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HomeMy WebLinkAboutWQ0002376_2022 Residual Annual Report_20230228 (2)Initial Review Reviewer Nathaniel.Thornburg Is this submittal an application? (Excluding additional information.) * Yes No If not an application what is the submittal type?* Annual Report Residual Annual Report Additional Information Other Annual Report Year* 2022 Permit Number (IR) * WQ0002376 Applicant/Permittee City of Reidsville Email Notifications Does this need review by the hydrogeologist? * Yes U No Regional Office Winston-Salem CO Reviewer Admin Reviewer Submittal Form Project Contact Information Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence. Name* Brent Collins Email Address* brent.collins@emaresourcesinc.com Project Information ......................... Application/Document Type* New (Fee Required) Modification - Major (Fee Required) Renewal with Major Modification (Fee Required) Annual Report Additional Information Other Phone Number* 336-399-3646 Modification - Minor Renewal GW-59, NDMR, NDMLR, NDAR-1, N DAR-2 Residual Annual Report Change of Ownership We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form. https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report Permit Type:* Wastewater Irrigation High -Rate Infiltration Other Wastewater Reclaimed Water Closed -Loop Recycle Residuals Single -Family Residence Wastewater Other Irrigation Permit Number:* WQ0002376 Has Current Existing permit number Applicant/Permittee Address* 1100 Vance Street, Reidsville, NC 27320 Facility Name* City of Reidsville Class B Residuals Program Please provide comments/notes on your current submittal below. At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg at nathaniel.thornburg@ncdenr.gov. Please attach all information required or requested for this submittal to be reviewed here. (Application Form, Engineering Plans, Specifications, Calculations, Etc.) 2022 Reidsville Annual Report - WQ0002376.pdf 13.7MB Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger than upload limit. * By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts of the application in correct order (as specified by the application). Mail payment to: NCDEQ — Division of Water Resources Attn: Non -Discharge Branch 1617 Mail Service Center Raleigh, NC 27699-1617 Signature Submission Date 2/28/2023 February 28, 2023 DENR/Water Quality Section Non -Discharge Compliance Unit 1617 Mail Service Center Raleigh, NC 27699-1617 Re: 2022 Annual Report - Reidsville Treatment and Land Application of Residuals Permit No. WQ0002376 Dear Sir or Madam: Enclosed is the 2022 Annual Report for the above referenced land application permit. During 2022 EMA Resources, Inc. land applied 307.76 dry tons of wastewater residuals to 237.7 acres of private farmland. Please contact Brent Collins - Director of Technical Services if you have any further questions regarding this report. Sincerely, Z.-e4:241- Brent Collins Director of Technical Services brent.collins&emaresourcesinc.com Phone 336975191441 — Fax 336975191442 755 Yadkinville Rd — Mocksville, NC 27028 --Resources, Inc. City of Reidsville 2022 Annual Report Residuals Land Application Permit No. WQ0002376 Prepared By: EMA Resources, Inc. Phone 336975191441 — Fax 336975191442 755 Yadkinville Rd — Mocksville, NC 27028 ANNUAL LAND APPLICATION CERTIFICATION FORM WQ Permit#: WQ0002376 County: Rockingham County Year: 2022 Facility Name (as shown on permit): City of Reidsville Land Application Operator: EMA Resources Inc. Phone: Land application of residuals as allowed by the permit occurred during the past calendar year? [0 Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were generated but not land applied, please attach an explanation on how the residuals were handled. Part A - Residuals Application Summary: 336-751-1441 Total number of application fields in thepermit] 56 Total number of fields utilized for land application during the year: 19 Total amount of dry tons applied during the year for all application sites: 307.76 Total number of acres utilizes for land application during the year: 237.7 Part B - Annual Compiance Statement: Facility was compliant during calendar year _2022_ with all conditions of the land application permit (including but not limited to items 1-13 below) issued by the Division of Water Quality. ❑ Yes ❑ No If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action taken. 1) Only residuals approved for this permit were applied to the permitted sites. 2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the limit specified in the permit. 3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of laboratory results are attached. 4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached. 5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3) copies of certified laboratory results are attached. 6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T . 1105(a) or the Pollutant Loading Rates in 15A NCAC 02T .I 105(b) (applicable to 40 CFR Part 503 regulated facilities). 7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part 503 regulated facilities). 8) All monitoring and reporting requirements in 15A NCAC 02T . I I I I were complied with (applicable to 40 CFR Part 503 regulated facilities). 9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior authorization was received from the Division of Water Quality. 10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are attached to include appropriate actions and remediations. 11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified in the permit. 12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred. 13) All buffer requirements as specified on the permit were maintained during each application of residuals. Part C - Certification: "I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate, and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Summer Woodard - City Manager Permittee Name and Title (type or print) &4 // Fottel; , 7` Feb 10, 2023 Ralph . Potter, Jr (Feb 10, 2023 07:38 EST) S�Wwg/- Gy000i��Gi_ Summer Woodard (Feb 10, 202316:24 EST) Signature of Permittee ;dzL Feb 10, 2023 Date 441� 1/2/2023 Signature of Preparer* Date Signature of Land Applier Date (if different from Permittee) (if different from Permittee and Preparer) * Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T .1102 (26) DEN FORM ACF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B WQ Permit Number: Facility Name: Residual Source WQ # or NPDES #: WWTP Name: Recidnal AnAvcic Data WQ0002376 Laboratory: City of Reidsville NCO024881 Reidsville WWTP 1) 2) 3) 4) 5) Waypoint Analytical Parameter (mg/kg) Conc. Limit (mg/kg a Sample or Composite Date 1/12/22 4/6/22 7/5/22 10/3/22 Percent Solids (%) NA 1.68 1.72 1.25 1.02 Arsenic 75 14.3 29.4 20 21.8 Cadmium 85 1.19 5.88 1.67 1.82 Copper 4,300 234 224 275 291 Chromium NA 38.7 39.5 55.4 48.2 Lead 840 53.9 55.4 69.2 67.4 Mercury 57 0.595 0.382 1.18 0.575 Molybdenum 75 8.04 14.7 11.7 12.3 Nickel 420 15.8 16.6 21.8 14 Selenium 100 19 29.4 26.7 29.1 Zinc 7,500 798 706 983 955 Total Phosphorus NA 22800 20600 23600 23400 TKN NA 88700 84700 143000 89100 Ammonia -Nitrogen NA 13500 14100 27300 11500 Nitrate and Nitrite NA 448 275 381 451 a For surface disposal facilities the ceiling concentration limits listed in this form are not applicable. Reference the individual permit for metals limits. "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." �GCCbrr tf �atte� ; 7y R Ph Pattc,J cF,bl¢,]D1317:38EST) Feb 10, 2023 Signature of Preparer * Date *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) DENR FORM RSSF (12/2006) ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past calendar year. Use additional forms as needed. WQ Permit Number: WQ0002376 Facility Name: City of Reidsville Residual Source NPDES # or WQ#: WWTP Name: Residual Analvsis Data NCO024881 Reidsville WWTP Laboratory: 1) Waypoint Analytical 2) 3) 4) 5) Parameter Sample or Composite Date 11 11 111 11 -------- 111 11 •11 11 -------- ------------ ------------ ------------ ------------ ------------ ------------ "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." Signature of Preparer * *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) Feb 10, 2023 Date DENR FORM RSSF - B (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Reidsville Total Dry Tons Applied (Annual): Permit #: WQ0002376 Cation Exchange Capacity (non 503 only): Operator: Harry Sharpe Owner: Daisy Purgason Predominant Soil Series: Acres Used: 20.67 Acres Permitted: 20.67 Site #: RC011 Field #: 38.28 NaB 1 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus ■■■■■■■■■■■■ Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5 6 7 81 9 10 11 12 y DT/Ac./ App. .fir Event 0.71 1.15 Arsenic 0.020 0.046 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.066 Cadmium 0.002 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Copper 0.330 0.631 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.961 Chromium 0.055 0.127 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.182 Lead 0.076 0.159 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.235 Mercury 0.001 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.011 0.027 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.038 denum Nickel 0.022 0.050 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.072 Selenium 0.027 0.061 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.088 Zinc 1.125 1 2.255 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.380 Total Phos- 32.148 54.138 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 86.286 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r_ 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: Operator: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville WQ Permit #: WQ0002376 Field #: 1 Acres Utilized: Daisy Purgason Annual Dry Tons Applied: 38.28 Site #: RC011 Acres Permitted: Harry Sharpe Crop 1 Name: Fescue -Hay Predominant Soil Series: Crop 1 Max. PAN: 178 NaB Crop 2 Name: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 20.67 20.67 0 o S Q Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Sod Cond. D Wet Moist) Precip. Past 24 Hrs. inches y 4 b co a� *o• o w N' °�J 4 - ro ?: ° * *� o TKN mg/kg Z o va o mg/kg Nitrate and Nitrite mg/kg PAN Applied lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2/21 78000 1.68 1 0.264 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 15.734 NA Fescue 2/22 39000 1.68 0.132 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 7.867 NA Fescue 3/3 91000 1.68 0.308 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 18.356 NA Fescue 7/22 52000 1.25 0.131 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 12.783 NA Fescue 7/25 91000 1.25 0.229 Reidsville WWTP Dry <.5" S 1 0.5 0.3 143000 27300 381 22.370 NA Fescue 7/26 97500 1.25 0.246 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 23.968 NA Fescue 9/16 65000 1.25 0.164 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 15.979 NA Fescue 9/19 84500 1.25 0.213 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 1 20.772 NA Fescue 9/21 65000 1.25 0.164 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 15.979 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 663000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 153.808 0.000 Lime Applied Annuallbs/acre 0.066 0.006 0.961 0.182 0.235 0.004 0.038 0.072 0.088 3.380 86.286 Date lbs/ac Prior Years Cumulative lbs/ac 0.306 0.052 4.018 0.981 0.852 0.015 0.19 0.52 0.364 11.248 Current Cumulative lbs/ac 0.372 0.058 4.979 1.163 1.087 0.019 0.228 0.592 0.452 14.628 Permitted C. P. L. R.**** 36 34 1 1338 1 1 267 1 15 1 1 374 1 89 1 2498 Permit PAN Limit 1 st/2nd Crop 178 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM MFLSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Reidsville Total Dry Tons Applied (Annual): Permit #: WQ0002376 Cation Exchange Capacity (non 503 only): Operator: Harry Sharpe Owner: Iris Sharpe Predominant Soil Series: Acres Used: 9.34 Acres Permitted: 9.34 Site #: RC011 Field #: 2.28 NaB 2 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 2 1 3 4 5j 6j 7j 81 9 10 11 12 _1J DT/Ac./ App. .fir Event 0.24 Arsenic 0.007 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.007 Cadmium 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Copper 0.114 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.114 Chromium 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.019 Lead 0.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.026 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 denum Nickel 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.008 Selenium 0.009 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.009 Zinc 0.389 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.389 Total Phos- 11.126 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 11.126 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r_ 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Iris Sharpe Operator: Harry Sharpe Crop 1 Name: Fescue -Hay WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 2.28 Site #: Predominant Soil Series: Crop 1 Max. PAN: 178 NaB Crop 2 Name: Acres Utilized: 9.34 RCO11 Acres Permitted: 9.34 Cation Exchange Capacity (non 503): Crop 2 Max. PAN: � Q Volume applied (enter one) Solids/ Liquid Cu. Yds Gallons % Solids Volume Applied per Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Sod Cond. D Wet Moist) Precip. Past 24 Hrs. inches y 4 - cob a� o o * N �' C ?: ° r TKN mg/kg Z � o va o mg/kg Nitrate and Nitrite mg/kg PAN Applied (lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/3 32500 1.68 0.244 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 14.508 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 32500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 14.508 0.000 Lime Applied Annuallbs/acre 0.007 0.001 0.114 0.019 0.026 0.000 0.004 0.008 0.009 0.389 11.126 Date lbs/ac Prior Years Cumulative lbs/ac 0.113 0.015 1.073 0.262 0.252 0.005 0.064 0.115 0.145 3.488 Current Cumulative lbs/ac 0.120 0.016 1.187 0.281 0.278 0.005 0.068 0.123 0.154 3.877 Permitted C. P. L. R.**** 36 34 1 1338 1 267 15 1 374 1 89 1 2498 Permit PAN Limit 1 st/2nd Crop 1 1 178 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: City of Reidsville Total Dry Tons Applied (Annual): 21.86 WQ0002376 Cation Exchange Capacity (non 503 only): Harry Sharpe Owner: Lawrence McCollum Predominant Soil Series: CgB2 8.95 Acres Permitted: 8.95 Site #: RC012 Field #: 1 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 1/12/22 2 4/6/22 3 7/5/22 4 5 6 7 8 9 10 11 12 % Solids 1.68 1.72 1.25 Arsenic 14.3 29.4 20 Cadmium 1.19 5.88 1.67 Copper 234 224 275 Chromium 38.7 39.5 55.4 Lead 53.9 55.4 69.2 Mercury 0.595 0.382 1.18 Molyb- denum 8.04 14.7 11.7 Nickel 15.8 16.6 21.8 Selenium 19 29.4 26.7 Zinc 798 706 983 Total Phos- horus 22800 20600 23600 Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5j 6j 7j 81 9 10 11 112 DT/Ac./ App. .fir Event 1.02 0.37 1.06 Arsenic 0.029 0.021 0.042 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.093 Cadmium 0.002 0.004 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Copper 0.476 0.164 0.583 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.223 Chromium 0.079 0.029 0.117 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.225 Lead 0.110 0.040 0.147 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.297 Mercury 0.001 0.000 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.016 0.011 0.025 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.052 denum Nickel 0.032 0.012 0.046 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.091 Selenium 0.039 0.021 0.057 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.117 Zinc 1.625 0.515 2.084 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.224 Total Phos- 46.421 15.038 50.032 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 111.491 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r_ 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Lawrence McCollum Operator: Harry Sharpe Crop 1 Name: Fescue -Hay WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 21.86 Site #: Predominant Soil Series: CgB2 Crop 1 Max. PAN: 209 Crop 2 Name: Acres Utilized: RC012 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 8.95 8.95 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a c� *o• o ,•d �, K w •, *� TKN mg/kg Z ; o M o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2/17 130000 1.68 1.018 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 60.562 NA Fescue 4/29 45500 1.72 0.365 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 20.788 NA Fescue 7/19 26000 1.25 0.151 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 14.761 NA Fescue 7/20 156000 1.25 0.909 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 88.567 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 357500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 184.6781 o.000 Lime Applied Annuallbs/acre 0.093 0.010 1.223 0.225 0.297 0.004 0.052 0.091 0.117 4.224 111.491 Date lbs/ac Prior Years Cumulative lbs/ac 0.329 0.053 3.879 0.974 0.848 0.019 0.218 0.538 0.428 11.5 Current Cumulative lbs/ac 0.422 1 0.063 5.102 1.199 1.145 0.023 0.270 0.629 0.545 15.724 Permitted C. P. L. R.**** 36 34 1 1338 1 1 267 1 15 1 1 374 89 2498 Permit PAN Limit lst/2nd Crop 209 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Reidsville Total Dry Tons Applied (Annual): Permit #: WQ0002376 Cation Exchange Capacity (non 503 only): Operator: Harry Sharpe Owner: Lawrence McCollum Predominant Soil Series: Acres Used: 3.52 Acres Permitted: 3.52 Site #: RC012 Field #: 8.01 RnB 2A Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 11 21 3 4 5j 6j 7j 81 9 10 ill 12 DT/Ac./ App. .fir Event 1.99 0.29 Arsenic 0.117 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.128 Cadmium 0.023 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.024 Copper 0.890 0.159 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.049 Chromium 0.157 0.032 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.189 Lead 0.220 0.040 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.260 Mercury 0.002 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.058 0.007 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.065 denum Nickel 0.066 0.013 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.079 Selenium 0.117 0.015 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.132 Zinc 2.806 0.568 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.374 Total Phos- 81.864 13.641 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 95.505 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r_ 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Lawrence McCollum Operator: Harry Sharpe Crop 1 Name: Fescue -Hay WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 8.01 Site #: Predominant Soil Series: RnB Crop 1 Max. PAN: 167 Crop 2 Name: 2A Acres Utilized: RC012 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 3.52 3.52 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F *o• o ,•d �, w •, *� TKN mg/kg Z ; o M o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 5/4 19500 1.72 0.397 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 22.652 NA Fescue 5/5 78000 1.72 1.589 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 90.608 NA Fescue 7/22 19500 1.25 0.289 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 28.149 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 117000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P i4i.4ogT o.000 Lime Applied Annuallbs/acre 0.128 0.024 1.049 0.189 0.260 0.002 0.065 0.079 0.132 3.374 95.505 Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 0 0 0 Current Cumulative lbs/ac 0.128 1 0.024 1.049 0.189 0.260 0.002 0.065 0.079 0.132 3.374 Permitted C. P. L. R.