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Home My WebLink AboutWQ0005763_Regional Office Physical File Scan Up To 11/29/2022Price, Bev From: Wessner, Alice Sent: Wednesday, September 08, 2010 2:33 PM To: Price, Bev Subject: RE: Tuckaseigee WASA Thanks. Short and sweet. I like it. Alice M. Wessner Environmental Engineer Land Application Unit Aquifer Protection Section Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 919-715-5208 919-715-0588 (fax) http://h2o.enr.state.nc.us/aps/lau.htm From: Price, Bev Sent: Wednesday, September 08, 2010 1:17 PM To: Wessner, Alice Subject: RE: Tuckaseigee WASA yes Bev Price - Bev.Price@ncdenr.gov North Carolina Dept. of Environment and Natural Resources Asheville Regional Office Division of Water Quality - Aquifer Protection Section 2090 U.S. 70 Highway Swannanoa, NC 28778 Tel: 828-296-4500 Fax: 828-299-7043 Notice: This e-mail contains a public record which is subject to disclosure to third parties and the public pursuant North Carolina's Public Records Law. N.C. Gen. Stat. §132-1, et seq. This e-mail may contain materials prepared during or in anticipation of a legal proceeding as part of preparation for that legal proceeding, in which case third party or public access to it is subject to N.C. Gen. Stat. §132-1.9 and may be denied until the conclusion of the legal proceeding, including the completion of all appeals and post -judgment proceedings, or, in the case where no legal proceeding has been commenced, upon the expiration of all applicable statutes of limitations and periods of repose. From: Wessner, Alice Sent: Wednesday, September 08, 2010 11:53 AM To: Price, Bev Subject: Tuckaseigee WASA I read your staff report and the amendments. So you are satisfied with the results of the analysis that they sent you and therefore they have complied with the requirements of their violation? Thanks. Alice M. Wessner Environmental Engineer Land Application Unit Aquifer Protection Section Division of Water Quality 1636 Mail Service Center Raleigh, NC 27699-1636 919-715-5208 919-715-0588 (fax) http://h2o.enr.state.nc.us/aps/lau.htm Il Vs �FWPIMV State of North Carolina Department of Environment and Natural Resources Division of Water Quality September 1, 2010 To: Aquifer Protection Section Central Office Attn: Alice Wessner From: Bev Price Asheville Regional Office I. GENERAL SITE VISIT INFORMATION 1. Was a site visit conducted? ® Yes or ❑ No Aquifer Protection Section Regional Staff Report Application No.: W00005763 Regional Login No.: a. Date of site visit: 5/6/10 - Annual Compliance Evaluation Inspection - Attached b. Site visit conducted by: Bev Price c. Inspection report attached? ® Yes or ❑ No d. Person contacted: Stan Bryson and their contact information: (828) 586 - 9318 ext. e. Driving directions: Correct in BIMS H. PROPOSED FACILITIES FOR NEW AND MODIFICATION APPLICATIONS 1. Facility Classification: (Please attach completed rating sheet to be attached to issued permit) . 2. Are the new treatment facilities adequate for the type of waste and disposal system? ❑ Yes or ❑ No If no, explain: 3. Are site conditions (soils, depth to water table, etc) consistent with the submitted reports? ❑ Yes ❑ No ❑ N/A If no, please explain: 4. Do the plans and site map represent the actual site (property lines, wells, etc.)? ❑ Yes ❑ No ❑ N/A If no, please explain: 5. Is the proposed residuals management plan adequate? ❑ Yes ❑ No ❑ N/A If no, please explain: 6. Are the proposed application rates (e.g., hydraulic, nutrient) acceptable? ❑ Yes ❑ No ❑ N/A If no, please explain: 7. Are there any setback conflicts for proposed treatment, storage and disposal sites? ❑ Yes or ❑ No If yes, attach a map showing conflict areas. 8. Is the proposed or existing groundwater monitoring program adequate? ❑ Yes ❑ No ❑ N/A If no, explain and recommend any changes to the groundwater monitoring program: 9. For residuals, will seasonal or other restrictions be required? ❑ Yes ❑ No ❑ N/A If yes, attach list of sites with restrictions (Certification B) FORM: APSRSR 04-10 Page 1 of 3 M. EXISTING FACILITIES FOF_ ,.