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HomeMy WebLinkAboutWQ0040672_Monitoring - 11-2022_20230106 (2)Monitoring Report Submittal Permit Number #* WQ0040672 Name of Facility:* Stevens Towing - Riverbulk Terminal WWTF Month: * November Year: * 2022 Report Information ................................................. Type* Upload Document* Revised - NDMR, NDAR-1, NDAR-2, NDMRNDAR2 signed.pdf 4.52MB NDMLR PDF Only Revised - GW-59 GW-59formssigned.pdf 8.06MB PDF Only Confirmation Email Address:* Name of Submitter: * Signature: Date of submittal: Initial Review Please upload one PDF containing all applicable monitoring reports (i.e., NDMR, NDAR-7, NDAR-2, NDMLR, GW-59). kevin@ebarge.net Kevin Robert Gagnon 1 /6/2023 This will be filled in automatically Reviewer: Gerald, Wanda Is the project number correct?* WQ0040672 Is the monitoring report accepted?* Yes No Regional Office* Washington Reviewer: _anonymous Review Date: 1/6/2023 . . . . WQ0040672 Its were due . 9A) YES F-ntlii—twto—m�i�t—�ii"n,-gr"e-,#u""-";I":2.�22--"'-'-' --- C Will this monitoring report (GW-59 and G1 T be submifted after the established due dale? ...... .. ........ Was any required information missing on the CM-59 report forms? Y I t-h-e-i, —ns' - w* e-r is 'YES", list in the space provided below the well identification riumber(s) and explain the probisms ancountereti in obtaining the raquirad information, Are any of the monitor %,tills In need of repair or inaintenanct (damageil caa ing. unlocked or inkqing, ca -rni in , p Ss Y E S 01111 id ratific ion plate, area ove rgrow n, etc.) ? If A e am wer is "Yes v ontaci fihv Regional Office 16r g u id,, kvicr. 1, Ali, ini - i 4 #aitteared constituents equal to or above the established standards? is NO It the answer to question 4 is "NO' skip to section 8. H the answer to question 4 is 1'iii- list the affected wells individually with conslituenUs) and conrentrationis) exceeding standards in the spam provided below: For the constituents identified in question 4 ab*ve, have standards been exceeded previously for the V F-S IN 0 i same cons*uent(s) In the same wells) In the last two years? skfP to section 8, If the answer to question 6 is "Y'ES" list in the space provided below, each well wah consfituentfs) e'ceding standards, concentration(.0 reported, and sample collection date for each occurrence (for the last twoyears). � t � { Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO j ...... .... If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REQIONAL OFF7CE IMMEDIATELY FOR OUIDANCE, It dw answer is "No". monitoring wells rmy be improperly located, dean the Regional Office, Is the permittee implementing previously approved actions required by the Division involving this 'N J groundwater quality problem? if the answer to question 7 is -YES" describe ftse actions in the space provided below, If the answer to question 7 is "NO" geaW ft ft1qMl Molt Wift 00 #AM an at' rare inav rewdrod to dgftMjUg. tft J=M the waste &IWA.M2UM Is hg)dag gt ft reldog and -WAgAlaw to a Ivoilbe of Violatiom 12'almy Lsyk&l rho, gmmttky 19 do, OIL AM421 gwfift& Thaperson completing thispoman (GIV-59A) m ofthe onitoring report should sign below and �ubmdiiija forto with GW-50 farm$ for required wells to the as provided at the top oaf tie curront GW-69 form. ........ . . ........ Signature of Permit (of AU#WrizeO AgerM GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM SUBMIT FORM ON YELLOW PAPER ONLY s DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES # g � INFORMATION PROCESSING UNIT 1617 MAIL SERVICE CENTER, RALEIGH, INC 27699-1617 Phone: 919.807.6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date:_ 12/31/2024 Facility Name: Stevens Towing- Riverbulk Terminal Non Discharge WCt0046672 UIC Permit Name (if different): NPDES Other Facility Address: Edenton, NC 27932 TYPE OF PERMITTED OPERATION BEING MONITORED Edenton, NC 27932 County Chowan ❑ Lagoon ❑ Remediation: Infiltration Gallery Spray Field ❑ Remediation: Contact Person: Simon Rich, III Telephone#: (252)482-1011 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: MW-4 No. of wells to be sampled: 3 ❑ Water Source Heat Pump ❑ Other: (from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): Mw-4 Date sample collected: 