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HomeMy WebLinkAboutWI0400587_Notification of Intent (NOI) – GW Remediation_20220903WithersRavenel 1NIP Our People. Your Success. September 1, 2022 Mr. Michael Rogers DWR - UIC Program 1636 Mail Service Center Raleigh, NC 27699 Subject: Notification of Intent to Construct or Operate Injection Wells Doc's One Stop 215 National Highway Thomasville, Davidson County, North Carolina NCDEQ Incident No. 17393 Mr. Rogers: Attached is a Notification of Intent to Construct or Operate Injection Wells for the State Lead site Doc's One Stop. This site previously had a UIC permit associated with placement of a Provectus Oxygen Releasing Substrate sock, Permit #WI0400417. Attached is a Notice of Intent for injection of Trap and Treat® BOS200® activated carbon. Sincerely, WithersRavenel Eliza betia A. Allyn, P.G. Environmental Project Geologist II 115 MacKenan Drive I Cary, NC 27511 t: 919.469.3340 I f: 919.467.6008 I www.withersravenel.com I License No. F-1479 Cary I Greensboro I Pittsboro I Raleigh I Wilmington North Carolina Department of Environmental Quality — Division of Water Resources NOTIFICATION OF INTENT (NOI) TO CONSTRUCT OR OPERATE INJECTION WELLS The following are `permitted by rule" and do not require an individual permit when constructed in accordance with the rules of 15A NCAC 02C.0200 (NOTE: This form must be received at least 14 DAYS prior to injection) AQUIFER TEST WELLS (15A NCAC 02C .0220) These wells are used to inject uncontaminated fluid into an aquifer to determine aquifer hydraulic characteristics. IN SITU REMEDIATION (15A NCAC 02C .0225) or TRACER WELLS (15A NCAC 02C .0229): 1) Passive Injection Systems - In -well delivery systems to diffuse injectants into the subsurface. Examples include ORC socks, iSOC systems, and other gas infusion methods (Note: Injection Event Records (IER) do not need to be submitted for replacement of each sock used in ORC systems). 2) Small -Scale Injection Operations — Injection wells located within a land surface area not to exceed 10,000 square feet for the purpose of soil or groundwater remediation or tracer tests. An individual permit shall be required for test or treatment areas exceeding 10,000 square feet. 3) Pilot Tests - Preliminary studies conducted for the purpose of evaluating the technical feasibility of a remediation strategy in order to develop a full scale remediation plan for future implementation, and where the surface area of the injection zone wells are located within an area that does not exceed five percent of the land surface above the known extent of groundwater contamination. An individual permit shall be required to conduct more than one pilot test on any separate groundwater contaminant plume. 4) Air Injection Wells - Used to inject ambient air to enhance in -situ treatment of soil or groundwater. Print Clearly or Type Information. Illegible Submittals Will Be Returned As Incomplete. DATE: September 1 , 20_22 PERMIT NO. (to be filled in by DWR) A. B. C. WELL TYPE TO BE CONSTRUCTED OR OPERATED (1) Air Injection Well ..Complete sections B through F, K, N (2) Aquifer Test Well .Complete sections B through F, K, N (3) Passive Injection System Complete sections B through F, H-N (4) X Small -Scale Injection Operation Complete sections B through N (5) Pilot Test Complete sections B through N (6) Tracer Injection Well Complete sections B through N STATUS OF WELL OWNER: State Government WELL OWNER(S) — State name of Business/Agency, and Name and Title of person delegated authority to sign on behalf of the business or agency: Name(s): NCDEQ-DWM, UST Section, Federal & State Lead Program (TF#17393); Attn: Sharon Ghiold Mailing Address: 1646 Mail Service Center City: Raleigh State: NC Zip Code: 27699-1646 County: Wake Day Tele No.: 919-707-8166 EMAIL Address: sharon.ghiold@ncdenr.gov Cell No.: NA Fax No.: 919-571-4718 Deemed Permitted GW Remediation NOI Rev. 1-06-2021 Page 1 D. PROPERTY OWNER(S) (if different than well owner/applicant) Name and Title: Sammy Zitawi Company Name N/A Mailing Address: 1408 Country Lake Drive City: Greensboro State: NC Zip Code: 27406 County: Guilford Day Tele No.: 336-655-8363 Cell No.: EMAIL Address: Fax No.: E. PROJECT CONTACT (Typically Environmental Engineering Firm) Name and Title: Elizabeth A. Allyn, P.G., Environmental Project Geologist II Company Name WithersRavenel, Inc. Mailing Address: 115 MacKenan Drive City: Cary State: NC Zip Code:27511 County: Wake Day Tele No.: 919-469-3340 Cell No.: 919-418-0279 EMAIL Address: lallyn@withersravenel.com Fax No.: 919-467-6008 F. PHYSICAL LOCATION OF WELL SITE (1) Facility Name & Address: Doc's One Stop; 215 National Highway, NCDEQ Incident #17393 City: Thomasville County: Davidson Zip Code: 27350 (2) Geographic Coordinates: Latitude**: 35.891510° Longitude**: -80.071460° Reference Datum: Google Earth Accuracy: +/- 5m Method of Collection: Google Earth **FOR AIR INJECTION AND AQUIFER TEST WELLS ONLY: A FACILITY SITE MAP WITH PROPERTY BOUNDARIES MAY BE SUBMITTED IN LIEU OF GEOGRAPHIC COORDINATES. G. TREATMENT AREA Land surface area of contaminant plume: 680 square feet Land surface area of inj. well network: —225 square feet ( 10,000 ft2 for small-scale injections) Percent of contaminant plume area to be treated 100% (must be < 5% of plume for pilot test injections) H. INJECTION ZONE MAPS — Attach the following to the notification. (1) Contaminant plume map(s) with isoconcentration lines that show the horizontal extent of the contaminant plume in soil and groundwater, existing and proposed monitoring wells, and existing and proposed injection wells; and (2) Cross-section(s) to the known or projected depth of contamination that show the horizontal and vertical extent of the contaminant plume in soil and groundwater, changes in lithology, existing and proposed monitoring wells, and existing and proposed injection wells. (3) Potentiometric surface map(s) indicating the rate and direction of groundwater movement, plus existing and proposed wells. Deemed Permitted GW Remediation NOI Rev. 1-06-2021 Page 2 DESCRIPTION OF PROPOSED INJECTION ACTIVITIES — Provide a brief narrative regarding the purpose, scope, and goals of the proposed injection activity. This should include the rate, volume, and duration of injection over time. Purpose: Elimination of 2B exceedances in groundwater at site Scope: Characterization samples for injection calculations followed by injection of BOS 200 activated carbon based in -situ remediation slurry into 9 injection points. Goals: Significant reduction of source area contamination through removal of dissolved -phase petroleum contamination with the aid of injections. J. APPROVED INJECTANTS — Provide a MSDS for each injectant (attach additional sheets if necessary). NOTE: Only injectants approved by the NC Division of Public Health, Department of Health and Human Services can be injected. Approved injectants can be found online at http://deq.nc.gov/about/divisions/water- resources/water-resources-permits/wastewater-branch/ground-water-protection/ground-water-approved-inj ectants. All other substances must be reviewed by the DHHS prior to use. Contact the UIC Program for more info (919- 807-6496). Injectant: BOS 200 Volume of injectant: 630 lbs BOS 200 diluted in 315 gal water Concentration at point of injection: — 2 lb BOS 200 / gal water Percent if in a mixture with other injectants: 46.5% BOS 200 Injectant: Volume of injectant: Concentration at point of injection: Percent if in a mixture with other injectants: Injectant: Volume of injectant: Concentration at point of injection: Percent if in a mixture with other injectants: K. WELL CONSTRUCTION DATA (1) Number of injection wells: 9 (injection points, not wells) Proposed 0 Existing (provide GW-1s) (2) For Proposed wells or Existing wells not having GW- 1s, provide well construction details for each injection well in a diagram or table format. A single diagram or line in a table can be used for multiple wells with the same construction details. Well construction details shall include the following (indicate if construction is proposed or as -built): Deemed Permitted GW Remediation NOI Rev. 1-06-2021 Page 3 L. SCHEDULES — Briefly describe the schedule for well construction and injection activities. 1) 9 injection points will be advanced for direct injection of BOS 200 slurry with additives. No injection wells will be installed during this process. M. MONITORING PLAN — Describe below or in separate attachment a monitoring plan to be used to determine if violations of groundwater quality standards specified in Subchapter 02L result from the injection activity. 1) Post -injection sampling of monitoring wells MW-1, MW-2, and MW-3 will be completed at the end of the injection event. 