-JDIFICATION AND RENEWAL API---'ATIONS 1. Are there appropriately certified Operators in Charge (ORCs) for the facility? ❑ Yes ❑ No ® N/A ORC: Certificate #: Backup ORC: Certificate #: 2. Are the design, maintenance and operation of the treatment facilities adequate for the type of waste and disposal system? ® Yes or ❑ No If no, please explain: 3. Are the site conditions (e.g., soils, topography, depth to water table, etc) maintained appropriately and adequately assimilating the waste? ❑ Yes or ❑ No NA If no, please explain: 4. Has the site changed in any way that may affect the permit (e.g., drainage added, new wells inside the compliance boundary, new development, etc.)? ❑ Yes or ® No If yes, please explain: 5. Is the residuals management plan adequate? ® Yes or ❑ No If no, please explain: 6. Are the existing application rates (e.g., hydraulic, nutrient) still acceptable? ❑ Yes or ❑ No If no, please explain: NA 7. Is the existing groundwater monitoring program adequate? ❑ Yes ❑ No ® N/A If no, explain and recommend any changes to the groundwater monitoring program: 8. Are there any setback conflicts for existing treatment, storage and disposal sites? ❑ Yes or ® No If yes, attach a map showing conflict areas. 9. Is the description of the facilities as written in the existing permit correct? ® Yes or ❑ No If no, please explain: 10. Were monitoring wells properly constructed and located? ❑ Yes ❑ No ® N/A If no, please explain: 11. Are the monitoring well coordinates correct in BIMS? ❑ Yes ❑ No ® N/A If no, please complete the following (expand table if necessary): Monitoring Well Latitude Longitude O / rr O , it o , rr o , it o r rr o r rr 0 r rr o r n o r rr 0 r rr 12. Has a review of all self -monitoring data been conducted (e.g., NDMR, NDAR, GW )? ® Yes or ❑ No Please summarize any findings resulting from this review: 13. Are there any permit changes needed in order to address ongoing BIMS violations? ❑ Yes or ® No If yes, please explain: 14. Check all that apply: ❑ No compliance issues ® Notice(s) of violation ❑ Current enforcement action(s) ❑ Currently under JOC ❑ Currently under SOC ❑ Currently under moratorium Please explain and attach any documents that may help clarify answer/comments (i.e., NOV, NOD, etc.) Issued NOV for failure to monitor Ignitability, Corrosivity and Reactivity for 2009 - see attached 15. Have all compliance dates/conditions in the existing permit been satisfied? ❑ Yes ❑ No ® N/A If no, please explain: FORM: APSRSR 04-10 Page 2 of 3 16. Are there any issues related t mpliance/enforcement that should be rest i before issuing this permit? ❑ Yes ®No❑N/A If yes, please explain: IV. REGIONAL OFFICE RECOMMENDATIONS 1. Do you foresee any problems with issuance/renewal of this permit? ❑ Yes or ® No If yes, please explain: 2. List any items that you would like APS Central Office to obtain through an additional information request: Item Reason 3. List specific permit conditions recommended to be removed from the permit when issued: Condition Reason 4. List specific special conditions or compliance schedules recommended to be included in the permit when issued: Condition Reason 5. Recommendation: ❑ Hold, pending receipt and review of additional information by regional office ® Hold, pending review of draft permit by regional office ❑ Issue upon receipt of needed additional information ❑ Issue ❑ Deny, (Please st to rea s: ) 6. Signature of report preparer: .fit/ivt-Cis,-- Signature of APS regional supervisor: Date: i C) V. ADDITIONAL REGIONAL STAFF REVIEW ITEMS FORM: APSRSR 04-10 Page 3 of 3 DATE �. 1 . L / S R I��I'{'6L f � •.. R GE. �' �XI!T,C.`U.DiYNG G 'S'EPA ) .. :... :. • '..::...-.�.