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HomeMy WebLinkAbout20030147 Ver 0_Monitoring Plan_20070511Yadkin-Pee Dee River Hydroelectric Project FERC No. 2206 MONTHLY WATER QUALITY STUDY OF LAKE TILLERY, BLEWETT FALLS LAKE, AND ASSOCIATED TAILWATERS Water Resources Work Group Issues No. 7 and 8 - Lake Tillery and Blewett Falls Lake and Tailwaters Water Quality PROGRESS ENERGY APRIL 2006 C 2006 Progress Energy TABLE OF CONTENTS Section Title ACRONYM LIST .................................................................................................... AL-1 EXECUTIVE SUMMARY ..........................................................................................ES-1 SECTION 1 - INTRODUCTION .................................................................................... 1-1 No. 1.1 Study Overview ............................................................................................................. 1-1 1.2 Surface Water Quality Classifications of Waters Associated with the Project ............. 1-2 1.3 Identified Sources of Water Quality Impairment of Waters Associated with the Project ............................................................................................................................ 1-2 SECTION 2 - STUDY OBJECTIVES ............................................................................. 2-1 SECTION 3 - SITE DESCRIPTION ............................................................................... 3-1 3.1 General Locale Description ........................................................................................... 3-1 3.1.1 Tillery Development .......................................................................................3-1 3.1.2 Blewett Falls Development ............................................................................. 3-4 3.2 Sampling Sites ...............................................................................................................3-5 3.2.1 Lake Tillery and Pee Dee River Tailwaters below Tillery Development....... 3-5 3.2.2 Blewett Falls Lake and Pee Dee River Tailwaters below Blewett Falls Development .......................................................................................... 3-6 SECTION 4 - METHODS ............................................................................................ 4-1 4.1 Conduct of Study ........................................................................................................... 4-1 4.2 Data Reduction and Analysis ........................................................................................ 4-2 4.3 Quality Assurance and Quality Control ........................................................................ 4-4 SECTION 5 - RESULTS AND DISCUSSION .................................................................. 5-1 5.1 Climatological and Hydrological Conditions during the Study Period ................... ...... 5-1 5.2 Lake and Tailwater Flow Conditions During Water Quality Sampling Trips ........ ...... 5-8 5.3 Water Quality Results .............................................................................................. .... 5-12 5.3.1 Lake Tillery ............................................................................................... .... 5-12 5.3.2 Pee Dee River Reach from the Tillery Hydroelectric Plant to Blewett Falls Lake .................................................................................................. .... 5-30 5.3.3 Blewett Falls Lake .................................................................................... .... 5-48 5.3.4 Pee Dee River Reach below the Blewett Falls Hydroelectric Plant ......... .... 5-67 i TABLE OF CONTENTS (Continued) Section Title 5.3.5 Longitudinal Trends in Water Quality Parameters for Project Waters During 2004 .................................................................................................. 5-80 5.3.6 State Water Quality Standards at Project Reservoirs and Tailwaters........... 5-85 SECTION 6 - SUMMARY ........................................................................................... 6-1 SECTION 7 - REFERENCES ........................................................................................ 7-1 APPENDICES No. APPENDIX A - RAW DATA LISTING FOR WATER QUALITY PARAMETERS COLLECTED IN LAKE TILLERY, THE PEE DEE RIVER, AND THE ROCKY RIVER DURING 2000, 2001, 2002, AND 2004 APPENDIX B - RAW DATA LISTING FOR WATER QUALITY PARAMETERS COLLECTED IN BLEWETT FALLS LAKE AND THE PEE DEE RIVER DURING 1999,200 1, AND 2004 APPENDIX C - RAW DATA LISTING FOR WATER CHEMISTRY PARAMETERS COLLECTED IN LAKE TILLERY, THE PEE DEE RIVER, AND THE ROCKY RIVER DURING 2000, 2002, AND 2004. APPENDIX D - RAW DATA LISTING FOR WATER CHEMISTRY PARAMETERS COLLECTED IN BLEWETT FALLS LAKE AND THE PEE DEE RIVER DURING 1999, 2001, AND 2004. APPENDIX E - MONTHLY TRENDS IN SOLIDS, TURBIDITY, AND NUTRIENT CONSTITUENTS IN LAKE TILLERY, REACH 1 OF THE PEE DEE RIVER, ROCKY RIVER, AND THE HEADWATERS OF BLEWETT FALLS LAKE DURING 2004 APPENDIX F - MONTHLY TRENDS IN SOLIDS, TURBIDITY, AND NUTRIENT CONSTITUENTS IN BLEWETT FALLS LAKE AND REACH 2 OF THE PEE DEE RIVER DURING GENERATION FLOWS IN 2004 ii LIST OF FIGURES Title Figure 3-1 Map of the Tillery Development and Pee Dee River (Reach 1) showing transects used in the monthly water quality study during 2004 .......................... Figure 3-2 Map of the Blewett Falls Development and Pee Dee River (Reach 2) showing transects used in the monthly water quality study during 2004 .......................... Figure 5-1 Comparison of monthly precipitation from 1999 to 2001 (gray bars) with the 30-year average (black line) and ranges of precipitation (vertical lines) for the period 1971 to 2000 ............................................................................................ Figure 5-2 Estimated stream flow (cfs) of the Pee Dee River (Reach 1) below the Tillery Hydroelectric Plant, 1999 to 2004 ...................................................................... Figure 5-3 Daily mean stream flow (cfs) (thin line) and historical long-term daily mean stream flow (thick line) for period of record at USGS gaging stations located on the Pee Dee River, North Carolina-South Carolina, below the Blewett Falls Hydroelectric Plant .................................................................................... Figure 5-4 Daily mean lake levels for Lake Tillery and Blewett Falls Lake during years that monthly water quality surveys were conducted at the Tillery and Blewett Falls developments, 1999 to 2004. (Note: No surveys were conducted in 2003.) .................................................................................................................. Figure 5-5 Total monthly flow (generation flows and dam spillage) from the Tillery Development during years that water quality surveys were conducted at the Yadkin-Pee Dee River Hydroelectric Project, 1999 to 2004. (Note: No wate quality surveys were performed in 2003.) .......................................................... Figure 5-6 Total monthly flow (generation flows and dam spillage) from the Blewett Falls Development during years that water quality surveys were conducted at the Yadkin-Pee Dee River Hydroelectric Project, 1999 to 2004. (Note: No water quality surveys were performed in 2003.) ............................................... Figure 5-7 Total generation flows (cfs) at the time that water quality sampling was conducted at the Tillery and Blewett Falls lakes and tailwaters, 1999 to 2004. (Note: Samples were collected at Tillery Development during 2000, 2002, and 2004 and at Blewett Falls Development during 1999, 2001, and 2004.).... Figure 5-8 Temporal and spatial trends in chlorophyll a concentrations in Lake Tillery during 2000, 2002, and 2004. (Note: Statistical results among lake stations are shown within each graph with different letter superscripts indicating age No. .3-2 .3-3 .5-2 .5-4 .5-5 .5-7 r .5-9 5-10 5-11 significantly different mean values.) .............................................................. ... 5-21 Figure 5-9 Monthly water temperature profiles in Lake Tillery during 2004 .................. ... 5-28 Figure 5-10 Monthly DO profiles in Lake Tillery during 2004 ......................................... ... 5-29 Figure 5-11 Monthly water temperature profiles in Lake Tillery during 2000 .................. ... 5-31 Figure 5-12 Monthly DO profiles in Lake Tillery during 2000 ......................................... ... 5-32 Figure 5-13 Monthly water temperature profiles in Lake Tillery during 2002 .................. ... 5-33 Figure 5-14 Monthly DO profiles in Lake Tillery during 2002 ......................................... ... 5-34 Figure 5-15 Monthly trends in water temperature, DO, specific conductance, pH, and turbidity at Stations TY1B and TY12B in Reach 1 of the Pee Dee River iu LIST OF FIGURES (Continued) Title Figure 5-16 Figure 5-17 Figure 5-18 Figure 5-19 Figure 5-20 Figure 5-21 Figure 5-22 Figure 5-23 Figure 5-24 Figure 5-25 5-45 5-46 TY1B and TY1213.) ........................................................................................... 5-47 below the Tillery Hydroelectric Plant and Station RR located in the Rocky River during 2000. (Note: No data were collected for Rocky River, Station RR, during 2000) ............................................................................................. Monthly trends in water temperature, DO, specific conductance, pH, and turbidity at Stations TY1B and TY12B in Reach 1 of the Pee Dee River below the Tillery Hydroelectric Plant and Station RR located in the Rocky River during 2002 ............................................................................................ Monthly trends in water temperature, DO, specific conductance, pH, and turbidity at Stations TY1B and TY12B in Reach 1 of the Pee Dee River below the Tillery Hydroelectric Plant and Station RR in the Rocky River during 2004. (Note: Power generation flow data are plotted for Stations Temporal and spatial trends in chlorophyll a concentrations in Blewett Falls Lake during 1999, 2001, and 2004. (Note: Statistical results among lake stations are shown within each graph with different letter superscripts indicating significantly different mean values.) ................................................ 5-56 Monthly water temperature profiles in Blewett Falls Lake during 2004........... 5-61 Monthly DO profiles in Blewett Falls Lake during 2004 .................................. 5-62 Monthly water temperature profiles in Blewett Falls Lake during 1999........... 5-63 Monthly DO profiles in Blewett Falls Lake during 1999 .................................. 5-64 Monthly water temperature profiles in Blewett Falls Lake during 2001........... 5-65 Monthly DO profiles in Blewett Falls Lake during 2001 .................................. 5-66 Monthly trends in water temperature, DO, specific conductance, pH, and turbidity at Stations BF1B, BF213, BF313, and BF413 in Reach 2 of the Pee Dee River below the Blewett Falls Hydroelectric Plant during 1999 ............... 5-77 No. Figure 5-26 Monthly trends in water temperature, DO, specific conductance, pH, and turbidity at Stations BF1B, BF213, BF313, and BF413 in Reach 2 of the Pee Dee River below the Blewett Falls Hydroelectric Plant during 2001 ............... 5-78 Figure 5-27 Monthly trends in water temperature, DO, specific conductance, pH, and turbidity at Stations BF1B, BF213, BF313, and BF413 in Reach 2 of the Pee Dee River below the Blewett Falls Hydroelectric Plant during 2004. (Note: Power generation data were plotted for all stations.) ........................................ 5-79 Figure 5-28 Spatial trends (means and ranges) in solids constituents, turbidity, and specific conductance in Lake Tillery, Blewett Falls Lake, and Reaches 1 and 2 of the Pee Dee River under power generation flow conditions during 2004. (Note: Statistical results are given for each water quality parameter and different letter superscripts indicate statistically different mean values.) ......... 5-81 Figure 5-29 Spatial trends (means and ranges) in nutrient constituents in Lake Tillery, Blewett Falls Lake, and Reaches 1 and 2 of the Pee Dee River under power generation flow conditions during 2004. (Note: Statistical results are given 1V LIST OF FIGURES (Continued) Title for each water quality parameter and different letter superscripts indicate statistically different mean values.) ................................................................... 5-82 Figure 5-30 Spatial trends (means and ranges) in anions and cations in Lake Tillery, Blewett Falls Lake, and Reaches 1 and 2 of the Pee Dee River under power generation flow conditions during 2004. (Note: Statistical results are given for each water quality parameter and different letter superscripts indicate statistically different mean values.) ................................................................... 5-83 No. v LIST OF TABLES Table Title No. Table 3-1 Coordinates for water quality stations located in Lake Tillery, Blewett Falls Lake, and associated tailwaters of the Pee Dee River (Reaches 1 and 2) below the Tillery and Blewett Falls Hydroelectric Plants during the monthly water quality study, 2004 ............................................................................................... 3-5 Table 4-1 Laboratory analytical methods, sample holding times, preservative types, and laboratory detection limits for water chemistry parameters analyzed for the monthly water quality studies at the Tillery and Blewett Falls developments.... 4-2 Table 5-1 Means, ranges (in parentheses), and spatial trends of selected water chemistry parameters from the surface and bottom waters at Stations TY132, TYF2, and TYK2 of Lake Tillery during 2004 .................................................................... 5-13 Table 5-2 Comparison of spatial trends of annual means for selected water chemistry parameters from the surface waters of Lake Tillery (Stations TY132, TYF2, and TYK2) for 2000, 2002, and 2004 ................................................................ 5-15 Table 5-3 Comparison of temporal trends of annual means for selected water chemistry parameters from the surface waters of Lake Tillery (Stations TY132, TYF2, and TYH2) for 2000, 2002, and 2004 ................................................................ 5-17 Table 5-4 Paired t-test results of differences between surface and bottom waters for selected water chemistry parameters in Lake Tillery during 2004 .................... 5-19 Table 5-5 Paired t-test results of differences between surface and bottom waters for selected water chemistry parameters in Lake Tillery during 2000, 2002, and 2004 .................................................................................................................... 5-20 Table 5-6 Kendall's tau b correlation coefficients of daily average lake level versus water quality parameters in the surface waters of Lake Tillery (Stations TY132, TYF2, and TYK2) for the years 2000, 2002, and 2004 ......................... 5-23 Table 5-7 Kendall's tau b correlation coefficients of daily average flow versus water quality parameters in the surface waters of Lake Tillery (Stations TY132, TYF2, and TYK2), the Pee Dee River tailwaters below the Tillery Hydroelectric Plant (Station TY113), and the Rocky River (Station RR) for the years 2000, 2002, and 2004 ......................................................................... 5-24 Table 5-8 Means, ranges (in parentheses), and spatial trends of water quality parameters from the surface waters (0.2 m depth) at stations within Lake Tillery during 2000, 2002, and 2004 ......................................................................................... 5-25 Table 5-9 Means, ranges (in parentheses), and spatial trends of selected water chemistry parameters during the no power generation period in Reach 1 of the Pee Dee River below the Tillery Hydroelectric Plant and the Rocky River during 2004 .................................................................................................................... 5-35 Table 5-10 Means, ranges (in parentheses), and spatial trends of selected water chemistry parameters during the power generation period in Reach 1 of the Pee Dee River below the Tillery Hydroelectric Plant and the Rocky River during 2004 .................................................................................................................... 5-37 vi LIST OF TABLES (Continued) Table Title Page No. Table 5-11 Paired t-test results of differences for selected water chemistry parameters between power generation and no power generation flows at Stations TY1B and TY1213 in Reach 1 of the Pee Dee River below the Tillery Hydroelectric Plant during 2004 ............................................................................................... 5-39 Table 5-12 Comparison of temporal trends of annual means for selected water chemistry parameters from bottom waters at Station TY132 in Lake Tillery and surface waters at Stations TY1B and TY12B in the Pee Dee River below the Tillery Hydroelectric Plant during 2000, 2002, and 2004 ............................................. 5-41 Table 5-13 Spatial trends of mean concentrations of selected water chemistry parameters at Station BF132 (bottom waters) in Lake Tillery, Stations TY1B and TY12B in Reach 1, Rocky River, and Station BFH2 in Blewett Falls Lake headwaters during 2004. Power generation flow data (except Rocky River) were used for the analysis ................................................................................................... 5-43 Table 5-14 Means, ranges (in parentheses), and spatial trends of water chemistry parameters from the surface and bottom waters of Blewett Falls Lake (Stations BF132, BFF2, and BFH2) during 2004 ............................................... 5-50 Table 5-15 Comparison of spatial trends of annual means for selected water chemistry parameters at Stations BF132, BFF2, and BFH2 from the surface waters of Blewett Falls Lake for 1999, 2001, and 2004 .................................................... 5-52 Table 5-16 Comparison of temporal trends of annual means for selected water chemistry parameters from the surface waters of Blewett Falls Lake (Stations BF132, BFF2, and BFH2) for 1999, 2001, and 2004 ..................................................... 5-53 Table 5-17 Paired t-test results of differences between surface and bottom waters at Stations BF132 and BFF2 for selected water chemistry parameters in Blewett Falls Lake during 2004 ...................................................................................... 5-55 Table 5-18 Kendall's tau b correlation coefficients of daily average lake level versus water quality parameters in the surface waters of Blewett Falls Lake (Stations BF132, BFF2, and BFH2) for the period of 1999, 2001, and 2004 .................... 5-57 Table 5-19 Kendall's tau b correlation coefficients of daily average flow (cfs) versus water quality parameters in the surface waters of Blewett Falls Lake (Stations BF132, BFF2, and BFH2), the Pee Dee River tailwaters below the Blewett Falls Hydroelectric Plant (Stations BFH3 and BF213), and the lower Pee Dee River (Stations BF133 and BF134) for the years 1999, 2001, and 2004 ............. 5-59 Table 5-20 Means, ranges (in parentheses), and spatial trends of selected water chemistry parameters from the surface waters in Reach 2 of the Pee Dee River below the Blewett Falls Hydroelectric Plant during power generation flows, 2004.... 5-68 Table 5-21 Comparison of temporal trends of annual means for selected water chemistry parameters from the surface waters at Station BF132 in Blewett Falls Lake and surface waters at Stations BF113, BF213, BF313, and BF413 in the Pee Dee River below the Blewett Falls Hydroelectric Plant during 1999, 2001, and 2004 .................................................................................................................... 5-71 vu LIST OF TABLES (Continued) Table Title No. Table 5-22 Means, ranges (in parentheses), and spatial trends of selected water chemistry parameters from the surface waters at Stations BF1B and BF213 in Reach 2 of the Pee Dee River below the Blewett Falls Hydroelectric Plant during the no power generation and power generation flow periods, 2004 ............................. 5-72 Table 5-23 Comparison of temporal trends of annual means for selected water chemistry parameters at Stations BF 113, BF213, BF313, and BF413 of Reach 2 of the Pee Dee River below the Blewett Falls Hydroelectric Plant for 1999, 2001, and 2004 .................................................................................................................... 5-74 Table 5-24 Water quality parameters measured at Project waters that have applicable North Carolina or South Carolina water quality standards ................................ 5-86 Table 5-25 Sample size (n) and the total number and percent of exceedances (in parenthesis) of water quality parameters measured during this study for the applicable North Carolina water quality standards at the Tillery and Blewett Falls Hydroelectric Plants, 1999-2004 ............................................................... 5-87 vui Acronym List Federal/State Agencies Advisory Council on Historic Preservation (ACHP) Federal Aviation Administration (FAA) Federal Energy Regulatory Commission (FERC) National Park Service (NPS) National Marine Fisheries Service (NMFS) National Oceanic and Atmospheric Administration (NOAA) National Resource Conservation Service (MRCS) formerly known as Soil Conservation Service National Weather Service (NWS) North Carolina Department of Environment and Natural Resources (NCDENR) North Carolina Environmental Management Commission (NCEMC) North Carolina Department of Natural and Economic Resources, Division of Environmental Management (NCDEM) North Carolina Division of Parks and Recreation (NCDPR) North Carolina Division of Water Resources (NCDWR) North Carolina Division of Water Quality (NCDWQ) North Carolina Natural Heritage Program (NCNHP) North Carolina State Historic Preservation Officer (NCSHPO) North Carolina Sustainable Energy Organization (NCSEO) North Carolina Wildlife Resources Commission (NCWRC) South Carolina Department of Natural Resources (SCDNR) South Carolina Department of Health and Environmental Control (SCDHEC) State Historic Preservation Office (SHPO) U. S. Army Corps of Engineers (ACOE) U. S. Department of Interior (DOI) U.S. Environmental Protection Agency (USEPA) U.S. Fish and Wildlife Service (USFWS) U.S. Geological Survey (USGS) U. S. Department of Agriculture (USDA) U.S. Forest Service (USES) Other Entities Alcoa Power Generating, Inc., Yadkin Division (APGI) Appalachian State University (ASU) Atlantic States Marine Fisheries Commission (ASMFC) Carolina Power & Light (CP&L) Electric Power Research Institute (EPRI) Energy Information Administration (EIA) Progress Energy (Progress) Robust Redhorse Conservation Commission (RRCC) The Nature Conservancy (TNC) University of North Carolina at Chapel Hill (UNCCH) Virginia Institute of Marine Science (VIMS) AL-1 List Facilities/Places Yadkin -Pee Dee River Project (entire two-development project including both powerhouses, dams and impoundments) Blewett Falls Development (when referring to dam, powerhouse and impoundment) Blewett Falls Dam (when referring to the structure) Blewett Falls Hydroelectric Plant (when referring to the powerhouse) Blewett Falls Lake (when referring to the impoundment) North Carolina Museum of Natural Sciences (NCMNS) Tillery Development (when referring to dam, powerhouse and impoundment) Tillery Dam (when referring to the structure) Tillery Hydroelectric Plant (when referring to the powerhouse) Lake Tillery (when referring to the impoundment) Documents 401 Water Quality Certification (401 WQC) Draft Environmental Assessment (DEA) Environmental Assessment (EA) Environmental Impact Statement (EIS) Final Environmental Assessment (FEA) Initial Consultation Document (ICD) Memorandum of Agreement (MOA) Memorandum of Understanding (MOU) National Register of Historic Places (NRHP) National Wetland Inventory (NWI) Notice of Intent (NOI) Notice of Proposed Rulemaking (NOPR) Preliminary Draft Environmental Assessment (PDEA) Programmatic Agreement (PA) Scoping Document (SD) Shoreline Management Plan (SMP) Laws/Regulations Clean Water Act (CWA) Code of Federal Regulations (CFR) Electric Consumers Protection Act (ECPA) Endangered Species Act (ESA) Federal Power Act (EPA) Fish and Wildlife Coordination Act (FWCA) National Environmental Policy Act (NEPA) National Historic Preservation Act (NHPA) AL-2 List Terminology Alternative Relicensing Process (ALP) Analysis-of-variance (ANOVA) Area of Potential Effect (APE) Biological oxygen demand (BOD) Chemical oxygen demand (COD) Combustion turbine generator (CTG) Cubic feet per second (cfs) Degrees Celsius (C) Degrees Fahrenheit (F) Dissolved oxygen (DO) Feet (ft) Gallons per day (gpd) Geographic Information Systems (GIS) Gigawatt Hour (GWh) Global Positioning System (GPS) Grams (g) Hectares (ha) Horsepower (hp) Kilogram (kg) Kilowatts (kW) Kilowatt-hours (kWh) Least significant difference (LSD) Mean Sea Level (msl) Megawatt (MW) Megawatt-hours (MWh) Micrograms per liter (gg/L) Milligrams per liter (mg/L) Millimeter (mm) Million gallons per day (mgd) National Geodetic Vertical Datum (NGVD) National Wetlands Inventory (NWI) Non-governmental Organizations (NGOs) Ounces (oz.) Outstanding Remarkable Value (ORV) Parts per billion (ppb) Parts per million (ppm) Photovoltaics (PV) Pounds (lbs.) Power Factor (p.f) Probable Maximum Flood (PMF) Programmable logic controller (PLC) Project Inflow Design Flood (IDF) Proportional stock density (PSD) Quality Assurance Project Plan (QAPP) AL-3 List Quality Assurance/Quality Control (QA/QC) Program Protection, mitigation, and enhancement (PM&E) Rare, Threatened, and Endangered Species (RTE) Ready for Environmental Assessment (REA) Relative stock density (RSD) Renewable fuels module (RFM) Resource Work Groups(RWG) Revolutions per Minute (rpm) Rights-of-way (ROW) River mile (RM) Stakeholders (federal and state resource agencies, NGOs, and other interested parties) Technical Working Group (TWG) Total organic carbon (TOC) Volts (V) Young-of-year (YOY) AL-4 Executive Summary A monthly water quality survey program was conducted at the Tillery and Blewett Falls developments during 2004 to characterize the existing water quality conditions in the Project reservoirs and downstream tailwaters, including the effects of the Rocky River tributary inflow. Historical data collected from Project-associated waters from 1999 to 2002 were also evaluated to examine temporal and spatial trends in water quality. The Water Resources Work Group had identified aneed for additional water quality studies at Project reservoirs andtailwaters during study plan scoping meetings held in 2003. Specific objectives of this study were to: (1) address meeting state water quality standards and supporting designated uses in the reservoirs and tailwaters; (2) evaluate the Project operation effects on water quality in both reservoirs and tailwaters; (3) determine cumulative effects of nutrient and sediment loading on reservoirs and tailwaters; and (4) assess water quality effects of Rocky River inflow. Lake Tillery was characterized as a deep, mesotrophic reservoir with moderate nutrient and solids concentrations, moderate water clarity, and weak buffering capacity with low to moderate anion and cation concentrations. The short hydraulic retention time of the reservoir (average of 8.3 days), coupled with the "filtering effect" of the four upstream reservoirs (i.e., High Rock Lake, Tuckertown Reservoir, Narrows Reservoir, and Falls Lake), influenced the nutrient and solids concentrations, turbidity values, and the trophic status of the reservoir. In contrast to Lake Tillery, Blewett Falls Lake was a shallow, nutrient-enriched eutrophic reservoir with greater solids and turbidity levels and a short retention time (average of 1.9 days). Water quality in Blewett Falls Lake as well as a large upstream portion of the Pee Dee River was influenced in varying degrees by inflow from Tillery Hydroelectric Plant, the Rocky River, and other tributaries within this river reach. Chlorophyll a (an indirect indicator of algal production) concentrations were lower on average in Lake Tillery than in Blewett Falls Lake. Algal dynamics in both reservoirs were largely influenced by the reservoirs' short hydraulic retention times which limited nutrient uptake by phytoplankton and subsequent production. Additionally, the turbid water conditions in Blewett Falls Lake also limited light penetration for photosynthesis. There was only one instance of chlorophyll a concentrations exceeding the North Carolina water quality standard in either reservoir during the survey period. Long-term data collected by the North Carolina Division of Water Quality (NCDWQ) and Progress Energy indicated the water quality conditions in the reservoirs appeared to have either improved or not appreciably changed since the 1980s depending upon the examined parameter and reservoir. Both reservoirs continued to support their designated water quality use designations based on recent assessments by the NCDWQ during 2002. The short hydraulic retention time of both Project reservoirs also influenced the spatial pattern of water quality parameters. Most water quality parameters were fairly uniform with few significant longitudinal differences (i.e., upstream to downstream) observed at either reservoir. The only exceptions at Lake Tillery were significantly greater nitrate + nitrite-nitrogen and total phosphorus concentrations in the upper and middle reservoir areas when compared to concentrations in the lower reservoir near the dam. Significant increases in these two nutrient parameters may have reflected inputs from the Yadkin River upstream of the reservoir and/or the Uwharrie River and algal dynamics and nutrient uptake rates. There were significant temporal differences in the water quality of each reservoir which reflected the precipitation levels and river inflow and outflow within agiven year. Generally, solids constituents, ES-1 Executive especially total dissolved solids, most nutrient constituents, anions and cations, chemical oxygen demand, total alkalinity, and specific conductance were greater during the lower flow, drought years (1999 to 2002) when compared to 2004, a year with greater flow levels. Lower reservoir inflow and outflow, coupled with evaporative processes, during the lower flow years would tend to increase total dissolved solids, nutrients, anions and cations, and specific conductance. Higher chemical oxygen demand values were likely the result of greater organic decomposition with increased hydraulic retention time in lower flow years. Temperature stratification and dissolved oxygen (DO) depletion dynamics in each reservoir were influenced by reservoir depth, the relative amount of precipitation and inflow within the river basin, and the amount of power generation within a given year. Lake Tillery experienced strong seasonal temperature stratification patterns usually occurring from May until September although stratification could either be prolonged or disrupted by one to two months depending upon precipitation levels and inflow and outflow conditions. The shallow nature of Blewett Falls Lake, coupled with river inflow and power plant operations, influenced the temperature stratification and DO depletion patterns within the reservoir. Unlike Lake Tillery which had a well-defined temperature stratification period, Blewett Falls Lake usually had very weak to moderate temperature stratification which could be disrupted with reservoir water column turnover during high river inflows and increased power plant generation. The epilmnion, metalimnion, and hypolimnion strata were not as well defined in Blewett Falls Lake during the stratification period compared with Lake Tillery. Temperature stratification and DO depletion were also independent processes in Blewett Falls Lake and therefore did not closely correspond as observed in Lake Tillery. Dissolved oxygen depletion occurred during the late spring, summer, and early fall months (usually May until September) in both reservoirs. The presence and persistence of low to anoxic DO conditions in the hypoliminion depended upon precipitation and flow conditions within a given year. In Lake Tillery, there were very strong top to bottom differences in DO during the stratification period with low to anoxic DO conditions (< 1 to 4 mg/L) occurring at the 12 to 19 m depth of the intake structure. The seasonal DO depletion was not quite as pronounced at Blewett Falls Lake and anoxic conditions were usually confined to the bottom two to three meters in the reservoir water column. Blewett Falls Lake also did not have avery large volume of anoxic water present during the stratification period as observed at Lake Tillery. The release of low DO water from both reservoirs during power generation periods resulted in corresponding low DO conditions in the Project tailwaters. Low DO conditions were also observed in each power plant tailwater during no power generation periods which suggested other factors algal respiration, organic matter decomposition, tributary inflow of low DO water, and/or power plant wicket gate leakage were also influencing DO dynamics in the tailwater areas, particularly during no generation periods. Inflow and outflow at the Proj ect reservoirs to river tailwaters was largely influenced by large-scale precipitation events in the river basin and upstream reservoir releases within the river basin, especially during years with average or above average precipitation levels. During low-flow years, reservoir outflow was mainly influenced by power plant generation. Large-scale precipitation events in the river basin resulted in rapid turnover and movement of water through the reservoirs and tributaries, such as the Rocky River, and increased the influx of total suspended solids, turbidity, nutrients, and certain metals in reservoirs and tailwaters. During periods of lower inflow, concentrations of total dissolved solids, anions and cations, and corresponding measurements of ES-2 Executive specific conductance increased. Point and nonpoint discharges, coupled with the amount of inflow and the length of the hydraulic retention time, also affected water quality in the reservoirs and tailwaters. The water quality of Lake Tillery was influenced by the lake's position in the Yadkin chain of lakes as the upstream reservoirs provided a "filtering effect" on solids, nutrients, and other water quality constituents. Downstream of the Tillery Development, water quality in the immediate tailwaters, from the Tillery Dam to the Rocky River confluence located 5 miles downstream, generally reflected water quality conditions in Lake Tillery during power generation and no power generation periods. The Rocky River, and to a lesser extent other tributaries within the tailwaters reach below Tillery, were significant sources of increased loading of nitrate + nitrite-nitrogen, total phosphorus, total organic carbon, chemical oxygen demand, anions and cations, and copper. The relative effect of the Rocky River and other tributaries on water quality in Pee Dee River reach below the Tillery Hydroelectric Plant was flow dependent, both from the tributaries themselves and from the amount of generation releases from the power plant. Inputs from the Rocky River and other tributaries influenced the water quality characteristics of Blewett Falls Lake, which were markedly different when compared to Lake Tillery. The relatively short retention time of both reservoirs under normal conditions resulted in little change in the water quality characteristics as water passed through the Project reservoirs, particularly Blewett Falls Lake. Water quality characteristics in the immediate tailwaters reach below the Blewett Falls Development were similar to Blewett Falls Lake. With increasing distance downstream, water quality in the lower Pee Dee River was changed by watershed inputs due to physiographic and land use changes and nonpoint and point source discharges. Operations of the Tillery and Blewett Falls Hydroelectric Plants did result in seasonally low DO concentrations in the tailwaters located downstream of each power plant. Dissolved oxygen concentrations were below the North Carolina instantaneous and daily average water quality standards during power plant generation periods in the summer months during the survey years. Other water quality variations from North Carolina water quality standards in Project reservoirs and tailwaters were the result of larger scale watershed effects and point and nonpoint source discharges, not the result of Project operations. ES-3 Section I - Introduction 1.1 Study Overview Progress Energy is currently relicensing the Blewett Falls and Tillery developments (i.e., Yadkin- Pee Dee River Hydroelectric Project No. 2206) with the Federal Regulatory Commission (FERC). As part of the relicensing process, Progress Energy established Resource Work Groups (RWGs) during May 2003 to identify environmental issues associated with Project operations and develop study plans, if necessary, specific to Project lands and associated lakes and tailwaters. The Water Resources Work Group identified the need for additional water quality studies of the Project reservoirs and tailwaters (i.e., Progress Energy [2004a], Water RWG Issue Nos. 7 and 8, "Lake Tillery and Blewett Falls Lakes & Tailwaters Water Quality"). The purpose of these studies was to evaluate the water quality in the Project reservoirs and the Pee Dee River below the Blewett Falls and Tillery Hydroelectric Plants. Specifically, these water quality studies addressed: (1) meeting state water quality standards and supporting designated uses in the reservoirs and tailwaters; (2) evaluating the Project operation effects on the water quality in both reservoirs and downstream tailwaters; (3) determining cumulative effects of nutrient and sediment loading on reservoirs and tailwaters; and (4) assessing water quality effects of Rocky River inflow. Cumulative effects are defined as the summation of the effects or observed changes in water quality from both point and nonpoint discharge sources into a water body. Three studies were developed to address the water quality issues: (1) a monthly sampling program at the Blewett Falls and Tillery developments to characterize the existing water quality conditions in the Project reservoirs and downstream tailwaters, including the effects of the Rocky River tributary inflow; (2) an intensive assessment of the spatial and temporal patterns of temperature and DO concentrations in the Pee Dee River downstream of each power plant; and (3) continuous monitoring of water temperature and DO from May through November in the upper, mid, and lower areas of the NCDWQ designated 303(d) impaired river sections below each hydroelectric dam. These studies also characterized the water quality of the Project tailwaters with and without power plant generation. This report addresses the monthly water quality sampling program conducted at Blewett Falls and Tillery developments to characterize the existing water quality conditions in the Project reservoirs and downstream tailwaters, including the effects of the Rocky River tributary inflow. Contemporary water quality data collected during 2004 at both developments, in addition to historical data collected during the 1999 to 2002 period, will be evaluated in this report. Separate reports have been issued that address water quality Issues No. 2 and 3, cited above (Progress Energy 2005a and 2005b). Historical water quality studies that have been conducted in the Yadkin-Pee Dee River Basin, including the Project reservoirs and tailwaters, were reviewed and presented in Progress Energy's Initial Consultation Document (Progress Energy 2003). This review includes both the North Carolina and South Carolina portions of the river. 1-1 Section 1 Introduction 1.2 Surface Water Quality Classifications of Waters Associated with the Project Surface water quality classifications are designations applied to surface water bodies, which define the best uses to be protected within the identified water body. These classifications have an associated set of water quality standards to protect the uses (NCDWQ 2004a, 2004b; South Carolina Department of Health and Environmental Control [SCDHEC] 2004a, 2004b). Lake Tillery has been classified by the NCDWQ as a drinking water supply (Class WS-IV, B, CA) and suitable for primary and secondary recreation uses, including fishing, wildlife, fish, aquatic life propagation and survival, and agriculture (NCDWQ 2005). There are two municipal water supply withdrawals from Lake Tillery, one intake for the Town of Norwood and one intake for Montgomery County (Figure 3-1). Blewett Falls Lake and the Pee Dee River reach from the Tillery Dam to Blewett Falls Lake have also been classified by the NCDWQ as drinking water supplies (Classes WS-IV and WS-V, B) and suitable for primary (Class B) and secondary recreation uses (Class C) including fishing, wildlife, fish, aquatic life propagation and survival, and agriculture. There are two municipal water supply withdrawals from Blewett Falls Lake, one intake for Anson County and one intake for Richmond County (Figure 3-2). Both lakes were classified as fully supporting the classified uses in a 1998 to 1999 lake assessment conducted by the NCDWQ (NCDWQ 2000, 2002). The Pee Dee River reach below the Blewett Falls Development to the North Carolina-South Carolina state line was classified as Class C or suitable for secondary recreational uses. In South Carolina, the Pee Dee River (also known as the Great Pee Dee River) from the state line to Florence County has been classified as "FW" or freshwaters, which are suitable for primary and secondary contact recreation, and as a source for drinking water (SCDHEC 2001). This designation also includes waters that are suitable for fishing and the survival and propagation of a balanced indigenous aquatic community. The monitoring sites at U.S. Highway 1 at Cheraw, South Carolina and at U. S. 15 and 401 near Society Hill, South Carolina were fully supporting aquatic life uses duringthe Pee Dee River watershed assessment conducted by the SCDHEC during 2001 (SCDHEC 2001). 1.3 Identified Sources of Water Quality Impairment of Waters Associated with the Project Impaired water quality refers to water bodies that do not met state designated water quality use classifications, such as water supply, fishing, or propagation of aquatic life (NCDWQ 2004a, 2006). Best professional judgment is applied by the responsible state water quality agency, along with numeric and narrative standards criteria and anti-degradation requirements defined in 40 CFR, Part 131, when evaluating the ability of a water body to serve its uses. Impaired water bodies are identified by the state water quality agency through a listing process of Section 303(d) of the Clean Water Act. The Pee Dee River from Tillery Dam (i.e., Norwood Dam) to the confluence of Turkey Top Creek, (24.5 river km or 15.2 RM), was listed as impaired for aquatic life due to low DO concentrations (NCDWQ 2003, 2004a, 2006) (Figure 3-1). In addition, the 6.3-mile segment of the Pee Dee River 1-2 Section 1 Introduction from Blewett Falls Dam to the confluence of Hitchcock Creek was also listed as impaired for aquatic life due to low DO concentrations (Figure 3-2). Hydro modification (dam releases) and minor municipal point discharge sources (below Tillery Dam only for latter source) were listed as the potential sources of impairment. The river segment below the Blewett Falls Dam was also listed as impaired for fish consumption due to a statewide fish consumption advisory for elevated mercury levels. This consumption advice is based on a regional advisory for mercury which extends south and east of U. S. Interstate 85 to the North Carolina coastline (NCDWQ 2003, 2006). Several large tributaries of the Pee Dee River below the Tillery and Blewett Falls developments within the study reach have been listed as impaired by the NCDWQ for North Carolina waters (NCDWQ 2003, 2004a, 2006). Below the Tillery Development, two sections of the upper Rocky River have been listed as impaired for aquatic life due to urban runoff/storm sewers and municipal wastewater point sources. These sections are from the headwater source to the Reedy Creek confluence and from the confluence of Reedy Creek to the confluence of Dutch Buffalo Creek. Violation of water quality standards for turbidity and fecal coliform were listed for the Rocky River section from the headwaters source to the Reedy Creek confluence. The NCDWQ ambient monitoring data for the Rocky River from 1996 to 2001 indicated that DO concentrations were adequate, pH values were occasionally high, and specific conductance values indicated anthropogenic impacts (NCDWQ 2002). Brown Creek, from the mouth of Lick Creek to the confluence with the Pee Dee River, has an overall impaired use due to impaired biological integrity and low DO. Agricultural use was listed as a potential source of the Brown Creek impairment. Below the Blewett Falls Development, Hitchcock Creek, including McKinney and Ledbetter Lakes, has afish consumption advisory due to elevated mercury levels in fish tissue. The NCDWQ (2002) has also documented low DO and pH conditions as well as industrial and wastewater discharges in Hitchcock Creek during past years (NCDWQ 2002). 1-3 Section 2 - Study Objectives The purpose of this study is to evaluate the water quality in the Project reservoirs and the Pee Dee River below the Tillery and Blewett Hydroelectric Plants (Progress Energy 2004a). This study was conducted to address water quality issues pertaining to: (1) meeting state water quality standards and supporting designated uses in both reservoirs and tailwaters; (2) evaluating the Project operation effects on the water quality in both reservoirs and downstream tailwaters; (3) determining cumulative effects of nutrient and sediment loading on reservoirs and tailwaters; and (4) assessing water quality effects of Rocky River inflow into the Pee Dee River. The specific study objective was to conduct amonthly sampling program at the Tillery and Blewett developments to characterize the existing water quality conditions in the Project reservoirs and downstream tailwaters, including the effects of Rocky River tributary inflow. An aspect of the study was to characterize the Project tailwaters with and without power plant generation flows at selected river stations. In addition to the contemporary data collected during the study period of 2004, comparable historical data from both developments for the period of 1999 to 2002 was also utilized to evaluate temporal changes in water quality relative to basinwide annual precipitation patterns and relative inflow. 2-1 Section 3 - Site Description 3.1 General Locale Description The Project is located on the Yadkin-Pee Dee River in south central North Carolina (Figures 3-1 and 3-2). The Yadkin-Pee River basin is the second largest in North Carolina covering 7,213 square miles as measured at the North Carolina-South Carolina state line (NCDWQ 2002). The Yadkin-Pee Dee River originates near the town of Blowing Rock and flows northeasterly for approximately 100 miles from the Blue Ridge Mountains into the Piedmont physiographical region. As the river turns southeast, it enters an area in Central North Carolina that has experienced considerable urban growth. This growing urban area extends from Charlotte to Raleigh/Durham and is known as the Piedmont Crescent (Appalachian State University [ASU] 1999). Just to the south of the Piedmont Crescent, the region enters an area known as the Uwharrie Lakes Region. This region is named for the chain of six reservoirs located along this reach of the Yadkin-Pee Dee River, two of which are Lake Tillery and Blewett Falls Lake. It is in this region that the Uwharrie River joins the Yadkin River at the upper end of Lake Tillery to form the Pee Dee River. The flow of the Yadkin-Pee Dee River is regulated by a federal flood control development and six hydroelectric developments on the main stem of the river. The first development, traveling downstream from the headwaters, is the W. Scott Kerr Dam, a federal flood control project. The next four developments make up the Yadkin Project (FERC No. 2197). These four hydroelectric developments, High Rock, Tuckertown, Narrows, and Falls, are owned and operated by Alcoa Power Generating, Inc. (APGI) and are located along a38-mile stretch of the river (river miles [RM] 272 to 234). High Rock Reservoir is operated as a storage reservoir and serves as the principal storage and water regulation facility for the lower Yadkin-Pee Dee River (APGI 2002). The next two hydroelectric developments on the river, located at RM 218 and 188 are the Tillery and Blewett Falls developments, which constitute Progress Energy's Yadkin-Pee Dee River Project. The primary purpose of the Project is to provide peaking and load-following generation. Its ability to provide such benefits and meet other flow-related needs is largely dependent on the schedule of flows being released from upstream reservoirs. Currently, an agreement between APGI and Progress Energy governs the release of waters from APGI developments to the Progress Energy developments. Additional Project related information is discussed in the Initial Consultation Document for the Project (Progress Energy 2003). 3.1.1 Tillery Development Construction of the Tillery Development began in 1926 and was completed in 1928. Lake Tillery extends approximately 15 miles upstream to the tailrace of the Falls Project powerhouse. At the normal maximum operating elevation of 277.3 Ili, Lake Tillery has an average depth of 23.6 ft and a maximum depth of approximately 71 ft at the dam. The depth ofthe intake extends from 39 to 62 ft (12 to 19 m) below the lake surface at normal maximum pool elevation. The reservoir has a surface NAVD 88 datum. Unless otherwise noted, all data are NAVD 88 datum. The NAVD 88 datum is 0.9 ft lower than the 1929NGVD datum (NAD 29). 3-1 Section 'l Tillery Hydroelectric Development - Water Quality Sampling Stations Uwharrie Ri ver APGI Falls Oam j?` I'?s TYK2 w c s Mountain - ? Creek - H TYH2 DarRxuva 28r?DRAnms Arm no snmv vwxm6rs ( ?:,?, t &amM Lo[atim.?uuiplion l?brveJ ' '3 Pll Ab[v h. as adaeNe - p pl tsiA..e (Fled 2IdA) ? TY2 BxM NC. NV rnxy P's1bMp ®tdjua abovx sBwlaea (Fl?E2I>d) W- Ns Abv C¢•- ca?b ? (P.dSaltb) ? ? -?:? rV3 Sxtm Y <oea]un -. l.rsl•. alvd(RM210,r) } ?? TYF2 rrs sep... H;,.,-,r to9aae (ru,naossl 'i y N6 Coeu]vr ie :d nm?ey iop treek above HlrvrettFAlls Lrke (HI!d ]Ol 8) ? } // Jacobs' I - -Creek - Lake Tillery, -- STANLY ` 9 TYD2 COUNTY y f Cedar Creek 9 TYB2 A MONTGOMERY ?' (1 COUNTY - - -Clarks - •i f =2 Ab C nm fP 1. P (FM 211 ?J ?Tillery Cam Creek ? I TY1 ?RR `- II - i TY2 ' TYCM1 ( l f b , i R k R r oc y ive TY 3 -TY5 RICHMOND COUN TY A TYCM4 TYCM2 -TY5 D TYCM3 t ANSON ' COUNTY rl • ? i - TY4 'fi,?? ` f// Le end 9 It / ' rf, ?cgw3m cro n^?do?: p a -u?am.o rrnm 3 a?«.s ?i Turkey Top _ ! Cr k i ('h? nnn' v irwe[ta oo snevrar<;ecx ? . ?/ii/l7J ee J?j1/l , ff rl, crndm 1-- +ng- n --d cayy? Mie Brown Creek 0 05 ? 2 ] 4 ; 6 y TY12B Site coxr>»uausaares plr>.urrmoraros cocarlavs smm? Locarionl?xevPan ?e:nure> TiChAI N.C. Hi•ln•-r731E3g (R([21 S:n TChd3 ZI C. Higl rl? E -d (P 313 r.?cMq Dor,uaednvfcoNlu- ?.ocru<?«vroP aEi,(El?dzn)E) Figure 3-1 Map of the Tillery Development and Pee Dee River (Reach 1) showing transects used in the monthly water quality study during 2004. LIOx11RY lVA1HR QlLtG?11'lC3?dLt]'RY SIArmr? t i:e ?ley SYa4a. LuvOor,Dnmytio., (Rf•'a bLle) PfR2 L - _S {R(1 t t rmz 1 - m n ,aiRlaa39a) rYlrz 3Nd :?oo-b.ba•lr c. xi???yz+m(erdaxa8) rYla lllp¢rrsxvoi urmp rip Bw?mas?P.mxae.l? nxz vmp?.%?oo:m.ui. beea•pale thm.,eieme Smm?lRetaso.ll Pae DaldabeLnv DDev HvdrocieMa[ Elnt w.w-. La[???emytim? ?aMeV SY3B B Ioa xarhoad ak np yL i4ue ?B3rt2159) NUB li.c. Hi'ynm 1N Bnd?(FSt a13.9? AA Ro hyR' U'.}3i61 Sa Pnd? (46mdes urearnm of Pex Der Rvttwnlnue) 3-2 Section 3 Site Blewett Falls Hydroelectric Development -Water Quality Sampling Stations r. Little River +y BFH2? Mountain Creek BFF2 RICHMOND ANSON COUNTY COUNTY Blewett Falls Lakel Buffalo- BM Upcerresenoixb°Imu Gxv,l'Llmds awa(ItM 1923) ' ,.t_ FBFB 2 Cartledge ;.v Creek _ ` ''? i Creek IBlewett Falls Dam 9 BFB2 J BF1 A BFCM1A A BFCM1 r r;; B F613 fj 1'? BF2 Thompson l Creek Legend [-=B 3 BF18 mn t.n a cn- / - e mrtioo ??/ M ?rve r c - aid DoRatvev rri,e? A BFCM2 Island PL c? oaps(el mpa rea Nmen ror a:m ao. pan Creek- 'Hitchcock Creek >y BF3B ?R MARLBORO COUNTY Jones A BFCM3 .' , -Creek ' 9DCIEWHILL,5C ' BF6L _ CHESTERFIELD This sectionofrrver COUNTY not to scale 2 Flat N Creek 7yny( SI: Slate LiwP MARLBORO DARLINGTON COUNTY COUNTY DILLON COUNTY Westfield Creek 'Black Creek ,,. BF61.` FLORENCE CHESTERFIELD COUNTY COUNTY d 1'' FLORENCE,4 -?ABF4B & BF2B ' ntlee o ps I z a a s a Figure 3-2 Map of the Blewwett Falls Development and Pee Dee River {Reach 2} showing transects used in the monthly water quality study during 2004. CIX4'LIN[70U5 WATER QLNLTIY MOMORLOCATIMS s+aean r« nar>;p?n tAe s hills) BFCMI At Bw,aletJb J? D x?reTplmn td- (RIJI ISS.I) BFCMIA Beba•ceronWa>epantirg iAe taikac°ard dazn(PM 1815) BECIvi2 U.S. Hi Jvray 99brv3pe rkd41A4'IJ BFC2oi3 Fiat Bebx m,abansw YHitclex): Cree): (RM 1£LIj iNTBNavE TEhmBAATnAE AND no srlrov TA.iNSE crs r,?x: p.oeamn ?,ipaon (Rh•erbllle) BFl Sli?1,Sybelwr perwrvla zepwntssg tlv ta4ace -d dam (RM 1880) BF2 Belo 6ipl lmd ,d Carlbdp Creek. cwdbaaxee (EA.41?? BFB M. u s. x;gwray r4 Bxia?° (?ri l?? BF4 Belo H_H AC?eek coMuazne(PM 181.1) BFS 6elo [[ill kce,dbc°na azd J?nv,Cwek shoal (RIvf 176A) BF6 Ezta=r UC Higlvrayl E,idge at Cbsm=r,SC (F1d 164.7) MgNi'HLY WATER QUALTTYICHEMIBTAY STATIONR B4 vett FaA Sahe Slemn Locetion?ecviption (Rberhlile) BFB2 Lav reazdam(PSri1W3J BFD2 Mid azisland (Ed 1£94) BFH2 Upyrresenoub°adaramxs (RM 195 ZJ P ce DceAve:bebsv Blnvett Falls }I+droelatre AaN 5tarion Loeetionikuripiion (RverMae) BFUH Belo,rfle>afeHbao`llu+°in Be PO+r°r PLnv tailrw.e (AM 1?.1J ?FI? fl. Ilyl 9Dudp (Fed IIIO'!) BF2E U.S. Hi?J-s l B,id? tCl-SC )U1 1643) BF3E pJS. Hi?I x?15lWIBxidg atSxiNy Hil1,SC (A1d 146 L) BF4E U.S. Hi?J av?6,n]I Bride rear Florereg SC (FIJI 100.?) 3-3 Section 3 Site Descripti area of approximately 5,697 acres and a total volume of 5.85 x 109 ft3. The average retention time for the reservoir is approximately 8.3 days at normal maximum operating pool elevation based on 1983 to 2000 inflow data. Lake Tillery is dendritic in shape with several large tributary arms (e.g., Mountain Creek, Jacobs Creek, and Cedar Creek complex). The reservoir has a shoreline length of approximately 118 miles with 55 percent of the shoreline in residential or commercial development (Progress Energy 2003). The remaining shoreline areas are forested, pasture, or agricultural. The inflows into Lake Tillery consist primarily of the outflow from the APGI's Falls Development coupled with inflow from the Uwharrie River. The Uwharrie River contributes 8.4 percent of total inflow volume, based on watershed area size. The current Progress Energy license allows for drawdowns at Lake Tillery of up to 22 ft below full pond. However, over the past several years, Progress Energy has voluntarily made its best efforts to operate Lake Tillery within a 4-11 range under normal circumstances and much of the time operating within a 2-11 range except during FERC-required inspection and maintenance periods (12-11 drawdown) (Progress Energy 2003). Outflows fromthe Tillery Development flow into BlewettFalls Lake after passing through a 17-mile reach of the Pee Dee River. Under normal circumstances, it takes approximately 8 hours for releases from the Tillery Development to be observed at the Blewett Falls powerhouse (Progress Energy 2003). 3.1.2 Blewett Falls Development The Blewett Falls' dam and powerhouse are located 17 miles upstream of the North Carolina-South Carolina state border. The construction of this facility began in 1905 and was brought into service in 1912. The normal maximum pool elevation is 177.2 ft' and the reservoir extends approximately 11 miles upstream. The average depth is 10.8 ft. and the maximum depth is approximately 35 ft. The depth of the intake extends from 20 to 33 ft. (6 to 10 m) below the lake surface at normal maximum pool elevation. The surface area of the reservoir at normal operating level is approximately 2,866 acres with atotal volume of 1.35 x 109 ft3. The mean hydraulic retention time is 1.9 days at normal maximum operating pool elevation based on 1983 to 2000 inflow data Blewett Falls Lake is relatively narrow with few large tributary arms. The reservoir has a shoreline length of approximately 46 miles including mainland and island shoreline areas. The Blewett Falls shoreline is relatively undeveloped with surrounding lands mainly forested (Progress Energy 2003). Some limited residential development exists along the shoreline, primarily in the lower lake. The Blewett Falls Development is operated in coordination with the upstream Tillery Development. The hydraulic capacity of Blewett Falls Lake is significantly less than Lake Tillery; therefore, Blewett Falls Lake must anticipate flows from Lake Tillery generation and begin generating in advance of flows reaching the lake. The normal operation of Blewett Falls Lake results in a daily drawdown of approximately 2 to 3 ft below the normal maximum operating level. This drawdown provides storage capacity needed to regulate flows from the Tillery Development. The Blewett Falls generating units normally begin operation at the same time that the Tillery Plant begins generation. Generation at Blewett Falls is usually stopped by midnight to allow the reservoir to refill. This operation is consistent year round and varies only with seasonal availability of water (Progress Energy 2003). 