2) Monitor site semi-annually until incident closed. N. SIGNATURE OF APPLICANT AND PROPERTY OWNER Well Owner/Applicant: "7 hereby certi& under penalty of law, that I am familiar with the information submitted in this document and all attachments thereto and that, based on my inquiry of those individuals immediately responsible for obtaining said information, I believe that the information is true, accurate and complete. I am aware that there are significant penalties, including the possibility of fines and imprisonment, for submitting false information. I agree to construct, operate, maintain, repair, and if applicable, abandon the injection well and all related appurtenances in accordance with the 15A NCAC 02C 0200 Rules." *de/44_ Signature of Applicant Elizabeth A. Allyn, PG, Environmental Project Geologist II, WithersRavenel On behalf on NCDEQ-DWM, UST Section for Incident #17393 Print or Type Full Name and Title Property Owner (if the property is not owned by the Well Owner/Applicant): "As owner of the property on which the injection well(s) are to be constructed and operated, I hereby consent to allow the applicant to construct each injection well as outlined in this application and agree that it shall be the responsibility of the applicant to ensure that the injection well(s) conform to the Well Construction Standards (15A NCAC 02C .0200)." "Owner" means any person who holds the fee or other property rights in the well being constructed. A well is real property and its construction on land shall be deemed to vest ownership in the land owner, in the absence of contrary agreement in writing. SEE ATTACHED NCDEQ STATE -LEAD ACCESS AGREEMENT FOR PROPERTY Signature* of Property Owner (if different from applicant) Print or Type Full Name and Title *An access agreement between the applicant and property owner may be submitted in lieu of a signature on this form. Please send 1 (one) hard color copy of his NOI along with a copy on an attached CD or Flash Drive at least two (2) weeks prior to injection to: DWR — UIC Program 1636 Mail Service Center Raleigh, NC 27699-1636 Telephone: (919) 807-6464 Deemed Permitted GW Remediation NOI Rev. 1-06-2021 Page 4 4110 WithersRavenel Our People. Your Success. FIGURES Doc's One Stop - NCDEQ Incident #17393 WR Project # 02172214.60 Notice of Intent - UIC September 2022 sign / light pole product li possible gas or water main CULBRETH AVE 01 unknown pipes (likely water) J4341O 4. T 12 O 0 g'7.5' MW-1 unknown pipe (found via GPR) LLULNU: SEWER LINE WATER LINE NATURAL GAS LINE ELECTRIC LINE UST SYSTEM PRODUCT LINE UNKNOWN LINE STORE I BUILDING • Primary BOS 200 Injection Points • Secondary BOS 200 Injection Points ed by DHomans 03-30-2020 Drawing Path: Q:\4305\18\109a Docs One Stop\3_gw elevation.mxd pl 95 (94.89) REFERENCE: 2018 AERIAL PHOTOGRAPH GIS BASE LAYERS WERE OBTAINED FROM DAVIDSON COUNTY AND NC ONEMAP. THIS MAP IS FOR INFORMATIONAL PURPOSES ONLY. ALL FEATURE LOCATIONS DISPLAYED ARE APPROXIMATED. THEY ARE NOT BASED ON CIVIL SURVEY INFORMATION, UNLESS STATED OTHERWISE. CULBRETH-AVE • �1 97.71 i) (94.89) Relative Groundwater Elevation on 3/10/2020 ® Type II Monitoring Well Groundwater Flow Direction Groundwater Contours (feet) Project Parcel GROUNDWATER ELEVATION MAP DOC'S ONE STOP TF-17393 215 NATIONAL HIGHWAY THOMASVILLE, DAVIDSON COUNTY, NORTH CAROLINA SCALE: 1"=40' DATE: 3-30-20 PROJECT NUMBER 4305-18-109A FIGURE NO. 3 J 410 WithersRavenel Our People. Your Success. DIAGRAM OF TYPICAL INJECTION POINT Doc's One Stop - NCDEQ Incident #17393 WR Project # 02172214.60 Notice of Intent - UIC September 2022 Boring # TBD Date TBD WR Rep TBD WithersRavenel 1/ Engineers 1 Planners 1 Surveyors TYPICAL INJECTION POINT - AREA B Job Name Doc's One Stop (NCDEQ Inc. 17393) Job # 02172214.60 Site Loc. Thomasville, Davidson County, NC Easting NA Driller TBD Northing NA Depth in Feet (below land surface) From To Soil Description (Field USCS Classification) Detail 0 4 Native Soils (TBD) Injection Interval DPT Injection Point 15 - 30 feet below land surface 4 10 DPT injection points extend to 30 feet below land surface. Injection intervals for each point are 4 to 10 feet below land surface. Following completion of injections, each point will be abandoned with bentonite and/or concrete to match original surface grade. Page 1 of 1 115 MacKenan Drive, Cory, North Carolina 27511 te1:919.469.3340 fax:919.467.6008 www.withersravenel.com 410 WithersRavenel Our People. Your Success. BOSS 200 SAFETY DATA SHEET Doc's One Stop - NCDEQ Incident #17393 WR Project # 02172214.60 Notice of Intent - UIC September 2022 TRAP & TREAT® BOS 200® Safety Data Sheet Calgo nCarbon® Issued: 06/05/2015 Supersedes: 12/30/2011 Version: 1.0 SECTION 1: Identification of the Substance/Mixture and of the Company/Undertaking 1.1. Product identifier Product name Product form Product code Other means of identification : Activated Carbon : Mixture : 3967 : Activated Carbon 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Adsorbent 1.3. Details of the supplier of the safety data sheet Calgon Carbon Corporation P.O. Box 717 Pittsburgh, PA 15230 412-787-6700 1.4. Emergency telephone number Emergency number : CHEMTREC (24 HRS): 1-800-424-9300 SECTION 2: Hazards Identification 2.1. Classification of the substance or mixture GHS-US classification Combustible Dust H232 Not classified as a simple asphyxiant. Product does not displace oxygen in the ambient atmosphere, but slowly adsorbs oxygen from a confined space when wet. Under conditions of anticipated and recommended use, product does not pose an asphyxiation hazard. 