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NC0090166_Application_20220912
NPDES Permit Application Press Club Cleaners Brownfields Property 3305 South Boulevard Charlotte, North Carolina RECEIVED 2 ?022 NC►DECJDWRINPDES H&H Job No. TCR-003 September 9, 2022 hart hickman SMARTER ENVIRONMENTAL SOLUTIONS #C-1269 Engineering #C-245 Geology 2923 South Tryon Street,Suite 100 3921 Sunset Ridge Rd,Suite 301 Charlotte,NC 28203 Raleigh,NC 27607 www.harthickman.com 704.586.0007 main 919.847.4241 main hart "'` hickman SMARTER ENVIRONMENTAL SOLUTIONS Via FedEx and Email September 9, 2022 North Carolina Department of Environmental Quality Division of Water Resources—Water Quality Permitting Section (NPDES) Archdale Building- 9th Floor 512 North Salisbury Street Raleigh,North Carolina 27604 Attn: Mr. Wren Thedford Re: NPDES Permit(Minor)Application Package Press Club Cleaners Brownfields Property 3305 South Boulevard Charlotte,North Carolina Brownfields Project Number 25101-21-060 H&H Job No. TCR-003 Dear Mr. Thedtord: 1.0 Introduction and Waiver Request Hart & Hickman, PC (H&H) is submitting this National Pollutant Discharge Elimination System (NPDES) permit application package (one original and two copies) for discharge of treated groundwater generated as part of redevelopment construction dewatering activities at the Press Club Cleaners Brownfields Property site located at 3305 and 3309 South Boulevard in Charlotte, North Carolina(the Site). Note that 3305 South Boulevard is used for the facility location in this application package. H&H is submitting this NPDES permit application package on behalf of the future Site property owner, CH MF BTH III/Charlotte LoSo LLC (also herein referred to as the Permit Applicant). The anticipated closing date for purchase of the Site by the future Site property owner is September 14, 2022. Authorization for H&H to act as CH MF BTH III/Charlotte LoSo LLC's representative for the purpose of submitting this NPDES permit application is included as Attachment A. 2923 South Tryon Street,Suite 100 3921 Sunset Ridge Rd,Suite 301 Charlotte,NC 28203 Raleigh,NC 27607 www.harthickman.com 704.586.0007 main 919.847.4241 main Mr. Wren Thedford September 9, 2022 Page 2 In addition to a $860 check payable to the North Carolina Division of Environmental Quality (NCDEQ) Division of Water Resources (DWR) for a minor NPDES permit, this NPDES permit application package includes the items listed below. • EPA Form 1 NPDES • EPA Form 2C NPDES (with Tables A, B, and C) • EPA Form 2E NPDES • Table 1 —Summary of Groundwater Analytical Data • Figure 1 —Site Location Topographic Map • Figure 2—Site Map and Temporary Monitoring Well Locations • Figure 3 —Treatment System and NPDES Discharge Locations Map • Attachment A—Designation of H&H as Authorized Representative for Permit Applicant • Attachment B—CMSWS Approval for Discharge to Storm Water Sewer System • Attachment C — Groundwater Treatment System Schematic and Drawings/Information Sheets for Treatment System Components • Attachment D—Laboratory Analytical Report(June 2022 Groundwater Samples) Site background information is presented in Section 2.0, a summary of groundwater conditions is presented in Section 3.0, proposed groundwater treatment system and NPDES discharge information are presented in Section 4.0, and an evaluation of alternatives is presented in Section 5.0. Waiver Request This NPDES permit application is for a new temporary discharge. Therefore,there are no existing effluent parameter monitoring data for the discharge and Permit Applicant is requesting a waiver for providing effluent parameter data. However, Site groundwater data(discussed in Section 3.0 and summarized in Table 1) has been utilized to complete EPA Form 2C Tables B and C since effluent data will not be available until the groundwater treatment system is in operation. Note that the maximum concentration of a compound detected in the most recent sample collected from P P monitoring well MW-4 was entered into the tables. These concentrations are representative of hart '` hickman https.//harthick.sharepoint.com/sites/masterfiles-l/shared documents/aaa-master projects/trammel)crow residential -to/tcr-003 press club cleaners/npdes permit/npdes application corer letter&supporting info.docs SMARTER ENVIRONMENTAL SOLUTIONS Mr. Wren Thedford September 9, 2022 Page 3 potential maximum compound concentrations anticipated to be present in treatment system influent (discussed in Section 3.0), rather than effluent data required by EPA Form 2C for an existing discharge. 2.0 Site Background Information The Site consists of three contiguous parcels of land which collectively total approximately 2.3 acres and is developed with an approximately 10,000 square-foot (sq ft) multi-tenant commercial building that consists of two units and a basement. The northern portion of the Site building was most recently operated as a dry-cleaning facility known as Press Club Cleaners. Currently,the Site building is partially occupied as a game room. Remaining portions of the Site consists of paved parking areas,driveways, and vegetated areas. A Site location topographic map is provided as Figure I, and a Site map is provided as Figure 2. Historical dry-cleaning operations have resulted in environmental media impacts at the Site. Based on the results of previous environmental assessment activities,the Site was entered into the North Carolina Department of Environmental Quality (DEQ) Dry-Cleaning Solvent Cleanup Act (DSCA) Program (DSCA Project No. DC600090) in October 2016. Assessment activities completed under the purview of the DSCA Program since 2016 have included installation of four permanent groundwater monitoring wells (identified as MW-1 through MW-4 in Figure 2) at the Site, and results of groundwater samples from one or more of the wells indicate compounds concentrations above North Carolina Administrative Code (NCAC) 15A 2L Groundwater Standards(2L standards) are present in Site groundwater(discussed Section 3.0). The Permit Applicant plans to redevelop the Site with a multi-story residential apartment building, and elected to enter the Site into the DEQ Brownfields Program to address environmental issues associated with the Site. A Letter of Eligibility to participate in the Brownfields Program was received on April 29, 2022, and the Brownfields project is referred to as Press Club Cleaners (Brownfields Project Number 25101-21-060). Proposed redevelopment of the Site generally includes razing the existing Site building, grading and excavation (for installation building and hart hickman hltps.//harthick.sharepointcom/sites/masterfiles-I/shared documents/aaa-master projects/tranmell crow residential -toitcr-003 press club cleaners/npdes permit/npdes application cover letter&supporting info doe,. SMARTER ENVIRONMENTAL SOLUTIONS Mr. Wren-Medford September 9,2022 Page 4 utility structures), and new building construction. Based on groundwater table elevations at the Site, it is anticipated that excavations installed for construction of multiple new storm water sewer lines will intersect the groundwater table. Approximate locations of the proposed storm water sewer lines are depicted in Figure 2. During installation of these structures,excavation dewatering will be performed to remove groundwater which infiltrates into the excavations. As such, this NPDES permit application is being submitted to allow for treatment and direct discharge of groundwater generated during the excavation dewatering activities. 3.0 Summary of Site Groundwater Conditions A summary of groundwater analytical for samples collected from the four permanent monitoring wells (MW-1 through MW-4) located on the Site is presented in Table 1, and monitoring well locations are shown in Figure 2. The laboratory analytical report for groundwater samples collected at the Site during June 2022 is provided as Attachment D. A discussion of the most recent(June 2022) groundwater sample data for the wells is presented below. During June 2022, H&H collected groundwater samples from monitoring wells MW-1 through MW-4 to assist with Brownfield assessment activities. The samples were submitted for laboratory analysis of volatile organic compounds (VOCs), semi-VOCs (SVOCs), and Resource Conservation and Recovery Act(RCRA) 8 metals. As shown in Table 1,results of analysis of the June 2022 samples indicate no SVOCs were detected in the samples, and no metals were detected above NCAC 2L .0202 Groundwater Standards(2L standards)or applicable surface water criteria in the samples. Results of analysis of the June 2022 samples indicate that tetrachloroethylene (PCE) was detected above the 2L standard of 0.7 micrograms per liter (µg/1) in two of the wells (MW-1 at 2,370 µg/1 and MW-4 at 65.6 µg/l). PCE is a common drycleaning solvent and is a VOC. In addition, the PCE degradation compounds trichloroethylene (TCE), cis-1,2- dichloroethylene (cDCE), and vinyl chloride (VC) were detected above 2L standards (70, 3, and 0.03 1.1g/1, respectively) in MW-1 only. The detections of these four compounds in MW-1 also exceed surface water criteria established for the compounds (see Table 1). There were no other VOCs detected above 2L standards or surface water criteria in the June 2022 groundwater samples. hart hickman https://harthick.sharepoim.com/sites/masterfiles-I/shared documents/aaa-master projects/trammell crow residential -tcrflcr-003 press club cleaners/npdes permit/npdes application corer letter&supporting info does SMARTER ENVIRONMENTAL SOLUTIONS Mr. Wren Thedford September 9, 2022 Page 5 As shown in Figure 2, MW-1 is located in the northern (upgradient) portion of the Site and MW- 4 is located in the southeastern (downgradient) portion of the Site. Because MW-4 is located in the general area of a portion of the proposed storm water sewer lines which, will be installed as part of Site redevelopment and MW-3 is located upgradient to cross-gradient of a separate portion of the proposed storm water sewer lines, the highest of the VOCs and metals concentrations detected in the June 2022 MW-3 and MW-4 samples are anticipated to be representative of the highest average treatment system influent concentrations. Therefore, these concentrations were utilized in the EPA Form 2C NPDES Tables. 4.0 Proposed Groundwater Treatment System and NPDES Discharge Information As previously discussed, excavations below the shallow groundwater table are planned for construction of proposed storm water sewer lines as part of Site redevelopment activities. The approximate locations of the proposed storm water sewer lines are shown in Figure 2. During construction of these structures, excavation dewatering will be conducted to remove groundwater which infiltrates into the excavations in order to allow for construction of the sewer lines. This NPDES permit application is being submitted to allow for direct discharge of treated groundwater which is removed from the excavation. As discussed in Section 3.0 above, Site assessment activities have indicated the presence of groundwater impacts at the Site. It is anticipated that the storm water sewer installation activities completed as part of Site redevelopment will be completed within a 1-month period,and that the sewer lines will be installed in sections in order to minimize the size of open excavations and the length of time an excavation is open. Using anticipated sewer line excavation dimensions and Site hydrogeologic data, H&H evaluated groundwater infiltration rates for multiple sewer line excavation segments. Based on the evaluation, H&H calculated a maximum groundwater infiltration rate of 40 gallons per day (gpd) per 10 linear foot (1f) of sewer line excavation. It is anticipated that approximately 50 to 100 If of sewer line excavation will be open at a given time, resulting in a maximum excavation dewatering rate of approximately 2,000 to 4,000 gpd. hart hickman hops://harthick.sharepoinl.com/sites/masterfiles-I/shared documents/aaa-master projects/Trammell crow residential -to/tcr-003 press club cleaners/npdes permit/npdes application cover letter&supporting info.docs SMARTER ENVIRONMENTAL SOLUTIONS Mr. Wren Thedford 1 September 9, 2022 Page 6 In order to manage groundwater extracted from the excavations, the Permit Applicant proposes use of a groundwater treatment system to treat VOCs in the extracted excavation groundwater and direct discharge of the treated groundwater effluent from the system under a NPDES permit into a City of Charlotte storm water culvert located adjacent to the southeastern corner of the Site. The culvert location is identified in Figures 2 and 3. Storm water flows through the culvert, then through various storm channels and Cityof Charlotte municipal storm water system structures and g p Y pipes to an outlet(proposed NPDES Outfall 001) which discharges to surface water(Little Hope Creek)approximately 1,200 ft southeast of the Site. In a letter dated September 8,2022,Charlotte- Mecklenburg Storm Water Services (CMSWS) approved discharge of treated groundwater from the Site to the storm water system under a NPDES permit. A copy of the letter is provided as Attachment B. Little Hope Creek generally flows to the southeast and converges with Little Sugar Creek. The length of Dairy Branch from the proposed NPDES outfall location to Little Sugar Creek is approximately 2.5 miles. Little Hope Creek and Little Sugar Creek are classified by DWR as Class C surface water bodies, and are discussed further in Section 5.0. Proposed groundwater extraction and treatment includes extraction of groundwater from the excavation using submersible pumps to transfer the water into an equalization tank. Groundwater in the equalization tank will then be pumped through the groundwater treatment system which will include a bag filtration unit (used to remove suspended sediments) and a liquid phase granular activated carbon(GAC) unit(used to remove VOCs). The proposed treatment system is designed for an operational flow rate of approximately 10 gallons per minute(gpm),which is conservatively higher than anticipated groundwater extraction rates of 1.5 to 3 gpm (for continuous extraction). However, it is anticipated that excavation dewatering and groundwater treatment will be intermittent and only conducted while construction personnel are on-Site. At an operation rate of 10 gpm, the treatment system will be capable of treating 4,000 gallons of groundwater (i.e., the maximum anticipated daily continuous extraction volume) in approximately seven hours. A groundwater treatment system schematic for the proposed groundwater treatment system is included in Attachment C. Drawings/information sheets for the major groundwater treatment hart hickman haps.//har htcksharepoml.com/sites/masterfiles-I/shared documents/aaa-master projects/trammell crow residential -to/Icr-003 press club cleaners/npdes permit/npdes application cover letter&supporting inl'o.docs SMARTER ENVIRONMENTAL SOLUTIONS Mr. Wren Thedford September 9, 2022 Page 7 components included in the system and for the GAC anticipated to be utilized in the systems are also included in Attachment C. As shown in the treatment system schematic, the proposed treatment system will include the following major components: • An approximately 6,900-gallon equalization tank. The tank will generally be filled to approximately 80 percent capacity(to allow for solids settling and volatilization of VOCs) prior to transferring water to the filtration components of the treatment system (described below). Sediments which accumulate in the equalization tank will be emptied as needed by an appropriately licensed waste management company and transported off-Site for disposal in accordance with applicable regulations. • A Rain For Rent BF 100 bag filter unit, or equivalent alternate. The bag filter unit is rated for a maximum flow rate of 100 gpm. It is anticipated that 10-micron bag filters will be utilized in the filter unit, but the filter size may be changed depending on performance. Spent bag filters will be disposed off-Site in accordance with applicable regulations. • Three Enviro-Equipment LPCD-55 (55-gallon) drums (or, equivalent alternative) filled with reactivated liquid phase GAC will be used for filtration of VOCs. Each GAC drum has a bed volume of approximately 6.6 cf and will be filled with approximately 200 lbs of GAC. In total, the three GAC drums will provide an empty bed contact time of approximately 15 minutes at a 10 gpm flow rate, which is at the high end of Enviro- Equipment's recommended contact time range of 10 to 15 minutes for effective reduction of VOC concentrations. Spent GAC media will be disposed off-Site in accordance with applicable regulations. Based on Enviro-Equipment's experience with similar projects and calculations performed using the June 2022 monitoring well MW-4 sample analytical data (discussed in Section 3.0), VOC breakthrough time assuming operation of the treatment system for seven hours per day at 10 gpm hart i hickman https/Iharthick.sharepoint-com/sites/masterfiles-I/shared documents/aaa-master projects/trammell crow residential -to/Icr-Otl3 press club cleaners/npdes permiUnpdes application cover letter&supporting info(loci. SMARTER ENVIRONMENTAL SOLUTIONS Mr. Wren Thedford September 9, 2022 Page 8 is significantly greater than the anticipated duration of excavation dewatering activities (i.e., approximately 30 days). Samples of influent and effluent from the GAC units will be collected on a weekly basis (at minimum) to monitor for breakthrough of VOCs. In addition, samples will be collected from the system effluent in accordance with NPDES permit requirements to demonstrate effluent discharge limitations are met. 5.0 Evaluation of Alternatives As previously mentioned, NPDES Outfall 001 is proposed to discharge to Little Hope Creek approximately 1,200 ft southeast of the Site. Little Hope Creek generally flows to the southeast approximately 2.5 miles before converging with Little Sugar Creek. Little Hope Creek and Little Sugar Creek are classified by DWR as Class C surface water bodies. Class C waters are protected for uses such as aquatic life propagation, survival and maintenance of biological integrity (including fishing and fish),wildlife,secondary contact recreation,and agriculture. Domestic and industrial wastewater discharges, including treated discharge from groundwater remediation projects addressing water quality problems where no practical alternative exists, are allowed to Class C surface waters. Based on a review of the North Carolina 2022 303(D) List, it does not appear that Little Hope Creek or Little Sugar Creek are impaired in the area of the Site. Little Sugar Creek is listed as impaired for benthos and fish community from the section of the creek located from NC Hwy 51 to the North Carolina-South Carolina state line. This section begins approximately 6.5 miles south of the Site. Total maximum daily loads(TMDLs) for Little Sugar Creek have been developed for dissolved oxygen(approved February 1996), fecal coliform (approved March 2002),and turbidity (approved February 2005). The proposed discharge is not a potential source of fecal coliform or oxygen-consumption processes. Suspended solids (which could adversely affect turbidity levels) will be removed be the groundwater treatment system and the effluent will be subject to total suspended solids limitations in the NPDES permit. We did not identify NPDES permitting hart "sop hickman https.//harthick.sharepomt.com/sites/masterfiles-I/shared documents/aaa-master projects/trammel)crow residential -to/tcr-003 press club cleaners/npdes permit/npdes application cover letter&supporting info.docx SMARTER ENVIRONMENTAL SOLUTIONS Mr. Wren Thedford September 9, 2022 Page 9 strategies which may limit the proposed discharge in the Catawba River Basinwide Water Quality Plan dated September 2010 (Basinwide Plan). Finally, no endangered species associated with Little Hope Creek or Little Sugar Creek were identified in the Basinwide Plan, and no endangered species potentially associated with aquatic environments were identified by the US Fish&Wildlife Service's Information for Planning and Consultation online tool in a user-defined area along Little Hope Creek. H&H has evaluated alternatives to direct discharge under a NPDES permit for management of groundwater generated during proposed Site redevelopment activities. The evaluated alternatives are listed below. • Connection to a municipal publicly owned treatment works(POTW) sewer system • Discharge to land surface/subsurface (including spray/drip irrigation, infiltration gallery, injection wells, etc.) • Spray irrigation Our evaluation of these alternatives to direct discharge under a NPDES permit is presented below. Discharge to a POTW Sewer System Charlotte Water does not allow discharge of groundwater to the POTW sanitary sewer system; therefore, this alternative is not a potential option for management of extracted groundwater generated at the Site. Spray/Drip Irrigation The Site is located in a developed area within the City of Charlotte, and land which is suitable for spray/drip irrigation of the treated groundwater is not available in the area of the Site. The adjacent property to the north of the Site is currently undeveloped, but development of the property with a grocery store is planned for 2022 and 2023. Based on this information,spray/drip irrigation is not considered a feasible alternative for management of extracted groundwater, and costs for the alternative were therefore not evaluated. hart hickman hops.//harthick.sharepointcom/sites/masterfites-I/shared documents/aaa-master projects/trammel)crow residential -tcr/lcr-003 press club cleaners/npdes permttlnpdes application cover letter&supporting info.docx SMARTER ENVIRONMENTAL SOLUTIONS Mr. Wren Thedford September 9, 2022 Page 10 Subsurface Discharge Because the groundwater table beneath the Site is shallow(approximately 2-3 ft bgs in the area of MW-4), there is a small volume of unsaturated soil that would quickly become saturated if extracted groundwater were applied to the unsaturated subsurface via drain fields or infiltration galleries. In addition, portions of the discharged water would be expected to infiltrate back into the aquifer beneath the Site, ultimately resulting in an inefficient and ineffective dewatering/discharge operation. Furthermore, saturation of shallow soil and continued addition of groundwater to the subsurface could result in daylighting of the water at the ground surface followed by overland flow and direct discharge to the storm water system and/or off-Site properties. Similarly,discharge of extracted groundwater into injection wells installed on the Site has the potential to result in groundwater mounding and increased groundwater extraction rates required for preventing infiltration of groundwater into the excavations. Finally, the Permit Applicant does not own off-Site property in the area of the Site which could be used for subsurface disposal of extracted groundwater generated at the Site. Based on the information presented above, subsurface discharge is not considered a feasible alternative for management of extracted groundwater, and costs for the alternative were therefore not evaluated. Alternatives Analysis Summary As presented above, there do not appear to be surface water quality issues associated with Little Hope Creek or Little Sugar Creek which would be impacted by the proposed discharge. In addition, our evaluation of three options for management of extracted groundwater generated as part of Site redevelopment activities indicates that alternatives to direct discharge of treated groundwater under a NPDES permit are not allowable or feasible. Therefore, direct discharge of treated groundwater effluent from the proposed treatment system via a NPDES permit is appropriate. hart ► hickman https://harthick.sharepoint.com/sites/masterhles-1/shared documents/aaa-master projects/trammell crow residential -to/tcr-003 press club cleaners/npdes permit/npdes application coser letter&supporting info.dots SMARTER ENVIRONMENTAL SOLUTIONS Mr. Wren Thedford September 9, 2022 Page 11 Please contact us if you have questions or need additional information. Sincerely, Hart& Hickman, PC cttitAittiA) Haley Martin, PG Scott Drury, PE Senior Project Geologist Project Manager Enclosures: NPDES Permit Application Package Check for$860, payable to NCDEQ cc: Mr. Robert Brooks—CH MF BTH III/Charlotte LoSo LLC (Via E-Mail) 11 hart hickman NW— hops.//harthick.sharepointcom/sites/masterfiles-I/shared documents/aaa-master projects/trammell crow residential -to/tcr-003 press club cleaners/npdes permit/npdes application cover letter&supporting info.docx SMARTER ENVIRONMEN1AL SOLUTIONS EPA Form 1 NPDES EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCR000166157 Press Club Cleaners OMB No.2040-0004 Form U.S.Environmental Protection Agency 1 IS EPA Application for NPDES Permit to Discharge Wastewater NPDES GENERAL INFORMATION SECTION 1.ACTIVITIES REQUIRING AN NPDES PERMIT(40 CFR 122.21(f)and(f)(1)) 1.1 Applicants Not Required to Submit Form 1 1.1.1 Is the facility a new or existing publicly owned 1 1 2 Is the facility a new or existing treatment works treatment works? treating domestic sewage? If yes,STOP. Do NOT complete ❑✓ No If yes,STOP. Do NOT ❑✓ No Form 1.Complete Form 2A. complete Form 1.Complete Form 2S. 1.2 Applicants Required to Submit Form 1 1.2.1 Is the facility a concentrated animal feeding 1.2.2 Is the facility an existing manufacturing, operation or a concentrated aquatic animal commercial,mining,or silvicultural facility that is a production facility? currently discharging process wastewater? ❑ Yes 4 Complete Form 1 ❑✓ No ❑ Yes 4 Complete Form ID No a and Form 2B. 1 and Form 2C. I Z 1.2.3 Is the facility a new manufacturing,commercial, 1.2.4 Is the facility a new or existing manufacturing, mining,or silvicultural facility that has not yet commercial,mining,or silvicultural facility that commenced to discharge? discharges only nonprocess wastewater? m ❑ Yes 4 Complete Form 1 ID No �✓ Yes 4 Complete Form ❑ No cc and Form 2D. 1 and Form 2E. • 1.2.5 Is the facility a new or existing facility whose discharge is composed entirely of stormwater associated with industrial activity or whose discharge is composed of both stormwater and non-stormwater? ❑ Yes 4 Complete Form 1 0✓ No and Form 2F unless exempted by 40 CFR 122.26(b)(14)(x)or b 15). SECTION 2.NAME,MAILING ADDRESS,AND LOCATION(40 CFR 122.21(f)(2)) 2.1 Facility Name Press Club Cleaners Brownfields Property 0 2.2 EPA Identification Number •ia O NCR000166157 J 2.3 Facility Contact Name(first and last) Title Phone number Sean Allen Development Manager (425)301-3806 Email address sallen@TCR.com 2.4 Facility Mailing Address Street or P 0, box 4509 Creedmoor Rd,Ste 308 City or town State ZIP code Raleigh North Carolina 28609 EPA Form 3510-1(revised 3-19) Page 1 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCR000166157 Press Club Cleaners OMB No.2040-0004 d 2.5 Facility Location . Street,route number,or other specific identifier Q U 3305 South Boulevard c County name County code(if known) 1.1 Mecklenburg 060 E J City or town State ZIP code z Charlotte North Carolina 28209 SECTION 3.SIC AND NAICS CODES(40 CFR 122.21(f)(3)) 3.1 SIC Code(s) Description(optional) 6513 Office of Real Estate&Construction-Operators of Apartment Buildings O U N 3 2 NAICS Code(s) Description(optional) 73 53111 Lessors of Residential Buildings and Dwellings U SECTION 4.OPERATOR INFORMATION(40 CFR 122.21(f)(4)) 4.1 Name of Operator CH MF BTH III/Charlotte LoSo,L.L.C.