1 1/14/2022 FIELD ANALYSES: WAS Well Depth: 17bgs ft. Well Diameter: 2 in. pH 00400: 6.58 units Temp. 00010: 15.33 oC DRY at Depth to Water Level 82546: 17.91 ft. below measuring point Screened Interval: 11 ft. to 17 ft. Spec. Cond. 00094: µMhos time of sampling,check Measuring Point is 3.12 ft. above land surface Relative M.P. Elevation: 23.98 ft. Odor 000m: none Volume of water pumped/bailed before sampling: .5 gallons Appearance orange/brown here:❑ Samples for metals were collected unfiltered: N YES ❑ NO and field acidified: ® YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 12/6/2022 Laboratory Name: Environmental Chemists, Inc. Certification No. 20-45107 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.02 mg/L Pb -Lead o1o51 .022 ug/L Coliform: MF Fecal 31616 <1 /100mL Nitrate (NO3) as N 00620 0.98 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.62 mg/L (Note: Use MPN method for highlyturbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): )issolved Solids:Total 70300 237 mg/L Al - Aluminum o11o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 0.148 ug/L TOC 00680 18.7 mg/L Ca - Calcium oo916 mg/L Chloride 0094o 24 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 0.040 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method#. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ■❑ Yes (1) ❑ No (0) >pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # SM 6200E Total Ammonia 00610 <0.2 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 0.078 ug/L method # TKN as N 00625 0.98 mg/L Ni - Nickel 01067 <0.01 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: A Permittee (or Authorized Aqent) Name and Title - Please print or type GW-59 Rev, 05-02-2017 mg/L Effluent Total VOCs: mg/L VOC Removal% SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM Please Print Clearly or Type Facility Name: Stevens Towing- Riverbulk Terminal Permit Name (if different): Facility Address: Edenton, NC 27932 Edenton, NC 27932 ""'- County Chowan Contact Person: Simon Rich, III Well Location/Site Name: MW-3 Telephone#: (252)482-1011 No. of wells to be sampled: 3 OF INFORMATION PROCESSING UNIT r MAIL SERVICE CENTER, RALEIGH, NC 27699.1617 Phone: 919-807-6306 ERMIT Number: on -Discharge W00040672 Expiration Date:_ 12/31 /2024 UIC 'DES Other 'PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: infiltration Gallery 0 Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: SAMPLING INFORMATION WELL ID NUMBER (from Permit): M'N-3 Date sample collected: 11/14/2022 Well Depth: 25bgs ft. Well Diameter: 2 in. Depth to Water Level 82546: 21.7 ft. below measuring point Screened Interval: 17 ft. to 25 ft. Measuring Point is 3.23 ft. above land surface Relative M.P. Elevation: 42.94 ft, Volume of water pumped/bailed before sampling: 2 gallons Samples for metals were collected unfiltered: 0 YES ❑ NO and field acidified: A YES ❑ NO FIELD ANALYSES: pH 00400: 6.61 units Temp. 00010: 14.39 -C Spec. Cond. 00094: µ Odor 00085: none Appearance yellow/brown If WELL WAS DRY at time ofMhos sampling, check here:❑ LABORATORY INFORMATION Date sample analyzed: 12/6/2022 Laboratory Name: Environmental Chemists, Inc. Certification No. 20-45107 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0.02 mg/L Pb -Lead o1o51 <0.028 ug/L Coliform: MF Fecal 31616 /100mL Nitrate (NO3) as N 00620 1.49 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 .63 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): )issolved Solids:Total 70300 165 mg/L Al - Aluminum of lo5 mg/L pH (Lab) 00403 units Ba - Barium 01007 0.179 ug/L TOC 00690 9.2 mg/L Ca - Calcium 00916 mg/L Chloride 00940 <5 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 0.062 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? I Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # SM 6200B Total Ammonia oo610 <0.2 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3as N: Ammonia Nitrogen, Total) Mn - Manganese 01055 0.154 ug/L method # TKN as N 00625 1.49 mg/L Ni - Nickel 01067 0.027 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% t-^� �� .N c r ,r._ % ! 0 2�rrd-•r, K ')��---' /-A, f'" 12/14/2022 t � t!`t ^t, Est-�t- �:.�ri!