3-4 Section 3 Site Descripti Periodic maintenance can require the lowering of the reservoir levels at both developments. At Tillery drawdowns are typically associated with the maintenance of the steel spillway gates, repairs to the trashrack system, or repairs to the upstream slope of the earthen embankment. Drawdowns required at Blewett Falls Lake are similar to the Tillery Development except that the most frequent maintenance requirement is to service the 4-ft-high, wooden flashboards atop the spillway. During periods of high flow, such as those encountered with the passing of tropical storm systems during September of 2004, damage or loss of these flashboards may occur and repairs require the lake to be drawn down about 4 to 5 ft over a period of time (Progress Energy 2003). 3.2 Sampling Sites 3.2.1 Lake Tillery and Pee Dee River Tailwaters below Tillery Development Water quality and chemistry sampling was conducted at five stations within Lake Tillery (Table 3-1 and Figure 3-1). These station locations were: (1) Station TY132, lower lake area near dam and intake structure at RM 216.3; (2) Station TYD2, lower lake area at RM 219.7; (3) Station TYF2, mid-lake area at RM 224.3; (4) Station TYH2, upper lake area at RM 228.1; and (5) Station TYK2, upper lake headwaters at RM 230.1. All five stations were sampled for water quality parameters (i.e., temperature, DO, pH, specific conductance, and turbidity) while only Stations TY132, TYF2, and TYK2 were sampled for water chemistry parameters (i.e., solids, nutrients, anion and ion constituents, total alkalinity, hardness, chemical oxygen demand [COD], biological oxygen demand [BOD], and selected trace metals). Table 3-1 Coordinates for water quality stations located in Lake Tillery, Blewett Falls Lake, and associated tailwaters of the Pee Dee River (Reaches 1 and 2) below the Tillery and Blewett Falls Hydroelectric Plants during the monthly water quality study, 2004. Studv Location/Station Station Latitude Station Longitude TYB2 35°12' 31.85" 80°04' 06.64" TYD2 35°14' 45.13" 80°05' 42.24" TYF2 35°18' 28.85" 80° 04' 47.41" TYH2 35°21' 34.67" 80°03' 56.66" TYK2 35° 23'22.75" 80°04' 01.03" Pee Dee River below Tillery Hydroelectric Plant-Reach I TY1B 35°12' 13.35" 80°03' 50.98" TY12B 35° 05'06.96" 79°59' 49.78" RR 35° 11' 37.49" 80° 06' 47.81 Blewett Falls Lake BFB2 34° 59'22.61 79° 52' 57.13" BFD2 35° 00'01.34" 79° 53' 50.56" BFF2 35° 01' 53.85" 79° 52' 58.22" BFH2 35° 03'37.24" 79° 54' 00.03" 3-5 Section 3 Site Descripti Study Location/Station Station Latitude Station Longitude Pee Dee River below Blewett Falls Hydroelectric Plant-Reach 2 BFOB 34° 58' 58.95" 79° 52' 30.21 BF1B 34°56' 44.68" 79°52' 11.03" BF2B 34° 42'26.20" 79°52' 29.29" BF3B 34°31' 36.07" 79°49' 58.13" BF4B 34°12' 15.62" 79°32' 53.89" Two stations in the Pee Dee River below the Tillery Hydroelectric Plant (i.e., Reach 1) were sampled for water quality and chemistry parameters (Table 3-1 and Figure 3-1). Station TY 1B was located in the power plant tailrace at RM 215.9, and Station TY12B was located justbelow the N.C. Highway 109 Bridge at RM 203.9. Station TY 12B was located approximately one mile downstream of Brown Creek, a major tributary within Reach 1. In addition, the Rocky River (i.e., Station RR) was sampled for water quality and chemistry parameters, and this station was located justbelow the N.C. Highway 52 Bridge, approximately 4.6 miles upstream of the confluence with the Pee Dee River. The Rocky River enters the Pee Dee River approximately 5 miles downstream of the Tillery Hydroelectric Plant. Station TY113 is located upstream of the Rocky River confluence while Station TY12B is located approximately 12 miles downstream of the Tillery Hydroelectric Plant and approximately 7 miles downstream of the Rocky River confluence. The Rocky River watershed includes several urban areas such as Mooresville, Kannapolis, Concord, Huntersville, and eastern portions of Charlotte. Besides the Rocky River and Brown Creek, other named tributaries entering Reach 1 include Clarks Creek, Cedar Creek, Turkey Top Creek, Savannah Creek, and the Little River (Figure 3-1). Clarks Creek enters into Reach 1 from the east just downstream of Station TY1B. The Town of Mount Gilead's Wastewater Treatment Plant discharges into Clarks Creek. The other tributaries enter into Reach 1 below Station TY12B and the surrounding lands within these watersheds are primarily forested and agricultural areas. 3.2.2 Blewett Falls Lake and Pee Dee River Tailwaters below Blewett Falls Development Water quality and chemistry sampling was conducted at four stations in Blewett Falls Lake (Table 3-1 and Figure 3-2). These station locations were: (1) Station BF132, lower lake area near dam and entrance of intake fore bay arm at RM 188.3; (2) Station BFD2, lower lake area near island at RM 189.4; (3) Station BFF2, mid lake area below the Grassy Islands complex at RM 192.3; and (4) Station BFH2, upper lake headwaters at RM 195.2. All four stations were sampled for water quality parameters (i.e., temperature, DO, pH, specific conductance, Secchi disk transparency, and turbidity). Stations BF132, BFF2, and BF112 were only sampled for water chemistry parameters (i.e., solids, nutrients, anion and ion constituents, total alkalinity, hardness, COD, BOD, and selected trace metals). Station BFD2 was only sampled in November and December 2004 for water quality while the other three stations were sampled monthly from January through December. Five stations in the Pee Dee River reach (i.e., Reach 2) below the Blewett Falls Hydroelectric Plant were utilized for the water quality survey. These stations encompassed an 88-mile reach of the Pee 3-6 Section 3 Site Descripti Dee River which included both North Carolina and South Carolina portions of the river. Reach 2 included the Piedmont Fall Line (Stations BFOB, BF 113, and BF2B) and upper Coastal Plain zones (Stations 3B and 413). All stations were sampled for water quality and chemistry parameters (Table 3-1 and Figure 3-1). Station BFOB was located in the immediate tailrace area below the hydroelectric plant near RM 188.1. Station BF1B was located just below the U. S. Highway 74 Bridge at RM 184.7. Station BF213 was located justbelow the U.S. Highway 1 Bridge near Cheraw, South Carolina at RM 164.7. Station BF313 was located just below the U. S. Highway 15/401 Bridge near Society Hill, South Carolina at RM 146.6. Station BF4B was located just below the U.S. Highway 76/301 Bridge near Florence, South Carolina at RM 100.2. Major named tributaries that enter into Reach 2 in the vicinity of water quality stations include Cartledge Creek, Island Creek, Hitchcock Creek, Little and Jones Creeks, Westfield Creek, Thompson Creek, Crooked Creek, Spot Mill Creek, Cedar Creek, and Three Creeks. Surrounding watersheds of these tributaries include forest, agriculture, industrial, and urban areas depending upon the tributary. 3-7 Section 4 - Methods 4.1 Conduct of Study Vertical profiles of water quality parameters (i.e., water temperature, dissolved oxygen, pH, specific conductance, and turbidity) were measured monthly at stations located in Lake Tillery and Blewett Falls Lake. Measurements were taken with an YSI® Model 650 multi-parameter instrument at the surface (0.2 m) and 1-m intervals from the surface to bottom of each lake station. Secchi disk transparency depth (m) was also measured in the surface waters at each lake station while turbidity was measured at the surface and bottom waters at each lake station. Water chemistry samples were collected concurrently with the water quality vertical profiles. Surface and bottom water chemistry samples were collected at Stations TY132 and TYF2 in Lake Tillery and Stations BFB2 and BFF2 in Blewett Falls Lake. Only surface samples were collected at Station TYK2 in Lake Tillery and Station BFH2 in Blewett Falls Lake because previous water quality surveys indicated that these headwater stations were shallow and well-mixed (Progress Energy 2003). Chlorophyll a samples were collected from a composite sample taken from the photic zone, defined as the surface, the Secchi disk transparency depth, and twice the Secchi disk transparency depth. Chlorophyll a samples were transferred to opaque bottles, placed on ice, and kept in the dark until analysis. For the river stations located in Reaches 1 and 2, including the Rocky River, water quality and chemistry samples were collected at the surface (0.2 m) in the mid-channel. Secchi disk transparency and chlorophyll a samples were not collected at the river stations. All water quality and chemistry data were collected from the lake and river stations during power generation conditions during 2004. Water quality and chemistry samples at Stations TY1B and TY 12B in Reach 1 and Stations BF 1B and BF2B in Reach 2 were also collected during low flow or no power generation conditions during 2004. The 2004 sampling program was designed to standardize month-to-month comparisons of the data relative to power generation conditions and to allow a comparison of water quality characteristics between the generation and no generation periods at the selected river stations below each power plant. Samples collected during the no power generation period were collected at least six hours after the last power generation event or when stream gages indicated stable, low flow conditions. In other survey years, samples were collected under a variety of flow conditions ranging from no power generation to power generation conditions. Water chemistry and chlorophyll a samples were collected using a nonmetallic Van Dorn sampler, transferred to labeled sample containers, and transported on ice to the laboratory. Chain-of-custody forms documented sample collection and transfer from the field to the laboratory. Samples were collected, preserved, and analyzed according to standard methods described in USEPA (1983) and APHA (1998) for the specified parameters. Table 4-1 lists laboratory analytical methods, sample holding times and preservative types, and the laboratory detection limits for the water chemistry parameters, including chlorophyll a. To ensure accuracy and precision of analytical methods, quality control checks were achieved using detection levels, percent recovery of known standards, analytical blanks, spikes, duplicates, and reference and control standards. 4-1 Section 4 Methods Table 4-1 Laboratory analytical methods, sample holding times, preservative types, and laboratory detection limits for water chemistry parameters analyzed for the monthly water quality studies at the Tillery and Blewett Falls developments. Parameter Analytical Method Holding Time Preservation Type Laboratory Detection Limit Total solids EPA 160.3 7 days Cool, 4'C 10.0 mg/L Total dissolved solids EPA 160.1 7 days Cool, 4'C 10.0 mg/L Total suspended solids EPA 160.2 7 davs Cool. 4'C 1 mg/L Total nitrogen Calculation 28 days H,SO, to pH <2 0.10 mg/L Total Kjeldahl nitrogen EPA 351.2 28 days H,SO, to pH <2 0.10 mg/L Ammonia-N EPA 350.1 28 days H,SO, to pH <2 0.02 mg/L Nitrate + nitrite-N EPA 353.2 28 days H,SO, to pH <2 0.02 mg/L Total phosphorus APHA 4500-P E 28 days Cool 4'C 2.0 Og/L Ascorbic acid , Total organic carbon SM5310C 28 days H,SO, to pH <2 0.5 mg/L Chlorophyll a APHA 10200 H 24 hours if pH < 7 Cool, dark ' 0.1 µg/L 3 weeks if pH >_ 7 conditions, 4 C Biological oxygen EPA 405.1 48 hours Cool 4'C 2.0 mg/L demand , cnemical oxygen EPA 410.4 28 days H,SO, to pH <2 10 mg/L demand Calcium EPA 200.8 6 months Cool, 4'C 0.10 mg/L Magnesium EPA 200.8 6 months Cool, 4'C 0.10 mg/L Sodium EPA 200.8 6 months Cool, 4'C 0.10 mg/L Chloride EPA 325.2 28 days Cool, 4'C 1.0 mg/L Sulfate Hach 8051 28 days Cool, 4 C 2.0 mg/L Hardness (calculated) 6 months Cool, 4'C 1.00 mg/L Total alkalinity EPA 310.2 14 days Cool, 4'C 1.00 mg/L Aluminum EPA 200.8 6 months HNO, to pH < 2 50.0 pg/L Copper EPA 200.8 6 months HNO, to pH < 2 1.0 µg/L Mercury EPA 245.1 28 days HNO, to pH < 2 0.2 pg/L 4.2 Data Reduction and Analysis Data reduction and analyses of environmental data were accomplished using PC SAS® software. Standard parametric statistical descriptors, means and ranges, were calculated to summarize and analyze the data for central tendency and dispersion. Data for the 2004 water quality study were analyzed within and between the Project reservoirs and receiving tailwaters. In addition, long-term temporal and spatial trends were evaluated using historical monthly water quality and chemistry data collected at the Project during the 1999 to 2002 period. Monthly sampling was performed at Lake Tillery and associated Pee Dee River tailwaters during 2000 and 2002 while monthly sampling was performed at Blewett Falls Lake and associated Pee Dee River tailwaters during 1999 and 2001. Monthly sampling was performed at the Rocky River during 2001, 2002, and 2004. The reservoir and tailwater data were collected during both power generation and no generation flow periods over all years, but these data provided a longer term perspective on cumulative effects of nutrient, sediment, and other constituents on the water quality in the reservoirs and downstream tailwaters. 4-2 Section 4 Methods Parametric statistical testing of the data was performed to evaluate hypotheses concerning spatial or temporal differences in the data using either one-way or two-way analysis-of-variance (ANOVA). Fisher's least significant difference (LSD) test was used to determine differences inthe mean values if there was a significant ANOVA F-test. A paired t-test was used to determine differences in water quality and chemistry parameters between the power generation and no power generation periods at Stations TY113, TY1213, BF113, and BF213. Water quality samples for the no power generation period were collected at least six hours after the last power plant generation event. Statistical tests were only made on those parameters with the majority of values above the laboratory detection limit. No transformations were made to the data prior to statistical tests. The General Linear Models Procedure of the Statistical Analysis System (SAS Institute, Inc. 1990) was used to perform the statistical tests. A Type I error rate of 5 percent (u, = 0.05) was used to judge the significance of the tests.2 Kendall's tau B correlation coefficients were computed to examine relationships between water quality and daily average flow (cfs) for the reservoirs, the receiving Pee Dee River tailwaters, and the Rocky River. Water quality and lake level relationships were also examined for each reservoir. The daily average flow data provided arelative indicator of precipitation levels and flow through the river basin over the period of study. The total power plant discharge, including power generation and spillage flows, was used in the correlation analysis for the reservoirs. A daily average flow was utilized for the analysis because of the relatively short retention times of both Project reservoirs (two to eight days). A daily average flow also better represented environmental conditions at the tailwater stations where flow conditions were more dynamic. The total power plant generation flow was also used for the correlation analysis of Station TY113 located below the Tillery Hydroelectric Plant. The USGS gaging station data (Rocky River at Norwood and Pee Dee River at Rockingham, Bennettsville, and Pee Dee gages) were used to calculate daily average flows at the Rocky River and Stations BF1B, BF3B, and BF4B located below the Blewett Falls Hydroelectric Plant. For Station BF213 below the Blewett Falls Plant, the daily average flow was estimated based the USGS Rockingham gage and the tributary discharge per square mile for the intervening watershed between Stations BF 1B and BF2B. For the correlation analysis, the daily average flow was computed for the 24-hour period when samples were collected. Data from 2000, 2002, and 2004 were used for the correlation analysis for Lake Tillery and the tailwater Station TY1B in Reach 1. Data from 2001, 2002, and 2004 were used for the correlation analysis of the Rocky River. Data from 1999, 2001, and 2004 were used for the correlation analysis for Blewett Falls Lake and the tailwater stations in Reach 2. Kendall's tau B correlation was based on ranking of the data and permitted analysis of data with values below the laboratory detection limit. Correlation analysis were judged significant at the P = 0.05 level. Flow, lake level, and precipitation data were evaluated to gain insight into the hydrological and climatological conditions affecting water quality in reservoirs and tailwaters. Power plant discharge data (generation and spillage), lake level data, USGS gaging station river flow data, and 2 Significance used in the text from here forward refers to the probability of an error in the conclusions drawn around a statistical finding or result. For example, if the difference between the mean score on a test for one group vs. another group was statistically significant at the 0.05 level, it would mean that the probability of error in the judgment that the two groups truly differ in their scores is 5 out of 100. 4-3 Section 4 Methods precipitation data were examined for the period of 1999 to 2004 (excluding 2003 as no water quality surveys were conducted in that year). Precipitation data were obtained from the Southeast Regional Climate Center (Wadesboro, NC COOP Station 318964) for the 1999 to 2004 period (Southeast Regional Climate Center 2005; State Climate Office of North Carolina 2005). 4.3 Quality Assurance and Quality Control All water quality and chemistry data were collected in accordance with Progress Energy's Quality Assurance/Quality Control (QA/QC) Program (Progress Energy 2004b, 2004c). In addition, Progress Energy filed a Quality Assurance Project Plan (QAPP) with the NCDWQ during 2004 regarding its relicensing water quality studies (Progress Energy 20044). The QAPP specifies the QA/QC framework that was followed during the conduct of these studies. Progress Energy is certified by the NCDWQ and the South Carolina Department of Health and Environmental Control to collect water quality and biological samples through Standard Operating Procedures. Specific procedures for instrument calibration and water quality sampling are detailed in Progress Energy's QA/QC Program and the QAPP. 4-4 Section 5 - Results and Discussion 5.1 Climatological and Hydrological Conditions during the Study Period Precipitation levels and subsequent flow conditions with the Yadkin-Pee Dee River Basin are important factors influencing the water quality in Project reservoirs and receiving tailwaters. Inflow at the Project reservoirs is largely influenced by large-scale precipitation events within the river basin while outflow is mainly influenced by power plant generation during average precipitation or drought years. Large-scale precipitation events can result in rapid turnover and flushing of water through reservoirs and tailwaters and increase the influx of solids, nutrients, and certain metals, which in turn influence the complex interaction of physical, chemical, and biological processes. Conversely, drought years with low precipitation levels and inflow can affect these same processes, most notably the reduction of solids and nutrient loadings (Wetzel 2001). It should be noted that the water quality data collected during the majority of the survey years (i.e., 1999 to 2002) occurred under low flow or drought conditions within the river basin. Low-flow conditions tend to reduce observable effects from nonpoint discharge sources (e.g., solids and nutrients) and magnify effects from point source discharges (e.g., anions and cations, COD, and specific conductance) (NCDWQ 2002). Annual precipitation levels varied widely during the study period of 1999 to 2004 (Figure 5-1). Annual precipitation levels ranged from 69.6 cm (27.4 inches) during 2001 to 134.8 cm (53.1 inches) during 1999 (Southeastern Regional Climate Center 2005). Precipitation levels were below the 30 year average (121.3 cm or 47.8 inches for period of 1971 to 2000) during 2000, 2001, 2002, and 2004, but above the long-term average for 1999 (Figure 5-1). The year 2002 was an "exceptional drought" year due to below normal rainfall totals in 2002 and preceding years (NCDWR 2005). In 2004, the annual rainfall level was 97.6 cm (38.4 inches) and was the second lowest year in total annual rainfall during the five years of water quality surveys (Figure 5-1). Monthly precipitation totals were below the 30 year average during eight months in 2004 and only exceeded the 30-year average in September due to larger precipitation events associated with tropical storms passing through the Yadkin-Pee Dee River Basin (Figures 5-2 and 5-3). In the Pee Dee River below the Tillery Hydroelectric Plant (Reach 1), mean annual daily stream flows estimates ranged from to 2,514 cfs in 2001 to 13,153 cfs in 2003 (Figure 5-2). Peak stream flows were generally greatest in later winter-early spring or the fall periods, which coincided with large scale precipitation events within the Yadkin-Pee Dee River Basin. Estimated daily stream flows were the lowest during the 1999 to 2002 period when compared to 2003 and 2004. The daily mean stream flows in the Pee Dee River (Reach 2) below the Blewett Falls Hydroelectric Plant were generally less than the historic long-term daily mean stream flow during most years (1999, 2001, 2002, and 2004) when water quality studies were conducted in that reach (Figure 5-3). There was aperiod of protracted drought from 1999 to 2002 in the Yadkin-Pee Dee River Basin, and daily mean stream flows were usually less than the long-term mean stream flow during this period. Annual mean stream flows at the USGS Rockingham gage ranged from 2,740 cfs (2001) to 14,069 cfs (2003) during the 1999 to 2004 period. Annual mean stream flow ranged from 2,772 cfs (2001) to 12,817 cfs (2003) at the USGS Bennettsville, South Carolina gage during the same period. At the 5-1 Section 5 Results and Discussions 40 E 35 u c 30 0 25 20 a? a` 15 r 10 Cc 0 5 a 0 40 35 c 30 0 0 25 20 d a` 15 s 10 r- 0 5 a 0 40 35 c 30 0 25 20 a? 0. 15 z 10 Cc 0 5 a 0 1999 2000 Annual precipitation = 69.6 cm Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Figure 5-1 Comparison of monthly precipitation from 1999 to 2001 (gray bars) with, the 30-year average (black line) and ranges of precipitation (vertical lines) for the period 1971 to 2000. (Data source: Wadesboro, NC COOP Station 318964) 5-2 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Section 5 Results and Discussions 40 35 30 0 41- 25 •- 20 a? a 15 10 c0 5 C 0 H Annual precipitation = 112.5 cm Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 40 2003 s 35 Annual precipitation = 137.1 cm c? 30 0 w 25 y a` 1 5 I 2 10 a 5 I I i I I i I I i I l1 1 1 I - I i I Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 40 2004 35 Annual precipitation = 97.6 cm = 30 25 ?5 T T T T T y 10 5 Q I I I I I i I ? I i I I - I I I I 1 L I I I I 1-1 i I I Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Figure 5-1 (Continued) 5-3 Section 5 Results and Discussions 160 000 3 140,000 ... ? .... ........... .... M 120,000 E 100,000 80,000 60,000 40,000 E_ 20,000 0 w ? n ? n ? o z o Date o < u 160.000 2000 3 140,000 M 120,000 E 100,000 80,000 60,000 40,000 E_ 20,000 0 W n n o z o o < Date 160000 2001 3 140000 M 120000 E 100000 80000 60000 40000 E 20000 W n n o z o o < Date 160.000 2002 3 140,000 M 120,000 E 100,000 80,000 60,000 40,000 E 20,000 W 0 n n o z o o ,< o < Date 160.000 2003 3 140,000 nmau nuuua? ouwaaeu rmw - v c?. M 120,000 E 100,000 80,000 60,000 40,000 E_ 20,000 0 w n n o z o Date o < u 160,000 2004 3 140,000 Mean Annual Estimated Flow =6,606 cfs o 120,000 E 100,000 80,000 60,000 40,000 E 20,000 W 0 - w n n o z o < Date Figure 5-2 Estimated stream flow (cfs) of the Pee Dee River (Reach 1) below the Tillery Hydroelectric Plant, 1999 to 2004. 5-4 Section 5 Results and Discussions USGS Rockingham Gage No. 02129000-Pee Dee River Mile 184.7 140,000 120,000 100,000 80,000 60,000- 40,000 20,000 2 0 l6 O O m O O O O O N N N N M M M M V It V V l7 p 67 6 N O O O O O O 0 O O O O O O O O O O O O O O O rn rn rn rn o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o 0 o 0 0 0 r r r r N N N N N N N N N N N N N N N N N N N N N r V I+ O r 7 I- O - ? tom- O r 7 r` 0 r V r_ O r V r` O r Date 140,000- 120,000- 100,000- E 80,000- 60,000 40,00 0 20, 000 a 0 0 O O O O O O N N N N CO M M M V* C "t "t U7 M M M M O O O O O O O O O O O O O O O O O O O O O O O M O O O O O O O O O O O O O O O O O O O O O N N N = N N ` N N N N ` N N ` ` N N . r V ti O r ct ti O r ct ti O r V ti O r et ti O r V h O Date USGS Pee Dee Gage No. 02131000-Pee Dee River Mile 100.2 w 140,000- 120,000- 0 E 100'000 80,000 m L v! 60,000 40,000- 20,000 0 Oi Oi 6] 61 O O O O N N N N M CO M CO <t <t .t 7 Ln a, rn O as 0 0 0 o a o 0 0 0 0 0 0 0 0 0 o 0 o 0 0 0 rn rn rn a o 0 0 0 0 0 o 0 o 0 0 0 0 o 0 0 0 o 0 0 0 r r r r N N N N N N N N N N N N N N N N N N N N N v r` o r v r~ o r v ? a ? v r~ o ? v n o ? v r` o Date Daily Mean Streamflow Long-Term Mean Daily Streamflow Figure 5-3 Daily mean stream flow (cfs) (thin line) and historical long-term daily mean stream flow (thick line) for period of record at USGS gaging stations located on the Pee Dee River, North Carolina-South Carolina, below the Blewett Falls Hydroelectric Plant. 5-5 USGS Bennettsville Gage No. 02130561-Pee Dee River Mile 147.0 Section 5 Results and Discussions USGS Pee Dee, South Carolina gage, annual mean stream flows ranged from 3,353 cfs (2001) to 15,378 cfs (2003) during this same period. Occasional peak stream flows during these years were the result of above average precipitation events such as tropical storm systems or other weather systems passing through the river basin (e.g., Hurricane Floyd in 1999 and Tropical Storms Ivan and Jeanne in September 2004). Daily mean stream flows in Reach 2 were only above the historic long- term daily mean average during 2003 the year water quality studies were not performed at the Project (Figure 5-3). In 2004, daily mean stream flows were less than the historic long-term mean stream flow during the first four months of the year, but were equal to or exceeded the long-term mean during the remainder of the year. Daily mean stream flows at the Rockingham gage ranged from 279 to 81,400 cfs in 2004 with an annual mean stream flow of 6,984 cfs (Figure 5-3). Lake levels were relatively stable in Lake Tillery during the years that water quality surveys were performed (Figure 5-4). Annual mean daily lake level deviations from the normal maximum operating pool elevation ranged from 0.3 ft in 2000 to 1.3 ft in 2004. The greatest variation in lake levels in Lake Tillery occurred in 2001 and 2004 (Figure 5-4). There was a noticeable decline in lake levels from September through November of 2001, due to a FERC required inspection and testing of the tainter gates at the Tillery Development. Low precipitation and inflows during this period resulted in this prolonged drawdown event. Lake levels also fluctuated in 2004 mainly due to flow requirements necessary to conduct the relicensing instream flow study in downstream riverine areas and the tropical storms that passed through the area during September. Lake levels in Lake Tillery were relatively stable during 2000 and 2002 which were the other years that water quality surveys were performed (Figure 5-4). In years that water quality surveys were performed, mean daily lake level fluctuations in Lake Tillery ranged from -0.1 to -1.0 ft from normal operating maximum pool elevation in 2000, from -0.1 to -3.4 ft in 2002, and from 0 to -7.8 ft in 2004 (Figure 5-4). Lake levels fluctuated more in Blewett Falls Lake due to the smaller plant hydraulic capacity and total reservoir volume and the additional accretion flows from the intervening watershed between the two hydroelectric plants (Figure 5-4). Annual mean daily lake level deviations ranged from 0.9 ft in 2000 to 2.4 ft in 2004. Similar to Lake Tillery, the years of greatest variation in lake levels occurred in 2001 and 2004. Additionally, there was some variation in Blewett Falls Lake levels during 1999, particularly during the winter, spring, and early fall months. A similar decline in lake levels occurred from September through November 2001 due to low inflows from the Tillery Hydroelectric Plant and the intervening watershed after the Tillery tainter gate inspection and testing period. The fluctuations in 2004 were also related to downstream flow requirements for the relicensing environmental studies (mainly instream flow study) and loss of flashboards with high flow events related to the tropical storms in September. In years that water quality surveys were performed, mean daily lake level fluctuations in Blewett Falls Lake ranged from -5.6 to +2.7 ft from normal operating maximum pool elevation in 1999; from -6.7 to +2.7 ft in 2001; and from -8.5 to +3.5 ft in 2004 (Figure 5-4). 5-6 Section 5 Results and Discussions 290 66 0 280 z r_ Lake Tillery Normal maximum operating elevation = 277.3 ft c 0 > 279 a) W 260 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month -1999 2000 2001 2002 2004 Normal Maximum Operating Elevatioi 190 68 0 > 180 z r_ Blewett Falls Lake 0 r > 170 W W 160 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month -1999 2000 2001 =2002 2004 Normal Maximum Operating Elevatioi Figure 5-4 Daily mean lake levels for Lake Tillery and Blewett Falls Lake during years that monthly water quality surveys were conducted at the Tillery and Blewett Falls developments, 1999 to 2004. (Note: No surveys were conducted in 2003.) Normal maximum operating elevation = 177.2 ft 5-7 Section 5 Results and Discussions Total annual flows (generation and dam spillage flows) at the Tillery Development ranged from 6.55 x 105 cfs in 2001 to 3.20 x 106 in 2003 (Figure 5-5). Total annual flows were the lowest during the 2000 to 2002 period which coincided with drought conditions in the basin. The greatest total annual flow occurred during 2003; a year that water quality studies were not conducted at the Project. Flows in 2003 were almost twice the flows observed in 2004 - the year with the second greatest annual flow for the 1999 to 2004 period. Very little surface spillage occurred at the dam tainter gates during the years (2000, 2002, and 2004) that water quality surveys were conducted at Lake Tillery. Some spillage of lake surface waters did occur in 2004 during September and December as a result of high-flow events from tropical storms and a low pressure weather system. At the Blewett Falls Development, the total annual flows ranged from 8.89 x 105 cfs in 2001 to 4.51 X 106 cfs in 2003 (Figure 5-6). Total annual flows from the Blewett Falls Development were also the lowest during the period of 1999-2002 compared to the 2003 and 2004 annual flows. Similar to flows at Tillery, the annual flow at the Blewett Falls Development during 2003 was almost twice the annual flow observed in 2004. Spillage of surface waters occurred more frequently at the Blewett Falls Development with spillage events occurring every year during the water quality surveys (Figure 5-6). There was no consistent pattern of more frequent spillage events during any particular month or season for either hydroelectric development during the 1999 to 2004 period. 5.2 Lake and Tailwater Flow Conditions During Water Quality Sampling Trips Power generation and flow conditions varied inthe Project reservoirs and tailwaters areas duringthe monthly water quality sampling trips conducted from 1999 to 2004 (Figure 5-7). Generation flows at the Tillery Development during the reservoir sampling trips ranged from 0 to 10,733 cfs during 2000, from 0 to 14,025 cfs during 2002, and from 3,786 to 13,646 cfs during 2004 (Figure 5-7). Three of the twelve monthly sampling trips at Lake Tillery in 2000 had no power generation during the sampling events (September, November, and December) while only two months had no power generation during 2002. All samples were collected from Lake Tillery under power generation conditions during 2004, as required by the RWG water quality study plan. At Station TY1B located in the immediate tailwaters below the Tillery Development, generation flows at the time of water quality sampling ranged from 0 to 12,396 cfs during 2000, from 0 to 9,168 cfs in 2002, and from 5,230 to 10,339 cfs in 2004 (Figure 5-7). Similar to the reservoir stations, all water quality samples at Stations TY1B and TY12B were collected under power generation flow conditions during 2004. Additional samples were also collected at Stations TY1B and TY12B under no power generation conditions (i.e., power plant leakage/spillage and tributary inflow) during 2004. The flows were estimated to be 100 cfs or less from the Tillery powerhouse and dam at the time that water quality samples were collected at Stations TY1B and TY12B. Flow conditions at Station TY12B included this leakage and tributary inflow (e. g., Rocky River and Brown Creek) into the 12-mile reach ofthe river between Stations TY1B and TY12B. 5-8 Section 5 Results and Discussions 0 E,05 W 5 E+05 4 E+05 LL 3 E+05 n 2 E+05 - 1 E+05 0 E+00 Figure 5-5 6 E+05 X 5 E+05 4 E+05 LL 3 E+05 2 E+05 - 1 E+05 0 E+00 6 E+05 W 5 E+05 4 E+05 LL 3 E+05 2 E+05 - 1 E+05 0 E+00 0 E+05 W 5 E+05 4 E+05 LL 3 E+05 n 2 E+05 - 1 E+05 0 E+00 6 E+05 W 5 E+05 4 E+05 LL 3 E+05 n 2 E+05 - 1 E+05 0 E+00 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 7nn7 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 6 E+05 X 5 E+05 4 E+05 LL 3 E+05 n 2 E+05 - 1 E+05 0 E+00 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 2004 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month ¦Generation Flow ODam spillage Total monthly flow (generation flows and dam spillage) from the Tillery Development during years that water quality surveys were conducted at the Yadkin-Pee Dee River Hydroelectric Project, 1999 to 2004. (Note: No water quality surveys were performed in 2003.) 5-9 Section 5 Results and Discussions 8 E+05 ZE+05 6 E+05 3 5 E+05 LL 4 E+05 n 3 E+05 o 2 E+05 1 E+05 0 E+00 8 E+05 ZE+05 6 E+05 3 5 E+05 LL 4 E+05 n 3 E+05 o 2 E+05 1 E+05 0 E+00 8 E+05 ZE+05 6 E+05 3 5 E+05 LL 4 E+05 n 3 E+05 o 2 E+05 1 E+05 0 E+00 8 E+05 ZE+05 ° 6 E+05 3 5 E+05 LL 4 E+05 n 3 E+05 o 2 E+05 1 E+05 0 E+00 8 E+05 E+05 ° 6 E+05 3 5 E+05 LL 4 E+05 n 3 E+05 o 2 E+05 1 E+05 0 E+00 E+05 B E+05 3 5E+05 LL 4E+05 n 3E+05 o 2E+05 1 E+05 0 E+00 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Innq Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec M onth 8 E+05 2004 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month ¦Generation Flow ODam spillage Figure 5-6 Total monthly flow (generation flows and dam spillage) from the Blewett Falls Development during years that water quality surveys were conducted at the Yadkin-Pee Dee River Hydroelectric Project, 1999 to 2004. (Note: No water quality surveys were performed in 2003.) 5-10 Section 5 Results and Discussions Lake Tillery 16000 St ations TYB2, TYD2, TYF2, TYH2, and TYK2 12000 U y 8000 O a 4000 0 (D D O o C Month 0 2000 ? 2002 ¦ 2004 Pee Dee River below Tillery Development 16000 12000 8000 3 0 a: 4000 I A W 1 0 . , m a c c C D 0 C ( o C Month 1132000 ? 2002 ¦ 2004 Blewett Falls Lake 16000 Stations BF132 BFF2 and BFI-12 0 12000 - » cs 8000 O LL 4000 ff m 0 L? ` N v c c CO o m Cr 0 cQ o - < Month 01999 ? 2001 ¦ 2004 Pee Dee River below Blewett Falls Development 16000 Station BF1B 12000 3 8000 0 UL 4000 0 IIHI C- 7 ? C C- > to 0 z 0 C (D 0 o m Z5 (a _0 < 0 Month 1 01999 ? 2001 ¦ 2004 Figure 5-7 Total generation flows (cfs) at the time that water quality sampling was conducted at the Tillery and Blewett Falls lakes and tailwaters, 1999 to 2004. (Note: Samples were collected at Tillery Development during 2000, 2002, and 2004 and at Blelvett Falls Development during 1999, 2001, and 2004.) 5-11 Section 5 Results and Discussions Generation flows at the Blewett Falls Development during the reservoir sampling trips ranged from 0 to 7,312 cfs during 1999, from 0 to 7,356 during 2001, and from 1,224 to 7,600 cfs during 2004 (Figure 5-7). Six of the 12 monthly sampling trips at Blewett Falls Lake were conducted under no power generation conditions during 1999 while nine of the 12 monthly sampling trips were conducted under no power generation conditions during 2001. All reservoir water quality samples were collected under power generation conditions during 2004, per study plan requirements. At Station BF1B located in the Blewett Falls tailwaters, power generation flows ranged from 1,092 to 13,194 cfs in 1999, from 0 to 7,296 cfs in 2001, and from 3,230 to 7,459 cfs in 2004 during sampling. All water quality samples were collected under power generation flow conditions during 1999 and 2004 while 3 of the 12 samples collected in 2001 were collected during no power generation flows (Figure 5-7). All water quality samples were collected under power generation flows at Stations BF1B, BF213, BF313, and BF413 during 2004, per study plan requirements. In addition, water quality samples were also collected under no power generation flow conditions atthe tailwater Stations BF1B and BF213 during 2004. Flows atthe USGS Rockingham gage (USGS Gage No. 02129000) ranged from 209 to 882 cfs at the time that Stations BF 1 B and BF213 were sampled under the no power generation low flow conditions. 5.3 Water Quality Results The water quality raw data (i.e., temperature, DO, specific conductance, pH, and Secchi disk transparency depth) collected at both Project reservoirs and the receiving Pee Dee River tailwaters of each hydroelectric development are presented in Appendices A and B. The water chemistry data are presented in Appendices C and D and includes alkalinity, hardness, turbidity, solids constituents (total solids, total dissolved solids, and total suspended solids), nutrient concentrations (nitrogen and phosphorus), total organic carbon (TOC), biological oxygen demand, chemical oxygen demand, and selected metal concentrations (aluminum, copper, and mercury). 5.3.1 Lake Tillery 5.3.1.1 Spatial and Temporal Trends in Lake Tillery Water Chemistry Lake Tillery was characterized as amesotrophic reservoir with moderate nutrient concentrations and solids concentrations, moderate water clarity, and weakly buffered with low to moderate anion and cation concentrations (i.e., chloride, sulfate, sodium, magnesium concentrations) (Tables 5-1 and 5-2; Appendix C). The short hydraulic retention time of the reservoir (average of 8.3 days), coupled with the "filtering effect" of the four upstream reservoirs (i.e., High Rock, Lake Tuckertown Reservoir, Narrows Reservoir, and Falls Lake), influenced the nutrient and solids concentrations, turbidity values, and the trophic status of the reservoir. A NCDWQ assessment of the lake in 1999 rated the reservoir as mesotrophic, owing to its relatively short hydraulic retention time, water clarity exceeding one meter in depth, and low algal productivity relative to moderate amounts of nutrients (NCDWQ 2000). The NCDWQ concluded that Lake Tillery was supporting its designated uses at the time of the survey in 1999. The NCDWQ also concluded the lake seemed to be supporting its 5-12 Section 5 Results and Discussions Table 5-1 Means, ranges (in parentheses), and spatial trends of selected water chemistry parameters from the surface and bottom waters at Stations TY132, TYF2, and TYK2 of Lake Tillery during 2004. Station Parameter'2 TYB2 TYB2 TY12 TYF2 TYK2 Surface Bottom Surface Bottom Surface Solids (mg/L) Temperature (EC) 18.6 15.9 18.4 15.4 16.8 (6.2-30.6) (5.9-25.3) (6.5-31.1) (5.7-25.8) (5.5-26.9) Dissolved oxygen (mg/L) 10.2 6.3 10.5 7.6 9.0 (7.0-13.8) (0.1-11.7) (6.5-14.4) (0.9-11.7) (4.8-12.5) Total solids 75 82 75 84 76 (51-123) (64-110) (58-111) (66-105) (56-110) Total dissolved 70 (51-103) 70 (56-109) 66 (51-103) 70 (52-111) 69 (54-112) Total suspended Turbidity (NTU) 3.7 (2.4-5.5) 5.6 (0.2-12) 9.5 (19-48) 19 (2.8-44) 4.4 (2.1-11) 8.4 (0.7-40) 8.4 (3.8-17) 21 (5.2-91) 4.0 (1.8-10) 8.0 (0.4-40) Seechi disk transparency depth (M) Nutrients (M&L) Total nitrogen 0.56 0.60 0.61 0.57 0.61 (0.34-1.32) (0.27-1.37) (0.33-1.84) (0.36-1.09) (0.28-1.69) Ammonia-N 0.04 0.08 0.08 0.09 0.11 (< 0.02-0.08) (< 0.02-0.23) (< 0.02-0.48) (0.02-0.20) (< 0.02-0.74) Nitrate +nitrite -N 0.43' 0.53 0.47' 0.56 0.58a (<0.02-0.74) (0.21-0.75) (<0.02-0.80) (0.21-0.78) (0.28-0.80) Total phosphorus 0.032' 0.050 0.039a 0.050 0.036' (0.018-0.047) (0.011-0.158) (0.023-0.065) (0.022-0.109) (0.018-0.072) Total organic carbon 2.8 2.9 2.9 2.8 2.8 (mg/L) (2.0-4.5) (2.2-5.2) (2.0-5.3) ' (2.1-5.3) (2.0-4.9) ' Chlorophyll a ((Dg/L) 10.3a (2.4-28) NA' 8.5 (2.4-18) NA 4.5 (1.5-9.0) Chemical oxygen demand <10 < 10 <10 <10 <10 (mg/L) (< 10-11) (< 10-16) (< 10-14) (< 10-13) (< 10-12) Biological oxygen < 2 < 2 < 2 < 2 < 2 demand (mg,=L) (< 2-2.3) (< 2-2.7) (< 2-2.1) (< 2-2.1) Calcium 4.9 4.9 4.9 5.1 5.0 (2.2-7.6) (2.0-5.8) (2.3-5.8) (3.5-5.8) (3.3-6.2) Magnesium 2.3 2.1 2.1 2.1 2.0 (< 1.0-4.7) (< 1.0-3.0) (< 1.0-3.0) (< 1.0-3.0) (< 1.0-3.0) Sodium 6.3 6.0 6.1 6.2 6.3 (4.6-8.2) (4.3-8.3) (4.5-7.6) (4.4-7.6) (4.5-7.7) Chloride 8.7 9.1 8.7 8.8 9.0 (6.2-13) (6.4-12) (6.1-12) (6.2-12) (5.9-12) Sulfate 6.0 5.4 7.1 5.7 6.3 (5.2-9.7) (3.0-6.4) (4.4-19) (4.9-7.2) (5.2-9.1) Specific conductance 90 94 91 93 92 ((DS/cm) (78-98) (75-108) (74-99) (74-105) (76-101) Hardness (calculated)4 21 21 21 21 20 (5.4-38) (5.1-26) (5.7-25) (8.8-24) (8.3-25) Total alkalinity4 21 21 22 20 20 (16-26) (17-28) (15-51) (15-28) (16-26) H PH 8.0 7.0 7.9 7.0 7.2 (7.1-8.8) (63-7.7) (68-91) (6.5-7.5) (6.6-7 7) 5-13 Section 5 Results and Discussions Station Parameterla TYB2 TYB2 TYF2 TYF2 TYK2 Surface Bottom Surface Bottom Surface Trace elements (d)?/L) Aluminum 130 666 181 371 200 (< 50-288) (59-4,780) (< 50-564) (75-778) (60-696) 1.8 2.4 1.8 2.1 1.9 Copper (< 2.0-11) (< 2.0-7.5) (< 2.0-2.7) (< 2.0-4.0) (<2.0-3.8) Mercury < 0.2 < 0.2 < 0.2 0.2 < 0.2 1 Sample size (n) equaled 12. Less than values (<) indicate the Lower Reporting Limit (LRL) for the parameter. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably reported. Statistical analyses were utilized only when mean concentrations were above the analytical lower reporting limits. Missing range values indicate that all measured values were less than the LRL for that parameter. 2 Statistical analyses were utilized only when the majority of parameter concentrations were above the analytical lower reporting limits. Fisher's protected least significant difference (LSD) test was applied only if the overall ANOVA F test for the treatment effect was significant. Means followed by different superscripts were significantly different (P< 0.05). Data were rounded to conform to laboratory reporting limit requirements. Such rounding may obscure mean differences. 3 NA means not applicable because no Secchi disk transparency depth or chlorophyll a data were collected from bottom waters. Total alkalinity units are mg/L as CaCO3 and hardness is calculated as mg equivalents CaC03/L. 5-14 Section 5 Results and Discussions Table 5-2 Comparison of spatial trends of annual means for selected water chemistry parameters from the surface waters of Lake Tillery (Stations TYB2, TYF2, and TYK2) for 2000, 2002, and 2004. Parameterl' x Station TYB2 TY12 TYK2 Temperature (BC) 19.1 18.8 16.9 Dissolved oxygen (mg/L) 9.8a 10.3a 8.8 b 72 77 79 Total dissolved 72 74 76 Total suspended 3.0 4.0 3.3 Turbidity (NTT-D 4.7 7.8 6.6 Secchi disk transparency (m) 1.6 1.4 1.7 Nutrients mm/L) Ammonia-N 0.03 0.05 0.07 Nitrate + nitrite-N 0.31' 0.36' 0.48a Total nitrogen 0.50 0.53 0.50 Total phosphorus 0.028b 0.037a 0.034ab Total organic carbon (mg/L) 3.2 3.5 3.1 Chemical oxygen demand 12 12 11 Chlorophyll a 8.8a 9.1a 4.1b Ions (mg1L) Calcium 5.1 5.2 53 Chloride 11 11 11 Magnesium 2.3 2.3 2.2 Sodium 9.1 9.0 9.5 Sulfate 9.0 9.4 9.4 Total alkalinity (mg/L as CaCO3) 24 24 23 Hardness (mg equivalents CaCO3/L) 22 22 22 Specific conductance ((DS/cm) 100 101 101 pH 7.7a 7.82 7.3' Aluminum 124 170 152 Copper 1.7 1.9 1.6 1 Sample size = 36 for all parameters except for total organic carbon (n = 35 at Station TYK2), turbidity (n = 32 at Station TYD2; n = 33 at Station TYH2; and n = 35 at Station TYK2) and Secchi disk transparency (n = 33 at Stations TYD2 and TYH2 and n = 25 at Station TYK2). 2 Statistical analyses were utilized only when the majority of parameter concentrations were above the analytical lower reporting limits. Fisher's protected least significant difference (LSD) test was applied only if the overall ANOVA F test for the treatment effect was significant. Means followed by different superscripts were significantly different (T 0.05). Data were rounded to conform to laboratory reporting limit requirements. Such rounding may obscure mean differences. 5-15 Section 5 Results and Discussions designated uses during the 2002 basinwide assessment. Long-term data collected by the NCDWQ and Progress Energy indicated the water quality conditions in the lake have not appreciably changed since the 1980s (CP&L 1987, 1993; North Carolina Department of Natural and Economic Resources, Division of Environmental Management [NCDEM] 1983, 1989, 1992a, 1992b; NCDWQ 1998). Lake Tillery did not exhibit any pronounced spatial gradient in water chemistry parameters within reservoir during 2004 or during the survey period of 2000, 2002, and 2004 (Tables 5-land 5-2). Lake Tillery has a fairly short average hydraulic retention time, which influenced spatial characteristics in water chemistry parameters and algal productivity, depending upon inflow, outflow, and relative precipitation amounts within a given year. Most measured water chemistry parameters were fairly uniform throughoutthe lake surface waters with few significant longitudinal differences (i.e., upstream to downstream) observed in mean values among Stations TY132, TYF2, and TYK2 (Tables 5-1 and 5-2). The only exceptions were significantly greater nitrate + nitrite- nitrogen andtotal phosphorus concentrations in the middle or upper portions of the lake comparedto the lower lake near the dam (Tables 5-1 and 5-2). Significant increases in these two parameters may have reflected inputs from either inflow from the Falls Development and/or the Uwharrie River. Temporal analysis of water chemistry parameters during 2000, 2002, and 2004 indicated significant differences among years in concentrations of total dissolved solids, total nitrogen, nitrate + nitrite- nitrogen, total organic carbon, chloride, sodium, sulfate, total alkalinity, and chemical oxygen demand (COD) (Table 5-3). Generally, concentrations of these parameters were greater in the lower flow, drought years of 2000 and 2002 when compared to 2004, a year with greater outflow levels (Figures 5-2 and 5-5). Exceptions to this temporal trend were significantly greater total nitrogen and nitrate+nitrite-nitrogen concentrations in 2004. Lower inflow and outflow, coupled with evaporative processes, during the lower flow drought years would increase dissolved solids, nutrients, and anion and cation concentrations. Higher COD values were likely the result of greater organic decomposition with increased hydraulic retention time during the lower flow years. Anion and cation concentrations in reservoir surface waters were in the low to moderate range during 2004 and ranked by ion type, respectively, as follows: chloride > sulfate > sodium and bicarbonate (alkalinity) > calcium > magnesium (Tables 5-1 and 5-3). This ranking was similar in 2000 and 2002 with the exception of sulfate and chloride rankings in 2002 (Table 5-3). Concentrations of chloride, sulfate, sodium, and total alkalinity were significantly greater during the lower flow, drought years of 2000 and 2002 when compared to concentrations in 2004 (Table 5-3). Calcium and magnesium exhibited no significant temporal trends during the three survey years. Occasional pulses of nutrients, aluminum, solids, and turbidity with lowered Secchi disk transparencies were observed in 2004 as well as other years (Appendix C, Tables C-1 to C-3). These pulses were related to large precipitation events in the river basin and subsequent increased inflows into the reservoir (e.g., January-February 2000, November-December 2002, and September-October 2004). For example, in September 2004, passage of tropical storms resulted in above normal precipitation and high flow events. There were observed increases in chloride, total nitrogen, ammonia-nitrogen, total phosphorus, total organic carbon, turbidity, total dissolved solids, and aluminum during September and October (Appendix C, Table C-3). 5-16 Section 5 Results and Discussions Table 5-3 Comparison of temporal trends of annual means for selected water chemistry parameters from the surface waters of Lake Tillery (Stations TYB2, TYF2, and TYH2) for 2000, 2002, and 2004. Parameter'' z Year 2000 2002 2004 Temperature CC) 18.7 18.2 17.9 Dissolved oxygen (mg/L) 9.7 9.3 9.9 Solids (M&L) Total solids 74 79 76 Total dissolved 73ab 802 68b Total suspended 3.1 3.1 4.0 Turbidity (NTq 7.0 6.0 7.3 Secchi disk transparency (m) 1.7a 1.6 a 1.2' Nutrients (M&L) Ainm onia-N 0.04 0.04 0.08 Nitrate + nitrite-N 0.32' 0.34' 0.49a Total nitrogen 0.36' 0.58a 0.59a Total phosphorus 0.034 0.030 0.035 Total organic carbon (mg/L) 3.5a 3.5a 2.8b Chemical oxygen demand 14a 14a 6.2b Chlorophyll a 7.6 6.6 7.8 Ions (mg1L) Calcium 5.1 5.5 4.9 Chloride 12a 12a 8.8 b Magnesium 2.3 2.4 2.1 Sodium l 0a 11 a 6.3b Sulfate 8.5b 13a 6.4` Total alkalinity (mg/L as CaCO3) 25a 24a 21' Hardness (mg equivalents CaCO3/L) 22 24 21 Specific conductance ((DS/cm) 101b l l la 91° pH 7.5 7.6 7.7 Aluminum 135 141 170 Copper 1.6 1.8 1.8 1 Sample size = 60 for all parameters except for turbidity (n = 55 for 2000; n = 59 for 2002; and n = 59 for 2004) and Secchi disk transparency (n = 58 for 2002 and n = 45 for 2004). 2 Statistical analyses were utilized only when the majority of parameter concentrations were above the analytical lower reporting limits. Fisher's protected least significant difference (LSD) test was applied only if the overall ANOVA F test for the treatment effect was significant. Means followed by different superscripts were significantly different (P - 0.05). Data were rounded to conform to laboratory reporting limit requirements. Such rounding may obscure mean differences. 5-17 Section 5 Results and Discussions A few differences were noted in surface versus bottom concentrations of water chemistry parameters during 2004 and for the three-year monitoring period of 2000, 2002, and 2004 (Tables 5-4 and 5-5). There were significantly greater concentrations of total suspended solids, ammonia-nitrogen, and total phosphorus and greater turbidity values in bottom waters at Stations TYB2 and TYF2 for the three-year period (Table 5-5). The total solids concentration was also greater in the bottom waters at Station TYB2 during this period. Bottom values for these parameters ranged from 1.1 to 2.7 times greater than the surface values. Significantly greater concentrations of ammorria-nitrogen in bottom waters reflected the seasonal changes in anoxic conditions and microbial activity. Total phosphorus and total suspended solids concentrations were interrelated as most phosphorus fractions are particulate in nature. The turbidity and solids differences in bottom waters likely reflected inflows from the Yadkin and Uwharrie Rivers and associated seasonal density gradients within the reservoir. Turbidity levels in the surface and bottom waters of Lake Tillery occasionally exceeded the North Carolina water quality standard of 25 NTU for reservoirs in all three survey years (Appendix C). The percentage of turbidity samples exceeding the North Carolina water quality standard ranged from 3 to 10 percent during the three years of water quality surveys and were most frequently observed in the bottom waters at Station TYB2. Peak turbidity values ranged from 27 to 90 NTU during this period. The trace metals copper and mercury were generally low in the reservoir during 2004 and during the 2000, 2002, and 2004 period (Tables 5-1 to 5-3). Mercury values were less than the laboratory reporting limit of 0.2 gg/L in 94 percent of surface and bottom water samples collected during the three years. Mercury values greater than the laboratory reporting limit were observed at Stations TYB2, TYF2, TYK2 during 2000 and ranged from 0.20 to 0.90 gg/L. These detectable values were greater than the North Carolina water quality standard of 0.012 gg/L (NCDWQ 2004b). Copper concentrations ranged from < 1.0 to 7.5 gg/L during the three years of water quality surveys (Appendix C). Only one copper value (Station TYB2, bottom water sample, 2004) was greater than the North Carolina Action Leve13 (NCDWQ 2004b). Aluminum levels were highly variable and ranged from < 50 to 4,780 mg/L during 2000, 2002, and 2004 (Appendix C). Aluminum is bound to clay soil particles, and there is usually apositive relationship between precipitation events, sediment levels, and aluminum loading in Piedmont reservoir systems (NCDWQ 2002). Chlorophyll a concentrations, an indirect indicator of algal productivity, were in the low to moderate range on Lake Tillery during 2004 as well as during 2000 and 2002 (Tables 5-1 to 5-3 and Figure 5-8). The reservoir has a relatively deep photic zone (mean Secchi disk depths > 1 m) so light penetration was typically not a limiting factor in phytoplankton production. There were no significant temporal differences in chlorophyll a concentrations among the three years (Table 5-3). Spatially, chlorophyll a mean concentrations were significantly greater at the lower and mid lake Stations TYB2 and TYF2 compared to the upper lake Station TYK2 (Tables 5-1 and 5-2 and Figure 5-8). This spatial pattern may have reflected the longitudinal spatial differences in total phosphorus and nitrate + nitrite-nitrogen concentrations and nutrient uptake and assimilation by phytoplankton as water flowed through the lake. Furthermore, Station K2 was located just 3 The Action Level refers to a waterborne concentration of an analyte that if exceeded may require further regulatory action by the responsible water quality agency (NCDWQ 2004b). 5-18 Section 5 Results and Discussions Table 5-4 Paired t-test results of differences between surface and bottom waters for selected water chemistry parameters in Lake Tillery during 2004. Parameter "7 Station TYB2 TY12 Solids (Mg/L) Total solids n.s. n.s. Total dissolved n.s. n.s. Total suspended n.s. x:=x bottom (8.4) > surface (4.4) Turbidity (NTTJ) bottom (19) > surface (5.6) n.s. Nutrients (mg/L) Total nitrogen n.s. n.s. Ammonia-N bottom (0.08) > surface (0.04) n.s. Nitrate + nitrite-N n.s. n.s. Total phosphorus n.s. n.s. Total organic carbon (mg/L) n.s. n.s. Ions (MzIL) Calcium n. s. n. s Magnesium n. s. n. s. Sodium n. s. n. s. Chloride n. s. n. s. Sulfate n.s. n.s. Hardness (calculated) n.s. n.s. Total alkalinity n.s. n.s. Trace elements (ftE) Aluminum n.s. .x bottom (371) > surface (181) Copper n. s. n. s. 1 A paired t-test was applied to determine differences between surface and bottom concentrations of each parameter when applicable. P values: n.s. = not significant (P > 0.05), * = 0.01 < P -- 005; k'k = 0.001 < P < 0.01. 2 Mean values are given in parenthesis for parameters with significant t-tests only. 5-19 Section 5 Results and Discussions Table 5-5 Paired t-test results of differences between surface and bottom waters for selected water chemistry parameters in Lake Tillery during 2000, 2002, and 2004. Station Parameters? TYB2 TYF2 Total solids Total dissolved Total suspended Turbidity (NTLD x: bottom (80) > surface (72) n.s. x: bottom (6.6) > surface (3.0) bottom (15) > surface n. s. n.s. bottom (7.3) > surface (4.0) :x bottom (16) > surface Total nitrogen Ammonia-N Nitrate + nitrite-N Total phosphorus Total organic carbon (mg/L) Chemical oxygen demand n.s. x= bottom (0.08) > surface (0.03) n.s. bottom (0.046) > surface (0.028) n.s. n.s. n. s. =x bottom (0.10) > surface (0.05) n.s. bottom (0.046) > surface (0.037) n.s. n.s. Ions (mg/L) Calcium n. s. n. s Magnesium n. s. n. s. Sodium n. s. n. s. Chloride n. s. n. s. Sulfate n.s. n.s. Hardness (calculated) n.s. n.s. Total alkalinity n.s. n.s. Trace elements (d)g/L) Aluminum n.s. =x bottom (438)> surface (170) Copper n. s. n. s. 1 A paired t-test was applied to determine differences between surface and bottom concentrations of each parameter when applicable. P values: n.s. = not significant (P> 0.05), *=0.01 <P<0.05, ** =0.001 <P<0.01, and*** =P _< 0.001. 2 Mean values are given in parenthesis for parameters with significant t-tests only. 5-20 Section 5 Results and Discussions 60 = 50 M 40 r = u.u4 TYB2a" TYF2a TYK2" 3. 30 0 20 10 L) 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Station TYB2 -& Station TYF2 Station TYK2 60 = 50 40 30 0 20 2 10 U 0 ?.no ....O.Y - Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Station TYB2 -Station TYF2 Station TYK2 60 50 40 >. 30 0 20 0 10 L) 0 nano ...m.y - Vv Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Station TYB2 -Station TYF2 *Station TYK2 Figure 5-8 Temporal and spatial trends in chlorophyll a concentrations in Lake Tillery during 2000, 2002, and 2004. (Note: Statistical results among lake stations are shown within each graph with different letter superscripts indicating significantly different mean values.) 5-21 Section 5 Results and Discussions downstream of Falls Lake and was in a transitional zone between semi-lotic and lentic environmental conditions which would affect nutrient assimilation and phytoplankton production. Peak chlorophyll a concentrations were observed in the lower and mid lake areas in either the spring or summer months of each year which usually coincided with pH values of eight to nine units (Appendix A and Figure 5-8). Chlorophyll a concentrations throughout Lake Tillery during all three survey years were also less than the North Carolina water quality standard of 40 gg/L (Tables 5-1 to 5-3 and Figure 5-8). 5.3.1.2 Relationships between Water Quality and Lake Level and Flow in Lake Tillery Kendall's tau b correlation analysis showed few significant correlation associations between daily average lake level and surface water quality parameters in Lake Tillery (Table 5-6). Weak negative correlations occurred between lake level and total nitrogen while weak positive correlations occurred with calcium, chloride, and aluminum. The lack of correlations between lake level and water quality parameters was not unexpected given that Lake Tillery has a relatively stable reservoir level and usually deviates less than 2 ft under most circumstances (Figure 5-4 and Progress Energy 2003). There were more significant correlations between daily average flow and surface water quality parameters in Lake Tillery (Table 5-7). Water temperature, specific conductance, and concentrations of sodium, chloride, sulfate, total alkalinity, and chlorophyll a had weak to moderately significant negative correlations with daily average flow. Significant positive correlations with daily average flow were observed for DO, total solids, total suspended solids, turbidity, ammonia-nitrogen, nitrate + nitrite-nitrogen, total phosphorus, calcium, aluminum, and copper (Table 5-7). No significant correlations were observed between flow and pH, COD, and concentrations of total dissolved solids, total nitrogen, total organic carbon, and magnesium. The daily average flow was a general indicator of reservoir retention time and inflow as the Tillery Hydroelectric Plant usually operated with inflows from the Falls Development located upstream. The significant negative correlations indicated a reservoir "flushing" effect with a shorter retention time as these parameters decreased with increased flow. Conversely, the positive correlations likely indicated increased inputs of those specific water quality parameters with flow. It should be noted that these correlation analyses included two extremely dry years (2000 and 2002) and one year with near normal precipitation levels (2004). No water quality surveys were conducted in 2003, a "wet" year with above average precipitation and flows (Figures 5-1 and 5-2). Generally, flow through the Yadkin-Pee Dee River Basin is largely influenced by regional precipitation events and subsequent inflows. During dry periods, power plant operations influence daily average flows to a greater extent than tributary inflow. 5.3.1.3 Spatial and Temporal Trends in Temperature, DO, PH, Specific Conductance, Secchi Disk Transparency, and Turbidity in Lake Tillery Surface Waters Mean temperatures in surface waters (0.2 m depth) throughout the reservoir ranged from 5.5' to 31.1'C during 2004 while DO concentrations ranged from 4.8 to 14.5 mg/L (Table 5-8). Means and ranges of water temperature and DO concentrations during 2004 were similarto values observed in 2000 and 2002 which were drier, lower flow years. There were no statistical differences among 5-22 Section 5 Results and Discussions Table 5-6 Kendall's tau b correlation coefficients of daily average lake level versus water quality parameters in the surface waters of Lake Tillery (Stations TYB2, TYF2, and TYK2) for the years 2000, 2002, and 2004. Parameter' Kendall's Tau b Correlation Coefficient Temperature n. s. Dissolved oxygen n. s. pH n. s. Specific conductance n. s. Total solids n. s. Total dissolved solids n. s. Total suspended solids n. s. Turbidity n. s. Total nitrogen -0.1677 Ammonia-N n.s Nitrate + nitrite-N n.s. Total phosphorus n. s. Total organic carbon n. s. Chlorophyll a n. s. Total alkalinity n. s. Chemical oxygen demand n. s. Calcium 0.0533 * Magnesium n. s. Sodium n. s. Chloride 0.2492 *** Sulfate n. s. Aluminum 0.0512 * Copper n. s. 1 Pvalues: n.s.=not significant(P>0.05),*=0.01<P<0.05; **=0.001<P<0.01,and***=P<0.001 5-23 Section 5 Results and Discussions Table 5-7 Kendall's tau b correlation coefficients of daily average fl ow versus water quality parameters in the surface wate rs of Lake Tillery ( Stations TYB2, TYF2, and TYK2), the Pee Dee River tailwaters below the Tillery Hydroelectric Plant (S tation TY113), an d the Rocky River (Station RR) for the years 2000, 2002, and 2004. Parameteri'2 Location La ke Tillery Tillery Tailwaters Rocky River Temperature -0.3914 -0.3956 -0.3095 Dissolved oxygen 0.2117 ** 0.2639 * n. s. pH n. s. n. s. n. s. Specific conductance -0.5074 -0.5304 -0.5806 Total solids 0.1423 n s -0.4549 * *** Total dissolved solids n. s. n. s. 0.5269 *** Total suspended solids 0.4521 0.3669 0.3909 Turbidity 0.4707 0.5168 0.5089 Total nitrogen n.s. n. s. n. s. Ammonia-N 0.3076 n. s. n. s. Nitrate + nitrite-N 0.3969 0.4552 n s *** *** . . Total phosphorus 0.465 0.3277 -0.4656 Total organic carbon n. s. n.s. -0.2370 Chlorophyll a 0.1647 NA NA Total alkalinity -0.2497 *** -0.3605 ** -0.5973 *** Chemical oxygen demand n. s. n. s. n. s. Calcium 0.1563 n. s. n. s. Magnesium n. s. n. s. -0.2672 Sodium -0.3064 -0.2354 -0.5832 *** * *** Chloride -0.1876 n s -0.5067 ** . . *** Sulfate -0.1800 n s -0.4387 ** *** Aluminum 0.4939 0.4800 0.2908 *** *** * Copper 0.3157 *** 0.3603 ** n. s. 1 Correlation analysis for Rocky River was for the years of 2001, 2002, and 2004. 2 Pvalues: n.s.=not significant(P>0.05), *=0.01<P<0.05; ** -0.001 <P<0.01, and -P< 0.001. 5-24 Section 5 Results and Discussions Table 5-8 Parameter' TYB2 T1D2 TYF2 TYM TYK2 Temperature (EC) 19.73 19.7a 19.4a 19 Oa 17.1° (6.6-31.3) (6.6-31.5) (4.9-31.5) (5.4-32.9) (5.6-26.6) 9 86 10 4ab 10 83 2ab 10 8 5e Dissolved oxygen (mg/L) . (5.1-15.3) . (5.3-15.4) . (6.8-15.2) . (7.1-13.0) (5.8-11.8) Specific conductance ((DS/cm) 101 101 101 101 101 (78-123) (77-124) (66-124) (70-130) (72-131) 7.4b 7.7a 7.8a 7.8a 7.4b pH (6.6-9.0) (6.9-9.0) (6.2-9.0) (7.0-8.5) (7.0-7.8) Turbidity (NTT_)) 2 5.1 5.5 8.5 9.8 7.4 (1.7-8.7) (2.2-10) (2.2-46) (2.8-33) (2.8-20) Secchi disk depth (m) 1.9 1.8 1.6 1.5 1.9 (1.0-2.7) (1.0-3.0) (0.4-2.4) (0.5-3.0) (0.7-3.0) 2002 Temperature (EC) 19.03 19.2a 18.53 18.3 16.9e (8.4-29.5) (8.9-30.0) (7.6-30.1) (7.4-29.8) (7.3-26.6) Dissolved oxygen (mg/L) 9.5a 9.6a 9.6a 9.9a 8 76 (6.4-12.4) (6.7-12.6) (7.0-11.5) (7.2-11.3) (5.0-11.6) Specific conductance ((DS/cm) 110 (70-136) 110 (72-143) 111 (72-144) 111 (71-141) 112 (73-150) pH 7.7a 7.7a 7.7a 7.6a 7.3b (7.0-9.2) (7.1-8.7) (7.0-8.7) (7.1-8.9) (6.9-7.5) Turbidity tNTg3 3.5 5.3 6.4 5.4 4.3 (0.3-18) (1.7-15.0) (1.8-30) (1.2-13) (1.0-12) Secchi disk depth (m)3 1.8 1.7 1.5 1.4 1.6 (0.9-2.8) (1.0-3.0) (0.7-2.5) (1.0-2.3) (1.0-2.3) Temperature (EC) 18.6a° 18.7a 18.4a° 17.8° 16.8° (6.2-30.6) (62-31.1) (6.5-31.1) (6.1-29.9) (5.5-26.9) Dissolved oxygen (mg/L) 10.2a 10.2a 10.5a 10.1a 9.06 (7.0-13.8) (6.4-14.1) (6.5-14.4) (6.3-14.5) (4.8-12.5) Specific conductance ((DS/cm) 90 87 91 (78-98) (52-99) (74-99) 92 (75-100) 92 (76-101) H p 8. Oa 7.8a 7.9a 7.5 7.2 (7.1-8.8) (6.8-9.0) (6.8-9.1) (6.7-8.4) (6.6-7.7) Turbidity (NTLD 5.6 5.2 8.4 7.5 8.0 (0.2-12) (0.5-16.0) (0.7-40) (0.9-33) (0.4-40) Secchi disk depth (m)4 1.2 1.2 1.2 1.1 1.8 (0.2-1.7) (0.1-1.8) (0.1-1.9) (0.1-1.7) (1.7-1.9) 1 Fisher's protected least significant difference (LSD) test was applied only if the overall ANOVA F test for the treatment was significant. Means follow ed by different superscripts were significantl y different (P < 0 .05). Data were rounded to conform to significant digit requirements. Rounding may obscure m ean differences. 2 Sample size was unequal for stations (n = 12 for Stations TYB2, TYF2, and TYK2; n = 10 for Station D2; and n = 9 for Station TYH2). 3 Sample size was unequal for stations (n = 12 for all parameters except for Station TYK2 where n = 10 for Secchi disk transparency and n = 11 for turbidity). 4 Sample size was unequal for stations (n = 12 for Stations TYB2 and TYF2; n = 9 for Stations TYD2 and TYH2; and n = 3 for Station TYK2). Means, ranges (in parentheses), and spatial trends of water quality parameters from the surface waters (0.2 m depth) at stations within Lake TillerT during 2000, 2002, and 2004. 5-25 Section 5 Results and Discussions annual means of surface temperature and DO among the three survey years of 2000, 2002, and 2004 (Table 5-3). Although not statistically significant, temperatures appeared to be slightly warmer during the low flow years of 2000 and 2002 (Tables 5-3 and 5-8). There were significant longitudinal differences in surface temperatures and DO concentrations during each survey year (Table 5-8). Temperature and DO concentrations increased from the reservoir headwaters (Station TYK2) to the mid and lower reservoir areas (Stations TY132, TYD2, TYF2, and TYH2) and likely reflected the inflows from the upstream Falls Development during the stratification period. Falls Lake receives inflows from Narrows Reservoir which has a deep hypolimnion with cooler temperatures and lower DO concentrations during the stratification period (APGI 2000). The average retention time of Falls Lake is very short (less than one day) so water quality inflow from Falls Lake into Lake Tillery headwaters would be expected to be similar to the water quality of the upstream releases from Narrows Reservoir. It is likely that inflows from the Uwharrie River increased temperature and DO during the stratification period as there were increases in both water quality parameters between Stations TYK2 and TYH2 during this summertime period (Appendix A, Tables A-1 to A-3). Dissolved oxygen concentrations in surface waters of Lake Tillery were above the North Carolina instantaneous (4.0 mg/L) and daily average (5.0 mg/L) water quality standards during 2000, 2002, and 2004. However, DO concentrations slightly less than 5.0 mg/L were observed at Station TYK2 during July 2004 (Appendix A, Table A-3). The DO concentrations on this sampling date ranged from 4.7 to 4.8 mg/L from the surface to three meters depth. The pH values in Lake Tillery ranged from 6.7 to 9.1 units during 2004, and the 2004 overall reservoir mean value was similar to mean pH values observed in 2000 and 2002 (Tables 5-3 and 5-8). There were significant longitudinal spatial differences in pH during 2000, 2002, and 2004 with pH values generally lower at Station TYK2 located in the headwaters compared to Stations TY132, TYD2, TYF2, and TYH2 located in the mid and lower reservoir (Table 5-8). The only exception to this spatial pattern was in 2000 when mean pH values were similar at Stations TY132 and TYK2. Spatial differences in pH were likely related to inflows from Falls Lake during the stratification period (i.e., lower pH in hypolimnetic waters discharged from Narrows Development). Furthermore, there was significantly greater phytoplankton production (as indirectly assessed through chlorophyll a concentrations) in the mid and lower reservoir compared to the headwaters (Table 5-3 and Figure 5-8). Station TYK2 was a semi-lotic in nature due to its close proximity to the Falls Development tailwaters so algal production was likely limited due to flow and subsequent nutrient uptake and assimilation. Nutrient uptake and assimilation and subsequent algal production were greater in the mid and lower reservoir areas which coincided with greater pH values in these areas due to carbon dioxide and pH dynamics associated with photosynthesis (Wetzel 2001). There were no longitudinal spatial differences in specific conductance, turbidity, or Secchi disk transparency at Lake Tillery during 2004 or for the 2000, 2002, and 2004 comparison period (Tables 5-1, 5-2, and 5-8). Additionally, there were no significant temporal differences in turbidity or Secchi disk transparency values for the three-year comparison period (Table 5-3). As previously mentioned, turbidity values were usually low with increased values coinciding with large-scale precipitation events in the river basin and subsequent increased inflows fromthe Falls Development and/or the Uwharrie River. Annual mean Secchi disk transparency depths for the five stations ranged from 1.1 to 1.9 m during the three years which indicated overall high water clarity and a fairly deep photic zone (Table 5-8). Annual mean specific conductance values were significantly greater for the lower flow years of 2000 and 2002 compared to the 2004 mean value (Table 5-3). This likely reflected the increased concentrations of anions and cations (i.e., chloride, sodium, and 5-26 Section 5 Results and Discussions sulfate) through evaporation and less dilution with lower flows. There was likely a "flushing" effect and dilution of anions and cations in reservoir waters during 2003 and 2004, years with above normal or near normal precipitation levels. 5.3.1.4 Temperature and DO Stratification Patterns in Lake Tillery Lake Tillery exhibited a defined seasonal pattern of temperature stratification and DO depletion during 2004 (Figures 5-9 and 5-10). The reservoir was isothermal with DO concentrations above 5 mg/L during winter, early spring, and fall months (January through April and September through December). Temperature stratification and DO depletion occurred from May until August with well defined epilmnion, metalimnion, and hypolimnion strata. Reservoir stratification began in May in the lower and mid reservoir areas (Stations TY132, TYD2, and TYF2) with a shallow thermocline observed at 2-3 m (Figure 5-9 and Appendix A, Table A-3). The reservoir stratification at Station TYH2 was weakly stratified from May through August. Stratification also deepened in the mid and lower reservoir areas as the summer progressed with the thermocline shifting from 2 to 3 m in May to 5 to 6 m in June and July and then shifting upwards again to 2 to 3 m in August (Figure 5-9). At Station TYH2, the thermocline remained at 1 to 3 m during the entire stratification period due to the shallower nature of the reservoir at this station and the flow-related effects from the Falls Development and/or the Uwharrie River. The lake destratified in September with isothermal conditions and DO concentrations greater than 5 mg/L due to above average precipitation and inflow from tropical storms. The temperature differential between surface and bottom waters generally decreased from May through August. A strong clinograde oxygen curve was observed from May through August of 2004 (Figure 5-10). Dissolved oxygen depletion in the hypolimnion was observed in June through August with DO concentrations less than 5 mg/L initially observed in the lower reservoir (Stations TY132 and TYD2) from the reservoir bottom up to 6 or 9 m from the water surface during June. The zone of DO depletion shifted upwards in the water column to 4 to 7 m below the water surface and progressed upstream in the reservoir to Stations TYF2 and TYH2 during July and August. Dissolved oxygen concentrations less than 4 mg/L at Station TY132 occurred at the depth of the intake structure (12 to 19 m) during June through August and most likely persisted into early September based on the continuous temperature and DO monitoring in the power plant tailwaters (Progress Energy 2005a and Appendix A, Table A-3). Dissolved oxygen concentrations below 4 mg/L at Station TYH2 were only observed in bottom waters (7-8 m) during August 2004. This area is shallower than the mid and lower reservoir areas and flow was often visible atthe surface during periods of operation by the Falls Development and/or high inflows from the Uwharrie River. These conditions likely inhibited strong, persistent stratification with an anoxic hypolimnion during periods of average to high precipitation and inflow. Station TYK2, located in the reservoir headwaters, was well-mixed and freely circulating throughout 2004. Temperatures and DO concentrations were fairly uniform from the surface to reservoir bottom (Figures 5-9 and 5-10 and Appendix A, Table A-3). As mentioned previously, DO concentrations less than 5 mg/L were only observed at Station TYK2 during July. 5-27 Section 5 Results and Discussions Ja n?uar ?. ?` 4.0 ?; E ? .? a ? .O p 1 .0 ?.? o ?? 1? ? ?? Water temperature (°C) E a 0 E a m 0 z W Q O E O February O.2 , { 4.0 ?.o ?I .!? ?1?6.0 ?,? o ? 1 ? ?,? 0 ? ?0 ? Water temperature (°C) rc? O. ,? o 4.0 ?.o ?I.? ?I?.o ?,0 e o ?? 15 o ? ?0 ? Water temperature (°C) ?4pri I ?.??}}, ?,Sl ?.o ??//yy r ?i?? q r1??y.0 L-4?.o 0 5 ?0 ? o Water temperature (°C) NGay ?. ? F ??? ? ?? '? 1 .0 ??? 0 ? ?0 1 ? o ? Water temperature (°C) Jury ?. ? ? ; 4.Q? r .? d 1 .o ?.? ?.? 1? ?? ? o ? Water temperature (°C) Water temperature (°C) Station TYB2 Station TYD2 - - - - - - ? Station TYF2 - - - -Station TYH2 Station TYK2 Figure 5-9 Monthly water temperature profiles in Lake Tillery during 2004. ?1ul ?. s. , ? 4?? ?'. .., ? . 90. a ? 1?.Q ?.? ? ? 1? ? 0 ? ? Water temperature (°C) August ?. u ,., 4,? ? ? ?.? a ?.o 0 1.? O.o 0 ? ?0 1 ?? Water temperature (°C) ptember ?. 4 ? ?.? .., ?.o ? ? 'f ?.o t ? ?1B,o o,o ?? ?? Water temperature (°C) ctvlr i ? °?} ^a+ ??.o W '}+yF ??}y. 4+ Lo.o o ? ?? 1? o o Water temperature (°C) ??''yy hJ?v?ml??r 4_J'. C s f; ? 4.0 - ? ? .. ? - r? Y Q ?I?.o o ? .o o,o Water temperature (°C) ?eeerr?b?r ,? 4,O ?, i ;? ? ? , Q ?,o Q ? .O o.O o ?D ?? 0 ?o 5 5-28 Section 5 Results and Discussions E t Q. m ? E CL N ? E C d E L a d ? E CL d ? E o. d ? 0.2 January i ? 4.0- 8.0- 12.0- 16.0 20.0 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) 0.2- February 4.0- 8.0- 12.0- 16.0- 20.0 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) March 0.2- 4.0- 8.0- 12.0- 16.0- 20.O 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) 0.2 April 4.0- 8.0- 12.0- 16.0- 20.0 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) 0.2- May 4.0- 8.0- 12.0 16.0 20.0 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) June 0.2 , 4.0 - - - 8.0- 12.0- 16.0 20.0 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) 0.2- July .2?. - 4.0 r _ 8.0 12.0 a 16.0- 20,0- 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) 0 2 August 4.0 E 8.0 _ r == y 12.0- 16.0- 20.0-1 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) Septem ber 0.2- E 4.0 1 L 8.0- 12.0- C3 16.0 20.0- 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) October 0.2- 4.0- 8.0 a 12.0 0 16.0- 20.0-1 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) November 0.2- 4.0- 8.0 a 12.0 p 16.0 20.0 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) December 0.2- E 4.0 r . w 8.0 S 12.0 0 16.0 20.0- 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) Station TYB2 Station TYD2 - - - - - - - Station TYF2 - - - - Station TYH2 Station TYK2 Figure 5-10 Monthly DO profiles in Lake Tillery during 2004. 5-29 Section 5 Results and Discussions Temperature stratification and DO depletion patterns differed slightly during the drought years of 2000 and 2002 (Figures 5-11 to 5-14). Stratification occurred earlier each year at all reservoir stations, except Station TYK2, and either began in March or April and persisted until August (2000) or September (2002). In 2000, there was a brief period of stratification in March; but the lake destratified by April, which was most likely related to increased precipitation and subsequent reservoir inflow and outflow (Figures 5-11 and 5-12). Stratification recurred in May and continued through August during 2000 (Figure 5-11). Thermal stratification was disrupted during early September 2000 with displacement of anoxic bottom waters throughout the water column, especially in the lower reservoir at Stations TY132 and TYD2 (Figures 5-11 and 5-12). Dissolved oxygen depletion (< 5 mg/L) also began in the hypolimnion in the lower and mid reservoir areas during June 2000 at depths ranging from 9 to 11 m (Figure 5-12 and Appendix A-1). The DO depletion also persisted until September 2000 with anoxic DO concentrations (<2mg/L) at the depth of the intake during this period. No DO concentrations below 5 mg/L were recorded at Stations TY112 or TYK2 during 2000. During the record drought year of 2002, weak temperature stratification began in March in the surface waters in the lower reservoir areas; became progressively stronger and deeper through August; and persisted through September although stratification was somewhatweaker (Figure 5-13 and Appendix A, Table A-2). During May 2002, DO concentrations less than 5.0 mg/L were found from the reservoir bottom up to 10 to 14 m below the water surface at Stations TY132, TYD2, and TYF2. Dissolved oxygen concentrations were below 5 mg/L for the lower 7 to 8 m of the water column at Stations TY132, TYD2, and TYF2 during September 2002. Dissolved oxygen concentrations were also below 5 mg/L in the lower 2 m of the water column at Stations TY112 and TYK2 during September 2002. Anoxic conditions (<2 mg/L) were noted at the depth of the intake structure from July through September 2002 which was similar to observations in 2000 and 2004 (Figures 5-10, 5-12, and 5-14). A small pocket of anoxic water also persisted at Station TYD2 until October 2002 (Figure 5-14 and Appendix A, Table A-2). 5.3.2 Pee Dee River Reach from the Tillery Hydroelectric Plant to Blewett Falls Lake 5.3.2.1 Spatial and Temporal Trends in Reach 1 Water Chemistry during Power Plant Generation and No Power Generation Periods The water quality in the Pee Dee River reach (i.e., Reach 1) from the Tillery Development to Blewett Falls Lake was spatially and temporally influenced by operations of the Tillery Hydroelectric Plant and inputs from tributaries from the intervening watershed, most notably the Rocky River (Tables 5-9 to 5-11 and Appendix C). Flow contributions from the Tillery Hydroelectric Plant during the power generation period, along with inflows from smaller tributaries, usually resulted in dilution of Rocky River and other tributary inflows. Conversely, the effects of the Rocky River inflow into Reach 1 below the confluence were most apparent during periods when the power plant did not generate for extended periods of time; during very low flow conditions associated with drought years; or during very high flow events associated with above normal precipitation events, depending upon the water quality parameter. The Rocky River (Station RR) had significantly greater hardness, total alkalinity, specific conductance, and concentrations of total 5-30 Section 5 0-2 January I E % 4 o E % CL 12 CL 20 0 5 10 15 20 25 30 35 Water temperature (OC) 0-2 February I E % 4 o E % CL 12 CL 20 0 5 10 1 E) 20 2 E) .1-0 35 Water temperature (OC) March o.2- 4 - E E CL 12 - CL o 201-- 0 5 10 15 20 25 30 35 Water temperature (OC) April 4- E E 8 - CL 12- i CL 20-L 0 5 10 -15 20 25 30 35 Water temperature (OC) 0-2 NbY 4 .P E r C E V 12 CL CL 16 0 20 f 0 5 10 15 20 25 10 35 Water temperature (OC) Results and Discussions 0-2 July f.4 a 12 16 20 0 5 10 15 20 25 30 35 Water temperature (OC) Aug u st 0.2 4 12 - 16 20 0 5 10 15 20 25 30 35 Water temperature (6C) Seplember 0.2 4 - 8 12 16 20 0 5 10 1 S 20 25 30 35 Water temperature (OC) October 0-2 4 - 12 115 20 0 5 10 15 20 25 30 35 Water temperature (OC) November 0.2 - 4 12 16 20 0 5 10 15 20 25 30 35 Water temperature (OC) June 0.2 December 4 4 E E CL 12 CL 12 16 16 20 20 0 S 10 15 20 25 30 35 0 5 1 15 20 25 30 5 Water temperature (OC) Water temperature (OC) Station TYB2 Station TYD2 ------- Station TYF2 — — - Station TYH2 Station TYK2 Figure 5-11 Monthly water temperature profiles in Lake Tillery during 2000, 5-31 Section 5 Jinuary 0.2 E 4 E s f s � 12 4) 1 +1 i (zi 20 0 2 4 6 8 10 12 14 1 i Dissolved oxygen (mg/L) 0,2February 4 / M E k E i i 1 i.i D 1 p 20 0 4 6' 0 10 12 14 16 Dissolved oxygen (mg/L) .irc h 0.2 r E 4 s 12 * o r � 1 20 U 2 4 6 8 10 12 14 10 Dissolved oxygen (mg/L) April 0.2 1 Results and Discussions July 0.2 4 12_ r 1' 20 �! U 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) August 0.2 4 - y --, IIII �111111111101111 8- . M + } y ` F • 12- r r 20 0 2 4 (5 8 10 12 '14 10 Dissolved oxygen (mg/L) 0.2 September 4 8- -12 .12 16 - 20 0 2 4 6 10 12 14 1�� Dissolved oxygen (mg/L) October 0.2 }, 4 1 4- 00 C 12 C 12- 1G 21G D € 2 U T 20 0 2 4 0 10 12 14 1 G k C) 2 4 [5 8 10 12 -14 -1 F Dissolved oxygen (mg/L) Dissolved oxygen (mg/L) May N overn bar 0.2 0.2 + 4- 4 I i d Y CL 12 CL -12 20 20 � 0 2 4 B 8 10 12 14 1a 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) Dissolved oxygen (mg/L) June December 0.2 4 � U. a - - 4 8 6 s s , CL 12 CL 1 a� a� 0 16 0 1 20 20 _ 0 2 4 6 8 10 12 14 1 0 2 4 6 8 10 12 14 16 Dissolved oxygen (mg/L) Dissolved oxygen (mg/L) Station TY132 Station TYD2 - - - - - - - Station TYF2 — — — - Station TYH2 Station TYK2 Figure 5-12 Monthly DO profiles in Lake Tillery during 2000. 5-32 Section 5 0.2 July , 4 E 8 t 12 16 20 0 5 10 15 20 25 30 35 Water temperature (C) 0.2 January 4 8 r r 12 16 20 0 5 10 15 20 25 30 35 Water temperature (°C) 0.2 February t 4 E 8 L 12 0 16 20 0 5 10 15 20 25 30 35 Water temperature (°C) March 0.2 A01- 4 E 8 L 12 16 20 0 5 10 15 20 25 30 35 Water temperature (°C) August 0.2 E 4 i 8 r 12 0 16 20 0 5 10 15 20 25 30 35 Water temperature (°C) 0.2 September , _ 4 E 8 L 12 16 20 0 5 10 15 20 25 30 35 Water temperature (°C) Results and Discussions April 0.2 E 8 E a 12 0. p 16 p 20 0 5 10 15 20 25 30 35 Water temperature (°C) 0.2 May 4 E 8 ?t L 12 0 16 20 0 5 10 15 20 25 30 35 Water temperature (°C) June 0.2 4 y;'! 8 ??. L 12 16 20 0 5 10 15 20 25 30 35 October 0.2 4 8 12 16 20 0 5 10 15 20 25 30 35 Water temperature (°C) November 0.2 7 4 ' 8 it L 12 16 20 0 5 10 15 20 25 30 35 Water temperature (°C) December 0.2 T < 4 8 ' L 12 m 16 20 0 5 10 15 20 25 30 35 Water temperature (°C) Water temperature (°C) Station TYB2 Station TYD2 • • • • • . • Station TYF2 -- - - Station TYH2 Station TYK2 Figure 5-13 Monthly water temperature profiles in Lake Tillery during 2002. 5-33 Section 5 Results and Discussions Januowv E i 12 •� Lam} 20 Dissolved oxygen (mg/L) E L Q1� D 1�� 20 0 2 4 C =) 8 .10 12 14 1 Dissolved oxygen (mg/L) rrcF-1 0. ;} 4` i' CL 1 CL W D 16 Pr 20 0 2 4 t=) a '10 12 14 16 Dissolved oxygen (mg/L) Agri I 0 . CL9 20 C) 2 4 a '1 '12 14 1 Dissolved oxygen (mg/L) C1 {} . ti CL July 0,2 4 12 W 11 16 20 2 4 C> B 1 ? 1: '14 16 Dissolved oxygen (mg/L) Aug u d CL 1 D 20 '10 -12 1/1 '15 Dissolved oxygen (mg/L) 0. r �. 4 E -- 1 1, D 16 20 a 2 4 6 113 10 12 14 -1 Dissolved oxygen (mg/L) Oaober 4- E 'I 1 CL a) .1( D _ 20� 10 12 14 '1 Cay Dissolved oxygen (mg/L) U. G � �rt 1 L 20 20 0 2 4 ri a '10 -12 1/1 1 C-) 0 2 4 6 a '10 -12 1/1 1 [5 Dissolved oxygen (mg/L) Dissolved oxygen (mg/L) Jury- 0. r 0, - E 4 E 4 12 1 0 '1V 0 16 !L .1 - - � 20 _ .. C) 2 4 (3 B 1 } '12 14 1 C) 2 4 Ci B -10 `12 14 1 E Dissolved oxygen (mg/L) Dissolved oxygen (mg/L) Station TY62 Station TYD2 - - - - - - - Station TYF2 — — — - Station TYH2 Station TYK2 Figure 5-14 Monthly DO profiles in Lake Tillery during 2002. 5-34 Section 5 Results and Discussions Table 5-9 Means, ranges (in parentheses), and spatial trends of selected water chemistry parameters during the no power generation period in Reach 1 of the Pee Dee River below the Tillery Hydroelectric Plant and the Rocky River during 2004. Parameter'2 TY1B TY12B RR No Power No Power Rocky River Generation Generation Temperature (EC) 16.7 166 17.6 (5.9-26.3) (7.0-27.1) (6.4-28.1) Dissolved oxygen(mg/L) 8.5 8.2 9.7 (4.4-12.4) (4.9-13.8) (6.8-13.8) Solids (mg/L) 81b 103b 165a Total solids (64-107) (64-150) (112-300) Total dissolved 73b 84b 142a (51-108) (54-107) (108-286) 3.9b l lb 18a Total suspended (4.8-22) (1.3-46) 6 9b 1826 24a Turbidity (NTq . (0.6-18) (9.1-30) (3.2-73) Nutrients (mg1L) Total nitrogen 0.58 0.63 0.81 a (0.32-1.4) (0.36-1.8) (0.31-2.4) Ammonia-N 0.04 0.04 0.02 (< 0.02-0.09) (< 0.02-0.09) (< 0.02-0.07) Nitrate +nitrite -N 0.57b 0.68b 2.6a (0.26-0.83) (0.30-1.2) (1.1-9.4) 0 032b 0 1026 0 3202 Total phosphorus . (0.015-0.059) . (0.056-0.276) . (0.113-1.09) Total organic carbon (mgiL) 2.7b 4.3a 4.92 (2.1-4.4) (2.8-6.7) (3.3-68) Chemical oxygen demand (mg/L) <10 <10 11 (<10-14) (< 10-18) (< 10-21) Biological oxygen demand (mg/L) < 2 < 2 < 2 Ions (mg/L) Calcium 5.0 6.5 12a (3.4-5.9) (5.4-8.9) (8.6-24) 2.1` 2.96 4.8a Magnesium (< 1.0-3.0) (1.5-4.3) (2.2-7.2) Sodium 6.36 8.01 16a (4.3-8.4) (5.8-9.1) (7.8-44) 9 1 b 12b 21 a Chloride . (6.7-12) (7.8-15) (10-70) Sulfate 6.0` 8.8b 17a (2.8-8.9) (4.8-16) (7.4-25) Hardness (calculated)' c 22 b 29 a 50 (8.4-25) (21-37) (31-90) Specific conductance ((DS/cm) b 92 (75-102) b 116 (88-146) a 222a (140-491) Total alkalinity' 20b 25 b 33 a (16-27) (16-32) (15-51) pH 7.5 7.6 7.8 (6.6-9.0) (7.1-8.0) (7.2-9.1) 5-35 Section 5 Results and Discussions Station Parameter'2 TY1B TY12B RR No Power No Potiver Generation Generation Rocky River Trace elements (0,q/L) 171-1 41 -A 7f),Aa Aluminum Copper (<50-485) (126-871) (96-2,080) 2.2v 2.8' 4.8a (< 2.0-5.7) (2.0-4.0) (3.2-7.0) Mercury 0.2 0.2 0.2 1 Sample size (n) equaled 12. Less than values (<) indicate the Lower Reporting Limit (LRL) for the parameter. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably reported. Statistical analyses were utilized only when mean concentrations were above the analytical lower reporting limits. Missing range values indicate that all measured values were less than the LRL for that parameter. 2 Fisher's protected least significant difference (LSD) test was applied only if the overall ANOVA F test for the treatment was significant. Means followed by different superscripts were significantly different (P # 0.05). Data were rounded to conform to significant digit requirements. Rounding may obscure mean differences. 3 Total alkalinity units are mglL as CaCO3 and hardness is calculated as mg equivalents CaCO3,,/L. 5-36 Section 5 Results and Discussions Table 5-10 Means, ranges (in parentheses), and spatial trends of selected water chemistry parame ters during the power generation period in Reach 1 of the Pee Dee River below the Tillery Hydroelectric Plant and the Rocky River during 2004. Station Parameter'2 TY1B TY12B RR Power Power Rocky River Generation Generation Temperature (EC) 16.9 (6.2-26.5) 17.2 (6.4-29.7) 17.6 (6.4-28.1) Dissolved oxygen (mg/L) 8.0 9.4 9.7 (2.9-12.2) (6.1-12.7) (6.8-13.8) Solids (mg/L) Total solids 80 7 96 165a (50-11 ) (72-141) (112-300) Total dissolved 69b 85b 142a (52-108) (62-109) (108-286) Total suspended 10 (3.125) 16 (3.9-46) 18 (1.3-46) Turbidity (NTU) 9.6b 1gab 24a (1.5-24) (7.2-45) (3.2-73) Nutrients (mg/L) Total nitrogen 0.89 0.66 0.81 (0.33-2.9) (0.34-2.0) (0.31-2.4) Ammonia-N 0.06a 0.02b 0.02b (< 0.02-0.13) (< 0.02-0.06) (< 0.02-0.07) 0.53b 0.74b 2.6a Nitrate + nitrite-N (0.20-0.80) (0.39-1.2) (1.1-9.4) 0.034b 0.091b 0.320a Total phosphorus (0.015-0.049) (0.038-0.197) (0.113-1.09) Total organic carbon (mg/l,) 2.8` (2.1-4.8) 3.8b (2.2-5.8) 4.9a (33-6.8) Chemical oxygen demand (mg/L) <10 (< 10-12) <10 (< 10-18) 11 (< 10-21) Biological oxygen demand (mg/L) <2 <2 < 2 Ions nn/L) Calcium 5.2 6.0 12a (3.3-6.4) (3.6-7.8) (8.6-24) 2. lb 2.6b 4.83 Magnesium (< 1.0-2.9) (< 1.0 -3.9) (2.2-7.2) 6.3b 6.6b 16a Sodium (4.4-8.7) (1.39.5) (7.8-44) 9 Ob 11 b 21 a Chloride . (7.0-12) (8.6-13) (10-70) Sulfate 5.5` 9.8b 17a (< 2.0-7.5) (5.2-26) (7.4-25) Hardness (calculated)3 b (8.2127) b b (9.2 0-635) b a 50 (31-90) Specific conductance ((DS/cm) gl (78-99) l l l (79-162) 222a (140-491) Total alkalinity3 b 1 b 22 a (17 26) (14-33) (15-51) H p 7.5 7.4 7.8 (6.8-8.5) (6.4-8.0) (7.2-9.1) 5-37 Section 5 Results and Discussions Station Trace elements Parameter' 2 T IB TPYWeB RR Power Rocky River Aluminum (51-600) (1221,260) (96.2,080) 2.0` 2.8" 4.82 Copper (< 2.0-3.3) (1.5-5.0) (3.2-7.0) Mercury < 0.2 < 0.2 < 0.2 1 Sample size (n) equaled 12. Less than values (<) indicate the Lower Reporting Limit (LRL) for the parameter. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably reported. Statistical analyses were utilized only when mean concentrations were above the analytical lower reporting limits. Missing range values indicate that all measured values during, were less than the LRL for that parameter. 2 Fisher's protected least significant difference (LSD) test was applied only if the overall ANOVA F test for the treatment was significant. Means followed by different superscripts were significantly different (P # 0.05). Data were rounded to conform to significant digit requirements. Rounding may obscure mean differences. 3 Total alkalinity units are mg/L as CaCO3 and hardness is calculated as mg equivalents CaCO31L. 5-38 Section 5 Results and Discussions Table 5-11 Paired t-test results of differences for selected water chemistry parameters between power generation and no power generation flows at Stations TY113 and TY12B in Reach 1 of the Pee Dee River below the Tillery Hydroelectric Plant during 2004. Station Parameters TY1B TY12B Temperature (EC) n.s. n.s. -k -k Dissolved oxygen (mg/J-) no generation > generation no generation > generation Solids (mg/L) Total solids n.s. n.s. Total dissolved n.s. n.s. Total suspended n.s. generation > no generation x: Turbidity (NTL1 n.s. seneration > no szeneration Total nitrogen n.s. n. s. Ammonia-N n. s. no generation > generation :x Nitrate + nitrite-N n. s. no generation > generation Total phosphorus n. s. n. s. Total organic carbon (mg/L) n.s. n. s. Ions (MzIL) Calcium n. s. n. s. Magnesium n. s. n. s. Sodium n. s. n. s. Chloride n. s. n. s. Sulfate n. s. n. s. Hardness (calculated) n. s. n. s. Total alkalinity n.s. n. s. Specific conductance (µS/cm) n.s. n.s. pH n. s. n. s. Trace Aluminum generation> no generation n.s. Copper n. s. n. s. 1 A paired t-test was applied to detennine differences between surface and bottom concentrations of each parameter when applicable. P values: n. s. = not significant (P> 0.05), = 0.01 < P # 0.05; ?`* = 0.001 <P #0.01. See Tables 4-1 and 4-2 for mean values of each parameter. 5-39 Section 5 Results and Discussions solids, total dissolved solids, turbidity, nitrate + nitrite-nitrogen, total phosphorus, total organic carbon, all anion and cation constituents, aluminum, and copper when compared to Stations TY113 and TY12B in Reach 1 duringthe no generation and power generation periods in 2004 (Tables 5-9 and 5-10). During no power generation or lower flow conditions, the Rocky River influence was observed below its confluence in Reach 1 with significantly greater concentrations of total organic carbon, magnesium, sulfate, and hardness at Station TY12B compared to Station TY1B (Table 5-9). During power generation, concentrations of total organic carbon, sulfate, and copper were significantly greater at Station TY12B compared to Station TY1B (Table 5-10). Ammonia-nitrogen was the only parameter that was significantly greater at Station TY113 than at Stations TY 12B and RR during the power generation period, and this reflected the increased ammonia concentrations in Lake Tillery bottom waters during the stratification and DO anoxia period (Table 5-3). A paired t-test was performed to evaluate power generation vs. no power generation flows at Stations TY113 and TY12B in Reach 1 (Table 5-11). There were few significant differences among water chemistry parameters between the two flow periods at each station, especially at Station TY1213. Total suspended solids, turbidity, and aluminum were significantly greater during power generation flows compared to the no power generation flows at Station TY113. Conversely, the nitrate + nitrite-nitrogen mean concentration was significantly greater during the no power generation flows at Station TY1B. At Station TY12B, ammonia-nitrogen was significantly greater during the no power generation period compared to the power generation period. The lack of differences between the two flow periods at each station may have been related to (1) the influence of wicket gate leakage and dam spillage at the Tillery Hydroelectric Plant, which may have been enough to minimize differences between the power generation and no power generation periods, mainly at Station TY 1 B and (2) the water from a previous power generation event (at least 6 hours between power generation events) had not completely passed at Station TY1213. The influence of Rocky River water quality on downstream water quality in Reach 1 was most evident when the water quality data for 2000, 2002, and 2004 were combined for comparison (Table 5-12). There were significantly greater concentrations of all solids constituents, turbidity, nitrate +nitrite-nitrogen, total phosporus, total organic carbon, COD, all anions and cations, copper, and specific conductance measurements at Station TY12B when compared to Station TY1B and the bottom waters of Lake Tillery (i. e., Station TY132). Water chemistry parameters were not measured during 2000 for the Rocky River (Station RR); however, statistical results of spatial trends for 2000 and 2004 indicated that the Rocky River affected downstream water quality in Reach 1 (Tables 5-9 and 5-10; Progress Energy 2003). The NCDWQ ambient monitoring data for the Rocky River from 1996 to 2001 indicated that although DO concentrations were adequate, pH values were occasionally high, and specific conductance values indicated anthropogenic impacts (NCDWQ 2002). Similarto the 2004 results, ammonia-nitrogen was significantly greater in Lake Tillery bottom waters for the three year comparison (Table 5-12). The mean ammonia-nitrogen concentration at Station TY113 was intermediate to the mean concentrations at Stations TY132 and TY1213. 5-40 Section 5 Results and Discussions Table 5-12 Comparison of temporal trends of annual means for selected water chemistry parameters from bottom waters at Station TYB2 in Lake Tillery and surface waters at Stations TY1B and TY12B in the Pee Dee River below the Tillery Hydroelectric Plant during 2000, 2002, and 2004. Station Parameter' TYB2 TY1B TY12B Total solids 80b 78b 1132 Total dissolved 741 76' 98a Total suspended 6.6' 6.8' 19a Turbidity (NTU) 151 8. lb 24a Nutrients (mgfL) Total nitrogen 0.52 0.59 0.66 Ammonia-N 0.08a 0.052' 0.03b Nitrate + nitrite-N 0.42b 0.41 b 0.59a Total phosphorus 0.05b 0.041 0.13a Total organic carbon (mg/L) 3.31 3.21 5.2a Chemical oxygen demand 111 l lb 17a Calcium 51' 5.3b 6.3a Chloride 1 lb 111 15a Magnesium 2.31 2.21 2.9a Sodium 8.9b 8 8b 12a Sulfate 8.51 8.61 13a Total alkalinity2 24 23 26 Specific conductance ((DS/cm) 99b 104' 1303 Trace elements (4?/L) Aluminum 369ab 208b 627a Copper 1.91 1.81 3.8a 1 Statistical analyses were utilized only when the majority of parameter concentrations were above the analytical lower reporting limits. Fisher's protected least significant difference (LSD) test was applied only if the overall ANOVA F test for the treatment effect was significant. Means followed by different superscripts were significantly different (P # 0.05). Data were rounded to conform to laboratory reporting limit requirements. Such rounding may obscure mean differences. Sample size = 12 for each year. 2 Total alkalinity units are mg/L as CaCO3. 5-41 Section 5 Results and Discussions Monthly trends of concentrations of nutrients, solids, and turbidity measured during 2004 at Station TYB2 in Lake Tillery (surface and bottom waters), at Stations TY 1B and TY12B in Reach 1, Rocky River (Station RR), and at Station BFH2 located in the Blewett Falls Lake headwaters are presented in Appendix E. All of these data were collected under power generation flow conditions so data were comparable from station to station. This comparison examined the cumulative effects of nutrient and solids loading in Reach 1 from the Lake Tillery bottom water released into the reach and the additional effects of tributary inflow (i.e., Rocky River, Brown Creek, Little River, and minor tributaries) until the water arrived at the headwaters of Blewett Falls Lake. Spatial trends of these water chemistry parameters did not closely coincide at all stations during 2004 (Appendix E). One exception was total nitrogen where peak concentrations were observed in June of 2004 at all stations, including surface and bottom waters of Lake Tillery. As expected, monthly trends at Station TY1B closely paralleled trends in the bottom waters of Lake Tillery given the depth of the intake structure in the lake. Greater turbidity, nitrate +nitrite-nitrogen, and ammonia-nitrogen were observed in the bottom waters than in the surface waters of Lake Tillery during the winter, spring, or summer months, depending upon the parameter. Peak concentrations of nutrients, solids, and turbidity were observed in the Rocky River during June or July 2004, but there were no corresponding peaks downstream at Station TY12B or Station BFH2. The lack of similarity of monthly trends in these water chemistry parameters among the Rocky River and downstream Stations TY12B and BFH2 may have reflected the time lag effect of Rocky River inflow into the downstream areas of the Pee Dee River and/or the dilution effect of inflows from the Tillery Hydroelectric Plant and downstream tributaries, such as Brown Creek and the Little River. A statistical comparison of all water chemistry parameters indicated significantly greater concentrations of mosttested parameters atthe Rocky River Station RR comparedto bottom waters of Lake Tillery, Stations TY 1 B and TY 12B in Reach 1, and Station BFH2 in the Blewett Falls Lake headwaters (Table 5-13). Total organic carbon and sulfate mean concentrations were the only parameters that showed significantly increased concentrations downstream of the Rocky River. Chemical oxygen demand, although not statistically tested, also exhibited an increasing trend with distance from the Tillery Hydroelectric Plant. Ammonia-nitrogen was the only parameter with significantly greater mean concentrations in Lake Tillery bottom waters and the immediate tailwaters Station TY1B, which confirmed previous spatial analyses. 5.3.2.2 Relationships between Water Quality and Flow in Lake Tillery Tailwaters and Rocky River Kendall's tau b correlation analysis indicated some similar relationships between water quality parameters and daily average flow at the tailwaters Station TY1B compared to the correlation analysis for Lake Tillery surface waters for the years 2000, 2002, and 2004 (Table 5-7). There were significant negative relationships between daily average flow and water temperature, specific conductance, total alkalinity, and sodium at Station TY1B, although correlation coefficients were weak to moderate (Table 5-'). Positive relationships were observed between daily average flow and DO, total suspended solids, turbidity, nitrate + nitrite-nitrogen, total phosphorus, aluminum, and copper at Station TY1B. Other parameters pH, total solids, total dissolved solids, total nitrogen, ammonia-nitrogen, total organic carbon, COD, calcium, magnesium, chloride, and sulfate did not exhibit any significant correlation with daily average flow at Station TY1B. 5-42 Section 5 Results and Discussions Table 5-13 Spatial trends of mean concentrations of selected water chemistry parameters at Station BF132 (bottom waters) in Lake Tillery, Stati ons TY113 and TY12B in Reach 1, Rocky River, and Station BFH2 in Blewett Falls Lake headwaters during 2004. Power generation flow data (excep t Rocky River) were used for the analysis. Station Parameterl'Z TYB2 TY1 B RR TY12B BFH2 Lake Tillery Pee Dee River Rocky River Pee Dee River Blewett Falls (Reach 1) (Reach 1) Lake Solids (Mg L) Total solids 82 80, 1652 96 84 Total dissolved 701 691 1422 851 721 Total suspended 9.5 10 18 16 7.4 Turbidity (NTL) 19a1 9.61 242 19a1 101 Nutrients (M&L) Total nitrogen 0.60 0.89 0.81 0.66 0.59 Ammonia-N 0.082 0.062 0.021 0.021 0.021 Nitrate + nitrite-N 0.531 0.531 2.642 0.741 0.631 Total phosphorus 0.0501 0.0341 0.3202 0.0911 0.0601 Total organic carbon 2 9c 8c 4 92 3 81 31c 3 (mg/L) . . . Chemical oxygen demand 6 7 6 0 11 8 8 7 0 (nglL) 3 . . . . Biological oxygen < 2 < 2 < 2 < 2 < 2 demand (mg,1) 3 Ions (M&L) Calcium 4.9 5.2 122 6.0 5.4 Magnesium 2.11 2.11 4.82 2.61 2.41 Sodium 6.01 6.31 16a 6.61 7.2 1 Chloride 9.11 9.01 21 a 111 9.81 Sulfate 5.4c 5 5c 17a 9 81 7 The Specific conductance 941 911 222a 1111 1011 (cDS;'cm) Hardness4 211 221 51 a 261 231 Total alkalinity4 211 211 33a 221 231 bH 7.Oc 7.51 7.8a1 7.41 8.0a Trace elements (d") Aluminum 666 291 703 528 259 Copper 2.41 2.01 4.8a 2.81 2.21 1 Sample size (n) equaled 12. Statistical analyses were utilized only when the majority of values for a particular parameter were above the analytical lower reporting limits. 2 Fisher's protected least significant difference (LSD) test was applied only if the overall ANOVA F test for the treatment was significant. Means followed by different superscripts were significantly different (P # 0.05). Data were rounded to conform to significant digit requirements. Rounding may obscure mean differences. 3 Data were not statistically tested due to number of values below the laboratory LRL. Total alkalinity units are mg/L as CaCO3 and hardness is calculated as mg equivalents CaCO3/L. 5-43 Section 5 Results and Discussions The correlation analysis for the Rocky River for the years 2001, 2002, and 2004 indicated significant negative relationships between daily average flow and water temperature, specific conductance, total solids, total dissolved solids, total phosphorus, total organic carbon, total alkalinity, and most anions and cations (Table 5-7). Significant positive correlations were noted between daily average flow and total suspended solids, turbidity, and aluminum. Other water quality parameters showed no significant relationship with daily average flow for the Rocky River. 5.3.2.3 Spatial and Temporal Trends in Temperature, DO, PH, Specific Conductance, and Turbidity in Reach 1 During Power Generation and No Power Generation Periods Water temperatures showed a typical seasonal progression in Reach 1 with lowest temperatures during January, February, or December and a summertime maxima during July or August for the three years evaluated (Figures 5-15 to 5-17). The temperature regime in the Rocky River (Station RR) followed the same seasonal pattern with a similar temperature range. Maximum summertime temperatures ranged from 26.5°to 30.3°C at Stations TY1B and TY12B in Reach 1 over this survey period with a slightly greater temperature maxima occurring at Station TY 12B. Water temperatures in Reach 1 did not exceed the North Carolina water quality standard of 32°C in any year (NCDWQ 2004b). The temperature regime within Reach 1 was uniform with no statistically significant spatial or temporal differences (Tables 5-9 to 5-11). No significant differences were noted in water temperatures between Stations TY113, TY1213, and RR during either the power generation or no power generation periods in 2004 (Tables 5-9 to 5-11 and Figure 5-17). Additionally, there were no significant differences in mean temperatures between the power generation and no power generation paired t-test comparisons for Stations TYlBand TY12B(Table s-11). Finally, a two-way ANOVA for Stations TY113, TY1213, and RR for the years 2002 and 2004 (no data collected at Station RR in 2000) found no significant difference in mean temperatures among stations. This comparison utilized the power generation data for Stations TY1B and TY12B for 2004. The DO regime in Reach 1 and the Rocky River exhibited a seasonal pattern of greater DO concentrations in the cooler winter and fall months and DO minima during the warmer summer and early autumn months (Figures 5-15 to 5-17). There were no significant differences in mean DO concentrations at Stations TY113, TY1213, and RR during 2004 for comparisons within the power generation and no power generation period. However, the paired t-tests indicated there were significantly greater DO concentrations in the no power generation period vs. the power generation period at Stations TY1B and TY12B during 2004 (Table 5-11). Lower DO concentrations were observed for these stations during the summer months when low DO water was released from the hypolimnion of Lake Tillery during power generation periods. The DO minimum was also lower at Stations TY 1B and TY 12B in Reach 1 when compared to the Rocky River (Station RR) (Figures 5- 16 and 5-17). Dissolved oxygen concentrations less than the North Carolina instantaneous DO standard of 4.0 mg/L were observed at Station TY 1 B during July and September 2000 and July 2004 (Figures 5-15 and 5-17 and Appendix A, Tables A-4 to A-7). No DO concentrations were less than 4.0 mg/L at Station TY12B during the monthly surveys (2000 to 2004). Dissolved oxygen concentrations less than 5.0 mg/L (North Carolina daily average DO standard) occurred in 12.5 percent of the monthly measurements at Station TY 1 B from 2000 to 2004 while 2.0 percent of the monthly DO measurements at Station TY 12B were below 5.0 mg/L. More detailed assessments 5-44 Section 5 Results and Discussions 40 30 0 20 10 n Temperature Jan Feb ivbr Apr ivby Jun Jul Aug Sep Oct Nov Dec Month 16 14 12 10 m 8 E 6 4 2 0 uissotvea oxygen Jan Feb Mar Apr ivby Jun Jul Aug Sep Oct Nov Dec Month 500 400 E 300 V1 200 100 0 Specific conductance Jan Feb ivbr Apr ivby Jun Jul Aug Sep Oct Nov Dec Month 10 9 8 a 7 6 5 4 Jan Feb ivbr Apr ivby Jun Jul Aug Sep Oct Nov Dec Month 200 150 z 100 z 50 0 Jan Feb ivbr Apr ivby Jun Jul Aug Sep Oct Nov Dec Month Station TY1 B -? Station TY12B Figure 5-15 Monthly trends in water temperature, DO, specific conductance, pH, and turbidity at Stations TY1B and TY12B in Reach 1 of the Pee Dee River below the Tillery Hydroelectric Plant and Station RR located in the Rocky River during 2000. (Note: No data were collected for Rocky River, Station RR, during 2000) 5-45 Section 5 Results and Discussions 40 30 0 20 10 0 Temperature ?r ¦ Jan Feb iVbr Apr ivby Jun Jul Aug Sep Oct Nov Dec Month 16 14 12 ? 10 m 8 E 6 4 2 0 uissoivea oxygen Jan Feb iVbr Apr ivby Jun Jul Aug Sep Oct Nov Dec Month 1000 800 E 600 0) 400 200 0 Jan Feb iVbr Apr ivby Jun Jul Aug Sep Oct Nov Dec Month 10 9 8 x 7 a 6 5 A Specific conduktance ¦--¦.. {-1` ¦ -tom{ Jan Feb Mar Apr ivby Jun Jul Aug Sep Oct Nov Dec Month 100 75 z 50 z 25 0 Turbidity Jan Feb iVbr Apr ivby Jun Jul Aug Sep Oct Nov Dec Month Station TY1 B + Station TY12B-0- Station RR Figure 5-16 Monthly trends in water temperature, DO, specific conductance, pH, and turbidity at Stations TY1B and TY12B in Reach 1 of the Pee Dee River below the Tillery Hydroelectric Plant and Station RR located in the Rocky River during 2002. 5-46 Section 5 Results and Discussions 40 30 U 20 10 0 Temperature Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 16 14 12 10 a 8 E 6 4 2 0 Dissolved oxygen Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 500 400 E 300 U) 200 100 0 10 s 8 x 7 a 6 5 4 Specific conductance Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month pH Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 100 75 50 z 25 0 Turbidity E Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Station TY1 B + Station TY12B -*- Station RR Figure 5-17 Monthly trends in water temperature, DO, specific conductance, pH, and turbidity at Stations TY1B and TY12B in Reach 1 of the Pee Dee River below the Tillery Hydroelectric Plant and Station RR in the Rocky River during 2004. (Note: Power generation flow data are plotted for Stations TY1B and TY12B.) 5-47 Section 5 Results and Discussions of DO dynamics in Reach 1, including attainment of the North Carolina water quality standards for DO, are given in Progress Energy 2005a and 2005b. All DO concentrations in the Rocky River were above 5.0 mg/L during 2001, 2002, and 2004 (Figures 5-16 and 5-17 and Appendix A, Tables A-5 to A-7). Peak values of specific conductance were noted in the summer months in the Rocky River (Station RR) and Station TY1213, especially during 2002 (Figures 5-15 to 5-17). Specific conductance values were uniform at Station TY1B. The mean specific conductance was significantly greater in the Rocky River than the mean values at Stations TY113 and TY1213, which were statistically similar, during the power generation and no power generation periods in 2004 (Tables 5-9 and 5-10). There was also no significant difference between the power generation and no power generation periods for the paired t-test comparisons for Stations TY1B and TY12B (Table 5-11). However, the influence of Rocky River inflow on specific conductance in Reach 1 was evident in the temporal comparison for 2000, 2002, and 2004 because specific conductance was significantly greater at Station TY12B that at Stations TY132 and TY113 (Table 5-12). The pH values at Stations TY1B and TY12B were usually uniform and exhibited no distinct seasonal trends during 2000, 2002, or 2004 (Figures 5-15 to 5-17). There were no significant differences in pH values during power generation or no power generation periods for these stations during 2004 or for all three monitoring years. All pH values in Reach 1 (Stations TY1B and TY1213) were within the North Carolina water quality pH standards of 6.0 to 9.0 units during the three years of monitoring and also during 2001 when some additional monitoring was conducted (Appendix A, Tables A-4 to A-7). One pH value (9.1 units) in the Rocky River slightly exceeded the North Carolina water quality standard during January 2004 (Figure 5-17 and Appendix A, Table A-7). Turbidity values exhibited seasonal variability and peak values were usually associated with precipitation events and subsequent inflows into the river basin (Figures 5-15 to 5-17). Turbidity values were generally greater in the Rocky River and Station TY1213; located downstream of the river confluence, when compared to Station TY113 during 2004 or for the three years of water quality surveys (Tables 5-9, 5-10, and 5-12). This spatial difference was attributed to the greater sediment loading in the Rocky River watershed. The paired t-test comparison indicated significantly greater turbidity values during the generation period vs. no generation period at Station TY1B during 2004 (Table 5-11). There were no significant differences between the two generation periods for Station TY1213. Occasional turbidity values greater than the North Carolina water quality standard of 50 NTU were observed at Station TY12B in 2000 and 2001 (103-157 NTU) and in the Rocky River during 2001 and 2004 (55 and 83 NTU). No monthly turbidity values exceeded the water quality standard at Station TY113 during the 2000-2004 period (Figures 5-15 to 5-17 and Appendix A, Tables A-4 to A-7). Turbidity levels were lower in the Tillery tailwaters due to the filtering effect of sediments by upstream reservoirs, including Lake Tillery. 5.3.3 Blewett Falls Lake 5.3.3.1 Spatial and Temporal Trends in Blewett Falls Lake Water Chemistry Blewett Falls Lake is a shallow, nutrient-enriched, turbid, eutrophic reservoir with elevated solids and turbidity and weakly buffered soft waters (Tables 5-14 and 5-15). Concentrations of total 5-48 Section 5 Results and Discussions nitrogen and total phosphorus were elevated in Blewett Falls Lake for the survey period of 1999, 2001, and 2004 and indicated eutrophic conditions (Wetzel 2001). This eutrophic characterization was consistent with results from previous investigations since the 1980s (NCDEM 1983, 1989, 1992; CP&L 1995; NCDWQ 1998, 2002). Nutrient and sediment inputs from the surrounding watershed, most notably the Rocky River, resulted in distinct differences in the water quality characteristics and trophic status of Blewett Falls Lake compared to Lake Tillery. Total solids, total suspended solids, turbidity, total phosphorus, total organic carbon, and specific conductance were greater in the surface waters of Blewett Falls Lake when compared to Lake Tillery during 2004 (Tables 5-1 and 5-14). For example, annual mean turbidity was 1.5 times greater in Blewett Falls Lake than in Lake Tillery during 2004. Conversely, Secchi disk transparency was less in Blewett Falls Lake due to its turbid nature, usually less than one meter deep. The short retention time of Blewett Falls Lake (average of two days) resulted in few longitudinal differences in water chemistry parameters from the headwaters to lower reservoir during 2004 or for the survey years of 1999, 2001, and 2004 (Tables 5-14 and 5-15). The only spatial difference during 2004 was a significantly greater mean concentration of total suspended solids at Station BFB2 compared to Station BFH2 (Table 5-14). The total suspended solids mean concentration at Station BFF2 did not significantly differ from the other two stations. Secchi disk transparency was significantly greater at the headwaters Station BFH2 compared to the mid and lower reservoir area forthe 1999, 2001, and 2004 period (Table 5-15). The nitrate +nitrite-nitrogen mean concentration at Station BFH2 was significantly greater than the mean concentration at Station BFB2. The nitrate+nitrite mean concentration at Station BFF2 was intermediate in statistical ranking to Stations BFB2 and BFH2. Temporal analysis of water chemistry parameters during 1999, 2001, and 2004 indicated significant differences among years for mean concentrations of DO, total solids, total dissolved solids, all nutrient, anion, and cation constituents, total organic carbon, chemical oxygen demand, total alkalinity, hardness, pH, specific conductance, and copper (Table 5-16). Generally, most of these parameters had significantly greater mean concentrations during the lower flow years of 1999 and/or 2001 when compared to 2004 (Figures 5-2 and 5-6). The exceptions were total nitrogen, nitrate + nitrite-nitrogen, DO, and pH, which were similar to or greater in 2004 when compared to 1999 and 2001. Anion and cation concentrations in reservoir surface waters were in the moderate range during 2004 and ranked respectively as follows: sodium > calcium > magnesium and bicarbonate (alkalinity) > chloride > sulfate (Tables 5-14 and 5-16). This ranking was similar to other survey years except that sodium and sulfate were more predominant in the lower flow years of 1999 and 2001. 