WQ0010583_2022 Residual Annual Report_20230228 (2)

Initial Review
Reviewer
Nathaniel.Thornburg
Is this submittal an application? (Excluding additional information.) *
Yes No
If not an application what is the submittal type?* Annual Report
Residual Annual Report
Additional Information
Other
Annual Report Year* 2022
Permit Number (IR) * WQ0010583
Applicant/Permittee Davie County
Email Notifications
Does this need review by the hydrogeologist? * Yes U No
Regional Office Winston-Salem
CO Reviewer
Admin Reviewer

Submittal Form
Project Contact Information
Please provide information on the person to be contacted by NDB Staff regarding electronic submittal, confirmation of receipt, and other correspondence.
Name* Brent Collins
Email Address*
[e-mail]
Project Information
.........................
Application/Document Type*
New (Fee Required)
Modification - Major (Fee Required)
Renewal with Major Modification (Fee
Required)
Annual Report
Additional Information
Other
Phone Number*
336-399-3646
Modification - Minor
Renewal
GW-59, NDMR, NDMLR, NDAR-1,
N DAR-2
Residual Annual Report
Change of Ownership
We no longer accept these monitoring reports through this portal. Please click on the link below and it will take you to the correct form.
https://edoes.deq.nc.gov/Forms/NonDischarge_Monitoring_Report
Permit Type:*
Wastewater Irrigation
High -Rate Infiltration
Other Wastewater
Reclaimed Water
Closed -Loop Recycle
Residuals
Single -Family Residence Wastewater
Other
Irrigation
Permit Number:*
WQ00010583
Has Current Existing permit number
Applicant/Permittee Address*
123 S. Main St., Mocksville, NC 27028
Facility Name*
Davie County Class B Residuals Program
Please provide comments/notes on your current submittal below.
At this time, paper copies are no longer required. If you have any questions about what is required, please contact Nathaniel Thornburg
at [e-mail].
Please attach all information required or requested for this submittal to be reviewed here.
(Application Form, Engineering Plans, Specifications, Calculations, Etc.)
2022 Davie County Water System Annual Report -
12.55MB
WQ0010583.pdf
Upload only 1 PDF document (less than 250 MB). Multiple documents must be combined into one PDF file unless file is larger
than upload limit.
* By checking this box, I acknowledge that I understand the application will not be accepted for pre -review until the fee (if required) has
been received by the Non -Discharge Branch. Application fees must be submitted by check or money order and made payable to the
North Carolina Department of Environmental Quality (NCDEQ). I also confirm that the uploaded document is a single PDF with all parts
of the application in correct order (as specified by the application).
Mail payment to:
NCDEQ — Division of Water Resources
Attn: Non -Discharge Branch
1617 Mail Service Center
Raleigh, NC 27699-1617
Signature
�r�rrt�ot�ly r
Submission Date 2/28/2023

February 28, 2023
DENR/Water Quality Section
Non -Discharge Compliance Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Re: 2022 Annual Report — Davie County Water System
Treatment and Land Application of Residuals
Permit No. WQ0010583
Dear Sir or Madam:
Enclosed is the 2022 Annual Report for the above referenced land application permit.
During 2022 EMA Resources, Inc. land applied 721.24 dry tons of wastewater residuals
to 114.41 acres of private farmland. Please contact Brent Collins - Director of Technical
Services if you have any further questions regarding this report.
Sincerely,
Z.-e4:241-
Brent Collins
Director of Technical Services
brent.collins&emaresourcesinc.com
Phone [phone] — Fax [phone]
755 Yadkinville Rd — Mocksville, NC 27028

--Resources, Inc.
Davie County Water System
2022 Annual Report
Residuals Land Application
Permit No. WQ0010583
Prepared By:
EMA Resources, Inc.
Phone [phone] — Fax [phone]
755 Yadkinville Rd — Mocksville, NC 27028

ANNUAL LAND APPLICATION CERTIFICATION FORM
WQ Permit#: WQ0010583 County: Davie Year:
2022
Facility Name (as shown on permit):
Land Application Operator:
Davie County Water System
EMA Resources Inc.
Phone: [phone]
Land application of residuals as allowed by the permit occurred during the past calendar year?
0 Yes ❑ No - If No, skip Part A, and Part B and proceed to Part C. Also, If residuals were
generated but not land applied, please attach an explanation on how the residuals were handled.
Part A - Residuals Application Summary:
Total number of application fields in the permit:
23
Total number of fields utilized for land application during the year:
6
Total amount of dry tons applied during the year for all application sites:
721.24
Total number of acres utilizes for land application during the year:
114.41
Part B - Annual Compiance Statement:
Facility was compliant during calendar year 2022 with all conditions of the land application permit
(including but not limited to items 1-13 below) issued by the Division of Water Quality. ® Yes 0 No
If no please, provide a written description why the facility was not compliant, the dates, and explain corrective action
taken.
1) Only residuals approved for this permit were applied to the permitted sites.
2) Soil pH was adjusted as specified in the permit and lime was applied (if needed) to achieve a soil pH of at least 6.0 or the
limit specified in the permit.
3) Annual soils analysis were performed on each site receiving residuals during the past calendar year and three (3) copies of
laboratory results are attached.
4) Annual TCLP analysis (if required) was performed and three (3) copies of certified laboratory results are attached.
5) All other monitoring was performed in accordance with the permit and reported during the year as required and three (3)
copies of certified laboratory results are attached.
6) The facility did not exceed any of the Pollutant Concentration Limits in 15A NCAC 02T .1105(a) or the Pollutant Loading
Rates in 15A NCAC 02T .1105(b) (applicable to 40 CFR Part 503 regulated facilities).
7) All general requirements in as specified in the Land Application Permit were complied with (applicable to 40 CFR Part
503 regulated facilities).
8) All monitoring and reporting requirements in 15A NCAC 02T .1111 were complied with (applicable to 40 CFR Part 503
regulated facilities).
9) All operations and maintenance requirements in the permit were complied with or, in the case of a deviation, prior
authorization was received from the Division of Water Quality.
10) No contravention of Ground Water Quality Standards occurred at a monitoring well or explanations of violations are
attached to include appropriate actions and remediations.
11) Vegetative cover was maintained and proper crop management was performed on each site receing residuals, as specified
in the permit.
12) No runoff of residuals from the application sites onto adjacent property or nearby surface waters has occurred.
13) All buffer requirements as specified on the permit were maintained during each application of residuals.
Part C - Certification:
"I certify, under penalty of law, that the above information is, to the best of my knowledge and belief, true, accurate,
and complete. I am aware that there are significant penalties for submitting false information, including the possibility
of fines and imprisonment for knowing violations."
Johnny Lambert - Utilities Director
Permittee Name and Title (type or print)
Timothy L Srm (Feb 6, 2023 10:15 EST)
Feb 6, 2023
,7oLLr LaIWbvt
Johnny Lam ert (Feb 6, 202311:55 EST)
Signature of Permittee
Feb 6, 2023
Date
2/6/2023
Signature of Preparer* Date Signature of Land Applier Date
(if different from Permittee) (if different from Permittee and Preparer)
* Preparer is defined in 40 CFR Part 503.9 (r) and 15A NCAC 02T. 1102 (26) DENR FORM ACF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM
Please note that your permit may contain additional parameters to be analyzed. The parameters can be reported in FORM RSSF - B
WQ Permit Number:
Facility Name:
Residual Source WQ # or
NPDES #:
WWTP Name:
Residual AnAvsk Data
WQ0010583
Davie County Water Systems
NCO024872
Cooleemee WWTP
Laboratory:
1)
2)
3)
4)
5)
Waypoint Analytical
Parameter
(mg/kg)
Conc.
Limit
(mg/ka
Sample or Composite Date
Digester
3/16/22
Basin
4/20/22
Basin
5/4/22
Basin
12/29/22
Percent Solids (%)
NA
3.57
9.34
6.55
3.53
Arsenic
75
51.4
6.53
34.9
6.86
Cadmium
85
1.61
0.527
0.509
0.571
Copper
4,300
542
97.4
130
158
Chromium
NA
37.2
45.9
505
42.6
Lead
840
47.8
23.8
51.7
26.9
Mercury
57
2.71
0.0712
0.104
0.197
Molybdenum
75
6.31
2.63
3.92
3.86
Nickel
420
26.8
18.3
38.6
22.4
Selenium
100
8.89
3.44
4.92
1670
Zinc
7,500
1800
299
440
623
Total Phosphorus
NA
17300
3440
6780
5740
TKN
NA
45300
11300
10200
19900
Ammonia -Nitrogen
NA
3560
2530
4280
2370
Nitrate and Nitrite
NA
136
58.1
73.5
138
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed
to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant
penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
z
`11a9i101 Feb 6 2023
rmorhYsm�FeE,
Signature of Preparer *
Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM RSSF (12/2006)

ANNUAL RESIDUAL SAMPLING SUMMARY FORM - B
Report all sampling analysis results for parameters not listed in FORM RSSF that are part of the WQ permit or were analyzed for over the past
calendar year. Use additional forms as needed.
WQ Permit Number:
WQ0010583
Facility Name: Davie County Water Systems
Residual Source
NPDES # or WQ#:
WWTP Name:
Residual Analvsis Data
NCO024872
Cooleemee WWTP
Laboratory: 1) Waypoint Analytical
2)
3)
4)
5)
Parameter
(mg/kg)
Sample or Composite Date
Digester
3/16/22
Basin
4/20/22
Basin
5/4/22
Basin
12/29/22
Aluminum
22600
32800
77700
25800
Calcium
13000
3270
5740
4970
Magnesium
2730
2120
3680
1610
pH
6.7
7.5
7.1
7.1
Potassium
2810
1530
2980
1440
Sodium
2500
618
1330
1670
PAN
14438
3954
3990
6582
SAR
0.98
0.63
0.86
0.99
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system
designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am aware that there are
significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations."
224g 4, , Fml?h
TimothyLSm (Feb6,2aTh 31a15ESr
Signature of Preparer *
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
Feb 6, 2023
Date
DENR FORM RSSF - B (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Davie County Water System Total Dry Tons Applied (Annual): 114.14
Permit #: WQ0010583 Cation Exchange Capacity (non 503 only):
Operator: Roger Spillman Owner: Roger Spillman Predominant Soil Series: CeB2
Acres Used: 18 Acres Permitted: 18 Site #: NC-DVO08 Field #: 4
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
M
Com-
posite
Date
BMW
Non
on
OEM
Eman
no
MEMO
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
6.34
Arsenic
0.263
1 0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.263
Cadmium
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
1.442
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.442
Chromium
3.493
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.493
Lead
0.479
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.479
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.042
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.042
denum
Nickel
0.361
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.361
Selenium
0.053
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.053
Zinc
4.686
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.686
Total
Phos-
64.805
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
64.805
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
1/24/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Davie County Water System
Land Owner: Roger Spillman
Operator: Roger Spillman
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0010583 Field #
Annual Dry Tons Applied: 114.14 Site #
Predominant Soil Series: CeB2
Crop 1 Max. PAN:
156
Crop 2 Name:
NC-DVO08
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
18
18
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
A lied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
��
F
o
,•d
TKN
mg/kg
Z
;
o 5
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
4/29/22
143000
7.945
2.632
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
20.908
NA
Fescue
4/30/22
201500
7.945
3.709
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
29.461
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
TOTALS:
01
344500
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
50.369
1 0.000
Lime Applied
Annuallbs/acre
0.263
0.007
1.442
3.493
0.479
0.001
0.042
0.361
0.053
4.686
64.805
Date
lbs/ac
Prior Years Cumulative lbs/ac
5.461
1.112
112.751
3.178
43.493
0.07
2.704
13.222
5.188
349.165
Current Cumulative lbs/ac
5.724
1.119
114.193
6.671
43.972
0.071
2.746
13.583
5.241
353.851
Permitted C. P. L. R.****
36
34
1 1338
1
1 267
1 15
1
374
1 89
1 2498
Permit PAN Limit 1st/2nd Crop
1 156
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
Z-e *Application Method: S - Surface, IN - Injection, INC - Incorporation
1/24/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Davie County Water System Total Dry Tons Applied (Annual): 120.60
Permit #: WQ0010583 Cation Exchange Capacity (non 503 only):
Operator: Roger Spillman Owner: Roger Spillman Predominant Soil Series: MrC2
Acres Used: 18 Acres Permitted: 18 Site #: NC-DVO08 Field #: 5
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
No
son
on
OEM
EMBEEM
MEMO
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
6.70
Arsenic
0.278
1 0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.278
Cadmium
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
1.524
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.524
Chromium
3.691
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.691
Lead
0.506
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.506
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.044
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.044
denum
Nickel
0.381
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.381
Selenium
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.056
Zinc
4.951
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
4.951
Total
Phos-
68.474
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
68.474
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
1/24/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Davie County Water System
Land Owner: Roger Spillman
Operator: Roger Spillman
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0010583 Field #
Annual Dry Tons Applied: 120.60 Site #
Predominant Soil Series: MrC2
Crop 1 Max. PAN:
118
Crop 2 Name:
NC-DVO08
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
18
18
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
A lied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
��
F
o
,•d
TKN
mg/kg
Z
;
o 5
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
4/27/22
52000
7.945
0.957
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
7.603
NA
Fescue
4/28/22
234000
7.945
4.307
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
34.213
NA
Fescue
4/29/22
78000
7.945
1.436
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
11.404
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
TOTALS:
01
364000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
53.220
o.000
Lime Applied
Annuallbs/acre
0.278
0.007
1.524
3.691
0.506
0.001
0.044
0.381
0.056
4.951
68.474
Date
lbs/ac
Prior Years Cumulative lbs/ac
1.593
1.029
108.641
0.882
42.251
0.064
2.61
12.235
5.211
333.409
Current Cumulative lbs/ac
1.871
1.036
110.165
4.573
42.757
0.065
2.654
12.616
5.267
338.360
Permitted C. P. L. R.****
36
34
1 1338
1
267
1 15
374
1 89
1 2498
Permit PAN Limit 1st/2nd Crop
118
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
Z-e *Application Method: S - Surface, IN - Injection, INC - Incorporation
1/24/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Davie County Water System Total Dry Tons Applied (Annual): 193.82
Permit #: WQ0010583 Cation Exchange Capacity (non 503 only):
Operator: Roger Spillman Owner: Roger Spillman Predominant Soil Series: MrB2
Acres Used: 20 Acres Permitted: 20 Site #: NC-DVO08 Field #: 6
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
No
son
on
OEM
EMBEEM
MEMO
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
9.69
Arsenic
0.401
1 0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.401
Cadmium
0.010
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
Copper
2.204
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.204
Chromium
5.339
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.339
Lead
0.732
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.732
Mercury
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
Molyb-
0.063
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.063
denum
Nickel
0.551
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.551
Selenium
0.081
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.081
Zinc
7.162
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
7.162
Total
Phos-
99.042
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
99.042
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
1/24/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Davie County Water System
Land Owner: Roger Spillman
Operator: Roger Spillman
Crop 1 Name:
Fescue -Pasture
WQ Permit #: WQ0010583 Field #
Annual Dry Tons Applied: 193.82 Site #
Predominant Soil Series: MrB2
Crop 1 Max. PAN:
141
Crop 2 Name:
NC-DVO08
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
20
20
Q
Volume applied
enter one Solids/
)
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
A lied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
��
F
o
,•d
TKN
mg/kg
Z
;
o 5
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
4/26/22
247000
7.945
4.092
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
32.502
NA
Fescue
4/27/22
149500
7.945
2.477
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
19.672
NA
Fescue
5/l/22
188500
7.945
3.123
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
24.804
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
TOTALS:
01
585000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
76.979
o.000
Lime Applied
Annuallbs/acre
0.401
0.010
2.204
5.339
0.732
0.002
0.063
0.551
0.081
7.162
99.042
Date
lbs/ac
Prior Years Cumulative lbs/ac
5.363
1.074
110.985
2.355
42.915
0.063
2.659
12.908
5.217
341.358
Current Cumulative lbs/ac
5.764
1.084
113.189
7.694
43.647
0.065
2.722
13.459
5.298
348.520
Permitted C. P. L. R.****
36
34
1 1338
1
267
15
374
1 89
1 2498
Permit PAN Limit 1st/2nd Crop
141
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
Z-e *Application Method: S - Surface, IN - Injection, INC - Incorporation
1/24/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Davie County Water System Total Dry Tons Applied (Annual): 167.96
Permit #: WQ0010583 Cation Exchange Capacity (non 503 only):
Operator: Roger Spillman Owner: Roger Spillman Predominant Soil Series: MrB2
Acres Used: 23.67 Acres Permitted: 23.67 Site #: NC-DVO08 Field #: 9
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
M
Com-
posite
Date
BMW
Non
on
OEM
Eman
no
MEMO
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
7.10
Arsenic
0.294
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.294
Cadmium
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
1.614
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.614
Chromium
3.909
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.909
Lead
0.536
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.536
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.046
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.046
denum
Nickel
0.404
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.000
0.404
Selenium
0.059
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.059
Zinc
5.244
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5.244
Total
Phos-
72.521
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
72.521
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
1/24/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Davie County Water System
Land Owner: Roger Spillman
Operator: Roger Spillman
Crop 1 Name: Rye Grass -Hay
WQ Permit #: WQ0010583 Field #
Annual Dry Tons Applied: 167.96 Site #
Predominant Soil Series: MrB2
Crop 1 Max. PAN:
136
Crop 2 Name:
NC-DVO08
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
23.67
23.67
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
A lied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
��
F
o
,•d
,
TKN
mg/kg
Z
;
o 5
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
5/16/22
78000
7.945
1.092
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
8.672
NA
Rye
5/17/22
123500
7.945
1.729
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
13.731
NA
Rye
5/18/22
182000
7.945
2.547
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
20.236
NA
Rye
5/19/22
123500
7.945
1.729
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
13.731
NA
Rye
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
0.000
0.000
TOTALS:
01
507000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
56.371
o.000
Lime Applied
Annuallbs/acre
0.294
0.007
1.614
3.909
0.536
0.001
0.046
0.404
0.059
5.244
72.521
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.329
0.919
7.109
1.8
1.496
0.009
0.471
1.197
2.205
8.064
Current Cumulative lbs/ac
0.623
0.926
8.723
5.709
2.032
0.010
0.517
1.601
2.264
13.308
Permitted C. P. L. R.****
36
34
1 1338
1
267
15
374
1 89
1 2498
Permit PAN Limit 1st/2nd Crop
136
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
Z-e *Application Method: S - Surface, IN - Injection, INC - Incorporation
1/24/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Davie County Water System Total Dry Tons Applied (Annual): 80.51
Permit #: WQ0010583 Cation Exchange Capacity (non 503 only):
Operator: Thomas Whitaker Owner: Thomas Whitaker Predominant Soil Series: ToB2
Acres Used: 15.75 Acres Permitted: 15.75 Site #: NC-DVO09 Field #: 2
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
No
son
on
OEM
EMBEEM
MEMO
Total
Phos-
phorus
Annual Heavv Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7
8
9
10
11
12
DT/Ac./
App.
Event
5.11
Arsenic
0.212
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.212
Cadmium
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
Copper
1.162
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.162
Chromium
2.816
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.816
Lead
0.386
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.386
Mercury
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
Molyb-
0.033
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.033
denum
Nickel
0.291
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
1 0.000
0.291
Selenium
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.043
Zinc
3.778
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.778
Total
Phos-
52.245
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
52.245
horus
"I certity, under penalty of law, that this document was prepared under my direction or supervision in accordance with
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
;d-e 1/24/2023
Signature of Land Applier
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Davie County Water System
Land Owner: Thomas Whitaker
Operator: Thomas Whitaker
Crop 1 Name: Fescue -Hay
WQ Permit #: WQ0010583 Field #
Annual Dry Tons Applied: 80.51 Site #
Predominant Soil Series: ToB2
Crop 1 Max. PAN:
188
Crop 2 Name:
NC-DV009
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
15.75
15.75
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
A lied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
��
F
o
,•d
,
TKN
mg/kg
Z
;
o 5
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
4/28/22
22500
7.945
0.473
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
3.760
NA
Fescue
4/29/22
27000
7.945
0.568
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
4.512
NA
Fescue
4/30/22
31500
7.945
0.663
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
5.264
NA
Fescue
5/2/22
27000
7.945
0.568
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
4.512
NA
Fescue
5/3/22
31500
7.945
0.663
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
5.264
NA
Fescue
5/4/22
36000
7.945
0.757
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
6.015
NA
Fescue
5/5/22
27000
7.945
0.568
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
4.512
NA
Fescue
5/6/22
40500
7.945
0.852
Davie County
Dry
<.5"
S
0.5
0.3
10750
3405
65.8
6.767
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
TOTALS:
01
243000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
40.604
0.000
Lime Applied
Annuallbs/acre
0.212
0.005
1.162
2.816
0.386
0.001
0.033
0.291
0.043
3.778
52.245
Date
lbs/ac
Prior Years Cumulative lbs/ac
0
0
0
0
0
0
0
0
0
0
Current Cumulative lbs/ac
0.212
0.005
1.162
2.816
0.386
0.001
0.033
0.291
0.043
3.778
Permitted C. P. L. R.****
36
34
1 1338
1
267
1 15
374
1 89
1 2498
Permit PAN Limit 1st/2nd Crop
1 188
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
Z-e *Application Method: S - Surface, IN - Injection, INC - Incorporation
1/24/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

