-02-09 Created: 2023-02-08 By: Brent Collins (brent.collins@emaresourcesinc.com) Status: Signed Transaction ID: CBJCHBCAABAAn7BLYYgCyLCBhCYbEQPUfvmRf2EV2d0- "2022 Unifi Annual Report - WQ0006594" History Document created by Brent Collins (brent.collins@emaresourcesinc.com) 2023-02-08 - 11:37:48 PM GMT- IP address: 206.85.202.26 P-► Document emailed to Ihaynes@unifi.com for signature 2023-02-08 - 11:39:05 PM GMT Email viewed by Ihaynes@unifi.com 2023-02-09 - 1:07:48 PM GMT- IP address: 174.111.15.82 dp Signer Ihaynes@unifi.com entered name at signing as Lisa Haynes 2023-02-09 - 1:11:17 PM GMT- IP address: 174.111.15.82 Gip Document e-signed by Lisa Haynes (Ihaynes@unifi.com) Signature Date: 2023-02-09 - 1:11:19 PM GMT - Time Source: server- IP address: 174.111.15.82 Q Agreement completed. 2023-02-09 - 1:11:19 PM GMT 0 Adobe Acrobat Sign