(Attn:Mr.Robert Brooks)***See Section 8.1*** o` 4.2 Is the name you listed in Item 4.1 also the owner?_ E ❑✓ 0 Yes ❑ No 4.3 Operator Status ❑ Public—federal El Public—state 0 Other public(specify) o 0 Private ❑ Other(specify) 4.4 Phone Number of Operator (984)220-8083 4.5 Operator Address Street or P.O.Box d 4509 Creedmoor Rd,Ste 308 o c City or town State ZIP code w o Raleigh North Carolina 27609 m a Email address of operator rbrooks@tcr.com SECTION 5.INDIAN LAND(40 CFR 122.21(f)(5)) - 5.1 Is the facility located on Indian Land? c c co ❑Yes ❑✓ No EPA Form 3510-1(revised 3-19) Page 2 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCR000166157 Press Club Cleaners OMB No.2040-0004 SECTION 6.EXISTING ENVIRONMENTAL PERMITS(40 CFR 122.21(f)(6)) 6.1 Existing Environmental Permits(check all that apply and print or type the corresponding permit number for each) ❑ NPDES(discharges to surface ❑ RCRA(hazardous wastes) ❑ UIC(underground injection of water) fluids) o NCR000166157 rn a ❑ PSD(air emissions) ❑ Nonattainment program(CAA) 0 NESHAPs(CAA) w ❑ Ocean dumping(MPRSA) 0 Dredge or fill(CWA Section 404) 0 Other(specify) SECTION 7.MAP(40 CFR 122.21(f)(7)) 7.1 Have you attached a topographic map containing all required information to this application?(See instructions for specific requirements.) co ✓❑Yes 0 No 0 CAFO—Not Applicable(See requirements in Form 2B.) SECTION 8.NATURE OF BUSINESS(40 CFR 122.21(f)(8)) 8.1 Describe the nature of your business. The facility was occupied by a dry cleaner from at least the late 1960s until the mid-2010s. Historical dry-cleaning operations have resulted in environmental media impacts at the Site,and the Site is currently being managed under the purview of the North Carolina Department of Environmental Quality(DEQ)Dry-Cleaning Solvent Cleanup Act (DSCA)Program(DSCA Program ID DC600090). The Permit Applicant is in the process of purchasing the Site (anticipated closing date of 09/14/22)and plans to redevelop the Site with a multi-story residential apartment building,and elected to enter the Site into the DEQ Brownfields Program to address environmental issues associated with the Site(Brownfields Project Number 25101-21-060). It is anticipated that excavations installed during Site z redevelopment for construction of multiple new storm water sewer lines will intersect the groundwater table. This NPDES permit application is being submitted to allow for direct discharge of treated groundwater generated during dewatering of the excavations. Refer to the NPDES permit application cover letter for additional details. SECTION 9.COOLING WATER INTAKE STRUCTURES(40 CFR 122.21(f)(9)) 9.1 Does your facility use cooling water? d 0 Yes ❑✓ No 4 SKIP to Item 10.1. 3 9.2 Identify the source of cooling water.(Note that facilities that use a cooling water intake structure as described at a,w 40 CFR 125,Subparts I and J may have additional application requirements at 40 CFR 122.21(r).Consult with your c �' NPDES permitting authority to determine what specific information needs to be submitted and when.) O Y SECTION 10.VARIANCE REQUESTS(40 CFR 122.21(f)(10)) 10.1 Do you intend to request or renew one or more of the variances authorized at 40 CFR 122.21(m)?(Check all that apply.Consult with your NPDES permitting authority to determine what information needs to be submitted and when.) 41 c ❑ Fundamentally different factors(CWA ❑ Water quality related effluent limitations(CWA Section 41) Section 301(n)) 302(b)(2)) ❑ Non-conventional pollutants(CWA ❑ Thermal discharges(CWA Section 316(a)) Section 301(c)and(g)) 0 Not applicable EPA Form 3510-1(revised 3-19) Page 3 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCR000166157 Press Club Cleaners OMB No.2040-0004 SECTION 11.CHECKLIST AND CERTIFICATION STATEMENT(40 CFR 122.22(a)and(d)) 11.1 In Column 1 below,mark the sections of Form 1 that you have completed and are submitting with your application. For each section,specify in Column 2 any attachments that you are enclosing to alert the permitting authority.Note that not all applicants are required to provide attachments. Column 1 Column 2 ❑✓ Section 1:Activities Requiring an NPDES Permit ❑ w/attachments ❑✓ Section 2:Name,Mailing Address,and Location ❑ w/attachments El Section 3:SIC Codes ❑ w/attachments ❑� Section 4:Operator Information ❑ w/attachments ❑✓ Section 5:Indian Land ❑ w/attachments ❑✓ Section 6:Existing Environmental Permits ❑ w/attachments ❑✓ Section 7:Map ❑ tpopographic ❑✓ wl additional attachments ❑✓ Section 8:Nature of Business ❑✓ w/attachments ❑� Section 9:Cooling Water Intake Structures ❑ w/attachments ❑ Section 10:Variance Requests ❑ w/attachments ✓❑ Section 11:Checklist and Certification Statement 0 w/attachments 11.2 Certification Statement s I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted. Based on my inquiry of the person or persons who manage the system,or those persons directly responsible for gathering the information, the information submitted is,to the best of my knowledge and belief,true,accurate,and complete. I am aware that there are significant penalties for submitting false information, including the possibility of fine and imprisonment for knowing violations. Name(print or type first and last name) Official title Scott Drury,PE Project Manager-Hart&Hickman,PC Signature Date signed 09/07/22 EPA Form 3510-1(revised 3-19) Page 4 EPA Form 2C NPDES Facility Form Approved 03/05/19 EPA Identification Number NPDES Permit Number ac ry Name pp NCR000166157 Press Club Cleaners OMB No.2040-0004 Form U.S.Environmental Protection Agency 2C ..r EPA Application for NPDES Permit to Discharge Wastewater NPDES EXISTING MANUFACTURING,COMMERCIAL,MINING,AND SILVICULTURE OPERATIONS SECTION 1.OUTFALL LOCATION(40 CFR 122.21(g)(1)) 1.1 Provide information on each of the facility's outfalls in the table below. o Outfall Receiving Water Name Latitude Longitude Number U 001 Little Hope Creek 35° 11' 32.8" N 80° 51' 57.9" W R i 0 SECTION 2.LINE DRAWING(40 CFR 122.21(g)(2)) co 2.1 Have you attached a line drawing to this application that shows the water flow through your facility with a water c i balance?(See instructions for drawing requirements.See Exhibit 2C-1 at end of instructions for example.) W c ❑ Yes ❑ No SECTION 3.AVERAGE FLOWS AND TREATMENT(40 CFR 122.21(g)(3)) 3.1 For each outfall identified under Item 1.1,provide average flow and treatment information.Add additional sheets if necessary. **Outfall Number** 001 Operations Contributing to Flow Operation Average Flow i Groundwater Treatment System 0.002 mgd c E mgd is E` mgd c N mgd 2 Treatment Units Description Code from Final Disposal of Solid or > (include size,flow rate through each treatment unit, Table 2C-1 Liquid Wastes Other Than a retention time,etc.) by Discharge i Equalization Tank,3 gpm,30 hours 1-U Appropriately Licensed Landfill Bag Filter,10 gpm,0.8 minutes 1-N Appropriately Licensed Landfill Granular Activated Carbon Unit(3 drums),10 gpm,15 min 2-A Appropriately Licensed Landfill EPA Form 3510-2C(Revised 3-19) Page 1 EPA Identification Number NPDES Permit Number I Facility Name Form Approved 03/05/19 NCR000166157 Press Club Cleaners OMB No.2040-0004 3.1 **Outfall Number** cont. Operations Contributing to Flow Operation Average Flow mgd mgd mgd mgd Description Code from Final Disposal of Solid or (include size,flow rate through each treatment unit. Liquid Wastes Other Than retention time,etc.) Table 2C-1 by Discharge C 0 c E - I **Outfall Number** y Operations Contributing to Flow o Operation Average Flow mgd < mgd mgd mgd Treatment Units Description Code from Final Disposal of Solid or (include size,flow rate through each treatment unit, Liquid Wastes Other Than Table 2C-1 retention time,etc.) by Discharge 3.2 Are you applying for an NPDES permit to operate a privately owned treatment works? d ❑ Yes ❑✓ No 4 SKIP to Section 4. D. 3.3 Have you attached a list that identifies each user of the treatment works? ❑ Yes ❑ No EPA Form 3510-2C(Revised 3-19) Page 2 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCR000166157 Press Club Cleaners OMB No.2040-0004 SECTION 4.INTERMITTENT FLOWS(40 CFR 122.21(g)(4)) 4.1 Except for storm runoff,leaks,or spills,are any discharges described in Sections 1 and 3 intermittent or seasonal? ❑� Yes ❑ No 4 SKIP to Section 5. 4.2 Provide information on intermittent or seasonal flows for each applicable outfall.Attach additional pages. if necessary. Outfall Operation Frecuency Flow Rate Number (list) Average Average Long-Term Maximum Duration Days/Week Months/Year Average Daily Treated Groundwater 5 days/week 1 months/year 0.002 mgd 0.004 mgd 30 days 001 days/week months/year mgd mgd days LT c days/week months/year mgd mgd days days/week months/year mgd mgd days days/week months/year mgd mgd days days/week months/year mgd mgd days days/week months/year mgd mgd days days/week months/year mgd mgd days days/week months/year mgd mgd days SECTION 5.PRODUCTION(40 CFR 122.21(g)(5)) 5.1 Do any effluent limitation guidelines(ELGs)promulgated by EPA under Section 304 of the CWA apply to your facility? ❑ Yes ❑✓ No 4 SKIP to Section 6. 5.2 Provide the following information on applicable ELGs. ELG Category ELG Subcategory Regulatory Citation a ' a 5.3 Are any of the applicable ELGs expressed in terms of production(or other measure of operation)? ❑ Yes ❑ No 4 SKIP to Section 6. 0 c0 5.4 Provide an actual measure of daily production expressed in terms and units of applicable ELGs. Outfall Operation,Product,or Material Quantity per Day Unit of -0 Number Measure O EPA Form 3510-2C(Revised 3-19) Page 1 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCR000166157 Press Club Cleaners OMB No.2040-0004 SECTION 6.IMPROVEMENTS(40 CFR 122.21(g)(6)) 6.1 Are you presently required by any federal,state,or local authority to meet an implementation schedule for constructing, upgrading,or operating wastewater treatment equipment or practices or any other environmental programs that could affect the discharges described in this application? ❑ Yes No 4 SKIP to Item 6.3. 6.2 Briefly identify each applicable project in the table below. • Affected Final Compliance Dates Brief Identification and Description of Outfalls Source(s)of o Project (list outfall Discharge Required Projected I— number) C N - - 41 -O a 6.3 Have you attached sheets describing any additional water pollution control programs(or other environmental projects that may affect your discharges)that you now have underway or planned?(optional item) ❑ Yes ❑ No ✓❑ Not applicable SECTION 7.EFFLUENT AND INTAKE CHARACTERISTICS(40 CFR 122.21(g)(7)) See the instructions to determine the pollutants and parameters you are required to monitor and. in turn.the tables you must complete.Not all applicants need to complete each table. Table A.Conventional and Non-Conventional Pollutants 7.1 Are you requesting a waiver from your NPDES permitting authority for one or more of the Table A pollutants for any of your outfalls? ❑� Yes ❑ No-SKIP to Item 7.3. 7.2 If yes,indicate the applicable outfalls below.Attach waiver request and other required information to the application. Outfall Number 001 Outfall Number Outfall Number 7.3 Have you completed monitoring for all Table A pollutants at each of your outfalls for which a waiver has not been N requested and attached the results to this application package? a ❑ No;a waiver has been requested from my NPDES R ❑ Yes permitting authority for all pollutants at all outfalls. ZS Table B.Toxic Metals,Cyanide,Total Phenols,and Organic Toxic Pollutants 7.4 Do any of the facility's processes that contribute wastewater fall into one or more of the primary industry categories listed in Exhibit 2C-3?(See end of instructions for exhibit.) ❑ Yes ✓❑ No 4 SKIP to Item 7.8. • 7.5 Have you checked"Testing Required"for all toxic metals,cyanide,and total phenols in Section 1 of Table B? ❑ Yes ❑ No 7.6 List the applicable primary industry categories and check the boxes indicating the required GC/MS fraction(s)identified in Exhibit 2C-3. Primary Industry Category Required GC/MS Fraction(s) (Check applicable boxes.) ❑Volatile ❑Acid 0 Base/Neutral ❑ Pesticide ❑Volatile 0 Acid 0 Base/Neutral ❑Pesticide ❑Volatile 0 Acid ❑ Base/Neutral ❑Pesticide EPA Form 3510-2C(Revised 3-19) Page 4 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCR000166157 Press Club Cleaners OMB No.2040-0004 7.7 Have you checked"Testing Required"for all required pollutants in Sections 2 through 5 of Table B for each of the GC/MS fractions checked in Item 7.6? ❑ Yes ❑ No 7.8 Have you checked"Believed Present"or"Believed Absent"for all pollutants listed in Sections 1 through 5 of Table B where testing is not required? ❑✓ Yes ❑ No 7.9 Have you provided(1)quantitative data for those Section 1,Table B,pollutants for which you have indicated testing is required or(2)quantitative data or other required information for those Section 1,Table B,pollutants that you have indicated are"Believed Present"in your discharge? ✓❑ Yes ❑ No 7.10 Does the applicant qualify for a small business exemption under the criteria specified in the instructions? ❑ Yes 4 Note that you qualify at the top of Table B, ❑✓ No -a then SKIP to Item 7.12. _ 7.11 Have you provided(1)quantitative data for those Sections 2 through 5,Table B,pollutants for which you have o determined testing is required or(2)quantitative data or an explanation for those Sections 2 through 5,Table B, y pollutants you have indicated are"Believed Present"in your discharge? •N ❑ Yes ❑ No .5' Table C.Certain Conventional and Non-Conventional Pollutants • 7.12 Have you indicated whether pollutants are"Believed Present"or"Believed Absent"for all pollutants listed on Table C s for all outfalls? Y0Yes ❑ No 7.13 Have you completed Table C by providing(1)quantitative data for those pollutants that are limited either directly or 0 indirectly in an ELG and/or(2)quantitative data or an explanation for those pollutants for which you have indicated t° "Believed Present"? ❑ Yes ❑Q No w Table D.Certain Hazardous Substances and Asbestos 7.14 Have you indicated whether pollutants are`Believed Present"or'Believed Absent"for all pollutants listed in Table D for all outfalls? ❑ Yes ❑✓ No 7.15 Have you completed Table D by(1)describing the reasons the applicable pollutants are expected to be discharged and(2)by providing quantitative data,if available? ❑ Yes ❑✓ No Table E.2,3,7,8-Tetrachlorodibenzo-p-Dioxin(2,3,7,8-TCDD) 7.16 Does the facility use or manufacture one or more of the 2,3,7,8-TCDD congeners listed in the instructions,or do you know or have reason to believe that TCDD is or may be present in the effluent? ❑ Yes 4 Complete Table E. EI No 4 SKIP to Section 8. 7.17 Have you completed Table E by reporting qualitative data for TCDD? ❑ Yes D No SECTION 8.USED OR MANUFACTURED TOXICS(40 CFR 122.21(g)(9)) 8.1 Is any pollutant listed in Table B a substance or a component of a substance used or manufactured at your facility as 0 an intermediate or final product or byproduct? ❑ Yes 0 No Ht SKIP to Section 9. u 8.2 List the pollutants below. 1. 4. 7. 2. 5. 8. CD 3. 6. 9. EPA Form 3510-2C(Revised 3-19) Page 5 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCR000166157 Press Club Cleaners OMB No.2040-0004 SECTION 9.BIOLOGICAL TOXICITY TESTS(40 CFR 122.21(g)(11)) 9.1 Do you have any knowledge or reason to believe that any biological test for acute or chronic toxicity has been made within the last three years on(1)any of your discharges or(2)on a receiving water in relation to your discharge? ❑ Yes ❑✓ No 4 SKIP to Section 10. H 9.2 Identify the tests and their purposes below. Test(s) Purpose of Test(s) Submitted to NPDES Date Submitted X Permitting Authority? o 70- ❑ Yes ❑ No Co" ❑ Yes ❑ No ❑ Yes ❑ No SECTION 10.CONTRACT ANALYSES(40 CFR 122.21(g)(12)) 10.1 Were any of the analyses reported in Section 7 performed by a contract laboratory or consulting firm? ❑✓ Yes ❑ No 4 SKIP to Section 11. 10.2 Provide information for each contract laboratory or consulting firm below. Laboratory Number 1 Laboratory Number 2 Laboratory Number 3 Name of laboratory firm Pace Analytical Services,PLC Laboratory address 9800 Kincey Ave,Ste 100 To Q Huntersville,NC 28078 5 Phone number (704)875-9092 Pollutant(s)analyzed VOCs,SVOCs,RCRA 8 metals SECTION 11.ADDITIONAL INFORMATION(40 CFR 122.21(g)(13)) 11.1 Has the NPDES permitting authority requested additional information? ❑ Yes ❑ No 4 SKIP to Section 12. 5 11.2 List the information requested and attach it to this application. 1. 4. 2. 5. 3. 6. EPA Form 3510-2C(Revised 3-19) Page 6 J EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCR000166157 Press Club Cleaners OMB No.2040-0004 SECTION 12.CHECKLIST AND CERTIFICATION STATEMENT(40 CFR 122.22(a)and(d)) 12.1 In Column 1 below,mark the sections of Form 2C that you have completed and are submitting with your application. For each section,specify in Column 2 any attachments that you are enclosing to alert the permitting authority.Note that not all applicants are required to complete all sections or provide attachments. Column 1 Column 2 ✓❑ Section 1:Outfall Location w/attachments ❑✓ Section 2:Line Drawing ✓❑ w/line drawing ❑ w/additional attachments Section 3:Average Flows and w/list of each user of Treatment El w/attachments El privately owned treatment works ❑✓ Section 4:Intermittent Flows ❑ w/attachments ❑ Section 5:Production ❑ w/attachments w/optional additional ❑ Section 6:Improvements ❑ w/attachments ❑ sheets describing any additional pollution control plans ❑✓ w/request for a waiver and ❑ w/explanation for identical supporting information outfalls w/small business exemption w/other attachments I'i ❑ request ❑ ❑ Section 7:Effluent and Intake ❑ w/Table A ❑� w/Table B C Characteristics 0 .0 ✓❑ w/Table C El w/Table D w/Table E w/analytical results as an v ❑ ❑ attachment ❑ Section 8:Used or Manufactured ❑ w/attachments Toxics "I Tests 9: Biological Toxicity 0 w/attachments Tests v ✓❑ Section 10:Contract Analyses ✓❑ w/attachments ❑ Section 11:Additional Information 0 w/attachments ❑ Section 12:Checklist and ❑ w/attachments Certification Statement 12.2 Certification Statement I certify under penalty of law that this document and all attachments were prepared under my direction or supervision in accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted.Based on my inquiry of the person or persons who manage the system,or those persons directly responsible for gathering the information, the information submitted is,to the best of my knowledge and belief,true, accurate,and complete.I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment for knowing violations. Name(print or type first and last name) Official title Scott Drury,PE(Hart&Hickman) Project Manager-Hart&Hickman,PC Signature Date signed 09/07/22 EPA Form 3510-2C(Revised 3-19) Page 7 Table A of EPA Form 2C NPDES EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE A.CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(iii))1 Effluent Intake Waiver (Optional) Units Maximum Maximum Long-Term Pollutant Requested (if applicable (specify) Daily Monthly Average Daily Number of Long-Term Number of Discharge Discharge Discharge Analyses Average Value Analyses (required) (if available) (if available) ❑ Check here if you have applied to your NPDES permitting authority for a waiver for all of the pollutants listed on this table for the noted outfall. 1 Biochemical oxygen demand ❑✓ Concentration (BOD5) Mass 2 Chemical oxygen demand ElConcentration (COD) Mass Concentration 3. Total organic carbon(TOC) Mass Concentration mg/L 30 4. Total suspended solids(TSS) 0 Mass Concentration 5. Ammonia(as N) ✓❑ Mass 6. Flow ❑ Rate gpd 4000 Temperature(winter) ❑✓ °C °C 7. - Temperature(summer) ❑✓ °C °C pH(minimum) ❑ Standard units s.u. 6.0 8. pH(maximum) ❑ Standard units s.u. 9.0 1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3). EPA Form 3510-2C(Revised 3-19) Page 9 Table B of EPA Form 2C NPDES EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence (check one) Effluent Intake (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of Discharge Discharge Discharge Analyses Average Analyses (required) (if available) g Value (if available) ❑ Check here if you qualify as a small business per the instructions to Form 2C and,therefore,do not need to submit quantitative data for any of the organic toxic pollutants in Sections 2 through 5 of this table. Note,however,that you must still indicate in the appropriate column of this table if you believe any of the pollutants listed are present in your discharge. Section 1.Toxic Metals,Cyanide,and Total Phenols 1.1 Antimony,total Concentration (7440-36-0) Mass 1 2 Arsenic,total 0Concentration (7440-38-2) Mass 1.3 Beryllium,total 0Concentration 0 El (7440-41-7) Mass Cadmium,total0 Concentration mg/L 0.000073 1.4 El El (7440-43-9) Mass 1.5 Chromium,total 0 ❑ Concentration mg/L 0.0023 0(7440-47-3) Mass 1.6 Copper,total Concentration El El 0 (7440-50-8) Mass Lead,total ✓ Concentration 1.7 El ID(7439-92-1) Mass Mercury,total Concentration 1.8 (7439-97-6) Mass Nickel,total Concentration 1.9 0 El (7440-02-0) Mass 1.10 Selenium,total ❑ Concentration mg/L 0.000093 0 El (7782-49-2) Mass 1.11 Silver,total 0Concentration 0 El (7440-22-4) Mass EPA Form 3510-2C(Revised 3-19) Page 11 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence (check one) Effluent Intake (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of D(eqh euiddge Discharge (if available) Discharge Analyses AValuee Analyses (if available) Thallium,total Concentration 1.12 (7440 28 0) ❑ ❑ 0 Mass Zinc,total0 Concentration 1.13 (7440-66-6) ❑ 0 Mass 1.14 Cyanide,total 0 ❑ 0 Concentration (57-12-5) Mass 1.15 Phenols,total 0 0 0 Concentration Mass Section 2.Organic Toxic Pollutants(GCIMS Fraction—Volatile Compounds) 21 Acrolein ❑ ❑ 0 Concentration (107-02-8) Mass 2.2 Acrylonitrile ❑ ❑ 0 Concentration (107-13-1) Mass 2.3 Benzene El ❑ 0 Concentration (71-43-2) Mass 2.4 Bromoform 0 0 0 Concentration (75-25-2) Mass 2.5 Carbon tetrachloride ❑ ❑ ❑ Concentration (56-23-5) Mass Chlorobenzene Concentration 2.6 (108-90-7) El El Mass 2.7 Chlorodibromomethane ❑ ❑ ❑ Concentration (124-48-1) Mass 2.8 Chloroethane 0 0 0 Concentration (75-00-3) Mass EPA Form 3510-2C(Revised 3-19) Page 12 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence (check one) Effluent Intake (optional) Pollutant]Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of Discharge Discharge Average (required) (if available) Discharge Analyses Value Analyses (if available) 2-chloroethylvinyl ether ❑ ❑✓ Concentration 2.9 (110-75-8) Mass Concentration mg/L 0.0017 2.10 Chloroform(67-66-3) ❑ El ❑ Mass 2.11 Dichlorobromomethane ❑ 0Concentration (75-27-4) Mass 212 1,1-dichloroethane El � 0Concentration (75-34-3) Mass 2.13 12-dichloroethane El ❑✓ Concentration (107-06-2) Mass 2.14 1,1-dichloroethylene ❑ . ❑✓ Concentration (75-35-4) Mass 2.15 1,2-dichloropropane El ❑ ElConcentration (78-87-5) Mass 2.16 1,3-dichloropropylene ❑ ❑ ❑ Concentration (542-75-6) Mass 2.17 Ethylbenzene El El ❑ Concentration (100-41-4) Mass 2.18 Methyl bromide ❑ Concentration El (74-83-9) ✓ Mass 2.19 Methyl chloride ❑ ❑ ElConcentration (74-87-3) Mass 2.20 Methylene chloride ❑ El ❑✓ Concentration (75-09-2) Mass 2.21 1,1,2,2-tetrachloroethane 0 ❑ Concentration (79-34-5) Mass EPA Form 3510-2C(Revised 3-19) Page 13 r EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence (check one) Effluent Intake — (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number.if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of Discharge (ifavalabe) De ischarge Analyses AverageValue Analyses (required) (if available) Tetrachloroethylene Concentration mg/L 0.0656 ✓ 2.22 (127-18-4) ❑ � Mass Toluene 0 Concentration 2.23 (108 88 3) El ❑ Mass 2.24 1,2-trans-dichloroethylene ❑✓ Concentration El El .. — (156-60-5) Mass 2.25 1,1,1-trichloroethane 0 ❑✓ Concentration (71-55-6) Mass 2.26 1,1,2-trichloroethane ❑ 0 ❑ Concentration (79-00-5) Mass 2.27 Trichloroethylene 0 Concentration mg/L 0.0018 El 0 (79-01-6) Mass 2.28 Vinyl chloride ❑ 0Concentration (75-01-4) Mass Section 3.Organic Toxic Pollutants(GC/MS Fraction—Acid Compounds) 3.1 2-chlorophenol 0 Concentration El El(95-57-8) Mass 2,4-dichlorophenol ✓ Concentration 3.2 (120-83-2) Mass 2,4-dimethylphenol Concentration 3.3 El 0 (105-67-9) Mass 3.4 4,6-dinitro-o-cresol El ❑ 0Concentration (534-52-1) Mass 3.5 2,4-dinitrophenol 0 0 ❑✓ Concentration . (51-28-5) Mass EPA Form 3510-2C(Revised 3-19) Page 14 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence (check one) Effluent Intake (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of Discharge (eq fired) ifavalablle) Discharge Analyses AValuee Analyses (if available) 3.6 2-nitrophenol Concentration (88-75-5) Mass 3.7 4-nitrophenol 0Concentration 0 El (100-02-7) Mass 3.8 p-chloro-m-cresol ❑ ❑ ❑ Concentration (59-50-7) Mass 3.9 Pentachlorophenol El 0 0Concentration (87-86-5) Mass Phenol 0 Concentration 3.10 (108-95-2) Mass 3.11 2,4,6-trichlorophenol � 0 Concentration (88-05-2) Mass Section 4.Organic Toxic Pollutants(GCIMS Fraction—Base/Neutral Compounds) 4.1 Acenaphthene El 0 ❑✓ Concentration (83-32-9) Mass 4 2 Acenaphthylene El2Concentration (208-96-8) Mass 4.3 Anthracene 0✓ Concentration 0 0 (120-12-7) Mass 4.4 Benzidine Concentration (92-87-5) Mass 4.5 Benzo(a)anthracene ElL✓ Concentration (56-55-3) Mass Benzo(a)pyrene El Concentration 4.6 (50-32-8) Mass EPA Form 3510-2C(Revised 3-19) Page 15 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence (check one) Effluent Intake (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Term aily of of Discharge (reguied) D(if available) DiDharge Analyses Averageischarge Value Analyses (if available) 4.7 3,4-benzofluoranthene 0 0 Concentration (205-99-2) Mass 4.8 Benzo(ghi)perylene ❑ 0 0Concentration (191-24-2) Mass _ Benzo(k)fluoranthene 0 Concentration 4.9 (207-08-9) Mass 4.10 Bis(2-chloroethoxy)methane 0 0 ❑ Concentration (111-91-1) Mass 4,11 Bis(2-chloroethyl)ether 0 0 Concentration (111-44-4) Mass 4.12 Bis(2-chloroisopropyl)ether El El ❑✓ Concentration (102-80-1) Mass 4.13 Bis(2-ethylhexyl)phthalate El ❑ ❑✓ Concentration (117-81-7) Mass 4-bromophenyl phenyl ether 0 Concentration 4.14 El 0 (101-55-3) Mass 4.15 Butyl benzyl phthalate ❑ Concentration (85-68-7) Mass 4.16 2-chloronaphthalene ❑ 0 0Concentration (91-58-7) Mass 4-chlorophenyl phenyl ether ✓ Concentration 4.17 (7005 72 3) ❑ ❑ Mass Chrysene 0 Concentration 4.18 0 0 (218-01-9) Mass 4 19 Dibenzo(a,h)anthracene El0 Concentration El (53-70-3) Mass EPA Form 3510-2C(Revised 3-19) Page 16 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))l Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Term Discharge Discharge Daily of Average of (required) (if available) Dischar(ifavailable)ge Analyses Value Analyses 1,2-dichlorobenzene ❑ Concentration 4.20 (95 50 1) Mass 1,3-dichlorobenzene ❑ ❑ Concentration 4.21 (541-73-1) Mass 1,4-dichlorobenzene ❑ Concentration 4.22 El El (106-46-7) Mass 3,3-dichlorobenzidine ElConcentration 4.23 0 El (91-94-1) Mass 4.24 Diethyl phthalate ❑ © Concentration (84-66-2) Mass 4.25 Dimethyl phthalate 0Concentration El 0 (131-11-3) Mass 4.26 Di-n-butyl phthalate © Concentration El 0 (84-74-2) Mass 4.27 2,4-dinitrotoluene El ❑✓ Concentration (121-14-2) Mass 4.28 2,6-dinitrotoluene Concentration 0 El El (606-20-2) Mass Di-n-octyl phthalate ❑ Concentration 4.29 0 El (117-84-0) Mass 1,2-Diphenylhydrazine