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WQ0004268_GW Monitoring - 07-2022_20220811
GW-59A COMPLIANCE REPORT FORM Permit # W00004268 (Submit one each monitoring period with GW-59 forms.) I Enter date monitoring results were due. (3/23/2022_) Will this monitoring report (GW-59 and GW-59A) YES O be submitted after the established due date? 2 Was any required information missing on the GW-59 report forms? YES NO IF the answer to question 1 or 2 is "YES", list in the space provided below the well identification number(s) and explain the problems encountered in obtaining the required information. 3 Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing YES NO identification plate, area overgrown, etc.)? If the answer is "Yes", contact the Regional Office for guidance. 4 Are any monitored constituents equal to or above the established standards? YES NO If the answer to question 4 is "NO", skip to section 8. If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s) exceeding standards in the space provided below: 1.) pH <6.5 at all monitoring wells MW1 — MW3 & R1 — R9. 2.) R8 exceeded nitrate + nitrite nitrogen level for the sampling period. 5 For the constituents identified in question 4 above, have standards been exceeded previously for the ES NO same constituent(s) in the same well(s) in the last two years? Please see the attached information. There has been no inflow into the lagoon system since prior to March, 2018. R8 has exceeded the standard in the past but is trending down.. Zones 1 & 2 are adjacent to R8 had 9.21lbs. PAN / acre applied from 5/3/2021 through 9/30/2021. There has been no application since 9/30/2021. No commercial N has been applied since acquiring the permitted property on any spray fields in the permit. 6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? Inside the review YES NO boundary. If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly located; contact the Regional Office. 7 Is the permittee implementing previously approved actions required by the Division involving this YES i NO groundwater quality problem? If the answer to question 7 is "YES", describe tho actions in theMace provided below. If the answer to question 7 is "NO", contact th � ?eaional O within 90 days; an evaluation may be required to determine the impact the waste dis . sal sV&em AsIhaving at the review and compliance boundaries surrounding this facility. Failure to _ so sub ct the permittee to a Notice of Violation, fines, and/or penalties. n N C ry �y Cti 8 The person c /e this portion (GW-59A) of fhb monitoring report should sign below and submit this to the the top the current GW-59 form. form with GW forms for required wells address provided at of I hereby acknowledge that the above information was evaluated and the information submitted in this report (Compliance Report GW-59A) is true and complete to the best of my knowledge. ,I /A , 8/3/2022 Signature of Permittee (or Authorized Agent) Date rw_aeA »iRt2nnz SUBMIT FORM ON YELLOW PAPER ONLY • DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: • • INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699-1617 Phone: 919-807.6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 4/30/2023 Facility Name: Murphy Brown Elliot & Rowan Tracts Non -Discharge WQ0004268 UIC Permit Name (if different): Murphy Brown WWIS NPDES Other Facility Address: PO Box 856, Warsaw NC 28398 TYPE OF PERMITTED OPERATION BEING MONITORED PO Box 856, Warsaw NC (�ggA8 County Sampson ❑ Lagoon ❑ Remediation: Infiltration Gallery (City) (state) (zip) X Spray Field ❑ Remediation: Contact Person: David Nordin Telephone#: 910-293-5574 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Elliot and Rowan sites No. of wells to be sampled: 12 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW - 1 Date sample collected: 7/9/2022 FIELD ANALYSES: WAS Well Depth: 30 ft. Well Diameter: 2 in. pH 00400: 4.4 units Temp. 000lo: 19 °C DRY at Depth to Water Level e2546: 26.5 ft. below measuring point Screened Interval: ft. to _ft. Spec. Cond. oo0sa: µMhos time of sampling, Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: None check Volume of water pumped/bailed before sampling: 2 gallons Appearance Clear/ Reddish here: ❑ Samples for metals were collected unfiltered: K YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/9/2022 thru 7/26/2022 Laboratory Name: Environmental Chemists, Inc. Certification No. 94 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 31 mg/L Nitrite (NO2) as N 00615 <0.02 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 < 1 /100mL Nitrate (NO3) as N 00620 6.17 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P'00665 0.15 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 703oo 312 mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 0068o 2.1 mg/L Ca - Calcium 00916 mg/L Chloride 00940 150 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 9 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.2 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3 as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% David Nordin, Director of Environmental Compliance Permittee (or Authorized Agent) Name and Title - Please print or type r J/2a 2 2 GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY • . DEPARTMENT OF: ENVIRONMENTAL WALITY - DIV, OF WATER. RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PRQCESSINGiuNIT COMPLIANCE REPORT FORM 161TMAIL.SERVICECENTER, RAI:EIOHNC'27688.161�7 phone; 919.8d7.8308 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 4/30/2023 Facility Name: Murphy Brown Elliot & Rowan Tracts Non -Discharge WQ0004268 UIC Permit Name (if different): Murphy Brown WWIS NPDES Other Facility Address: PO Box 856, Warsaw NC 28398 TYPE OF PERMITTED OPERATION BEING MONITORED PO Box 856, Warsaw NC (�@MS8 County Sampson ❑ Lagoon ❑ Remediation: Infiltration Gallery (City) (Slate) (zip) ❑■ Spray Field El Remediation: Contact Person: David Nordin Telephone#: 910-293-5574 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Elliot and Rowan sites No. of wells to be sampled: 12 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW - 2 Date sample collected: 7/9/2022 FIELD ANALYSES: WAS Well Depth: 19.75 ft. Well Diameter: 2 in. pH 00400: 5.4 units Temp. 000lo: 18.5 °C DRY at Depth to Water Level szsas: 11.4 ft. below measuring point Screened Interval: ft. to _ft. Spec. Cond. 000sa: µMhos time ofsampling, Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Odor 000as: None check Volume of water pumped/bailed before sampling: 5 gallons Appearance Clear here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/9/2022 thru 7/26/2022 Laboratory Name: Environmental Chemists, Inc. Certification No. 94 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 21 mg/L Nitrite (NO2) as N oo515 <0.02 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 < 1 /100mL Nitrate (NO3) as N 00620 0.35 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 <0.04 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 157 mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 0068o 2.2 mg/L Ca - Calcium 00916 mg/L Chloride 0094o 43 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 15 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? X Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia oo610 <0.2 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% David Nordin, Director of Environmental Compliance Permittee (or Authorized Agent) Name and Title - Please print or type 20.22 GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTALQUALITY •,DIV; OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: , , , INFORMATION'FROCESSINC9rUNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER,'RAL'eIGHrNC27689.1617 Phones 919-807.6306 FACILITY INFORMATION Please Print Clearty or Type PERMIT Number: Expiration Date: 4/30/2023 Facility Name: Murphy Brown Elliot & Rowan Tracts Non -Discharge WQ0004268 UIC Permit Name (if different): Murphy Brown WWIS NPDES Other Facility Address: PO Box 856, Warsaw NC 28398 TYPE OF PERMITTED OPERATION BEING MONITORED PO Box 856, Warsaw NC (�f89' 8 County Sampson ❑ Lagoon ❑ Remediation: Infiltration Gallery (City) (state) (Zip) K Spray Field El Remediation: Contact Person: David Nordin Telephone#: 910-293-5574 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Elliot and Rowan sites No. of wells to be sampled: 12 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW - 3 Date sample collected: 7/9/2022 FIELD ANALYSES: WAS Well Depth: 17 ft. Well Diameter: 2 in. pH 00400: 5.8 units Temp. 000lo: 19.8 eC DRY at Depth to Water Level 82546: 4.8 ft. below measuring point Screened Interval: ft. to _ft. Spec. Cond. 000sa: µMhos time ofsampling, Measuring Point is 2 ft. above land surface Relative M.P. Elevation: ft. Odor 00085: Sulfur check Volume of water pumped/bailed before sampling: 5 gallons Appearance Reddish/ Tan / Clear here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/9/2022 thru 7/26/2022 Laboratory Name: Environmental Chemists, Inc. Certification No. 94 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 23 mg/L Nitrite (NO2) as N 00615 <0.02 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 56 /100ml- Nitrate (NO3) as N 00620 0.05 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.32 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 416 mg/L Al - Aluminum o11o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 1.2 mg/L Ca - Calcium 00916 mg/L Chloride 0094o 88 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 43 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.2 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese o1o55 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% David Nordin, Director of Environmental Compliance Permittee (or Authorized Agent) Name and Title - Please print or type ,20.Z2 GW-59 Rev.05-02-2017 Sl IRMIT PnRM ON YFI I OW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699.1617 Phone: 919.807.6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 4/30/2023 Facility Name: Murphy Brown Elliot & Rowan Tracts Non -Discharge WQ0004268 UIC Permit Name (if different): Murphy Brown WWIS NPDES Other Facility Address: PO Box 856, Warsaw NC 28398 TYPE OF PERMITTED OPERATION BEING MONITORED PO Box 856, Warsaw NC I`L8968 County Sampson ❑ Lagoon ❑ Remediation: Infiltration Gallery {city! (state) (zip) 0 Spray Field ❑ Remediation: Contact Person: David Nordin Telephone#: 910-293-5574 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Elliot and Rowan sites No. of wells to be sampled: 12 ❑ Water Source Heat Pump ❑ Other: from Permit If WELL SAMPLING INFORMATION WELL ID NUMBER (from Permit): MW - R1 Date sample collected: 7/9/2022 FIELD ANALYSES: WAS Well Depth: 15 ft. Well Diameter: 2 in. pH 00400: 4.6 units Temp. 00010: 22.9 °C DRY at time of Depth to Water Level 82546: 5.8 ft. below measuring point