ANNUAL METALS FIELD LOADING SUMMARY FORM*
Attach this form to the corresponding Field Loading Summary Form to be submitted in Annual Report
Facility Name: Davie County Water System Total Dry Tons Applied (Annual): 44.21
Permit #: WQ0010583 Cation Exchange Capacity (non 503 only):
Operator: Adam Taylor Owner: James Taylor Predominant Soil Series: ApB
Acres Used: 18.99 Acres Permitted: 18.99 Site #: NC-R001 Field #: 1
Residual Analysis Data (Heavy Metals and Total Phosphorus use mg/kg, % Solids use Raw Percent #):
Com-
posite
Date
Total
Phos-
phorus
Annual Heavy Metal Field Loadings (Calculated in lbs/acre):
Total
11
2 1
3
4
5j
6j
7j
81
9
10
11 1
12
DT/Ac./
App.
.fir
Event
2.33
Arsenic
0.239
1 0.000
0.000
1 0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.000
1 0.239
Cadmium
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
Copper
2.524
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.524
Chromium
0.173
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.173
Lead
0.223
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.223
Mercury
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
Molyb-
0.029
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.029
denum
Nickel
0.125
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1 0.000
0.000
0.125
Selenium
0.041
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.041
Zinc
8.381
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
8.381
Total
Phos-
80.549
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
80.549
horus
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with
a system designed to assure that qualified personnel properly gathered and evaluated the information submitted. I am
aware that there are significant penalties for submitting false information, including the possibility of fines and
imprisonment for knowing violations".
Signature of Land Applier
1/24/2023
Date
DENR FORM MFLSF (12/2006)

ANNUAL LAND APPLICATION FIELD SUMMARY FORM
PLEASE MAKE A COPY OF THIS BLANK FORM TO BE COMPLETED AND SUBMITTED FOR EACH FIELD APPLIED ON
PLACE A "N/A" IN A BLANK OR BOX WHEN NOT APPLICABLE.
Facility Name: Davie County Water System
Land Owner: James Taylor
Operator: Adam Taylor
Crop 1 Name: Fescue - Hay
WQ Permit #: WQ0010583 Field #
Annual Dry Tons Applied: 44.21 Site #
Predominant Soil Series: ApB
Crop 1 Max. PAN: 237 Crop 2 Name:
NC-RO01
Acres Utilized:
Acres Permitted:
Cation Exchange Capacity (non 503):
Crop 2 Max. PAN:
18.99
18.99
Q
Volume applied
enter one Solids/
( )
Liquid
Cu. Yds Gallons
o
/o
Solids
Volume
A lied per
pp p
Acre
(Dry Tons/Ac)
Residual Sources
(NPDES #, WQ#,
Fert., Animal
Waste, etc)
Soil
Cond.
(may'
Wet,
Moist)
Precip.
Past 24
Ms.
inches
a
��
F
o
,•d
,
TKN
mg/kg
Z
;
o 5
M o
mg/kg
Nitrate
and
Nitrite
mg/kg
PAN Applied
( lbs/acre)
Name of Crop Type
Receiving Residual
Application
Crop 1
Crop 2
Crop 1
Crop 2
3/15/22
4500
3.57
0.035
Davie County
Dry
<.5"
S
0.5
0.3
45300
3560
136
1.019
NA
Fescue
3/16/22
31500
3.57
0.247
Davie County
Dry
<.5"
S
0.5
0.3
45300
3560
136
7.131
NA
Fescue
3/21/22
67500
3.57
0.529
Davie County
Dry
<.5"
S
0.5
0.3
45300
3560
136
15.280
NA
Fescue
3/22/22
49500
3.57
0.388
Davie County
Dry
<.5"
S
0.5
0.3
45300
3560
136
11.205
NA
Fescue
3/28/22
58500
3.57
0.459
Davie County
Dry
<.5"
S
0.5
0.3
45300
3560
136
13.243
NA
Fescue
3/29/22
63000
3.57
0.494
Davie County
Dry
<.5"
S
0.5
0.3
45300
3560
136
14.261
NA
Fescue
3/30/22
22500
3.57
0.176
Davie County
Dry
<.5"
S
0.5
0.3
45300
3560
136
5.093
NA
Fescue
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Residuals Applications totals on FORM FSF supp ( attach FORM FSF supp to this form):
TOTALS:
01
297000
As
Cd
Cu
Cr
Pb
Hg
Mo
Ni
Se
Zn
P
67.231
o.000
Lime Applied
Annuallbs/acre
0.239
0.007
2.524
0.173
0.223
0.013
0.029
0.125
0.041
8.381
80.549
Date
lbs/ac
Prior Years Cumulative lbs/ac
0.036
0.003
0.047
0.036
0.027
0.005
0.021
0.018
0.049
0.144
Current Cumulative lbs/ac
0.275
0.010
2.571
0.209
0.250
0.018
0.050
0.143
0.090
8.525
Permitted C. P. L. R.****
36
34
1 1338
1
267
1 15
1
374
1 89
1 2498
Permit PAN Limit 1st/2nd Crop
237
"I certify, under penalty of law, that this document was prepared under my direction or supervision in accordance with a system designed to assure that
qualified personnel properly gathered and evaluated the information submitted. I am aware that there are significant penalties for submitting false
information, including the possibility of fines and imprisonment for knowing violations."
Z-e *Application Method: S - Surface, IN - Injection, INC - Incorporation
1/24/2023 **Volatilization Rate: Surface - 0.5, Injection/Incorporation - 1.0
Signature of Land Applier Date *** Mineralization Rates: Compost -0.1, anaerobially digested -0.2,
aerobically digested -0.3, raw sludge -0.4
****C.P.L.R.: Cumulative Pollutant Loading Rate
DENR FORM FSF (12/2006)

Waypointo
ANALYTICAL
3/28/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-077-0020
Client Project Description: Cooleemee, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 3/18/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-077-0020
Page 2 of 8

Waypoint
ANALYTICAL
Report Number: 22-077-0020
Client Project Description: Cooleemee, NC
Lab No Client Sample ID
92406 Cooleemee
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Matrix Date Collected Date Received
Solids 03/16/2022 06:30 03/18/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Cooleemee, NC
Lab Report Number: 22-077-0020
Date: 3/25/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 98890 (Mull Bottom)
Analyte: Iron
QC Batch No: 1-606777/1-605969
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 98890 (Mull Bottom)
Analyte: Potassium
QC Batch No: 1-607078/1-605969
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 57193 (4 day composite)
Analyte: Mercury
QC Batch No: 1-606654/1-605971
The matrix spike, matrix spike duplicate and the post digestion spike were all outside of the quality control
acceptance ranges. Matrix interference is suspected
Page 4 of 8

waypANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Project Cooleemee, NC
Information :
Report Date : 03/28/2022
nReceived : 03/18/2022
C-�*�-� =
Connie Cook
Report Number : 22-077-0020
REPORT OFANALYSIS
Project
Manager
Lab No : 92406
Matrix:
Solids
Sample ID : Cooleemee
Sampled:
3/16/2022
6:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
96.4
%
1
03/22/22 17:42
FMM
SW-DRYWT
Ammonia Nitrogen
3560
mg/Kg -
dry
444
2780
1
03/25/22 08:50
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
<136
mg/Kg -
dry
136
136
1
03/22/22 14:34
ZBD
4500NO3F-2016
Organic N
41720
mg/Kg -
dry
5139
1
03/25/22 08:50
CALCULATION
pH
6.7
S.U.
1
03/25/2214:30
ADM
9045D
Total Solids
3.57
%
0.010
0.010
1
03/22/22 17:42
FMM
2540G-2011
Total Volatile Solids
63.6
%
0.010
0.010
1
03/22/22 17:42
FMM
2540G-2011
Total Kjeldahl Nitrogen
45300
mg/Kg -
dry
5140
1
03/25/22 16:04
CLP 4500NORGD-2011
Phosphorus
17300
mg/Kg -
dry
76.7
139
1
03/24/22 01:43
EAL
6010D
Aluminum
22600
mg/Kg -
dry
128
139
1
03/24/22 01:43
EAL
6010D
Arsenic
51.4
mg/Kg -
dry
6.67
13.9
1
03/24/22 01:43
EAL
6010D
Cadmium
1.613
mg/Kg -
dry
0.556
2.78
1
03/24/22 01:43
EAL
6010D
Calcium
13000
mg/Kg -
dry
1080
1390
1
03/25/22 02:08
EAL
6010D
Chromium
37.2
mg/Kg -
dry
6.56
6.94
1
03/24/22 01:43
EAL
6010D
Copper
542
mg/Kg -
dry
8.61
13.9
1
03/24/22 01:43
EAL
6010D
Iron
41700
mg/Kg -
dry
237
278
1
03/24/22 01:43
EAL
6010D
Lead
47.8
mg/Kg -
dry
5.00
8.33
1
03/24/22 01:43
EAL
6010D
Magnesium
2730
mg/Kg -
dry
71.7
139
1
03/24/22 01:43
EAL
6010D
Manganese
2380
mg/Kg -
dry
9.03
13.9
1
03/24/22 01:43
EAL
6010D
Mercury
2.71
mg/Kg -
dry
0.185
0.425
1
03/23/22 13:11
ZMT
7471A
Molybdenum
6.313
mg/Kg -
dry
3.75
6.94
1
03/24/22 01:43
EAL
6010D
Nickel
26.8
mg/Kg -
dry
3.33
6.94
1
03/24/22 01:43
EAL
6010D
Potassium
2810
mg/Kg -
dry
172
278
1
03/24/22 01:43
JTR
6010D
Qualifiers/ DF
Dilution Factor
J
Estimated value
Definitions MQL
Method Quantitation Limit
Page 5 of 8

