WQ0040672_Monitoring - 07-2022_20220818 (2)

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DWR - NonDischarge Monitoring Report Submittal
'
•4 ..
NORTH CAROLINA
Enrlranmenlel QHaflly
Monitoring Report Submittal
..............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................
Permit Number#* WQ0040672
Name of Facility:* Stevens Towing-Riverbulk Terminal WWTF
Month:* July Year:* 2022
Report Information
..................................................................................................................................................................................................................................................................................................
Type* Upload Document*
NDMR, NDAR-1, NDAR-2, NDMLR NDAR2&NDMRsigned.pdf 3.56MB
PDF Only
GW-59 GW-59 July 2022 signed.pdf 6.25MB
PDF Only
Please upload one PDF containing all applicable monitoring reports
(i.e., NDMR, NDAR-1, NDAR-2,NDMLR,GW-59).
Confirmation Email Address:* [e-mail]
Name of Submitter:* Kevin Robert Gagnon
Signature: 1
Date of submittal: 8/18/2022
This will be filled in automatically
Initial Review
..............................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................................

Reviewer: Gerald,Wanda
Is the project number correct?* WQ0040672
Is the monitoring report accepted?* Yes No
Regional Office* Washington
Reviewer: _anonymous
Review Date: 8/30/2022

WQ0040672
E• nter date monitoring results were due. 8.3f22 Will this monitoring report and GlA59A) ! i AD
be submitted after the established due dale'?
, asiis requircit information missing on the I;VV-59 report forms? YES
til0 answer to gaesnah " or 2 is 'YES', liSt in the space pircvided below the c if too 'tiitt arta "
explain the problems encoi..intecet7 in obtaining the required r ntof mapOn,
3 Ar,;,,4o-ty au;monitor weik ii need of repair or maimenance tdamaged casing, Unl(wkud or missing.cap,missing YES 1131)
identification[laic-.3rea wiergywin,eto.)7;r; ‘so tOt 511, ke,gio 0,14CC r01, Thj0/%'c%
4 Are any monitored constituents equal to or above the established standards'? YES 11111"
.„, .
the answer to question 4 is "NO sxip :0 SOCD017
If the answer to question 4 is "YES"list tla affected wells tbdividaatly with txtastittentis)and cancentrationi:„st
o,xceeit.fing standards th the space provided below:
5 F• or the constituents identified in question 4 above, have standards been exceeded previously for the
same constituent(s) in the same well(s) in the last two years?
2 the,ti,-1,3,,rof to;.7z.iestrori 5 is „skp to section
If the answer to question 5 is ''YES", ;Jot o the space provided be/ow, each ote,';wIfh c:c.msretu0.0t1S)ex;:eed,ng
standards, concentrationtst rei.)Ori'6'd„9nd samp / fr.).r each occurrence(Jai the last rwo years
6 Are the monitoring wells listed in section 5 located at or beyond the review boundary? YES NO
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE.If the answer is "NO", monitoring wells may be improperly
located;contact the Regional Office.
7 is tic perrnittee lirnpierrienting previously approved actions required by the Division involving this , \L't.
groundwater quality problem?
• The answer to quesrt6P 7 is "?'ES„ i'tit,?scia be those actions iTt the space prov idea below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days;an evaluation may 12e
required to determine the impact the waste disposal system is having at the revie and corn!fiance
boundaries surrounding this facility. Failure to do so may subject the permittee to ii Notide of Violation,
fines,and/or penalties.
g T• he person completing this portion fGVw.59A)of the monitoring report should sign below and submit this
form with GiV-59 forms for required wells to the address provided at the top of the current GW-59 form.