Concentration 4.30 (as azobenzene)(122-66-7) Mass Fluoranthene Concentration 4.31 (206-44-0) Mass 4.32 Fluorene ❑✓ Concentration El 0(86-73-7) Mass EPA Form 3510-2C(Revised 3-19) Page 17 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence Intake (check one) Effluent (optional) Pollutant/Parameter Testing Units Long-Term (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long- Number Present Absent Daily Monthly Daily of Term of Discharge Discharge Average (required) (if available) Dischar(ifavailable)ge Analyses Value Analyses 4.33 Hexachlorobenzene ❑ 0 Concentration (118 74 1) ✓ Mass — Hexachlorobutadiene 0 'Concentration 4.34 (87-68-3) Mass 4.35 Hexachlorocyclopentadiene ❑ El Concentration (77-47-4) Mass 4.36 Hexachloroethane ❑ ❑ a Concentration (67-72-1) Mass 4.37 Indeno(1,2,3-cd)pyrene 0 ❑ El Concentration (193-39-5) Mass 4.38 Isophorone ❑✓ Concentration (78-59-1) Mass _ 4.39 Naphthalene ❑ Concentration (91-20-3) Mass 4.40 Nitrobenzene ❑✓ Concentration 0 El (98-95-3) Mass 4.41 N-nitrosodimethylamine ❑ ❑✓ Concentration (62-75-9) Mass N-nitrosodi-n-propylamine 1:3Concentration 4.42 (621-64-7) ❑ ❑ Mass _ 4.43 N-nitrosodiphenylamine ❑ ❑ Concentration (86-30-6) Mass 4.44 Phenanthrene ❑ 0 Concentration (85-01-8) Mass Pyrene Concentration 4.45 (129 00 0) 0 ❑ 0 Mass EPA Form 3510-2C(Revised 3-19) Page 18 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence (check one) Effluent Intake (optional) Pollutant/Parameter Testing Units Long-Term Maximum Maximum Long- (and CAS Number,if available) Required Believed Believed (specify) Daily Monthly Average Number Term Number Present Absent Daily of of Discharge Discharge Analyses Average Analyses (required) q (if available) ifavalablle) (if available) ValUe 4.46 1,2,4-trichlorobenzene Concentration — (120-82-1) Massi Section 5.Organic Toxic Pollutants(GC/MS Fraction—Pesticides) 5.1 Aldrin ❑ � Concentration (309 00 2) Mass a-BHC Concentration 5.2 (319-84-6) CI ✓� Mass R-BHC 0 Concentration 5.3 El El (319-85-7) Mass 5.4 y-BHC 0Concentration 0 El (58-89-9) Mass b-BHC Concentration 5.5 (319 86 8) El ❑ 0 Mass Chlordane 0 Concentration 5.6 El 0 (57-74-9) Mass 5.7 4,4'-DDT a Concentration 0 El (50-29-3) Mass 4,4'-DDE ❑� Concentration 5.8 El 0 (72-55-9) Mass 5.9 4,4'-DDD 0 Concentration El 0 (72-54-8) Mass Dieldrin 0 Concentration 5.10 (60 57 1) ❑ 0 - Mass 5.11 a-endosulfan 0Concentration 0 0 (115-29-7) Mass EPA Form 3510-2C(Revised 3-19) Page 19 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence Intake (check one) Effluent (optional) Pollutant]Parameter Testing Units Long-Term - (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Long Number Present Absent Daily Monthly Daily of Term of Discharge Discharge Discharge Analyses Average Analyses (required) (if available) Value (if available) 5.12 R-endosulfan 0 ❑ ❑ Concentration (115-29-7) Mass Endosulfan sulfate Concentration 5.13 (1031 07 8) El El ❑✓ Mass 5.14 Endrin 0 0 ❑ Concentration (72-20-8) Mass Endrin aldehyde Concentration 5.15 (7421 93 4) ❑ ❑ ❑ Mass 5.16 Heptachlor 0 El ElConcentration (76-44-8) Mass Heptachlor epoxide Concentration 5.17 (1024-57-3) ❑ ❑ ❑✓ Mass PCB-1242 Concentration 5.18 (53469-21-9) 0 ❑ ❑ Mass PCB-1254 Concentration 5.19 (11097-69-1) ❑ 0 ❑✓ Mass PCB-1221 Concentration 5.20 (11104-28-2) 0 ❑ ✓❑ Mass PCB-1232 Concentration 5.21 (11141-16-5) ❑ ❑ ❑✓ Mass PCB-1248 Concentration 5.22 (12672-29-6) ❑ ❑ 0 Mass PCB-1260 Concentration 5.23 (11096-82-5) ❑ ❑ ❑✓ Mass PCB 1016 Concentration 5.24 (12674-11-2) 0 ❑ ✓❑ Mass EPA Form 3510-2C(Revised 3-19) Page 20 1, EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners ow. OMB No.2040-0004 TABLE B.TOXIC METALS,CYANIDE,TOTAL PHENOLS,AND ORGANIC TOXIC POLLUTANTS(40 CFR 122.21(g)(7)(v))1 Presence or Absence (check one) Effluent Intake (optional) Pollutant/Parameter Testing Units Long-Term Long- (and CAS Number,if available) Required Believed Believed (specify) Maximum Maximum Average Number Number Present Absent Daily Monthly Term Discharge Discharge Daily of Average of (required) (if available) Discharge Analyses Analyses Value (if available) Toxaphene Concentration 5.25 (8001-35-2) 0 0 Mass 1 Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3), EPA Form 3510-2C(Revised 3-19) Page 21 Table C of EPA Form 2C NPDES EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE C.CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(vi))1 Presence or Absence (check one) Effluent Intake (Optional) Pollutant Units Maximum Lon Term Believed Believed (specify) Maximum Daily Monthly Average Daily Number of Long-Term Number of Present Absent Discharge I Average (required) Discharge Discharge Analyses Analyses q ) (if available) (if available) Value ❑ Check here if you believe all pollutants on Table C to be present in your discharge from the noted outfall.You need not complete the"Presence or Absence"column of Table C for each pollutant. ❑ Check here if you believe all pollutants on Table C to be absent in your discharge from the noted outfall.You need not complete the"Presence or Absence"column of Table C for each pollutant. 1 Bromide ❑ ❑✓ Concentration (24959-67-9) Mass 2 Chlorine,total El ❑ Concentration residual Mass Concentration 3. Color ❑ 0 • Mass Concentration 4. Fecal coliform ❑ 0 Mass 5 Fluoride ❑ ❑ Concentration (16984-48-8) Mass Concentration 6 Nitrate-nitrite 0 ❑✓ Mass Nitrogen,total Concentration 7. organic(as N) ❑ Mass _ Concentration 8. Oil and grease 0 0 Mass 9 Phosphorus(as ❑ ❑ Concentration P),total(7723-14-0) Mass _ 10. Sulfate(as SO4) 0 ❑✓ Concentration (14808-79-8) Mass 11. Sulfide(as S) 0 0 Concentration Mass EPA Form 3510-2C(Revised 3-19) Page 23 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE C.CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)(vi))1 Presence or Absence Intake (check one) Effluent (Optional) Pollutant Units Maximum Long-Term Believed Believed (specify) Maximum Daily Long-Term Present Absent Discharge Monthly Average Daily Number of Average Number of (required) Discharge Discharge Analyses Value Analyses cif available) f available) 12. Sulfite(as SO3) ❑ ❑✓ Concentration (14265-45-3) Mass Concentration 13. Surfactants ❑ ❑ Mass 14. Aluminum,total ❑ ❑ Concentration (7429-90-5) Mass 15. Barium,total ❑✓ ❑ Concentration mg/L 0.164 (7440-39-3) Mass 16. Boron,total ❑ 0 Concentration (7440-42-8) Mass 17 Cobalt,total ❑ ❑ Concentration (7440-48-4) Mass Iron,total El Concentration 18. (7439-89-6) Mass 0 - 19. Magnesium,total ❑ ❑ Concentration (7439-95-4) Mass Molybdenum, Concentration 20. total ❑ E Mass (7439-98-7) 21. Manganese,total ❑ 0 Concentration (7439-96-5) Mass 22. Tin,total ❑ ❑ Concentration (7440-31-5) Mass 23. Titanium,total ❑ ❑ Concentration (7440-32-6) Mass EPA Form 3510-2C(Revised 3-19) Page 24 EPA Identification Number NPDES Permit Number Facility Name Outfall Number Form Approved 03/05/19 NCR000166157 Press Club Cleaners 001 OMB No.2040-0004 TABLE C.CERTAIN CONVENTIONAL AND NON CONVENTIONAL POLLUTANTS(40 CFR 122.21(g)(7)ivi))1 Presence or Absence (check one) Effluent Intake (Optional) Pollutant Units Maximum Long-Term Believed Believed (specify) Maximum Daily Monthly Average Daily Number of Long-Term Number of Present Absent Discharge Discharge Discharge Analyses Average Analyses (required) (if available) (if available) Value 24. Radioactivity Concentration Alpha,total 0 ❑✓ - Mass Concentration Beta,total ❑ 2 — Mass Concentration Radium,total 0 E Mass Concentration Radium 226,total 0 0 Mass ' Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3). EPA Form 3510-2C(Revised 3-19) Page 25 EPA Form 2E NPDES EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCR000166157 Press Club Cleaners OMB No.2040-0004 U.S.Environmental Protection Agency FORM Application for NPDES Permit to Discharge Wastewater 2E NPDES ��EPA MANUFACTURING,COMMERCIAL,MINING,AND SILVICULTURAL FACILITIES WHICH DISCHARGE ONLY NONPROCESS WASTEWATER SECTION 1.OUTFALL LOCATION(40 CFR 122.21(h)(1)) 1.1 Provide information on each of the facilit 's outfalls in the table below. Outfall ReceivingWater Name Latitude Longitude Number g J 001 Little Hope Creek 35° 11' 32.8" N 80° 51 57.9' W 0 SECTION 2.DISCHARGE DATE(40 CFR 122.21(h)(2)) 2.1 Are you a new or existing discharger?(Check only one response.) s ❑✓ New discharger ❑ Existing discharger 4 SKIP to Section 3. en2.2 Specify your anticipated discharge date: 02/27/2023 SECTION 3.WASTE TYPES(40 CFR 122.21(h)(3)) 3.1 What types of wastes are currently being discharged if you are an existing discharger or will be discharged if you are a new discharger?(Check all that apply.) ❑ Sanitary wastes ❑✓ Other nonprocess wastewater(describe/explain ❑ Restaurant or cafeteria waste directly below) a�i ❑ Non-contact cooling water Groundwater from Excavations Q 3.2 Does the facility use cooling water additives? ❑ Yes ✓❑ No 4 SKIP to Section 4. 3.3 List the cooling water additives used and describe their composition. Cooling Water Additives Composition of Additives (list) (if available to you) SECTION 4.EFFLUENT CHARACTERISTICS(40 CFR 122.21(h)(4)) 4 1 Have you completed monitoring for all parameters in the table below at each of your outfalls and attached the results to this application package? El Yes No;a waiver has been requested from my NPDES permitting authority (attach waiver request and additional information)4 SKIP to Section 5. 4.2 Provide data as requested in the table below.1(See instructions for specifics.) Number of Maximum Daily Average Daily Source Parameter or Pollutant Analyses Discharge Discharge (use codes (if actual data (specify units) (specify units) per reported) Mass Conc. Mass Conc. instructions) rBiochemical oxygen demand(BOD5) I c.> Total suspended solids(TSS) Oil and grease w Ammonia(as N) Discharge flow pH(report as range) Temperature(winter) Temperature(summer) Sampling shall be conducted according to sufficiently sensitive test procedures(i.e.,methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I,subchapter N or 0.See instructions and 40 CFR 122.21(e)(3). EPA Form 3510-2E(revised 3-19) Page 1 EPA Identification Number NPDES Permit Number Facility Approved Form A roved 03/05/19 NCR000166157 Press Club Cleaners OMB No.2040-0004 4.3 Is fecal coliform believed present,or is sanitary waste discharged(or will it be discharged)? O Yes ❑ No 4 SKIP to Item 4.5. 4.4 Provide data as requested in the table below.' (See instructions for specifics.) Number of Maximum Daily Average Daily Source Parameter or Pollutant Analyses Discharge Discharge (Use codes (if actual data (specify units) (speci units) per reported) Mass Conc. Mass Conc. Instructions.) Fecal coliform d E.coli a Enterococci 4.5 Is chlorine used(or will it be used)? v) El Yes El No 4 SKIP to Item 4.7. .N 4.6 Provide data as requested in the table below.' (See instructions for specifics.) Number of Maximum Daily Average Daily Source R Parameter or Pollutant Analyses Discharge Discharge (use codes v (if actual data (specify units) (specify units) per reported) Mass Conc. Mass Conc. instructions) c 3 Total Residual Chlorine I 1 w 4.7 Is non-contact cooling water discharged(or will it be discharged)? ❑ Yes ❑ No 4 SKIP to Section 5. 4.8 Provide data as requested in the table below.' (See instructions for specifics.) ' Number of Maximum Daily Average Daily Source Parameter or Pollutant Analyses Discharge Discharge (use codes (if actual data (specify units) (speci units) per reported) Mass Conc. Mass Conc. instructions) Chemical oxygen demand(COD) Total organic carbon(TOC) SECTION 5.FLOW(40 CFR 122.21(h)(5)) 5.1 Except for stormwater water runoff,leaks,or spills,are any of the discharges you described in Sections 1 and 3 of this application intermittent or seasonal? ✓ Yes-4 Complete this section. No 4 SKIP to Section 6. ❑ P 0 33 5.2 Briefly describe the frequency and duration of flow. LL The discharge will occur during a portion of property redevelopment construction activities(while excavations for construction of storm water sewer lines are open). The discharge is expected to be intermittent(approximately seven hours per day)for a period of up to one month. The discharge will be permanently terminated after construction of subsurface structures beneath the groundwater table is completed. SECTION 6.TREATMENT SYSTEM(40 CFR 122.21(h)(6)) 6.1 Briefly describe any treatment system(s)used(or to be used). E =) Groundwater generated bydewateringof excvations will be treated usingphysical filtration/adsorption rocesses. The � P YP cn groundwater will be pumped into an equalization tank,then through a bag filter,and three granular activated carbon mfiltration units prior to direct discharge to a culvert located adjacent to the facility property. Refer to the NPDES permit E application package for additional information/details. R N F-• 'Sampling shall be conducted according to sufficiently sensitive test procedures(i.e..methods)approved under 40 CFR 136 for the analysis of pollutants or pollutant parameters or required under 40 CFR chapter I.subchapter N or 0.See instructions and 40 CFR 122.21(e)(3). EPA Form 3510-2E(revised 3-19) Page 2 EPA Identification Number NPDES Permit Number Facility Name Form Approved 03/05/19 NCR000166157 Press Club Cleaners OMB No.2040-0004 SECTION 7.OTHER INFORMATION(40 CFR 122.21(h)(7)) 7.1 Use the space below to expand upon any of the above items.Use this space to provide any information you believe the reviewer should consider in establishing permit limitations.Attach additional sheets as needed. Treated effluent from the groundwater treatment system will be discharged to a storm water culvert adjacent to the the facility property. Storm water flows through the culvert,then through various storm channels and City of Charlotte w municipal storm water system structures and pipes to an outlet(proposed NPDES Outfall 001)which discharges to surface water(Little Hope Creek)approximately 1,200 ft southeast of the Site. Refer to figures included in the NPDES permit application package for culvert,flow path,and discharge locations. Documentation of Charlotte-Mecklenburg Storm Water Services approval to discharge into the storm water sewer is included in the NPDES permit application package. SECTION 8.CHECKLIST AND CERTIFICATION STATEMENT(40 CFR 122.22(a)and(d)) 8.1 In Column 1 below,mark the sections of Form 2E that you have completed and are submitting with your application. For each section,specify in Column 2 any attachments that you are enclosing to alert the permitting authority.Note that not all applicants are required to provide attachments. Column 1 Column 2 ❑✓ Section 1:Outfall Location ❑✓ w/attachments(e.g.,responses for additional outfalls) ❑✓ Section 2:Discharge Date ❑ w/attachments ❑✓ Section 3:Waste Types ❑ w/attachments ❑✓ Section 4: Effluent Characteristics ❑� w/attachments ❑✓ Section 5:Flow ❑ w/attachments CCI in ❑✓ Section 6:Treatment System ❑✓ w/attachments ❑✓ Section 7:Other Information w/attachments ❑✓ Section 8:Checklist and Certification Statement ❑ w/attachments 8.2 Certification Statement /certify under penalty of law that this document and all attachments were prepared under my direction or supervision in i accordance with a system designed to assure that qualified personnel properly gather and evaluate the information submitted.Based on my inquiry of the person or persons who manage the system,or those persons directly responsible for gathering the information,the information submitted is,to the best of my knowledge and belief, true, accurate,and complete. I am aware that there are significant penalties for submitting false information,including the possibility of fine and imprisonment for knowing violations. Name(print or type first and last name) Official title Scott Drury,PE Project Manager-Hart&Hickman,PC Signature Date signed 09/07/22 EPA Form 3510-2E(revised 3-19) Page 3 Table 1 Summary of Groundwater Analytical Data Press Club Cleaners Brownfields Property Charlotte,North Carolina H&H Job No.TCR-003 Sample Location/ID MW-1 MW-2 MW-3 MW-4 "> Surface Water 2L Standard Sample Date 04/26/17 12/08/20 06/17/22 04/26/17 12/08/20 06/17/22 04/26/17 12/08/20 06/17/22 6/17/22(DUP) 04/26/17 12/08/20 06/17/22 Criteria��� VOCs lua/L) Acetone 10 1 6,000 2,000"' Chloroform 1.2 1.9 0.28 J <<<3 43 2 6 1.7 1 7 0.92 0.91 0.83 J 70 2,000(3) cis-1,2-Dichloroethylene 70 22 166 <0.38 5.1 3.3 2.6 70 60°r Hexachlorobutadiene 0.77 J .?.1) <2.0 0.4 le)Methyl tert-butyl ether(MTBE) 0.33 J - <0 50 <0.42 20 1,500t'r Naphthalene .. 0.67 J <0 10 <U 64 6 12t4t Tetrachloroethylene 240 IN 2.370 '0.50 <0.29 0.78 0.31 J 58 72 66.6 0.7 3.3(2) Trichloroethylene 74 17 ]§mot <0.51 <0.38 2.3 2.7 1.8 3 30i2r Vinyl Chloride 4.5 2.9 20.5 . 0.58 •- 0.03 2.41'' SVOCs(ua/L) . Metals fuss/L) Arsenic 0.82 J 10 10r2r Barium 142 165 164 38.3 700 21,000w Cadmium <U iitii, v,r. 0.073 J 0.069 J 2 0.31(2") Cr".63.4(2,n,dr Chromium(Total) 0.90 J NI 2.3 2.3 0.50 J 10 Cr*.=11 i2, Lead 0.35 J 15 1.62 a"•dt Mercury <p.I- 1 0.012(2) Selenium 0.14 J 0.093 J 20 5121 Silver 20 0.06 r2.d' Notes 1)North Carolina Department of Environmental Quality(DEQ)15A NCAC 02L.0202 Groundwater Standards(2L Standards)dated April 202: 2)NC 15A North Carolina Administrative Code 02B.0202 Surface Water Quality Standard(2B Standard)for Class C Surface Waters from table dated July 2021 -Lowest potentially applicable value presented(including chronic values for cadmium,chromium,lead,and silver -There is no established 2B Standard for total chromium.Trivalent chromium(Cr+3)and hexavalent chromium(Cr+6)are presented in tabli h)hardness-dependent dissolved metal 2B Standard(derived using the DEQ Hardness-Dependent Metal Calculator and an EPA-published median hardness of 67 mg/L for Little Sugar Creek d)=dissolved metal standard. See 15A NCAC 02B.0211 for more information 3)EPA National Recommended Water Quality Criteria for Aquatic Life&Human Health for Class C Surface Waters from table dated July 202' 4)North Carolina In-Stream Target Values for Surface Waters for Class C Waters from table date July 2021 Only those VOCs detected in at least one sample are included in table Bold concentration exceeds the 2L Standard Bold concentration exceeds the 2L Standard and applicable surface water criteria' VOCs=volatile organic compounds;SVOCs=semi-volatile organic compounds;pgii=micrograms per liter -=not applicable;BDL=below laboratory method detection limit;NA=not analyzed:DUP=field duplicate sampli J=Compound was detected above the laboratory method detection limit,but below the laboratory reporting limit resulting in a laboratory estimated concentration. Table 1(Page 1 of 1) Mips nnaMCF.snrapalnl.00MMeUMS5terFtles-116nred 0ocamereNWaa*r ProlenanrammeM Craw Remdenbal-TCRIrC13-000 Press Club Cleaners/(2E6 PermCGW D.Ia Hari&Hickman,PC ON SS t Charlotte CMIx.rah .s,1u2" .ire:..- SdI 0 iceElam S.h r r ,y��,/ s�,r2 Iwl�. ; y�'�' reG Davnk - f �t y <F 911 P ` v' I Y Canddte Sch "`�y �c ' III SITE ,, Q 49 -� �� NPDES Outfall 001 a" `(*h 35°11'32.8" N. r °� 3 80°51'57.9" \N 9,y � •-'? MId Sch µ,s` '' a P . .y /� C� aN . rye' a Q" O fs lrpi ElamSchd seO, ,, Holy TnnK/ "o - o.o Cathodic IR°Cy - 4 4 f Mid Sas Techskills-Charlotte. '� vac w vP 2 CdLnswood `Phi. n ;�q � 4 r 1rp H s Language Acad •. l 4 4 I r ? i/ 1] /p . tLN'. ' --. 4 , , .F. l_ }`. Saint A,, ` Pytc" CathNlc Sda a,,,' _ fir �ii N 2^K L y J .iGOR i 1 V. USGS The National Map:National Boundaries Dataset,3DEP Elevation,l,,, ` Program,Geographic / P Names Information;System,National Hydrograptiy Dataset.National Land Cover Database,National Structures Dataset,and National Transportation Dataset:USGS Global Ecosystems; U.S.Census Bureau TIGER/Line data; USFS Road Data;Natural'Earth Data;tJ.S. Department of State Humanitarian Information Unit and'NOAA National Ao Centers for Environmental Information,U.S.Coastal Relief Model.Data refreshed May.2020. TITLE SITE LOCATION MAP 0 00 4,000 \ 2.0 PROJECT ,_r ..�. PRESS CLUB CLEANERS SCALE IN FEET BROWNFIELDS PROPERTY 3305 SOUTH BLVD U.S.G.S. QUADRANGLE MAP CHARLOTTE, NORTH CAROLINA 11 2923 South Tryon Street-Suite 1 ul I CHARLOTTE WEST AND CHARLOTTE EAST, hart '1%• hickman Charlotte,North Carolina28203 lb'NORTH CAROLINA 2019 704-586-0007(p)704-586-0373(0 SMARTER ENVIRONMENTAL SOLUTIONS t.ICen,e'C-I269 #C-245 Geology QUADRANGLE DATE: 08-17-22 REVISION NO: 0 7.5 MINUTE SERIES (TOPOGRAPHIC) JOB NO: TCR-003 FIGURE NO: 1 ' J$ /i LEGEND BLUME SUPPLY r �- SITE PROPERTY BOUNDARY 3316 SOUTH BOULEVARD) I , 'J ri. .WIIIIIIIIIIIIIII CATS LIGHT RAIL < i�� 1 n141/4 MONITORING WELL r Ar f —ss — PROPOSED STORM WATER '! ,,,. 0 SEWER LINE(APPROXIMATE) LIDL US OPERATIONS LLC PARCEL ,,► "' (3229 SOUTH BOULEVARD) i GROCERY STORE DEVELOPMENT PLANNED(2022-2023) ii GRACIE BARRA BRAZILIAN JIU-JITSU (3324 SOUTH BOULEVARD MW-1 - �q e R 4 /',,,,' ` f/ Jv : .` , ,,, ^, ' J , E=1,, O i NOTES .....�. may,.. q. - 'r s 1. AERIAL IMAGERY OBTAINED FROM MECKLENBURG COUNTY GIS,2022. ./'. PROPOSED GROUNDWATER TREATMENT SYSTEM EFFLUENT 2. BASE DATA OBTAINED FROM MECKLENBURG COUNTY _` DISCHARGE LOCATION(CULVERT) GIS,2022. / 4 j Y zt9 m v 4 , a'. ,. ram, ® .. o. Arlh, Q L YGF -, —/ a APPROXIMATE `Y MULTI-TENANT COMMERCIAL V . 0 60 20 a (3401 SOUTH BOULEVARD) € e SCALE IN FEET < .mow E * .\. •. %.u SITE MAP >r "� PRESS CLUB CLEANERS BROWNFIELDS PROPERTY 3305 SOUTH BLVD $ CHARLOTTE, NORTH CAROLINA L- `N PRESIDENTIAL • 2923 South 7run Street Suite11X1 t g ,° " hart 1 h i c k ma n Charlotte,North(.arol+na 28^_03 a e '' _ 704-586-0007(p)714586-0373(0 re/ .k� - .. ' .: =.b" '4' v° _ ,t.. .d. : .. I.iansC 0 C-12G91/#C 245 Gcolo ✓ SMARTER ENVIRONMENTAL SOLUTIONS F+.' To E 1' ,.r-%- 3 DATE 08 22-22 IS¢ 1 REVISION NO.0 '; JOB NO,TCR-003 FIGURE NO.2 i i Q. 3325 / �Lv� "` 311 301 409 `V 8 • 3216 3.• 4 ,�. 4 - '0 41 a 18 •6 . .: lek 32• 18230152: �� 401 2 10 . .` /3308323 �g •0 .‘ ,`,4 �44 � � '� 439 321111181, , l0//0 te 3225 �0c3235 `® , ,.ti /el, . i� 0y 3227 0$28�S . 421 s \N, 7SITE 3229 .�' ' 2 401 6 '' 40• / 0 41 1170 3305 \ / • 4/ 3309 PROPOSED GROUNDWATER TREATMENT SYSTEM EFFLUENT DISCHARGE LOCATION 419 sA CULVERT(NOT DEPICTED/NO STRUCTURE ID ON CLTex) ° \:, - 35°11'39.5"N,80ev.°52'05.4"W 11 121 1: 0 427- • -16 127 -. s 133 \'!�,� �� r 340 139 ,.�►. t�, . • 50 ., 0,. 4# c„ .. : 4;44k4 466 N. • i ,1 tedt ,,, .:1, 4. ,411411111111.111t4 . 410 30 * 8; 3435 Ni, ,-. 4410 4444'\/' ,41 :3 '�4N 4417 111 `40. 34 ,� ♦ 40 4131:(4i% 1.it 1. , .415 ir 4 is a341' 36 31 . :g18 s+4 3.+ 31• PROP it OSED NPDES OUTFACE 001-.` 26 '_ a END SECTION-WALL OUTLET lipp. ' • �203 $' 3 STRUCTURE ID:MARSH2.36 �207 ! 35°11'32.8"N,80°51'57.9"W a0 . ,,c 12 0///S . ■ 215 4 * •• ; t. Q % 4 r•I • a • ® 221225 $, ,. ` '12 '° ■,233 08 4 ilki . �2�: M 2 R 2 Rt9 STREAM NAME:LITTLE HOPE CREEK'" �, . r 4. • 2 : w STREAM INDEX:11-137-8-3 ,. / e■ _ 301 CONVERGENCES WITH LITTLE SUGAR CREEK 0 a . 1 APPROXIMATE LENGTH:2.5 MILES Idi5c0 ; 309 3, 5 418Ilk 313 t; 42 1 224 ``` 3514 # \ ? 4. 34 >>�. 50 ditir . , ‘ it.. 216 , 1 12 `` �, 225 1 A.) e'' • 227 221 352% 35' 31- Al, , Or I tR 21 * � # ® , 3527 s 3 vn 13540 lip ` + 40 . t2 SO tillp0.,'354835334111111111. ` a 539 51014` At y.i. • 5''516 •151 ir 45P4)0 �+ © .ram 43 - 8 43' , 3511‘ 50'S6 366 42� `'' 4 '607 •�` S 432 - �, -, i LEGEND gr, 4 - - - SITE PROPERTY BOUNDARY Z APPROXIMATE S GO STORM STRUCTURE(ACTIVE) 0 200 400 I 1 STORM PIPE(ACTIVE) SCALE IN FEET c II, STORM CHANNEL f TREATMENT SYSTEM DISCHARGE AND STREAM NPDES OUTFALL LOCATIONS MAP PROJECT PRESS CLUB CLEANERS A BROWNFIELDS PROPERTY 3305 SOUTH BLVD s CHARLOTTE, NORTH CAROLINA 11 okle 2, I S,,,,,'i n ns ue SFr",Sr 1110 hart hick 11a 1 (.h»arhmc.Ar,nn(..Tirdin.l 2420 SW -ua.;BG-(Inuclh,-1)4,86-111- I) € NOTE:STORM WATER SEWER BASE MAP OBTAINED FROM THE �crinr 1 t-1_h' C-_��Gr�,I ;� SMARTER ENVIRONMENIAI SOLUTIONS T 2 J CITY OF CHARLOTTE'S GIS CHARLOTTE EXPLORER(CLTEx) E DATE:8-22-22 REVISION NO.0 JOB NO.TCR-003 FIGURE NO.3 i it Attachment A Designation of H&H as Authorized Representative for Permit Applicant TRAMMELL CROW RESIDENTIAL 4509 Creedmoor Road, Suite 308 Raleigh,NC 27612 August 30,2022 Via Electronic Mail Hart& Hickman,PC 2923 S.Tryon Street, Suite 100 Charlotte,NC 28203 Attn: Mr. Scott Drury,PE,Project Manager RE: Representative Authorization for NPDES Permit Application Press Club Dry Cleaners Brownfields Property 3305 South Blvd. Charlotte,NC,28209 Brownfields Project Number 25101-21-060 H&H Job No.TCR-003 Dear Scott, CF MF BTH IlI/Charlotte LoSo LLC (permit applicant) authorizes Hart and Hickman, PC to act as its representative for the purpose of submitting a NPDES Permit application to the NC Department of Environmental Quality for direct discharge of treated groundwater generated during redevelopment construction activities at the Former Press Club Dry Cleaners Property located at 3305 South Boulevard, 121 Hartford Avenue,and 139 Hartford Avenue in Charlotte,North Carolina. If you have any questions regarding this authorization or require additional information,please contact me at 202-290-0541 or via email at rbrooks@tcr.com. Sincerely, Robert Brooks Vice President Page 1 of 1 Attachment B CMSWS Approval for Discharge to Storm Water Sewer System Charlotte-Mecklenburg cl /1 STORM WATER StormWater.CharMeck.org Services n September 8,2022 NC Department of Environmental Quality Mooresville Regional Office Division of Water Resources—Water Quality Permitting Unit 610 E. Center Avenue Suite 301 Mooresville,NC 28115 Re: NPDES permit application-request to discharge into the City of Charlotte municipal stormwater system from 3305 & 3309 South Blvd. Division of Water Resources: Regarding Hart&Hickman's request(on behalf of site property owner CH MF BTH III/Charlotte LoSo LLC)in their NPDES permit application to discharge treated water from a remediation system at the above-referenced location into Charlotte's stormwater system, Charlotte Mecklenburg Storm Water Services(CMSWS)approves the discharge. CMSWS would like to make the permittee and NC DEQ aware of the following considerations and information: • CMSWS reserves the right to access, inspect, sample,and review documentation regarding the groundwater treatment system at any time. • In the event of an illicit discharge,bypass,or exceedance of permit discharge limits,CH MF BTH III/Charlotte LoSo LLC or its consultant shall immediately notify CMSWS and immediately implement corrective actions. • CMSWS reserves the right to rescind approval of discharge to the City of Charlotte's MS4 for due cause including gross improper operation of the system,an established trend of discharge limit exceedances,failure to provide notification of illicit discharges and system bypasses,and similar reasons. • CMSWS does not guarantee adequate capacity is available to permitted dischargers to keep any property or street free of water or harm as a result of this discharge. It is recommended that if discharge flows are anticipated to be high,the discharger should avoid discharging during wet weather. • CMSWS takes no responsibility for backflows from the public drainage system into the permitted discharger's system. If you have any questions,please contact Craig Miller at(704) 336-7605. • 2145 Sutlle Avenue ( 600 East 4th Street • Charlotte,NC 28208 Charlotte,NC 28202 charlottenc.gov Hart&Hickman/CH MF BTH Ill-Charlotte LoSo LLC September 8,2022 Page 2 Sincerely, — off-. Craig Miller NPDES Permit Supervisor cc: Hart& Hickman/CH MF BTH III-Charlotte LoSo LLC Attachment C Groundwater Treatment System Schematic and Drawings/Information Sheets for Treatment System Components INFLUENT (GROUNDWATER WITH VOCS) FROM EXCAVATION DEWATERING PUMP(S) 3 GPM (MAX) • 6.900 GAL) TANK ( EXCAVATION DEWATERING PUMP(S) V PI 0 0 ® �� • LPCD-66 LPCD-55 200 LPCD-55 200 0 200 LB LIQUID LB LIQUID LB LIQUID PHASE GAC • PHASE GIC A PHASE CAC TRANSFER PUMP DRUM DRUM DRUM OPERATED AT 10 GPM (MAX) ♦♦ I 1 BF100 BAG FILTER I / 1 EFFLUENT DISCHARGE TO CULVERT I a 1 ' f LEGEND PROPOSED GROUNDWATER TREATMENT TOTALIZING FLOW METER(LIQUID) SYSTEM SCHEMATIC kJ - SH PRESSURE SWITCH HIGH/HIGH PROJECT PRESS CLUB CLEANERS PI PRESSURE INDICATOR BROWNFIELDS PROPERTY CHARLOTTE, NORTH CAROLINA H GATE/BALL VALVE CHECK VALVE • Sth ry W � hart 1 h i c k m a n Ch2923arlotteou,\Tonhon CarolinaStreet-S 28203uite1 SAMPLE PORT • 704-586--0007(p)7O4-586-0373(f) SMARTER E`JIRONMENTAL SOLUTIONS I.iccnsc#C-I269/#C-245 Geology DATE:08-22-22 REVISION NO.0 JOB NO.TCR-003 ATTACHMENT NO.3 3 Po y Tank EZ KLEEN ' 6900 Overview: The EZ KLEEN®6900 Gallon Acid Tank is made from cross- linked polyethylene for superior durability and safety.This tank EZ KLEEN` is ideal for temporary storage of water,chemicals and other liquids.The EZ KLEEN 6900 is portable lightweight and ideal �R for use in construction,manufacturing,power plants and a /_ variety of industrial applications. Qrzi Features: 1-800-742-7246 EZ KLEEN Poly Tanks have two molded in 3 inch flanges on the 240397 bottom of every tank for superior drainage and ease of cleaning. Each EZ KLEEN tank comes with a pad standard. Specs: Accessories: • Spillguard Material Cross linked polyethylene • Suction and Discharge Hoses Capacity 6900 gallons • AOD pumps Dry weight 2400 lbs. • Spillguard hose bridges Footprint: 120"x 161" 120" 3" Top Fill 27 PVC Vent � � 24" Manwey Lid Ladder Bracket Aluminum Ladder \/I 161" .4zfon , cf() 41, ij��,11 6 t It�•/'lil /I y Two 3" PVC Butterfly Valves w/ Vitae seals, FIPT Outlets. Liquid Ingenuity PUMPS • TANKS • FILTRATION • PIPE • SPILLGUARDS 800-742-7246 Rain for Rent is a registered trademark of Western Oilfields Supply Company.Features and specifications are subject to change without notice. rainforrent.com Bag Filter BF100 Overview: The BF100 bag filter unit features one bag filter tank and utilizes 7"x 30"bag filters for superior filtration from 100 to 1 micron for flows up to 100 GPM. -- Features: • No moving parts • Skid mounted • Fitted with bleed valves and pressure gauges • • Chambers constructed of 304 Stainless Steel r►� • Piping constructed of 304 stainless steel ''` • Stainless Steel Inlet and outlet manifolds Specs: Accessories: • Spillguard Max Flow 100 GPM • Suction and Discharge Hoses Material Stainless Steel Max PSI 125 PSI Dry weight 325 lbs. Footprint: 48"x 36" Inlet x outlet 2"x 2"Flange c 11 I ci�sy�c I �., FO R 'p 116 .2 17611 erl I.Q Irl la,i Irl _ "V" Liquid Ingenuity, PUMPS • TANKS • FILTRATION • PIPE • SPILLGUARDS 800-742-7246 Rain for Rent is a registered trademark of Western Oilfields Supply Company.Features and specifications are subject to change without notice. ra Info rrent.co m ,_ Enviro-Equipment, Inc. Remediation Division LPCD-55 — Liquid Phase Carbon Drum Available as empty drums with no media or filled with .