-�. Permittee (or Authorized Aq t) Name and Title - Please print or type Signature of Permittee (or Authorized Aqent) (Date) GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY ROUNDWATER QUALITY MONITORING: OMPLIANCE REPORT FORM or Facility Name: Stevens Towing- Riverbulk Terminal Permit Name (if different): Facility Address: Edenton, NC 27932 Edenton, NC 27932 County Chowan Contact Person: Simon Rich, III Well Location/Site Name: MW-1 .L ID NUMBER (from Permit): MW-1 Depth: 15 bgs ft h to Water Level 82546: 16.13 ft. below measuring point Suring Point is 2.95 ft. above land surface me of water pumped/bailed before sampling: 1 pies for metals were collected unfiltered: ® YES Telephone#: (252) 482-1011 No. of wells to be sampled: 3 DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES INFORMATION PROCESSING UNIT 1617 MAIL, SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919.807-6306 PERMIT Number: Expiration Date: 12/31/2024 Non -Discharge WQ0040672 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge Date sample collected: 11/14/2022 Well Diameter: 2 in. Screened Interval: 9 ft. to 15 ft. Relative M.P. Elevation: 23.92 ft, —gallons ❑ NO and field acidified: AYES ❑ NO 'ate sample analyzed: 12/6/2022 Laboratory Name: Environmental Chemists, Inc ARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 mg/L Nitrite (NO2) as N 00615 <0,02 mg/L Coliform: MF Fecal 31616 <1 /100mL Nitrate (NO3) as N 00620 .63 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 1.01 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L ssolved Solids:Total 70300 132 mg/L AI -Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 -230 ug/L TOC oo68o 38.5 mg/L Ca - Calcium oo916 mg/L Chloride 00940 15 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 .072 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L Phenol 32730 ug/L Fe - Iron 01045 ug/L Sulfate 00945 mg/L Hg - Mercury 71900 ug/L Decific Conductance 00095 µMhos K - Potassium 00937 mg/L Total Ammonia oo610 <0.2 mg/L Mg - Magnesium 00927 mg/L (Ammonia Nitrogen, NH3 as N: Ammonia Nitrogen, Total) Mn - Manganese 01055 0.113 ug/L TKN as N 00625 .63 mg/L Ni - Nickel 01067 0.031 ug/L For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: Permittee (or Authorized Ape t) Name and Title - Please print or type GW-59 Rev.05-02-2017 mg/L ❑ Water Source Heat Pump ❑ Other If WELL FIELD ANALYSES: WAS pH 00400: 5.16 units Temp. 000lo: 15.61 °C DRY at Spec. Cond. 000e4: µMhos time ofsampling, Odor 00085: none check Appearance brownish/yellow here:❑ Certification No. 20-45107 Pb - Lead 01051 0.035 ug/L Zn - Zinc 01092 mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? 9 Yes (1) ❑ No (0) VOC 7873 , method # Effluent Total VOCs: method # method # method # mg/L VOC Removal% Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 1 910.392.0223 Lab 0 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 0 252.473.5702 Lab/Fax 400'., 255-A Wilmington Highway, Jacksonville, NC 28540 a' 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS info&"� ,,environmentalchemists.com Quible & Associates Date of Report: Dec 06, 2022 PO Box 870 Manteo Report#: 22M-2686 Kitty Hawk NC 27946 Report M 2022-22672 Attention., Customer ID: 08100100 Project ID: Stevens Towing MW Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-55676 Site: MW-1 11/14/2022 10:50AM Water Troy Murphy Test Method Results Date Analyzed Lead EPA 200.7, Rev 4.4, 1994 0.035 mg/L 11/29/2022 Manganese EPA 200.7, Rev 4.4, 1994 0.113 mg/L 11/29/2022 Nickel EPA 200.7, Rev 4.4, 1994 0.031 mg/L 11/29/2022 Barium EPA 200.7, Rev. 4.4, 1994 0.230 mg/L 11/29/2022 Chromium EPA 200.7, Rev. 4.4, 1994 0.072 mg/L 11/29/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0,1993 < 0.2 mg/L 11/18/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 132 mg/L 11/15/2022 Total Phosphorus SM 4500 P (F-H)-2011 1.01 mg/L 11/23/2022 Total Organic Carbon (TOC) SM 5310 B-2014 38.5 mg/L 11/15/2022 Chloride SM4500 CI E-2011 15 mg/L 11/16/2022 1, 1, 1,2-Tetrachloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1, 1, 1 -Trichloroethane SW 846 Method 8260D15030B <0.5 pg/L 11/16/2022 1, 1,2,2-Tetrachloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1, 1,2-Trichloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,1-Dichloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,1-Dichloroethene SW 846 Method 826OD/5030B <0.5 pg/L 