2.2. Label elements GHS-US labeling Signal word (GHS-US) Hazard statements (GHS-US) 2.3. Other hazards Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS-US) No data available Warning : H232 - May form combustible dust concentrations in air : Wet activated carbon can deplete oxygen from air in enclosed spaces. If use in an enclosed space is required, procedures for work in an oxygen deficient environment should be followed. SECTION 3: Composition/Information on Ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % Activated Carbon (CAS No) 7440-44-0 >_ 80 Gypsum (Hydrated calcium sulfate) (CAS No) 13397-24-5 < 20 SECTION 4: First Aid Measures 4.1. Description of first aid measures First -aid measures general First -aid measures after inhalation First -aid measures after skin contact First -aid measures after eye contact First -aid measures after ingestion If exposed or concerned, get medical attention/advice. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before re -use. Never give anything to an unconscious person. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF ON SKIN (or clothing): Remove affected clothing and wash all exposed skin with water for at least 15 minutes. IF IN EYES: Immediately flush with plenty of water for at least 15 minutes. Remove contact lenses if present and easy to do so. Continue rinsing. IF SWALLOWED: Rinse mouth thoroughly. Do not induce vomiting without advice from poison control center or medical professional. Get medical attention if you feel unwell. 06/05/2015 TRAP & TREAT® BOS 200® 3967 For Internal Use Only: PR#85 Page 1 of 7 Activated Carbon Safety Data Sheet 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. However, dust may cause irritation and redness of the eyes, irritation of the skin and respiratory system. The effects of long-term, low-level exposures to this product have not been determined. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting Measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Water spray. Carbon dioxide. Dry chemical. Foam. Sand. : None known. 5.2. Special hazards arising from the substance or mixture Fire hazard Explosion hazard Reactivity 5.3. Advice for firefighters Firefighting instructions : Dust may be combustible under specific conditions. May be ignited by heat, sparks or flames. : Dust may form explosive mixture in air. : No dangerous reactions known under normal conditions of use. Carbon oxides, ammonia, or toxic halide fumes may be emitted upon combustion of the material. : Wear NIOSH-approved self-contained breathing apparatus suitable for the surrounding fire. Use water spray or fog for cooling exposed containers. Evacuate area. SECTION 6: Accidental Release Measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Evacuate area. Keep upwind. Ventilate area. Spill should be handled by trained clean-up crews properly equipped with respiratory equipment and full chemical protective gear (see Section 8). 6.1.1. For non -emergency personnel No additional information available 6.1.2. For emergency responders No additional information available 6.2. Environmental precautions Prevent entry to sewers and public waters. Avoid release to the environment. Product is not soluble, but can cause particulate emission of discharged into waterways. Dike all entrances to sewers and drains to avoid introducing material to waterways. Notify authorities if product enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections No additional information available : Sweep or shovel spills into appropriate container for disposal. Minimize generation of dust. : Sweep or shovel spills into appropriate container for disposal. Minimize generation of dust. Dispose of material in compliance with local, state, and federal regulations. SECTION 7: Handling and Storage 7.1. Precautions for safe handling Precautions for safe handling Avoid dust formation. Avoid contact with skin, eyes and clothing. Do not handle until all safety precautions have been read and understood. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Keep away from sources of ignition - No smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep container tightly closed in a cool, dry, and well -ventilated place. Keep away from ignition sources. SECTION 8: Exposure Controls/Personal Protection 8.1. Control parameters Activated Carbon (7440-44-0)* OSHA PEL (TWA) (mg/m3) <_ 5 (Respirable Fraction) <_ 15 (Total Dust) 06/05/2015 TRAP & TREAT® BOS 200® 3967 For Internal Use Only: PR#85 2/7 Activated Carbon Safety Data Sheet Gypsum (Hydrated calcium sulfate) (13397-24-5)* OSHA PEL (TWA) (mg/m3) <_ 5 (Respirable Fraction) <_ 15 (Total Dust) *Exposure limits are for inert or nuisance dust. No specific exposure limits have been established for this activated carbon product by OSHA or ACGIH. 8.2. Exposure controls Appropriate engineering controls Provide adequate general and local exhaust ventilation. Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. Use explosion -proof equipment with flammable materials. Ensure adequate ventilation, especially in confined areas. Wet activated carbon can deplete oxygen from air in enclosed spaces. If use in an enclosed space is required, procedures for work in an oxygen deficient environment should be followed. Personal protective equipment : Gloves. Safety glasses. Insufficient ventilation: wear respiratory protection. Hand protection Eye protection Skin and body protection Respiratory protection Gloves should be classified under Standard EN 374 or ASTM F1296. Suggested glove materials are: Neoprene, Nitrile/butadiene rubber, Polyethylene, Ethyl vinyl alcohol laminate, PVC or vinyl. Suitable gloves for this specific application can be recommended by the glove supplier. Use eye protection suitable to the environment. Avoid direct contact with eyes. Wear long sleeves, and chemically impervious PPE/coveralls to minimize bodily exposure. Use NIOSH-approved dust/particulate respirator. Where vapor, mist, or dust exceed PELs or other applicable OELs, use NIOSH-approved respiratory protective equipment. SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Physical state Appearance Color Odor Odor threshold pH Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Auto -ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Relative vapor density at 20 °C Apparent density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Explosive limits 9.2. Other information No additional information available Solid Granular, powder, or pelletized substance Black Odorless No data available No data available Not applicable Not applicable Not applicable Not applicable No data available > 220 °C No data available > 220 °C Not applicable Not applicable 0.4 - 0.8 g/cc Carbon and gypsum are insoluble; fertilizer components are soluble Not applicable Not applicable Not applicable Not applicable No data available No data available No data available 06/05/2015 TRAP & TREAT® BOS 200® For Internal Use Only: PR#85 3/7 3967 Activated Carbon Safety Data Sheet SECTION 10: Stability and Reactivity 10.1. Reactivity No dangerous reactions known under normal conditions of use. 10.2. Chemical stability Stable under use and storage conditions as recommended in section 7. 10.3. Possibility of hazardous reactions None known. 10.4. Conditions to avoid Avoid dust formation. Heat. Ignition sources. Exposure to high concentrations of organic compounds may cause bed temperature to rise. 10.5. Incompatible materials Alkali metals. Strong oxidizing agents. 10.6. Hazardous decomposition products Carbon monoxide (CO), carbon dioxide (CO2). Ammonia. Toxic halide fumes. SECTION 11: Toxicological Information 11.1. Information on toxicological effects Acute toxicity : Not classified Activated Carbon (7440-44-0) LD50 oral rat > 2000 mg/kg Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Not classified Not classified Not classified Not classified Not classified Silica: Crystalline, quartz (14808-60-7) IARC group 1 - Carcinogenic to humans The International Agency for Research on Cancer (IARC) has classified "silica dust, crystalline, in the form of quartz or cristobalite" as carcinogenic to humans (group 1). However these warnings refer to crystalline silica dusts and do not apply to solid activated carbon containing crystalline silica as a naturally occuring, bound impurity. As such, we have not classified this product as a carcinogen in accordance with the US OSHA Hazard Communication Standard (29 CFR §1910.1200) but recommmend that users avoid inhalation of product in a dust form. Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Symptoms/injuries after inhalation Sym ptoms/injuries Not classified Not classified Not classified Not classified Not classified Not expected to present a significant hazard under anticipated conditions of normal use. However, dust may cause irritation and redness of the eyes, irritation of the skin and respiratory system. The effects of long-term, low-level exposures to this product have not been determined. SECTION 12: Ecological information 12.1. Toxicity No additional information available 12.2. Persistence and degradability No additional information available 12.3. Bioaccumulative potential No additional information available 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available 06/05/2015 TRAP & TREAT® BOS 200® For Internal Use Only: PR#85 4/7 3967 Activated Carbon Safety Data Sheet SECTION 13: Disposal Considerations 13.1. Waste treatment methods Waste treatment and disposal methods Additional information Vacuum or shovel material into a closed container. Dispose in a safe manner in accordance with local/national regulations. Do not allow the product to be released into the environment. Activated carbon is an adsorbent media; hazard classification is generally determined by the adsorbate. Consult U.S. EPA guidelines listed in 40 CFR 261.3 for more information on hazardous waste disposal. SECTION 14: Transport Information 14.1. In accordance with DOT Not classified as hazardous for domestic land transport UN-No.(DOT) DOT NA no. Proper Shipping Name (DOT) Department of Transportation (DOT) Hazard Classes Hazard labels (DOT) Packing group (DOT) DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) 14.2. Transport by sea Not classified as hazardous for water transport IMO / IMDG UN/NA Identification Number UN- Proper Shipping Name Transport Hazard Class 14.3. Air transport Not classified as hazardous for air transport ICAO / IATA UN/NA No UN- Proper Shipping Name Transport Hazard Class Packing Group Marine Pollutant 14.4. Additional information Other information None on finished product None on finished product Not regulated None on finished product None on finished product None on finished product None on finished product : None on finished product : Not regulated : None on finished product : None on finished product : Not regulated : None on finished product : None on finished product : None on finished product Under the UN classification for activated carbon, all activated carbons have been identified as a class 4.2 product. However, this product type or an equivalent has been tested according to the United Nations Transport of Dangerous Goods test protocol for a "self -heating substance" (United Nations Transportation of Dangerous Goods, Manual of Tests and Criteria, Part 111, Section 33.3.1.6 - Test N.4 - Test Method for Self Heating Substances) and it has been specifically determined that this product type or an equivalent does not meet the definition of a DOT self -heating substance (class 4.2) or any other hazard class. SECTION 15: Regulatory Information 15.1. US Federal regulations Activated Carbon Profile 85 All chemical substances in this product are listed in the EPA (Environment Protection Agency) TSCA (Toxic Substances Control Act) Inventory or are exempt. SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Cobalt (7440-48-4)* Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section 313 - Emission Reporting 0.1 % *Present below de minimis level 15.2. International regulations No additional information available 06/05/2015 TRAP & TREAT® BOS 200® 3967 For Internal Use Only: PR#85 5/7 Activated Carbon Safety Data Sheet 15.3. US State regulations California Proposition 65 WARNING: This product contains, or may contain, trace quantities of a substance(s) known to the state of California to cause cancer, birth defects, or other reproductive harm. Silica: Crystalline, quartz (14808-60-7) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) Yes No No No NA Cobalt (7440-48-4) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) Yes No No No NA Titanium dioxide (13463-67-7) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) Yes No No No NA Aluminum oxide (1344-28-1) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Massachusetts - Right to Know List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List Calcium sulfate (7778-18-9) U.S. - Massachusetts - Right to Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Silica: Crystalline, quartz (14808-60-7) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Massachusetts - Right to Know List Gypsum (Hydrated calcium sulfate) (13397-24-5) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Ammonium Nitrate (6484-52-2) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Massachusetts - Right To Know List U.S. - Pennsylvania - RTK (Right to Know) List Limestone (1317-65-3) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other Information Indication of changes Revision Date Other information For internal use only Revision 1.0: New SDS Created. 