5-49 Section 5 Results and Discussions Table 5-14 Means, ranges (in parentheses), and spatial trends of water chemistry parameters from the surface and bottom waters of Blewett Falls Lake (Stations BF132, BFF2, and BFH2) during 2004. Parameter"' BFB2 BFB2 BFF2 BFF2 BFH2 Surface Bottom Surface Bottom Surface Temperature (EC) 18.6 16.9 18.7 17.1 18.2 (6.9-30.9) (6.4-27.6) (6.2-30.9) (6.0-27.7) (65-30.2) 11 0 7 3 10 2 7 4 10 - Dissolved oxygen (mg/L) . . . . . , (7.7-14.1) (1.4-12.4) (6.8-12.7) (0.7-12.6) (7.0-13.2) Total solids 90 109 86 112 84 (73-121) (78-180) (71-105) (84-186) (64-115) Total dissolved 74 (51-118) 72 (56-111) 70 (54-106) 73 (56-104) 72 (52-105) Total suspended l la 10 8.4ab 8.4 7.4b (3.3-18) (6.6-168) (4.4-17) (8.2-100) (4.4-17) Turbidity (NTtD 12 (0.5-20) 37 (6.5-76) 12 (0.9-28) 53 (2.6-153) 10 (0.5-31) Secchi disk transparency 0.7 NA 4 0.8 NA 4 0.9 depth (m) (0.3-1.1) (0.4-1.5) (0.4-1.4) Nutrients (mg/L) Total nitrogen 0.57 0.95 0.62 0.68 0.59 (0.37-0.80) (0.32-3.9) (0.36-1.4) (0.40-1.2) (0.30-1.3) Ammonia-N 0.03 0.07 0.03 0.09 0.02 (__ 0.02-0.11) (< 0.02-0.19) (< 0.02-0.14) (< 0.02-0.31) (< 0.02-0.07) Nitrate + nitrite-N 0.51 0.65 0.58 0.56 0.63 (< 0.02-0.86) (0.24-1.54) (< 0.02-0.87) (0.13-0.86) (< 0.02-1.4) Total phosphorus 0.062 0.133 0.061 0.095 0.061 (0.037-0.086) (0.051-0.654) (0.044-0.092) (0.054-0.205) (0.033-0.122) Total organic carbon (mg/L) 3.2 3.3 3.2 3.2 3.3 (2.2-4.6) (2.3-4.8) (2.2-4.4) (2.2-4.5) (2.5-4.8) Chlorophyll a((Dg/L) (3.9-33) 16 NA4 (1.51-0 26 NA4 8.5 (1.2-26) Chemical oxygen demand < 10 <10 <10 <10 <10 (mg/L) (< 10-14) (< 10-14) (< 10-22) (< 10-18) (< 10-14) Biological oxygen demand < 2 < 2 < 2 1.2 < 2 (mg/L) (< 2-3.4) < 2-4.2 (< 2-3.0) (< 3.6) (< 2-2.5) Calcium 5.4 5.9 5.3 5.8 5.4 (1.8-6.5) (1.8-8.9) (1.9-6.4) (2.0-7.2) (1.6-7.1) Magnesium 2.3 2.8 2.3 2.6 2.4 (< 1.0-2.7) (< 1.0-6.6) (< 1.0-3.0) (1.0-3.5) (< 1.0-3.6) Sodium 6.9 6.9 7.1 7.3 7.2 (4.8-8.6) (5.1-8.7) (5.0-9.5) (5.7-10) (4.8-12) Chloride 9.8 9.8 9.7 9.9 9.8 (6.8-13) (7.6-12) (6.7-13) (6.8-14) (6.8-16) Sulfate 6.9 7.0 6.9 7.4 7.1 (5.1-9.7) (5.3-10) (5.6-8.6) (5.2-12) (3.5-12) Specific conductance ((DS/cm) 99 (85-114) 104 (92-130) 101 (83-117) 106 (95-131) 101 (78-150) Hardness(calculated)5 23 26 22 25 23 (4.5-27) (4.4-49) (4.7-28) (9.2-32) (4.1-32) Total alkalinity' 23 23 22 23 23 (20-26) (19-26) (18-26) (15-36) (19-33) H p 8.2 7.2 7.9 7.3 8.0 (7.1-9.6 (6.6-7.9) (7.0-9.1) (6.6-7.8) (6.9-9.0) 5-50 Section 5 Results and Discussions Station Parameter BFB2 BFB2 BFF2 BFF2 BFH2 Surface Bottom Surface Bottom Surface Trace elements (Og/L) Aliuninum 290 927 309 1,018 259 (90-721) (181-3,080) (86-940) (284-3,830) (104-884) Copper 2.6 3.3 2.2 4.0 2.2 (1.3-5.3) (1.6-5.9) (< 2.0-3.6) (1.6-9.4) (< 2.0-4.2) Mercury < 0.2 < 0.2 < 0.2 < 0.2 < 0.2 1 Sample size (n) equaled 12. Less than values (<) indicate the Lower Reporting Limit (LRL) for the parameter. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably reported. Statistical analyses were utilized only when mean concentrations were above the analytical lower reporting limits. Missing range values indicate that all measured values were less than the LRL for that parameter. 2 Fisher's protected least significant difference (LSD) test was applied only if the overall ANOVA F test for the treatment was significant. Means followed by different superscripts were significantly different (P # 0.05). Data were rounded to conform to significant digit requirem ents. Rounding may obscure mean differences. The statistical test results only apply to surface waters at Stations BFB2, BFF2, and BFH2. 3 December values for total suspended solids, chemical oxygen demand, aluminum, and copper were omitted due to suspected sample contamination. 4 NA means not applicable because no Secchi disk transparency or chlorophyll a data were collected from bottom waters. 5 Total alkalinity units are mg/L as CaCO3 and hardness is calculated as mg equivalents CaCO3/L. 5-51 Section 5 Results and Discussions Table 5-15 Comparison of spatial trends of annual means for selected water chemistry parameters at Stations BFB2, BFF2, and BFH2 from the surface waters of Blewett Falls Lake for 1999, 2001, and 2004. Parameter"' Station 13FB2 BFF2 BFH2 Temperature CC) 18.6 18.5 17.9 Dissolved oxygen (mg/L) 10.0 10.0 9.7 Total solids 9b 9-1) 94 Total dissolved 88 85 89 Total suspended 8.9 9.5 7.2 Turbidity (NTq 14 15 11 Secchi disk transparency depth (m) 0.8b 0.81 l.la Ainm onia-N 0.06 0.04 0.04 Nitrate + nitrite-N 0.40b 0.46x1 0.58a Total nitrogen 0.56 0.56 0.48 Total phosphorus 0.078 0.087 0.089 Total organic carbon (mg/L) 4.2 3.9 3.9 Chemical oxygen demand 12 12 11 Chlorophyll a (, ig/L) 15a 13a 6.76 Calcium 6.0 5.9 6.1 Chloride 12 12 13 Magnesium 2.6 2.5 2.6 Sodium 12 12 13 Sulfate 10 9.7 11 Total alkalinity (mg/L as CaCO3) 28 27 28 Hardness (mg equivalents CaCO3/L) 26 25 26 Specific conductance ((DS/cm) 123 122 125 pH 7.4 7.4 7.4 Aluminum 266 292 239 Copper 2.9 19 3.2 1 Sample size (n) equaled 36 for each parameter and station. Less than values (<) indicate the Lower Reporting Limit tLRL) for the parameter. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably reported. Statistical analyses were utilized only when mean concentrations were above the analytical lower reporting limits. Missing range values indicate that all measured values were less than the LRL for that parameter. 2 Fisher's protected least significant difference (LSD) test was applied only if the overall ANOVA F test for the treatment was significant. Means followed by different superscripts were significantly different (P # 0.05). Data were rounded to conform to significant digit requirements. Rounding may obscure mean differences. 5-52 Section 5 Results and Discussions Table 5-16 Comparison of temporal trends of annual means for selected water chemistry parameters from the surface waters of Blewett Falls Lake (Stations BFB2, BFF2, and BFH2) for 1999, 2001, and 2004. Parameter' Year 1999 2001 2004 Temperature (BC) 18.5 18.0 18.5 Dissolved oxygen (mg/L) 9.1b 10.1a 10.5a Solids (mg/L) Total solids 91' 107a 87' Total dissolved 90a 100a 72' Total suspended 8.0 8.7 8.8 Turbidity (NTI) 15 14 11 Secchi disk transuarencv denth (m) 0.9 0.9 0.8 Nutrients (mg/L) Ammonia-N 0.05a 0.07a 0.03b Nitrate + nitrite-N 0.37' 0.50ab 0.57a Total nitrogen 0.42' 0.58a 0.59a Total phosphorus 0.075b 0.117a 0.061' Total organic carbon (mg/L) 4.6b 4 8a 3.2c Chemical oxygen demand I lb 16a 8.0` Chloronhvll a (uaI) 9.4 14 11 Ions (mg/L) Calcium 5.41 7 2a 5.4 b Chloride 12b 15a 8` Magnesium 2.5b 2.9a 2.3b Sodium 14a 15a 7.Ob Sulfate 9.0' 14a 6.9` Total alkalinity (mg/L as CaCO3) 28' 34a 23` Hardness (mg equivalents CaCO3/L) 24' 30a 23' Specific conductance ((DS/cm) 124b 145a 100` pH 7.Ob 7.2b 8.0a Trace elements (d?%L) Aluminum 228 283 286 Copper 3.93 2.6b 2.4b 1 Sample size (n) equaled 36 for each parameter and year. Less than values (<) indicate the Lower Reporting Limit tLRL) for the parameter. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably reported. Statistical analyses were utilized only when mean concentrations were above the analytical lower reporting limits. Missing range values indicate that all measured values were less than the LRL for that parameter. 2 Fishers protected least significant difference (LSD) test was applied only if the overall ANOVA F test for the treatment was significant. Means followed by different superscripts were significantly different (P # 0.05). Data were rounded to conform to significant digit requirements. Rounding may obscure mean differences. 5-53 Section 5 Results and Discussions There were some significant differences in surface versus bottom concentrations of several water chemistry variables at Stations BFB2 and BFF2 during 2004 (Tables 5-14 and 5-17). The Pee Dee River inflow likely influenced concentrations of several water chemistry parameters in the bottom waters at Station BFF2. Annual mean concentrations of total solids, total suspended solids, turbidity, ammonia-nitrogen, total phosphorus, aluminum, and copper were significantly greater in bottom waters than in surface waters at Stations BFF2. At Station BFB2, only total solids and turbidity were significantly greater in bottom waters compared to surface waters. Copper and mercury concentrations were generally low in the reservoir during 1999, 2001, and 2004 (Tables 5-14 to 5-16 and Appendix D, Tables D-1 to D-3). Mercury concentrations were less than the laboratory reporting limit of 0.2 gg/L for all samples collected in the three survey years. Copper concentrations occasionally exceeded the North Carolina Action Level of 7 gg/L with the greatest number of samples exceeding the Action Level occurring in 1999 (25 percent of the 36 samples collected from Stations BFB2, BFF2, and BFH2) (Appendix D, Tables D-1 to D-3). Chlorophyll a concentrations were variable and ranged from 1.8 to 41 gg/L in 1999, from 2.7 to 39 gg/L in 2001, and from 1.2 to 33 gg/L in 2004 (Figure 5-18). Although total nitrogen and phosphorus concentrations were elevated in Blewett Falls Lake, annual mean chlorophyll a concentrations were in the moderate range (9.4 to 14 gg/L) reflecting meostrophic conditions. Algal dynamics were largely influenced by reservoir's short hydraulic retention time which limited nutrient uptake by phytoplankton and subsequent production. Additionally, turbid water conditions, resulting mainly from sediment inputs, limited light penetration for photosynthesis. During periods of lower inflow and power generation, algal photosynthesis and production increased and subsequently chlorophyll a concentrations peaked. No significant temporal differences in mean chlorophyll a concentrations were found among the three survey years (Table 5-16). There was a significant longitudinal difference in chlorophyll a concentrations from the headwaters to the lower reservoir over the three survey years (Table 5-15 and Figure 5-18). Chlorophyll a concentrations were greater at the mid and lower reservoir stations than at the headwaters station for the three-year period. Only one chlorophyll a value exceeded the North Carolina water quality standard of 40 gg/L, and that value (41 gg/L) occurred at Station BFF2 during June 1999. 5.3.3.2 Relationships between Water Quality and Lake Level and Flow in Blewett Falls Lake Kendall's tau b correlation analysis showed several significant, but weak relationships between daily average lake level and water quality parameters in Blewett Falls Lake (Table 5-18). There were significant negative correlations between lake level and pH, total suspended solids, and aluminum (i.e., a lower lake level corresponded to a greater concentration of a given parameter). Significant positive correlations occurred between lake level and specific conductance, ammonia-nitrogen, total alkalinity, sodium, and sulfate. The negative correlations suggested that lake level was lowered during anticipated high flow events to capture the inflow or that the dam flash boards were displaced due to the amount of inflow compared to the reservoir volume and power plant hydraulic capacity. Aluminum and total suspended solids are usually elevated during and immediately after high-flow events while pH can be lower due to the slightly acidic nature of precipitation. Conversely, ahigher lake level may have indicated less lake level fluctuation during lower flow periods which usually 5-54 Section 5 Results and Discussions Table 5-17 Paired t-test results of differences between surface and bottom waters at Stations BFB2 and BFF2 for selected water chemistry parameters in Blewett Falls Lake during 2004. Parameterr12 Station BFB2 BFF2 Solids (m,-,IL) Total solids bottom > surface bottom > surface Total dissolved n.s. n.s. ** Total suspended n.s. bottom > surface Turbidity (NTL>7 bottom => surface bottom > surface Nutrients (mg/L) Total nitrogen n.s. n. s. Ammonia-N n. s. bottom > surface Nitrate + nitrite-N n.s. n. s. .k Total phosphorus n. s. bottom > surface Total organic carbon (mg/L) n. s. n. s. Ions (nwlL) Calcium n. s. n. s. Magnesium n. s. n. s. Sodium n. s. n. s. Chloride n. s. n. s. Sulfate n. S. n. s. Hardness (calculated) n. S. n. s. Total alkalinity n.s. n. s. Trace elements (0,qJL) .k Aluminum n. s. bottom > surface Copper n. s. bottom > surface 1 A paired t-test was applied to determine differences between surface and bottom concentrations of each parameter when applicable. P values: n.s. =not significant (P> 0.05), * = 0.01 < P # 0.05; ** = 0.001 < P # 0.01, and *** = P 0.001. See Tables 4-1 and 4-2 for values of each parameter. 2 Bottom samples of aluminum, copper, total suspended solids, and COD during December 2004 were excluded from analysis due to suspected sample contamination. 5-55 Section 5 Results and Discussions a 60 Blewett Falls Lake -1999 = 50 40 '5. 30 0 20 B 10 V 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Station BFB2 -Station BFF2 Station BFI-12 60 50 40 S 30 0 20 0 10 L) 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Station BFB2 -Station BFF2 Station BFI-12 60 50 40 30 0 20 0 10 V 0 Blewett Falls Lake - 2004 P= Not Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Station BFB2 -Station BFF2 Station BFI-12 Figure 5-18 Temporal and spatial trends in chlorophyll a concentrations in Blewett Falls Lake during 1999, 2001, and 2004. (Note: Statistical results among lake stations are shown within each graph with different letter superscripts indicating significantly different mean values.) 5-56 Section 5 Results and Discussions Table 5-18 Kendall's tau b correlation coefficients of daily average lake level versus water quality parameters in the surface waters of Blewett Falls Lake (Stations BFB2, BFF2, and BFH2) for the period of 1999, 2001, and 2004. Parameter' Kendall's Tau b Correlation Coefficient Temperature n. s. Dissolved oxygen n. s. PH -0.3287 *** Specific conductance 0.1*57 Total solids n. s. Total dissolved solids n. s. Total suspended solids 0.1346 Turbidity n. s. Total nitrogen n. s. Ammonia-N 0.2701 *** Nitrite + nitrate-N n. s. Total phosphorus n. s. Total organic carbon n. s. Chlorophyll a n. s. Total alkalinity 0.1809 ** Chemical oxygen demand n. s. Calcium n. s. Magnesium n. s. Sodium 0.1905 ** Chloride n. s. Sulfate 0.1649 * Aluminum -0.1532 * Copper n. s. 1 Pvalues: n.s.=not significant(P>0.05),*=0.01<P#0.05;**=0.001<P#0.01,and***=P<0.001 5-57 Section 5 Results and Discussions corresponded to increased anion and cation concentrations, specific conductance, and total alkalinity. The response of ammonia-nitrogen concentrations may have resulted from denitrification processes and increased concentrations with a greater retention time associated with lower flow and associated lake level conditions. Weak to moderately significant negative relationships existed for the majority of correlations between daily average flow and water quality parameters, which included total solids, total dissolved solids, ammonia-nitrogen, total phosphorus, total organic carbon, chlorophyll a, total alkalinity, COD, all anions and cations, and specific conductance (Table 5-19). Higher flow resulted in increased reservoir flushing with a shorter reservoir retention time, and subsequently decreased concentrations of these parameters. Most high flow events occurred during the winter, early spring or fall months (usually associated with passage of low pressure and tropical storm weather systems). Lower flow periods, including both inflow and outflow, coupled with evaporative processes, increased solids, anions, cations, specific conductance, nutrients, and subsequent algal photosynthesis and chlorophyll a concentrations. The higher COD values likely resulted from greater organic decomposition with increased hydraulic retention time during lower flow periods. There were weak, but significant positive correlations between flow and DO, nitrate + nitrite- nitrogen, aluminum, and copper (Table 5 19). 5.3.3.3 Spatial and Temporal Trends in Temperature, Dissolved Oxygen, pH, Specific Conductance, Secchi Disk Transparency, and Turbidity in Blewett Falls Lake Surface Waters The temperature and DO regimes in Blewett Falls Lake surface waters were uniform with no longitudinal gradient observed for either parameter during 2004 or for the 1999, 2001, and 2004 survey period (Tables 5-14 and 5-15 and Appendix B, Tables B-1 to B-3). Water temperatures in the reservoir follow an annual seasonal cycle with minimum temperature ranging from 6°to 8°C and maximum temperatures ranging from 28°to 32°C (Appendix B, Tables B-1 to B-3). There were no instances of water temperatures exceeding the North Carolina water standard of 32°C during the three years of water quality surveys. Dissolved oxygen concentrations in reservoir surface waters were above the North Carolina instantaneous (4.0 mg/L) and daily average (5.0 mg/L) water quality standards in 2004 as well as in 1999 and 2001 (Appendix B, Tables B-1 to B-3). There were some instances of supersaturated dissolved oxygen conditions, and these events were usually associated with phytoplankton blooms in the reservoir (e.g., May 2001 and 2004 and July to August 2004). There were significantly greater mean DO concentrations during 2001 and 2004 compared to 1999 which may have resulted from greater algal photosynthesis during those years (Table 5-16 and Figure 5-18). The pH values in reservoir surface waters ranged from near neutral to basic during the survey years of 1999, 2001, and 2004 (Tables 5-14 and 5-16 and Appendix B, Tables B-1 to B-3). Similar to temperature and DO, there were no significant longitudinal or spatial differences in pH values within the reservoir during 2004 orforthe three year survey period (Tables 5-14 and 5-15). However, the mean pH value was significantly greater in 2004 compared to the 1999 and 2001 mean values (Table 5-16). There were occasional pH values in reservoir surface waters that exceeded the North 5-58 Section 5 Results and Discussions Table 5-19 Kendall's tau b correlation coefficients of daily average flow (cfs) versus water quality parameters in the surface waters of Blewett Falls Lake (Stations BFB2, BFF2, and BFH2), the Pee Dee River tailwaters below the Blewett Falls Hydroelectric Plant (Stations BF113 and BF2B), and the lower Pee Dee River (Stations BFB3 and BFB4) for the years 1999, 2001, and 2004. Location Parameter Blewett Falls Lower Pee Dee Blewett Falls Lake Tailwaters River Temperature -0.1775 -0.2715 -0.2498 Dissolved oxygen 0.1556 0.1* 17 n. s. pH n. s. n. s. n. s. Specific conductance -0.3890 -0.4848 -0.5296 Total solids -0.2142 n s -0.3010 Total dissolved solids -0.2017 n s -0.3483 Total suspended solids n. s. 0.3166 0.3198 Turbidity n. s. 0.3229 0.4156 Total nitrogen n. s. n. s. n. s. Ammonia-N -0.2229 -0.2205 n. s. Nitrate-nitrite-N 0.1553 0.3770 0.3997 Total phosphorus -0.2009 n s -0.1892 Total organic carbon -0.2118 n s -0.1606 Chlorophyll a -0. **32 NA NA Total alkalinity -0.4271 -0.3882 -0.4887 Chemical oxygen demand 0 .25 15 n. s. -0.1891 ** * Calcium -0.2370 n. s. n. s. Magnesium -0.2270 -0.2418 n. s. Sodium -0.3397 -0.3759 -0.5443 Chloride -0.3240 -0.3663 -0.4524 Sulfate -0.3781 -0.3785 -0.3976 Aluminum 0.1585 0.3911 0.3420 Copper 0.1420 n. s. n. s. 1 Average daily flow estimated for BF2B by applying average flow (cfs) per square mile to USGS Rockingham gage data. 2 Pvalues: n.s.=notsignificant(P>0.05),*=0.01<P#0.05, **=0.001<P#0.01,and***=P<0.001. 5-59 Section 5 Results and Discussions Carolina water quality standard of 9.0 units (NCDWQ 2004b), and these exceedances were associated with algal bloom conditions, especially during 2004 (Appendix B, Tables B-1 to B-3). Approximately 3 and 11 percent of the surface water pH measurements taken during 2001 and 2004, respectively, exceeded 9.0 units. No pH values measured in 1999 from Blewett Falls Lake exceeded 9.0 units. There were no spatial differences in specific conductance orturbidity from the headwaters to lower reservoir area during 2004 or for the 1999, 2001, and 2004 period (Tables 5-14 and 5-15). Both water quality parameters were greater in Blewett Falls Lake when compared to Lake Tillery, which reflected the influence of the Rocky River inflow on the reservoir's water quality (Tables 5-2 and 5-15). Annual mean specific conductance values were significantly greater during the lower flow years of 1999 and 2001 compared to 2004 and corresponded to the significant increases of anions, cations, and total dissolved solids in reservoir waters (Table 5-16). There were no temporal differences in mean turbidity values among the three years of water quality surveys (Table 5-16). However, there were several instances during the three years of water quality surveys when turbidity values in both surface and bottom waters of Blewett Falls Lake exceeded the North Carolina water quality standard of 25 NTU (NCDWQ 2004b). The number of turbidity exceedances per total number of sample measurements for surface waters within a given year were 14 percent during 1999, 11 percent during 2001, and 6 percent during 2004 (Appendix D, Tables D-1 to D-3). For bottom water measurements at Stations BFB2 and BFF2 during 2004, the number of turbidity exceedances was 79 percent of the total number of measurements. Annual peak turbidity values in reservoir surface waters ranged from 31 to 52 NTU during 1999, 2001, and 2004. Secchi disk transparencies indicated turbid water conditions in Blewett Falls Lake (Tables 5-14 to 5-16 and Appendix B, Tables B-1 to B-3). The mean reservoir-wide Secchi disk transparency ranged from 0.8 to 0.9 m during the 1999, 2001, and 2004 survey period (Table 5-16). These turbid conditions resulted in a shallow photic zone (approximately 1 to 2 m) within the reservoir. Spatially, the headwaters Station BFH2 had a significantly greater Secchi disk transparency depth than the mid and lower reservoir areas (Stations BFB2 and BFF2) for the three year survey period (Table 5-15). No spatial differences were noted in Secchi disk transparencies during 2004 (Table 5-14). 5.3.3.4 Temperature and DO Stratification Patterns in Blewett Falls Lake The shallow nature of Blewett Falls Lake, coupled with river inflow and power plant operations, influenced the temperature stratification and DO depletion patterns within the reservoir (Figures 5-19 to 5-24). In contrast to Lake Tillery, which had a well-defined temperature stratification period, Blewett Falls Lake had very weak to moderate temperature stratification in the middle and lower reservoir areas during the summer months. Water temperature differences from the surface to bottom waters ranged from 0.4°to 5.2°C during the temperature stratification periods of 1999, 2001, and 2004. The upper reservoir (Station BFH2) was always well-mixed and uniform in temperature and DO throughout the year due to the shallow, semi-riverine nature of this headwaters area (Appendix B, Tables B-1 to B-3). Temperature stratification and DO depletion were also independent processes in Blewett Falls Lake and therefore did not closely correspond together as observed in Lake Tillery. There were also no well-defined epilimnion, metalimnion, and hypolimnion strata in Blewett Falls Lake during the stratification period as was the case in Lake Tillery. 5-60 Section 5 January 0.2 i� 0.2 E 2.0 E 2,O 4.0d �^ .0 CL Q F CL Q .0 i ,0 8.0 8.0 U 5 10 '15 20 25 30 35 0 Water temperature (°C) February Results and Discussions 5 10 15 2C) 25 53 1 � 5 Water temperature (°C) August 0.2 0,2 . 2.0 E 2.0 1 4.0 4,0 CL X3.0 &0 5 10 15 0 25 30 35 0 5 1 '15 20 25 30 35 Water temperature (°C) Water temperature (°C) March Se Pte Mbe r 0,2 0,2 T 2.0 2, O 1 4.0 � 4-U .[ _D 8.0 0 5 10 '15 20 25 30 35 0 5 10 15 20 25 ;. 0 35 Water temperature (°C) Water temperature (°C) pri I 2 October 0.2 ■ o, k ■ , + 2.0 11 0 d0 ' . } 8. C) C 5 10 15 20 25 30 35 0 5 10 15 20 25 30 35 Water temperature (°C) Water temperature (°C) 0,2 i ;, 0,2 E 2, E 2,0 4.0 4,0 a -yy C r .l? Q .0 i 8, �+��yF 8,0- P 0 5 10 15 20 25 30 35 0 6 10 15 20 25 '10 35 Water temperature (°C) Water temperature (°C) June December 0.2 � r� 0,2- E .0 # E O 4.0 4.0 CL CL T T 8.0 L 5 10 15 20 25 :_ 0 :_r 0 5 10 15 20 25 30 3 Water temperature (°C) Water temperature (°C) Station BFB2 Station BFD2------- Station BFF2— — — - Station BFH2 Figure 5-19 Monthly water temperature profiles in Blewett Falls Lake during 2004. 5-61 Section 5 E i.i E January 0,2 ■ 2.0 ti ■ 4.0 6.0 ■ ■ 8.0 0 2 4 B 8 12 14 1 Dissolved oxygen (mg/L) February 0 2.0 4. C- G. 0 G.0 � i 0 2 4 6 8 1 12 14 1 Dissolved oxygen (mg/L) March 0-2 • 2.0 F .0 F 6.0 ■ 8.0 0 2 4 8 10 12 14 16 Dissolved oxygen (mg/L) .April 0,2 2.0 4.0 6.0 0 2 4 G 8 '10 12 14 1 Dissolved oxygen (mg/L) May R 2.0 r r 4.0 6.0 .0 0 2 4 (; 8 10 '12 14 10 Dissolved oxygen (mg/L) ,luno 0.2 1 F I _i E CL 0 E CL 0 a 20O 4.0CL Results and Discussions July I{{I���' .2- /'f� 4 I 4 L-0 - 4-0- 6.0, -6.0 + 8.01 - 0 2 4 C) 8 10 12 '14 '1 G) Dissolved oxygen (mg/L) August 0. - -F_ 2.0-" r .0 r 8.0-1 2 4 6 8 10 12 14 1 Dissolved oxygen (mg/L) September 0.2 f ■ 2-0 4-0 r -0 ' 8.0 0 2 4 8 10 12 14 16 Dissolved oxygen (mg/L) October 0.2 �r 2-0 4-0 e -0 ,0 C) 2 4 9 10 12 14 16 Dissolved oxygen (mg/L) November 0.2 2, 0 4.0 , 8.■ 0 o � . 0 2 4 r � 10 12 -14 16 Dissolved oxygen (mg/L) Der,ernher 0.2 2.0 4,0 .0 8,0 0 2 4 6 8 10 12 14 16 0 2 4 6 8 10 12 14 1 Dissolved oxygen (mg/L) Dissolved oxygen (mg/L) Station BF132 Station BFD2------- Station BFF2- - - - Station BFI -12 Figure 5-20 Monthly DO profiles in Blewett Falls Lake during 2004. 5-62 Section 5 Results and Discussions 0-2 1: January 0.2 Ju ly E 2.0 E 2.0 4.0 4-0 6-0 6.0 0 5 '10 15 20 25 30 35 0 5 10 '15 20 25 30 � �} Water temperature (°C) Water temperature (°C) February August 0.2 0.2 ' 1 E 2.0 E 2.0" �// r } = 4.0 I 4-0 ,f 1CL (1) - (1) 6.0 0 0 ' &0 `` .0 0 5 10 '15 20 25 �0 35 o 5 10 15 20 25 30 35 Water temperature (°C) Water temperature (°C) Isla re h September 0.2 0.2 I .� 2.0 2.0. 4.0 4-0 CL CL p $_0 8.0 0 5 110 15 20 25 30 35 0 5 10 '15 20 25 30 35 Water temperature (°C) Water temperature (°C) Agri I October 0.2 I 0.2 2.0 ':� 2.0 E E 4.0 s4.0- 6,0 .[ ,i w 6.0- 8_0 .0 g0 D 8.0} 0 5 10 15 20 25 30 35 0 5 10 15 20 25 30 35 Water temperature (°C) Water temperature (°C) I1by November 0.2 O.2� 2.0 % 2.0- 4,0 .0 4.0 ' ' s 4.0- 6,0 �.' .0 o 8.0 EI.0 - 0 5 10 15 20 25 30 35 0 5 10 15 20 25 30 35 Water temperature (°C) Water temperature (°C) June December 0-2 � 0-2 2.0 2.0 s 4.0 s 4.0 a� _06.0 8.0.o 5 10 15 20 25 30 35 0 5 10 15 20 25 30 35 Water temperature (°C) Water temperature (°C) Station BFB2 - - - - - - - Station BFF2 - - - -Station BFH2 Figure 5-21 Monthly water temperature profiles in Blewett Falls Lake during 1999. 5-63 Section 5 Results and Discussions 0-2 January 1 02 July 2,0 2.oE E 4.0 s 4.0 C CL 6,0 6.0 (1) 0 2 4 d 10 '12 14 16' 0 2 4 G 8 '10 12 14 1G Dissolved oxygen (mg/L) Dissolved oxygen (mg/L) February August 0.2 0.2 E 2.0 2.0 4-0 s 4.0 oCL 6.0 6.0 0 2 4 6 10 12 14 16 -2 4 6 8 '1 12 14 16 Dissolved oxygen (mg/L) Dissolved oxygen (mg/L) March Septemb -or 0-2 0.2 2-0 2.0 4,0 s 4.0 6,0 6.0 8.0 8.0 0 2 4 G 8 10 12 '14 16 2 4 6 8 1 '12 '14 10 Dissolved oxygen (mg/L) Dissolved oxygen (mg/L) April October 0.2 - 02 2-0 2.0 E E 4,0 f 4.0 CL 6,0 6.0 8.0- 0 2 4 (3) B 10 '12 '14 16 0 2 4 G 8 1 12 14 16 Dissolved oxygen (mg/L) Dissolved oxygen (mg/L) Ifty November 0-2 0,2- 2.0 2.0 E E 4-0 4,0 6-0 6.0 8.0 o .0 0 2 4 6 8 10 12 14 16 0 2 4 63 '10 '12 '14 16 Dissolved oxygen (mg/L) Dissolved oxygen (mg/L) June December 0.2 0-2 2.0 2.0 4.0 4-0 CL 6.0 CL 6.0 C 8.0 08.0 2 4 5 8 10 12 14 16 0 2 4 G 8 10 12 14 16 Dissolved oxygen (mg/L) Dissolved oxygen (mg/L) Station BFB2 ------- Station BFF2 - - - - Station BFH2 Figure 5-22 Monthly DO profiles in Blewett Falls Lake during 1999. 5-64 Section 5 Results and Discussions January July 0.2 0.2- E 2.0 E ZO P 4.0 4.0 - CL CL 6.0 a 6.0- 0 5 10 15 20 25 30 35 0 5 10 15 20 25 30 35 Water temperature (OC) Water temperature (OC) February August 0.2 0.2 E 2.0 E 2-0 4.0 4.0 CL CL Q 6.0 Q 6.0 8.0 8.0 5 10 15 20 29 30 35 0 5 10 15 20 25 30 35 Water temperature (OC) Water temperature (OC) March September 0.2 0,2 E 2.0 2-0 E 4.0 s 4.0 6.0 CL 6 -0 8,0 8.0 0 5 10 1,5 20 25 30 35 a 5 10 15 20 25 30 35 Water temperature (OC) Water temperature (OC) 0,2- April 0-2 Ootober E %..Wo 2.0- 2-0 4.0 Q.]CL 6,0 Q6.0 &0 0 5 1 cry 15 20 25 30 3 5 0 5 10 15 20 25 3G 35 Water temperature (OC) Water temperature (OC) huy November 02 I 2.0 202 ,0 E X E 4-0 CL 6-0 CL 6.0 8-0 D 8,0 0 5 1 15 20 2�) 30 35 0 5 10 15 20 25 3D 35 Water temperature (OC) Water temperature (OC) June December 0.2 1: 0.2 2.0 ZO E E 4.0 14. U 1-1 cL 1-1 CL 6.0 6.0 8.0 Q 8.0 0 5 1, 15 20 25 no 35 0 5 10 15 20 25 30 35 Water temperature (OC) Water temperature (OC) Station BFB2 ------- Station BFF2 - - - - Station BFH2 Figure 5-23 Monthly water temperature profiles in Blewett Falls Lake during 2001, 5-65 Section 5 January 0, I ,04-0 i 4.0 C 6.0 8.0 Dissolved oxygen (mg/L) February 0. , 0 I 1 1 . 4.0 1 i.i 0 6,0 8.0 Dissolved oxygen (mg/L) rVb rr, h 0, E ,0 1 � I s 4,0 � 1 6,0 D ,0 . a 0 2 4 6 3 10 1. '14 1 Dissolved oxygen (mg/L) April 0.2 E .0 s 4.0 1-1 C 6,0 ; o 8.o- 0 2 4 6 8 '10 '12 14 1 Dissolved oxygen (mg/L) lVbY 0-2 4.0 C 6.0 ,0 0 2 4 € i 10 12 14 1 Dissolved oxygen (mg/L) June 0, r 2.0 4,0 F 6,0 "r . 0 2 4 G 3 '10 '1. '14 1 Dissolved oxygen (mg/L) Results and Discussions July 0, l .0 4,0- CL ,0C .0 - s Dissolved oxygen (mg/L) August 0. i E 2.0 f' 4.0 - r .0 �. 8.0 4 G 8 1 '1 '14 16 Dissolved oxygen (mg/L) pternber 0.2 ark E 2.0"r ! 4.0CL (1) I Dissolved oxygen (mg/L) October 0. 2.0- 4.0- 6,0- 8.0- 6 04.0 ,0. r 0 2 4 6 8 10 1 '14 1 Dissolved oxygen (mg/L) November 0_ ,0 - s _J ,0 r Dissolved oxygen (mg/L) December 0_ 1 2. yy0yyy ' ^/ &+_ i C ,0 Dissolved oxygen (mg/L) Station BFB2 - - - - - - -Station BFF2 — — — —Station BFH2 Figure 5-24 Monthly DO profiles in Blewett Falls Lake during 2001. 5-66 Section 5 Results and Discussions In the middle and lower reservoir areas, the water column was uniformly mixed and free-circulating during January through April and again during September through December (Figures 5-19, 5-21, and 5-23). Temperature stratification usually occurred in the reservoir during May through August, although thermal stratification was weak and subject to turnover depending upon power plant operations and the amount of river inflow. During 1999, thermal stratification existed in May and June; de-stratification and water column turnover occurred in July and only a weak thermocline existed in August (Figure 5-21). Temperature stratification was weakto nonexistent in Blewett Falls Lake during 2001 (Figure 5-23). One exception was the temperature stratification and DO depletion that occurred in the reservoir during November 2001 (Figures 5-23 and 5-24). This stratification was related to the drawdown of Lake Tillery for dam tainter gate inspection and maintenance during September 2001 (Figure 5-4). Consequently, there was infrequent power generation from both Tillery and Blewett Falls Hydroelectric Plants with subsequent low inflow into Blewett Falls Lake and lower lake levels from September through November (Figures 5-4 to 5-6). These conditions, along with the eutrophic nature of Blewett Falls Lake, were likely responsible for the temperature stratification and DO depletion that occurred during November 2001. During 2004, temperature stratification occurred during May with temperature differences of 4.1° and 5.2°C from the surface to bottom waters at Stations BFF2 and BF132, respectively. Stratification continued from June through August although it was weaker during these months when compared to May (Figure 5-19). Dissolved oxygen depletion was more evidentthan temperature stratification in Blewett Falls Lake. Dissolved oxygen concentrations were less than 4 mg/L at the intake structure depth (6 to 10 m) beginning in May or June and remained below 4 mg/L through August or September of 1999, 2001, and 2004 (Figures 5-20, 5-22, and 5-24). The occurrence of DO depletion in September or other fall months (e. g., November 2001) was related to the frequency of precipitation events within the river basin and subsequent inflow and power plant generation levels. A strong clinograde curve was usually observed with DO concentrations declining rapidly from 2 to 6 m, depending upon the location. Low DO concentrations of 2 mg/L or less were usually only found at depths of 2 to 3 m from the reservoir bottom. Blewett Falls Lake also did not have a very large volume of anoxic water (DO < 2 mg/L) present during the temperature stratification period as observed at Lake Tillery. 5.3.4 Pee Dee River Reach below the Blewett Falls Hydroelectric Plant 5.3.4.1 Spatial and Temporal Trends in Reach 2 Water Chemistry during Power Plant Generation and No Power Generation Periods The water quality of the immediate downstream area of this river reach (below Station BF1B atU.S. Highway 74) resembled the water quality characteristics of Blewett Falls Lake due to the shallow depth of the power plant intake and the well-mixed water column during most of the year. With increasing distance from the power plant, water quality characteristics were more influenced by physiographic topography changes, watershed inflow, natural inputs of organic matter, and point and nonpoint discharge sources. Reach 2 transitioned from the Piedmont Fall Line zone into the Sandhills and Coastal Plain physiographic regions with changes in several physical features including channel gradient, substrate and soil properties, and land use patterns. 5-67 Section 5 Results and Discussions Table 5-20 Means, ranges (in parentheses), and spatial trends of selected water chemistry parameters from the surface waters in Reach 2 of the Pee Dee River below the Blevvett Falls Hydroelectric Plant during power generation flows, 2004. Parameter'^z BFOB BF1B atanon BF2B BOB BF4B Temperature (EC) 17.8 18.1 18.0 18.3 18.3 (6.8-28.7) (7.0-29.5) (6.8-30.2) (5.9-30.4) (7.2-30.5) Dissolved oxygen (mg/L) 9.0 8.3 9.5 9.1 8.2 (5.7-12.5) (4.4-13.1) (6.4-13.9) (6.7-12.9) (3.1-11.5) Solids (MgL) Total solids 94°` 93- 87` 102"° 112° (74-108) (67-119) (51-139) (84-132) (81-148) Total dissolved 71` 71be 79b 893 91a (56-103) (52-103) (64-110) (64-110) (73-108) 16ab 12b l lb 15ab 20a Total suspended (8-34) (6-20) (3-26) (6-25) (9.8-41) Turbidity (NTL17 8 8 5 19 24 2 (2 2 32) (2.1 3) (1.4 2) (1.5 -47) ( /1.9-52) Nutrients (Mg/L) Total nitrogen 0.65 0.62 0.54 0.52 0.56 (0.35-1.5) (0.35-1.8) (0.33-1.3) (0.37-0.92) (0.43-1.10) Ammonia-N 0.03 0.05 0.04 0.03 0.03 (< 0.02-0.08) (< 0.02-0.13) (< 0.02-0.09) (< 0.02-0.07) (< 0.02-0.10) Nitrate + nitrite-N 0.56 0.60 0.61 0.63 0.61 (0.08-1.0) (0.27-1.0) (0.16-1.0) (0.34-0.91) (0.24-0.96) Total phosphorus 0.068' 0.072' 0.067' 0.080b 0.095" (0.049-0.087) (0.047-0.099) (0.036-0.157) (0.054-0.173) (0.036-0.159) Total organic carbon (mg/L) 3 .2 b 3.3 b 3.4b 4. la 4.7 a (2.4-4.7) (2.6-4.7) (2.6-6.3) (3.0-8.0) (3.0-11) Chemical oxygen demand 7.3 6.6 6.6 9.5 12 (mg/L) (< 10-13) (< 10-13) (< 10-16) (< 10-21) (< 10-31) Biological oxygen demand < 2 < 2 < 2 < 2 < 2 (lug/L) (< 2-2.6) (< 2-2.2) Calcium 5.4 5.2 5.2 5.1 5.3 (1.7-6.5) (1.6-6.6) (2.2-7.0) (2.3-6.5) (2.1-7.0) Magnesium 2.3 2.4 2.3 2.3 2.5 (< 1.0-2.9) (< 1.0-3.0) (< 1.0-3.0) (< 1.0-3.1) (< 1.0-4.5) Sodium 6.8b 6.9b 7.3' 10a 12a (5.2-8.4) (4.9-8.8) (5.1-9.0) (7.0-17) (8.1-21) Chloride 9.8C 9.8` 12b° 14ab 17a (7.1-12) (7.2-12) (8.1-22) (10-21) (8.0-50) Sulfate 5.9° 6.5` 6.8° 8.4b 9.8a (< 2.0-7.3) (5.2-8.1) (5.5-8.9) (5.4-12) (6.3-15) Hardness (calculated)3 23 22 22 22 23 (4.2-27) (19-28) (5.5-30) (5.8-27) (5.3-36) 100' 99b 99b 118a 1253 Specific conductance ((DS/cm) (90-109) (90-115) (78-113) (99-151) (98-182) Total alkalinity' 22b 22b 21b 233' 24a (18-26) (17-25) (15-25) (19-29) (17-32) H p 7.5 7.4 7.6 7.4 7.3 (7.1-8.1) (6.7-7.9) (7.1-8.6) (6.9-8.0) (6.8-7.8) 5-68 Section 5 Results and Discussions Parameter's^Z Station BFOB BF1B BF2B BF3B BF4B Trace elements (Oga/L) Aluminum 449 436 356 479 1,026 (199-746) (144-792) (87-560) (216-864) (292-5,320) Copper 2.5" 2.4b 2.4' 2.8a' 3.2a (1.5-4.0) (1.5-3.4) (1.5-4.6) (1.5-4.4) (1.9-5.1) Mercury < 0.2 < 0.2 < 0.2 < 0.2 < 0.2 (< 0.2-0.2) 1 Sample size (n) equaled 12. Less than values (<) indicate the Lower Reporting Limit (LRL) for the parameter. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably reported. Statistical analyses were utilized only when mean concentrations were above the analytical lower reporting limits. Missing range values indicate that all measured values during, were less than the LRL for that parameter. 2 Fisher's protected least significant difference (LSD) test was applied only if the overall ANOVA F test for the treatment was significant. Means followed by different superscripts were significantly different (P # 0.05). Data were rounded to conform to significant digit requirements. Rounding may obscure mean differences. 3 Total alkalinity units are mg/L as CaCO3 and hardness is calculated as mg equivalents CaCO3/L. 5-69 Section 5 Results and Discussions Waters of Reach 2 were slightly acidic to slightly basic in pH, moderately soft, and with low buffering capacity during the survey period of 1999, 2001, and 2004 (Table 5-20). Water quality characteristics in the immediate tailwaters (Stations BFOB and BF1B) essentially mirrored the water quality in Blewett Falls Lake because of the short hydraulic retention time of the reservoir (Tables 5-14, 5-20, and 5-21). However, there were some significant changes in water quality with increasing distance from the power plant which suggested other factors, including point and nonpoint discharges, influenced water quality in Reach 2, particularly below Station BF213 located approximately 23 miles downstream. During power generation flows in 2004, there were significant increases in solids constituents, total phosphorus, total organic carbon, sodium, chloride, sulfate, specific conductance, total alkalinity, and copper from the power plant tailwaters to the Coastal Plain of South Carolina (Stations BF313 and BF413) (Table 5-20). No significant differences were found for total nitrogen, ammonia-nitrogen, nitrate + nitrite-nitrogen, calcium, magnesium, hardness, aluminum, or pH during power generation flows in 2004. Similar spatial differences were found for these same water quality parameters during the survey period of 1999, 2001, and 2004 (Table 5-21). A paired t-test comparison of power generation and no power generation flow periods at Stations BF 1 B and BF213 during 2004 indicated few significant differences among water quality parameters between the two flow periods (Table 5-22). At Station BF113, total solids, turbidity, and aluminum were significantly greater during the power generation period than during the no power generation period. At Station BF213, total suspended solids, ammonia-nitrogen, and aluminum were significantly greater during the power generation period. These results suggested the main effects of flow releases from the Blewett Falls Hydroelectric Plant were increased concentrations of total solids, turbidity, and aluminum in the immediate tailwaters. Solids, turbidity, and aluminum loading in the watershed were driven by nonpoint source sediment inputs into the river, especially upstream of the Blewett Falls Development during high precipitation and inflow events. Temporal analysis of the surface waters at Stations BF 113, BF213, BF313, and BF413 for the years 1999, 2001, and 2004 indicated significant differences in water quality parameters during the lowest flow year of 2001 when compared to the higher flow years of 1999 and 2004 (Table 5-23 and Figures 5-3 and 5-6). Total solids, total dissolved solids, ammonia-nitrogen, total phosphorus, total organic carbon, COD, all anions and cations, total alkalinity, and specific conductance were significantly greater during the lowest inflow year of 2001 when compared to 2004, a wetter year (Table 5-23). Conversely, total suspended solids, turbidity, nitrate + nitrite-nitrogen, pH, and aluminum were significantly greater during 2004. Mean values for most of these parameters for the year 1999 were usually intermediate in statistical ranking; either grouped with 2001 or 2004 depending upon the parameter. Total nitrogen was the only water chemistry parameter that did not significantly differ among the three years. Monthly trends of concentrations of nutrients, solids, and turbidity measured at Station BFB2 in Blewett Falls Lake (bottom waters) and at Stations BFOB, BF1B, BF213, BF313, and BF413 in Reach 2 during 2004 are presented in Appendix F. All of these data were collected under power generation flow conditions so data were comparable from station to station. This comparison examined the cumulative effects of nutrient and solids from Blewett Falls Lake into the downstream reach of the Pee Dee River. As mentioned previously, Stations BFOB and BF 1B essentially mirrored the water 5-70 Section 5 Results and Discussions Table 5-21 Comparison of temporal trends of annual means for selected water chemistry parameters from the surface waters at Station BFB2 in Blewett Falls Lake and surface waters at Stations BF1B, BF213, BF313, and BF413 in the Pee Dee River below the Blevvett Falls Hydroelectric Plant during 1999, 2001, and 2004. Station Parameter' BFB2 BF1B BRB BF3B BF4B Temperature (°C) NA2 18.6 18.8 19.0 18.8 Dissolved oxygen (mg/L) NA2 8.3' 9 8a 9 0ab 8.4 b Solids (mg/L) Total solids 96' 95b 9lb 116a 12 la Total dissolved 88b 83b 88b 104a 105a Total suspended 8.9°d 9.6b` 6.4d 12b 18a Turbidity (NTU) 14' 16b 13b 16b 22a Nutrients (mg/L) Total nitrogen 0.56 0.51 0.42 0.61 0.64 Ammonia-N 0.06 0.09 0.05 0.07 0.06 Nitrate + nitrite-N 0.40 0.49 0.48 0.47 0.45 Total phosphorus 0.078b 0.076' 0.074b 0.087b 0.1172 Total organic carbon (mg/L) 4.2b 4.Ob 4.0b 5.1a 5.7a Chemical oxygen demand 12 13 13 14 15 Ions (mg/L) Calcium 6.08 5.7ab 5.4' 5.4b 52' Chloride 12' 12b 13' 168 16a Magnesium 2.6 2.6 2.4 2.4 2.4 Sodium 12a 12a 12a 18' 18b Sulfate 10' 9.8b 9.7b 13a 12a Total alkalinity' 28ab 26 be 25` 30a 28ab Specific conductance ((DS/cm) 123b 12 lb 120b 153a 145a nH NAZ 7.1 ab 7.2a 7.1 ab 7.0' Trace elements (Og/L) Aluminum 261b 370' 287' 387b 626' Copper 2.9 3.0 2.3 3.2 3.4 1 Statistical analyses were utilized only when the majority of parameter concentrations were above the analytical lower reporting limits. Fisher's protected least significant difference (LSD) test was applied only if the overall ANOVA Ftest for the treatment effect was significant. Means followed by different superscripts were significantly different (P # 0.05). Data were rounded to conform to laboratory reporting limit requirements. Such rounding may obscure mean differences. Sample size= 12 for each year. The power generation flow data set in 2004 was used in this analysis. 2 Station BFB2 was not included in the statistical analysis of this parameter. 3 Total alkalinity units are mg/L as CaCO3. 5-71 Section 5 Results and Discussions Table 5-22 Means, ranges (in parentheses), and spa tial trends of selected water chemistry parameters from the surface waters at Sta tions BF113 and BF213 in Reach 2 of the Pee Dee River below the Blewett Falls Hydroelectric Plant during the no power generation and power generation flow periods, 2004. Station Parameter' 2 BF1B BF1B MB MB No Power Power No Power Power Generation Generation Generation Generation Temperature (EC) 17.5 18.1 18.5 18.0 (65-27.6) (7.0-29.5) (7.7-31.1) (6.8-30.2) Dissolved oxygen (mg/L) 7.9 8.3 9.7 9.5 (3.3-12.5) (4.4-13.1) (7.4-12.7) (6.4-13.9) Solids (mg/L) 82 Total solids 93 82 87 ( ) 66-104 ( ) 67-119 ( ) 58-107 ( ) 51-139 Total dissolved 6 71 73 9 (59-108) (52-103) (57-106) (64-110) Total suspended 8.4 12 5.56 l la (1.5-27) (6.2-20) (1.7-12) (3.2-26) Turbidity (NTLD 116 18a 10 19 (0.6-19) (2.1-33) (0.7-19) (1.4-52) Total nitrogen (0.27-1.2) (0.35-1.8) (0.30-1.0) (0.33-1.3) Ammonia-N 0.04 0.05 (<0.02- 0.016 0.04a (< 0.02-0.11) 0.13) (<0.02-0.05) (<0.02-0.09) Nitrate +nitrite-N 0.60 0.60 0.57 0.61 (0.31-1.0) (0.27-1.0) (0.06-0.98) (0.16-1.0) Total phosphorus 0.060 0.072 0 ( 0.058 0.067 (0.037-0.084) 99) 0 ( (0.028-0.090) (0.036-0.157) Total organic carbon 3.2 3.3 3.5 3.4 (mg/L) (2.4-4.3) (2.6-4.7) (2.5-5.0) (2.6-6.3) Chemical oxygen demand (mg/L) <10 (< 10-11) < 10 (< 10-13) <10 (< 10-16) <10 (< 10-16) Biological oxygen demand (mg/L) < 2 (< 2 2 2) < 2 < 2 Calcium 5.0 5.2 5.0 5.2 (3.2-6.5) (1.6-6.6) (3.1-65) (2.2-7.0) Magnesium 2.2 2.4 2.2 2.3 (< 1.0-3.1) (< 1.0-3.0) (< 1.0-2.8) (< 1.0-3.0) Sodium 6.6 6.9 7.1 7.3 (4.9-10) (4.9-8.8) (5.2-9.0) (5.1-9.0) Chloride 9.7 9.8 10 12 (7.2-12) (7.2-12) (7.7-13) (8.1-22) Sulfate 6.8 6.5 7.0 68 (5.0-8.0) (5.2-8.1) (5.1-11) (5.5-8.9) Hardness (calculated)3 22 22 1 22 (8.0-27) (3.9-28) (7.7 27) (5.5 -30) Specific conductance ((DS/cm) (89.911) (90-99 115) (889$05) (789913) Total alkalinity3 0 22 0 21 (11-25) (17-25) (12-24) (18-25) H p 7.4 7.4 7.7 7.6 (6.9-7.9) (6.7-7.9) (7.0-9.2) (7.1-8.6) 5-72 Section 5 Results and Discussions Station Parameter' 2 BF1B BF1B BFZB B12B No Power Power No Power Power Generation Generation Generation Generation Trace elements (Og/L) 272 436a 245 356a Aluminum (107-762) (144-792) (97-412) (87-560) Copper 2.3 2.4 2.1 2.4 (1.6-3.0) (1.5-3.4) (1.4-3.0) (1.5-4.6) Mercury < 0.2 < 0.2 <0.2 < 0.2 1 Sample size (n) equaled 12. Less than values (-) indicate the Lower Reporting Limit (LRL) for the parameter. The LRL is a statistically determined limit beyond which chemical concentrations cannot be reliably reported. Statistical analyses were utilized only when mean concentrations were above the analytical lower reporting limits. Missing range values indicate that all measured values during, were less than the LRL for that parameter. 2 A paired t-test was applied only to each station to compare the no power generation and power generation periods. Means within each station that have different superscripts were significantly different (P # 0.05). Data were rounded to conform to significant digit requirements. Rounding may obscure mean differences. 3 Total alkalinity units are mg/L as CaCO3 and hardness is calculated as mg equivalents CaCO3/L. 5-73 Section 5 Results and Discussions Table 5-23 Comparison of temporal trends of annual means for selected water chemistry parameters at Stations BF113, BF213, BF313, and BF413 of Reach 2 of the Pee Dee River below the Blewett Falls Hydroelectric Plant for 1999, 2001, and 2004. Year Parameter) 1999 2001 2004 Temperature (BC) 19.0 19.3 18.2 Dissolved oxygen (mg,I) 8.4 9.4 8.8 Total solids 101° 118a 991, Total dissolved 92b 110a 83` Total suspended 12a 8.2b 143 Turbidity (NTq 19a 12b 20a Ammonia-N 0.072 0.09a 0.04 Nitrate + nitrite-N 0.38b 0.43' 0.61a Total nitrogen 0.60 0.46 0.56 Total phosphorus 0.079b 0.108a 0.078b Total organic carbon (mg/L) 4.8a 5.4a 3.9b Chemical oxygen demand 15a 17a 8.7b Calcium 4.9b 6.23 5.2b Chloride 12b 18a 13b Magnesium 2.3b 2.63 2.4b Sodium 16b 20a 9.1 Sulfate 8.5b 17a 7.9b Total alkalinity (mg/L as CaCO3) 27b 33a 22° Specific conductance ((DS/cm) 128b 1662 110° nH 6.9b 7.Ob 7.4a Trace elements (1g E) Aluminum 409x" 268' 574a Copper 3.7a 2.5b 2.7b 1 Statistical analyses were utilized only when the majority of parameter concentrations were above the analytical lower reporting limits. Fisher's protected least significant difference (LSD) test was applied only if the overall ANOVA F test for the treatment effect was significant. Means followed by different superscripts were significantly different (P # 0.05). Data were rounded to conform to laboratory reporting limit requirements. Such rounding may obscure mean differences. 5-74 Section 5 Results and Discussions quality conditions in Blewett Falls Lake (Station BFB2) as seasonal trends of all of these parameters were similar among the three stations (Figures F-1 to F-9). With increasing distance downstream, monthly trends began to deviate and the magnitude of difference suggested that either the lag affect of flow travel time from upstream areas and/or point and nonpoint sources within the watershed were influencing these parameters. Total solids, total dissolved solids, total phosphorus, and total organic carbon also significantly increased at the lowermost downstream Stations BF313 and BF4B (Table 5-20 and Figures F-1, F-2, F-8, and F-9). 5.3.4.2 Relationships between Water Quality and Flow in Reach 2 of the Pee Dee River Water quality stations within Reach 2 of the Pee Dee River were divided into two segments for the Kendall's tau b correlation analysis of daily average flow vs. water quality parameters. Stations BF 1 B and BF213 were grouped into the Blewett Falls tailwaters and Stations BF313 and BF4B were grouped into the lower Pee Dee River (Table 5-19). This grouping was made due to increasing flow contributions with a larger watershed downstream of the hydroelectric plant. Additionally, the ANOVA indicated that other factors, including anthropogenic related point and nonpoint sources, were influencing the water quality at these lowermost stations. Daily average flow estimates were obtained from nearby USGS gaging stations (i.e., Rockingham, Bennettsville, and Pee Dee gages). In the case of Station BFB2, the USGS Rockingham gage data were used, and flow was adjusted based on the average flow (cfs) per square mile between the gage and the water quality station. The correlation analysis showed similar correlations between flow and water quality parameters in both segments of Reach 2 with afew exceptions (Table 5-19). In the Blewett Falls tailwaters, there were significant negative correlations between flow and water temperature, specific conductance, ammonia-nitrogen, total alkalinity, magnesium, sodium, chloride, and sulfate. The correlations indicated the greater the flow, the less the concentration or measurement of the parameter or vice- versa. Similar significant negative correlations existed for flow and these water quality parameters in the lower Pee Dee River (Table 5-19) except that correlations for total solids, total dissolved solids, COD, total phosphorus, and total organic carbon were also significant at this segment while the correlation with magnesium was not significant. During lower flow conditions, especially conditions associated with drought, there were increases in most anions and cations in the both sections of Reach 2 and, correspondingly, increases in total dissolved solids, total alkalinity, and specific conductance. Nutrient constituents total phosphorus, total organic carbon, and ammonia- nitrogen (Blewett Falls tailwaters section only) can also be expected to increase under these low flow conditions. Under higher flow conditions, these parameters can be expected to decrease. Weak to moderately significant positive correlations were found between flow and DO, total suspended solids, turbidity, nitrate +nitrite-nitrogen, and aluminum in both Reach 2 sections except that the DO correlation was not significant in the lower Pee Dee River (Table 5-19). Therefore, concentrations of these parameters can be expected to increase with increased flows in the river and decrease with lower flows. 5.3.4.3 Spatial and Temporal Trends in Temperature, DO, PH, Specific Conductance, and Turbidity in Reach 2 during Power Generation and No Power Generation Periods Water temperatures showed a seasonal progression in Reach 2 with lowest temperatures from 6' to 9'C during January or February and summertime maxima from 29' to 32'C during July or August 5-75 Section 5 Results and Discussions during 1999, 2001, and 2004 (Figures 5-25 to 5-27). Maximum water temperatures in Reach 2 did not exceed the North Carolina water quality standard (32.0°C). There were no significant spatial or temporal differences in mean water temperatures during 2004 or for 1999, 2001, and 2004 combined (Tables 5-20, 5-21, and 5-23). Furthermore, there were no significant differences in mean water temperatures between the power generation and no power generation periods during 2004 (Table 5-22). The DO regime in Reach 2 exhibited a seasonal pattern of greater DO concentrations in the cooler winter and fall months and DO minima during the warmer summer and early autumn months (Figures 5-25 to 5-27). There were instances where DO concentrations were below 4.0 mg/L or 5.0 mg/L during 1999, 2001, and 2004 at Station BF 1B and Station BF413 (Appendix B, Tables B-4 to B-6). No DO concentrations were below 5.0 mg/L at Stations BF213 and BF313 during this three- year period. At Station BF113, DO concentrations below 5.0 mg/L were noted in August of 1999 (4.4 mg/L) and August 2001 (4.8 mg/L). Additionally, DO concentrations below 5.0 mg/L at Station BF1B were observed during the power generation and no power generation periods during June through August of 2004. In July, the DO concentration at Station BF1B was below the North Carolina instantaneous water quality standard (i.e., 3.3 mg/L). The DO concentration at Station BF413 was 3.1 mg/L during September 2004 (Figure 5-27). The DO concentration at Station B17313, located upstream of Station BF413, was 7.0 mg/L on this same date. This low DO event may have been related to anthropogenic effects or tributary inflow of low DO swamp water. In 2004, there were no significant differences in mean DO concentrations among stations in Reach 2 during the power generation and no power generation periods (Tables 5-20 and 5-22). Mean DO concentrations did significantly differ among stations when data from all three survey years were combined (Table 5-21). The mean DO concentration was significantly greater at Station BF213 than at Stations BF 1B and BF413 (Table 5-21). There were no significant temporal differences in mean DO concentrations among years (Table 5-23). Peak values of specific conductance were observed in the summer months, and there was more variability in values at Stations BF313 and BF413 during the lower flow years of 1999 and 2001 (Figures 5-25 to 5-27). Mean specific conductance values were significantly greater at Stations BF313 and BF413 than at the upstream Stations BFOB, BF 113, and BF213 during 2004 and for the 1999, 2001, and 2004 period which suggested point source discharges were influencing water quality at these downstream stations (Tables 5-20 and 5-21). Temporal differences were also found among years with significantly greater mean specific conductance values during the lower flow years of 1999 and 2001 when compared to the higher flow year of 2004 (Table 5-23). There were no significant differences in mean specific conductance values between the power generation and no power generation periods at Stations BF1B and BF213 during 2004 (Table 5-22). 5-76 Section 5 Results and Discussions 40 30 O 20 0 10 0 14 12 10 J 8 ° E 6 4 2 0 Temperature Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Dissolved oxygen Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Specific conductance 400 E 300 N 200 = 100 0 9 8 x 7 6 5 4 60 50 40 30 Z 20 10 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month pH Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month iu Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Station BF1 B - Station BF213 Station BF313 Station BF4B Figure 5-25 Monthly trends in water temperature, DO, specific conductance, pH, and turbidity at Stations BF1B, BF2B, BF3B, and BF4B in Reach 2 of the Pee Dee River below the Blewett Falls Hydroelectric Plant during 1999. 5-77 Section 5 Results and Discussions 40 30 V 20 10 0 14 12 10 J 8 ° E 6 4 2 400 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month VIJJVIVCY Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Specific conductance E 300 N 200 = 100 0 9 8 x 7 6 5 A Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month pH Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 60 50 40 30 Z 20 10 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month -Station BF1B -A-Station BF213 -Station BF313 - Station BF4B Figure 5-26 Monthly trends in water temperature, DO, specific conductance, pH, and turbidity at Stations BF1B, BF2B, BF3B, and BF4B in Reach 2 of the Pee Dee River below the Blewett Falls Hydroelectric Plant during 2001. 5-78 Section 5 Results and Discussions 40 30 0 20 10 0 14 12 10 J 8 O 6 4 2 0 Temperature Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Dissolved oxygen Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Specific conductance 400 E 300 N 200 ? 100 0 s a x 7 a 6 5 4 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month pH Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 60 50 40 30 Z 20 10 0 Turbidity X Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Station BF1 B -A? Station BF213 Station BF313 - Station BF4B Figure 5-27 Monthly trends in water temperature, DO, specific conductance, pH, and turbidity at Stations BF1B, BF2B, BF3B, and BF4B in Reach 2 of the Pee Dee River below the Blewett Falls Hydroelectric Plant during 2004. (Note: Power generation data were plotted for all stations.) 5-79 Section 5 Results and Discussions The pH values were fairly uniform and exhibited no seasonal trends during 1999 and 2004 (Figures 5-25 and 5-27); however, there was more variability in pH values during the lowest flow year of 2001 (Figure 5-26). All monthly pH values collected in North Carolina waters during 1999, 2001, and 2004 met the water quality standards for pH (Appendix B, Tables B-4 to B-6; NCDWQ 2004a). There was only one instance of a monthly pH value (9.2 units) not meeting South Carolina water quality standards and that occurred at Station BF2B during the no generation period in July 2004 (Appendix B, Table B-6). There were no significant differences in mean pH values among stations during the power generation and no power generation periods during 2004 (Tables 5-20 and 5-22). There were significant differences in mean pH values among stations and among years for the 1999, 2001, and 2004 period (Tables 5-21 and 5-23). The mean pH value at Station BF4B was significantly lower compared to the other stations for 1999, 2001, and 2004, and the annual mean pH value was significantly greater during the higher flow year of 2004. Turbidity values were highly variable within each year and were mainly influenced by large scale precipitation events and inflow within the river basin (Figures 5-25 to 5-27). No turbidity values at Station BF1B were above the North Carolina water quality standard during the three year period (Appendix B, Tables B-4 to B-6). There were only two occurrences of turbidity exceeding 50 NTU in the lower reach Pee Dee River during 2004 (Figure 5-27 and Appendix B, Table B-6). There were no significant differences in mean turbidity values among stations during the power generation period in 2004 (Table 5-20). However, mean turbidity was significantly greater during the power generation period than the no power generation period at Station BF1B during 2004 (Table 5-22). Significant spatial and temporal differences occurred among mean turbidity values for years 1999, 2001, and 2004 (Tables 5-21 and 5-23). Mean turbidity values were greatest at Station BF4B compared to the other stations (Table 5-21). The mean turbidity values for 1999 and 2004 were also greater than the mean value for 2001 (Table 5-23). 5.3.5 Longitudinal Trends in Water Quality Parameters for Project Waters During 2004 Longitudinal trends in water quality parameters from the Lake Tillery headwaters (Station TYK2) to the Coastal Plain of South Carolina (Station BF4B), including the Rocky River, were examined and statistically tested to determine how water quality parameters changed as water passed through the Project reservoirs and with additional inflow from tributaries within the watershed (Figures 5-28 to 5-30). This comparison was made for the monthly water quality data collected under power generation flow conditions during 2004. All reservoir and tailwaters stations associated with the Project were sampled during this year. Bottom water samples were used for Stations TYB2 and BFB2 for Lake Tillery and Blewett Falls Lake, respectively. It should be noted that this analysis only reflects longitudinal trends that existed under the flow conditions and climate patterns that existed during 2004. These trends may or may not be similar during years with different flow and climate conditions. 5-80 Section 5 Results and Discussions 60 Total Suspended Solids a b be P < 0.0001 a abc abc cd abc cd c cd cd BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 TY 12B RR TY1B TYB2 TY K2 Station Total Dissnlved Snlids 50 40 m 30 E 20 10 0 EE aoo a P < 0.0001 250 200 150 100 C C D'. T 50 0 BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 BF12B RR TY1B TYB2 TY K2 Station Total Solids E 300 a < 0-0001 250 200 b c 50 b be c be 100 C 50 0 100 e0 60 t Z ao 20 0 600 500 E 400 Y 300 N ? zoo 100 0 BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 TY 12B RR TY1B TYB2 TY K2 Station Turbiditv a b P < 0.0001 be be c be bcd cd be cd d c BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 TY 12B RR TY1B TYB2 TY K2 Station Snecific Conductance a P < 0.0001 b be cd cd cd bcd bcd bcd d c BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 TY 12B RR TY1B TYB2 TY K2 Station Figure 5-28 Spatial trends (means and ranges) in solids constituents, turbidity, and specific conductance in Lake Tillery, Blewett Falls Lake, and Reaches 1 and 2 of the Pee Dee River under power generation flow conditions during 2004. (Note: Statistical results are given for each water quality parameter and different letter superscripts indicate statistically different mean values.) 5-81 Section 5 Results and Discussions 1.00 Ammonia-N 0.80 0.60 m E 0.40 0.20 0 00 P = 0.05 a b b b b b ab b b b ab ab BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 TY 12B RR TY1B TYB2 TY K2 Station 12 0 Nitrate+N itrite-N 10.0 8.0 m 6.0 E 4.0 2.0 00 a P < 0.0001 b b b b b b b b b b b BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 BF12B RR TY1B TYB2 TY K2 Station 3.5 3.0 2.5 2.0 m E 1.5 1.0 0.5 0.0 BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 TY 12B RR TY1B TYB2 TY K2 Station 1.200 Total Phosphorus 1.000 0.800 m 0.600 E 0.400 0.200 0 000 P < 0.0001 b b b b b b b b b b b f + ¦ ¦ i BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 TY 12B RR TY1B TYB2 TY K2 Station 12.0 10.0 8.0 m 6.0 E 4.0 2.0 0.0 P < 0.0001 BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 TY 12B RR TY1B TYB2 TY K2 Station Figure 5-29 Spatial trends (means and ranges) in nutrient constituents in Lake Tillery, Blewett Falls Lake, and Reaches 1 and 2 of the Pee Dee River under power generation flow conditions during 2004. (Note: Statistical results are given for each water quality parameter and different letter superscripts indicate statistically different mean values.) 5-82 Section 5 Results and Discussions 30.0 Calcium 25.0 20.0 m 15.0- E 10.0 5.0 00 a < 0 -0001 b b b b b b b BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 TY 12B RR TY1B TYB2 TY K2 Station 10.0 8.0 6.0 m E 4.0 2.0 0.0 BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 BF12B RR TY1B TYB2 TV K2 Station 50 Sodium 40 30 m E 20 10 0 a P < 0.0001 b b c c c c c c c c c f • BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 TV 12B RR TY1B TYB2 TY K2 Station 80 Chloride 60 J m 40 E 20 0 a P < 0.0001 a c c c c c c c c c c IP IP a M • N BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 TY 12B RR TY1B TYB2 TY K2 Station 30 Sulfate 25 E 20 Y 15 N ? 10 5 0 a P < 0.0001 b be cd cd d cd d cd BF4B BF3B BF2B BF1B BFOB BFB2 BFH2 TY 12B RR TY1B TYB2 TY K2 Station Figure 5-30 Spatial trends (means and ranges) in anions and cations in Lake Tillery, Blewett Falls Lake, and Reaches 1 and 2 of the Pee Dee River under power generation flow conditions during 2004. (Note: Statistical results are given for each water quality parameter and different letter superscripts indicate statistically different mean values.) 5-83 Section 5 Results and Discussions There were significant spatial differences in solids and nutrients constituents, anions and cations, turbidity, and specific conductance (Figures 5-28 to 5-30). The only exceptions were total nitrogen concentrations, which did not significantly differ from the upstream to downstream monitoring stations (Figure 5-29). Solids constituents and turbidity did not exhibit a defined spatial pattern as there was considerable overlapping of mean values for all parameters based on the statistical rankings. In particular, total suspended solids and turbidity were highly variable from the upstream to downstream stations. A few spatial patterns were observed for total solids and total dissolved solids. Mean concentrations of these two solids constituents were significantly greater in the Rocky River than other stations. There also appeared to be some additional increases in these two solids constituents at Station BF413 located in the lower segment of Reach 2 below the Blewett Falls Hydroelectric Plant (Figure 5-28). Ammonia-nitrogen mean concentrations were significantly greater at Station TYK2 in the headwaters of Lake Tillery and generally decreased with increasing distance downstream (Figure 5-29). Mean ammonia-nitrogen concentrations at Station TY132 in Lake Tillery, Station TY1B in Reach 1, and Station BFB2 in Blewett Falls Lake were intermediate to the mean concentrations at Station TYK2 and other stations. Nitrate + nitrite-nitrogen and total phosphorus concentrations were significantly greater in the Rocky River compared to mean concentrations in Project reservoirs and the mainstem river. Mean concentrations at these latter stations did not significantly differ from each other. There were additional inputs of total organic carbon from the Rocky River into Reach 1 and also downstream of the Blewett Falls Hydroelectric Plant in Reach 2 at Stations BF313 and BF413 (Figure 5-29). Mean total organic concentrations were significantly lower in Lake Tillery, Blewett Falls Lake, and the tailwaters stations located immediately downstream (Stations BFOB and BF113). The spatial pattern of total organic mean concentrations also suggested dilution of concentrations with additional tributary inflow in Reach 1 and Blewett Falls Lake. Mean concentrations of anions and cations and specific conductance were significantly greater inthe Rocky River (Station RR) compared to the reservoir and mainstem river stations (Figure 5-30). There were no significant spatial differences in mean concentrations of calcium and magnesium from Lake Tillery tailwaters to river stations below Blewett Falls Lake, which indicated no cumulative changes in concentrations of these two parameters through both hydroelectric developments. Mean sodium concentrations were significantly greater at Stations BF313 and BF413 compared to upstream stations indicating additional inputs in this downstream section of the river. Mean chloride concentrations were also significantly greater at Station BF413 and similar to mean concentrations at Station BF313 and the Rocky River. Mean sulfate concentrations significantly increased at Station TY1213, which indicated the influence of inputs from the Rocky River. Sulfate mean concentrations were significantly lower in Blewett Falls Lake and the tailwaters stations located downstream in the Fall Line zone (Stations BFOB, BF 113, and BF213). Additional tributary input may have diluted sulfate concentrations in these downstream areas. Mean sulfate concentrations then increased at Stations BF313 and BF413 and indicated additional loading in this section of the river. Correspondingly, the spatial pattern of specific conductance mean values was very similar to the observations for sodium, chloride, and sulfate (Figure 5-28). 5-84 Section 5 Results and Discussions 5.3.6 State Water Quality Standards at Project Reservoirs and Tailwaters 5.3.6.1 North Carolina Waters North Carolina has an established set of water quality standards applicable to waters within the state depending upon the best usage classification. These standards are outlined in the NCDWQ "Redbook" for surface waters and wetlands under the N.C. Administrative Code 15A NCAC 02B.0200) (NCDWQ 2004b). The basic set of standards, applies to Class C waters, which "shall be suitable for aquatic life propagation and maintenance of biological integrity (including fishing and fish), wildlife, secondary recreation, agriculture and any other usage except for primary recreation or as a source of water supply for drinking, culinary or food processing purposes". Blewett Falls Lake and the Pee Dee River reach from the Tillery Dam to Blewett Falls Lake have been classified by the NCDWQ as drinking water supplies (Classes WS-IV and WS-V, B) and suitable for primary (Class B) and secondary recreation uses (Class C) including fishing, wildlife, fish, aquatic life propagation and survival, and agriculture. Additional primary recreation and drinking water numeric and narrative standards also apply to Lake Tillery, the Pee Dee River from Tillery Dam to Blewett Falls Lake, and Blewett Falls Lake (NCDWQ 2004b, 2005). The Pee Dee River below Blewett Falls Lake to the North Carolina-South Carolina state line has a Class C designation. The water quality parameters that were monitored during this survey and the number and percentage of values that exceeded the applicable North Carolina water quality standard are given in Tables 5-24 and 5-25. Summer temperature maxima were generally below 32°C in the Project reservoirs and tailwaters (Table 5-25). There was only one instance of atemperature value exceeding 32°C and that occurred at Lake Tillery (Station TYH2) on ahot summer day in August 2000 (Appendix A, Table A-1). The Tillery and Blewett Falls Hydroelectric Plants do not produce or release heated discharges into the reservoir or tailwaters so this isolated occurrence was related to a climatic event. Monthly DO concentrations in Project reservoir surface waters were usually greater than the North Carolina instantaneous (4.0 mg/L) and daily average water (5.0 mg/L) quality standards during the monitoring period. The only exception occurred at Station TYK2 in Lake Tillery during July 2004 where DO values ranged from 4.7 to 4.8 mg/L throughout the water column. These lower DO concentrations did not result from operation of the Tillery Hydroelectric Plant as this shallow, well- mixed station was the farthest upstream station and not prone to typical reservoir stratification and DO depletion like the deeper reservoir areas. The NCDWQ (2002) observed a DO value of 4.8 mg/L downstream of this station (near Station TYH2) during August 1999. All other DO values measured by the NCDWQ were above 5.0 mg/L during summer surveys of Lake Tillery during 1994 and 1999. The Yadkin-Pee Dee River Basin Association (YPDRBA) has monitored Lake Tillery near Station TYF2 from 1998 to 2001 (NCDWQ 2002). No DO values measured by the YPDRBA were below the North Carolina water quality standards at this monitoring site for the 1998 to 2001 period. 5-85 Section 5 Results and Discussions Table 5-24 Water quality parameters measured at Project waters that have applicable North Carolina or South Carolina water quality standards. North Carolina South Carolina Water Quality Standard' Water Quality Standard' Parameter Class WS-IV Class C and WS-V Freshwaters Aquatic Life Drinking Waters Temperature < 32°C and < 2.8°C above < 32.2°C and < 2.8°C above natural temperature natural temperature Dissolved oxygen > 5.0 mg/L daily average and > 5.0 mg/L daily average >4.0 mg/L instantaneous with low of 4.0 mg/L pH Between 6.0 to 9.0 units Between 6.0 and 8.5 units Turbidity <_ 25 NTU for reservoirs and _< 50 NTU <50 NTU for streams Copper 7 pg/L Action Level 3.8 µg/L CMC 2.9 pg/L CCC Chloride 230 mg/L Action Level Mercury < 0.012 µg L 1.6 pg/L CMC 0.91 pg/L CCC Chlorophyll a < 40 pg/L Total dissolved solids < 500 mg/L Total hardness < 100 m2/L Sulfates < 250 mg/L i More detailed numeric and narrative criteria are provided in NCDWQ (2004b) and SCDHEC (2004a). 1 Class B water quality standards apply to primary recreation, including frequent or organized swimming (NCDWQ 2004b). Water quality standards applicable to Class C waters also apply to Class B waters. Water quality standards applicable to Class B waters include: "(a) Sewage, industrial wastes, or other wastes: none which are not effectively treated to the satisfaction of the Commission , in determining the degree of treatment required for such waste discharged into waters to be used for bathing, the Commission shall consider the quality and quantity of the sewage and wastes involved and the proximity of such discharges to waters in this class, discharges in the immediate vicinity of bathing areas may not be allowed if the Director determines that the waste can not be reliably treated to ensure the protection of primary recreation, (b) Organisms of coliform group: fecal coliforms not to exceed geometric mean of 200/100 ml (MF count) based on at least five consecutive samples examined during the 30-day period and not to exceed 400/100 ml in more than 20 percent of the samples examined during such period." 5-86 Section 5 Results and Discussions Table 5-25 Sample size (n) and the total number and percent of exceedances (in parenthesis) of water quality parameters measured during this study for the applicable North Carolina water quality standards at the Tillery and Blewett Falls Hydroelectric Plants, 1999-2004. Exceedances from North Carolina Water Quality Standards' Pee Dee River Pee Dee River Locatiion? Lake Tillery below Tillery- Blewett Falls below Blewett Reach 1 Lake Falls-Reach 2 TYB2, TYD2, BFB2, BFF2, Station TYF2, TYH2, TY1B TY12B and BFH2 BF1B and TYK2 Parameter Temperature Surface n = 180 n = 47 n-48 n = 108 n = 36 (<1 m depth) 1(0.6%) 0 0 0 0 Uissolved oxygen Surface (<Imdepth) n=180 n=47 n=48 n=108 n=36 <4.0 mg/L 0 3(6.4%) 0 0 0 <5.0 mg/L 1(0.6%) 6(12.8%) 1(2.1%) 0 5(13.9%) pH Surface (<1 m depth) n = 180 <6 0units 0 n=47 n=48 n = 108 n=36 . > 9.0 units 4(2.2%) 5(4.6%) 0 0 0 Bottom n = 24 < 6.0 units n = 95 0 > 9 0 units 0 NW NW NW . 0 0 Turbidity Surface n-180 n- 48 n- 108 n- 36 (Q m depth) 6(3.3%) n = 47 3(6.2%) 11(10.2%) 0 0 Bottom n = 95 N/A NW n = 24 NW 9(9.5%) 19(79.2%)4 Copper Surface n = 108 n = 108 n = 36 (Q m depth) 0 n 47 % 9(8.3%) 3 (8.3%) 0 4 (8.3 0) Bottom n = 96 N/A' N/A' n = 24 NW 1 (1.0%) 2 (8.3%)' Chloride Surface n = 108 n = 47 n- 108 (<1 m depth) 0 0 n- 48 0 n- 36 0 0 Bottom n 096 NW NW n 24 NW 0 5-87 Section 5 Results and Discussions Exceedances from North Carolina Water Quality Standards' Pee Dee River Pee Dee River Blewett Falls Location Lake Tillery below Tillery- below Blewett Lake Reach 1 Falls-Reach 2 TYB2, TYD2, BFB2, BFF2, Station TYF2, TYH2, TY1B TY12B BF1B and BFH2 and TYK2 Parameter Surface n = 108 n 47 n 48 n = 108 (<1 m depth) 0 0 0 0 n=36 0 Bottom n = 96 N/A' N/A' n = 24 13( 13.5%) 0 Total dissolved solids Surface n = 108 n = 47 n = 48 n = 108 n = 36 (<1 m depth) 0 0 0 0 0 Bottom n 96 N/A' N/A' n 024 0 Total hardness Surface n = 108 n 47 n = 108 n = 36 (<1 m depth) 0 0 1(2.1%) 0 0 Bottom n -96 N/A' N/A' n 24 N/A' 0 Sulfate Surface n = 108 n 47 n 48 n- 108 n- 36 (<1 m depth) 0 0 0 0 0 Bottom n 96 N/A' N/A' n = 24 N/A' Chlorophyll a Photic zone n = 108 N/A' N/A' n 0 108 NSA' 0 1 (0.9%) Refer to Table 5-24 for the North Carolina water quality standard numeric value. 2 The years 2000, 2002, and 2004 were evaluated for Lake Tillery ; 2000, 2001, 2002, and 2004 were evaluated for Stations TY 1 B and TY 12B in Reach 1 of the Pee Dee River, 1999, 2001, and 2004 were evaluated for Blewett Falls Lake and Reach 2 of the Pee Dee River. 3 Not applicable (N/A). 4 Turbidity values were only measured in bottom waters at Stations BFB2 and BFF2 of Blewett Falls Lake during 2004. 5 Copper value for Station BFB2, bottom waters, December 2004, not included in this analysis due to suspected sample contamination (Appendix D, Table D-3). 6 The laboratory lower reporting limit for mercury is 0.20 pg/L therefore no values that were less than the reporting limit were included in this analysis. Only values that were greater than 0.20 pg/L were considered exceedances from the North Carolina water quality standard. 5-88 Section 5 Results and Discussions Detailed assessments of DO dynamics in the tailwater reaches of the Pee Dee River below the Tillery and Blewett Falls Hydroelectric Plants (i.e., Reaches 1 and 2) can be found in Progress Energy 2005a and 2005b. These assessments, conducted in 2004, also evaluated DO concentrations relative to the North Carolina instantaneous and daily average water quality standards. The following discussion will focus on results from the monthly survey data which may not be similar to results from the intensive DO studies conducted in 2004. Monthly DO concentrations below the North Carolina water quality standards were more frequently observed in the Tillery and Blewett Falls tailwaters compared to reservoir waters (Table 5-25). At Station TY113, located in the immediate tailwaters below the Tillery Plant, 6.4 percent of the monthly DO values were below 4.0 mg/L and 12.8 percent of the monthly DO values were below 5.0 mg/L during 2000, 2001, 2002, and 2004. Only one occurrence was noted below 5.0 mg/L at Station TY1213, located downstream of the Rocky River confluence. Dissolved oxygen values less than 5.0 mg/L were also noted in July 2004 in Reach 1 during the no power generation period at Stations TY1B and TY12B (Appendix A, Table A-6). Below Blewett Falls Hydroelectric Plant, 13.9 percent of the DO values were less than 5.0 mg/L while no DO values were less than 4.0 mg/L for the 1999, 2001, and 2004 period (Table 5-25 and Appendix B, Tables B-4 to B-6). During 2004, DO values below both North Carolina water quality standards were also measured at Station BE 1B during the no power generation period in July (3.3.mg/L) and August (4.5 mg/L) (i.e., 17 percent or two of the 12 monthly DO values). Long-term monitoring by the NCDWQ (2002) from 1996 to 2001 showed DO concentrations below the daily average water quality standard of 5.0 mg/L for at least 10 percent of the measurements during the six year period at the following locations: (1) Pee Dee River at N.C. Highway 731 below the Tillery Hydroelectric Plant (just downstream of Station TY113); (2) Brown Creek, a major tributary associated with the Pee Dee National Wildlife Refuge; (3) Pee Dee River atN.C. Highway 109 (corresponds to Station TY12B); (4) Pee Dee River atU.S. Highway 74 below the BlewettFalls Hydroelectric Plant (corresponds to Station BF1B), and(5)Marks Creek, atributary downstream of the Blewett Falls Plant. The NCDWQ (2002) indicated that low DO levels in the Pee Dee River from Tillery (Norwood) Dam to Turkey Top Creek seem to be related to reservoir hypolimnetic releases from the Tillery Hydroelectric Plant. Low DO concentrations have also been measured in Brown Creek, Clarks Creek, and the Little River within this reach during past years by the NCDWQ and YPDRBA. Inflow of low DO water from tributaries may also contribute, to some extent, to the seasonal low DO conditions in the Pee Dee River. The YPDRBA performed long-term monitoring of water quality at 71 sites within the river basin from 1998 to 2001 (NCDWQ 2002). The YPDRBA found 4.9 and 16.4 percent of DO measurements were below the North Carolina instantaneous and daily average DO standards, respectively, at its monitoring site located at U.S. Highway 74 below the Blewett Falls Plant. This YPDRBA sampling site corresponds to Station BF1B. There were afew instances of PH values exceeding the upper limit (9.0 units) of the North Carolina water quality standards in the surface waters of Lake Tillery and Blewett Falls Lake (Tables 5-24 and 5-25). The percentage of exceedances, based on total sample size, ranged from 2.2 percent at Lake Tillery for the 2000, 2002, and 2004 period to 4.6 percent at Blewett Falls Lake for the 1999, 2001, and 2004 period. These pH excursions were related to algal blooms during the spring or summer months and not as a result of Project operations. There were no instances of pH values 5-89 Section 5 Results and Discussions exceeding the North Carolina water quality standards in reservoir bottom waters or in the tailwaters reaches below each power plant (Table 5-25). The NCDWQ (2002) found a small percentage of samples (5.5 to 5.7 percent) that had pH values that were below 6.0 units at the N. C. Highway 109 (Reach 1) and U. S. Highway 74 (Reach 2) sites during the 1996 to 2000 monitoring period. No pH values exceeded the water quality standards at the N.C. Highway 731 monitoring site (Reach 1). These low pH values may have been related to inflow of lower pH water from tannic-stained tributaries within each reach. No pH values measured by the YPDRBA at the Lake Tillery or U.S. Highway 74 monitoring sites from 1998 to 2001 exceeded the state water quality standard. All chlorophyll a values were below the North Carolina water quality standard of 40 gg/L at Lake Tillery for the 2000, 2002, and 2004 period (Table 5-25). At Blewett Falls Lake, only one chlorophyll a sample exceeded the water quality standard. (0.9 percent of total number of collected samples). No chlorophyll a samples collected by the NCDWQ or YPDRBA from the Project reservoirs exceeded the water quality standard (NCDWQ 2002). Turbidity values above the North Carolina water quality standards were measured in surface and bottom waters of Lake Tillery and Blewett Falls Lake and in surface waters at Station TY12B, located downstream of the Rocky River (Table 5-25). Generally, the percentage of samples that exceeded either the reservoir (25 NTU) or stream (50 NTU) standards was greater in reservoir bottom waters and in Blewett Falls Lake. A large percentage of bottom water samples (79 percent) collected from Blewett Falls Lake during 2004 exceeded the reservoir water quality standard. However, high turbidities in reservoir waters were not necessarily reflective of high turbidity conditions in the immediate tailwaters downstream of each hydroelectric development. No turbidity values were above the stream water quality standard at Stations TY1B or BF1B below the Tillery and Blewett Falls Hydroelectric Plants, respectively, during the survey period (Table 5-25). Turbidity values greater than 50 NTU were measured in a small percentage of samples (1.8 to 2.6 percent) collected by the NCDWQ and YPDRBA from the N.C. Highway 731 and U. S. Highway 74 sites below the Tillery and Blewett Falls plants, respectively. Approximately 8 percent of samples measured by the NCDWQ at the N.C. Highway 109 site (Station TY12B) exceeded the 50 NTU level (NCDWQ 2002). Turbidity values exceeding the stream water quality standard were also measured by the NCDWQ and YPDRBA in several tributaries of Reach 1 (Rocky River, Clarks Creek, Brown Creek, and Little River) from 1996 to 2001. Copper concentrations occasionally exceeded the North Carolina Action Level of 7 gg/L with the greatest frequency of exceedances occurring downstream of the Rocky River at Station TY 12B in Reach 1, in Blewett Falls Lake, and at Station BF 1B in the Blewett Falls tailwaters (Table 5-25). The spatial pattern of copper value exceedances suggested that the Rocky River or some other tributary was a source of copper input into the intervening watershed of Reach 1 below the Tillery Hydroelectric Plant. Copper concentrations greater than 7 gg/L were measured by the NCDWQ in the Rocky River, Brown Creek, and Little River during 1996 and 2001 with the greatest percentage of exceedances (28 percent of 50 samples) occurring in the Rocky River site near Norwood, NC (NCDWQ 2002). The NCDWQ found less than 10 percent exceedance of copper values from the Action Level at the following stations: (1) Pee Dee River at N.C. Highway 731 (Reach 1); (2) Pee River at N.C. Highway 109 (Reach 1); and (3) Pee Dee River at U. S. Highway 74 (Reach 2). Mercury concentrations above the North Carolina water quality standard occurred in bottom waters of Lake Tillery during the 2000, 2002, and 2004 period (Table 5-25). Mercury concentration were 5-90 Section 5 Results and Discussions less than the laboratory report limit of 0.2 gg/L in Lake Tillery surface waters, at Stations TY 1 B and TY12B in Reach 1, in Blewett Falls Lake, and at Station BF113 in Reach 2. Total dissolved solids, chloride, sulfate, and total hardness were below the North Carolina water quality standards in Project reservoirs and tailwaters with one exception during the survey period (Table 5-25). One total hardness value (128 mg/L) exceeded the North Carolina water quality standard of 100 mg/L at Station TY12B during August 2001. Fecal coliform was not evaluated in the water quality surveys of Project reservoirs and tailwaters. However, data collected by the NCDWQ and YPDRBA from 1996 to 2001 were reviewed for relevance to Project waters (NCDWQ 2002). The North Carolina water quality standard for fecal coliform is 200/100 ml for all freshwater bodies. Fecal coliform counts were less than the state water quality standard for the majority of samples collected from waters associated with the Project. 5-91 Section 6 - Summary A monthly water quality survey program was conducted at the Tillery and Blewett Falls developments during 2004 to characterize the existing water quality conditions in the Project reservoirs and downstream tailwaters, including the effects of the Rocky River tributary inflow. Historical data collected from Project associated waters during the 1999 to 2002 period were also evaluated to examine temporal and spatial trends in water quality. The Water Resources Work Group had identified a need for additional water quality studies at Project reservoirs and tailwaters during study plan scoping meetings held in 2003. Specific objectives of this study were to: (1) address meeting state water quality standards and supporting designated uses in the reservoirs and tailwaters; (2) evaluate the Project operation effects on water quality in both reservoirs and tailwaters; (3) assess cumulative effects of nutrient and sediment loading on reservoirs and tailwaters; and (4) determine water quality effects of Rocky River inflow. The water quality data collected during the majority of the survey years (i. e., 1999 to 2002) occurred under low flow, drought conditions within the Yadkin-Pee Dee River basin. Flow conditions during 2004 were near normal for most of the year with the exception of high flow events associated with passage of several tropical storm systems in September. Low-flow conditions tended to reduce observable effects (e.g., solids and nutrients) from nonpoint discharge sources and magnify effects (e.g., anions and cations, COD, and specific conductance) from point source discharges. High-flow events tend to magnify the effects of nonpoint discharge sources. These flow and climate conditions have to be considered when interpreting the survey results. Lake Tillery was characterized as a deep, mesotrophic reservoir with moderate nutrient and solids concentrations, moderate water clarity, and weakly buffered with low to moderate anion and cation concentrations. The short hydraulic retention time of the reservoir (average of 8.3 days), coupled with the "filtering effect" of the four upstream reservoirs (i.e., High Rock Lake, Tuckertown Reservoir, Narrows Reservoir, and Falls Lake), influenced the nutrient and solids concentrations, turbidity values, and the trophic status of the reservoir. In contrast to Lake Tillery, Blewett Falls Lake was a shallow, nutrient-enriched, eutrophic reservoir with greater solids and turbidity levels. Water quality in Blewett Falls Lake, as well as a large upstream portion of the Pee Dee River, was influenced in varying degrees by inflow from the Tillery Hydroelectric Plant, Rocky River, and other tributaries within this river reach. Chlorophyll a (an indirect indicator of algal production) concentrations were lower on average in Lake Tillery when compared to Blewett Falls Lake. Algal dynamics in both reservoirs were largely influenced by the reservoirs' short hydraulic retention times which limited nutrient uptake by phytoplankton and subsequent production. Additionally, the turbid water conditions in Blewett Falls Lake limited light penetration for photosynthesis. There were very few instances of chlorophyll a concentrations exceeding the North Carolina water quality standard in either lake during the survey period. Long-term data collected the NCDWQ and Progress Energy indicated the water quality conditions in the reservoirs appeared to have either improved or not appreciably changed since the 1980s depending upon the examined parameter and reservoir. Both reservoirs continued to support their designated water quality use designations based on recent assessments by the NCDWQ during 2002. The short hydraulic retention time of both Project reservoirs also influenced the spatial pattern of water quality parameters. Most water quality parameters were fairly uniform with few significant longitudinal differences (i.e., upstream to downstream) observed at either reservoir. The only 6-1 Section 6 exceptions at Lake Tillery were significantly greater nitrate + nitrite-nitrogen and total phosphorus concentrations in the upper and middle reservoir areas when compared to the lower reservoir near the dam. Significant increases in these two nutrient parameters may have reflected inputs from the river upstream of the reservoir and/or the Uwharrie River and algal dynamics and nutrient uptake rates. There were significant temporal differences in the water quality of each reservoir which reflected precipitation levels and river inflow and outflow within a given year. Generally, solids constituents (especially total dissolved solids), most nutrient constituents, anions and cations, COD, total alkalinity, and specific conductance were greater during the lower flow, drought years (1999-2002) when compared to 2004, a year with greater flow levels. Lower reservoir inflow and outflow during the lower flow years tended to increase total dissolved solids, nutrients, anions and cations, and specific conductance. Higher COD values were likely the result of greater organic decomposition with increased hydraulic retention time in lower flow years. Temperature stratification and DO depletion dynamics in each reservoir were influenced by reservoir depth, the relative amount of precipitation and inflow within the river basin, and the amount of power generation. Lake Tillery usually experienced strong seasonal temperature stratification patterns from May until September, although stratification could either be prolonged or disrupted by one to two months depending upon precipitation levels and inflow and outflow conditions. The shallow nature of Blewett Falls Lake, coupled with river inflow and power plant operations, influenced the temperature stratification and DO depletion patterns within the reservoir. Unlike Lake Tillery which had awell-defined temperature stratification period, Blewett Falls Lake usually had very weak to moderate temperature stratification which could be disrupted with reservoir water column turnover during high river inflows and increased power plant generation. The epilmnion, metalimnion, and hypolimnion strata were also not as well defined in Blewett Falls Lake during the stratification period as was the case for Lake Tillery. Temperature stratification and DO depletion were also independent processes in Blewett Falls Lake and therefore did not closely correspond together as observed in Lake Tillery. Dissolved oxygen depletion occurred during the late spring, summer, and early fall months (usually May until September) in both reservoirs. The presence and persistence of low to anoxic DO conditions in the hypoliminion depended upon precipitation and flow conditions within a given year. In Lake Tillery, there were very strong top to bottom differences in DO during the stratification period with low to anoxic DO conditions (< 1 to 4 mg/L) occurring at the 12 to 19 m depth of the intake structure. The seasonal DO depletion was not quite as pronounced at Blewett Falls Lake, and anoxic conditions were usually confined to the bottom two to three meters in the reservoir water column. Blewett Falls Lake also did not have avery large volume of anoxic water present during the stratification period as observed at Lake Tillery. The release of low DO water from both reservoirs during power generation periods resulted in corresponding low DO conditions in the Project tailwaters. Low DO conditions were also observed in each power plant tailwaters during no power generation periods which suggested other factors algal respiration, organic matter decomposition, tributary inflow of low DO water, and/or power plant wicket gate leakage were also influencing DO dynamics in the tailwater areas, particularly during no power generation periods. 6-2 Section 6 The influence of lake levels and flows through the Project reservoirs on water quality was examined with correlation analysis during this study. The correlation analysis examined the statistical relationship betweenfactors being correlated and can be either negative (i.e., inverse relationship) or positive (i.e., corresponding relationship). Results of the correlation analysis for lake levels indicated weak relationships for only a few water quality parameters for Lake Tillery or Blewett Falls Lake. For Lake Tillery, weak negative correlations occurred between lake level and total aluminum while weak positive relationships occurred for calcium and chloride. The weak correlation between lake level and water quality parameters was not unexpected given that Lake Tillery has a relatively stable lake level and generally did not deviated more than 2 ft except for a few circumstances during the survey period. At Blewett Falls Lake, there were significant, but weak negative correlations between lake level and pH, total suspended solids, and aluminum and positive correlations with specific conductance, ammonia-nitrogen, total alkalinity, sodium, and sulfate. Generally, results from this lake level correlation analysis were indicative of the amount of inflow into the Project reservoirs as well as seasonal changes in water quality. Weak to moderate correlations existed between daily average flow and the examined water quality parameters for Lake Tillery and Blewett Falls Lake. Results of the correlation analysis were also inconsistent between both lakes. Water temperature, most anions and cations, and specific conductance were negatively correlated with flow at both Project reservoirs while positive correlations occurred for DO, nitrate + nitrite-nitrogen, and aluminum. However, there were differing relationships between flow and turbidity, solids constituents, ammonia-nitrogen, total phosphorus, total organic carbon, chemical oxygen demand, and copper at both reservoirs. Observed relationships between flow and water quality were likely related to the: (1) reservoirs' hydraulic retention time and amount of inflow; (2) relative differences in the water quality characteristics between the two lakes; and (3) degree of influence of upstream nonpoint and point source discharges on reservoir water quality. The water quality in the Pee Dee River reach from the Tillery Development to Blewett Falls Lake (i.e., Reach 1) was spatially and temporally influenced by operation of the Tillery Hydroelectric Plant and inputs from tributaries in the intervening watershed, most notably the Rocky River. Water quality characteristics in the five mile segment from the Tillery Hydroelectric Plant to the confluence with the Rocky River confluence resembled water quality characteristics of Lake Tillery during power generation periods. Below the confluence, inflows of the Rocky River and other major tributaries (i. e., Brown Creek and Little River) affected the water quality for the remaining 12 miles of this river reach and Blewett Falls Lake. Flow contributions from the Tillery Hydroelectric Plant during power generation periods influenced the degree of effect that the Rocky River had on water quality in this reach. The effects of the Rocky River and other tributaries within this river reach was most apparent during periods when the power plant did not generate for extended periods of time; during very low stream flow conditions (e.g., anions and cations, total dissolved solids, and specific conductance); or during very high-flow events associated with high precipitation events in the watershed (e.g., total suspended solids, turbidity, and aluminum). The Rocky River was a source of loading for solids constituents, turbidity (an indirect measure of sediment loading), nitrate + nitrite- nitrogen, total phosphorus, total organic carbon, chemical oxygen demand, anions and cations, and copper. Specific conductance, an indicator of concentrations of anions and cations, was also greater in the Rocky River. Conversely, higher DO concentrations in the Rocky River helped ameliorate the 6-3 Section 6 seasonal effects of low DO discharges from the Tillery Hydroelectric Plant in this mainstem river reach below the Rocky River confluence. Operational effects of the Tillery Hydroelectric Plant on the water quality within Reach 1 were assessed by examining water quality characteristics during power generation and no power generation periods during 2004. Water quality samples for the no power generation period were collected at least six hours after the last power plant generation event. DO concentrations were significantly lower during the power generation period compared to the no power generation period at the immediate tailwaters station (Station TY1B) and at the station located 12 miles downstream at N. C. Highway 109 bridge (Station TY12B). Total suspended solids, turbidity, and aluminum were significantly greater at the immediate tailwaters station during the power generation period. Conversely, the nitrate + nitrite-nitrogen concentration was significantly greater during the no generation period at this same station. At Station TY1213, ammonia-nitrogen was significantly greater during the no power generation period than the power generation period. There were no other significant differences in water quality parameters between the two generation periods at Station TY1213. The lack of differences in water quality characteristics between the two flow periods may have related to: (1) the influence of wicket gate leakage and dam spillage at the Tillery Hydroelectric Plant may have been enough to minimize differences between the power generation and no power generation periods; and (2) the water from previous generation events had not completely passed at Station TY1213. Water quality in the Blewett Falls tailwaters resembled lake water quality immediately below the hydroelectric plant, butthere were significant changes asthe river transitioned into the Coastal Plain of South Carolina. With increasing distance from the power plant, water quality characteristics were more influenced by physiographic topography changes, watershed inflow, natural inputs of organic matter, and point and nonpoint discharge sources. During power generation flow conditions in 2004, there were significant increases in solids constituents, total phosphorus, total organic carbon, COD, sodium, chloride, sulfate, total alkalinity, aluminum, copper, and specific conductance from the power plant tailwaters to the Coastal Plain of South Carolina. Similar spatial differences were also found for these same water quality parameters during 1999, 2001, and 2004. These changes in water quality were not the result of power plant operations; rather, they were the result of watershed effects and point and nonpoint discharges in the Coastal Plain portion of the river. A comparison of power generation and no power generation flow periods was examined at Stations BF1B and BF213, located 3.4 and 23.4 miles, respectively, downstream of the Blewett Falls Hydroelectric Plant. Few consistent significant differences were found in the water quality between the two flow periods at both stations. The results suggested the main effects of water quality releases from the Blewett Falls Hydroelectric Plant were increased concentrations of total solids, turbidity, and aluminum in the immediate tailwaters at Station BF1B. The only consistent significant difference noted at both Stations BF 1B and BF213 was increased aluminum levels during power generation flows. Solids, turbidity, and aluminum loading in Blewett Falls Lake was driven by nonpoint source sediment inputs from the upstream reach of the Pee Dee River, including inputs from the Rocky River and other tributaries. In summary, inflow and outflow at the Project reservoirs and river tailwaters were largely influenced by large-scale precipitation events in the river basin and upstream reservoir releases within the river 6-4 Section 6 basin, particularly during years with average or above average precipitation levels. During low-flow years, reservoir outflow was mainly influenced by power plant generation. Large-scale precipitation events in the river basin resulted in rapid turnover and movement of water through the reservoirs and tributaries, such as the Rocky River, and increased the influx of total suspended solids, turbidity, nutrients, and certain metals in reservoirs and tailwaters. During periods of lower inflow, concentrations of total dissolved solids, anions and cations, and corresponding measurements of specific conductance increased. In large part, operations of both hydroelectric plants did not influence water quality characteristics as much as watershed effects from point and nonpoint discharges and the amount of inflow and the hydraulic retention time. The water quality of Lake Tillery was influenced by the lake's position in the Yadkin chain of lakes because the upstream reservoirs provided a "filtering effect" on solids, nutrients, and other water quality constituents. Downstream of the Tillery Development, water quality in the immediate tailwaters, from the Tillery Dam to the Rocky River confluence five miles downstream, generally reflected water quality conditions in Lake Tillery during power generation and no power generation periods. The Rocky River, and to a lesser extent other tributaries within the tailwaters reach below Tillery, were significant sources of increased loading of nitrate + nitrite-nitrogen, total phosphorus, total organic carbon, chemical oxygen demand, anions and cations, and copper. The relative effect of the Rocky River and other tributaries on water quality in the Pee Dee River reach below the Tillery Hydroelectric Plant was flow dependent, both from the tributaries themselves and the amount of generation releases from the power plant. Inputs from the Rocky River and other tributaries influenced the water quality characteristics of Blewet Falls Lake, which were markedly different when compared to Lake Tillery. The relatively short residence time of both lakes under normal conditions resulted in little change in the water quality characteristics as water passed through the Project reservoirs, particularly Blewet Falls Lake. Water quality characteristics in the immediate tailwaters reach below the Blewet Falls Development were similar to Blewert Falls Lake. With increasing distance downstream, water quality in the lower Pee Dee River was changed by watershed inputs from physiographic and land use changes and nonpoint and point source discharges. Operations of the Tillery and Blewert Falls Hydroelectric Plants did result in seasonally low DO concentrations in the tailwaters located downstream of each power plant. Dissolved oxygen concentrations were below the North Carolina instantaneous and daily average water quality standards during power plant generation periods during the summer months during the survey years. With the exception of DO, other water quality variations from North Carolina water quality standards in Project reservoirs and tailwaters were the result of larger-scale watershed effects and point and nonpoint source discharges not as a result of Project operations. 6-5 Section 7 - References Alcoa Power Generating, Inc. 2002. Yadkin Hydroelectric Project FERC No. 2197 NC. Project Relicensing Initial Consultation Document, September, 2002. Alcoa Power Generating Inc., Yadkin Division, Badin, NC. American Public Health Association. 1998. Standard methods for the examination of water and wastewater. 20th edition. American Public Health Association, Washington, D.C. Appalachian State University. 1999. North Carolina's Central Park: assessing tourism and outdoor recreation in the Uwharrie Lakes region. Appalachian State University, September 1999. Carolina Power & Light Company. 1987. Environmental surveys of Lake Tillery and Blewett Falls Lake during 1986. Carolina Power & Light Company, New Hill, North Carolina. 1993. Tillery Hydroelectric Plant. 1992 environmental monitoring report. Carolina Power & Light Company, New Hill, North Carolina. 1995. Blewett Hydroelectric Plant. 1993 environmental monitoring report. Carolina Power & Light Company, New Hill, North Carolina. North Carolina Department of Natural and Economic Resources, Division of Environmental Management. 1983. North Carolina clean lakes classification survey 1982. Report No. 83- 03. North Carolina Department of Natural Resources and Community Development, Division of Environmental Management, Water Quality Section, Raleigh, North Carolina. 1989. North Carolina lakes monitoring report. 1988. Report No. 89-04. North Carolina Department of Natural Resources and Community Development, Division of Environmental Management, Water Quality Section, Raleigh, North Carolina. 1992a. North Carolina lake assessment report. Report No. 92-02. North Carolina Department of Natural Resources and Community Development, Division of Environmental Management, Water Quality Section, Raleigh, North Carolina. 1992b. Water quality progress in North Carolina. 1990-1991. 305(b) report. Report 92-06. North Carolina Department of Environment, Health, and Natural Resources, Division of Environmental Management, Water Quality Section, Raleigh, North Carolina. North Carolina Division of Water Quality. 1998. Yadkin-Pee Dee River basinwide water quality management plan. May 1998. North Carolina Department of Environment and Natural Resources, Division of Water Quality, Raleigh, North Carolina. 2000. Water quality progress in North Carolina 1998-1999 305(b) report. North Carolina Division of Water Quality, Water Quality Section, Raleigh, North Carolina. 7-1 Section 7 References 2002. Basinwide assessment report. Yadkin River Basin. June 2002. North Carolina Department of Environment, Health, and Natural Resources, Division of Water Quality, Water Quality Section, Environmental Services Branch, Raleigh, North Carolina 2003. Yadkin-Pee Dee River basinwide water quality plan. North Carolina Department of Environment and Natural Resources, Division of Water Quality, Raleigh, North Carolina. March 2003. 2004a. North Carolina water quality assessment and impaired waters list (2004 integrated 305(b) and 303(d) report). Public review draft: April 27, 2004. North Carolina Department of Environment and Natural Resources, Water Quality Section Planning Branch, Raleigh, North Carolina 2004b. NC DENR-Division of Water Quality "Redbook". Surface waters and wetlands standards. NC Administrative Code 15A NCAC 0213.0100, .0200 & .0300. Amended effective: August 1, 2004. North Carolina Department of Environment and Natural Resources, Division of Water Quality, Raleigh, North Carolina. 2005. Basinwide information management system. North Carolina waterbodies reports (including stream classifications). .0309 Yadkin River Basin. Internet web site http://h2o.enr.state.nc.us/bims/reports/basinsandwaterbodies/hydroYadkin.pdf. North Carolina Division of Water Quality. (Accessed on May 3, 2005.) 2006. North Carolina water quality assessment and impaired waters list (2004 integrated 305(b) and 303(d) report). Public review draft: February 2006. North Carolina Department of Environment and Natural Resources, Water Quality Section - Planning Branch, Raleigh, North Carolina North Carolina Division of Water Resources. 2005. Yadkin-Pee Dee River Basin drought news. North Carolina Department of Environment and Natural Resources, Division of Water Resources, Internet web site. www.ncwater.org/Drought Monitoring/Yadkin_PeeDee_ and Lumber/dmarchivenews/. (Accessed May 3, 2005.) Progress Energy. 2003. Initial consultation document. Yadkin-Pee Dee River Project. FERC No. 2206. February 2003. Submitted by Progress Energy, Raleigh, North Carolina. 2004a. RWG meeting summary notes, templates, & study plans. Yadkin-Pee Dee River Project FERC No. 2206. January 2004. Progress Energy. 2004b. Biology Program Procedures Manual (Procedures EVC-TSDC-00058, EVC-TSDC- 00062, and EVC-TSDC-00069). Progress Energy Carolinas, Inc., Raleigh, North Carolina. 20041. Biology Program Quality Assurance Manual. Progress Energy Carolinas, Inc., Raleigh, North Carolina. 7-2 Section 7 References 2004d. Yadkin-Pee Dee Hydroelectric Project FERC Project No. 2206. Relicensing water quality studies of the Pee Dee River and Project reservoirs. Quality Assurance Project Plan. December 2004. 2005a. Yadkin-Pee Dee River Hydroelectric Project FERC No. 2206. Continuous water quality monitoring in the Pee Dee River below the Tillery and Blewett Falls Hydroelectric Plants. Water Resources Group Issues Nos. 7 and 8, Lake Tillery and Blewett Falls Lakes & Tailwaters Water Quality. Draft Report. Progress Energy, March 2005. 2005b. Yadkin-Pee Dee River Hydroelectric Project FERC No. 2206. Intensive temperature and dissolved oxygen study of the Pee Dee River below the Tillery and Blewett Falls Hydroelectric Plants. Water Resources Group Issues Nos. 7 and 8, Lake Tillery and Blewett Falls Lakes & Tailwaters Water Quality. Draft Report. Progress Energy, March 2005. SAS Institute. 1990. SAS/STAT User's Guide, version 6, 4th edition, vol.1. SAS Institute. Cary, North Carolina. Southeast Regional Climate Center. 2005. Historic climate summaries for Wadesboro, NC COOP Station 318964. http://www.dnr.state.sc.us Columbia, South Carolina. State Climate Office of North Carolina. 2005. Precipitation and mean daily temperature for Wadesboro, NC COOP Station 318964. http://www.nc-climate.ncsu.edu Raleigh, North Carolina. South Carolina Department of Health and Environmental Control. 2001. Watershed water quality assessment: Pee Dee Basin. March 2001. South Carolina Department of Health and Environmental Control, Columbia, South Carolina. 2004a. Water classifications and standards. Regulation 61-68. South Carolina Department of Health and Environmental Control, Bureau of Water, Columbia, South Carolina. 2004b. State of South Carolina integrated report for 2004. Part IL Assessment and reporting. Submitted 4/1/2004. South Carolina Department of Health and Environmental Control, Columbia, South Carolina 2004c. The State of South Carolina's 2004 integrated report. Part L Listing of impaired waters. South Carolina Department of Health and Environmental Control, Columbia, South Carolina. U.S. Environmental Protection Agency. 1983. Methods for chemical analyses of water and wastes. U.S. Environmental Protection Agency, EPA-600/4-79-020, Cincinnati, Ohio. Wetzel, R.G. 2001. Limnology, lake and river ecosystems. Third edition. Academic Press, San Diego, California. 