�� reactivated carbon, virgin carbon or a variety of specialty i ` medias upon request/ z ill ;0,.. - ' \\ , gin` . /4,. 8x30 Mesh GAC - Pressure Drop _ 12 10 • :\ '` a 8 • !\ EI+V\RO-EOu1PMENT WC' 0 4 v. Z. 2 I' 0 • ':,. Si 0 ).2 0.4 0.6 0.8 1 1.2 1.4 Pressure Drop(PSIG) LPCD-55 Specifications Dimensions 2'10" Tall x 24" Internal Piping SCH 40 PVC Diameter Inlet / Outlet 2" Female NPT Internal Coating Epoxy GAC Fill 200 Pounds Max Pressure / 10 PSIG / 140 F Temp Shipping Weight 250 Pounds Bed Depth / 2.4 Feet / 6.6 cubic Volume feet Operational 600 Pounds Cross Sectional 2.8 square Feet Weight Bed Area 10120 Industrial Drive • Pineville, NC 28134 • 704-556-7723 www.enviroequipment.com Enviro-Equipment Inc. 10120 Industrial Drive Pineville NC 28134 PRODUCT BULLETIN 8x30 Mesh Liquid Phase Reactivated Carbon Reactivated Granular Activated Carbon(GAC)(8 x 30) is a hard, reactivated,carbon manufactured from pooled spent carbon which is recommended for a variety of waste water and process water treatment. It efficiently removes chlorine, taste and odor compounds, and volatile organics, even with brief contact times. DOWNFLOW PRESSURE DROP so • 45 a wi• 40 . 0 35 Dense Packed m LL 30 0 .-- 25 LL cx 20 a O 15 = 10 Loose Packed 0 d 5 0 1 2 3 4 S 6 7 8 9 10 SUPERFICIAL VELOCITY,GPM FT' TYPICAL PHYSICAL PROPERTIES / SPECIFICATIONS Iodine Number, Min 800 Bulk Density,Min(lbs per cubic foot) 29-31 Particle Size—mesh size 8x30 Moisture,max as packed-%w/w 2% STANDARD PACKAGING: 551b or 27.51b POLYLINED POLYPROPYLENE BAGS. 2001b FIBER DRUMS. 10001b SUPERSACKS. This information is offered solely for your consideration and verification. It has been gathered from reference materials and/or test procedures and is believed to be true and accurate. None of this information shall constitute a warranty or representation,expressed or implied for which we assume legal responsibility or that the information or goods is fit for any particular use either alone or in combination with other goods or processes. Attachment D Laboratory Analytical Report (June 2022 Groundwater Samples) 1 Pace Analytical Services,LLC e 9800 Kincey Ave. Suite 100 aceAnalytical Huntersville,NC 28078 www.pacolabs.com (704)875-9092 June 24, 2022 Haley Martin Hart& Hickman 2923 S. Tryon St Suite 100 Charlotte, NC 28203 RE: Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Dear Haley Martin: Enclosed are the analytical results for sample(s)received by the laboratory on June 17,2022. The results relate only to the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the laboratory's Quality Manual,where applicable, unless otherwise noted in the body of the report. The test results provided in this final report were generated by each of the following laboratories within the Pace Network: •Pace Analytical Services-Asheville •Pace Analytical Services-Charlotte If you have any questions concerning this report, please feel free to contact me. Sincerely, Kevin Godwin kevin.godwin@pacelabs.com 1(704)875-9092 Project Manager Enclosures ,, -.. s` z=' REPORT OF LABORATORY ANALYSIS x This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,LLC. Page 1 of 54 Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite100 Huntersville,NC 28078078 www.pacalabs.com (704)875-9092 CERTIFICATIONS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Pace Analytical Services Charlotte South Carolina Laboratory ID:99006 South Carolina Certification#:99006001 9800 Kincey Ave.Ste 100,Huntersville,NC 28078 South Carolina Drinking Water Cert.#:99006003 North Carolina Drinking Water Certification#:37706 Florida/NELAP Certification#:E87627 North Carolina Field Services Certification#:5342 Kentucky UST Certification#:84 North Carolina Wastewater Certification#: 12 Louisiana DoH Drinking Water#:LA029 South Carolina Laboratory ID:99006 Virginia/VELAP Certification#:460221 Pace Analytical Services Asheville 2225 Riverside Drive,Asheville,NC 28804 South Carolina Laboratory ID:99030 Florida/NELAP Certification#:E87648 South Carolina Certification#:99030001 North Carolina Drinking Water Certification#:37712 Virginia/VELAP Certification#:460222 North Carolina Wastewater Certification#:40 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,LLC. Page 2 of 54 L Pace Analytical Services,LLC a 9800 Kincey Ave. Suite 100 aceAnalytical Huntersville,NC 28078 www.pacalabs.cam (704)875-9092 i SAMPLE SUMMARY Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Lab ID Sample ID Matrix Date Collected Date Received 92610548001 MW-1 Water 06/17/22 13:55 06/17/22 15:05 92610548002 MW-2 Water 06/17/22 12:30 06/17/22 15:05 92610548003 MW-3 Water 06/17/22 11:05 06/17/22 15:05 92610548004 MW-4 Water 06/17/22 10:05 06/17/22 15:05 92610548005 GW-DUP Water 06/17/22 00:00 06/17/22 15:05 92610548006 Trip Blank Water 06/17/22 00:00 06/17/22 15:05 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,LLC. Page 3 of 54 Pace Analytical Services,LLC s aceAnalytical 9800 Kincey Ave. Suite100 Huntersville,NC 28078078 www.pacdabs.cam (704)875-9092 SAMPLE ANALYTE COUNT Project Press Club Cleaners TCR-003 Pace Project No.: 92610548 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92610548001 MW-1 EPA 6020E DBB1 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8270E PKS 74 PASI-C EPA 8260D CL 63 PASI-C 92610548002 MW-2 EPA6020B DBB1 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8270E PKS 74 PASI-C EPA 8260D CL 63 PASI-C 92610548003 MW-3 EPA6020B DBB1 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8270E PKS 74 PASI-C EPA 8260D CL 63 PASI-C 92610548004 MW-4 EPA 6020E DBB1 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8270E PKS 74 PASI-C EPA 8260D CL 63 PASI-C 92610548005 GW-DUP EPA6020B DBB1 7 PASI-A EPA 7470A NMP 1 PASI-A EPA 8270E PKS 74 PASI-C EPA 8260D CL 63 PAS I-C 92610548006 Trip Blank EPA 8260D CL 63 PASI-C PASI-A=Pace Analytical Services-Asheville PASI-C=Pace Analytical Services-Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, without the written consent of Pace Analytical Services,LLC. Page 4 of 54 Pace Analytical Services,LLC aceAnalyticals 9800 Kincey Ave. Suite 100 Huntersville,NC 28078 wwo.paeNe6s.com (704)875-9092 i ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-1 Lab ID: 92610548001 Collected: 06/17/22 13:55 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method:EPA 6020B Preparation Method:EPA 3010A Pace Analytical Services-Asheville Arsenic ND ug/L 1.0 0.087 1 06/18/22 16:52 06/20/22 05:30 7440-38-2 Barium 21.3 ug/L 1.0 0.21 1 06/18/22 16:52 06/20/22 05:30 7440-39-3 Cadmium ND ug/L 0.20 0.060 1 06/18/22 16:52 06/20/22 05:30 7440-43-9 Chromium 1.3 ug/L 1.0 0.50 1 06/18/22 16:52 06/20/22 05:30 7440-47-3 Lead ND ug/L 1.0 0.077 1 06/18/22 16:52 06/20/22 05:30 7439-92-1 Selenium 0.10J ug/L 2.0 0.072 1 06/18/22 16:52 06/20/22 05:30 7782-49-2 Silver ND ug/L 0.40 0.070 1 06/18/22 16:52 06/20/22 05:30 7440-22-4 7470 Mercury Analytical Method:EPA 7470A Preparation Method:EPA 7470A Pace Analytical Services-Asheville Mercury ND ug/L 0.20 0.12 1 06/21/22 14:14 06/23/22 12:32 7439-97-6 8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C Pace Analytical Services-Charlotte Acenaphthene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 19:36 83-32-9 Acenaphthylene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 19:36 208-96-8 Aniline ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 19:36 62-53-3 Anthracene ND ug/L 10.0 2.3 1 06/22/22 11:22 06/22/22 19:36 120-12-7 Benzo(a)anthracene ND ug/L 10.0 2.7 1 06/22/22 11:22 06/22/22 19:36 56-55-3 Benzo(a)pyrene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 19:36 50-32-8 Benzo(b)fluoranthene ND ug/L 10.0 2.6 1 06/22/22 11:22 06/22/22 19:36 205-99-2 Benzo(g,h,i)perylene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 19:36 191-24-2 Benzo(k)fluoranthene ND ug/L 10.0 2.7 1 06/22/22 11:22 06/22/22 19:36 207-08-9 Benzoic Acid ND ug/L 50.0 22.0 1 06/22/22 11:22 06/22/22 19:36 65-85-0 Benzyl alcohol ND ug/L 20.0 2.9 1 06/22/22 11:22 06/22/22 19:36 100-51-6 4-Bromophenylphenyl ether ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 19:36 101-55-3 Butylbenzylphthalate ND ug/L 10.0 3.1 1 06/22/22 11:22 06/22/22 19:36 85-68-7 4-Chloro-3-methylphenol ND ug/L 10.0 3.3 1 06/22/22 11:22 06/22/22 19:36 59-50-7 4-Chloroaniline ND ug/L 20.0 3.6 1 06/22/22 11:22 06/22/22 19:36 106-47-8 bis(2-Chloroethoxy)methane ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 19:36 111-91-1 bis(2-Chloroethyl)ether ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 19:36 111-44-4 2-Chloronaphthalene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 19:36 91-58-7 2-Chlorophenol ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 19:36 95-57-8 4-Chlorophenylphenyl ether ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 19:36 7005-72-3 Chrysene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 19:36 218-01-9 Dibenz(a,h)anthracene ND ug/L 10.0 3.0 1 06/22/22 11:22 06/22/22 19:36 53-70-3 Dibenzofuran ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 19:36 132-64-9 1,2-Dichlorobenzene ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 19:36 95-50-1 1,3-Dichlorobenzene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 19:36 541-73-1 1,4-Dichlorobenzene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 19:36 106-46-7 3,3'-Dichlorobenzidine ND ug/L 20.0 8.1 1 06/22/22 11:22 06/22/22 19:36 91-94-1 2,4-Dichlorophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 19:36 120-83-2 Diethylphthalate ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 19:36 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 19:36 105-67-9 Dimethylphthalate ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 19:36 131-11-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 5 of 54 Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite 100 Huntersville,NC 28078078 www.pacalabs.cam (704)875-9092 ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-1 Lab ID: 92610548001 Collected: 06/17/22 13:55 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C Pace Analytical Services-Charlotte Di-n-butylphthalate ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 19:36 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 20.0 7.8 1 06/22/22 11:22 06/22/22 19:36 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 26.0 1 06/22/22 11:22 06/22/22 19:36 51-28-5 2,4-Dinitrotoluene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 19:36 121-14-2 2,6-Dinitrotoluene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 19:36 606-20-2 Di-n-octylphthalate ND ug/L 10.0 3.9 1 06/22/22 11:22 06/22/22 19:36 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 6.0 3.7 1 06/22/22 11:22 06/22/22 19:36 117-81-7 Fluoranthene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 19:36 206-44-0 Fluorene ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 19:36 86-73-7 Hexachloro-1,3-butadiene ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 19:36 87-68-3 Hexachlorobenzene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 19:36 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 19:36 77-47-4 v1 Hexachloroethane ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 19:36 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 10.0 2.9 1 06/22/22 11:22 06/22/22 19:36 193-39-5 Isophorone ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 19:36 78-59-1 1-Methylnaphthalene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 19:36 90-12-0 2-Methylnaphthalene ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 19:36 91-57-6 2-Methylphenol(o-Cresol) ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 19:36 95-48-7 3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 19:36 15831-10-4 Naphthalene ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 19:36 91-20-3 2-Nitroaniline ND ug/L 20.0 3.0 1 06/22/22 11:22 06/22/22 19:36 88-74-4 3-Nitroaniline ND ug/L 20.0 3.8 1 06/22/22 11:22 06/22/22 19:36 99-09-2 IL 4-Nitroaniline ND ug/L 20.0 5.1 1 06/22/22 11:22 06/22/22 19:36 100-01-6 Nitrobenzene ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 19:36 98-95-3 2-Nitrophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 19:36 88-75-5 4-Nitrophenol ND ug/L 50.0 6.6 1 06/22/22 11:22 06/22/22 19:36 100-02-7 N-Nitrosodimethylamine ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 19:36 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 10.0 1.3 1 06/22/22 11:22 06/22/22 19:36 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 3.0 1 06/22/22 11:22 06/22/22 19:36 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 19:36 108-60-1 Pentachlorophenol ND ug/L 20.0 3.8 1 06/22/22 11:22 06/22/22 19:36 87-86-5 Phenanthrene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 19:36 85-01-8 Phenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 19:36 108-95-2 Pyrene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 19:36 129-00-0 1,2,4-Trichlorobenzene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 19:36 120-82-1 2,4,5-Trichlorophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 19:36 95-95-4 2,4,6-Trichlorophenol ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 19:36 88-06-2 Surrogates Nitrobenzene-d5(S) 80 % 10-144 1 06/22/22 11:22 06/22/22 19:36 4165-60-0 2-Fluorobiphenyl(S) 53 % 10-130 1 06/22/22 11:22 06/22/22 19:36 321-60-8 Terphenyl-d14(S) 132 % 34-163 1 06/22/22 11:22 06/22/22 19:36 1718-51-0 Phenol-d6(S) 42 % 10-130 1 06/22/22 11:22 06/22/22 19:36 13127-88-3 2-Fluorophenol(S) 54 % 10-130 1 06/22/22 11:22 06/22/22 19:36 367-12-4 2,4,6-Tribromophenol(S) 110 % 10-144 1 06/22/22 11:22 06/22/22 19:36 118-79-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 6 of 54 Pace Analytical Services,LLC 9800 Kincey Ave Suite 100 ace Analytical Huntersville,NC 28078 www.pacelabs.com (704)875-9092 i ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-1 Lab ID: 92610548001 Collected: 06/17/22 13:55 Received: 06/17/22 15:05 Matrix:Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method:EPA 8260D Pace Analytical Services-Charlotte Acetone ND ug/L 312 63.9 12.5 06/23/22 00:44 67-64-1 Benzene ND ug/L 12.5 4.3 12.5 06/23/22 00:44 71-43-2 Bromobenzene ND ug/L 12.5 3.6 12.5 06/23/22 00:44 108-86-1 Bromochloromethane ND ug/L 12.5 5.8 12.5 06/23/22 00:44 74-97-5 Bromodichloromethane ND ug/L 12.5 3.8 12.5 06/23/22 00:44 75-27-4 Bromoform ND ug/L 12.5 4.3 12.5 06/23/22 00:44 75-25-2 IK Bromomethane ND ug/L 25.0 20.8 12.5 06/23/22 00:44 74-83-9 2-Butanone(MEK) ND ug/L 62.5 49.5 12.5 06/23/22 00:44 78-93-3 Carbon tetrachloride ND ug/L 12.5 4.2 12.5 06/23/22 00:44 56-23-5 Chlorobenzene ND ug/L 12.5 3.6 12.5 06/23/22 00:44 108-90-7 Chloroethane ND ug/L 12.5 8.1 12.5 06/23/22 00:44 75-00-3 v1 Chloroform ND ug/L 12.5 5.4 12.5 06/23/22 00:44 67-66-3 Chloromethane ND ug/L 12.5 6.8 12.5 06/23/22 00:44 74-87-3 2-Chlorotoluene ND ug/L 12.5 4.0 12.5 06/23/22 00:44 95-49-8 4-Chlorotoluene ND ug/L 12.5 4.0 12.5 06/23/22 00:44 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 25.0 4.2 12.5 06/23/22 00:44 96-12-8 Dibromochloromethane ND ug/L 12.5 4.5 12.5 06/23/22 00:44 124-48-1 1,2-Dibromoethane(EDB) ND ug/L 12.5 3.4 12.5 06/23/22 00:44 106-93-4 Dibromomethane ND ug/L 12.5 4.9 12.5 06/23/22 00:44 74-95-3 1,2-Dichlorobenzene ND ug/L 12.5 4.2 12.5 06/23/22 00:44 95-50-1 1,3-Dichlorobenzene ND ug/L 12.5 4.2 12.5 06/23/22 00:44 541-73-1 1,4-Dichlorobenzene ND ug/L 12.5 4.2 12.5 06/23/22 00:44 106-46-7 Dichlorodifluoromethane ND ug/L 12.5 4.3 12.5 06/23/22 00:44 75-71-8 1,1-Dichloroethane ND ug/L 12.5 4.6 12.5 06/23/22 00:44 75-34-3 1,2-Dichloroethane ND ug/L 12.5 4.0 12.5 06/23/22 00:44 107-06-2 1,1-Dichloroethene ND ug/L 12.5 4.4 12.5 . 06/23/22 00:44 75-35-4 cis-1,2-Dichloroethene 165 ug/L 12.5 4.8 12.5 06/23/22 00:44 156-59-2 trans-1,2-Dichloroethene ND ug/L 12.5 5.0 12.5 06/23/22 00:44 156-60-5 1,2-Dichloropropane ND ug/L 12.5 4.4 12.5 06/23/22 00:44 78-87-5 1,3-Dichloropropane ND ug/L 12.5 3.6 12.5 06/23/22 00:44 142-28-9 2,2-Dichloropropane ND ug/L 12.5 4.8 12.5 06/23/22 00:44 594-20-7 v1 1,1-Dichloropropene ND ug/L 12.5 5.3 12.5 06/23/22 00:44 563-58-6 cis-1,3-Dichloropropene ND ug/L 12.5 4.6 12.5 06/23/22 00:44 10061-01-5 trans-1,3-Dichloropropene ND ug/L 12.5 4.5 12.5 06/23/22 00:44 10061-02-6 Diisopropyl ether ND ug/L 12.5 3.8 12.5 06/23/22 00:44 108-20-3 Ethylbenzene ND ug/L 12.5 3.8 12.5 06/23/22 00:44 100-41-4 Hexachloro-1,3-butadiene ND ug/L 25.0 19.1 12.5 06/23/22 00:44 87-68-3 2-Hexanone ND ug/L 62.5 6.0 12.5 06/23/22 00:44 591-78-6 p-Isopropyltoluene ND ug/L 12.5 5.2 12.5 06/23/22 00:44 99-87-6 Methylene Chloride ND ug/L 62.5 24.4 12.5 06/23/22 00:44 75-09-2 4-Methyl-2-pentanone(MIBK) ND ug/L 62.5 33.9 12.5 06/23/22 00:44 108-10-1 Methyl-tert-butyl ether ND ug/L 12.5 5.3 12.5 06/23/22 00:44 1634-04-4 Naphthalene ND ug/L 12.5 8.1 12.5 06/23/22 00:44 91-20-3 v1 1 Styrene ND ug/L 12.5 3.6 12.5 06/23/22 00:44 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 12.5 3.9 12.5 06/23/22 00:44 630-20-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 7 of 54 Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite100 Huntersville,NC 28078078 www.pacetahs.com (704)875-9092 ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-1 Lab ID: 92610548001 Collected: 06/17/22 13:55 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method:EPA 8260D Pace Analytical Services-Charlotte 1,1,2,2-Tetrachloroethane ND ug/L 12.5 2.8 12.5 06/23/22 00:44 79-34-5 Tetrachloroethene 2370 ug/L 12.5 3.6 12.5 06/23/22 00:44 127-18-4 Toluene ND ug/L 12.5 6.1 12.5 06/23/22 00:44 108-88-3 1,2,3-Trichlorobenzene ND ug/L 12.5 10.1 12.5 06/23/22 00:44 87-61-6 v1 1,2,4-Trichlorobenzene ND ug/L 12.5 8.0 12.5 06/23/22 00:44 120-82-1 1,1,1-Trichloroethane ND ug/L 12.5 4.2 12.5 06/23/22 00:44 71-55-6 1,1,2-Trichloroethane ND ug/L 12.5 4.1 12.5 06/23/22 00:44 79-00-5 Trichloroethene 183 ug/L 12.5 4.8 12.5 06/23/22 00:44 79-01-6 Trichlorofluoromethane ND ug/L 12.5 3.7 12.5 06/23/22 00:44 75-69-4 1,2,3-Trichloropropane ND ug/L 12.5 3.3 12.5 06/23/22 00:44 96-18-4 Vinyl acetate ND ug/L 25.0 16.4 12.5 06/23/22 00:44 108-05-4 Vinyl chloride 20.5 ug/L 12.5 4.8 12.5 06/23/22 00:44 75-01-4 1 Xylene(Total) ND ug/L 12.5 4.2 12.5 06/23/22 00:44 1330-20-7 m&p-Xylene ND ug/L 25.0 8.9 12.5 06/23/22 00:44 179601-23-1 o-Xylene ND ug/L 12.5 4.2 12.5 06/23/22 00:44 95-47-6 Surrogates 4-Bromofluorobenzene(S) 97 % 70-130 12.5 06/23/22 00:44 460-00-4 1,2-Dichloroethane-d4(S) 109 % 70-130 12.5 06/23/22 00:44 17060-07-0 Toluene-d8(S) 98 % 70-130 12.5 06/23/22 00:44 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 8 of 54 Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite 100 Huntersville,NC 28078 www.pac.Iahs.com (704)875-9092 I ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-2 Lab ID: 92610548002 Collected: 06/17/22 12:30 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method:EPA 6020E Preparation Method:EPA 3010A Pace Analytical Services-Asheville Arsenic 0.82J ug/L 1.0 0.087 1 06/18/22 16:52 06/20/22 05:49 7440-38-2 Barium 142 ug/L 1.0 0.21 1 06/18/22 16:52 06/20/22 05:49 7440-39-3 11 Cadmium ND ug/L 0.20 0.060 1 06/18/22 16:52 06/20/22 05:49 7440-43-9 Chromium 0.90J ug/L 1.0 0.50 1 06/18/22 16:52 06/20/22 05:49 7440-47-3 Lead 0.35J ug/L 1.0 0.077 1 06/18/22 16:52 06/20/22 05:49 7439-92-1 Selenium 0.14J ug/L 2.0 0.072 1 06/18/22 16:52 06/20/22 05:49 7782-49-2 Silver ND ug/L 0.40 0.070 1 06/18/22 16:52 06/20/22 05:49 7440-22-4 7470 Mercury Analytical Method:EPA 7470A Preparation Method:EPA 7470A Pace Analytical Services-Asheville Mercury ND ug/L 0.20 0.12 1 06/21/22 14:14 06/23/22 12:34 7439-97-6 8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C Pace Analytical Services-Charlotte Acenaphthene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 20:02 83-32-9 Acenaphthylene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 20:02 208-96-8 Aniline ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 20:02 62-53-3 Anthracene ND ug/L 10.0 2.3 1 06/22/22 11:22 06/22/22 20:02 120-12-7 Benzo(a)anthracene ND ug/L 10.0 2.7 1 06/22/22 11:22 06/22/22 20:02 56-55-3 Benzo(a)pyrene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 20:02 50-32-8 Benzo(b)fluoranthene ND ug/L 10.0 2.6 1 06/22/22 11:22 06/22/22 20:02 205-99-2 Benzo(g,h,i)perylene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 20:02 191-24-2 Benzo(k)fluoranthene ND ug/L 10.0 2.7 1 06/22/22 11:22 06/22/22 20:02 207-08-9 Benzoic Acid ND ug/L 50.0 22.0 1 06/22/22 11:22 06/22/22 20:02 65-85-0 Benzyl alcohol ND ug/L 20.0 2.9 1 06/22/22 11:22 06/22/22 20:02 100-51-6 4-Bromophenylphenyl ether ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 20:02 101-55-3 Butylbenzylphthalate ND ug/L 10.0 3.1 1 06/22/22 11:22 06/22/22 20:02 85-68-7 4-Chloro-3-methylphenol ND ug/L 10.0 3.3 1 06/22/22 11:22 06/22/22 20:02 59-50-7 4-Chloroaniline ND ug/L 20.0 3.6 1 06/22/22 11:22 06/22/22 20:02 106-47-8 bis(2-Chloroethoxy)methane ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 20:02 111-91-1 bis(2-Chloroethyl)ether ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 20:02 111-44-4 2-Chloronaphthalene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 20:02 91-58-7 2-Chlorophenol ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 20:02 95-57-8 4-Chlorophenylphenyl ether ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 20:02 7005-72-3 Chrysene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 20:02 218-01-9 Dibenz(a,h)anthracene ND ug/L 10.0 3.0 1 06/22/22 11:22 06/22/22 20:02 53-70-3 Dibenzofuran ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 20:02 132-64-9 1,2-Dichlorobenzene ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 20:02 95-50-1 1,3-Dichlorobenzene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 20:02 541-73-1 1,4-Dichlorobenzene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 20:02 106-46-7 3,3'-Dichlorobenzidine ND ug/L 20.0 8.1 1 06/22/22 11:22 06/22/22 20:02 91-94-1 2,4-Dichlorophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 20:02 120-83-2 Diethylphthalate ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 20:02 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 20:02 105-67-9 Dimethylphthalate ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 20:02 131-11-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 9 of 54 Pace Analytical Services,LLC is aceAnalytical 9800 Kincey Ave. Suite100 Huntersville,NC 28078078 www.pacelabs.com (704)875-9092 ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-2 Lab ID: 92610548002 Collected: 06/17/22 12:30 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C Pace Analytical Services-Charlotte Di-n-butylphthalate ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 20:02 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 20.0 7.8 1 06/22/22 11:22 06/22/22 20:02 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 26.0 1 06/22/22 11:22 06/22/22 20:02 51-28-5 2,4-Dinitrotoluene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 20:02 121-14-2 2,6-Dinitrotoluene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 20:02 606-20-2 Di-n-octylphthalate ND ug/L 10.0 3.9 1 06/22/22 11:22 06/22/22 20:02 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 6.0 3.7 1 06/22/22 11:22 06/22/22 20:02 117-81-7 Fluoranthene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 20:02 206-44-0 Fluorene ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 20:02 86-73-7 Hexachloro-1,3-butadiene ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 20:02 87-68-3 Hexachlorobenzene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 20:02 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 20:02 77-47-4 v1 Hexachloroethane ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 20:02 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 10.0 2.9 1 06/22/22 11:22 06/22/22 20:02 193-39-5 Isophorone ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 20:02 78-59-1 1-Methylnaphthalene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 20:02 90-12-0 2-Methylnaphthalene ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 20:02 91-57-6 2-Methylphenol(o-Cresol) ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 20:02 95-48-7 3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 20:02 15831-10-4 Naphthalene ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 20:02 91-20-3 2-Nitroaniline ND ug/L 20.0 3.0 1 06/22/22 11:22 06/22/22 20:02 88-74-4 3-Nitroaniline ND ug/L 20.0 3.8 1 06/22/22 11:22 06/22/22 20:02 99-09-2 IL 4-Nitroaniline ND ug/L 20.0 5.1 1 06/22/22 11:22 06/22/22 20:02 100-01-6 Nitrobenzene ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 20:02 98-95-3 2-Nitrophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 