I hereby agknowlieidge thrt e idove information wee evaluated and tlai information submitted in this
(Cornpli* eeRpottGW-59A)is 1 and compt4,ri,to the b zt Of my icrw
/1/3 744
Signature ot Permittee(or Authorized Agent) Date

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY-DIV.OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: = INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM - 1617 MAIL SERVICE CENTER,RALEIGH,NC 27699-1617 Phone:[phone]
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 12/31/2024
Facility Name: Stevens Towing-Riverbulk Terminal Non-Discharge WQ0040672 U I C
Permit Name(if different): NPDES Other
Facility Address: Edenton,NC 27932 TYPE OF PERMITTED OPERATION BEING MONITORED
Edenton NC 2/932 County Chowan ❑ Lagoon El Remediation: Infiltration Gallery
0 Spray Field ❑Remediation:
Contact Person: Simon Rich, III Telephone#: [phone] ❑ Rotary Distributor ❑Land Application of Sludge
Well Location/Site Name:MW-4 No.of wells to be sampled: 3 ❑ Water Source Heat Pump ❑Other:
from Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-4 Date sample collected: 7/19/2022 FIELD ANALYSES: WAS
Well Depth: 17 bps ft. Well Diameter: 2 in. pH 00400. 5.56 units Temp.00010: 27.1 °C DRY at
Depth to Water Level 82546: 16.76 ft. below measuring point Screened Interval: 11 ft. to 17 ft. Spec. Cond.00094 µMhos time of
sampling,
Measuring Point is 3.12 ft. above land surface Relative M.P. Elevation: 23.98 ft. Odor 00085 none check
Volume of water pumped/bailed before sampling: 2 gallons Appearance yellowish here:
Samples for metals were collected unfiltered: ill YES ❑ NO and field acidified: ®YES ❑NO
LABORATORY INFORMATION
Date sample analyzed:8/8/2022 Laboratory Name: Environmental Chemists,Inc. Certification No. 20-45107
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N 00615 0.02 mg/L Pb-Lead 01051 .047 ug/L
Coliform: MF Fecal 31616 <4 /100mL Nitrate(NO3)as N 00620 0.12 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P 00665 0.50 mg/L
(Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Dissolved Solids:Total 70300 285 mg/L Al-Aluminum 01105 mg/L
pH(Lab)00403 units Ba-Barium 01007 0.258 ug/L
TOC 00680 46.1 mg/L Ca-Calcium o0916 mg/L
Chloride 00940 33 mg/L Cd-Cadmium 01027 ug/L
Arsenic 01002 ug/L Chromium:Total 01034 0.086 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS:(by GC, GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron 01045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg-Mercury 71900 ug/L Lab Report Attached? 0 Yes(1) ❑ No(0)
Specific Conductance 00095 µMhos K- Potassium 00937 mg/L VOC 7873 method# SM 6200B
Total Ammonia 00610 0.2 mg/L Mg-Magnesium 00927 mg/L method#
(Ammonia Nitrogen,NH.,as N.Ammonia Nitrogen,Total) Mn-Man anese 01055 0.135
g ug/L method#
TKN as N 00625 0.14 mg/L Ni - Nickel 01067 0.020 ug/L method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
,a,
Ctf fha-�o=the:b s - -
t etaf o lee"
m kti w d a. belreft'e tnformaho >s bm tt d.. � . � �
( fY . f, and ti u a e in trlsYe ort,ts,:true:aocurate�and.com [to an that the al caG ta.w-,� Y 9 0 -report .�> P e 4t h an ytt da as;produced-� ustn approved methgdsnf analysis a a� ,.:.:;
-_ information,i ri:1, s.
QNitZ certified iaborato I am aware that there malt a ot`submtttm false clutl " - .