WayP�'��'
2790 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Cooleemee, NC
Mr. Brent Collins
Report Date : 03/28/2022
755 Yadkinville Rd
Information :
Received : 03/18/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-077-0020
REPORT OFANALYSIS
Project Manager
Lab No : 92406
Matrix: Solids
Sample ID : Cooleemee
Sampled: 3/16/2022 6:30
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
<8.89
mg/Kg - dry
8.89
13.9 1 03/24/22 01:43 EAL 6010D
Sodium
2500
mg/Kg - dry
361
694 1 03/25/22 02:08 EAL 6010D
Zinc
1800
mg/Kg - dry
22.5
34.7 1 03/24/22 01:43 EAL 6010D
Sulfur
8080
mg/Kg - dry
144
278 1 03/24/22 01:43 EAL 6010D
Sodium Absorption Ratio
0.98
Ratio
0.01
0.01 1 03/24/22 01:43 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 6 of 8

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-077-0020
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: IMakayla Weaver Date & Time: 03/18/2022 09:14:33
Page 7 of 8

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Digester 3/16/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 2500 89.25 23 3.880435
Calcium 13000 464.1 20 23.205
Magnesium 2730 97.461 12 8.12175
Percent Solids 3.57
SAR 0.98
SAR =
Na+
a (Ca2+ + M;42+ )
3.88043
0.5( 23.205 2 + 8.12175 2 )

Waypointo
ANALYTICAL
5/4/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-111-0008
Client Project Description: Cooleemee, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 4/21/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-111-0008
Page 2 of 9

Waypoint
ANALYTICAL
Report Number: 22-111-0008
Client Project Description: Cooleemee, NC
Lab No Client Sample ID
95439 Davie County Basin
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Matrix Date Collected Date Received
Solids 04/20/2022 09:00 04/21/2022
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Cooleemee, NC
Lab Report Number: 22-111-0008
Date: 5/4/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 95889
Analyte: Aluminum
QC Batch No: 1-613308/1-612535
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 95889
Analyte: Arsenic
QC Batch No: 1-613308/1-612535
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 95889
Analyte: Iron
QC Batch No: 1-613308/1-612535
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 95889
Analyte: Potassium
QC Batch No: 1-613308/1-612535
The matrix spike, matrix spike duplicate and the dilution test were all outside of the quality control acceptance
ranges. Matrix interference is suspected.
Sample 95889
Analyte: Manganese
QC Batch No: 1-613308/1-612535
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 95889
Analyte: Molybdenum
QC Batch No: 1-613308/1-612535
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 95889
Analyte: Lead
QC Batch No: 1-613308/1-612535
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 95889
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Analyte: Selenium
QC Batch No: 1-613308/1-612535
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 95943 (Little Patuxent Class A)
Analyte: Mercury
QC Batch No: 1-613427/1-612896
The matrix spike, matrix spike duplicate and the post digestion spike were all outside of the quality control
acceptance ranges. Matrix interference is suspected
Page 5 of 9

waypANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Project Cooleemee, NC
Information :
Report Date : 05/04/2022
nReceived : 04/21/2022
C-�*�-� =
Connie Cook
Report Number : 22-111-0008
REPORT OFANALYSIS
Project
Manager
Lab No : 95439
Matrix:
Solids
Sample ID : Davie County Basin
Sampled:
4/20/2022
9:00
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
90.7
%
1
04/25/22 17:36
FMM
SW-DRYWT
Ammonia Nitrogen
2530
mg/Kg -
dry
172
1080
1
05/04/22 10:45
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
58.1
mg/Kg -
dry
53.3
53.3
1
04/25/22 14:40
ZBD
4500NO3F-2016
Organic N
8763
mg/Kg -
dry
266.7
537.6
1
04/28/22 16:00
CALCULATION
pH
7.5
S.U.
1
04/28/2215:20
DRS
9045D
Total Solids
9.34
%
0.010
0.010
1
04/25/22 17:36
FMM
2540G-2011
Total Volatile Solids
25.8
%
0.010
0.010
1
04/25/22 17:36
FMM
2540G-2011
Total Kjeldahl Nitrogen
11300
mg/Kg -
dry
538
1
04/28/22 16:00
CLP 4500NORGD-2011
Phosphorus
3440
mg/Kg -
dry
29.7
53.8
1
04/27/22 02:31
JTR
6010D
Aluminum
32800
mg/Kg -
dry
49.7
53.8
1
04/27/22 02:31
JTR
6010D
Arsenic
6.53
mg/Kg -
dry
2.58
5.38
1
04/27/22 18:49
JTR
6010D
Cadmium
0.5273
mg/Kg -
dry
0.215
1.08
1
04/27/22 02:31
JTR
6010D
Calcium
3270 B
mg/Kg -
dry
416
538
1
04/27/22 02:31
JTR
6010D
Chromium
45.9
mg/Kg -
dry
2.54
2.69
1
04/27/22 02:31
JTR
6010D
Copper
97.4
mg/Kg -
dry
3.33
5.38
1
04/27/22 02:31
JTR
6010D
Iron
96300
mg/Kg -
dry
91.6
108
1
04/27/22 02:31
JTR
6010D
Lead
23.8
mg/Kg -
dry
1.94
3.23
1
04/27/22 02:31
JTR
6010D
Magnesium
2120
mg/Kg -
dry
27.7
53.8
1
04/27/22 02:31
JTR
6010D
Manganese
608
mg/Kg -
dry
3.49
5.38
1
04/27/22 02:31
JTR
6010D
Mercury
<0.0712
mg/Kg -
dry
0.0712
1.63
1
04/27/22 13:54
JTR
7471A
Molybdenum
2.633
mg/Kg -
dry
1.45
2.69
1
04/27/22 02:31
JTR
6010D
Nickel
18.3
mg/Kg -
dry
1.29
2.69
1
04/27/22 02:31
JTR
6010D
Potassium
1530
mg/Kg -
dry
66.5
108
1
04/27/22 02:31
JTR
6010D
Qualifiers/ B Analyte detected in blank
DF
Dilution Factor
Definitions J Estimated value
MQL
Method Quantitation Limit
Page 6 of 9

WayP�'��'
2790 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Cooleemee, NC
Mr. Brent Collins
Report Date : 05/04/2022
755 Yadkinville Rd
Information :
Received : 04/21/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-111-0008
REPORT OFANALYSIS
Project Manager
Lab No : 95439
Matrix: Solids
Sample ID : Davie County Basin
Sampled: 4/20/2022 9:00
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
<3.44
mg/Kg - dry
3.44
5.38 1 04/27/22 18:49 JTR 6010D
Sodium
618
mg/Kg - dry
140
269 1 04/27/22 02:31 JTR 6010D
Zinc
299
mg/Kg - dry
8.71
13.4 1 04/27/22 02:31 JTR 6010D
Sulfur
1900
mg/Kg - dry
55.7
108 1 04/27/22 02:31 JTR 6010D
Sodium Absorption Ratio
0.63 B
Ratio
0.01
0.01 1 04/27/22 02:31 CALCULATION
Qualifiers/ B Analyte detected in blank
Definitions
DF Dilution Factor
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-111-0008
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT102
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: IMakayla Weaver Date & Time: 04/21/2022 10:00:26
Page 8 of 9

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Basin 4/20/22
mg/kg mg/L Equiv Weight Milli Equiv
Sodium 618 57.7212 23 2.509617
Calcium 3270 305.418 20 15.2709
Magnesium 2120 198.008 12 16.50067
Percent Solids 9.34
SAR 0.63
SAR — Na
2 (Ca2+ + Mg2- )
2.50962
0.5( 15.271 2 + 16.50067 2 )

Waypointo
ANALYTICAL
5/13/2022
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Road
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 22-125-0121
Client Project Description: Cooleemee, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 5/5/2022 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 8

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2022
Florida
State Program
- NELAP
E871157
06/30/2022
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2022
Illinois
State Program
- NELAP
200078
10/10/2022
Kentucky
State Program
80215
06/30/2022
Kentucky
State Program
KY90047
12/31/2022
Louisiana
State Program
- NELAP
LA037
12/31/2022
Louisiana
State Program
- NELAP
04015
06/30/2022
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
415
12/31/2022
Pennsylvania
State Program
- NELAP
68-03195
05/31/2022
South Carolina
State Program
84002
06/30/2022
South Carolina
State Program
84002
06/30/2022
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2022
Virginia
State Program
00106
06/30/2022
Virginia
State Program
- NELAP
460181
09/14/2022
Page 1 of 1 00001/22-125-0121
Page 2 of 8

Waypoint
ANALYTICAL
Report Number: 22-125-0121
Client Project Description: Cooleemee, NC
Lab No Client Sample ID
86758 Cooleemee Basin
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Matrix Date Collected Date Received
Solids 05/04/2022 07:45 05/05/2022
Page 3 of 8

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Cooleemee, NC
Lab Report Number: 22-125-0121
Date: 5/13/2022
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 86758 (Cooleemee Basin)
Analyte: Aluminum
QC Batch No: L616110/1-615485
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 86758 (Cooleemee Basin)
Analyte: Potassium
QC Batch No: 1-615959/1-615485
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Sample 87210 (ST22MAYO1-03-001)
Analyte: Mercury
QC Batch No: 1-615775/1-615359
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Page 4 of 8

waypANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Road
Mocksville , NC 27028
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Project Cooleemee, NC
Information :
Report Date : 05/13/2022
nReceived : 05/05/2022
C-�*�-� =
Connie Cook
Report Number : 22-125-0121
REPORT OFANALYSIS
Project
Manager
Lab No : 86758
Matrix:
Solids
Sample ID : Cooleemee Basin
Sampled:
5/4/2022
7:45
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
93.5
%
1
05/06/22 16:11
FMM
SW-DRYWT
Ammonia Nitrogen
4280
mg/Kg -
dry
246
1540
1
05/13/22 13:00
JPJ
4500NH3C-2011
Nitrate+Nitrite-N
<73.5
mg/Kg -
dry
73.5
73.5
1
05/11/22 14:32
ZBD
4500NO3F-2016
Organic N
5923
mg/Kg -
dry
381.5
769.2
1
05/10/22 15:26
CALCULATION
pH
7.1
S.U.
1
05/12/2215:54
DRS
9045D
Total Solids
6.55
%
0.010
0.010
1
05/06/22 16:11
FMM
2540G-2011
Total Volatile Solids
24.5
%
0.010
0.010
1
05/06/22 16:11
FMM
2540G-2011
Total Kjeldahl Nitrogen
10200
mg/Kg -
dry
769
1
05/10/22 15:26
CLP 4500NORGD-2011
Phosphorus
6780
mg/Kg -
dry
42.5
76.9
1
05/12/22 18:08
EAL
6010D
Aluminum
77700
mg/Kg -
dry
71.1
76.9
1
05/13/22 12:21
TJS
6010D
Arsenic
34.9
mg/Kg -
dry
3.69
7.69
1
05/12/22 18:08
EAL
6010D
Cadmium
0.5093
mg/Kg -
dry
0.308
1.54
1
05/12/22 18:08
EAL
6010D
Calcium
5740
mg/Kg -
dry
595
769
1
05/12/22 18:08
EAL
6010D
Chromium
505
mg/Kg -
dry
3.63
3.85
1
05/12/22 18:08
EAL
6010D
Copper
130
mg/Kg -
dry
4.77
7.69
1
05/12/22 18:08
EAL
6010D
Iron
73500
mg/Kg -
dry
131
154
1
05/12/22 18:08
EAL
6010D
Lead
51.7
mg/Kg -
dry
2.77
4.62
1
05/12/22 18:08
EAL
6010D
Magnesium
3680
mg/Kg -
dry
39.7
76.9
1
05/12/22 18:08
EAL
6010D
Manganese
809
mg/Kg -
dry
5.00
7.69
1
05/12/22 18:08
EAL
6010D
Mercury
0.1043
mg/Kg -
dry
0.0892
2.05
1
05/11/22 14:05
ZMT
7471A
Molybdenum
3.92
mg/Kg -
dry
2.08
3.85
1
05/12/22 18:08
EAL
6010D
Nickel
38.6
mg/Kg -
dry
1.85
3.85
1
05/12/22 18:08
EAL
6010D
Potassium
2980
mg/Kg -
dry
95.1
154
1
05/12/22 18:08
EAL
6010D
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 5 of 8

WayP�'��'
2790 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Cooleemee, NC
Mr. Brent Collins
Report Date : 05/13/2022
755 Yadkinville Road
Information :
Received : 05/05/2022
Mocksville , NC 27028
Connie Cook
Report Number : 22-125-0121
REPORT OFANALYSIS
Project Manager
Lab No : 86758
Matrix: Solids
Sample ID : Cooleemee Basin
Sampled: 5/4/2022 7:45
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
<4.92
mg/Kg - dry
4.92
7.69 1 05/12/22 18:08 EAL 6010D
Sodium
1330
mg/Kg - dry
200
385 1 05/12/22 18:08 EAL 6010D
Zinc
440
mg/Kg - dry
12.5
19.2 1 05/12/22 18:08 EAL 6010D
Sulfur
7950
mg/Kg - dry
79.7
154 1 05/12/22 18:08 EAL 6010D
Sodium Absorption Ratio
0.85
Ratio
0.01
0.01 1 05/12/22 18:08 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 6 of 8

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 22-125-0121
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT100
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
# Yes
0 No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
# Yes
0 No
Water - Sample containers properly preserved
0 Yes
0 No
N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Signature: IHannah R. Brown Date & Time: 05/05/2022 13:50:51
Page 7 of 8

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Basin 5/4/22
mg/kg mg/L
Equiv Weight Milli Equiv
Sodium
1330 87.115
23 3.787609
Calcium
5740 375.97
20 18.7985
Magnesium
3680 241.04
12 20.08667
Percent Solids
6.55
SAR
0.86
Na
SAR —
(Ca2+ + Mg2- )
2
3.78761
0.5( 18.799 2 + 20.08667 2 )

Waypointo
ANALYTICAL
1 /11 /2023
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville, NC, 27028
Ref: Analytical Testing
Lab Report Number: 23-003-0057
Client Project Description: Cooleemee, NC
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Dear Mr. Brent Collins:
Waypoint Analytical, LLC. received sample(s) on 1/3/2023 for the analyses presented in the following report.
The above referenced project has been analyzed per your instructions. The analyses were performed in
accordance with the applicable analytical method. Where the laboratory was not responsible for the sampling
stage (refer to the chain of custody) results apply to the sample as received.
The analytical data has been validated using standard quality control measures performed as required by the
analytical method. Quality Assurance, method validations, instrumentation maintenance and calibration for all
parameters (NELAP and non-NELAP) were performed in accordance with guidelines established by the USEPA
(including 40 CFR 136 Method Update Rule May 2021) and NELAC unless otherwise indicated. Any parameter
for which the laboratory is not officially NELAP accredited is indicated by a '—'symbol. These are not included in
the scope because NELAP accreditation is either not available or has not been applied for. Additional
certifications may be held/are available for parameters, where NELAP accreditation is not required or applicable.
A full list of certifications is available upon request.
Certain parameters (chlorine, pH, dissolved oxygen, sulfite...) are required to be analyzed within 15 minutes of
sampling. Usually, but not always, any field parameter analyzed at the laboratory is outside of this holding time.
Refer to sample analysis time for confirmation of holding time compliance.
The results are shown on the attached Report of Analysis(s). Results for solid matrices are reported on an as -
received basis unless otherwise indicated. This report shall not be reproduced except in full and relates only to
the samples included in this report.
Please do not hesitate to contact me or client services if you have any questions or need additional information.
Sincerely,
Connie Cook
Project Manager
Laboratory's liability in any claim relating to analyses performed shall be limited to, at laboratory's option, repeating the
analysis in question at laboratory's expense, or the refund of the charges paid for performance of said analysis.
Page 1 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 Fax [phone]
www.waypointanalytical.com
Certification Summary
Laboratory ID: WP MTN: Waypoint Analytical, LLC., Memphis, TN
State
Program
Lab ID
Expiration Date
Alabama
State Program
40750
02/28/2023
Arkansas
State Program
88-0650
02/07/2023
California
State Program
2904
06/30/2023
Florida
State Program
- NELAP
E871157
06/30/2023
Georgia
State Program
C044
02/18/2023
Georgia
State Program
04015
06/30/2023
Illinois
State Program
- NELAP
200078
10/10/2023
Kentucky
State Program
80215
06/30/2023
Kentucky
State Program
KY90047
12/31/2023
Louisiana
State Program
- NELAP
LA037
12/31/2023
Louisiana
State Program
- NELAP
04015
06/30/2023
Mississippi
State Program
MS
02/11/2023
North Carolina
State Program
47701
07/31/2023
North Carolina
State Program
415
12/31/2023
Pennsylvania
State Program
- NELAP
68-03195
05/31/2023
South Carolina
State Program
84002
06/30/2023
Tennessee
State Program
02027
02/11/2023
Texas
State Program
- NELAP
T104704180
09/30/2023
Virginia
State Program
00106
06/30/2023
Virginia
State Program
- NELAP
460181
09/14/2023
Page 1 of 1 00001/23-003-0057
Page 2 of 9

Waypoint
ANALYTICAL
Report Number: 23-003-0057
Client Project Description: Cooleemee, NC
Lab No Client Sample ID
88847 Cooleemee Basin
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Sample Summary Table
Matrix Date Collected Date Received
Solids 12/29/2022 08:30 01/03/2023
Page 3 of 9

Waypointo
ANALYTICAL
Client: EMA Resources Inc
Project: Cooleemee, NC
Lab Report Number: 23-003-0057
Date: 1 /11 /2023
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
CASE NARRATIVE
Metals Analysis Method 601 OD
Sample 88654 (BH-4, 1'-3')
QC Batch No: L657242/L656673
One or more Internal Standards are outside method acceptance criteria. Re -analysis and/or sample dilutions are
required.
Sample 88654 (BH-4, 1'-3')
Analyte: Aluminum
QC Batch No: L657436/L656673
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88654 (BH-4, 1'-3')
Analyte: Iron
QC Batch No: L657436/L656673
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88654 (BH-4, 1'-3')
Analyte: Potassium
QC Batch No: L657436/L656673
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Sample 88654 (BH-4, 1'-3')
Analyte: Magnesium
QC Batch No: L657436/L656673
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88654 (BH-4, 1'-3')
Analyte: Manganese
QC Batch No: L657436/L656673
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A dilution test
was performed and passed quality control acceptance ranges. No matrix interference is suspected.
Sample 88654 (BH-4, 1'-3')
Analyte: Lead
QC Batch No: L657436/L656673
The matrix spike and/or the matrix spike duplicate was outside quality control acceptance ranges. A post
digestion spike was performed and passed quality control acceptance ranges. No matrix interference is
suspected.
Solids Total Mercury Analysis - CVAA Method 7471A
Page 4 of 9

Waypointo
ANALYTICAL
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 0 fax [phone]
www.waypointanalytical.com
Sample 88914 (D-12 0-0.5')
Analyte: Mercury
QC Batch No: 1-657315/1-657083
The matrix spike, matrix spike duplicate and the post digestion spike were all outside of the quality control
acceptance ranges. Matrix interference is suspected
Page 5 of 9

waypANALYTICAL
46245
EMA Resources Inc
Mr. Brent Collins
755 Yadkinville Rd
Mocksville , NC 27028
2790 Whitten Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
www.waypointanalytical.com
Project Cooleemee, NC
Information :
Report Date : 01/11/2023
nReceived : 01/03/2023
C-�*�-� =
Connie Cook
Report Number : 23-003-0057
REPORT OFANALYSIS
Project
Manager
Lab No : 88847
Matrix:
Solids
Sample ID : Cooleemee Basin
Sampled:
12/29/2022
8:30
Test
Results
Units
MDL
MQL
DF
Date / Time
By
Analytical
Analyzed
Method
Moisture
96.5
%
1
01/03/23 16:01
FMM
SW-DRYWT
Ammonia Nitrogen
23703
mg/Kg -
dry
457
2860
1
01/11/23 14:00
CLP
4500NH3C-2011
Nitrate+Nitrite-N
<138
mg/Kg -
dry
138
138
1
01/09/23 14:10
ZBD
4500NO3F-2016
Organic N
175703
mg/Kg -
dry
708.6
1429
1
01/05/23 16:48
CALCULATION
pH
7.1
S.U.
1
01/11/2310:00
SAR
9045D
Total Solids
3.53
%
0.010
0.010
1
01/03/23 16:01
FMM
2540G-2011
Total Volatile Solids
37.4
%
0.010
0.010
1
01/03/23 16:01
FMM
2540G-2011
Total Kjeldahl Nitrogen
19900
mg/Kg -
dry
1430
1
01/05/23 16:48
ANH 4500NORGD-2011
Phosphorus
5740
mg/Kg -
dry
78.9
143
1
01/05/23 22:04
TJS
6010D
Aluminum
25800
mg/Kg -
dry
132
143
1
01/05/23 22:04
TJS
6010D
Arsenic
<6.86
mg/Kg -
dry
6.86
14.3
1
01/05/23 22:04
TJS
6010D
Cadmium
<0.571
mg/Kg -
dry
0.571
2.86
1
01/05/23 22:04
TJS
6010D
Calcium
4970
mg/Kg -
dry
1110
1430
1
01/05/23 22:04
TJS
6010D
Chromium
42.6
mg/Kg -
dry
6.74
7.14
1
01/05/23 22:04
TJS
6010D
Copper
158
mg/Kg -
dry
8.86
14.3
1
01/05/23 22:04
TJS
6010D
Iron
87100
mg/Kg -
dry
243
286
1
01/05/23 22:04
TJS
6010D
Lead
26.9
mg/Kg -
dry
5.14
8.57
1
01/05/23 22:04
TJS
6010D
Magnesium
1610
mg/Kg -
dry
73.7
143
1
01/05/23 22:04
TJS
6010D
Manganese
597
mg/Kg -
dry
9.29
14.3
1
01/05/23 22:04
TJS
6010D
Mercury
<0.197
mg/Kg -
dry
0.197
4.51
1
01/06/23 13:55
JTR
7471A
Molybdenum
<3.86
mg/Kg -
dry
3.86
7.14
1
01/05/23 22:04
TJS
6010D
Nickel
22.4
mg/Kg -
dry
3.43
7.14
1
01/05/23 22:04
TJS
6010D
Potassium
1440
mg/Kg -
dry
177
286
1
01/05/23 22:04
TJS
6010D
Qualifiers/ DF Dilution Factor
J
Estimated value
Definitions MQL Method Quantitation Limit
Page 6 of 9

WayP�'��'
2790 Whitten
Road, Memphis, TN 38133
Main 901.213.2400 ° Fax [phone]
ANALYTICAL
www.waypointanalyiical.com
46245
EMA Resources Inc
Project
Cooleemee, NC
Mr. Brent Collins
Report Date : 01/11/2023
755 Yadkinville Rd
Information :
Received : 01/03/2023
Mocksville , NC 27028
Connie Cook
Report Number : 23-003-0057
REPORT OFANALYSIS
Project Manager
Lab No : 88847
Matrix: Solids
Sample ID : Cooleemee Basin
Sampled: 12/29/2022 8:30
Test
Results
Units
MDL
MQL DF Date / Time By Analytical
Analyzed Method
Selenium
<9.14
mg/Kg - dry
9.14
14.3 1 01/05/23 22:04 TJS 6010D
Sodium
1670
mg/Kg - dry
371
714 1 01/05/23 22:04 TJS 6010D
Zinc
623
mg/Kg - dry
23.1
35.7 1 01/05/23 22:04 TJS 6010D
Sulfur
9770
mg/Kg - dry
148
286 1 01/05/23 22:04 TJS 6010D
Sodium Absorption Ratio
0.98
Ratio
0.01
0.01 1 01/05/23 22:04 CALCULATION
Qualifiers/ DF Dilution Factor
Definitions
J Estimated value
Page 7 of 9

s
WayPAoi nt ..(2) �79p Whitten Road,3.240 Memphis, TN 38133
21.2440
Main 901.213.240fl °Fax [phone]
N A LYT I C A L www.waypointanalytical.com
Shipment Receipt Form
Customer Number: 46245
Customer Name: EMA Resources Inc
Report Number: 23-003-0057
Shipping Method
0 Fed Ex 0 US Postal 0 Lab
0 UPS 0 Client 0 Courier
0 Other:
Thermometer ID:
IT136
Shipping container/cooler uncompromised?
* Yes
0 No
Number of coolers/boxes received
Custody seals intact on shipping container/cooler?
0 Yes
0 No
Not Present
Custody seals intact on sample bottles?
0 Yes
0 No
Not Present
Chain of Custody (COC) present?
# Yes
0 No
COC agrees with sample label(s)?
# Yes
0 No
COC properly completed
# Yes
0 No
Samples in proper containers?
# Yes
0 No
Sample containers intact?
# Yes
0 No
Sufficient sample volume for indicated test(s)?
# Yes
0 No
All samples received within holding time?
# Yes
0 No
Cooler temperature in compliance?
0 Yes
No
Cooler/Samples arrived at the laboratory on ice.
Samples were considered acceptable as cooling
process had begun.
0 Yes
No
Water - Sample containers properly preserved
Yes
0 No
0 N/A
Water - VOA vials free of headspace
0 Yes
0 No
N/A
Trip Blanks received with VOAs
0 Yes
0 No
N/A
Soil VOA method 5035 — compliance criteria met
0 Yes
0 No
0 N/A
F_ High concentration container (48 hr)
F_ High concentration pre -weighed (methanol -14 d)
F_ Low concentration EnCore samplers (48 hr)
F_ Low conc pre -weighed vials (Sod Bis -14 d)
Special precautions or instructions included? 0 Yes * No
Comments:
Sample was received outside of temperature compliance. Approval to analyze
per client.
Signature: lEmily M. Peterson Date & Time: 01/03/2023 11:38:44
Page 8 of 9

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Page 9 of 9

Basin 12/29/22
mg/kg
mg/L
Equiv Weight Milli Equiv
Sodium
1670
58.951
23 2.563087
Calcium
4970
175.441
20 8.77205
Magnesium
1610
56.833
12 4.736083
Percent Solids
3.53
SAR
0.99
SAR =
Na+
a (Ca2+ + M;42+ )
2.56309
0.5( 8.7721 2 + 4.73608 2 )

(� ace Analytical
ANALYTICAL REPORT
March 25, 2022
EMA Resources
Sample Delivery Group
Samples Received:
Project Number:
Description:
Report To:
L147264O
03/17/2022
Sludge
Mr. Brent Collins
755 Yadkinville Road
Mocksville, NC 27028
Entire Report Reviewed By
zw ��w -a
T. Alan Harvill
Project Manager
Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be
reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace
Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067and
ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided,
and as the samples are received.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1472640 03/25/22 15:26 1 of 21

TABLE OF CONTENTS
Cp: Cover Page
Tc: Table of Contents
2
Ss: Sample Summary
3
Cn: Case Narrative
4
Sr: Sample Results
5
COOLEEMCE L1472640-01
5
Qc: Quality Control Summary
7
Wet Chemistry by Method 9012 B
7
Wet Chemistry by Method 9034-9030B
8
Wet Chemistry by Method 9045D
9
Wet Chemistry by Method D93/1010A
10
Mercury by Method 7470A
11
Metals (ICP) by Method 6010D
12
Volatile Organic Compounds (GC/MS) by Method 8260D
13
Chlorinated Acid Herbicides (GC) by Method 8151A
15
Pesticides (GC) by Method 8081B
16
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
17
GI: Glossary of Terms
19
al: Accreditations & Locations
20
Sc: Sample Chain of Custody
21
ACCOUNT: PROJECT: SDG:
DATE/TIME: PAGE:
EMA Resources L1472640
03/25/22 15:26 2 of 21

COOLEEMCE L1472640-01 Waste
Method
Preparation by Method 1311
Preparation by Method 1311
Wet Chemistry by Method 9012 B
Wet Chemistry by Method 9034-9030B
Wet Chemistry by Method 9045D
Wet Chemistry by Method D93/1010A
Mercury by Method 7470A
Metals (ICP) by Method 6010D
Volatile Organic Compounds (GC/MS) by Method 8260D
Chlorinated Acid Herbicides (GC) by Method 8151A
Pesticides (GC) by Method 8081B
Semi Volatile Organic Compounds (GC/MS) by Method 8270E
SAMPLE SUMMARY
Collected by
Brent Collins
Batch
Dilution Preparation
date/time
W G 1834467
1 03/18/2 213:3 8
W G1834468
1 03/18/2210:17
WG1834187
1 03/21/22 00:21
WG1835624
1 03/22/2217:28
WG1835091
1 03/22/2213:00
WG1835433
1 03/21/22 02:00
WG1835553
1 03/21/22 08:58
WG1835821
1 03/22/22 07:57
W G1835402
1 03/21/22 15:55
WG1837165
1 03/23/22 23:25
W G18352 84
1 03/22/2212:17
WG1835281
1 03/22/2217:29
Collected date/time Received date/time
03/16/22 09:30 03/17/2210:00 C
P
Analysis
date/time
03/18/2213:38
03/18/2210:17
03/22/2217:04
03/23/22 03:29
03/22/2215:51
03/21/22 02:00
03/22/2213:29
03/23/2218:14
03/21/2215:55
03/24/2212:10
03/23/22 20:10
03/23/22 05:49
Analyst
JAV
JAV
LDT
CAT
PSN
WOS
ABL
ZSA
BMB
HMH
CCW
JNJ
Location
FC
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Fn
Mt. Juliet, TN
Mt. Juliet, TN
Mt. Juliet, TN
Fr
Mt. Juliet, TN
Mt. Juliet, TN
Rc
Mt. Juliet, TN
Mt. Juliet, TN
GI
F
RC
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1472640 03/25/22 15:26 3 of 21

CASE NARRATIVE
All sample aliquots were received at the correct temperature, in the proper containers, with the FP
appropriate preservatives, and within method specified holding times, unless qualified or notated within
the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FC
have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control
are within established criteria except where addressed in this case narrative, a non-conformance form
or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FS
knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the
quality of the data have been identified by the laboratory, and no information or data have been
knowingly withheld that would affect the quality of the data. 0
Fr
Rc
aV3� /,07 Wa GI
T. Alan Harvill [Al
Project Manager
RC
Project Narrative
All Reactive Cyanide results reported in the attached report were determined as totals using method 9012 B.
All Reactive Sulfide results reported in the attached report were determined as totals using method 9034-903013.
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1472640 03/25/22 15:26 4 of 21

SAMPLE RESULTS - 01
L1472640
COOLEEMCE
Collected date/time: 03/16/22 09:30
Preparation by Method 1311
Result Qualifier Prep
Batch
Analyte
date / time
TCLP Extraction
3/18/2022 138:04 PM
WG1834467
TCLP ZHE Extraction
- 3/18/2022 10:17:57 AM
WG1834468
Fluid
1 3/18/2022 138:04 PM
WG1834467
Initial pH
7.83 3/18/2022 138:04 PM
WG1834467
Final pH
5.32 3/18/2022 138:04 PM
WG1834467
Wet Chemistry by Method 9012 B
Result Qualifier RDL
Analyte mg/kg mg/kg
Reactive Cyanide ND 0.250
Wet Chemistry by Method 9034-9030B
Result Qualifier RDL
Analyte mg/kg mg/kg
Reactive Sulfide ND 25.0
Wet Chemistry by Method 9045D
Dilution Analysis Batch
date / time
1 03/22/202217:04 WG1834187
Dilution Analysis Batch
date / time
1 03/23/2022 03:29 WG1835624
Result Qualifier Dilution Analysis Batch
Analyte su date / time
Corrosivity by pH 7.10 T8 1 03/22/202215:51 WG1835091
Sample Narrative:
L1472640-01 WG1835091: 7.1 at 20C
Wet Chemistry by Method D93/1010A
Result
Analyte Deg. F
Ignitability DNI at170
Mercury by Method 7470A
Qualifier Dilution Analysis Batch
date / time
1 03/21/2022 02:00 WG1835433
Result Qualifier RDL Limit
Analyte mg/I mg/I mg/I
Mercury ND 0.0100 0.20
Metals (ICP) by Method 6010D
Result
Qualifier RDL
Limit
Analyte
mg/I
mg/I
mg/I
Arsenic
ND
0.100
5
Barium
0.125
0.100
100
Cadmium
ND
0.100
1
Chromium
ND
0.100
5
Lead
ND
0.100
5
Selenium
ND
0.100
1
Silver
ND
0.100
5
Volatile Organic
Compounds (GC/MS) by Method
8260D
Result
Qualifier RDL
Limit
Analyte
mg/I
mg/I
mg/I
Benzene
ND
0.0500
0.50
Carbon tetrachloride
ND
0.0500
0.50
Chlorobenzene
ND
J4 0.0500
100
Chloroform
ND
0.250
6
ACCOUNT:
PROJECT:
EMA Resources
Dilution Analysis Batch
date / time
1 03/22/202213:29 WG1835553
Dilution Analysis
Batch
date / time
1 03/23/202218:14
WG1835821
1 03/23/202218:14
WG1835821
1 03/23/202218:14
WG1835821
1 03/23/202218:14
WG1835821
1 03/23/202218:14
WG1835821
1 03/23/202218:14
WG1835821
1 03/23/202218:14
WG1835821
Dilution Analysis
Batch
date / time
1 03/21/202215:55
WG1835402
1 03/21/202215:55
WG1835402
1 03/21/202215:55
WG1835402
1 03/21/202215:55
WG1835402
SDG:
DATE/TIME: PAGE:
L1472640
03/25/22 15:26 5 of 21

COOLEEMCE SAMPLE RESULTS
Collected date/time: 03/16/22 09:30 L1472640
Volatile Organic Compounds (GC/MS) by Method 8260D
- 01
Result
Qualifier RDL Limit Dilution
Analysis
Batch
Analyte
mg/I
mg/I mg/I
date/time
1,2-Dichloroethane
ND
0.0500 0.50 1
03/21/202215:55
WG1835402
1,1-Dichloroethene
ND
0.0500 0.70 1
03/21/202215:55
WG1835402
2-Butanone (MEK)
ND
J4 0.500 200 1
03/21/202215:55
WG1835402
Tetrachloroethene
ND
0.0500 0.70 1
03/21/202215:55
WG1835402
Trichloroethene
ND
0.0500 0.50 1
03/21/202215:55
WG1835402
Vinyl chloride
ND
0.0500 0.20 1
03/21/202215:55
WG1835402
(S) Toluene-dH
116
80.0-120
031211202215.55
WG1835402
(S) 4-Bromofluorobenzene
110
77.0-126
031211202215.55
WG1835402
(S) 1,2-Dichloroethane-d4
97.5
70.0-130
031211202215.55
WG1835402
Chlorinated Acid Herbicides (GC) by Method 8151A
Result
Analyte mg/I
2,4,5-TP (Silvex) ND
2,4-D ND
(S)2,4-DichlorophenylAcetic Acid 56.2
Pesticides (GC) by Method 8081B
Qualifier RDL
mg/I
0.00200
0.00200
14.0-158
Limit
mg/I
1
10
Dilution Analysis
date/time
1 03/24/2022 12:10
1 03/24/202212:10
031241202212.10
Batch
WG1837165
WG1837165
WG1837165
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
Chlordane
ND
0.00500
0.03
1 03/23/2022 20:10
WG1835284
Endrin
ND
0.00500
0.02
1 03/23/2022 20:10
WG1835284
Heptachlor
ND
0.00500
0.0080
1 03/23/2022 20:10
WG1835284
Heptachlor epoxide
ND
0.00500
0.0080
1 03/23/2022 20:10
WG1835284
Lindane
ND
0.00500
0.40
1 03/23/2022 20:10
WG1835284
Methoxychlor
ND
0.00500
10
1 03/23/2022 20:10
WG1835284
Toxaphene
ND
0.0100
0.50
1 03/23/2022 20:10
WG1835284
(S)Decochlorobiphenyl
73.2
10.0-128
031231202220.10
WG1835284
(S) Tetrochloro-m-xylene
81.3
10.0-127
031231202220.10
WG1835284
Semi Volatile Organic Compounds
(GC/MS) by Method 8270E
Result
Qualifier RDL
Limit
Dilution Analysis
Batch
Analyte
mg/I
mg/I
mg/I
date/time
1,4-Dichlorobenzene
ND
0.100
7.50
1 03/23/2022 0549
WG1835281
2,4-Dinitrotoluene
ND
0.100
0.13
1 03/23/2022 0549
WG1835281
Hexachlorobenzene
ND
0.100
0.13
1 03/23/2022 0549
WG1835281
Hexachloro-1,3-butadiene
ND
0.100
0.50
1 03/23/2022 0549
WG1835281
Hexachloroethane
ND
0.100
3
1 03/23/2022 0549
WG1835281
Nitrobenzene
ND
0.100
2
1 03/23/2022 0549
WG1835281
Pyridine
ND
0.100
5
1 03/23/2022 0549
WG1835281
3&4-Methyl Phenol
ND
0.100
400
1 03/23/2022 0549
WG1835281
2-Methylphenol
ND
0.100
200
1 03/23/2022 0549
WG1835281
Pentachlorophenol
ND
0.100
100
1 03/23/2022 0549
WG1835281
2,4,5-Trichlorophenol
ND
0.100
400
1 03/23/2022 0549
WG1835281
2,4,6-Trichlorophenol
ND
0.100
2
1 03/23/2022 0549
WG1835281
(S) 2-Fluorophenol
35.7
10.0-120
0312312022 05.49
WG1835281
(S) Phenol-d5
23.9
10.0-120
0312312022 05.49
WG1835281
(S) Nitrobenzene-d5
60.2
10.0-127
0312312022 05.49
WG1835281
(S) 2-Fluorobiphenyl
56.9
10.0-130
0312312022 05.49
WG1835281
(S) 2,4, 6-Tribromophenol
68.0
10.0-155
0312312022 05.49
WG1835281
(S) p-Terphenyl-d14
73.6
10.0-128
0312312022 05.49
WG1835281
ACCOUNT:
PROJECT:
SDG:
DATE/TIME: PAGE:
EMA Resources
L1472640
03/25/22 15:26 6 of 21

WG1834187
QUALITY CONTROL SUMMARY
Wet Chemistry by Method 9012 B
L1472640-01
Method Blank (MB)
C p
(MB) R3772756-1 03/22/22 16:55
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/kg mg/kg mg/kg
TC
I
Reactive Cyanide U 0.0390 0.250
FS
L1472953-01 Original Sample (OS) • Duplicate (DUP)
[�n]
(OS) L1472953-01 03/22/22 17:10 • (DUP) R3772756-5 03/22/22 1711
Original Result DUP Result Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
F
Analyte mg/kg mg/kg
Reactive Cyanide ND ND 1 0.000
20
L1473220-02 Original Sample (OS) • Duplicate (DUP)
GI
(OS) L1473220-02 03/22/22 17:22 • (DUP) R3772756-6 03/22/22 17:23
Original Result DUP Result Dilution DUP RPD
DUP Qualifier DUP RPD
Limits
FAI
Analyte mg/kg mg/kg
Reactive Cyanide 0.959 1.21 1 23.5
P1 20
FSc
Laboratory Control Sample (LCS)
(LCS) R3772756-2 03/22/22 16:56
Spike Amount LCS Result LCS Rec.
Analyte mg/kg mg/kg
Reactive Cyanide 2.50 2.30 92.0
Rec. Limits LCS Qualifier
85.0-115
L1473220-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1473220-02 03/22/22 17:22 • (MS) R3772756-7 03/22/22 17:24 • (MSD) R3772756-8 03/22/22 17:25
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Cyanide 1.67 0.959 1.47 1.31 30.6 21.3 1 75.0-125 J6 J6 11.2 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1472640 03/25/22 15:26 7 of 21

WG1835624
Wet Chemistry by Method 9034-9030B
Method Blank (MB)
(MB) R3772322-1 03/23/22 03:29
MB Result MB Qualifier MB MDL
Analyte mg/kg mg/kg
Reactive Sulfide 8.03 J 7.63
Laboratory Control Sample (LCS)
(LCS) R3772822-2 03/23/22 03:29
Spike Amount LCS Result LCS Rec.
Analyte mg/kg mg/kg
Reactive Sulfide 100 76.3 76.3
QUALITY CONTROL SUMMARY
L1472640-01
MB RDL
mg/kg
25.0
Rec. Limits LCS Qualifier
53.8-124
L1472737-15 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1472737-15 03/23/22 03:29 • (MS) R3772822-3 03/23/22 03:29 • (MSD) R3772822-4 03/23/22 03:29
Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/kg mg/kg mg/kg mg/kg
Reactive Sulfide 100 ND 59.9 51.6 47.8 39.4 1 10.0-136 15.0 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1472640 03/25/22 15:26 3 of 21

WG1835091 QUALITY CONTROL SUMMARY
Wet Chemistry by Method 9045D L1472640-01
L1471704-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1471704-01 03/22/22 15:51 • (DUP) R3772697-2 03/22/22 15:51
Original Result DUP Result Dilution DUP RPD
Analyte su su
Corrosivity by pH 5.69 5.69 1 0.000
Sample Narrative:
OS: 5.69 at20.2C
DUP 5.69 at20.3C
L1473031-09 Original Sample (OS) • Duplicate (DUP)
(OS) L1473031-09 03/22/22 15:51 • (DUP) R3772697-3 03/22/22 15:51
Original Result DUP Result Dilution DUP RPD
Analyte su su
Corrosivity by pH 6.95 6.97 1 0.287
Sample Narrative:
OS: 6.95 at20.8C
DUP: 6.97 at20.7C
Laboratory Control Sample (LCS)
(LCS) R3772697-1 03/22/22 15:51
Spike Amount LCS Result LCS Rec. Rec. Limits
Analyte su su
Corrosivity by pH 10.0 9.95 99.5 99.0-101
Sample Narrative:
LCS: 9.95 at 20.2C
DUP Qualifier DUP RPD
Limits
DUP Qualifier DUP RPD
Limits
1
LCS Qualifier
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1472640 03/25/22 15:26 9 of 21

WG1835433 QUALITY CONTROL SUMMARY
Wet Chemistry by Method D93/1010A L1472640-01
L1472602-01 Original Sample (OS) • Duplicate (DUP)
(OS) L1472602-01 03/21/22 02:00 • (DUP) R3772294-3 03/21/22 02:00
Original Result DUP Result Dilution DUP RPD
Analyte Deg. F Deg. F
Ignitability 132 140 1 5.89
L1472606-02 Original Sample (OS) • Duplicate (DUP)
DUP Qualifier DUP RPD
Limits
i
10
(OS) L1472606-02 03/21/22 02:00 • (DUP) R3772294-4 03/21/22 02:00
Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD
Limits
Analyte Deg. F Deg. F
Ignitability 116 120 1 3.40 10
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3772294-1 03/21/22 02:00 • (LCSD) R3772294-2 03/21/22 02:00
Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits
Analyte Deg. F Deg. F Deg. F
Ignitability 126 130 126 103 99.8 95.6-104 3.13 10
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1472640 03/25/22 15:26 10 of 21

WG1835553 QUALITY CONTROL SUMMARY
Mercury by Method 7470A L1472640-01
Method Blank (MB)
(MB) R3772669-1 03/22/22 12:43
MB Result MB Qualifier MB MDL MB RDL
Analyte mg/I mg/I mg/I
Mercury U 0.00330 0.0100
Laboratory Control Sample (LCS)
(LCS) R3772669-2 03/22/22 12:45
Spike Amount LCS Result LCS Rec.
Analyte mg/I mg/I
Mercury 0.0300 0.0330 110
Rec. Limits LCS Qualifier
80.0-120
L1471765-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1471765-02 03/22/22 12:47 • (MS) R3772669-3 03/22/22 12:53 • (MSD) R3772669-4 03/22/22 12:55
Spike Amount
Original Result
MS Result
MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
Analyte mg/I
mg/I
mg/I
mg/I
Mercury 0.0300
ND
0.0326
0.0324 109 108 1 75.0-125 0.480 20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1472640 03/25/22 15:26 11 of 21

WG1835821
Metals (ICP) by Method 6010D
Method Blank (MB)
(MB) R3773340-1 03/23/22 1712
MB Result
MB Qualifier MB MDL
Analyte mg/I
mg/I
Arsenic U
0.0333
Barium U
0.0333
Cadmium U
0.0333
Chromium U
0.0333
Lead U
0.0333
Selenium 0.0501
J 0.0333
Silver U
0.0333
Laboratory Control Sample (LCS)
(LCS) R3773340-2 03/23/22 1715
Spike Amount
LCS Result
Analyte
mg/I
mg/I
Arsenic
10.0
8.98
Barium
10.0
9.33
Cadmium
10.0
9.07
Chromium
10.0
8.91
Lead
10.0
9.06
Selenium
10.0
9.16
Silver
2.00
1.66
LCS Rec.
89.8
93.3
90.7
89.1
90.6
91.6
83.1
QUALITY CONTROL SUMMARY
L1472640-01
MB RDL
mg/I
0.100
0.100
0.100
0.100
0.100
0.100
0.100
Rec. Limits
80.0-120
80.0-120
80.0-120
80.0-120
80.0-120
80.0-120
80.0-120
LCS Qualifier
L1471765-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1471765-02 03/23/22 17:13 • (MS) R3773340-4 03/23/22 17:23 • (MSD) R3773340-5 03/23/22 17:26
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
Arsenic
10.0
ND
9.89
9.86
98.9
98.6
Barium
10.0
0.104
9.95
9.99
98.5
98.8
Cadmium
10.0
ND
9.80
9.82
98.0
98.2
Chromium
10.0
ND
9.49
9.51
94.9
95.1
Lead
10.0
ND
9.84
9.87
98.4
98.7
Selenium
10.0
ND
10.0
10.0
99.9
99.6
Silver
2.00
ND
1.81
1.83
90.5
91.6
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
1 75.0-125
0.352
20
1 75.0-125
0.346
20
1 75.0-125
0.169
20
1 75.0-125
0.183
20
1 75.0-125
0.279
20
1 75.0-125
0.287
20
1 75.0-125
1.15
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1472640 03/25/22 15:26 12 of 21

WG1835402 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1472640-01
Method Blank (MB)
(MB) R3772224-3 03/21/22 1125
MB Result
Analyte
mg/I
Benzene
U
Carbon tetrachloride
U
Chlorobenzene
U
Chloroform
U
1,2-Dichloroethane
U
1,1-Dichloroethene
U
2-Butanone (MEK)
U
Tetrachloroethene
U
Trichloroethene
U
Vinyl chloride
U
(S) Toluene-dH
114
(S) 4-Bromofluorobenzene 107
(S) 1,2-Dichloroethane-d4 98.5
MB Qualifier MB MDL
mg/I
MB RDL
mg/I
0.0167
0.0500
0.0167
0.0500
0.0167
0.0500
0.0833
0.250
0.0167
0.0500
0.0167
0.0500
0.167
0.500
0.0167
0.0500
0.0167
0.0500
0.0167
0.0500
80.0-120
77.0-126
70.0-130
Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD)
(LCS) R3772224-1 03/21/22 09:53 • (LCSD) R3772224-2 03/21/22 10:31
Spike Amount
LCS Result
LCSD Result
LCS Rec.
LCSD Rec.
Rec. Limits
Analyte
mg/I
mg/I
mg/I
Benzene
0.250
0.249
0.261
99.6
104
70.0-123
Carbon tetrachloride
0.250
0.275
0.281
110
112
68.0-126
Chlorobenzene
0.250
0.291
0.312
116
125
80.0-121
Chloroform
0.250
0.257
0.273
103
109
73.0-120
1,2-Dichloroethane
0.250
0.245
0.268
98.0
107
70.0-128
1,1-Dichloroethene
0.250
0.242
0.287
96.8
115
71.0-124
2-Butanone (MEK)
1.25
2.07
2.00
166
160
44.0-160
Tetrachloroethene
0.250
0.262
0.275
105
110
72.0-132
Trichloroethene
0.250
0.243
0.254
97.2
102
78.0-124
Vinyl chloride
0.250
0.248
0.301
99.2
120
67.0-131
(S) Toluene-dH
110
113
80.0-120
(S) 4-Bromofluorobenzene
109
108
77.0-126
(S) 1,2-Dichloroethane-d4
103
103
70.0-130
LCS Qualifier
J4
LCSD Qualifier RPD
4.71
2.16
J4 6.97
6.04
8.97
17.0
3.44
4.84
4.43
19.3
RPD Limits
20
20
20
20
20
20
20
20
20
20
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1472640 03/25/22 15:26 13 of 21

WG1835402 QUALITY CONTROL SUMMARY
Volatile Organic Compounds (GC/MS) by Method 8260D L1472640-01
L1471504-05 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1471504-05 03/21/22 12:03 • (MS) R3772224-4 03/21/22 13:43 • (MSD) R3772224-5 03/21/22 19:07
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
Benzene
0.250
ND
0.315
0.365
126
146
Carbon tetrachloride
0.250
ND
0.360
0.397
144
159
Chlorobenzene
0.250
ND
0.355
0.343
142
137
Chloroform
0.250
ND
0.297
0.315
119
126
1,2-Dichloroethane
0.250
ND
0.297
0.293
119
117
1,1-Dichloroethene
0.250
ND
0.321
0.356
128
142
2-Butanone (MEK)
1.25
ND
2.37
2.13
189
170
Tetrachloroethene
0.250
ND
0.338
0.329
135
132
Trichloroethene
0.250
ND
0.292
0.307
117
123
Vinyl chloride
0.250
ND
0.351
0.380
140
152
(S) Toluene-dH
113
ill
(S) 4-Bromofluorobenzene
106
104
(S) 1,2-Dichloroethane-d4
98.9
102
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
1 17.0-158
14.7
27
1 23.0-159
9.78
28
1 33.0-152
3.44
27
1 29.0-154
5.88
28
1 29.0-151
1.36
27
1 11.0-160
10.3
29
1 10.0-160
J5 J5 10.7
32
1 10.0-160
2.70
27
1 10.0-160
5.01
25
1 10.0-160
7.93
27
80.0-120
77.0-126
70.0-130
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1472640 03/25/22 15:26 14 of 21

WG1837165
Chlorinated Acid Herbicides (GC) by Method 8151A
Method Blank (MB)
(MB) R3773733-1 03/24/22 1112
MB Result
Analyte mg/I
2,4,5-TP (Silvex) U
2,4-D U
(S) Z4-Dichlorophenyl Acetic 46.4
Acid
QUALITY CONTROL SUMMARY
L1472640-01
MB Qualifier MB MDL
MB RDL
mg/I
mg/I
0.000667
0.00200
0.000667
0.00200
14.0-158
Laboratory Control Sample (LCS)
(LCS) R3773788-2 03/24/22 1127
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/I
mg/I
2,4,5-TP (Silvex) 0.0500
0.0262
52.4
50.0-125
2,4-D 0.0500
0.0301
60.2
50.0-120
(S) Z4-Dichlorophenyl Acetic
46.8
14. 0-158
Acid
L1471765-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1471765-02 03/24/22 13:08 • (MS) R3773733-3 03/24/22 13:23 • (MSD) R3773733-4 03/24/22 13:37
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
2,4,5-TP (Silvex)
0.0500
ND
0.0307
0.0263
61.4
52.6
2,4-D
0.0500
ND
0.0386
0.0310
77.2
62.0
(S) Z4-Dichlorophenyl Acetic
59.2
51.4
Acid
ACCOUNT:
EMA Resources
PROJECT:
Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits
1 50.0-125 15.4 20
1 50.0-120 J3 21.8 20
14.0-158
SDG: DATE/TIME: PAGE:
L1472640 03/25/22 15:26 15 of 21

WG1835284
Pesticides (GC) by Method 8081B
Method Blank (MB)
QUALITY CONTROL SUMMARY
L1472640-01
(MB) R3773693-1 03/23/22 18:40
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
Chlordane
U
0.00167
0.00500
Endrin
U
0.00167
0.00500
Heptachlor
U
0.00167
0.00500
Heptachlor epoxide
U
0.00167
0.00500
Gamma BHC
U
0.00167
0.00500
Methoxychlor
U
0.00167
0.00500
Toxaphene
U
0.00333
0.0100
(S) Decachlorobiphenyl
76.4
10.0-128
(S) Tetrochloro-m-xylene
80.9
10.0-127
Laboratory Control Sample (LCS)
(LCS) R3773693-2 03/23/22 18:53
Spike Amount
LCS Result
Analyte
mg/I _
mg/I
Endrin
0.0100
0.0106
Heptachlor
0.0100
0.0105
Heptachlor epoxide
0.0100
0.00995
Gamma BHC
0.0100
0.00973
Methoxychlor
0.0100
0.0116
(S) Decachlorobiphenyl
(S) Tetrochloro-m-xylene
LCS Rec.
106
105
99.5
97.3
116
84.6
80.2
Rec. Limits LCS Qualifier
57.0-134
27.0-132
57.0-130
55.0-129
54.0-155
10.0-128
10.0-127
L1471704-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1471704-01 03/23/22 19:19 • (MS) R3773693-3 03/23/22 19:32 • (MSD) R3773693-4 03/23/22 19:45
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Analyte
mg/I
mg/I
mg/I
mg/I
Endrin
0.0100
ND
0.00987
0.00990
98.7
99.0
Heptachlor
0.0100
ND
0.0103
0.0101
103
101
Heptachlor epoxide
0.0100
ND
0.00904
0.00892
90.4
89.2
Gamma BHC
0.0100
ND
0.00908
0.00895
90.8
89.5
Methoxychlor
0.0100
ND
0.0102
0.0105
102
105
(S) Decachlorobiphenyl
64.1
679
(S) Tetrochloro-m-xylene
79.8
77.7
ACCOUNT:
EMA Resources
PROJECT:
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
RPD Limits
1 10.0-160
0.303
39
1 16.0-136
1.96
40
1 10.0-160
1.34
36
1 14.0-141
1.44
40
1 10.0-160
2.90
34
10.0-128
10.0-127
SDG:
DATE/TIME:
PAGE:
L1472640
03/25/22 15:26
16 of 21

WG1835281 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1472640-01
Method Blank (MB)
(MB) R3773134-2 03/23/22 0143
MB Result
MB Qualifier MB MDL
MB RDL
Analyte
mg/I
mg/I
mg/I
1,4-Dichlorobenzene
U
0.0333
0.100
2,4-Dinitrotoluene
U
0.0333
0.100
Hexachlorobenzene
U
0.0333
0.100
Hexachloro-1,3-butadiene
U
0.0333
0.100
Hexachloroethane
U
0.0333
0.100
Nitrobenzene
U
0.0333
0.100
Pyridine
U
0.0333
0.100
3&4-Methyl Phenol
U
0.0333
0.100
2-Methylphenol
U
0.0333
0.100
Pentachlorophenol
U
0.0333
0.100
2,4,5-Trichlorophenol
U
0.0333
0.100
2,4,6-Trichlorophenol
U
0.0333
0.100
(S) 2-Fluorophenol
45.1
10.0-120
(S) Phenol-d5
30.6
10.0-120
(S) Nitrobenzene-d5
75.6
10.0-127
(S) 2-Fluorobiphenyl
71.1
10.0-130
(S) 2,4, 6-Tribromophenol
85.0
10. 0-155
(S) p-Terphenyl-d14
88.7
10.0-128
Laboratory Control Sample (LCS)
(LCS) R3773134-1 03/23/22 0126
Spike Amount
LCS Result
LCS Rec.
Rec. Limits LCS Qualifier
Analyte mg/I
mg/I
1,4-Dichlorobenzene 0.500
0.323
64.6
18.0-120
2,4-Dinitrotoluene 0.500
0.504
101
49.0-124
Hexachlorobenzene 0.500
0.418
83.6
44.0-120
Hexachloro-1,3-butadiene 0.500
0.394
78.8
19.0-120
Hexachloroethane 0.500
0.332
66.4
15.0-120
Nitrobenzene 0.500
0.359
71.8
27.0-120
Pyridine 0.500
0.170
34.0
10.0-120
3&4-Methyl Phenol 0.500
0.305
61.0
31.0-120
2-Methylphenol 0.500
0.293
58.6
28.0-120
Pentachlorophenol 0.500
0.440
88.0
23.0-120
2,4,5-Trichlorophenol 0.500
0.431
86.2
44.0-120
2,4,6-Trichlorophenol 0.500
0.407
81.4
42.0-120
(S) 2-Fluorophenol
27.6
10.0-120
(S) Phenol-d5
19.9
10.0-120
(S) Nitrobenzene-d5
72.6
10.0-127
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1472640 03/25/22 15:26 17 of 21

WG1835281 QUALITY CONTROL SUMMARY
Semi Volatile Organic Compounds (GC/MS) by Method 8270E L1472640-01
Laboratory Control Sample (LCS)
(LCS) R3773134-1 03/23/22 0126
Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier
Analyte mg/I mg/I
(S) 2-Fluorobiphenyl 71.2 10.0-130
(S) 2,4, 6-Tribromophenol 79.5 10. 0-155
(S) p-Terphenyl-d14 80.1 10.0-128
L1470788-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD)
(OS) L1470733-02 03/23/22 02:10 • (MS) R3773134-3 03/23/22 02:32 • (MSD) R3773134-4 03/23/22 0254
Spike Amount
Original Result
MS Result
MSD Result
MS Rec.
MSD Rec.
Dilution Rec. Limits
MS Qualifier MSD Qualifier RPD
Analyte
mg/I
mg/I
mg/I
mg/I
1,4-Dichlorobenzene
0.500
ND
0.252
0.327
50.4
65.4
1 17.0-120
25.9
2,4-Dinitrotoluene
0.500
ND
0.433
0.465
86.6
93.0
1 39.0-125
7.13
Hexachlorobenzene
0.500
ND
0.343
0.383
68.6
76.6
1 35.0-122
11.0
HexachIaro-1,3-butadiene
0.500
ND
0.310
0.386
62.0
77.2
1 12.0-120
21.8
Hexachloroethane
0.500
ND
0.275
0.358
55.0
71.6
1 10.0-120
26.2
Nitrobenzene
0.500
ND
0.299
0.344
59.8
68.8
1 12.0-120
14.0
Pyridine
0.500
ND
0.159
0.184
31.8
36.8
1 10.0-120
14.6
3&4-Methyl Phenol
0.500
ND
0.284
0.308
56.8
61.6
1 10.0-120
8.11
2-Methylphenol
0.500
ND
0.258
0.295
51.6
59.0
1 10.0-120
13.4
Pentachlorophenol
0.500
ND
0.388
0.404
77.6
80.8
1 10.0-128
4.04
2,4,5-Trichlorophenol
0.500
ND
0.375
0.403
75.0
80.6
1 33.0-120
7.20
2,4,6-Trichlorophenol
0.500
ND
0.342
0.392
68.4
78.4
1 26.0-120
13.6
(S) 2-Fluorophenol
36.8
44.4
10.0-120
(S) Phenol-d5
25.5
28.0
10.0-120
(S) Nitrobenzene-d5
57.0
68.1
10.0-127
(S) 2-Fluorobiphenyl
56.2
671
10.0-130
(S)2,4,6-Tribromophenol
81.0
85.0
10.0-155
(S) p-Terphenyl-d14
76.4
79.8
10.0-128
RPD Limits
40
25
24
34
40
30
37
36
30
37
31
31
ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources L1472640 03/25/22 15:26 13 of 21

GLOSSARY OF TERMS
Guide to Reading and Understanding Your Laboratory Report
The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not
intended as a comprehensive explanation, and ifyou have additional questions please contactyour project representative.
Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name,
Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and
Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received.
Abbreviations and Definitions
u
Fc
Fss]
MDL
Method Detection Limit.
ND
Not detected at the Reporting Limit (or MDL where applicable).
Fn
RDL
Reported Detection Limit.
Rec.
Recovery.
Fr
RPD
Relative Percent Difference.
SDG
Sample Delivery Group.
Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and
F
(S)
Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be
detected in all environmental media.
U
Not detected at the Reporting Limit (or MDL where applicable).
Analyte
The name ofthe particular compound or analysis performed. Some Analyses and Methods will have multiple analytes
reported.
Ifthe sample matrix contains an interfering material, the sample preparation volume or weight values differ from the
F
Dilution
standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the
laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the
result reported has already been corrected for this factor.
Rc
These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal
Limits
for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or
duplicated within these ranges.
Original Sample
The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control
sample. The Original Sample may not be included within the reported SDG.
This column provides a letter and/or number designation that corresponds to additional information concerning the result
Qualifier
reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and
potentially a discussion of possible implications ofthe Qualifier in the Case Narrative if applicable.
The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. Ifthere was
no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL"
Result
(Below Detectable Levels). The information in the results column should always be accompanied by either an MDL
(Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect
or report for this analyte.
Uncertainty
(Radiochemistry)
Confidence level of 2 sigma.
A brief discussion about the included sample results, including a discussion of any non -conformances to protocol
Case Narrative (Cn)
observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will
be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report.
Quality Control
This section ofthe report includes the results ofthe laboratory quality control analyses required by procedure or
Summary (Qc)
analytical methods to assist in evaluating the validity ofthe results reported for your samples. These analyses are not
being performed on your samples typically, but on laboratory generated material.
This is the document created in the field when your samples were initially collected. This is used to verify the time and
Sample Chain of
date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This
Custody (Sc)
chain of custody also documents all persons (excluding commercial shippers) that have had control or possession ofthe
samples from the time of collection until delivery to the laboratory for analysis.
This section ofyour report will provide the results of all testing performed on your samples. These results are provided
Sample Results (Sr)
by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for
each sample will provide the name and method number for the analysis reported.
Sample Summary (Ss)
This section ofthe Analytical Report defines the specific analyses performed for each sample ID, including the dates and
times of preparation and/or analysis.
Qualifier
Description
J
The identification ofthe analyte is acceptable, the reported value is an estimate.
J3
The associated batch QC was outside the established quality control range for precision.
J4
The associated batch QC was outside the established quality control range for accuracy.
J5
The sample matrix interfered with the ability to make any accurate determination, spike value is high.
J6
The sample matrix interfered with the ability to make any accurate determination, spike value is low.
P1
RPD value not applicable for sample concentrations less than 5 times the reporting limit.
T8
Sample(s) received past/too close to holding time expiration.
ACCOUNT:
PROJECT: SDG: DATE/TIME: PAGE:
EMA Resources
L1472640 03/25/22 15:26 19 of 21

