NC0006351_Meeting Notes_19950126

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NPDES Meeting Of 1/26/95 Agenda
1. Introduction
a) Meet Players
b) Overview Of CSI/MRD History
c) Site Highlights
d) Overview Of Products
2. Pesticide Producing Processes
a)
Chroiu_.
e �io►1w;
Aim
c)
Mold Guard Series
i) Product Line .- .t/(4 Gem`""-• /H-4r
a) Mold Inhibitor/Preservative
b) Grain Feed Additive - 4
c) Flavoring
ii) Waste Water
a) Washdown Between Different Batches
b) Stormwater
(1) Storage Dikes
b) CCA/Arsenic Acid
i) Recycle Process/Wash Water
a)~CCA Plant �,- u �2
b) Arsenic Acid Plant-m0
c) Bag Unloading- emu.,/
d) Chrome Unloading - EGG/,4e
ii) Stormwater
a) Driveways - Inter -Plant Movements
b) Loaded Tanker Parking
Copper Count N 44 ,.. .
i) Product Line 4ouo 493 of_ trig Scrap air", (71`46-
a) CCN (FIFRA) - Fungicide On Citrus Crop
ii) Process Description
a) Recycle Scrubber Stream
iii) Waste Water
WvJ G(uc 1 a) Stormwater
(1) Process Area
(2) Filtration b•3
Cw co 4
ti�
/4A/1

d) Copper Ammonium Carbonate/Amine Copper Carbonate
i) Product Line
a) Copsol (FIFRA) - Burlap Bag Treatment (bwrdiz,)
b) ACQ-C (FIFRA) - Wood Treatment
c) Copper Ammonium Carbonate - Industrial Chemical
d) ACQ-D (FIF1 A ood Treatment
ii) Process Description ein
a) No Separation Of FIFRA/Non-FIFRA Products
b) MEA Process
A®n Arm
iii) Waste Water norc/fYprhuYn-
a) Washdown Between CAC/ACC
b) Stormwater - Outside '
c) MEA Scrubber Solution �°"
3. Water Balance
a) Overall
b) Plant Specific
4. Review Development Document
a) Stormwater Not Included
b) Deminimus -, ,� .. /d/acaa —
c) Treatments Are Not Applicable
i) Land Application
ii) Evaporation
5. Recommendations
a) MEA Segregation
i) Clean Air Act Impacted
ii) Compliance Schedule Z
b) Copper Ammonium Carbonate No -Segregation
i) Most Stormwater Related - 4
er)i
ii) Look At Housekeeping Through SWPPP
iii) Allow Discharge - Manage Through SWPPP
au 6446 kJ;

c) Copper Count N
i) All Stormwater Related - M '" '1A4'44
ii) Look At Housekeeping Through SWPPP
iii) Allow Discharge - Manage Through SWPPP
d) Mold Guard , , (F'/f,#)
w
i) Not Applicable - : i -c. c z t.'� . stCL
a/41,, ii) Continue With SWPPP items
%J.
obfrjrAr flFgt-/ yri“:0-3,0 .
Other Concerns csf Draft Pe it
a) Groundwater Monitoring
i) Regulated under RCI�A /14-13
ii) Permit requirement tos Supply copy of RC
information
b) Acute Toxicity
i) 90% vs. 45%
c) BOD
i) Low Potential
ii) Reduce Frequency to Monthly
d) TSS & NH3
i) Reduce Frequency to 2/Month
e) Copper
i) Permit Limit Value -7
ii) Calculation Basis
Pris4-
11/44&txtlij LC --i ,Z4-75% /42e.e�•te-Ac
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CHEMICAL SPECIALTIES, Inc®
MINERAL RESEARCH & DEVELOPMENT
Operations Commenced: 1964
Mineral Research & Development Corp.
Purchased by Laporte, Inc.: 1985
as Mineral Research & Development Corp.
Merged:
Wood Treatment combined with
Chemical Specialties, Inc.
Two Companies @ Harrisburg
CSI - Valdosta, Ga.
CSI - Gilmer, Tx.
MRD - Freeport, Tx.
12/31/93
CSI into MRDC
MRDC Changes Name to Chemical Specialties, Inc.
MRD Remains as a Division of CSI

CHEMICAL SPECIALTIES, Inc.
MINERAL RESEARCH & DEVELOPMENT
Site Highlight
• Commitment To Waste Reduction And Pollution Prevention
• Second Year Into Five Year Infrastructure Development
• 85% Of Prior Three Years Capital - Safety, Health & Environmental
Approx. $6 M.
• Reduced Hazardous Waste Generation By 50% In Last Four Years
Some Projects:
1. Trioxide Warehouse - /WA; o n f,, -174
2. Upgrade Waste Treatment System - IZ 30, 004' ' �� wf SO
3. Arsenic Acid Recovery Project -I yo
�t.t�, . 4x&, 9�
r i'L al halmes omole,
Trioxide Bag Washing -� �us�, cmo
5. Refurbishment/Elimination Of Site SWMU's
6. Scrubber Control Systems