-; - ""'-ate...:.,..: _�r-_' . . - Aug.31, 2010 4:16PM No.0228 P. 2 Tuckaseigee Water & Sewer Authority Serving Jackson County 1246 West Main Street Soya, NC 28779 Ph. (828) 586-5189 Fax (828) 631-9089 August 31, 2010 Attn: Bev Price NC DENR/DWQ Aquifer Protection Section -.Asheville Regional Office 2090 US Highway 70 Swannanoa NC 28778=8211 Subject: N'OV-2010-PC-0613 Permit #WQ0005763 Dear Ms. Price, The Corrosivity, Ignitability, and Reactivity analysis was inadvertently left off of the analysis conducted on TWSA's lime residual during 2009. This error became apparent when I started to put together the 2009 sludge report. Due to construction, the TWSA has not been generating residuals since the beginning of 2010 but we have been dewatering raw sludge and sending this product to the landfill. I had the subject analysis performed on this raw sludge. Additionally there was a small quantity of residuals left on the storage pad (< 50 lbs) and we had the analysis performed on this material. I have forwarded you a copy of these results. Please contact .me with any questions or comments. Sincerely, Stan Bryson Wastewater Plant Operations Superintendent Tuckaseigee Water and Sewer Authority xc: 1V4r. Joe Cline, Executive Director, TWSA i Aug, 31. 2010 4:16PM � + e (_,111arceAnolytical ww+lpaubreoa.cw/r March 30, 2010 Mr. Stan Bryson Tuckase'igee Water & Sewer Co. 1246 West Main Street Sylva, NC 28779 RE: Project: TWSA Lime & Sludge Analysis Pace Project No.:-9265144 Pace Analytical Serylces, Inc. 2225 Riverside Dr, Asheville, NC 28804 (828)254-7978 • -' -mil i No, 0228 Pace Analytical Services, Inc, 9800 Kincey Ave. Suite 100 Huntersville, NO 2BD78 (704)875-9092 Dear Mr. Bryson: Enclosed are the analytical results for sample(s) received by the laboratory -on March 11, 2010. The results relafe only to the samples included in this report. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals analyses were performed at our face Asheville laboratory and Organic testing was performed at our Pace Huntersville laboratory. unless otherwise footnoted. All Microbiological analyses were performed at the laboratory where the samples were received. If you have any questions concern inq'this report, please feel free to-contnf-t, mP !�jc`• f v• mix`. o= _� _ - -..-._.- wrri.wuiiari�twNexc:�IdUS.t;utn - . Project Manager Ericl�res - 5 REPORT OF LABOaATORY ANALYSIS This report shall not be reproduced, except in full, Without the wrlttgn consent of Pace Analytical Services, Inc-- w Aoco. Pago i of i Aug, 31. 2010 4:16PM No.0228 P. 4 MflSUMMIT ENVIRONMENTAL TECHNOLOGIES, INC. Analytical Laboratories Client 1 # collected Anelvtc TW-SA lime Residual 1003491-01 11-Mar-10 Flash Point lent # J a¢jL Collected Andyte TWSA lime Residual 1003491-01 11-Mar-10 pH Ghent ID# Lab by Collected Analvtc TWSA Lime Residual 1003491-01 11-Mar-10 Reactive Cyanide Lab 1D# Colleded Analvte TWSA lime Residual 1003491-01 11-Mario Reactive Sulfide gimlo- J ID# ]acted Analvtc TWSA Raw Sludge 1003491-02 11-Mar-10 Flash Point cligll I Lab 1D# Collected Anal% TWSA Raw Sludge 1003491-02 11-Mar-10 PH MMLIDM Lab 1D# Collected Anal3d TWSA Raw Sludge 1003491-02 11•Mar-10 Reactive Cyanide Client 1 # .Lab 1Y7# olleeted Anal3a TWSA Raw Sludge 1003491-02 11-Mar-10 Reactive Sulfide 4. v March 22, 2010 Client: Pace Analytical Services, Inc. Address: 2225 Riverside Drive Asheville, NC 28804 Received: 3/12/2010 Project #: 9265144 Rdsult Units MaJdX Method DF Run Anaiyst 5-140F S 1010 1 12-Mar-SO DVW Result UdI t ix Me r DF LO(1 Run Analvst 11.16 su®19.9C S 9040 1 0.01 15-Mar-10 CXS Result 11D& Matrix Method DF QQ Run &Alyst ND mg/kg S 7.3.3.2 1 0.5 16-Mar-10 TRB $0uh JhiiLs Matrix Mabod DF I-00 Run Analyst ND mg/kg 5 7.3.4.2 1 25 16-Mar-10 TRg Rtsult Dmits Matrix Method DF 1. 0 Run Aga Lst > 14OF 5 1010 1 12-Mar-10 DVW Bgguit llQlts Matrix Ms3t1od D� LOQ. sp Malyst 6.54 su@19.4C S 9040 i 0.01 15-Mar-10 CXS 13a.S111_t its Matrix M" DF LOO Run AnAlysl ND mg/kg S 7.3.3.2 1 0.5 16-Mar-10 TRB B-Im t SjpL Matrix Method DIP = Run Analyst ND mg/kg S 7.3.4.2 1 25 16-Mar-10 TRB Page 4 "Analytical Integrity" - EPA Certified - NELAP Certified 3310 Win Street - Cuyahoga I=ails, Ohio 44223 • Phone: 330-253-8211 - Fax: 330-2553-4489 Web Site; www.settek.com ACDENR North Carolina Department of Environment and Natural Resources Division of Water Quality Beverly Eaves Perdue Coleen H. Sullins Dee Freeman Governor Director Secretary May 24, 2010 CERTIFIED MAIL 7009 1680 0000 7514 7577 RETURN RECEIPT REQUESTED RECEIPT # Joe Cline, Director Executive Tuckaseigee Water & Sewer Authority 1246 W. Main St. Sylva, NC 28779 Subject: Notice