11/16/2022 1,1-Dichloropropene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2,3-Trichlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2,3-Trichloropropane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2,4-Trichlorobenzene SW 846 Method 8260D15030B <0.5 pg/L 11/16/2022 1, 2,4-Trimethyl benzene SW 846 Method 6260D/5030B <0.5 pg/L 11/16/2022 1,2-Dibromo-3-Chloropropane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2-Dibromoethane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2-Dichlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2-Dichloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2-Dichloropropane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1, 3,5-Trimethyl benzene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,3-Dichlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,3-Dichloropropane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,4-Dichlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 2,2-Dichloropropane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 2-Chlorotoluene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 Report #:: 2022-22672 Page 1 of 9 Quible & Associates DateDec 0, 2022 PO Box 870 Manteo Report #: 22M-2686 Kitty Hawk NC 27946 Report #: 2022-22672 Attention: Customer ID: 0100100 Project ID: Stevens Towing MW 4-Chlorotoluene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 Benzene SW 846 Method 8260D/5030B <0.5 p/L 11 /16/202 Bromobenzene SW 846 Method 8260D15030B <0.5 p /L 11 /16/2022 Bromochloromethane SW 846 Method 826OD15030B <0.5 p /L 11 /16/ 022 Bromodichloromethane SW 846 Method 8260D/5030B <0.5 p/L 11/16/2022 Bromoform SW 846 Method 8260D15030B <0.5 p /L 11 /16/ 022 romomethane SW 846 Method 8260D15030B <0.5 p /L 11/16/2022 Carbon tetrachloride SW 846 Method 8260D/5030B <0.5 p/L 11 /16/022 Chlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/202 Chloroethane SW 846 Method 8260D15030B <0.5 p /L 11/16/2022 Chloroform SW 846 Method 8260D/5030B <0.5 p/L 11/16/2022 Chloromethane SW 846 Method 826OD15030B <0. p /L 11 /16/ 02 cis- 1,2-Dichloroethene SW 846 Method 8260D/5030B <0. p /L 11/1 / 022 cis-1,3-ichloropropene SW 846 Method 8260D/5030B <0.5 p/L 11/16/2022 Dibromochloromethane SW 846 Method 8260D/5030B <0.5 p/L 11 /16/022 ibroomethane SW 846 Method 8260D/5030B <0. p/L 11 /16/2022 Dichlorodifluoromethane sw 846 Method 8260D15030B <0.5 p /L 11/16/ 022 Ethylbenzene SW 846 Method 8260D/5030B <0.5 p/L 11 /16/202 Hexachlorobutadiene SW 846 Method 8260D/5030B <0.5 p/L 11/16/2022 Isopropylbenzene SW 846 Method 8260D/5030B <0.5 p/L 11/16/022 +P Xylene SW 846 Method 8260D/5030B <1.0 p/L 11 /16/022 Methylene chloride SW 846 Method 8260D/5030B <0.5 p/L 11 /16/02 Naphthalene SW 846 Method 8260D/5030B <0. p/L 11 /16/202 n-Butylbenzene SW 846 Method 8260D/5030B <0.5 p /L 11 /16/ 022 n-Propylbenzene SW 846 Method 8260D/5030B <0.5 p/L 11 /16/202 ortho-Xylene SW 846 Method 8260D/5030B <0. p/L 11 /16/02 p-Isopropyltoluene sw 846 Method 8260D/5030B <0. p/L 11 /16/02 sec-B utyl benzene SW 846 Method 8260D/5030B <0.5 p/L 11 /16/02 Styrene SW 846 Method 8260D/5030B <0. p/L 11/16/2022 tent-Butylbenzene SW 846 Method 8260D/5030B <0.5 p/L 11 /16/2022 Tetrachloroethene SW 846 Method 8260D15030B <0. p /L 11 /16/ 022 Toluene SW 846 Method 8260D/5030B <0.5 p/L 11/16/2022 Trans- 1,2-Dichloroethene SW 846 Method 8260D/5030B <0. p/L 11 /16/022 Trans-1,3-dichloropropene SW 846 Method 8260D/5030B <0.5 p /L 11/16/2022 Trichloroethene SIN 846 Method 8260D/5030B <0.5 p/L 11/16/2022 Trichlorofluoromethane SW 846 Method 8260D/5030B <0. p/L 11/16/02 Report ::2022-22672 Page 2 of 9 Quible & Associates Date of Report: Dec 06, 2022 PO Box 870 Manteo Report #: 22M-2686 Kitty Hawk NC 27946 Report #: 2022-22672 Attention: Customer ID: 08100100 Project ID: Stevens Towing MW Mae Vinyl chloride SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 Nitrate Nitrogen (Calc) Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2 0, 1993 0.63 mg/L 11/16/2022 Nitrate Nitrogen Subtraction Method 0.63 mg/L 12/02/2022 Lab ID Sample ID: M-3712 Collect Date/Time Matrix Sampled by 22-55677 Site: MW-1 11114/2022 10:50 AM Water Troy Murphy Test Method Results Date Analyzed Nitrite Nitrogen SM 4500 NO2 B-2011 <0.02 mg/L 11/16/2022 Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100ml- 11/14/2022 Report #:: 2022-22672 Page 3 of 9 Quible & Associates Date of Report: Dec 06, 2022 PO Box 870 Manteo Report #: 22M-2686 Kitty Hawk NC 27946 Report #: 2022-22672 Attention: Customer ID: 08100100 Project ID: Stevens Towing MW Lab ID Sample ID: Collect Datome Matrix Sampled by 22-55678 Site: MW-3 11/14/2022 10:20AM Water Troy Murphy Test Method Results Date Analyzed Lead EPA 200.7, Rev 4.4, 1994 0.028 mg/L 11/29/2022 Manganese EPA 200.7, Rev 4.4, 1994 0.154 mg/L 11/29/2022 Nickel EPA 200.7, Rev 4.4, 1994 0.027 mg/L 11/29/2022 Barium EPA 200.7, Rev. 4.4, 1994 0.179 mg/L 11/29/2022 Chromium EPA 200.7, Rev. 4.4, 1994 0.062 mg/L 11/29/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0,1993 < 0.2 mg/L 11/22/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 165 mg/L 11/15/2022 Total Phosphorus SM 4500 P (F-H)-2011 0.63 mg/L 11/23/2022 Total Organic Carbon (TOC) SM 5310 B-2014 9.2 mg/L 11/15/2022 Chloride SM4500 CI E-2011 < 5 mg/L 11/16/2022 1, 1, 1,2-Tetrachloroethane SW 846 Method 8260D/5030B <0. 5 pg/L 11/16/2022 1, 1, 1 -Trichloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1, 1,2,2-Tetrachloroethane SW 646 Method 8260D/5030B <0.5 pg/L 11/16/2022 1, 1,2-Trichloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,1-Dichloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,1-Dichloroethene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,1-Dichloropropene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2,3-Trichlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2,3-Trichloropropane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2,4-Trichlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2,4-Trimethylbenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2-Dibromo-3-Chloropropane SW 846 Method 8260D15030B <0.5 pg/L 11/16/2022 1,2-Dibromoethane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2-Dichlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2-Dichloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,2-Dichloropropane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,3,5-Trimethylbenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,3-Dichlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,3-Dichloropropane SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 1,4-Dichlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/16/2022 2,2-Dichloropropane SW 846 Method 8260D15030B <0.5 pg/L 11/16/2022 2-Chlorotoluene SW 846 Method 8260D/5030B <0-5 pg/L 11/16/2022 Report #:: 2022-22672 Page 4 of 9 Quible & Associates Date o Dec 06, 2022 PO Box 870 Manteo -66 Kitty Hawk NC 202-22672 Attention: Customer ID: 0100100 Project ID: Stevens Towing MW -Chlorotoluene SW 846 Method 8260D/5030B <0.5 p /L 11 /16/ 022 Benzene SW 846 Method 8260D15030B <0.5 p /L 11 /16/202 romobenzene SW 846 Method 8260D/5030B <0. p /L 11 /16/ 0 2 romochlorometh ne SW 846 Method 8260D/5030B <0. p /L 11/16/ 02 romodichloromethane SW 846 Method 8260D15030B <0.5 p /L 11/16/ 022 Bromoform SW 846 Method 8260D/5030B <0.5 p /L 11 /16/ 022 Bromomethane SW 846 Method 8260D/5030B <0. pg/L 11/16/2022 Carbon tetrachloride SW 846 Method 8260D/5030B <0. p /L 11/16/2022 Chlorobenzene SW 846 Method 8260D/5030B <0.5 p /L 11 /16/ 02 Chloroethane SW 846 Method 8260D/5030B <0.5 p /L 11 /16/ 02 Chloroform SW 846 Method 826OD/5030B <0. p /L 11/16/2022 Chloromethane SW 846 Method 8260D/5030B <0.5 p /L 11/16/ 02 cis- 1,2-Dichloroethene SW 846 Method 8260D/5030B <0.5 p /L 11 /16/ 0 2 cis- 1,3-Dichloropropene SW 846 Method 826oD/5030B <0. p /L 11/16/2022 ibromochloromethane SW 846 Method 8260D/5030B <0. p /L 11/16/2022 Dibromomethane SW 846 Method 8260D/5030B <0. p /L 11 /16/ 0 2 Dichlorodifluoromethane SW 846 Method 8260D/5030B <0. p /L 11/16/2022 Ethylbenzene SW 846 Method 8260D/5030B <0. p /L 11/16/2022 Hexachlorobutadiene SW 846 Method 8260D/5030B <0. p /L 11 /16/ 022 Isopropylbenzene SW 846 Method 8260D15030B <0.5 p /L 11/16/ 022 +P Xylene SW 846 Method 8260D/5030B <1.0 p /L 11 /16/20 2 Methylene chloride SW 846 Method 8260D/5030B <0. p /L 11 /16/ 02 Naphthalene SW 846 Method 8260D/5030B <0. p /L 11 /16/ 02 n- utylbenzene SW 846 Method 8260D/5030B <0.5 p /L 11 /16/2022 n-Propylbenzene SW 846 Method 8260D/5030B <0.5 p /L 11 /16/ 02 ortho- ylene SW 846 Method 