20:02 88-75-5 4-Nitrophenol ND ug/L 50.0 6.6 1 06/22/22 11:22 06/22/22 20:02 100-02-7 N-Nitrosodimethylamine ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 20:02 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 10.0 1.3 1 06/22/22 11:22 06/22/22 20:02 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 3.0 1 06/22/22 11:22 06/22/22 20:02 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 20:02 108-60-1 Pentachlorophenol ND ug/L 20.0 3.8 1 06/22/22 11:22 06/22/22 20:02 87-86-5 Phenanthrene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 20:02 85-01-8 Phenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 20:02 108-95-2 Pyrene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 20:02 129-00-0 1,2,4-Trichlorobenzene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 20:02 120-82-1 2,4,5-Trichlorophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 20:02 95-95-4 2,4,6-Trichlorophenol ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 20:02 88-06-2 Surrogates Nitrobenzene-d5(S) 36 % 10-144 1 06/22/22 11:22 06/22/22 20:02 4165-60-0 2-Fluorobiphenyl(S) 22 % 10-130 1 06/22/22 11:22 06/22/22 20:02 321-60-8 Terphenyl-d14(S) 139 % 34-163 1 06/22/22 11:22 06/22/22 20:02 1718-51-0 Phenol-d6(S) 20 % 10-130 1 06/22/22 11:22 06/22/22 20:02 13127-88-3 2-Fluorophenol(S) 28 % 10-130 1 06/22/22 11:22 06/22/22 20:02 367-12-4 2,4,6-Tribromophenol(S) 115 % 10-144 1 06/22/22 11:22 06/22/22 20:02 118-79-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 10 of 54 Pace Analytical Services,LLC ^Q��/ i^�' 9800 Kincey Ave. Suite 100 l�li V Huntersville,NC 28078 / www.pacelabs.com (704)875-9092 1 i I ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 ' Sample: MW-2 Lab ID: 92610548002 Collected: 06/17/22 12:30 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method:EPA 8260D Pace Analytical Services-Charlotte Acetone ND ug/L 25.0 5.1 1 06/22/22 11:00 67-64-1 Benzene ND ug/L 1.0 0.34 1 06/22/22 11:00 71-43-2 Bromobenzene ND ug/L 1.0 0.29 1 06/22/22 11:00 108-86-1 Bromochloromethane ND ug/L 1.0 0.47 1 06/22/22 11:00 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/22/22 11:00 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/22/22 11:00 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/22/22 11:00 74-83-9 v2 2-Butanone(MEK) ND ug/L 5.0 4.0 1 06/22/22 11:00 78-93-3 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/22/22 11:00 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/22/22 11:00 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/22/22 11:00 75-00-3 Chloroform ND ug/L 1.0 0.43 1 06/22/22 11:00 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/22/22 11:00 74-87-3 2-Chlorotoluene ND ug/L 1.0 0.32 1 06/22/22 11:00 95-49-8 4-Chlorotoluene ND ug/L 1.0 0.32 1 06/22/22 11:00 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/22/22 11:00 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/22/22 11:00 124-48-1 1,2-Dibromoethane(EDB) ND ug/L 1.0 0.27 1 06/22/22 11:00 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/22/22 11:00 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/22/22 11:00 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 0.34 1 06/22/22 11:00 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/22/22 11:00 106-46-7 Dichlorodifluoromethane ND ug/L 1.0 0.35 1 06/22/22 11:00 75-71-8 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/22/22 11:00 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/22/22 11:00 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/22/22 11:00 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 06/22/22 11:00 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 06/22/22 11:00 156-60-5 ' 1,2-Dichloropropane ND ug/L 1.0 0.36 1 06/22/22 11:00 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.28 1 06/22/22 11:00 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.39 1 06/22/22 11:00 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.43 1 06/22/22 11:00 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.36 1 06/22/22 11:00 10061-01-5 trans-1,3-Dichloropropene ND ug/L 1.0 0.36 1 06/22/22 11:00 10061-02-6 Diisopropyl ether ND ug/L 1.0 0.31 1 06/22/22 11:00 108-20-3 Ethylbenzene ND ug/L 1.0 0.30 1 06/22/22 11:00 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1.5 1 06/22/22 11:00 87-68-3 2-Hexanone ND ug/L 5.0 0.48 1 06/22/22 11:00 591-78-6 p-Isopropyltoluene ND ug/L 1.0 0.41 1 06/22/22 11:00 99-87-6 Methylene Chloride ND ug/L 5.0 2.0 1 06/22/22 11:00 75-09-2 4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 2.7 1 06/22/22 11:00 108-10-1 Methyl-tert-butyl ether ND ug/L 1.0 0.42 1 06/22/22 11:00 1634-04-4 Naphthalene ND ug/L 1.0 0.64 1 06/22/22 11:00 91-20-3 Styrene ND ug/L 1.0 0.29 1 06/22/22 11:00 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.31 1 06/22/22 11:00 630-20-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 11 of 54 Pace Analytical Services,LLC 9800 Kincey Ave. Suite100 aceAnalytical Huntersville,NC 28078078 www.pacdabs.com (704)875-9092 i i ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-2 Lab ID: 92610548002 Collected: 06/17/22 12:30 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method:EPA 8260D Pace Analytical Services-Charlotte 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 06/22/22 11:00 79-34-5 Tetrachloroethene ND ug/L 1.0 0.29 1 06/22/22 11:00 127-18-4 Toluene ND ug/L 1.0 0.48 1 06/22/22 11:00 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 0.81 1 06/22/22 11:00 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 0.64 1 06/22/22 11:00 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 06/22/22 11:00 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 06/22/22 11:00 79-00-5 Trichloroethene ND ug/L 1.0 0.38 1 06/22/22 11:00 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 06/22/22 11:00 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 06/22/22 11:00 96-18-4 Vinyl acetate ND ug/L 2.0 1.3 1 06/22/22 11:00 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 06/22/22 11:00 75-01-4 Xylene(Total) ND ug/L 1.0 0.34 1 06/22/22 11:00 1330-20-7 m&p-Xylene ND ug/L 2.0 0.71 1 06/22/22 11:00 179601-23-1 o-Xylene ND ug/L 1.0 0.34 1 06/22/22 11:00 95-47-6 Surrogates 4-Bromofluorobenzene(S) 100 % 70-130 1 06/22/22 11:00 460-00-4 1,2-Dichloroethane-d4(S) 112 % 70-130 1 06/22/22 11:00 17060-07-0 % Toluene-d8(S) 102 70-130 1 06/22/22 11:00 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 12 of 54 Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite 100 Huntersville,NC 28078 www.pacelabs.com (704)875-9092 I ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-3 Lab ID: 92610548003 Collected: 06/17/22 11:05 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method:EPA 6020E Preparation Method:EPA 3010A Pace Analytical Services-Asheville Arsenic ND ug/L 1.0 0.087 1 06/18/22 16:52 06/20/22 06:00 7440-38-2 Barium 165 ug/L 1.0 0.21 1 06/18/22 16:52 06/20/22 06:00 7440-39-3 Cadmium 0.073J ug/L 0.20 0.060 1 06/18/22 16:52 06/20/22 06:00 7440-43-9 Chromium 2.3 ug/L 1.0 0.50 1 06/18/22 16:52 06/20/22 06:00 7440-47-3 Lead ND ug/L 1.0 0.077 1 06/18/22 16:52 06/20/22 06:00 7439-92-1 Selenium ND ug/L 2.0 0.072 1 06/18/22 16:52 06/20/22 06:00 7782-49-2 Silver ND ug/L 0.40 0.070 1 06/18/22 16:52 06/20/22 06:00 7440-22-4 7470 Mercury Analytical Method:EPA 7470A Preparation Method:EPA 7470A Pace Analytical Services-Asheville Mercury ND ug/L 0.20 0.12 1 06/21/22 14:14 06/23/22 12:36 7439-97-6 8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C Pace Analytical Services-Charlotte Acenaphthene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 20:27 83-32-9 Acenaphthylene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 20:27 208-96-8 Aniline ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 20:27 62-53-3 Anthracene ND ug/L 10.0 2.3 1 06/22/22 11:22 06/22/22 20:27 120-12-7 Benzo(a)anthracene ND ug/L 10.0 2.7 1 06/22/22 11:22 06/22/22 20:27 56-55-3 Benzo(a)pyrene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 20:27 50-32-8 Benzo(b)fluoranthene ND ug/L 10.0 2.6 1 06/22/22 11:22 06/22/22 20:27 205-99-2 Benzo(g,h,i)perylene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 20:27 191-24-2 Benzo(k)fluoranthene ND ug/L 10.0 2.7 1 06/22/22 11:22 06/22/22 20:27 207-08-9 Benzoic Acid ND ug/L 50.0 22.0 1 06/22/22 11:22 06/22/22 20:27 65-85-0 M1 Benzyl alcohol ND ug/L 20.0 2.9 1 06/22/22 11:22 06/22/22 20:27 100-51-6 4-Bromophenylphenyl ether ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 20:27 101-55-3 Butylbenzylphthalate ND ug/L 10.0 3.1 1 06/22/22 11:22 06/22/22 20:27 85-68-7 I 4-Chloro-3-methylphenol ND ug/L 10.0 3.3 1 06/22/22 11:22 06/22/22 20:27 59-50-7 4-Chloroaniline ND ug/L 20.0 3.6 1 06/22/22 11:22 06/22/22 20:27 106-47-8 bis(2-Chloroethoxy)methane ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 20:27 111-91-1 bis(2-Chloroethyl)ether ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 20:27 111-44-4 2-Chloronaphthalene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 20:27 91-58-7 2-Chlorophenol ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 20:27 95-57-8 R1 4-Chlorophenylphenyl ether ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 20:27 7005-72-3 Chrysene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 20:27 218-01-9 Dibenz(a,h)anthracene ND ug/L 10.0 3.0 1 06/22/22 11:22 06/22/22 20:27 53-70-3 Dibenzofuran ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 20:27 132-64-9 1,2-Dichlorobenzene ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 20:27 95-50-1 1,3-Dichlorobenzene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 20:27 541-73-1 M1 1,4-Dichlorobenzene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 20:27 106-46-7 3,3'-Dichlorobenzidine ND ug/L 20.0 8.1 1 06/22/22 11:22 06/22/22 20:27 91-94-1 2,4-Dichlorophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 20:27 120-83-2 R1 Diethylphthalate ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 20:27 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 20:27 105-67-9 Dimethylphthalate ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 20:27 131-11-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 13 of 54 Pace Analytical Services,LLC 6 ace p nal tical 9800 Kincey Ave. Suite 100 t�l�Hll Y�l� Huntersville,NC 28078 www.pacalebs.cam (704)875-9092 ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-3 Lab ID: 92610548003 Collected: 06/17/22 11:05 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C Pace Analytical Services-Charlotte Di-n-butylphthalate ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 20:27 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 20.0 7.8 1 06/22/22 11:22 06/22/22 20:27 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 26.0 1 06/22/22 11:22 06/22/22 20:27 51-28-5 M1 2,4-Dinitrotoluene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 20:27 121-14-2 2,6-Dinitrotoluene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 20:27 606-20-2 Di-n-octylphthalate ND ug/L 10.0 3.9 1 06/22/22 11:22 06/22/22 20:27 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 6.0 3.7 1 06/22/22 11:22 06/22/22 20:27 117-81-7 Fluoranthene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 20:27 206-44-0 Fluorene ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 20:27 86-73-7 Hexachloro-1,3-butadiene ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 20:27 87-68-3 M1 Hexachlorobenzene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 20:27 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 20:27 77-47-4 v1 Hexachloroethane ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 20:27 67-72-1 M1 Indeno(1,2,3-cd)pyrene ND ug/L 10.0 2.9 1 06/22/22 11:22 06/22/22 20:27 193-39-5 Isophorone ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 20:27 78-59-1 1-Methylnaphthalene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 20:27 90-12-0 2-Methylnaphthalene ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 20:27 91-57-6 2-Methylphenol(o-Cresol) ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 20:27 95-48-7 3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 20:27 15831-10-4 Naphthalene ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 20:27 91-20-3 R1 2-Nitroaniline ND ug/L 20.0 3.0 1 06/22/22 11:22 06/22/22 20:27 88-74-4 3-Nitroaniline ND ug/L 20.0 3.8 1 06/22/22 11:22 06/22/22 20:27 99-09-2 IL 4-Nitroaniline ND ug/L 20.0 5.1 1 06/22/22 11:22 06/22/22 20:27 100-01-6 Nitrobenzene ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 20:27 98-95-3 2-Nitrophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 20:27 88-75-5 R1 4-Nitrophenol ND ug/L 50.0 6.6 1 06/22/22 11:22 06/22/22 20:27 100-02-7 M1 N-Nitrosodimethylamine ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 20:27 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 10.0 1.3 1 06/22/22 11:22 06/22/22 20:27 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 3.0 1 06/22/22 11:22 06/22/22 20:27 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 20:27 108-60-1 Pentachlorophenol ND ug/L 20.0 3.8 1 06/22/22 11:22 06/22/22 20:27 87-86-5 Phenanthrene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 20:27 85-01-8 Phenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 20:27 108-95-2 Pyrene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 20:27 129-00-0 1,2,4-Trichlorobenzene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 20:27 120-82-1 2,4,5-Trichlorophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 20:27 95-95-4 R1 ug/L henol ND u /L 10.0 1.6 1 06/22/22 11:22 06/22/22 20:27 88-06-2 R1 P Surrogates Nitrobenzene-d5(S) 65 % 10-144 1 06/22/22 11:22 06/22/22 20:27 4165-60-0 2-Fluorobiphenyl(S) 49 % 10-130 1 06/22/22 11:22 06/22/22 20:27 321-60-8 Ter hen I-d14 S 125 34-163 1 06/22/22 11:22 06/22/22 20:27 1718-51-0 P Y ( ) % Phenol-d6(S) 37 % 10-130 1 06/22/22 11:22 06/22/22 20:27 13127-88-3 2-Fluorophenol(S) 51 % 10-130 1 06/22/22 11:22 06/22/22 20:27 367-12-4 2,4,6-Tribromophenol(S) 99 % 10-144 1 06/22/22 11:22 06/22/22 20:27 118-79-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 14 of 54 Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite100 Huntersville,NC 28078078 www.pacalabs.com (704)875-9092 il i ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-3 Lab ID: 92610548003 Collected: 06/17/22 11:05 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method:EPA 8260D Pace Analytical Services-Charlotte Acetone ND ug/L 25.0 5.1 1 06/22/22 11:18 67-64-1 Benzene ND ug/L 1.0 0.34 1 06/22/22 11:18 71-43-2 Bromobenzene ND ug/L 1.0 0.29 1 06/22/22 11:18 108-86-1 Bromochloromethane ND ug/L 1.0 0.47 1 06/22/22 11:18 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/22/22 11:18 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/22/22 11:18 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/22/22 11:18 74-83-9 v2 2-Butanone(MEK) ND ug/L 5.0 4.0 1 06/22/22 11:18 78-93-3 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/22/22 11:18 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/22/22 11:18 108-90-7 Chloroethane ND ug/L 1.0 '0.65 1 06/22/22 11:18 75-00-3 Chloroform 1.7 ug/L 1.0 0.43 1 06/22/22 11:18 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/22/22 11:18 74-87-3 2-Chlorotoluene ND ug/L 1.0 0.32 1 06/22/22 11:18 95-49-8 4-Chlorotoluene ND ug/L 1.0 0.32 1 06/22/22 11:18 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/22/22 11:18 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/22/22 11:18 124-48-1 1,2-Dibromoethane(EDB) ND ug/L 1.0 0.27 1 06/22/22 11:18 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/22/22 11:18 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/22/22 11:18 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 0.34 1 06/22/22 11:18 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/22/22 11:18 106-46-7 Dichlorodifluoromethane ND ug/L 1.0 0.35 1 06/22/22 11:18 75-71-8 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/22/22 11:18 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/22/22 11:18 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/22/22 11:18 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 06/22/22 11:18 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 06/22/22 11:18 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 06/22/22 11:18 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.28 1 06/22/22 11:18 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.39 1 06/22/22 11:18 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.43 1 06/22/22 11:18 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.36 1 06/22/22 11:18 10061-01-5 trans-1,3-Dichloropropene ND ug/L 1.0 0.36 1 06/22/22 11:18 10061-02-6 Diisopropyl ether ND ug/L 1.0 0.31 1 06/22/22 11:18 108-20-3 Ethylbenzene ND ug/L 1.0 0.30 1 06/22/22 11:18 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1.5 1 06/22/22 11:18 87-68-3 2-Hexanone ND ug/L 5.0 0.48 1 06/22/22 11:18 591-78-6 p-lsopropyltoluene ND ug/L 1.0 0.41 1 06/22/22 11:18 99-87-6 Methylene Chloride ND ug/L 5.0 2.0 1 06/22/22 11:18 75-09-2 4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 2.7 1 06/22/22 11:18 108-10-1 Methyl-tert-butyl ether ND ug/L 1.0 0.42 1 06/22/22 11:18 1634-04-4 Naphthalene ND ug/L 1.0 0.64 1 06/22/22 11:18 91-20-3 Styrene ND ug/L 1.0 0.29 1 06/22/22 11:18 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.31 1 06/22/22 11:18 630-20-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, I Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 15 of 54 Pace Analytical Services,LLC e aceAnalytical 9800 Kincey Ave. Suite100 Huntersville,NC 28078078 www.pacelabs.com (704)875-9092 ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-3 Lab ID: 92610548003 Collected: 06/17/22 11:05 Received: 06/17/22 15:05 Matrix:Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method:EPA 8260D Pace Analytical Services-Charlotte 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 06/22/22 11:18 79-34-5 Tetrachloroethene ND ug/L 1.0 0.29 1 06/22/22 11:18 127-18-4 Toluene ND ug/L 1.0 0.48 1 06/22/22 11:18 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 0.81 1 06/22/22 11:18 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 0.64 1 06/22/22 11:18 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 06/22/22 11:18 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 06/22/22 11:18 79-00-5 Trichloroethene ND ug/L 1.0 0.38 1 06/22/22 11:18 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 06/22/22 11:18 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 06/22/22 11:18 96-18-4 Vinyl acetate ND ug/L 2.0 1.3 1 06/22/22 11:18 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 06/22/22 11:18 75-01-4 Xylene(Total) ND ug/L 1.0 0.34 1 06/22/22 11:18 1330-20-7 m&p-Xylene ND ug/L 2.0 0.71 1 06/22/22 11:18 179601-23-1 o-Xylene ND ug/L 1.0 0.34 1 06/22/22 11:18 95-47-6 Surrogates 4-Bromofluorobenzene(S) 100 % 70-130 1 06/22/22 11:18 460-00-4 1,2-Dichloroethane-d4(S) 113 % 70-130 1 06/22/22 11:18 17060-07-0 Toluene-d8(S) 101 % 70-130 1 06/22/22 11:18 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 16 of 54 Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite 100 Huntersville,NC 28078 www.pacelabs.com (704)875-9092 i ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-4 Lab ID: 92610548004 Collected: 06/17/22 10:05 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method:EPA 6020B Preparation Method:EPA 3010A Pace Analytical Services-Asheville Arsenic ND ug/L 1.0 0.087 1 06/18/22 16:52 06/20/22 06:04 7440-38-2 Barium 38.3 ug/L 1.0 0.21 1 06/18/22 16:52 06/20/22 06:04 7440-39-3 Cadmium ND ug/L 0.20 0.060 1 06/18/22 16:52 06/20/22 06:04 7440-43-9 Chromium 0.50J ug/L 1.0 0.50 1 06/18/22 16:52 06/20/22 06:04 7440-47-3 Lead ND ug/L 1.0 0.077 1 06/18/22 16:52 06/20/22 06:04 7439-92-1 Selenium 0.093J ug/L 2.0 0.072 1 06/18/22 16:52 06/20/22 06:04 7782-49-2 Silver ND ug/L 0.40 0.070 1 06/18/22 16:52 06/20/22 06:04 7440-22-4 7470 Mercury Analytical Method:EPA 7470A Preparation Method:EPA 7470A Pace Analytical Services-Asheville Mercury ND ug/L 0.20 0.12 1 06/21/22 14:14 06/23/22 12:39 7439-97-6 8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C Pace Analytical Services-Charlotte Acenaphthene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 21:44 83-32-9 Acenaphthylene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 21:44 208-96-8 Aniline ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 21:44 62-53-3 Anthracene ND ug/L 10.0 2.3 1 06/22/22 11:22 06/22/22 21:44 120-12-7 Benzo(a)anthracene ND ug/L 10.0 2.7 1 06/22/22 11:22 06/22/22 21:44 56-55-3 Benzo(a)pyrene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 21:44 50-32-8 Benzo(b)fluoranthene ND ug/L 10.0 2.6 1 06/22/22 11:22 06/22/22 21:44 205-99-2 Benzo(g,h,i)perylene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 21:44 191-24-2 Benzo(k)fluoranthene ND ug/L 10.0 2.7 1 06/22/22 11:22 06/22/22 21:44 207-08-9 Benzoic Acid ND ug/L 50.0 22.0 1 06/22/22 11:22 06/22/22 21:44 65-85-0 Benzyl alcohol ND ug/L 20.0 2.9 1 06/22/22 11:22 06/22/22 21:44 100-51-6 4-Bromophenylphenyl ether ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 21:44 101-55-3 Butylbenzylphthalate ND ug/L 10.0 3.1 1 06/22/22 11:22 06/22/22 21:44 85-68-7 4-Chloro-3-methylphenol ND ug/L 10.0 3.3 1 06/22/22 11:22 06/22/22 21:44 59-50-7 4-Chloroaniline ND ug/L 20.0 3.6 1 06/22/22 11:22 06/22/22 21:44 106-47-8 bis(2-Chloroethoxy)methane ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 21:44 111-91-1 bis(2-Chloroethyl)ether ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 21:44 111-44-4 2-Chloronaphthalene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 21:44 91-58-7 2-Chlorophenol ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 21:44 95-57-8 4-Chlorophenylphenyl ether ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 21:44 7005-72-3 Chrysene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 21:44 218-01-9 Dibenz(a,h)anthracene ND ug/L 10.0 3.0 1 06/22/22 11:22 06/22/22 21:44 53-70-3 Dibenzofuran ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 21:44 132-64-9 1,2-Dichlorobenzene ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 21:44 95-50-1 1,3-Dichlorobenzene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 21:44 541-73-1 1,4-Dichlorobenzene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 21:44 106-46-7 3,3'-Dichlorobenzidine ND ug/L 20.0 8.1 1 06/22/22 11:22 06/22/22 21:44 91-94-1 2,4-Dichlorophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 21:44 120-83-2 Diethylphthalate ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 21:44 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 21:44 105-67-9 Dimethylphthalate ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 21:44 131-11-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM - without the written consent of Pace Analytical Services,LLC. Page 17 of 54 Pace Analytical Services,LLC a aceAnalytical 9800 Kincey Ave. Suite100 Huntersville,NC 28078078 / www.pacelabs.com (704)875-9092 ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-4 Lab ID: 92610548004 Collected: 06/17/22 10:05 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C Pace Analytical Services-Charlotte Di-n-butylphthalate ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 21:44 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 20.0 7.8 1 06/22/22 11:22 06/22/22 21:44 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 26.0 1 06/22/22 11:22 06/22/22 21:44 51-28-5 2,4-Dinitrotoluene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 21:44 121-14-2 2,6-Dinitrotoluene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 21:44 606-20-2 Di-n-octylphthalate ND ug/L 10.0 3.9 1 06/22/22 11:22 06/22/22 21:44 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 6.0 3.7 1 06/22/22 11:22 06/22/22 21:44 117-81-7 Fluoranthene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 21:44 206-44-0 Fluorene ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 21:44 86-73-7 Hexachloro-1,3-butadiene ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 21:44 87-68-3 Hexachlorobenzene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 21:44 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 21:44 77-47-4 v1 Hexachloroethane ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 21:44 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 10.0 2.9 1 06/22/22 11:22 06/22/22 21:44 193-39-5 Isophorone ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 21:44 78-59-1 1-Methylnaphthalene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 21:44 90-12-0 2-Methylnaphthalene ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 21:44 91-57-6 2-Methylphenol(o-Cresol) ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 21:44 95-48-7 3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 21:44 15831-10-4 Naphthalene ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 21:44 91-20-3 2-Nitroaniline ND ug/L 20.0 3.0 1 06/22/22 11:22 06/22/22 21:44 88-74-4 3-Nitroaniline ND ug/L 20.0 3.8 1 06/22/22 11:22 06/22/22 21:44 99-09-2 IL 4-Nitroaniline ND ug/L 20.0 5.1 1 06/22/22 11:22 06/22/22 21:44 100-01-6 Nitrobenzene ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 21:44 98-95-3 2-Nitrophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 21:44 88-75-5 4-Nitrophenol ND ug/L 50.0 6.6 1 06/22/22 11:22 06/22/22 21:44 100-02-7 N-Nitrosodimethylamine ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 21:44 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 10.0 1.3 1 06/22/22 11:22 06/22/22 21:44 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 3.0 1 06/22/22 11:22 06/22/22 21:44 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 21:44 108-60-1 Pentachlorophenol ND ug/L 20.0 3.8 1 06/22/22 11:22 06/22/22 21:44 87-86-5 Phenanthrene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 21:44 85-01-8 Phenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 21:44 108-95-2 Pyrene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 21:44 129-00-0 1,2,4-Trichlorobenzene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 21:44 120-82-1 2,4,5-Trichlorophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 21:44 95-95-4 2,4,6-Trichlorophenol ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 21:44 88-06-2 Surrogates Nitrobenzene-d5(S) 78 % 10-144 1 06/22/22 11:22 06/22/22 21:44 4165-60-0 2-Fluorobiphenyl(S) 52 % 10-130 1 06/22/22 11:22 06/22/22 21:44 321-60-8 Terphenyl-d14(S) 141 % 34-163 1 06/22/22 11:22 06/22/22 21:44 1718-51-0 Phenol-d6(S) 54 % 10-130 1 06/22/22 11:22 06/22/22 21:44 13127-88-3 2-Fluorophenol(S) 59 % 10-130 1 06/22/22 11:22 06/22/22 21:44 367-12-4 2,4,6-Tribromophenol(S) 119 % 10-144 1 06/22/22 11:22 06/22/22 21:44 118-79-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 18 of 54 Pace Analytical Services,LLC 9800 Kincey Ave. Suite100 aceAnalytical Huntersville,NC 28078078 www.pacelabs.com (704)875-9092 1 ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-4 Lab ID: 92610548004 Collected: 06/17/22 10:05 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method:EPA 8260D Pace Analytical Services-Charlotte Acetone ND ug/L 25.0 5.1 1 06/22/22 13:27 67-64-1 Benzene ND ug/L 1.0 0.34 1 06/22/22 13:27 71-43-2 Bromobenzene ND ug/L 1.0 0.29 1 06/22/22 13:27 108-86-1 Bromochloromethane ND ug/L 1.0 0.47 1 06/22/22 13:27 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/22/22 13:27 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/22/22 13:27 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/22/22 13:27 74-83-9 v2 2-Butanone(MEK) ND ug/L 5.0 4.0 1 06/22/22 13:27 78-93-3 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/22/22 13:27 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/22/22 13:27 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/22/22 