of Violation NOV-2010-PC-0613 Permit No. WQ0005763 JacksonCounty Dear Mr. Cline, On May 6, 2010, staff of the NC Division of Water Quality (DWQ), Aquifer Protection Section (APS), inspected the subject wastewater treatment and disposal system. We wish to thank Mr. Stan Bryson, who was present and assisted during the inspection. The following item specifies the permit condition that was in violation during the time of the inspection. (Also please refer to the attached inspection report.) III. MONITORING AND REPORTING REQUIREMENTS Condition 3. requires a corrosivity, ignitability and reactivity analysis be conducted by the Permittee annually. A review of the 2009 Annual Report shows that the ignitability and reactivity analysis were not conducted. You are required to provide a written response to this Notice within 15 days of receipt. Please include in your response all corrective actions already taken and a schedule for completion of any corrective actions not addressed. AQUIFER PROTECTION SECTION —Asheville Regional Office (ARO) 2090 U:S. 70 Highway, Swannanoa, NC 28778-8211 Phone: 828-296-4500'\ FAX: 828-299-7043 Customer Service:1-877-623-6748 Internet: www.ncwaterguality.org An Equal Opportunity \ Affirmative Action Employer NorthCarolina Naturally, Mr. Cline Permit No WQ0005763 May 24, 2010 Page 2 of 2 Failure to comply with conditions in a permit may result in a recommendation of enforcement action, to the Director of the Division of Water Quality who may issue a civil penalty assessment of not more that twenty-five thousand ($25,000) dollars against any "person" whoviolates or fails to act in accordance with the terms, conditions, or requirements of a permit under authority of G.S. 143-215.6A. Please note that each day a violation continues may be considered a separate violation, subject to additional civil penalties. If you have any questions concerning this Notice, please contact Beverly Price me at 828-296-4500. Sincerely, G. Landon Davidson, L.G. Aquifer Protection Supervisor attachments: cc: Stan Bryson, WWTP ORC Jac!kpmCounty Environmental Health Department Aquifer Protection Section Central Files R Compliance Inspection Report Permit: WQ0005763 Effective: 08/26/05 Expiration: 07/31/13 Owner: Tuckaseigee Water & Sewer Authority SOC: Effective: Expiration: Facility: TWSA Class A EQ Residuals Production Facility and Distribution Program County: Jackson 1871 N River Rd Region: Asheville Sylva NC 28779 Contact Person: Joe Cline Title: Executive Director Phone: 828-586-5189 Directions to Facility: From the intersection of North River Road (SR 1359) and Hwy. 441 in Dillsboro, turn left onto SR 1359. Travel approximately 2 miles to TWSA Plant#1 on the left. System Classifications: Primary ORC: Certification: Phone: Secondary ORC(s): On -Site Representative(s): 24 hour contact name On -site representative Related Permits: Inspection Date: 06/06/2010 Primary Inspector: Beverly Price Secondary Inspector(s): Stan D Bryson Stan D Bryson Entry Time: 10:00 AM Reason for Inspection: Routine Permit Inspection Type: Distribution of Residual Solids (503) Facility Status: 0 Compliant ■ Not Compliant Question Areas: Miscellaneous Questions 0 Record Keeping ■ Pathogen and Vector Attraction (See attachment summary) Exit Time: 11:00 AM Phone: 828-586-5189 Phone: 828-586-5189 Phone: 828-296-4500 Inspection Type: Compliance Evaluation Treatment 0 Sampling Page: 1 Permit: WQ0005763 Owner - Facility: Tuckaseigee Water & Sewer Authority Inspection Date: 05/06/2010 Inspection Type: Compliance Evaluation Reason for Visit: Routine Inspection Summary: The inspection included a review of 2009 Annual Report. The Ignitability and Reactivity analysis was not conducted in 2009. The WWTP is being upgraded. As part of the upgrade, a Fenton Dryer will be installed to process residuals. Residuals have been hauled to the landfill since Jan. 2010, they do not expect to produce any Class A product this year. The permit should be modified to include the Whittier WWTP as a residuals source. The facility is currently permitted to distribute 250 dry tons/year. In 2009, 205 dry tons were