826oD/5030B <0.5 p /L 11/16/2022 p-Isopropyltoluene SW 846 Method 8260D/5030B <0.5 p/L 11/16/2022 sec -Butyl benzene SW 846 Method 8260D/5030B <0.5 p /L 11 /16/ 02 Styrene SW 846 Method 8260D/5030B <0.5 p /L 11 /16/ 022 tert-B utyl benzene SW 846 Method 8260D/5030B <0.5 p /L 11/16/2022 Tetrachloroethene SW 846 Method 8260D/5030B <0. p /L 11/16/2022 Toluene SW 846 Method 8260D/5030B <0. p /L 11 /16/ 02 Trans- 1,2-Dichloroethene SW 846 Method 8260D15030B <0.5 p /L 11/16/ 02 Trans-1,3-dichloropropene SW 846 Method 8260D/5030B <0.5 p /L 11/16/2022 Trichloroethene SW 846 Method 8260D/5030B <0.5 p /L 11 /16/2022 Trichlorofluoromethane SW 846 Method 826oD/5030B <0.5 p /L 11 /161202 Report ::2022-22672 Page 5 of 9 Quible & Associates PO Box 870 Kitty Hawk NC 27946 Attention: Vinyl chloride Nitrate Nitrogen (Calc) Nitrate+Nitrite-Nitrogen Nitrate Nitrogen Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 11 910.392.0223 Lab 11 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 11 252,473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 1" 910.347.5843 Lab/Fax infogenvironmentalchemists.com AT1111-11 " OF, M. TIM VZ141 film-ORM EPA 353.2, Rev. 2.0,1993 Subtraction Method Date of Report: Dec 06, 2022 Manteo Report #: 22M-2686 Report #: 2022-22672 Customer ID: 08100100 Project ID: Stevens Towing MW 9f 0 mom Him$ WNIMPTIT17 Report M 2022-22672 Page 6 of 9 Test . . ......... Method — . . ........... . . . .. Results . ....... . .......... . Date Analyzed .. . . .. . . . ........ Lead EPA 200.7, Rev 4.4, 1994 0.022 mg/L 11/29/2022 Manganese EPA 200.7, Rev 4.4, 1994 0.078 mg/L 11/29/2022 Nickel EPA 200.7, Rev 4.4, 1994 <0.01 mg/L 11/29/2022 Barium EPA 200.7, Rev. 4.4,1994 0.148 mg/L 11/29/2022 Chromium EPA 200.7, Rev. 4.4, 1994 0.040 mg/L 11/29/2022 Ammonia Nitrogen EPA 350. 1, Rev. 2.0, 1993 < 0.2 mg/L 11/18/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 237 mg/L 11/15/2022 Total Phosphorus SM 4500 P (F-H)-2011 0.62 mg/L 11/23/2022 Total Organic Carbon (TOC) SM 5310 B-2014 18.7 mg/L 11/15/2022 Chloride SM4500 CI E-2011 24 mg/L 11/16/2022 1, 1, 1,2-Tetrachloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1, 1, 1 -Trichloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1, 1,2,2-Tetrachloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1, 1,2-Trichloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1,1-Dichloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1,1-Dichloroethene SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1,1-Dichloropropene SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1,2,3-Trichlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1,2,3-Trichloropropane SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1,2,4-Trichlorobenzene SW 846 Method 8260D15030B <0.5 pg/L 11/17/2022 1,2,4-Trimethylbenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1,2-Dibromo-3-Chloropropane SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1,2-Dibromoethane SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1,2-Dichlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1,2-Dichloroethane SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1,2-Dichloropropane SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1, 3,5-Trimethyl benzene SW 846 Method 826OD15030B <0.5 pg/L 11/17/2022 1,3-Dichlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1,3-Dichloropropane SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 1,4-Dichlorobenzene SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 2,2-Dichloropropane SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 2-Chlorotoluene SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 Report #:: 2022-22672 Page 7 of 9 Quible & Associatesto Dec 0, 2022 PO Box 7 : 22 -266 Kitty7 02-22672 Attention: Customer ID: 0100100 Project ID: Stevens Towing MW -Chlorotoluene SW 846 Method 8260D/5030B <0.5 p/L 11/17/02 Benzene SW 846 Method 8260D/5030 <0. p/L 11/17/2022 Bromobenzene SW 846 Method 8260D/5030B <0.5 p/L 11/17/2022 Bromochloromethane SW 846 Method 8260D/5030B <0.5 p/L 11/17/2022 Bromodichloromethane SW 846 Method 8260D/5030B <0.5 p/L 11/17/2022 Bromoform SW 846 Method 8260D15030 <0.5 p /L 11/17/2022 r0 O ethane SW 846 Method 8260D/5030B <0.5 p/L 11/17/2022 Carbon tetrachloride SW 846 Method 8260D/5030B <0. p/L 