Screened Interval: ft. to _ft. Spec. Cond. 00094: µ Mhos sampling, Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Odor 0008s: None check Volume of water pumped/bailed before sampling: 5 gallons Appearance Clear / Tan here: ❑ Samples for metals were collected unfiltered: 0 YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/9/2022 thru 7/26/2022 Laboratory Name: Environmental Chemists, Inc. Certification No. 94 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 20 mg/L Nitrite (NO2) as N 00615 <0.02 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 < 1 /100mL Nitrate (NO3) as N 00620 3.53 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.68 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 160 mg/L AI - Aluminum 011o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 0068o 2.7 mg/L Ca - Calcium 00916 mg/L Chloride 00940 55 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 16 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? K Yes (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.2 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total) Mn - Manganese o1o55 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Emuent I otai vuL;s: IttyrL VVIi RuiiivvaI /O David Nordin, Director of Environmental Compliance Permittee (or Authorized Agent) Name and Title - Please print or type D22 GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY - DIV. OF WATER RESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NO 27699.1617 Phone: 919-807-6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date. 4/30/2023 Facility Name: Murphy Brown Elliot & Rowan Tracts Non -Discharge W00004268 UIC Permit Name (if different): Murphy Brown WWIS NPDES Other Facility Address: PO Box 856, Warsaw NC 28398 TYPE OF PERMITTED OPERATION BEING MONITORED PO Box 856, Warsaw NC (�821't8 County Sampson ❑ Lagoon ❑ Remediation: Infiltration Gallery (City) (Slate) (Zip) l] Spray Field El Remediation: Contact Person: David Nordin Telephone#: 910-293-5574 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Elliot and Rowan sites No. of wells to be sampled: 12 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW - R2 Date sample collected: 7/9/2022 FIELD ANALYSES: WAS Well Depth: 15 ft. Well Diameter: 2 in. pH 00400: 4.3 units Temp. 000lo: 22.5 oC DRY at Depth to Water Level azsas: 5.9 ft. below measuring point Screened Interval: ft. to _ft. Spec. Cond. 00094: µMhos time ofsampling, Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Odor 000a5: None check Volume of water pumped/bailed before sampling: 5 gallons Appearance Clear here: ❑ Samples for metals were collected unfiltered: ❑■ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/9/2022 thru 7/26/2022 Laboratory Name: Environmental Chemists, Inc. Certification No. 94 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 <20 mg/L Nitrite (NO2) as N 00615 <0.02 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 < 1 /100mL Nitrate (NO3) as N 00620 8.48 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.05 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): [lissolved Solids:Total 70300 97 mg/L Al - Aluminum oil o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 0.5 mg/L Ca - Calcium 00916 mg/L Chloride 00940 10 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 16 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.2 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total) Mn - Manganese olo55 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%. David Nordin, Director of Environmental Compliance Permittee (or Authorized Agent) Name and Title - Please print or type 21DAZ GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY ROUNDWATER QUALITY MONITORING: OMPLIANCE REPORT FORM Clearly or Type Facility Name: Murphy Brown Elliot & Rowan Tracts Permit Name (if different): Murphy Brown WWIS Facility Address: PO Box 856, Warsaw NC 28398 PO Box 856, Warsaw NC (�18168 County Sampson (C W (State) (Zip) act Person: David Nordin Location/Site Name: Elliot and Rowan sites WELL ID NUMBER (from Permit): MW - R3 Well Depth: 18 ft. Depth to Water Level 82546: 8 ft. below measuring point Measuring Point is 3 ft. above land surface Telephone#: 910-293-5574 No. of wells to be sampled: 12 Date sample collected: 7/9/2022 Well Diameter: 2 in. Screened Interval: ft. Relative M.P. Elevation: PERMIT Number: Expiration Date: 4/30/2023 Non -Discharge W00004268 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery X Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: to _ ft. ft. Volume of water pumped/bailed before sampling: 5 gallons Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑_NO Date sam le anal zed: 7/9/2022 thru 7/26/2022 Laboratory Name: Environmental Chemists, Inc. p Y PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 <20 mg/L Nitrite (NO2) as N 00615 <0.02 Coliform: MF Fecal 31616 < 1 /100mL Nitrate (NO3) as N 00620 1.30 Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.06 (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 [lissolved Solids:Total 70300 196 mg/L Al - Aluminum 01105 pH (Lab) 00403 units Ba - Barium 01007 TOC 00680 0.7 mg/L Ca - Calcium 00916 Chloride 00940 13 mg/L Cd - Cadmium 01027 Arsenic 01002 ug/L Chromium: Total 01034 Grease and Oils 00552 mg/L Cu - Copper 01042 Phenol 32730 ug/L Fe - Iron 01045 Sulfate 00945 96 mg/L Hg - Mercury 71900 Specific Conductance 00095 µMhos K - Potassium 00937 Total Ammonia 00610 <0.2 mg/L Mg - Magnesium 00927 (Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total) Mn - Manganese 01055 TKN as N 00625 mg/L Ni - Nickel 01067 mg/L mg/L mg/L mg/L mg/L ug/L mg/L ug/L ug/L mg/L ug/L ug/L mg/L mg/L ug/L ug/L FIELD ANALYSES: pH 00400: 4.5 units Spec. Cond. 00094: Odor 000e5: None Appearance Clear Pb - Lead o1o51 Zn - Zinc 01092 Temp. 000lo: 23.5 oC µMhos Certification No. 94 ug/L mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? 0 Yes (1) ❑ No (0) VOC 7873 method # method # method # method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VUL; Kemovai ie If WELL DRY at time of sampling, check here: ❑ GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM FACILITY INFORMATION Please Print Clearly or Type Facility Name: Murphy Brown Elliot & Rowan Tracts Permit Name (if different): Murphy Brown WWIS Facility Address: PO Box 856, Warsaw NC 28398 PO Box 856, Warsaw NC ('"8168 County Sampson (city) (State) (Lip) act Person: David Nordin Location/Site Name: Elliot and Rowan sites Telephone#: 910-293-5574 No. of wells to be sampled: 12 PERMIT Number: Expiration Date: 4/30/2023 Non -Discharge W00004268 UIC NPDES Other TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery X Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: from Permit) SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW - R4 Date sample collected: 7/9/2022 FIELD ANALYSES: WAS Well Depth: 15 ft. Well Diameter: 2 in. pH 00400: 4.4 units Temp. 00010: 21.1 °C DRY at Depth to Water Level 82546: 7.6 ft. below measuring point Screened Interval: ft. to _ft. Spec. Cond. 00094: µMhos time ofsampling, Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Odor 000as: None check Volume of water pumped/bailed before sampling: 5.0 gallons Appearance Clear / Tan here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/9/2022 thru 7/26/2022 Laboratory Name: Environmental Chemists, Inc. Certification No. 94 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 21 mg/L Nitrite (NO2) as N 00615 <0.02 mg/L Pb - Lead o1o51 ug/L Coliform: MF Fecal 31616 < 1 /100mL Nitrate (NO3) as N 00620 3.54 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.24 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 171 mg/L Al - Aluminum oil o5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 0068o 2.4 mg/L Ca - Calcium 00916 mg/L Chloride 0094o 53 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 30 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.2 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH3asN; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg1L Effluent Total VOCs: mg/L I certify that, to the best of my knowledge and belief, the information submitted in this report is true, accurate, and complete, and that the laboratory analytical data was produced using approved methods of analysis by a DWR-certified laboratory. I am aware that there are significant penalties for submitting false information, including the possibility of fines and imprisonment for knowing violations. David Nordin, Director of Environmental Compliance Permittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.05-02-2017 Signature Ift"W 9/3/.7.0.2„Z (Date) SUBMIT FORM ON YELLOW PAPER ONLY DEPARTMENT OF ENVIRONMENTAL QUALITY'- DIV. OF WATEKRESOURCES GROUNDWATER QUALITY MONITORING: INFORMATION PRocEsslNCi UNIT COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIGH, NC 27699.1617 Phone: 919.607:6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 4/30/2023 Facility Name: Murphy Brown Elliot & Rowan Tracts Non -Discharge WQ0004268 UIC Permit Name (if different): Murphy Brown WWIS NPDES Other Facility Address: PO Box 856, Warsaw NC 28398 TYPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery PO Box 856, Warsaw NC (IAS8 County Sampson (City) (state) (Zip) ❑■ Spray Field ❑ Remediation: Contact Person: David Nordin Telephone#: 910-293-5574 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Elliot and Rowan sites No. of wells to be sampled: 12 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW - R5 Date sample collected: 7/9/2022 FIELD ANALYSES: WAS Well Depth: 17 ft. Well Diameter: 2 in. pH 00400: 4.6 units Temp. 00010: 24.5 °C DRY at Depth to Water Level 82546: 5.8 ft. below measuring point Screened Interval: ft. to _ft. Spec. Cond. 000sa: µMhos time ofsampling, Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Odor 000as: None check Volume of water pumped/bailed before sampling: 5 gallons Appearance Clear / Tan here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/9/2022 thru 7/26/2022 Laboratory Name: Environmental Chemists, Inc. Certification No. 94 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 <20 mg/L Nitrite (NO2) as N 00615 <0.02 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 < 1 /100mL Nitrate (NO3) as N 00620 9.10 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100ml- Phosphorus: Total as P 00665 0.05 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 136 mg/L Al - Aluminum o1105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 0.9 mg/L Ca - Calcium 00916 mg/L Chloride 00940 16 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 13 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? ❑■ Yes (1) ❑ No (0) Specific Conductance o0095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia o0610 < 0.2 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen: NH3as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% David Nordin, Director of Environmental Compliance Permittee (or Authorized Agent) Name and Title - Please print or type •.20a 2 GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: and 1 copy COMPLIANCE REPORT FORM 1s FACILITY INFORMATION Please Print Clearly or Type pE Facility Name: Murphy Brown Elliot & Rowan Tracts Nc Permit Name (if different): Murphy Brown WWIS NI Facility Address: PO Box 856, Warsaw NC 28398 Tl PO Box 856, Warsaw NC ('18168 County Sampson (City) (state) (Lip) Contact Person: David Nordin Telephone#: 910-293-5574 Well Location/Site Name: Elliot and Rowan sites No. of wells to be sampled: 12 from Permit SAMPLING INFORMATION WELL ID NUMBER (from Permit): MW - R6 Date sample collected: 7/9/2022 Well Depth: 18 ft. Well Diameter: 2 in. Depth to Water Level 82546:7 ft. below measuring point Screened Interval: ft. to _ft. Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Volume of water pumped/bailed before sampling: 5 gallons Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/9/2022 thru 7/26/22 Laboratory Name: Environmental Chemists, Inc. PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 42 mg/L Nitrite (NO2) as N 00615 0.03 mg/L Coliform: MF Fecal 31616 21 /100mL Nitrate (NO3) as N 00620 3.47 mg/L Coliform: MF Total 31504 /100ml- Phosphorus: Total as P 00665 0.10 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L issolved Solids:Total 70300 187 mg/L Al - Aluminum oilo5 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 13.3 mg/L Ca - Calcium 00916 mg/L Chloride 0094o 21 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L Phenol 32730 ug/L Fe - Iron 01045 ug/L Sulfate 00945 23 mg/L Hg - Mercury 71900 ug/L Specific Conductance 00095 µMhos K - Potassium 00937 mg/L Total Ammonia 00610 <0.2 mg/L Mg - Magnesium 00927 mg/L (Ammonia Nitrogen; NH. as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L TKN as N 00625 mg/L Ni - Nickel 01067 ug/L ESOURCES ` - RMIT Number: Expiration Date: 4/30/2023 n-Discharge WQ0004268 UIC ,DES Other PE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery ❑■ Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge ❑ Water Source Heat Pump ❑ Other: FIELD ANALYSES: pH 00400: 5.4 units Spec. Cond. 00094: Odor 00085: None Appearance Clear / Tan Temp. 00010: 21 °C µMhos Certification No. 94 Pb - Lead o1o51 ug/L Zn - Zinc 01092 mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? K Yes (1) ❑ No (0) VOC 7873 method # method # method # method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% G W-59 Rev. 05-02-2017 DRY at time of sampling, check here: ❑ SUBMIT FORM ON YELLOW PAPER ONLY ,.,DEPARTMENT OF,ENVIRONMENTAL QUALITY_= t)IV, OF WATER•RESQURCES GROUNDWATER QUALITY MONITORING: iN1=6RMTION PRacesslNGrUNIT COMPLIANCE REPORT FORM 1617 MAIL"SERVICE CENTER, RALEIGH, NO 17699.1617 Phone: 919.807.6306 FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 4/30/2023 Facility Name: Murphy Brown Elliot & Rowan Tracts Non -Discharge W00004268 UIC Permit Name (if different): Murphy Brown WWIS NPDES Other Facility Address: PO Box 856, Warsaw NC 28398 TYPE OF PERMITTED OPERATION BEING MONITORED PO Box 856, Warsaw NC (�YgS8 County Sampson ❑ Lagoon ❑ Remediation: Infiltration Gallery (City) (state) (zip) A Spray Field ❑ Remediation: Contact Person: David Nordin Telephone#: 910-293-5574 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Elliot and Rowan sites No. of wells to be sampled: 12 ❑ Water Source Heat Pump ❑ Other: from Permit SAMPLING INFORMATION if WELL WELL ID NUMBER (from Permit): MW - R7 Date sample collected: 7/9/2022 FIELD ANALYSES: WAS Well Depth: 15 ft. Well Diameter: 2 in. pH 00400: 4.5 units Temp. 00010: 21.2 eC DRY at Depth to Water Level 82546:7.5 ft. below measuring point Screened Interval: ft. to _ft. Spec. Cond. 00094: µMhos time of sampling, Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Odor 000ss: None check Volume of water pumped/bailed before sampling: 5 gallons Appearance Clear here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO LABORATORY INFORMATION Date sample analyzed: 7/9/2022 thru 7/26/2022 Laboratory Name: Environmental Chemists, Inc. Certification No. 94 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 21 mg/L Nitrite (NO2) as N 00615 <0.02 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 9 /100mL Nitrate (NO3) as N 00620 0.31 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.05 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 206 mg/L Al -Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 0068o 4.2 mg/L Ca - Calcium 00916 mg/L Chloride 0094o 66 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 46 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? 0 Yes (1) ❑ No (0) pecific Conductance 00095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia 00610 <0.20 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH,as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOc Removal ie David Nordin, Director of Environmental Compliance Permittee (or Authorized Agent) Name and Title - Please print or type 20=_ GW-59 Rev.05-02-2017 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING:, ;,, NFoMRTlarr p1�p�ss1NC#.uNIT COMPLIANCE REPORT FORM,,�T,Mdl��svlcc�N7R;,nIaH� N2�rear�01ahona;.s1e soT ssos FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 4/30/2023 Facility Name: Murphy Brown Elliot & Rowan Tracts Non -Discharge W00004268 UIC Permit Name (if different): Murphy Brown WWIS NPDES Other Facility Address: PO Box 856, Warsaw NC 28398 TYPE OF PERMITTED OPERATION BEING MONITORED PO Box 856, Warsaw NC (�8168 County Sampson ❑ Lagoon ❑ Remediation: Infiltration Gallery (City) (State) (zip) ❑■ Spray Field Remediation: Contact Person: David Nordin Telephone#: 910-293-5574 ❑ Rotary Distributor ❑ Land Application of Sludge Well Location/Site Name: Elliot and Rowan sites No. of wells to be sampled: 12 ❑ Water Source Heat Pump ❑ Other: (from Permit SAMPLING INFORMATION If WELL WELL ID NUMBER (from Permit): MW - R8 Date sample collected: 7/9/2022 FIELD ANALYSES: WAS Well Depth: 18 ft. Well Diameter: 2 in. pH 00400: 4.6 units Temp. 00010: 22.6 °C DRY at Depth to Water Level 82546:10.1 ft. below measuring point Screened Interval: ft. to — ft. Spec. Cond. 00094: µMhos time of sampling, Measuring Point is 3 ft. above land surface Relative M.P. Elevation: ft. Odor 0008s: None check Volume of water pumped/bailed before sampling: 5 gallons Appearance Red / Tan here: ❑ Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO Date sample analyzed: 7/9/2022 thru 7/26/2022 Laboratory Name: Environmental Chemists, Inc. Certification No. 94 PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 <20 mg/L Nitrite (NO2) as N 00615 <0.02 mg/L Pb - Lead 01051 ug/L Coliform: MF Fecal 31616 < 1 /100mL Nitrate (NO3) as N 00620 13.7 mg/L Zn - Zinc 01092 mg/L Coliform: MF Total 31504 /100mL Phosphorus: Total as P 00665 0.15 mg/L (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other (Specify Compounds and Concentration Units): issolved Solids:Total 70300 138 mg/L Al - Aluminum 01105 mg/L pH (Lab) 00403 units Ba - Barium 01007 ug/L TOC 00680 <0.5 mg/L Ca - Calcium o0916 mg/L Chloride 00940 7 mg/L Cd - Cadmium 01027 ug/L Arsenic 01002 ug/L Chromium: Total 01034 ug/L Grease and Oils 00552 mg/L Cu - Copper 01042 mg/L ORGANICS: (by GC, GC/MS, HPLC) Phenol 32730 ug/L Fe - Iron 01045 ug/L (Specify test and method #. ATTACH LAB REPORT.) Sulfate 00945 13 mg/L Hg - Mercury 71900 ug/L Lab Report Attached? 0 Yes (1) ❑ No (0) Specific Conductance o0095 µMhos K - Potassium 00937 mg/L VOC 7873 method # Total Ammonia o0610 <0.2 mg/L Mg - Magnesium 00927 mg/L method # (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese 01055 ug/L , method # TKN as N 00625 mg/L Ni - Nickel 01067 ug/L method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% Permittee (or Authorized Agent) Name and Title - Please print or type GW-59 Rev.05-02-2017 Signature of Permittee (or Authorized Agent) (Date) •2 SUBMIT FORM ON YELLOW PAPER ONLY GROUNDWATER QUALITY MONITORING: COMPLIANCE REPORT FORM FACILITY INFORMATION Please Pnnt Clearly or Type Facility Name: Murphy Brown Elliot & Rowan Tracts Permit Name (if different): Murphy Brown WWIS Facility Address: PO Box 856, Warsaw NC 28398 PO Box 856, Warsaw NC (�Y9168 County Sampson ict Person: David Nordin Location/Site Name: Elliot and Rowan sites WELL ID NUMBER (from Permit): MW - R9 Well Depth: 17 ft. Depth to Water Level 82546: 16.7 ft. below measuring point Measuring Point is 3 ft. above land surface Telephone#: 910-293-5574 No. of wells to be sampled: 12 Date sample collected: 7/9/2022 Well Diameter: 2 in. Screened Interval: ft. Relative M.P. Elevation: to _ ft. ft. Volume of water pumped/bailed before sampling: 4 gallons Samples for metals were collected unfiltered: ❑ YES ❑ NO and field acidified: ❑ YES ❑ NO ERMIT Number: Expiration Date: 4/30/2023 on -Discharge W00004268 UIC PDES Other YPE OF PERMITTED OPERATION BEING MONITORED ❑ Lagoon ❑ Remediation: Infiltration Gallery 0 Spray Field ❑ Remediation: ❑ Rotary Distributor ❑ Land Application of Sludge late sample analyzed: 7/9/2022 thru 7/26/2022 Laboratory Name: Environmental Chemists, Inc. ARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations. COD 00335 25, mg/L Nitrite (NO2) as N 00615 <0.02 Coliform: MF Fecal 31616 < 1 /100ml- Nitrate (NO3) as N 00620 8.45 Coliform: IMF Total 31504 /100ml- Phosphorus: Total as P 00665 0.41 (Note: Use MPN method for highly turbid samples) Orthophosphate 70507 ssolved Solids:Total 70300 110 mg/L Al - Aluminum o11o5 pH (Lab) 00403 units Ba - Barium 01007 TOC 00680 1.1 mg/L Ca - Calcium 00916 Chloride 00940 8 mg/L Cd - Cadmium 01027 Arsenic 01002 ug/L Chromium: Total 01034 Grease and Oils 00552 mg/L Cu - Copper 01042 Phenol 32730 ug/L Fe - Iron 01045 Sulfate 00945 16 mg/L Hg - Mercury 71900 pecific Conductance 00095 µMhos K - Potassium 00937 Total Ammonia oo610 <0.20 mg/L Mg - Magnesium 00927 (Ammonia Nitrogen; NH, as N; Ammonia Nitrogen, Total) Mn - Manganese o1055 TKN as N 00625 mg/L Ni - Nickel 01067 mg/L mg/L mg/L mg/L mg/L ug/L mg/L ug/L ug/L mg/L ug/L ug/L mg/L mg/L ug/L ug/L ❑ Water Source Heat Pump ❑ Other: FIELD ANALYSES: pH 00400: 4.3 units Spec. Cond. 00094: Odor000m: None Temp. 000lo: 21.6 °C µMhos Appearance Tan / Turbid Pb - Lead o1o51 Zn - Zinc 01092 Certification No. 94 ug/L mg/L Other (Specify Compounds and Concentration Units): ORGANICS: (by GC, GC/MS, HPLC) (Specify test and method #. ATTACH LAB REPORT.) Lab Report Attached? ❑■ Yes (1) ❑ No (0) VOC 7873 method # method # method # method # For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal% G W-59 Rev. 05-02-2017 If WELL DRY at time of sampling, check here: ❑ R-3 Date DTW Field Temp. Field pH EC Fecal Coliform CI COD NO, N NH ,- N Total-P TDS SO TOC ft. C Std. Units umhos/cm MPN/100 ml !0 6.90 15.2 4.5 NT <5 48.0 <20 5.31 <0.20 0110 216 45.0 1.40 0 6.90 20.4 4.1 NT <1 49 0 