**** 1 36 34 1 1338 1 1 267 1 15 1 1 374 1 89 1 2498 Permit PAN Limit lst/2nd Crop 1 1 167 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: City of Reidsville Total Dry Tons Applied (Annual): 24.41 WQ0002376 Cation Exchange Capacity (non 503 only): Harry Sharpe Owner: Lawrence McCollum Predominant Soil Series: CgB2 10.94 Acres Permitted: 10.94 Site #: RC012 Field #: 2B Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 11 21 3 4 5j 6j 7j 81 9 10 ill 12 DT/Ac./ App. .fir Event 1.36 0.87 Arsenic 0.080 0.035 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.115 Cadmium 0.016 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.019 Copper 0.611 0.477 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.088 Chromium 0.108 0.096 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.204 Lead 0.151 0.120 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.271 Mercury 0.001 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molyb- 0.040 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.060 denum Nickel 0.045 0.038 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.083 Selenium 0.080 0.046 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.127 Zinc 1.926 1.705 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.630 Total Phos- 56.197 40.922 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 97.119 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r_ 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Lawrence McCollum Operator: Harry Sharpe Crop 1 Name: Fescue -Hay WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 24.41 Site #: Predominant Soil Series: CgB2 Crop 1 Max. PAN: 209 Crop 2 Name: Acres Utilized: RC012 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 10.94 10.94 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a c� *o• o ,•d �, K w •, *� TKN mg/kg 84700 Z ; o M o mg/kg 14100 Nitrate and Nitrite mg/kg 275 PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 5/2 78000 1.72 0.511 Reidsville WWTP Dry <.5" S 0.5 0.3 29.154 NA Fescue 5/3 78000 1.72 0.511 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 29.154 NA Fescue 5/4 52000 1.72 0.341 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 19.436 NA Fescue 7/21 149500 1.25 0.712 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 69.438 NA Fescue 7/22 32500 1.25 0.155 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 15.095 NA Fescue 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 390000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 162.2761 o.000 Lime Applied Annuallbs/acre 0.115 0.019 1.088 0.204 0.271 0.003 0.060 0.083 0.127 3.630 97.119 Date lbs/ac Prior Years Cumulative lbs/ac 0 0 0 0 0 0 0 0 0 0 Current Cumulative lbs/ac 0.115 1 0.019 1.088 0.204 0.271 0.003 0.060 0.083 0.127 3.630 Permitted C. P. L. R.**** 36 34 1 1338 1 1 267 1 15 1 1 374 89 2498 Permit PAN Limit lst/2nd Crop 209 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Reidsville Total Dry Tons Applied (Annual): 29.35 Permit #: WQ0002376 Cation Exchange Capacity (non 503 only): Operator: Ronnie Marshall Owner: Bennett Farms LLC Predominant Soil Series: FrD2 Acres Used: 57.22 Acres Permitted: 57.22 Site #: RC015 Field #: 1 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 2 1 3 4 5j 6j 7j 81 9 10 11 1 12 _1J DT/Ac./ App. .fir Event 0.51 Arsenic 0.030 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.030 Cadmium 0.006 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.006 Copper 0.230 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.230 Chromium 0.041 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.041 Lead 0.057 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.057 Mercury 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Molyb- 0.015 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.015 denum Nickel 0.017 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Selenium 0.030 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.030 Zinc 0.724 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.724 Total Phos- 21.136 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 21.136 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Bennett Farms LLC Operator: Ronnie Marshall Crop 1 Name: Fescue -Hay WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 2935 Site #: Predominant Soil Series: FrD2 Crop 1 Max. PAN: 154 Crop 2 Name: Acres Utilized: RC015 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 57.22 57.22 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # - w •, * N *� TKN mg/kg Z ; o M o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 5/6 65000 1.72 0.081 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 4.645 NA Fescue 5110 136500 1.72 0.171 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 9.754 NA Fescue 5111 130000 1.72 0.163 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 9.290 NA Fescue 5/12 78000 1.72 0.098 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 5.574 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 409500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 29,26-7 o.000 Lime Applied Annuallbs/acre 0.030 0.006 0.230 0.041 0.057 0.000 0.015 0.017 0.030 0.724 21.136 Date lbs/ac Prior Years Cumulative lbs/ac 0.329 0.053 3.879 0.974 0.848 0.019 0.218 0.538 0.428 11.5 Current Cumulative lbs/ac 0.359 1 0.059 4.109 1.015 0.905 0.019 0.233 0.555 0.458 12.224 Permitted C. P. L. R.**** 36 34 1 1338 1 1 267 1 15 1 1 374 1 89 1 2498 Permit PAN Limit lst/2nd Crop 154 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: City of Reidsville Total Dry Tons Applied (Annual): 3.05 WQ0002376 Cation Exchange Capacity (non 503 only): Thomas Carter Owner: Mary Stanley Predominant Soil Series: CgB2 3.66 Acres Permitted: 3.66 Site #: RC019 Field #: 3 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date OEM MEMO Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 2 1 3 4 5j 6j 7 8 9 10 11 12 _1J DT/Ac./ App. .fir Event 0.83 Arsenic 0.033 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.033 Cadmium 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Copper 0.458 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.458 Chromium 0.092 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.092 Lead 0.115 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.115 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.019 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.019 denum Nickel 0.036 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.036 Selenium 0.044 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.044 Zinc 1.638 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.638 Total Phos- 39.318 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 39.318 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r_ 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Mary Stanley Operator: Thomas Carter Crop 1 Name: Fescue -Pasture WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 3.05 Site #: Predominant Soil Series: CgB2 Crop 1 Max. PAN: 156 Crop 2 Name: Acres Utilized: RC019 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 3.66 3.66 0 Q Volume applied enter one Solids/ Liquid Cu. Yds Gallons o /o Solids Volume A lied er pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a c� w *o• o ,•d � # w , * N' *� TKN mg/kg Z ; o oa o �• mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 9/15 58500 1.25 0.833 Reidsville WWTP Dry <.5" S 0.5 1 0.3 143000 27300 381 81.217 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF so pp to this form): TOTALS: 01 58500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 81.217 0.000 Lime Applied Annuallbs/acre 0.033 0.003 0.458 0.092 0.115 0.002 0.019 0.036 0.044 1.638 39.318 Date lbs/ac Prior Years Cumulative lbs/ac 0.062 0.02 1.513 0.072 0.184 0.009 0.118 0.347 0.03 3.995 Current Cumulative lbs/ac 0.095 0.023 1.971 0.164 0.299 0.011 0.137 0.383 0.074 5.633 Permitted C. P. L. R.**** 36 1 34 1 1338 1 1 267 1 15 1 1 374 89 2498 Permit PAN Limit lst/2nd Crop 156 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Reidsville Total Dry Tons Applied (Annual): 25.88 Permit #: WQ0002376 Cation Exchange Capacity (non 503 only): Operator: Donald Lovelace Owner: Lofton Lovelace Predominant Soil Series: CdB2 Acres Used: 11.09 Acres Permitted: 11.09 Site #: RC041 Field #: 1 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite- Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 2 1 3 4 5j 6j 7j 81 9 10 11 1 12 _1J DT/Ac./ App. .fir Event 0.82 1.51 Arsenic 0.023 0.089 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.112 Cadmium 0.002 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.020 Copper 0.384 0.678 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.062 Chromium 0.064 0.120 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.183 Lead 0.089 0.168 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.256 Mercury 0.001 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.013 0.044 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.058 denum Nickel 0.026 0.050 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 1 0.076 Selenium 0.031 0.089 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.120 Zinc 1.310 2.136 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.447 Total Phos- 37.438 62.336 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 99.773 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 2/ 14/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Lofton Lovelace Operator: Donald Lovelace Crop 1 Name: Fescue -Pasture WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 25.88 Site #: Predominant Soil Series: CdB2 Crop 1 Max. PAN: 156 Crop 2 Name: Acres Utilized: RC041 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 11.09 11.09 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu_ Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # w •, * N *� TKN mg/kg Z ; o oa o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/4 45500 1.68 0.287 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 17.106 NA Fescue 3/5 84500 1.68 0.534 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 31.769 NA Fescue 4/22 169000 1.72 1.093 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 62.312 NA Fescue 4/23 65000 1.72 0.420 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 23.966 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4-0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 364000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 135.153 0.000 Lime Applied Annuallbs/acre 0.112 0.020 1.062 0.183 0.256 0.002 0.058 0.076 0.120 3.447 99.773 Date lbs/ac Prior Years Cumulative lbs/ac 0.451 0.27 12.364 1.769 2.81 0.06 0.603 1.675 0.6 26.492 Current Cumulative lbs/ac 0.563 0.290 13.426 1.952 3.066 0.062 0.661 1.751 0.720 29.939 Permitted C. P. L. R.****1 36 34 1 1338 1 1 267 1 15 1 1 374 1 89 1 2498 Permit PAN Limit lst/2nd Crop 156 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 2/14/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Reidsville Total Dry Tons Applied (Annual): 21.10 Permit #: WQ0002376 Cation Exchange Capacity (non 503 only): Operator: Donald Lovelace Owner: Lofton Lovelace Predominant Soil Series: CdB2 Acres Used: 8.81 Acres Permitted: 8.81 Site #: RC041 Field #: 2 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or Com- posite Date 1 4/6/22 2 Unifi 7/25/22 3 4 5 6 7 8 9 10 11 12 % Solids 1.72 2.15 Arsenic 29.4 15.2 Cadmium 5.88 0.952 Copper 224 171 Chromium 39.5 57.6 Lead 55.4 82.4 Mercury 0.382 0.576 Molyb- denum 14.7 6.43 Nickel 16.6 23.9 Selenium 29.4 15.2 Zinc 706 671 Total Phos- horus 20600 3790 Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 1 2 3 4 5j 6j 7j 81 9 10 11 12 DT/Ac./ App. .fir Event 1.27 1.13 Arsenic 0.075 0.034 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.109 Cadmium 0.015 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Copper 0.569 0.385 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.954 Chromium 0.100 0.130 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.230 Lead 0.141 0.185 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.326 Mercury 0.001 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.037 0.014 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.052 denum Nickel 0.042 0.054 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.096 Selenium 0.075 0.034 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.109 Zinc 1.793 1.510 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.303 Total Phos- 52.324 8.528 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 60.852 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Lofton Lovelace Operator: Donald Lovelace Crop 1 Name: Fescue -Pasture WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 21.10 Site #: Predominant Soil Series: CdB2 Crop 1 Max. PAN: 156 Crop 2 Name: 2 RC041 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 8.81 8.81 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu_ Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # w •, * N *� TKN mg/kg 84700 Z ; o oa o mg/kg 1 14100 Nitrate and Nitrite mg/kg 275 PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 4/21 156000 1.72 1.270 Reidsville WWTP Dry <.5" S 0.5 0.3 72.404 NA Fescue 8/31 26000 2.15 0.265 Unifi Dry <.5" S 0.5 0.3 33800 2120 7240 9.421 NA Fescue 9/1 84500 2.15 0.860 Unifi Dry <.5" S 0.5 0.3 33800 2120 7240 30.620 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 266500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 112.4461 0.000 Lime Applied Annuallbs/acre 0.109 0.017 0.954 0.230 0.326 0.002 0.052 0.096 0.109 3.303 60.852 Date lbs/ac Prior Years Cumulative lbs/ac 0.223 0.244 8.373 0.762 1.792 0.04 0.399 1.151 0.311 16.688 Current Cumulative lbs/ac 0.332 1 0.261 9.327 0.992 2.118 0.042 0.451 1.247 0.420 19.991 Permitted C. P. L. R.**** 36 34 1 1338 267 1 15 1 1 374 1 89 1 2498 Permit PAN Limit lst/2nd Crop 156 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Reidsville Total Dry Tons Applied (Annual): 2.80 Permit #: WQ0002376 Cation Exchange Capacity (non 503 only): Operator: Donald Lovelace Owner: Lofton Lovelace Predominant Soil Series: CdB2 Acres Used: 1.99 Acres Permitted: 1.99 Site #: RC041 Field #: 3 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date OEM MEMO Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 11 21 3 4 5j 6j 7 8 9 10 11 12 DT/Ac./ App. .fir Event 1.41 Arsenic 0.083 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.083 Cadmium 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 Copper 0.630 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.630 Chromium 0.111 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.111 Lead 0.156 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.156 Mercury 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.001 Molyb- 0.041 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.041 denum Nickel 0.047 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 1 0.000 0.047 Selenium 0.083 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.083 Zinc 1.985 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.985 Total Phos- 57.927 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 57.927 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Lofton Lovelace Operator: Donald Lovelace Crop 1 Name: Fescue -Pasture WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 2.80 Site #: Predominant Soil Series: CdB2 Crop 1 Max. PAN: 156 Crop 2 Name: Acres Utilized: RC041 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 1.99 1.99 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu_ Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # w •, * N *� TKN mg/kg 84700 Z ; o oa o mg/kg 1 14100 Nitrate and Nitrite mg/kg 275 PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 4/21 39000 1.72 1.406 Reidsville WWTP Dry <.5" S 0.5 0.3 80.136 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 39000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 80.136 0.000 Lime Applied Annuallbs/acre 0.083 0.017 0.630 0.111 0.156 0.001 0.041 0.047 0.083 1.985 57.927 Date lbs/ac Prior Years Cumulative lbs/ac 0.352 0.294 9.662 0.827 1.802 0.134 0.432 1.222 0.428 17.557 Current Cumulative lbs/ac 0.435 1 0.311 10.292 0.938 1.958 0.135 0.473 1.269 0.511 19.542 Permitted C. P. L. R.**** 36 34 1 1338 267 1 15 1 1 374 1 89 1 2498 Permit PAN Limit lst/2nd Crop 156 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Reidsville Total Dry Tons Applied (Annual): 58.93 Permit #: WQ0002376 Cation Exchange Capacity (non 503 only): Operator: Donald Lovelace Owner: Lofton Lovelace Predominant Soil Series: CdB2 Acres Used: 17.2 Acres Permitted: 17.2 Site #: RC041 Field #: 4 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Sample or posme Date 1 1/12/22 2 4/6/22 3 Unifi 7/25/22 4 5 6 7 8 9 10 11 12 % Solids 1.68 1.72 2.15 Arsenic 14.3 29.4 15.2 Cadmium 1.19 5.88 0.952 Copper 234 224 171 Chromium 38.7 39.5 57.6 Lead 53.9 55.4 82.4 Mercury 0.595 0.382 0.576 Molyb- denum 8.04 14.7 6.43 Nickel 15.8 16.6 23.9 Selenium 19 29.4 15.2 Zinc 798 706 671 Total Phos- horus 22800 20600 3790 Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 1J 2 1 3 4 5j 6j 7 8 9 10 11 12 DT/Ac./ App. .fir Event 0.64 0.62 2.17 Arsenic 0.018 0.037 0.066 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.121 Cadmium 0.002 0.007 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.013 Copper 0.297 0.279 0.741 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.318 Chromium 0.049 0.049 0.250 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.348 Lead 0.068 0.069 0.357 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.495 Mercury 0.001 0.000 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Molyb- 0.010 0.018 0.028 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.056 denum Nickel 0.020 0.021 0.104 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.144 Selenium 0.024 0.037 0.066 1 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.000 0.000 0.127 Zinc 1.013 0.880 2.909 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4.803 Total Phos- 28.956 25.668 16.433 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 71.057 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Lofton Lovelace Operator: Donald Lovelace Crop 1 Name: Fescue -Pasture WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 58.93 Site #: Predominant Soil Series: CdB2 Crop 1 Max. PAN: 156 Crop 2 Name: 4 RC041 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 17.2 17.2 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu_ Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # w •, * N *� TKN mg/kg Z ; o oa o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/5 32500 1.68 0.132 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 7.878 NA Fescue 3/7 123500 1.68 0.503 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 29.938 NA Fescue 4/23 39000 1.72 0.163 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 9.272 NA Fescue 4/25 110500 1.72 0.461 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 26.269 NA Fescue 8/29 123500 2.15 0.644 Unifi Dry <.5" S 0.5 0.3 33800 2120 7240 22.922 NA Fescue 8/30 182000 2.15 0.949 Unifi Dry <.5" S 0.5 0.3 33800 2120 7240 33.780 NA Fescue 8/31 110500 2.15 0.576 Unifi Dry <.5" S 0.5 0.3 33800 2120 7240 20.510 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 721500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 150,56 00.000 Lime Applied Annuallbs/acre 0.121 0.013 1.318 0.348 0.495 0.004 0.056 0.144 0.127 4.803 71.057 Date lbs/ac Prior Years Cumulative lbs/ac 0.456 0.291 12.952 2.431 2.697 0.064 0.619 1.686 0.603 28.255 Current Cumulative lbs/ac 0.577 1 0.304 14.270 2.779 3.192 0.068 0.675 1.830 0.730 33.058 Permitted C. P. L. R.