_._.�.� _._-...:,. ._,. ._ ?�` _.;._._. ..,.. . P t sf ,. ._ g... !pF._�.�ngthepossibil)tyofflnesancJimpnsonmentfarknov�tmgvfolaGons _�
8/12/2022
Permittee(or Authorized Agent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date)
GW-59 Rev.05-02-2017

SUBMIT FORM ON YELLOW PAPER ONLY
DEPARTMENT OF ENVIRONMENTAL QUALITY-DIV.OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER,RALEIGH,NC 27699-1617 Phone:[phone]
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 12/31/2024
Facility Name: Stevens Towing-Riverbulk Terminal Non-Discharge WQ0040672 UIC
Permit Name(if different): NPDES Other
Facility Address: Edenton,NC 27932 TYPE OF PERMITTED OPERATION BEING MONITORED
Edenton NC 20132 County Chowan ❑ Lagoon 0 Remediation: Infiltration Gallery
it Spray Field ❑Remediation:
Contact Person: Simon Rich,III Telephone#: [phone]o11 ❑ Rotary Distributor ❑Land Application of Sludge
Well Location/Site Name:MW-3 No.of wells to be sampled: 3 ❑ Water Source Heat Pump ❑Other:
t Fam Pet mill
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-3 Date sample collected: 7/19/2022 FIELD ANALYSES: WAS
Well Depth: 25bgs ft. Well Diameter: 2 in. pH 00400 6.06 units Temp.00010: 25.4 °C DRY at
Depth to Water Level 82546:20.88 ft. below measuring17 25 time of
p point Screened Interval: ft. to ft. Spec. Cond. 00094 [Mhos sampling:
Measuring Point is 3.23 ft.above land surface Relative M.P. Elevation: 42.94 ft. Odor 00085 slight sulfur check
Volume of water pumped/bailed before sampling: 4 gallons Appearance yellowish here:
Samples for metals were collected unfiltered: El YES ❑ NO and field acidified: 1*YES ❑NO
LABORATORY INFORMATION
Date sample analyzed:8/8/2022 Laboratory Name: Environmental Chemists,Inc. Certification No, 20-45107
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N 00615 <0.02 mg/L Pb-Lead 01051 <0.01 ug/L
Coliform: MF Fecal 31616 <1 /100mL Nitrate (NO3)as N 00620 4.67 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P 00665 .66 mg/L
(Note: Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
Jissolved Solids:Total 70300 194 mg/L Al-Aluminum 01105 mg/L
pH (Lab)00403 units Ba-Barium 01007 0.052 ug/L
TOC 0068o 11.4 mg/L Ca- Calcium 00916 mg/L
Chloride 00940 <5 mg/L Cd-Cadmium 01027 ug/L
Arsenic o1002 ug/L Chromium:Total 01034 0.013 ug/L
Grease and Oils 00552 mg/L Cu -Copper 01042 mg/L ORGANICS: (by GC,GC/MS, HPLC)
Phenol 32730 ug/L Fe-Iron 01045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg- Mercury 71900 ug/L Lab Report Attached? 0 Yes(1) ❑ No(0)
Specific Conductance 00095 [Mhos K- Potassium 00937 mg/L VOC 7873 , method# SM 6200B
Total Ammonia 00610 <0.2 mg/L Mg-Magnesium 00927 mg/L , method#
(Ammonia Nitrogen;NH?as N,Ammonia Nitrogen,Total) Mn- Manganese 01055 0.197 ug/L , method#
TKN as N 00625 4.67 mg/L Ni-Nickel 01067 <0.01 ug/L ,method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
lerti Y-tha that; the-to
best of ofimYkno edti e nd.beItEfi._.the�ormat tan submitted i.this report a c�uratoa ttic om tete=a d 2hatthe.,_.aba7 tory=a nd IY.tc.
at date precluded-using tn. ppr agedmethodsrof_aha.,;ly ais b��-
---.DWR ce7tifle: laborao .t am.;a. are;t att a e= r i ,. � .,..,_
S1 t yr (� , h 7 pre n�ca t �nalttes fors[ mltttn .fatse,t information, nclutli ahe possibility =fin `a tl. ns ,, ,�:,
rY 9 -�_ _.,J 4 �? tX of es and imi o�martt for knowingv�lation �
i — 8/12/2022
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i
7 ,t rt ti.,5.�., r cr C j l €.