980 pp. 7-3 APPENDICES APPENDIX A RAW DATA LISTING FOR WATER QUALITY PARAMETERS COLLECTED IN LAKE TILLERY, THE PEE DEE RIVER, AND THE ROCKY RIVER DURING 2000, 2001, 2002, AND 2004 Table A-1 Water temperature, dissolved oxygen, specific conductance, pH, and Secchi disk transparency data collected from Lake Tillery (Stations TYB2, TYD2, TYF2, TYH2, and TYK2) during 2000. January 24, 2000 Depth Temperature Dissolved oxygen Specific conductance pH (m) (BC) (mg/L) (4)S/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 7.9 7.5 6.8 6.3 7.5 10.3 10.4 10.6 11.3 11.6 86 84 82 79 84 7.5 7.7 7.2 7.4 7.7 1.0 7.9 7.5 6.8 6.3 7.5 10.3 10.4 10.6 11.3 11.6 86 84 82 79 84 7.5 7.7 7.2 7.4 7.7 2.0 7.9 7.5 6.8 6.3 7.5 10.3 10.4 10.6 11.3 11.6 86 84 82 79 84 7.5 7.7 7.2 7.4 7.7 3.0 7.9 7.5 6.8 6.3 7.5 10.3 10.4 10.6 11.3 11.6 86 84 82 79 84 7.5 7.7 7.2 7.4 7.7 4.0 7.9 7.5 6.8 6.3 7.5 10.3 10.4 10.6 11.2 11.6 86 84 82 79 84 7.5 7.7 7.2 7.5 7.7 5.0 7.9 7.5 6.8 6.2 10.3 10.4 10.6 11.2 86 84 82 78 7.5 7.7 7.2 7.6 6.0 7.9 7.5 6.8 6.2 10.3 10.4 10.6 11.2 86 84 82 78 7.5 7.7 7.2 7.6 7.0 7.9 7.5 6.8 6.0 10.3 10.4 10.6 11.2 86 84 82 77 7.5 7.7 7.2 7.8 8.0 7.9 7.5 6.8 5.7 10.3 10.4 10.6 11.1 86 84 82 76 7.5 7.7 7.2 7.9 9.0 7.9 7.5 6.8 10.3 10.4 10.6 86 84 82 7.5 7.7 7.2 10.0 7.9 7.5 6.8 10.3 10.4 10.6 86 84 82 7.5 7.7 7.3 11.0 7.9 7.5 6.8 10.3 10.4 10.7 86 84 81 7.6 7.7 7.4 12.0 7.9 7.5 6.8 10.3 10.4 10.6 86 84 81 7.6 7.7 7.6 13.0 7.9 7.5 6.8 10.3 10.4 10.4 86 84 81 7.6 7.7 7.6 14.0 7.9 7.4 6.8 10.3 10.3 10.3 86 84 81 7.6 7.7 7.6 15.0 7.9 7.4 10.3 10.3 86 84 7.6 7.8 16.0 7.9 10.3 86 7.6 17.0 7.9 10.3 86 7.6 18.0 7.9 10.3 86 7.6 February 1, 2000 Depth Tempera ture Dissolved oxygen Specific conductance pH (m) (BC) (mg/L) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 6.6 6.6 4.9 5.4 5.6 11.5 12.6 12.4 11.5 10.8 81 80 66 70 75 6.6 6.9 6.2 7.0 7.0 1.0 6.5 6.2 4.9 5.4 5.6 11.4 12.4 12.2 11.5 10.8 81 79 66 70 75 6.6 6.9 6.3 7.0 7.0 2.0 6.0 6.2 4.9 5.4 5.6 11.3 12.4 12.1 11.5 10.8 80 79 66 70 75 6.7 6.9 6.4 7.0 7.0 3.0 5.8 5.6 4.9 5.4 5.6 11.2 12.4 12.0 11.5 10.8 79 78 66 70 75 6.8 6.9 6.4 7.0 7.0 4.0 5.8 5.5 4.9 5.4 5.6 11.2 12.2 12.0 11.4 10.8 79 77 66 70 75 6.8 7.0 6.4 7.0 7.0 5.0 5.8 5.5 4.9 5.4 11.0 12.2 12.0 11.4 79 77 66 70 6.8 7.0 6.5 7.0 6.0 5.8 5.5 4.9 5.4 11.0 12.2 12.0 11.4 79 77 66 70 6.8 7.0 6.5 7.0 7.0 5.8 5.5 4.8 5.4 11.0 12.2 12.0 11.4 79 77 66 70 6.8 7.0 6.5 7.0 8.0 5.8 5.5 4.8 11.0 12.2 12.0 79 77 66 6.8 7.0 6.5 9.0 5.8 5.5 4.8 11.0 12.2 12.0 79 77 66 6.8 7.0 6.5 10.0 5.8 5.5 4.8 11.0 12.2 12.0 79 77 66 6.8 7.0 6.5 11.0 5.8 5.5 4.8 11.0 12.2 12.0 79 77 66 6.8 7.0 6.5 12.0 5.8 5.5 4.8 11.0 12.1 12.0 79 77 65 6.8 6.9 6.6 13.0 5.8 5.5 4.8 11.0 12.1 12.0 79 77 65 6.8 6.9 6.6 14.0 5.7 5.5 4.7 11.0 12.1 11.5 79 77 65 6.8 6.9 6.7 15.0 5.7 5.5 11.0 12.1 79 77 6.8 6.9 16.0 5.7 5.5 11.0 12.1 79 77 6.8 6.9 17.0 5.7 5.5 11.0 12.0 79 77 6.8 6.9 18.0 5.7 10.8 78 6.8 Appendix A - 1 Table A-1 (continued) March 8, 2000 Depth Temperature Dissolved oxygen Specific conductance pH (m) (HC) (mg/L) (OS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 18.2 15.9 15.1 13.0 9.5 15.3 15.4 15.2 13.0 11.8 107 102 101 94 87 9.0 9.0 9.0 8.4 7.5 1.0 13.0 14.0 14.9 12.9 9.5 15.4 15.2 14.7 12.6 11.5 94 97 101 94 87 9.0 9.0 8.9 8.2 7.5 2.0 11.4 12.7 11.9 12.7 9.5 13.2 15.1 14.0 12.5 11.4 90 94 93 93 87 8.2 8.9 8.7 8.1 7.5 3.0 10.6 10.7 11.5 9.9 9.5 12.6 13.4 13.2 11.8 11.4 88 90 92 87 87 8.2 8.5 8.4 8.0 7.5 4.0 10.3 10.2 10.9 9.7 9.5 12.4 12.1 13.1 11.6 11.4 86 89 90 86 87 8.1 8.2 8.3 7.9 7.5 5.0 10.1 10.0 10.8 9.7 11.7 12.1 12.9 11.5 86 89 89 86 8.0 8.2 8.2 7.9 6.0 9.4 9.9 10.4 9.7 11.7 12.0 12.2 11.4 84 89 88 86 7.9 8.1 8.2 7.8 7.0 9.3 9.7 10.2 9.6 11.4 11.8 12.0 11.3 85 88 88 86 7.8 8.0 8.1 7.8 8.0 9.0 9.6 10.1 11.3 11.6 11.9 87 88 88 7.8 8.0 8.0 9.0 8.9 9.3 10.0 11.2 11.5 11.9 86 88 88 7.8 7.9 8.0 10.0 8.8 8.9 9.8 11.2 11.3 11.6 85 87 87 7.8 7.9 7.9 11.0 8.6 8.6 9.8 11.2 11.1 11.5 84 87 87 7.8 7.8 7.9 12.0 8.2 8.6 9.7 11.0 10.9 11.5 83 86 87 7.7 7.8 7.8 13.0 8.1 8.0 9.7 10.9 10.8 11.4 83 85 87 7.7 7.7 7.8 14.0 8.0 8.0 10.9 10.5 82 85 7.7 7.7 15.0 7.8 7.8 10.7 10.4 81 84 7.6 7.7 16.0 7.7 7.7 10.7 10.3 81 83 7.6 7.6 17.0 7.6 7.7 10.6 10.0 80 86 7.6 7.6 18.0 7.6 10.4 80 7.5 April 6, 2000 Depth Temperature Dissolved oxygen Specific conductance pH (m) (HC) (mg/L) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 15.5 15.7 15.4 14.5 13.7 10.7 10.7 10.7 10.0 9.4 78 77 76 72 72 7.4 7.5 7.5 7.5 7.2 1.0 15.5 15.6 15.3 14.3 13.7 10.7 10.6 10.7 9.7 9.4 78 77 76 72 72 7.4 7.5 7.5 7.5 7.2 2.0 15.5 15.6 15.2 14.3 13.7 10.7 10.6 10.7 9.6 9.4 78 77 76 72 72 7.4 7.5 7.5 7.5 7.2 3.0 14.9 15.6 15.2 14.3 13.7 10.4 10.6 10.7 9.6 9.3 77 77 76 72 72 7.5 7.5 7.5 7.5 7.2 4.0 14.8 15.5 15.1 14.1 10.2 10.6 10.7 9.5 76 77 76 72 7.5 7.5 7.5 7.4 5.0 14.8 15.4 14.4 14.1 10.1 10.6 10.4 9.5 76 77 75 72 7.5 7.5 7.5 7.4 6.0 14.7 15.3 14.3 14.0 10.1 10.5 10.0 9.6 76 77 74 72 7.5 7.5 7.5 7.4 7.0 14.7 15.3 14.3 13.7 10.0 9.9 10.0 9.5 76 77 74 71 7.5 7.5 7.5 7.4 8.0 14.5 14.4 13.7 13.6 9.8 9.8 9.6 9.4 76 75 73 71 7.5 7.5 7.5 7.4 9.0 14.3 14.3 13.6 9.7 9.6 9.4 75 75 73 7.5 7.5 7.5 10.0 14.3 14.2 13.6 9.7 9.5 9.4 75 75 73 7.5 7.5 7.5 11.0 14.2 14.1 13.5 9.7 9.5 9.3 75 75 73 7.5 7.5 7.5 12.0 14.1 14.1 13.5 9.6 9.4 9.3 75 75 73 7.4 7.5 7.4 13.0 14.0 14.1 13.5 9.5 9.4 9.2 75 75 73 7.4 7.5 7.4 14.0 14.0 13.9 13.5 9.5 9.3 9.2 75 75 73 7.4 7.4 7.4 15.0 13.9 13.7 13.4 9.4 9.0 9.1 75 75 72 7.4 7.4 7.4 16.0 13.7 13.2 9.2 8.7 74 74 7.4 7.4 17.0 13.5 12.9 8.9 8.1 74 73 7.4 7.4 18.0 13.5 8.8 74 7.4 Appendix A - 2 Table A-1 (continued) May 2, 2000 Depth Temperature Dissolved oxygen Specific conductance pH (m) (HC) (mg/L) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 19.8 20.2 19.8 19.0 16.6 8.4 10.7 10.9 10.5 8.5 79 79 77 74 72 7.0 7.7 7.7 7.7 7.3 1.0 17.7 20.2 19.4 18.5 16.6 8.9 10.7 11.0 9.9 8.5 75 79 76 73 72 7.1 7.8 7.9 7.6 7.3 2.0 16.6 18.9 18.9 17.2 16.6 8.2 10.5 10.8 9.4 8.5 73 76 75 72 72 7.0 7.8 7.9 7.5 7.3 3.0 16.4 17.9 18.5 16.8 16.6 8.2 9.8 10.6 8.9 8.5 73 75 74 71 72 7.0 7.8 7.9 7.4 7.3 4.0 16.3 17.6 18.0 16.7 16.6 8.2 9.1 10.2 8.5 8.5 73 74 73 70 72 7.0 7.7 7.8 7.4 7.3 5.0 16.3 17.1 17.7 16.6 8.1 8.6 9.5 8.4 73 73 72 70 6.9 7.6 7.7 7.3 6.0 16.3 17.0 17.6 16.6 8.1 8.4 9.2 8.3 73 72 72 70 7.0 7.5 7.6 7.3 7.0 16.2 16.5 17.6 16.6 7.9 8.1 9.1 8.2 72 71 72 70 7.0 7.4 7.6 7.3 8.0 16.1 16.4 17.4 16.6 7.8 8.1 8.8 8.0 72 71 71 70 7.0 7.4 7.6 7.3 9.0 16.0 16.2 16.7 7.7 7.9 8.4 71 70 68 7.0 7.4 7.5 10.0 16.0 16.0 16.5 7.7 7.8 8.2 71 70 68 7.0 7.4 7.4 11.0 16.0 15.8 16.4 7.7 7.7 8.1 71 69 68 7.0 7.4 7.4 12.0 16.0 15.8 16.3 7.7 7.5 8.0 71 69 67 7.0 7.3 7.4 13.0 16.0 15.8 16.2 7.6 7.5 8.0 71 69 66 7.0 7.3 7.4 14.0 15.9 15.8 15.7 7.6 7.5 7.8 71 69 65 7.0 7.3 7.4 15.0 15.9 15.8 15.7 7.6 7.5 7.6 71 69 65 7.0 7.3 7.3 16.0 15.9 15.8 7.5 7.5 71 69 7.0 7.3 17.0 15.8 15.7 7.5 7.2 71 70 7.0 7.2 18.0 15.5 4.6 72 6.8 June 12,2000 Depth Temperature Dissolved oxygen Specific conductance pH (m) (HC) (mg/ L) (OS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 27.2 27.9 28.0 27.8 22.7 8.9 9.6 9.8 10.0 6.1 110 112 111 111 102 7.6 8.0 8.3 8.3 7.3 1.0 25.7 26.8 27.0 27.2 22.7 9.4 10.0 9.9 10.1 6.1 107 109 108 110 102 7.7 8.3 8.3 8.4 7.3 2.0 25.3 26.5 26.2 27.1 22.7 9.5 9.9 9.5 10.1 6.1 106 109 106 109 102 7.8 8.4 8.1 8.4 7.3 3.0 24.6 25.0 25.3 26.9 22.7 9.2 8.7 8.5 9.9 6.1 105 105 106 109 102 7.8 8.2 7.9 8.3 7.3 4.0 24.1 23.8 24.7 26.8 8.3 7.1 7.6 9.7 103 103 104 108 7.7 7.8 7.7 8.3 5.0 23.5 23.4 23.3 25.1 7.4 6.8 6.0 7.9 102 101 102 106 7.6 7.7 7.6 8.1 6.0 23.2 23.3 22.9 23.0 6.1 6.4 5.6 5.9 101 101 102 102 7.5 7.6 7.5 7.7 7.0 22.9 22.8 22.6 23.0 5.6 5.5 5.3 5.8 101 100 101 102 7.5 7.4 7.5 7.7 8.0 22.7 22.6 22.3 23.0 5.2 5.4 5.1 5.8 100 100 101 104 7.4 7.4 7.5 7.5 9.0 22.3 22.4 21.9 4.9 5.4 5.0 100 100 100 7.3 7.3 7.5 10.0 22.2 22.1 21.8 4.9 5.3 4.7 99 100 100 7.2 7.2 7.5 11.0 22.0 21.9 21.7 4.8 5.2 4.6 99 99 100 7.2 7.2 7.5 12.0 21.7 21.6 21.7 4.5 4.7 4.5 99 99 100 7.1 7.1 7.4 13.0 21.2 21.2 21.5 4.2 3.8 4.4 98 98 99 7.1 7.1 7.3 14.0 20.9 21.0 21.3 3.9 3.6 4.0 97 98 99 7.0 7.0 7.3 15.0 20.5 20.5 21.3 3.7 3.2 3.7 97 97 99 7.0 7.0 7.2 16.0 20.0 20.1 3.3 2.6 96 97 6.9 7.0 17.0 19.6 19.9 2.8 2.2 95 97 6.9 6.9 18.0 18.8 1.4 97 6.8 Appendix A - 3 Table A-1 (continued) July 10, 2000 Depth Temperature Dissolved oxygen Specific conductance pH (m) (BC) (mg/L) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 29.5 29.9 30.0 29.8 25.5 8.9 8.9 9.3 9.4 5.8 114 114 115 116 114 7.9 8.0 8.6 8.5 7.7 1.0 28.8 29.3 29.9 29.6 25.5 8.9 9.2 9.3 9.5 5.7 112 113 115 115 114 7.9 8.3 8.6 8.5 7.6 2.0 28.0 28.9 29.6 29.3 25.5 8.4 9.3 9.3 9.5 5.8 110 113 114 115 114 7.8 8.4 8.6 8.5 7.6 3.0 28.0 28.7 29.2 29.2 25.5 8.4 9.3 9.1 9.5 5.8 109 112 112 114 114 7.5 8.4 8.6 8.5 7.6 4.0 26.7 28.1 29.0 28.7 3.6 8.3 9.0 9.5 109 110 112 113 7.4 8.3 8.5 8.4 5.0 26.2 26.0 28.7 28.5 2.9 5.0 8.5 8.6 109 111 111 113 7.3 8.0 8.3 8.2 6.0 26.0 25.5 28.4 27.2 3.5 3.8 8.1 6.7 111 112 111 114 7.3 7.8 8.2 8.1 7.0 25.8 25.2 27.3 26.8 3.9 3.2 6.9 5.5 111 111 112 114 7.2 7.7 8.1 7.9 8.0 25.5 25.1 26.8 2.2 3.2 6.0 109 111 113 7.2 7.6 8.1 9.0 25.3 24.9 25.9 2.2 3.2 4.4 109 110 112 7.2 7.6 7.9 10.0 25.2 24.5 25.2 2.2 1.6 4.0 109 107 112 7.2 7.5 7.8 11.0 24.7 24.2 24.6 2.0 1.4 2.9 107 106 111 7.2 7.4 7.7 12.0 24.2 24.0 24.2 1.2 1.4 2.3 104 105 110 7.1 7.4 7.8 13.0 24.0 23.7 24.1 1.2 1.3 2.0 104 104 110 7.0 7.4 7.8 14.0 23.5 23.4 23.7 1.2 1.1 0.5 102 104 110 7.0 7.3 7.8 15.0 23.1 23.2 23.7 1.2 0.7 0.4 101 104 110 7.0 7.3 7.5 16.0 22.9 22.5 1.1 0.3 101 111 7.0 7.2 17.0 22.5 22.3 0.9 0.1 101 125 7.0 7.1 18.0 21.6 0.1 108 6.9 August 8, 2000 Depth Temperature Dissolved oxygen Specific conductance pH (m) (BC) (mg/L) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 31.3 31.5 31.5 32.9 26.6 11.9 11.9 12.3 11.8 7.5 123 124 124 130 129 8.0 8.1 8.4 8.2 7.7 1.0 29.1 30.0 30.4 31.7 26.6 12.4 12.5 12.8 12.5 7.5 119 121 123 127 129 8.2 8.2 8.4 8.3 7.7 2.0 28.2 29.3 29.8 30.0 26.6 12.8 12.6 13.1 13.1 7.5 117 119 121 123 129 8.2 8.2 8.5 8.4 7.7 3.0 28.1 29.0 29.5 29.2 26.6 9.2 11.8 12.9 11.7 7.5 117 118 120 122 129 8.2 8.2 8.5 8.4 7.7 4.0 27.5 28.3 29.2 28.8 7.6 9.2 11.5 10.4 115 118 119 124 8.1 8.0 8.4 8.2 5.0 27.2 27.6 28.4 27.5 5.0 6.9 9.7 7.7 116 118 119 127 8.0 8.0 8.4 8.0 6.0 26.8 27.0 27.7 26.6 2.2 4.5 8.4 7.6 116 119 120 127 7.8 7.9 8.2 8.0 7.0 26.6 26.5 27.1 26.6 1.8 2.6 5.7 7.3 116 121 122 127 7.8 7.8 8.2 8.0 8.0 26.5 26.3 26.7 26.6 1.4 2.5 4.8 7.0 116 121 123 127 7.7 7.8 8.0 7.9 9.0 26.3 26.1 26.5 1.1 2.4 4.5 116 120 123 7.7 7.8 8.0 10.0 26.1 25.9 26.3 0.9 2.2 4.0 116 120 124 7.7 7.7 7.9 11.0 26.0 25.8 26.1 0.8 1.2 3.7 116 119 124 7.6 7.7 7.8 12.0 26.0 25.7 26.0 0.7 1.1 3.3 116 119 125 7.6 7.7 7.8 13.0 25.6 25.6 25.9 0.5 1.0 2.9 117 119 125 7.6 7.6 7.8 14.0 25.5 25.5 25.8 0.3 0.7 2.4 117 119 125 7.6 7.6 7.7 15.0 25.4 25.4 0.2 0.4 118 119 7.6 7.5 16.0 25.3 24.9 0.2 0.3 118 121 7.5 7.5 17.0 24.8 24.2 0.1 0.1 119 137 7.5 7.4 18.0 23.9 0.1 130 7.4 Appendix A - 4 Table A-1 (continued) Sep tember 5, 2000 Depth Temperature Dissolved oxygen Specific conductance pH (m) (HC) (mg/L ) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 26.6 26.8 27.2 26.9 26.1 5.1 5.3 6.8 7.1 6.8 118 119 121 126 131 6.9 7.0 7.2 7.3 7.1 1.0 26.6 26.8 27.2 26.9 26.1 5.1 5.3 6.8 7.0 6.8 118 119 121 126 131 6.9 7.0 7.2 7.3 7.1 2.0 26.6 26.8 27.2 26.9 26.1 5.0 5.3 6.8 7.0 6.8 118 119 121 126 131 6.9 7.0 7.2 7.3 7.1 3.0 26.6 26.8 27.2 26.9 26.1 5.0 5.3 6.6 7.0 6.8 117 119 121 126 131 6.9 7.0 7.2 7.3 7.1 4.0 26.6 26.8 27.2 26.9 5.0 5.3 6.6 7.0 117 119 121 126 6.9 7.0 7.2 7.3 5.0 26.6 26.8 27.2 26.9 5.0 5.2 6.6 7.0 117 119 121 126 6.9 7.0 7.2 7.3 6.0 26.6 26.8 27.1 26.9 5.0 5.2 6.4 7.0 117 119 122 126 6.9 7.0 7.2 7.3 7.0 26.6 26.8 26.9 26.9 5.0 5.2 5.3 7.0 117 119 125 126 6.9 7.0 7.1 7.3 8.0 26.6 26.8 26.8 26.9 5.0 4.8 4.6 6.7 117 119 128 128 6.9 6.9 7.0 7.2 9.0 26.6 26.8 26.5 5.0 4.8 3.3 117 119 131 6.9 6.9 7.0 10.0 26.6 26.8 26.4 5.0 4.8 3.1 117 119 131 6.9 6.9 6.9 11.0 26.6 26.5 26.3 5.0 2.6 2.8 117 123 131 6.9 6.9 6.9 12.0 26.6 26.4 26.3 5.0 2.2 2.7 117 125 131 6.9 6.8 6.8 13.0 26.6 26.4 26.2 5.0 2.2 2.6 117 125 132 6.9 6.8 6.8 14.0 26.6 26.4 26.0 4.8 2.2 2.1 117 125 133 6.9 6.8 6.8 15.0 26.3 26.4 26.0 0.7 2.2 1.5 122 125 136 6.8 6.8 6.8 16.0 26.2 26.3 0.6 2.7 125 127 6.7 6.8 17.0 25.9 25.8 0.6 1.8 125 133 6.7 6.8 18.0 25.1 0.8 131 6.6 October 4, 2000 Depth Temperature Dissolved oxygen Specific conductance pH (m) (HC) (mg/L ) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 24.1 25.2 26.2 24.8 22.7 7.6 10.2 11.0 10.1 7.3 115 119 124 129 125 7.1 7.8 8.5 8.1 7.8 1.0 23.5 24.1 25.1 24.4 22.7 7.5 10.3 11.5 9.5 7.3 114 116 122 128 125 7.1 8.0 8.7 8.0 7.8 2.0 23.2 23.7 23.6 24.0 22.7 7.0 10.5 10.8 8.9 7.3 113 115 119 127 125 7.1 8.2 8.6 8.0 7.8 3.0 23.1 23.4 23.4 22.8 22.7 6.3 8.6 10.3 7.0 7.3 113 114 120 124 125 7.1 8.0 8.4 7.8 7.7 4.0 23.1 23.2 23.1 22.4 6.2 7.7 10.2 6.7 113 114 121 124 7.1 7.9 8.3 7.7 5.0 23.0 23.1 22.8 22.3 6.3 6.2 9.2 6.4 113 114 122 123 7.1 7.8 8.1 7.6 6.0 23.0 23.0 22.6 22.2 6.4 6.1 9.0 6.3 113 114 121 123 7.0 7.7 8.0 7.5 7.0 23.0 23.0 22.4 22.2 6.5 6.2 8.5 6.3 113 114 120 123 7.0 7.6 8.0 7.5 8.0 23.0 22.9 22.2 22.2 6.5 6.3 8.0 6.3 113 115 120 124 7.0 7.6 8.0 7.5 9.0 22.9 22.9 22.0 5.9 6.3 7.2 114 115 120 7.0 7.5 7.9 10.0 22.9 22.8 22.0 5.9 6.4 7.1 114 116 120 7.0 7.5 7.7 11.0 22.9 22.8 22.0 5.9 6.4 7.1 114 115 121 7.0 7.5 7.6 12.0 22.9 22.7 21.9 5.9 6.5 6.9 114 116 120 7.0 7.4 7.5 13.0 22.9 22.6 21.8 5.9 6.6 6.8 114 115 120 7.0 7.4 7.5 14.0 22.9 22.3 21.7 5.9 6.6 6.5 114 117 120 7.0 7.4 7.5 15.0 22.8 22.1 5.8 6.8 114 118 7.0 7.4 16.0 22.8 22.0 5.7 6.8 114 119 7.0 7.3 17.0 22.8 22.0 5.6 6.8 114 119 7.0 7.3 18.0 22.8 21.9 5.3 6.4 116 127 7.0 7.3 Appendix A - 5 Table A-1 (continued) November 15, 2000 Depth Temperature Dissolved oxygen Specific conductance pH (m) (HC) (mg/L ) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 17.7 17.5 17.0 16.8 17.2 9.0 9.1 10.1 8.3 7.6 109 108 111 113 114 7.1 7.3 7.3 7.3 7.2 1.0 17.7 17.5 17.0 16.8 17.2 8.8 9.0 9.6 8.2 7.6 109 108 111 113 114 7.1 7.2 7.3 7.3 7.2 2.0 17.7 17.5 17.0 16.5 17.2 8.8 9.0 9.5 8.2 7.6 109 107 111 112 114 7.1 7.2 7.3 7.3 7.2 3.0 17.3 17.3 17.0 16.4 17.2 8.8 8.9 9.5 8.2 7.6 106 107 111 112 114 7.1 7.2 7.3 7.2 7.2 4.0 17.3 17.3 16.9 16.2 8.8 8.8 9.5 8.2 106 107 111 111 7.1 7.2 7.3 7.1 5.0 17.3 17.3 16.8 16.2 8.7 8.8 9.4 8.2 106 107 110 111 7.1 7.2 7.3 7.1 6.0 17.3 17.3 16.8 16.2 8.7 8.8 9.4 8.2 106 107 110 111 7.1 7.2 7.3 7.1 7.0 17.2 17.3 16.8 16.2 8.5 8.8 9.4 8.2 107 107 110 111 7.1 7.2 7.2 7.1 8.0 17.2 17.3 16.7 16.1 8.5 8.7 9.2 8.1 107 107 110 112 7.1 7.2 7.2 7.1 9.0 17.2 17.2 16.7 8.4 8.6 9.1 107 107 110 7.0 7.1 7.2 10.0 17.2 17.2 16.7 8.3 8.6 9.1 107 107 110 7.0 7.1 7.2 11.0 17.1 17.2 16.7 8.3 8.5 9.1 107 107 110 7.0 7.1 7.2 12.0 17.1 17.2 16.7 8.3 8.5 9.0 107 107 112 7.0 7.1 7.2 13.0 17.1 17.2 16.7 8.2 8.5 2.5 107 107 113 7.0 7.1 7.2 14.0 17.1 17.2 16.7 8.1 8.4 0.4 106 107 122 7.0 7.1 7.2 15.0 17.1 17.2 8.1 8.4 106 107 7.0 7.1 16.0 17.1 17.2 8.1 8.2 106 107 7.0 7.1 17.0 17.1 17.2 8.1 8.2 106 107 7.0 7.1 18.0 17.1 17.2 8.1 8.2 106 106 6.9 7.1 December 5, 2000 Depth Temperature Dissolved oxygen Specific conductance pH (m) (HC) (mg/L ) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 12.0 11.5 10.9 10.8 11.7 9.8 9.6 10.1 9.8 9.1 93 93 99 100 102 7.0 7.3 7.3 7.3 7.3 1.0 11.9 11.5 10.9 10.9 11.6 9.8 9.6 10.1 9.7 8.9 93 93 98 100 101 7.0 7.3 7.3 7.3 7.3 2.0 11.8 11.5 10.5 10.5 11.7 9.8 9.6 10.0 9.6 8.9 93 93 98 99 101 7.0 7.3 7.4 7.4 7.3 3.0 11.8 11.5 10.5 10.5 11.6 9.8 9.6 10.0 9.5 8.9 93 93 98 98 101 7.0 7.3 7.4 7.4 7.3 4.0 11.8 11.5 10.4 10.4 9.8 9.6 9.8 9.3 93 93 97 98 7.0 7.3 7.3 7.3 5.0 11.8 11.4 10.3 10.3 9.8 9.6 9.8 9.3 93 93 97 98 7.0 7.3 7.3 7.3 6.0 11.8 11.4 10.3 10.3 9.6 9.6 9.7 9.2 93 93 97 98 7.0 7.3 7.3 7.3 7.0 11.7 11.2 10.3 10.3 9.5 9.3 9.7 9.2 92 93 97 98 7.0 7.3 7.3 7.3 8.0 11.6 11.2 10.2 10.3 9.4 9.3 9.6 9.2 92 93 97 98 7.0 7.3 7.3 7.3 9.0 11.6 11.2 10.2 9.3 9.3 9.6 92 93 97 7.0 7.3 7.3 10.0 11.6 11.2 10.2 9.3 9.2 9.6 92 93 97 7.0 7.3 7.3 11.0 11.6 11.2 10.2 9.3 9.2 9.6 92 93 97 7.0 7.3 7.3 12.0 11.5 11.2 10.2 9.2 9.2 9.6 92 93 97 7.0 7.3 7.3 13.0 11.5 11.2 10.2 9.2 9.2 9.6 92 93 97 7.0 7.3 7.3 14.0 11.5 11.2 10.2 9.2 9.2 9.6 92 93 97 7.0 7.3 7.3 15.0 11.5 11.2 10.2 9.2 9.2 9.4 92 93 97 7.0 7.3 7.3 16.0 11.5 11.2 9.1 9.2 92 93 7.0 7.3 17.0 11.5 11.2 9.1 9.2 92 93 7.0 7.3 18.0 11.5 11.0 9.0 8.9 92 95 7.0 7.2 Appendix A - 6 Table A-1 (continued) Secchi disk transparency depth (m) Date TYB2 TYD2 TYF2 TYH2 TYK2 January 24, 2000 1.6 1.4 1.5 1.2 1.7 February 1, 2000 1.8 1.2 0.4 0.5 0.7 March 8, 2000 1.0 1.0 1.0 1.0 1.2 April 6, 2000 1.4 1.5 1.2 1.1 1.1 May 2, 2000 1.8 1.4 1.2 1.0 1.5 June 12, 2000 2.2 2.2 2.2 1.9 2.1 July 10, 2000 1.8 1.6 1.7 1.3 1.9 August 8, 2000 2.1 2.3 2.0 1.6 1.7 September 5, 2000 2.2 3.0 1.9 1.2 1.9 October 4, 2000 2.7 2.1 1.9 1.9 2.5 November 15, 2000 1.7 1.7 2.0 2.8 2.9 December 5, 2000 2.0 1.9 2.4 3.0 3.0 Appendix A - 7 Table A-2 Water temperature, dissolved oxygen, specific conductance, and pH data collected from Lake Tillery (Stations TYB2, TYD2, TYF2, TYH2, and TYK2) during 2002. January 15, 2002 Depth Temperature Dissolved oxygen Specific conductance pH (m) (BC) (mg/L) ((DS/cm) 0.2 9.4 9.0 9.1 9.1 9.0 10.7 10.9 10.7 10.8 10.7 78 77 81 79 80 7.5 7.5 7.5 7.4 7.4 1.0 9.4 9.0 9.0 9.0 9.0 10.4 10.8 10.3 10.8 10.6 77 77 81 79 80 7.6 7.5 7.5 7.4 7.4 2.0 8.8 8.9 9.0 8.7 9.0 10.4 10.7 10.2 10.8 10.6 76 76 81 78 80 7.6 7.5 7.4 7.4 7.4 3.0 8.7 8.6 8.5 8.3 8.9 10.4 10.7 10.1 10.7 10.6 76 76 79 78 79 7.6 7.5 7.4 7.4 7.3 4.0 8.7 8.5 8.4 8.2 8.8 10.4 10.6 10.0 10.6 10.7 76 76 79 78 79 7.5 7.5 7.4 7.4 7.4 5.0 8.6 8.5 8.3 8.2 10.3 10.5 9.9 10.6 76 76 79 77 7.5 7.5 7.4 7.4 6.0 8.6 8.5 8.3 8.1 10.3 10.5 9.9 10.6 76 76 79 77 7.5 7.5 7.4 7.3 7.0 8.6 8.5 8.3 8.0 10.2 10.4 9.9 10.5 75 76 79 76 7.5 7.5 7.4 7.3 8.0 8.6 8.5 8.3 8.0 10.1 10.3 9.8 10.4 76 76 79 76 7.5 7.5 7.4 7.3 9.0 8.6 8.4 8.3 10.1 10.2 9.8 76 76 79 7.5 7.5 7.4 10.0 8.6 8.4 8.3 10.1 10.2 9.8 76 76 79 7.5 7.5 7.4 11.0 8.6 8.4 8.3 10.0 10.2 9.8 76 76 79 7.5 7.5 7.4 12.0 8.6 8.4 8.3 10.0 10.2 9.8 76 77 79 7.5 7.5 7.4 13.0 8.6 8.4 8.3 10.0 10.1 9.8 76 77 79 7.5 7.5 7.4 14.0 8.6 8.4 8.3 9.9 10.1 9.7 76 78 79 7.5 7.5 7.3 15.0 8.6 8.3 9.7 9.9 76 78 7.5 7.5 16.0 8.6 8.3 9.6 9.7 76 78 7.5 7.5 17.0 8.5 8.4 9.4 9.0 76 78 7.5 7.4 18.0 8.5 9.3 77 7.5 February 5, 2002 Depth Tempera ture Dissolved oxygen Specific cond uctance pH (m) (BC) (mg/L ) (OS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 9.0 9.0 7.9 8.0 8.6 10.7 10.5 9.8 11.2 10.9 100 99 101 102 104 7.6 7.5 7.8 7.6 7.5 1.0 9.0 9.0 8.0 8.0 8.6 10.8 10.6 10.6 11.3 11.1 100 99 101 102 104 7.6 7.5 7.8 7.6 7.5 2.0 9.0 9.0 8.0 8.0 8.6 10.8 10.7 11.3 11.4 11.2 100 99 101 102 104 7.6 7.5 7.8 7.6 7.6 3.0 9.0 9.0 7.9 8.0 8.6 10.8 10.8 11.9 11.5 11.4 100 99 101 102 104 7.6 7.5 7.8 7.7 7.6 4.0 9.0 9.0 7.9 8.0 8.6 10.9 10.8 12.1 11.6 11.5 100 99 101 102 104 7.6 7.5 7.7 7.7 7.7 5.0 9.0 9.0 7.9 8.0 11.0 10.9 12.2 11.6 100 99 101 102 7.6 7.6 7.7 7.7 6.0 9.0 9.0 7.9 8.0 11.0 11.0 12.2 11.7 100 99 101 102 7.6 7.6 7.7 7.7 7.0 9.0 9.0 7.9 8.0 11.0 11.0 12.3 11.8 100 99 101 102 7.6 7.6 7.7 7.7 8.0 9.0 9.0 7.9 8.0 11.1 11.0 ND' 11.9 100 99 101 102 7.6 7.6 7.9 7.7 9.0 9.0 9.0 7.9 11.2 11.1 ND 101 99 101 7.5 7.6 7.9 10.0 9.0 9.0 7.9 11.2 11.1 ND 101 99 101 7.5 7.6 7.9 11.0 9.0 9.0 7.9 11.3 11.2 ND 101 99 101 7.5 7.6 7.9 12.0 9.0 9.0 7.9 11.3 11.2 ND 101 99 101 7.5 7.6 7.9 13.0 9.0 9.0 7.9 11.4 11.3 ND 100 99 101 7.5 7.6 7.9 14.0 9.0 9.0 7.9 11.4 11.3 ND 100 99 101 7.5 7.6 7.8 15.0 9.0 8.9 8.2 11.4 11.4 3.1 100 99 115 7.5 7.6 7.7 16.0 9.0 8.9 11.5 11.4 100 99 7.5 7.6 17.0 9.0 8.9 11.5 11.5 100 99 7.5 7.6 18.0 9.0 11.5 100 7.5 Appendix A - 8 Table A-2 (continued) March 14, 2002 Depth Tempera ture Dissolved oxygen Specific conductance pH (m) (BC) (mg/L) (CDS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 13.5 14.6 12.0 11.3 12.0 12.4 12.6 11.5 11.0 11.6 102 105 95 95 98 8.1 8.4 7.7 7.4 7.5 1.0 11.4 13.0 11.9 10.8 11.2 12.6 13.1 11.3 11.0 11.7 97 100 95 94 96 8.2 8.6 7.5 7.3 7.4 2.0 11.1 11.0 11.3 10.2 11.0 12.1 12.0 11.2 10.9 11.6 97 98 94 92 96 7.9 8.0 7.4 7.3 7.4 3.0 11.0 10.5 10.5 10.0 10.9 11.6 11.4 10.8 10.8 11.6 98 98 93 92 96 7.7 7.7 7.4 7.2 7.4 4.0 11.0 10.3 10.4 9.9 11.5 11.2 10.7 10.7 99 98 92 92 7.6 7.5 7.2 7.2 5.0 11.0 10.3 10.2 9.9 11.4 11.0 10.4 10.6 99 99 92 92 7.6 7.4 7.1 7.2 6.0 11.0 10.3 10.1 9.9 11.4 10.9 10.3 10.5 99 98 92 92 7.6 7.4 7.1 7.1 7.0 11.0 10.1 10.0 9.9 11.4 10.7 10.3 10.4 99 100 91 92 7.6 7.4 7.1 7.1 8.0 11.0 10.0 9.8 9.9 11.4 10.7 10.1 10.4 99 99 91 92 7.6 7.4 7.1 7.1 9.0 11.0 9.9 9.4 11.4 10.6 9.8 99 99 90 7.6 7.3 7.1 10.0 10.8 9.7 9.2 11.4 10.5 9.4 99 99 91 7.6 7.3 7.1 11.0 10.5 9.7 9.2 11.1 10.4 9.4 98 98 90 7.6 7.3 7.0 12.0 10.0 9.7 9.2 10.7 10.4 9.3 98 98 90 7.5 7.3 7.0 13.0 9.9 9.7 9.2 10.6 10.3 9.3 98 98 90 7.4 7.3 7.0 14.0 9.7 9.6 9.2 10.4 10.3 9.3 97 98 90 7.4 7.3 7.0 15.0 9.5 9.2 10.0 9.6 97 96 7.3 7.2 16.0 9.4 9.0 9.7 9.2 97 92 7.2 7.2 17.0 9.4 8.9 9.2 9.0 96 92 7.2 7.1 18.0 9.3 9.1 97 7.1 April 11, 2002 Depth Temperature Dissolved oxygen Specific conductance pH (m) (BC) (mg/L) (OS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 17.5 18.5 16.9 15.5 14.3 10.4 10.7 10.7 9.3 9.2 112 114 108 105 102 7.6 8.3 7.8 7.1 7.1 1.0 17.2 17.1 16.7 15.2 14.2 10.4 11.1 10.7 9.3 9.0 111 112 109 105 102 7.8 8.4 7.8 7.0 6.9 2.0 16.8 16.3 15.8 15.0 14.2 10.5 11.4 10.5 9.2 9.0 111 109 106 103 102 7.9 8.4 7.8 7.0 6.9 3.0 16.2 15.8 15.6 14.9 14.2 10.1 10.7 10.3 9.2 9.0 109 109 106 103 102 7.9 7.9 7.6 7.0 6.9 4.0 15.9 15.7 15.5 14.9 9.8 10.2 10.1 9.1 108 107 106 103 7.6 7.7 7.4 6.9 5.0 15.3 15.7 14.9 14.9 9.3 9.7 9.8 9.1 107 108 104 104 7.5 7.5 7.5 6.9 6.0 15.2 15.5 14.4 14.8 8.8 9.3 9.3 9.1 107 108 103 104 7.3 7.4 7.2 6.9 7.0 15.2 15.3 14.2 14.6 8.8 9.1 9.1 9.0 107 106 102 104 7.2 7.3 7.2 7.0 8.0 15.1 15.0 14.0 8.8 8.9 9.0 107 106 102 7.2 7.3 7.1 9.0 14.9 14.8 13.9 8.8 8.8 8.8 106 106 102 7.2 7.3 7.1 10.0 14.8 14.7 13.9 8.7 8.7 8.8 104 105 103 7.2 7.2 7.0 11.0 14.7 14.4 13.9 8.6 8.6 8.8 104 103 102 7.2 7.2 7.0 12.0 14.4 14.1 13.9 8.4 8.4 8.8 104 105 102 7.2 7.2 7.0 13.0 14.2 13.8 13.9 8.3 8.2 8.8 104 103 102 7.1 7.2 7.0 14.0 13.9 13.4 13.9 8.1 7.8 8.8 103 101 102 7.1 7.0 7.0 15.0 13.2 13.0 7.9 7.6 100 101 7.1 7.0 16.0 12.7 12.8 7.5 7.3 100 101 7.0 7.0 17.0 12.3 12.3 6.6 6.7 100 100 6.9 6.9 Appendix A - 9 Table A-2 (continued) May 14, 2002 Depth Temperature Dissolved oxygen Specific conductance pH (m) (HC) (mg/L) ((DS/cm) D2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 22.4 22.8 23.3 22.8 19.0 8.9 9.1 9.8 10.1 9.8 120 120 120 118 106 7.9 7.9 8.3 8.2 7.3 1.0 22.4 22.7 23.3 22.8 18.9 8.9 9.1 9.8 10.3 9.8 120 119 120 118 106 8.1 7.9 8.3 8.4 7.2 2.0 22.4 22.6 23.3 21.8 18.7 8.9 9.0 9.8 9.8 9.8 120 120 120 115 106 8.1 7.9 8.3 8.2 7.2 3.0 22.4 22.5 23.1 21.3 18.6 8.9 8.9 9.6 9.4 9.8 120 120 119 113 105 8.1 7.9 8.2 7.8 7.2 4.0 22.4 22.1 21.9 20.0 8.9 8.6 8.6 8.8 120 118 116 110 8.1 7.7 7.8 7.5 5.0 22.4 22.0 20.1 18.9 8.9 8.3 7.1 8.6 120 118 111 107 8.1 7.6 7.5 7.4 6.0 22.4 21.6 18.9 18.5 8.9 8.1 6.2 8.2 119 118 108 105 8.1 7.5 7.1 7.3 7.0 22.4 21.4 18.2 18.5 8.9 7.8 5.5 8.1 119 117 107 105 8.1 7.4 6.8 6.9 8.0 22.4 20.5 17.9 18.5 8.8 7.0 5.2 8.0 119 116 106 105 8.1 7.2 6.7 6.9 9.0 22.3 19.1 17.9 8.8 5.5 5.1 120 110 106 8.0 7.0 6.7 10.0 22.3 18.3 17.3 8.8 5.2 4.5 119 109 106 8.0 6.8 6.7 11.0 21.7 17.6 17.2 8.1 4.8 4.3 118 107 106 7.7 6.8 6.6 12.0 20.7 17.2 17.1 7.0 4.5 4.0 116 106 106 7.5 6.7 6.6 13.0 18.6 17.1 16.9 5.1 4.3 3.8 110 105 105 7.4 6.7 6.5 14.0 18.2 16.6 16.8 4.9 4.0 3.7 108 103 105 7.1 6.6 6.5 15.0 17.1 16.5 4.4 3.9 106 104 7.0 6.6 16.0 15.8 15.9 3.9 3.5 103 102 6.9 6.6 17.0 15.3 15.0 3.5 2.3 102 103 6.8 6.5 18.0 15.1 15.0 2.9 1.9 101 102 6.6 6.4 June 6, 2002 Depth Temperature Dissolved oxygen Specific conductance pH (m) (HC) (mg/L) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 26.5 27.9 28.5 28.0 21.1 9.9 10.3 10.6 10.9 7.4 136 143 144 141 119 8.0 8.1 7.9 8.1 7.4 1.0 24.6 28.0 28.5 27.9 21.1 10.3 10.3 10.3 10.9 7.3 132 144 144 141 119 8.0 8.2 8.0 8.1 6.8 2.0 24.1 28.0 28.2 27.7 21.1 10.4 10.4 10.7 10.9 7.2 129 144 143 140 119 7.9 8.2 8.0 8.1 6.8 3.0 22.8 27.2 27.6 27.2 21.1 9.9 9.9 10.2 10.2 7.2 126 140 140 137 119 7.7 8.2 8.0 7.9 6.7 4.0 22.4 22.3 27.3 26.8 8.5 7.3 10.2 9.6 124 122 139 136 7.4 7.2 7.9 7.7 5.0 22.0 21.5 26.2 26.6 7.2 6.5 9.3 9.6 122 121 133 134 7.1 7.0 7.5 7.6 6.0 21.6 21.3 23.9 24.0 6.1 6.1 7.8 8.3 121 120 126 128 6.9 6.9 7.2 7.3 7.0 21.4 20.9 22.4 22.6 5.8 5.5 7.2 7.3 122 120 122 123 6.8 6.9 7.0 7.2 8.0 20.9 20.7 21.6 22.4 5.2 5.4 6.2 7.0 120 118 120 122 6.7 6.8 6.9 7.1 9.0 20.7 20.6 19.8 5.1 5.3 4.6 120 119 117 6.7 6.8 6.8 10.0 20.2 20.2 19.7 4.6 5.2 4.3 120 119 117 6.7 6.8 6.7 11.0 20.0 20.1 19.7 4.5 5.1 4.0 119 119 117 6.6 6.7 6.6 12.0 19.8 19.9 19.6 4.5 5.0 3.9 118 118 117 6.6 6.7 6.6 13.0 19.6 19.6 19.5 4.5 4.9 3.9 117 117 117 6.6 6.7 6.6 14.0 19.4 19.4 19.5 4.6 4.9 3.7 117 116 117 6.6 6.7 6.6 15.0 19.2 19.1 19.5 4.6 4.4 2.2 116 116 118 6.6 6.6 6.5 16.0 19.0 19.0 4.7 4.1 116 115 6.5 6.6 17.0 18.8 18.6 3.9 3.3 115 116 6.5 6.6 18.0 18.1 18.3 2.0 0.3 120 154 6.5 6.6 Appendix A - 10 Table A-2 (continued) July 1, 2002 Depth Temperature Dissolved oxygen Specific conductance pH (m) (BC) (mg/L) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 29.5 30.0 30.1 29.8 26.1 10.4 10.3 10.2 10.7 9.0 136 135 134 135 127 9.2 8.7 8.7 8.9 7.3 1.0 28.9 29.3 29.5 29.6 26.0 11.0 10.6 10.5 10.8 8.9 134 133 134 135 127 9.3 9.0 8.9 9.0 7.1 2.0 28.3 29.2 28.8 28.2 25.9 11.7 10.6 10.4 11.1 8.9 132 133 131 132 128 9.3 9.1 8.9 9.0 7.1 3.0 27.9 29.1 28.4 27.5 25.9 11.2 10.5 9.4 9.9 8.9 129 132 126 129 127 9.2 9.1 8.5 8.7 7.1 4.0 27.5 27.2 26.7 26.2 10.0 8.5 7.5 7.5 126 123 124 127 8.9 8.3 8.3 8.2 5.0 26.3 26.3 26.0 25.8 7.0 5.4 5.1 5.8 124 123 124 125 8.5 7.7 7.6 7.8 6.0 25.1 25.1 25.1 25.3 3.0 3.4 4.3 4.5 122 124 124 123 7.3 7.3 7.4 7.3 7.0 24.2 24.3 24.5 24.8 2.0 3.3 4.2 3.8 122 123 123 122 7.3 7.3 7.2 7.2 8.0 23.5 23.5 24.2 23.5 1.4 2.9 4.4 2.8 120 121 123 123 7.1 7.2 7.1 7.1 9.0 23.2 23.0 23.7 1.5 2.6 4.2 119 120 122 6.9 7.1 6.9 10.0 22.8 22.5 23.5 1.0 1.9 3.9 119 119 123 6.8 7.0 6.9 11.0 22.4 22.1 22.8 1.0 1.4 2.3 118 117 124 6.8 6.9 6.8 12.0 22.2 21.7 22.2 1.1 1.1 0.9 117 115 124 6.7 6.8 6.7 13.0 21.8 21.5 21.6 1.0 0.8 0.5 116 114 124 6.7 6.7 6.6 14.0 21.6 21.3 1.0 0.7 114 110 6.7 6.6 15.0 21.2 20.9 0.9 0.6 114 116 6.6 6.6 16.0 21.0 20.6 0.8 0.4 114 123 6.6 6.6 17.0 20.5 20.2 0.8 0.3 115 123 6.6 6.3 18.0 19.6 0.5 127 6.6 August 27, 2002 Depth Temperature Dissolved oxygen Specific conductance pH (m) (BC) (mg/L) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 29.2 29.0 28.6 28.4 26.6 7.6 7.5 7.0 8.4 5.0 131 130 137 141 149 7.6 7.4 7.3 7.3 6.9 1.0 29.2 29.0 28.6 28.4 26.6 7.5 7.5 7.0 8.2 5.0 131 131 138 141 149 7.7 7.5 7.4 7.5 6.9 2.0 29.2 29.0 28.6 28.3 26.6 7.5 7.5 7.0 7.5 5.0 131 131 137 141 150 7.7 7.5 7.4 7.5 6.9 3.0 29.2 29.0 28.4 28.2 26.6 7.4 7.4 6.5 7.2 5.0 131 130 137 141 150 7.7 7.5 7.3 7.4 6.9 4.0 29.2 29.0 28.1 27.5 7.4 7.3 4.3 4.6 131 129 139 145 7.6 7.5 7.2 7.5 5.0 29.2 29.0 27.8 27.4 7.2 7.2 2.8 3.9 131 130 140 146 7.6 7.5 7.0 7.1 6.0 29.1 28.8 27.4 27.3 7.1 5.3 1.6 3.6 130 131 141 146 7.6 7.4 6.9 7.0 7.0 28.9 28.7 27.2 27.2 6.4 4.4 1.0 3.3 130 131 142 147 7.5 7.2 6.8 6.9 8.0 27.7 27.9 26.9 0.3 1.3 0.4 133 132 141 7.0 7.0 6.8 9.0 27.3 27.5 26.6 0.2 0.5 0.2 135 135 141 6.9 6.9 6.7 10.0 26.9 27.0 26.2 0.3 0.3 0.2 136 137 143 6.8 6.8 6.7 11.0 26.4 26.5 26.0 0.2 0.3 0.2 137 139 143 6.8 6.8 6.7 12.0 26.0 26.4 25.6 0.2 0.2 0.2 136 138 147 6.7 6.7 6.7 13.0 25.7 26.0 25.4 0.2 0.3 0.2 136 141 149 6.6 6.7 6.7 14.0 25.4 25.4 25.3 0.2 0.2 0.2 134 143 149 6.6 6.7 6.7 15.0 24.8 25.3 0.2 0.2 135 141 6.6 6.7 16.0 24.3 24.8 0.2 0.2 140 142 6.6 6.7 17.0 24.0 24.3 0.2 0.2 141 150 6.6 6.7 18.0 23.2 0.2 149 6.6 Appendix A - 11 Table A-2 (continued) Sep tember 24, 2002 Depth Temperature Dissolved oxygen Specific conductance pH (m) (BC) (mg/ L) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 26.6 26.4 26.2 26.3 25.4 8.4 7.6 7.0 8.4 5.5 125 125 126 124 150 7.8 7.4 7.5 7.7 7.2 1.0 26.6 26.3 26.2 26.3 25.2 8.3 7.6 6.9 8.4 5.3 125 125 126 125 149 7.9 7.5 7.5 7.8 7.2 2.0 26.5 26.2 26.1 26.3 24.5 8.2 7.1 6.9 8.3 4.7 125 124 125 125 148 7.9 7.5 7.5 7.8 7.2 3.0 26.3 26.1 26.1 26.3 24.5 8.1 6.7 6.9 8.3 4.5 124 123 126 125 147 7.9 7.4 7.5 7.8 7.1 4.0 26.3 26.1 26.0 26.3 7.9 6.6 6.3 8.3 124 125 125 124 7.8 7.4 7.4 7.7 5.0 26.2 26.1 26.0 25.9 7.7 6.3 6.3 6.6 124 125 125 123 7.7 7.3 7.3 7.5 6.0 26.2 26.0 25.9 25.2 7.4 6.2 5.4 3.4 124 125 126 113 7.6 7.3 7.3 7.2 7.0 26.1 26.0 25.8 24.9 7.4 6.0 4.5 2.8 124 126 126 106 7.6 7.3 7.2 7.0 8.0 26.1 26.0 25.4 7.6 6.0 1.9 124 125 129 7.6 7.3 7.0 9.0 26.1 26.0 25.3 7.7 5.8 1.2 124 124 129 7.6 7.3 6.9 10.0 26.0 25.9 25.1 6.9 3.6 0.9 124 125 126 7.5 7.2 6.8 11.0 25.8 25.8 24.9 3.8 3.0 1.0 125 125 120 7.3 7.0 6.8 12.0 25.2 25.1 24.8 0.3 0.4 1.1 128 128 115 7.0 6.9 6.7 13.0 24.9 24.7 24.3 0.3 0.2 1.5 129 127 100 6.8 6.8 6.8 14.0 24.4 24.4 24.0 0.2 0.3 1.3 127 122 92 6.8 6.8 6.7 15.0 24.0 24.2 23.9 0.2 0.9 0.7 121 111 96 6.8 6.7 6.6 16.0 23.7 23.8 0.2 0.2 118 120 6.7 6.8 17.0 23.2 23.2 0.2 0.2 120 128 6.7 6.8 October 29, 2002 Depth Temperature Dissolved oxygen Specific conductance pH (m) (BC) (mg/L ) ( (DS/cm ) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 19.5 19.4 18.6 18.4 19.1 6.4 6.7 8.0 7.2 6.8 102 103 126 124 131 7.2 7.1 7.0 7.1 7.0 1.0 19.5 19.5 18.8 18.4 19.1 6.4 6.5 7.0 7.1 6.8 102 103 127 124 131 7.1 7.1 7.0 7.0 7.0 2.0 19.6 19.5 18.8 18.5 19.1 6.4 6.5 6.9 7.1 6.8 102 103 127 124 131 7.0 7.0 7.0 7.0 6.9 3.0 19.6 19.5 18.8 18.5 19.1 6.4 6.4 6.8 7.1 6.8 102 103 127 124 131 7.0 7.0 7.0 7.0 6.9 4.0 19.6 19.5 18.8 18.5 6.4 6.4 6.8 7.1 102 104 127 124 7.0 7.0 6.9 6.9 5.0 19.6 19.5 18.8 18.5 6.4 6.4 6.8 7.1 102 104 127 124 7.0 6.9 6.9 6.9 6.0 19.6 19.5 18.8 18.5 6.4 6.4 6.8 7.1 102 105 127 124 6.9 6.9 6.9 6.9 7.0 19.6 19.5 18.8 18.5 6.4 6.4 6.8 7.0 101 104 127 122 6.9 6.9 6.9 6.9 8.0 19.6 19.5 18.8 18.5 6.4 6.4 6.8 7.0 102 102 127 124 7.0 7.0 6.9 6.9 9.0 19.6 19.5 18.8 6.4 6.4 6.8 102 104 127 6.9 6.9 6.9 10.0 19.6 19.5 18.8 6.4 6.4 6.8 102 104 127 6.9 6.9 6.9 11.0 19.6 19.5 18.8 6.4 6.4 6.8 102 104 127 6.9 6.9 6.9 12.0 19.5 19.5 18.8 6.4 6.4 6.8 102 104 127 6.9 6.9 6.9 13.0 19.5 19.4 18.8 6.4 6.3 6.8 102 111 127 6.9 6.9 6.9 14.0 19.5 19.2 18.8 6.3 6.1 6.8 104 118 79 6.9 6.8 7.4 15.0 19.5 19.1 6.3 5.6 104 123 6.9 6.8 16.0 19.4 19.1 6.1 5.5 110 123 6.8 6.8 17.0 19.4 19.1 5.9 0.2 113 123 6.8 6.8 18.0 19.4 19.1 5.6 0.2 117 142 6.8 6.8 Appendix A - 12 Table A-2 (continued) November 19, 2002 Depth Temperature Dissolved oxygen Specific conductance pH (m) (HC) (mg/L ) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 16.8 15.2 13.7 14.1 14.3 8.5 8.7 9.4 9.4 8.2 105 102 91 97 99 7.4 7.3 7.7 7.6 7.5 1.0 16.4 15.2 13.8 14.0 14.3 8.4 8.5 9.3 8.8 8.0 103 102 91 98 99 7.4 7.3 7.6 7.5 7.2 2.0 16.2 14.9 13.8 13.9 14.3 8.1 8.5 9.3 8.8 8.0 103 100 91 97 99 7.2 7.3 7.5 7.4 7.0 3.0 16.2 14.8 13.8 13.9 14.3 8.1 8.6 9.3 8.7 8.0 103 99 91 99 99 7.2 7.3 7.4 7.3 7.0 4.0 16.2 14.7 13.8 13.7 8.1 8.6 9.3 8.8 103 99 92 96 7.2 7.2 7.4 7.3 5.0 16.2 14.6 13.8 13.5 8.0 8.6 9.3 9.1 103 99 92 92 7.2 7.2 7.3 7.3 6.0 16.2 14.6 13.8 13.5 8.0 8.6 9.3 9.0 103 100 91 96 7.1 7.2 7.3 7.2 7.0 16.2 14.5 13.8 13.3 8.0 8.5 9.3 9.3 103 98 91 91 7.1 7.1 7.2 7.1 8.0 16.2 14.2 13.8 13.3 8.0 8.5 9.3 9.4 104 99 91 90 7.1 7.1 7.2 7.1 9.0 16.2 14.2 13.8 8.0 8.5 9.2 104 97 92 7.1 7.1 7.1 10.0 16.1 14.1 13.8 8.0 8.5 9.3 104 96 91 7.1 7.1 7.1 11.0 16.1 14.1 13.8 8.0 8.5 9.3 104 96 92 7.1 7.0 7.1 12.0 16.1 14.0 13.8 8.0 8.5 9.2 104 95 91 7.1 7.0 7.1 13.0 16.1 14.0 13.8 8.0 8.7 9.3 104 94 91 7.1 7.0 7.1 14.0 16.0 14.0 13.8 8.0 8.7 9.3 104 92 79 7.1 7.0 7.4 15.0 16.0 14.0 8.1 8.7 103 94 7.1 7.0 16.0 16.0 14.0 8.1 8.7 103 94 7.1 7.0 17.0 16.0 14.0 8.1 8.7 103 94 7.0 7.0 18.0 16.0 8.0 103 7.0 December 18, 2002 Depth Temperature Dissolved oxygen Specific conductance pH (m) (HC) (mg/L ) ((DS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 8.4 8.9 7.7 7.4 7.3 9.6 10.2 10.5 11.3 10.6 70 72 72 71 73 7.0 7.1 7.2 7.1 7.0 1.0 8.3 8.4 7.6 7.3 7.4 9.6 9.6 10.4 11.3 10.5 70 71 72 71 73 7.0 7.0 7.1 7.1 7.0 2.0 8.3 8.2 7.5 7.3 7.4 9.6 9.5 10.4 11.2 10.5 70 70 72 71 73 6.9 7.0 7.1 7.0 7.0 3.0 8.2 8.1 7.4 7.3 7.4 9.5 9.5 10.4 11.1 10.5 70 68 72 71 73 6.9 7.0 7.1 7.0 7.0 4.0 8.2 8.0 7.4 7.3 9.5 9.7 10.4 11.1 70 67 72 71 6.9 6.9 7.0 7.0 5.0 8.2 8.0 7.3 7.3 9.5 9.8 10.5 11.1 70 67 72 71 6.9 6.9 7.0 7.0 6.0 8.2 7.9 7.3 7.3 9.5 9.8 10.5 11.0 70 67 72 71 6.9 6.9 7.0 7.0 7.0 8.2 7.9 7.2 7.3 9.5 10.4 10.5 10.9 70 70 72 71 6.9 6.9 7.0 7.0 8.0 8.2 7.9 7.2 7.3 9.5 10.8 10.4 10.9 70 72 72 71 6.9 6.9 7.0 7.0 9.0 8.2 7.9 7.1 9.5 11.1 10.4 70 71 72 6.9 6.9 7.0 10.0 8.2 7.9 7.1 9.5 11.3 10.4 70 70 72 6.9 6.9 7.0 11.0 8.2 7.8 7.1 9.5 11.4 10.4 70 70 72 6.9 6.9 7.0 12.0 8.2 7.8 7.1 9.5 11.4 10.5 70 70 72 6.9 6.9 7.0 13.0 8.2 7.8 7.1 9.5 11.4 10.5 70 70 72 6.9 6.9 7.0 14.0 8.2 7.8 7.4 9.5 11.5 10.5 70 70 79 6.9 6.9 7.4 15.0 8.2 7.8 9.5 11.5 70 71 6.9 6.9 16.0 8.1 7.8 9.6 11.5 68 70 6.9 6.9 17.0 8.1 7.8 9.6 9.7 67 71 6.9 6.9 18.0 8.1 9.6 68 6.9 Appendix A - 13 Table A-2 (continued) Secchi disk transparency depth (m) Date TYB2 TYD2 TYF2 TYH2 TYK2 January 15, 2002 2.2 1.8 2.5 2.3 2.2 February 5, 2002 0.9 1.0 1.2 1.5 1.2 March 14, 2002 1.3 1.4 1.3 1.2 1.3 April 11, 2002 1.7 1.3 1.4 1.5 1.4 May 14, 2002 1.9 1.4 1.3 1.1 1.7 June 6, 2002 1.5 1.3 1.5 1.4 3.0' July 1, 2002 2.1 2.0 1.6 1.5 1.9 August 27, 2002 2.7 3.0 2.1 1.5 1.6 September 24, 2002 2.8 2.7 1.8 1.3 3.0' October 29, 2002 1.7 2.3 1.8 1.6 2.3 November 14, 2002 2.1 1.2 0.7 1.0 1.0 December 18, 2002 1.0 1.1 1.2 1.1 1.2 Missing data due to either measurements were not obtained during sampling or because the Secchi disk was observed on river or lake bottom during sampling. In such instances, the depth of the lake bottom is listed as a reference to Secchi depth. Appendix A - 14 Table A-3 Water temperature, dissolved oxygen, specific conductance, and pH data collected from Lake Tillery (Stations TYB2, TYD2, TYF2, TYH2, and TYK2) during 2004. January 19, 2004 Depth Temperature Dissolved oxygen Specific conductance pH B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 6.5 6.5 6.5 6.3 6.6 11.8 11.6 11.8 12.3 12.5 85 86 87 91 87 7.4 7.4 7.4 7.5 7.4 1.0 6.5 6.5 6.5 6.2 6.6 11.8 11.6 11.8 12.3 12.3 85 86 87 91 87 7.4 7.4 7.4 7.5 7.3 2.0 6.5 6.5 6.5 5.8 6.6 11.8 11.6 11.8 12.5 12.3 85 87 87 93 87 7.4 7.4 7.4 7.6 7.3 3.0 6.5 6.5 6.5 5.8 6.6 11.8 11.6 11.8 12.5 12.3 85 87 87 93 87 7.4 7.4 7.4 7.6 7.3 4.0 6.5 6.4 6.5 5.8 11.8 11.6 11.8 12.5 86 87 87 93 7.4 7.3 7.4 7.6 5.0 6.5 6.4 6.5 5.8 11.8 11.6 11.8 12.5 86 87 87 93 7.4 7.3 7.4 7.5 6.0 6.5 6.4 6.4 5.8 11.8 11.6 11.8 12.5 86 87 87 93 7.4 7.3 7.4 7.5 7.0 6.5 6.4 6.4 5.8 11.8 11.6 11.8 12.5 86 87 87 93 7.4 7.3 7.4 7.5 8.0 6.5 6.4 6.4 5.8 11.7 11.6 11.8 12.5 86 87 87 93 7.3 7.3 7.4 7.5 9.0 6.5 6.4 6.4 11.7 11.6 11.8 86 87 87 7.3 7.3 7.4 10.0 6.5 6.4 6.4 11.7 11.6 11.8 86 87 87 7.3 7.3 7.4 11.0 6.5 6.4 6.4 11.7 11.6 11.8 86 87 87 7.3 7.3 7.4 12.0 6.5 6.4 6.4 11.7 11.5 11.7 86 87 87 7.3 7.3 7.4 13.0 6.5 6.4 6.4 11.7 11.5 11.7 86 87 88 7.3 7.3 7.4 14.0 6.5 6.4 6.4 11.7 11.5 11.7 86 87 88 7.3 7.3 7.4 15.0 6.5 6.4 6.4 11.7 11.5 11.7 86 87 88 7.3 7.3 7.4 16.0 6.5 6.4 11.7 11.5 86 87 7.3 7.3 17.0 6.6 6.4 8.4 11.5 86 87 6.8 7.3 February 23, 2004 Depth Temperature Dissolved oxygen Specific conductance pH B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 1.0 6.1 6.1 6.3 6.0 5.5 12.4 12.2 11.9 11.9 12.1 95 95 93 93 91 7.8 7.6 7.5 7.4 7.4 2.0 6.1 6.2 6.3 5.9 5.5 12.3 12.1 11.8 11.8 12.0 95 95 93 93 91 7.8 7.6 7.5 7.4 7.3 3.0 6.1 6.1 6.3 5.8 5.5 12.2 12.1 11.8 11.8 12.0 94 97 93 91 91 7.8 7.6 7.5 7.4 7.3 4.0 6.0 6.0 6.6 5.8 12.1 12.1 11.7 11.8 96 97 93 92 7.7 7.6 7.4 7.4 5.0 6.0 6.0 6.4 5.7 12.1 12.0 11.8 11.8 94 93 93 92 7.7 7.6 7.4 7.4 6.0 5.9 5.9 6.4 5.7 12.0 12.0 11.8 11.7 94 99 93 92 7.7 7.5 7.4 7.4 7.0 5.9 5.9 6.2 5.7 11.9 11.9 11.8 11.7 98 94 94 92 7.6 7.5 7.4 7.4 8.0 5.9 5.9 6.3 11.9 11.9 11.7 96 96 92 7.6 7.5 7.4 9.0 5.9 5.9 6.3 11.8 11.9 11.7 95 96 93 7.6 7.5 7.4 10.0 5.9 5.9 6.3 11.8 11.9 11.7 98 93 92 7.6 7.5 7.4 11.0 5.9 5.9 6.3 11.8 11.9 11.7 95 96 92 7.6 7.5 7.4 12.0 5.9 5.9 6.3 11.8 11.9 11.7 96 98 93 7.6 7.5 7.4 13.0 5.9 5.8 6.2 11.7 11.9 11.7 96 98 94 7.5 7.5 7.4 14.0 5.9 5.8 6.2 11.7 11.8 11.7 96 96 94 7.5 7.5 7.4 15.0 5.9 5.8 6.2 11.6 11.8 11.7 99 98 94 7.5 7.5 7.3 16.0 5.9 5.8 11.7 11.8 98 98 7.5 7.5 17.0 5.9 5.8 11.7 11.7 95 95 7.5 7.4 Appendix A - 15 Table A-3 (continued) March 17, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) (° C) (mg/L) ( µS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 10.6 10.6 10.1 9.4 9.0 12.2 11.7 12.2 11.1 12.1 90 52 95 94 95 8.3 7.5 7.8 7.4 7.6 1.0 10.6 10.4 10.1 9.3 9.0 12.3 11.7 12.2 11.4 12.0 90 86 95 94 95 8.1 7.5 7.7 7.5 7.5 2.0 10.6 10.2 10.0 9.3 9.0 12.3 11.7 12.2 11.4 11.9 90 92 95 94 95 8.1 7.5 7.7 7.5 7.5 3.0 10.5 9.9 10.0 9.2 9.0 12.3 11.5 12.1 11.4 11.9 90 91 94 94 92 8.1 7.5 7.7 7.5 7.5 4.0 10.3 9.8 10.0 9.2 12.2 11.5 12.0 11.4 90 91 94 89 8.0 7.5 7.7 7.5 5.0 10.2 9.6 9.9 9.2 12.1 11.4 12.0 11.4 89 92 94 95 8.0 7.5 7.7 7.5 6.0 10.1 9.5 9.9 9.2 12.0 11.3 11.8 11.3 91 91 86 95 8.0 7.5 7.6 7.5 7.0 10.1 9.4 9.9 9.2 11.9 11.2 11.9 11.4 89 90 96 93 8.0 7.5 7.6 7.5 8.0 9.6 9.3 9.8 9.2 11.8 11.1 11.9 11.3 92 90 96 95 7.9 7.5 7.6 7.5 9.0 9.3 9.1 9.9 11.6 11.1 11.9 90 90 93 7.9 7.5 7.6 10.0 9.1 9.0 9.7 11.4 11.0 11.9 89 86 95 7.9 7.5 7.5 11.0 8.9 8.9 9.7 11.3 11.0 11.8 91 91 96 7.8 7.5 7.5 12.0 8.9 8.8 9.5 11.2 10.9 11.8 90 91 94 7.8 7.5 7.5 13.0 8.7 8.7 9.4 11.1 10.8 11.7 90 93 94 7.7 7.6 7.5 14.0 8.7 8.6 9.4 11.0 10.8 11.7 93 92 94 7.7 7.6 7.5 15.0 8.7 8.5 9.4 11.0 10.7 11.6 92 91 95 7.7 7.6 7.5 16.0 8.7 8.5 10.9 10.8 90 92 7.7 7.6 April 6, 2004 Depth Temperature Dissolved oxygen Specific conductance pH 0.2 13.1 12.2 12.6 12.5 12.5 11.0 10.6 10.5 10.7 11.6 94 96 99 98 98 8.2 7.7 7.7 7.6 7.7 1.0 13.1 12.2 12.5 12.3 12.4 11.0 10.6 10.5 10.7 11.5 94 95 98 98 99 8.2 7.7 7.7 7.6 7.7 2.0 13.1 12.2 12.4 12.1 12.4 11.0 10.5 10.4 10.7 11.5 94 96 96 98 98 8.2 7.7 7.6 7.6 7.6 3.0 13.1 12.2 12.3 12.1 12.4 11.0 10.5 10.4 10.7 11.4 95 95 97 98 98 8.1 7.6 7.6 7.6 7.6 4.0 13.1 12.2 12.3 12.1 11.0 10.5 10.3 10.6 95 95 98 98 8.1 7.6 7.6 7.6 5.0 13.1 12.2 12.2 12.1 10.9 10.5 10.3 10.6 93 95 98 97 8.1 7.6 7.6 7.6 6.0 13.1 12.2 12.1 12.0 10.9 10.5 10.2 10.6 93 95 96 97 8.0 7.6 7.6 7.6 7.0 13.1 12.2 11.9 12.0 11.0 10.5 10.1 10.6 95 95 98 99 8.0 7.6 7.5 7.6 8.0 13.1 12.2 11.6 12.0 11.0 10.5 9.9 10.6 95 95 95 99 8.0 7.6 7.5 7.6 9.0 13.1 12.2 11.3 11.0 10.5 9.8 94 97 95 8.0 7.6 7.5 10.0 13.1 12.2 11.1 10.9 10.5 9.6 94 97 97 8.0 7.6 7.4 11.0 12.9 12.1 11.1 10.9 10.4 9.5 94 95 94 7.9 7.6 7.4 12.0 12.5 12.1 11.1 10.5 10.3 9.5 94 94 97 7.9 7.6 7.4 13.0 12.3 12.1 11.1 10.3 10.3 9.4 95 95 97 7.8 7.6 7.3 14.0 12.2 11.8 11.0 10.2 10.1 9.3 94 93 94 7.8 7.5 7.3 15.0 11.9 11.7 10.8 9.9 9.8 9.2 95 95 93 7.7 7.5 7.3 16.0 11.7 11.1 9.7 9.7 94 95 7.6 7.5 17.0 11.5 10.9 9.7 9.4 95 94 7.6 7.3 18.0 11.4 9.5 93 7.5 Appendix A - 16 Table A-3 (continued) May 11, 2004 Depth Tempera ture Dissolved oxygen Specific conductance pH (m) (° C) (mg/L) ( µS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 25.2 26.0 25.8 22.6 18.5 10.8 9.8 11.4 9.7 8.5 93 93 93 93 94 8.8 9.0 9.1 7.7 7.2 1.0 25.0 26.0 25.6 22.2 18.5 10.9 10.9 11.3 9.8 8.1 93 93 93 93 95 8.8 9.1 9.0 7.6 7.2 2.0 23.1 25.4 24.9 21.2 18.5 11.2 11.2 11.2 9.3 8.1 92 93 92 94 95 8.6 9.0 8.8 7.5 7.1 3.0 21.8 20.1 23.7 20.4 11.1 9.0 10.7 8.8 92 92 91 93 8.2 8.0 8.3 7.4 4.0 20.7 19.7 21.5 19.3 10.9 8.1 10.5 8.6 92 92 92 94 7.9 7.6 8.0 7.3 5.0 20.3 19.0 20.5 19.2 10.8 8.0 8.8 8.3 92 93 93 93 8.2 7.9 7.6 7.3 6.0 19.6 18.3 19.7 19.2 10.5 7.6 8.3 8.1 93 92 93 93 8.1 7.7 7.4 7.2 7.0 19.3 18.2 19.7 19.1 9.3 7.4 8.1 8.2 92 92 92 94 7.9 7.6 7.3 7.2 8.0 18.9 18.0 19.6 19.1 8.1 7.3 8.1 8.0 93 92 93 94 7.6 7.5 7.2 7.1 9.0 18.5 17.9 19.5 7.8 7.3 8.0 91 93 93 7.5 7.6 7.1 10.0 18.2 17.8 19.2 7.2 7.3 7.9 92 93 93 7.3 7.4 7.1 11.0 17.9 17.6 19.1 7.1 7.3 7.7 91 92 92 7.3 7.3 7.1 12.0 17.7 17.4 18.4 7.2 7.3 7.4 92 92 94 7.1 7.2 7.0 13.0 17.6 17.3 18.3 7.2 7.2 7.1 92 93 93 7.1 7.1 7.0 14.0 17.4 16.9 18.2 7.3 6.8 6.8 92 92 93 7.1 7.1 7.0 15.0 17.0 16.5 7.2 6.6 92 93 7.1 7.0 16.0 16.8 15.8 7.1 5.6 93 95 7.1 7.0 17.0 16.5 15.6 6.8 4.8 93 96 7.0 6.9 18.0 16.2 6.4 94 7.0 June 22, 2004 Depth Tempera ture Dissolved oxygen Specific conductance pH 0.2 27.8 28.0 27.5 26.2 24.2 13.8 14.1 14.4 14.5 7.2 92 92 94 98 101 8.7 8.5 8.1 7.6 7.0 1.0 27.8 28.0 27.5 26.1 24.2 13.8 14.2 14.4 14.3 7.0 92 92 94 99 102 8.6 8.5 8.0 7.4 6.9 2.0 27.8 28.0 27.5 25.5 24.2 13.6 14.0 14.2 13.4 7.0 92 91 92 98 101 8.5 8.2 7.9 7.2 6.8 3.0 27.7 28.0 27.4 24.2 13.4 13.1 13.9 9.9 92 90 93 101 8.2 7.9 7.7 6.9 4.0 27.1 27.8 26.4 24.2 9.8 12.6 11.5 8.8 94 92 96 101 7.9 7.7 7.3 6.7 5.0 26.3 27.2 26.0 24.1 6.7 11.7 10.3 8.4 94 92 97 101 6.9 7.5 7.1 6.6 6.0 25.0 24.7 25.5 24.1 5.7 6.7 9.3 8.2 96 98 98 101 6.8 7.0 6.9 6.6 7.0 24.3 24.3 25.0 24.1 4.8 6.0 8.0 8.1 97 97 99 101 6.8 6.9 6.7 6.6 8.0 24.0 23.8 24.7 24.1 4.4 5.5 7.6 8.0 97 99 100 100 6.5 6.9 6.6 6.6 9.0 23.8 23.7 24.6 4.1 5.2 7.1 98 101 100 6.5 6.9 6.6 10.0 23.7 23.3 24.5 3.7 4.9 6.9 96 100 102 6.4 6.7 6.6 11.0 23.3 23.2 24.4 3.3 4.4 6.4 100 98 100 6.4 6.6 6.5 12.0 23.1 23.0 24.4 3.3 3.6 6.4 97 99 99 6.4 6.6 6.5 13.0 22.9 22.9 24.2 3.2 3.4 5.8 98 97 101 6.3 6.4 6.5 14.0 22.5 22.5 24.1 2.5 3.1 5.2 98 99 102 6.5 6.4 6.5 15.0 22.3 22.1 24.1 2.3 2.4 5.0 99 99 101 6.3 6.3 6.5 16.0 21.9 21.8 2.1 1.7 100 101 6.3 6.4 17.0 21.4 21.3 1.3 1.6 99 105 6.3 6.3 18.0 20.3 0.7 108 6.3 Appendix A - 17 Table A-3 (continued) July 13, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) (° C) (mg/L) ( µS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 Q2 30.6 31.1 31.1 29.9 26.8 9.1 9.2 10.0 9.6 4.8 93 93 96 98 98 8.8 8.8 8.9 8.4 7.4 1.0 29.4 30.2 31.0 29.4 26.8 9.3 9.0 9.9 8.8 4.7 93 92 96 97 98 8.7 8.7 8.9 7.5 7.2 2.0 29.1 29.9 30.8 28.6 26.8 9.5 8.0 9.6 7.8 4.7 93 92 95 99 98 8.7 8.3 8.8 7.2 7.1 3.0 28.6 29.8 30.1 27.8 26.8 8.6 7.1 9.0 5.9 4.7 92 90 94 99 98 8.4 7.9 8.6 7.0 7.0 4.0 28.2 28.0 29.5 27.1 6.0 4.5 7.2 4.9 94 96 96 99 7.8 7.6 7.8 7.0 5.0 27.4 27.1 28.4 27.1 3.8 3.4 5.3 4.8 96 99 98 99 7.4 7.3 7.5 7.0 6.0 27.0 26.3 27.6 27.0 2.8 2.3 4.2 4.8 98 99 99 99 7.2 7.1 7.2 7.1 7.0 26.9 26.1 26.9 27.0 2.4 1.9 2.9 4.8 98 100 100 99 7.1 6.9 7.0 7.1 8.0 26.6 26.1 26.6 27.0 2.1 1.8 2.3 4.9 98 100 101 99 7.0 6.8 6.9 7.4 9.0 26.5 25.9 26.2 1.8 1.9 1.8 98 99 101 6.9 7.1 6.8 10.0 26.3 25.8 26.0 1.8 1.7 1.6 99 99 102 6.9 6.9 6.8 11.0 26.0 25.6 25.7 1.6 1.6 1.3 99 100 102 6.8 7.1 6.7 12.0 25.8 25.5 25.6 1.5 1.5 1.2 99 100 103 6.8 6.9 6.7 13.0 25.6 25.3 25.6 1.6 1.5 1.1 99 100 103 6.8 6.7 6.7 14.0 25.4 25.1 25.4 1.2 0.4 0.9 100 146 104 6.7 6.9 6.7 15.0 25.2 1.1 100 6.7 16.0 25.0 1.1 100 6.7 17.0 24.6 0.5 102 6.7 18.0 24.1 0.1 108 6.7 Aug ust 24, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) C C) (mg/L) (µS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 29.3 30.4 29.5 29.4 26.9 10.2 10.0 11.4 10.4 7.3 98 99 99 100 100 8.7 8.8 9.0 8.3 7.2 1.0 27.9 28.8 29.1 29.0 26.9 10.6 10.6 11.5 9.2 7.0 98 98 99 99 100 8.8 8.9 9.0 7.8 7.1 2.0 27.6 28.3 28.1 27.4 26.8 10.2 10.8 11.1 8.5 6.9 98 98 99 99 100 8.8 9.0 8.9 7.7 7.1 3.0 27.4 27.7 27.9 26.9 26.8 9.6 9.2 9.5 6.6 6.9 98 97 98 100 100 8.7 8.6 8.6 7.6 7.0 4.0 27.4 27.4 27.7 26.8 9.0 8.2 7.8 5.9 97 97 98 100 8.5 8.3 8.1 7.4 5.0 27.3 27.4 27.4 26.8 8.5 8.0 6.1 5.4 97 97 98 100 8.3 8.3 7.7 7.1 6.0 27.3 27.2 27.0 26.6 8.0 7.3 4.9 5.1 97 97 99 100 8.1 8.2 7.5 7.1 7.0 27.2 26.9 26.6 26.5 6.7 5.4 3.7 4.9 97 98 99 101 7.9 8.0 7.3 7.1 8.0 27.0 26.7 26.4 26.2 4.6 4.6 3.2 2.1 98 97 99 104 7.7 8.0 7.2 6.9 9.0 26.4 26.5 26.3 2.8 3.4 3.0 97 97 99 7.8 7.9 7.1 10.0 26.3 26.4 26.2 2.8 3.0 2.8 96 97 100 7.6 7.7 7.0 11.0 26.1 26.2 26.1 2.4 2.8 2.5 97 97 100 7.4 7.7 7.0 12.0 26.0 26.0 26.1 2.5 2.7 2.4 97 97 100 7.3 7.6 6.9 13.0 25.8 26.0 26.0 2.4 2.3 1.8 97 98 102 7.2 7.3 6.9 14.0 25.6 25.9 25.9 2.3 2.2 1.4 97 99 103 7.1 7.2 6.9 15.0 25.6 25.6 25.8 1.9 1.1 1.0 98 101 105 7.0 7.1 6.8 16.0 25.5 25.6 1.7 1.0 98 102 7.0 7.1 17.0 25.4 25.4 1.0 0.7 101 106 6.9 7.0 18.0 25.3 0.2 107 6.8 Appendix A - 18 Table A-3 (continued) September 21, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) (° C) (mg/L) (µS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 24.3 24.1 23.7 23.7 23.5 7.0 6.4 6.5 6.5 7.0 96 91 87 84 84 7.6 7.1 7.2 7.0 7.1 1.0 24.3 24.1 23.6 23.6 23.5 6.6 6.2 6.5 6.5 6.9 96 91 87 84 84 7.4 7.1 7.2 7.0 7.0 2.0 24.1 23.8 23.3 23.6 23.5 6.5 5.8 6.3 6.5 6.9 95 91 87 84 84 7.4 7.1 7.2 7.0 7.0 3.0 24.0 23.8 23.2 23.6 23.5 6.2 5.8 6.1 6.5 6.9 95 91 87 84 84 7.3 7.1 7.1 7.0 7.0 4.0 24.0 23.7 23.1 23.6 6.0 5.9 6.0 6.5 95 90 87 84 7.3 7.1 7.1 7.0 5.0 24.0 23.7 23.1 23.6 5.9 6.1 5.9 6.4 95 91 87 84 7.3 7.1 7.1 7.0 6.0 23.9 23.7 23.1 23.3 5.9 6.1 5.9 6.1 96 91 87 84 7.2 7.1 7.1 7.0 7.0 23.9 23.7 23.1 23.2 5.9 6.1 5.9 6.0 96 91 87 84 7.2 7.1 7.0 7.0 8.0 23.9 23.7 23.1 22.8 5.9 6.0 5.9 5.8 96 91 87 85 7.2 7.1 7.0 7.1 9.0 23.9 23.6 23.1 5.9 5.9 5.9 96 90 87 7.2 7.1 7.0 10.0 23.9 23.6 23.1 5.9 5.6 5.9 96 89 87 7.2 7.0 7.0 11.0 23.9 23.5 23.0 5.9 5.6 5.9 96 89 87 7.2 7.0 7.0 12.0 23.9 23.5 23.0 5.9 5.5 5.9 96 89 87 7.2 7.0 7.0 13.0 23.9 23.5 23.1 5.9 5.4 5.9 96 90 87 7.2 7.0 7.0 14.0 23.9 23.4 23.0 5.9 5.2 5.8 96 89 87 7.2 7.0 7.0 15.0 23.9 23.3 23.0 5.9 5.1 5.8 96 89 88 7.2 7.0 7.0 16.0 23.8 23.3 6.0 5.1 96 89 7.2 7.0 17.0 23.7 23.3 5.9 5.0 96 88 7.1 7.0 18.0 23.7 5.8 96 7.0 October 19, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) C C) (mg/L) (µS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 21.4 21.4 21.0 20.9 20.5 7.0 7.6 7.3 6.3 6.4 78 76 74 75 76 7.3 7.0 7.2 6.8 6.8 1.0 21.3 21.4 20.9 20.9 20.5 7.0 7.6 7.0 6.3 6.4 78 76 74 75 76 7.3 7.0 7.1 6.8 6.8 2.0 21.2 21.4 20.8 20.9 20.5 6.9 7.5 6.8 6.2 6.3 78 76 74 75 76 7.2 7.0 7.0 6.8 6.8 3.0 21.1 21.3 20.6 20.8 20.5 6.7 7.5 6.1 6.2 6.3 78 76 74 75 76 7.2 7.0 7.0 6.8 6.8 4.0 21.0 21.3 20.6 20.7 6.6 7.4 6.1 6.1 78 76 74 75 7.2 7.0 6.9 6.8 5.0 21.0 21.3 20.6 20.5 6.6 7.4 6.0 6.2 78 76 74 75 7.1 7.0 6.9 6.8 6.0 21.0 21.3 20.5 20.5 6.6 7.3 5.9 6.2 78 76 74 75 7.1 7.0 6.9 6.8 7.0 21.0 21.3 20.5 20.4 6.5 7.2 5.8 6.2 77 76 74 75 7.1 6.9 6.8 6.7 8.0 21.0 21.2 20.4 20.4 6.3 6.8 5.7 6.2 77 76 74 75 7.0 6.9 6.8 6.7 9.0 20.9 21.2 20.4 6.2 6.6 5.7 77 76 74 7.0 6.9 6.8 10.0 20.8 21.1 20.4 5.9 6.0 5.7 76 75 74 7.0 6.8 6.8 11.0 20.8 20.6 20.3 5.7 5.8 5.6 75 74 74 6.9 6.8 6.8 12.0 20.8 20.3 20.3 5.6 5.7 5.5 75 74 74 6.9 6.8 6.7 13.0 20.8 20.3 20.3 5.5 5.7 5.5 75 74 74 6.9 6.9 6.7 14.0 20.8 20.3 20.3 5.5 5.7 5.5 75 74 74 6.9 6.9 6.7 15.0 20.7 20.3 20.3 5.5 5.7 5.5 75 74 74 6.9 6.9 6.7 16.0 20.7 20.3 5.5 5.6 75 74 6.8 6.9 17.0 20.7 20.3 5.5 5.4 75 74 6.8 6.9 18.0 20.7 5.5 75 6.8 Appendix A - 19 Table A-3 (continued) November 17, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) (° C) (mg/L) (µ S/cm ) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 16.6 16.4 15.1 15.9 16.3 7.4 7.8 8.5 8.3 8.1 85 86 92 90 89 7.1 6.8 6.8 6.7 6.6 1.0 16.6 16.4 15.0 15.8 16.3 7.2 7.7 8.2 8.2 8.1 85 86 92 90 89 7.1 6.8 6.7 6.6 6.6 2.0 16.6 16.4 14.9 15.7 16.3 7.2 7.7 8.2 8.1 8.0 85 86 92 90 89 7.0 6.8 6.7 6.6 6.6 3.0 16.6 16.4 14.9 15.4 16.3 7.2 7.7 8.2 8.0 8.0 85 86 92 90 89 7.0 6.8 6.7 6.6 6.6 4.0 16.6 16.3 14.8 15.4 7.2 7.6 8.1 7.9 85 86 92 90 7.0 6.8 6.6 6.6 5.0 16.6 16.2 14.8 15.0 7.2 7.5 8.0 7.9 85 86 92 92 7.0 6.7 6.6 6.5 6.0 16.6 16.2 14.8 14.7 7.2 7.5 8.0 7.8 85 86 92 92 7.0 6.7 6.6 6.5 7.0 16.6 16.2 14.8 14.0 7.1 7.5 8.0 7.6 85 86 92 96 6.9 6.7 6.6 6.5 8.0 16.6 16.2 14.8 14.0 7.1 7.5 8.0 7.5 85 86 92 96 6.9 6.7 6.6 6.4 9.0 16.6 16.1 14.8 7.1 7.5 8.0 85 86 92 6.9 6.7 6.6 10.0 16.6 16.1 14.8 7.1 7.5 8.0 85 86 92 6.9 6.7 6.6 11.0 16.6 16.0 14.8 7.1 7.4 8.0 85 87 92 6.8 6.7 6.6 12.0 16.6 16.0 14.8 7.1 7.4 8.0 85 87 92 6.8 6.7 6.6 13.0 16.6 16.0 14.8 7.1 7.4 8.0 85 87 92 6.8 6.7 6.6 14.0 16.6 15.9 14.8 7.1 7.4 8.0 85 87 92 6.8 6.7 6.6 15.0 16.5 15.8 14.8 7.0 7.4 7.9 85 87 92 6.8 6.6 6.6 16.0 16.5 15.8 7.0 7.4 85 87 6.8 6.6 17.0 16.5 15.8 7.0 7.4 85 87 6.8 6.6 18.0 16.4 15.8 6.9 4.4 85 90 6.8 6.6 December 15, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) C C) (mg/L) (µS/cm) B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 B2 D2 F2 H2 K2 0.2 11.6 11.4 10.5 10.9 11.3 9.8 11.0 10.2 10.0 10.1 90 88 89 89 88 7.7 7.8 7.6 7.5 7.5 1.0 11.6 11.4 10.5 10.9 11.3 9.8 10.4 10.0 10.0 9.9 90 88 89 89 88 7.6 7.6 7.6 7.5 7.5 2.0 11.6 11.4 10.5 10.9 11.3 9.8 10.4 10.0 9.9 9.9 90 88 89 89 88 7.6 7.6 7.5 7.5 7.5 3.0 11.6 11.4 10.5 10.8 11.3 9.8 10.4 10.0 9.9 9.8 90 88 89 89 88 7.6 7.6 7.5 7.5 7.4 4.0 11.6 11.4 10.5 10.8 9.8 10.4 10.0 9.9 90 88 89 89 7.6 7.5 7.5 7.4 5.0 11.6 11.4 10.5 10.8 9.8 10.4 9.9 9.9 90 88 89 89 7.6 7.5 7.5 7.4 6.0 11.6 11.4 10.5 10.8 9.8 10.4 9.9 9.9 90 88 89 89 7.6 7.5 7.5 7.4 7.0 11.6 11.4 10.5 10.8 9.8 10.3 9.9 9.8 90 88 89 89 7.5 7.5 7.5 7.4 8.0 11.6 11.3 10.5 10.8 9.8 10.3 9.8 9.8 90 88 89 89 7.5 7.5 7.5 7.4 9.0 11.6 11.3 10.5 9.8 10.3 9.8 90 88 89 7.5 7.5 7.5 10.0 11.6 11.3 10.5 9.8 10.3 9.8 90 88 89 7.5 7.5 7.4 11.0 11.6 11.3 10.5 9.8 10.3 9.8 90 88 89 7.5 7.5 7.4 12.0 11.6 11.3 10.5 9.8 10.3 9.8 90 88 89 7.5 7.5 7.4 13.0 11.6 11.3 10.5 9.7 10.3 9.8 90 88 89 7.5 7.4 7.4 14.0 11.6 11.3 10.5 9.7 10.3 9.8 90 88 89 7.5 7.4 7.4 15.0 11.6 11.3 10.5 9.7 10.3 9.7 90 88 89 7.5 7.4 7.3 16.0 11.5 11.3 9.7 10.3 90 88 7.5 7.4 17.0 11.5 11.3 9.7 10.3 90 88 7.5 7.4 18.0 11.4 9.6 92 7.2 Appendix A - 20 Table A-3 (continued) Secchi disk transparency depth (m) Date TYB2 TYD2 TYF2 TYH2 TYK2 January 19 1.7 1.8 1.5 1.6 3.0' February 23 1.2 0.8 0.5 0.5 3.0' March 17 0.9 N,V 1.1 ND 3.0' April6 1.3 ND 1.4 ND 3.0' May 11 0.2 0.1 0.1 0.1 2.0' June 22 1.6 1.5 1.5 1.4 1.7 July 13 1.5 1.4 1.5 1.5 3.0' August 24 1.3 1.6 0.9 1.1 1.9 September 21 1.1 1.1 1.1 1.0 3.0' October 19 1.2 1.1 0.9 1.0 3.0' November 17 1.7 ND 1.9 ND 1.7 December 15 1.0 1.1 1.6 1.7 3.0' Missing data due to either measurements were not obtained during sampling or because the Secchi disk was observed on river or lake bottom during sampling. In such instances, the depth of the lake bottom is listed as a reference to Secchi depth. 2 No data were collected at the station on the listed date. Appendix A - 21 Table A-4 Water temperature, dissolved oxygen, specific conductance, pH, Secchi disk transparency, and turbidity data collected from the Pee Dee River (Stations TY1B and TY12B) below the Tillery Hydroelectric Plant during 2000. Station TY1B Dissolved Specific Temperature oxygen conductance Secchi disk Turbidity Date (BC) (mg/L) ((DS/cm) pH depth (m) (NTt) 01/24/00 7.4 10.2 100 7.6 ND' 10 02/01/00 6.0 11.7 87 6.6 ND 10 03/08/00 11.6 12.5 109 6.9 ND 7.1 04/06/00 14.6 9.9 85 7.0 ND 9.9 05/02/00 17.4 8.4 90 6.8 ND 11 06/12/00 22.4 7.5 102 7.3 ND 4.4 07/10/00 24.9 3.5 136 6.7 ND 3.8 08/08/00 28.1 8.6 167 7.4 ND 5.1 09/05/00 25.5 3.0 123 6.6 ND 4.3 10/04/00 23.2 6.7 149 7.3 ND 6.9 11115100 17.6 9.5 111 6.5 ND 3.1 12/05/00 12.5 10.8 140 7.2 ND 4.3 Station TY12B Dissolved Specific Temperature oxygen conductance Secchi disk Turbidity Date (BC) (mg/L) (cDS/cm) pH depth (m) (NTt) 01/24/00 2.9 12.5 104 8.1 0.2 157 02/01/00 3.2 12.4 66 6.7 0.2 46 03/08/00 12.4 11.7 138 6.8 1.2 9.0 04/06/00 15.2 10.0 127 7.4 1.0 15 05/02/00 17.7 8.4 110 6.7 0.5 43 06/12/00 24.1 6.8 117 7.3 0.9 13 07/10/00 30.3 8.1 381 6.9 1.2 8.8 08/08/00 27.4 6.9 124 6.8 0.3 44 09/05/00 23.2 5.8 72 7.0 0.3 106 10/04/00 23.5 8.0 132 7.0 0.9 16 11115100 15.1 9.9 116 6.4 0.9 5.6 12/05/00 8.7 11.0 122 7.0 1.7 6.4 1 Secchi disk transparency depth was not determined because sampling was conducted by wading at this station Appendix A - 22 Table A-5 Water temperature, dissolved oxygen, specific conductance, pH, Secchi disk transparency, and turbidity data collected from the Pee Dee River (Stations TY1B, TY12B, and RR) below the Tillery Development during 2001. Specific Dissolved conductance Secchi disk Turbidity 01/17/01 NS' NS NS NS NS NS 02/21/01 9.4 11.9 102 7.0 NV 4.0 03/27/01 10.8 10.6 95 6.7 ND 6.7 04/11/01 13.1 10.8 98 7.2 ND 4.6 05110101 16.4 7.4 103 7.4 ND 5.4 06/13/01 21.3 6.5 92 7.1 ND 2.6 07/18/01 24.7 4.6 121 8.0 ND 1.3 08/20/01 25.6 5.0 132 7.2 ND 1.7 09/18/01 24.1 5.5 127 6.1 ND 2.8 10/30/01 19.6 10.9 126 7.1 ND 3.0 11/28/01 16.1 9.1 122 7.9 ND 5.9 12/18/01 14.6 9.6 118 6.9 ND 3.8 Station TY12B Specific Temperature Dissolved conductance Secchi disk Turbidity Date ($C) oxygen (mg/L) ((DS/cm) pH depth (m) (NTfl) 01/17/01 6.8 11.8 118 6.7 1.3 11 02/21/01 9.1 10.2 85 6.8 0.5 40 03/27/01 10.9 10.4 120 6.7 0.6 23 04/11/01 15.7 9.6 125 7.1 1.3 4.2 05110101 20.2 8.7 201 7.2 3 4.0 06/13/01 24.6 8.0 119 7.5 0.9 4.0 07/18/01 24.4 4.5 121 8.1 15 4.4 08/20/01 26.4 5.3 129 7.3 103 09/18/01 23.2 6.4 134 6.3 7.5 10/30/01 14.8 11.6 218 7.2 4.9 11/28/01 15.6 8.5 228 7.9 12 12/18/01 13.9 9.6 174 6.8 10 12 Appendix A - 23 Table A-5 (continued) Station RR Specific Temperature Dissolved conductance Secchi disk Turbidity Date ($C) oxygen (mg/L) (TS/cm) pH depth (m) (NTfl) 01/17/01 NS NS NS NS NS NS 02/21/01 10.5 10.7 149 6.9 ND 33 03/27/01 11.9 12.0 151 6.8 ND 22 04/11/01 22.3 8.1 225 7.1 ND 13 05110101 21.8 8.3 466 7.4 ND 12 06/13/01 27.6 7.7 452 8.2 ND 4.5 07/18/01 28.6 7.0 462 7.2 ND 12 08/20/01 26.3 6.6 383 7.2 ND 83 09/18/01 20.0 7.8 552 7.3 ND 12 10/30/01 12.9 13.0 627 7.5 ND 4.7 11/28/01 17.0 9.4 603 7.7 ND 17 12/18/01 13.6 10.8 316 7.1 ND 17 1 No data collected at these stations during January 2001. 2 Secchi disk transparency depth was not determined because sampling was conducted by wading. 3 Secchi disk transparency depth was not obtained or Secchi disk was on the river bottom before the transparency depth was reached. Appendix A - 24 Table A-6 Water temperature, dissolved oxygen, specific conductance, pH, and turbidity data collected from the Pee Dee River (Stations TY1B, TY12B, and RR) below the Tillery Development during 2002. Specific Temperature Dissolved conductance Turbidity Date (BC) oxygen (mg/L) ((DS/cm) pH (NTt) 01/15/2002 9.7 12.4 80 7.7 2.7 02/04/2002 9.0 14.4 104 7.6 27 03/14/2002 10.6 11.0 99 7.2 8.1 04/11/2002 14.6 8.9 104 7.5 8.8 05/14/2002 19.7 7.0 112 7.3 3.8 06/06/2002 20.5 9.4 120 7.0 3.1 07/01/2002 22.9 5.4 120 7.8 1.4 08/27/2002 24.8 4.8 137 7.2 3.5 09/24/2002 24.4 5.7 116 7.5 3.0 10/29/2002 18.9 7.6 105 7.4 5.6 11/14/2002 16.7 8.8 105 7.4 4.7 12/18/2002 8.1 10.2 68 7.2 25 Station TY1B Specific Temperature Dissolved conductance Turbidity Date (BC) oxygen (mg/L) ((DS/cm) pH (NTt) 01/15/2002 8.1 12.0 78 6.1 0.5 02/04/2002 9.5 13.8 102 8.1 1.7 03/14/2002 11.4 9.5 136 7.1 2.5 04/11/2002 16.0 8.2 118 7.3 28 05/14/2002 19.2 7.0 128 7.3 19 06/06/2002 25.4 8.1 181 6.8 12 07/01/2002 28.0 7.3 432 7.9 6.7 08/27/2002 26.8 6.4 137 7.7 9.7 09/24/2002 24.6 6.5 162 8.0 18 10/29/2002 18.2 7.2 113 8.2 23 11/14/2002 15.4 8.6 104 7.8 5.4 12/18/2002 6.6 10.3 55 7.2 40 Station TY1B Specific Temperature Dissolved conductance Turbidity Date (BC) oxygen (mg/L) (TS/cm) pH (NTt) 01/15/2002 6.5 13.7 186 7.3 0.6 02/04/2002 9.1 14.2 186 7.9 9.3 03/14/2002 12.0 9.6 230 7.3 10 04/11/2002 18.8 8.6 263 7.7 14 05/14/2002 24.0 7.3 529 7.8 22 06/06/2002 29.1 7.2 468 7.3 8.9 07/01/2002 28.9 7.2 1,006 8.4 10 08/27/2002 27.0 6.7 419 7.7 9.0 09/24/2002 24.3 7.8 375 7.8 10 10/29/2002 16.3 8.9 257 7.1 11 11/14/2002 14.2 6.7 151 7.3 9.4 12/18/2002 6.8 12.2 106 7.2 22 Appendix A - 25 Table A-7 Water temperature, dissolved oxygen, specific conductance, pH, and turbidity data collected from the Pee Dee River below the Tillery Development (Stations TY1B, TY12B, and RR) during 20041. Station TY1B (Non Generation Flow) Specific Temperature Dissolved conductance Turbidity Date (BC) oxygen (mg/L) ((DS/cm) pH (NTfl) 01/15/2002 7.2 12.4 86 7.7 2.2 02/04/2002 5.9 12.2 95 7.7 11 03/14/2002 8.9 12.2 94 8.5 18 04/11/2002 10.7 9.1 102 9.0 7.9 05/14/2002 18.1 7.7 92 7.6 9.1 06/06/2002 22.2 7.4 99 7.4 2.7 07/01/2002 25.9 4.4 92 6.8 0.6 08/27/2002 26.3 5.0 98 7.0 1.3 09/24/2002 23.6 5.9 95 7.3 4.2 10/29/2002 20.4 5.8 75 6.6 14 11/14/2002 17.5 8.9 88 6.9 5.0 12/18/2002 13.3 11.1 89 7.6 7.1 Station TY1B (Generation Flow) Specific Temperature Dissolved conductance Turbidity Date (BC) oxygen (mg/L) ((DS/cm) pH (NTfl) 01/15/2002 6.3 11.9 86 7.4 6.5 02/04/2002 6.2 12.2 95 8.0 18 03/14/2002 9.5 11.5 92 8.5 15 04/11/2002 13.0 9.5 95 7.9 11 05/14/2002 18.8 8.1 81 7.6 9.4 06/06/2002 23.6 5.2 97 7.2 4.7 07/01/2002 26.3 2.9 99 6.8 1.5 08/27/2002 26.5 4.0 99 7.0 3.0 09/24/2002 24.0 6.0 96 7.2 5.3 10/29/2002 20.9 6.4 78 7.4 24 11/14/2002 16.5 7.8 88 7.1 8.5 12/18/2002 11.5 10.5 90 7.6 8.9 Ctwt:nn RR _ P.Azv R:v.r Specific Temperature Dissolved conductance Turbidity Date (BC) oxygen (mg/L) ($S/cm) pH (NTfl) 01/15/2002 6.4 13.8 257 9.1 3.2 02/04/2002 11.0 11.3 183 7.5 20 03/14/2002 14.4 10.1 196 7.7 17 04/11/2002 15.6 9.3 181 8.3 16 05/14/2002 25.6 7.9 248 7.7 17 06/06/2002 25.7 11.1 230 7.7 73 07/01/2002 28.1 6.8 491 7.5 21 08/27/2002 27.4 7.4 197 7.6 8.6 09/24/2002 19.0 8.3 146 7.5 28 10/29/2002 17.3 9.1 181 7.5 9.4 11/14/2002 9.9 11.0 214 7.2 26 12/18/2002 10.5 10.7 140 7.7 55 Appendix A - 26 Table A-7 (continued) Station TY12B (Non Generation Flow ) Specific Temperature Dissolved conductance Turbidity Date (BC) oxygen (mg/L) ((DS/cm) pH (NTfl) 01/15/2002 7.2 13.8 125 8.0 27 02/04/2002 7.0 11.0 113 7.5 30 03/14/2002 10.0 10.7 115 8.0 18 04/11/2002 13.2 8.4 146 8.0 17 05/14/2002 19.4 7.9 106 7.4 16 06/06/2002 25.8 5.4 124 7.9 21 07/01/2002 27.1 4.9 112 7.1 14 08/27/2002 26.3 5.2 111 7.3 21 09/24/2002 20.8 6.5 103 7.3 17 10/29/2002 20.4 6.7 88 7.3 9.1 11/14/2002 12.9 8.9 131 7.2 9.4 12/18/2002 8.5 9.7 115 7.7 13 Station TY12B (Generation Flow) Specific Temperature Dissolved conductance Turbidity Date (BC) oxygen (mg/L) ((DS/cm) pH (NTfl) 01/15/2002 6.4 12.7 97 7.7 7.2 02/04/2002 7.9 10.9 140 7.8 30 03/14/2002 10.1 11.5 97 7.7 17 04/11/2002 13.2 9.8 97 8.0 9.0 05/14/2002 20.9 8.1 96 7.8 15 06/06/2002 25.8 10.1 125 7.0 29 07/01/2002 27.9 6.1 103 7.2 26 08/27/2002 29.7 8.2 162 7.7 16 09/24/2002 21.3 7.8 120 7.4 45 10/29/2002 21.2 6.9 79 7.0 15 11/14/2002 14.8 8.3 99 6.4 10 12/18/2002 7.6 11.8 119 7.7 12 Appendix A - 27 APPENDIX B RAW DATA LISTING FOR WATER QUALITY PARAMETERS COLLECTED IN BLEWETT FALLS LAKE AND THE PEE DEE RIVER DURING 1999, 2001, AND 2004 Table B-1 Water temperature, dissolved oxygen, specific conductance, pH, Secchi disk transparency, and turbidity data collected from Blewett Falls Lake (Stations BFB2, BFF2, and BFH2) and the Pee Dee River (Station TY12B) during 1999. January 19, 1999 Depth Temperature Dissolved oxygen Specific conductance pH B2 F2 H2 TY12B B2 F2 H2 TY12B B2 F2 H2 TY12B B2 F2 H2 TY12B 0.2 8.9 8.4 8.0 9.2 9.2 10.9 10.3 10.7 87 96 93 142 7.0 6.9 7.0 7.0 1.0 8.9 8.4 8.0 9.2 10.7 10.3 87 97 94 7.0 6.9 7.0 2.0 8.9 8.5 8.0 9.2 10.6 10.2 87 99 94 7.0 7.0 7.0 3.0 8.9 8.4 9.2 10.6 87 100 7.0 7.0 4.0 8.9 8.4 9.2 10.6 87 102 7.0 7.0 5.0 8.9 8.4 9.2 10.5 87 102 7.0 7.0 6.0 8.9 8.4 9.2 10.3 87 102 7.0 7.0 7.0 8.9 8.4 9.2 10.2 87 102 7.0 7.0 8.0 8.9 9.2 87 7.0 February 1, 1999 Depth Temperature Dissolved oxygen Specific conductance pH B2 F2 H2 TY12B B2 F2 H2 TY12B B2 F2 H2 TY12B B2 F2 H2 TY12B 0.2 8.6 8.5 8.4 8.8 11.2 11.3 11.9 11.9 79 84 82 82 6.5 6.7 6.7 6.9 1.0 8.6 8.5 11.2 11.4 79 84 6.6 6.7 2.0 8.6 8.5 11.2 11.4 79 84 6.6 6.7 3.0 8.6 8.5 11.2 11.4 79 84 6.6 6.7 4.0 8.6 8.5 11.2 11.4 80 84 6.7 6.7 5.0 8.5 8.5 11.2 11.4 80 85 6.7 6.7 6.0 8.6 10.3 83 6.6 March 5, 1999 Depth Temperature Dissolved oxygen Specific conductance pH (m) C C) (mg/L) (µS/cm) B2 F2 H2 TY12B B2 F2 H2 TY12B B2 F2 H2 TY12B B2 F2 H2 TY12B 0.2 10.0 8.9 9.5 8.6 11.7 11.6 12.3 10.6 92 76 111 106 6.9 7.0 7.1 6.8 1.0 10.0 8.9 9.5 11.5 11.6 12.1 93 76 111 6.9 7.0 7.1 2.0 10.0 8.9 9.5 11.5 11.5 12.1 93 76 111 6.9 7.0 7.1 3.0 10.0 8.9 11.4 11.4 93 76 6.9 7.0 4.0 10.0 8.8 11.3 11.3 93 76 6.9 7.0 5.0 10.0 8.8 11.2 11.3 93 76 6.9 7.0 6.0 10.0 8.8 11.2 11.3 93 76 6.9 7.0 7.0 9.9 8.9 11.1 10.7 93 76 6.9 7.0 8.0 9.9 . 10.8 93 6.9 Appendix B - 1 Table B-1 (continued) April 15-16, 1999 Depth Temperature Dissolved oxygen Specific conductance pH 0.2 18.6 17.4 16.4 14.5 9.2 9.8 10.2 9.7 105 111 97 1.0 18.6 17.4 16.4 9.2 9.8 10.2 104 111 97 2.0 18.5 17.3 16.4 8.7 9.5 10.2 104 110 97 3.0 18.4 17.1 8.4 9.5 104 110 4.0 18.4 17.0 8.3 9.4 104 109 5.0 17.9 16.8 8.1 9.3 104 108 6.0 17.7 16.8 7.9 5.5 104 112 7.0 17.7 7.3 104 8.0 17.5 6.8 104 95 6.2 6.4 6.6 6.3 6.4 6.6 6.3 6.4 6.6 6.3 6.4 6.3 6.4 6.3 6.4 6.3 6.4 6.3 6.3 6.1 May 14, 1999 Depth Temperature Dissolved oxygen Specific conductance pH 0.2 22.8 21.3 19.2 18.9 10.6 9.3 1.0 20.7 21.2 19.2 9.1 9.1 2.0 19.9 20.5 19.2 8.3 8.7 3.0 19.5 20.2 8.3 8.7 4.0 19.2 20.0 8.2 8.5 5.0 18.8 19.4 7.5 8.4 6.0 18.8 19.1 7.4 8.2 7.0 18.7 18.7 7.3 6.0 8.0 18.5 7.0 9.6 8.0 124 115 105 149 6.8 6.3 6.2 6.3 9.4 112 114 105 7.0 6.2 6.2 9.4 106 111 105 6.5 6.4 6.2 104 111 6.5 6.2 103 111 6.4 6.2 99 106 6.4 6.2 99 104 6.4 6.2 98 109 6.4 6.2 98 6.4 June 11, 1999 Depth Temperature Dissolved oxygen Specific conductance pH 0.2 27.6 26.6 24.1 22.0 10.2 8.8 1.0 27.6 26.5 24.1 10.2 8.5 2.0 27.6 26.1 24.1 10.3 7.8 3.0 26.2 25.5 8.3 6.5 4.0 25.2 25.1 5.8 5.5 5.0 23.7 24.6 4.0 4.9 6.0 23.5 24.1 3.5 3.2 7.0 23.1 22.6 2.3 0.5 8.0 22.8 1.8 . 