distributed. The permittee might consider increasing the permitted volume with a permit modification. An Notice of Violation will be issued for failure to monitor for Ignitability and Reactivity. Page: 2 Permit: WO0005763 Owner - Facility: Tuckaseigee Water & Sewer Authority Inspection Date: 05/06/2010 Inspection Type: Compliance Evaluation Reason for Visit: Routine Type Yes No NA NE Land Application ❑ Distribution and Marketing ■ Record Keeping Yes No NA NE Is GW monitoring being conducted, if required? ❑ ❑ ■ ❑ Are GW samples from all MWs sampled for all required parameters? ❑ ❑ ■ ❑ Are there any GW quality violations? Cl ❑ ■ ❑ Is GW-59A certification form completed for facility? ❑ ❑ ■ ❑ Is a copy of current permit on -site? ■ ❑ ❑ ❑ Are current metals and nutrient analysis available? ■ ❑ ❑ ❑ Are nutrient and metal loading calculating most limiting parameters? ■ ❑ ❑ ❑ a. TCLP analysis? ■ ❑ ❑ ❑ b. SSFA (Standard Soil Fertility Analysis)? ❑ ❑ ■ ❑ Are PAN balances being maintained? ❑ ❑ ■ ❑ Are PAN balances within permit limits? ❑ ❑ ■ ❑ Has land application equipment been calibrated? ❑ ❑ ■ ❑ Are there pH records for alkaline stabilization? ■ ❑ ❑ ❑ Are there pH records for the land application site? Cl ❑ ■ ❑ Are nutrient/crop removal practices in place? ❑ ❑ ■ ❑ Do lab sheets support data reported on Residual Analysis Summary? ■ ❑ ❑ ❑ Are hauling records available? ■ ❑ ❑ ❑ Are hauling records maintained and up-to-date? ■ ❑ ❑ ❑ # Has permittee been free of public complaints in last 12 months? ■ ❑ ❑ ❑ Has application occurred during Seasonal Restriction window? IF, ❑ ■ ❑ Comment: Pathogen and Vector Attraction Yes No NA NE a. Fecal coliform SM 9221 E (Class A or B) ■ ❑ ❑ ❑ Class A, all test must be <1000 MPN/dry gram ■ Geometric mean of 7 samples per monitoring period for class B<2.0*10E6 CFU/dry gram ❑ Fecal coliform SM 9222 D (Class B only.) ❑ ❑ ■ ❑ Page: 3 Permit: W00005763 Owner - Facility: Tuckaseigee Water & Sewer Authority Inspection Date: 05/06/2010 Inspection Type: Compliance Evaluation Reason for Visit: Routine Geometric mean of 7 samples per monitoring period for class B<2.0*10E6 CFU/dry gram n b. pH records for alkaline stabilization (Class A) ■ n n n c. pH records for alkaline stabilization (Class B) ❑ ❑ ■ n Temperature corrected ■ d. Salmonella (Class A, all test must be < 3MPN/4 gram day) n n ■ o e. Time/Temp on: ■ n ❑ Cl Digester (MCRT) Compost n Class A lime stabilization ■ f. Volatile Solids Calculations n n ■ o g. Bench -top Aerobic/Anaerobic digestion results 0 ❑ ■ ❑ Comment: Tranfmanf Yes No NA NE Check all that apply Aerobic Digestion ■ Anaerobic Digestion n Alkaline Pasteurization (Class A) ■ Alkaline Stabilization (Class B) n Compost n Drying Beds n Other n Comment: Sampling Yes No NA NE Describe sampling: Approximately 10-20 grabs are collected, then composited for VAR verification. Once it passes VAR, product goes to final pile for fecals/metals/nutrients testing. 20-30 grabs are collected form the final pile for TCLP/nutrients/metals. 6 grabs are collected for fecals analysis. Is sampling adequate? ■ ❑ ❑ Is sampling representative? ■ n n n Comment: Page: 4 r t-. RE CEMED Tuckaseigee Water & Sewer Serving Jackson County 1246 West Main Street Sylva, NC 28779 Ph. (828) 586-5189 Fax (828) 631-9089 Aug. 13th, 2008 Attn: Mr. Ed Hardee NC DENR/DWQ Aquifer Protection Section Land Application Unit 1636 Mail Service Center Raleigh NC 27699-1636 Subject: Notice of Violation Response(NOV-2008-PC-0545) TWSA Residuals Production and Distribution Facility Permit # WQ0005763 Dear Mr. Hardee, AUG 25 2000 Asheville Regional Office✓ Awifer Protection --- RECEIVED / DENR / DWQ AQUIFER-PPnTprTInN, FrCTION AUG 212008 A review of our records shows that on the dates noted in the NOV (9/7/07 and 11/8/07), we had calibrated the ph meter and logged in the facilities log book that the 24 hour ph analysis had been performed. The operator failed to log the result on the form. A more careful approach to handling data should result in no further violations of this type. On 11/19/07 the two hour ph analysis showed the ph to be above 12 and it is thought that the ph of 