ACCREDITATIONS & LOCATIONS
Pace Analytical National 12065 Lebanon Rd Mount Juliet, TN 37122
Alabama
40660
Nebraska
N E-OS-15-05
Alaska
17-026
Nevada
TN000032021-1
Arizona
AZ0612
New Hampshire
2975
Arkansas
88-0469
New Jersey—NELAP
TNO02
California
2932
New Mexico
TN00003
Colorado
TN00003
New York
11742
Connecticut
PH-0197
North Carolina
Env375
Florida
E87487
North Carolina'
DW21704 _
Georgia
NELAP
North Carolina 3
41
Georgia'
923
North Dakota
R-140
Idaho
TN00003
Ohio—VAP
CL0069
Illinois
200008
Oklahoma
9915
Indiana
C-TN-01
Oregon
TN200002
Iowa
364
Pennsylvania
68-02979
Kansas
E-10277
Rhode Island
LA000356
Kentucky' 6
KY90010
South Carolina
84004002
Kentucky 2
16
South Dakota
n/a
Louisiana
A130792
Tennessee'"
2006
Louisiana
LA018
Texas
T104704245-20-18
Maine
TN00003
Texas5
LABO152
Maryland
324
Utah
TN000032021-11
Massachusetts
M-TNO03
Vermont
VT2006
Michigan
9958
Virginia
110033
Minnesota
047-999-395
Washington
C847
Mississippi
TN00003
West Virginia
233
Missouri
340
Wisconsin
998093910
Montana
CERT0086
Wyoming
A2 LA
A2LA— ISO 17025
1461.01
AIHA-LAP,LLC EMLAP
100789
A2 LA — ISO 17025 5
1461.02
DOD
1461.01
Canada
1461.01
USDA
P330-15-00234
EPA—Crypto
TN00003
Drinking Water 2 Underground Storage Tanks 3 Aquatic Toxicity "Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable
Not all certifications held by the laboratory are applicable to the results reported in the attached report.
Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace Analytical.
Rc
ACCOUNT: PROJECT: SDG: DATE/TIME:
EMA Resources L1472640 03/25/22 15:26
PAGE:
20 of 21

Company Name/Address:
Billing Information,
EMA Resources
Mr. Brent Collins
755 Yadkinville Road f'K
755 Yadkinville Road
Mocksviile, NC 27028
Mocksville, NC 27028
Report to:
Email To:
Mr, Brent Collins
[e-mail];roy.whitak
Project Description
City/State /1 � Please Circle.
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Sludge
Collected: %L�M`G//rfG
Client Project #
Lab Project #
Phone: [phone]
Coll by (print
Site/Facility ID #
P.c- #
Q
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Z
Collected by (signature):
Rush? (Lab MUST Be Notified) Quote ##
11
C7
+-
A60e`l_
—Same Day _Fil
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Immediately
Next Day __ 111iQRadaiii Date Results Needed
_ Two Day , OWOO*l No.
=
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Packed on Ice N _ Y
_ Three Day of
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>
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Sample ID
Comp/Grab
Matrix • Depth
Date
Time
ntrs
55
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Remarks:
pH
Temp
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c,I
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Flow
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Time:
Received by: {Signature)
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Preservation Correct/Checked: �, N
PAD screen <D. 5 mR/hr: ✓_Y
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Relinquished by! (S"gnature)
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ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Davie County Water System
WWTP Name: Cooleemee WWTP
WQ Permit Number:
NPDES Number:
WQ0010583
NCO024872
Monitoring Period: From 3/16/2022
To 3/16/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
I Alt B (Alk Treatment)❑
I Alt. C (Prior Testing)❑
A1t.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑ Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑ Pasteurization ❑
Class B:
I Alt. (1) Fecal Density El Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying ❑
1 Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Cl; 2020
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
u nim
Geo. Mean[Waximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
6354
12455
31073
MPN/g
0
4x Year
G
SM92210E
CFU
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
I weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-daybench) ©
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
0 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Tim Smith - WWTP ORC Brent Collins; Director of Technical Services
Prreparer Name and Title (type or print) Land Applier Name and Title(ifapplicable)(type or print)
L Feb 6, 2023 Jj dv' 2/6/2023
Timothy L Smi i (Feb 6, 2023 10:15 EST) Z
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

Analytical Results
EMA Resources, Inc.
755 Yadkinville Rd.
Mocksville, NC 27028
Receive Date: 03/16/2022
Reported: 03/17/2022
For: Cooleemee
Comments: GEOMETRIC MEAN: 12455 MPN/g
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
220316-21-01
Fecal Coliforms
1
13736
MPN/g
SM92210E-2006
03/16/2022
MD
220316-21-01
Percent Solids
1
3.64
%
SM2540B-2011
03/16/2022
MD
220316-21-02
Fecal Coliforms
2
22161
MPN/g
SM92210E-2006
03/16/2022
MD
220316-21-02
Percent Solids
2
3.61
%
SM2540B-2011
03/16/2022
MD
220316-21-03
Fecal Coliforms
3
6354
MPN/g
SM92210E-2006
03/16/2022
MD
220316-21-03
Percent Solids
3
3.62
%
SM2540B-2011
03/16/2022
MD
220316-21-04
Fecal Coliforms
4
31073
MPN/g
SM92210E-2006
03/16/2022
MD
220316-21-04
Percent Solids
4
3.54
%
SM2540B-2011
03/16/2022
MD
220316-21-05
Fecal Coliforms
5
6590
MPN/g
SM92210E-2006
03/16/2022
MD
220316-21-05
Percent Solids
5
3.49
%
SM2540B-2011
03/16/2022
MD
220316-21-06
Fecal Coliforms
6
8403
MPN/g
SM92210E-2006
03/16/2022
MD
220316-21-06
Percent Solids
6
3.57
%
SM2540B-2011
03/16/2022
MD
220316-21-07
Fecal Coliforms
7
13967
MPN/g
SM92210E-2006
03/16/2022
MD
220316-21-07
Percent Solids
7
3.58
%
SM2540B-2011
03/16/2022
MD
Respectfully submitted,
X�- � �'?- J, ;'�
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 4

Condition of Receipt
Sample Number 220316-21-01 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220316-21-02 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220316-21-03 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220316-21-04 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220316-21-05 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220316-21-06 Temp on Arrival: 3.0
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 4

Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
Sample Number 220316-21-07 Temp on Arrival: 3.0
Parameter Schedule: Percent Solids
Received on Ice
Parameter Schedule: Fecal Coliforms
Sodium Thiosulfate Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 3 of 4

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Analytical Results
EMA Resources, Inc.
755 Yadkinville Rd.
Mocksville, NC 27028
Receive Date: 03/16/2022
Reported: 04/22/2022
For: Cooleemee
Comments:
STATESVILLE
ANALYTICAL
Sample Number Parameter Sample ID Result Unit Method Analyzed Analyst
220316-20-01 30 Day Benchscale Cooleemee
Respectfully submitted,
X�- � � " �-' J, ;'�
Melissa Myers
NC Cert #440,
NCDW Cert #37755,
EPA #NC00909
12.2
EPA625-R-92/0 03/16/2022 MD
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 1 of 5

Condition of Receipt
Sample Number 220316-20-01 Temp on Arrival: 3.0
Parameter Schedule:
Received on Ice
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 2 of 5

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PO Bo 2289 Statesville, NC 28687.704 872 4 97
Page se5

STATESVILLE
ANALYTICAL
Analytical Results
EMA Resources
755 Yadkinville Rd
Mocksville, NC 27028
Entered: 3/16/22
Reported: 4/22/22
Sample ID: 220316-20-01
PARAMETER: Vector Attraction Reduction/Aerobically Digested Sludge (30day)
Total Solids
Volatile Solids
% Volatile Solids
Week
1
1.69
1.10
0.6509
Week
2
1.64
1.06
0.6463
Week
3
1.63
1.04
0.6380
Week
4
1.56
0.99
0.6346
Week
5
1.56
0.97
0.6218
Week
6
1.53
0.95
0.6209
Volatile Solids Reduction: 0.6509 - 0.6209 X 100 = 12.2
0.6509 - (0.6509 X 0.6209)
Respectfully submitted,
Melissa Myers
Statesville Analytical, Inc.
NC WW Cert.# 440NC
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 4 of 5

30 Day Bench Worksheet
Sample ID # 22016-20-01
WEEK 1
Samples
Total Solids
Volatile Solids
% Volatile Fraction
1
1.68
1.09
2
1.69
1.09
3
1.70
1.12
Average:
1.69
1.10
0.6509
WEEK 2
Samples
Total Solids
Volatile Solids
% Volatile Fraction
1
1.62
1.04
2
1.67
1.07
3
1.63
1.06
Average:
1.64
1.06
0.6463
WEEK 3
Samples
Total Solids
Volatile Solids
% Volatile Fraction
1
1.62
1.04
2
1.63
1.04
3
1.63
1.05
Average:
1.63
1.04
0.6380
WEEK 4
Samples
Total Solids
Volatile Solids
% Volatile Fraction
1
1.59
1.01
2
1.55
0.97
3
1.55
0.99
Average:
1.56
0.99
0.6346
WEEK 5
Samples
Total Solids
Volatile Solids
% Volatile Fraction
1
1.56
0.96
2
1.57
0.97
3
1.56
0.97
Average:
1.56
0.97
0.6218
WEEK 6
Samples
Total Solids
Volatile Solids
% Volatile Fraction
1
1.52
0.95
2
1.56
0.96
3
1.52
0.93
Average:
1.53
0.95
0.6209
Van Kleeck Reduction: 0.6509- 0.6209 X 100 = 12.2 %
0.6509 - ( 0.6509 X 0.6209)
Final Result: 12.2 %
PO Box 228 • Statesville, NC 28687 • 704/872/4697
Page 5 of 5

ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Davie County Water System
WWTP Name: Cooleemee WWTP
WQ Permit Number:
NPDES Number:
WQ0010583
NCO024872
Monitoring Period: From 4/20/2022
To 4/20/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
I Alt B (Alk Treatment)❑
I Alt. C (Prior Testing)❑
A1t.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑ Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑ Pasteurization ❑
Class B:
I Alt. (1) Fecal Density El Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying ❑
1 Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Cl; 2020
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
u nim
Geo. Mean[Waximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
2132
4042
6257
col/g
0
4x Year
C
SM9222D
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
I weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-daybench) ©
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
0 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Tim Smith - WWTP ORC Brent Collins; Director of Technical Services
P-reparer Name and Title (type or print) Land Applier Name
and Title(ifapplicable)(type or print)
//i?-IO�G L c�i?'ll�Gl Feb 6, 2023 �J) f dv' 2/6/2023
Timothy L Smi (Feb 6, 2U231U:15 EST) ,�f
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

r`
Contact: Brent Collins
Client: EMA Resources, Inc
755 Yadkinville Road
Mocksville, NC 27028
Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Page 1
Report Date: 5/2/2022
Date Sample Rcvd: 4/20/2022
Meritech Work Order #
04202206 Sample: Davie County Basin 1 Grab
4/20/22
Parameters
Result Analysis Date Reporting Limit
Method
% Total Solids
9.59 % 4/21/22 0-100 %
SM 2540B
Fecal Coliform (Sludge)
6,257 col/g dry wt 4/20/22 1500 col/g dry wt
SM 9222D
Meritech Work Order #
04202207 Sample: Davie County Basin 2 Grab
4/20/22
Parameters
Result Analysis Date Reporting Limit
Method
% Total Solids
9.12 % 4/21/22 0-100 %
SM 2540B
Fecal Coliform (Sludge)
5,482 col/g dry wt 4/20/22 1500 col/g dry wt
SM 9222D
Meritech Work Order #
04202208 Sample: Davie County Basin 3 Grab
4/20/22
Parameters
Result Analysis Date Reporting Limit
Method
% Total Solids
9.44 % 4/21/22 0-100 %
SM 2540B
Fecal Coliform (Sludge)
4,237 col/g dry wt 4/20/22 1500 col/g dry wt
SM 9222D
Meritech Work Order #
04202209 Sample: Davie County Basin 4 Grab
4/20/22
Parameters
Result Analysis Date Reporting Limit
Method
% Total Solids
9.53 % 4/21/22 0-100 %
SM 2540B
Fecal Coliform (Sludge)
4,197 col/g dry wt 4/20/22 1500 col/g dry wt
SM 9222D
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No. 165
r
Contact: Brent Collins
Client: EMA Resources, Inc
755 Yadkinville Road
Mocksville, NC 27028
Page 2
Report Date: 5/2/2022
Date Sample Rcvd: 4/20/2022
Meritech Work Order # 04202210 Sample: Davie County Basin 5 Grab 4/20/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 9.38 % 4/21/22 0-100 % SM 2540E
Fecal Coliform (Sludge) 2,132 col/g dry wt 4/20/22 1500 col/g dry wt SM 9222D
Meritech Work Order # 04202211 Sample: Davie County Basin 6 Grab 4/20/22
Parameters
Result
Analysis Date
Reporting Limit
Method
% Total Solids
9.43 %
4/21/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
3,181 col/g dry wt
4/20/22
1500 col/g dry wt
SM 9222D
Meritech Work Order # 04202212 Sample: Davie County Basin 7 Grab 4/20/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 9.39 % 4/21/22 0-100 % SM 254013
Fecal Coliform (Sludge) 4,260 col/g dry wt 4/20/22 1500 col/g dry wt SM 9222D
I hereby certify that] have reviewed and approve these data. I/ /Jz' Z2 : :
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

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Contact: Brent Collins
Client: EMA Resources, Inc
755 Yadkinville Road
Mocksville, NC 27028
Merztech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Report Date: 6/8/2022
Date Sample Rcvd: 4/20/2022
Vector Attraction Reduction Aerobically Digested Sludge 30 Day Test
Meritech Work Order # 04202213 Sample: Davie County Basin Composite 4/20/22
Total Solids Volatile Solids % Volatile Solids
Week 1 1.44 0.42 0.291
Week 2
1.81
0.500
0.275
Week 3
1.46
0.410
0.280
Week 4
1.82
0.470
0.258
Week 5
1.18
0.340
0.288
Van Kleek Reduction (%): 1.67
I hereby certify that I have reviewed and approve these data.OOPL�
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

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ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Davie County Water System
WWTP Name: Cooleemee WWTP
WQ Permit Number:
NPDES Number:
WQ0010583
NCO024872
Monitoring Period: From 5/4/2022
To 5/4/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
I Alt B (Alk Treatment)❑
I Alt. C (Prior Testing)❑
A1t.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑ Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑ Pasteurization ❑
Class B:
I Alt. (1) Fecal Density El Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying ❑
1 Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Cl; 2020
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
u nim
Geo. Mean[Waximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
137
139
142
col/g
0
4x Year
C
SM9222D
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
I weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-daybench) ©
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
0 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Tim Smith - WWTP ORC Brent Collins; Director of Technical Services
P-rreparter, Name and Title (type or print) Land Applier Name and Title (if applicable)(type or print)
Feb 6, 2023 �J) f d 2/6/2023
Timothy LSmi (Feb 6, 202310:15 EST) ,Gf�"'�
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