**** 36 34 1 1338 1 1 267 1 15 1 1 374 1 89 1 2498 Permit PAN Limit lst/2nd Crop 156 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Reidsville Total Dry Tons Applied (Annual): 10.51 Permit #: WQ0002376 Cation Exchange Capacity (non 503 only): Operator: Thomas Carter Owner: Thomas Carter Predominant Soil Series: CdB2 Acres Used: 9.29 Acres Permitted: 9.29 Site #: RC119 Field #: 5 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 11 21 3 4 5j 6j 7j 81 9 10 11 12 DT/Ac./ App. .fir Event 1.13 Arsenic 0.045 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.045 Cadmium 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 0.622 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.622 Chromium 0.125 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.125 Lead 0.157 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.157 Mercury 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molyb- 0.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.026 denum Nickel 0.049 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 1 0.000 0.049 Selenium 0.060 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.060 Zinc 2.224 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.224 Total Phos- 53.383 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 53.383 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Thomas Carter Operator: Thomas Carter Crop 1 Name: Fescue -Pasture WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 10.51 Site #: Predominant Soil Series: CdB2 Crop 1 Max. PAN: 156 Crop 2 Name: Acres Utilized: RC 119 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 9.29 9.29 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # w •, * N' *� TKN mg/kg Z ; o oa o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 9/14 201500 1.25 1.131 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 110.212 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 201500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 110.212 0.000 Lime Applied Annuallbs/acre 0.045 0.004 0.622 0.125 0.157 0.003 0.026 0.049 0.060 2.224 53.383 Date lbs/ac Prior Years Cumulative lbs/ac 0.533 0.327 16.872 2.352 3.324 0.099 0.72 2.209 0.681 37.861 Current Cumulative lbs/ac 0.578 0.331 17.494 2.477 3.481 0.102 0.746 2.258 0.741 40.085 Permitted C. P. L. R.**** 36 34 1 1338 1 267 1 15 374 1 89 2498 Permit PAN Limit lst/2nd Crop 156 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Reidsville Total Dry Tons Applied (Annual): 18.38 Permit #: WQ0002376 Cation Exchange Capacity (non 503 only): Operator: Thomas Carter Owner: Thomas Carter Predominant Soil Series: CdB2 Acres Used: 9.81 Acres Permitted: 9.81 Site #: RC119 Field #: 9 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 11 21 3 4 5j 6j 7j 81 9 10 11 12 DT/Ac./ App. .fir Event 1.11 0.76 Arsenic 0.032 0.030 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.062 Cadmium 0.003 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.005 Copper 0.521 0.418 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.939 Chromium 0.086 0.084 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.170 Lead 0.120 0.105 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.225 Mercury 0.001 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molyb- 0.018 0.018 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.036 denum Nickel 0.035 0.033 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 1 0.068 Selenium 0.042 0.041 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.083 Zinc 1.778 1.494 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 3.272 Total Phos- 50.798 35.872 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 86.670 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Thomas Carter Operator: Thomas Carter Crop 1 Name: Fescue -Pasture WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 18.38 Site #: Predominant Soil Series: CdB2 Crop 1 Max. PAN: 156 Crop 2 Name: RC119 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 9.81 9.81 0 ° '5 N ° Q Volume applied (enter one) Solids/ Liquid Cu_ Yds Gallons % Solids Volume Applied per PP P Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a F'5 c� w *o• o ;� �, # w K * N' *� TKN mg/kg Z �o o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 3/4 156000 1.68 1.114 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 66.303 NA Fescue 9/20 117000 1.25 0.622 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 60.602 NA Fescue 9/21 26000 1.25 0.138 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 13.467 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 4-0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 299000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 140.37 00.000 Lime Applied Annuallbs/acre 0.062 0.005 0.939 0.170 0.225 0.003 0.036 0.068 0.083 3.272 86.670 Date lbs/ac Prior Years Cumulative lbs/ac 0.27 0.095 6.481 1.526 1.18 0.037 0.268 0.866 0.337 15.145 Current Cumulative lbs/ac 0.332 0.100 7.420 1.696 1.405 0.040 0.304 0.934 0.420 18.417 Permitted C. P. L. R.****1 36 34 1 1338 1 1 267 1 15 1 1 374 1 89 1 2498 Permit PAN Limit lst/2nd Crop 1 156 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Reidsville Total Dry Tons Applied (Annual): 4.75 Permit #: WQ0002376 Cation Exchange Capacity (non 503 only): Operator: Thomas Carter Owner: Thomas Carter Predominant Soil Series: CgB2 Acres Used: 6.52 Acres Permitted: 6.52 Site #: RC119 Field #: 10 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 2 1 3 4 5j 6j 7j 81 9 10 11 12 _1J DT/Ac./ App. Event 0.73 Arsenic 0.029 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 Cadmium 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Copper 0.400 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.400 Chromium 0.081 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.081 Lead 0.101 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.101 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.017 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.017 denum Nickel 0.032 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.032 Selenium 0.039 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.039 Zinc 1.431 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1.431 Total Phos- 34.362 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 34.362 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Thomas Carter Operator: Thomas Carter Crop 1 Name: Fescue -Pasture WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 4.75 Site #: Predominant Soil Series: CgB2 Crop 1 Max. PAN: 156 Crop 2 Name: 10 Acres Utilized: RC 119 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 6.52 6.52 0 Q Volume applied enter one Solids/ Liquid Cu. Yds Gallons o /o Solids Volume A lied er pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a c� w *o• o ,•d � # w , * N' *� TKN mg/kg Z ; o oa o �• mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 9/15 91000 1.25 0.728 Reidsville WWTP Dry <.5" S 0.5 1 0.3 143000 27300 381 70.919 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF so pp to this form): TOTALS: 01 91000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 70.919 0.000 Lime Applied Annuallbs/acre 0.029 0.002 0.400 0.081 0.101 0.002 0.017 0.032 0.039 1.431 34.362 Date lbs/ac Prior Years Cumulative lbs/ac 0.2 0.05 2.663 0.977 0.543 0.032 0.18 0.548 0.189 10.144 Current Cumulative lbs/ac 0.229 0.052 3.063 1.058 0.644 0.034 0.197 0.580 0.228 11.575 Permitted C. P. L. R.**** 36 1 34 1 1338 1 1 267 1 15 1 1 374 89 2498 Permit PAN Limit lst/2nd Crop 156 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Reidsville Total Dry Tons Applied (Annual): 33.21 Permit #: WQ0002376 Cation Exchange Capacity (non 503 only): Operator: Auman French Owner: State of N.C. Predominant Soil Series: CdB2 Acres Used: 18.33 Acres Permitted: 18.33 Site #: RC126 Field #: 2 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite- Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 2 1 3 4 5j 6j 7j 81 9 10 11 1 12 _1J DT/Ac./ App. .fir Event 0.82 0.99 Arsenic 0.023 0.058 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.082 Cadmium 0.002 0.012 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.014 Copper 0.384 0.444 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.828 Chromium 0.063 0.078 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.142 Lead 0.088 0.110 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.198 Mercury 0.001 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.013 0.029 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.042 denum Nickel 0.026 0.033 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 1 0.059 Selenium 0.031 0.058 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.089 Zinc 1.309 1.401 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.709 Total Phos- 37.392 40.870 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 78.262 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville State of N.C. Operator: Airman French Crop 1 Name: Fescue -Hay WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 33.21 Site #: Predominant Soil Series: CdB2 Crop 1 Max. PAN: 209 Crop 2 Name: 2 RC 126 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 18.33 18.33 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu. Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # w •, * N *� TKN mg/kg Z ; o oa o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2/15 136500 1.68 0.522 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 31.049 NA Fescue 2/16 78000 1.68 0.298 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 17.742 NA Fescue 4/26 110500 1.72 0.432 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 24.650 NA Fescue 4/27 104000 1.72 0.407 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 23.200 NA Fescue 4/28 1 39000 1.72 0.153 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 8.700 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 0.000 TOTALS: 01 468000 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 105.3411 0.000 Lime Applied Annuallbs/acre 0.082 0.014 0.828 0.142 0.198 0.002 0.042 0.059 0.089 2.709 78.262 Date lbs/ac Prior Years Cumulative lbs/ac 0.414 0.076 5.029 1.416 1.44 0.033 0.274 0.736 0.523 16.072 Current Cumulative lbs/ac 0.496 1 0.090 5.857 1.558 1.638 0.035 0.316 0.795 0.612 18.781 Permitted C. P. L. R.**** 36 34 1 1338 267 1 15 374 1 89 1 2498 Permit PAN Limit lst/2nd Crop 209 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: City of Reidsville Total Dry Tons Applied (Annual): 17.94 WQ0002376 Cation Exchange Capacity (non 503 only): Auman French Owner: State of N.C. Predominant Soil Series: CgB2 10.8 Acres Permitted: 10.8 Site #: RC 126 Field #: 5 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite- Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 2 1 3 4 5j 6j 7j 81 9 10 11 12 _1J DT/Ac./ App. .fir Event 0.97 0.69 Arsenic 0.028 0.041 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.068 Cadmium 0.002 0.008 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.010 Copper 0.454 0.310 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.764 Chromium 0.075 0.055 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.130 Lead 0.105 0.077 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.181 Mercury 0.001 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.016 0.020 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.036 denum Nickel 0.031 0.023 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.054 Selenium 0.037 0.041 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.077 Zinc 1.548 0.976 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.524 Total Phos- 44.232 28.469 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 72.701 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r_ 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. Facility Name: City of Reidsville Land Owner: State of N.C. Operator: Airman French Crop 1 Name: Small Grain WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 17.94 Site #: Predominant Soil Series: CgB2 Crop 1 Max. PAN: 116 Crop 2 Name: Acres Utilized: RC 126 Acres Permitted: Cation Exchange Capacity (non 503): Corn Crop 2 Max. PAN 10.8 10.8 0 50 o � N Q Volume applied enter one Solids/ ) Liquid Cu Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a F �a w *o• o ,•d �, # w •, * N *� TKN mg/kg Z ; o M o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 2/16 149500 1.68 0.970 Reidsville WWTP Dry <.5" S 0.5 0.3 88700 13500 448 57.716 NA SG 4/28 65000 1.72 0.432 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 Na 24.610 Corn 4/29 39000 1.72 0.259 Reidsville WWTP Dry <.5" S 0.5 0.3 84700 14100 275 Na 14.766 Corn 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0 0 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): 0.000 1 0.000 TOTALS: 0 253500 As Cd Cu Cr Pb H Mo Ni Se Zn P 57.716 39.375 Lime Applied Annuallbs/acre 0.068 0.010 0.764 0.130 0.181 0.002 0.036 0.054 0.077 2.524 72.701 Date lbs/ac Prior Years Cumulative lbs/ac 0.333 0.068 4.5 1.271 1.287 0.028 0.226 0.667 0.413 14.154 Current Cumulative lbs/ac 0.401 1 0.078 5.264 1.401 1.468 0.030 0.262 0.721 0.490 16.678 Permitted C. P. L. R.**** 36 34 1 1338 1 1 267 1 15 1 1 374 1 89 1 2498 Permit PAN Limit lst/2nd Crop 116 1 50 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: City of Reidsville Total Dry Tons Applied (Annual): 16.60 Permit #: WQ0002376 Cation Exchange Capacity (non 503 only): Operator: Dennis Williams Owner: Dennis Williams Predominant Soil Series: CdB2 Acres Used: 14.66 Acres Permitted: 14.66 Site #: RC128 Field #: 1 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus Annual Heavv Metal Field Loadings (Calculated in lbs/acre): Total 11 21 3 4 5j 6j 7j 81 9 10 11 12 DT/Ac./ App. .fir Event 1.13 Arsenic 0.045 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.045 Cadmium 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 0.623 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.623 Chromium 0.125 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.125 Lead 0.157 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.157 Mercury 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molyb- 0.026 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.026 denum Nickel 0.049 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 1 0.000 0.049 Selenium 0.060 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.060 Zinc 2.226 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.226 Total Phos- 53.430 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 53.430 horus "I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4; 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Dennis Williams Operator: Dennis Williams Crop 1 Name: Fescue -Pasture WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 16.60 Site #: Predominant Soil Series: CdB2 Crop 1 Max. PAN: 156 Crop 2 Name: Acres Utilized: RC 128 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 14.66 14.66 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu_ Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # w •, * N' *� TKN mg/kg Z ; o oa o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 7/18 188500 1.25 0.670 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 65.335 NA Fescue 7/19 130000 1.25 0.462 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 45.059 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 318500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 110.394 0.000 Lime Applied Annuallbs/acre 0.045 0.004 0.623 0.125 0.157 0.003 0.026 0.049 0.060 2.226 53.430 Date lbs/ac Prior Years Cumulative lbs/ac 0.112 0.022 1.748 0.375 0.368 0.01 0.073 0.189 0.131 5.885 Current Cumulative lbs/ac 0.157 0.026 2.371 0.500 0.525 0.013 0.099 0.238 0.191 8.111 Permitted C. P. L. R.**** 36 34 1 1338 1 267 1 15 374 1 89 2498 Permit PAN Limit lst/2nd Crop 156 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: City of Reidsville Total Dry Tons Applied (Annual): WQ0002376 Cation Exchange Capacity (non 503 only): Dennis Williams Owner: Timothy Stevens Predominant Soil Series: 4.2 Acres Permitted: 4.2 Site #: RC 128 Field #: 4.41 PcD2 2 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 11 21 3 4 5j 6j 7j 81 9 10 11 12 DT/Ac./ App. .fir Event 1.05 Arsenic 0.042 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.042 Cadmium 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 0.577 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.577 Chromium 0.116 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.116 Lead 0.145 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.145 Mercury 0.002 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.002 Molyb- 0.025 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.025 denum Nickel 0.046 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.046 Selenium 0.056 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.056 Zinc 2.062 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.062 Total Phos- 49.513 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 49.513 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r_ 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Timothy Stevens Operator: Dennis Williams Crop 1 Name: Fescue -Hay WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 4.41 Site #: Predominant Soil Series: PcD2 Crop 1 Max. PAN: 158 Crop 2 Name: 2 RC 128 Acres Utilized: Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 4.2 4.2 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu_ Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # w •, * N' *� TKN mg/kg Z ; o oa o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 7/16 84500 1.25 1.049 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 102.230 NA Fescue 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 84500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 102.230 0.000 Lime Applied Annuallbs/acre 0.042 0.004 0.577 0.116 0.145 0.002 0.025 0.046 0.056 2.062 49.513 Date lbs/ac Prior Years Cumulative lbs/ac 0.058 0.014 1.521 0.345 0.334 0.009 0.053 0.171 0.08 4.36 Current Cumulative lbs/ac 0.100 0.018 2.098 0.461 0.479 0.011 0.078 0.217 0.136 6.422 Permitted C. P. L. R.**** 36 34 1 1338 1 267 1 15 374 1 89 2498 Permit PAN Limit lst/2nd Crop F 158 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) ANNUAL METALS FIELD LOADING SUMMARY FORM* Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report Facility Name: Permit #: Operator: Acres Used: City of Reidsville Total Dry Tons Applied (Annual): WQ0002376 Cation Exchange Capacity (non 503 only): Dennis Williams Owner: Timothy Stevens Predominant Soil Series: 10.7 Acres Permitted: 10.7 Site #: RC128 Field #: 13.21 PcD2 3 Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #): Com- posite Date Total Phos- phorus Annual Heavy Metal Field Loadings (Calculated in lbs/acre): Total 11 21 3 4 5j 6j 7j 81 9 10 11 12 DT/Ac./ App. .fir Event 1.24 Arsenic 0.049 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.049 Cadmium 0.004 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.004 Copper 0.679 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.679 Chromium 0.137 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.137 Lead 0.171 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.171 Mercury 0.003 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.003 Molyb- 0.029 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.029 denum Nickel 0.054 0.000 0.000 0.000 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 1 0.000 0.054 Selenium 0.066 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.066 Zinc 2.428 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 2.428 Total Phos- 58.292 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 58.292 horus "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations". Z�fz 4;�r_ 1/2/2023 Signature of Land Applier Date DENR FORM MFLSF (12/2006) Facility Name: Land Owner: ANNUAL LAND APPLICATION FIELD SUMMARY FORM PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE. City of Reidsville Timothy Stevens Operator: Dennis Williams Crop 1 Name: Fescue -Hay WQ Permit #: WQ0002376 Field #: Annual Dry Tons Applied: 13.21 Site #: Predominant Soil Series: PcD2 Crop 1 Max. PAN: 158 Crop 2 Name: Acres Utilized: RC 128 Acres Permitted: Cation Exchange Capacity (non 503): Crop 2 Max. PAN: 10.7 10.7 0 o � N Q Volume applied enter one Solids/ ( ) Liquid Cu_ Yds Gallons o /o Solids Volume Applied per pp p Acre (Dry Tons/Ac) Residual Sources (NPDES #, WQ#, Fert., Animal Waste, etc) Soil Cond. (may' Wet, Moist) Precip. Past 24 Ms. inches a �a F w *o• o ,•d �, # w •, * N' *� TKN mg/kg Z ; o oa o mg/kg Nitrate and Nitrite mg/kg PAN Applied ( lbs/acre) Name of Crop Type Receiving Residual Application Crop 1 Crop 2 Crop 1 Crop 2 7/14 39000 1.25 0.190 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 18.520 NA Fescue 7/15 175500 1.25 0.855 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 83.342 NA Fescue 7/16 39000 1.25 0.190 Reidsville WWTP Dry <.5" S 0.5 0.3 143000 27300 381 18.520 NA Fescue 0.000 0.000 0.000 0.000 1 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form): TOTALS: 01 253500 As Cd Cu Cr Pb Hg Mo Ni Se Zn P 120.383 0.000 Lime Applied Annuallbs/acre 0.049 0.004 0.679 0.137 0.171 0.003 0.029 0.054 0.066 2.428 58.292 Date lbs/ac Prior Years Cumulative lbs/ac 0.049 0.015 1.445 0.32 0.272 0.008 0.054 0.181 0.063 3.71 Current Cumulative lbs/ac 0.098 0.019 2.124 0.457 0.443 0.011 0.083 0.235 0.129 6.138 Permitted C. P. L. R.