13:27 75-00-3 Chloroform 0.83J ug/L 1.0 0.43 1 06/22/22 13:27 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/22/22 13:27 74-87-3 2-Chlorotoluene ND ug/L 1.0 0.32 1 06/22/22 13:27 95-49-8 4-Chlorotoluene ND ug/L 1.0 0.32 1 06/22/22 13:27 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/22/22 13:27 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/22/22 13:27 124-48-1 1,2-Dibromoethane(EDB) ND ug/L 1.0 0.27 1 06/22/22 13:27 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/22/22 13:27 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/22/22 13:27 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 0.34 1 06/22/22 13:27 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/22/22 13:27 106-46-7 Dichlorodifluoromethane ND ug/L 1.0 0.35 1 06/22/22 13:27 75-71-8 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/22/22 13:27 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/22/22 13:27 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/22/22 13:27 75-35-4 cis-1,2-Dichloroethene 2.6 ug/L 1.0 0.38 1 06/22/22 13:27 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 06/22/22 13:27 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 06/22/22 13:27 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.28 1 06/22/22 13:27 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.39 1 06/22/22 13:27 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.43 1 06/22/22 13:27 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.36 1 06/22/22 13:27 10061-01-5 trans-1,3-Dichloropropene ND ug/L 1.0 0.36 1 06/22/22 13:27 10061-02-6 Diisopropyl ether ND ug/L 1.0 0.31 1 06/22/22 13:27 108-20-3 Ethylbenzene ND ug/L 1.0 0.30 1 06/22/22 13:27 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1.5 1 06/22/22 13:27 87-68-3 2-Hexanone ND ug/L 5.0 0.48 1 06/22/22 13:27 591-78-6 p-lsopropyltoluene ND ug/L 1.0 0.41 1 06/22/22 13:27 99-87-6 Methylene Chloride ND ug/L 5.0 2.0 1 06/22/22 13:27 75-09-2 4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 2.7 1 06/22/22 13:27 108-10-1 Methyl-tert-butyl ether ND ug/L 1.0 0.42 1 06/22/22 13:27 1634-04-4 Naphthalene ND ug/L 1.0 0.64 1 06/22/22 13:27 91-20-3 Styrene ND ug/L 1.0 0.29 1 06/22/22 13:27 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.31 1 06/22/22 13:27 630-20-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10AM without the written consent of Pace Analytical Services,LLC. Page 19 of 54 Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite 100 Huntersville,NC 28078 www.pacolabs.com (704)875-9092 i I ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: MW-4 Lab ID: 92610548004 Collected: 06/17/22 10:05 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method:EPA 8260D Pace Analytical Services-Charlotte 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 06/22/22 13:27 79-34-5 Tetrachloroethene 65.6 ug/L 1.0 0.29 1 06/22/22 13:27 127-18-4 Toluene ND ug/L 1.0 0.48 1 06/22/22 13:27 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 0.81 1 06/22/22 13:27 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 0.64 1 06/22/22 13:27 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 06/22/22 13:27 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 06/22/22 13:27 79-00-5 Trichloroethene 1.8 ug/L 1.0 0.38 1 06/22/22 13:27 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 06/22/22 13:27 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 06/22/22 13:27 96-18-4 Vinyl acetate ND ug/L 2.0 1.3 1 06/22/22 13:27 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 06/22/22 13:27 75-01-4 Xylene(Total) ND ug/L 1.0 0.34 1 06/22/22 13:27 1330-20-7 m&p-Xylene ND ug/L 2.0 0.71 1 06/22/22 13:27 179601-23-1 o-Xylene ND ug/L 1.0 0.34 1 06/22/22 13:27 95-47-6 Surrogates 4-Bromofluorobenzene(S) 100 % 70-130 1 06/22/22 13:27 460-00-4 1,2-Dichloroethane-d4(S) 115 % 70-130 1 06/22/22 13:27 17060-07-0 Toluene-d8(S) 100 % 70-130 1 06/22/22 13:27 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 20 of 54 Pace Analytical Services,LLC ® 9800 Kincey Ave. Suite 100 aceAnalytical Huntersville,NC 28078 www.pacalabs.com (704)875-9092 ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: GW-DUP Lab ID: 92610548005 Collected: 06/17/22 00:00 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6020 MET ICPMS Analytical Method:EPA 6020B Preparation Method:EPA 3010A Pace Analytical Services-Asheville Arsenic ND ug/L 1.0 0.087 1 06/18/22 16:52 06/20/22 06:08 7440-38-2 Barium 164 ug/L 1.0 0.21 1 06/18/22 16:52 06/20/22 06:08 7440-39-3 Cadmium 0.069J ug/L 0.20 0.060 1 06/18/22 16:52 06/20/22 06:08 7440-43-9 Chromium 2.3 ug/L 1.0 0.50 1 06/18/22 16:52 06/20/22 06:08 7440-47-3 Lead 0.34J ug/L 1.0 0.077 1 06/18/22 16:52 06/20/22 06:08 7439-92-1 Selenium ND ug/L 2.0 0.072 1 06/18/22 16:52 06/20/22 06:08 7782-49-2 Silver ND ug/L 0.40 0.070 1 06/18/22 16:52 06/20/22 06:08 7440-22-4 7470 Mercury Analytical Method:EPA 7470A Preparation Method:EPA 7470A Pace Analytical Services-Asheville Mercury ND ug/L 0.20 0.12 1 06/21/22 14:14 06/23/22 12:41 7439-97-6 8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C Pace Analytical Services-Charlotte Acenaphthene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 22:09 83-32-9 Acenaphthylene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 22:09 208-96-8 Aniline ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 22:09 62-53-3 Anthracene ND ug/L 10.0 2.3 1 06/22/22 11:22 06/22/22 22:09 120-12-7 Benzo(a)anthracene ND ug/L 10.0 2.7 1 06/22/22 11:22 06/22/22 22:09 56-55-3 Benzo(a)pyrene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 22:09 50-32-8 Benzo(b)fluoranthene ND ug/L 10.0 2.6 1 06/22/22 11:22 06/22/22 22:09 205-99-2 Benzo(g,h,i)perylene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 22:09 191-24-2 Benzo(k)fluoranthene ND ug/L 10.0 2.7 1 06/22/22 11:22 06/22/22 22:09 207-08-9 Benzoic Acid ND ug/L 50.0 22.0 1 06/22/22 11:22 06/22/22 22:09 65-85-0 Benzyl alcohol ND ug/L 20.0 2.9 1 06/22/22 11:22 06/22/22 22:09 100-51-6 4-Bromophenylphenyl ether ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 22:09 101-55-3 Butylbenzylphthalate ND ug/L 10.0 3.1 1 06/22/22 11:22 06/22/22 22:09 85-68-7 4-Chloro-3-methylphenol ND ug/L 10.0 3.3 1 06/22/22 11:22 06/22/22 22:09 59-50-7 4-Chloroaniline ND ug/L 20.0 3.6 1 06/22/22 11:22 06/22/22 22:09 106-47-8 bis(2-Chloroethoxy)methane ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 22:09 111-91-1 bis(2-Chloroethyl)ether ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 22:09 111-44-4 2-Chloronaphthalene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 22:09 91-58-7 2-Chlorophenol ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 22:09 95-57-8 4-Chlorophenylphenyl ether ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 22:09 7005-72-3 II Chrysene ND ug/L 10.0 2.8 1 06/22/22 11:22 06/22/22 22:09 218-01-9 Dibenz(a,h)anthracene ND ug/L 10.0 3.0 1 06/22/22 11:22 06/22/22 22:09 53-70-3 Dibenzofuran ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 22:09 132-64-9 1,2-Dichlorobenzene ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 22:09 95-50-1 1,3-Dichlorobenzene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 22:09 541-73-1 1,4-Dichlorobenzene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 22:09 106-46-7 3,3'-Dichlorobenzidine ND ug/L 20.0 8.1 1 06/22/22 11:22 06/22/22 22:09 91-94-1 2,4-Dichlorophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 22:09 120-83-2 Diethylphthalate ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 22:09 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 22:09 105-67-9 Dimethylphthalate ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 22:09 131-11-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 21 of 54 Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite 100 Huntersville,NC 28078078 www.pacelabs.com (704)875-9092 ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: GW-DUP Lab ID: 92610548005 Collected: 06/17/22 00:00 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8270E RVE Analytical Method:EPA 8270E Preparation Method:EPA 3510C Pace Analytical Services-Charlotte Di-n-butylphthalate ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 22:09 84-74-2 4,6-Dinitro-2-methylphenol ND ug/L 20.0 7.8 1 06/22/22 11:22 06/22/22 22:09 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 26.0 1 06/22/22 11:22 06/22/22 22:09 51-28-5 2,4-Dinitrotoluene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 22:09 121-14-2 2,6-Dinitrotoluene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 22:09 606-20-2 Di-n-octylphthalate ND ug/L 10.0 3.9 1 06/22/22 11:22 06/22/22 22:09 117-84-0 bis(2-Ethylhexyl)phthalate ND ug/L 6.0 3.7 1 06/22/22 11:22 06/22/22 22:09 117-81-7 Fluoranthene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 22:09 206-44-0 Fluorene ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 22:09 86-73-7 Hexachloro-1,3-butadiene ND ug/L 10.0 1.8 1 06/22/22 11:22 06/22/22 22:09 87-68-3 Hexachlorobenzene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 22:09 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 22:09 77-47-4 v1 Hexachloroethane ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 22:09 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 10.0 2.9 1 06/22/22 11:22 06/22/22 22:09 193-39-5 Isophorone ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 22:09 78-59-1 1-Methylnaphthalene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 22:09 90-12-0 2-Methylnaphthalene ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 22:09 91-57-6 2-Methylphenol(o-Cresol) ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 22:09 95-48-7 3&4-Methylphenol(m&p Cresol) ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 22:09 15831-10-4 Naphthalene ND ug/L 10.0 2.1 1 06/22/22 11:22 06/22/22 22:09 91-20-3 2-Nitroaniline ND ug/L 20.0 3.0 1 06/22/22 11:22 06/22/22 22:09 88-74-4 3-Nitroaniline ND ug/L 20.0 3.8 1 06/22/22 11:22 06/22/22 22:09 99-09-2 IL 4-Nitroaniline ND ug/L 20.0 5.1 1 06/22/22 11:22 06/22/22 22:09 100-01-6 Nitrobenzene ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 22:09 98-95-3 2-Nitrophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 22:09 88-75-5 4-Nitrophenol ND ug/L 50.0 6.6 1 06/22/22 11:22 06/22/22 22:09 100-02-7 N-Nitrosodimethylamine ND ug/L 10.0 1.9 1 06/22/22 11:22 06/22/22 22:09 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 10.0 1.3 1 06/22/22 11:22 06/22/22 22:09 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 3.0 1 06/22/22 11:22 06/22/22 22:09 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 10.0 1.2 1 06/22/22 11:22 06/22/22 22:09 108-60-1 Pentachlorophenol ND ug/L 20.0 3.8 1 06/22/22 11:22 06/22/22 22:09 87-86-5 Phenanthrene ND ug/L 10.0 2.0 1 06/22/22 11:22 06/22/22 22:09 85-01-8 Phenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 22:09 108-95-2 Pyrene ND ug/L 10.0 2.2 1 06/22/22 11:22 06/22/22 22:09 129-00-0 1,2,4-Trichlorobenzene ND ug/L 10.0 1.7 1 06/22/22 11:22 06/22/22 22:09 120-82-1 2,4,5-Trichlorophenol ND ug/L 10.0 1.4 1 06/22/22 11:22 06/22/22 22:09 95-95-4 2,4,6-Trichlorophenol ND ug/L 10.0 1.6 1 06/22/22 11:22 06/22/22 22:09 88-06-2 Surrogates Nitrobenzene-d5(S) 58 % 10-144 1 06/22/22 11:22 06/22/22 22:09 4165-60-0 2-Fluorobiphenyl(S) 45 % 10-130 1 06/22/22 11:22 06/22/22 22:09 321-60-8 Terphenyl-d14(S) 140 % 34-163 1 06/22/22 11:22 06/22/22 22:09 1718-51-0 Phenol-d6(S) 34 % 10-130 1 06/22/22 11:22 06/22/22 22:09 13127-88-3 2-Fluorophenol(S) 40 % 10-130 1 06/22/22 11:22 06/22/22 22:09 367-12-4 2,4,6-Tribromophenol(S) 102 % 10-144 1 06/22/22 11:22 06/22/22 22:09 118-79-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 22 of 54 Pace Analytical Services,LLC aceAnalytical® 9800 KinceyPve. Suite 100 Huntersville,NC 28078 www.pacalabs.eom (704)875-9092 I i ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: GW-DUP Lab ID: 92610548005 Collected: 06/17/22 00:00 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method:EPA 8260D Pace Analytical Services-Charlotte Acetone ND ug/L 25.0 5.1 1 06/22/22 11:37 67-64-1 Benzene ND ug/L 1.0 0.34 1 06/22/22 11:37 71-43-2 Bromobenzene ND ug/L 1.0 0.29 1 06/22/22 11:37 108-86-1 Bromochloromethane ND ug/L 1.0 0.47 1 06/22/22 11:37 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/22/22 11:37 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/22/22 11:37 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/22/22 11:37 74-83-9 v2 2-Butanone(MEK) ND ug/L 5.0 4.0 1 06/22/22 11:37 78-93-3 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/22/22 11:37 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/22/22 11:37 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/22/22 11:37 75-00-3 Chloroform 1.7 ug/L 1.0 0.43 1 06/22/22 11:37 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/22/22 11:37 74-87-3 2-Chlorotoluene ND ug/L 1.0 0.32 1 06/22/22 11:37 95-49-8 4-Chlorotoluene ND ug/L 1.0 0.32 1 06/22/22 11:37 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/22/22 11:37 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/22/22 11:37 124-48-1 1,2-Dibromoethane(EDB) ND ug/L 1.0 0.27 1 06/22/22 11:37 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/22/22 11:37 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/22/22 11:37 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 0.34 1 06/22/22 11:37 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/22/22 11:37 106-46-7 I Dichlorodifluoromethane ND ug/L 1.0 0.35 1 06/22/22 11:37 75-71-8 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/22/22 11:37 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/22/22 11:37 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/22/22 11:37 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 06/22/22 11:37 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 06/22/22 11:37 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 06/22/22 11:37 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.28 1 06/22/22 11:37 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.39 1 06/22/22 11:37 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.43 1 06/22/22 11:37 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.36 1 06/22/22 11:37 10061-01-5 trans-1,3-Dichloropropene ND ug/L 1.0 0.36 1 06/22/22 11:37 10061-02-6 Diisopropyl ether ND ug/L 1.0 0.31 1 06/22/22 11:37 108-20-3 Ethylbenzene ND ug/L 1.0 0.30 1 06/22/22 11:37 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1.5 1 06/22/22 11:37 87-68-3 2-Hexanone ND ug/L 5.0 0.48 1 06/22/22 11:37 591-78-6 p-Isopropyltoluene ND ug/L 1.0 0.41 1 06/22/22 11:37 99-87-6 Methylene Chloride ND ug/L 5.0 2.0 1 06/22/22 11:37 75-09-2 4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 2.7 1 06/22/22 11:37 108-10-1 Methyl-tert-butyl ether ND ug/L 1.0 0.42 1 06/22/22 11:37 1634-04-4 Naphthalene ND ug/L 1.0 0.64 1 06/22/22 11:37 91-20-3 Styrene ND ug/L 1.0 0.29 1 06/22/22 11:37 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.31 1 06/22/22 11:37 630-20-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, I Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 23 of 54 Pace Analytical Services,LLC cs 9800 Kincey Ave. Suite100 aceAnalytical Huntersville,NC 28078078 www.pacelabs.com (704)875-9092 I ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: GW-DUP Lab ID: 92610548005 Collected: 06/17/22 00:00 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method:EPA 8260D Pace Analytical Services-Charlotte 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 06/22/22 11:37 79-34-5 Tetrachloroethene ND ug/L 1.0 0.29 1 06/22/22 11:37 127-18-4 Toluene ND ug/L 1.0 0.48 1 06/22/22 11:37 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 0.81 1 06/22/22 11:37 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 0.64 1 06/22/22 11:37 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 06/22/22 11:37 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 06/22/22 11:37 79-00-5 Trichloroethene ND ug/L 1.0 0.38 1 06/22/22 11:37 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 06/22/22 11:37 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 06/22/22 11:37 96-18-4 Vinyl acetate ND ug/L 2.0 1.3 1 06/22/22 11:37 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 06/22/22 11:37 75-01-4 Xylene(Total) ND ug/L 1.0 0.34 1 06/22/22 11:37 1330-20-7 m&p-Xylene ND ug/L 2.0 0.71 1 06/22/22 11:37 179601-23-1 o-Xylene ND ug/L 1.0 0.34 1 06/22/22 11:37 95-47-6 Surrogates 4-Bromofluorobenzene(S) 103 % 70-130 1 06/22/22 11:37 460-00-4 1,2-Dichloroethane-d4(S) 115 % 70-130 1 06/22/22 11:37 17060-07-0 Toluene-d8(S) 100 % 70-130 1 06/22/22 11:37 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 24 of 54 Pace Analytical Services,LLC 9800 Kincey Ave. Suite 100 aceAnalytical Huntersville,NC 28078 www.pacalabs.com (704)875-9092 I I ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: Trip Blank Lab ID: 92610548006 Collected: 06/17/22 00:00 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method:EPA 8260D Pace Analytical Services-Charlotte Acetone ND ug/L 25.0 5.1 1 06/21/22 10:33 67-64-1 Benzene ND ug/L 1.0 0.34 1 06/21/22 10:33 71-43-2 Bromobenzene ND ug/L 1.0 0.29 1 06/21/22 10:33 108-86-1 Bromochloromethane ND ug/L 1.0 0.47 1 06/21/22 10:33 74-97-5 Bromodichloromethane ND ug/L 1.0 0.31 1 06/21/22 10:33 75-27-4 Bromoform ND ug/L 1.0 0.34 1 06/21/22 10:33 75-25-2 Bromomethane ND ug/L 2.0 1.7 1 06/21/22 10:33 74-83-9 v2 2-Butanone(MEK) ND ug/L 5.0 4.0 1 06/21/22 10:33 78-93-3 Carbon tetrachloride ND ug/L 1.0 0.33 1 06/21/22 10:33 56-23-5 Chlorobenzene ND ug/L 1.0 0.28 1 06/21/22 10:33 108-90-7 Chloroethane ND ug/L 1.0 0.65 1 06/21/22 10:33 75-00-3 Chloroform ND ug/L 1.0 0.43 1 06/21/22 10:33 67-66-3 Chloromethane ND ug/L 1.0 0.54 1 06/21/22 10:33 74-87-3 2-Chlorotoluene ND ug/L 1.0 0.32 1 06/21/22 10:33 95-49-8 4-Chlorotoluene ND ug/L 1.0 0.32 1 06/21/22 10:33 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.34 1 06/21/22 10:33 96-12-8 Dibromochloromethane ND ug/L 1.0 0.36 1 06/21/22 10:33 124-48-1 1,2-Dibromoethane(EDB) ND ug/L 1.0 0.27 1 06/21/22 10:33 106-93-4 Dibromomethane ND ug/L 1.0 0.39 1 06/21/22 10:33 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 0.34 1 06/21/22 10:33 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 0.34 1 06/21/22 10:33 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 0.33 1 06/21/22 10:33 106-46-7 Dichlorodifluoromethane ND ug/L 1.0 0.35 1 06/21/22 10:33 75-71-8 1,1-Dichloroethane ND ug/L 1.0 0.37 1 06/21/22 10:33 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.32 1 06/21/22 10:33 107-06-2 1,1-Dichloroethene ND ug/L 1.0 0.35 1 06/21/22 10:33 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 0.38 1 06/21/22 10:33 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 0.40 1 06/21/22 10:33 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.36 1 06/21/22 10:33 78-87-5 1,3-Dichloropropane ND ug/L 1.0 0.28 1 06/21/22 10:33 142-28-9 2,2-Dichloropropane ND ug/L 1.0 0.39 1 06/21/22 10:33 594-20-7 1,1-Dichloropropene ND ug/L 1.0 0.43 1 06/21/22 10:33 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 0.36 1 06/21/22 10:33 10061-01-5 trans-1,3-Dichloropropene ND ug/L 1.0 0.36 1 06/21/22 10:33 10061-02-6 Diisopropyl ether ND ug/L 1.0 0.31 1 06/21/22 10:33 108-20-3 Ethylbenzene ND ug/L 1.0 0.30 1 06/21/22 10:33 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1.5 1 06/21/22 10:33 87-68-3 2-Hexanone ND ug/L 5.0 0.48 1 06/21/22 10:33 591-78-6 p-lsopropyltoluene ND ug/L 1.0 0.41 1 06/21/22 10:33 99-87-6 Methylene Chloride ND ug/L 5.0 2.0 1 06/21/22 10:33 75-09-2 4-Methyl-2-pentanone(MIBK) ND ug/L 5.0 2.7 1 06/21/22 10:33 108-10-1 Methyl-tert-butyl ether ND ug/L 1.0 0.42 1 06/21/22 10:33 1634-04-4 Naphthalene ND ug/L 1.0 0.64 1 06/21/22 10:33 91-20-3 Styrene ND ug/L 1.0 0.29 1 06/21/22 10:33 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.31 1 06/21/22 10:33 630-20-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 25 of 54 Pace Analytical Services,LLC s 9800 Kincey Ave. Suite 100 aceAnalytical Huntersville,NC 28078 www.pacelabs.com (704)875-9092 ANALYTICAL RESULTS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Sample: Trip Blank Lab ID: 92610548006 Collected: 06/17/22 00:00 Received: 06/17/22 15:05 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method:EPA 8260D Pace Analytical Services-Charlotte 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 06/21/22 10:33 79-34-5 Tetrachloroethene ND ug/L 1.0 0.29 1 06/21/22 10:33 127-18-4 Toluene ND ug/L 1.0 0.48 1 06/21/22 10:33 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 0.81 1 06/21/22 10:33 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 0.64 1 06/21/22 10:33 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 0.33 1 06/21/22 10:33 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.32 1 06/21/22 10:33 79-00-5 Trichloroethene ND ug/L 1.0 0.38 1 06/21/22 10:33 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.30 1 06/21/22 10:33 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.26 1 06/21/22 10:33 96-18-4 Vinyl acetate ND ug/L 2.0 1.3 1 06/21/22 10:33 108-05-4 Vinyl chloride ND ug/L 1.0 0.39 1 06/21/22 10:33 75-01-4 Xylene(Total) ND ug/L 1.0 0.34 1 06/21/22 10:33 1330-20-7 m&p-Xylene ND ug/L 2.0 0.71 1 06/21/22 10:33 179601-23-1 o-Xylene ND ug/L 1.0 0.34 1 06/21/22 10:33 95-47-6 Surrogates 4-Bromofluorobenzene(S) 99 % 70-130 1 06/21/22 10:33 460-00-4 1,2-Dichloroethane-d4(S) 113 % 70-130 1 06/21/22 10:33 17060-07-0 Toluene-d8(S) 100 % 70-130 1 06/21/22 10:33 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 26 of 54 1 aceAClalytical Pace Analytical Services,LLC 9800 Kincey Ave. Suite 100 Huntersville,NC 00 www.pacdaba.com (704)875-9092 i i QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 QC Batch: 705899 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Laboratory: Pace Analytical Services-Asheville Associated Lab Samples: 92610548001,92610548002,92610548003,92610548004,92610548005 METHOD BLANK: 3682851 Matrix: Water Associated Lab Samples: 92610548001,92610548002,92610548003,92610548004,92610548005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.12 06/23/22 11:41 LABORATORY CONTROL SAMPLE: 3682852 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Mercury ug/L 2.5 3.0 120 80-120 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3682853 3682854 MS MSD 92610311001 Spike Spike MS MSD MS MSD %Rec Max Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.8 2.9 113 115 75-125 2 25 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 27 of 54 Pace Analytical Services,LLC e aceAnalytical 9800 Kincey Ave. Suite 100 Huntersville,NC 28078 www.pacelahs.com (704)875-9092 QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 QC Batch: 705477 Analysis Method: EPA 6020E QC Batch Method: EPA 3010A Analysis Description: 6020 MET Laboratory: Pace Analytical Services-Asheville Associated Lab Samples: 92610548001,92610548002,92610548003,92610548004,92610548005 METHOD BLANK: 3681143 Matrix: Water Associated Lab Samples: 92610548001,92610548002,92610548003,92610548004,92610548005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Arsenic ug/L ND 1.0 0.087 06/20/22 05:22 Barium ug/L ND 1.0 0.21 06/20/22 05:22 Cadmium ug/L ND 0.20 0.060 06/20/22 05:22 Chromium ug/L ND 1.0 0.50 06/20/22 05:22 Lead ug/L ND 1.0 0.077 06/20/22 05:22 Selenium ug/L ND 2.0 0.072 06/20/22 05:22 Silver ug/L ND 0.40 0.070 06/20/22 05:22 LABORATORY CONTROL SAMPLE: 3681144 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Arsenic ug/L 50 48.0 96 80-120 Barium ug/L 50 50.1 100 80-120 Cadmium ug/L 50 50.8 102 80-120 Chromium ug/L 50 51.4 103 80-120 Lead ug/L 50 51.9 104 80-120 Selenium ug/L 50 49.0 98 80-120 Silver ug/L 25 25.5 102 80-120 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3681145 3681146 MS MSD 92610548001 Spike Spike MS MSD MS MSD %Rec Max Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual Arsenic ug/L ND 50 50 48.6 48.1 97 96 75-125 1 20 Barium ug/L 21.3 50 50 73.6 72.5 105 103 75-125 1 20 Cadmium ug/L ND 50 50 51.2 51.1 102 102 75-125 0 20 Chromium ug/L 1.3 50 50 53.7 53.0 105 103 75-125 1 20 Lead ug/L ND 50 50 52.9 52.8 106 106 75-125 0 20 Selenium ug/L 0.10J 50 50 49.2 49.2 98 98 75-125 0 20 Silver ug/L ND 25 25 25.3 25.3 101 101 75-125 0 20 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 28 of 54 Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite 100 Huntersville,NC 28078 078 www.paeNabs.com (704)875-9092 QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 QC Batch: 705694 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Laboratory: Pace Analytical Services-Charlotte Associated Lab Samples: 92610548006 METHOD BLANK: 3682156 Matrix: Water Associated Lab Samples: 92610548006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 06/21/22 03:12 1 1,1,1-Trichloroethane ug/L ND 1.0 0.33 06/21/22 03:12 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 06/21/22 03:12 1,1,2-Trichloroethane ug/L ND 1.0 0.32 06/21/22 03:12 1,1-Dichloroethane ug/L ND 1.0 0.37 06/21/22 03:12 1,1-Dichloroethene ug/L ND 1.0 0.35 06/21/22 03:12 1,1-Dichloropropene ug/L ND 1.0 0.43 06/21/22 03:12 1,2,3-Trichlorobenzene ug/L ND 1.0 0.81 06/21/22 03:12 1,2,3-Trichloropropane ug/L ND 1.0 0.26 06/21/22 03:12 1,2,4-Trichlorobenzene ug/L ND 1.0 0.64 06/21/22 03:12 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 06/21/22 03:12 1,2-Dibromoethane(EDB) ug/L ND 1.0 0.27 06/21/22 03:12 1,2-Dichlorobenzene ug/L ND 1.0 0.34 06/21/22 03:12 1,2-Dichloroethane ug/L ND 1.0 0.32 06/21/22 03:12 1,2-Dichloropropane ug/L ND 1.0 0.36 06/21/22 03:12 1,3-Dichlorobenzene ug/L ND 1.0 0.34 06/21/22 03:12 1,3-Dichloropropane ug/L ND 1.0 0.28 06/21/22 03:12 1,4-Dichlorobenzene ug/L ND 1.0 0.33 06/21/22 03:12 2,2-Dichloropropane ug/L ND 1.0 0.39 06/21/22 03:12 2-Butanone(MEK) ug/L ND 5.0 4.0 06/21/22 03:12 2-Chlorotoluene ug/L ND 1.0 0.32 06/21/22 03:12 2-Hexanone ug/L ND 5.0 0.48 06/21/22 03:12 4-Chlorotoluene ug/L ND 1.0 0.32 06/21/22 03:12 4-Methyl-2-pentanone(MIBK) ug/L ND 5.0 2.7 06/21/22 03:12 Acetone ug/L ND 25.0 5.1 06/21/22 03:12 Benzene ug/L ND 1.0 0.34 06/21/22 03:12 Bromobenzene ug/L ND 1.0 0.29 06/21/22 03:12 Bromochloromethane ug/L ND 1.0 0.47 06/21/22 03:12 Bromodichloromethane ug/L ND 1.0 0.31 06/21/22 03:12 Bromoform ug/L ND 1.0 0.34 06/21/22 03:12 Bromomethane ug/L ND 2.0 1.7 06/21/22 03:12 v2 Carbon tetrachloride ug/L ND 1.0 0.33 06/21/22 03:12 Chlorobenzene ug/L ND 1.0 0.28 06/21/22 03:12 Chloroethane ug/L ND 1.0 0.65 06/21/22 03:12 Chloroform ug/L ND 1.0 0.43 06/21/22 03:12 Chloromethane ug/L ND 1.0 0.54 06/21/22 03:12 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 06/21/22 03:12 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 06/21/22 03:12 Dibromochloromethane ug/L ND 1.0 0.36 06/21/22 03:12 Dibromomethane ug/L ND 1.0 0.39 06/21/22 03:12 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 29 of 54 Pace Analytical Services,LLC s aceAnalytical 9800 Kincey Ave. Suite100 Huntersville,NC 28078078 www.pacelabs.com (704)875-9092 I QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 METHOD BLANK: 3682156 Matrix: Water Associated Lab Samples: 92610548006 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Dichlorodifluoromethane ug/L ND 1.0 0.35 06/21/22 03:12 Diisopropyl ether ug/L ND 1.0 0.31 06/21/22 03:12 Ethylbenzene ug/L ND 1.0 0.30 06/21/22 03:12 Hexachloro-1,3-butadiene ug/L ND 2.0 1.5 06/21/22 03:12 m&p-Xylene ug/L ND 2.0 0.71 06/21/22 03:12 Methyl-tert-butyl ether ug/L ND 1.0 0.42 06/21/22 03:12 Methylene Chloride ug/L ND 5.0 2.0 06/21/22 03:12 Naphthalene ug/L ND 1.0 0.64 06/21/22 03:12 o-Xylene ug/L ND 1.0 0.34 06/21/22 03:12 p-Isopropyltoluene ug/L ND 1.0 0.41 06/21/22 03:12 Styrene ug/L ND 1.0 0.29 06/21/22 03:12 Tetrachloroethene ug/L ND 1.0 0.29 06/21/22 03:12 Toluene ug/L ND 1.0 0.48 06/21/22 