CHEMICAL SPECIALTIES, Inc.
MINERAL RESEARCH & DEVELOPMENT
Products Produced at Harrisburg
CSI ad ~"
Arsenic Acid
CCA
D-Blaze
Ultrawood
MRD
NITRATES
Aluminum Nitrate
Calcium Nitrate
Magnesium Nitrate
Manganese Nitrate
Zinc Nitrate
CHLORIDES
Magnesium Chloride
Manganese Chloride
Zinc Chloride
OTHERS
dw„,„6
Calcium Chelate
Copper Ammonium Carbonate
Copper Count N
ORA Cop
Zinc/Magnesium Acetate
Zinc Ammonium Carbonate
Mold Guard Products
nu ear'in . u"try
latex gloves, concrete, fertilizer
fertilizer, textiles, ink processing
fertilizer
fertilizer
textiles, baby food, good grade products
fertilizer
galvanizing flux, battery industry
fertilizer
biocide, wood preservative, industrial
product
¢'fungicide -d-�-
animal feed additive- mites nrfr' 'l 0Gr 7
fertilizer
fertilizer
mold inhibitor, animal feed additive

644-(.4.
21 31 41 51 61 7L e1 91 1d
to
131
141
15�
+d
VOLD GUARD SERIES
17L
201
211
221
231
24 1
251
PROPIONIC
ACID
(©)
MOLD
GUARD
BASE
MANUAL ADDITION
AMMONIA
BENZOIC ACID
2 S,,,r ;,FLAVORINGS
PROPYLENE
GLYCOL
Iwo %eod H2O
TO WWT
2--
MOLD
GUARD
REACTOR
WWT
'©'
d,,it,ti,itLzt
281 271 281 291 30
A
A
M CHEMICAL SPECIALITIES, INC.
CSI IN7d'J3lIX. ION cow
MOLD GUARD SERIES
s
n
n
A
Darr YD.
1
OCAS
a

1 I 21 31 41 51 5 1 7 1 5 1 9 1 ICI 11I 11 131 141 151 161 IA 1$ 191 _ 201 211 221 231 24I 251 251 271 251 291 30
—t
WWT
COPPER COUNT N
COPPER ANVONIUV CARBONATE
AvINE COPPER CARBONATE
1©1
>C
CAC
REACTOR
ACC
REACTOR
CCA/ACC
AA
STORAGE
CAC/ACC
STORAGE
CAC/ACC
STORAGE
ACETIC
STORAGE
AMMONIA STORAGE
CCN
REACTOR
CCN
REACTOR
CCN
REACTOR
CHEMICAL SPECIALITIES, INC.
hasa G NOQfH CAvgillA
COPPER COUNT N
COPPER AMMONIA CARBONATE
AMINE COPPER CARBONATE
RLYMICINI
DATE
er
NM PO NI
I `" I

21 31 41 al a 1 7 9I 91 1(1 1i 1� 131 141 151 101 171 1d tsl 201 211 221 231_ 241 251
COUNTY WATER SUPPLY
74,400 GPD
i
OVE2ALL
WATER 3ALA\C
RAIN WATER LIME
19,200 GPD 1,000 GPD
1
gal 271 2a 1 291 30
PRODUCTS
44,500 GPD
EVAPORATION
31,100 GPD
tb
tiJ
CONSUMPTION
100 GPD
DRAIN FIELD
2,500 GPD
WASTE DISPOSAL
200 GPD
1
1
DISCHARGE
16,200 GPD
1
M CHEIIICAL SPECIALITIES, INC.
OVERALL.
WATER BALANCE
i
s
NM MP
arywors
ADAC/ pa
0,40. yen

11 21 31 41 01 9 L
7 1 B 1 9 1 1d I1J 1a 131 141 151 161 171 1g 10]
RAIN
290 GPD
Jij,o,4r„
•776--) fV°COUNTY
WATER
0 GPD
rarbAr
470 GPD
COPPER COUNT N /�
COPPER AN\IONIUN CARBO\ATE
1010 GPD
CCN
PROCESS
✓a
AREA
5,700 GPD
5,160 GPD
RAIN
290 GPD
CCN
SCRUBBER
0/,,f) safrL
3y5 ibi 5re4N„
540 GPD
EVAPORATION
30 GPD
COUNTY
WATER
200 GPD -r
201 2,1 221 231 241 251 261 271 281 291 301
a
RAIN
270 GPD
300 GPD
CAC
SCRUBBER
COUNTY
WATER
650 GPD
1 1
1
CAC
PROCESS 350 GPD
AREA
RAIN
270 GPD ++ I '' `_
Jlv ✓'f'►wr�t.t�. --�i wAsk —'^
M CHEMICAL SPECIALITIES, INC.
CBI 11418I23. P a1" °aim
COPPER COUNT N
COPPER AMMONIA CARBONATE
AMINE COPPER CARBONATE
lirrIBIONS
1 "' I

1 21 31 41
51 6 L 71 5_1 91 11 11I 1i
s470 GPD
RAIN
290 GPD
COUNTY
WATER
1010IGPD
1
CCN
PROCESS
AREA
All
131 141 151 1t 171 111 191 201 211 24
COPPER COU\T \
\E COPPER CARBO\ATE
5.700 GPD
5,160 GPD
RAIN
290 GPD
CCN
SCRUBBER
EVAPORATION
30 GPD
COUNTY
WATER
200 GPD
540 GPD
300 GPD
231 241 251 24 271 261 291
RAIN
270 GPD
i
COUNTY
WATER
650 GPD
ACC
SCRUBBER
I010GP
ACC
PROCESS
AREA
350 GPD
RAIN
270 GPD
4-0
Tv4rivfAjd 0 el.' r:td° '61‘
2.00
PPAk
M CHEMICAL SPECIALITIES, INC.
COPPER COUNT N
AMINE COPPER CARBONATE
OD DO MS
Rrvesooms
I `" I
DD••• rotate