**** 36 34 1 1338 1 267 1 15 374 1 89 2498 Permit PAN Limit lst/2nd Crop i F-158 "I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations." *Application Method: S - Surface, IN - Injection, INC - Incorporation 1/2/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0 Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2, aerobically digested -0.3, raw sludge -0.4 ****C.P.L.R.: Cumulative Pollutant Loading Rate DENR FORM FSF (12/2006) Waypointo ANALYTICAL 1 /24/2022 EMA Resources Inc Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 22-014-0007 Client Project Description: Reidsville, NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Brent Collins: Waypoint Analytical, LLC. received sample(s) on 1/14/2022 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Danyale Love Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 7 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2022 Arkansas State Program 88-0650 02/07/2022 California State Program 2904 06/30/2022 Florida State Program - NELAP E871157 06/30/2022 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2022 Illinois State Program - NELAP 200078 10/10/2022 Kentucky State Program 80215 06/30/2022 Kentucky State Program KY90047 12/31/2022 Louisiana State Program - NELAP LA037 12/31/2022 Louisiana State Program - NELAP 04015 06/30/2022 Mississippi State Program MS 02/11/2023 North Carolina State Program 415 12/31/2022 Pennsylvania State Program - NELAP 68-03195 05/31/2022 South Carolina State Program 84002 06/30/2022 South Carolina State Program 84002 06/30/2022 Tennessee State Program 02027 02/11/2023 Texas State Program - NELAP T104704180 09/30/2022 Virginia State Program 00106 06/30/2022 Virginia State Program - NELAP 460181 09/14/2022 Page 1 of 1 00001/22-014-0007 Page 2 of 7 Waypoint ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Sample Summary Table Report Number: 22-014-0007 Client Project Description: Reidsville, NC Lab No Client Sample ID Matrix Date Collected Date Received 95817 Sludge Solids 01/12/202211:50 01/14/2022 Page 3 of 7 Waypointo ANALYTICAL 46245 EMA Resources Inc Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Report Number : 22-014-0007 Lab No : 95817 Sample ID : Sludge Project Reidsville, NC Information : 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com REPORT OFANALYSIS Report Date : 01/24/2022 Received : 01/14/2022 Danyale Love Project Manager Matrix: Solids Sampled: 1 / 12/ 2022 11:50 Test Results Units MDL MQL DF Date / Time Analyzed By Analytical Method Moisture 98.32 % 0.010 0.010 1 01/17/22 16:08 FMM SW-DRYWT Ammonia Nitrogen 13500 mg/Kg - dry 952 5950 1 01/21/22 15:00 JPJ 4500NH3C-2011 Nitrate+Nitrite-N 448 mg/Kg - dry 273 273 1 01/19/22 16:14 ZBD 4500NO3F-2011 Organic N 75180 mg/Kg - dry 952.4 5952 1 01/20/22 10:00 CALCULATION pH 7.2 S.U. 1 01/19/2215:02 DRS 9045D Total Solids 1.68 % 0.010 0.010 1 01/17/22 16:08 FMM 2540G-2011 Total Volatile Solids 75.4 % 0.010 0.010 1 01/17/22 16:08 FMM 2540G-2011 Total Kjeldahl Nitrogen 88700 mg/Kg - dry 595 14900 1 01/20/22 10:00 JPJ ;M-4500-NH3C-TKI` Phosphorus 22800 mg/Kg - dry 164 298 1 01/18/22 23:57 EAL 6010D Aluminum 13700 mg/Kg - dry 275 298 1 01/18/22 23:57 EAL 6010D Arsenic <14.3 mg/Kg - dry 14.3 29.8 1 01/18/22 23:57 EAL 6010D Cadmium <1.19 mg/Kg - dry 1.19 5.95 1 01/18/22 23:57 EAL 6010D Calcium 13000 mg/Kg - dry 2300 2980 1 01/18/22 23:57 EAL 6010D Chromium 38.7 mg/Kg - dry 14.0 14.9 1 01/18/22 23:57 EAL 6010D Copper 234 mg/Kg - dry 18.5 29.8 1 01/20/22 18:26 EAL 6010D Iron 13100 mg/Kg - dry 507 595 1 01/18/22 23:57 EAL 6010D Lead 53.9 mg/Kg - dry 10.7 17.9 1 01/18/22 23:57 EAL 6010D Magnesium 4510 mg/Kg - dry 154 298 1 01/18/22 23:57 EAL 6010D Manganese 555 mg/Kg - dry 19.3 29.8 1 01/18/22 23:57 EAL 6010D Mercury 0.5953 mg/Kg - dry 0.405 0.929 1 01/17/22 13:12 JW2 7471A Molybdenum <8.04 mg/Kg - dry 8.04 14.9 1 01/18/22 23:57 EAL 6010D Nickel 15.8 mg/Kg - dry 7.14 14.9 1 01/18/22 23:57 EAL 6010D Potassium 6010 mg/Kg - dry 368 595 1 01/18/22 23:57 EAL 6010D Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 4 of 7 • Waypoint 27090 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 ANALYTICAL www.waypointanalyiical.com 46245 EMA Resources Inc Project Reidsville, NC Brent Collins Report Date : 01/24/2022 755 Yadkinville Rd Information : Received : 01/14/2022 Mocksville , NC 27028 Danyale Love Report Number : 22-014-0007 REPORT OFANALYSIS Project Manager Lab No : 95817 Matrix: Solids Sample ID : Sludge Sampled: 1/12/2022 11:50 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <19.0 mg/Kg - dry 19.0 29.8 1 01/18/22 23:57 EAL 6010D Sodium 6490 mg/Kg - dry 774 1490 1 01/18/22 23:57 EAL 6010D Zinc 798 mg/Kg - dry 48.2 74.4 1 01/18/22 23:57 EAL 6010D Sulfur 11800 mg/Kg - dry 308 595 1 01/18/22 23:57 EAL 6010D Sodium Absorption Ratio 1.61 Ratio 0.01 0.01 1 01/18/22 23:57 CALCULATION Qualifiers/ DF Dilution Factor Definitions J Estimated value Page 5 of 7 s WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133 21.2440 Main 901.213.240fl °Fax 901.213.2440 N A LYT I C A L www.waypointanalytical.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 22-014-0007 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: IT102 Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: IMakayla Weaver Date & Time: 01/14/2022 09:37:57 Page 6 of 7 � c � N ] y C) LL `S U7 �+ E E E ' 0 ❑: N ° N N Yas m ' x V a o N V� Z E Z L... d x m a O G m 2 V a U p p o u u x a x x x s u ¢ O - i X 2 iL Q] — I S a, in C m w Q w u la S_ CJ c c N Z La Z 17 2 L7 _ d v m `a TDO a m u �n VJ SAi � a � y s W r o w -� O E H o 0 O Y L.) Q nEl A V a 5p!1051el41 CL N alue6J0/0lRJa!N c CL o LO m N o o z W E GIuOUJWV/N>Il p -Tt: r ii a a s x E < N o07q ) c w (CIO Log) Swim � Z Z Z D u v Q N V a` � -p U N ❑ y GI \' V1 VI 5A iE Q a a=isodwo(�J �a qej{9) ] a m a .a' [Aa)l 03 as;aa) ><Ik3eW � c c c 3a c E - - v saauieauoa;o AagwnN C� aj m rr mIt, 0 ` T U U � g � Q1 �+ C � d w ru a [I] C o O I G(-j G LL CDrow m D m 7 �° CO c •Q U CO N d I" E p C y ^i• � E v+ a o � o b � W Q P LO E a) o v o E y 47 N N E P F N M U ;-- a ii m> V7 O 2 L N a } y dQ Ln V 2 LO o u d o �i N a o �� T N � o N v _ ro o0 r�► CDLsJ r- :ED. a` Page 7 of 7 1 /12/2022 mg/kg mg/L Equiv Weight Milli Equiv Sodium 6490 109.032 23 4.740522 Calcium 13000 218.4 20 10.92 Magnesium 4510 75.768 12 6.314 Percent Solids 1.68 SAR 1.61 SAR = Na+ a (Ca2+ + M;42+ ) 4.74052 0.5( 10.92 2 + 6.31400 2 ) Waypointo ANALYTICAL 4/15/2022 EMA Resources Inc Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 22-097-0046 Client Project Description: Reidsville, NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Brent Collins: Waypoint Analytical, LLC. received sample(s) on 4/7/2022 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Connie Cook Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 9 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2023 Arkansas State Program 88-0650 02/07/2023 California State Program 2904 06/30/2022 Florida State Program - NELAP E871157 06/30/2022 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2022 Illinois State Program - NELAP 200078 10/10/2022 Kentucky State Program 80215 06/30/2022 Kentucky State Program KY90047 12/31/2022 Louisiana State Program - NELAP LA037 12/31/2022 Louisiana State Program - NELAP 04015 06/30/2022 Mississippi State Program MS 02/11/2023 North Carolina State Program 415 12/31/2022 Pennsylvania State Program - NELAP 68-03195 05/31/2022 South Carolina State Program 84002 06/30/2022 South Carolina State Program 84002 06/30/2022 Tennessee State Program 02027 02/11/2023 Texas State Program - NELAP T104704180 09/30/2022 Virginia State Program 00106 06/30/2022 Virginia State Program - NELAP 460181 09/14/2022 Page 1 of 1 00001/22-097-0046 Page 2 of 9 Waypoint ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Sample Summary Table Report Number: 22-097-0046 Client Project Description: Reidsville, NC Lab No Client Sample ID Matrix Date Collected Date Received 89658 Reidsville Solids 04/06/202210:40 04/07/2022 Page 3 of 9 Waypointo ANALYTICAL Client: EMA Resources Inc Project: Reidsville, NC Lab Report Number: 22-097-0046 Date: 4/15/2022 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 fax 901.213.2440 www.waypointanalytical.com CASE NARRATIVE Metals Analysis Method 601 OD Sample 99495 (SS-1) Analyte: Arsenic QC Batch No: 1-610642/1-609727 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post digestion spike was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 99495 (SS-1) Analyte: Calcium QC Batch No: 1-610642/1-609727 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 99495 (SS-1) Analyte: Iron QC Batch No: 1-610642/1-609727 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 99495 (SS-1) Analyte: Potassium QC Batch No: 1-610642/1-609727 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 99495 (SS-1) Analyte: Magnesium QC Batch No: 1-610642/1-609727 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 99495 (SS-1) Analyte: Manganese QC Batch No: 1-610642/1-609727 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 99495 (SS-1) Analyte: Phosphorus QC Batch No: 1-610642/1-609727 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 99495 (SS-1) Page 4 of 9 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 fax 901.213.2440 www.waypointanalytical.com Analyte: Lead QC Batch No: 1-610642/1-609727 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Page 5 of 9 Waypointo ANALYTICAL 46245 EMA Resources Inc Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Project Reidsville, NC Information : 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Report Date : 04/15/2022 nReceived : 04/07/2022 C-�*�-� = Connie Cook Report Number : 22-097-0046 REPORT OFANALYSIS Project Manager Lab No : 89658 Matrix: Solids Sample ID : Reidsville Sampled: 4/6/2022 10:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 98.3 % 1 04/07/22 16:58 FMM SW-DRYWT Ammonia Nitrogen 14100 mg/Kg - dry 941 5880 1 04/15/22 10:00 JPJ 4500NH3C-2011 Nitrate+Nitrite-N <275 mg/Kg - dry 275 275 1 04/14/22 15:34 ZBD 4500NO3F-2016 Organic N 70650 mg/Kg - dry 941.2 5882 1 04/14/22 09:30 CALCULATION pH 7.2 S.U. 1 04/14/2216:03 DRS 9045D Total Solids 1.72 % 0.010 0.010 1 04/07/22 16:58 FMM 2540G-2011 Total Volatile Solids 77.3 % 0.010 0.010 1 04/07/22 16:58 FMM 2540G-2011 Total Kjeldahl Nitrogen 84700 mg/Kg - dry 588 14700 1 04/14/22 09:30 JPJ ;M-4500-NH3C-TKI` Phosphorus 20600 mg/Kg - dry 162 294 1 04/12/22 23:37 TJS 6010D Aluminum 13400 mg/Kg - dry 272 294 1 04/13/22 13:45 TJS 6010D Arsenic <29.4 mg/Kg - dry 14.1 29.4 1 04/12/22 23:37 TJS 6010D Cadmium <5.88 mg/Kg - dry 1.18 5.88 1 04/12/22 23:37 TJS 6010D Calcium 11300 mg/Kg - dry 2280 2940 1 04/12/22 23:37 TJS 6010D Chromium 39.5 mg/Kg - dry 13.9 14.7 1 04/12/22 23:37 TJS 6010D Copper 224 mg/Kg - dry 18.2 29.4 1 04/12/22 23:37 TJS 6010D Iron 12300 mg/Kg - dry 501 588 1 04/12/22 23:37 TJS 6010D Lead 55.4 mg/Kg - dry 10.6 17.6 1 04/12/22 23:37 TJS 6010D Magnesium 4080 mg/Kg - dry 152 294 1 04/12/22 23:37 TJS 6010D Manganese 405 mg/Kg - dry 19.1 29.4 1 04/12/22 23:37 TJS 6010D Mercury <0.382 mg/Kg - dry 0.382 0.876 1 04/14/22 14:37 ZMT 7471A Molybdenum <14.7 mg/Kg - dry 7.94 14.7 1 04/12/22 23:37 TJS 6010D Nickel 16.6 mg/Kg - dry 7.06 14.7 1 04/12/22 23:37 TJS 6010D Potassium 6180 mg/Kg - dry 364 588 1 04/12/22 23:37 TJS 6010D Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 6 of 9 • Waypoint 27090 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 ANALYTICAL www.waypointanalyiical.com 46245 EMA Resources Inc Project Reidsville, NC Brent Collins Report Date : 04/15/2022 755 Yadkinville Rd Information : Received : 04/07/2022 Mocksville , NC 27028 Connie Cook Report Number : 22-097-0046 REPORT OFANALYSIS Project Manager Lab No : 89658 Matrix: Solids Sample ID : Reidsville Sampled: 4/6/2022 10:40 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <29.4 mg/Kg - dry 18.8 29.4 1 04/12/22 23:37 TJS 6010D Sodium 7880 mg/Kg - dry 765 1470 1 04/12/22 23:37 TJS 6010D Zinc 706 mg/Kg - dry 47.6 73.5 1 04/12/22 23:37 TJS 6010D Sulfur 13400 mg/Kg - dry 305 588 1 04/13/22 13:45 TJS 6010D Sodium Absorption Ratio 2.10 Ratio 0.01 0.01 1 04/12/22 23:37 CALCULATION Qualifiers/ B Analyte detected in blank Definitions DF Dilution Factor Page 7 of 9 s WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133 21.2440 Main 901.213.240fl °Fax 901.213.2440 N A LYT I C A L www.waypointanalytical.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 22-097-0046 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: IT102 Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: IMakayla Weaver Date & Time: 04/07/2022 10:50:46 Page 8 of 9 a IZ C: N o ai Y Ur E r r N ❑ U a_ r 04 M 0 U o o ❑+�} J N0 ry z N rr [NQ Q ry N H 'O y U Z CL d m U Z ❑ z o V ¢ ❑ L - u�sxaxxxu Q - c 7 y N O7 Q- ❑ it vl C � U ❑ w �a J' i - � � � W � C c W Y n E m w � _ g O s 7 ^^JJ u b N E � E CO fL S U Z v ? - W '13c n I I i m o w a a O a ►..T a E � rii E E r Hd 7- SP!IpS fetal r a V VJ Q Q ❑ E T !A U c W m N �lue6ap/a}ea11N m� o N 'dlN�l J a m E o ° z E � EIUO W o n A c - r ❑ ❑ ra (OD6o9) 5l�laW z z z c a w 7 a in ❑ U a` L7 l7 L7 U o m Q a a%lsodwo(3I io gej(q) z 1 a m a } [ w a cr a a c a d c {AaH ❑; �ayaal xii;eyy a E c c - c - y sjauEe;uoa yo jagwnN N s w ff m c ;? 0 V aCOa _ m c UJ a _ ra a m d7 ro n �O a E +' a C u � (D M- o C nnll d ` N ❑ a a ❑ `J Gl = v C T V � U d a C J CO a n a y ro �1 Y ❑ a D L J Q a0 [] C\1 y T M a H w �J S �z a �4 z E g N z (r 7 Q z m zLu LU 1- a a L—,; , Page 9 of 9 4/6/2022 mg/kg mg/L Equiv Weight Milli Equiv Sodium 7880 135.536 23 5.89287 Calcium 11300 194.36 20 9.718 Magnesium 4080 70.176 12 5.848 Percent Solids 1.72 SAR 2.11 SAR — Na 2 (Ca2+ + Mg2- ) 5.89287 0.5( 9.718 2 + 5.84800 2 ) Waypointo ANALYTICAL 7/14/2022 EMA Resources Inc Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 22-187-0030 Client Project Description: Reidsville, NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Brent Collins: Waypoint Analytical, LLC. received sample(s) on 7/6/2022 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Connie Cook Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 8 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2023 Arkansas State Program 88-0650 02/07/2023 California State Program 2904 06/30/2023 Florida State Program - NELAP E871157 06/30/2023 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2023 Illinois State Program - NELAP 200078 10/10/2022 Kentucky State Program 80215 06/30/2022 Kentucky State Program KY90047 12/31/2022 Louisiana State Program - NELAP LA037 12/31/2022 Louisiana State Program - NELAP 04015 06/30/2023 Mississippi State Program MS 02/11/2023 North Carolina State Program 415 12/31/2022 Pennsylvania State Program - NELAP 68-03195 05/31/2023 South Carolina State Program 84002 06/30/2022 Tennessee State Program 02027 02/11/2023 Texas State Program - NELAP T104704180 09/30/2022 Virginia State Program 00106 06/30/2023 Virginia State Program - NELAP 460181 09/14/2022 Page 1 of 1 00001/22-187-0030 Page 2 of 8 Waypoint ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Sample Summary Table Report Number: 22-187-0030 Client Project Description: Reidsville, NC Lab No Client Sample ID Matrix Date Collected Date Received 88270 Reidsville Solids 07/05/202210:45 07/06/2022 Page 3 of 8 Waypointo ANALYTICAL Client: EMA Resources Inc Project: Reidsville, NC Lab Report Number: 22-187-0030 Date: 7/14/2022 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 fax 901.213.2440 www.waypointanalytical.com CASE NARRATIVE Metals Analysis Method 601 OD Sample 88271 (Long Creek) Analyte: Aluminum QC Batch No: 1-626224/1-625887 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 88271 (Long Creek) Analyte: Potassium QC Batch No: 1-626224/1-625887 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Solids Total Mercury Analysis - CVAA Method 7471A Sample 88270 (Reidsville) QC Batch No: 1-626150/1-625869 Target analyte(s) was identified in the method blank associated with this project, below the Method Quantitation Limit. Per laboratory protocol any associated affected sample result is flagged "B" to indicate that it was detected in the method blank. Page 4 of 8 Waypointo ANALYTICAL 46245 EMA Resources Inc Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Project Reidsville, NC Information : 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Report Date : 07/14/2022 nReceived : 07/06/2022 C-�*�-� = Connie Cook Report Number : 22-187-0030 REPORT OFANALYSIS Project Manager Lab No : 88270 Matrix: Solids Sample ID : Reidsville Sampled: 7/5/2022 10:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 98.8 % 1 07/08/22 15:43 FMM SW-DRYWT Ammonia Nitrogen 27300 mg/Kg - dry 1330 8330 1 07/14/22 13:30 JPJ 4500NH3C-2011 Nitrate+Nitrite-N <381 mg/Kg - dry 381 381 1 07/07/22 14:43 ZBD 4500NO3F-2016 Organic N 115300 mg/Kg - dry 1333 8333 1 07/14/22 07:00 CALCULATION pH 7.7 S.U. 1 07/12/2215:07 DRS 9045D Total Solids 1.25 % 0.010 0.010 1 07/08/22 15:43 FMM 2540G-2011 Total Volatile Solids 73.9 % 0.010 0.010 1 07/08/22 15:43 FMM 2540G-2011 Total Kjeldahl Nitrogen 143000 mg/Kg - dry 833 20800 1 07/14/22 07:00 JPJ ;M-4500-NH3C-TKI` Phosphorus 23600 mg/Kg - dry 230 417 1 07/11/22 22:43 TJS 6010D Aluminum 17000 mg/Kg - dry 385 417 1 07/11/22 22:43 TJS 6010D Arsenic <20.0 mg/Kg - dry 20.0 41.7 1 07/11/22 22:43 TJS 6010D Cadmium <1.67 mg/Kg - dry 1.67 8.33 1 07/11/22 22:43 TJS 6010D Calcium 13900 mg/Kg - dry 3230 4170 1 07/12/22 19:28 EAL 6010D Chromium 55.4 mg/Kg - dry 19.7 20.8 1 07/12/22 19:28 EAL 6010D Copper 275 mg/Kg - dry 25.8 41.7 1 07/11/22 22:43 TJS 6010D Iron 14300 mg/Kg - dry 710 833 1 07/11/22 22:43 TJS 6010D Lead 69.2 mg/Kg - dry 15.0 25.0 1 07/11/22 22:43 TJS 6010D Magnesium 4590 mg/Kg - dry 215 417 1 07/11/22 22:43 TJS 6010D Manganese 416 mg/Kg - dry 27.1 41.7 1 07/12/22 19:28 EAL 6010D Mercury 1.18 JB mg/Kg - dry 0.494 11.3 1 07/11/22 14:09 ZMT 7471A Molybdenum 11.73 mg/Kg - dry 11.3 20.8 1 07/11/22 22:43 TJS 6010D Nickel 21.8 mg/Kg - dry 10.0 20.8 1 07/11/22 22:43 TJS 6010D Potassium 8830 mg/Kg - dry 515 833 1 07/11/22 22:43 TJS 6010D Qualifiers/ B Analyte detected in blank DF Dilution Factor Definitions J Estimated value MQL Method Quantitation Limit Page 5 of 8 • Waypoint 27090 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 ANALYTICAL www.waypointanalyiical.com 46245 EMA Resources Inc Project Reidsville, NC Brent Collins Report Date : 07/14/2022 755 Yadkinville Rd Information : Received : 07/06/2022 Mocksville , NC 27028 Connie Cook Report Number : 22-187-0030 REPORT OFANALYSIS Project Manager Lab No : 88270 Matrix: Solids Sample ID : Reidsville Sampled: 7/5/2022 10:45 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <26.7 mg/Kg - dry 26.7 41.7 1 07/11/22 22:43 TJS 6010D Sodium 10000 mg/Kg - dry 1080 2080 1 07/11/22 22:43 TJS 6010D Zinc 983 mg/Kg - dry 67.5 104 1 07/11/22 22:43 TJS 6010D Sulfur 15800 mg/Kg - dry 432 833 1 07/11/22 22:43 TJS 6010D Sodium Absorption Ratio 2.05 Ratio 0.01 0.01 1 07/11/22 22:43 CALCULATION Qualifiers/ B Analyte detected in blank Definitions DF Dilution Factor Page 6 of 8 s WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133 21.2440 Main 901.213.240fl °Fax 901.213.2440 N A LYT I C A L www.waypointanalytical.