03:12 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 06/21/22 03:12 trans-1,3-Dichloropropene ug/L ND 1.0 0.36 06/21/22 03:12 Trichloroethene ug/L ND 1.0 0.38 06/21/22 03:12 Trichlorofluoromethane ug/L ND 1.0 0.30 06/21/22 03:12 Vinyl acetate ug/L ND 2.0 1.3 06/21/22 03:12 Vinyl chloride ug/L ND 1.0 0.39 06/21/22 03:12 Xylene(Total) ug/L ND 1.0 0.34 06/21/22 03:12 1,2-Dichloroethane-d4(S) % 110 70-130 06/21/22 03:12 4-Bromofluorobenzene(S) % 103 70-130 06/21/22 03:12 Toluene-d8(S) % 100 70-130 06/21/22 03:12 LABORATORY CONTROL SAMPLE: 3682157 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 51.1 102 70-130 1,1,1-Trichloroethane ug/L 50 51.9 104 70-130 1,1,2,2-Tetrachloroethane ug/L 50 48.2 96 70-130 1,1,2-Trichloroethane ug/L 50 49.8 100 70-130 1,1-Dichloroethane ug/L 50 52.7 105 70-130 1,1-Dichloroethene ug/L 50 53.3 107 70-132 1,1-Dichloropropene ug/L 50 55.3 111 70-131 1,2,3-Trichlorobenzene ug/L 50 45.7 91 70-134 1,2,3-Trichloropropane ug/L 50 48.9 98 70-130 1,2,4-Trichlorobenzene ug/L 50 47.6 95 70-130 1,2-Dibromo-3-chloropropane ug/L 50 47.7 95 70-132 1,2-Dibromoethane(EDB) ug/L 50 50.3 101 70-130 1,2-Dichlorobenzene ug/L 50 48.2 96 70-130 1,2-Dichloroethane ug/L 50 51.7 103 70-130 1,2-Dichloropropane ug/L 50 51.3 103 70-130 1,3-Dichlorobenzene ug/L 50 47.6 95 70-130 1,3-Dichloropropane ug/L 50 49.8 100 70-130 Results presented on this page are in the units indicated by the"units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 30 of 54 Pace Analytical Services,LLC 9800 Kincey Ave. Suite 100 aceAnalytical Huntersville,NC 28078 www.pacelabs.com (704)875-9092 I QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 LABORATORY CONTROL SAMPLE: 3682157 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers 1,4-Dichlorobenzene ug/L 50 47.3 95 70-130 2,2-Dichloropropane ug/L 50 48.8 98 70-130 2-Butanone(MEK) ug/L 100 112 112 70-133 2-Chlorotoluene ug/L 50 48.9 98 70-130 2-Hexanone ug/L 100 102 102 70-130 4-Chlorotoluene ug/L 50 48.9 98 70-130 4-Methyl-2-pentanone(MIBK) ug/L 100 100 100 70-130 Acetone ug/L 100 100 100 70-144 Benzene ug/L 50 47.6 95 70-130 Bromobenzene ug/L 50 48.3 97 70-130 Bromochloromethane ug/L 50 53.7 107 70-130 Bromodichloromethane ug/L 50 50.9 102 70-130 Bromoform ug/L 50 52.0 104 70-131 Bromomethane ug/L 50 42.1 84 30-177 v3 Carbon tetrachloride ug/L 50 49.1 98 70-130 Chlorobenzene ug/L 50 48.7 97 70-130 Chloroethane ug/L 50 49.4 99 46-131 Chloroform ug/L 50 52.4 105 70-130 Chloromethane ug/L 50 53.8 108 49-130 cis-1,2-Dichloroethene ug/L 50 53.7 107 70-130 cis-1,3-Dichloropropene ug/L 50 51.8 104 70-130 Dibromochloromethane ug/L 50 51.0 102 70-130 Dibromomethane ug/L 50 48.4 97 70-130 Dichlorodifluoromethane ug/L 50 62.7 125 52-134 Diisopropyl ether ug/L 50 56.0 112 70-131 Ethylbenzene ug/L 50 49.3 99 70-130 Hexachloro-1,3-butadiene ug/L 50 45.4 91 70-131 m&p-Xylene ug/L 100 99.4 99 70-130 Methyl-tert-butyl ether ug/L 50 53.3 107 70-130 I Methylene Chloride ug/L 50 48.1 96 68-130 Naphthalene ug/L 50 50.4 101 70-133 o-Xylene ug/L 50 50.1 100 70-130 p-lsopropyltoluene ug/L 50 51.6 103 70-130 Styrene ug/L 50 48.5 97 70-130 Tetrachloroethene ug/L 50 46.9 94 70-130 Toluene ug/L 50 46.7 93 70-130 trans-1,2-Dichloroethene ug/L 50 54.9 110 70-130 trans-1,3-Dichloropropene ug/L 50 51.9 104 70-130 Trichloroethene ug/L 50 49.0 98 70-130 Trichlorofluoromethane ug/L 50 46.8 94 61-130 Vinyl acetate ug/L 100 114 114 70-140 Vinyl chloride ug/L 50 56.9 114 59-142 Xylene(Total) ug/L 150 149 100 70-130 1,2-Dichloroethane-d4(S) % 110 70-130 4-Bromofluorobenzene(S) % 103 70-130 Toluene-d8(S) % 100 70-130 Results presented on this page are in the units indicated by the"units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 31 of 54 Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite100 Huntersville,NC 28078078 www.pacelabs.com (704)875-9092 i QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3682158 3682159 MS MSD 92610489001 Spike Spike MS MSD MS MSD %Rec Max Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 25.5 23.6 128 118 70-135 8 30 1,1,1-Trichloroethane ug/L ND 20 20 26.9 24.7 134 124 70-148 8 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 24.5 22.3 122 112 70-131 9 30 1,1,2-Trichloroethane ug/L ND 20 20 24.4 22.7 122 113 70-136 7 30 1,1-Dichloroethane ug/L ND 20 20 27.0 24.7 135 124 70-147 9 30 1,1-Dichloroethene ug/L ND 20 20 27.7 25.2 139 126 70-158 9 30 1,1-Dichloropropene ug/L ND 20 20 28.6 26.3 143 131 70-149 8 30 1,2,3-Trichlorobenzene ug/L ND 20 20 24.0 22.4 120 112 68-140 7 30 1,2,3-Trichloropropane ug/L ND 20 20 23.8 22.2 119 111 67-137 7 30 1,2,4-Trichlorobenzene ug/L ND 20 20 24.7 22.3 123 112 70-139 10 30 1,2-Dibromo-3- ug/L ND 20 20 23.6 21.2 118 106 69-136 11 30 chloropropane 1,2-Dibromoethane(EDB) ug/L ND 20 20 25.2 22.9 126 115 70-137 9 30 1,2-Dichlorobenzene ug/L ND 20 20 25.0 22.7 125 114 70-133 10 30 1,2-Dichloroethane ug/L ND 20 20 25.9 23.9 129 120 67-138 8 30 1,2-Dichloropropane ug/L ND 20 20 25.9 23.9 129 120 70-138 8 30 1,3-Dichlorobenzene ug/L ND 20 20 25.2 22.9 126 114 70-133 10 30 1,3-Dichloropropane ug/L ND 20 20 25.2 23.0 126 115 70-136 9 30 1,4-Dichlorobenzene ug/L ND 20 20 24.2 22.2 121 111 70-133 9 30 2,2-Dichloropropane ug/L ND 20 20 26.8 24.8 134 124 52-155 8 30 2-Butanone(MEK) ug/L ND 40 40 54.7 51.0 137 128 61-147 7 30 2-Chlorotoluene ug/L ND 20 20 26.1 23.6 130 118 70-141 10 30 2-Hexanone ug/L ND 40 40 51.3 47.0 128 118 67-139 9 30 4-Chlorotoluene ug/L ND 20 20 25.9 23.6 129 118 70-135 9 30 4-Methyl-2-pentanone ug/L ND 40 40 48.6 45.1 122 113 67-136 8 30 (MIBK) Acetone ug/L ND 40 40 47.8 44.6 120 112 55-159 7 30 Benzene ug/L 0.43J 20 20 25.1 23.3 124 115 67-150 7 30 Bromobenzene ug/L ND 20 20 24.7 22.7 124 114 70-134 8 30 Bromochloromethane ug/L ND 20 20 26.2 24.3 131 121 70-146 8 30 Bromodichloromethane ug/L ND 20 20 25.0 23.1 125 116 70-138 8 30 Bromoform ug/L ND 20 20 24.4 21.9 122 110 57-138 11 30 Bromomethane ug/L ND 20 20 20.8 18.9 104 94 10-200 10 30 v3 Carbon tetrachloride ug/L ND 20 20 25.3 23.6 126 118 70-147 7 30 Chlorobenzene ug/L ND 20 20 25.3 23.2 126 116 70-137 9 30 Chloroethane ug/L ND 20 20 28.1 25.8 140 129 51-166 8 30 Chloroform ug/L ND 20 20 26.7 24.7 134 123 70-144 8 30 Chloromethane ug/L ND 20 20 25.5 23.7 128 118 24-161 7 30 cis-1,2-Dichloroethene ug/L 0.64J 20 20 27.8 25.6 136 125 67-148 8 30 cis-1,3-Dichloropropene ug/L ND 20 20 25.6 23.4 128 117 70-142 9 30 Dibromochloromethane ug/L ND 20 20 24.7 22.7 123 114 68-138 8 30 Dibromomethane ug/L ND 20 20 23.5 22.0 118 110 70-134 7 30 Dichlorodifluoromethane ug/L ND 20 20 26.5 24.1 133 121 43-155 9 30 Diisopropyl ether ug/L ND 20 20 27.6 25.5 138 128 65-146 8 30 Ethylbenzene ug/L 0.33J 20 20 26.0 23.7 128 117 68-143 9 30 Hexachloro-1,3-butadiene ug/L ND 20 20 25.4 23.0 127 115 62-151 10 30 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 32 of 54 aceAnalyticalPace Analytical Services,LLC 9800 Kincey Ave. Suite 100 Huntersville,NC 28078 www.pacelaEs.eom (704)875-9092 Ii I QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3682158 3682159 MS MSD 92610489001 Spike Spike MS MSD MS MSD %Rec Max Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual m&p-Xylene ug/L ND 40 40 52.6 48.3 132 121 53-157 9 30 Methyl-tert-butyl ether ug/L ND 20 20 26.3 24.2 132 121 59-156 8 30 Methylene Chloride ug/L ND 20 20 23.9 21.9 119 110 64-148 9 30 Naphthalene ug/L 35.1 20 20 60.7 58.3 128 116 57-150 4 30 o-Xylene ug/L 1.7 20 20 27.9 25.1 131 117 68-143 11 30 p-lsopropyltoluene ug/L ND 20 20 27.7 24.9 138 125 70-141 10 30 Styrene ug/L ND 20 20 24.6 22.4 123 112 70-136 10 30 Tetrachloroethene ug/L 1.8 20 20 25.8 23.8 120 110 70-139 8 30 Toluene ug/L ND 20 20 23.7 22.0 119 110 47-157 8 30 trans-1,2-Dichloroethene ug/L ND 20 20 28.0 25.8 140 129 70-149 8 30 trans-1,3-Dichloropropene ug/L ND 20 20 25.3 23.6 127 118 70-138 7 30 Trichloroethene ug/L 0.54J 20 20 25.8 23.8 126 116 70-149 8 30 Trichlorofluoromethane ug/L ND 20 20 24.6 22.6 123 113 61-154 9 30 Vinyl acetate ug/L ND 40 40 53.5 49.3 134 123 48-156 8 30 Vinyl chloride ug/L ND 20 20 28.1 25.8 140 129 55-172 8 30 Xylene(Total) ug/L 1.7 60 60 80.6 73.5 132 120 66-145 9 30 1,2-Dichloroethane-d4(S) % 106 107 70-130 4-Bromofluorobenzene(S) % 102 103 70-130 Toluene-d8(S) % 99 99 70-130 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 33 of 54 Pace Analytical Services,LLC s aceA(lalytical 9800 Kincey Ave. Suite 100 Huntersville,NC 28078 www.pacelabs.com (704)875-9092 i QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 QC Batch: 706000 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Laboratory: Pace Analytical Services-Charlotte Associated Lab Samples: 92610548002,92610548003,92610548004,92610548005 METHOD BLANK: 3683525 Matrix: Water Associated Lab Samples: 92610548002,92610548003,92610548004,92610548005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 06/22/22 03:58 1,1,1-Trichloroethane ug/L ND 1.0 0.33 06/22/22 03:58 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 06/22/22 03:58 1,1,2-Trichloroethane ug/L ND 1.0 0.32 06/22/22 03:58 1,1-Dichloroethane ug/L ND 1.0 0.37 06/22/22 03:58 1,1-Dichloroethene ug/L ND 1.0 0.35 06/22/22 03:58 1,1-Dichloropropene ug/L ND 1.0 0.43 06/22/22 03:58 1,2,3-Trichlorobenzene ug/L ND 1.0 0.81 06/22/22 03:58 1,2,3-Trichloropropane ug/L ND 1.0 0.26 06/22/22 03:58 1,2,4-Trichlorobenzene ug/L ND 1.0 0.64 06/22/22 03:58 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 06/22/22 03:58 1,2-Dibromoethane(EDB) ug/L ND 1.0 0.27 06/22/22 03:58 1,2-Dichlorobenzene ug/L ND 1.0 0.34 06/22/22 03:58 1,2-Dichloroethane ug/L ND 1.0 0.32 06/22/22 03:58 1,2-Dichloropropane ug/L ND 1.0 0.36 06/22/22 03:58 1,3-Dichlorobenzene ug/L ND 1.0 0.34 06/22/22 03:58 1,3-Dichloropropane ug/L ND 1.0 0.28 06/22/22 03:58 1,4-Dichlorobenzene ug/L ND 1.0 0.33 06/22/22 03:58 2,2-Dichloropropane ug/L ND 1.0 0.39 06/22/22 03:58 2-Butanone(MEK) ug/L ND 5.0 4.0 06/22/22 03:58 2-Chlorotoluene ug/L ND 1.0 0.32 06/22/22 03:58 2-Hexanone ug/L ND 5.0 0.48 06/22/22 03:58 4-Chlorotoluene ug/L ND 1.0 0.32 06/22/22 03:58 4-Methyl-2-pentanone(MIBK) ug/L ND 5.0 2.7 06/22/22 03:58 Acetone ug/L ND 25.0 5.1 06/22/22 03:58 Benzene ug/L ND 1.0 0.34 06/22/22 03:58 Bromobenzene ug/L ND 1.0 0.29 06/22/22 03:58 Bromochloromethane ug/L ND 1.0 0.47 06/22/22 03:58 Bromodichloromethane ug/L ND 1.0 0.31 06/22/22 03:58 Bromoform ug/L ND 1.0 0.34 06/22/22 03:58 Bromomethane ug/L ND 2.0 1.7 06/22/22 03:58 v2 Carbon tetrachloride ug/L ND 1.0 0.33 06/22/22 03:58 Chlorobenzene ug/L ND 1.0 0.28 06/22/22 03:58 Chloroethane ug/L ND 1.0 0.65 06/22/22 03:58 Chloroform ug/L ND 1.0 0.43 06/22/22 03:58 Chloromethane ug/L ND 1.0 0.54 06/22/22 03:58 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 06/22/22 03:58 cis-1,3-Dichloropropene ug/L ND 1.0 0.36 06/22/22 03:58 Dibromochloromethane ug/L ND 1.0 0.36 06/22/22 03:58 Dibromomethane ug/L ND 1.0 0.39 06/22/22 03:58 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 34 of 54 Pace Analytical Services,LLC 9800 Kincey Ave. Suite100 aceAnalytical Huntersville,NC 28078078 www.pacatabs.com (704)875-9092 I i QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 METHOD BLANK: 3683525 Matrix: Water Associated Lab Samples: 92610548002,92610548003,92610548004,92610548005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Dichlorodifluoromethane ug/L ND 1.0 0.35 06/22/22 03:58 Diisopropyl ether ug/L ND 1.0 0.31 06/22/22 03:58 Ethylbenzene ug/L ND 1.0 0.30 06/22/22 03:58 Hexachloro-1,3-butadiene ug/L ND 2.0 1.5 06/22/22 03:58 m&p-Xylene ug/L ND 2.0 0.71 06/22/22 03:58 Methyl-tert-butyl ether ug/L ND 1.0 0.42 06/22/22 03:58 Methylene Chloride ug/L ND 5.0 2.0 06/22/22 03:58 Naphthalene ug/L ND 1.0 0.64 06/22/22 03:58 o-Xylene ug/L ND 1.0 0.34 06/22/22 03:58 p-Isopropyltoluene ug/L ND 1.0 0.41 06/22/22 03:58 Styrene ug/L ND 1.0 0.29 06/22/22 03:58 Tetrachloroethene ug/L ND 1.0 0.29 06/22/22 03:58 Toluene ug/L ND 1.0 0.48 06/22/22 03:58 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 06/22/22 03:58 trans-1,3-Dichloropropene ug/L ND 1.0 0.36 06/22/22 03:58 Trichloroethene ug/L ND 1.0 0.38 06/22/22 03:58 Trichlorofluoromethane ug/L ND 1.0 0.30 06/22/22 03:58 Vinyl acetate ug/L ND 2.0 1.3 06/22/22 03:58 Vinyl chloride ug/L ND 1.0 0.39 06/22/22 03:58 Xylene(Total) ug/L ND 1.0 0.34 06/22/22 03:58 1,2-Dichloroethane-d4(S) % 113 70-130 06/22/22 03:58 4-Bromofluorobenzene(S) % 102 70-130 06/22/22 03:58 Toluene-d8(S) % 100 70-130 06/22/22 03:58 LABORATORY CONTROL SAMPLE: 3683526 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 50.2 100 70-130 1,1,1-Trichloroethane ug/L 50 52.4 105 70-130 1,1,2,2-Tetrachloroethane ug/L 50 48.4 97 70-130 1,1,2-Trichloroethane ug/L 50 50.2 100 70-130 1,1-Dichloroethane ug/L 50 53.8 108 70-130 1,1-Dichloroethene ug/L 50 54.5 109 70-132 1,1-Dichloropropene ug/L 50 55.5 111 70-131 1,2,3-Trichlorobenzene ug/L 50 45.7 91 70-134 1,2,3-Trichloropropane ug/L 50 47.6 95 70-130 1,2,4-Trichlorobenzene ug/L 50 47.0 94 70-130 1,2-Dibromo-3-chloropropane ug/L 50 45.6 91 70-132 1,2-Dibromoethane(EDB) ug/L 50 50.4 101 70-130 1,2-Dichlorobenzene ug/L 50 48.4 97 70-130 1,2-Dichloroethane ug/L 50 53.3 107 70-130 1,2-Dichloropropane ug/L 50 52.5 105 70-130 1,3-Dichlorobenzene ug/L 50 47.7 95 70-130 1,3-Dichloropropane ug/L 50 50.2 100 70-130 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 35 of 54 Pace Analytical Services,LLC 9800 Kincey Ave. Suite100 aceAnalytical Huntersville,NC 28078078 www.pacelabs.com (704)875-9092 i I QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 LABORATORY CONTROL SAMPLE: 3683526 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers 1,4-Dichlorobenzene ug/L 50 46.8 94 70-130 2,2-Dichloropropane ug/L 50 48.7 97 70-130 2-Butanone(MEK) ug/L 100 114 114 70-133 2-Chlorotoluene ug/L 50 49.3 99 70-130 2-Hexanone ug/L 100 103 103 70-130 4-Chlorotoluene ug/L 50 49.0 98 70-130 4-Methyl-2-pentanone(MIBK) ug/L 100 102 102 70-130 Acetone ug/L 100 102 102 70-144 Benzene ug/L 50 48.1 96 70-130 Bromobenzene ug/L 50 47.9 96 70-130 Bromochloromethane ug/L 50 53.8 108 70-130 Bromodichloromethane ug/L 50 51.4 103 70-130 Bromoform ug/L 50 50.3 101 70-131 Bromomethane ug/L 50 41.5 83 30-177 v3 Carbon tetrachloride ug/L 50 48.7 97 70-130 Chlorobenzene ug/L 50 48.5 97 70-130 Chloroethane ug/L 50 48.9 98 46-131 Chloroform ug/L 50 53.4 107 70-130 Chloromethane ug/L 50 53.7 107 49-130 cis-1,2-Dichloroethene ug/L 50 54.7 109 70-130 cis-1,3-Dichloropropene ug/L 50 52.2 104 70-130 Dibromochloromethane ug/L 50 50.4 101 70-130 Dibromomethane ug/L 50 48.2 96 70-130 Dichlorodifluoromethane ug/L 50 58.7 117 52-134 Diisopropyl ether ug/L 50 57.9 116 70-131 Ethylbenzene ug/L 50 49.0 98 70-130 Hexachloro-1,3-butadiene ug/L 50 44.4 89 70-131 m&p-Xylene ug/L 100 98.1 98 70-130 Methyl-tert-butyl ether ug/L 50 54.8 110 70-130 Methylene Chloride ug/L 50 50.3 101 68-130 Naphthalene ug/L 50 50.2 100 70-133 o-Xylene ug/L 50 49.8 100 70-130 p-Isopropyltoluene ug/L 50 51.2 102 70-130 Styrene ug/L 50 48.4 97 70-130 Tetrachloroethene ug/L 50 45.2 90 70-130 Toluene ug/L 50 46.6 93 70-130 trans-1,2-Dichloroethene ug/L 50 55.5 111 70-130 trans-1,3-Dichloropropene ug/L 50 52.7 105 70-130 Trichloroethene ug/L 50 47.9 96 70-130 Trichlorofluoromethane ug/L 50 46.9 94 61-130 Vinyl acetate ug/L 100 118 118 70-140 Vinyl chloride ug/L 50 57.1 114 59-142 Xylene(Total) ug/L 150 148 99 70-130 1,2-Dichloroethane-d4(S) % 114 70-130 4-Bromofluorobenzene(S) % 103 70-130 Toluene-d8(S) % 101 70-130 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 36 of 54 Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite100 Huntersville,NC 28078078 www.pacelabs.com (704)875-9092 i QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3683527 3683528 MS MSD 92610715001 Spike Spike MS MSD MS MSD %Rec Max Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 23.6 22.3 118 112 70-135 5 30 1,1,1-Trichloroethane ug/L ND 20 20 25.7 24.2 128 121 70-148 6 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 23.1 22.1 116 111 70-131 4 30 1,1,2-Trichloroethane ug/L ND 20 20 23.2 21.8 116 109 70-136 6 30 1,1-Dichloroethane ug/L ND 20 20 26.2 24.8 131 124 70-147 6 30 1,1-Dichloroethene ug/L ND 20 20 26.9 25.6 134 128 70-158 5 30 1,1-Dichloropropene ug/L ND 20 20 27.3 25.9 136 130 70-149 5 30 1,2,3-Trichlorobenzene ug/L ND 20 20 22.0 21.4 110 107 68-140 3 30 1,2,3-Trichloropropane ug/L ND 20 20 22.8 21.8 114 109 67-137 5 30 1,2,4-Trichlorobenzene ug/L ND 20 20 21.7 21.4 108 107 70-139 1 30 1,2-Dibromo-3- ug/L ND 20 20 21.4 21.4 107 107 69-136 0 30 chloropropane 1,2-Dibromoethane(EDB) ug/L ND 20 20 23.7 22.5 118 113 70-137 5 30 1,2-Dichlorobenzene ug/L ND 20 20 22.7 22.7 114 114 70-133 0 30 1,2-Dichloroethane ug/L ND 20 20 25.1 23.6 125 118 67-138 6 30 1,2-Dichloropropane ug/L ND 20 20 25.1 23.7 125 119 70-138 5 30 1,3-Dichlorobenzene ug/L ND 20 20 22.8 22.2 114 111 70-133 3 30 1,3-Dichloropropane ug/L ND 20 20 24.1 22.8 121 114 70-136 6 30 1,4-Dichlorobenzene ug/L ND 20 20 22.6 22.0 113 110 70-133 3 30 2,2-Dichloropropane ug/L ND 20 20 26.0 24.5 130 123 52-155 6 30 2-Butanone(MEK) ug/L ND 40 40 53.4 51.1 134 128 61-147 4 30 2-Chlorotoluene ug/L ND 20 20 23.9 23.7 119 118 70-141 1 30 2-Hexanone ug/L ND 40 40 49.8 48.3 125 121 67-139 3 30 4-Chlorotoluene ug/L ND 20 20 24.4 23.4 122 117 70-135 4 30 4-Methyl-2-pentanone ug/L ND 40 40 46.3 45.3 116 113 67-136 2 30 (MIBK) Acetone ug/L ND 40 40 47.4 45.7 119 114 55-159 4 30 Benzene ug/L ND 20 20 23.7 22.5 118 113 67-150 5 30 Bromobenzene ug/L ND 20 20 22.6 22.2 113 111 70-134 2 30 Bromochloromethane ug/L ND 20 20 24.8 23.4 124 117 70-146 6 30 Bromodichloromethane ug/L ND 20 20 23.8 22.7 119 113 70-138 5 30 Bromoform ug/L ND 20 20 22.4 21.1 112 106 57-138 6 30 Bromomethane ug/L ND 20 20 19.8 18.8 99 94 10-200 5 30 v3 Carbon tetrachloride ug/L ND 20 20 23.8 22.7 119 114 70-147 5 30 Chlorobenzene ug/L ND 20 20 23.7 22.4 118 112 70-137 6 30 Chloroethane ug/L ND 20 20 27.8 26.2 139 131 51-166 6 30 Chloroform ug/L ND 20 20 25.5 24.7 127 123 70-144 3 30 Chloromethane ug/L ND 20 20 26.9 25.7 135 128 24-161 5 30 v3 cis-1,2-Dichloroethene ug/L ND 20 20 26.2 24.8 131 124 67-148 5 30 cis-1,3-Dichloropropene ug/L ND 20 20 23.9 22.6 120 113 70-142 5 30 Dibromochloromethane ug/L ND 20 20 23.2 21.7 116 108 68-138 7 30 Dibromomethane ug/L ND 20 20 21.7 20.7 109 103 70-134 5 30 Dichlorodifluoromethane ug/L ND 20 20 29.2 27.3 146 136 43-155 7 30 Diisopropyl ether ug/L ND 20 20 26.9 25.4 134 127 65-146 6 30 Ethylbenzene ug/L ND 20 20 24.2 23.1 121 115 68-143 5 30 Hexachloro-1,3-butadiene ug/L ND 20 20 19.9 19.8 99 99 62-151 0 30 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 37 of 54 Pace Analytical Services,LLC ® 9800 Kincey Ave. Suite 100 aceAnalytical Huntersville,NC 28078 www.pacelabs.com (704)875-9092 i QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3683527 3683528 MS MSD 92610715001 Spike Spike MS MSD MS MSD %Rec Max Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual m&p-Xylene ug/L ND 40 40 48.6 46.3 122 116 53-157 5 30 Methyl-tert-butyl ether ug/L ND 20 20 25.2 23.6 126 118 59-156 6 30 Methylene Chloride ug/L ND 20 20 23.2 22.0 116 110 64-148 5 30 Naphthalene ug/L ND 20 20 24.3 23.4 121 117 57-150 4 30 o-Xylene ug/L ND 20 20 24.1 22.9 121 115 68-143 5 30 p-Isopropyltoluene ug/L ND 20 20 24.7 23.9 123 119 70-141 3 30 Styrene ug/L ND 20 20 22.7 21.5 114 108 70-136 5 30 Tetrachloroethene ug/L ND 20 20 22.2 21.2 111 106 70-139 5 30 Toluene ug/L ND 20 20 22.2 21.5 111 108 47-157 3 30 trans-1,2-Dichloroethene ug/L ND 20 20 27.0 25.7 135 128 70-149 5 30 trans-1,3-Dichloropropene ug/L ND 20 20 24.1 23.0 120 115 70-138 5 30 Trichloroethene ug/L ND 20 20 23.6 22.5 118 112 70-149 5 30 Trichlorofluoromethane ug/L ND 20 20 24.2 22.6 121 113 61-154 7 30 Vinyl acetate ug/L ND 40 40 52.5 49.7 131 124 48-156 6 30 Vinyl chloride ug/L ND 20 20 28.4 26.6 142 133 55-172 7 30 Xylene(Total) ug/L ND 60 60 72.8 69.3 121 115 66-145 5 30 1,2-Dichloroethane-d4(S) % 108 109 70-130 4-Bromofluorobenzene(S) % 105 103 70-130 Toluene-d8(S) % 99 99 70-130 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 38 of 54 Pace Analytical Services,LLC ace Analytical _a'ytical 9800 Kincey Ave. Suite 100 078 VG�I li Huntersville,NC 28078 www.pacelabs.com (704)875-9092 r l QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 QC Batch: 706344 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Laboratory: Pace Analytical Services-Charlotte Associated Lab Samples: 92610548001 METHOD BLANK: 3685190 Matrix: Water Associated Lab Samples: 92610548001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.31 06/22/22 19:11 1,1,1-Trichloroethane ug/L ND 1.0 0.33 06/22/22 19:11 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 06/22/22 19:11 1,1,2-Trichloroethane ug/L ND 1.0 0.32 06/22/22 19:11 1,1-Dichloroethane ug/L ND 1.0 0.37 06/22/22 19:11 1,1-Dichloroethene ug/L ND 1.0 0.35 06/22/22 19:11 ' 1,1-Dichloropropene ug/L ND 1.0 0.43 06/22/22 19:11 1,2,3-Trichlorobenzene ug/L ND 1.0 0.81 06/22/22 19:11 v1 1,2,3-Trichloropropane ug/L ND 1.0 0.26 06/22/22 19:11 1,2,4-Trichlorobenzene ug/L ND 1.0 0.64 06/22/22 19:11 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.34 06/22/22 19:11 1,2-Dibromoethane(EDB) ug/L ND 1.0 0.27 06/22/22 19:11 1,2-Dichlorobenzene ug/L ND 1.0 0.34 06/22/22 19:11 1,2-Dichloroethane ug/L ND 1.0 0.32 06/22/22 19:11 1,2-Dichloropropane ug/L ND 1.0 0.36 06/22/22 19:11 1,3-Dichlorobenzene ug/L ND 1.0 0.34 06/22/22 19:11 1,3-Dichloropropane ug/L ND 1.0 0.28 06/22/22 19:11 1,4-Dichlorobenzene ug/L ND 1.0 0.33 06/22/22 19:11 2,2-Dichloropropane ug/L ND 1.0 0.39 06/22/22 19:11 v1 2-Butanone(MEK) ug/L ND 5.0 4.0 06/22/22 19:11 2-Chlorotoluene ug/L ND 1.0 0.32 06/22/22 19:11 2-Hexanone ug/L ND 5.0 0.48 06/22/22 19:11 4-Chlorotoluene ug/L ND 1.0 0.32 06/22/22 19:11 4-Methyl-2-pentanone(MIBK) ug/L ND 5.0 2.7 06/22/22 19:11 Acetone ug/L ND 25.0 5.1 06/22/22 19:11 Benzene ug/L ND 1.0 0.34 06/22/22 19:11 Bromobenzene ug/L ND 1.0 0.29 06/22/22 19:11 Bromochloromethane ug/L ND 1.0 0.47 06/22/22 19:11 Bromodichloromethane ug/L ND 1.0 0.31 06/22/22 19:11 Bromoform ug/L ND 1.0 0.34 06/22/22 19:11 IK Bromomethane ug/L ND 2.0 1.7 06/22/22 19:11 Carbon tetrachloride ug/L ND 1.0 0.33 06/22/22 19:11 Chlorobenzene ug/L ND 1.0 0.28 06/22/22 19:11 Chloroethane ug/L ND 1.0 0.65 06/22/22 19:11 v1 Chloroform ug/L ND 1.0 0.43 06/22/22 19:11 Chloromethane ug/L ND 1.0 0.54 06/22/22 19:11 cis-1,2-Dichloroethene ug/L ND 1.0 0.38 06/22/22 19:11 ' cis-1,3-Dichloropropene ug/L ND 1.0 0.36 06/22/22 19:11 Dibromochloromethane ug/L ND 1.0 0.36 06/22/22 19:11 Dibromomethane ug/L ND 1.0 0.39 06/22/22 19:11 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 39 of 54 ' Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite100 Huntersville,NC 28078078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 METHOD BLANK: 3685190 Matrix: Water Associated Lab Samples: 92610548001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Dichlorodifluoromethane ug/L ND 1.0 0.35 06/22/22 19:11 Diisopropyl ether ug/L ND 1.0 0.31 06/22/22 19:11 Ethylbenzene ug/L ND 1.0 0.30 06/22/22 19:11 Hexachloro-1,3-butadiene ug/L ND 2.0 1.5 06/22/22 19:11 m&p-Xylene ug/L ND 2.0 0.71 06/22/22 19:11 Methyl-tert-butyl ether ug/L ND 1.0 0.42 06/22/22 19:11 Methylene Chloride ug/L ND 5.0 2.0 06/22/22 19:11 Naphthalene ug/L ND 1.0 0.64 06/22/22 19:11 v1 o-Xylene ug/L ND 1.0 0.34 06/22/22 19:11 p-Isopropyltoluene ug/L ND 1.0 0.41 06/22/22 19:11 Styrene ug/L ND 1.0 0.29 06/22/22 19:11 Tetrachloroethene ug/L ND 1.0 0.29 06/22/22 19:11 Toluene ug/L ND 1.0 0.48 06/22/22 19:11 trans-1,2-Dichloroethene ug/L ND 1.0 0.40 06/22/22 19:11 trans-1,3-Dichloropropene ug/L ND 1.0 0.36 06/22/22 19:11 Trichloroethene ug/L ND 1.0 0.38 06/22/22 19:11 Trichlorofluoromethane ug/L ND 1.0 0.30 06/22/22 19:11 Vinyl acetate ug/L ND 2.0 1.3 06/22/22 19:11 Vinyl chloride ug/L ND 1.0 0.39 06/22/22 19:11 Xylene(Total) ug/L ND 1.0 0.34 06/22/22 19:11 1,2-Dichloroethane-d4(S) % 101 70-130 06/22/22 19:11 4-Bromofluorobenzene(S) % 95 70-130 06/22/22 19:11 Toluene-d8(S) % 97 70-130 06/22/22 19:11 LABORATORY CONTROL SAMPLE: 3685191 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 56.8 114 70-130 1,1,1-Trichloroethane ug/L 50 52.9 106 70-130 1,1,2,2-Tetrachloroethane ug/L 50 54.2 108 70-130 1,1,2-Trichloroethane ug/L 50 50.9 102 70-130 1,1-Dichloroethane ug/L 50 51.7 103 70-130 1,1-Dichloroethene ug/L 50 53.7 107 70-132 1,1-Dichloropropene ug/L 50 56.7 113 70-131 1,2,3-Trichlorobenzene ug/L 50 62.5 125 70-134 v1 1,2,3-Trichloropropane ug/L 50 53.3 107 70-130 1,2,4-Trichlorobenzene ug/L 50 59.2 118 70-130 1,2-Dibromo-3-chloropropane ug/L 50 58.1 116 70-132 1,2-Dibromoethane(EDB) ug/L 50 53.7 107 70-130 1,2-Dichlorobenzene ug/L 50 54.9 110 70-130 1,2-Dichloroethane ug/L 50 52.6 105 70-130 1,2-Dichloropropane ug/L 50 54.4 109 70-130 1,3-Dichlorobenzene ug/L 50 56.3 113 70-130 1,3-Dichloropropane ug/L 50 53.3 107 70-130 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 40 of 54 Pace Analytical Services,LLC aceAnalytical® 9800 Kincey Ave. Suite100 Huntersville,NC 28078078 www.pacelabs.com (704)875-9092 I QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 LABORATORY CONTROL SAMPLE: 3685191 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers 1,4-Dichlorobenzene ug/L 50 55.1 110 70-130 2,2-Dichloropropane ug/L 50 63.5 127 70-130 v1 2-Butanone(MEK) ug/L 100 112 112 70-133 2-Chlorotoluene ug/L 50 55.4 111 70-130 2-Hexanone ug/L 100 122 122 70-130 4-Chlorotoluene ug/L 50 55.5 111 70-130 4-Methyl-2-pentanone(MIBK) ug/L 100 111 111 70-130 Acetone ug/L 100 110 110 70-144 Benzene ug/L 50 51.2 102 70-130 Bromobenzene ug/L 50 54.7 109 70-130 Bromochloromethane ug/L 50 51.1 102 70-130 Bromodichloromethane ug/L 50 53.4 107 70-130 Bromoform ug/L 50 60.6 121 70-131 IK Bromomethane ug/L 50 59.5 119 30-177 Carbon tetrachloride ug/L 50 53.0 106 70-130 Chlorobenzene ug/L 50 54.5 109 70-130 Chloroethane ug/L 50 61.0 122 46-131 v1 Chloroform ug/L 50 51.6 103 70-130 Chloromethane ug/L 50 55.1 110 49-130 cis-1,2-Dichloroethene ug/L 50 52.6 105 70-130 cis-1,3-Dichloropropene ug/L 50 59.1 118 70-130 Dibromochloromethane ug/L 50 56.1 112 70-130 Dibromomethane ug/L 50 52.9 106 70-130 Dichlorodifluoromethane ug/L 50 50.1 100 52-134 Diisopropyl ether ug/L 50 54.6 109 70-131 Ethylbenzene ug/L 50 55.7 111 70-130 Hexachloro-1,3-butadiene ug/L 50 58.8 118 70-131 m&p-Xylene ug/L 100 111 111 70-130 Methyl-tert-butyl ether ug/L 50 51.9 104 70-130 Methylene Chloride ug/L 50 55.0 110 68-130 Naphthalene ug/L 50 64.8 130 70-133 v1 I o-Xylene ug/L 50 53.4 107 70-130 i p-lsopropyltoluene ug/L 50 59.2 118 70-130 Styrene ug/L 50 56.5 113 70-130 Tetrachloroethene ug/L 50 53.0 106 70-130 Toluene ug/L 50 50.9 102 70-130 trans-1,2-Dichloroethene ug/L 50 54.3 109 70-130 trans-1,3-Dichloropropene ug/L 50 54.5 109 70-130 Trichloroethene ug/L 50 54.0 108 70-130 Trichlorofluoromethane ug/L 50 56.8 114 61-130 Vinyl acetate ug/L 100 115 115 70-140 Vinyl chloride ug/L 50 53.4 107 59-142 Xylene(Total) ug/L 150 165 110 70-130 1,2-Dichloroethane-d4(S) % 100 70-130 4-Bromofluorobenzene(S) % 99 70-130 Toluene-d8(S) % 99 70-130 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 41 of 54 Pace Analytical Services,LLC 9800 Kincey Ave. Suite 100 aceAnalytical Huntersville,NC 28078 www.pacelabs.com (704)875-9092 I QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3685192 3685193 MS MSD 92610914001 Spike Spike MS MSD MS MSD %Rec Max Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 200 200 231 236 116 118 70-135 2 30 1,1,1-Trichloroethane ug/L ND 200 200 253 243 127 122 70-148 4 30 1,1,2,2-Tetrachloroethane ug/L ND 200 200 226 226 113 113 70-131 0 30 1,1,2-Trichloroethane ug/L ND 200 200 216 212 108 106 70-136 