34 4.36 <0.20 0.110 208 58.0 1.50 20 4.80 19.1 4.8 NT <1 7.0 <20 9.5 <0.02 0.380 73 15.0 0.80 !1 6.40 12.6 4.4 NT <1 18.0 <20 0.18 <0.02 0.390 103 27.0 1.70 1 7.80 20.0 1 4.3 NT <7 200 <20 3.76 <0.02 0.070 170 81.0 1.30 21 8 80 18.6 3.86 NT <1 14.0 <20 2.58 <0.02 0.060 204 103.0 0,80 !2 7.80 13.8 4.80 NT <1 12.0 <20 0.63 <0.20 0.040 196 101.0 100 2 Boo 23.5 4.50 NT <1 130 <20 1.30 <0.02 0.060 196 96.0 0.70 7.2 17.9 4.4 NT <1 22.6 34.0 3.5 <0.20 0.2 170.8 65.8 1.2 4.8 12.6 3.9 NT <1 7.0 <20 0.2 <0.02 0.0 73.0 15.0 0.7 c 6.8 23.5 4.8 NT <5 49.0 34.0 9.5 <0.20 0.4 216.0 103.0 1.7 ds. 6.5 -8.5 250 10 1.5 500 250 R-4 Date DTW Field Temp. Field pH EC Fecal Coliform CI COD NQ- N NH ,- N Total-P TDS SO TOC tt. C Std. Units umhos/cm MPN/100 ml mg/ L-____ 20 6.80 15.8 4.6 NT <5 63.0 20.0 2,36 <0,20 0.29 190 19.0 2.10 !0 7,20 21 b 4.4 NT <1 70.0 41.0 1.57 <0.20 0.32 179 20.0 3.00 20 5.10 193 4.9 NT <1 TO 35.0 4.24 0.03 0.56 77 14.0 3.10 21 7D0 13.0 4.5 NT <7 48.0 <20 0.76 0.41 181 22.0 2.50 !l 7.20 22.6 4.4 NT <1 490 23.0 3.86 <0.02 0.38 156 25.0 3.00 21 8.50 204 3.7 NT <1 64.0 22.0 0,20 <0.02 0.55 211 23.0 1.30 22 7.00 139 4.9 NT 0 51 0 20.0 2.80 <0.20 017 179 27.0 2.70 2 7.60 21 1 4.4 NT <1 53.0 21.0 3.54 <0.02 024 171 30.0 2.40 1 7.1 18.5 4.5 NT <1 50.6 26.0 2.4 <0.20 0.4 168.0 22.5 2.5 1 5.1 13.0 3.7 NT <1 7.0 <20 0.2 <0.20 0.2 77.0 14.0 1.3 a 8.5 22.6 4.9 NT <5 70.0 41.0 4.2 0.03 0.6 211.0 30.0 3.1 tds. 6.5- 8.5 250 10 1.5 500 250 R-5 Data DTW Field Temp. Field PH EC Fecal Coliform CI COD NO, N NH ,- N Total-P TDS SO TOC g. CI Sid. Units jumhos/cm MPNI100 ml I fed I tan tan 580 25 3 4.7 NT <1 190 20 7.54 <0.20 0.05 118 17.0 1.50 4.20 20.7 4.8 NT <1 240 <20 14.30 <0.02 0.36 140 14.0 1.20 5.40 13.3 4.6 NT <1 22.0 <20 17.60 <0.02 0.27 186 14.0 1.10 5,90 24.5 4.5 NT <1 17.0 <20 10.30 <0.02 0.07 113 15.0 0.80 EN2 6.50 20.2 4.0 NT <1 19.0 <20 13.30 <0.02 0.05 153 14.0 0.80 640 13.9 5.1 NT <124.0 <20 514 <0.20 02 1534 14.1 100 5.80 24.5 4.6 NT <7 160 <20 9.10 <0.02 0.1 136.0 130 5.7 19.8 4.7 NT <1 21.5 <20 11.3 <0.20 0.1 147.9 14.4 1.1 Min 4.2 13.3 4.0 NT <1 16.0 <20 5.1 <0.02 0.1 113.0 13.0 0.8 Max 6-5 25.3 5.1 NT <5 31.0 20.0 17.6 0.2 0.4 186.0 17.0 1.5 GWStds. 6.5-8.5 250 10 1.5 500 250 I M-h Sample Date DTW Field Temp. Field pH EC Fecal Coliform CI COD NO, N NH ,- N Total-P TDS SO TOC g, C Std. Units umhos/cm MPN/100 ml - mgf L--- Mar-20 7 10 163 5.4 NT 15 44.0 45.0 3.62 <0.02 0.29 256 39.0 13,40 Jul-20 130 21.4 5.4 NT <1 42.0 61.0 1.2 <0.20 0.09 215 32.0 16.60 Nov-20 620 210 60 NT 206 24.0 50.0 1,28 <0.02 051 159 22.0 15.10 Mar-20 /.001 NT <1 30.0 40.0 0.17 0.03 0,39 184 27.0 1420 6.902 NT 59 30.0 35.0 2.47 0,02 0.07 187 28.0 13.00 907 NT <1 36 0 48.0 0.32 <0.02 0.08 200 38.0 15.50 6903 R21.05.4 NT 1 290 26.0 4.5 <0.20 007 198 29.0 8.60 700 NT 21 210 42.0 347 003 010 187 230 13.30 IGWStds. 7.0 3 NT 70.3 32.0 43.4 2.1 0.03 0.2 198.3 29.8 6.2 7 NT <I 21.0 26.0 0.2 <0.02 0.1 159.0 22.0 7.9 0 NT 200.0 44.0 61.0 4.5 0.0 0.5 256.0 39.0 16.6 6.5-8.5 250 1 10 1.5 500 250 R-7 Sample Data DTW Field Temp. Field pH EC Fecal Coliform cl COD NO, N NH ,- N Total-P TDS SO TOc ft. ' C Sid. Units umhos/cm MPN/100 ml - mg/ L--- Mar-20 4.80 16.1 4.9 NT <5 110.0 <20 0.08 <0.20 0.14 272 22.0 4.30 Jul-20 6.80 21.3 4.9 NT <1 78.0 39 <0.02 <0.20 0.07 185 17.0 4.80 Nov-20 4.00 19.9 5.0 1 NT 1 81.0 29 0.16 <0.02 0.32 187 29.0 5.30 Mar-21 1 5.80 14.0 4.8 1 NT <1 38.0 <20 0.02 <0.02 0.15 151 28.0 4,60 Jul-21 7.80 21.0 5.1 NT <1 71.0 <20 0.23 <0.02 0.05 188 20.0 4.20 Nov-21 10.00 19.1 4.3 NT <1 79.0 720 0.09 <0.02 0.06 191 32.0 3.60 Mar-22 600 14.3 5.2 NT <t 73.0 <20 0.33 <0.20 0.07 215 390 4.00 Jul-22 /.50 21.2 4.5 NT 9 1 66.0 21 0.31 <0.02 0.05 206 46.0 4.20 Mean 6.6 18.4 4.8 NT 5.0 74.5 29.7 0.2 <0.20 0.1 199.4 29.1 4.4 Min 4.0 14.0 4.3 NT < I 38.0 <20 <0.02 <0.20 0.05 151.0 17.0 3.6 Max 10.0 21.3 i 5.2 NT 9.0 110.0 39.0 0.3 <0.20 0.3 272.0 46.0 5.3 GWStds. 6.5-8.5 250 1 1 10 1 1.5 500 250 Murphy Brown - Elliot & Rowan Tracts, Turkev, NC. Permit # WQ0004268 Groundwater Quality' MW-1 Sample Date DTW Field Temp. Field pH EC Fecal Coliform Cl COD NO; N NH ,- N Total-P TDS SO TOC ft. C Std. Units umhoslcm MPN/100 ml - mg/ L--- Mar-20 23.30 19.4 5.2 NT <1 77.0 <20 7.36 <0.20 0.190 321 75.0 2.90 Jul-20 22.50 19.2 4.9 NT <1 63.0 26 6.30 <0.20 0.040 321 90.0 2.30 Nov-20 24.10 19.0 4.7 NT <1 170.0 30 7.52 <0.02 0.400 386 34.0 2.50 Mar-21 21.00 17.1 5.7 NT <1 16.0 <20 043 <0.02 0.280 181 52.0 1.10 19.40 18.4 4.9 NT <7 530 <20 14.40 <0-02 <0.04 438 195.0 2.30 25.80 17.6 5.1 NT <1 121.0 <20 17.60 <0.02 0.090 484 2Z0 1.50 2650 17.3 6.2 NT <1 124.0 <20 13.90 020 0.040 360 120.0 1.60 2580 190 4.4 NT <1 1500 31 6.17 <0.02 0.150 312 9.0 2.10 rNo,-21 23.6 18.4 5.1 NT <I 96.8 29.0 9.2 <0.20 0.2 350.42.0 19.4 17.1 4.4 NT <1 16.0 <20 0.4 <0.02 <0.04 181.0 9.0 1.1 26.5 19.4 6.2 NT <1 170.0 31.0 17.6 0.2 0.4 484.0 195.0 2.9 6.5 - 8.5 1 250 1 10 1.5 500 250 MW-2 Sample Date DTW Field Temp. Field pH EC Fecal Coliform Cl COD NO H,-,-N NN Total-P TDS SO TOC ft. C Std. Units umhos/cm MPN/100 ml - mg/ L- Mar-20 9.30 16.6 5.6 NT <1 38.0 <20 0.23 <0.2 0.07 162 20.0 3.10 Jul-20 9.70 is 5.3 NT <1 39.0 <20 0.31 <0.2 <0.04 134 18.0 2.80 Nov-20 8.90 19.3 5.6 NT <1 35.0 32 0.18 <0.02 0.24 118 18.0 2.90 Mar-21 9.20 14.9 5.4 NT <1 39.0 <20 0.04 <0.02 0.09 136 15.0 3.20 9.80 17.9 5.5 NT <1 28.0 <20 0.35 <0.02 0.05 122 18.0 2.90 10.30 18.9 4.8 NT <7 24.0 <20 0.14 <0.02 <0.04 123 19.0 2.40 1020 153 5.7 NT <1 390 <20 027 <02 <0.04 142 16.0 2.30 11.40 18.5 5.4 NT <1 430 21 035 <002 <0.04 157 150 2.20 oNov-21 9.9 17.5 5.4 NT <1 35.6 26.5 0.2 <0.02 0.1 136.8 17.4 2.7 8.9 14.9 4.8 NT <1 24.0 <20 0.04 <0.02 <0.04 118.0 15.0 2.2 11.4 193 5.7 NT <1 43.0 32.0 0.4 <0.2 0.2 162.0 20.0 3.2 6.5-8.5 250 10 1.5 500 250 MW-3 Sample Date DTW Field Temp. Field pH EC Fecal Coliform CI COD NO,- N NH ,- N Total•P TDS SO TOC g. C Std. Units umhos/cm MPN/100 ml Mar-20 3.20 154 6.3 NT <7 139.0 <20 <0.02 <0.20 0.67 251 51.0 0.80 Jul-20 4.10 1901 5.6 NT <1 108.0 <20 0.04 <0.20 0.49 400 45.0 0.90 Nov-20 2.60 19.0 6.0 NT 12 126.0 <20 0.03 <0.02 0.75 433 54.0 1.00 Mar-21 3.80 13.5 5.6 NT <1 154.0 <20 <0.02 <0.02 0.31 579 62.0 0.80 Jul-21 5.00 18.4 5.7 NT 54 60.0 <20 0.17 <0.02 1.31 350 3Z0 1.40 Nov-21 5.50 18.2 5.1 NT <1 60.0 <20 0.07 <0.02 1.92 339 37.0 <0.50 Mar-22 4.20 14.8 5.7 NT <1 125.0 <20 0.06 <0.2 7.94 493 58.0 1.00 Jul-22 4.80 19.8 5.8 NT 56 88.0 23 0.05 <0.02 0.32 416 43.0 1.20 Mean 4.2 17.3 5.7 NT 40.7 107.5 1 23.0 0.1 <0.20 1.7 407.6 48.4 1.0 Min 2.6 13.5 5.1 NT <I 60.0 <20 <0.02 <0.02 0.3 251.0 37.0 <0.5 Max 5.5 19.8 6.3 NT 56.0 154.0 23.0 0.2 <0.20 7.9 579.0 62.0 1.4 GWStds. 6.5-8.5 1 1 250 10 1 1.5 1 1 Soo 250 R-1 DTW Field Temp. Field pH EC Fecal Coliform Cl COD NO,- N NH,- N Total-P TDS SO TOC 6Nov-20 ft. C Std. Units umhos/cm MPNl100 ml mg/ L____ 5.20 15.2 4.8 NT <5 27.0 <20 0.09 <0.20 0.69 142 16.11 1.30 6.30 22.7 4.2 NT <1 19.0 21 1.09 <0.02 0.87 ill 17.0 0.80 4.60 19.3 5.0 NT <1 27.0 <20 0.17 <0.02 1.42 107 18.0 1.50 Mar-21 S 20 12.6 1 4.1 NT <1 30.0 <20 013 <0.02 1.61 120 15.0 3.50 Jul-21 5.90 23.1 4.2 NT <1 49.0 <20 3.57 <0.02 0.66 155 14.0 2.20 Nov-21 /.70 17.8 3.9 NT <1 30.0 42 0.12 <0.02 0.45 147 29.0 0.60 Mar-22 5.60 127 4.6 NT <1 34.0 <20 1.09 <0.2 3.27 128 11.0 2.00 Jul-22 5.80 22.9 4.6 NT <1 55.0 20 353 <0.02 0.68 160 16.0 2.70 Mean 5.8 18.3 4.4 NT <I 33.9 27.7 1.2 <0.02 1.2 133.8 17.0 1.8 Min 4.6 12.6 3.9 NT <I 19.0 <20 0.1 <0.02 0.5 107.0 11.0 0.6 Max 7.7 23.1 5.0 NT <5 55.0 42.0 3.6 <0.20 3.3 160.0 29.0 IS GWStds. 6.5$.51 250 1 10 1.5 1 500 1 250 R-2 Sample Date DTW Field Temp. Field pH EC Fecal Coliform Cl COD NO,- N NH ,- N Total-P TDS SO TOC g. C Sid. Units umhos/cm MPN/100 ml -- mg/ L-- Mar-20 5.20 16.8 4.4 NT <5 12.0 <20 12.4 <0.2 0.17 149 11.0 1 A 0 Jul-20 5.40 24.5 4.1 NT <7 120 <20 9.58 <0.2 0.11 97 6.0 0.60 Nov-20 3.80 NT <1 11.0 <20 2.6 0.04 0.40 96 40.0 0.70 Mar-21 5.30 2 NT <1 11.0 <20 0.45 <0.02 0.41 119 40.0 0.60 5.80 0 NT <1 14.0 <20 9.09 <0.02 0.18 108 10.0 0.60 720 7 NT <1 13.0 <20 9.75 <0.02 6.14 107 6.0 <0.50 6.70 1M224.3 3 NT <1 11.0 <20 0.23 <0.20 0.29 136 13.0 0.80 5.90 3 NT <1 10.0 <20 8.48 <0-02 0.05 97 160 0.50 VGWStds� 5.7 2 NT <1 11.8 <20 6.6 004 0.2 113.6 17.8 0.7 3.8 7 NT <1 10.0 <20 0.2 <0.02 0.1 96.1 6.00.5 7.2 5 NT <5 14.0 120 12.4 0.04 0.4 149.0 40.0 1.1 6.5 -8.5 1 250 10 1.5 500 250 R-8 Sample Data DTW Field Temp. Field pH EC Fecal Coliform Cl COD NO,- N NH ,- N Total-P TDS S0 TOC ft. C Sid. Units umhos/cm MPN/100 ml - mg/ L-- Mar-20 5.80 16.3 6.4 NT <5 10.0 <20 116.2 <0.2 0.16 165 14.0 0.90 Jul-20 6.00 22.6 6.1 NT <7 10.0 <20 15.7 <0.2 0.12 155 14.0 0.80 Nov-20 3.80 21.2 6.4 NT <1 9.0 -20 17.4 0,03 0.24 129 14.0 0.70 Mar-21 5.70 14.0 6.2 NT <7 9.0 <20 16.1 0.02 0.28 158 15.0 0.50 Jul-21 7.80 22.2 5.2 NT <1 11.0 <20 12.7 10.02 0.19 154 15.0 0.70 Nov-21 9.50 20.8 5.2 NT <1 8.0 <20 12.5 <0.02 0.12 140 14.0 <0.5 Mar-22 7.20 15.0 6.1 NT <1 7.0 <20 8.82 70.2 0.10 141 15.0 0,50 Jul-22 10.10 22.6 4.6 NT <1 7.0 <20 1 13.7 <0.02 1 0.15 1 138 13.0 <0.5 Mean 7.0 19.3 5.8 NT <1 8.9 <201 14.1 1 0.03 0.2 147.5 14.3 0.7 Min 3.8 14.0 4.6 NT <I 7.0 <20 8.8 <0. 12 0.1 129.0 111) <0.5 Max 10.1 22.6 6.4 NT <5 11.0 120 17.4 0.03 0.3 1 165.0 15.0 0.9 GWStds. 6.5 - 8.5 250 10 1.5 1 500 250 R-9 Sample Date DTW Field Temp. Field pH EC Fecal Coliform Cl COD NO, N NH,. N Total-P TDS SU TOC C Sid. Units umhos/cm MPN/100 ml - mg/ L--_ Mar-20 8.50 17.2 4.9 NT <5 6.0 20 6.00 <0.20 0.38 106 21.0 1.00 Ju1-20 8,60 23.7 4.7 NT <7 6.0 72 5,49 <0.20 1,65 100 20.0 190 Nov-20 7.20 21.7 4.7 NT <7 8.0 <20 19.10 <0.02 0,55 109 18.0 1.10 Mar-21 9.60 12 4 4.5 NT <7 9.0 32 1.31 <0.02 0.40 129 17.0 1.90 Jul-21 9.30 21.2 4.0 NT <1 11.0 <20 9.39 <0.02 0.41 144 17.0 1.30 Nov-21 10.20 20.1 3.79 NT <1 9.0 30 10.60 <0.02 0.63 140 17.0 1.30 Mar-22 12.30 15.0 4.70 NT <1 8.0 <20 5.22 <0.20 0.17 117 16.0 1.00 Jul-22 16.70 21.6 4.30 NT <i 8.0 25 8.45 <0.02 0.41 110 16.0 1.10 Mean 10.3 19.1 4.4 NT <1 8.1 35.8 8.2 <0.20 0.6 119.4 17.8 1.3 Min 7.2 '12.4 3.8 NT <1 6.0 <20 1.3 <0.20 0.2 100.0 16.0 1.0 Max 16.7 23.7 4.9 NT <5 11.0 72.0 19.1 <0.20 1.7 144.0 21.0 1.9 GWStds. 6.5-8.5 250 10 1.5 i Soo 250 NOTES: u not match groundwater standards. rhos/cm = micromhos per centimete r; mg/L= parts per million; NT= Not Tested DTW - depth to groundwater; Field Temp = field temperature; EC- electrical conductivity; Cl- chloride; COD- chemical oxygen demand; NO,- N - nitrate-nilroge n; NH,-N - ammonia- nitrogen; Total-P - Total Phospho rus; TDS = tola I dissolved soli ds; 90.,= total sulfa te; and TOG = total organic carbon Ile, NC, ENCO Laboratories, Cary, NC, and Enviromental Chemists, Inc. Iliot & Rowan Tracts- Turkey, NC lundwater Quality' Date: _ c) 2-2- r_ Analyst: _ -i 't t C e.V ` Certification N 94 Facility Name: Jam_ 1 LIQO n } rp' PermitN: --n(4,;� tdr/ pH Rrfe-- Mmh—1 SM4inn H+R -1011 1—tci—nt IT-) Calibration Time Cal Buffer 4.0 s u Cal Buffer 10,0 s It Check Buffer 7.0 s.0 Comments -7, 10 L1. Do (°' Io,o I (`' `7.01 "' •phl check buffer must read within ± 0.1 pH units of the buffer's true value 4 su buffer Lot#/: Ricca 4112869 Exo 1 1/22 7 su buffer Lot#/: Ricca 2112A38 E\P. 1223 10 su buffer Lot#: RICCA 2112750 Exo_ 523 Sample location Sample Collection Time* Sample Analysis Time* pH Result s u ►Post -analysis Buffer Check value s.u. CommentSlData Qualifiers J 2 e 45 P. '. 