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 22-187-0030 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: IT135 Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: lEmily M. Peterson Date & Time: 07/06/2022 09:39:14 Page 7 of 8 a N a a Y +- ¢+ a L,L C � Q �_ w a� o U _ 3 ❑cu rL ❑ p Y Z ate+ 6 a❑. ❑ ❑ O Z -0 �5 L❑n N N ✓ w �J!\ VJ C�7 N S G N Z O fV 2 0! E Z Cp Cp U ❑7 N m3� x � ii Qa=rnQe � ❑ � = N 0! yy2 a oc�=0❑ aQ Q p r o a ry a m z m a Q =_ L ��Y - o L x I O Q u CQ fo ) = q) L KL O ait in Q m V❑ W u lD _- rt s a N Z z 0 N Cl) Y Lk Q G 4 d1 �� u U N > ; v � � c 9 ...� � z 0 ?� E m d a a = S �� rn VJ a a s Im 2 = y tj �� v o oN snip i a w ad -n = w � � � ,.J H u m L r�' C �❑ a aF s v M L'J SplloSlplol .� ,o a u Cl) m o n m o m ❑ a V7 a � c0 �u o N aiuebJp/a}ea N V] Li 1 a Tt N d CO o ° °1 E eivau WV/NA-L c v_ :t Y ; 3 C E `❑ ¢ m s m a m = r 1�i 2a` ` 2 z Z c U a r n o t - a c E l7 -: L7 l7 a alisodwo(:)] jo qei{q} - [ha)j ol as;ay} xu;eyy rr s�auie�u❑�;o�agwn� m I V � E ro n w cr v x a+ s u y iL+ a a cc m U7 m C O r a s Q V a _ a 0 A m � ❑ N � o U2, n L7ia m o= o v a u a [� m E y a o y a u m a` CL �] c a T a Oc y E m 7 T y V � ❑ b co J a � J o QL W L G7 U O Q a M V r F m D aj E 5Y= N E 2<} c QLO v d ❑ a ac a �J v Qj 0 0LO o m V d a Page 8 of 8 7/5/2022 mg/kg mg/L Equiv Weight Milli Equiv Sodium 10000 125 23 5.434783 Calcium 13900 173.75 20 8.6875 Magnesium 4590 57.375 12 4.78125 Percent Solids 1.25 SAR 2.09 SAR = Na+ a (Ca2+ + M;42+ ) 5.43478 0.5( 8.6875 2 + 4.78125 2 ) Waypointo ANALYTICAL 10/13/2022 EMA Resources Inc Brent Collins 755 Yadkinville Rd Mocksville, NC, 27028 Ref: Analytical Testing Lab Report Number: 22-277-0020 Client Project Description: Reidsville, NC 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Dear Brent Collins: Waypoint Analytical, LLC. received sample(s) on 10/4/2022 for the analyses presented in the following report. The above referenced project has been analyzed per your instructions. The analyses were performed in accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling stage (refer to the chain of custody) results apply to the sample as received. The analytical data has been validated using standard quality control measures performed as required by the analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA (including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in the scope because NELAP accreditation is either not available or has not been applied for. Additional certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable. A full list of certifications is available upon request. Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time. Refer to sample analysis time for confirmation of holding time compliance. The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as - received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to the samples included in this report. Please do not hesitate to contact me or client services if you have any questions or need additional information. Sincerely, Connie Cook Project Manager Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis. Page 1 of 8 Waypointo ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 Fax 901.213.2440 www.waypointanalytical.com Certification Summary Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN State Program Lab ID Expiration Date Alabama State Program 40750 02/28/2023 Arkansas State Program 88-0650 02/07/2023 California State Program 2904 06/30/2023 Florida State Program - NELAP E871157 06/30/2023 Georgia State Program C044 02/18/2023 Georgia State Program 04015 06/30/2023 Illinois State Program - NELAP 200078 10/10/2023 Kentucky State Program 80215 06/30/2023 Kentucky State Program KY90047 12/31/2022 Louisiana State Program - NELAP LA037 12/31/2022 Louisiana State Program - NELAP 04015 06/30/2023 Mississippi State Program MS 02/11/2023 North Carolina State Program 415 12/31/2022 Pennsylvania State Program - NELAP 68-03195 05/31/2023 South Carolina State Program 84002 06/30/2022 Tennessee State Program 02027 02/11/2023 Texas State Program - NELAP T104704180 09/30/2022 Virginia State Program 00106 06/30/2023 Virginia State Program - NELAP 460181 09/14/2023 Page 1 of 1 00001/22-277-0020 Page 2 of 8 Waypoint ANALYTICAL 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Sample Summary Table Report Number: 22-277-0020 Client Project Description: Reidsville, NC Lab No Client Sample ID Matrix Date Collected Date Received 92501 Reidsville Solids 10/03/202212:20 10/04/2022 Page 3 of 8 Waypointo ANALYTICAL Client: EMA Resources Inc Project: Reidsville, NC Lab Report Number: 22-277-0020 Date: 10/12/2022 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 0 fax 901.213.2440 www.waypointanalytical.com CASE NARRATIVE Metals Analysis Method 601 OD Sample 97015 (Bolster) Analyte: Potassium QC Batch No: 1-641846/1-641319 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 97015 (Bolster) Analyte: Magnesium QC Batch No: 1-642077/1-641319 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 97015 (Bolster) Analyte: Manganese QC Batch No: 1-641846/1-641319 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 97015 (Bolster) Analyte: Sodium QC Batch No: 1-641846/1-641319 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 97015 (Bolster) Analyte: Sulfur QC Batch No: 1-642077/1-641319 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Sample 97015 (Bolster) Analyte: Zinc QC Batch No: 1-642350/1-641319 The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test was performed and passed quality control acceptance ranges. No matrix interference is suspected. Solids Total Mercury Analysis - CVAA Method 7471A Sample 89992 (September Monthly Comp) Analyte: Mercury QC Batch No: 1-641708/1-641289 The matrix spike, matrix spike duplicate and the post digestion spike were all outside of the quality control acceptance ranges. Matrix interference is suspected Page 4 of 8 Waypointo ANALYTICAL 46245 EMA Resources Inc Brent Collins 755 Yadkinville Rd Mocksville , NC 27028 Project Reidsville, NC Information : 2790 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 www.waypointanalytical.com Report Date : 10/13/2022 nReceived : 10/04/2022 C-�*�-� = Connie Cook Report Number : 22-277-0020 REPORT OFANALYSIS Project Manager Lab No : 92501 Matrix: Solids Sample ID : Reidsville Sampled: 10/3/2022 12:20 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Moisture 98.9 % 1 10/04/22 15:59 FMM SW-DRYWT Ammonia Nitrogen 11500 mg/Kg - dry 1450 9090 1 10/12/22 15:20 JPJ 4500NH3C-2011 Nitrate+Nitrite-N <451 mg/Kg - dry 451 451 1 10/08/22 11:25 ZBD 4500NO3F-2016 Organic N 77550 mg/Kg - dry 1455 9091 1 10/12/22 09:50 CALCULATION pH 6.9 S.U. 1 10/11/2216:00 SAR 9045D Total Solids 1.02 % 0.010 0.010 1 10/04/22 15:59 FMM 2540G-2011 Total Volatile Solids 71.4 % 0.010 0.010 1 10/04/22 15:59 FMM 2540G-2011 Total Kjeldahl Nitrogen 89100 mg/Kg - dry 909 22700 1 10/12/22 09:50 JPJ ;M-4500-NH3C-TKI` Phosphorus 23400 mg/Kg - dry 251 455 1 10/07/22 00:01 JTR 6010D Aluminum 17100 mg/Kg - dry 420 455 1 10/07/22 00:01 JTR 6010D Arsenic <21.8 mg/Kg - dry 21.8 45.5 1 10/07/22 00:01 JTR 6010D Cadmium <1.82 mg/Kg - dry 1.82 9.09 1 10/07/22 00:01 JTR 6010D Calcium 13500 mg/Kg - dry 3520 4550 1 10/07/22 00:01 JTR 6010D Chromium 48.2 mg/Kg - dry 21.5 22.7 1 10/07/22 00:01 JTR 6010D Copper 291 mg/Kg - dry 28.2 45.5 1 10/07/22 00:01 JTR 6010D Iron 16100 mg/Kg - dry 775 909 1 10/07/22 00:01 JTR 6010D Lead 67.4 mg/Kg - dry 16.4 27.3 1 10/07/22 00:01 JTR 6010D Magnesium 3750 mg/Kg - dry 235 455 1 10/07/22 00:01 EAL 6010D Manganese 535 mg/Kg - dry 29.5 45.5 1 10/07/22 00:01 JTR 6010D Mercury <0.575 mg/Kg - dry 0.575 13.2 1 10/06/22 13:17 TJS 7471A Molybdenum <12.3 mg/Kg - dry 12.3 22.7 1 10/07/22 00:01 JTR 6010D Nickel 14.03 mg/Kg - dry 10.9 22.7 1 10/07/22 00:01 JTR 6010D Potassium 4850 mg/Kg - dry 562 909 1 10/07/22 00:01 JTR 6010D Qualifiers/ DF Dilution Factor J Estimated value Definitions MQL Method Quantitation Limit Page 5 of 8 • Waypoint 27090 Whitten Road, Memphis, TN 38133 Main 901.213.2400 ° Fax 901.213.2440 ANALYTICAL www.waypointanalyiical.com 46245 EMA Resources Inc Project Reidsville, NC Brent Collins Report Date : 10/13/2022 755 Yadkinville Rd Information : Received : 10/04/2022 Mocksville , NC 27028 Connie Cook Report Number : 22-277-0020 REPORT OFANALYSIS Project Manager Lab No : 92501 Matrix: Solids Sample ID : Reidsville Sampled: 10/3/2022 12:20 Test Results Units MDL MQL DF Date / Time By Analytical Analyzed Method Selenium <29.1 mg/Kg - dry 29.1 45.5 1 10/07/22 00:01 JTR 6010D Sodium 5850 mg/Kg - dry 1180 2270 1 10/07/22 00:01 JTR 6010D Zinc 955 mg/Kg - dry 73.6 114 1 10/07/22 00:01 JTR 6010D Sulfur 12000 mg/Kg - dry 471 909 1 10/07/22 23:01 TJS 6010D Sodium Absorption Ratio 1.20 Ratio 0.01 0.01 1 10/07/22 00:01 CALCULATION Qualifiers/ DF Dilution Factor Definitions J Estimated value Page 6 of 8 s WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133 21.2440 Main 901.213.240fl °Fax 901.213.2440 N A LYT I C A L www.waypointanalytical.com Shipment Receipt Form Customer Number: 46245 Customer Name: EMA Resources Inc Report Number: 22-277-0020 Shipping Method 0 Fed Ex 0 US Postal 0 Lab 0 UPS 0 Client 0 Courier 0 Other: Thermometer ID: IT102 Shipping container/cooler uncompromised? * Yes 0 No Number of coolers/boxes received Custody seals intact on shipping container/cooler? 0 Yes 0 No Not Present Custody seals intact on sample bottles? 0 Yes 0 No Not Present Chain of Custody (COC) present? # Yes 0 No COC agrees with sample label(s)? # Yes 0 No COC properly completed # Yes 0 No Samples in proper containers? # Yes 0 No Sample containers intact? # Yes 0 No Sufficient sample volume for indicated test(s)? # Yes 0 No All samples received within holding time? # Yes 0 No Cooler temperature in compliance? # Yes 0 No Cooler/Samples arrived at the laboratory on ice. Samples were considered acceptable as cooling process had begun. # Yes 0 No Water - Sample containers properly preserved 0 Yes 0 No N/A Water - VOA vials free of headspace 0 Yes 0 No N/A Trip Blanks received with VOAs 0 Yes 0 No N/A Soil VOA method 5035 — compliance criteria met 0 Yes 0 No 0 N/A F_ High concentration container (48 hr) F_ High concentration pre -weighed (methanol -14 d) F_ Low concentration EnCore samplers (48 hr) F_ Low conc pre -weighed vials (Sod Bis -14 d) Special precautions or instructions included? 0 Yes * No Comments: Signature: IMakayla Weaver Date & Time: 10/04/2022 09:21:30 Page 7 of 8 Li T 'c (n E E E s N fJj i o U u_ n o ra I O O N rvo 4 �� 2 N3�ry Yz V `b'myay ° U Z �1 L ❑ sx v �rK aaxq D E o Q 2 � G °o O am 2 u V f,J 2 i 2' 2 2 T u _ 4 O i a Y i`n amu❑u,LLi7x_ � � /'jam � c x { a a a —_ Cl) Y MEMO N 77 ti N mco w E I EVJ 3 2 atj a tA N c SAI y LV m 0 Q o w ° O y E E E Hd a Sp!los lelolCL o c v 4 a y m N oiue6j0fo}ejl!N , V) ui t E a V J d o ,o a eruawwdWll o a w? CJ E ¢ p N m C -- ° 7 D 7 D a (CiQl09) 51e�aW z z a _ .Ua v w U a z u m m Q a al!SOOWo{]] �a qe��g} 2 ` -, a m m {lia}! 01 as}aa] xuleyy � J � C 7 N 7 N 3 _y a C C C E u }o lagwn� saau!ewo:)in Li a ., LL Q fo O W d Y C C C Gi a p^ p ai E Li �p $ a` (r} C a a Q y R E a � } y w � a � cc j 2 a a Q M E N a m OY C7 ;yn E s _rat ❑ z � N C (� C C<C N F Lon N�� Q L W ti Or Page 8 of 8 10/3/2022 mg/kg mg/L Equiv Weight Milli Equiv Sodium 5850 59.67 23 2.594348 Calcium 13500 137.7 20 6.885 Magnesium 3750 38.25 12 3.1875 Percent Solids 1.02 SAR 1.16 SAR = Na+ a (Ca2+ + M;42+ ) 2.59435 0.5( 6.885 2 + 3.18750 2 ) 13 ace Analytical ' ANALYTICAL REPORT February 01, 2022 EMA Resources Sample Delivery Group: L1451137 Samples Received: 01/13/2022 Project Number: Description: Sludge Report To: Mr. Brent Collins 755 Yadkinville Road Mocksville, NC 27028 Entire Report Reviewed By: z � �� Cassandra Foster Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy ofthe information provided, and as the samples are received. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 1 of 21 TABLE OF CONTENTS Cp: Cover Page Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 4 Sr: Sample Results 5 REIDSVILLE L1451137-01 5 Qc: Quality Control Summary 7 Wet Chemistry by Method 9012 B 7 Wet Chemistry by Method 9034-9030B 8 Wet Chemistry by Method 9045D 9 Wet Chemistry by Method D93/1010A 10 Mercury by Method 7470A 11 Metals (ICP) by Method 6010D 12 Volatile Organic Compounds (GC/MS) by Method 8260D 13 Chlorinated Acid Herbicides (GC) by Method 8151A 15 Pesticides (GC) by Method 8081B 16 Semi Volatile Organic Compounds (GC/MS) by Method 8270E 17 GI: Glossary of Terms 19 al: Accreditations & Locations 20 Sc: Sample Chain of Custody 21 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 2 of 21 SAMPLE SUMMARY REIDSVILLE L1451137-01 Waste Collected by Brent Collins Collected date/time 01/12/221110 Received date/time 01/13/2209:00 FP Method Batch Dilution Preparation Analysis Analyst Location date/time date/time F Preparation by Method 1311 WG1803662 1 01/18/2213:57 01/18/2213:57 KAH Mt. Juliet, TN Preparation by Method 1311 WG1804365 1 01/21/22 0755 01/21/22 0755 MLB Mt. Juliet, TN Wet Chemistry by Method 9012 B WG1801996 1 01/16/22 03:09 01/18/2217:18 JER Mt. Juliet, TN Wet Chemistry by Method 9034-9030B WG1803159 1 01/16/2218:00 01/17/2216:00 SAC Mt. Juliet, TN Wet Chemistry by Method 9045D WG1802442 1 01/14/22 14:46 01/18/2212:00 GI Mt. Juliet, TN Fn Wet Chemistry by Method D93/1010A WG1803602 1 01/19/22 0140 01/19/22 0140 WOS Mt. Juliet, TN Mercury by Method 7470A WG1806615 1 01/23/22 0800 01/24/22 09:06 ABL Mt. Juliet, TN Metals (ICP) by Method 6010D WG1806670 1 01/23/22 17:54 01/24/22 09:41 CCE Mt. Juliet, TN Fr Volatile Organic Compounds (GC/MS) by Method 8260D WG1804892 1 01/20/22 0151 01/20/22 0151 BMB Mt. Juliet, TN Chlorinated Acid Herbicides (GC) by Method 8151A WG1806269 1 01/28/22 0917 01/31/22 03:41 JMB Mt. Juliet, TN Rc Pesticides (GC) by Method 8081B WG1806067 1 01/25/22 05:55 01/25/221133 JMB Mt. Juliet, TN Semi Volatile Organic Compounds (GC/MS) by Method 8270E WG1806064 1 01/24/22 03:21 01/24/2215:55 BJP Mt. Juliet, TN GI SAI RC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 3 of 21 CASE NARRATIVE All sample aliquots were received at the correct temperature, in the proper containers, with the FP appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FC have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FS knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. 0 Fr FQ-cl GI Cassandra Foster Project Manager RC Project Narrative All Reactive Cyanide results reported in the attached report were determined as totals using method 9012 B. All Reactive Sulfide results reported in the attached report were determined as totals using method 9034-903013. Sample Delivery Group (SDG) Narrative Sample quantity was not sufficient to complete analysis per recommended method guidelines for the following samples. Lab Sample ID Project Sample ID Method L1451137-01 REIDSVILLE 9034-9030B ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 4 of 21 SAMPLE RESULTS - 01 L1451137 REIDSVILLE Collected date/time: 01/12/22 11:10 Preparation by Method 1311 Result Qualifier Prep Batch Analyte date / time TCLP Extraction 1/21/2022 7:55:09 AM WG1804365 TCLP ZHE Extraction - 1/18/20221:57:12 PM WG1803662 Fluid 1 1/21/2022 7:55:09 AM WG1804365 Initial pH 7.34 1/21/2022 7:55:09 AM WG1804365 Final pH 5.07 1/21/2022 7:55:09 AM WG1804365 Wet Chemistry by Method 9012 B Result Qualifier RDL Analyte mg/kg mg/kg Reactive Cyanide ND 0.250 Wet Chemistry by Method 9034-9030B Result Qualifier RDL Analyte mg/kg mg/kg Reactive Sulfide ND 25.0 Wet Chemistry by Method 9045D Dilution Analysis Batch date / time 1 01/18/202217:18 WG1801996 Dilution Analysis Batch date / time 1 01/17/202216:00 WG1803159 Result Qualifier Dilution Analysis Batch Analyte su date / time Corrosivity by pH 7.52 T8 1 01/18/202212:00 WG1802442 Sample Narrative: L1451137-01 WG1802442: 7.52 at16.2C Wet Chemistry by Method D93/1010A Result Analyte Deg. F Ignitability DNI at170 Mercury by Method 7470A Qualifier Dilution Analysis Batch date / time 1 01/19/2022 0140 WG1803602 Result Qualifier RDL Limit Analyte mg/I mg/I mg/I Mercury ND 0.0100 0.20 Metals (ICP) by Method 6010D Result Qualifier RDL Limit Analyte mg/I mg/I mg/I Arsenic ND 0.100 5 Barium ND 0.100 100 Cadmium ND 0.100 1 Chromium ND 0.100 5 Lead ND 0.100 5 Selenium 0.137 0.100 1 Silver ND 0.100 5 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier RDL Limit Analyte mg/I mg/I mg/I Benzene ND J3 0.0500 0.50 Carbon tetrachloride ND J3 0.0500 0.50 Chlorobenzene ND 0.0500 100 Chloroform ND 0.250 6 ACCOUNT: PROJECT: EMA Resources Dilution Analysis Batch date / time 1 01/24/2022 09:06 WG1806615 Dilution Analysis Batch date / time 1 01/24/2022 09:41 WG1806670 1 01/24/2022 09:41 WG1806670 1 01/24/2022 09:41 WG1806670 1 01/24/2022 09:41 WG1806670 1 01/24/2022 09:41 WG1806670 1 01/24/2022 09:41 WG1806670 1 01/24/2022 09:41 WG1806670 Dilution Analysis Batch date / time 1 01/20/2022 0151 WG1804892 1 01/20/2022 0151 WG1804892 1 01/20/2022 0151 WG1804892 1 01/20/2022 0151 WG1804892 SDG: DATE/TIME: PAGE: L1451137 02/01/22 09:23 5 of 21 REIDSVILLE SAMPLE RESULTS Collected date/time: 01/12/22 11:10 L1451137 Volatile Organic Compounds (GC/MS) by Method 8260D - 01 Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date/time 1,2-Dichloroethane ND 0.0500 0.50 1 01/20/2022 01:51 WG1804892 1,1-Dichloroethene ND J3 0.0500 0.70 1 01/20/2022 01:51 WG1804892 2-Butanone (MEK) ND 0.500 200 1 01/20/2022 01:51 WG1804892 Tetrachloroethene ND J3 0.0500 0.70 1 01/20/2022 01:51 WG1804892 Trichloroethene ND J3 0.0500 0.50 1 01/20/2022 01:51 WG1804892 Vinyl chloride ND J3 0.0500 0.20 1 01/20/2022 01:51 WG1804892 (S) Toluene-dH 98.3 80.0-120 0112012022 01.51 WG1804892 (S) 4-Bromofluorobenzene 99.8 77.0-126 0112012022 01.51 WG1804892 (S) 1,2-Dichloroethane-d4 104 70.0-130 011201202201.51 WG1804892 Chlorinated Acid Herbicides (GC) by Method 8151A Result Analyte mg/I 2,4,5-TP (Silvex) ND 2,4-D ND (S) 2,4-Dichlorophenyl Acetic Acid 70.4 Pesticides (GC) by Method 8081B Qualifier RDL mg/I 0.00200 0.00200 14.0-158 Limit mg/I 1 10 Dilution Analysis date/time 1 01/31/2022 03:41 1 01/31/2022 03:41 0113112022 03.41 Batch WG1806269 WG1806269 WG1806269 Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date/time Chlordane ND 0.00500 0.03 1 01/25/20221133 WG1806067 Endrin ND 0.00500 0.02 1 01/25/20221133 WG1806067 Heptachlor ND 0.00500 0.0080 1 01/25/20221133 WG1806067 Heptachlor epoxide ND 0.00500 0.0080 1 01/25/20221133 WG1806067 Lindane ND 0.00500 0.40 1 01/25/20221133 WG1806067 Methoxychlor ND 0.00500 10 1 01/25/20221133 WG1806067 Toxaphene ND 0.0100 0.50 1 01/25/20221133 WG1806067 (S) Decochlorobiphenyl 82.6 10.0-128 011251202211.33 WG1806067 (S) Tetrochloro-m-xylene 78.5 10.0-127 011251202211.33 WG1806067 Semi Volatile Organic Compounds (GC/MS) by Method 8270E Result Qualifier RDL Limit Dilution Analysis Batch Analyte mg/I mg/I mg/I date/time 1,4-Dichlorobenzene