11.91 on the initial sample was the result of improper mixing of the sample prior to analysis. Personnel have been instructed in the proper procedures for sample analysis and in the event that a sample fails to reach criteria these residuals will not be made available for distribution to the public. Three copies of the TCLP analysis are included with this correspondence and we regret the omission of this item from the report. I am hopeful this response to the noted'NOV is sufficient. Please let me know if you have questions or comments. I can be reached at the letterhead address or by phone at 828-586- 9318. Sincere , &7x�� Stan Bryson Wastewater Plant Operations Superintendent Tuckaseigee Water and Sewer Authority xc: Mr. Joe Cline, Executive Director, TWSA aceAnalytical ° www.pacelabs.com February 28, 2007 Mr. Stan Bryson Tuckaseigee Water & Sewer Auth 1246 West Main Street Sylva, NC 28779 Pace Analytical Services, Inc. 9800 Kincey Avenue, Suite 100 Huntersville, NC 28078 Phone, 704.875.9092 Faz 704.875.9091 MAR - 5 2007 RE: Lab Project Number: 92137955 Client Project ID: TWSA LIME RESIDUAL -ANNUAL Dear Mr. Bryson: Pace Analytical Services, Inc. 2225 Riverside Drive Asheville, NC 28804 Phone: 828.254,7176 Fax: 828.252.4618 Enclosed are the analytical results for sample(s) received by the laboratory on February 13, 2007. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. Inorganic Wet Chemistry and Metals Analyses were performed at our Pace Asheville laboratory and Organic testing was performed at our Pace Charlotte laboratory unless otherwise footnoted. If you have any questions concerning this report please feel free to contact me. Sincerely, Williams tom.williams@pacelabs.com (828) 254-7176 Project Manager Enclosures Asheville Certification IDs NC Wastewater 40 REPORT OF LABORATORY ANALYSIS NC Drinking Water 37712 This report shall not be reproduced, except in full, Sc 99030 without the written consent of Pace Analytical Services, Inc. FL NELAP E87648 N neI Charlotte Certification IDs NC Wastewater 12 NG Drinking Water 37706 Sc 99006 FL NELAP E87627 aceAnalytical ° www.pacelabs.com Lab Sample No: 928002690 Client Sample ID: TWSA LIME.RESIDUAL Pace Analytical Services, Inc. 9800 Kincey Avenue, Suite l00 Huntersville, NC 28078 Phone: 704.875.9092 Fax: 704.875.9091 Pace Analytical Services, Inc. 2225 Riverside Drive Asheville, NC 28804 Phone: 828.254.7176 Fax., 828.252.4618 Lab Project Number: 92137955 Client Project ID: TWSA LIME RESIDUAL -ANNUAL Project Sample Number: 92137955-002 Date Collected: 02/13/07 09:00 Matrix: Soil Date Received: 02/13/07 13:31 Parameters Results Units Report Limit Analyzed Metals By CAS No. Qual RegLmt Trace ICP Metals, TCLP Leach. Method: EPA 6010 Date Digested 02/15/07 14:00 02/15/07 14:00 Trace ICP Metals, TCLP Leach. Prep/Method: EPA 3010 / EPA 6010 Arsenic NO mg/l 0.025 02/15/07 14:48 EWS 7440-38.2 Barium 0.40 mg/l 0.025 02/15/07 14:48 EWS 7440-39.3 Cadmium Chromium ND mg/l 0.0050 02/15/07 14:48 EWS 7440-43.9 Lead ND mg/1 0.025 02/15/07 14:48 EWS 7440-47-3 Selenium 0.028 mg/1 0.025 02/15/07 14:48 EWS 7439-92.1 Silver NO mg/l 0.050 02/15/07 14:48 EWS 7782-49-2 Date Digested NO mg/l 0.025 02/15/07 14:48 EWS 7440-22-4 02/15/07 09:45 02/15/07 09:45 Mercury, CVAAS, TCLP Leachate Method: EPA 7470 Mercury NO m /1 9 0.00020 02/15/07 12:28 ALV 7439-97-6 GUMS Semivolatiles Semivolatile Organics, TCLP Prep/Method: EPA 3510 / EPA 8270 1,4-Dichlorobenzene NO mg/l 0.75 02/20/07 02:31 BET 106-46-7 2,4 Dinitrotoluene NO mg/l 0.013 02/20/07 02:31 BET 121-14.2 Hexachloro-1,3-butadiene NO mg/l 0.050 02/20/07 02:31 BET 87-68.3 Hexachlorobenzene NO mg/l 0.013 02/20/07 02:31 BET 118-74.1 Hexachloroethane NO mg/l 0.30 02/20/07 02:31 BET 67-72.1 2-Methylphenol (o-Cresol) NO mg/l 0,050 02/20/07 02:31 BET 95-48-7 3&4-Methylphenol NO mg/l 0.010 02/20/07 02:31 BET Nitrobenzene ND mg/l 0.20 02/20/07 02:31 BET 98-95-3 Pentachlorophenol NO mg/l 0.050 02/20/07 02:31 BET 87-86.5 Pyridine NO mg/l 0.50 02/20/07 02:31 BET 110-86-1 2,4,5-Trichlorophenol NO mg/l 0.25 02/20/07 02:31 BET 95-95-4 2,4,6-Trichlorophenol NO mg/l 0.20 02/20/07 02:31 BET 88-06-2 