Permittee(or Authorized Apeent)Name and Title-Please print or type Signature of Permittee(or Authorized Agent) (Date)
GW-59 Rev.05-02-2017

SUBMIT FORM ON YELLOW PAPER ONLY
,-,m7maiitztidginat DEPARTMENT OF ENVIRONMENTAL QUALITY-DIV.OF WATER RESOURCES
GROUNDWATER QUALITY MONITORING: INFORMATION PROCESSING UNIT
COMPLIANCE REPORT FORM 1617 MAIL SERVICE CENTER,RALEIGH,NC 27699-1617 Phone:[phone]
FACILITY INFORMATION Please Print Clearly or Type PERMIT Number: Expiration Date: 12/31/2024
Facility Name: Stevens Towing-Riverbulk Terminal Non-Discharge W00040672 UIC
Permit Name(if different): NPDES Other
Facility Address: Edenton,NC 27932 TYPE OF PERMITTED OPERATION BEING MONITORED
Edenton,NC 27932 County Chowan ❑ Lagoon ❑ Remediation: Infiltration Gallery
■❑ Spray Field ❑ Remediation:
Contact Person: Simon Rich.ill Telephone#: [phone] ❑ Rotary Distributor ❑Land Application of Sludge
Well Location/Site Name:Mw-1 No.of wells to be sampled: 3 ❑ Water Source Heat Pump ❑Other:
(torn Permit)
SAMPLING INFORMATION If WELL
WELL ID NUMBER(from Permit): MW-1 Date sample collected: 7/19/2022 FIELD ANALYSES: WAS
Well Depth: 15bgs ft. Well Diameter: 2 in. pH 00400 5.48 units Temp. 00010. 29.3 °C DRY at
Depth to Water Level 82546: 15.10 ft. below measuring point Screened Interval: 9 ft. to 15 ft. Spec.Cond.00094. µMhos time ofsampling,
Measuring Point is 2.95 ft.above land surface Relative M.P. Elevation: 23.92 ft. Odor 00085. none check
Volume of water pumped/bailed before sampling: 5 gallons Appearance clear/yellowish here:
Samples for metals were collected unfiltered: 0 YES ❑ NO and field acidified: [OYES ❑NO
LABORATORY INFORMATION
Date sample analyzed:8/8/2022 Laboratory Name: Environmental Chemists,Inc. Certification No. 20-45107
PARAMETERS NOTE: Values should reflect dissolved and colloidal concentrations.
COD 00335 mg/L Nitrite(NO2)as N 00615 <0.02 mg/L Pb-Lead 01051 0.011 ug/L
Coliform: MF Fecal 31616 a1 /100mL Nitrate (NO3)as N 00620 .39 mg/L Zn-Zinc 01092 mg/L
Coliform: MF Total 31504 /100mL Phosphorus:Total as P 00665 1.19 mg/L
(Note Use MPN method for highly turbid samples) Orthophosphate 70507 mg/L Other(Specify Compounds and Concentration Units):
3issolved Solids:Total 70300 146 mg/L Al-Aluminum 01105 mg/L
pH (Lab)00403 units Ba-Barium 01007 .140 ug/L
TOC 00680 26.8 mg/L Ca-Calcium 00916 mg/L
Chloride 0094o 18 mg/L Cd-Cadmium 01027 ug/L
Arsenic 01002 ug/L Chromium:Total 01034 .045 ug/L
Grease and Oils 00552 mg/L Cu-Copper 01042 mg/L ORGANICS:(by GC, GC/MS, H PLC)
Phenol 32730 ug/L Fe-Iron 01045 ug/L (Specify test and method#.ATTACH LAB REPORT.)
Sulfate 00945 mg/L Hg- Mercury 71900 ug/L Lab Report Attached? 0 Yes(1) ❑ No(0)
Specific Conductance 00095 µMhos K- Potassium 00937 mg/L VOC 7873 , method#
Total Ammonia 00610 .4 mg/L Mg- Magnesium 00927 mg/L , method#
(Ammonia Nitrogen:NH,as N Ammonia Nitrogen.Total) Mn- Manganese 01055 0.072 ug/L .method#
TKN as N 00625 .39 mg/L Ni-Nickel 01067 0.020 ug/L , method#
For Remediation Systems Only(Attach Lab Reports): Influent Total VOCs: mg/L Effluent Total VOCs: mg/L VOC Removal%
Ieertif yahat,to th .Pest ofmI;kno led e=a0tl behefi the inforrhatidn sUtr"fitted In this report is true,' ccuranand-andca;.mP e�e:.and=tha kthe':