4-to 5.41 Do 02. S-4e I 1 0: 2 1 U : S4 4•�;S -a 1D',2.2 1o,.14 4.33 ► Post analysis buffer check is required when performing analyses at multiple sampling locations and must be within + 0.1 units of the buffer's true value All pl1 values in pH units (i.e., s u ) Record all data to the nearest 0.01 s u. and report to the nearest 0 1 s u. Total Residual Chlorine (TRC) Referener Method' SM 41no CI-C.7oI I Hach 9167 HR- ( Please circle annlicahle Method Instrument ID' Daily Check Post -analysis Check Std Time check Sample Sample Sample TRC Result Standard Result (when analyzing Standard Location Collection Analysis jig or mg/L Comments'Data Qualifiers pg. L or mg/L at multi le sites) Analyzed Time Time TRC Daily Check Standard true value µg/L or mg/L acceptance range ug/L or mg/L Check standards must recover within t10% of the check standard's true value Annual Calibration Curve Verification Date: LOT # _IDEXX 2109792 Exp. Date: 08/31/22 Reagent Blank Value: (When applicable. Analyze and document a reagent blank when standards, sample dilutions or PT Samples are prepared) Dissolved Oxygen (DO) Rrr-- Methm QM dint n C: _7nI I Inct ntment In Calibration: Venficauon Time Calibration vanablc Meter reading or?u efficiency after calibration • Post -analysis calibration verification (when necessary) Comments Temperature Barometric pressure Theoretical Value mgtL Calculated Value mg1L Use this row when performing a verification instead of calibration Sample Location Sample Collection Time 'Sample Analysis Time DO reading m Comments+Data Qualifiers ♦ When performing analyses at multiple locations, the meter must be recalibrated at each site before analysis or a post -analysis calibration venfcaton must be perlonnea. • If sample is measured directly in the stream and -or onsite, only time analyzed would be recorded with a note that they are measured in situ or immediately Temperature QM 7iin R-7nin Instmment Ili Sample Location Sample Collection Time *Sample Analysis Time Temperature °C Comments.'DataQualifters v30 S ' LUS S•. 4 Vb,5 q-.00 q,0?- 1- I o 3 2 10.3 or LZ 9 • If sample is measured directly in the stream and/or on site, only time analyzed would be recorded, won a note mai mey are measurcu in situ or tmmcummy Annual Verification Date 3 - 2-10 _ Field Personnel Note: QA.001 Rev 1-2022 Date: —7I 91122 Analyst: _ ,�) . iJ (AV e K Certification # 94 Facility Name: 1 f�IU0,r Permit #: W Q l^ie�01 + 2- og pH Reference Method. SM4500 H+B -201 1 Instrument ID Calibration Time Cal Buffer 4.0 s u Cal Buffer 10 0 s u Check Buffer 7.0 s u Comments -].01 1J) *pH check buffer must read within t 0 1 pH units of the buffer's true value 4 su buffer Lot#/: Ricca 4112869 Exo I U22 7 su buffer Lot#/: Ricca 2112A38 Exp. 12123 10 su buffer Lot#: RICCA 2112750 Exa. 5123 Sample location Sample Collection Times Sample Analysis Times pH Result s u 0-Post-analysis Buffer Check value s.u. Comments/Data Qualifiers O I - f0'I3 �4-t4 _� ►�:�v IC)'.ol 4.45 p,-5 :50 Cj S -i P,- Cl'-LAo 1 01 4a I s -301 R- 01'. 3 0 1 0•' 3 2 4 SC) ► Post analysis buffer check is required when performing analyses at multiple sampling locations and must be within s 0.1 units of the buffer's true value All pH values in pH units (i e., s u.). Record all data to the nearest 0.01 s u and report to the nearest 0.1 s.0 Total Residual Chlorine (TRC) Reference Method: SM 4500 CI-G201 I Hach 8167 HR. ( Please circle aoolicable Method Instrument ID' Daily Check Post -analysis Check Sid Time check Sample Sample Sample TRC Result Standard Result (when analyzing Standard Location Collection Analysts µg,L or mg/L CommenwData Qualifiers pg/L or mg/L at multiple sites) Analyzed Time Time TRC Daily Check Standard true value. _ _ — µg/L or mg/L acceptance range µg/L or mg/L Check standards must recover within t10% of the check standard's true value Annual Calibration Curve Verification Date: LOT # 1DEXX 2109792 Exp, Date: 08/31 /22 Reagent Blank Value: __(When applicable. Analyze and document a reagent blank when standards, sample dilutions or PT Samples are prepared) Dissolved Oxygen (DO) Reference Method SM 4500 O G: 2011 Instrument ID Calibration% Verification Time Calibration variable Meter reading or % efficiency after calibration • Post -analysis calibration verification (when necessary) Comments Temperature Barometric ressure Theoretical Value m Calculated Value mg/L Use this row when performing a verification instead of calibration Sample Location Sample Collection Time *Sample Analysis 'rime DO reading m L Comments'Data Qualifiers ♦ When performing analyses at multiple locations, the meter must be recalibrated at each site before analysis or a post -analysis calibration verification must be performed. If sample is measured directly in the stream and/or onsite, only time analyzed would be recorded with a note that they are measured in situ or immediately Temperature Reference Method SM 2550 B-2010 Instrument ID. Sample Location Sample Collection Time 'Sample Analysis Time Temperature °C Comments.,DataQualifiers - 10•,i 2 I0%' 3 Z3 S 1�-LA ID'00 IO'.QI V I R _5 q %so Ci "s a4.5 -+ 1 930, Q ' 12 ZI •2- • If sample is measured direct)!gn the stream and or on site, only time analyzed would be recorded, with a note that they are measured in situ or immediately Annual Verification Date - a Field Personnel Note: QA.001 Rev 1-2022 Date: —7 I - 122 Analyst: jcqj Pow,rr Certification # 94 Facility Name: Q` c (-, t'., �e � / Permit#: �r'�iJL C)lDQ L 2-� b pH Reference Method SM4500 H+B -2011 Instrument ID Calibration Time Cal Buffer 4 0 s u Cal Buffer 10 0 s u Check Buffer 7 0 s u Comments if,p0 ") 110,0( ") -7,p1 (4) 'pl l check buffer must read within ± 0 1 pH units of the buffer's true value. 4 su buffer Lot#L Ricca 4112869 Exo 11J22 7 su buffer Lot#/: Ricca 21 12A38 Exo. 1223 10 su buffer Loti!_ RICCA 2112750 Exo, 523 Sample location Sample Collection Time♦ Sample Analysis Time* pH Result s.0 ►Post -analysis Buffer Check value s u. Comments Data Qualifiers - G'.2-0 q - 2-2-L4-5 C) % 4 (.o I o •- LAI 4 9-. ► Post analysis buffer check is required when performing analyses at multiple sampling locations and must be within a 0.1 units of the buffer's true value All pl1 values in pH units (i.e, s.u.). Record all data to the nearest 0.01 s u and report to the nearest 0.1 s u Total Residual Chlorine (TRC) Reference Metlind' SM 450t1 CI-G201 i Hach R 167 HR- ( Please circle nnnlicahle Method Instrument ID Daily Check Post -analysis Time check Sample Sample Standard Result Check Sid Standard Sample Collection Analysis TRC Result Comments/Data Qualifiers pgiL or mg/L (when analyzing Analyzed Location Time Time pg/L or mg/L at multiple sites) TRC Daily Check Standard true value µg/L or mg/L acceptance range µg/L or mg/L Check standards must recover within t 100/. of the check standard's true value Annual Calibration Curve Verification Date: LOT # iDEXX 2109792 Exp. Date: 08/31/22 Reagent [clank Value: (When applicable. Analyze and document a reagent blank when standards, sample dilutions or PT Samples are prepared) Dissolved Oxygen (DO) Reference Method SM 4500 O G.-2011 Instrument ID Calibration! Verification Time Calibration variable Meter reading or % efficiency after calibration •Post -analysis calibration verification (when necessary) Comments Temperature Barometric ressure Theoretical Value m L Calculated Value mg/L Use this row when performing a verification instead of calibration Sample Location Sample Collection Time 'Sample Analysis Time DO reading m L Comments Data Qualifiers ♦ When performing analyses at multiple locations, the meter must be recahbrated at each site before analysis or a post -analysis calibration verification must be performed ' If sample is measured directly in the stream and,or onsite, only time analyzed would be recorded with a note that they are measured in situ or immediately Temperature Reference Method SM 7SSn ti_7nln Inetniment 11) Sample Location Sample Collection Time *Sample Analysis Time Temperature °C Comments?Data Qualifiers R-8 9'.7-0 Zz z2,e --- -_-- -- — _ • If sample is measured direct) in the stream and'or on site, only lime anal} zed would be recorded, with a note that they are measured insitu or immediately Annual VenFtication Date � • 22- Field Personnel Note: QA.001 Rev 1-2022 Environmental Chemist, Inc., Wilmington, INC Lab #94 6602 Windmill Way Wilmington, NC 28405 910.392.0223 Sample Receipt Checklist Clien5h ITWFR( ,T,j �+— Date: Report Number: A a Receipt of sample: ECHEM Pickup Client Delivery ❑ JUPS ❑ FedEx ❑ Other ❑ ❑ YES 10 NO N/A 1. Were custody seals present on the cooler? ❑ YES ID NO 14 N/A 12. If custody seals were present, were they intact/unbroken? Original temperature upon receipt •C Corrected temperature upon receipt •C How temperature taken: ❑ Temperature Blank Y Against Bottles IR Gun ID: Thomas Traceable S/N 192511657 IR Gun Correction Factor •C: 0.0 ❑ YES ❑ NO 3. If temperature of cooler exceeded 6•C, was Project Mgr./QA notified? 10 YES ❑ NO 4. Were proper custody procedures (relinquished/received) followed? �7 YES ❑ NO 5. Were sample ID's listed on the COC? YES ❑ NO 6. Were samples ID's listed on sample containers? YES ❑ NO 7. Were collection date and time listed on the COC? YES ❑ NO 8. Were tests to be performed listed on the COC? YES ❑ NO 1 9. Did samples arrive in proper containers for each test? YES ❑ NO 110. Did samples arrive in good condition for each tast7 YES ❑ NO 11. Was adequate sample volume availableT Ck YES ❑ NO 12. Were samples received within proper holding time for requested tests? YES ❑ NO 13. Were acid preserved samples received at a pH of <2? YES ❑ NO 14. Were cyanide samples received at a pH >12? ❑ YES ❑ NO 15. Were sulfide samples received at a pH >9? YES ❑ NO 16. Were NH3/TKN/phenol received at a chlorine residual of <0.5 m/L? ** ❑ YES ❑ NO 17. Were Sulfide/Cyanide received at a chlorine residual of <0.5 m/L? ❑ YES ❑ NO 18. Were orthophosphate samples filtered in the field within 15 minutes? * TOC/Volatiles are pH checked at time of analysis and recorded on the benchsheet. ** Bacteria samples are checked for Chlorine at time of analysis and recorded on the benchsheet. Sample Preservation: (Must be completed for any sample(s) incorrectly preserved or with headspace) Sample(s) were received incorrectly preserved and were adjusted accordingly by adding (circle one): H2SO4 HNO3 HCI NaOH Time of preservation: If more than one preservative is needed, notate in comments below Note: Notify customer service immediately for incorrectly preserved samples. Obtain a new sample or notify the state lab if directed to analyzed by the customer. Who was notified, date and time: Volatiles Sample(s) were received with headspace COMMENTS: DOC. QA.002 Rev 1 � u Analytical & Consulting Chemists ENVIRONMENTAL CHEMISTS, INC NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 C()l I r-rTI(IN ANTI t^.I-IAIN M: (-I ICTr)nv 6602 Windmill Way Wilmington, NC 26405 OFFICE: 910-392-0223 FAX 910-392-4424 CLIENT: Smithfield Hog Production -Warsaw PROJECT NAME: Del Monte Facility REPORT NO: t�.