11/17/202 Chlorobenzene SW 846 Method 8260D/5030B <0.5 p/L 11/17/02 Chloroethane SW 846 Method 8260D/5030B <0.5 p/L 11/17/2022 Chloroform SW 846 Method 8260D/5030 <0.5 p/L 11/17/2022 Chloromethane SW 846 Method 8260D/5030B <0.5 p/L 11/17/02 cis-1,- iclrete SW 846 Method 8260D/5030B <0. p/L 11/17/2022 cis-1,- ichloropropene SW 846 Method 8260D/5030B <0.5 p/L 11/17/2022 ibro ochloro ethane SW 846 Method 8260D/5030 <0.5 p/L 11/17/202 Dibromomethane SW 846 Method 8260®/5030B <0. p/L 11/17/2022 Dichlorodifluoromethane SW 846 Method 8260D/5030 <0. p/L 11/17/02 t yl enzene SW 846 Method 8260D/6030B <0.5 p /L 11/17/2022 Hexachlorobutadiene SW 846 Method 8260D/5030B <0.5 p/L 11/17/202 Isopropyl benzene SW 846 Method 826oD/5030B <0.5 p/L 11/17/2022 M+P XyleneSW 846 Method 8260D/5030B <1.0 p/L 11/17/2022 Methylene chloride SW 846 Method 8260D/5030B <0.5 p/L 11/17/2022 Naphthalene SW 846 Method 8260D/5030B <0.5 p/L 11/17/2022 n-Butylbenzene SW 846 Method 8260D/5030B <0.5 p/L 11/17/2022 n-Propylbenzene SW 846 Method 8260D/5030 <0.5 p/L 11/17/2022 ortho-Xylene SW 846 Method 8260D/5030B <0.5 p/L 11/17/2022 p-Isopropyltoluene SW 846 Method 8260D/5030B <0. p/L 11/17/2022 sec-B utylbenzene SW 846 Method 8260D/5030B <0.5 p/L 11/17/02 Styrene SW 846 Method 8260D/5030B <0.5 p/L 11/17/2022 tert-B utylbenzene SW 846 Method 8260D/5030B <0.5 p/L 11/17/202 Tetrachloroethene SW 846 Method 8260D/5030 <0. p/L 11/17/2022 Toluene SW 846 Method 8260D/5030B <0.5 p /L 11/17/2022 Trans- 1,- ich loroeth ene SW 846 Method 8260D/5030B <0. p/L 11/17/2022 Trans-1,- ichloropropene SW 846 Method 8260D/5030B <0.5 p/L 11/17/202 Trichloroethene SW 846 Method 8260D/5030B <0. p/L 11/17/202 Trichlorofluoromethane SW 846 Method 8260D/5030B <0.5 p/L 11/17/02 Report ::2d22-22672 Page 8 of 9 Quible & Associates Date of Report: Dec 06, 2022 PO Box 870 Manteo Report #: 22M-2686 Kitty Hawk NC 27946 Report #: 2022-22672 Attention: Customer ID: 08100100 Project ID: Stevens Towing MW Vinyl chloride SW 846 Method 8260D/5030B <0.5 pg/L 11/17/2022 Nitrate Nitrogen (Calc) Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2.0,1993 0.98 mg/L 11/16/2022 Nitrate Nitrogen Subtraction Method 0.98 mg/L 12/02/2022 Lab ID Sample ID: M-3713 Collect Date/Time Matrix Sampled by 22-55680 Site: MW-3 11/14/2022 10:20 AM Water Troy Murphy Test Method Results to Analyzed Nitrite Nitrogen SM 4500 NO2 B-2011 <0.02 mg/L 11/16/2022 Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100ml- 11/14/2022 Lab ID Sample ID: M-3714 Collect Date/Time Matrix Sampled by 22-55681 Site: MW-4 11/14/2022 11:35 AM Water Troy Murphy Test Method Results Date Analyzed Nitrite Nitrogen SM 4500 NO2 B-2011 <0.02 mg/L 11/16/2022 Fecal Coliform SM 9222 D-2015 MIF <1 Colonies/100ml- 11/14/2022 Comment: Reviewedby: . ........ . ... . ................... ....................... t,7- "I'l""I'll""I'll'll""I'll""IlI . . . ........................................................................... . ... Report #:: 2022-22672 Page 9 of 9 Environmental Chemist, Inc., Wilmington, NC Lab #94 6602 Windmill Way W'WGllr'raiingtcun, NC 2 405 91 .392.0223 Sample Recelpt Checklist CNient°_ R Date; �/._...�....... :. ......... Report Number: _ 2022 uceceiput raf sarnpue: .... L.C.t-�EM V:z CkU V. ............................._ Ciienl; Delivery Y.:::::::Y JV�S I!::::... FeriG=x N G� (I the0.. N::V:� YES CW6t ��/ere ....____. _ ._____ .._ cuu.s'taady seeps present on tG'tie caacallsar? ..,,..... YES N` O N`�/ �Lf cuast�dy .seak w pre p:uresent, Welre they intact/u.ur' b intact/unbroken? T. o .............. .......... b V ................. Na Original temperature upon recerp�t. Colrrected temperature gun receill�t......... ..Guavur ter'npaer«a'tuure taV<eru ®® If. �N...... erat:uure V Nan&C II. i�ppa6n...„t V3ottNes _ Ift C'::tuun III.) ..... Thomas -rraceabe .S/IV 192.511657 IR Gun Correction Factor �C 0J.z .. YES Nl NO 1...If temperature of cooler exceeded " was I1:1raaject Mgr./QA notified? N YES -YES II.°°p NO 4. Were proper custody procedures (reNGnquuished/received) followed? ff N._G N�0 5, WWere sarnpGe IIN)'s Misted on.. t av .......... YES "...G NO ....................... 6. Were saarnjpNes III "s Nusted on salrnpa e containers? YIPS 0 NO ........ ..`..m _ 7. Were coHec::tion date and time listed on The COU .............. YES N ... ............... _ ............ ®....................... 8. Were tests to be performed fisted on the COC? .. Vel0 ............... 9. Did samples arrive in proper containers for each 'te.st? _...... . 10. Did -samples arrive in good con diu'ti on for each test? .......................YII:::S ...... El ...INO 11. Was adequate e samplevoCu.uu"ne QuvauVa:uhVe;" 13 YES 13 NO 12 Were sarripu es received Within p rq:")er ho"Iding time for reqU steel tests? ............... YIf. S D NO .1.3. Were acid preserved salrnpa es received at a p l-I of �2? FJ YES NO _ 1.4. Were cyanide samples received at au pH :r12? YES p.. p NC) .15. Were surrlfade samples received' at a p:1H >9? YES NO .N0, 16. Were NH3 FKN I'Ihen0 (received at a chlorine resudu.uaY of <6.6 n1 /L, u�l Yes u �.� t.-Were SuuVfVde/Q:yalnuda receuvu"d at a chVol pne resualuuaall of6. u�u/P_: V� Y E % �I Wt/a�re ortG'wo�rltiospalY�ate sau paves filtered in the fueVd WGtGDGn .S rrwiln�utes? FOC/`wColatiles are pH checked at time of analysis and recorded on the bench sheet. Bacteria: samples are checked for Chlorine at time of analysis and recorded on the benchsher.:=.t. Sample Preservation: (Must be completed for any .saampa e(s) lncorrecdy preserved or with Iheadspaace) Sarnpa e(s) ...... were received Incorrectly preserved and Were adjustedaccordln,& by adding (clrcVeone): II-I2,SO4 NGN03 NG N NaOV 1 Time of pareselrvatlon4 If more than one preservative Is needed, notate in comments below Dote: Notify custorner .service immedsateiy for, incorrectly prRreserrred sarnp les. Curtain a new .sample or notify the state Iah if directed to analyzed by the ccr.storner. Who was notified, date and time VoVat0es SaauqAe(s) were received With headspaace HUM DOC. QA,002 IRev 1 R 6602 Windmill Way Wilmington, NC 28405 4=10 ENVIRONMENTAL CHEMISTS, INC OFFICE: 910-392-0223 FAX 910-392-4424 Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 info@environmentalchemists.com f"s I I &I ^InA IIL I �I— Client: Quible and Associates PROJECT NAME: Stevens Towl!jg�-qenton, NC 'ADDRESS: Post Office Drawer 870 Permit: WAnil. 72 !PO NO: Kitty Hawk, NC 27966 REPORT TO: Brian Rubino P.G. PHONE/FAX: 'COPY TO: Simon Rich/Stevens Towing A!mail: brubino@ Au �Jblexom Depth to water: I Gallons Bailed: I— F of 3 wells (19394) due in Transfer ---- CoNection 410 rch, July and November. 2. Cj\1 1 lu Temperature when Received — x Accepted: Rejeelt Delivered By: Received By: Comments: 8136- Q-11&493M M--7ML*=- ANALYSIS REQUESTED (Chloride, NO2, TIDS NH3, NO3, TP Z— 2 Ba, Cr, Plb, Mn, Ni Fecal Coliform uested: 42---Time: -- ------------ 3UND: I 6602 Windmill Way Wilmington, NC 28405 4=D) ENVIRONMENTAL CHEMISTS, INC OFFICE: 910-392-0223 FAX 910-392-4424 Analytical & Consulting Chemists NCIDENR: DWO CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 info@environmentalchemists.com ADDRESS: Post Office Drawer 870 Permit: WQ0040672 PO NO: Kitty Hawk, NC 27966 REPORT TO: Brian Rubino, P.G. �PHONE/ AX 100=11 COPY TO: Simon Rich/Stevens Towing email: brubin2 le.corg SAMPLE TYPE: I = Ixf1upTit- F =rZghipmt X#1 QT QZ Sample Identification Date MW Collection E Time M MIR C 0 PRESERVATION U3 M W a S E 0 0 z z z z x i L LU ANALYSIS REQUESTEL) iE Chloride, NO2, TDS DePih to water: C P X-_ NHi, NO3, TP' G G Gallons Bailed.- C P X 13a, Cr, Pb, Mn, Ni G G PH(fieldh Wol C P x Coliform G G Color: YCG I C P I x --Fecal TOC G G Odor, Vlid~ x VOC'L(Novernber� G G C P G G C P G G Total of 3 wells (1,3,4) due in March. JuIv and November - Relinquished By: pir eceived By: 71 12 Temperature when lkecefvecQ�l 1 -:2- Accepted: xe;' Rejected: Resample Req sted: ue Delivered ByR : t eceived By: Time: Date:. 1'14�12 Comments: TURNAROUND: M ,'Gallons Bailed: 0, 5" Odor: Delivered By: Comments: 6602 Windmill Way Wilmington, NC 28405 ENVIRONMENTAL CHEMISTS, INC OFFICE: 910-392-0223 FAX 910-392-4424 NCDENR: DWQ CERTIFICA71ON # 94 NCDHHS: DLS CERTIFICATION # 37729 info@environmentalchemists.com COLLECTION AND CHAIN OF CUSTODY Alm- ROJECT NAME: Stevens Towinj:Edenton, NC REPORT NO: A - Perrnit: 2 WQ0040672 �EPORT TO: Brian WRubino, P.G. �= PHONE/FAX: email: brubiq!�@quible.com ANALYSIS REQUESTED NIIIIIIIIwQ M x NH3, NO3, TP _U X Ba- Cr Ph Mn, Ni x iFecal Coliform x TOG FI VOC's Movember) ested: Time: