WQ0024508_Monitoring - 07-2022_20220909 (3)

Monitoring Report Submittal
Permit Number #*
Name of Facility:*
Month: * July
Report Information
Type *
GW-59
WQ0024508
Carolina Research Center
Confirmation Email Address:*
Name of Submitter: *
Signature:
Date of submittal:
Initial Review
Year:* 2022
Upload Document*
GW 59-Smithers July.pdf 2.11 MB
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMIR, NDAR-1, NDAR-2, NDMILR, GW-59).
[e-mail]
Jessica Mize
jwd rA lip
Reviewer: Gerald, Wanda
9/9/2022
This will be filled in automatically

Is the project number correct?* WQ0024508
Is the monitoring report accepted?* Yes No
Regional Office* Winston-Salem
Reviewer: _anonymous
Review Date: 9/13/2022

SUBMIT FARM ON YELt_O'.A' PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL GUALIT ON. OF WATER RE RESOURCES
!GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FOR� . � � 1617 MAIL SERVICE CENTER. RAtEPGH, EEC 2T6 9.1a1 T
FACILITY INFORMATION
>.-ar.;f F,r i PERMIT !lumber: 11'€-}0024' 1)\ Fxpiration Date: .ip til `;t). -'02_1
r l:t„ Name_ +.-..siht a Peac ,ch t';_. cr Noon-Dis harrve UIC
ern-ut Plan te I f c r' e,eriti
Simmers Vkcrcm I I. ' NPDFS Gather
F _slit== Address: =ana t )ti-tl; rit €t It Ror r l TYPE OF PERMITTED OPERATION BEING MONITORED
County;?I,titt.rttc Lagoon Rerred€ alionl; Infiltrat>on Gapers:
0 Spray Field El iiemedia ivxi
CUlitaze., Person, Ciw,� zieske Telephone',: •-_6-:71<._0I ? l El f-'.�rtP, x` Distributor ®'Land Appltcaflon _ f Sludge
)i,Vell L:cafianl i:e Harr e; IMF of welts to be sampled:
EJ Water Soot-ce Heat Pump E Ir.
SAMPLING INFORMATION
It WELL
WELL [Cf NUMBER (from Permit): x I\\ -3
Ciate s mplr� cQl e+ t d: is yp 2022-
FIELD ANALYSES:
WAS
�!+ I_!
=vein Both' I ft.
-r{I Diameter:
Ve � . ,.
[ r1 „, , :, =<il:ts Tci. p t, t
€ C
e .
. R'Y�;t
R,
DIDth tr `,"eater Level ..:- it. o to measuring point Scrotaned Interval: tt
to f.
Spec. Cod „o_r
lr;Erc of
-
sampling,
i s ri c Point it is if, 3bove land surface
F I rti=? fal.t '. Oevalron
ft.
Odor c ^tt9
check
VoWine of water p lrTi ed bided be,r,r� san cling. i .
dalln. s
Appearance
it.'re,
Samples tzar metals were collected unfiltered° W YEl: S
(l NO and field acidified [N YES
El NO
LABORATORY INFORMATION
Date sanip e analyzed: (t .'8-ll�;t l tl, 20-12
Laboratory Nine. P acc Atriil�tic
it N::i jccs
Cerlificati€art Ns
-ttl 033
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD , .,t rL
Nitrite (,NO_-) as N cts>>F
mrili.
Ph 1 en
ug1L
Coliform MIF , ecal ;. [st-a <IM 110011il._
Nitrate (NO:,.) as N o'cu---1 is.}
fnq!L
Zn Zinc J�-=l
cil-
Co o, rn MF ! oa' v?=,< '1' 0ml-
Phosphorus" Total as P 3A
mcrT
Orthophosphate
111grL
Other (Sp eciEv Corn pot and Concentration
Units),
jissolved So'ids_Total = S5.9 mg? L
A$ - Aliurnit uni o i € :
mg L
PH (Lab) . can i units
B a - Far in t „`
ugfL
TOC ,ri ,3w I . r„alL
Ca - Catcturn l a
rnq;L
i Chloride fic9 s 4.7 rnmL
Cd - Cadmium o-'e
ug1L
Arsenic �vur'=_- ugtL
� �ii t
Chr�n�tun�' Total �
tglL
Grease and .. r.-:=.Luz.
-
'? . L
Cu Capp :+, _-,.
mqT
ORGANICS: (bv EEC. GCIMS. HPLC)
Phenol - rra
uglL
Le - Iran , miL. ,
ug1L
(Specify test and method 4. ATTACH LAB REPORT.)
Sr(fare =E; 5 -
n L
Flo Men.-.iry 7 1qo,
ug/L
Late Report Attached? Eli ''Peck) El Now
,::,l,:C `c),�etni�t nc. .5� •�r-
of`,`lhas
K- Potassium ooq-,�= _
i-1 gig-
lt€�'._. '�74 - methoo rx
Total Arnmeniz, ...I ;1. t .ItI
nna;'L
>~ (I Macnesium ri[;il•I?;
rN a/L
Iti tlt+? f
v.
Mn r tal ariese -
ug/L
method
KN as N :Qr_'
ntaI
Ni - Ni a,el o,,Lj&7
ugfL
inethod
For Rernediation Systems Only (Attach Lab Reports):
r �;iy 3tx 1 it.-L' €.)11
Influen- rcital VOC.s
m 'L Effluent Total VOCs:
mg'L VOC Removal°'_

SUBr•.•11T FODt?r I ON YELLO'Ar PAP--R ONLY
rqDEPARTMENT OF ENVIRONMENTAL QUALITY . DIV, OF WATER PESOJr'- ES
GROUNDWATER QUALITY MONITORING: � . - .. INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER, RALEIG , NC 27699a1617
FACILITY INFORMATION _y a a` y "- 7:pe PERMIT Nurnber:yy titllt'-I_ 0S Expiration Date Al
t1 'II"
I
Faci :ter N.-n e t . it,r1 t 1.;s=° 51€ t'Cin-j Non-OisHharne L1lC - -
r.n.. i Name hT clr I r=r i;it S,a i;IrL€, 4 4 €c�Et L._t. NPDES Otfle.r
--
Fa'---�flib Address_ ''?€It r t.r ._.E'3zl it Road TYPE OF PERMITTED OPERATION BEING MONITORED
-- —
SI..r,, Camp N(' County, rll.,.imi c Lagoon Rernediation InNtication Ga left'
® Spray Field ❑ Reinediatio
ccrr'.ac't Person Crrr:, F Wskc Telephone# ,s 170-01-11 El P lary DiStributo, ® Land Appficalion of Sludge -.
E%`ef Locat€on"Site Narne No, o� wells to be sariPted: Water Source Heat Pump © Other
SAMPLING INFORMATION
If WELL
WELL ID NUMBER (train Permit): alto'-_
Date sarnple =wullected: 0
27 et)'b
FIELD ANALYSES:
WAS
Wei! Depth � Iit
- rt� l [flan €ter;
n.
c�Ff 4r. 3I ; ,� ttr�its
TCrap C.g:,IL `It-; =c
DRY at
13 "r . below me sunng point S,rcened I'ntcrvai:
to It,
Spec, C=gin J 094
11111105
tine (r
.r3 ipling,
M asurina Point €s it. above laird sutra e
Relative N1.P, Elevation:
ft.
Odor ,wwa-.
heck
lu me of 3ater Lum r /laa,l a before sampling 1 'z
gallons
An,earance
nere.�
Samn;es for metals were collected unfiltered: N YES
NO and field acidified. M YES
NO
LABORATORY INFORMATION
tat ; sa nfle anafy-ze I, =�,-08. It)1" 02'
LaDorat=_,ry N me I'.i 11f .I.ts.tll
=,I in ,
Cbrtiflr.�.tion
No. •Ita
PARAMETERS NOTE; Values should reflect dissolved and colloidal concentrations.
CLAD oia S mr;`L
Nitrite j'NO.) as N _ _z1;,
n 1,'L
Pb - Lead o }u,
urgiL
Crshiorm, MF Fecal sat; : _ l,{# 1t~0mr,
Nitrate INO,I as N ce620 Ltl.�ti
aid L
III - Zinc , .,_
rra°L
Cofif mn, NIF Total .. " (,,DniL
Phosphorus:Total`ice r' i°F1V � 1. s
n --I"L
Orthophosphate :0t,;:,
ttl'`L
ether iSpesif}=Compounds
and t..nncer,rrac:cria tJrr3as.
solved Sol€ds Tot l J „ 1011 kT a,L
A! - Aluminum (;i "r_`
nigT
PH i r.LI f u- _: units
Ba - Banutn ovau;
ugtL
TOC (r -'Tib 3 I .o nigN1
Ca - Calcium m s3Coic
nigil-
.hlcririe 00t,,ro rngiL
Cd - CadI1111,1111 lr127
ug/L
Arsenic iou-- ug1L
011-0rultim Total usruitx.
ug]L
Grea%e and Oils _n-,
nia''L
Cu - Copper v=tlw,
rtttlr
ORGANICS: iby= GC. Cry r IS. HPLC)
Phenol z vs£
uglL
Fe - Ir-" 01--us
ugil-
(Specify test and method - ATTACH LAB REPORT.)
`tsl lie. . ,t
tt `L
Hg -Mercury 719i,*
ugiL
Lab Report Attached? Yc>n (1) No i"tt'
cr
*
Potassium
__.
tgLar!
-.._
{tit 78,= rnethod .»
Total Arriiuc.nia -,_lo - 0,10
nt;.`L
Mq .. agne5iUrn 012927.
ing,L
,. method P
. - N �, . <„ _ f
.
Mn Manganese'jli ur,
uglL
rnet,tad ;
TliN as N ,.,.; <
rng L
Ni - N c el _,-M,67
utg]L
method
For Remediation Systems Only (Attach Leh Reports): Influent Taal i OC s: naq%L Effluent Total VOCs: mg, L VOC Removal-
Pwirrtoe v .+u hori. UPI Agru 0 N ,., v aiul I e_L - .ea_ e r .re € ur lone
GIN-59 2 06-07--'tJl%3

SUBMIT FORM ON YELLOW PAPER ONLY
OEPARTME iT OF ENVIRONMENTAL LtALN's . DIV OF NEATER RESOURCE
GROUNDWATER QUALITY MONITORING: � � � INFOP iATION PROCESSING UNIT
COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER. RALEIGH, NC 2' 99-161'.
FACILITY INFORMATION pwaseFrrraCll , vo, 7vpe PERMIT Number: wt oo_,_I�I)s Expiration Date- April .=ll. 2024 -
a_ility Name- `e- l `:aroh It -.Se, ill -h {chit l Nou_ is i mo UIC
r-rt i s )ante (if difie nT' Smith) Vi+cieni LL% NPDES Oiher
Facility Address: 'itrttl 0ua1;CnN I1 Rood TYPE OF PERMITTED OPERATION BEING MONITORED
n t IItt S il, ,l } Al.tin:uicc
L�un1}� ❑ Lag-oon ❑ fF'c'1[iec?E3ti{1rt: tr1l[ltrCil#ciil Gallery
❑ Snra, Field ❑ Rtjue i lion:
Ctrae, Person (JuN ; Ic4.c Te°ehone4: i fir170-1 141 ❑ Rotary Disiri utor ❑ Land Application of Slung
Well Lora ion!Sile Name Noof wells to he ;-ampled' ; ❑.':rater Source Heat Pump ❑ Omer:
WELL ID NUMBER (from Permit): file €
j' II Dzjr
j1h, T
Depth to ',,' ater L-Vel . ,' -r_i ft. oeln . ine asunn=g point
Nieasuri .o Foint is t. above land surface
Volume of .rater pumlle.d1basled before sampling
Sannoles for metals .were collected unfiltered: [K YES
Date sampie collected: 07F271,2022
Well Diameterin.
Screened interval, ft, to ft.
Relative I L P. Elevation' ft .__.W
gallons
NO and fEeld acidifier): A YES ❑ NO
Cate sample analvzed. Laboratory Name:
PARAMETERS NOTE: Values should reflect dissolver) and colloidal concentrations.
COD 00355
n a.1
Nitrite (NO,1 as N 00615
-_:irorrn: M-- Fecal ,t tt.
, 00ML
Nitrate (NO..' as N 00620
Colitorm- MF Total
i100rn L
Phosphorus: Trltal as P 4r=6rsc®
N __, U _. u 1 r .hi..-:
OrIbophosphat uta: ,
�idveu Solids Total
n.y'L
Al - t lumi ur i , ., - g
pH (Lab) :t -,3,
units
B,a - Barium oeeo
i)f' €.f-e Cz ``-7
nia L
--
Co ` Calr,Eurn 00906_
Chloride oxl4e
rng''L
Cd - Cadmium "t_=.e
ArSen1 ti'°u_
uglL
Chromium,'oral = u=
Grease anti Oil$ rjuN_._
mg-1
Cu = )Copper 1 vi.112
_...
Phenol :`"m,
ug/L
�� < Iran 5. r•,�i
Swfale __ � .
rrtg: 1
H_ f lurcr ry f is?
3oc-cific Condtiti,.Irance 'c ; s,.
ilMhos
K - Potassium oosila?
Total Arum? is nocilo
mcd. L
Mg - Nlagnesium C,092'
T KN as N iluz5
rug/L
Ni - Nickel o. f;—,
mg/
aujiL
mg/L
mglL
mr"
uglL
ntu1L
ugiL
uglL
ma iL
ug7L
ug/L
nig[L
n Ig;L
ug/L
ug/L
FIELD ANALYSES:
pH on;to units
Spec Conti v nay,4
Odor c cia
Appearance
Ph Len inSi
bn - Zinc . 9?
l'` WELL
Temp woios CDRY at
tirite ofIrl tn�==s
Certification N€,.
uglL
mo;L
Other iSpec&,r Compounds, and Conte ati ation nits
ORGANICS: (icy GC. GC/MS, HPLC:)
(Specify test and method #. ATTACH LAB REPORT.)
Lab Report Attached` ❑ es (l ) ❑ Per i la
V 0 C __ method 4
method
method
uethod v
For Remediation Systems Only (Attach Lab Reports): Influent Total VOCs: mgiL Effluent Total VOCs: mg/L VOC Removal%

GROUNDWATER MONITORING FIELD LOG
Facility Carolina Research Center
Weather 77°-Sunny
Personnel Present: COMMENTS:
July 27, 2022 Garrett Dreyer
Date
-- ----- ----
�otal Depth (FT.)
11111111111111W,
WaterDepth(FT.)
Conversion Factor
Well Volume (GAL.)
Volume (GAL.) X 3
Volume Removed (GAL.)
QamplingDate
SamplingTime(hrs.)
�ampling Method
�pil (Standard Units)
Conductivity(pmhos/cm)
Dissolved Oxygen (mg/L)
�tbservatlons/Sampling

aceAnalytical
www.pacdabsxom
l(
ANALYTICAL RESULTS
Project: Carolina Research Center
Pace Project No.: 92617073
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Sample: MW 2
Lab ID: 92617073001 Collected: 07/27/22 10:45
Received: 07/27/22 14:30 Matrix: Water
Parameters
Results Units Report Limit DF
Prepared Analyzed
CAS No. Qual
2540C Total Dissolved Solids
Analytical Method: SM 254OC-2015
Pace Analytical Services - Eden
Total Dissolved Solids -
100 mg/L 55.6 1
08/02/22 11:10
353.2 NO2IN03 unpres EDN
Analytical Method: EPA 353.2 Rev 2.01993
Pace Analytical Services - Eden
Nitrogen, Nitrate
ND mg/L 0.20 5
07/28/22 18:14
14797-55-8
MB10 9222D Fecal Coliform EDN
Analytical Method: SM 9222D-2015 Preparation Method: SM 9222D-2015
Pace Analytical Services - Eden
Fecal Coliforms
ND CFU/100 mL 1.0 1
07/27/2215:22 07/28/2213:45
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Chloride
3.5 mg/L 1.0 1
07/30/22 08:16
16887-00-6
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.01993
Pace Analytical Services - Asheville
Nitrogen, Ammonia
NO mg/L 0.10 1
08/10/22 12:43
7664-41-7
365.1 Phosphorus, Total
Analytical Method: EPA 365.1 Rev 2.01993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
Phosphorus
4.8 mg/L 0.050 1
08/03/2218:08 08/0412218:28
7723-14-0
5310B TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services - Asheville
Total Organic Carbon
ND mg/L 1.0 1
08/02122 07:18
7440-44-0
Date: 08/29/2022 01:37 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 20