1 borato}analyticaldata was produced using-approved n _a Proved methods ofa ai Yst s bY
a �
Q R-certified=laborato t:a. w re t.atthere.are significant=:penaltiesrfoC submt in false,nfo metton<tncludm the osstbtlt offCnes nd imprisonment for khawtn .vtolahorrs,
�� nl ?x!� � 1i .,_ � 9 t r._, 9_�.� tY � !?1p -b, .,-. �...� ,_. ..,_ ,., .�_
8/12/2022
Permittee(or Authorized Agent)Name and Title-Please print or type ' Signature of Permittee(or Authorized Agent) (Date)
GW-59 Rev.05-02-2017

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,NAl YincAL&coNso'PING CHEMISTS in for a cavil onarnen I a 161)(la l al a ram
Quible &Associates Date of Report: Aug 11, 2022
PO Box 870 Manteo Report#: 22M-1480
Kitty Hawk NC 27946 Report#: 2022-13664
Attention: Brian Rubino Customer ID: 08100100
Project ID: Stevens Towing
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-33199 Site: PPI -001 Effluent 7/19/2022 11:00 AM Water Client
Test Method Results Date Analyzed
Ammonia Nitrogen EPA 350.1,Rev.2.0,1993 1.6 mg/L 07/28/2022
Total Dissolved Solids (TDS) SM 2540 C-2015 138 mg/L 07/21/2022
Total Phosphorus SM 4500 P(F-H)-2011 0.20 mg/L 07/29/2022
Chloride SM4500 CI E-2011 < 5 mg/L 07/22/2022
Total Nitrogen (Calc)
Total Kjeldahl Nitrogen (TKN) EPA 351.2,Rev.2.0,1993 2.0 mg/L 07/29/2022
Nitrate+Nitrite-Nitrogen EPA 353.2,Rev,2.0,1993 0.11 mg/L 07/25/2022
Total Nitrogen Total Nitrogen 2.1 mg/L 08/08/2022
Lab ID Sample ID: M-2216 Collect Date/Time Matrix Sampled by
22-33200 Site: PPI -001 Effluent 7/19/2022 11:00 AM Water Client
Test Method Results Date Analyzed
Fecal Coliform ldexx Colilert-18 <1 MPN/100m1 07/19/2022
Residue Suspended (TSS) SM 2540 D-2015 5.2 mg/L 07/21/2022
pH SM 4500 H B-2011 7.3 units 07/19/2022
Result estimated Analyzed out of 15 minutes hold time.
Nitrite Nitrogen SM 4500 NO2 B-2011 0.05 mg/L 07/20/2022
BOD SM 5210 B-2016 8 mg/L 07/20/2022
Comment:
. ( ,
Reviewed by:
Report#::2022-13664 Page 1 of 1

Environmental Chemist, Inc., Wilmington, NC Lab#94
6602 Windilill Way
Wilmington, NC 28405
910,392,0223
Sarnplo Receily ct Chtcklist
r....Ar!, $,-,7%,,,,J,,l(i'i( , D ,t : -7 a c 22 Report Number:
_.........._
Receipt of sample: ECHEM Pickup 0 Client Delivery 0 UPS 1'7 FedEx 0 Other 1."„:1
0 YES 0 NO )111, NM 1. Were custody seals present on the cooler?
—
'D YES 0 NO ,N , N/A 2, If custody seals were present, were they intact/unbroken?
Original temperature upon receipt , °C Corrected temperatire upon receip , . °C'
How temperature taken: 0 Temperature Blank Agair—Y- ""----=---- =--- -
IR Gun ID:Thomas Traceable S/N 192511657 IR Gun Correction Factor°C: 0.0
. w YES 0 NO _ ___. _ _
3. If temperature of cooler exceeded 6 C, was Project Mgr./QA notified?
.
_ ,...._
ZIP YES 0 NO 4. 't, ere proper custody procedures (relinquished/received) followed?
___. _ __
YES 0 NO 5. Were sample ID's listed on the COC?
. . _
!IF YES 0 NO 6, Were samples ID's listed on sample containers? )
___ _..
te. YES 0 NO 7. Were collectioil date and time listed on the COC?
,15ri YES ND NO 8„ Were ti'pft, in ii- i)-''Fnrsrc? i _-,1-.0ti on the COC?
(
iN- YES jD NO I 10,„ Did saNulp„) di ..... . good i condition for each test?
.„,
YES
m . L ‘pp lirri. cilia! a, e i
YES 0 NO i 12, VVere s nple , received within proper holdinp time for requested tiPtiP)
„
_ I„1
IP YES 0 lN0 l.. Were a,„'iP rm o'l'i I' ',2( samples received at a pH pl <2? *_ _ _
YES 0 NO 114, Were cyanidp sa Moles rii.iceived at a pH >12?
0 YES 0 NO 15, Were siullide samples received at a pH>9?
YES ID NO 16. Were NH3/TRN/Phenol received at a chlorine residual of<0.5 m/L? '''"
(0 YES 0 NO I-17„ Were Sulfide/Cyarolde received at a chlorine residual of<0,5 re/L?
"0 YES 0 NO 118, Were orophosphate samples filtered in thie field within 15 minutes?
* TOC/V&atNes are pH checked at time cf analys's and recorded on the benchshee.t.
** Bacteria samples are checked for Chlorine at time of analysis and recorded on the bencrisheet„
,
,
'Sample Preservation: (Must be completed for any sample(s) incorrectly preserved or with headspace)
Sample(s) were received incorrectly preserved and were adjusted accordingly'by adding(circle one): H2S0,, FIN03 HD NaOH
Time of preservation: If more than one preservative is needed, notate in comments below
_________
ote:Notify custome-se,Vce vr—ed atey f2- -: re:';y p-eserved sampes Oa "7 a new siimpLe,G'-
'1or,fy tne. state lab I'd rected T::,a'-'a Red by me :.:sto-ne...Wo Yr23 rot,: :ed;date and t'rne:
Voatiles Sample(s)
were received with headspace
DOC QA;002 ;,:ei 1

6602 Windmill Way Wilmington,NC 213406
ENVIRONMENTAL CHEMISTS, INC OFFICE:910-392-0223 FAX [phone]
Analytical&Consulting Chemists NCDENR:DWQ CERTIFICATION#94 NCDHHS:DLS CERTIFICATION#37729 [e-mail]
COLLECTION AND CHAIN OF CUSTODY
Client: Quible and Associates PROJECT NAME:Steven's Towing/Edenton REPORT NO: 6-Zir) 1 qgo
ADDRESS:Post Office Drawer 870 CONTACT NAME: Brian Rubino,P.G. PO NO: D a--13u;..4
Kitty Hawk, NC 27966 REPORT TO: PHONE/FAX:
COPY TO: email:
Sampled By: SAMPLE TYPE:I=influent, E=Effluent,W=Well,ST=Stream,SO=Soil,SL=Sludge,Other:
Collection • .. PRESERVATION
cLa c, , ••
Sample Identification i P t° 8 g ° 5 ANALYSIS REQUESTED
Date Time Temp en 8 c.) z— I-) 2 mMEI g
liqpit w av,". #.7 4,-1a, I 4 w C ig .
PPI 00 - F Effluent 6) G rn1--20X BOD, TSS, NO2, pH
(Mae ept/Nov) C P :___--)r'Allr
G ---G -'f:-t:S -53k9 c)k X' ------4, NH3, Total N (calc),Total P
C P
pH (field): -7,5C, G G X Fecal Coliform
C P
G G
C P
PPI 07iVTF Effluent G G X TDS, Chloride
(Mar/ ul Nov) C P
G G
C P
G G
C P
G G
Transfer Relinquished By: Date/Time Received By: DateMme
?-71112.3 1-3°
Temperature when Received°C: I Accepted: ‘---- i 2ejt Resample Requested:
Delivered By: ( k)i(?() Received By:\--- ..:‹.ez-c rr .,,r :,17-- _. ---,------- Date: i 1,20A2-1------Time: i 7 r r„r_ri)
Comments: i TURNAROUND: t

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ANALYTICAL&CONSULTING CHEMISTS cnvisonmsn ilk. coin
Quible &Associates Date of Report: Aug 08, 2022
PO Box 870 Manteo Report#: 22M-1480