06/05/2015 Author: CJS. PR #85 Prepared according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/05/2015 TRAP & TREAT® BOS 200® For Internal Use Only: PR#85 6/7 3967 Activated Carbon Safety Data Sheet NFPA health hazard : 0 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials. NFPA fire hazard : 1 - Must be preheated before ignition can occur. NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 0 Flammability : 1 Physical : 0 Personal Protection This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. The information is this document applies to this specific material as supplied. It may not be valid if product is used in combination with other materials. It is the user's responsibility to determine the suitability and completeness of this information for their particular use. While the information and recommendations set forth herein are believed to be accurate as of the date hereof, Calgon Carbon Corporation makes no warranty with respect to the same, and disclaims all liability for reliance thereon. 06/05/2015 TRAP & TREAT® BOS 200® For Internal Use Only: PR#85 7/7 3967 4110 WithersRavenel Our People. Your Success. AST ENVIRONMENTAL PROPOSAL Doc's One Stop - NCDEQ Incident #17393 WR Project # 02172214.60 Notice of Intent - UIC September 2022 �T Client Name Withers Ravenel Project Location Docs One Stop - Thomasville, NC Area A MW-1 Site Information Predominate Geology of Treatment Zone Treatment Zone Area (ft^2) 225 Contamination Depth Start (ft bgs) 4.0 Contamination Depth End (ft bgs) 10.0 Treatment Volume (yd^3) 50.0 Triangular Grid Spacing (ft) 5.0 Number of Injection Points - Design 9 Injection Interval Distance (ft) 2.0 Number of Injection Intervals per Point - Design 3.5 Total Number of Injection Intervals 32 Effective Porosity 30% Pore Volume (L) 11,470 Soil Density (Ib/ft^3) 110 Speciated COC Design Calculations Contaminant of Concern Benzene Design Basis Soil (mg/kg) or Groundwater (mg/L) Groundwater Design Concentration 2.100 Design Endpoint 0.050 Contaminant of Concern Mass Loading (Ib/ft^3) 3.93E-05 BOS 200 per Injection Interval - Design (Ib) 20 BOS 200 Slurry Volume per Interval (gal) 10 Average BOS 200 per Injection Point (Ib) 70 BOS 200 Total (Ib) 630 TPH Design Calculations TPH Groundwater Concentration (mg/L) TPH Soil Concentration (mg/kg) TPH Mass (Ib) BOS 200 Total Demand (Ib) Design Basis Select Speciated or TPH Speciated Design BOS 200 Total per Area (Ib) 630 Trap & Treat Bacteria Calculations Bacteria Concentrate (gal) 1 Sulfate Demand Calculations Supplemental Gypsum per Interval - Design (Ib) 10 Total Supplemental Gypsum (Ib) 315 Slurry and Water Volumes Slurry Volume per Interval (gal) 10 Estimated Water Volume (gal) 315 Summary BOS 200 Total (Ib) 650 BOS 200 Unit Price ($, per RPI website) $6.75 Bacteria Concentrate (gal) 5 Bacteria Concentrate Price ($, per RPI website) $115.00 Supplemental Gypsum Total (Ib) 350 Gypsum Unit Price ($) $0.45 Estimated Shipping and Tax ($/Ib) $0.25 Total Material Price ($) $5,283 Number of Field Days to Complete 2 Mobilization ($) $2,000 Injection Location Markout ($) Total Installation Price ($) $13,400 Estimated Air Knife - 1-2 days ($) $7,500 Total Estimated Price ($) $26,183 Totals 225 50 9 32 650 650 5 350 315 1 day - $4,500 7/26/2022 ASSUMPTIONS AST has made the following assumptions regarding this approach: 1. Pricing for products and services is valid for 180 days from the date of this proposal. 2. AST will support Withers Ravenel in preparing the UIC permit. 3. Pricing of the BOS 200° is based on the quantities outlined above. Should any of the Proposed Injection Areas be removed from this design, pricing of the BOS 200° must be adjusted to conform to the pricing structure shown at: http://www.trapandtreat.com/products/quantity-pricing/ 4. There will be adequate water onsite (25-gpm service) to prepare the BOS materials for injection. The water service within 200' of all injection locations and fire hoses can be placed and remain in -place for the duration of the injection. Shuttling of water is not required. The water will be provided at no cost to AST. Hydrant permits and fees will be provided by others. 5. The site stratigraphy allows for pushing up to 250 linear feet of 2.25" Geoprobe® rods per day and injection of up to 500 lbs. of BOS 200° per day. 6. Work is performed during standard work week and hours (Monday -Saturday 7am-6pm) 7. Asphalt/concrete penetrations will be patched with like materials. 