2 30 1,1-Dichloroethane ug/L ND 200 200 236 225 118 112 70-147 5 30 1,1-Dichloroethene ug/L ND 200 200 240 250 120 125 70-158 4 30 1,1-Dichloropropene ug/L ND 200 200 263 255 131 127 70-149 3 30 1,2,3-Trichlorobenzene ug/L ND 200 200 241 233 121 117 68-140 3 30 v1 1,2,3-Trichloropropane ug/L ND 200 200 217 221 108 111 67-137 2 30 1,2,4-Trichlorobenzene ug/L ND 200 200 227 227 114 114 70-139 0 30 1,2-Dibromo-3- ug/L ND 200 200 223 224 112 112 69-136 0 30 chloropropane 1,2-Dibromoethane(EDB) ug/L ND 200 200 229 231 114 115 70-137 1 30 1,2-Dichlorobenzene ug/L ND 200 200 237 226 118 113 70-133 4 30 1,2-Dichloroethane ug/L ND 200 200 230 233 115 116 67-138 1 30 1,2-Dichloropropane ug/L ND 200 200 246 236 123 118 70-138 4 30 1,3-Dichlorobenzene ug/L ND 200 200 238 236 119 118 70-133 1 30 1,3-Dichloropropane ug/L ND 200 200 236 235 118 118 70-136 0 30 1,4-Dichlorobenzene ug/L ND 200 200 235 230 118 115 70-133 2 30 2,2-Dichloropropane ug/L ND 200 200 275 269 138 135 52-155 2 30 v1 2-Butanone(MEK) ug/L ND 400 400 462 442 115 111 61-147 4 30 2-Chlorotoluene ug/L ND 200 200 236 231 118 115 70-141 2 30 2-Hexanone ug/L ND 400 400 476 473 119 118 67-139 1 30 4-Chlorotoluene ug/L ND 200 200 233 228 117 114 70-135 2 30 4-Methyl-2-pentanone ug/L ND 400 400 435 423 109 106 67-136 3 30 (MIBK) Acetone ug/L ND 400 400 461 463 115 116 55-159 0 30 Benzene ug/L ND 200 200 237 236 118 118 67-150 0 30 Bromobenzene ug/L ND 200 200 225 228 113 114 70-134 1 30 Bromochloromethane ug/L ND 200 200 236 243 118 122 70-146 3 30 Bromodichloromethane ug/L ND 200 200 236 236 118 118 70-138 0 30 Bromoform ug/L ND 200 200 265 266 133 133 57-138 0 30 IK Bromomethane ug/L ND 200 200 194 251 97 125 10-200 25 30 Carbon tetrachloride ug/L ND 200 200 243 245 122 122 70-147 1 30 Chlorobenzene ug/L ND 200 200 237 242 119 121 70-137 2 30 Chloroethane ug/L ND 200 200 256 275 128 137 51-166 7 30 v1 Chloroform ug/L ND 200 200 234 243 117 122 70-144 4 30 Chloromethane ug/L ND 200 200 237 264 119 132 24-161 11 30 cis-1,2-Dichloroethene ug/L 196 200 200 426 421 115 113 67-148 1 30 cis-1,3-Dichloropropene ug/L ND 200 200 242 249 121 125 70-142 3 30 Dibromochloromethane ug/L ND 200 200 247 250 124 125 68-138 1 30 Dibromomethane ug/L ND 200 200 234 229 117 114 70-134 2 30 Dichlorodifluoromethane ug/L ND 200 200 217 243 108 122 43-155 12 30 Diisopropyl ether ug/L 17.2 200 200 248 248 115 115 65-146 0 30 Ethylbenzene ug/L ND 200 200 240 244 120 122 68-143 2 30 Hexachloro-1,3-butadiene ug/L ND 200 200 232 243 116 121 62-151 5 30 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 42 of 54 1 Pace Analytical Services,LLC aeAnalytical 9800 Kincey Ave. Suite 100 Huntersville,NC 28078 078 / www.pacelabs.com (704)875-9092 I QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3685192 3685193 MS MSD 92610914001 Spike Spike MS MSD MS MSD %Rec Max Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual m&p-Xylene ug/L ND 400 400 480 483 120 121 53-157 1 30 Methyl-tert-butyl ether ug/L ND 200 200 213 223 106 111 59-156 5 30 Methylene Chloride ug/L ND 200 200 213 222 107 111 64-148 4 30 Naphthalene ug/L ND 200 200 239 234 119 117 57-150 2 30 v1 o-Xylene ug/L ND 200 200 228 233 114 116 68-143 2 30 p-Isopropyltoluene ug/L ND 200 200 256 247 128 124 70-141 4 30 Styrene ug/L ND 200 200 237 242 118 121 70-136 2 30 Tetrachloroethene ug/L 1350 200 200 1610 1590 131 122 70-139 1 30 Toluene ug/L ND 200 200 226 222 113 111 47-157 1 30 trans-1,2-Dichloroethene ug/L 5.1J 200 200 238 250 116 122 70-149 5 30 trans-1,3-Dichloropropene ug/L ND 200 200 231 232 115 116 70-138 1 30 Trichloroethene ug/L 572 200 200 842 830 135 129 70-149 1 30 Trichlorofluoromethane ug/L ND 200 200 227 237 113 118 61-154 4 30 Vinyl acetate ug/L ND 400 400 472 482 118 120 48-156 2 30 Vinyl chloride ug/L ND 200 200 242 262 121 131 55-172 8 30 Xylene(Total) ug/L ND 600 600 708 716 118 119 66-145 1 30 1,2-Dichloroethane-d4(S) % 103 101 70-130 4-Bromofluorobenzene(S) % 98 101 70-130 Toluene-d8(S) % 100 99 70-130 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 43 of 54 Pace Analytical Services,LLC s aceAnalytical 9800 Kincey Ave. Suite100 Huntersville,NC 28078078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 QC Batch: 706114 Analysis Method: EPA 8270E QC Batch Method: EPA 3510C Analysis Description: 8270E Water MSSV RVE Laboratory: Pace Analytical Services-Charlotte Associated Lab Samples: 92610548001,92610548002,92610548003,92610548004,92610548005 METHOD BLANK: 3683914 Matrix: Water Associated Lab Samples: 92610548001,92610548002,92610548003,92610548004,92610548005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,2,4-Trichlorobenzene ug/L ND 10.0 1.7 06/22/22 15:43 1,2-Dichlorobenzene ug/L ND 10.0 1.8 06/22/22 15:43 1,3-Dichlorobenzene ug/L ND 10.0 1.6 06/22/22 15:43 1,4-Dichlorobenzene ug/L ND 10.0 1.7 06/22/22 15:43 1-Methylnaphthalene ug/L ND 10.0 2.0 06/22/22 15:43 2,2'-Oxybis(1-chloropropane) ug/L ND 10.0 1.2 06/22/22 15:43 2,4,5-Trichlorophenol ug/L ND 10.0 1.4 06/22/22 15:43 2,4,6-Trichlorophenol ug/L ND 10.0 1.6 06/22/22 15:43 2,4-Dichlorophenol ug/L ND 10.0 1.4 06/22/22 15:43 2,4-Dimethylphenol ug/L ND 10.0 1.7 06/22/22 15:43 2,4-Dinitrophenol ug/L ND 50.0 26.0 06/22/22 15:43 2,4-Dinitrotoluene ug/L ND 10.0 1.6 06/22/22 15:43 2,6-Dinitrotoluene ug/L ND 10.0 1.7 06/22/22 15:43 2-Chloronaphthalene ug/L ND 10.0 1.7 06/22/22 15:43 2-Chlorophenol ug/L ND 10.0 1.2 06/22/22 15:43 2-Methylnaphthalene ug/L ND 10.0 1.9 06/22/22 15:43 2-Methylphenol(o-Cresol) ug/L ND 10.0 1.9 06/22/22 15:43 2-Nitroaniline ug/L ND 20.0 3.0 06/22/22 15:43 2-Nitrophenol ug/L ND 10.0 1.4 06/22/22 15:43 3&4-Methylphenol(m&p Cresol) ug/L ND 10.0 1.2 06/22/22 15:43 3,3'-Dichlorobenzidine ug/L ND 20.0 8.1 06/22/22 15:43 3-Nitroaniline ug/L ND 20.0 3.8 06/22/22 15:43 IL 4,6-Dinitro-2-methylphenol ug/L ND 20.0 7.8 06/22/22 15:43 4-Bromophenylphenyl ether ug/L ND 10.0 1.8 06/22/22 15:43 4-Chloro-3-methylphenol ug/L ND 10.0 3.3 06/22/22 15:43 4-Chloroaniline ug/L ND 20.0 3.6 06/22/22 15:43 4-Chlorophenylphenyl ether ug/L ND 10.0 2.0 06/22/22 15:43 4-Nitroaniline ug/L ND 20.0 5.1 06/22/22 15:43 4-Nitrophenol ug/L ND 50.0 6.6 06/22/22 15:43 Acenaphthene ug/L ND 10.0 2.0 06/22/22 15:43 Acenaphthylene ug/L ND 10.0 2.0 06/22/22 15:43 Aniline ug/L ND 10.0 1.6 06/22/22 15:43 Anthracene ug/L ND 10.0 2.3 06/22/22 15:43 Benzo(a)anthracene ug/L ND 10.0 2.7 06/22/22 15:43 Benzo(a)pyrene ug/L ND 10.0 2.8 06/22/22 15:43 Benzo(b)fluoranthene ug/L ND 10.0 2.6 06/22/22 15:43 Benzo(g,h,i)perylene ug/L ND 10.0 2.8 06/22/22 15:43 Benzo(k)fluoranthene ug/L ND 10.0 2.7 06/22/22 15:43 Benzoic Acid ug/L ND 50.0 22.0 06/22/22 15:43 Benzyl alcohol ug/L ND 20.0 2.9 06/22/22 15:43 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 44 of 54 1 Pace Analytical Services,LLC ® 9800 Kincey Ave. Suite 100 ace Analytical Huntersville,NC 28078 www.pacelabs.com (704)875-9092 1 QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 METHOD BLANK: 3683914 Matrix: Water Associated Lab Samples: 92610548001,92610548002,92610548003,92610548004,92610548005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers bis(2-Chloroethoxy)methane ug/L ND 10.0 1.8 06/22/22 15:43 bis(2-Chloroethyl)ether ug/L ND 10.0 1.9 06/22/22 15:43 bis(2-Ethylhexyl)phthalate ug/L ND 6.0 3.7 06/22/22 15:43 Butylbenzylphthalate ug/L ND 10.0 3.1 06/22/22 15:43 Chrysene ug/L ND 10.0 2.8 06/22/22 15:43 Di-n-butylphthalate ug/L ND 10.0 2.2 06/22/22 15:43 Di-n-octylphthalate ug/L ND 10.0 3.9 06/22/22 15:43 Dibenz(a,h)anthracene ug/L ND 10.0 3.0 06/22/22 15:43 Dibenzofuran ug/L ND 10.0 2.1 06/22/22 15:43 Diethylphthalate ug/L ND 10.0 2.0 06/22/22 15:43 Dimethylphthalate ug/L ND 10.0 2.1 06/22/22 15:43 Fluoranthene ug/L ND 10.0 2.2 06/22/22 15:43 Fluorene ug/L ND 10.0 2.1 06/22/22 15:43 Hexachloro-1,3-butadiene ug/L ND 10.0 1.8 06/22/22 15:43 Hexachlorobenzene ug/L ND 10.0 2.2 06/22/22 15:43 Hexachlorocyclopentadiene ug/L ND 10.0 1.6 06/22/22 15:43 v1 Hexachloroethane ug/L ND 10.0 1.4 06/22/22 15:43 Indeno(1,2,3-cd)pyrene ug/L ND 10.0 2.9 06/22/22 15:43 Isophorone ug/L ND 10.0 1.7 06/22/22 15:43 N-Nitroso-di-n-propylamine ug/L ND 10.0 1.3 06/22/22 15:43 N-Nitrosodimethylamine ug/L ND 10.0 1.9 06/22/22 15:43 N-Nitrosodiphenylamine ug/L ND 10.0 3.0 06/22/22 15:43 Naphthalene ug/L ND 10.0 2.1 06/22/22 15:43 Nitrobenzene ug/L ND 10.0 1.9 06/22/22 15:43 Pentachlorophenol ug/L ND 20.0 3.8 06/22/22 15:43 Phenanthrene ug/L ND 10.0 2.0 06/22/22 15:43 Phenol ug/L ND 10.0 1.4 06/22/22 15:43 Pyrene ug/L ND 10.0 2.2 06/22/22 15:43 2,4,6-Tribromophenol(S) % 117 10-144 06/22/22 15:43 2-Fluorobiphenyl(S) % 56 10-130 06/22/22 15:43 2-Fluorophenol(S) % 59 10-130 06/22/22 15:43 Nitrobenzene-d5(S) % 77 10-144 06/22/22 15:43 Phenol-d6(S) % 41 10-130 06/22/22 15:43 Terphenyl-d14(S) % 138 34-163 06/22/22 15:43 LABORATORY CONTROL SAMPLE: 3683915 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers 1,2,4-Trichlorobenzene ug/L 50 11.7 23 18-130 1,2-Dichlorobenzene ug/L 50 11.9 24 20-130 1,3-Dichlorobenzene ug/L 50 9.8J 20 18-130 1,4-Dichlorobenzene ug/L 50 10.7 21 18-130 1-Methylnaphthalene ug/L 50 21.4 43 29-130 2,2'-Oxybis(1-chloropropane) ug/L 50 28.2 56 28-130 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 45 of 54 aceAnalytical Pace Analytical Services,LLC 980 Kincey Ave. Suite 100 Huntersville,NC 28078 www.paealabs.eom (704)875-9092 QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 LABORATORY CONTROL SAMPLE: 3683915 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers 2,4,5-Trichlorophenol ug/L 50 58.0 116 35-130 2,4,6-Trichlorophenol ug/L 50 56.7 113 31-130 2,4-Dichlorophenol ug/L 50 47.5 95 35-130 2,4-Dimethylphenol ug/L 50 47.0 94 34-130 2,4-Dinitrophenol ug/L 250 307 123 10-153 2,4-Dinitrotoluene ug/L 50 61.4 123 37-136 2,6-Dinitrotoluene ug/L 50 59.7 119 33-136 2-Chloronaphthalene ug/L 50 26.3 53 26-130 2-Chlorophenol ug/L 50 41.4 83 37-130 2-Methylnaphthalene ug/L 50 19.7 39 29-130 2-Methylphenol(o-Cresol) ug/L 50 40.9 82 35-130 2-Nitroaniline ug/L 100 103 103 37-130 2-Nitrophenol ug/L 50 49.5 - 99 32-130 3&4-Methylphenol(m&p Cresol) ug/L 50 37.7 75 34-130 3,3'-Dichlorobenzidine ug/L 100 108 108 34-136 3-Nitroaniline ug/L 100 108 108 37-138 IL 4,6-Dinitro-2-methylphenol ug/L 100 122 122 21-157 4-Bromophenylphenyl ether ug/L 50 58.3 117 38-130 4-Chloro-3-methylphenol ug/L 100 108 108 37-130 4-Chloroaniline ug/L 100 89.9 90 38-130 4-Chlorophenylphenyl ether ug/L 50 50.9 102 33-130 4-Nitroaniline ug/L 100 108 108 42-137 4-Nitrophenol ug/L 250 146 59 10-130 Acenaphthene ug/L 50 38.9 78 33-130 Acenaphthylene ug/L 50 39.1 78 35-130 Aniline ug/L 50 30.1 60 22-130 Anthracene ug/L 50 51.5 103 48-130 Benzo(a)anthracene ug/L 50 59.2 118 48-137 Benzo(a)pyrene ug/L 50 46.9 94 49-138 Benzo(b)fluoranthene ug/L 50 45.3 91 52-138 Benzo(g,h,i)perylene ug/L 50 44.2 88 48-140 Benzo(k)fluoranthene ug/L 50 46.9 94 48-139 Benzoic Acid ug/L 250 137 55 10-130 Benzyl alcohol ug/L 100 84.0 84 35-130 bis(2-Chloroethoxy)methane ug/L 50 47.4 95 34-130 bis(2-Chloroethyl)ether ug/L 50 41.6 83 36-130 bis(2-Ethylhexyl)phthalate ug/L 50 62.2 124 32-165 Butylbenzylphthalate ug/L 50 61.4 123 34-161 Chrysene ug/L 50 57.7 115 47-131 Di-n-butylphthalate ug/L 50 59.1 118 39-144 Di-n-octylphthalate ug/L 50 53.8 108 30-170 Dibenz(a,h)anthracene ug/L 50 46.3 93 49-138 Dibenzofuran ug/L 50 45.5 91 33-130 Diethylphthalate ug/L 50 56.9 114 38-131 Dimethylphthalate ug/L 50 55.4 111 37-130 Fluoranthene ug/L 50 59.4 119 46-137 Fluorene ug/L 50 50.7 101 37-130 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 46 of 54 Pace Analytical Services,LLC aceAnalytical 9800 Kincey Ave. Suite 100 Huntersville,NC 28078 www.paeelabs.eom (704)875-9092 QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 LABORATORY CONTROL SAMPLE: 3683915 Spike LCS LCS %Rec Parameter Units Conc. Result %Rec Limits Qualifiers Hexachloro-1,3-butadiene ug/L 50 7.1J 14 11-130 Hexachlorobenzene ug/L 50 53.3 107 38-130 Hexachlorocyclopentadiene ug/L 50 8.3J 17 10-130 v1 Hexachloroethane ug/L 50 6.9J 14 14-130 Indeno(1,2,3-cd)pyrene ug/L 50 46.8 94 41-130 Isophorone ug/L 50 45.6 91 33-130 N-Nitroso-di-n-propylamine ug/L 50 43.3 87 36-130 N-Nitrosodimethylamine ug/L 50 35.9 72 34-130 N-Nitrosodiphenylamine ug/L 50 55.9 112 37-130 Naphthalene ug/L 50 20.6 41 30-130 Nitrobenzene ug/L 50 43.7 87 36-130 Pentachlorophenol ug/L 100 104 104 23-149 Phenanthrene ug/L 50 56.0 112 44-130 Phenol ug/L 50 26.7 53 18-130 Pyrene ug/L 50 58.8 118 47-134 2,4,6-Tribromophenol(S) % 146 10-144 SO 2-Fluorobiphenyl(S) % 84 10-130 2-Fluorophenol(S) % 70 10-130 Nitrobenzene-d5(S) % 111 10-144 Phenol-d6(S) % 56 10-130 Terphenyl-d14(S) % 134 34-163 i MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3683916 3683917 MS MSD 92610548003 Spike Spike MS MSD MS MSD %Rec Max Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual 1,2,4-Trichlorobenzene ug/L ND 100 100 15.1J 20.9 15 21 10-130 30 1,2-Dichlorobenzene ug/L ND 100 100 12.OJ 21.8 12 22 10-130 30 1,3-Dichlorobenzene ug/L ND 100 100 9.3J 17.7J 9 18 10-130 30 M1 1,4-Dichlorobenzene ug/L ND 100 100 10.4J 19.2J 10 19 10-130 30 1-Methylnaphthalene ug/L ND 100 100 35.4 36.8 35 37 10-130 4 30 2,2'-Oxybis(1- ug/L ND 100 100 44.4 47.7 44 48 12-142 7 30 chloropropane) 2,4,5-Trichlorophenol ug/L ND 100 100 78.7 44.2 79 44 10-143 56 30 R1 2,4,6-Trichlorophenol ug/L ND 100 100 62.1 28.4 62 28 10-147 75 30 R1 2,4-Dichlorophenol ug/L ND 100 100 67.5 46.3 67 46 10-138 37 30 R1 2,4-Dimethylphenol ug/L ND 100 100 73.2 75.6 73 76 25-130 3 30 2,4-Dinitrophenol ug/L ND 500 500 70.5J ND 14 0 10-165 30 M1 2,4-Dinitrotoluene ug/L ND 100 100 104 105 104 105 29-148 2 30 2,6-Dinitrotoluene ug/L ND 100 100 98.6 98.2 99 98 26-146 0 30 2-Chloronaphthalene ug/L ND 100 100 44.3 45.0 44 45 11-130 2 30 2-Chlorophenol ug/L ND 100 100 62.3 41.5 62 42 10-133 40 30 R1 2-Methylnaphthalene ug/L ND 100 100 32.0 35.3 32 35 13-130 10 30 2-Methylphenol(o-Cresol) ug/L ND 100 100 66.4 65.4 66 65 20-130 2 30 I 2-Nitroaniline ug/L ND 200 200 170 157 85 78 24-136 8 30 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 47 of 54 Pace Analytical Services,LLC a 9800 Kincey Ave. Suite 100 aac eAnalytical Huntersville,NC 28078 www.pacelabs.com (704)875-9092 QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3683916 3683917 MS MSD 92610548003 Spike Spike MS MSD MS MSD %Rec Max Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual 2-Nitrophenol ug/L ND 100 100 71.2 45.1 71 45 10-153 45 30 R1 3&4-Methylphenol(m&p ug/L ND 100 100 62.2 60.8 62 61 16-130 2 30 Cresol) 3,3'-Dichlorobenzidine ug/L ND 200 200 202 216 101 108 10-153 7 30 3-Nitroaniline ug/L ND 200 200 193 191 97 95 22-151 1 30 IL 4,6-Dinitro-2-methylphenol ug/L ND 200 200 64.5 22.4J 32 11 10-180 30 4-Bromophenylphenyl ether ug/L ND 100 100 95.7 97.3 96 97 25-130 2 30 4-Chloro-3-methylphenol ug/L ND 200 200 179 158 90 79 25-133 12 30 4-Chloroaniline ug/L ND 200 200 153 146 77 73 14-132 5 30 4-Chlorophenylphenyl ether ug/L ND 100 100 84.1 82.5 84 82 19-130 2 30 4-Nitroaniline ug/L ND 200 200 186 187 93 93 29-150 0 30 4-Nitrophenol ug/L ND 500 500 ND ND 0 0 10-130 30 M1 Acenaphthene ug/L ND 100 100 65.3 64.3 65 64 16-130 1 30 Acenaphthylene ug/L ND 100 100 65.0 64.1 65 64 15-137 1 30 Aniline ug/L ND 100 100 56.7 52.5 57 52 10-130 8 30 Anthracene ug/L ND 100 100 89.1 89.9 89 90 37-136 1 30 Benzo(a)anthracene ug/L ND 100 100 111 114 111 114 40-145 2 30 Benzo(a)pyrene ug/L ND 100 100 89.7 90.6 90 91 41-146 1 30 Benzo(b)fluoranthene ug/L ND 100 100 85.4 87.8 85 88 39-151 3 30 Benzo(g,h,i)perylene ug/L ND 100 100 80.3 83.4 80 83 40-147 4 30 Benzo(k)fluoranthene ug/L ND 100 100 89.5 90.8 89 91 40-146 1 30 Benzoic Acid ug/L ND 500 500 ND ND 0 0 10-130 30 M1 Benzyl alcohol ug/L ND 200 200 143 137 72 68 25-130 5 30 bis(2- ug/L ND 100 100 73.1 68.4 73 68 23-130 7 30 Chloroethoxy)methane bis(2-Chloroethyl)ether ug/L ND 100 100 71.5 68.8 71 69 25-130 4 30 bis(2-Ethylhexyl)phthalate ug/L ND 100 100 116 120 116 120 28-166 4 30 Butylbenzylphthalate ug/L ND 100 100 119 123 119 123 33-165 3 30 Chrysene ug/L ND 100 100 108 112 108 112 38-141 4 30 Di-n-butylphthalate ug/L ND 100 100 109 112 109 112 32-153 3 30 Di-n-octylphthalate ug/L ND 100 100 104 107 104 107 30-175 4 30 Dibenz(a,h)anthracene ug/L ND 100 100 84.8 88.8 85 89 39-148 5 30 Dibenzofuran ug/L ND 100 100 76.8 75.4 77 75 20-130 2 30 Diethylphthalate ug/L ND 100 100 99.1 98.3 99 98 28-142 1 30 Dimethylphthalate ug/L ND 100 100 94.1 90.8 94 91 26-136 4 30 Fluoranthene ug/L ND 100 100 105 109 105 109 39-143 3 30 Fluorene ug/L ND 100 100 82.7 81.4 83 81 24-132 2 30 Hexachloro-1,3-butadiene ug/L ND 100 100 6.5J 10.2J 6 10 10-130 30 M1 Hexachlorobenzene ug/L ND 100 100 90.3 89.9 90 90 29-130 0 30 Hexachlorocyclopentadiene ug/L ND 100 100 14.5J 13.1J 15 13 10-130 30 v1 Hexachloroethane ug/L ND 100 100 4.5J 10.9J 4 11 10-130 30 M1 Indeno(1,2,3-cd)pyrene ug/L ND 100 100 84.9 88.9 85 89 39-148 5 30 Isophorone ug/L ND 100 100 77.0 72.6 77 73 23-130 6 30 N-Nitroso-di-n-propylamine ug/L ND 100 100 74.0 70.4 74 70 25-130 5 30 N-Nitrosodimethylamine ug/L ND 100 100 66.9 57.4 67 57 22-130 15 30 N-Nitrosodiphenylamine ug/L ND 100 100 93.8 93.5 94 93 26-134 0 30 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 48 of 54 , aceAnalytical PaceAnalytical Services,LLC Kincey Ave. Suite 100 Huntersville,NC 28078 www.pacHehs.cam (704)875-9092 QUALITY CONTROL DATA Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 MATRIX SPIKE&MATRIX SPIKE DUPLICATE: 3683916 3683917 MS MSD 92610548003 Spike Spike MS MSD MS MSD %Rec Max Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD RPD Qual Naphthalene ug/L ND 100 100 27.2 38.2 27 38 14-130 34 30 R1 Nitrobenzene ug/L ND 100 100 68.8 67.6 69 68 25-130 2 30 Pentachlorophenol ug/L ND 200 200 56.4 28.5J 28 14 10-175 30 Phenanthrene ug/L ND 100 100 97.2 97.8 97 98 36-133 1 30 Phenol ug/L ND 100 100 46.8 34.9 47 35 10-130 29 30 Pyrene ug/L ND 100 100 115 113 115 113 40-143 2 30 2,4,6-Tribromophenol(S) % 98 64 10-144 2-Fluorobiphenyl(S) % 60 66 10-130 2-Fluorophenol(S) % 50 21 10-130 Nitrobenzene-d5(S) % 93 81 10-144 Phenol-d6(S) % 50 34 10-130 Terphenyl-d14(S) % 124 126 34-163 Results presented on this page are in the units indicated by the"Units"column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 49 of 54 Pace Analytical Services,LLC 9800 Kincey Ave. Suite 100 aceAnalytical Huntersville,NC 28078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 DEFINITIONS DF-Dilution Factor,if reported,represents the factor applied to the reported data due to dilution of the sample aliquot. ND-Not Detected at or above adjusted reporting limit. TNTC-Too Numerous To Count J-Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PQL-Practical Quantitation Limit. RL-Reporting Limit-The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S-Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270.The result for each analyte is a combined concentration. Consistent with EPA guidelines,unrounded data are displayed and have been used to calculate%recovery and RPD values. LCS(D)-Laboratory Control Sample(Duplicate) MS(D)-Matrix Spike(Duplicate) DUP-Sample Duplicate RPD-Relative Percent Difference NC-Not Calculable. SG-Silica Gel-Clean-Up U-Indicates the compound was analyzed for,but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Reported results are not rounded until the final step prior to reporting.Therefore,calculated parameters that are typically reported as 'Total'may vary slightly from the sum of the reported component parameters. Pace Analytical is TNI accredited.Contact your Pace PM for the current list of accredited analytes. TNI-The NELAC Institute. ANALYTE QUALIFIERS IK The recalculated concentration of the calibration standard(s)did not meet method acceptance criteria;this result should be considered an estimated value. IL This analyte exceeded secondary source verification criteria low for the initial calibration.The reported results should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample(LCS)recovery. R1 RPD value was outside control limits. SO Surrogate recovery outside laboratory control limits. v1 The continuing calibration verification was above the method acceptance limit.Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit.The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. v3 The continuing calibration verification was below the method acceptance limit.Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 50 of 54 1 Pace Analytical Services,LLC s 9800 Kincey Ave. Suite 100 aceAnalytical Huntersville,NC 28078 www.pacalabs.com (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Press Club Cleaners TCR-003 Pace Project No.: 92610548 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92610548001 MW-1 EPA 3010A 705477 EPA 6020E 705490 92610548002 MW-2 EPA 3010A 705477 EPA 6020E 705490 92610548003 MW-3 EPA 3010A 705477 EPA 6020E 705490 92610548004 MW-4 EPA 3010A 705477 EPA 6020E 705490 92610548005 GW-DUP EPA 3010A 705477 EPA 6020B 705490 92610548001 MW-1 EPA 7470A 705899 EPA 7470A 706144 92610548002 MW-2 EPA 7470A 705899 EPA 7470A 706144 92610548003 MW-3 EPA 7470A 705899 EPA 7470A 706144 92610548004 MW-4 EPA 7470A 705899 EPA 7470A 706144 92610548005 GW-DUP EPA 7470A 705899 EPA 7470A 706144 92610548001 MW-1 EPA 3510C 706114 EPA 8270E 706271 92610548002 MW-2 EPA 3510C 706114 EPA 8270E 706271 92610548003 MW-3 EPA 3510C 706114 EPA 8270E 706271 92610548004 MW-4 EPA 3510C 706114 EPA 8270E 706271 92610548005 GW-DUP EPA 3510C 706114 EPA 8270E 706271 92610548001 MW-1 EPA 8260D 706344 92610548002 MW-2 EPA 8260D 706000 92610548003 MW-3 EPA 8260D 706000 92610548004 MW-4 EPA 8260D 706000 92610548005 GW-DUP EPA 8260D 706000 92610548006 Trip Blank EPA 8260D 705694 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced,except in full, Date:06/24/2022 11:10 AM without the written consent of Pace Analytical Services,LLC. Page 51 of 54 -r rurr-nuiv r-Duos vull sample L;ondltion Upon Receipt ce _ Effective Date: 05/12/202205/12/2022 J Laboratory receiving samples: Asheville Edeni ) Greenwood n Huntersville • Raleigh❑ Mechanicsville❑ Atlanta[1] Kernersville0 Sample Condition Client[dme• � Upon Receipt (� 111 WO# • 92610548 464, -4- I UtProject Stliv'efCourier; ❑FedEx ❑UPS CUSPS lent III III II II 111111 III III ❑Commercial ❑Pace ❑Other: 92610548 ---- Custody Seal Present? Dyes o Seals Intact? Dyes 1:2114o ! ‘n�� , Date/Initials Person Examining Contents: r 1'/r Packing Material: ❑Bubble Wrap Bubble Bags N I r g ❑ one ❑ Other Biological Tissue Frozen? Thermomet !� n i/ Dyes ❑No /A IR Gun ID: I, L�1,f,r� , 4 111 v'L`� Type of Ice: [ly/ei ❑Blue [None '1 Correction Factor: Cooler Temp: Add/Subtract(°C) v Temp should be above freezing to 6'C Cooler Temp Corrected('C): j OSamples out of temp criteria.Samples on ice,cooling process ( has begun USDA Regulated Soil/A,water sample) Did samples origins to a quarantine zone within the United States:CA,NY,or SC Did samples originate from a foreign source(internationally, (check maps)?Dyes ❑No including Hawaii and Puerto Rico)?❑Yes ❑No Comments/Discrepancy: Chain of Custody Present? d ❑No ON/A 1. Samples Arrived within Hold Time? es ❑No ON/A 2. Short Hold Time Analysis(<72 hr.)? Dyes No N/A 3. Rush Turn Around Time Requested? Dyes ON/A 4. Sufficient Volume? es ❑No ON/A S. Correct Containers Used? es ONo ❑N/A 6. -Pace Containers Used? ltes ❑No ON/A Containers Intact? k"" ONO i ON/A 7. Dissolved analysis:Samples Field Filtered? Oyes Qfvo ON/A 8. Sample Labels Match COC? ( es ❑No ON/A 9. -Includes Date/Time/ID/Analysis Matrix: Ai/ Headspace in VOA Vials(>5-6mm)? ,ro ❑N/A 10. �J Trip Blank Present? Yes ❑No ON/A 11. Trip Blank Custody Seals Present? es ❑No ON/A - COMMENTS/SAMPLE DISCREPANCY Field Data Required? ['Yes ❑No Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time: Project Manager SCURF Review: Date: PrQjec.Manager SRF Review: _ Date. - Page 52 of 54 Qualtrax ID:69614 Page 1 of 2 v .. rt—r urrr. csvv-rr wi-nVIV 1-UV13J vu I— ample ' oriaition upon Receipt • !Pace Effective Date: 05/12/202205/12/2022 • _ -__- -- ---92610548 `Check mark top half of box if pH and/or dechlorination is verified and Project i Wo1T q/22 within the acceptance range for preservation samples. Due Date 06/2 PM: KRG Exceptions:VOA,Conform,TOC,Oil and Grease,ORO/8015(water)DOC,LLHg CLIENT: 92—Her t. H 1 CIt "'Bottom half of box is to list number of bottles e"`Check all unpreserved Nitrates for chlorine v O J >z r z zx rt., a 2 a zZ ouv a m_¢ z -, z t<1z r. Zz ZNZ7 71 Cz N U z (e no '0v v Ol y Q m in m vNwnOV N _ V O ° rv2 = Q 4D " ¢ ¢ a 2 z a2 2 2 as = _ :; _ c. o. 2°n vn n a ° a y v Z 11 Q Q ,v Z O 0./ , M - nve -- 7a ¢ MeZ ? ai .n n II 41 a 2? O O Q O a O v1 o O7 = -A - aS w cccaIynz Nt7a _ NmzN 0 = c c au v _ = Nz = 2 Z ry a O i z z O • 12 tl u N N i x ` `FA „ i . i, f ' ` w -0 `; .o a m z D = Y m v 7. n = ara tO Ammo a EnEE ¢ ¢ a aa ^ v m E c -0 a a. ia a a a EQQQ qa ¢ O> O O7 O n In i aQ E aJE Ev E o `mE ; E E E E E E EE EA O O — Ny� ev3 _ - = 0ofo00 ' no 0 0 Vo , p, In ...I yNH , HNN ..11 NNR qVp0 N Vl .# 7M N VV7 M {N m LL F. _ M 4 4 Q T i 4 O . aF- 6 6 6 Is-, Nva a a a a a d m1114% , 3Q lQ7 Q Q p p t>7 > O ° > a h a t7 7 m > p IIILN .t 4 illm XI. silk , iim 1 6 ik1 1 11\111 . Mk 7 k , 9NI , \\ LO u 11 I 12 \ . \1410 , . . pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt ri—atepreservation adjusted Time preservation Amount of Preservative [ Lot q adjusted added Note: Whenever there is a discrepancy affecting North Carolina compliance samples,a copy of this form will be sent to the North Carolina DENR Certification Office(i.e. Out of hold,incorrect preservative,out of temp,incorrect containers. Page 53 of 54 Qualtrax ID:69614 Page 2 of 2 CHAIN-OF-CUSTODY /Analytical Request Document ace' The Chain-of-Custody is a LEGAL DOCUMENT All relevant fields must be completed accurately. Submitting a sample via this chain of custody constitutes acknowledgment and acceptance of the Pace Terms and Conditions found at https://info.pacelabs.com/hubfs/pas-standard-terms.pdf. Section A Section B Section C Required Chant Information: Required Project Information: Invoice Information: Page: 1 Of Company. Hart&Hickman Report To: Haley Martin Attention 7 l r Address- 2923 S.Tryon St Copy To. 7-�3 0 T.t A r7 44,r-i-N I C nu N a .�;),�1'1(� ((��i1 �'k�i���.I �f Y1.CC✓� i .L i -. Company Name Suite 100,Charlotte.NC 28203 Address. Regulatory Agency Email: hmartiniaharth:ckman.corn Purchase Order#: Pace Quote. Phone: 17041506-r8107 Fan Project Name. -Tet.e Fre Ss (..1 46 (t LL n l:.( m.j Pace Project Manager: kev godwmapaceiabs.corn State I Location Requested Due Date. •27 J-' j } "'.a, E i'Ct Y Mill Project s. r C.g - 0 C 3 Pace Profile#- 12733 3.4 ` NC Requested Analysis Filtered(Y/N) _ (1--- Z Ma1Rix coos - o COLLECTED Preservatives >- Dr�nung Were OW g U O " Water WI 3 1 -, E Was.water WW _ a o E Prom, Pm CC O N r O Z SAMPLE ID °" tl a ti START END u F.-- \V o o V One Character per box. Wvw Wew L,r. a Z w -.� U `D tO m c (A-Z.0-9/.-) Ad AR 0 5 W :.1 y N Y 7 m is m -. St Sample Ids must be unique Diner of Z Z r7 �. Z SU • P q rusue rs x w w p ei O c jp g ,� Q iq m a H ¢ 0 O. c O 2 U O `" m ,r Q - m m SI o m K i- v VJ L V DATE TIME DATE TIME rn 0 I x M z Z M 0 i`- m w m cc r. cc T' \, - I wT G /,-rr L 55 E L X X X eol 2 M �, � 2 1 1130 1 XX 9J1- 3 Mw - : - - XX ;C 0 4 M '� ' 'a`�� _ , X X X _ d0`? 5 (, ij r 1 — V ✓ < ',),( X 6 i rtP in IV IV - °J) 7 9 10 11 12 _ ` , Q ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE - ITI TIME L ACCEPTED BY f AFFILIATION DATE TIME SAMPLE CONDITIONS -S , F r 9 S 1 w SAMPLER NAME AND SIGNATURE PRINT Name of SAMPLER:-� . c o A m 0 SIGNATURE of SAMPLER: ' DATE Signed: ( 1 w v z iq' at Z E N Z