�LL •' %Ls�L ADDRESS: CONTACT NAME: Kraig Westerbeck PO NO: REPORT TO: PHONE/FAX: COPY TO: E-MAIL: Sampled Bv: SAMPI F TYPF• I = Infliianf F = Ffflnant W = Wall AT = Sfraam Rr) = Snil SI = Slnrina C)thar- Identification Collection CL :E>1 E `o o 0 c 88 o a " rn ,Sample r E " m � 7 Z PRESERVATION ANALYSIS REQUESTED pate Time Tem T7___ o v _ 0 z 0 c Z o w x o Well: LL %G C P 7 X Chloride, NO2, TDS, Sulfate G G y Depth to water:: 310 C P X NH3, NO3, Total P, COD G G Gallons Bailed: Z- C P X TOC G G ph (field) C P X Fecal Coliform G G Odor: A ^ IL C P G G Color: Lt `�'� /�1C•s G G C P G G C P G G C P G G Transfer Relinquished By: DatelTirne Received By: Dateffime 1. 2. Temperature when Received °C: Delivered By: Comments: Accepted: ived By: ected: Resample uested: Date: Hly LI Time:��3 TURMAROUND: Analytical & Consulting Chemists ENVIRONMENTAL CHEMISTS, INC NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 COLLECTION AND CHAIN OF CUSTODY 6602 Windmill Way Wilmington, NC 28405 OFFICE: 910-392-0223 FAX 910-3924424 CLIENT: Smithfield Hog Production -Warsaw PROJECT NAME: Del Monte Facility REPORT NO: of — / � C� ADDRESS: CONTACT NAME: Kraig Westerbeck PO NO: REPORT TO: PHONEIFAX: COPY TO: E-MAIL: Sampled By: SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil, SL = Sludge, Other: Sample Identification Collection y A w y m .n E `o o _ C C7 `o ° a " v c J L E " of W m 2 g z PRESERVATION ANALYSIS REQUESTED Date Time Temp i Z u x y w o z 0 a Z g x ~ r o Well: -7 21 e Y4 / 7 C P 31D�� X JChloride, NO2, TDS, Sulfate G G Depth to water:: C P ��� X NH3, NO3, Total P, COD G G Gallons Bailed: C P X TOC G G ph (field) 0 C P X Fecal Coliform G G Odor: C P G G Color: G �`� C P G G C P G G C P G G C P G G Transfer Relinquished By: DatelTime Received By: DatelTime 1. 2. Temperature when Received QC: Accepted: Rejected: Resampoe equested: Delivered By: Received By: Date: , Time: Comments: �� TURNAROUND: ENVIRONMENTAL CHEMISTS, INC 602Windmill Way -0Wilmington, AX NC 92-440 Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 OFFICE: COLLECTION AND CHAIN OF CUSTODY CLIENT: Smithfield Hog Production -Warsaw PROJECT NAME: Del Monte Facility REPORT NO: ADDRESS: CONTACT NAME: Kraig Westerbeck PO NO: REPORT TO: PHONE/FAX: COPY TO: E-MAIL: Sampled By: SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil, SL = Sludge, Other: Sample Identification p Collection N E m F- N N ii o E C7 U N S° o` c a U v Q `o rn L E U W m °� g Z PRESERVATION ANALYSIS REQUESTED Date Time Temp w Z zz u x v h = r O T. = O Z o rr ~ - x O 11 Well: "7 9 22 'i �� - c C P X Chloride, NO2, TDS, Sulfate G G Y Depth to water:: S"� C P X NH3, NO3, Total P, COD G G Gallons Bailed: S C P X TOC G G h (field) s' C P X Fecal Ccliform G G Odor: fw C P G G Color: :" 4 6. C P G G C C P G G C P G G C P G G Transfer Relinquished By: Date/Time Received By: Date/Time 1. 2. Temperature when Received °C: of Accepted: `T Rejected: Res pie Requested: Delivered By: Cam_ CReceived By: �' Date: Time:L o 3 Comments: TRN ROUND: ENVIRONMENTAL CHEMISTS, INC 602Wi 910392-0223ndmill Way Wilmington, C2840 OFF92-4424 Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 COLLECTION AND CHAIN OF CUSTODY CLIENT: Smithfield Hog Production -Warsaw PROJECT NAME: Del Monte Facility REPORT NO: ADDRESS: CONTACT NAME: Kraig Westerbeck PO NO: REPORT TO: PHONE/FAX: COPY TO: E-MAIL: Sampled By: SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil, SL = Sludge, Other: Sample Identification Collection m v� w CL 8O E o _ `o o a " ` C o` rn t E " Ix m Z PRESERVATION ANALYSIS REQUESTED Date Time Temp w o Z = ao N z - a Z o = - r= o /p� Well: 9- 1 1-Z 'S q D L X Chloride, NO2, TDS, Sulfate G G M Depth to water:: �o C P ��� X NH3, NO3, Total P, COD G G Gallons Bailed: C P X TOC G G ph (field) I C P CL X Fecal Coliform G G Odor:. ��'K C P G G Color: C P G G C P G G C P G G C P G G Transfer Relinquished By: DatelTime Received By: Date/Time 1. 2. Temperature when Received °C: Accepted: r Rejected: Resamp equested: Delivered By: C Received By: cC C Date: 7 Time: /_' 0 Comments: TURNAROUND: Analytical & Consulting Chemists ENVIRONMENTAL CHEMISTS, INC NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 COLLECTION AND CHAIN OF CUSTODY 6602 Windmill Way Wilmington, NC 28405 OFFICE: 910-392-0223 FAX 910-392-4424 CLIENT: Smithfield Hog Production -Warsaw PROJECT NAME: Del Monte Facility REPORT NO: ADDRESS: CONTACT NAME: Kraig Westerbeck PO NO: REPORT TO: PHONE/FAX: COPY TO: E-MAIL: Sampled By: SAMPLE TYPE: I = Influent. E = Effluent. W = Well. ST = Stream. SO = Soil. SL = Sludae_ OthPc le Identification Collection d U °'N e > W_ OSam a o A :C° U0• .0C P E Q W mm PRESERVATION J ANALYSIS REQUESTED Date Time Temp W q Vo x z.0 ~ o Well: it Z 2'1- /e.t- Z LL ' C P 31D� X Chloride, NO2, TDS, Sulfate G G Depth to water:: a- f �' X NH3, NO3, Total P, COD G G Gallons Bailed: C P X TOC G G h (field) C P X Fecal Coliform G G Odor: C P G G Color: C'{GG/ C P G G C P G G C P G G C P G G Transfer Relinquished By: Date/Time Received By: I Date/Time 1. 2. Temperature when Received OC: Accepted: Rejected: Resamp a quested: Delivered By: �C� Received By: C'� Date:? �), Time: Comments: TURNAROUND: Analytical & Consulting Chemists ENVIRONMENTAL CHEMISTS, INC NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 COLLECTION AND CHAIN OF CUSTODY 6602 Windmill Way Wilmington, NC 28405 OFFICE: 910-392-0223 FAX 910-392-4424 CLIENT: Smithfield Hog Production -Warsaw PROJECT NAME: Del Monte Facility REPORT NO:,;g� �o ADDRESS: CONTACT NAME: Kraig Westerbeck PO NO: REPORT TO: PHONE/FAX: COPY TO: E-MAIL: Sampled By: SAMPLE TYPE: I = Influent, E = Effluent, W = Well. ST = Stream. SO = Soil. SL = Sludae. Other_ Identification Collection E>1 N °2 a 8Sample ° o od " ` �` `o E " otu m gZ) Z PRESERVATION r ANALYSIS REQUESTED Date Time Temp z O u _ `o x" o z xx z O x z o Well: °I 2ti I�it L'3 C P %0Toi X Chloride, NO2, TDS, Sulfate G G G tf Depth to water:: l 6 C P X NH3, NO3, Total P, COD G G / Gallons Bailed: S C P X TOC G G ph (field) 14' ya C P X Fecal Coliform G G Odor: A one C P G G Color: c fc U C P G G C P G G C P G G C P G G Transfer Relinquished By: Date/Time Received By: Date/Time 1. 2. Temperature when Received °C: Accepted: L---- Rejected: Resampl R quested: Delivered By: � Received By: C�k- Date: Time: Comments: TURNAROUND: ENVIRONMENTAL CHEMISTS, INC 6602 Windmill Way Wilmington, NC 28405 OFFICE: 910-392-0223 FAX 910-392-4424 Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 COLLECTION AND CHAIN OF CUSTODY CLIENT: Smithfield Hog Production -Warsaw ADDRESS: PROJECT NAME: Del Monte Facility CONTACT NAME: Kraig Westerbeck REPORT NO: as - PO NO: REPORT TO: PHONE/FAX: COPY TO: E-MAIL: Sampled By: SAMPLE TYPE: I = Influent. E = Effluent- W = Wall ST = Ctrpnm cn = cwr cr = cra .. n•i Sample Identification Collection a a© E F n E `o _ CU `o O a C J o` rn cLi E O W m g z PRESERVATION ANALYSIS REQUESTED Date Time Temp z o Z = o r 0 z = ox a Z o = w r= o �I Well -1 X L/ (c q j� /3 X Chloride, NO2. TDS, Sulfate G G Depth to water:: `T t C P { X NH3, NO3, Total P, COD G G Gallons Bailed: S C P X ITOC G G / ph (field) y.y S C P X Fecal Coliform G G Odor: 3AL C P G G Color ea./ C P G G G G C P G G T- C P G G Transfer Relinquished By: Date/Time Received By: Date/Time 7. 2. I rill veiaLuie w11C11 rlecelveu t. _J Accepted: Y Rejected: Resamp a Requested: Delivered By: 1E Received By: C Date: Time: f -0 Comments: TURNAROUND: • ENVIRONMENTAL CHEMISTS, INC 6602 OFFICE millW-yW3F'Agton, NC 284 2840 Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 COLLECTION AND CHAIN OF CUSTODY CLIENT: Smithfield Hog Production -Warsaw PROJECT NAME: Del Monte Facility REPORT NO: a — ADDRESS: CONTACT NAME: Kraig Westerbeck PO NO: REPORT TO: PHONE/FAX: COPY TO: E-MAIL: Sampled By: SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil, SL = Sludge, Other: Sample Identification Collection 61 y E a V) r 0 M CL `o o t9 C.) _ C L) :9 0 Ua C J o 6 :2E 2 W m 3Z PRESERVATION ANALYSIS REQUESTED Date Time Temp w z = 'o N i x Z g = w Well Z Y•' ` 09 X Chloride, NO2, TDS, Sulfate G G n Depth to water:: `l C P �' X XC I NH3, NO3, Total P, COD TOG G C G P i Gallons Bailed: S G G y.&.N,_' ph (field) —4- C P X Fecal Coliform G G Odor: A C P G G Color: G CG/ C P G G rr C P G G C P G G C P G G Transfer Relinquished By: Date/Time Received By: Date/Time 1. 2. Temperature when Received °C: "' Accepted:_ _ Rejected: Resample Requested: Delivered By: Received By* � k' Date: --, 2 Time: Comments: TURNA OUND: ENVIRONMENTAL CHEMISTS, INC 602Windmil910lWayWilmi392-0223 ngton, C29405 OFF92-4424 Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 COLLECTION AND CHAIN OF CUSTODY CLIENT: Smithfield Hog Production -Warsaw PROJECT NAME: Del Monte Facility REPORT NO: ADDRESS: CONTACT NAME: Kraig Westerbeck PO NO: REPORT TO: PHONE/FAX: COPY TO: E-MAIL: Sampled By: SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil, SL = Sludge, Other: Sample Identification Collection ay 47 o a C o O cf7 c° U v c� L E V 2w °' 2 z PRESERVATION ANALYSIS REQUESTED Date Time Temp z °Z = 0 = o T o Z ° f- ~O Well: G 22, 4Y J C r c C P ! 9 , X Chloride, NO2, TDS, Sulfate G G „ Depth to water:: i`f C P �`� ti X NH3, NO3, Total P, COD G G / Gallons Bailed: 5 C P X TOC G G ph (field) fi �`1 C P X Fecal Ccliform G G Odor: C P G G Color: C P G G C P G G C P G G --T, C P IT. T T I G G d Transfer Relinquished By: Date/Time Received By: Date/Time 1. 2. Temperature when Received °C: Accepted: Delivered By: Received By Comments: Rejected: RiesamplRequested: (a Date:? ,; Time: _3 TURNAROUND: ENVIRONMENTAL CHEMISTS, INC 602Wi 4mill Way Wilmington, NC 28406 2-0 23FAX910-3 2-4424 Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 COLLECTION AND CHAIN OF CUSTODY CLIENT: Smithfield Hog Production -Warsaw PROJECT NAME: Del Monte Facility REPORT NO: Da— ADDRESS: CONTACT NAME: Kraig Westerbeck PO NO: REPORT TO: PHONE/FAX: COPY TO; E-MAIL: Sampled By: SAMPLE TYPE: I = Influent, E = Effluent, W = Well. ST = Stream, SO = Soil. SL = Sludae. Other: Sample Identification Collection ca E T A r- a o a `o E a o `o o a. 0" `o m t E aw m QJ z PRESERVATION ANALYSIS REQUESTED Date Time Temp z o Z op W _ o y or a Z o = w x o Well: 1L J 2 L D� X Chloride, NO2, TDS, Sulfate G G Depth to water:: 90 �' X NH3, NO3 Total P, COD G G Gallons Bailed: C P X TOC G G � ph (field) •� J C P X Fecal Coliform G G Odor: C P G G Color: C' «J C P G G C P G G C P G G C P G G Transfer Relinquished By: Date/Time Received By: Date/Time 1. 