Kitty Hawk NC 27946 Report#: 2022-13657
Attention: Brian Rubino Customer ID: 08100100
Project ID: Stevens Towing MW
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-33179 Site: MW-1 7/19/2022 10:50 AM Water Troy Murphy
Test Method Results Date Analyzed
Lead EPA 200.7,Rev 4.4,1994 0.011 mglL 07/22/2022
Manganese EPA 200.7,Rev 4.4,1994 0.072 mglL 07/22/2022
Nickel EPA 200.7,Rev 4.4,1994 0.020 mg/L 07/22/2022
Barium EPA 200.7,Rev.4.4,1994 0.140 mg/L 07/22/2022
Chromium EPA 200.7,Rev.4.4,1994 0.045 mglL 07/22/2022
Ammonia Nitrogen EPA 350.1,Rev.2.0,1993 0.4 mglL 07/28/2022
Total Dissolved Solids (TDS) SM 2540 C-2015 147 mg/L 07/21/2022
Total Phosphorus SM 4500 P(F-H)-2011 1.19 mg/L 07/29/2022
Total Organic Carbon (TOC) SM 5310 B-2014 26.8 mg/L 07/21/2022
Chloride SM4500 CI E-2011 18 mg/L 07/21/2022
Nitrate Nitrogen (Cale)
Nitrate+Nitrite-Nitrogen EPA 353.2,Rev.2.0,1993 0.39 mg/L 07/25/2022
Nitrate Nitrogen Subtraction Method 0.39 mg/L 08/08/2022
Lab ID Sample ID: M-2217 Collect Date/Time Matrix Sampled by
22-33180 Site: IVIW-1 7/19/2022 10:50 AM Water Troy Murphy
Test Method Results Date Analyzed
Nitrite Nitrogen SM 4500 NO2 B-2011 <0.02 mg/L 07/20/2022
Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100m L 07/19/2022
Report#::2022-13657 Page 1 of 3

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Quible &Associates Date of Report: Aug 08, 2022
PO Box 870 Manteo Report#: 22M-1480
Kitty Hawk NC 27946 Report#: 2022-13657
Attention: Brian Rubino Customer ID: 08100100
Project ID: Stevens Towing MW
Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-33181 Site: MW-3 7/19/2022 10:30 AM Water Troy Murphy
Test Method Results Date Analyzed.
Lead EPA 200.7,Rev 4.4,1994 <0.01 mg/L 07/22/2022
Manganese EPA 200.7,Rev 4.4,1994 0.197 mg/L 07/22/2022
Nickel EPA 200.7,Rev 4.4,1994 <0.01 mg/L 07/22/2022
Barium EPA 200.7,Rev.4.4,1994 0.052 mg/L 07/22/2022
Chromium EPA 200.7,Rev.4.4,1994 0.013 mg/L 07/22/2022
Ammonia Nitrogen EPA 350.1,Rev.2.0,1993 < 0.2 mg/L 07/28/2022
Total Dissolved Solids (TDS) SM 2540 C-2015 194 mg/L 07/21/2022
Total Phosphorus SM 4500 P(F-H)-2011 0.66 mg/L 07/29/2022
Total Organic Carbon (TOC) SM 5310 B-2014 11.4 mg/L 07/21/2022
Chloride SM4500 CI E-2011 < 5 mg/L 07/21/2022
Nitrate Nitrogen (Calc)
Nitrate+Nitrite-Nitrogen EPA 353.2,Rev.2.0,1993 4.67 mg/L 07/26/2022
Nitrate Nitrogen Subtraction Method 4.67 mg/L 08/08/2022
Lab ID Sample ID: M-2218 Collect Date/Time Matrix Sampled by
22-33182 Site: MW-3 7/19/2022 10:30 AM Water Troy Murphy
Test Method Results Date Analyzed
Nitrite Nitrogen SM 4500 NO2 B-2011 <0,02 mg/L 07/20/2022
Fecal Coliform SM 9222 D-2015 MF <1 Colonies/100mL 07/19/2022
Report#::2022-13657 Page 2 of 3

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ANALYTICAL. x• 0 'NSULTING CHEMmrs a nfa Clt en CCen vi non n uent allarh ern is U .awa:au>C"a.