8. All utilities and underground appurtenances will be located prior to AST arriving on site. AST will not be responsible for repairs to mis-marked or unmarked buried utilities and other appurtenances. 9. Investigated derived waste will be drummed and staged on site for disposal by others. 10. Boring logs will be prepared by others during the injection effort. 11. The total depth throughout the area identified in the injection design will be accessible via direct push utilizing a Geoprobe° 7000 series rig. 12. Traffic control will be provided by others if required. 13. The project is non -union and will not require prevailing wages. 14. After hours security will be provided by others at no cost to AST, if deemed necessary. 15. Withers Ravenel will provide a dumpster for general refuse such as empty paper bags, pallets and other non -hazardous waste. 16. Cold Weather Protocol a. All injection work is to be performed with overnight temperatures above 32 degrees F. If injections are to be performed with overnight lows below 32 degrees F, the installation price will be subject to an additional 25% charge to account for loss time for additional shutdown/startup time for the injection system. b. Injection work in temperatures below 20 degrees F is a health and safety concern for the injection crew. If temperatures are not above 20 degrees F by 10 a.m., no injection work will be performed that day. A daily stand by rate will be charged for days lost due to cold weather. Payment terms are full payment of product and shipping costs upon arrival. Payment of injection services is not to exceed 60 calendar days from date of invoice. Interest will accrue at a monthly rate of 1.5% for all outstanding balances including interest. The interest rate will be prorated for partial months. sign / light pole product li possible gas or water main CULBRETH AVE 01 unknown pipes (likely water) J4341O 4. T 12 O 0 g'7.5' MW-1 unknown pipe (found via GPR) LLULNU: SEWER LINE WATER LINE NATURAL GAS LINE ELECTRIC LINE UST SYSTEM PRODUCT LINE UNKNOWN LINE STORE I BUILDING • Primary BOS 200 Injection Points • Secondary BOS 200 Injection Points 410 WithersRavenel Our People. Your Success. ACCESS AGREEMENT Doc's One Stop - NCDEQ Incident #17393 WR Project # 02172214.60 Notice of Intent - UIC September 2022 Sharon Ghiold DWM UST Section 1637 Mail Service Ctr Raleigh, NC 27699-1637 Dear Ms. Ghiold: RE: Site Access Agreement Doc's One Stop Shop 215 National Highway Thomasville, Davidson County, NC (WSRO) STF #17393, Facility ID 0-001630 I am/We are the owner(s) of a parcel of property, located at or near the incident in question, and hereby permit the Department of Environment and Natural Resources (Department) or its contractor to enter upon said property for the purpose of conducting an investigation of the groundwaters under the authority of G.S. 143-215.3(a)2. I am/We are granting permission with the understanding that: 1. The investigation shall be conducted by the UST Section of the Department's Division of Waste Management or its contractor. 2. The costs of construction and maintenance of the site and access shall be borne by the Department or its contractor. The Department or its contractor shall protect and prevent damage to the surrounding lands. 3. Unless otherwise agreed, the Department or its contractor shall have access to the site by the shortest feasible route to the nearest public road. The Department or its contractor may enter upon the land at reasonable times and have full right of access during the period of the investigation. 4. Any claims which may arise against the Department or its contractor shall be governed by Article 31 of Chapter 143 of the North Carolina General Statutes, Tort Claims Against State Departments and Agencies, and as otherwise provided by law. 5. The information derived from the investigation shall be made available to the owner upon request and is a public record, in accordance with G.S. 132-1. 6. The activities to be carried out by the Department or its contractor are for the primary benefit of the Department and of the State of North Carolina. Any benefits accruing to the owner are incidental. The Department or its contractor is not and shall not be construed to be an agent, employee, or contractor of the land owner. Doc's One Stop TF #17393 January 18, 2013 Page 2 I/We agree not to interfere with, remove, or any way damage the Department's well(s) or its contractor's well(s) and equipment during the investigation. ox^ Signatufe 4VYtrt i4-/-4:1k/; Type/Print Name of Owner or Agent Phone Number I V°g C; +r (k-e pry_ Address Greeor%aara f r_ Z 79 0 City/State/Zip Code t 26-13 Date