Meritech, Inc.
Environmental. Laboratory
Laboratory Certification No.165
Page 1
Contact: Brent Collins Report Date: 5/11/2022
Client: EMA Resources, Inc
755 Yadkinville Road
Mocksville, NC 27028 Date Sample Rcvd: 5/4/2022
Meritech Work Order # 05042202 Sample: Cooleemee Basin 1 Grab 5/4/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 6AS % 5/5/22 0-100 % SM 2540B
Fecal Coliform (Sludge) <141 col/g dry wt 5/4/22 141 col/g dry wt SM 9222D
Meritech Work Order # 05042203 Sample: Cooleemee Basin 2 Grab 5/4/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 6.38 % 5/5/22 0-100 % SM 2540B
Fecal Coliform (Sludge) <142 col/g dry wt 5/4/22 142 col/g dry wt SM 9222D
Meritech Work Order # 05042204 Sample: Cooleemee Basin 3 Grab 5/4/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 6.52 % 5/5/22 0-100 % SM 2540E
Fecal Coliform (Sludge) <139 col/g dry wt 5/4/22 139 col/g dry wt SM 9222D
Meritech Work Order # 05042205 Sample: Cooleemee Basin 4 Grab 5/4/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 6.52 % 5/5/22 0-100 % SM 2540B
Fecal Coliform (Sludge) <139 col/g dry wt 5/4/22 139 col/g dry wt SM 9222D
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Alp
a
Contact: Brent Collins
Client: EMA Resources, Inc
755 Yadkinville Road
Mocksville, NC 27028
Page 2
Report Date: 5/11/2022
Date Sample Rcvd: 5/4/2022
Meritech Work Order # 05042206 Sample: Cooleemee Basin 5 Grab 5/4/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 6.63 % 5/5/22 0-100 % SM 2540B
Fecal Coliform (Sludge) <137 col/g dry wt 5/4/22 137 col/g dry wt SM 9222D
Meritech Work Order # 05042207
Parameters
% Total Solids
Fecal Coliform (Sludge)
Meritech Work Order # 05042208
Parameters
% Total Solids
Fecal Coliform (Sludge)
Sample: Cooleemee Basin 6 Grab
Result
6.60 %
<138 col/g dry wt
Result
Analysis Date Reporting Limit
5/5/22 0-100 %
5/4/22 138 col/g dry wt
Sample: Cooleemee Basin 7 Grab
6.56 %
<139 col/g drywt
Analysis Date Reporting Limit
5/5/22 0-100 %
5/4/22 139 col/gdry wt
5/4/22
Method
SM 2540B
SM 9222D
5/4/22
Method
SM 2540B
SM 9222D
I hereby certify that I have reviewed and approve these data. .-sQ.mo-ncko` Ua{ac- pc�V
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] £ax.[phone]

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Contact: Brent Collins
Client: EMA Resources, Inc
755 Yadkinville Road
Mocksville, NC 27028
Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Report Date: 6/20/2022
Date Sample Rcvd: 5/4/2022
Vector Attraction Reduction Aerobically Digested Sludge 30 Day Test
Meritech Work Order # 05042209 Sample: Cooleemee Basin Composite 5/4/22
Total Solids Volatile Solids % Volatile Solids
Week 1 1.20 0.310 0.260
Week 2
1.12
0.270
0.237
Week 3
1.05
0.300
0.287
Week 4
0.660
0.170
0.262
Week 5
0.680
0.190
0.273
Van Kleek Reduction (%): -6.90
I hereby certify that I have reviewed and approve these data.
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

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ANNUAL PATHOGEN AND VECTOR ATTRACTION REDUCTION FORM (02T Rules)
Facility Name: Davie County Water System
WWTP Name: Cooleemee WWTP
WQ Permit Number:
NPDES Number:
WQ0010583
NCO024872
Monitoring Period: From 12/29/2022
To 12/29/2022
Pathogen Reduction (15A NCAC 02T .1106) - Please indicate level achieved and alternative performed:
Class A:
Alt. A (time/temp) ❑
I Alt B (Alk Treatment)❑
I Alt. C (Prior Testing)❑
A1t.D (No Prior Test) ❑
Process to Further Reduce Pathogengs ❑
If applicable to alternative performed (Class A only) indicate "Process to Further Reduce Pathogens":
Compost 01
Heat Drying ❑ Heat Treatment ❑
Thermophilic ❑
Beta Ray ❑
1 Gamma Ray ❑ Pasteurization ❑
Class B:
I Alt. (1) Fecal Density El Alt. (2) Process to Significantly Reduce Pathogens ❑
If applicable to alternative
performed (Class B only) indicate "Process to Significantly Reduce Pathogens":
Lime Stabilization ❑
1 Air Drying ❑
1 Composting ❑
Aerobic Digestion ❑
Anaerobic Digestion ❑
If applicable to alternative performed (Class A or Cl; 2020
Parameter
Allowable Level
in Sludge
Pathogen Density
g �
Number o
Excee-
dences
Frequency
of Analysis
Sample
Type
Analytical
Tech -pique
u nim
Geo. Mean[Waximurr
Units
Fecal Coliform
2 x 10 to the
6th power
per gram of
total solids
MPN
CFU
58140
74011
105572
col/g
0
4x Year
C
SM9222D
1000 mpn per gram
of total solid (dry
weight)
Salmonella bacteria
(in lieu of fecal
coliform)
3 MPN per 4 grams
total solid (dry
I weight)
Vector Attraction Reduction (15A NCAC 02T .1107) - Please indicate alternative performed:
Alt. I (VS reduction) ❑
Alt. 2 (40-day bench) ❑
Alt. 3 (30-daybench) ❑
Alt. 4 (Spec. Oz uptake) ❑
Alt. 5 (14-Day Aerobic) ❑
Alt. 6 (Alk. Stabilization ❑
Alt 7 (Drying - Stable) ❑
jAlt. 8 (Drying - Unstable) ❑
Alt. 9 (Injection) ❑
Alt. 10 (Incorporation) ❑
No vector attraction reduction alternatives were performed ❑
CERTIFICATION STATEMENT (please check the appropriate statement)
0 "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have been met."
❑ "I certify, under penalty of law, that the pathogen requirements in 15A NCAC 02T .1106 and the
vector attraction reduction requirement in 15A NCAC 02T .1107 have not been met." (Please note if
you check this statement attach an explanation why you have not met one or both of the
requirements.)
"This determination has been made under my direction and supervision in accordance with the system
designed to ensure that qualified personnel properly gather and evaluate the information used to determine
that the pathogen and vector attraction reduction requirements have been met. I am aware that there are
significant penalties for false certification including fine and imprisonment."
Tim Smith - WWTP ORC Brent Collins; Director of Technical Services
Prreparer Name and Title (type or print) Land Applier Name and Title(ifapplicable)(type or print)
//i�iDtLl�l L Feb 6, 2023 �/ j f �u''� 2/6/2023
Timothy L Smi (Feb 6, 202310:15 EST) ,Gf�'�'
Signature of Preparer* Date Signature of Land Applier (if applicable) Date
*Preparer is defined in 40 CFR Part 503.9(r) and 15A NCAC 2T .1102 (26)
DENR FORM PVRF 02T (12/2006)

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Contact: Brent Collins
Client: EMA Resources, Inc
755 Yadkinville Road
Mocksville, NC 27028
Page 1
Report Date: 1/6/2023
Date Sample Rcvd: 12/29/2022
Meritech Work Order #
12292208 Sample: Cooleemee Basin 1 Grab
12/29/22
Parameters
Result Analysis Date Reporting
Limit
Method
% Total Solids
3.60 % 12/29/22 0-100 %
SM 2540E
Fecal Coliform (Sludge)
77,778 CFU/g dry wt 12/29/22
928 CFU/g dry wt
SM 9222D
Meritech Work Order #
12292209 Sample: CooIeemee Basin 2 Grab
12/29/22
Parameters
Result Analysis Date Reporting
Limit
Method
% Total Solids
3.59 % 12/29/22 0-100 %
SM 2540B
Fecal Coliform (Sludge)
83,565 CFU/g dry wt 12/29/22
928 CFU/g dry wt
SM 9222D
Meritech Work Order #
12292210 Sample: Cooleemee Basin 3 Grab
12/29/22
Parameters
Result Analysis Date Reporting
Limit
Method
% Total Solids
3.65 % 12/29/22 0-100 %
SM 2540B
Fecal Coliform (Sludge)
79,452 CFU/g dry wt 12/29/22
928 CFU/g dry wt
SM 9222D
Meritech Work Order #
12292211 Sample: Cooleemee Basin 4 Grab
12/29/22
Parameters
Result Analysis Date Reporting
Limit
Method
% TotaI Solids
3.41 % 12/29/22 0-100 %
SM 2540B
Fecal Coliform (Sludge)
105,572 CFU/g dry wt 12/29/22
928 CFU/g dry wt
SM 9222D
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] fax.[phone]

Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
Contact: Brent Collins
Client: EMA Resources, Inc
755 Yadkinville Road
MocksviIle, NC 27028
Page 2
Report Date: 1/6/2023
Date Sample Rcvd: 12/29/2022
Meritech Work Order # 12292212 Sample: Cooleemee Basin 5 Grab 12/29/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 3.44 % 12/29/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 58,140 CFU/g dry wt 12/29/22 928 CFU/g dry wt SM 9222D
Meritech Work Order # 12292213 Sample: Cooleemee Basin 6 Grab 12/29/22
Parameters
Result
Analysis Date
Reporting Limit
Method
% Total Solids
3.42 %
12/29/22
0-100 %
SM 2540B
Fecal Coliform (Sludge)
61,404 CFU/g dry wt
12/29/22
928 CFU/g drywt
SM 9222D
Meritech Work Order # 12292214 Sample: Cooleemee Basin 7 Grab 12/29/22
Parameters Result Analysis Date Reporting Limit Method
% Total Solids 3.52 % 12/29/22 0-100 % SM 2540B
Fecal Coliform (Sludge) 62,500 CFU/g dry wt 12/29/22 928 CFU/g dry wt SM 9222D
1 hereby certify that I have reviewed and approve these data.
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
tel.[phone] f ax. [phone]

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Meritech, Inc.
Environmental Laboratory
Laboratory Certification No.165
F
Contact: Brent Collins
Client: EMA Resources, Inc
755 Yadkinville Road
Mocksville, NC 27028
Report Date: 1/5/2023
Date Sample Rcvd: 12/29/2022
Meritech Work Order # 12292215 Sample. Cooleemee Basin - VS In Grab 12/29/22
Parameters Result Analysis Date Reporting Limit Method
• Total Solids 0.64 % 12/29/22 0-100 % SM 2540B
• Volatile Solids 0.42 % 12/29/22 0-100 % SM 2540E
Meritech Work Order # 12292216 Sample: Cooleemee Basin - VS Out Grab 12/29/22
Parameters
Result
Analysis Date
Reporting Limit
Method
% Total Solids
3.43 %
12/29/22
0-100 %
SM 2540B
% Volatile Solids
1.29 %
12/29/22
0-100 %
SM 2540E
I hereby certify that I have reviewed and approve these data. t7Cy)
Laboratory Representative
642 Tamco Road, Reidsville, North Carolina 27320
teI.[phone] fax.[phone]

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Basin 12/29/22
Volatile Solids IN 0.42
%Total Solids IN 0.64
Fractional Volatile Solids IN 0.656
Volatile Solids OUT 1.29
Total Solids OUT 3.43
Fractional Volatile Solids OUT 0.376
Volatile Solids
As a decimal
Volatile Solids In 0.656
Volatile Solids Out 0.376
Volatile Solids Redu 1 68.4

NCDA&CS Agronomic Division Phone: [phone] Website: www.ncagr.gov/agronomi/ Report No. FY22-SL033176
k5i I"14'4+;4,
Client:
Roger Spillman
Advisor: Brent Collins
Predictive
PO Box 378
EMA Resources Inc
°± f'
Cooleemee, NC 27014
755 Yadkinville Rd
�- Soil Report Mehlich-3 Extraction
Mocksville, NC 27028
Sampled County : Davie
_1
Links to Helpful Information
Sampled: Received: 05/03/2022 Completed: 05/10/2022 Farm: DV08
Client ID:
411288
Advisor ID: 405413
Sample ID: 00006
Recommendations: Lime
Nutrients (lb/acre)
More
Crop (tons/acre) N P2O5
K2O
Mg S Mn Zn
Cu B
Information
Lime History:
1 -Bermuda hay/past., M 0.0 180-220 0
130
0 0 pH$ 0
0 0
Note: 12 Note: $
2 -Bermuda hay/past., M 0.0 180-220 0
130
0 0 pH$ 0
0 0
Note: 12 Note: $
Test Results [units - W/V in g/cm3; CEC and Na in meq/100 cm3; NO3-N in mg/dm3]:
Soil Class: Mineral
HM% W/V CEC BS% Ac pH P-1 K-1 Ca% Mg%
S-1 Mn-I
Mn-All Mn-Al2 Zn-I Zn-AI
Cu-I Na ESP SS-1 NO3-N
0.22 1.01 20.2 95 1.1 6.8 65 43 60 34
35 338
207 207 1039 1039
281 0.1 1
North Carolina
Tai wLm Truk f and Ctwinlsskm
Reprogramming of the laboratory -information -management system that makes this report possible is being funded
through a grant from the North Carolina Tobacco Trust Fund Commission.
Thank you for using agronomic services to manage nutrients and safeguard environmental quality.
- Steve Troxler, Commissioner of Agriculture

Page 1 of 1
Report No: 22-356-0769
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: Roger Spillman
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm:DV08
Date Received: 12/22/2022
Date of Report: 12/29/2022
Lab No Field ID
Sample ID
Soil Class
HM% W/V
pH
Ac
P-1
K-1
S-1
Mn-I
Mn-All Mn-Al2
Zn-I
Zn-AI
Cu-I
CEC
BS %
Ca %
Mg %
ESP
Na
21260
04
MIN
1.7
6.0
1.0
2
75
102
69
0 0
90
90
35
6.4
84
43
35
0.7
0
21261
05
MIN
2.1
6.5
1.1
24
24
17
950
0 0
340
340
120
14.9
92
58
33
0.5
0.1
21262
09
MIN
2.0
6.8
0.5
14
19
15
1094
0 0
220
220
90
18.4
97
59
37
0.5
0.1
Comment:
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

Page 1 of 1
Report No: 22-356-0764
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: Thomas Whitaker
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm:DV09
Date Received: 12/22/2022
Date of Report: 12/29/2022
Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I CEC BS % Ca % Mg % ESP Na
21250 02 MIN 1.7 5.5 2.1 19 113 31 425 0 0 168 168 90 8.2 74 41 26 0.5 0
Comment
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

Page 1 of 1
Report No: 22-356-0762
Account No: 46245
Advisor: EMA Resources Inc
755 Yadkinville Road
Mocksville NC 27028
Waypo'10 t
ANALYTICAL
Client: James Taylor
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Farm: R001
Date Received: 12/22/2022
Date of Report: 12/29/2022
Lab No Field ID Sample ID Soil Class HM% W/V pH Ac P-1 K-1 S-1 Mn-I Mn-All Mn-Al2 Zn-I Zn-AI Cu-I CEC BS % Ca % Mg % ESP Na
21247 01 MIN 1.2 5.6 1.2 27 18 21 25 0 0 110 110 90 5.0 77 49 25 1.0 0
Comment
Test result units = CEC and Na in meq/100cm3; NO3 N in mg/dm3; W/V in g/cm3
North Carolina Division of Water Quality Certification #257, Analysis and fertility recommendations shown on this report are performed in accordance within NCDA guidelines, Analysis prepared by: Waypoint Analytical Virginia, Inc.

Signature Pages
Final Audit Report
Created: 2023-02-06
By: Brent Collins ([e-mail])
Status: Signed
Transaction ID: CBJCHBCAABAADkAHkuJbl9-YrgbAZpl7_V2BhmDv_u41
"Signature Pages" History
Document created by Brent Collins ([e-mail])
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2023-02-06
dp Signer [e-mail] entered name at signing as Timothy L Smith
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Gip Document e-signed by Timothy L Smith ([e-mail])
Signature Date: 2023-02-06 - 3:15:08 PM GMT - Time Source: server- IP address: 67.213.60.238
Q Agreement completed.
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ACF Form
Final Audit Report
Created: 2023-02-06
By: Brent Collins ([e-mail])
Status: Signed
Transaction ID: CBJCHBCAABAA4aLv4iYKwpn94t7n6Ofi4hzX_eSaCxQ5
"ACF Form" History
Document created by Brent Collins ([e-mail])
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2023-02-06
dp Signer [e-mail] entered name at signing as Johnny Lambert
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Gip Document e-signed by Johnny Lambert ([e-mail])
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