Nitrobenzene-d5 (S) 88 % 02/20/07 02:31 BET 4165-60-0 2-Fluorobiphenyl (S) 83 % 02/20/07 02:31 BET 321-60-8 Terphenyl-d14 (S) 76 % 02/20/07 02:31 BET 1718-51-0 Phenol-d5 (S) 39 % 02/20/07 02:31 BET 4165-62-2 2-Fluorophenol (S) 59 % 02/20/07 02:31 BET 367-12-4 2,4,6-Tribromophenol (S) 78 % 02/20/07 02:31 BET 118-79-6 Date Extracted 02/15/07 02/15/07 Date: 02/28/07 Asheville Certification IDs NC Wastewater 40 REPORT OF LABORATORY ANALYSIS NC Drinking Water 37712 This report shall not be reproduced, except in full, Sc 99030 without the written consent of Pace Analytical Services, Inc. FL NELAP E87648 a�ac_ Page: 3 of 5 Charlotte Certification IDs NC Wastewater 12 NC Drinking Water 37706 SC 99006 FL NELAP E87627 ace Analytical ° www.pacelabs.com Lab Sample No: 928002690 Client Sample ID: TWSA LIME RESIDUAL Pace Analytical Services, Inc. 9800 Kincey Avenue, Suite 100 Huntersville, NC 28078 Phone: 704.875.9092 Fax., 704, 875.9091 Pace Analytical Services, Inc. 2225 Riverside Drive Asheville, NC 28804 Phone: 828,254.7176 Fax: 828.252.4618 Lab Project Number: 92137955 Client Project ID: TWSA LIME RESIDUAL -ANNUAL Project Sample Number: 92137955-002 Date Collected: 02/13/07 09:00 Matrix: Soil Date Received: 02/13/07 13:31 Parameters Results Units Report Limit Analyzed By CAS No. Qual RegLmt GC Semivolatiles Pesticides, TCLP Leachate Prep/Method: EPA 3535 / EPA 8081 gamma-BHC (Lindane) NO mg/l 0.040 02/21/07 00:40 RCS1 58-89-9 Chlordane ND mg/l 0.0030 02/21/07 00:40 RCS1 57-74-9 Endrin ND mg/l 0.0020 02/21/07 00:40 RCS1 72-20-8 Heptachlor NO mg/l 0.00080 02/21/07 00:40 RCS1 76-44-8 Methoxychlor NO mg/l 1.0 02/21/07 00:40 RCS1 72-43-5 Toxaphene NO mg/l 0.050 02/21/07 00:40 RCS1 8001-35-2 Tetrachloro-m-xylene (S) 43 9 02/21/07 00:40 RCS1 877-09-8 Decachlorobiphenyl (S) 6 02/21/07 00:40 RCS1 2051-24.3 1 Date Extracted 02/15/07 02/15/07 GUMS Volatiles Volatile Organics, TCLP Leach Benzene 2-Butanone (MEK) Carbon tetrachloride Chlorobenzene Chloroform 1,4-Dichlorobenzene 1,2-Dichloroethane 1,1-Dichloroethene Tetrachloroethene Trichloroethene Vinyl chloride Toluene-d8 (S) 4-Bromofluorobenzene (S) Dibromofluoromethane (S) 1,2-Dichloroethane-d4 (S) Date: 02/28/07 Method: EPA 8260 ND mg/l 0.12 02/17/07 02:25 DLK 71.43-2 NO mg/l 2.5 02/17/07 02:25 DLK 78-93-3 ND mg/l 0.12 02/17/07 02:25 DLK 56-23-5 ND mg/l 0.12 02/17/07 02:25 DLK 108-90-7 ND mg/l 0.12 02/17/07 02:25 DLK 67.66-3 NO mg/l 0.12 02/17/07 02:25 DLK 106-46-7 NO mg/l 0.12 02/17/07 02:25 DLK 107-06-2 ND mg/l 0.12 02/17/07 02:25 DLK 75-35-4 NO mg/l 0.12 02/17/07 02:25 DLK 127-18-4 NO mg/l 0.12 02/17/07 02:25 DLK 79-01-6 ND mg/l 0.12 02/17/07 02:25 DLK 75-01-4 99 % 02/17/07 02:25-DLK 2037-26-5 97 X 02/17/07 02:25 DLK 460-00-4 98 % 02/17/07 02:25 DLK 1868-53-7 111 Y 02/17/07 02:25 DLK 17060-07-0 Asheville Certification IDs NC Wastewater 40 REPORT OF LABORATORY ANALYSIS NC Drinking Water 37712 This report shall not be reproduced, except in full, SC 99030 without the written consent of Pace Analytical Services, Inc. FL NELAP E87648 !ndac = Page: 4 of 5 Charlotte Certification IDs NC Wastewater 12 NC Drinking Water 37706 Sc 99006 FL NELAP E87627 Pace. Analytical Services, Inc. Pace Analytical Services, Inc. 9800 Kincey Avenue, Suite 100 2225 Riverside Drive Huntersville, NC 28078 Asheville, NC 28804 ace Analytical o Phone; 704.875.9092 Phone: 828.254.7176 Fax: 704.875.9091 Fax: 828-252.4618 www.pacelabs.com Lab Project Number: 92137955. Client Project ID: TWSA LIME RESIDUAL -ANNUAL PARAMETER FOOTNOTES Method 9071E modified to use ASE. All pH, Free -Chlorine, Total Chlorine and Ferrous`Iron analyses conducted -outside of EPA recommended immediate hold time. Depending on the moisture content the PRLs,can be elevated for all soil samples -reported on a dry weight basis. 