6.8 6.8 152 133 140 111 6.6 151 133 140 6.6 151 127 141 145 126 134 132 130 124 129 129 129 138 129 Appendix B - 2 8.1 7.4 7.0 6.9 8.1 7.4 6.9 8.3 7.4 6.9 8.2 7.3 7.9 7.2 7.7 7.1 7.6 6.9 7.4 6.8 7.3 Table B-1 (continued) July 14, 1999 Depth Temperature Dissolved oxygen Specific conductance pit 0.2 25.9 23.9 22.8 22.8 6.2 6.1 6.7 1.0 25.9 23.9 22.8 5.7 6.1 6.5 2.0 26.0 23.2 22.8 5.3 5.9 6.4 3.0 26.0 22.8 5.3 5.8 4.0 26.0 22.7 5.3 5.7 5.0 26.0 22.7 5.3 5.7 6.0 26.0 22.7 5.2 5.7 7.0 25.9 22.7 5.1 5.2 8.0 25.6 4.7 9.0 25.5 4.7 7.3 144 161 112 144 161 112 144 150 112 144 124 144 118 144 113 144 112 144 113 146 147 130 6.9 6.8 6.8 6.9 6.8 6.8 6.9 6.8 6.8 6.9 6.7 6.9 6.7 6.9 6.7 6.9 6.7 6.9 6.7 6.9 6.8 6.8 August 2, 1999 Depth Temperature Dissolved oxygen Specific conductance pit 0.2 31.6 30.5 31.9 27.3 9.7 9.9 9.1 1.0 31.6 30.5 31.9 9.7 9.8 9.0 2.0 31.5 29.1 31.9 9.6 6.6 8.9 3.0 30.9 28.3 9.2 4.2 4.0 30.3 28.0 8.4 3.6 5.0 30.0 27.7 8.0 2.8 6.0 28.7 27.5 3.4 2.1 7.0 28.2 27.3 2.5 1.4 8.0 28.0 1.8 9.0 27.7 1.1 4.6 161 152 209 161 152 210 161 144 211 160 156 158 155 157 151 148 149 148 150 148 148 123 8.1 7.7 7.9 8.1 7.7 7.9 8.1 7.7 7.9 8.1 7.5 8.0 7.4 7.8 7.3 7.7 7.3 7.4 7.1 7.3 7.2 7.1 September 9, 1999 Depth Temperature Dissolved oxygen Specific conductance pit 0.2 26.5 27.6 27.1 25.9 8.9 6.3 5.7 1.0 26.3 27.6 27.1 8.2 6.2 5.7 2.0 25.9 27.5 27.1 7.1 6.0 5.7 3.0 25.5 27.4 5.2 5.6 4.0 25.2 27.1 4.5 5.6 5.0 25.0 26.2 3.9 4.4 6.0 24.9 25.6 3.5 3.7 7.0 24.9 25.2 3.0 0.2 8.0 24.9 2.9 9.0 24.8 1.4 5.3 157 254 218 155 257 218 148 252 218 142 221 141 190 143 147 147 135 145 189 138 138 126 7.5 7.3 7.1 7.5 7.2 7.1 7.5 7.2 7.1 7.4 7.2 7.3 7.2 7.2 7.2 7.2 7.1 7.1 6.8 7.1 7.0 7.5 Appendix B - 3 Table B-1 (continued) October 21, 1999 Depth Temperature Dissolved oxygen Specific conductance pit 0.2 19.2 19.4 19.3 19.8 6.8 7.1 7.5 1.0 19.2 19.4 19.3 6.7 6.8 7.3 2.0 19.2 19.4 19.3 6.7 6.8 7.3 3.0 19.1 19.4 6.8 6.8 4.0 19.1 19.4 7.0 6.7 5.0 19.0 19.2 6.9 6.6 6.0 18.9 19.2 6.9 6.1 7.0 18.8 6.9 8.0 18.8 6.7 7.3 106 105 100 106 104 99 104 104 100 105 104 105 103 105 101 114 103 118 119 116 7.2 6.9 6.7 7.2 7.0 6.9 7.2 7.0 6.9 7.2 7.0 7.2 6.9 7.1 7.0 7.1 6.9 7.0 7.0 7.1 November 10, 1999 Depth Temperature Dissolved oxygen Specific conductance pit 0.2 15.7 16.6 16.8 16.3 8.4 9.7 8.6 1.0 15.7 16.1 16.8 8.4 9.7 8.6 2.0 15.7 16.0 16.8 8.1 9.8 8.5 3.0 15.6 16.0 7.8 9.7 4.0 15.6 16.0 8.0 9.7 5.0 15.6 16.0 7.6 9.7 6.0 15.6 15.4 7.5 9.3 7.0 15.6 15.3 7.4 9.3 8.0 15.6 7.2 9.0 15.6 6.3 8.9 121 142 116 121 152 116 121 156 115 121 159 121 161 121 162 121 181 121 195 121 126 165 6.7 7.0 7.2 6.7 7.0 7.1 6.6 7.0 7.0 6.6 6.9 6.6 6.9 6.6 6.9 6.6 6.9 6.6 6.9 6.6 6.6 7.1 December 2, 1999 Depth Temperature Dissolved oxygen Specific conductance pit 0.2 12.2 12.5 11.9 9.9 7.5 8.6 8.9 1.0 12.2 12.5 11.9 7.4 8.4 8.9 2.0 12.3 12.5 11.9 7.1 8.4 8.9 3.0 12.3 12.5 7.2 8.4 4.0 12.3 12.4 7.2 8.4 5.0 12.3 12.4 7.2 8.4 6.0 12.3 12.2 7.2 8.2 7.0 12.3 12.2 7.2 8.0 8.0 12.3 7.3 9.0 12.3 7.3 10.6 148 96 90 148 96 90 148 96 90 148 96 148 98 148 98 148 101 148 105 148 148 113 6.7 7.1 7.0 6.6 7.0 7.0 6.7 7.0 6.9 6.8 7.0 6.9 7.0 6.9 7.0 6.9 7.0 6.9 7.0 6.9 6.9 6.8 Appendix B - 4 Table B-1 (continued) Secchi disk transparency depth (m) Date BFB2 BFF2 BFM TY12B January 19, 1999 0.7 0.7 0.4 1 February 1, 1999 0.7 0.7 -- -- March 5, 1999 0.5 0.7 0.9 1.2 April 15-16, 1999 0.6 0.8 1.2 1.7 May 14, 1999 1.1 0.6 1.2 1.1 June 11, 1999 1.3 0.8 1.3 1.2 July 14, 1999 0.6 0.7 1.4 1.4 August 2, 1999 1.3 0.8 1.2 1.3 September 9, 1999 1.0 0.8 1.3 1.8 October 21, 1999 0.6 0.6 1.2 1.1 November 10, 1999 1.2 1.2 1.8 2.0 December 2, 1999 0.6 0.8 1.6 1.4 Missing data due to either measurements were not obtained during sampling or because the Secchi disk was observed on river or lake bottom during sampling. Appendix B - 5 Table B-2 Water temperature, dissolved oxygen, specific conductance, pH, and Secchi disk transparency data collected from Blewett Falls Lake (Stations BFB2, BFF2, BFH2) and the Pee Dee River (Station TY12B) during 2001. January 17, 2001 Depth Temperature Dissolved oxygen Specific conductance pH (m) C C) (mg/L) (µS/cm) B2 F2 H2 TY12B B2 F2 H2 TY12B B2 F2 H2 TY12B B2 F2 H2 TY12B 0.2 6.3 7.2 8.0 6.8 12.6 12.7 14.2 11.8 94 105 235 118 6.6 7.1 8.1 6.7 1.0 6.2 7.1 8.0 12.6 12.7 14.2 93 104 235 6.6 7.0 8.2 2.0 6.2 7.1 8.0 12.6 12.7 14.2 93 104 234 6.6 7.0 8.2 3.0 6.2 7.1 12.6 12.7 93 104 6.6 7.0 4.0 6.2 7.1 12.6 12.7 93 104 6.6 7.0 5.0 6.2 7.1 12.6 12.7 93 104 6.6 7.0 6.0 6.2 7.1 12.6 12.7 93 104 6.6 7.0 7.0 6.2 6.7 12.6 12.8 93 104 6.6 7.0 8.0 6.1 12.6 93 6.6 9.0 6.0 12.3 93 6.6 February 21, 2001 Depth Temperature Dissolved oxygen Specific conductance pH (m) (° C ) (m g/L) (µ S/cm) B2 F2 H2 TY12B B2 F2 H2 TY12B B2 F2 H2 TY12B B2 F2 H2 TY12B 0.2 11.1 9.8 9.1 9.1 10.2 11.9 10.7 10.2 136 101 107 85 6.6 6.8 6.9 6.8 1.0 11.1 9.8 9.1 9.S 11.7 10.7 135 101 107 6.6 6.8 6.9 2.0 11.1 9.8 9.1 9.S 11.6 10.7 135 101 107 6.6 6.8 6.9 3.0 11.1 9.8 9.S 11.6 135 101 6.6 6.8 4.0 11.1 9.8 9.f 11.6 135 101 6.6 6.8 5.0 11.1 9.6 9.f 11.5 135 103 6.6 6.8 6.0 11.0 9.6 9.f 11.5 135 103 6.6 6.8 7.0 10.9 9.4 9.f 11.3 134 104 6.7 6.8 8.0 10.7 9.; 132 6.7 9.0 10.3 9.1 130 6.7 March 27, 2001 Depth Temperature Dissolved oxygen Specific conductance pH 0.2 11.9 12.1 11.0 10.9 9.7 10.5 11.6 10.4 93 112 98 120 6.6 6.5 6.9 1.0 11.9 12.1 11.0 9.7 10.5 11.6 93 112 98 6.6 6.5 6.9 2.0 11.9 12.1 11.0 9.7 10.3 11.6 93 112 98 6.6 6.5 6.9 3.0 11.9 12.1 9.7 10.3 93 112 6.6 6.5 4.0 11.9 12.1 9.7 10.2 93 112 6.6 6.5 5.0 11.9 12.1 9.6 10.2 93 112 6.6 6.5 6.0 11.9 12.1 9.6 10.2 93 112 6.6 6.5 7.0 11.8 12.1 9.5 9.9 92 110 6.6 6.6 8.0 11.8 9.4 92 6.6 9.0 11.7 9.2 92 6.6 6.7 Appendix B - 6 Table B-2 (continued) April 11, 2001 Depth Temperature Dissolved oxygen Specific conductance pH 0.2 17.6 16.7 13.8 15.7 1.0 17.5 16.2 13.8 2.0 16.7 15.7 13.8 3.0 16.5 15.3 4.0 16.1 15.1 5.0 16.0 15.0 6.0 15.9 14.9 7.0 15.8 14.9 8.0 15.7 9.0 15.5 10.2 10.2 10.2 9.6 124 125 100 125 6.9 7.0 7.0 10.0 10.2 10.2 123 118 100 6.9 7.0 7.0 9.6 10.4 10.2 118 113 100 6.9 7.0 7.0 9.6 10.6 114 109 6.9 7.0 9.5 10.6 111 108 6.9 7.0 9.4 10.7 111 107 6.9 7.0 9.4 10.7 110 106 6.9 7.0 9.4 10.7 107 106 6.9 7.0 9.2 107 6.9 8.7 108 6.9 7.1 May 10, 2001 Depth Temperature Dissolved oxygen Specific conductance pH 0.2 22.4 22.4 20.5 20.2 12.3 12.4 10.0 8.7 1.0 22.4 22.3 20.3 12.5 12.3 9.6 2.0 21.7 21.4 19.9 10.3 9.7 8.7 3.0 21.0 20.5 8.0 7.0 4.0 20.5 19.9 7.6 5.3 5.0 20.1 19.3 6.8 4.2 6.0 19.8 19.1 5.6 3.5 7.0 19.4 18.6 5.4 0.3 8.0 19.3 4.7 9.0 18.9 3.0 59 146 117 201 7.2 7.0 7.5 59 146 118 7.5 6.9 7.6 52 143 118 7.6 6.9 7.5 47 158 7.6 7.0 41 138 7.5 7.0 37 127 7.4 7.1 35 128 7.4 7.1 35 138 7.3 7.1 36 7.2 37 7.1 7.2 June 13, 2001 Depth Temperature Dissolved oxygen Specific conductance pH 0.2 25.6 27.2 26.0 24.6 8.7 11.2 7.7 1.0 25.6 27.0 26.0 8.9 10.8 7.6 2.0 25.0 25.8 25.9 6.2 8.4 7.4 3.0 24.6 25.1 4.3 6.6 4.0 24.2 24.5 3.9 5.1 5.0 23.6 23.9 3.2 2.4 6.0 23.4 23.3 2.6 0.5 7.0 23.1 22.8 2.0 0.3 8.0 22.9 1.6 9.0 22.5 1.0 8.0 124 124 143 119 8.8 9.3 7.6 124 122 143 8.8 9.1 7.6 117 114 142 7.4 7.7 7.5 116 111 7.1 7.3 113 110 7.0 7.2 111 113 6.9 7.0 111 114 6.9 6.9 111 122 6.8 6.9 112 6.8 117 6.9 7.5 Appendix B - 7 Table B-2 (continued) July 18, 2001 Depth Temperature Dissolved oxygen Specific conductance pit 0.2 27.1 27.5 26.4 24.4 10.7 10.5 6.6 4.5 142 146 165 121 8.1 8.0 7.8 1.0 27.1 27.5 26.4 10.7 10.7 6.9 141 144 165 8.1 8.1 7.7 2.0 26.9 27.3 26.4 9.2 10.2 7.1 140 147 166 8.1 8.1 7.7 3.0 26.8 27.2 8.3 9.1 138 148 8.0 8.0 4.0 26.6 26.8 6.3 7.6 138 149 7.9 7.9 5.0 26.3 26.4 3.8 6.4 137 145 7.8 7.8 6.0 26.1 26.2 3.6 5.5 136 144 7.6 7.8 7.0 26.1 25.4 3.4 0.8 136 144 7.5 7.6 8.0 25.9 1.8 138 7.5 9.0 25.8 1.6 139 7.4 8.1 August 20, 2001 Depth Temperature Dissolved oxygen Specific conductance pit 0.2 28.5 28.4 28.2 26.4 6.3 8.5 6.0 1.0 28.5 28.1 27.5 6.2 8.1 5.8 2.0 28.5 28.1 27.2 5.7 7.5 5.5 3.0 28.4 28.0 5.3 7.1 4.0 28.4 27.8 5.1 6.5 5.0 28.2 27.3 2.4 4.3 6.0 28.1 27.1 1.8 3.7 7.0 28.0 27.1 1.7 3.4 8.0 28.0 1.5 9.0 27.9 1.2 5.3 185 148 148 129 7.4 7.4 7.4 184 152 148 7.5 7.5 7.4 184 152 150 7.5 7.6 7.4 183 151 7.5 7.6 181 151 7.5 7.6 169 135 7.4 7.5 168 131 7.3 7.4 166 131 7.3 7.3 164 7.3 162 7.3 7.3 September 18, 2001 Depth Temperature Dissolved oxygen Specific conductance pit 0.2 24.0 23.6 23.9 23.2 7.3 8.5 8.9 1.0 24.0 23.0 23.1 7.3 8.3 8.4 2.0 24.0 22.8 22.8 7.3 7.6 8.1 3.0 24.0 22.8 7.3 7.5 4.0 24.0 22.7 7.3 7.4 5.0 24.0 22.7 7.3 7.2 6.0 24.0 22.6 7.2 6.3 7.0 24.0 22.6 7.1 6.2 8.0 23.9 6.0 9.0 23.6 5.4 6.4 152 132 128 134 6.4 6.5 6.4 152 131 126 6.4 6.5 6.3 152 130 126 6.3 6.4 6.3 152 130 6.3 6.4 152 131 6.2 6.3 152 131 6.2 6.2 152 130 6.1 6.1 152 131 6.1 6.1 148 5.9 144 6.0 6.3 Appendix B - 8 Table B-2 (continued) October 30, 2001 Depth Temperature Dissolved oxygen Specific conductance pH 0.2 16.2 14.0 13.3 14.8 9.2 11.6 11.8 11.6 201 160 172 218 7.1 7.2 7.4 7.2 1.0 16.2 14.0 9.2 11.9 201 159 7.0 7.3 2.0 16.2 14.0 9.4 11.5 201 155 7.1 7.3 3.0 16.2 13.9 9.3 10.7 200 150 7.2 7.3 4.0 16.2 13.6 9.4 10.0 200 137 7.2 7.3 5.0 16.2 13.4 9.4 9.6 200 137 7.2 7.3 6.0 16.2 13.4 9.4 9.5 201 137 7.2 7.3 7.0 16.2 9.4 201 7.2 November 28, 2001 Depth Temperature Dissolved oxygen Specific conductance pH 0.2 14.6 16.0 15.9 15.6 11.2 10.2 8.4 1.0 14.6 15.9 11.2 10.2 2.0 13.9 15.5 9.1 9.8 3.0 13.7 14.5 8.5 8.6 4.0 13.7 13.3 8.5 7.8 5.0 13.3 12.0 7.8 6.4 6.0 13.0 11.9 6.6 5.3 7.0 12.9 5.9 8.0 12.9 3.8 8.5 197 204 264 228 7.4 7.7 7.6 197 204 7.4 7.7 196 198 7.4 7.7 195 200 7.4 7.6 195 186 7.4 7.6 194 177 7.4 7.5 194 178 7.3 7.4 196 7.3 199 7.2 7.9 December 18, 2001 Depth Temperature Dissolved oxygen Specific conductance pH 0.2 13.7 14.0 14.5 13.9 10.1 9.0 10.1 9.6 150 159 122 174 6.0 6.7 6.6 1.0 13.7 14.0 14.5 10.0 9.1 10.1 150 160 122 6.1 6.7 6.6 2.0 13.7 14.0 14.5 10.0 9.2 10.2 150 159 122 6.1 6.7 6.6 3.0 13.7 14.0 10.0 9.3 149 159 6.2 6.7 4.0 13.7 13.9 10.0 9.4 149 152 6.2 6.7 5.0 13.7 13.9 10.0 9.4 149 151 6.2 6.7 6.0 13.7 10.0 149 6.2 7.0 13.7 9.9 150 6.3 8.0 13.7 9.9 150 6.3 9.0 13.7 9.8 150 6.3 6.8 Appendix B - 9 Table B-2 (continued) Secchi disk Date BFB2 BFF2 BFFU TY12B January 17, 2001 1.7 1.2 1.3 1.3 February 21, 2001 0.6 0.5 0.5 0.5 March 27, 2001 0.3 0.4 1.2 0.6 April 11, 2001 0.7 0.8 1.3 1.3 May 10, 2001 0.9 0.9 0.9 1 June 13, 2001 1.0 0.9 0.9 0.9 July 18, 2001 1.1 0.8 1.1 1.5 August 20, 2001 1.1 0.9 0.9 -- September 18, 2001 0.8 0.9 1.0 October 30, 2001 0.7 0.6 -- November 28, 2001 1.1 0.9 -- -- December 18, 2001 0.6 0.5 0.8 1.0 Missing data due to either measurements were not obtained during sampling or because the Secchi disk was observed on river or lake bottom during sampling. Appendix B - 10 Table B-3 Water temperature, dissolved oxygen, specific conductance, and pH data collected from Blewett Falls L ake (S tations BFB2, BF D2, BFF2, and BFH2) during 20041. January 20, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) (° Q (mg/L) ( µS/cm) B2 F2 H2 B2 F2 H2 B2 F2 H2 B2 F2 H2 0.2 6.9 6.2 6.5 12.4 12.7 13.2 94 98 86 7.8 7.8 8.1 1.0 6.9 6.2 6.5 12.4 12.6 13.3 94 98 86 7.6 7.8 8.1 2.0 6.8 6.1 6.5 12.4 12.6 13.4 94 98 86 7.6 7.8 8.2 3.0 6.8 6.1 12.4 12.6 94 98 7.5 7.8 4.0 6.7 6.1 12.4 12.6 94 98 7.5 7.7 5.0 6.6 6.0 12.4 12.6 94 98 7.5 7.7 6.0 6.5 6.0 12.4 12.6 94 98 7.5 7.7 7.0 6.4 6.0 12.3 12.6 93 98 7.5 7.7 8.0 6.4 12.2 92 7.5 February 22, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) (° Q (mg/L) ( µS/cm) B2 F2 H2 B2 F2 H2 B2 F2 H2 B2 F2 H2 0.2 8.0 8.4 8.3 12.9 12.4 13.0 99 94 119 7.6 7.7 7.6 1.0 7.8 6.8 8.3 12.8 12.6 13.0 100 94 119 7.6 7.6 7.6 2.0 7.7 6.6 8.3 12.8 12.6 12.9 98 94 118 7.6 7.6 7.6 3.0 7.6 6.5 12.7 12.5 102 93 7.6 7.6 4.0 7.6 6.5 12.6 12.5 99 96 7.5 7.6 5.0 7.5 6.5 12.6 12.5 99 96 7.5 7.5 6.0 7.5 6.5 12.5 12.4 101 96 7.5 7.5 7.0 7.5 6.5 12.5 12.4 101 97 7.5 7.5 8.0 7.5 12.4 105 7.5 March 15, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) (° Q (mg/L) (µS/cm) 0.2 11.7 12.4 11.6 13.6 12.2 12.6 98 107 115 8.3 7.9 8.0 1.0 11.5 12.0 11.6 13.5 12.4 12.6 98 108 115 8.3 7.9 8.0 2.0 11.3 11.6 11.6 13.3 12.1 12.6 97 109 114 8.2 7.8 7.9 3.0 10.9 11.6 13.0 11.9 97 108 8.2 7.8 4.0 10.6 11.5 12.6 11.9 95 112 8.1 7.8 5.0 10.4 11.5 12.3 11.9 97 108 8.0 7.8 6.0 10.3 11.5 12.0 11.9 97 110 8.0 7.8 7.0 10.2 11.5 12.0 11.9 98 112 7.9 7.8 8.0 10.1 11.8 94 7.9 Appendix B - 11 Table B-3 (continued) Ap ril 4, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) (° Q (mg/L) (µS/cm) B2 F2 H2 B2 F2 H2 B2 F2 H2 B2 F2 H2 0.2 12.8 13.5 14.4 9.2 9.8 10.1 102 107 150 7.6 8.0 8.3 1.0 12.8 13.5 9.2 9.8 101 107 7.6 8.0 2.0 12.8 13.5 9.2 9.8 102 108 7.6 7.9 3.0 12.8 13.4 9.2 9.8 101 108 7.6 7.9 4.0 12.8 13.4 9.2 9.6 101 111 7.6 7.8 5.0 12.8 12.8 9.2 8.4 102 123 7.6 7.5 6.0 12.8 12.7 9.2 8.0 103 127 7.6 7.6 7.0 12.8 12.7 9.2 7.6 101 131 7.6 7.6 8.0 12.8 9.2 101 7.6 Ma y 10, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) (° Q (mg/L) (µS/cm) B2 F2 H2 B2 F2 H2 B2 F2 H2 B2 F2 H2 0.2 25.2 25.6 22.2 14.1 9.6 11.9 105 117 94 9.6 7.9 8.8 1.0 24.7 24.1 22.2 14.0 9.8 11.9 104 114 94 9.5 7.8 8.9 2.0 23.1 22.8 12.6 9.7 102 114 8.7 7.7 3.0 22.9 22.2 12.0 9.5 101 112 8.6 7.7 4.0 21.9 21.6 10.7 9.0 103 111 8.2 7.6 5.0 21.4 21.5 9.4 8.5 102 108 8.0 7.5 6.0 20.7 8.6 99 7.9 7.0 20.0 7.1 100 7.5 June 21, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) C Q (mg/L) (µS/cm) B2 F2 H2 B2 F2 112 B2 F2 H2 B2 F2 112 0.2 27.8 27.0 26.1 10.5 8.9 7.0 114 108 97 9.2 7.9 7.5 1.0 27.8 26.6 26.1 10.4 8.2 6.9 114 107 96 9.2 7.8 7.3 2.0 27.6 26.0 8.9 6.9 113 103 8.7 7.4 3.0 27.1 25.7 7.0 4.9 114 99 8.2 7.0 4.0 26.6 25.5 5.0 4.4 108 99 7.5 7.0 5.0 26.3 25.4 4.3 3.6 108 99 7.3 6.7 6.0 25.9 25.1 3.4 2.6 108 101 6.9 6.7 7.0 25.7 24.9 3.0 1.5 106 104 6.9 6.6 Appendix B - 12 Table B-3 (continued) July 12,2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) (° C) (mg/L) (µS/cm) B2 F2 H2 B2 F2 H2 B2 F2 H2 B2 F2 H2 0.2 30.9 30.9 29.4 11.2 11.4 11.9 107 107 97 9.0 9.0 8.7 1.0 30.2 30.7 29.4 11.5 11.6 11.9 107 107 97 9.0 9.0 8.7 2.0 29.6 30.2 10.8 12.5 106 108 8.9 9.1 3.0 29.3 28.9 8.0 10.0 104 108 8.2 8.4 4.0 28.4 28.6 4.8 7.7 103 106 7.6 8.0 5.0 28.1 28.0 3.8 4.1 104 107 7.4 7.6 6.0 27.9 27.7 2.9 2.2 105 108 7.2 7.2 7.0 27.8 2.6 105 7.1 8.0 27.6 2.0 107 6.9 August 23, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) (° C) (mg/L) (µS/cm) 0.2 29.8 29.9 30.2 12.4 11.8 11.1 103 100 97 9.3 9.1 9.0 1.0 28.7 27.5 12.6 9.2 102 100 9.3 8.4 2.0 28.1 27.1 10.4 7.1 100 100 9.0 7.9 3.0 27.9 27.0 8.0 5.7 99 101 8.4 7.6 4.0 27.6 26.8 5.9 4.8 100 102 7.8 7.4 5.0 27.2 26.8 4.3 3.1 99 105 7.5 7.2 6.0 27.0 26.6 3.1 1.9 99 109 7.1 7.1 7.0 26.9 26.5 2.9 0.7 100 115 7.0 7.0 8.0 26.7 2.2 101 6.9 September 24, 2004 Depth Temperature Dissolved oxygen Specific conductance pH (m) (° C) (mg/L) (µ S/cm) B2 F2 H2 B2 F2 H2 B2 F2 H2 B2 F2 H2 0.2 23.7 23.8 23.8 7.7 6.8 8.2 101 92 90 7.6 7.4 7.6 1.0 23.7 23.8 23.8 7.7 6.7 8.1 101 92 90 7.6 7.4 7.6 2.0 23.7 23.7 7.6 6.6 101 92 7.5 7.4 3.0 23.7 23.7 7.6 6.6 101 92 7.5 7.3 4.0 23.7 23.5 7.5 6.5 101 93 7.5 7.3 5.0 23.7 23.5 7.4 6.4 101 94 7.5 7.3 6.0 23.7 23.5 7.3 6.3 101 94 7.4 7.3 7.0 23.1 23.5 6.0 6.3 104 95 7.3 7.2 Appendix B - 13 Table B-3 (continued) October 18, 2004 Depth Temperature Di ssolved oxygen Specific conductance pH (m) to C) (mg/L) (µS/cm) B2 F2 112 B2 F2 112 B2 F2 112 B2 F2 H2 0.2 20.4 20.9 20.5 8.0 7.8 7.6 85 83 78 7.5 7.4 7.2 1.0 20.1 20.7 20.4 8.0 7.7 7.5 87 83 78 7.4 7.4 7.2 2.0 19.8 20.4 7.9 7.5 88 82 7.4 7.3 3.0 19.7 20.3 7.7 7.5 89 82 7.4 7.3 4.0 19.6 20.2 7.3 7.5 90 82 7.3 7.3 5.0 19.5 20.2 6.7 7.5 91 82 7.3 7.2 6.0 19.5 20.1 6.5 7.5 92 84 7.2 7.2 7.0 19.3 20.1 6.2 7.3 97 96 7.2 7.1 8.0 19.3 5.9 103 7.1 November 18 and 30,2004 2 Depth Te mperature Dissolved oxygen Specific conductance pH (m) to C) (mg/L) (µS/cm) 0.2 14.6 14.0 15.6 15.7 9.5 10.6 9.4 8.5 93 98 93 84 7.1 7.8 7.0 6.9 1.0 14.6 13.5 15.4 15.7 9.4 10.0 9.3 8.4 93 101 93 84 7.0 7.8 7.0 6.8 2.0 14.3 13.2 15.3 15.7 9.2 9.8 9.2 8.4 100 105 94 84 6.9 7.8 6.9 6.7 3.0 14.2 13.2 15.2 9.2 9.7 9.0 100 106 94 6.8 7.7 6.8 4.0 14.1 13.2 14.8 9.0 9.7 8.9 100 106 97 6.8 7.7 6.8 5.0 13.8 13.2 14.5 8.9 9.6 8.8 103 107 102 6.7 7.7 6.7 6.0 13.7 12.8 14.2 8.8 9.6 8.9 108 116 105 6.7 7.7 6.7 7.0 13.7 12.6 14.1 8.6 9.7 8.9 110 121 107 6.6 7.6 6.6 8.0 13.2 . 14.1 8.5 8.8 130 108 6.6 6.6 December 14, 2004 Depth Temperature Di ssolved oxygen Specific conductance pH (m) C C) (mg /L) (µS/cm) B2 D2 F2 H2 B2 D2 F2 H2 B2 D2 F2 H2 B2 D2 F2 H2 0.2 11.7 10.9 10.3 10.0 9.9 9.8 9.5 10.7 92 100 101 107 7.7 7.7 7.5 7.7 1.0 11.7 10.9 10.3 9.9 9.6 9.5 92 100 100 7.7 7.6 7.5 2.0 11.7 10.9 10.3 9.9 9.6 9.4 92 100 100 7.7 7.6 7.4 3.0 11.7 10.9 10.3 9.8 9.5 9.4 92 100 100 7.6 7.5 7.4 4.0 11.7 10.9 10.3 9.8 9.5 9.3 92 100 101 7.6 7.5 7.4 5.0 11.7 10.9 10.3 9.8 9.5 9.3 92 100 101 7.6 7.5 7.4 6.0 11.7 11.0 10.3 9.7 9.5 9.3 93 100 102 7.6 7.5 7.4 7.0 11.7 9.6 93 7.5 No water quality data were collected at Station D2 for January through October 2004. 2 Stations B2, F2, and H2 data were collected on November 18 while StationD2 data were collected on November 30. Appendix B - 14 Table B-3 (continued) Station Date BFB2 BFD2 BFF2 BFH2 January 20, 2004 0.9 ND' 1.2 2.02 February 22, 2004 0.8 ND 0.9 1.0 March 15, 2004 0.7 ND 0.7 1.0 April 4, 2004 0.6 ND 0.9 1.0 May 10, 2004 0.8 ND 0.8 1.02 June 21, 2004 0.9 ND 0.8 1.1 July 12, 2004 1.1 ND 0.9 0.9 August 23, 2004 0.7 ND 0.6 0.7 September 24, 2004 0.6 ND 0.7 1.0 October 18, 2004 0.3 ND 0.7 1.02 November 18 and 30', 2004 1.0 0.7 1.5 1.4 December 14, 2004 0.5 0.3 0.4 0.4 1 No Secchi disk transparency measurements were taken at Station BFD2 from January through October 2004. 2 Missing data due to either measurements were not obtained during sampling or because the Secchi disk was observed on river or lake bottom during sampling. In such instances, the depth of the lake bottom is listed as a reference to Secchi disk transparency depth. 3 Secchi disk transparency measurements were taken at Stations 1317132, BFF2, and BFH2 on November 18th and at Station BFD2 on November 30th. Appendix B - 15 Table B-4 Water temperature, dissolved oxygen, specific conductance, pH, Secchi disk transparency, and turbidity data collected from the Pee Dee River (Stations BF113, BF2B, BF3B, BF4B, and BF5B) below the Blewett Falls Hydroelectric Plant during 1999. Station BF1B Date oxygen conductance Secchi disk Turbidity (NTil) 01/18/99 9.1 10.7 92 6.9 18 02/02/99 8.8 11.3 81 6.8 -- 26 03/04/99 10.9 11.4 95 6.4 0.5 25 04/15/99 19.1 8.6 102 6.2 1.1 7.7 05/13/99 20.1 6.9 105 6.0 1.0 9.4 06/10/99 27.3 7.4 138 6.8 1.0 12 07/13/99 26.1 5.3 144 6.9 0.5 33 08/02/99 29.4 4.4 150 7.3 0.9 13 09/08/99 27.1 5.7 156 7.5 0.5 24 10/20/99 19.4 6.2 106 7.3 0.5 34 11/09/99 16.5 7.7 121 7.0 1.5 12 12/02/99 10.7 7.3 132 7.1 1.3 8.5 Station BF2B Dissolved Specific Temperature oxygen conductance Secchi disk Turbidity (NTil) Date (C) (mg/L) (CDS/cm) pH depth (m) 01/18/99 10.4 11.4 89 6.9 44 02/02/99 9.4 11.0 78 6.7 -- 32 03/04/99 10.2 12.0 86 6.5 0.9 12 04/15/99 17.8 9.5 95 6.3 -- 48 05/13/99 22.0 8.8 112 6.6 1.5 7.8 06/10/99 27.7 7.8 148 7.3 1.6 7.4 07/13/99 24.5 7.8 136 7.0 1.7 6.2 08/02/99 32.2 8.3 162 7.3 1.8 3.8 09/08/99 27.1 8.5 160 7.4 1.9 5.0 10/20/99 19.4 7.4 104 7.4 0.7 25 11/09/99 16.3 9.6 112 7.3 1.7 6.0 12/01/99 12.6 9.9 118 6.9 1.3 11 Station BF3B Dissolved Specific Temperature oxygen conductance Secchi disk Turbidity (NTil) Date (C) (mg/L) (CDS/cm) pH depth (m) 01/18/99 10.1 11.5 96 6.9 23 02/02/99 9.3 10.9 81 6.7 -- 30 03/04/99 10.7 10.7 107 6.9 0.7 18 04/15/99 17.9 9.4 124 6.3 1.2 9.1 05/13/99 21.1 7.9 133 6.4 0.8 20 06/10/99 27.6 7.6 178 7.2 0.9 15 07/13/99 24.3 7.2 189 7.0 0.8 23 08/02/99 32.3 8.2 197 7.2 0.6 9.4 09/08/99 27.9 6.8 220 7.3 0.8 19 10/20/99 19.2 7.7 109 7.3 0.6 32 11/09/99 16.0 8.5 134 7.3 1.2 6.9 12/01/99 12.4 9.3 123 6.8 1.0 17 Appendix B - 16 Table B-4 (continued) Station BF4B Dissolved Specific Temperature oxygen conductance Secchi disk Turbidity Date ($C) (mg/L) ((DS/cm) pH depth (m) (NTil) 01/18/99 9.6 11.0 90 6.8 23 02/03/99 9.6 10.8 81 6.7 -- 30 03/04/99 10.1 10.5 96 6.7 0.6 18 04/15/99 19.2 7.3 119 6.4 0.8 9.1 05/13/99 21.8 7.2 128 6.7 0.5 20 06/10/99 28.4 7.0 210 7.1 0.7 15 07/13/99 23.8 5.2 158 6.7 0.4 23 08/02/99 31.0 7.6 233 6.8 0.7 9.4 09/08/99 27.2 6.9 232 7.2 0.6 19 10/20/99 19.8 5.1 85 7.0 0.4 32 11/09/99 14.5 7.2 76 7.2 0.5 6.9 12/01/99 12.7 9.2 118 6.7 0.8 17 Station BF5B Dissolved Specific Temperature oxygen conductance Secchi disk Turbidity Date ($C) (mg/L) ((DS/cm) pH depth (m) (NTil) 01/18/99 9.5 10.8 96 6.7 28 02/03/99 11.1 8.6 73 6.6 -- 21 03/04/99 10.8 10.4 98 6.5 0.5 29 04/15/99 19.1 6.6 144 6.4 0.6 24 05/13/99 21.0 5.7 97 6.6 0.6 17 06/10/99 28.3 7.6 188 7.0 0.5 34 07/13/99 27.3 6.1 194 6.6 0.7 23 08/02/99 32.1 8.0 249 7.1 0.5 27 09/08/99 26.8 6.0 229 7.2 0.5 29 10/20/99 20.3 5.0 95 7.1 0.5 26 11/09/99 15.1 7.5 131 7.0 1.0 12 12/01/99 12.6 8.4 124 6.7 0.6 29 Appendix B - 17 Table B-5 Water temperature, dissolved oxygen, specific conductance, pH, Secchi disk transparency, and turbidity data collected from the Pee Dee River (Stations BF113, BF2B, BF3B, BF4B, and BF5B) below the Blewett Falls Hydroelectric Plant during 2001. Station BF1B Dissolved Specific oxygen conductance Secchi disk Date 02/20/01 11.7 10.5 130 6.9 0.7 18 03/26/01 12.6 10.2 94 6.9 0.4 43 04/10/01 19.4 10.8 115 6.8 1.2 4.9 05/09/01 23.6 9.2 147 7.2 1 5.5 06/12/01 26.9 6.3 123 7.3 1.3 4.2 07/17/01 27.6 5.3 141 7.4 0.7 14 08/19/01 29.3 4.8 188 7.3 -- 8.0 09/17/01 25.3 10.0 162 6.3 -- 4.5 10/29/01 16.5 10.4 188 6.8 2.2 3.1 11/27/01 16.5 9.4 210 7.9 -- 2.1 12/17/01 14.1 8.8 156 6.2 1.1 12 Station BF2B Dissolved Specific Temperature oxygen conductance Secchi disk 02/20/01 11.8 12.5 127 7.0 1.3 11 03/26/01 13.9 11.5 84 6.7 0.6 31 04/10/01 19.2 9.7 117 6.6 1.0 9.3 05/09/01 22.3 9.6 146 7.3 -- 2.2 06/12/01 27.7 7.9 136 7.9 1.9 07/17/01 28.9 8.8 173 7.2 4.3 08/19/01 28.8 7.8 189 7.4 6.9 09/17/01 23.0 10.2 167 6.7 2.6 10/29/01 13.7 13.2 146 7.7 1.6 11/27/01 17.7 10.3 200 7.9 1.5 12/17/01 13.9 11.0 152 6.3 3.5 Station BF3B Dissolved Specific Temperature oxygen conductance Secchi disk Date ($C) (mg/L) ((DS/cm) pH depth (m) Turbidity (NTil) 01/16/01 9.8 12.2 126 7.3 -- 6.5 02/20/01 10.7 11.1 151 7.0 1.0 13 03/26/01 13.9 9.9 115 6.6 0.5 35 04/10/01 19.1 9.4 125 6.7 0.7 18 05/09/01 22.6 7.6 198 7.2 -- 5.3 06/12/01 27.8 7.1 148 7.2 5.4 07/17/01 28.7 7.5 173 6.9 12 08/19/01 29.3 6.0 314 7.2 10 09/17/01 24.3 8.0 211 6.0 6.5 10/29/01 17.2 11.1 326 7.0 2.6 11/27/01 18.9 8.6 292 7.5 7.7 12/17/01 14.9 9.8 216 6.2 17 Appendix B - 18 Table B-5 (continued) Station BF4B Dissolved Specific Temperature oxygen conductance Secchi disk Turbidity Date ($C) (mg/L) ((DS/cm) pH depth (m) (NTil) 01/16/01 10.3 10.6 79 6.6 0.7 13 02/20/01 10.7 11.1 109 6.6 0.5 37 03/26/01 12.5 9.2 89 6.5 0.4 47 04/10/01 18.0 8.7 113 6.5 0.7 22 05/09/01 22.8 9.3 167 7.1 -- 30 06/12/01 26.1 5.2 139 6.7 0.7 12 07/17/01 28.7 8.9 211 6.8 0.6 21 08/19/01 29.5 6.8 203 7.4 -- 21 09/17/01 22.8 9.1 240 6.3 9.1 10/29/01 15.6 11.0 197 6.8 4.1 11/27/01 17.7 8.6 310 7.5 4.5 12/17/01 14.7 8.6 244 6.4 8.6 Station BF5B Dissolved Specific Temperature oxygen conductance Secchi disk Turbidity Date ($C) (mg/L) ((DS/cm) pH depth (m) (NTil) 01/16/01 8.4 11.7 115 6.5 1.0 11 02/20/01 11.7 9.8 116 6.5 0.5 40 03/26/01 12.2 8.7 91 6.4 0.5 41 04/10/01 18.0 7.1 108 6.0 0.6 17 05/09/01 22.6 7.3 179 7.0 -- 15 06/12/01 27.1 6.7 185 7.2 0.5 14 07/17/01 28.2 9.0 198 6.4 0.6 17 08/19/01 29.4 6.0 248 7.4 -- 37 09/17/01 23.1 8.1 243 6.2 -- 13 10/29/01 15.7 12.4 173 7.0 1.0 5.2 11/27/01 17.9 8.5 234 6.9 1.1 6.0 12/17/01 13.9 9.9 253 6.0 0.9 14 Missing data due to either measurements were not obtained during sampling or because the Secchi disk was observed on river or lake bottom during sampling. Appendix B - 19 Table B-6 Water temperature, dissolved oxygen, specific conductance, and pH data collected from the Pee Dee River (Stations BFOB, BF1B, BF2B, BF3B, and BF4B) below the Blewett Falls Development during 2004. Station BFOB (Generation Flow) Dissolved oxygen Specific conductance Turbidity Date Temperature (BC) (mg/L) ((DS/cm) pH (NTil) 1/20/2004 6.8 12.4 92 7.7 10 2/22/2004 7.4 12.5 102 7.6 22 3/15/2004 10.5 12.2 98 7.8 24 4/4/2004 13.0 8.6 101 7.7 24 5/10/2004 22.2 9.9 99 7.5 2.2 6/21/2004 26.6 5.7 109 7.4 32 7/12/2004 28.7 5.7 105 7.1 9.7 8/23/2004 28.1 8.2 99 8.1 6.5 9/24/2004 23.7 7.3 102 7.4 18 10/18/2004 19.7 7.1 90 7.2 27 11/18/2004 14.0 8.7 103 7.1 19 12/13/2004 12.4 10.1 94 7.4 25 Station BF1B (Non Generation Flow) Dissolved oxygen Specific conductance Turbidity Date Temperature (BC) (mg/L) ((DS/cm) pH (NTU) 1/19/2004 7.8 12.5 94 7.8 19 2/22/2004 6.5 11.5 102 7.6 17 3/14/2004 9.9 11.1 94 7.9 17 4/4/2004 12.5 7.6 102 7.8 13 5/14/2004 23.4 7.6 94 7.3 0.6 6/22/2004 25.5 7.7 106 7.5 15 7/13/2004 27.2 3.3 102 7.0 3.0 8/23/2004 27.6 4.5 95 7.0 6.3 9/24/2004 22.5 5.9 102 7.5 9.1 10/25/2004 18.9 6.3 89 7.2 13 11/15/2004 15.0 8.0 95 6.9 6.6 12/8/2004 12.9 8.7 111 7.3 9.1 Station BF1B (Generation Flow) Dissolved oxygen Specific conductance Turbidity Date Temperature (BC) (mg/L) ((DS/cm) pH (NTU) 1/20/2004 7.0 13.1 90 7.8 11 2/22/2004 8.3 12.9 100 7.8 21 3/15/2004 10.8 12.2 97 7.7 27 4/4/2004 16.0 9.6 98 7.9 33 5/10/2004 22.0 6.3 99 7.2 2.1 6/21/2004 26.0 4.4 109 7.5 28 7/12/2004 29.1 4.9 102 7.0 14 8/23/2004 29.5 4.4 93 7.0 11 9/24/2004 22.5 5.8 102 7.3 19 10/18/2004 19.9 6.9 92 7.1 17 11/17/2004 14.2 8.8 115 6.7 15 12/13/2004 12.2 10.6 94 7.6 23 Appendix B - 20 Table B-6 (continued) Station BF2B (Non Generation Flow) Dissolved oxygen Specific conductance Turbidity Date Temperature (BC) (mg/L) (cpS/cm) pH (NTU) 1/18/2004 7.7 12.6 88 7.9 2.2 2/25/2004 7.9 11.9 105 7.7 19 3/14/2004 12.5 12.7 96 7.9 17 4/4/2004 13.2 9.8 97 8.0 9 5/14/2004 22.8 9.1 93 7.4 0.7 6/21/2004 27.3 7.9 103 8.1 12 7/12/2004 31.1 8.4 104 9.2 1.2 8/23/2004 27.2 7.4 97 7.6 7 9/24/2004 23.4 7.7 104 7.5 14 10/18/2004 20.1 8.9 90 7.5 15 11/15/2004 14.5 10.1 95 7.0 16 12/8/2004 13.8 10.2 105 7.1 12 Station BF2B (Generation Flow) Temperature (BC) Dissolved oxygen Specific conductance Turbidity Date (mg/L) ((DS/cm) pH (NTU) 1/20/2004 6.8 13.9 93 8.6 13 2/22/2004 8.5 13.0 99 7.7 34 3/15/2004 13.0 11.4 95 7.8 29 4/6/2004 14.0 11.2 104 7.8 9.5 5/10/2004 21.0 8.7 98 7.2 1.4 6/23/2004 26.8 6.5 105 7.3 52 7/15/2004 30.2 8.2 113 8.1 5.6 8/26/2004 27.4 6.8 102 7.5 9.8 9/22/2004 21.6 6.9 112 7.3 20 10/21/2004 20.9 6.4 78 7.4 24 11/17/2004 14.8 10.5 94 7.1 25 12/14/2004 11.1 10.6 93 7.7 11.2 Station BF3B (Generation Flow) Dissolved oxygen Specific conductance Turbidity Date Temperature (BC) (mg/L) ((DS/cm) pH (NTU) 1/21/2004 5.9 12.9 103 7.9 12 2/25/2004 9.1 11.8 116 7.6 21 3/14/2004 11.8 11.6 99 7.6 19 4/6/2004 14.5 10.1 124 7.4 16 5/12/2004 23.0 7.9 115 7.5 1.5 6/23/2004 27.7 7.3 136 7.1 47 7/15/2004 30.4 6.7 129 8.0 15 8/26/2004 28.2 7.0 151 7.5 16 9/22/2004 22.5 7.0 126 7.3 24 10/21/2004 20.8 7.9 103 7.2 19 11/17/2004 13.9 9.1 109 6.9 18 12/14/2004 11.7 9.5 99 7.5 19 Appendix B - 21 Table B-6 (continued) Station BF4B (Generation Flow) Dissolved oxygen Specific conductance Turbidity Date Temperature (BC) (mg/L) (cpS/cm) pH (NTU) 1/21/2004 7.2 11.5 135 7.6 16 2/25/2004 9.2 11.5 112 7.5 22 3/14/2004 12.2 11.0 105 7.5 25 4/6/2004 15.5 8.8 110 7.0 25 5/12/2004 22.1 7.5 122 7.4 2.9 6/23/2004 28.6 6.2 182 7.2 39 7/15/2004 30.5 5.9 160 7.8 52 8/26/2004 27.7 6.7 149 7.2 12 9/22/2004 21.5 3.1 98 6.8 16 10/21/2004 20.5 7.6 111 7.1 21 11/18/2004 12.6 9.5 117 7.1 21 12/14/2004 11.9 9.5 102 7.4 34 Appendix B - 22 APPENDIX C RAW DATA LISTING FOR WATER CHEMISTRY PARAMETERS COLLECTED IN LAKE TILLERY, THE PEE DEE RIVER, AND THE ROCKY RIVER DURING 2000, 2002, AND 2004 Table C-1 Concentrations of water chemistry parameters in Lake Tillery (Stations TYB2, TYF2, and TYK2) and the Pee Dee River (Stations TY1B and TY12B) during 2000.1 Lake Tillery (Station TYB2, surface) -2000 Month Total Hardness Cl- SO-q Ca 2+ Mg2+ Na TN NH3-N Nitrate + TP Alkalinity (calculated) nitrite-N Jan 32 22 13 10 5.2 2.1 11 0.37 < 0.05 < 0.02 0.037 Feb 27 24 13 9.0 5.6 2.3 12 0.94 <0.05 0.61 0.032 Mar 24 24 12 8.0 5.8 2.4 11 0.87 < 0.05 0.35 0.049 Apr 28 25 11 8.0 6.0 2.5 11 0.94 < 0.05 0.53 0.040 May 22 23 12 9.3 5.5 2.3 9.1 0.75 0.08 0.57 0.028 Jun 21 20 11 7.0 4.3 2.2 8.4 0.59 < 0.05 0.31 0.012 Jul 21 22 7.0 8.0 4.9 2.3 9.3 0.31 < 0.05 0.05 0.018 Aug 28 20 12 8.0 4.4 2.2 8.6 0.64 < 0.05 0.02 0.016 Sep 27 21 12 8.0 4.7 2.3 9.7 0.18 <0.05 0.07 0.018 Oct 28 20 13 7.0 4.5 2.2 10 <0.50 <0.05 0.02 0.018 Nov 26 20 14 9.0 4.4 2.2 11 0.56 < 0.05 0.22 0.030 Dec 30 22 15 10 5.0 2.4 13 0.62 0.11 0.22 0.030 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 3.0 8.7 72 <5 73 130 1.6 <0.2 NV 21 Feb 2.9 7.0 78 <5 67 160 1.4 <0.2 <2 <20 Mar 3.2 5.4 88 <5 74 98 2.3 <0.2 3.0 <20 Apr 3.5 8.3 92 <5 83 250 2.0 <0.2 <2 <20 May 3.8 7.0 54 <5 80 <100 1.7 <0.2 <2 <20 Jun 3.4 5.1 70 <5 61 <50 1.5 <0.2 <2 <20 Jul 3.3 3.5 56 <5 61 <50 1.2 <0.2 <2 48 Aug 3.7 1.7 62 <3 68 <50 1.6 <0.2 <2 <20 Sep 4.1 2.6 68 <3 83 67 1.2 <0.2 <2 <20 Oct 3.3 2.9 58 <5 67 71 1.9 <0.2 <2 <20 Nov 3.4 3.7 72 <5 81 59 1.3 <0.2 <2 <20 Dec 3.7 5.7 60 <5 39 <50 1.6 <0.2 <2 <20 Appendix C - 1 Table C-1 (continued) Lake Tillery (Station TYB2, bottom)-2000 Month Total Hardness CI SO4 Cap' Mgr' Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 24 21 13 10 5.1 2.1 11 0.83 <0.05 0.52 0.035 Feb 29 25 12 9.0 6.0 2.5 12 0.59 <0.05 0.59 0.033 Mar 20 24 12 8.0 5.8 2.4 11 0.86 < 0.05 0.56 0.056 Apr 26 25 12 8.0 5.9 2.5 10 0.97 < 0.05 0.60 0.040 May 21 23 11 9.0 5.4 2.2 8.9 0.64 0.06 0.64 0.044 Jun 23 13 11 7.0 4.9 2.2 8.0 0.62 0.10 0.62 0.036 Jul 23 24 7.0 8.0 5.5 2.4 9.0 0.69 < 0.05 0.39 0.020 Aug 32 23 12 7.0 5.2 2.4 8.8 0.91 0.20 0.06 0.058 Sep 27 22 12 7.0 4.9 2.4 10 0.37 <0.05 0.07 0.020 Oct 30 21 13 8.0 4.6 2.3 11 0.81 <0.05 0.04 0.036 Nov 24 20 14 9.0 4.3 2.2 11 0.57 <0.05 0.23 0.026 Dec 30 22 14 9.0 4.8 2.3 12 0.59 <0.05 0.23 0.030 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 3.1 9.8 72 6.0 52 170 1.4 < 0.2 ND < 20 Feb 2.9 19 86 <5 71 180 1.5 <0.2 <2 <20 Mar 3.1 8.8 92 <5 83 280 2.7 <0.2 <2 <20 Apr 3.4 15 100 <5 86 330 2.2 <0.2 <2 <20 May 3.6 20 68 8.0 81 160 1.7 <0.2 <2 <20 Jun 3.1 14 72 < 5 76 140 2.1 0.2 < 2 < 20 Jul 3.2 5.0 46 <5 66 <50 <1.0 0.3 <2 <20 Aug 3.3 15 74 <3 82 <50 1.3 0.9 <2 <20 Sep 4.2 8.0 82 <3 76 <50 1.4 0.4 <2 <20 Oct 3.7 12 60 <5 69 120 1.8 0.5 <2 34 Nov 3.4 5.5 86 <5 84 120 1.4 <0.2 <2 <20 Dec 3.8 7.0 70 <5 51 63 1.7 <0.2 <2 <20 Appendix C - 2 Table C-1 (continued) Lake Tillery (Station TYF2, surface)-2000 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 24 22 12 10 5.3 2.2 11 0.86 < 0.05 0.57 0.039 Feb 24 25 11 8.0 5.9 2.6 9.5 0.64 <0.05 0.47 0.070 Mar 24 25 13 8.0 5.9 2.4 11 0.98 < 0.05 0.45 0.080 Apr 27 25 12 8.0 5.9 2.4 10 0.95 < 0.05 0.56 0.048 May 21 23 11 9.0 5.5 2.3 9.0 0.52 0.06 0.52 0.055 Jun 21 20 11 7.0 4.2 2.2 8.2 0.28 < 0.05 0.28 0.018 Jul 22 22 8.0 8.0 5.0 2.4 9.6 0.28 < 0.05 < 0.02 0.024 Aug 24 20 11 7.0 4.5 2.3 9.1 0.64 < 0.05 0.02 0.024 Sep 25 20 12 7.0 4.4 2.2 9.8 0.28 <0.05 0.02 0.028 Oct 31 19 13 8.0 4.2 2.1 10 1.1 <0.05 <0.02 0.031 Nov 26 19 9.0 9.0 4.3 2.1 11 0.68 < 0.05 0.32 0.028 Dec 30 24 11 11 5.6 2.4 13 0.75 0.07 0.40 0.028 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.7 8.7 66 <5 79 150 1.6 <0.2 ND <20 Feb 4.1 46 94 19 81 1,200 4.2 <0.2 <2 <20 Mar 4.0 7.2 90 6.0 68 150 1.7 <0.2 4.0 <20 Apr 3.5 8.4 92 <5 92 250 2.0 <0.2 2.0 23 May 3.9 8.7 74 6.0 81 <100 1.9 <0.2 4.0 <20 Jun 3.4 3.8 66 <5 66 <50 2.0 <0.2 <2 21 Jul 3.5 3.5 52 <5 57 <50 1.0 <0.2 <2 <20 Aug 3.8 2.2 66 <3 72 <50 1.3 <0.2 <2 <20 Sep 3.6 3.6 92 <3 76 <50 1.1 <0.2 <2 <20 Oct 3.8 3.5 60 <5 60 <50 1.4 <0.2 3.0 45 Nov 3.9 3.0 78 <5 88 <50 1.4 <0.2 <2 <20 Dec 3.6 3.8 70 <5 43 <50 2.0 <0.2 <2 <20 Appendix C - 3 Table C-1 (continued) Lake Tillery (Station TYF2, bottom)-2000 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 29 22 13 10 5.3 2.2 11 0.74 < 0.05 0.59 0.068 Feb 22 26 11 8.0 5.8 2.7 9.1 0.66 <0.05 0.47 0.065 Mar 20 25 12 8.0 6.0 2.4 11 0.84 < 0.05 0.55 0.052 Apr 26 25 11 8.0 5.9 2.4 10 0.96 < 0.05 0.62 0.041 May 24 26 9.9 7.8 6.0 2.6 6.8 0.70 0.10 0.45 0.054 Jun 23 20 11 7.0 4.5 2.2 8.1 0.43 0.05 0.43 0.025 Jul 24 24 11 8.0 5.6 2.5 9.6 0.56 < 0.05 0.36 0.020 Aug 28 22 12 8.0 5.0 2.4 10 0.79 0.06 0.18 0.026 Sep 33 22 13 8.0 4.8 2.3 11 0.40 0.13 0.09 0.037 Oct 30 21 15 9.0 4.7 2.3 12 1.1 <0.05 0.20 0.023 Nov 24 20 10 9.0 4.5 2.2 12 0.72 < 0.05 0.31 0.044 Dec 39 23 11 11 5.3 2.3 13 0.77 0.61 0.41 0.026 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.7 11 70 <5 75 150 1.1 <0.2 ND <20 Feb 3.9 50 96 8.0 83 2,000 4.5 <0.2 <2 <20 Mar 3.3 8.7 76 <5 84 230 1.9 0.2 <2 20 Apr 3.5 13 94 <5 97 300 2.3 <0.2 <2 <20 May 5.1 23 74 9.0 90 < 100 2.3 0.5 < 2 < 20 Jun 3.5 11 80 9.0 69 <50 1.4 0.2 <2 <20 Jul 3.3 4.7 48 <5 60 53 3.0 0.2 <2 <20 Aug 3.4 5.7 72 <3 80 <50 1.4 <0.2 <2 <20 Sep 3.3 11 104 5.2 92 120 1.5 <0.2 <2 <20 Oct 3.6 8.3 62 <5 67 110 2.0 0.3 <2 21 Nov 3.7 11 88 <5 89 89 1.5 <0.2 <2 <20 Dec 4.0 6.3 76 <5 59 <50 1.5 <0.2 <2 <20 Appendix C - 4 Table C-1 (continued) Lake Tillery (Station TYK2, surface)-2000 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 24 23 13 10 5.5 2.4 11 0.62 < 0.05 0.62 0.043 Feb 27 24 12 9.0 5.8 2.3 11 0.70 0.09 0.53 0.038 Mar 20 25 13 8.0 6.1 2.4 11 0.82 < 0.05 0.52 0.059 Apr 23 24 11 8.0 5.6 2.3 9.9 0.98 0.08 0.65 0.044 May 21 23 12 9.4 5.4 2.2 9.0 1.0 0.09 0.62 0.043 Jun 23 20 11 7.0 4.5 2.2 8.3 0.66 < 0.05 0.42 0.026 Jul 24 24 12 8.0 5.4 2.5 11 0.41 < 0.05 0.26 0.022 Aug 28 24 12 8.0 5.3 2.5 11 0.85 < 0.05 0.19 0.029 Sep 31 22 9.0 8.0 4.9 2.3 12 0.25 <0.05 0.07 0.025 Oct 31 21 9.0 8.0 4.7 2.2 13 1.0 <0.05 0.26 0.024 Nov 24 20 14 10 4.6 2.1 12 0.74 < 0.05 0.40 0.030 Dec 13 23 16 11 5.4 2.4 13 0.76 <0.05 0.45 0.024 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.6 9.1 72 7.0 74 440 1.5 <0.2 ND <20 Feb 2.8 20 86 <5 82 540 1.8 <0.2 <2 <20 Mar 3.6 9.6 76 <5 80 280 1.9 <0.2 <2 <20 Apr 3.5 11 98 <5 95 360 1.9 <0.2 <2 <20 May 3.2 8.8 54 <5 83 <100 1.4 <0.2 <2 <20 Jun 3.2 5.9 78 <5 53 73 1.2 <0.2 <2 <20 Jul 2.8 5.0 50 <5 68 <50 <1.0 <0.2 <2 <20 Aug 3.6 4.8 76 <3 81 <50 1.3 <0.2 <2 <20 Sep 3.4 3.6 98 <3 90 <50 1.3 <0.2 <2 <20 Oct 3.4 4.0 66 <5 56 <50 1.6 <0.2 <2 38 Nov 3.8 2.8 90 <5 89 <50 1.3 <0.2 <2 <20 Dec ND 3.6 74 <5 69 <50 1.8 <0.2 <2 <20 Appendix C - 5 Table C-1 (continued) Lake Tillery (Station TYK2, bottom)-2000 Month Total Alkalinity Hardness (calculated) CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ nitrite-N TP Jan 24 22 13 10 5.2 2.1 11 0.95 < 0.05 0.62 0.046 Feb 24 24 12 9.0 5.8 2.3 11 0.85 <0.05 0.55 0.058 Mar 24 24 13 8.0 5.7 2.3 11 0.92 <0.05 0.58 0.060 Apr 23 24 11 8.0 5.7 2.3 10 1.02 < 0.05 0.65 0.044 May 21 31 11 9.3 5.3 2.2 9.1 0.62 0.09 0.62 0.042 Jun 23 21 10 7.0 4.6 2.2 8.2 0.43 <0.05 0.43 0.032 Jul 23 23 12 8.0 5.3 2.4 11 0.27 < 0.05 0.27 0.050 Aug 32 23 13 8.0 5.2 2.4 11 0.80 <0.05 0.12 0.028 Sep 29 22 13 8.0 4.9 2.3 12 0.21 0.06 0.07 0.025 Oct 31 21 14 9.0 4.7 2.2 13 1.1 <0.05 0.29 0.026 Nov 26 20 10 10 4.5 2.1 11 0.74 < 0.05 0.40 0.032 Dec 30 23 16 10 5.4 2.4 14 0.87 0.08 0.47 0.024 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.6 8.6 78 <5 78 160 1.5 <0.2 ND <20 Feb 3.0 20 94 <5 77 680 2.6 <0.2 <2 <20 Mar 3.7 9.8 82 <5 76 330 1.8 <0.2 <2 <20 Apr 3.7 11 90 <5 88 360 2.2 <0.2 <2 31 May 3.3 8.9 58 <5 84 110 2.0 <0.2 <2 <20 Jun 3.2 6.0 70 6.0 71 71 1.3 <0.2 <2 <20 Jul 2.9 8.1 50 <5 59 <50 <1.0 0.3 <2 <20 Aug 3.8 4.2 72 <3 84 <50 1.6 0.4 <2 <20 Sep 3.7 3.5 92 <3 96 <50 1.4 0.5 <2 <20 Oct 3.6 4.3 58 <5 57 94 2.9 0.2 <2 36 Nov 3.6 2.8 92 <5 82 76 1.4 <0.2 <2 <20 Dec 3.6 3.5 66 <5 66 <50 2.2 <0.2 <2 <20 Units are in mg/liter except trace metals which are in (Dg/liter and turbidity which is in NTU. Total alkalinity is measured as mg/L as CaCO, and hardness is calculated as mg equivalents CaCO,/L. 2 ND means no data collected for that particular station location, depth, and sample date. Appendix C - 6 Table C-2 Concentrations of water chemistry parameters in Lake Tillery (Stations TYB2, TYF2, and TYK2) during 2002.1 Lake Tillery (Station TYB2, surface) -2002 Month Total Hardness CI SOq Ca 2+ Mg2+ Na TN NH3-N Nitrate + TP Alkalinity (calculated) nitrite-N Jan 32 26 12 12 6.8 2.2 13 <0.10 0.02 0.26 0.024 Feb 28 25 15 13 6.4 2.3 12 0.37 0.05 0.07 0.042 Mar 24 26 14 12 6.6 2.3 9.9 0.48 <0.02 0.55 0.031 Apr 25 29 11 12 6.6 3.0 10 1.45 <0.02 0.54 0.027 May 18 26 10 12 6.7 2.4 10 0.37 <0.02 0.32 0.020 Jun 27 40 14 11 9.7 3.8 9.1 0.44 <0.02 0.14 0.020 Jul 21 29 11 12 4.8 4.0 11 0.31 <0.02 <0.02 0.020 Aug 23 12 9.5 12 2.3 1.6 13 0.46 <0.02 <0.02 0.018 Sep 24 8.2 11 13 1.4 1.2 11 0.33 <0.02 <0.02 0.014 Oct 22 8.6 12 14 1.7 1.0 10 0.51 0.03 0.21 0.024 Nov 26 21 10 14 4.9 2.2 11 0.45 0.02 0.36 0.026 Dec 20 23 7.4 17 5.3 2.5 6.5 1.39 0.08 0.59 0.052 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 3.6 3.0 77 1.6 74 88 2.2 <0.2 <2 16 Feb 3.4 11 90 7.8 86 197 2.1 <0.2 2 14 Mar 2.3 5.0 68 <1.0 97 316 2.2 <0.2 <2 <10 Apr 2.9 3.3 57 4.8 80 57 1.9 <0.2 <2 17 May 3.4 2.8 73 1.6 44 <50 1.6 <0.2 2 <10 Jun 3.8 2.7 85 3.6 71 <50 1.1 <0.2 <2 16 Jul 3.3 1.5 72 2.8 63 <50 1.8 <0.2 <2 17 Aug 2.7 2.0 63 2.0 97 <50 1.2 <0.2 <2 13 Sep 2.8 1.5 68 1.0 62 <50 <1.0 <0.2 <2 21 Oct 4.9 4.9 56 1.2 72 644 1.7 <0.2 <2 13 Nov 3.8 3.6 83 3.6 88 309 1.6 <0.2 <2 18 Dec 4.4 18 74 4.0 78 176 3.0 <0.2 <2 22 Appendix C - 7 Table C-2 (continued) Lake Tillery (Station TYB2, bottom)-2002 Month Total Alkalinity Hardness (calculated) CI SO4 Cap' Mgr' Na TN NH3-N Nitrate+ nitrite-N TP Jan 31 26 13 12 6.7 2.6 14 0.54 0.02 0.29 0.062 Feb 28 25 15 12 6.3 2.2 12 0.34 0.03 0.12 0.051 Mar 25 27 16 12 6.8 2.4 11 0.53 < 0.02 0.64 0.030 Apr 22 27 14 12 6.1 2.8 9.8 1.19 0.05 0.67 0.039 May 20 26 11 12 6.6 2.4 10 0.27 < 0.02 0.59 0.021 Jun 25 38 13 10 9.3 3.5 8.4 0.38 0.05 0.42 0.018 Jul 21 32 11 12 5.9 4.1 11 0.18 0.04 0.4 0.021 Aug 37 18 9.2 8.2 4.3 1.7 12 0.71 0.41 <0.02 0.089 Sep 36 11 10 5.1 2.5 1.2 8.4 0.86 0.55 <0.02 0.184 Oct 22 8.7 13 14 1.8 1.0 11 0.51 0.05 0.22 0.031 Nov 25 18 11 14 3.6 2.1 11 0.47 0.03 0.36 0.027 Dec 18 24 7.0 18 5.4 2.5 6.3 1.27 0.25 0.57 0.066 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 4.4 4.5 88 29 79 402 2.1 <0.2 <2 13 Feb 3.6 17 100 8.4 82 280 2.6 <0.2 <2 15 Mar 2.2 21 79 1.2 106 245 2.2 <0.2 <2 11 Apr 2.5 21 70 9.8 92 248 2.2 <0.2 <2 17 May 2.9 18 74 5.4 46 137 1.7 <0.2 <2 <10 Jun 3.5 5.0 90 4.2 78 98 1.2 <0.2 <2 12 Jul 2.6 2.5 84 1.2 70 <50 <1.0 <0.2 <2 12 Aug 3.0 2.8 75 1.2 110 <50 <1.0 <0.2 <2 15 Sep 5.2 23 87 7.7 75 351 1.0 <0.2 3.4 32 Oct 4.6 ND 75 3.6 77 1,324 1.9 <0.2 <2 14 Nov 3.6 6.5 79 4.2 83 307 1.9 <0.2 <2 20 Dec 4.6 27 77 10 69 203 2.2 <0.2 <2 20 Appendix C - 8 Table C-2 (continued) Lake Tillery (Station TYF2, surface)-2002 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 32 25 13 12 6.2 2.2 14 0.58 0.23 0.43 0.026 Feb 28 25 16 13 6.3 2.3 13 0.28 0.08 0.15 0.034 Mar 23 25 14 12 6.1 2.3 9.1 0.38 <0.02 0.69 0.041 Apr 19 27 14 13 6.1 2.9 9.6 1.96 <0.02 0.53 0.029 May 19 36 11 12 8.8 3.3 9.4 0.49 <0.02 0.34 0.025 Jun 27 39 14 11 9.6 3.7 8.9 0.45 <0.02 0.08 0.021 Jul 22 27 11 12 4.5 3.9 11 0.32 <0.02 <0.02 0.024 Aug 23 14 9.9 13 3.1 1.6 13 0.40 <0.02 <0.02 0.024 Sep 25 8.6 10 14 1.6 1.1 11 0.38 <0.02 0.02 0.026 Oct 27 9.4 16 14 2.1 <1.0 14 0.60 0.03 0.38 0.026 Nov 24 26 11 13 6.5 2.2 8.7 0.49 0.06 0.50 0.049 Dec 19 24 7.7 15 5.6 2.5 7.0 1.14 0.09 0.70 0.056 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 8.5 2.9 86 2.2 84 50 1.7 <0.2 <2 14 Feb 2.6 7.1 82 5.2 85 121 1.9 <0.2 <2 <10 Mar 2.4 9.7 79 1.4 102 214 2.1 <0.2 <2 <10 Apr 2.5 4.4 78 4.2 92 66 2.0 <0.2 <2 16 May 3.4 2.8 65 3.4 38 <50 1.6 <0.2 2.6 <10 Jun 4.5 3.2 90 3.8 74 <50 1.1 <0.2 <2 17 Jul 3.3 2.0 80 1.8 72 <50 1.8 <0.2 <2 14 Aug 2.8 3.1 70 2.0 123 <50 1.2 <0.2 <2 16 Sep 3.1 3.4 78 3.0 63 233 1.0 <0.2 <2 28 Oct 4.3 6.4 82 2.0 82 360 4.6 <0.2 <2 15 Nov 4.7 18 103 5.5 88 733 2.7 <0.2 <2 19 Dec 3.8 30 81 6.2 84 110 3.1 <0.2 <2 16 Appendix C - 9 Table C-2 (continued) Lake Tillerv (Station TYF2. bottom)-2002 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 33 25 14 13 6.2 2.2 14 0.66 0.40 0.42 0.026 Feb 28 26 16 12 6.4 2.3 13 0.32 0.05 0.10 0.036 Mar 24 26 14 12 6.4 2.4 9.7 0.52 <0.02 0.72 0.073 Apr 20 28 14 12 6.2 3.1 9.7 1.20 0.04 0.61 0.059 May 17 33 10 12 8.3 2.9 9.1 0.29 0.04 0.53 0.032 Jun 21 39 13 10 9.6 3.7 8.6 0.58 0.11 0.38 0.038 Jul 24 38 10 11 7.9 4.4 10 0.55 0.13 0.30 0.032 Aug 37 16 9.7 10 4.0 1.6 12 0.74 0.38 <0.02 0.064 Sep 22 11 7.5 12 2.4 1.2 6.0 0.65 0.20 0.15 0.063 Oct 26 9.7 16 15 2.2 1.0 14 0.56 0.02 0.38 0.028 Nov 24 27 11 11 7.0 2.3 8.8 0.56 0.05 0.50 0.059 Dec 21 25 8.1 12 5.7 2.5 7.1 1.05 0.09 0.68 0.056 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 4.6 3.6 80 2.2 76 68 2.0 < 0.2 < 2 14 Feb 2.6 8.3 80 5.2 91 143 1.7 <0.2 <2 11 Mar 2.5 28 88 13 106 743 2.9 <0.2 <2 11 Apr 2.6 14 109 38 89 1835 4.0 < 0.2 < 2 19 May 2.9 13 70 7.0 36 217 2.0 <0.2 <2 <10 Jun 3.2 10 99 11 80 249 1.3 <0.2 <2 <10 Jul 2.5 3.5 91 11 76 <50 2.1 <0.2 <2 <10 Aug 2.8 3.5 77 2.6 118 80 <1 <0.2 <2 15 Sep 7.6 32 92 9.0 75 3100 2.6 <0.2 <2 40 Oct 4.3 ND 89 3.0 85 720 1.7 < 0.2 < 2 17 Nov 4.8 18 107 7.8 83 813 1.9 <0.2 <2 19 Dec 3.9 11 68 3.0 62 131 2.2 <0.2 <2 19 Appendix C - 10 Table C-2 (continued) Lake Tillery (Station TYK2, surface)-2002 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 29 23 14 12 5.6 2.1 14 0.56 0.17 0.54 0.028 Feb 28 23 17 12 5.9 2.1 12 0.27 0.03 0.08 0.032 Mar 23 25 15 12 6.2 2.3 10 0.48 <0.02 0.79 0.04 Apr 20 26 14 13 5.9 2.8 9.8 1.39 0.04 0.64 0.034 May 17 30 10 14 7.4 3.0 8.4 0.29 <0.02 0.54 0.022 Jun 25 39 12 11 9.4 3.8 9.2 0.50 <0.02 0.49 0.019 Jul 23 33 11 11 6.7 4.0 11 0.31 0.02 0.32 0.030 Aug 31 16 11 13 3.8 1.6 14 0.47 0.07 0.11 0.024 Sep 30 10 13 14 2.2 1.1 13 0.38 0.05 0.20 0.016 Oct 27 10 16 16 2.4 1.0 15 0.51 0.03 0.42 0.027 Nov 24 26 12 16 6.6 2.2 9.9 0.36 0.07 0.59 0.061 Dec 17 26 8.7 16 6.1 2.7 7.8 1.15 0.08 0.69 0.060 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 4.3 3.4 76 1.6 64 56 1.8 <0.2 <2 <10 Feb 2.7 5.4 80 4.4 89 90 1.4 <0.2 <2 11 Mar 2.2 7.2 76 <1.0 110 178 2.2 <0.2 <2 <10 Apr 2.5 4.5 75 4.8 96 75 2.3 <0.2 <2 14 May 2.8 2.8 70 3.0 41 <50 1.8 <0.2 <2 <10 Jun 3.1 3.6 86 3.4 77 56 1.6 <0.2 <2 <10 Jul 2.7 4.3 89 5.2 66 <50 1.8 <0.2 <2 12 Aug 3.0 2.8 82 1.6 133 <50 <1.0 <0.2 <2 30 Sep 3.1 1.0 99 1.0 80 <50 <1.0 <0.2 <2 22 Oct 4.4 3.1 79 <1.0 88 58 2.3 <0.2 <2 15 Nov 3.7 13 113 5.2 80 401 <1.0 <0.2 <2 18 Dec 3.8 12 94 6.8 69 152 2.2 <0.2 <2 19 Appendix C - 11 Table C-2 (continued) Lake Tillery (Station TYK2, bottom)-2002 Month Total Alkalinity Hardness (calculated) CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ nitrite-N TP Jan 30 23 14 14 5.8 2.1 14 0.54 0.11 0.56 0.028 Feb 28 24 16 12 6.1 2.2 13 0.29 0.03 0.08 0.036 Mar 23 25 15 12 6.3 2.3 10 0.45 < 0.02 0.79 0.042 Apr 20 26 14 13 5.8 2.7 9.6 1.38 0.04 0.65 0.034 May 16 30 9.9 12 7.2 2.9 8.3 0.35 <0.02 0.54 0.021 Jun 24 38 13 11 9.1 3.7 8.9 0.49 <0.02 0.49 0.018 Jul 22 35 12 12 7.1 4.2 12 0.48 <0.02 0.31 0.042 Aug 30 15 11 13 3.6 1.5 14 0.69 0.06 0.06 0.020 Sep 30 11 14 12 2.3 1.2 14 0.36 0.04 0.21 0.016 Oct 26 9.7 16 16 2.2 < 1.0 14 0.60 0.03 0.42 0.032 Nov 25 25 12 16 6.4 2.1 9.8 0.36 0.06 0.59 0.062 Dec 21 24 8.3 15 5.7 2.5 7.3 1.06 0.08 0.72 0.062 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 3.8 3.4 82 <1.0 80 74 2.0 <0.2 <2 10 Feb 2.7 5.3 83 4.8 95 110 1.6 <0.2 <2 <10 Mar 2.2 13 81 2.8 100 200 4.8 < 0.2 < 2 <10 Apr 2.5 7.0 84 5.0 91 78 2.2 <0.2 <2 14 May 3.2 7.6 62 2.4 48 <50 2.0 <0.2 <2 <10 Jun 3.3 3.8 90 2.2 71 <50 1.1 <0.2 <2 10 Jul 2.9 3.9 79 4.0 75 64 1.8 < 0.2 < 2 <10 Aug 3.0 3.2 79 3.3 126 <50 <1.0 <0.2 <2 14 Sep 3.0 1.4 98 <1.0 80 80 <1.0 <0.2 <2 24 Oct 4.3 ND 78 2.0 86 670 2.9 <0.2 <2 18 Nov 3.6 15 119 5.2 70 338 <1.0 <0.2 <2 18 Dec 3.8 12 99 7.4 64 139 2.2 <0.2 <2 20 Units are in mg/liter except trace metals which are in (Dg/liter and turbidity which is in NTU. Total alkalinity is measured as mg/L as CaCO, and hardness is calculated as mg equivalents CaCO,/L. Appendix C - 12 Table C-3 Concentrations of water chemistry parameters in Lake Tillery (Stations TYB2, TYF2, and TYK2) during 2004.1 Lake Tillery (Station TYB2, surface)-2004 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 21 5.4 9.6 5.8 2.2 < 1 4.7 0.63 0.04 0.71 0.039 Feb 23 23 8.0 6.3 5.7 2.2 6.4 0.34 0.06 0.74 0.047 Mar 19 21 9.3 7.2 5.1 2.0 6.2 0.51 <0.02 0.71 0.041 Apr 20 22 11 5.5 5.2 2.3 6.8 0.45 < 0.02 0.62 0.027 May 22 22 7.5 5.2 4.9 2.4 7.1 0.43 <0.02 0.33 0.021 Jun 21 20 7.4 5.2 4.3 2.2 6.3 1.32 0.05 0.06 0.026 Jul 17 24 13 5.7 4.8 2.8 5.5 0.58 <0.02 0.03 0.020 Aug 26 21 7.0 5.7 4.8 2.2 7.2 0.54 0.06 <0.02 0.018 Sep 23 22 7.1 5.8 5.0 2.2 8.2 0.42 0.06 0.40 0.037 Oct 16 20 8.8 5.2 4.9 1.8 5.3 0.56 0.07 0.45 0.036 Nov 19 20 9.1 9.7 4.8 1.9 4.6 0.42 <0.02 0.54 0.029 Dec 22 38 6.2 5.2 7.6 4.7 7.7 0.54 0.08 0.61 0.040 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.2 5.8 70 2.9 66 140 1.4 <0.2 <2 <10 Feb 2.0 11 78 5.2 60 126 1.5 <0.2 2.0 <10 Mar 2.3 12 123 5.2 103 258 1.9 <0.2 <2 10 Apr 2.4 5.6 82 3.9 66 63 2.0 <0.2 <2 <10 May 2.5 2.4 74 2.8 71 75 1.5 <0.2 <2 <10 Jun 2.7 3.5 74 3.9 90 34 1.5 < 0.2 2.3 <10 Jul 2.7 0.6 50 2.8 60 <50 1.4 <0.2 <2 <10 Aug 2.6 0.2 70 2.4 58 <50 <2 <0.2 <2 <10 Sep 3.1 3.6 76 2.8 86 145 2.0 <0.2 <2 <10 Oct 4.5 5.2 72 3.0 64 288 2.1 <0.2 <2 <10 Nov 3.5 9.3 68 4.1 56 136 3.1 <0.2 <2 11 Dec 2.8 7.6 64 5.5 59 242 2.3 <0.2 <2 <10 Appendix C - 13 Table C-3 (continued) Lake Tillery (Station TYB2, bottom)-2004 Month Total Hardness CF SO4 Ca2+ Mgz+ Na TN NH3-N Nitrate+ TP Jan 19 5.1 9.1 5.6 2.0 < 1.0 Feb 22 23 12 5.5 5.6 2.2 Mar 18 21 9.6 6.4 5.0 2.0 Apr 20 26 11 6.3 5.8 2.8 May 21 25 7.6 5.1 5.8 2.5 Jun 21 22 7.3 6.0 5.3 2.2 Jul 26 25 12 3.0 5.0 3.0 Aug 28 22 7.4 5.3 5.1 2.2 Sep 23 22 7.4 5.1 5.2 2.2 Oct 17 19 11 5.1 4.6 1.8 Nov 18 18 9.0 5.3 4.4 1.8 Dec 22 21 6.4 6.3 5.0 2.1 nitrite-N 4.6 0.36 0.06 0.71 0.045 6.6 0.38 0.12 0.75 0.048 6.0 0.83 0.06 0.74 0.05C 7.2 0.63 0.05 0.64 0.158 7.3 0.27 0.02 0.55 0.042 6.3 1.4 0.06 0.47 0.011 5.5 0.72 0.23 0.28 0.03S 7.1 0.60 0.10 0.21 0.03C 8.3 0.70 0.07 0.42 0.045 4.5 0.59 0.09 0.50 0.05E 4.3 0.40 <0.02 0.53 0.032 4.9 0.39 0.08 0.61 0.041 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.3 23 77 7.7 66 160 1.6 < 0.2 < 2 <10 Feb 2.2 36 80 6.3 58 352 1.5 <0.2 <2 <10 Mar 2.4 14 106 9.8 109 653 2.2 <0.2 <2 <10 Apr 3.5 17 110 48 56 4,780 7.5 <0.2 <2 16 May 2.2 19 94 8.8 74 322 1.9 <0.2 <2 <10 Jun 2.3 2.8 74 2.9 84 59 2.7 <0.2 <2 <10 Jul 2.4 6.0 71 4.1 56 142 1.4 <0.2 <2 <10 Aug 2.7 33 78 3.8 60 195 <2 <0.2 <2 <10 Sep 3.2 8.9 80 7.4 81 328 2.0 <0.2 <2 <10 Oct 5.2 16 76 6.0 66 572 2.4 <0.2 <2 <10 Nov 3.5 4.3 68 4.8 57 191 2.7 <0.2 <2 14 Dec 2.8 44 64 5.4 70 240 2.0 <0.2 <2 <10 Appendix C - 14 Table C-3 (continued) Lake Tillery (Station TYF2, surface)-2004 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 15 5.7 8.9 5.0 2.3 < 1 4.7 0.40 0.06 0.73 0.041 Feb 23 23 7.9 5.8 5.5 2.2 6.2 0.47 0.11 0.76 0.062 Mar 20 22 9.9 6.5 5.2 2.1 6.8 0.39 <0.02 0.80 0.038 Apr 22 25 11 5.6 5.8 2.6 7.4 0.43 <0.02 0.57 0.023 May 51 22 7.3 19 5.0 2.3 6.9 0.46 <0.02 0.30 0.030 Jun 19 22 7.5 7.4 4.8 2.3 6.6 1.84 0.03 0.11 0.037 Jul 19 25 12 4.4 5.0 3.0 5.6 0.58 <0.02 0.06 0.028 Aug 25 21 7.3 7.6 4.7 2.2 7.6 0.65 0.02 <0.02 0.029 Sep 20 20 6.1 6.0 4.6 2.0 6.9 0.56 0.08 0.54 0.045 Oct 16 20 10 5.9 4.9 1.8 4.5 0.77 0.48 0.56 0.065 Nov 20 22 9.8 5.2 5.3 2.1 5.3 0.43 0.03 0.59 0.032 Dec 20 24 6.5 6.0 5.6 2.3 5.3 0.33 0.08 0.62 0.035 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.1 5.1 71 3.3 64 98 1.2 <0.2 <2 <10 Feb 2.6 40 87 11 56 564 1.6 <0.2 <2 10 Mar 2.0 9.9 111 7.0 103 242 1.6 <0.2 <2 <10 Apr 2.5 7.1 66 4.0 51 83 2.2 <0.2 <2 <10 May 2.8 2.4 84 4.7 69 64 1.6 <0.2 <2 <10 Jun 2.6 4.2 67 4.2 68 33 1.6 <0.2 2.7 <10 Jul 2.6 0.7 58 3.6 54 <50 1.2 <0.2 <2 <10 Aug 2.6 1.2 78 3.0 66 <50 <2 <0.2 2.7 <10 Sep 3.7 7.5 74 3.4 80 256 2.0 <0.2 <2 <10 Oct 5.3 13 73 3.3 66 512 2.3 <0.2 <2 14 Nov 3.4 5.6 74 2.1 60 123 2.7 <0.2 <2 12 Dec 2.7 4.4 60 3.3 62 145 1.8 <0.2 <2 <10 Appendix C - 15 Table C-3 (continued) Lake Tillery (Station TYF2, bottom)-2004 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 15 8.8 8.9 5.5 3.5 <1 4.9 0.36 0.04 0.73 0.041 Feb 21 21 8.0 5.5 5.2 2.0 5.9 0.64 0.11 0.77 0.064 Mar 18 22 10 7.2 5.3 2.1 6.9 0.36 0.02 0.78 0.109 Apr 18 22 11 5.3 5.1 2.2 6.6 0.82 0.10 0.71 0.029 May 21 23 7.1 5.2 5.2 2.3 6.7 0.52 0.09 0.47 0.036 Jun 21 24 7.6 5.2 5.8 2.4 6.8 1.09 0.08 0.43 0.022 Jul 20 24 12 4.9 4.9 3.0 5.5 0.69 0.15 0.33 0.059 Aug 28 23 7.2 5.3 5.3 2.3 7.6 0.71 0.11 0.21 0.043 Sep 20 20 6.2 6.5 4.7 2.0 7.0 0.54 0.04 0.54 0.070 Oct 16 20 11 5.6 4.7 1.9 4.4 0.37 0.20 0.55 0.059 Nov 21 23 9.7 5.8 5.6 2.2 5.4 0.40 0.02 0.57 0.033 Dec 22 23 6.4 5.9 5.5 2.3 6.8 0.38 0.07 0.64 0.036 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.1 5.2 70 3.8 68 75 1.3 < 0.2 < 2 <10 Feb 2.6 33 88 8.7 53 580 1.9 <0.2 <2 <10 Mar 2.2 12 105 11 111 490 2.2 < 0.2 < 2 < 10 Apr 2.3 9.1 75 6.2 55 177 1.9 <0.2 <2 <10 May 2.6 12 80 11 74 415 1.8 <0.2 <2 <10 Jun 2.5 19 82 6.1 79 217 2.0 < 0.2 2.1 <10 Jul 2.2 91 103 17 52 197 1.5 <0.2 <2 <10 Aug 2.6 15 100 10 67 500 <2 <0.2 <2 <10 Sep 3.7 11 80 11 80 778 4.0 <0.2 <2 <10 Oct 5.3 23 85 7.5 72 712 2.5 <0.2 <2 12 Nov 3.3 9.0 70 3.9 63 143 2.2 < 0.2 < 2 13 Dec 2.7 8.1 66 3.8 65 166 2.6 <0.2 <2 <10 Appendix C - 16 Table C-3 (continued) Lake Tillery (Station TYK2, surface)-2004 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Jan 16 8.3 9.3 6.1 3.3 < 1 Feb 19 22 7.9 5.8 5.3 2.0 Mar 20 22 10 6.0 5.3 2.1 Apr 21 24 11 6.3 5.8 2.3 May 22 24 7.2 5.2 5.6 2.3 Jun 20 25 7.6 7.6 6.2 2.4 Jul 22 24 12 9.1 4.9 3.0 Aug 26 20 7.9 6.0 4.6 2.0 Sep 19 19 5.9 5.7 4.4 1.9 Oct 16 19 12 6.0 4.6 1.8 Nov 20 19 9.5 5.9 4.5 1.8 Dec 20 21 6.4 5.6 5.0 2.1 nitrite-N 4.7 0.35 0.07 0.76 0.043 6.2 0.66 0.14 0.80 0.072 7.0 0.84 0.04 0.80 0.041 7.6 0.51 <0.02 0.65 0.028 6.8 0.37 0.07 0.48 0.025 7.2 1.69 0.07 0.44 0.018 5.6 0.67 0.06 0.43 0.02E 7.7 0.57 <0.02 0.28 0.021 6.8 0.59 0.05 0.54 0.044 4.5 0.28 0.74 0.53 0.045 5.1 0.41 < 0.02 0.59 0.031 6.4 0.34 0.07 0.65 0.037 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.1 5.2 70 2.9 66 72 1.3 <0.2 <2 <10 Feb 2.6 40 87 10 65 696 1.9 <0.2 <2 <10 Mar 2.0 12 110 2.6 112 252 3.8 <0.2 <2 <10 Apr 2.2 4.9 78 3.9 60 69 1.9 <0.2 <2 <10 May 2.5 3.3 81 4.4 72 128 1.6 <0.2 <2 <10 Jun 2.4 2.8 76 3.8 75 78 1.8 < 0.2 2.1 <10 Jul 2.6 2.2 64 3.4 54 60 1.6 <0.2 <2 <10 Aug 2.4 0.4 75 1.8 66 208 <2 <0.2 <2 <10 Sep 3.4 6.8 73 3.4 72 289 2.0 <0.2 <2 <10 Oct 4.9 9.1 80 5.2 62 283 2.0 <0.2 <2 11 Nov 3.5 4.7 65 2.4 57 104 2.2 <0.2 <2 12 Dec 2.6 4.2 56 3.7 66 161 1.8 <0.2 <2 <10 Units are in mg/liter except trace metals which are in (Dg/liter and turbidity which is in NTU. Total alkalinity is measured as mg/L as CaCO, and hardness is calculated as mg equivalents CaCO,/L. Appendix C - 17 Table C-4 Concentrations of water chemistry parameters in the Pee Dee River (Stations TY1B and TY12B) during 2000.1 Pee Dee River below the Tillery Development (Station TY1B, surface)-2000 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 29 20 13 10 4.7 2.0 10 0.81 < 0.05 0.51 0.032 Feb 24 23 13 9.0 5.4 2.2 11 0.83 <0.05 0.58 0.033 Mar 20 23 12 8.0 5.5 2.3 10 0.82 < 0.05 0.56 0.048 Apr 13 24 11 8.0 5.8 2.4 10 0.88 <0.05 0.56 0.038 May 21 22 12 9.4 5.3 2.2 9.0 0.63 < 0.05 0.63 0.040 Jun 21 20 11 7.0 4.7 2.1 8.0 0.89 < 0.05 0.55 0.029 Jul 22 23 12 8.0 5.4 2.4 9.6 0.54 < 0.05 0.32 0.016 Aug 28 22 12 7.0 5.0 2.4 9.6 0.70 < 0.05 0.15 0.018 Sep 31 24 12 7.0 5.4 2.5 10 0.27 <0.05 0.08 0.026 Oct 28 22 12 7.0 4.9 2.4 11 0.83 <0.05 0.14 0.026 Nov 24 19 14 9.0 4.1 2.1 11 0.51 < 0.05 0.21 0.024 Dec 26 21 15 9.0 4.6 2.2 12 0.55 < 0.05 0.24 0.026 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 3.0 10 64 5.0 74 150 1.5 <0.2 NV <20 Feb 2.8 10 98 <5 77 190 1.4 <0.2 <2 <20 Mar 3.7 7.1 90 <5 77 230 2.0 <0.2 <2 27 Apr 3.4 9.9 96 <5 96 260 2.0 <0.2 <2 <20 May 3.3 11 54 <5 79 160 1.7 <0.2 <2 <20 Jun 3.1 4.4 68 <5 68 <50 1.6 <0.2 <2 <20 Jul 3.0 3.8 36 5.0 53 80 <1.0 <0.2 <2 <20 Aug 2.9 5.1 66 <3 75 <50 1.3 <0.2 <2 <20 Sep 4.0 4.3 68 <3 95 <50 1.4 <0.2 <2 <20 Oct 3.2 6.9 58 <5 70 140 1.6 <0.2 <2 27 Nov 3.7 3.1 76 <5 73 <50 1.4 <0.2 <2 <20 Dec 4.3 4.3 66 <5 80 58 1.6 <0.2 <2 <20 Appendix C - 18 Table C-4 (continued) Pee Dee River below the Tillery Development (Station TY1213, surface)-2000 Month Total Hardness CF SO4 Ca 2, Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 24 37 19 14 8.2 4.0 13 2.7 0.14 1.43 0.471 Feb 15 24 12 8.0 5.1 2.7 6.1 1.2 <0.05 0.58 0.193 Mar 36 33 16 12 7.6 3.4 16 1.0 <0.05 0.66 0.125 Apr 43 39 17 13 9.0 4.0 20 1.3 < 0.05 0.89 0.142 May 29 35 15 13 8.2 3.6 14 1.3 0.08 1.00 0.162 Jun 25 22 8.0 12 5.0 2.4 9.2 0.98 < 0.05 0.59 0.068 Jul 57 30 38 31 8.8 4.3 50 1.4 <0.05 0.66 0.376 Aug 24 26 11 7.0 5.8 2.8 9.6 1.1 < 0.05 0.32 0.128 Sep 10 20 8.0 5.0 4.2 2.2 3.6 1.0 <0.05 0.19 0.246 Oct 31 26 14 10 5.7 2.8 12 1.4 <0.05 0.27 0.072 Nov 28 20 15 9.0 4.3 2.2 12 0.53 < 0.05 0.24 0.056 Dec 32 27 18 13 6.2 2.9 16 0.89 <0.05 0.50 0.096 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 7.9 157 244 125 110 2,100 11 < 0.2 N,V 44 Feb 8.7 46 116 28 76 1,700 5.3 <0.2 <2 42 Mar 4.0 9.0 106 7.0 85 270 2.5 <0.2 <2 <20 Apr 4.8 15 136 12 117 510 3.7 <0.2 <2 <20 May 5.1 43 160 40 111 860 10 <0.2 <2 <20 Jun 3.4 13 78 6.0 80 210 1.8 <0.2 <2 <20 Jul 5.2 8.8 150 <5 168 79 7.6 <0.2 2.0 <20 Aug 7.9 44 102 <3 100 1,200 4.9 <0.2 <2 <20 Sep 19 106 144 59 112 2,600 11 <0.2 3.0 67 Oct 4.1 16 74 9.0 82 360 3.4 <0.2 <2 23 Nov 3.8 5.6 88 <5 85 84 <1.0 <0.2 <2 <20 Dec 4.4 6.4 84 <5 123 140 3.5 <0.2 <2 <20 Units are in mg/liter except trace metals which are in (Dg/liter and turbidity which is in NTU. Total alkalinity is measured as mg/L as CaCO, and hardness is calculated as mg equivalents CaCO,/L. 2 No Biological Oxygen Demand (BOD) data were collected during January. Appendix C - 19 Table C-5 Concentrations of water chemistry parameters in the Pee Dee River (Stations TY1B and TY12B) and Rocky River (Station RR) during 2001.1 Pee Dee River below Tillery Development (Station TY1B)-2001 Month Total Hardness CT SO4 Ca 2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan ND2 ND ND ND ND ND ND ND ND ND ND Feb 29 25 14 9.0 6.0 2.5 14 0.80 <0.05 0.48 0.020 Mar 26 26 14 8.8 6.3 2.5 12 1.1 < 0.05 0.62 0.029 Apr 24 25 10 12 6.4 2.2 9.3 1.0 0.11 0.62 0.033 May 25 27 12 12 6.6 2.7 10 0.91 0.34 0.61 0.034 Jun 24 20 9.5 11 4.7 2.1 8.3 0.85 0.15 0.57 0.018 Jul 27 22 8.2 51 5.2 2.1 7.2 0.82 0.12 0.48 0.016 Aug 28 24 9.0 11 6.2 2.2 8.7 0.59 < 0.05 0.26 0.019 Sep 27 25 9.5 13 6.1 2.3 9.8 0.42 0.07 0.07 0.024 Oct 32 27 13 12 6.9 2.3 11 0.57 0.03 0.06 0.034 Nov 29 28 9.9 12 7.2 2.4 11 0.50 0.05 0.13 0.027 Dec 31 29 9.3 12 7.3 2.7 11 0.50 <0.02 0.15 0.028 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan ND ND ND ND ND ND ND ND ND ND Feb 3.0 4.0 68 <5 39 69 1.1 <0.2 <2 <20 Mar 4.2 6.7 82 <5 82 190 2.1 <0.2 <2 <20 Apr 3.2 4.6 100 4.2 103 84 3.0 <0.2 <2 <10 May 3.1 5.4 94 4.0 73 106 2.0 <0.2 <2 <10 Jun 3.1 2.6 86 1.6 63 115 2.0 <0.2 <2 18 Jul 3.2 1.3 78 1.8 106 <50 2.0 <0.2 <2 38 Aug 2.9 1.7 87 <1 67 <50 1.0 <0.2 <2 11 Sep 4.1 2.8 73 2.0 13 <50 2.0 <0.2 <2 13 Oct 2.7 3.0 87 2.0 79 <50 1.9 <0.2 <2 17 Nov 3.8 5.9 70 4.2 94 91 1.2 < 0.2 < 2 10 Dec 5.4 3.8 96 2.6 94 67 1.9 <0.2 <2 10 Appendix C - 20 Table C-5 (continued) Pee Dee River below Tillery Development (Station TY12B)-2001 Month Total Hardness CF SO4 Ca 2, Mgz+ Na TN NH3-N Nitrate+ Jan 33 29 6 10 6.8 3.1 Feb 19 30 6 7.0 6.5 3.4 Mar 27 38 3 14 8.6 4.0 Apr 30 30 3 15 7.6 2.8 May 41 39 3 20 9.2 3.8 Jun 28 24 1 15 5.4 2.5 Jul 27 22 1 11 5.1 2.2 Aug 22 128 3 15 4.8 2.0 Sep 32 25 1 13 6.3 2.3 Oct 43 32 8 26 7.8 3.0 Nov 50 39 9 33 9.6 3.6 Dec 39 36 6 20 8.3 3.7 nitrite-N 13 0.75 0.08 0.32 9.1 0.88 < 0.05 0.23 13 1.8 <0.05 1.21 12 1.2 0.08 0.76 24 0.83 0.22 0.62 12 0.99 0.10 0.59 7.6 0.76 0.14 0.42 7.8 2.0 0.07 1.02 11 0.52 < 0.05 0.08 30 1.1 <0.02 0.62 33 1.3 0.02 0.80 18 1.6 <0.02 0.83 TP 0.068 0.144 0.154 0.072 0.118 0.081 0.026 0.313 0.054 0.204 0.298 0.269 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 5.1 11 97 <5 80 170 1.7 <0.2 <2 <20 Feb 14 40 96 12 <20 780 3.2 <0.2 <2 <20 Mar 4.9 23 98 16 90 690 3.3 <0.2 <2 <20 Apr 3.4 4.2 111 4.6 93 113 4.0 < 0.2 < 2 14 May 4.1 4.0 130 2.6 119 57 3.0 <0.2 <2 <10 Jun 3.6 4.0 108 3.4 69 94 2.0 <0.2 <2 18 Jul 3.1 4.4 85 5.4 95 67 2.0 <0.2 <2 18 Aug 9.1 103 167 51 91 1,950 6.0 <0.2 2.4 26 Sep 3.5 7.5 89 6.4 63 73 1.6 <0.2 <2 <10 Oct 3.3 4.9 150 3.6 143 91 2.3 <0.2 <2 21 Nov 6.3 12 160 7.6 178 264 2.4 < 0.2 < 2 19 Dec 6.6 12 134 7.6 124 194 3.4 <0.2 <2 16 Appendix C - 21 Table C-5 (continued) Rocky River (Station RR)-2001 Month Total Alkalinity Hardness (calculated) CF SO4 Ca 2, Mgz+ Na TN NH3-N Nitrate+ nitrite-N TP Jan N,V ND ND ND ND ND ND ND ND ND ND Feb 31 48 19 17 11 5.0 15 2.3 0.06 1.62 0.272 Mar 32 51 21 18 12 5.2 16 2.2 0.05 1.63 0.158 Apr 42 50 21 24 12 4.7 20 1.7 0.10 1.17 0.238 May 83 62 53 53 14 6.6 65 1.9 0.09 1.43 0.676 Jun 86 59 57 52 12 6.9 65 3.2 0.12 2.38 0.805 Jul 66 54 42 12 13 5.3 45 2.6 0.17 2.02 0.487 Aug 51 43 47 37 10 4.3 46 3.2 <0.05 2.20 0.582 Sep 75 54 71 77 13 5.4 85 2.4 <0.05 1.52 0.848 Oct 104 62 94 94 14 6.5 111 4.3 <0.02 3.25 1.053 Nov 90 64 69 82 14 7.1 88 6.2 <0.02 5.21 1.120 Dec 57 50 34 48 11 5.4 42 2.0 0.02 1.99 0.788 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan ND ND ND ND ND ND ND ND ND ND Feb 8.0 33 100 14 132 890 5.3 <0.2 <2 <20 Mar 5.8 22 142 15 121 860 3.4 <0.2 <2 48 Apr 4.6 13 156 12 144 172 4.0 <0.2 <2 15 May 6.8 12 295 24 258 186 7.0 <0.2 <2 21 Jun 6.7 4.5 314 6.6 270 166 6.0 0.21 < 2 26 Jul 5.3 12 243 8.8 258 269 6.0 <0.2 <2 22 Aug 7.4 83 284 48 204 1,670 6.0 <0.2 <2 26 Sep 6.4 12 327 5.4 319 264 6.8 <0.2 <2 17 Oct 6.3 4.7 436 4.1 420 99 5.9 <0.2 <2 23 Nov 9.9 17 361 18 365 597 6.5 <0.2 <2 30 Dec 8.4 17 243 14 228 380 5.5 <0.2 <2 20 Units are in mg/liter except trace metals which are in (Dg/liter and turbidity which is in NTU. Total alkalinity is measured as mg/L as CaCO, and hardness is calculated as mg equivalents CaCO,/L. 2 No data were collected in January. Appendix C - 22 Table C-6 Concentrations of water chemistry parameters in the Pee Dee River (Stations TY1B and TY12B) and Rocky River (Station RR) during 2002.1 Pee Dee River below Tillery Development (Station TY1B)-2002 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 31 25 12 12 6.3 2.1 13 0.34 0.03 0.27 0.021 Feb 29 24 16 12 6.2 2.2 11 0.43 <0.02 0.06 0.040 Mar 26 27 15 11 6.8 2.4 11 0.76 <0.02 0.58 0.150 Apr 20 26 14 12 5.9 2.7 9.3 1.13 0.07 0.58 0.034 May 18 36 10 12 8.8 3.4 9.8 0.45 < 0.02 0.44 0.020 Jun 25 40 13 12 9.8 3.8 9.1 0.54 0.04 0.40 0.021 Jul 22 35 11 9.6 7.2 4.2 10 0.18 0.04 0.34 0.020 Aug 35 16 9.6 9.4 3.8 1.5 11 0.80 0.29 <0.02 0.062 Sep 26 10 10 10 2.1 1.2 8.5 0.41 0.10 0.19 0.020 Oct 23 8.1 12 15 1.6 < 1.0 9.6 0.46 0.04 0.22 0.026 Nov 24 19 11 14 4.0 2.2 11 0.43 0.02 0.37 0.026 Dec 17 23 7.1 16 5.2 2.5 6.3 0.96 0.08 0.58 0.057 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 4.6 2.7 79 1.8 84 77 1.9 <0.2 <2 10 Feb 3.6 27 85 29 86 235 1.8 <0.2 <2 17 Mar 2.2 8.1 84 14 111 189 2.3 <0.2 <2 15 Apr 2.6 8.8 80 7.0 92 174 1.8 <0.2 <2 17 May 3.2 3.8 78 4.6 45 52 1.8 <0.2 <2 <10 Jun 3.2 3.1 98 3.4 80 100 1.4 <0.2 <2 10 Jul 2.6 1.4 83 <1.0 75 398 2.5 <0.2 <2 <10 Aug 3.0 3.5 78 1.8 129 <50 1.4 <0.2 <2 <10 Sep 4.6 3.0 83 3.2 72 155 1.3 <0.2 <2 26 Oct 4.5 5.6 77 3.0 68 687 2.0 < 0.2 < 2 15 Nov 3.9 4.7 72 4.4 80 312 1.8 <0.2 <2 16 Dec 4.6 25 101 11 63 234 2.4 <0.2 <2 22 Appendix C - 23 Table C-6 (continued) Pee Dee River below Tillery Development (Station TY12B)-2002 Month Total Hardness CF SO4 Ca2+ Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 32 26 13 13 6.7 2.2 14 <0.10 0.05 0.27 0.034 Feb 28 28 16 12 6.9 2.7 12 0.62 <0.02 0.07 0.110 Mar 29 36 20 20 8.9 3.3 14 0.63 <0.02 0.73 0.042 Apr 24 30 16 13 6.5 3.4 10 1.05 0.03 0.49 0.125 May 20 40 13 14 9.7 3.9 12 0.48 0.03 0.54 0.088 Jun 31 38 20 16 9.1 3.8 13 0.45 0.02 0.62 0.143 Jul 51 54 48 46 9.4 7.4 55 0.55 <0.02 0.63 0.438 Aug 29 15 9.9 11 3.4 1.5 11 0.45 0.04 0.06 0.094 Sep 32 12 16 16 2.6 1.4 14 0.37 0.06 0.30 0.155 Oct 24 10 13 14 2.2 1.1 11 0.64 0.05 0.37 0.077 Nov 24 31 13 16 7.5 2.9 10 0.72 0.03 0.63 0.179 Dec 11 21 9.4 18 4.3 2.5 4.9 2.33 0.03 0.42 0.119 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 4.6 5.0 84 4.8 77 122 2.4 <0.2 <2 12 Feb 3.4 17 146 50 93 1,450 4.7 <0.2 <2 18 Mar 4.2 25 123 26 146 497 3.8 <0.2 <2 18 Apr 4.8 28 106 18 94 488 2.8 <0.2 <2 24 May 3.3 19 86 14 55 320 2.7 <0.2 2.6 <10 Jun 3.7 12 122 12 103 285 1.8 <0.2 <2 10 Jul 4.5 6.7 233 4.6 209 170 4.2 <0.2 2.1 17 Aug 3.0 9.7 74 7.2 119 234 1.6 <0.2 <2 14 Sep 4.4 18 141 20 98 908 2.2 <0.2 <2 24 Oct 5.0 23 91 4.8 71 338 2.4 <0.2 <2 17 Nov 6.0 54 120 31 105 842 4.8 <0.2 <2 29 Dec 16 40 120 20 102 456 4.6 <0.2 2.4 50 Appendix C - 24 Table C-6 (continued) Rocky River (Station RR)-2002 Month Total Hardness CF SO4 Ca2+ Mgz+ Na TN NH3-N Nitrate+ TP Jan 55 53 35 49 13 5.2 Feb 39 52 26 32 12 5.3 Mar 47 57 33 31 14 5.6 Apr 42 50 32 30 12 5.3 May 56 76 70 55 19 7.0 Jun 62 61 46 41 16 5.2 Jul 98 84 123 115 13 12 Aug 56 37 41 50 5.4 5.7 Sep 53 32 39 57 4.8 4.9 Oct 24 36 36 35 5.3 5.6 Nov 32 68 15 20 17 6.2 Dec 23 34 13 22 7.7 3.7 nitrite-N 39 0.96 0.32 1.85 0.510 21 0.48 < 0.02 0.41 0.335 28 1.01 0.13 2.04 0.489 26 1.91 <0.02 1.52 0.309 68 0.77 0.04 2.18 0.924 48 0.75 0.04 2.01 1.05 151 0.92 0.06 1.57 1.41 49 0.87 0.05 1.42 1.21 42 0.62 0.04 2.11 0.632 28 0.76 <0.02 2.49 0.383 10 1.34 0.05 5.36 0.419 8.7 1.66 0.02 2.22 0.173 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 8.5 6.0 211 1.2 209 133 4.8 <0.2 <2 21 Feb 4.3 9.3 152 6.2 160 180 3.9 <0.2 <2 20 Mar 3.7 100 253 82 176 2,424 7.7 <0.2 <2 23 Apr 3.8 14 179 13 174 213 3.6 <0.2 <2 20 May 7.1 22 278 5.0 254 152 6.0 <0.2 2.4 15 Jun 6.5 8.9 255 13 229 255 4.5 <0.2 <2 17 Jul 8.2 10 552 6.2 499 454 9.0 <0.2 <2 30 Aug 7.5 9.0 220 6.7 293 303 4.6 <0.2 <2 38 Sep 6.7 10 229 3.5 218 549 4.8 <0.2 <2 36 Oct 5.7 11 199 21 182 956 4.7 <0.2 <2 21 Nov 12 94 172 52 176 168 10 <0.2 3.9 44 Dec 4.7 22 142 11 117 96 3.4 <0.2 <2 20 Units are in mg/liter except trace metals which are in (Dg/liter and turbidity which is in NTU. Total alkalinity is measured as mg/L as CaCO, and hardness is calculated as mg equivalents CaCO,/L. Appendix C - 25 Table C-7 Concentrations of water chemistry parameters in the Pee Dee River (Stations TY1B and TY12B) and Rocky River (RR) below the Tillery Hydroelectric Plant during 2004.1 Pee Dee River below Tillery Development (Station TY1B, No Generation Flow)-2004 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 18 8.4 9.2 6.4 3.4 < 1 4.9 0.33 0.06 0.73 0.034 Feb 25 24 7.7 5.2 5.9 2.2 6.8 0.38 0.06 0.82 0.041 Mar 17 22 11 5.2 5.2 2.1 6.6 1.14 0.06 0.83 0.036 Apr 19 21 11 6.5 4.5 2.3 6.8 0.42 0.04 0.69 0.024 May 21 23 7.8 5.2 5.4 2.4 7.0 0.32 <0.02 0.47 0.025 Jun 22 24 7.6 7.9 5.6 2.3 6.4 1.39 0.09 0.46 0.015 Jul 21 25 12 2.8 5.1 3.0 5.6 0.48 0.04 0.43 0.017 Aug 27 21 6.7 6.2 5.0 2.2 7.2 0.62 <0.02 0.26 0.024 Sep 23 22 6.9 6.0 5.1 2.1 8.4 0.59 0.06 0.49 0.041 Oct 18 19 10 5.3 4.6 1.8 4.3 0.36 <0.02 0.49 0.058 Nov 16 24 11 8.9 5.8 2.2 5.3 0.46 < 0.02 0.55 0.030 Dec 20 20 8.9 6.2 4.5 2.1 6.1 0.51 0.06 0.58 0.038 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.1 2.2 69 2.7 74 97 1.6 <0.2 <2 <10 Feb 2.1 11 82 4.5 56 156 1.2 <0.2 <2 <10 Mar 2.3 18 104 5.2 108 326 2.0 <0.2 <2 <10 Apr 2.2 7.9 107 3.9 89 134 1.6 <0.2 <2 <10 May 2.4 9.1 100 8.1 74 222 2.0 < 0.2 < 2 < 10 Jun 2.4 2.7 72 2.4 76 88 2.8 <0.2 <2 <10 Jul 2.5 0.6 64 1.8 51 <50 1.4 <0.2 <2 <10 Aug 2.6 1.3 74 2.3 70 105 <2 <0.2 <2 <10 Sep 3.2 4.2 76 3.0 76 143 2.0 <0.2 <2 <10 Oct 4.4 14 72 5.0 66 485 3.0 <0.2 <2 12 Nov 3.5 5.0 74 2.0 66 96 2.8 <0.2 <2 14 Dec 2.7 7.1 75 5.6 66 224 5.7 <0.2 <2 <10 Appendix C - 26 Table C-7 (continued) Pee Dee River below Tillery Development (Station TY1B, Generation Flow)-2004 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 19 8.2 9.1 6.5 3.3 < 1 4.8 0.33 0.13 0.72 0.039 Feb 22 24 7.8 5.8 6.0 2.3 6.8 0.35 0.06 0.80 0.047 Mar 19 21 9.2 5.3 5.1 2.0 6.2 2.87 <0.02 0.76 0.035 Apr 21 24 11 5.0 5.5 2.4 7.1 0.75 < 0.02 0.63 0.044 May 21 24 7.6 5.1 5.4 2.5 7.2 0.35 0.04 0.46 0.022 Jun 19 22 7.5 <2 5.1 2.2 6.2 2.45 0.09 0.38 0.015 Jul 20 27 12 7.4 6.0 2.9 5.3 0.61 0.13 0.32 0.020 Aug 26 22 7.0 7.5 5.0 2.2 7.4 0.53 < 0.02 0.20 0.029 Sep 23 22 7.1 6.0 5.2 2.1 8.7 0.73 0.07 0.43 0.038 Oct 18 24 11 5.3 6.4 2.0 6.1 0.40 0.09 0.44 0.049 Nov 17 19 8.9 5.9 4.6 1.8 4.4 0.45 <0.02 0.56 0.033 Dec 23 20 9.2 5.7 4.8 2.1 5.8 0.87 0.08 0.64 0.043 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.1 6.5 83 16 68 240 1.8 < 0.2 < 2 10 Feb 2.2 18 117 7.5 52 252 1.5 <0.2 <2 <10 Mar 2.3 15 100 14 108 347 2.0 <0.2 <2 <10 Apr 2.5 11 84 25 62 336 2.2 <0.2 <2 <10 May 3.0 9.4 91 18 68 600 2.0 <0.2 <2 <10 Jun 2.6 4.7 71 4.4 69 51 2.0 < 0.2 < 2 <10 Jul 2.5 1.5 58 6.9 60 363 1.8 <0.2 <2 <10 Aug 2.6 3.0 76 3.4 62 143 < 2 < 0.2 < 2 <10 Sep 3.2 5.3 72 3.1 80 148 2 <0.2 <2 <10 Oct 4.8 24 76 6.4 64 404 2.4 < 0.2 < 2 <10 Nov 3.0 8.5 74 16 55 213 3.3 <0.2 <2 12 Dec 2.8 8.9 50 7.4 82 400 2.3 <0.2 <2 <10 Appendix C - 27 Table C-7 (continued) Pee Dee River below Tillery Development (Station TY12131 No Generation Flow)-2004 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 16 21 15 16 5.7 1.5 9.1 0.44 < 0.02 1.24 0.276 Feb 21 27 12 9.2 6.1 2.8 7.2 0.53 0.04 0.68 0.089 Mar 24 30 14 9.0 7.0 3.1 9.0 0.75 0.04 0.72 0.086 Apr 32 37 15 8.5 7.8 4.3 8.1 0.57 0.04 0.96 0.120 May 24 26 8.6 5.4 6.0 2.8 8.5 0.36 0.03 0.59 0.056 Jun 24 28 9.9 7.0 6.3 3.0 9.1 1.81 0.08 0.68 0.115 Jul 26 28 13 4.8 6.1 3.1 6.3 0.53 0.05 0.43 0.061 Aug 28 24 8.0 6.1 5.4 2.6 8.6 0.58 <0.02 0.30 0.071 Sep 24 27 7.8 13 6.0 2.8 8.0 0.57 <0.02 0.53 0.117 Oct 22 24 11 5.5 5.6 2.4 5.8 0.54 0.09 0.46 0.066 Nov 26 36 14 12 8.9 3.4 8.6 0.49 <0.02 0.96 0.097 Dec 29 31 11 8.5 6.8 3.4 7.7 0.43 0.05 0.59 0.077 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 3.0 27 117 8.6 101 197 2.7 < 0.2 < 2 11 Feb 5.8 30 150 15 58 637 2.7 <0.2 <2 18 Mar 4.8 18 106 10 107 348 2.5 <0.2 <2 <10 Apr 3.9 17 122 8.6 92 231 2.4 <0.2 <2 <10 May 3.5 16 100 14 86 445 2.2 <0.2 <2 <10 Jun 3.2 21 112 12 84 871 4.0 <0.2 <2 <10 Jul 2.8 14 74 10 54 213 2.0 <0.2 <2 <10 Aug 3.1 21 103 22 75 635 3.0 <0.2 <2 <10 Sep 6.7 17 102 11 88 451 3.0 <0.2 <2 18 Oct 5.8 9.1 82 8.0 80 419 2.3 <0.2 <2 12 Nov 4.0 9.4 102 4.8 98 126 3.3 <0.2 <2 14 Dec 5.5 13 64 6.3 92 378 3.0 <0.2 <2 14 Appendix C - 28 Table C-7 (continued) Pee Dee River below Tillery Development (Station TY12B, Generation Flow)-2004 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 14 9.0 9.7 7.5 3.6 < 1 5.4 0.34 0.02 0.81 0.052 Feb 24 35 13 11 7.8 3.7 9.5 0.46 <0.02 1.16 0.127 Mar 17 23 9.0 5.7 5.5 2.3 6.8 0.71 0.03 0.73 0.051 Apr 21 23 11 5.3 5.4 2.4 7.1 0.58 <0.02 0.64 0.038 May 23 26 8.6 5.2 6.0 2.8 8.0 0.42 0.04 0.46 0.071 Jun 22 29 10 8.5 6.7 2.9 9.4 1.98 0.06 0.72 0.122 Jul 17 28 13 26 5.9 3.1 5.8 0.59 0.03 0.39 0.064 Aug 33 35 11 16 7.6 3.9 1.3 0.71 <0.02 0.78 0.177 Sep 27 31 9.2 8.7 7.0 3.2 8.6 0.57 <0.02 0.98 0.197 Oct 16 21 12 7.3 5.1 1.9 5.2 0.64 0.05 0.52 0.060 Nov 22 23 10 7.6 5.6 2.1 5.3 0.47 <0.02 0.71 0.058 Dec 27 27 11 8.6 6.2 2.7 6.9 0.45 0.03 0.97 0.077 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.2 7.2 77 4.3 67 122 1.5 <0.2 <2 11 Feb 5.8 30 86 22 107 749 3.4 <0.2 <2 18 Mar 2.4 17 106 3.9 109 512 2.5 <0.2 <2 <10 Apr 2.5 9.0 72 5.2 62 216 2.0 <0.2 <2 <10 May 5.3 15 99 18 80 517 2.5 <0.2 <2 14 Jun 3.0 29 118 19 86 626 3.5 <0.2 <2 <10 Jul 2.6 26 77 18 64 415 2.3 < 0.2 < 2 < 10 Aug 4.7 16 141 24 93 699 4.0 < 0.2 < 2 < 10 Sep 5.3 45 138 46 104 1,260 5.0 <0.2 <2 <10 Oct 4.9 15 85 14 76 639 2.6 <0.2 <2 13 Nov 3.5 10 74 5.3 66 226 2.5 <0.2 <2 14 Dec 3.2 12 82 10 104 354 2.2 <0.2 <2 <10 Appendix C - 29 Table C-7 (continued) Rocky River (Station RR, surface)-2004 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Jan 15 31 22 25 8.7 2.2 Feb 22 47 17 16 11 5.0 Mar 19 49 10 16 12 4.8 Apr 40 50 19 16 12 4.9 May 51 53 21 17 12 5.8 Jun 38 48 21 22 12 4.6 Jul 30 90 70 7.4 24 7.2 Aug 40 43 14 18 9.7 4.6 Sep 30 34 11 13 9.9 2.2 Oct 35 53 11 15 13 5.3 Nov 50 66 22 19 16 6.1 Dec 30 40 14 14 8.6 4.6 nitrite-N 16 0.48 <0.02 2.50 0.113 12 0.60 0.02 2.82 0.221 15 0.62 <0.02 1.68 0.207 12 0.65 0.02 1.31 0.223 21 0.63 0.05 2.44 0.43S 17 2.40 0.07 1.85 0.47S 44 1.25 0.06 9.37 1.09 15 0.69 <0.02 1.30 0.201 9.4 0.78 <0.02 1.50 0.258 14 0.31 <0.02 1.68 0.197 15 0.51 < 0.02 4.17 0.227 7.8 0.80 0.03 1.12 0.192 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 3.6 3.2 159 1.3 137 96 4.4 <0.2 <2 <10 Feb 4.4 20 117 16 108 311 3.9 <0.2 <2 16 Mar 3.3 17 112 5.2 120 293 3.2 <0.2 <2 10 Apr 4.7 16 148 12 115 305 3.9 <0.2 <2 <10 May 5.6 17 206 24 158 633 4.6 <0.2 <2 12 Jun 4.7 73 194 46 124 1,580 6.5 <0.2 <2 <10 Jul 6.8 21 300 23 286 617 5.9 <0.2 <2 18 Aug 5.5 8.6 151 10 113 647 5.0 < 0.2 < 2 <10 Sep 6.7 28 138 16 125 950 7.0 <0.2 <2 19 Oct 5.0 9.4 139 16 134 524 3.8 <0.2 <2 11 Nov 3.7 26 164 8.5 165 400 3.6 <0.2 <2 11 Dec 5.0 55 156 41 119 2,080 5.7 <0.2 <2 21 Units are in mg/liter except trace metals which are in (Dg/liter and turbidity which is in NTU. Total alkalinity is measured as mg/L as CaCO, and hardness is calculated as mg equivalents CaCO,/L. Appendix C - 30 APPENDIX D RAW DATA LISTING FOR WATER CHEMISTRY PARAMETERS COLLECTED IN BLEWETT FALLS LAKE AND THE PEE DEE RIVER DURING 1999, 2001, AND 2004 Table D-1 Concentrations of water chemistry parameters in Blewett Falls Lake (Stations BFB2, BFF2, and BFH2) during 1999.1 Blewett Falls Lake (Station BFB2, surface) -1999 Month Total Hardness CT SO4 Ca 2, Mg2+ Na TN NH3-N Nitrate+ Alkalinity (calculated) nitrite-N Jan 26 22 11 5.0 5.5 2.1 14 0.71 0.15 0.35 Feb 23 24 9.0 5.0 5.6 2.5 10 0.97 <0.05 0.58 Mar 26 24 11 7.0 6.0 2.2 15 0.99 <0.05 0.57 Apr 23 24 10 9.0 5.8 2.4 13 0.84 <0.05 0.38 May 23 23 11 11 5.5 2.3 12 0.98 0.07 0.31 Jun 30 27 11 10 6.3 2.8 16 0.91 <0.05 0.10 Jul 24 26 10 7.0 5.9 2.7 15 0.36 0.24 0.14 Aug 28 23 9.0 7.0 4.9 2.6 14 0.55 <0.05 <0.02 Sep 36 22 12 8.9 4.5 2.5 15 0.32 <0.05 <0.02 Oct 28 21 11 9.0 4.6 2.4 11 0.50 0.09 0.34 Nov 31 19 14 11 5.3 2.6 14 0.79 <0.05 0.38 Dec 41 33 18 14 7.2 3.6 20 1.3 0.18 0.69 Month TP TOC Turbidity TS TSS TDS Al Cu Hg COD Jan 0.057 4.7 23 87 4.0 62 350 6.9 <0.2 <20 Feb 0.068 4.1 28 92 9.0 88 620 3.4 <0.2 <20 Mar 0.079 3.9 32 112 11 86 380 7.5 <0.2 <20 Apr 0.054 3.4 8.8 89 6.5 80 220 2.4 <0.2 <20 May 0.055 3.4 3.5 77 3.3 79 <50 <1.0 <0.2 <20 Jun 0.048 4.1 5.3 85 3.0 168 120 2.1 <0.2 <20 Jul 0.073 3.3 23 99 14 86 340 2.2 <0.2 <20 Aug 0.042 3.6 3.2 88 <3 85 <50 <1.0 <0.2 <20 Sep 0.059 3.9 5.6 88 4.4 94 <50 7.5 <0.2 <20 Oct 0.076 4.9 28 94 16 78 670 <1.0 <0.2 <20 Nov 0.050 5.1 11 88 10 113 200 4.4 <0.2 <20 Dec 0.169 6.5 20 82 8.0 109 370 3.4 <0.2 20 Appendix D - 1 Table D-1 (continued) Blewett Falls Lake (Station BFF2, surface)-1999 Month Total Alkalinity Hardness (calculated) CF Jan 28 24 12 Feb 24 24 11 Mar 23 21 9.0 Apr 14 25 11 May 27 20 11 Jun 24 24 10 Jul 33 28 13 Aug 20 22 9.0 Sep 49 27 22 Oct 23 21 11 Nov 33 28 16 Dec 25 22 13 SO4- Ca2+ Mgz+ Na 7.0 5.9 2.3 15 7.0 5.7 2.3 11 5.0 5.2 2.0 9.8 11 5.9 2.4 14 11 4.7 2.0 9.8 11 5.6 2.5 13 8.0 6.3 3.0 18 6.0 4.8 2.5 14 17 5.5 3.2 29 7.0 4.4 2.4 11 15 6.2 3.0 19 9.0 4.7 2.4 13 TN NH3-N Nitrate + nitrite-N 0.81 <0.05 0.47 0.93 <0.05 0.50 0.75 < 0.05 0.49 0.84 < 0.05 0.42 0.91 <0.05 0.38 1.0 < 0.05 0.28 0.94 0.11 0.54 0.70 <0.05 <0.02 0.71 0.06 0.36 0.54 <0.05 0.31 0.82 <0.05 0.42 0.81 0.16 0.32 Month TP TOC Turbidity TS TSS TDS Al Cu Hg COD Jan 0.071 4.5 23 91 5.0 78 330 9.9 <0.2 <20 Feb 0.073 4.7 24 94 7.5 92 280 5.2 <0.2 <20 Mar 0.052 3.5 21 86 6.3 81 510 5.1 <0.2 <20 Apr 0.077 3.9 12 96 12 89 180 7.4 <0.2 <20 May 0.077 3.5 17 87 10 74 170 < 1.0 < 0.2 < 20 Jun 0.075 3.5 13 87 9.8 72 190 < 1.0 < 0.2 <20 Jul 0.111 3.3 16 107 9.3 94 330 2.1 <0.2 21 Aug 0.056 3.7 9.6 94 9.3 79 140 2.1 <0.2 <20 Sep 0.225 5.4 10 142 8.4 133 180 9.2 <0.2 <20 Oct 0.063 4.2 26 92 27 87 900 1.1 <0.2 <20 Nov 0.096 4.7 10 104 6.0 137 160 2.7 <0.2 <20 Dec 0.054 2.7 20 72 6.0 74 320 1.8 <0.2 20 Appendix D - 2 Table D-1 (continued) Blewett Falls Lake (Station BFH2, surface)-1999 Month Total Hardness CF SO4 Ca 2, Mg2+ Na TN NH3-N Nitrate+ Alkalinity (calculated) nitrite-N Jan 28 28 12 6.0 6.5 2.8 14 0.92 < 0.05 0.48 Feb 24 24 10 7.0 5.6 2.3 11 0.93 <0.05 0.58 Mar 30 29 13 9.0 7.0 2.8 16 0.96 <0.05 0.53 Apr 14 22 10 8.0 5.3 2.1 12 0.92 <0.05 0.58 May 27 21 11 10 4.9 2.1 11 0.93 <0.05 0.46 Jun 26 25 11 12 5.8 2.6 15 1.0 0.09 0.54 Jul 24 24 8.0 6.0 5.3 2.5 12 0.79 < 0.05 0.44 Aug 32 24 13 10 5.3 2.8 20 0.56 <0.05 0.18 Sep 36 25 18 14 5.2 2.8 24 0.59 <0.05 0.30 Oct 26 20 10 6.0 4.4 2.3 11 0.50 <0.05 0.26 Nov 33 22 13 11 4.9 2.4 14 0.55 <0.05 0.27 Dec 31 20 12 9.0 4.3 2.2 12 0.71 0.11 0.28 Month TP TOC Turbidity TS TSS TDS Al Cu Hg COD Jan 0.092 4.4 27 98 15 86 1,100 5.8 <0.2 <20 Feb 0.064 4.1 20 91 3.5 88 230 7.9 <0.2 <20 Mar 0.086 3.7 12 105 3.7 99 300 14 <0.2 <20 Apr 0.044 3.0 9.9 83 4.8 76 150 7.6 <0.2 <20 May 0.041 3.3 7.8 74 5.5 75 120 3.4 <0.2 <20 Jun 0.070 3.4 11 93 7.2 80 260 <1.0 <0.2 <20 Jul 0.054 2.9 7.0 73 5.3 72 210 1.6 <0.2 <20 Aug 0.124 3.6 7.6 117 9.7 111 170 <1.0 <0.2 <20 Sep 0.150 4.1 9.0 114 7.2 100 130 8.0 <0.2 <20 Oct 0.046 4.5 13 66 <5 76 220 <1.0 <0.2 <20 Nov 0.047 4.4 7.4 80 9.0 103 140 1.7 <0.2 <20 Dec 0.031 2.7 9.6 52 8.0 70 140 1.4 <0.2 <20 Units are in mg/liter except trace metals which are in (Dg/liter and turbidity which is in NTU. Total alkalinity is measured as mg/L as CaCO, and hardness is calculated as mg equivalents CaCO,/L. Appendix D - 3 Table D-2 Concentrations of water chemistry parameters in Blewett Falls Lake (Stations BFB2, BFF2, and BFH2) during 2001.1 Blewett Falls Lake (Station BFB2, surface)-2001 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 33 26 11 10 6.0 2.6 13 0.91 0.08 0.50 0.067 Feb 32 35 19 14 8.0 3.6 18 1.6 <0.05 0.95 0.223 Mar 22 29 13 9.7 6.6 3.0 9.8 1.6 <0.05 0.75 0.162 Apr 28 29 12 15 7.3 2.7 11 1.2 0.07 0.71 0.086 May 33 35 18 18 8.4 3.3 15 0.74 0.25 0.21 0.091 Jun 30 25 13 14 5.7 2.6 12 1.1 0.13 0.24 0.072 Jul 31 28 10 14 6.9 2.6 9.8 0.72 0.07 0.09 0.060 Aug 36 27 15 14 6.7 2.5 17 0.83 <0.05 0.14 0.090 Sep 34 28 12 13 6.8 2.6 14 0.69 0.11 0.09 0.076 Oct 40 31 26 22 7.2 3.1 24 1.1 0.03 0.34 0.118 Nov 46 35 25 20 8.4 3.5 26 0.90 <0.02 0.08 0.084 Dec 37 31 14 16 7.4 3.1 17 0.87 0.12 0.26 0.094 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 4.0 6.7 89 <5 73 95 1.6 <0.2 <2 <20 Feb 8.1 25 106 13 106 400 4.1 <0.2 <2 <20 Mar 7.5 52 90 21 88 1,000 4.3 <0.2 <2 33 Apr 3.6 13 121 7.8 86 177 3.0 <0.2 <2 14 May 5.3 4.2 108 3.0 84 <50 2.0 <0.2 3.5 <10 Jun 4.8 2.8 118 4.2 76 87 2.0 <0.2 4.2 20 Jul 5.4 4.7 86 3.6 104 <50 2.0 <0.2 2.7 26 Aug 4.4 7.2 114 6.2 94 157 2.0 < 0.2 2.3 <10 Sep 4.2 14 90 9.0 78 230 1.9 <0.2 <2 10 Oct 3.4 16 147 15 108 336 2.5 <0.2 <2 22 Nov 5.7 6.0 114 7.5 138 51 2.1 <0.2 4.0 24 Dec 6.3 13 110 9.6 108 182 2.9 <0.2 <2 13 Appendix D - 4 Table D-2 (continued) Blewett Falls Lake (Station BFF2, surface)-2001 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 33 30 15 <2 7.0 3.0 16 1.1 0.10 0.66 0.079 Feb 28 30 14 9.0 7.1 3.0 13 1.2 <0.05 0.66 0.126 Mar 26 31 14 11 7.1 3.1 12 1.4 <0.05 0.86 0.126 Apr 27 28 9.8 12 7.1 2.4 2.4 0.95 0.07 0.62 0.078 May 32 31 15 16 7.6 3.0 13 0.91 0.10 0.27 0.065 Jun 30 24 11 10 5.3 2.5 11 1.2 0.11 0.10 0.100 Jul 31 26 9.8 12 6.3 2.5 9.2 1.0 0.07 0.17 0.096 Aug 31 21 11 11 5.2 2.0 9.2 0.84 <0.05 0.16 0.098 Sep 32 26 10 11 6.6 2.4 11 0.55 <0.05 0.04 0.058 Oct 39 33 20 18 8.0 3.1 18 0.82 <0.02 0.22 0.146 Nov 44 34 24 23 8.3 3.3 25 1.1 <0.02 0.40 0.136 Dec 36 34 15 16 8.0 3.5 17 1.6 0.05 0.94 0.265 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 3.8 12 93 5.7 77 230 1.8 <0.2 <2 <20 Feb 6.3 39 80 13 83 540 2.9 <0.2 <2 <20 Mar 4.7 38 92 28 87 860 3.5 <0.2 <2 24 Apr 3.3 15 87 6.4 97 118 3.0 <0.2 <2 10 May 4.6 5.3 97 3.8 83 <50 2.0 <0.2 2.3 13 Jun 5.5 4.3 107 5.0 75 <50 2.0 <0.2 4.0 18 Jul 4.5 8.9 90 9.0 113 113 3.0 <0.2 2.7 31 Aug 4.0 13 106 9.4 78 153 1.0 <0.2 3.0 20 Sep 3.8 9.0 84 7.0 73 141 1.8 <0.2 <2 13 Oct 3.3 18 134 15 114 350 2.5 <0.2 2.7 23 Nov 5.3 11 116 9.2 129 269 2.2 <0.2 <2 18 Dec 6.6 20 133 12 121 292 2.7 <0.2 <2 14 Appendix D - 5 Table D-2 (continued) Blewett Falls Lake (Station BFH2, surface)-2001 Month Total Alkalinity Hardness (calculated) CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ nitrite-N TP Jan 62 57 34 28 13 5.9 37 2.9 0.09 2.24 0.395 Feb 28 34 16 11 7.9 3.5 13 1.7 <0.05 1.05 0.170 Mar 25 27 14 9.6 6.3 2.7 12 1.1 <0.05 0.66 0.051 Apr 29 30 12 15 7.5 2.7 11 1.1 0.09 0.73 0.040 May 23 28 13 12 6.8 2.8 11 0.87 0.34 0.48 0.058 Jun 31 24 14 16 5.4 2.6 13 1.1 0.10 0.67 0.156 Jul 33 28 12 15 6.8 2.7 12 0.90 0.07 0.60 0.102 Aug 29 23 11 11 5.6 2.1 11 0.82 < 0.05 0.42 0.100 Sep 31 26 9.9 9.3 6.4 2.3 10 0.51 <0.05 <0.02 0.044 Oct 42 31 21 20 7.5 2.9 21 0.88 <0.02 0.39 0.142 Nov 52 38 32 33 9.2 3.6 34 1.5 0.02 0.97 0.278 Dec 32 28 10 12 6.8 2.6 11 0.64 <0.02 0.20 0.081 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 6.3 11 188 <5 M 220 4.4 <0.2 <2 <20 Feb 6.9 42 102 15 9 690 3.5 <0.2 <2 <20 Mar 3.3 10 64 8.0 9 210 2.5 <0.2 <2 <20 Apr 3.8 6.2 117 9.6 6 169 4.0 <0.2 <2 14 May 4.1 8.3 97 5.8 4 84 3.0 <0.2 <2 11 Jun 4.4 5.2 125 7.0 9 115 2.0 < 0.2 2.0 20 Jul 3.6 7.5 101 7.8 M 135 3.0 <0.2 <2 20 Aug 4.7 11 106 6.8 7 193 2.0 < 0.2 < 2 13 Sep 3.8 5.6 73 4.4 0 68 1.4 <0.2 <2 12 Oct 2.9 4.9 132 3.5 S 74 2.2 <0.2 <2 19 Nov 6.6 9.5 146 8.4 2 222 5.1 < 0.2 2.0 17 Dec 5.3 11 96 9.6 0 152 1.7 <0.2 <2 25 Units are in mg/liter except trace metals which are in (Dg/liter and turbidity which is in NTU. Total alkalinity is measured as mg/L as CaCO, and hardness is calculated as mg equivalents CaCO,/L. Appendix D - 6 Table D-3 Concentrations of water chemistry parameters in Blewett Falls Lake (Stations BFB2, BFF2, and BFH2) during 2004.1 Blewett Falls Lake (Station BFB2, surface)-2004 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 20 4.5 12 6.8 1.8 <1 5.2 0.37 <0.02 0.78 0.052 Feb 23 24 8.6 9.7 5.8 2.4 6.6 0.42 0.03 0.86 0.064 Mar 20 25 11 7.9 5.9 2.4 7.3 0.46 < 0.02 0.73 0.060 Apr 22 25 12 5.9 5.9 2.6 7.9 0.65 < 0.02 0.67 0.051 May 24 26 8.0 5.6 6.0 2.7 8.1 0.62 < 0.02 0.26 0.052 Jun 23 26 8.7 5.6 6.1 2.5 8.6 0.69 < 0.02 0.27 0.073 Jul 23 21 13 8.8 4.2 2.6 4.8 0.69 < 0.02 0.10 0.037 Aug 26 22 7.5 6.5 5.0 2.3 7.1 0.80 0.11 <0.02 0.066 Sep 24 26 7.7 7.0 6.1 2.5 8.5 0.58 <0.02 0.57 0.086 Oct 21 24 11 5.1 5.8 2.2 6.0 0.67 <0.02 0.53 0.077 Nov 26 27 12 7.5 6.5 2.6 6.7 0.43 0.04 0.74 0.054 Dec 22 24 6.8 6.3 6.0 2.2 6.5 0.41 0.07 0.58 0.066 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.2 10 76 8.8 61 194 1.5 < 0.2 < 2 < 10 Feb 2.7 18 81 9.3 118 195 1.6 <0.2 <2 10 Mar 2.6 17 121 9.0 105 335 2.3 <0.2 <2 <10 Apr 2.4 20 112 16 51 282 1.9 <0.2 <2 10 May 3.7 0.5 73 8.0 65 146 1.8 < 0.2 3.4 14 Jun 2.9 12 84 7.2 68 232 5.3 <0.2 2.2 <10 Jul 2.9 1.1 76 3.3 64 90 1.3 < 0.2 2.5 < 10 Aug 3.8 3.1 73 4.8 58 200 2.0 <0.2 3.2 <10 Sep 4.0 14 100 14 92 385 3.0 <0.2 <2 <10 Oct 4.6 18 96 13 64 401 4.4 < 0.2 < 2 13 Nov 3.6 14 107 18 76 721 4.3 < 0.2 < 2 12 Dec 3.1 19 78 16 66 305 2.2 <0.2 <2 <10 Appendix D - 7 Table D-3 (continued) Blewett Falls Lake (Station BFB2, bottom)-2004 Month Total Hardness CF SO4 Ca 2, Me+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 19 4.4 11 7.1 1.8 < 1 5.1 0.45 < 0.02 0.75 0.051 Feb 26 26 8.7 9.7 6.3 2.6 7.0 0.40 <0.02 1.02 0.079 Mar 21 24 11 6.9 5.6 2.4 6.9 0.52 <0.02 0.77 0.070 Apr 22 23 12 5.4 5.4 2.4 7.2 0.80 < 0.02 0.66 0.054 May 25 30 8.3 5.9 7.1 3.0 8.2 0.55 0.06 0.45 0.079 Jun 23 26 8.3 5.8 6.0 2.6 7.7 1.71 0.12 0.44 0.079 Jul 22 29 12 10 6.3 3.1 5.9 0.90 0.19 0.27 0.119 Aug 25 23 7.6 7.6 5.3 2.4 7.1 0.63 0.08 0.24 0.091 Sep 24 27 7.8 6.1 6.5 2.7 8.7 0.58 0.03 0.60 0.100 Oct 24 28 12 5.3 6.5 2.7 6.5 0.32 0.13 1.54 0.127 Nov 21 22 10 6.9 5.3 2.1 5.2 0.62 < 0.02 0.65 0.092 Dec 23 50 9.6 7.4 8.9 6.6 6.9 3.932 0.18 0.42 0.6542 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.3 13 78 9.4 56 181 1.6 <0.2 <2 <10 Feb 2.9 30 95 14 64 304 2.4 <0.2 <2 13 Mar 2.8 34 108 19 111 762 2.9 <0.2 <2 <10 Apr 2.3 28 106 17 57 398 1.9 <0.2 <2 <10 May 4.1 6.5 130 41 76 3,080 5.9 <0.2 2.8 14 Jun 2.6 66 93 18 70 576 3.1 <0.2 2.4 <10 Jul 3.0 46 107 48 61 1240 3.2 <0.2 <2 11 Aug 3.3 28 96 18 68 1750 3.0 <0.2 <2 <10 Sep 4.2 76 105 22 95 617 3.0 <0.2 <2 <10 Oct 4.8 52 132 40 77 1020 3.8 <0.2 <2 10 Nov 3.7 38 78 6.6 66 272 5.6 <0.2 <2 14 Dec 4.1 31 1802 16 82 62 20,0002 402 <0.2 4.2 962 Appendix D - 8 Table D-3 (continued) Blewett Falls Lake (Station BFF2, surface)-2004 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 18 4.7 11 8.0 1.9 < 1 5.7 0.38 0.02 0.83 0.051 Feb 23 23 7.8 8.6 5.6 2.2 6.6 0.48 0.04 0.83 0.044 Mar 22 26 12 8.2 6.1 2.6 8.1 0.92 < 0.02 0.87 0.068 Apr 24 23 12 5.7 5.2 2.5 8.0 0.57 <0.02 0.66 0.052 May 26 28 9.3 6.5 6.4 2.9 9.5 0.49 < 0.02 0.69 0.080 Jun 19 24 8.7 5.6 5.7 2.5 7.5 1.38 <0.02 0.44 0.092 Jul 22 27 13 7.9 5.7 3.0 6.8 0.90 <0.02 0.09 0.056 Aug 26 21 7.2 5.8 4.9 2.2 7.2 0.52 <0.02 <0.02 0.047 Sep 21 22 6.7 5.7 5.4 2.2 7.8 0.46 0.14 0.58 0.057 Oct 19 24 11 5.6 6.0 2.3 6.3 0.36 <0.02 0.64 0.058 Nov 20 21 10 7.1 5.2 2.0 5.0 0.40 < 0.02 0.68 0.047 Dec 24 24 7.8 7.6 5.4 2.5 6.3 0.52 0.07 0.65 0.085 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.2 7.2 76 5.1 62 192 3.6 < 0.2 < 2 <10 Feb 2.7 14 94 5.5 54 146 1.4 <0.2 <2 <10 Mar 3.0 17 101 9.6 106 298 2.2 <0.2 <2 22 Apr 2.5 12 105 10 68 178 1.8 <0.2 <2 11 May 3.7 0.9 88 8.9 74 287 2.5 <0.2 <2 <10 Jun 2.8 20 84 6.6 68 496 2.4 <0.2 2.3 <10 Jul 2.8 2.5 71 6.2 59 86 1.6 <0.2 3 13 Aug 2.9 7.8 80 8.6 62 392 <2.0 <0.2 2 <10 Sep 3.6 10 86 12 77 283 2.0 <0.2 <2 <10 Oct 4.4 8.6 84 6.9 67 275 2.6 <0.2 <2 <10 Nov 3.5 9.8 80 4.4 58 132 3.0 <0.2 <2 12 Dec 4.3 28 88 17 78 940 3.1 <0.2 <2 15 Appendix D - 9 Table D-3 (continued) Blewett Falls Lake (Station BFF2, bottom)-2004 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 15 9.2 10 9.1 2.0 1.0 5.7 0.46 0.02 0.52 0.068 Feb 24 24 7.8 8.7 5.8 2.3 6.6 0.47 0.05 0.74 0.054 Mar 23 26 12 7.5 6.2 2.6 7.9 0.84 <0.02 0.86 0.096 Apr 28 29 14 12 6.2 3.3 10 1.04 0.19 0.71 0.205 May 25 29 8.7 7.6 6.6 3.0 9.2 0.54 0.06 0.61 0.083 Jun 19 26 7.7 5.9 6.0 2.6 6.9 1.15 0.15 0.34 0.077 Jul 24 32 13 6.3 7.2 3.5 6.8 0.83 0.21 0.22 0.074 Aug 36 30 8.2 6.5 6.4 3.3 7.4 1.10 0.31 0.13 0.179 Sep 21 23 6.8 5.2 5.7 2.2 7.9 0.46 <0.02 0.59 0.066 Oct 20 22 11 5.8 5.4 2.2 5.8 0.40 0.03 0.53 0.076 Nov 22 28 11 6.4 6.9 2.6 6.4 0.41 < 0.02 0.79 0.072 Dec 22 24 7.9 7.8 5.4 2.5 6.5 0.50 0.04 0.64 0.089 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.2 19 84 13 66 587 9.4 <0.2 <2 <10 Feb 2.2 18 97 8.2 56 284 1.6 <0.2 <2 11 Mar 2.9 28 112 33 104 854 3.1 <0.2 <2 18 Apr 2.8 153 186 100 90 1,940 5.2 <0.2 <2 10 May 3.9 2.6 115 36 74 993 3.4 < 0.2 2 < 10 Jun 2.6 90 88 27 66 719 3.2 <0.2 <2 <10 Jul 2.6 65 90 30 57 726 2.5 < 0.2 < 2 < 10 Aug 2.9 77 178 84 73 3,830 7.0 <0.2 <3.6 13 Sep 3.6 30 95 21 82 439 3.0 <0.2 <2 <10 Oct 4.5 78 104 23 60 884 3.5 <0.2 <2 <10 Nov 3.5 35 91 11 73 335 3.2 <0.2 <2 13 Dec 4.2 36 101 25 80 631 2.9 <0.2 <2 11 Appendix D - 10 Table D-3 (continued) Blewett Falls Lake (Station BFH2, surface)-2004 Month Total Alkalinity Hardness (calculated) CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ nitrite-N TP Jan 21 4.1 9.5 5.8 1.6 < 1 4.9 0.55 0.05 0.69 0.037 Feb 28 30 9.8 12 7.0 2.9 8.0 0.39 <0.02 1.36 0.089 Mar 22 27 13 10 6.4 2.7 8.7 0.69 <0.02 1.03 0.081 Apr 33 32 16 7.4 7.1 3.6 12 0.74 0.02 1.13 0.122 May 22 25 7.4 5.6 5.8 2.6 7.8 0.30 <0.02 0.44 0.033 Jun 20 23 7.5 5.2 5.3 2.4 6.6 1.33 0.06 0.40 0.043 Jul 24 26 12 3.5 5.3 3.0 5.9 0.73 <0.02 0.14 0.034 Aug 24 21 7.0 5.5 4.7 2.2 7.1 0.65 <0.02 <0.02 0.042 Sep 20 21 6.8 5.9 5.1 2.1 7.9 0.43 0.07 0.56 0.052 Oct 19 21 10 5.2 5.1 2.0 5.4 0.43 0.02 0.53 0.055 Nov 22 20 9.6 9.7 4.7 1.9 4.8 0.37 <0.02 0.55 0.035 Dec 23 27 8.6 9.4 5.9 2.9 6.7 0.52 <0.02 0.74 0.103 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.5 6.0 64 2.7 56 115 1.3 <0.2 <2 <10 Feb 3.0 13 105 5.8 52 152 1.8 <0.2 <2 <10 Mar 2.8 14 107 9.2 105 280 2.3 <0.2 <2 <10 Apr 3.5 9.3 115 5.6 104 136 2.2 <0.2 <2 <10 May 3.0 0.5 71 5.5 72 185 1.7 <0.2 <2 <10 Jun 2.7 13 72 7.6 64 252 2.3 <0.2 2.3 <10 Jul 2.7 3.8 64 6.8 60 104 1.7 <0.2 2.5 <10 Aug 3.0 5.6 79 7.0 64 280 <2.0 <0.2 <2 <10 Sep 3.8 7.5 82 7.6 80 226 2.0 <0.2 <2 <10 Oct 4.6 11 84 11 58 314 2.5 <0.2 <2 12 Nov 3.5 7.7 76 4.8 63 177 4.2 <0.2 <2 13 Dec 4.8 31 92 15 83 884 3.2 <0.2 <2 14 Units are in mg/liter except trace metals which are in (Dg/liter and turbidity which is in NTU. Total alkalinity is measured as mg/L as CaCO, and hardness is calculated as mg equivalents CaCO,/L. 2 Aluminum (20,000 µg/L), copper (40 pg/L), total nitrogen (3.93), total phosphorus (0.654), total suspended solids (168), and COD (96 mg/L) values were unusually high at Station B2, bottom waters, during December 2004 and suspected of being contaminated with lake bottom sediments. Appendix D - 11 Table D-4 Concentrations of water chemistry parameters in the Pee Dee River below the Blewett Falls Development (Stations BF1B, BF2B, BF3B, and BF4B) during 1999.1 Pee Dee River below Blewett Falls Development (Station BF1B)-1999 Month Total Hardness CT SO4 Ca 2, Mgr Na TN NH3-N Nitrate+ Alkalinity (calculated) nitrite-N Jan 28 25 11 7.0 5.8 2.5 14 0.77 <0.05 0.42 Feb 24 23 10 6.0 5.6 2.2 11 0.90 <0.05 0.56 Mar 25 25 8.0 4.0 5.9 2.4 12 0.85 < 0.05 0.56 Apr 8 23 10 8.0 5.3 2.3 12 0.89 0.11 0.45 May 23 19 10 10 4.4 2.0 9.1 0.94 0.16 0.49 Jun 26 24 9.8 8.9 5.2 2.6 14 1.0 0.17 0.25 Jul 28 25 9.0 7.0 5.7 2.7 15 0.92 0.22 0.19 Aug 28 23 9.0 7.0 4.9 2.5 13 0.73 0.13 0.07 Sep 28 21 12 9.1 4.2 2.6 16 0.35 0.14 0.09 Oct 26 23 10 10 5.0 2.6 10 0.64 0.06 0.45 Nov 31 24 14 11 5.3 2.7 14 0.71 0.21 0.41 Dec 35 29 17 13 6.4 3.2 18 1.2 0.09 0.59 Month TP TOC Turbidity TS TSS TDS Al Cu Hg COD Jan 0.050 4.5 18 86 5.0 66 570 10.0 <0.2 <20 Feb 0.072 3.6 26 103 11 97 350 6.7 <0.2 <20 Mar 0.070 3.5 25 104 9.0 91 540 2.4 <0.2 <20 Apr 0.046 3.8 7.7 84 4.0 72 210 7.1 <0.2 <20 May 0.051 4.1 9.4 74 5.0 77 150 <1.0 <0.2 <20 Jun 0.056 3.7 12 86 14 72 290 2.7 <0.2 <20 Jul 0.107 3.5 33 95 26 80 680 2.4 <0.2 <20 Aug 0.055 3.4 13 93 11 88 430 2.2 <0.2 39 Sep 0.066 3.6 24 97 18 54 510 9.6 <0.2 <20 Oct 0.093 5.2 34 76 20 84 970 1.6 <0.2 36 Nov 0.051 4.7 12 88 <5 94 230 1.7 <0.2 <20 Dec 0.130 4.7 8.5 106 <5 109 180 3.0 <0.2 23 Appendix D - 12 Table D-4 (continued) Pee Dee River below Blewett Falls Development (Station BF2B)-1999 Month Total Hardness CF SO4 Ca 2, Mgz+ Na TN NH3-N Nitrate+ Alkalinity (calculated) nitrite-N Jan 25 22 11 6.0 5.1 2.2 12 0.73 < 0.05 0.41 Feb 22 17 10 5.0 5.1 2.2 10 1.1 <0.05 0.69 Mar 23 22 7.0 3.0 5.2 2.1 11 0.88 <0.05 0.52 Apr 14 20 10 8.0 4.5 2.2 9.2 0.76 < 0.05 0.44 May 27 20 10 10 4.7 2.1 10 0.85 < 0.05 0.53 Jun 24 22 12 9.6 4.8 2.4 15 0.85 < 0.05 0.41 Jul 24 25 10 7.0 5.4 2.7 15 0.84 0.10 0.38 Aug 20 20 12 7.0 4.1 2.4 14 0.43 < 0.05 0.12 Sep 32 21 13 9.4 4.4 2.5 17 0.39 <0.05 0.09 Oct 26 23 10 9.0 4.9 2.5 9.4 0.74 <0.05 0.48 Nov 24 22 14 10 4.9 2.3 13 0.71 < 0.05 0.39 Dec 29 24 16 11 5.2 2.6 17 0.90 0.09 0.42 Month TP TOC Turbidity TS TSS TDS Al Cu Hg COD Jan 0.058 4.0 44 99 17 75 1,400 1.9 <0.2 <20 Feb 0.076 4.2 32 108 14 100 560 4.0 <0.2 <20 Mar 0.055 3.9 12 88 <3 87 320 5.0 <0.2 <20 Apr 0.047 3.9 4.8 75 <3 69 130 2.9 <0.2 <20 May 0.076 3.9 7.8 82 3.0 78 130 <1.0 <0.2 <20 Jun 0.057 3.5 7.4 85 3.8 76 160 3.6 <0.2 <20 Jul 0.064 3.5 6.2 29 <3 84 140 1.5 <0.2 <20 Aug 0.056 3.7 3.8 89 <3 83 110 1.5 <0.2 52 Sep 0.053 4.0 5.0 94 <3 64 100 2.1 <0.2 <20 Oct 0.081 5.6 25 82 13 101 760 1.5 <0.2 22 Nov 0.054 5.3 6.0 74 < 5 97 190 1.4 < 0.2 <20 Dec 0.073 4.0 11 112 <5 93 220 2.4 <0.2 <20 Appendix D - 13 Table D-4 (continued) Pee Dee River below Blewett Falls Development (Station BF3B)-1999 Month Total Hardness CF SO4 Ca 2, Mgz+ Na TN NH3-N Nitrate+ Alkalinity (calculated) nitrite-N Jan 25 18 13 6.0 4.4 1.8 18 0.72 <0.05 0.32 Feb 23 20 10 5.0 4.8 2.0 12 0.99 <0.05 0.67 Mar 32 24 7.0 3.0 6.0 2.2 23 1.0 0.08 0.46 Apr 37 20 13 10 4.6 2.0 18 0.78 0.07 0.38 May 27 22 13 12 5.1 2.2 16 0.83 0.08 0.51 Jun 38 22 14 12 4.8 2.4 21 0.86 0.27 0.39 Jul 28 25 19 9.0 5.2 2.8 26 0.93 0.06 0.47 Aug 28 20 12 8.0 4.0 2.4 20 0.44 < 0.05 0.06 Sep 40 21 19 13 4.4 2.4 26 4.9 0.07 0.12 Oct 26 23 12 9.0 5.0 2.5 11 0.66 <0.05 0.48 Nov 31 21 16 12 4.7 2.3 19 0.69 < 0.05 0.40 Dec 33 22 17 12 5.0 2.4 18 0.79 0.10 0.33 Month TP TOC Turbidity TS TSS TDS Al Cu Hg COD Jan 0.065 5.1 23 92 13 70 430 5.0 <0.2 <20 Feb 0.073 5.1 30 121 14.5 102 320 4.6 <0.2 <20 Mar 0.086 4.8 18 113 8.7 107 340 7.9 <0.2 <20 Apr 0.092 4.1 9.1 104 7.2 95 180 7.2 <0.2 <20 May 0.078 4.9 20 104 12 83 220 3.0 <0.2 21 Jun 0.093 3.8 15 111 11.6 95 260 2.7 <0.2 <20 Jul 0.119 4.6 23 127 15.5 102 470 2.2 < 0.2 21 Aug 0.076 4.0 9.4 111 12.7 95 390 2.3 <0.2 <20 Sep 0.102 5.1 19 147 17 82 390 9.3 <0.2 <20 Oct 0.096 6.7 32 94 18 105 1,200 2.0 <0.2 24 Nov 0.059 6.1 6.9 88 <5 118 150 1.6 <0.2 <20 Dec 0.073 3.8 17 128 12 99 430 2.2 <0.2 <20 Appendix D - 14 Table D-4 (continued) Pee Dee River below Blewett Falls Development (Station BF4B)-1999 Month Total Alkalinity Hardness (calculated) CF SO4 Ca 2, Mg2+ Na TN NH3-N Nitrate+ nitrite-N Jan 25 22 12 7.0 5.3 2.0 15 0.59 <0.05 0.36 Feb 22 20 10 5.0 4.8 1.9 11 0.99 <0.05 0.62 Mar 26 22 5.0 < 2 5.2 2.1 15 0.76 0.07 0.44 Apr 15 21 14 9.0 4.8 2.1 17 0.92 0.08 0.54 May 23 20 12 11 4.5 2.0 14 0.72 < 0.05 0.48 Jun 40 21 16 13 4.6 2.1 28 0.99 0.06 0.35 Jul 24 24 13 7.0 5.5 2.4 19 0.83 0.16 0.33 Aug 36 22 19 10 4.8 2.5 27 0.53 <0.05 0.08 Sep 40 20 18 13 4.1 2.4 30 5.8 <0.05 0.06 Oct 16 18 10 6.0 4.0 2.0 8.2 0.48 <0.05 0.27 Nov 18 19 12 7.0 4.3 2.1 11 0.77 <0.05 0.20 Dec 26 19 16 11 4.2 2.0 18 0.78 <0.05 0.29 Month TP TOC Turbidity TS TSS TDS Al Cu Hg COD Jan 0.077 6.5 25 91 14 60 430 4.3 <0.2 <20 Feb 0.079 5.6 25 106 14 100 320 4.0 <0.2 <20 Mar 0.091 4.3 26 105 14 97 390 2.5 <0.2 <20 Apr 0.094 4.7 16 99 16 90 310 6.6 <0.2 <20 May 0.091 5.3 32 111 32 188 320 <1.0 <0.2 23 Jun 0.122 4.0 23 133 26 106 430 7.4 <0.2 <20 Jul 0.137 7.4 26 117 28 115 600 2.1 <0.2 <20 Aug 0.102 5.6 15 141 15 125 430 2.1 <0.2 47 Sep 0.128 4.2 26 165 30 118 570 15 <0.2 <20 Oct 0.095 9.2 35 104 23 91 1,000 1.3 <0.2 24 Nov 0.094 15 13 92 7.0 114 360 1.4 <0.2 39 Dec 0.091 4.6 26 122 17 96 370 1.9 <0.2 <20 Units are in mg/liter except trace metals which are in (Dg/liter and turbidity which is in NTU. Total alkalinity is measured as mg/L as CaCO, and hardness is calculated as mg equivalents CaCO,/L. Appendix D - 15 Table D-5 Concentrations of water chemistry parameters in the Pee Dee River below the Blewett Falls Development (Stations BF1B, BF2B, BF3B, and BF4B) during 2001.1 Pee Dee River below Blewett Falls Development (Station BF1B)-2001 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 29 27 14 10 6.2 2.7 13 0.98 0.05 0.59 0.060 Feb 32 33 18 12 7.5 3.4 18 1.1 <0.05 0.63 0.140 Mar 22 28 13 9.3 6.5 2.9 9.3 1.4 <0.05 0.79 0.160 Apr 26 27 10 13 6.6 2.4 9.8 0.92 0.12 0.66 0.057 May 27 27 15 15 6.3 2.8 13 0.96 0.41 0.48 0.074 Jun 27 23 12 15 5.0 2.5 12 1.1 0.22 0.53 0.084 Jul 28 25 9.3 12 5.9 2.4 8.7 0.90 0.17 0.38 0.066 Aug 36 27 15 14 6.9 2.3 17 0.94 0.08 0.41 0.097 Sep 32 26 13 12 6.4 2.4 14 0.72 <0.05 0.30 0.077 Oct 39 29 24 22 6.8 3.0 23 0.81 <0.02 0.34 0.062 Nov 46 35 25 24 8.5 3.4 25 0.89 0.06 0.30 0.052 Dec 37 32 15 17 7.5 3.2 17 0.39 0.07 0.39 0.106 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 3.3 6.0 91 <5 68 130 1.6 <0.2 <2 <20 Feb 5.6 18 80 14 112 330 2.5 <0.2 <2 <20 Mar 6.8 43 94 18 92 1,300 4.6 <0.2 3.0 33 Apr 3.8 4.9 90 <1 83 138 3.0 <0.2 <2 17 May 4.5 5.5 91 2.6 84 82 3.0 <0.2 <2 13 Jun 4.3 4.2 102 5.0 79 131 2.0 < 0.2 < 2 23 Jul 4.2 14 113 8.6 111 276 3.0 <0.2 <2 17 Aug 4.1 8.0 119 4.8 90 173 2.0 < 0.2 < 2 12 Sep 4.0 4.5 85 2.2 80 87 1.9 <0.2 <2 <10 Oct 3.2 3.1 124 1.4 116 58 1.7 <0.2 <2 16 Nov 5.4 2.1 108 2.2 130 79 1.6 <0.2 <2 21 Dec 6.3 12 120 12 115 186 2.3 <0.2 <2 15 Appendix D - 16 Table D-5 (continued) Pee Dee River below Blewett Falls Development (Station BF2B)-2001 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 25 20 13 8.0 4.6 2.0 12 0.55 0.07 0.22 0.030 Feb 30 29 20 11 6.8 3.0 19 0.95 <0.05 0.55 0.087 Mar 16 23 8.9 8.0 5.2 2.5 9.0 1.3 <0.05 0.75 0.134 Apr 25 27 11 14 6.7 2.5 10 0.97 0.09 0.68 0.066 May 30 31 14 15 7.2 3.2 15 0.78 0.34 0.50 0.056 Jun 29 22 14 16 4.8 2.5 13 1.1 0.10 0.63 0.088 Jul 26 23 16 14 5.4 2.4 13 0.79 0.06 0.46 0.070 Aug 33 24 16 18 6.0 2.2 17 0.87 <0.05 0.45 0.084 Sep 30 27 15 16 6.5 2.6 16 0.64 <0.05 0.27 0.354 Oct 33 25 21 13 5.9 2.4 18 0.43 <0.02 0.04 0.043 Nov 38 28 26 23 6.6 2.8 23 0.50 <0.02 0.06 0.030 Dec 34 29 16 18 6.9 2.9 18 0.49 < 0.02 0.49 0.080 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 3.8 2.7 81 <5 123 53 1.3 <0.2 <2 <20 Feb 4.7 11 84 8.0 95 210 1.6 <0.2 <2 21 Mar 7.0 31 78 12 81 880 3.6 <0.2 <2 35 Apr 3.9 9.3 96 4.0 79 180 3.0 <0.2 <2 18 May 4.0 2.2 96 <1 98 50 3.0 <0.2 <2 12 Jun 4.3 1.9 114 1.0 82 66 2.0 <0.2 <2 19 Jul 4.4 4.3 127 1.0 127 95 2.0 <0.2 <2 20 Aug 3.8 6.9 117 3.4 90 162 2.0 <0.2 <2 10 Sep 3.7 2.6 102 1.2 88 51 2.0 <0.2 <2 <10 Oct 3.5 1.6 100 <1 98 <50 2.0 <0.2 <2 18 Nov 5.6 1.5 100 1.2 119 <50 1.6 <0.2 <2 21 Dec 6.2 3.5 131 2.0 119 <50 2.3 <0.2 <2 13 Appendix D - 17 Table D-5 (continued) Pee Dee River below Blewett Falls Development (Station BF3B)-2001 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 33 18 16 10 4.2 1.9 19 0.64 0.07 0.25 0.050 Feb 35 27 25 15 6.5 2.7 27 1.0 <0.05 0.44 0.074 Mar 21 24 16 10 5.6 2.5 14 1.4 0.09 0.62 0.146 Apr 27 25 12 17 6.2 2.3 13 1.1 0.10 0.57 0.088 May 36 29 20 24 6.7 3.0 24 1.3 0.40 0.64 0.096 Jun 30 18 15 14 3.7 2.1 16 0.98 0.14 0.44 0.088 Jul 31 23 14 14 5.3 2.3 14 0.91 0.05 0.42 0.094 Aug 43 30 25 26 7.7 2.5 31 1.0 0.08 0.46 0.091 Sep 37 29 20 17 7.2 2.7 22 1.0 0.22 0.34 0.123 Oct 62 27 42 37 6.9 2.3 52 0.75 0.04 0.14 0.133 Nov 47 30 37 35 7.2 2.9 43 0.76 0.10 0.10 0.073 Dec 44 30 23 25 7.1 3.0 32 0.43 0.04 0.43 0.088 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 5.0 6.5 107 9.6 105 220 1.5 < 0.2 < 2 < 20 Feb 6.5 13 118 10 116 260 1.5 <0.2 2.0 <20 Mar 7.9 35 94 13 90 1,000 4.0 <0.2 3.0 31 Apr 5.1 18 99 16 89 344 3.0 <0.2 <2 14 May 6.7 5.3 140 4.8 111 102 3.0 <0.2 <2 15 Jun 4.6 5.4 128 5.6 96 182 2.0 <0.2 <2 21 Jul 4.8 12 138 7.0 128 217 3.0 <0.2 <2 25 Aug 5.7 10 167 12 137 233 2.0 < 0.2 < 2 23 Sep 4.6 6.5 117 11 100 150 1.9 <0.2 <2 12 Oct 6.5 2.6 202 1.2 209 92 2.4 <0.2 <2 32 Nov 8.6 7.7 156 6.2 177 264 2.0 <0.2 <2 28 Dec 8.3 17 162 16 155 332 3.1 <0.2 <2 19 Appendix D - 18 Table D-5 (continued) Pee Dee River below Blewett Falls Development (Station BF4B)-2001 Month Total Alkalinity Hardness (calculated) CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ nitrite-N TP Jan 17 15 13 7.0 3.5 1.6 10 1.0 0.06 0.18 0.067 Feb 29 24 16 10 5.6 2.5 17 0.85 <0.05 0.42 0.119 Mar 19 24 14 8.8 5.5 2.5 10 1.4 < 0.05 0.69 0.175 Apr 26 25 11 16 6.2 2.3 11 1.0 0.09 0.54 0.094 May 35 28 16 16 6.4 2.8 20 0.73 0.33 0.31 0.138 Jun 36 22 17 16 4.7 2.4 21 1.1 0.16 0.46 0.167 Jul 37 22 18 17 5.1 2.3 20 0.99 <0.05 0.44 0.158 Aug 36 25 17 16 6.3 2.2 22 0.79 <0.05 0.23 0.157 Sep 40 29 22 23 7.2 2.7 31 1.0 <0.05 0.38 0.187 Oct 45 19 24 21 4.6 1.8 30 0.72 <0.02 0.28 0.239 Nov 55 29 38 39 6.9 2.8 49 0.96 0.04 0.45 0.215 Dec 50 32 25 27 7.6 3.2 37 0.47 0.08 0.47 0.164 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 9.9 13 95 6.7 99 0 1.6 <0.2 <2 <20 Feb 4.8 37 94 28 80 5 1.9 <0.2 <2 <20 Mar 8.1 47 100 21 92 M 4.4 <0.2 <2 <20 Apr 4.7 22 102 16 78 9 5.0 <0.2 <2 20 May 4.7 30 143 31 93 4 3.0 <0.2 <2 12 Jun 6.3 12 131 7.2 99 M 2.0 <0.2 2.0 24 Jul 6.7 21 177 15 151 4 3.0 <0.2 2.3 30 Aug 3.9 21 151 25 97 5 3.0 < 0.2 < 2 15 Sep 4.6 9.1 145 6.2 118 9 2.3 <0.2 <2 16 Oct 3.4 4.1 132 7.6 133 9 2.2 <0.2 <2 <10 Nov 7.9 4.5 176 1.8 195 8 2.4 <0.2 <2 27 Dec 8.4 8.6 165 6.0 161 1 3.4 <0.2 <2 20 Units are in mg/liter except trace metals which are in (Dg/liter and turbidity which is in NTU. Total alkalinity is measured as mg/L as CaCO, and hardness is calculated as mg equivalents CaCO,/L. Appendix D - 19 Table D-6 Concentrations of water chemistry parameters in the Pee Dee River below the Blewett Falls Development (Stations BFOB, BF1B, BF2B, BF3B, and BF4B) during 2004.1 Pee Dee River below Blewett Falls Development (Station BFOB, Generation Flow)-2004 Month Total Hardness CF SO4 Cat Mgz+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 18 4.2 10 6.2 1.7 < 1 5.2 0.35 < 0.02 0.76 0.049 Feb 26 27 8.6 7.3 6.5 2.7 7.3 0.57 0.03 1.04 0.073 Mar 20 24 11 7.2 5.8 2.4 7.2 0.89 < 0.02 0.77 0.063 Apr 22 22 12 5.6 5.0 2.2 6.8 0.70 <0.02 0.66 0.058 May 22 26 8.0 5.9 5.9 2.7 7.8 0.50 0.02 0.40 0.061 Jun 23 25 8.9 6.0 5.9 2.5 7.9 1.5 0.07 0.41 0.075 Jul 21 25 12 < 2 5.2 2.9 5.4 0.43 0.08 0.23 0.052 Aug 26 22 7.1 6.1 5.0 2.3 7.1 0.74 <0.02 0.08 0.063 Sep 24 25 7.6 6.4 5.9 2.5 8.4 0.59 <0.02 0.58 0.087 Oct 20 26 12 5.9 6.1 2.5 6.3 0.57 0.04 0.46 0.086 Nov 22 26 11 6.6 6.4 2.5 6.3 0.42 < 0.02 0.72 0.059 Dec 24 23 9.6 6.8 5.2 2.4 6.6 0.58 0.05 0.63 0.086 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.4 10 74 7.9 58 199 1.5 <0.2 <2 <10 Feb 2.9 22 102 9.8 56 264 1.8 <0.2 <2 12 Mar 2.6 24 108 12 103 355 2.2 <0.2 <2 <10 Apr 2.5 24 104 14 69 309 1.8 <0.2 <2 <10 May 3.6 2.2 92 25 71 746 2.4 <0.2 2.1 10 Jun 2.7 32 90 15 76 446 2.7 <0.2 2.6 <10 Jul 2.6 9.7 82 13 66 388 1.9 <0.2 <2 <10 Aug 3.4 6.5 79 8.0 60 446 2.0 < 0.2 2 12 Sep 3.9 18 100 18 88 500 3.0 <0.2 <2 <10 Oct 4.7 27 101 22 70 687 3.4 <0.2 <2 <10 Nov 3.6 19 90 8.5 66 386 3.8 <0.2 <2 13 Dec 3.0 25 100 34 69 665 4.0 <0.2 <2 <10 Appendix D - 20 Table D-6 (continued) Pee Dee River below Blewett Falls Development (Station BF113, No Generation Flow)-2004 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 14 8.0 10 8.0 3.2 <1 4.9 0.27 < 0.02 0.67 0.063 Feb 24 27 8.6 7.7 6.5 2.7 7.2 0.77 0.03 1.04 0.068 Mar 20 23 11 5.8 5.4 2.4 6.9 0.60 0.02 0.79 0.058 Apr 21 21 11 8.0 4.5 2.3 7.1 0.68 0.03 0.65 0.044 May 21 21 7.6 6.2 4.8 2.3 6.8 0.42 0.07 0.40 0.059 Jun 19 22 8.2 5.0 5.0 2.4 7.3 1.2 0.11 0.41 0.055 Jul 22 24 12 7.4 4.8 3.1 5.8 0.58 0.10 0.31 0.037 Aug 22 16 7.2 7.5 3.3 1.9 5.7 0.57 <0.02 0.36 0.084 Sep 24 25 7.6 6.3 5.7 2.6 10 0.53 0.05 0.62 0.082 Oct 11 24 11 6.5 5.8 2.3 5.6 0.41 0.05 0.62 0.071 Nov 18 22 11 5.6 5.4 2.1 5.1 0.47 0.03 0.59 0.051 Dec 25 23 11 7.1 5.4 2.4 6.7 0.39 0.02 0.71 0.051 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.4 19 89 27 70 216 1.7 <0.2 <2 <10 Feb 3.0 17 82 8.3 60 254 2.3 <0.2 <2 <10 Mar 2.8 17 104 6.0 108 280 2.4 <0.2 <2 11 Apr 2.8 13 66 6.4 76 210 1.7 <0.2 <2 <10 May 3.1 0.6 78 8.8 81 257 1.6 <0.2 <2 <10 Jun 2.8 15 73 4.2 70 244 2.2 < 0.2 < 2 < 10 Jul 2.8 3.0 66 3.4 59 107 1.6 <0.2 <2 <10 Aug 3.6 6.3 81 7.8 76 762 3.0 <0.2 <2 <10 Sep 4.3 9.1 94 16 84 293 3.0 <0.2 <2 <10 Oct 3.9 13 90 8.8 83 348 2.8 <0.2 <2 10 Nov 3.8 6.6 90 1.5 77 130 2.8 <0.2 <2 11 Dec 3.6 9.1 74 3.5 68 162 2.2 <0.2 <2 <10 Appendix D - 21 Table D-6 (continued) Pee Dee River below Blewett Falls Development (Station BF1B, Generation Flow)-2004 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 17 3.9 9.7 6.7 1.6 < 1 4.9 0.35 < 0.02 0.72 0.047 Feb 22 28 8.4 7.9 6.6 2.7 7.4 0.37 0.04 1.02 0.077 Mar 19 24 11 6.8 5.6 2.4 7.0 0.45 < 0.02 0.76 0.066 Apr 20 22 11 5.4 5.0 2.3 7.2 0.76 0.03 0.56 0.058 May 23 26 7.9 6.2 5.8 2.7 7.8 0.48 0.03 0.45 0.062 Jun 21 25 8.0 5.2 5.6 2.6 7.9 1.8 0.13 0.45 0.075 Jul 23 24 12 7.7 4.8 3.0 5.5 0.60 0.11 0.27 0.049 Aug 21 18 7.2 5.5 3.5 2.4 7.0 0.65 0.02 0.33 0.092 Sep 24 27 7.8 6.4 6.1 2.8 8.8 0.53 0.04 0.63 0.099 Oct 22 25 12 5.2 6.0 2.5 6.3 0.58 0.06 0.69 0.083 Nov 25 26 12 8.1 6.4 2.5 6.8 0.42 0.04 0.75 0.076 Dec 22 22 9.8 6.8 5.0 2.3 6.4 0.54 0.06 0.62 0.077 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.6 11 67 8.4 60 207 1.5 <0.2 <2 <10 Feb 3.1 21 104 11 56 322 2.1 <0.2 <2 11 Mar 2.8 27 106 13 103 404 2.6 < 0.2 < 2 <10 Apr 2.6 33 119 13 52 253 1.9 <0.2 <2 <10 May 3.6 2.1 88 20 77 741 2.3 <0.2 <2 11 Jun 2.8 28 91 12 76 479 2.7 < 0.2 2.2 <10 Jul 2.6 14 78 13 66 484 2.1 <0.2 <2 <10 Aug 3.6 11 80 6.2 68 476 2.0 <0.2 <2 <10 Sep 4.4 19 102 15 88 531 3.0 <0.2 <2 <10 Oct 4.7 17 85 11 76 396 2.8 <0.2 <2 <10 Nov 3.7 15 102 6.4 68 144 3.4 <0.2 <2 13 Dec 3.3 23 98 16 66 792 3.0 <0.2 <2 <10 Appendix D - 22 Table D-6 (continued) Pee Dee River below Blewett Falls Development (Station BF2B, No Generation Flow)-2004 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 12 7.7 10 6.8 3.1 <1 5.2 0.30 <0.02 0.65 0.028 Feb 23 27 8.5 8.1 6.5 2.7 7.7 0.34 <0.02 0.98 0.063 Mar 19 22 11 7.8 5.2 2.3 7.0 0.39 <0.02 0.76 0.052 Apr 20 22 13 5.6 4.9 2.3 8.6 0.65 <0.02 0.61 0.037 May 20 21 7.9 5.4 4.5 2.3 7.2 0.37 <0.02 0.45 0.040 Jun 15 19 8.7 5.8 4.1 2.2 8.5 1.04 0.05 0.46 0.075 Jul 24 24 13 6.7 4.8 2.8 5.5 0.48 <0.02 0.06 0.037 Aug 20 20 7.7 5.1 4.3 2.3 7.4 0.53 <0.02 0.39 0.084 Sep 23 25 8.3 7.1 5.9 2.6 9.0 0.44 <0.02 0.64 0.090 Oct 22 26 12 11 6.4 2.5 6.5 0.39 <0.02 0.67 0.085 Nov 20 23 12 7.1 5.6 2.1 5.2 0.67 <0.02 0.57 0.056 Dec 22 20 11 7.1 4.7 2.0 7.0 0.35 <0.02 0.61 0.049 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.5 2.2 68 2.1 64 178 1.5 <0.2 <2 <10 Feb 3.1 19 91 7.2 57 227 1.8 <0.2 <2 11 Mar 3.0 17 107 12 106 301 2.2 <0.2 <2 <10 Apr 3.0 9.0 76 1.9 62 123 1.5 < 0.2 < 2 <10 May 3.0 0.7 77 3.9 70 231 1.6 < 0.2 < 2 <10 Jun 3.2 12 77 3.4 78 306 2.4 <0.2 <2 <10 Jul 3.0 1.2 58 1.7 58 97 1.4 <0.2 <2 <10 Aug 3.9 7.0 77 2.6 64 260 3.0 < 0.2 < 2 <10 Sep 4.4 14 97 12 96 412 2.0 <0.2 <2 <10 Oct 5.0 15 82 9.0 70 364 2.8 <0.2 <2 <10 Nov 4.2 16 90 5.6 78 212 2.8 <0.2 <2 15 Dec 3.7 12 82 4.3 70 225 1.9 <0.2 <2 16 Appendix D - 23 Table D-6 (continued) Pee Dee River below Blewett Falls Development (Station BF2B, Generation Flow)-2004 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 18 5.5 10 8.9 2.2 <1 5.3 0.36 <0.02 0.72 0.055 Feb 21 30 9.4 6.7 7.0 2.9 8.9 0.52 <0.02 1.02 0.067 Mar 20 22 11 7.0 5.1 2.3 7.1 0.51 <0.02 0.75 0.063 Apr 20 24 12 7.5 5.5 2.5 9.0 0.33 0.08 0.62 0.036 May 21 24 8.1 5.9 5.3 2.6 7.9 0.44 0.03 0.55 0.056 Jun 22 22 8.9 5.8 4.7 2.4 7.6 0.38 0.09 0.38 0.076 Jul 22 25 22 5.5 5.0 3.0 6.8 0.53 <0.02 0.16 0.037 Aug 24 22 13 5.5 4.7 2.4 8.4 0.52 0.08 0.28 0.077 Sep 25 28 14 8.5 6.7 2.7 8.5 0.86 0.08 0.92 0.157 Oct 20 23 12 6.1 5.5 2.2 6.5 0.38 <0.02 0.58 0.069 Nov 20 21 12 8.5 5.3 2.0 5.1 0.34 <0.02 0.60 0.057 Dec 22 22 9.7 5.6 5.4 2.1 6.6 1.3 <0.02 0.71 0.057 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 2.7 13 76 10 64 224 1.6 < 0.2 < 2 <10 Feb 3.0 34 139 26 110 368 1.9 <0.2 <2 <10 Mar 3.1 29 104 11 106 458 2.4 <0.2 <2 <10 Apr 2.8 9.5 71 9.7 64 196 1.5 <0.2 <2 <10 May 3.5 1.4 83 13 76 438 2.2 <0.2 <2 <10 Jun 2.6 52 80 17 64 461 2.5 <0.2 <2 <10 Jul 2.8 5.6 51 3.2 79 87 2.3 <0.2 <2 <10 Aug 3.5 9.8 76 7.9 66 324 2.6 <0.2 <2 <10 Sep 6.3 20 118 14 107 560 4.6 <0.2 <2 16 Oct 4.1 24 86 8.6 71 518 2.8 <0.2 <2 <10 Nov 3.7 25 86 6.0 70 350 2.7 <0.2 <2 14 Dec 3.1 11 70 6.7 76 291 2.1 <0.2 <2 <10 Appendix D - 24 Table D-6 (continued) Pee Dee River below Blewett Falls Development (Station BF3B, Generation Flow)-2004 Month Total Hardness CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ TP Alkalinity (calculated) nitrite-N Jan 19 5.8 12 10 2.3 < 1 7.2 0.37 0.05 0.69 0.054 Feb 23 27 12 8.8 6.4 2.7 10 0.50 <0.02 0.88 0.069 Mar 19 22 12 6.9 5.1 2.2 7.4 0.44 < 0.02 0.72 0.080 Apr 24 26 16 7.0 6.0 2.6 11 0.53 0.03 0.60 0.055 May 23 23 10 5.4 5.0 2.6 9.7 0.43 0.04 0.44 0.063 Jun 21 24 18 9.6 5.1 2.6 11 0.56 0.07 0.48 0.084 Jul 24 24 17 10 4.7 3.1 16 0.60 0.02 0.36 0.056 Aug 29 20 21 10 4.2 2.4 17 0.57 <0.02 0.34 0.115 Sep 25 27 11 12 6.5 2.6 12 0.92 <0.02 0.91 0.173 Oct 22 22 14 8.0 5.4 2.2 8.8 0.38 0.02 0.90 0.080 Nov 20 22 10 6.1 5.5 2.0 7.7 0.41 0.03 0.58 0.061 Dec 22 22 11 6.5 5.1 2.1 7.0 0.58 0.04 0.70 0.070 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 3.0 12 84 8.5 70 216 1.5 <0.2 <2 <10 Feb 4.0 21 105 10 106 437 2.4 <0.2 <2 14 Mar 3.3 19 106 16 103 424 2.5 < 0.2 < 2 <10 Apr 3.4 16 85 13 64 364 1.7 <0.2 <2 <10 May 4.5 1.5 105 15 84 452 3.0 <0.2 <2 12 Jun 3.4 47 101 15 81 487 2.8 <0.2 <2 <10 Jul 3.6 15 111 25 110 864 4.0 <0.2 <2 <10 Aug 4.5 16 115 18 98 518 2.9 <0.2 <2 14 Sep 8.0 24 132 22 109 570 4.4 <0.2 <2 21 Oct 4.6 19 98 17 84 455 2.9 <0.2 <2 11 Nov 4.2 18 97 6.1 80 341 3.0 <0.2 <2 12 Dec 3.8 19 86 13 82 622 2.5 <0.2 <2 <10 Appendix D - 25 Table D-6 (continued) Pee Dee River below Blewett Falls Development (Station BF4B, Generation Flow)-2004 Month Total Alkalinity Hardness (calculated) CT SO4 Ca2, Mg2+ Na TN NH3-N Nitrate+ nitrite-N TP Jan 17 5.3 16 15 2.1 < 1 13 0.43 0.09 0.58 0.066 Feb 21 29 16 9.5 6.9 2.8 10 0.43 0.08 0.96 0.074 Mar 20 22 13 8.8 5.0 2.2 9.9 0.54 0.05 0.74 0.062 Apr 22 24 14 9.1 5.3 2.5 9.6 0.44 < 0.02 0.62 0.085 May 27 24 11 6.3 5.1 2.6 11 0.45 0.03 0.50 0.094 Jun 28 25 23 15 5.4 2.9 21 0.65 0.07 0.71 0.036 Jul 25 26 50 7.9 5.1 3.3 10 0.52 0.02 0.24 0.098 Aug 32 22 20 9.8 4.9 2.4 19 0.58 <0.02 0.48 0.141 Sep 25 24 8.0 13 5.7 2.4 8.2 1.1 0.03 0.49 0.159 Oct 23 23 14 8.7 5.6 2.2 10 0.50 0.10 0.63 0.099 Nov 26 21 14 9.2 5.4 1.9 10 0.49 < 0.02 0.61 0.125 Dec 23 36 11 6.4 7.0 4.5 9.0 0.60 0.03 0.75 0.105 Month TOC Turbidity TS TSS TDS Al Cu Hg BOD COD Jan 4.2 16 105 15 84 293 1.9 <0.2 <2 <10 Feb 3.9 22 118 11 108 388 2.4 <0.2 <2 29 Mar 3.9 25 106 23 104 450 2.7 <0.2 <2 <10 Apr 3.0 25 101 20 82 612 2.2 <0.2 <2 <10 May 4.6 2.9 128 27 78 1,240 3.0 <0.2 <2 <10 Jun 3.9 39 148 41 104 5,320 3.7 <0.2 <2 <10 Jul 3.2 52 81 9.8 93 778 3.1 <0.2 <2 <10 Aug 5.2 12 124 14 88 473 3.9 <0.2 <2 12 Sep 11 16 128 13 106 292 3.4 <0.2 <2 31 Oct 4.9 21 100 20 86 752 3.2 <0.2 <2 14 Nov 4.6 21 112 14 73 431 5.1 <0.2 <2 16 Dec 3.8 34 98 29 87 1,290 3.4 <0.2 <2 11 Units are in mg/liter except trace metals which are in (Dg/liter and turbidity which is in NTU. Total alkalinity is measured as mg/L as CaCO3 and hardness is calculated as mg equivalents CaCO,/L. Appendix D - 26 APPENDIX E MONTHLY TRENDS IN SOLIDS, TURBIDITY, AND NUTRIENT CONSTITUENTS IN LAKE TILLERY (STATION TYB2), REACH 1 OF THE PEE DEE RIVER (STATIONS TY1B AND TY12B), ROCKY RIVER (STATION RR), AND THE HEADWATERS OF BLEWETT FALLS LAKE (STATION BFH2) DURING 2004 300 250 200 cn 150 E 100 50 0 300 250 200 rn 150 E 100 50 0 300 250 200 J a? 150 E 100 50 0 300 250 200 rn 150 E 100 50 0 300 250 200 rn 150 E 100 50 0 Banc I Illcl - LIED LIV II IJL Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month ROCKY River -5tation RR Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month --*--Surface - ?- - Bottom Figure E-1 Monthly trends in total solids at Station TY132 in Lake Tillery, Stations TY1B and TY12B (Generation Flow) hi Reach 1 below the Tillery Hydroelectric Plant, Station RR in the Rocky River, and Station BFH2 located in the Blewett Falls Lake headwaters during 2004. ?ppendix E - 1 _L 300 250 200 J rn 150 8 100 50 0 300 250 200 J rn 150 E 100 50 0 300 250 200 rn 150 8 100 50 0 300 250 200 J `af 150 £ 100 50 0 300 250 200 J rn 150 E 100 50 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Pee Dee River - Station TY1 B Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month -surface - i- - Bottom Figure E-2 Monthly trends in total dissolved solids at Station TYB2 in Lake Tillery, Stations TY113 and TY12B (Generation Flow) in Reach 1 below the Tillery Hydroelectric Plant, Station RR in the Rocky River, and Station BFH2 located in the Blewett Falls Lake headwaters during 2004. ppendix E - 2 A L 80 70 60 50 40 8 30 20 10 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 80 70 60 50 40 8 30 20 10 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 80 70 60 50 ai 40 AIL 8 30 20 10 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 80 70 60 50 ai 40 8 30 20 10 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 80 70 60 50 as 40 8 30 20 10 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 1-9-Surface - ?- - Bottom Figure E-3 Monthly trends in total suspended solids at Station TY132 in Lake Tillery, Stations TY113 and TY12B (Generation Flow) in Reach 1 below the Tillery Hydroelectric Plant, Station RR in the Rocky River, and Station BFI-12 located in the Blewett Falls Lake headwaters during 2004. ppendix E - 3 A L 80 60 7 H 40 Z 20 0 80 60 t- 4 0 Z 20 0 80 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 60 F- 40 Z 20 0 80 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 60 F- 40 Z 20 0 80 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 60 I- 40 Z 20 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month --*--Surface - -- -Bottom Figure E-4 Monthly trends in turbidity at Station TYB2 in Lake Tillery, Stations TY1B and TY12B (Generation Flow) in Reach 1 below the Tillery Hydroelectric Plant, Station RR in the Rocky River, and Station BFH2 located in the Blewett Falls Lake headwaters during 2004. ppendix E - 4 A L Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 3.00 2.50 2.00 J rn 1.50 8 1.00 0.50 0.00 3.00 2.50 2.00 J 'af 1.50 E 1.00 0.50 0.00 3.00 2.50 2.00 m 1.50 H 1.00 0.50 0.00 3.00 2.50 2.00 J `af 1.50 E 1.00 0.50 0.00 3.00 2.50 2.00 J of 1.50 1.00 0.50 0.00 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Pee Dee River - Station TY1 B Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month -surface - i- - Bottom Figure E-5 Monthly trends in total nitrogen at Station TYB2 in Lake Tillery, Stations TY113 and TY12B (Generation Flow) in Reach 1 below the Tillery Hydroelectric Plant, Station RR in the Rocky River, and Station BFH2 located in the Blewett Falls Lake headwaters during 2004. ppendix E - 5 A L 1.50 1.2 5 1.0 0 J m 0.75 E 0.50 0.25 0.00 1.50 1.25 1.00 J m 0.75 E 0.50 0.25 0.00 L"dKe 1 Illery - - ?a Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 10.00 8.00 6.00 ai E 4.00 2.00 0.00 1.50 1.25 1.00 c? 0.75 E 0.50 0.25 0.00 1.50 1.25 1.00 J c? 0.75 E 0.50 0.25 0.00 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 1-0--Surface - -- - Bottom Figure E-6 Monthly trends in nitrate + nitrite-nitrogen at Station TY132 in Lake Tillery, Stations TY1B and TY12B (Generation Flow) in Reach 1 below the Tillery Hydroelectric Plant, Station RR in the Rocky River, and Station BFH2 located in the Blewett Falls Lake headwaters during 2004. ppendix E - 6 A L 0.25 0.20 0.15 E 0.10 0.05 0.00 0.25 0.20 0.15 E 0.10 0.05 0.00 0.25 0.20 0.15 rn E 0.10 0.05 0.00 0.25 0.20 0.15 E 0.10 0.05 0.00 0.25 0.20 0.15 E 0.10 0.05 0.00 I akp Tillaru _ Rtntinn TYR9 M~ s ? ? ? ? r r r Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month --o-Surface - i- - Bottom Figure E-7 Monthly trends in ammonia-nitrogen at Station TYB2 in Lake Tillery, Stations TY1B and TY12B (Generation Flow) in Reach 1 below the Tillery Hydroelectric Plant, Station RR in the Rocky River, and Station BFH2 located in the Blewett Falls Lake headwaters during 2004. ppendiY E - 7 A L 1.2 5 1.0 0 t4 0.75 rn E 0.50 0.25 0.00 1.25 1.00 0.75 a? E 0.50 0.25 0.00 1.25 1.00 0.75 E 0.50 0.25 0.00 1.25 1.00 t4 0.75 rn E 0.50 0.25 0.00 1.25 1.00 0.75 rn E 0.50 0.25 0.00 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month --?--surface - ?- - Bottom Figure E-S Monthly trends in total phosphorus at Station TYB2 in Lake Tillery, Stations TY113 and TY12B (Generation Flow) in Reach 1 below the Tillery Hydroelectric Plant, Station RR in the Rocky River, and Station BFI-12 located in the Blewett Falls Lake headwaters during 2004. ppendix E - 8 A L 8.0 6.0 rn 4.0 E 2.0 0.0 8.0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 6.0 cm 4.0 E 2.0 0.0 8.0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 6.0 ai 4.0 E 2.0 0.0 8.0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 6.0 rn 4.0 E 2.0 0.0 8.0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 6.0 rn 4.0 E 2.0 0.0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 1--o-surface, - i- - Bottom Figure E-9 Monthly trends in total organic carbon at Station TYB2 in Lake Tillery, Stations TY1B and TY12B (Generation Flow) in Reach 1 below the Tillery Hydroelectric Plant, Station RR in the Rocky River, and Station BFH2 located in the Blewett Falls Lake headwaters during 2004. ppendix E - 9 A L APPENDIX F MONTHLY TRENDS IN SOLIDS, TURBIDITY, AND NUTRIENT CONSTITUENTS IN BLEWETT FALLS LAKE (STATION BFB2) AND REACH 2 OF THE PEE DEE RIVER (STATIONS BFOB, BF1B, BF2B, BF3B, AND BF4B) DURING GENERATION FLOWS IN 2004 150 125 100 J m 75 E 50 25 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec M onth Figure F-1 150 125 100 J m 75 E 50 25 0 150 125 100 J m 75 E 50 25 0 150 125 100 J m 75 E 50 25 0 150 125 100 m 75 E 50 25 0 150 125 100 J m 75 £ 50 25 0 Blewett Falls Lake - Station BFB2 . Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec M onth Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec M onth Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec M onth Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec M onth Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec M onth +surface - i- -Bottom Monthly trends in total solids at Station BFB2 in Blewett Falls Lake, Stations BFOB, BF1B, BF2B, BF3B, and BF413 in Reach 2 below the Blewett Falls Hydroelectric Plant during generation flows in 2004. Appendix F - 1 Rlewett Falls Lake - Station RFR7 J E 125 100 75 50 - - 25 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 150 125 100 75 50 25 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 150 125 100 J c, 75 E 50 25 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 150 125 100 J 75 50 25 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 150 125 100 J 75 50 25 0 Pee Dee River - Station BFOB Pee Dee River -Station BFI B Pee Dee River - Station BF2B Jr Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Figure F-2 150 125 100 J a 75 E 50 25 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 1--+--Surface - ?- -Bottom Monthly trends in total dissolved solids at Station BFB2 in Blewett Falls Lake, Stations BFOB, BF1B, BF213, BF313, and BF4B in Reach 2 below the Blewett Falls Hydroelectric Plant during generation flows in 2004. Appendix F - 2 80 70 60 50 c 40 E 30 20 10 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Figure F-3 80 70 60 50 a? 40 E 30 20 10 80 70 60 50 rn 40 E 30 20 10 0 Blewett Falls Lake - Station BFB2 Pee Dee River - Station BFOB Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 80 70 60 50 ci 40 E 30 20 10 0 80 70 60 50 a? 40 E 30 20 10 80 70 60 50 rn 40 E 30 20 10 0 Pee Dee River - Station BF2B Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month --?-Surface - i- -Bottom Monthly trends In total suspended solids at Station BFB2 in Blewett Falls Lake, Stations BFOB, BF1B, BF213, BF313, and BF413 in Reach 2 below the Blewett Falls Hydroelectric Plant during generation flo" s in 2004. Appendix F - 3 100 75 50 25 0 100 75 50 25 0 100 75 Z 50 25 0 100 75 Z 50 25 0 100 75 Z 50 25 0 100 75 Z 50 25 0 6lewett Fallc Lake - Station SFB7 P. ? . Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month -?-Surface - i- -Bottom Figure F-4 Monthly trends in turbidity at Station BFB2 in Blewett Falls Lake, Stations BFOB, BF113, BF213, BF313, and BF413 in Reach 2 below the Blewett Falls Hydroelectric Plant during generation flows in 2004. Appendix F - 4 2.00 1.75 1.50 1.25 a 1.00 E 0.75 0.50 0.25 0.00 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Figure F-5 2.00 1.75 1.50 1.25 g 1.00 t 0.75 0.50 0.25 0.00 2.00 1.75 1.50 1.25 1.00 E 0.75 0.50 0.25 0.00 2.00 1.75 1.50 1.25 1.00 0.75 0.50 0.25 0.00 2.00 1.75 1.50 1.25 c 1.00 E 0.75 0.50 0.25 0.00 2.00 1.75 1.50 1.25 1.00 E 0.75 0.50 0.25 0.00 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Pee Dee River - Station BFI B Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Pee Dee River - Station BF4B 70, Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Surface - i- -Bottom Monthly trends in total nitrogen at Station BFB2 in Blevvett Falls Lake, Stations BFOB, BF113, BF213, BF313, and BF4B in Reach 2 below the Blewett Falls Hydroelectric Plant during generation flows in 2004. Appendix F - 5 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 1.75 1.50 1.25 1.00 E 0.75 0.50 0.25 0.00 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Figure F-6 1.75 1.50 1.25 ci 1.00 0.75 0.50 0.25 0.00 1.75 1.50 1.25 -4 1.00 E 0.75 0.50 0.25 0.00 1.75 1.50 1.25 1.00 0.75 0.50 0.25 0.00 1.75 1.50 1.25 1.00 0.75 0.50 0.25 0.00 1.75 1.50 1.25 -4 1.00 E 0.75 0.50 0.25 0.00 Blewett Falls Lake - Station BFB2 r Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Pee Dee River - Station BFI B Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month -0-Surface - i- - Bottom Monthly trends in nitrate + nitrite-nitrogen at Station BFB2 in Blewett Falls Lake, Stations BFOB, BF1B, BF213, BF313, and BF413 in Reach 2 below the Blewett Falls Hydroelectric Plant during generation flows in 2004. Appendix F - 6 0.25 0.20 0.15 E 0.10 0.05 0.00 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Figure F-7 0.25 0.20 0 15 of E 0.10 0.05 0.00 0.25 0.20 0 15 m E 0.10 0.05 0.00 0.25 0.20 0.15 m E 0 10 0.05 0.00 0.25 0.20 0.15 m E 0 10 0.05 0.00 0.25 0.20 0.15 rn E 0.10 0.05 0.00 Blewett Falls Lake - Station BFB2 s ¦ Pee Dee River - Station BFOB Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Pee Dee River -Station BFI B Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Pee Dee River - Station BF4B Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 1-0-Surface - -- -Bottom Monthly trends in ammonia-nitrogen at Station BFB2 in Blewett Falls Lake, Stations BFOB, BF1B, BF213, BF313, and BF413 in Reach 2 below the Blewett Falls Hydroelectric Plant during generation flows in 2004. Appendix F - 7 0.50 0.40 0.30 E 0.20 0.10 0.00 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Figure F-8 0.50 0.40 -? 0.30 0.20 0.10 0.00 0.50 0.40 0.30 a E 0.20 0.10 0.00 0.50 0.40 0.30 0.20 0.10 0.00 0.50 0.40 0.30 a? E 0.20 0.10 0.00 0.50 0.40 0.30 a E 0.20 0.10 0.00 Blewett Falls Lake - Station BFB2 4 4P Pee Dee River - Station BFOB Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Pee Dee River -Station BFI B Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Pee Dee River - Station BF2B Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 1--+--Surface - -- -Bottom Monthly trends in total phosphorus at Station BFB2 in Blewett Falls Lake, Stations BFOB, BF1B, BF213, BF313, and BF413 in Reach 2 below the Blewett Falls Hydroelectric Plant during generation flows in 2004. Appendix F - 8 12.0 10.0 8.0 J `af 6.0 E 4.0 Figure F-9 2.0 0.0 12.0 10.0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 8.0 J 6.0 4.0 2.0 0.0 12.0 10.0 J 8.0 '?m 6.0 E 4.0 2.0 0.0 12.0 10.0 8.0 J 6.0 4.0 2.0 0.0 12.0 10.0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Pee Dee River -Station BFI B Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Pee Dee River - Station BF2B Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month J 8.0 % 6.0 E 4.0 2.0 0.0 12.0 10.0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 8.0 J 6.0 4.0 2.0 0.0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month 1-0-Surface - ?- - Bottom Monthly trends in total organic carbon at Station BFB2 in Blelvett Falls Lake, Stations BFOB, BF1B, BF213, BF313, and BF413 in Reach 2 below the Ble-%vett Falls Hydroelectric Plant during generation flows in 2004. Appendix F - 9