Pace Analytical Services, LLC
® 9800 KinceyAve. Suite 100
aLaumalytical Huntersville, NC 28078
www.pacelabsxam [phone]
ANALYTICAL RESULTS
Project Carolina Research Center
Pace Project No.: 92617073
Sample: MW 3 Lab ID: 92617073002 Collected: 07/27/22 10:10 Received: 07/27/22 14:30 Matrix: Water
Parameters
2540C Total Dissolved Solids
Total Dissolved Solids
353.2 NO2/NO3 unpres EDN
Nitrogen, Nitrate
MBIO 9222D Fecal Coliform EDN
Fecal Coliforms
300.0 IC Anions 28 Days
Chloride
350.1 Ammonia
Nitrogen, Ammonia
365.1 Phosphorus, Total
Phosphorus
5310E TOC
Total Organic Carbon
Date: 08/29/2022 01:37 PM
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Analytical Method: SM 2540C-2015
Pace Analytical Services - Eden
85.9 mg/L 29.4 1 08/02/2211:10
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services - Eden
ND mg/L 0.20 5 07/28/2218:16 14797-55-8
Analytical Method: SM 9222D-2015 Preparation Method: SM 922213-2015
Pace Analytical Services - Eden
ND CFU/100 mL 1.0 1 07/27/2215:22 07/28/22 13:45
Analytical Method. EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
4.6 mg/L 1.0
1 07/30/22 08:35
16887-00-6
Analytical Method: EPA 350.1 Rev 2.01993
Pace Analytical Services - Asheville
ND mg/L 0.10
1 08/10/2212:47
7664-41-7
Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993
Pace Analytical Services - Asheville
5.4 mg/L 0.10
2 08/03/2218:08 08/04/2219:19
7723-14-0
Analytical Method: SM 531OB-2014
Pace Analytical Services - Asheville
1.7 mg/L 1.0
1 08/02/22 08:06
7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, I.I.C.
Page 5 of 20

Pace Analytical Services, LLC
Kincey Ave.10
ace MalXical a 9800Hun ersville, C'te 28078
WWW. paceiatis.cam [phone]
CERTIFICATIONS
Project: Carolina Research Center
Pace Project No.: 92617073
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Flodda/NELAP Certification #: E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification #: 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification #: 40
Pace Analytical Services Eden
205 East Meadow Road Suite A, Eden, NC 27288
North Carolina Drinking Water Certification M 37738
North Carolina Wastewater Certification #: 633
Virginia/VELAP Certification #: 460025
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 20

CHAIN -OF -CUSTODY Analytical Request ocur> ent
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Chain -of -Custody is aLEGAL DOCUMENT - Completeall releventfields
111111111111111apany:
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Carolina Research
Center
Billing lnformatlon:
n ., �- 9261 73
Container Preservative Type
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sort To:
I
Email To:
,* Preservatisre Types: (1) nitric acid, (2) sulfuric add, (3) hydrochloric acid. (&) sodium hydroxlde, (5) zinc acetate, -
(6) methanol, (7) sodium Wutfate, (8) sodium thiosulfate, (9) hexane, (A) ascorbic add, (B) ammonium sulfate,
(C) ammonium hydroxide. (D) TSP, Jul Unpr rved, (Q) Other
ry To:
j
Site Collection Info/Address:
Analyses
tourer Project Name/Number:'
-
Mate: County/City; Time Zone Collected;
MT I ] CT
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3
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Site/Facility ID #:
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Purchase Order €f:
DW PWS IID #:
Quote#:
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Imme late y Pace on ice:Yes
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as appropriate ( ] Retu
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,Dispose .-
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C ] Day C ] Day I ] a Day I. IS Day
Analysis:
aIIII�>_tI
Hold -
Hold:
(Expedite Charms Apply)
0
Z
0
latrix Codes (insert in Matrix b6x
below): Drinking Water (DW), Ground Water (GW), Wastewater ( VV],
roduct (P), SoiVSolid (Sl_), Oil (91.1,
Wipe (WP), Air (AR), Tissue (TS), Bioassay (B), Vapor (Y), Either (UT)
-
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tra
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1._ l—
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Comp
Comp /
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Composite Start)
Composite End
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Ctns
t`s
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ram.., �=I - .: x� ,�,.:---
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tons / Possible Hazards,
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Groundwater onittariM I
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i u _ y: (Signature)
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