ND 0.100 7.50 1 01/24/202215:55 WG1806064 2,4-Dinitrotoluene ND 0.100 0.13 1 01/24/202215:55 WG1806064 Hexachlorobenzene ND 0.100 0.13 1 01/24/202215:55 WG1806064 Hexachloro-1,3-butadiene ND 0.100 0.50 1 01/24/202215:55 WG1806064 Hexachloroethane ND 0.100 3 1 01/24/202215:55 WG1806064 Nitrobenzene ND 0.100 2 1 01/24/202215:55 WG1806064 Pyridine ND 0.100 5 1 01/24/202215:55 WG1806064 3&4-Methyl Phenol ND 0.100 400 1 01/24/202215:55 WG1806064 2-Methylphenol ND 0.100 200 1 01/24/202215:55 WG1806064 Pentachlorophenol ND 0.100 100 1 01/24/202215:55 WG1806064 2,4,5-Trichlorophenol ND 0.100 400 1 01/24/202215:55 WG1806064 2,4,6-Trichlorophenol ND 0.100 2 1 01/24/202215:55 WG1806064 (S) 2-Fluorophenol 30.7 10.0-120 011241202215.55 WG1806064 (S) Phenol-d5 18.5 10.0-120 011241202215:55 WG1806064 (S) Nitrobenzene-d5 61.0 10.0-127 011241202215:55 WG1806064 (S) 2-Fluorobiphenyl 70.5 10.0-130 011241202215:55 WG1806064 (S)2,4,6-Tribromophenol 65.5 10.0-155 011241202215:55 WG1806064 (S) p-Terphenyl-d14 84.6 10.0-128 011241202215:55 WG1806064 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 6 of 21 WG1801996 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9012 B L1451137-01 Method Blank (MB) C p (MB) R3751051-1 01/13/22 16:57 MB Result MB Qualifier MB MDL MB RDL Analyte mg/kg mg/kg mg/kg TC I Reactive Cyanide U 0.0390 0.250 FS L1450489-01 Original Sample (OS) • Duplicate (DUP) [�n] (OS) L1450439-01 01/13/22 17:02 • (DUP) R3751051-3 01/13/22 17:03 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits F Analyte mg/kg mg/kg Reactive Cyanide ND ND 1 200 P1 20 L1450842-01 Original Sample (OS) • Duplicate (DUP) GI (OS) L1450342-01 01/13/22 1714 • (DUP) R3751051-6 01/13/22 1715 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits FAI Analyte mg/kg mg/kg Reactive Cyanide ND ND 1 0.000 20 FSc Laboratory Control Sample (LCS) (LCS) R3751051-2 01/18/22 16:58 Spike Amount LCS Result LCS Rec. Analyte mg/kg mg/kg Reactive Cyanide 2.50 2.48 99.3 Rec. Limits LCS Qualifier 85.0-115 L1450489-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1450439-02 01/13/22 17:04 • (MS) R3751051-4 01/13/22 17:05 • (MSD) R3751051-5 01/13/22 17:06 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg mg/kg Reactive Cyanide 1.67 ND 1.46 1.47 87.8 88.4 1 75.0-125 0.675 20 L1451691-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1451691-01 01/13/22 17:26 • (MS) R3751051-7 01/13/22 17:27 • (MSD) R3751051-8 01/13/22 17:28 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/kg mg/kg mg/kg mg/kg Reactive Cyanide 1.67 ND 0.322 0.281 19.4 16.9 1 75.0-125 J6 J6 13.7 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 7 of 21 -------------- WG1803159 Wet Chemistry by Method 9034-9030B Method Blank (MB) (MB) R3750639-1 01/17/22 16:00 MB Result MB Qualifier MB MDL MB RDL Analyte mg/kg mg/kg mg/kg Reactive Sulfide U 7.63 25.0 QUALITY CONTROL SUMMARY L1451137-01 Laboratory Control Sample (LCS) (LCS) R3750639-2 01/17/22 16:00 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/kg mg/kg Reactive Sulfide 100 76.0 76.0 70.0-130 L1451691-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1451691-01 01/17/22 16:00 • (MS) R3750639-3 01/17/22 16:00 • (MSD) R3750639-4 01/17/22 16:00 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte mg/kg mg/kg mg/kg mg/kg Reactive Sulfide 100 60.1 160 150 100 89.8 1 70.0-130 6.71 RPD Limits 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 3 of 21 WG1802442 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9045D L1451137-01 Laboratory Control Sample (LCS) C (LCS) R3750350-1 01/13/22 12:00 p Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier ITC] Analyte su su % % Corrosivity by pH 10.0 10.0 100 99.0-101 F Sample Narrative: SS LCS:10 at17.1C [Cn] 5 Sr �GI FAI FSC1 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 9 of 21 WG1803602 QUALITY CONTROL SUMMARY Wet Chemistry by Method D93/1010A L1451137-01 L1451137-01 Original Sample (OS) • Duplicate (DUP) (OS) L1451137-01 01/19/22 0140 • (DUP) R3751037-3 01/19/22 0140 Original Result DUP Result Dilution DUP RPD Analyte Deg. F Deg. F Ignitability DNI at170 DNI at170 1 0.000 L1451792-01 Original Sample (OS) • Duplicate (DUP) DUP Qualifier DUP RPD Limits i 10 (OS) L1451792-01 01/19/22 01:40 • (DUP) R3751037-4 01/19/22 0140 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte Deg. F Deg. F Ignitability DNI at170 DNI at170 1 0.000 10 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3751037-1 01/19/22 0140 • (LCSD) R3751037-2 01/19/22 0140 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte Deg. F Deg. F Deg. F Ignitability 126 124 128 98.2 101 95.6-104 3.18 10 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 10 of 21 WG1806615 QUALITY CONTROL SUMMARY Mercury by Method 7470A L1451137-01 Method Blank (MB) (MB) R3752331-1 01/24/22 08:33 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I Mercury U 0.00330 0.0100 Laboratory Control Sample (LCS) (LCS) R3752881-2 01/24/22 08:35 Spike Amount LCS Result LCS Rec. Analyte mg/I mg/I Mercury 0.0300 0.0300 100 Rec. Limits LCS Qualifier 80.0-120 L1449147-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1449147-01 01/24/22 08:37 • (MS) R3752331-3 01/24/22 08:40 • (MSD) R3752331-4 01/24/22 08:42 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/I mg/I mg/I mg/I Mercury 0.0300 ND 0.0300 0.0304 100 101 1 75.0-125 1.13 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 11 of 21 WG1806670 Metals (ICP) by Method 6010D Method Blank (MB) (MB) R3752956-1 01/24/22 0904 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I Arsenic U 0.0333 0.100 Barium U 0.0333 0.100 Cadmium U 0.0333 0.100 Chromium U 0.0333 0.100 Lead U 0.0333 0.100 Selenium U 0.0333 0.100 Silver U 0.0333 0.100 Laboratory Control Sample (LCS) (LCS) R3752956-2 01/24/22 09:06 QUALITY CONTROL SUMMARY L1451137-01 Spike Amount LCS Result LCS Rec. Rec. Limits Analyte mg/I mg/I Arsenic 10.0 9.51 95.1 80.0-120 Barium 10.0 9.55 95.5 80.0-120 Cadmium 10.0 9.57 95.7 80.0-120 Chromium 10.0 9.50 95.0 80.0-120 Lead 10.0 9.72 97.2 80.0-120 Selenium 10.0 9.96 99.6 80.0-120 Silver 2.00 1.77 88.4 80.0-120 LCS Qualifier L1451976-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1451976-02 01/24/22 09:09 • (MS) R3752956-4 01/24/22 09:14 • (MSD) R3752956-5 01/24/22 09:17 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Analyte mg/I mg/I mg/I mg/I Arsenic 10.0 ND 9.46 9.47 94.6 94.7 Barium 10.0 0.171 9.51 9.59 93.4 94.2 Cadmium 10.0 ND 9.45 9.50 94.5 95.0 Chromium 10.0 ND 9.35 9.38 93.5 93.8 Lead 10.0 ND 9.52 9.57 95.2 95.7 Selenium 10.0 ND 9.65 9.75 96.5 97.5 Silver 2.00 ND 1.74 1.75 86.9 87.3 Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits 1 75.0-125 0.0860 20 1 75.0-125 0.915 20 1 75.0-125 0.585 20 1 75.0-125 0.367 20 1 75.0-125 0.561 20 1 75.0-125 0.965 20 1 75.0-125 0.446 20 ACCOUNT: EMA Resources PROJECT: SDG: DATE/TIME: PAGE: L1451137 02/01/22 09:23 12 of 21 WG1804892 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1451137-01 Method Blank (MB) (MB) R3751605-3 01/19/22 2324 MB Result Analyte mg/I Benzene U Carbon tetrachloride U Chlorobenzene U Chloroform U 1,2-Dichloroethane U 1,1-Dichloroethene U 2-Butanone (MEK) U Tetrachloroethene U Trichloroethene U Vinyl chloride U (S) Toluene-dH 97.4 (S) 4-Bromofluorobenzene 96.1 (S) 1,2-Dichloroethane-d4 104 MB Qualifier MB MDL mg/I MB RDL mg/I 0.0167 0.0500 0.0167 0.0500 0.0167 0.0500 0.0833 0.250 0.0167 0.0500 0.0167 0.0500 0.167 0.500 0.0167 0.0500 0.0167 0.0500 0.0167 0.0500 80.0-120 77.0-126 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3751605-1 01/19/22 20:57 • (LCSD) R3751605-2 01/19/22 2117 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits Analyte mg/I mg/I mg/I Benzene 0.250 0.213 0.222 85.2 88.8 70.0-123 Carbon tetrachloride 0.250 0.254 0.258 102 103 68.0-126 Chlorobenzene 0.250 0.217 0.213 86.8 85.2 80.0-121 Chloroform 0.250 0.226 0.224 90.4 89.6 73.0-120 1,2-Dichloroethane 0.250 0.220 0.222 88.0 88.8 70.0-128 1,1-Dichloroethene 0.250 0.231 0.241 92.4 96.4 71.0-124 2-Butanone (MEK) 1.25 1.26 1.08 101 86.4 44.0-160 Tetrachloroethene 0.250 0.227 0.233 90.8 93.2 72.0-132 Trichloroethene 0.250 0.252 0.247 101 98.8 78.0-124 Vinyl chloride 0.250 0.209 0.208 83.6 83.2 67.0-131 (S) Toluene-dH 98.3 98.0 80.0-120 (S) 4-Bromofluorobenzene 102 101 77.0-126 (S) 1,2-Dichloroethane-d4 102 104 70.0-130 LCS Qualifier LCSD Qualifier RPD 4.14 1.56 1.86 0.889 0.905 4.24 15.4 2.61 2.00 0.480 RPD Limits 20 20 20 20 20 20 20 20 20 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 13 of 21 WG1804892 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1451137-01 L1451137-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1451137-01 01/20/22 0151 • (MS) R3751605-4 01/20/22 03:57 • (MSD) R3751605-5 01/20/22 0413 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte mg/I mg/I mg/I mg/I Benzene 0.250 ND 0.182 0.136 72.8 54.4 1 17.0-158 J3 28.9 27 Carbon tetrachloride 0.250 ND 0.196 0.114 78.4 45.6 1 23.0-159 J3 52.9 28 Chlorobenzene 0.250 ND 0.188 0.158 75.2 63.2 1 33.0-152 17.3 27 Chloroform 0.250 ND ND ND 77.2 62.0 1 29.0-154 21.8 28 1,2-Dichloroethane 0.250 ND 0.219 0.215 87.6 86.0 1 29.0-151 1.84 27 1,1-Dichloroethene 0.250 ND 0.186 0.111 74.4 44.4 1 11.0-160 J3 50.5 29 2-Butanone (MEK) 1.25 ND 1.47 1.64 118 131 1 10.0-160 10.9 32 Tetrachloroethene 0.250 ND 0.185 0.110 74.0 44.0 1 10.0-160 J3 50.8 27 Trichloroethene 0.250 ND 0.177 0.122 70.8 48.8 1 10.0-160 J3 36.8 25 Vinyl chloride 0.250 ND 0.155 0.0940 62.0 37.6 1 10.0-160 J3 49.0 27 (S) Toluene-dH 101 98.1 80.0-120 (S) 4-Bromofluorobenzene 103 103 77.0-126 (S) 1,2-Dichloroethane-d4 106 106 70.0-130 L1450582-01 Original Sample (OS) • Matrix Spike (MS) (OS) L1450532-01 01/20/22 00:27 • (MS) R3751605-6 01/20/22 04:40 Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier Analyte mg/I mg/I mg/I Benzene 0.250 ND 0.210 84.0 1 17.0-158 Carbon tetrachloride 0.250 ND 0.262 105 1 23.0-159 Chlorobenzene 0.250 ND 0.218 87.2 1 33.0-152 Chloroform 0.250 ND ND 87.2 1 29.0-154 1,2-Dichloroethane 0.250 ND 0.224 89.6 1 29.0-151 1,1-Dichloroethene 0.250 ND 0.244 97.6 1 11.0-160 2-Butanone (MEK) 1.25 ND 1.36 109 1 10.0-160 Tetrachloroethene 0.250 ND 0.239 95.6 1 10.0-160 Trichloroethene 0.250 ND 0.236 94.4 1 10.0-160 Vinyl chloride 0.250 ND 0.228 91.2 1 10.0-160 (S) Toluene-dH 97.7 80.0-120 (S) 4-Bromofluorobenzene 103 77.0-126 (S) 1,2-Dichloroethane-d4 106 70.0-130 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 14 of 21 WG1806269 Chlorinated Acid Herbicides (GC) by Method 8151A Method Blank (MB) (MB) R3755450-1 01/31/22 02:57 MB Result Analyte mg/I 2,4-D U 2,4,5-TP (Silvex) U (S) Z4-Dichlorophenyl Acetic 62.4 Acid QUALITY CONTROL SUMMARY L1451137-01 MB Qualifier MB MDL MB RDL mg/I mg/I 0.000667 0.00200 0.000667 0.00200 14.0-158 Laboratory Control Sample (LCS) (LCS) R3755450-2 01/31/22 03:11 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I 2,4-D 0.0500 0.0370 74.0 50.0-120 2,4,5-TP (Silvex) 0.0500 0.0351 70.2 50.0-125 (S) Z4-Dichlorophenyl Acetic 58.0 14. 0-158 Acid L1452051-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1452051-01 01/31/22 04:39 • (MS) R3755450-3 01/31/22 04:54 • (MSD) R3755450-4 01/31/22 05:03 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Analyte mg/I mg/I mg/I mg/I 2,4-D 0.0500 ND 0.0382 0.0387 76.4 77.4 2,4,5-TP (Silvex) 0.0500 ND 0.0339 0.0340 67.8 68.0 (S) Z4-Dichlorophenyl Acetic 55.2 64.0 Acid ACCOUNT: EMA Resources PROJECT: Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits 1 50.0-120 1.30 20 1 50.0-125 0.295 20 14.0-158 SDG: DATE/TIME: PAGE: L1451137 02/01/22 09:23 15 of 21 WG1806067 Pesticides (GC) by Method 8081B Method Blank (MB) QUALITY CONTROL SUMMARY L1451137-01 (MB) R3753433-1 01/25/22 10:05 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I Gamma BHC U 0.00167 0.00500 Endrin U 0.00167 0.00500 Heptachlor U 0.00167 0.00500 Heptachlor epoxide U 0.00167 0.00500 Methoxychlor U 0.00167 0.00500 Chlordane U 0.00167 0.00500 Toxaphene U 0.00333 0.0100 (S) Decachlorobiphenyl 101 10.0-128 (S) Tetrochloro-m-xylene 86.6 10.0-127 Laboratory Control Sample (LCS) (LCS) R3753433-2 01/25/22 1014 Spike Amount LCS Result LCS Rec. Rec. Limits Analyte mg/I mg/I Gamma BHC _ 0.0100 0.0103 103 55.0-129 Endrin 0.0100 0.0111 ill 57.0-134 Heptachlor 0.0100 0.0121 121 27.0-132 Heptachlor epoxide 0.0100 0.0108 108 57.0-130 Methoxychlor 0.0100 0.0115 115 54.0-155 (S) Decachlorobiphenyl 96.7 10.0-128 (S) Tetrochloro-m-xylene 91.4 10.0-127 LCS Qualifier L1447999-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1447999-01 01/25/22 10:23 • (MS) R3753433-3 01/25/22 10:31 • (MSD) R3753433-4 01/25/22 10:40 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Analyte mg/I mg/I mg/I mg/I Gamma BHC 0.0100 ND 0.00847 0.00902 84.7 90.2 Endrin 0.0100 ND 0.00991 0.0106 99.1 106 Heptachlor 0.0100 ND 0.0107 0.0114 107 114 Heptachlor epoxide 0.0100 ND 0.00941 0.00983 94.1 98.3 Methoxychlor 0.0100 ND 0.0108 0.0116 108 116 (S) Decachlorobiphenyl 96.1 95.8 (S) Tetrochloro-m-xylene 78.4 84.8 Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits 1 14.0-141 6.29 40 1 10.0-160 6.73 39 1 16.0-136 6.33 40 1 10.0-160 4.37 36 1 10.0-160 7.14 34 10.0-128 10.0-127 ACCOUNT: EMA Resources PROJECT: SDG: DATE/TIME: L1451137 02/01/22 09:23 PAGE: 16 of 21 WG1806064 QUALITY CONTROL SUMMARY Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1451137-01 Method Blank (MB) (MB) R3752967-2 01/24/22 12:41 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/I mg/I 1,4-Dichlorobenzene U 0.0333 0.100 2,4-Dinitrotoluene U 0.0333 0.100 Hexachlorobenzene U 0.0333 0.100 Hexachloro-1,3-butadiene U 0.0333 0.100 Hexachloroethane U 0.0333 0.100 Nitrobenzene U 0.0333 0.100 Pyridine U 0.0333 0.100 2-Methylphenol U 0.0333 0.100 3&4-Methyl Phenol U 0.0333 0.100 Pentachlorophenol U 0.0333 0.100 2,4,5-Trichlorophenol U 0.0333 0.100 2,4,6-Trichlorophenol U 0.0333 0.100 (S) Nitrobenzene-d5 75.2 10.0-127 (S) 2-Fluorobiphenyl 78.7 10.0-130 (S) p-Terphenyl-d14 96.1 10.0-128 (S) Phenol-d5 22.6 10.0-120 (S) 2-Fluorophenol 37.9 10.0-120 (S) 2,4, 6-Tribromophenol 85.5 10. 0-155 Laboratory Control Sample (LCS) (LCS) R3752967-1 01/24/22 12:20 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I 1,4-Dichlorobenzene 0.500 0.404 80.8 18.0-120 2,4-Dinitrotoluene 0.500 0.442 88.4 49.0-124 Hexachlorobenzene 0.500 0.438 87.6 44.0-120 Hexachloro-1,3-butadiene 0.500 0.374 74.8 19.0-120 Hexachloroethane 0.500 0.425 85.0 15.0-120 Nitrobenzene 0.500 0.366 73.2 27.0-120 Pyridine 0.500 0.102 20.4 10.0-120 2-Methylphenol 0.500 0.258 51.6 28.0-120 3&4-Methyl Phenol 0.500 0.279 55.8 31.0-120 Pentachlorophenol 0.500 0.418 83.6 23.0-120 2,4,5-Trichlorophenol 0.500 0.429 85.8 44.0-120 2,4,6-Trichlorophenol 0.500 0.434 86.8 42.0-120 (S) Nitrobenzene-d5 68.1 10.0-127 (S) 2-Fluorobiphenyl 84.7 10.0-130 (S) p-Terphenyl-d14 100 10.0-128 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 17 of 21 WG1806064 QUALITY CONTROL SUMMARY Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1451137-01 Laboratory Control Sample (LCS) (LCS) R3752967-1 01/24/22 12:20 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I (S) Phenol-d5 25.3 10.0-120 (S) 2-Fluorophenol 42.4 10.0-120 (S) 2,4, 6-Tribromophenol 89.0 10. 0-155 L1450299-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1450299-01 01/24/22 13:24 • (MS) R3752967-3 01/24/22 13:46 • (MSD) R3752967-4 01/24/22 14:07 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits Analyte mg/I mg/I mg/I mg/I 1,4-Dichlorobenzene 0.500 ND 0.329 0.353 65.8 70.6 1 17.0-120 2,4-Dinitrotoluene 0.500 ND 0.362 0.393 72.4 78.6 1 39.0-125 Hexachlorobenzene 0.500 ND 0.374 0.406 74.8 81.2 1 35.0-122 HexachIaro-1,3-butadiene 0.500 ND 0.318 0.344 63.6 68.8 1 12.0-120 Hexachloroethane 0.500 ND 0.336 0.367 67.2 73.4 1 10.0-120 Nitrobenzene 0.500 ND 0.303 0.329 60.6 65.8 1 12.0-120 Pyridine 0.500 ND 0.102 0.213 20.4 42.6 1 10.0-120 2-Methylphenol 0.500 ND 0.214 0.256 42.8 51.2 1 10.0-120 3&4-Methyl Phenol 0.500 ND 0.231 0.269 46.2 53.8 1 10.0-120 Pentachlorophenol 0.500 ND 0.351 0.383 70.2 76.6 1 10.0-128 2,4,5-Trichlorophenol 0.500 ND 0.343 0.388 68.6 77.6 1 33.0-120 2,4,6-Trichlorophenol 0.500 ND 0.346 0.405 69.2 81.0 1 26.0-120 (S) Nitrobenzene-d5 59.7 64.0 10.0-127 (S) 2-Fluorobiphenyl 70.6 79.1 10.0-130 (S) p-Terphenyl-d14 89.8 93.7 10.0-128 (S) Phenol-d5 20.7 23.6 10.0-120 (S) 2-Fluorophenol 32.1 38.7 10.0-120 (S)2,4,6-Tribromophenol 74.5 77.5 10.0-155 MS Qualifier MSD Qualifier RPD RPD Limits J3 7.04 40 8.21 25 8.21 24 7.85 34 8.82 40 8.23 30 70.5 37 17.9 30 15.2 36 8.72 37 12.3 31 15.7 31 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 13 of 21 GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and ifyou have additional questions please contactyour project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions u Fc Fss] MDL Method Detection Limit. ND Not detected at the Reporting Limit (or MDL where applicable). Fn RDL Reported Detection Limit. Rec. Recovery. Fr RPD Relative Percent Difference. SDG Sample Delivery Group. Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and F (S) Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. U Not detected at the Reporting Limit (or MDL where applicable). Analyte The name ofthe particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. Ifthe sample matrix contains an interfering material, the sample preparation volume or weight values differ from the F Dilution standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. Rc These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal Limits for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. Original Sample The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications ofthe Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. Ifthere was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section ofthe report includes the results ofthe laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity ofthe results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession ofthe samples from the time of collection until delivery to the laboratory for analysis. This section ofyour report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section ofthe Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description J3 The associated batch QC was outside the established quality control range for precision. J6 The sample matrix interfered with the ability to make any accurate determination, spike value is low. P1 RPD value not applicable for sample concentrations less than 5 times the reporting limit. T8 Sample(s) received past/too close to holding time expiration. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: EMA Resources L1451137 02/01/22 09:23 19 of 21 ACCREDITATIONS & LOCATIONS Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122 Alabama 40660 Nebraska N E-OS-15-05 Alaska 17-026 Nevada TN000032021-1 Arizona AZ0612 New Hampshire 2975 Arkansas 88-0469 New Jersey—NELAP TNO02 California 2932 New Mexico TN00003 Colorado TN00003 New York 11742 Connecticut PH-0197 North Carolina Env375 Florida E87487 North Carolina' DW21704 _ Georgia NELAP North Carolina 3 41 Georgia' 923 North Dakota R-140 Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky' 6 KY90010 South Carolina 84004002 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee'" 2006 Louisiana LA018 Texas T104704245-20-18 Maine TN00003 Texas5 LABO152 Maryland 324 Utah TN000032021-11 Massachusetts M-TNO03 Vermont VT2006 Michigan 9958 Virginia 110033 Minnesota 047-999-395 Washington C847 Mississippi TN00003 West Virginia 233 Missouri 340 Wisconsin 998093910 Montana CERT0086 Wyoming A2 LA A2LA— ISO 17025 1461.01 AIHA-LAP,LLC EMLAP 100789 A2 LA — ISO 17025 5 1461.02 DOD 1461.01 Canada 1461.01 USDA P330-15-00234 EPA—Crypto TN00003 Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical. Rc ACCOUNT: PROJECT: SDG: DATE/TIME: EMA Resources L1451137 02/01/22 09:23 PAGE: 20 of 21 Company Name/Address: Billing information. EMA Resources Mr. Brent Collins 755 Yadkinville Road ` 755 Yadkinville Road Mocksville, NC 27028 Mocksville, NC 27028 Report to: Email To. Mr. Brent Collins brent.collins@emaresourcesinc.com;roy.whitak Project Description: Sludge City/State nn yy`` llr //1%- lease Circle: PT Collected: F.l-ds r MT CT ET Phone 336-751-1441 Client Project # Lab Project # Collected by (print). ICJ fli al r`ii'lS Collected by (signature): Immediately Packed on Ice li Y ✓ P Sample ID j`t• 13�11��� Site/Facility ID # P.O. # Rush? (Lab MUST Be Notified) Quote N —Same Day _ Five Day _ Next Day _ 5 Day (Rad Only) Date Results Needed _ Two Day _ 10 Day (Rad Only) Three Day Comp/Grab Matrix' Depth Date Tim1 — C SS S r �1 rZ17.