2. Temperature when Received °C: J Accepted: Rejected: Resam le equested: Delivered By: Received By: r Dat0 Time: I' Comments: TURNAROUND: ENVIRONMENTAL CHEMISTS, INC 6602 OFFICE mill Way 2-0Wilmi223 ngton, C2840 Analytical & Consulting Chemists NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 COLLECTION AND CHAIN OF CUSTODY CLIENT: Smithfield Hog Production -Warsaw PROJECT NAME: Del Monte Facility REPORT NO: ADDRESS: CONTACT NAME: Kraig Westerbeck PO NO: REPORT TO: PHONE/FAX: COPY TO: E-MAIL: Sampled By: SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil SL = Sludge Other: Sample Identification Collection a m E>1 m r- m a o o E E 0 o c U Y o � o a " ` c J _`o L E " ❑ w 4 2 J z PRESERVATION ANALYSIS REQUESTED Date Time Temp z O z � v o z 0 = x 0 a _ L = w = o A Well: O - z_2- 9 r a LZ - C P ! X Chloride, NO2, TDS, Sulfate G G Depth to water:: z1 C P `� X NH3, NO3, Total P, COD G G Gallons Bailed: ! C P X TOC G G / ph (field) y- ss C P I X I I Fecal Coliform G G Odor: /l a ^t C P G G Color: w Ied�'S G G C P G G C P G G C P G G Transfer Relinquished By: Date/Time Received By: Daterrime 1. 2. Temperature When Received "C: Accepted: ✓ Rejected: Resamp a equested: Delivered By: � (� ;i> _ Received By: �' Date: 1 Time: ' U Comments: TUR AROUND: � •u Analytical & Consulting Chemists ENVIRONMENTAL CHEMISTS, INC NCDENR: DWQ CERTIFICATION # 94 NCDHHS: DLS CERTIFICATION # 37729 COLLECTION AND CHAIN OF CUSTODY 6602 Windmill Way Wilmington, NC 28405 OFFICE: 910-392-0223 FAX 910-392-4424 CLIENT: Smithfield Hog Production -Warsaw PROJECT NAME: Del Monte Facility REPORT NO: C�' — % Jl ADDRESS: CONTACT NAME: Kraig Westerbeck PO NO: REPORT TO: PHONEIFAX: COPY TO: E-MAIL: Sampled By: SAMPLE TYPE: I = Influent, E = Effluent, W = Well, ST = Stream, SO = Soil, SL = Sludge, Other: Sample Identification Collection E F U, d E `o o U c `o o a " _ c J `o rn L E O w m M z PRESERVATION ANALYSIS REQUESTED Date Time Temp i o _ o N _ 0 z 0 a z o = w s j Well: / '_/• L ! U X Chloride, NO2, TDS, Sulfate G G L�J + Depth to water:Z$'a C P `\ . X INH3, NO3, Total P, COD G G Gallons Bailed: '7 C P X TOC G G of ph (field) '! • } Z C P X Fecal Coliform G G Odor: C P G G f Color:b•f C P G G C P G G C P G G C P G G Transfer Relinquished By: Date/Time Received By: Date/Time 1. 2. Temperature when Received °C: --3 Accepted: Rejected: Resam le Requested: Delivered By: C Received By: � Date3 Time: Comments: TURNAROUND: F"000- _- __77 SMf ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab . 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info(genvironmentalchemists.com Smithfield Hog Productions - Warsaw Date of Report: Jul 26, 2022 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2022-12826 Project ID: Del Monte -Monitoring Wells Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-31087 Site: MW-1 7/9/2022 8:30 AM Water JCB/Envirochem Test Method Results Date Analyzed Color Color Clear/Reddish 07/09/2022 Depth to water, ft. Depth to Water, Ft. 25.8 feet 07/09/2022 Sulfate EPA 300.0, Rev. 2.1, 1993 9 mg/L 07/12/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0, 1993 < 0.2 mg/L 07/15/2022 Gallons bailed before sampling Gallons Bailed before sampling 2.0 gallons 07/09/2022 Odor Qualitative None 07/09/2022 Total Dissolved Solids (TDS) SM 2W C-2015 312 mg/L 07111 /2022 Temperature SM 2550 B-2010 19.0 C 07/09/2022 pH SM 4500 H B-2011 4.4 units 07/09/2022 Total Phosphorus SM 4500 P (F-H)-2011 0.15 mg/L 07/20/2022 COD SM 5220 D-2011 31.0 mg/L 07/15/2022 Total Organic Carbon (TOC) SM 5310 B-2014 2.1 mg/L 07/12/2022 Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100mL 07/09/2022 Chloride SM4500 Cl E-2011 150 mg/L 07/12/2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353.2, Rev. 2.0, 1993 < 0.02 mg/L 07/11/2022 Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2.0, 1993 6.17 mg/L 07/12/2022 Nitrate Nitrogen Subtraction Method 6.17 mg/L 07/26/2022 Report #:: 2022-12826 Page 1 of 12 _707 Environmental Chemists, Inc. envirochem 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS info(a?environmentalchemists.com Smithfield Hog Productions - Warsaw Post Office Box 856 Warsaw NC 28398 Attention: Amy Elmore Date of Report: Jul 26, 2022 Customer PO #: Customer ID: 08110011 Report #: 2022-12826 Project ID: Del Monte -Monitoring Wells Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-31088 Site: MW-2 7/9/2022 8:45 AM Water JCB/Envirochem Test Method Results Date Analyzed Color Color Clear 07/09/2022 Depth to water, ft. Depth to water, Ft. 11.4 feet 07/09/2022 Sulfate EPA 300.0, Rev. 2.1, 1993 15 mg/L 07/12/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0, 1993 < 0.2 mg/L 07/15/2022 Gallons bailed before sampling Gallons Bailed before sampling 5.0 gallons 07/09/2022 Odor Qualitative None 07/09/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 157 mg/L 07/11/2022 Temperature SM 2550 B-2010 18.5 C 07/09/2022 pH SM 4500 H B-2011 5.4 units 07/09/2022 Total Phosphorus SM 4500 P (F-H)-2011 < 0.04 mg/L 07/20/2022 COD SM 5220 D-2011 21.0 mg/L 07/15/2022 Total Organic Carbon (TOC) SM 5310 B-2014 2.2 mg/L 07/12/2022 Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100mL 07/09/2022 Chloride SM4500 Cl E-2011 43 mg/L 07/12/2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA353.2, Rev. 2.0, 1993 < 0.02 mg/L 07/11/2022 Nitrate+Nitrite-Nitrogen EPA353.2, Rev. 2.0, 1993 0.35 mg/L 07/12/2022 Nitrate Nitrogen Subtraction Method 0.35 mg/L 07/26/2022 Report #:: 2022-12826 Page 2 of 12 rppp- _.- -77 Environmental Chemists, Inc. envlroichem mi,6602 Windmill Way, Wilmington, NC 28405 . 910.392.0223 Lab . 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 . 252.473.5702 Lab/Fax sMi 255-A Wilmington Highway, Jacksonville, NC 28540 ■ 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS info(aenvironmentalchemists.com Smithfield Hog Productions -Warsaw Post Office Box 856 Warsaw NC 28398 Attention: Amy Elmore Date of Report: Jul 26, 2022 Customer PO #: Customer ID: 08110011 Report #: 2022-12826 Project ID: Del Monte -Monitoring Wells Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-31089 Site: MW-3 7/9/2022 9:00 AM Water JCB/Envirochem Test Method Results Date Analyzed Color Color Reddish/Tan/Clear 07/09/2022 Depth to water, ft. Depth to water, Ft. 4.8 feet 07/09/2022 Sulfate EPA 300.0, Rev. 2.1, 1993 43 mg/L 07/12/2022 Ammonia Nitrogen EPA 350.1. Rev. 2.0, 1993 < 0.2 mg/L 07/15/2022 Gallons bailed before sampling Gallons Bailed before sampling 5.0 gallons 07/09/2022 Odor Qualitative Sulfur 07/09/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 416 mg/L 07/11 /2022 Temperature SM 2550 B-2010 19.8 C 07/09/2022 pH SM 4500 H B-2011 5.8 units 07/09/2022 Total Phosphorus SM 4500 P (F-H)-2011 0.32 mg/L 07/20/2022 COD SM 5220 D-2011 23.0 mg/L 07/15/2022 Total Organic Carbon (TOC) SM 5310 B-2014 1.2 mg/L 07/12/2022 Fecal Coliform SM 9222 D-2015 MF 56 Colonies/100mL 07/09/2022 Chloride SM4500 Cl E-2011 88 mg/L 07/12/2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353.2, Rev. 2.0, 1993 < 0.02 mg/L 07/11/2022 Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2.0, 1993 0.05 mg/L 07/12/2022 Nitrate Nitrogen Subtraction Method 0.05 mg/L 07/26/2022 Report #:: 2022-12826 Page 3 of 12 row"W7 -:""7 Environmental Chemists, Inc. envirolchem 7 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax IL 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 - 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS info@environmentalchemists.com Smithfield Hog Productions - Warsaw Date of Report: Jul 26, 2022 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2022-12826 Project ID: Del Monte -Monitoring Wells Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-31090 Site: MW-R1 7/9/2022 10:32 AM Water JCB/Envirochem Test Method Results Date Analyzed Color Color Clear/Tan 07/09/2022 Depth to water, ft. Depth to water, Ft. 5.8 feet 07/09/2022 Sulfate EPA 300 0, Rev. 2.1, 1993 16 mg/L 07/12/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0, 1993 < 0.2 mg/L 07/15/2022 Gallons bailed before sampling Gallons Bailed before sampling 5.0 gallons 07/09/2022 Odor Qualitative None 07/09/2022 Total Dissolved Solids (TDS) SM 2540 c-2015 160 mg/L 07/11/2022 Temperature SM 2550 B-2010 22.9 C 07/09/2022 pH SM 4500 H B-2011 4.6 units 07/09/2022 Total Phosphorus SM 4500 P (F-H)-2011 0.68 mg/L 07/20/2022 COD SM 5220 D-2011 20.0 mg/L 07/15/2022 Total Organic Carbon (TOC) SM 5310 B-2014 2.7 mg/L 07/12/2022 Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100mL 07/09/2022 Chloride SM4500 Cl E-2011 55 mg/L 07/12/2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353.2, Rev. 2.0, 1993 < 0.02 mg/L 07/11/2022 Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2.0. 1993 3.53 mg/L 07/12/2022 Nitrate Nitrogen Subtraction Method 3.53 mg/L 07/26/2022 Report #:: 2022-12826 Page 4 of 12 Environmental Chemists, Inc. envirochem6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS info@ environmentalchemists.com Smithfield Hog Productions - Warsaw Date of Report: Jul 26, 2022 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2022-12826 Project ID: Del Monte -Monitoring Wells Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-31091 Site: MW-R2 7/9/2022 10:22 AM Water JCB/Envirochem Test Method Results Date Analyzed Color Color Clear 07/09/2022 Depth to water, ft. Depth to water, Ft. 5.9 feet 07/09/2022 Sulfate EPA 300.0, Rev. 2.1, 1993 16 mg/L 07/12/2022 Ammonia Nitrogen EPA 350 1, Rev. 2.0,1993 < 0.2 mg/L 07/15/2022 Gallons bailed before sampling Gallons Bailed before sampling 5.0 gallons 07/09/2022 Odor Qualitative None 07/09/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 97 mg/L 07/11/2022 Temperature SM 2550 B-2010 22.5 C 07/09/2022 pH SM 4500 H B-2011 4.3 units 07/09/2022 Total Phosphorus SM 4500 P (F-H)-2011 0.05 mg/L 07/20/2022 COD SM 5220 D-2011 <20 mg/L 07/15/2022 Total Organic Carbon (TOC) SM 5310 B-2014 0.5 mg/L 07/12/2022 Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100mL 07/09/2022 Chloride SM4500 Cl E-2011 10 mg/L 07/12/2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA353.2, Rev.2.0, 1993 < 0.02 mg/L 07/11/2022 Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2.0, 1993 8.48 mg/L 07/13/2022 Nitrate Nitrogen Subtraction Method 8.48 mg/L 07/26/2022 Report #:: 2022-12826 Page 5 of 12 sn+ ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab . 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info"n environmentalchemists.com Smithfield Hog Productions - Warsaw Date of Report: Jul 26, 2022 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2022-12826 Project ID: Del Monte -Monitoring Wells Lab ID Sample ID: Collect Daterrime Matrix Sampled by 22-31092 Site: MW-R3 7/9/2022 10:12 AM Water JCB/Envirochem Test Color Depth to water, ft. Sulfate Ammonia Nitrogen Gallons bailed before sampling Odor Total Dissolved Solids (TDS) Temperature pH Total Phosphorus COD Total Organic Carbon (TOC) Fecal Coliform Chloride Nitrate Nitrogen (Calc) Nitrite Nitrogen Nitrate+ Nitrite-N itrogen Nitrate Nitrogen Method Color Depth to Water, Ft EPA 300.0, Rev. 2.1, 1993 EPA 350.1, Rev. 2.0, 1993 Gallons Bailed before sampling Qualitative SM 2540 C-2015 SM 2550 B-2010 SM 4500 H B-2011 SM 4500 P (F-H)-2011 SM 5220 D-2011 SM 5310 B-2014 SM 9222 D-2015 MF SM4500 Cl E-2011 EPA 353.2, Rev. 2.0, 1993 EPA 353.2, Rev. 2.0, 1993 Subtraction Method Results Date Analyzed Clear 07/09/2022 8.0 feet 07/09/2022 96 mg/L 07/12/2022 < 0.2 mg/L 07/15/2022 5.0 gallons 07/09/2022 None 07/09/2022 196 mg/L 07/11/2022 23.5 C 07/09/2022 4.5 units 07/09/2022 0.06 mg/L 07/20/2022 <20 mg/L 07/15/2022 0.7 mg/L 07/12/2022 <1 Colonies/100mL 07/09/2022 13 mg/L 07/12i2022 < 0.02 mg/L 1.30 mg/L 1.30 mg/L 07/ 11 /2022 07/13/2022 07/26/2022 Report*: 2022-12826 Page 6 of 12 envirochem SM, ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910,347.5843 Lab/Fax infota environmentalchemists.com Smithfield Hog Productions - Warsaw Date of Report: Jul 26, 2022 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2022-12826 Project ID: Del Monte -Monitoring Wells Lab ID Sample ID: Collect Datetrime Matrix Sampled by 22-31093 Site: MW-R4 7/9/2022 10:00 AM Water JCB/Envirochem Test Method Results Date Analyzed Color Color Clear/Tan 07/09/2022 Depth to water, ft. Depth to Water, Ft. 7.6 feet 07/09/2022 Sulfate EPA 300.0, Rev. 2.1, 1993 30 mg/L 07/12/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0, 1993 < 0.2 mg/L 07/15/2022 Gallons bailed before sampling Gallons Bailed before sampling 5.0 gallons 07/09/2022 Odor Qualitative None 07/09/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 171 mg/L 07/11/2022 Temperature SM 2550 B-2010 21.1 C 07/09/2022 pH SM 4500 H B-2011 4.4 units 07/09/2022 Total Phosphorus SM 4500 P (F-H)-2011 0.24 mg/L 07/20/2022 COD SM 5220 D-2011 21.0 mg/L 07/15/2022 Total Organic Carbon (TOC) SM 5310 B-2014 2.4 mg/L 07/12/2022 Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100ml- 07/09/2022 Chloride SM4500 Cl E-2011 53 mg/L 07/12/2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353.2, Rev. 2.0, 1993 < 0.02 mg/L 07/11/2022 Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2.0, 1993 3.54 mg/L 07/13/2022 Nitrate Nitrogen Subtraction Method 3.54 mg/L 07/26/2022 Report #:: 2022-12826 Page 7 of 12 ropp" -- - —'77 SM ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 - 910.392.0223 Lab - 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 - 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 - 910.347.5843 Lab/Fax info@environmentalchemists.com Smithfield Hog Productions - Warsaw Date of Report: Jul 26, 2022 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2022-12826 Project ID: Del Monte -Monitoring Wells Lab ID Sample ID: Collect DatelTime Matrix Sampled by 22-31094 Site: MW-R5 7/9/2022 9:50 AM Water JCB/Envirochem Test Method Results Date Analyzed Color Color Clear/Tan 07/09/2022 Depth to water, ft. Depth to water, Ft. 5.8 feet 07/09/2022 Sulfate EPA 300.0, Rev. 2.1, 1993 13 mg/L 07/12/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0, 1993 < 0.2 mg/L 07/15/2022 Gallons bailed before sampling Gallons Bailed before sampling 5.0 gallons 07/09/2022 Odor Qualitative None 07/09/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 136 mg/L 07/11 /2022 Temperature SM 2550 B-2010 24.5 C 07/09/2022 pH SM 4500 H B-2011 4.6 units 07/09/2022 Total Phosphorus SM 4500 P (F-H)-2011 0.05 mg/L 07/20/2022 COD SM 5220 D-2011 <20 mg/L 07/15/2022 Total Organic Carbon (TOC) SM 5310 B-2014 0.9 mg/L 07/12/2022 Fecal Coliform SM 9222 0-2015 MF <1 Colonies/100mL 07/09/2022 Chloride SM4500 Cl E-2011 16 mg/L 07/12/2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA353.2, Rev. 2.0, 1993 < 0.02 mg/L 07/11/2022 Nitrate+Nitrite-Nitrogen EPA353.2. Rev.2.0, 1993 9.10mg/L 07/13/2022 Nitrate Nitrogen Subtraction Method 9.10 mg/L 07/26/2022 Report #:: 2022-12826 Page 8 of 12 y --.,qq7 Environmental Chemists, Inc. envirochem6602 Windmill Way, Wilmington, NC 28405 . 910.392.0223 Lab . 910.392.4424 Fax fM 710 Bowsertown Road, Manteo, NC 27954 . 252.473.5702 Lab/Fax - 255-A Wilmington Highway, Jacksonville, NC 28W • 910.347.5843 Lab/Fax ANALYTICAL & CONSULTING CHEMISTS info@environmentalchemists.com Smithfield Hog Productions - Warsaw Post Office Box 856 Warsaw NC 28398 Attention: Amy Elmore Date of Report: Jul 26, 2022 Customer PO #: Customer ID: 08110011 Report #: 2022-12826 Project ID: Del Monte -Monitoring Wells Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-31095 Site: MW-R6 7/9/2022 9:40 AM Water JCB/Envirochem Test Method Results Date Analyzed Color Color Clear/Tan 07/09/2022 Depth to water, ft. Depth to water, Ft. 7.0 feet 07/09/2022 Sulfate EPA 300.0. Rev. 2.1, 1993 23 mg/L 07/12/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0, 1993 < 0.2 mg/L 07/15/2022 Gallons bailed before sampling Gallons Bailed before sampling 5.0 gallons 07/09/2022 Odor Qualitative None 07/09/2022 Total Dissolved Solids (TDS) SM 2sAO C-2015 187 mg/L 07/11/2022 Temperature SM 2550 B-2010 21.0 C 07/09/2022 pH SM 4500 H B-2011 5.4 units 07/09/2022 Total Phosphorus SM 4500 P (F-H)-2011 0.10 mg/L 07/20/2022 COD SM 5220 D-2011 42.0 mg/L 07/15/2022 Total Organic Carbon (TOC) SM 5310 B-2014 13.3 mg/L 07/12/2022 Fecal Coliform SM 9222 D-2015 MF 21 Colonies/100mL 07/09/2022 Chloride SM4500 C E-2011 21 mg/L 07/12/2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353.2, Rev. 2.0, 1993 0.03 mg/L 07/11/2022 Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2.0, 1993 3.47 mg/L 07/13/2022 Nitrate Nitrogen Subtraction Method 3.47 mg/L 07/26/2022 Report #:: 2022-12825 Page 9 of 12 F157 _Tq7 �MI ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 - 910.392.0223 Lab . 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 . 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 . 910.347.5843 Lab/Fax info@environmentalchemists.com Smithfield Hog Productions - Warsaw Date of Report: Jul 26, 2022 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2022-12826 Project ID: Del Monte -Monitoring Wells Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-31096 Site: MVV-R7 7/9/2022 9:30 AM Water JCB/Envirochem Test Method Results Date Analyzed Color Color Clear 07/09/2022 Depth to water, ft. Depth to water, Ft. 7.5 feet 07/09/2022 Sulfate EPA 300.0, Rev. 2.1, 1993 46 mg/L 07/12/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0, 1993 < 0.2 mg/L 07/15/2022 Gallons bailed before sampling Gallons Bailed before sampling 5.0 gallons 07/09/2022 Odor Qualitative None 07/09/2022 Total Dissolved Solids (TDS) SM 2540iC-2015 206 mg/L 07/11/2022 Temperature SM 2550 B-2010 21.2 C 07/09/2022 pH SM 4500 H B-2011 4.5 units 07/09/2022 Total Phosphorus SM 4500 P (F-H)-2011 0.05 mg/L 07/20/2022 COD SM 5220 D-2011 21.0 mg/L 07/15/2022 Total Organic Carbon (TOC) SM 5310 B-2014 4.2 mg/L 07/12/2022 Fecal Coliform SM 9222 D-2015 MF 9 Colonies/100ml- 07/09/2022 Chloride SM4500 Cl E-2011 66 mg/L 07/12/2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA 353.2, Rev. 2 0 1993 < 0.02 mg/L 07/11/2022 Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2 0 1993 0.31 mg/L 07/13/2022 Nitrate Nitrogen Subtraction Method 0.31 mg/L 07/26/2022 Report #. 2022-12826 Page 10 of 12 FFP�__. 77 sr.+ ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 - 910.392.0223 Lab - 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 - 252.473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 - 910.347.5843 Lab/Fax info a�environmenta]chemists.com Smithfield Hog Productions - Warsaw Date of Report: Jul 26, 2022 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2022-12826 Project ID: Del Monte -Monitoring Wells Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-31097 Site: MW-R8 7/9/2022 9:20 AM Water JCB/Envirochem Test Method Results Date Analyzed Color Color Tan/Reddish 07/09/2022 Depth to water, ft. Depth to water, Ft. 10.1 feet 07/09/2022 Sulfate EPA 300.0, Rev, 2.1, 1993 13 mg/L 07/12/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0, 1993 < 0.2 mg/L 07/15/2022 Gallons bailed before sampling Gallons Bailed before sampling 5.0 gallons 07/09/2022 Odor Qualitative None 07/09/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 138 mg/L 07/11/2022 Temperature SM 2550 B-2010 22.6 C 07/09/2022 pH SM 4500 H B-2011 4.6 units 07/09/2022 Total Phosphorus SM 4500 P (F-H)-2011 0.15 mg/L 07/20/2022 COD SM 5220 D-2011 <20 mg/L 07/15/2022 Total Organic Carbon (TOC) SM 5310 B-2014 <0.5 mg/L 07/12/2022 Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100mL 07/09/2022 Chloride SM4500 Cl E-2011 7 mg/L 07/12/2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA353.2, Rev.2.0, 1993 < 0.02 mg/L 07/11/2022 Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2.0, 1993 13.7 mg/L 07/13/2022 Nitrate Nitrogen Subtraction Method 13.7 mg/L 07/26/2022 Report #:: 2022-12826 Page 11 of 12 ANALYTICAL & CONSULTING CHEMISTS Environmental Chemists, Inc. 6602 Windmill Way, Wilmington, NC 28405 • 910.392.0223 Lab • 910.392.4424 Fax 710 Bowsertown Road, Manteo, NC 27954 • 252,473.5702 Lab/Fax 255-A Wilmington Highway, Jacksonville, NC 28540 • 910.347.5843 Lab/Fax info(a environmentalchemists.com Smithfield Hog Productions - Warsaw Date of Report: Jul 26, 2022 Post Office Box 856 Customer PO #: Warsaw NC 28398 Customer ID: 08110011 Attention: Amy Elmore Report #: 2022-12826 Project ID: Del Monte -Monitoring Wells Lab ID Sample ID: Collect Date/Time Matrix Sampled by 22-31098 Site: MW-R9 7/9/2022 10:46 AM Water JCB/Envirochem Test Method Results Date Analyzed Color Color Tan/Turbid 07/09/2022 Depth to water, ft. Depth to water, Ft. 16.7 feet 07/09/2022 Sulfate EPA 300.0, Rev. 2.1, 1993 16 mg/L 07/12/2022 Ammonia Nitrogen EPA 350.1, Rev. 2.0,1993 < 0.2 mg/L 07/15/2022 Gallons bailed before sampling Gallons Bailed before sampling 4.0 gallons 07/09/2022 Odor Qualitative None 07/09/2022 Total Dissolved Solids (TDS) SM 2540 C-2015 110 mg/L 07/11/2022 Temperature SM 2550 B-2010 21.15C 07/09/2022 pH SM 4500 H B-2011 4.3 units 07/09/2022 Total Phosphorus SM 4500 P (F-H)-2011 0.41 mg/L 07/20/2022 COD SM 5220 D-2011 25.0 mg/L 07/15/2022 Total Organic Carbon (TOC) SM 5310 B-2014 1.1 mg/L 07/12/2022 Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100mL 07/09/2022 Chloride SM4500 Cl E-2011 8 mg/L 07/12/2022 Nitrate Nitrogen (Calc) Nitrite Nitrogen EPA353.2, Rev. 2.0, 1993 < 0.02 mg/L 07/11/2022 Nitrate+Nitrite-Nitrogen EPA 353.2, Rev. 2.0, 1993 8.45 mg/L 07/13/2022 Nitrate Nitrogen subtraction Method 8.45 mg/L 07/26/2022 Comment: Reviewed by: Re