2-Chloroethyl vinyl. ether has been showm to degrade in the presence of acid. ND Not detected at or above adjusted reporting limit . NC Not Calculable J Estimatedconcentration above the adjusted method detection limit and below the adjusted reporting limit MDL Adjusted Method Detection Limit (S) Surrogate [1] Surrogate recovery outside of control limits. The data was accepted based on valid recovery of remaining surrogate. rl. Date: 02/28/07 Page: 5 of 5 Asheville Certification IDs NC Wastewater 40 REPORT OF LABORATORY ANALYSIS Charlotte Certification IDs NC Wastewater 12 NC Drinking Water 37712, This report shall not be reproduced, except in full,. NC Drinking Water 37706 Sc, 99030 without the written consent of.Pace Analytical Services, Inc. SC . 37706 FL.NELAP E87648 N ACCCq Wa ° , '" FL NELAP E87627 a`�".µ.- .. �.�qy a ne act Analytical Environmental Services, Inc. Date: 19-Feb-07 CLIENT: Pace Analytical Services, Inc. Client Sample ID: 928002690 Lab Order: 0702769 Tag Number: Project: 92137955 Collection Date: 2/13/2007 9:00:00 AM Lab ID: 0702769-OOIA Matrix: SOLID Analyses Result Limit Qual Units DatchID DF Date Analyzed HERBICIDES, TCLP SW1311/8151A (SW3510B) Analyst: El 2,4,5-TP (Silvex) BRL 0.050 mg/L 82864 1 2/19/2007 1:02:00 PM 2,4-D BRL 0.050 mg/L 82864 1 2/19/2007 1:02:00 PM Surr: DCAA 111 25.2-164 %REC 82864 1 2/19/2007 1:02:00 PM �.vu,au,umm i.cvct BRL Below Reporting Limit H Holding times for preparation or analysis exceeded N Analyte not NELAC certified Rpt Limit Reporting Limit B Analyte detected in the associated Method Blank E Value above quantitation range J Analyte detected below quantitation limits P NELAC analyte certification pending S Spike Recovery outside accepted recoverpyq its of 1 ivv. v-rc f I PRECISION PETROLEUM LABS INC. 5915 Star Lane Houston, TX 77057 Ph.71.3-690-9425 Pax:713-680-9564 CERTMCATE OF ANALYSIS COMPANY: PACE ANALTYICAL INVOICE No.: 33018 LAB REFERENCE No.: 2007-02-323 PRODUCT ID: 928002690 PROJECT#92137955 DATE RECEIVED: 02-14-2007 AUTHORIZED BY: TOM WILLIAMS TOT METHOD MPORTING Ph LDIIT- RESULTS S.W.9040 0.01 13.2. Ignitability (Flash point), COC D-92- 70OF > 400 Reactive Cyanides, PPM S.W. 9010 0.01 BRL Reactive Sutfiides, PPM' , S.W. 9030 1-0 BRL RRL = BELOW REPORTING LIlYIIT PRECI6I4N PE TRODUM LABS, L US RESPONSIBUM Y'FOR THE ABOVE ANALYSIS, OPINIONS OR INTERPRETATIONS IS .LEWTED TO THE MOICE AMOUNT. Analytical Environmental Services, Inc. CLIENT: Pace Analytical Services, Inc. Work Order: 0702769 Project: 92137955 Sample ID: MB-82864 SampType: MBLK Client ID: Batch ID: 82864 Analyte Result 2,4,5-TP (Silvex) BRL 2,4-D BRL Surr: DCAA 0.003932 Sample ID: LCS-82864 SampType: LCS Client ID: Batch ID: 82864 Analyte Result 2,4,5-TP (Silvex) BRL 2,4-D BRL Surr: DCAA 0.00523 Sample ID: 0702761-001AMS SampType: MS Client ID: Batch ID: 82864 Analyte Result 2,4,5-TP (Silvex) BRL 2,4-D BRL Surr: DCAA 0.005203 TestCode: 1311_H Units: mg/L TestNo: SW1311/8151 PQL SPK value SPK Ref Val 0.050 0.050 0 0.005 0 TestCode: 1311_H Units: mg/L TestNo: SW1311/8151 PQL SPK value SPK Ref Val 0.050 0.005 0 0.050 0.005 0 0 0.005 0 TestCode: 1311_H Units: mg/L TestNo: SW1311/8151 PQL SPK value SPK Ref Val 0.050 0.005 0 0.050 0.005 0 0 0.005 0 Date: 19-Feb-07 ANALYTICAL QC SUMMARY REPORT TestCode: 1311 H Prep Date: 2/16/2007 RunNo: 99350 Analysis' Date: 2/16/2007 SegNo: 1992493 %REC Lowl-imit HighLimit RPD Ref Val %RPD RPDLimit Qual 78.6 25.2 164 0 0 Prep Date: 2/16/2007 Analysis Date: 2/16/2007 %REC Lowl-imit HighLimit RPD Ref Val 99.4 58.2 125 0 91.8 37.3 130 0 105 25.2 164 0 Prep Date: 2/16/2007 Analysis Date: 2/16/2007 %REC - LowLimit HighLimit RPD Ref Val 108 50.1 139 0 98.4 29.2 149 0 104 25.2 164 0 Qualifiers: B Analyte detected in the associated Method Blank BRL Below Reporting Limit H Holding times for preparation or analysis exceeded J Analyte detected below quantitation limits R RPD outside accepted recovery limits S Spike Recovery outside accepted recovery limits RunNo: 99350 SegNo: 1992495 %RPD RPDLimit Qua[ 0 0 0 RunNo: 99350 SegNo: 1992506 %RPD RPDLimit Qua] 0 0 0 E Value above quantitation range N Analyte not NELAC certified Page 1 of I Analvtical Environmental Services. Inc. Date: 19-Feb-07 CLIENT: Pace Analytical Services, Inc. Project: 92137955 CASE, NARRATIVE Lab Order: 0702769 No collection date or time was labeled on sample container. This information was taken from COC for login. COC indicates a water sample was submitted, however a solid sample was submitted. Page 1 of 1