� is rid ul o w � L 11 O No. U J � of e-1 :ntrs N � U I— 2 X X Chain of Custody Page — of W aceArralytica! F 17065 te5anon Rd Mart I, Iiet. TN 37177 Submitting a urnplevla this chain of costpdy [on51Rv[ef xanpwledj—nt and aaeplinte of the Pace Terri end Cnnditlnns found at. httpa //info. pace abt-wm/h,bh/paa standard terma.pdt SDG# LIuS! 1 3`7 H119 Acctnum: EMARES Template:311413 Preiogin: P895413 PM: 807 -Justin Carr PB: 061,E a' }a — Shipped via: Fli Ground Remarks Sample p )lab only} ' Matrix:Remarks: Sample Rece' I. t. COC Seal Present/Intact: P y 14 SS -Soil AIR -Air F-Filter pH Temp GW- Groundwater B- Bioassay cOC Signed/accurate: N —N WW - Wastewater Flow Other Bottles arrive intact: DW -Drinking Water Correct bottles used: �f'_N OT Other Samples returned via: Sufficient volume sent: � --N - UPS FedEx Courier Tracking if if APplicable — — — V0A Zero Headspace: Y N Correct/Checked: � _N Relinquished by: (Signature) Date: Time: Received by, (Signature) Trip Blank Received: Yes /4Z"' I ]Preservation RpD Screen <p.5 mR/hr: N TBR Relinquished by : (Signature) Date Time: Received by: (Signature) /17 Tem "C Bottles Received: If preservation required by Login: Date/Time Relinquished by : (Signature) Date: Time: Received for 1 1: (Signature) Date Time: Hold: Condition: NCF ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Reidsville WQ Permit Number: WQ0002376 WWTP Name: Reidsville WWTP NPDES Number: NCO024881 Monitoring Period: From l/l/2022 To 3/31/2022 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ Alt B (Alk Treatment) ❑ Alt. C (Prior Testing) ❑ A1t.D (No Prior Test) ❑ Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost 131 Heat Drying ❑ Heat Treatment ❑ Thermophilic Beta Ray ❑ 1 Gamma Ray ❑ Pasteurization ❑ Class B: jAlt. (1) Fecal Density 0 I Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ 1 Air Drying ❑ 1 Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g y Number o Excee- dences Frequency of Analysis Sample Type Analytical Tech -pique Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN CFU 29762 47377 65476 col/g 0 Quarterly G SM9222D 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.1 (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) 10 Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ lAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) 0 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the uirements. "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Ralph Potter - Interim Wastewater Superintendent and Pretreatment Coordinator Brent Collins; Director of Technical Services Preparer Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print) L'Z4 /� 7/- Feb 10, 2023 4;2�- 1/2/2023 Ralph . Potter, Jr (Feb 10, 2023 07:38 EST) Signature of Preparer* Date Signature of Land Applier (if applicable) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) Date DENR FORM PVRF 02T (12/2006) Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road Mocksville, NC 27028 Page 1 Report Date: 1/21/2022 Date Sample Rcvd: 1/12/2022 Meritech Work Order # 01122255 Sample: Reidsville 1 Grab 1/12/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.68 % 1/13/22 0-100 % SM 2540B Fecal Coliform (Sludge) 29,762 col/g dry wt 1/12/22 130 col/g dry wt SM 9222D Meritech Work Order # 01122256 Sample: Reidsville 2 Grab 1/12/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.70 % 1/13/22 0-100 % SM 2540B Fecal Coliform (Sludge) 64,706 col/g dry wt 1/12/22 130 col/g dry wt SM 9222D Meritech Work Order # 01122257 Sample: Reidsville 3 Grab 1/12/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.74 % 1/13/22 0-100 % SM 2540B Fecal Coliform (Sludge) 45,977 col/g dry wt 1/12/22 130 col/g dry wt SM 9222D Meritech Work Order # 01122258 Sample: Reidsville 4 Grab 1/12/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.68 % 1/13/22 0-100 % SM 2540B Fecal Coliform (Sludge) 65,476 col/g dry wt 1/12/22 130 col/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 f ax. (336) 342-1522 Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 ASP Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road Mocksville, NC 27028 Page 2 Report Date: 1/21/2022 Date Sample Rcvd: 1/12/2022 Meritech Work Order # 01122259 Sample: Reidsville 5 Grab 1/12/22 Parameters Result Analysis Date Reortin Limit Method % Total Solids 1.7 % 1/13/22 0-100 % SM 2540B Fecal Coliform (Sludge) 41,176 col/g dry wt 1/12/22 130 col/g dry wt SM 9222D Meritech Work Order # 01122260 Sample: Reidsville 6 Grab 1/12/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.74 % 1/13/22 0-100 % SM 2540B Fecal Coliform (Sludge) 34,483 col/g dry wt 1/12/22 130 col/g dry wt SM 9222D Meritech Work Order # 01122261 Sample: Reidsville 7 Grab 1/12/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.69 % 1/13/22 0-100 % SM 2540B Fecal Coliform (Sludge) 65,089 col/g dry wt 1/12/22 130 col/g dry wt SM 9222D I hereby certify that have reviewed and approve these data. C 0. H c ' - Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 m a rti. c+- aC E > o a p 0 0 O O 6. N Q 2 Q V Q V * 14 L ❑ c .� E n a ' O N c mo ~ Q c was O J Q7 Z c m v a c 'a O Q : GO 4� E N E i� ,zr W C SG rl r 1 3 O N tLo i� r-O fi m E o 0 0 o Ln -� m m * Ln UJ u `( LJ O X a O iO E Lj- c X co eCL L6 LL � - V 1..1� O v5 o ,N V} Ul i 00 v -M O ? —_ � i U > O I aJ -0 'j U -0 a n s } � < u O ra v LnO E u u ur 1� m ', ° r O `° Ln E ,ci vl O m U Z = L7 � C � ❑ V1 n- r- 6] iJ O ro O Q L1 uLo V D O Z ai ui of w E E E (u Qj • E } N N V �N w U ` '! O O O O N ry m m O 'n a H uu aLO E m 0 m mQ a �= g Q c E o - .Q +•� CL VJ . - L �+ I [1 u.. Q1 � i L O N o W E @i w 0 0 cn v rl c a m— y �O Z O �� Ln W z g a w -- N �'1 T ai O Z W ~ E Q .} * .. v L N j 0 Q U a O U a cr v _ O V cc w W- 4- L o O 7 _ - J 5 LL a O E Ln a -0 p v mc� _ 2: Ln ❑ ❑ ❑ ❑ T rev Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road Mocksville, NC 27028 Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Report Date: 2/23/2022 Date Sample Rcvd: 1/12/2022 Vector Attraction Reduction / Aerobically Digested Sludge (30 Day Test) Meritech Work Order # 01122254 Sample: Reidsville Composite 1/12/22 Total Solids Volatile Solids % Volatile Solids Week 1 1.77 1.33 0.751 Week 2 1.45 1.07 0.754 Week 3 1.70 1.27 0.748 Week 4 1.64 1.23 0.750 Week 5 1.40 1.06 0.753 Van Kleek Reduction (%): -0.82 I hereby certify that I have reviewed and approve these data. Pass or Pail Pass Laboratory Representative 642 TaYnco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 U�o 0 0 In � tn 00 w a' CL gm 0 0 o in tf, kn 104) I U `" U 6 � kn Vl 0❑ CE o O U U � q r' N 'd d co 0 0 tn N V.1 r!1 W a o CIO U o O o > O O II c p, c II �I U AI U o t V-1� a �ro �C9 o �q to F 0 N U b Q-I 7r v N D aGF2 U o � O O bIn V"t V'1 � G CDa z 00 w a w � ro N m ci V N N kn EQ is M1• M1• fl Q O C m d; O. J _ /1 ❑ 3 p C .� u n o. Q � E E CL' E E o 07 p a� E u E o ao � r � CY d C ` rl rl O -4 [-I c Y H 00 v ar to n o m m m G/l .. s m E O O rc z 0-U- Lu a M1. 2Ll A y LL O V of 00 Qj L a l` .0 L w ai U N >` -O O Q �. - �F C 61 Y i MV V V Q) L 3 ✓1 00 '� O .. O Y W ^cu 6J 'a •7 U -6 b CC (a Y 0 m a cQ U Lf1 C sue+ O _ Q M N u u _ C w rr, ao—' o a z 0 rc c = v c o ° # u c Y ❑ �n c L a Qr o v o a ` 0 U d d a 0 c v v ni a r r V1 • 00 N V N C w T N O (V Cp y 0 0 N O i m m a � E y n L rn m ¢ n 0 m rn o ti cotc v O Q a \ o U r o a.75 b a L o W z HW O O m c V rB 1 m 4 o O a u 'm t L Ul W 5 0 z V) v w m Z r y } O W 6 ` m s o a NU LD O Q a _ Q] r N L Vi C C G (� O 1yco Q Ci s I cc lee ai J 0 O } i w U a CL o ro ❑ ❑ ❑ ❑ ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Reidsville WQ Permit Number: WQ0002376 WWTP Name: Reidsville WWTP NPDES Number: NCO024881 Monitoring Period: From 4/l/2022 To 6/30/2022 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ Alt B (Alk Treatment) ❑ Alt. C (Prior Testing) ❑ A1t.D (No Prior Test) ❑ Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost 131 Heat Drying ❑ Heat Treatment ❑ Thermophilic Beta Ray ❑ 1 Gamma Ray ❑ Pasteurization ❑ Class B: jAlt. (1) Fecal Density 0 I Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ 1 Air Drying ❑ 1 Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g y Number o Excee- dences Frequency of Analysis Sample Type Analytical Tech -pique Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN CFU 11834 40722 173410 col/g 0 Quarterly G SM9222D 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.1 (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) 10 Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ lAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) 0 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the uirements. "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Ralph Potter - Interim Wastewater Superintendent and Pretreatment Coordinator Brent Collins; Director of Technical Services Preparers Name andTitle(type or print) Land Applier Name and Title (if applicable)(type or print) L,Jj4 // �0����c.L//- Feb 10, 2023 �) ¢ 4; //__- Ralph .Potter,Jr(Feb10,202307:38EST) ,C1��' rs'l�"" 1/2/2023 Signature of Preparer* Date Signature of Land Applier (if applicable) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) Date DENR FORM PVRF 02T (12/2006) Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 Page 1 Contact: Brent Collins Report Date: 4/14/2022 Client: EMA Resources, Inc 7SS YadkinviIle Road Mocksville, IBC 27028 Date Sample Rcvd: 4/6/2022 Meritech Work Order # 04062232 Sample: Reidsville 1 Grab 4/6/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.72 % 4/7/22 0-100 % SM 2540B Fecal Coliform (Sludge) 98,837 col/g dry wt 4/6/22 3788 col/g dry wt SM 9222D Meritech Work Order # 04062233 Sample: Reidsville 2 Grab 4/6/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.73 % 4/7/22 0-100 % SM 2S40B Fecal Coliform (Sludge) 173,410 col/g dry wt 4/6/22 3788 col/g dry wt SM 9222D Meritech Work Order # 04062234 Sample: Reidsville 3 Grab 4/6/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.68 % 4/7/22 0-100 % SM 2540B Fecal Coliform (Sludge) 172,619 col/g dry wt 4/6/22 3788 col/g dry wt SM 9222D Meritech Work Order # 04062235 Sample: Reidsville 4 Grab 4/6/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.72 % 4/7/22 0-100 % SM 2540B Fecal Coliform (Sludge) 20,930 col/g dry wt 4/6/22 3788 col/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 1pa wrR Page 2 Contact: Brent Collins Report Date: 4/14/2022 Client: EMA Resources, Inc 75S YadkinviIle Road Mocksville, NC 27028 Date Sample Rcvd: 4/6/2022 Meritech Work Order # 04062236 Sample: Reidsville 5 Grab 4/6/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.80 % 4/7/22 0-100 % SM 2540B Fecal Coliform (Sludge) 14,444 col/g dry wt 4/6/22 3788 col/g dry wt SM 9222D Meritech Work Order # 04062237 Sample: Reidsville 6 Grab 4/6/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.69 % 4/7/22 0-100 % SM 2540E Fecal Coliform (Sludge) 11,834 col/g dry wt 4/6/22 3788 cal/g drywt SM 9222D Meritech Work Order # 04062238 Sample: Reidsville 7 Grab 4/6/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.71 % 4/7/22 0-100 % SM 2540E Fecal Coliform (Sludge) 17,544 col/g dry wt 4/6/22 3788 col/g dry wt SM 9222D I hereby certify that I have reviewed and approve these data. y -(YZp, r q. C)tN L) Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)3424748 fax.(336)342-1522 O m O c a El � E o en m Y a CL �' � E a Q c rn } H z O U V a i rl ci 3 0 ci rl C H } I9 C!S LIl Y v � � m m ,; \ o � Ln C � CL n Ly w D i y Ln 1 C N v ...1 r� m co N (N N a� ra un c p U = c VJ a1-4 N Ln Q Ln O L' a '_ E H'i 7 Lr1 L u f, 2? in Y m V cc V d V 2 VI Q _ �IO V O C N p ro U r Z t� }, L V C ]G ~ ❑ N o ai C E E O U Q Q a � ocu c o ti a a � C a I— 7 y a -� c V,n 00 N N W u a W a m m Ln E Rf Q 0- m o L ° _ o V X •i C/] .r M tt OL _ n 7 L o W uj a o V) g h M U ro o O W U �' W QJ N r� T' 1n h L [6 > s 0 Lt,l H Q a a b _ o V z � s p �`y 1 u1i CL- � LL - El 11 o .AN Pip" - Contact: Brent Collins CIient: EMA Resources, Inc 755 YadkinviIle Road Mocksville, IBC 27028 Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 Report Date: 5/18/2022 Date Sample Rcvd: 4/6/2022 Vector Attraction Reduction / Aerobically Digested Sludge 30 Day Test Meritech Work Order # 04062231 Sample: Reidsville Composite 4/6/22 Total Solids Volatile Solids % Volatile Solids Week 1 0.950 0.720 0.759 Week 2 0.870 0.670 0.777 Week 3 0.880 0.670 0.758 Week 4 0.920 0.670 0.732 Week 5 0.840 0.620 0.745 Van Kleek Reduction (%): 7.31 I hereby certify that I have reviewed and approve these data. Pass or Fail Pass Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 0 p kn r OEM r U I 'a r � O u ca w mw=m a p O n kn v H � ca a G U U C O �z U y � a Cf) En -a c N C 4 V T U� U z z A Ulo a F 2 Cm n N z z 0 0. n Len 9� N U G MW U 0 FA ad ul Awe u U c N M1- � � 9• Y Y 'o a� = O O ° + 0 rcu Q CL 7t ~ a -C 0 u L yV O p_p ui ai E ti N O J O v u u i 0 w ` ci r-I C F 3 �9 `C1 Ln Ln .n n n u L^ 1 I C� ` m y m m m V mi m V) Ln I I + it f ❑ w N SC 0 J t m p O t m Z Q LL w a a cr XIf r o ' o - v 3 00 CJ �- Q] col QJ N CO) ol U V = ci Q) ' a r 0 C Q) Q T Q _0 Q Y i C /1 N a) 'a o Q °° c Ln �..) C C Ln U L p G F + v ? Ln o a, M °' 4 w r, � oa = m Qj a v m O cn 4 cc cc s CI = 0 en p x V \ L1 C C n. ti r ❑ 0 n a Q1 y Q l7 V r�Cv O 0 0 Y E E Qa i as V co9 r s yNj e~,i w U _ n E c a m m u E ` a Ln m l F E E O m m m o CJ Q O ai u m u a)U dD v E 0 Ln a E Ln v eu C) p m v o m c U N m S d O ids O s U 'ro �` �' o �► ci vl LLI LZ 0 Z E u G1 (_} `J E 01 w a)Qj X k a w H K C C O V K `-' O a LU �n O a � v ,� O - ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Reidsville WQ Permit Number: WQ0002376 WWTP Name: Reidsville WWTP NPDES Number: NCO024881 Monitoring Period: From 7/l/2022 To 9/30/2022 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ Alt B (Alk Treatment) ❑ Alt. C (Prior Testing) ❑ A1t.D (No Prior Test) ❑ Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost 131 Heat Drying ❑ Heat Treatment ❑ Thermophilic Beta Ray ❑ 1 Gamma Ray ❑ Pasteurization ❑ Class B: jAlt. (1) Fecal Density 0 I Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ 1 Air Drying ❑ 1 Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g y Number o Excee- dences Frequency of Analysis Sample Type Analytical Tech -pique Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN CFU 689 727 804 col/g 0 Quarterly G SM9222D 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.1 (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) 10 Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ lAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) 0 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the uirements. "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Ralph Potter - Interim Wastewater Superintendent and Pretreatment Coordinator Brent Collins; Director of Technical Services Preparer Name and 7Title (type or print) Land Applier Name and Title (if applicable)(type or print) Lao /. 2LZ2Z�7/- Feb 10, 2023 ') fi 4/ l!._ • 1/2/2023 Ralph . Potter, Jr (Feh 10, 2023 07:38 EST) �(j�" rs'�"" Signature of Preparer* Date Signature of Land Applier (if applicable) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) Date DENR FORM PVRF 02T (12/2006) Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road Mocksville, NC 27028 Page 1 Report Date: 7/13/2022 Date Sample Rcvd: 7/5/2022 Meritech Work Order # 07052209 Sample: Reidsville 1 Grab 7/5/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.30 % 7/6/22 0-100 % SM 2540B Fecal Coliform (Sludge) <699 CFU/g dry wt 7/5/22 699 CFU/g dry wt SM 9222D Meritech Work Order # 07052210 Sample: Reidsville 2 Grab 7/5/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.24 % 7/6/22 0-100 % SM 2540B Fecal Coliform (Sludge) <733 CFU/g dry wt 7/5/22 733 CFU/g dry wt SM 9222D Meritech Work Order # 07052211 Sample: Reidsville 3 Grab 7/5/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.13 % 7/6/22 0-100 % SM 2540B Fecal Coliform (Sludge) 804 CFU/g dry wt 7/5/22 130 CFU/g dry wt SM 9222D Meritech Work Order # 070S2212 Sample: Reidsville 4 Grab 7/5/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.30 % 7/6/22 0-100 % SM 2540B Fecal Coliform (Sludge) 699 CFU/g dry wt 7/5/22 130 CFU/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Amp Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road Page 2 Report Date: 7/13/2022 Mocksville, NC 27028 Date Sample Rcvd: 7/5/2022 Meritech Work Order # 07052213 Sample: Reidsville 5 Grab 7/5/22 Parameters Result Analysis Date Reporting limit Method % Total Solids 1.32 % 7/6/22 0-100 % SM 2540B Fecal Coliform (Sludge) 689 CFU/g dry wt 7/5/22 130 CFU/g dry wt SM 9222D Meritech Work Order # 07052214 Parameters % Total Solids Fecal Coliform (Sludge) Meritech Work Order # 070S2215 Parameters % Total Solids Fecal Coliform (Sludge) Sample: Reidsville 6 Grab Result 1.20 % <758 CFU/g dry wt Result Analysis Date 7/6/22 7/5/22 Sample: Reidsville 7 Grab 1.27 % <716 CFU/g dry wt Analysis Date 7/6/22 7/5/22 7/5/22 Reporting Limit Method 0-100 % SM 2540B 758 CFU/g dry wt SM 9222D 7/5/22 Reporting Limit Method 0-100 % SM 2540B 716 CFU/g dry wt SM 9222D I hereby certify' that I have reviewed and approve these data. O-HaMpcJL) Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fxc(336)342-1522 m a rl- Y Y o o v❑ r O O () V C Q fu �o y d C y p ❑ l o N .lf--• 'o a a a1 ti `—� u E y m n E E av N i cu J c °- .F b ci iv l ao r, Ln bj yj a d co �. ❑ n w � c ro Z rl U- w d rl M1- + ci w co cn o LL L QLn O a Q N 00 w d o V J r Q} i CD T t r\ L N _a �, (!I a cu U m a 7ai O LM V N U a s Q c p ru a� V � w r, m 3 ro I2 o m I a L c �o o r- u ui �+ O z M1. N c c 0 H G �� U Q Q a V Q c ci ai ni E E E E N LM ~ a f c ra } V � N � LLJ U " cl) yy O N 0 m O Ln in Q m Q E Q LO Lb OC M U O � O o �. O Q m U bb Eo o V J o x y •� i e� ~ a m L J Lm Q }, ~ N O 05 QJ o W z ~ 1 o N 41 Z (V \ C o O c, L N W b E s U LU S z E N �x N 'n .9 r � G m � a1 O - CO cr- t2 LA N U m E O O U a°Jc w ._ _ / 41 tea= u >7 b O 4- w > o a E Ln o �w VG C L Q 0 N ❑ ❑ ❑ ❑ Meritech, Inc, Environmental Laboratory Laboratory Certification No.165 Contact: Brent Collins Client: EMA Resources, Inc 755 Xadkinville Road Mocksville, NC 27028 Report Date: 8/8/2022 Date Sample Rcvd: 7/5/2022 Vector Attraction Reduction / Aerobically Digested Sludge (30 Day Test) Meritech Work Order # 07052208 Sample: Reidsville Composite 7/5/22 Total Solids Volatile Solids % Volatile Solids Week 1 1.23 0.920 0.743 Week 2 1.19 0.890 0.743 Week 3 1.10 0.830 0.749 Week 4 0.990 0.740 0.745 Week 5 1.07 0.810 0.755 Van Meek Reduction (%): -6.23 I hereby certify thatl have reviewed and approve these data. �� _ f Q Wan a k' Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 Id U a 0 i �; z n. n 2F: �, ro c N a) CL 0 cd cd 00 N \ � Q c Q j \ 2 / " n m m -0 � ¥ � y2 ) ; \ / � & & § ) Cd m m ) ~ . y � � y � \ / _ c / / 2 = 0 ) CD { 0. � � \ ! 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CC 0 O O ` � v Cl) D -- w_ ^ O � A L V ; hc N D D D G L •� C L `r C C � C a L � _ A yp r y 4 W W H W _ A s .c o 0 0 M o Ln 4.1 C 1I'1 0 UT in o O 3t D G C G o 0 •C C `Tr "C G Fri •C G w�L+ '� •C on L= C e0 bn to :eo W V M W J Ln LU Q 0. z 0 u u 0 v rl ri c Ln Ln - r� n O enm m m a u r w O a_ LL LU b d 00 N _ -0 O Ln "IU Q — Z O O 4J Y — � iC Nf Lnv0 Ln ui L U Q m 1E O O a N O Q * a, ro a FA 0 c O N fl } Q c m c Y 3 Q N a � � h N C 0 T (U °' X ru h ' d C O }r Ln rlWl � O L1.1 C a Q ;:,. a � O :2 V { c � Z3 C] 3 �• m � q1 � to _ v O v c c O at Q u O r y' V N V y� n N Ln CoeC Cc m N O � m — Q 6 0 m m La U in U a� Qj °J t 'L -� V Q ra LL a, o W EU � UJ O O Z _ o O N ui w Q u z rn w U j 2 ~ 0 _ C � � U fm O Ui V cu .cu ►1 1 tw E_ _E E tlo 7 111 Y ~ GO d; y y� y E o a $ 11 J on E O 4 0 d X '6 L L 41 7 Li c: 0 ❑ ❑ ❑ ❑ ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules) Facility Name: City of Reidsville WQ Permit Number: WQ0002376 WWTP Name: Reidsville WWTP NPDES Number: NCO024881 Monitoring Period: From 10/1/2022 To 12/31/2022 Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed: Class A: Alt. A (time/temp) ❑ Alt B (Alk Treatment) ❑ Alt. C (Prior Testing) ❑ A1t.D (No Prior Test) ❑ Process to Further Reduce Pathogengs ❑ If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens": Compost 131 Heat Drying ❑ Heat Treatment ❑ Thermophilic Beta Ray ❑ 1 Gamma Ray ❑ Pasteurization ❑ Class B: jAlt. (1) Fecal Density 0 I Alt. (2) Process to Significantly Reduce Pathogens ❑ If applicable to alternative performed (Class B only) indicate "Process to Significantly Reduce Pathogens": Lime Stabilization ❑ 1 Air Drying ❑ 1 Composting ❑ jAerobic Digestion ❑ Anaerobic Digestion ❑ If applicable to alternative performed (Class A or Class B) complete the following monitoring data: Parameter Allowable Level in Sludge Pathogen Density g y Number o Excee- dences Frequency of Analysis Sample Type Analytical Tech-nique Minimum Geo. Mean Maximum Units Fecal Coliform 2 x 10 to the 6th power per gram of total solids MPN CFU 5005 8614 15994 col/g 0 Quarterly G SM9222D 1000 mpn per gram of total solid (dry weight) Salmonella bacteria (in lieu of fecal coliform) 3 MPN per 4 grams total solid (dry weight) Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed: Alt.1 (VS reduction) ❑ Alt. 2 (40-day bench) ❑ Alt. 3 (30-day bench) 10 Alt. 4 (Spec. Oz uptake) ❑ Alt. 5 (14-Day Aerobic) ❑ Alt. 6 (Alk. Stabilization ❑ Alt 7 (Drying - Stable) ❑ lAlt. 8 (Drying - Unstable) ❑ Alt. 9 (Injection) ❑ Alt. 10 (Incorporation) ❑ No vector attraction reduction alternatives were performed ❑ CERTIFICATION STATEMENT (please check the appropriate statement) 0 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have been met." ❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if you check this statement attach an explanation why you have not met one or both of the uirements. "This determination has been made under my direction and supervision in accordance with the system designed to ensure that qualified personnel properly gather and evaluate the information used to determine that the pathogen and vector attraction reduction requirements have been met. I am aware that there are significant penalties for false certification including fine and imprisonment." Ralph Potter - Interim Wastewater Superintendent and Pretreatment Coordinator Brent Collins; Director of Technical Services Preparer Name and -T7itle (type or print) Land Applier Name and Title (if applicable)(type or print) L7" � �btt2�,% Feb 10, 2023 ') fi 1/2/2023 Ralph . Potter, Jr (Feb 10, 2023 07:38 EST) ;G�"' Signature of Preparer* Date Signature of Land Applier (if applicable) *Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26) Date DENR FORM PVRF 02T (12/2006) Meritech, Inc. Environmental Laboratory Laboratory Certification No. 165 !p Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road Mocksville, NC 27028 Page 1 Report Date: 10/13/2022 Date Sample Rcvd: 10/3/2022 Meritech Work Order # 10032230 Sample: Reidsville 1 Grab Parameters Result Analysis Date Reporting Limit % TotaI Solids 1.08 % 10/4/22 0-100 % Fecal Coliform (Sludge) 5,051 CFU/g dry wt 10/3/22 130 CFU/g dry wt Meritech Work Order # 10032231 Parameters Sample: Reidsville 2 Grab Result Analysis Date % Total Solids 1.04 % 10/4/22 Fecal Coliform (Sludge) 15,994 CFU/g dry wt 10/3/22 Meritech Work Order # 10032232 Sample: Reidsville 3 Grab Parameters Result Analysis Date % Total Solids 1.12 % 10/4/22 Fecal Coliform (Sludge) 7,305 CFU/g dry wt 10/3/22 Meritech Work Order # 10032233 Sample: Reidsville 4 Grab Parameters Result Analysis Date % Total Solids 1.08 % 10/4/22 Fecal Coliform (Sludge) 10,101 CFU/g drywt 10/3/22 10/3/22 Method SM 2540B SM 9222D 10/3/22 Reporting Limit Method 0-100 % SM 2540B 130 CFU/gdry wt SM 9222D 10/3/22 Reporting Limit Method 0-100 % SM 2540B 130 CFU/g dry wt SM 9222D 10/3/22 Reporting Limit Method 0-100 % SM 2540B 130 CFU/g dry wt SM 9222D 642 Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Contact: Brent Collins Client: EMA Resources, Inc 755 Yadkinville Road Mocksville, NC 27028 Page 2 Report Date: 10/13/2022 Date Sample Rcvd: 10/3/2022 Meritech Work Order # Parameters % Total Solids Fecal Coliform (Sludge) 10032234 Sample: Reidsville 5 Grab Result Analysis Date 1.08 % 10/4/22 10,101 CFU/g dry wt 10/3/22 Reporting Limit 0-100 % 130 CFU/g dry wt 10/3/22 Method SM 2540B SM 9222D Meritech Work Order # 10032235 Sample: Reidsville 6 Grab 10/3/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.09 % 10/4/22 0-100 % SM 2540B Fecal Coliform (Sludge) 5,005 CFU/g dry wt 10/3/22 130 CFU/g dry wt SM 9222D Meritech Work Order # 10032236 Sample: Reidsville 7 Grab 10/3/22 Parameters Result Analysis Date Reporting Limit Method % Total Solids 1.09 % 10/4/22 0-100 % SM 2540B Fecal CoIiform (Sludge) 11,676 CFU/g dry wt 10/3/22 130 CFU/g dry wt SM 9222D I hereby certify that I have reviewed and approve these data. Laboratory Representative 642 Tamco Road, Reidsville, North Carolina 27320 te1.(336)3424748 fax.(336)342-1522 O c u 3 P CN1 m � � N Ln n n a �o Lo cn rn m m `o 1 Ul C Y w ❑ p x d W p Z a LL a a • N w h N E Q N O Q m rn - s U 0 M rmn R 0 Vy d LL 41 a W ra Fm W O S sp Z N 0 � 'L V) W O z U > w w ~ O N -a V v E 0 1- E w W � GJ � 0 Ln !a q vl- .I I A I L y w N C a N E E N z Y m m 6 c as a G E E 0 Ln 4` V) Q) L O n QS l- O X D 4-1 - j LL O � '— zn Meritech, Inc. Environmental Laboratory Laboratory Certification No.165 Contact: Brent Collins Client: EMA Resources, Inc 755 YadkinvTe Road Mocksville, NBC 27028 Report Date: 11/8/2022 Date Sample Rcvd: 10/3/2022 Vector Attraction Reduction Aerobically Digested Sludge 30 Day Test Meritech Work Ord r # 100 2237 Sample: Reidsville Composite 10/3/22 To al Solids Volatile Solids n Volatile Solids Week 1 0.650 0.480 0.738 Week 2 0.700 0.510 0.730 Week 3 0.650 0.470 0.723 Week 4 0.590 0.420 0.712 Week 5 0.530 0.380 0.721 Van Kleek Reduction C% : 8.2 I hereby certify that 1 have revi�wed and approve these data. d�L Ll, Laboratory Representative Tamco Road, Reidsville, North Carolina 27320 tel.(336)342-4748 fax.(336)342-1522 I U H w U �� c oZir U 'o f l U c o c h C i inLei t C C w 'rmi n C C y INN I Q � � a O � U e O 0 0 0 0 a o c O � 't7 a U U o a O Vl O O V5 1!"t co O U r b U � 0 O W N GA Id u Q Q c� o 8 C, � � V / N � r � 00 91. v } ❑❑ L � � o 0 W � � W E L a N w L3 rv, M , Vl� ` O 3 O11,5 3 , a C Q tn tr o tr L p C tn q o tn C C C C CD 60 t-ibD aw it tq r tr C9 'L .G ;p a2 � W ,C u R aJ ai C M CO3� v J � � m .a o a q . a o q q o Ull O a � R O � O a ,,. 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L.L 0 Page 1 of 1 Report No: 23-003-0514 Account No: 46245 Advisor: EMA Resources Inc 755 Yadkinville Road Mocksville NC 27028 Waypo'10 t ANALYTICAL Client: Daisy Purgason 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: RC11 Date Received:01/03/2023 Date of Report: 01/04/2023 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I CEC BS % Ca % Mg % ESP Na 23654 01 MIN 1.6 6.1 0.7 18 11 35 31 0 0 43 43 30 5.0 86 60 24 1.0 0.1 Comment Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc. Page 1 of 1 Report No: 23-003-0513 Account No: 46245 Advisor: EMA Resources Inc 755 Yadkinville Road Mocksville NC 27028 Waypo'10 t ANALYTICAL Client: Iris Sharpe 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: RC11 Date Received:01/03/2023 Date of Report: 01/04/2023 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I CEC BS % Ca % Mg % ESP Na 23652 02 MIN 1.2 4.9 1.8 26 33 60 38 0 0 68 68 25 4.0 56 33 18 0.9 0 Comment Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL008066 kSi l"14'4+;4, Client: Lawrence McCollum Advisor: Brent Collins Predictive 434 Truman Rd EMA Resources Inc °± f' Reidsville, NC 27320 755 Yadkinville Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County : Rockingham _1 Links to Helpful Information Sampled: 09/26/2022 Received: 10/10/2022 Completed: 10/20/2022 Farm: RC12 Client ID: 289332 Advisor ID: 405413 Sample ID: 00001 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.9 120-200 0 90 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.32 1.07 7.5 75 1.9 5.5 121 23 52 22 82 144 103 330 330 125 0.1 1 North Carolina Tai wLv Truk f and Ct wmisskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY22-SL034059 kSi l"14'4+;4, Client: Lawrence McCollum Advisor: Brent Collins Predictive 434 Truman Rd EMA Resources Inc °± f' Reidsville, NC 27320 755 Yadkinville Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County : Rockingham _ Links to Helpful Information Sampled: Received: 05/16/2022 Completed: 05/23/2022 Farm: RC12 Client ID: 289332 Advisor ID: 405413 Sample ID: 0002A Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 80 0 20 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.13 1.13 6.9 83 1.2 6.0 84 31 51 29 15 118 88 43 43 43 0.1 1 Sample ID: 0002B Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 20 30 0 20 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.27 1.00 5.8 74 1.5 5.9 51 60 46 23 21 163 115 98 98 56 0.0 North Carolina Tai wLv Truk f and Ct wmisskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY22-SL032572 k5i I"14'4+;4, Client: Bennett Farm Advisor: Brent Collins Predictive 313 Bennett Farm Road EMA Resources Inc °± f' Stokesdale, NC 27357 755 Yadkinville Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County : Rockingham _1 Links to Helpful Information Sampled: Received: 04/20/2022 Completed: 05/03/2022 Farm: RC 15 Client ID: 530291 Advisor ID: 405413 Sample ID: 00001 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 80 80 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 80 80 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.81 0.98 8.1 86 1.2 6.1 26 29 54 30 35 185 127 127 297 297 68 0.1 1 North Carolina Tcbwim Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL008064 k5i I"14'4+;4, Client: William Mary Stanley Advisor: Brent Collins Predictive 381 King Carter Rd EMA Resources Inc °± f' Reidsville, NC 27320 755 Yadkinville Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County : Rockingham _1 Links to Helpful Information Sampled: Received: 10/10/2022 Completed: 10/20/2022 Farm: RC019 Client ID: 427989 Advisor ID: 405413 Sample ID: 00003 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 90 100 0 20 pH$ 0 0 0 Note: 12 Note: $ 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.41 1.07 8.4 92 0.6 6.8 21 22 59 32 24 67 45 41 41 48 0.1 1 North Carolina Tai wLm Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL008052 kSi l"14'4+;4, Client: Donald Lovelace Advisor: Brent Collins Predictive 3575 NC Hwy 150 EMA Resources Inc °± f' Reidsville, NC 27320 755 Yadkinville Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County : Rockingham _1 Links to Helpful Information Sampled: 10/05/2022 Received: 10/10/2022 Completed: 10/20/2022 Farm: RC41 Client ID: 535610 Advisor ID: 405413 Sample ID: 00002 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 0 60 0 0 pH$ 0 0 0 Note: 12 Note: $ 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.22 0.96 21.6 95 1.2 6.8 247 38 67 27 47 149 95 467 467 339 0.4 2 Sample ID: 00003 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 80 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.27 1.07 9.8 87 1.2 6.3 135 30 72 13 42 504 315 168 168 158 0.1 1 North Carolina Tcbwiv Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL008052 Donald Lovelace Page 2 of 3 Sample ID: 00004 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Fescue/OGrass/Tim, M 0.0 120-200 0 10 0 0 pH$ 0 0 0 Note: 12 Note: $ 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.18 1.07 11.8 90 1.2 6.5 172 71 69 18 65 346 217 248 248 210 0.4 3 Sample ID: 0005X Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.5 120-200 0 30 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.36 1.06 9.6 81 1.8 5.8 137 59 61 17 49 363 235 232 232 156 0.3 3 Page 1 of 1 Report No: 23-003-0516 Account No: 46245 Advisor: EMA Resources Inc 755 Yadkinville Road Mocksville NC 27028 Waypo'10 t ANALYTICAL Client: Lofton Lovelace 7621 Whitepine Road, Richmond, VA 23237 Main 804-743-9401 ° Fax 804-271-6446 www.waypointanalytical.com Farm: RC41 Date Received:01/03/2023 Date of Report: 01/04/2023 Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I CEC BS % Ca % Mg % ESP Na 23656 01 MIN 1.1 6.7 0.7 40 15 6 256 0 0 75 75 130 14.6 95 63 30 1.4 0.2 Comment Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3 North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc. NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL008065 k5i I"14'4+; 4 L Client: Thomas / Tommy Carter Advisor: Brent Collins Predictive 381 King Carter Rd EMA Resources Inc °± f' Reidsville, NC 27320 755 Yadkinville Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County : Rockingham _1 Links to Helpful Information Sampled: 09/12/2022 Received: 10/10/2022 Completed: 10/20/2022 Farm: RC119 Client ID: 480518 Advisor ID: 405413 Sample ID: 00009 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 50 0 20 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.51 1.18 7.8 85 1.2 6.2 102 47 61 21 25 329 211 182 182 108 0.1 1 Sample ID: 00005 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.5 120-200 0 20 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.56 1.04 10.8 82 1.9 5.8 424 66 66 13 71 239 160 594 594 258 0.1 1 North Carolina Tai wLm Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL008065 Thomas / Tommy Carter Page 2 of 3 Sample ID: 00010 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 60 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.71 1.21 6.3 82 1.2 6.0 106 38 53 25 86 716 446 148 148 87 0.0 NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY22-SL032583 k5i I"14'4+; 4 L Client: Thomas / Tommy Carter Advisor: Brent Collins Predictive 381 King Carter Rd EMA Resources Inc °± f' Reidsville, NC 27320 755 Yadkinville Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County : Rockingham _1 Links to Helpful Information Sampled: Received: 04/20/2022 Completed: 05/03/2022 Farm: RC119 Client ID: 480518 Advisor ID: 405413 Sample ID: 00009 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 40 0 0 0 0 0 0 Note: 12 2- Fescue/OGrass/Tim, M 0.0 120-200 0 40 0 0 0 0 0 0 Note: 12 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.51 0.96 10.9 90 1.0 6.4 150 48 65 24 33 238 154 154 226 226 154 0.1 1 North Carolina Tcbwim Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY22-SL029472 k5i I"14'4+;4, Client: State of NC Advisor: Brent Collins Predictive 1612 Crutchfield Rd EMA Resources Inc °± f' Reidsville, NC 27320 755 Yadkinville Rd �- Soil Report Mehlich-3 Extraction Mocksville, NC 27028 Sampled County : Rockingham _1 Links to Helpful Information Sampled: Received: 03/17/2022 Completed: 03/30/2022 Farm: RC126 Client ID: 442976 Advisor ID: 405413 Sample ID: 00002 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 0 70 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.27 1.05 6.6 81 1.3 5.9 163 32 60 18 44 242 162 198 198 133 0.1 2 Sample ID: 00005 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1 -Small Grain (SG) 0.0 80-100 0 90 0 0 0 0 0 0 Note: 3 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.36 0.94 10.6 90 1.0 6.5 136 26 74 15 39 302 184 263 263 154 0.1 1 North Carolina Tai wLm Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL008055 k5i I"14'4+;4 Client: Dennis Williams Advisor: Predictive 140 Andy Trail Reidsville, NC 27320 �- Soil Report Mehlich-3 Extraction Sampled County : Rockingham _1 Links to Helpful Information Sampled: 10/05/2022 Received: 10/10/2022 Completed: 10/20/2022 Farm: RC128 Client ID: 441122 Advisor ID: Sample ID: 00001 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.6 120-200 0 100 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.27 1.08 8.7 79 1.8 5.7 65 22 50 28 41 173 121 151 151 122 0.1 1 Sample ID: 00002 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 90 30 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-AI2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.18 1.10 9.0 89 1.0 6.5 21 57 54 31 47 734 450 77 77 ill 0.1 1 North Carolina Tcbwim Truk f and Ctwinlsskm Reprogramming of the laboratory -information -management system that makes this report possible is being funded through a grant from the North Carolina Tobacco Trust Fund Commission. Thank you for using agronomic services to manage nutrients and safeguard environmental quality. - Steve Troxler, Commissioner of Agriculture NCDA&CS Agronomic Division Phone: (919) 733-2655 Website: www.ncagr.gov/agronomi/ Report No. FY23-SL008055 Dennis Williams Page 2 of 3 Sample ID: 00003 Recommendations: Lime Nutrients (lb/acre) More Crop (tons/acre) N P2O5 K2O Mg S Mn Zn Cu B Information Lime History: 1-Fescue/OGrass/Tim, M 0.0 120-200 100 40 0 0 0 0 0 0 Note: 12 2 - 0.0 Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]: Soil Class: Mineral HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg% S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I Na ESP SS-1 NO3-N 0.13 0.99 9.8 89 1.1 6.4 18 53 50 36 32 237 153 108 108 63 0.1 1 Signature Pages Final Audit Report Created: 2023-02-07 By: Brent Collins (brent.collins@emaresourcesinc.com) Status: Signed Transaction ID: CBJCHBCAABAA5L1-TOsTggmdzlt2OsflNOdmb5cb4wF8k "Signature Pages" History Document created by Brent Collins (brent.collins@emaresourcesinc.com) 2023-02-07 - 1:37:00 PM GMT- IP address: 206.85.202.26 P-► Document emailed to rpotter@ci.reidsvi Ile. nc.us for signature 2023-02-07 - 1:44:56 PM GMT Email viewed by rpotter@ci.reidsville.nc.us 2023-02-10 - 12:37:15 PM GMT- IP address: 12.234.212.82 2023-02-10 dp Signer rpotter@ci.reidsvi Ile. nc.us entered name at signing as Ralph H. Potter, Jr 2023-02-10 - 12:38:36 PM GMT- IP address: 12.234.212.82 Gip Document e-signed by Ralph H. Potter, Jr (rpotter@ci.reidsvi Ile. nc.us) Signature Date: 2023-02-10 - 12:38:38 PM GMT - Time Source: server- IP address: 12.234.212.82 Q Agreement completed. 2023-02-10 - 12:38:38 PM GMT 0 Adobe Acrobat Sign Pages from 2022 WQ0002376 Final Audit Report Reidsville Annual Report - Created: 2023-02-10 By: Brent Collins(brent.collins@emaresourcesinc.com) Status: Signed Transaction ID: CBJCHBCAABAAja6XvwVSCAvjNPdbbA6gjJiO08ni-Nxb 2023-02-10 "Pages from 2022 Reidsville Annual Report - WQ0002376" Histo ry Document created by Brent Collins(brent.collins@emaresourcesinc.com) 2023-02-10 - 5:42:45 PM GMT- IP address: 206.85.202.26 77+ Document emailed to swoodard@ci.reidsville.nc.us for signature 2023-02-10 - 5:43:07 PM GMT Email viewed by swoodard@ci.reidsville.nc.us 2023-02-10 - 9:24:01 PM GMT- IP address: 12.234.212.82 b Signer swoodard@ci.reidsville.nc.us entered name at signing as Summer Woodard 2023-02-10 - 9:24:17 PM GMT- IP address: 12.234.212.82 CSr, Document e-signed by Summer Woodard (swoodard@ci.reidsville.nc.us) Signature Date: 2023-02-10 - 9:24:19 PM GMT - Time Source: server- IP address: 12.234.212.82 0 Agreement completed. 2023-02-10 - 9:24:19 PM GMT U Adobe Acrobat Sign