Quible &Associates Date of Report: Aug 08, 2022
PO Box 870 Manteo Report#: 22M-1480
Kitty Hawk NC 27946 Report#: 2022-13657
Attention: Brian Rubino Customer ID: 08100100
Project ID: Stevens Towing MW
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Lab ID Sample ID: Collect Date/Time Matrix Sampled by
22-33184 Site: MW-4 7/19/2022 11:30 AM Water Troy Murphy
Test Method Results Date Analyzed
Lead EPA 200.7,Rev 4.4,1994 0.047 mg/L 07/22/2022
Manganese EPA 200.7,Rev 4.4,1994 0.135 mg/L 07/22/2022
Nickel EPA 200.7,Rev 4.4,1994 0.020 mg/L 07/22/2022
Barium EPA 200.7,Rev.4.4,1994 0.258 mg/L 07/22/2022
Chromium EPA 200.7,Rev.4 4,1994 0.086 mg/L 07/22/2022
Ammonia Nitrogen EPA 350.1,Rev.2.0,1993 0.2 mg/L 07/28/2022
Total Dissolved Solids (IDS) SM 2540 C-2015 285 mg/L 07/21/2022
Total Phosphorus SM 4500 P(F-H)-2011 0.50 mg/L 07/29/2022
Total Organic Carbon (TOC) SM 5310 B-2014 46.1 mg/L 07/21/2022
Chloride SM4500 CI E-2011 33 mg/L 07/21/2022
Nitrate Nitrogen (Cale)
Nitrate+Nitrite-Nitrogen EPA 353.2,Rev.2.0,1993 0.14 mg/L 07/25/2022
Nitrate Nitrogen Subtraction Method 0.12 mg/L 08/08/2022
Lab ID Sample ID: M-2219 Collect Date/Time Matrix Sampled by
22-33185 Site: MW-4 7/19/2022 11:30 AM Water Troy Murphy
Test Method Results Date Analyzed
Nitrite Nitrogen SM 4500 NO2 B-2011 0.02 mg/L 07/20/2022
Fecal Coliform SM 9222 D-2015 MF <4 Colonies/100mL 07/19/2022
Comment:
Reviewed by:
Report#::2022-13657 Page 3 of 3

Envirenmental Chemist, Inc., „,-ilmington, LiC, Lab#94
6602 Windmill Way
Wilmington, NC 28405
910.392,0223
SaAir3le keceipt Checklist
1 2 0 '22
c c. ' ) ( v i i) 0 i ")
cIL,H t !b ;\kA e„) ..,, ' ' '.,, ' -(„ et....1 Dd.tel - " _ _ „ Report Number; 2022-
___
„Receipt of sample: ECHEM Pickup 0 Client Delivery 0 UPS FedEx 0 Other 0
0 YES 0 NO ri N/A 1. Were custody seals present on the cooler?
,,Ilk
D YES D NO al N/A
ii. 2. If custody seals were present, were they intact/unbroken?
Original temperature upon receiptt °C Corrected temperature upon receipt °C
__
How temperature taken: 0 Temperature Blank r)( Against Bottles
IR Gun ID:Thomas Traceable S/N 192511657 IR Gun I, Correctior -- ------
Factor . 0,0
___. ..._.
r YES 0 NO 3. If temperature of cooler exceeded 6°C, was Project Mgr./QA notified? ..._. ..
31 YES 0 NO 4. Were proper custody procedures (relinquished/received)foliowed? ----'
: YES 0 NO 5, Were sample ID's listed on the COC?
'AP YES 0 NO 6, Were samples ID's listed on sample containers?
te. YES 0 NO 7 V i e L.e CuHH:t.k..m date and time listed on the COC?
YES ED NO '"I Were te513 tO b2' porformed listed on the COC?
I
;.:, --;:blitaineo-s fur eaol, tea,:
,>itIt' YES ED NO _10. Did samples arrive in good condition for each test?
__,_. ..._
_ _I!
IX' YES 0 NO ) 11 liV1.5 P`t?T..,':' ,? s?rt7onNr vohime available?'
1_ „ „
YES 0 NO 172. \A/elm i,a1 J g d k'S received within proper holding time for mgt./0 eh
4 YES 0 NO li 13„ We c :, *'1 i'I'ez,erved samples received at a pH of<2? *
0 YES 0 NO 14, Were (yanido samples received at a pH >12?
0 YES JUNO 15, Were sillfide samples received at a pld>9?
_YES E::: NO .
16. Were NI IiVIKN/Phenol received at a chlorine residual of<0.5 m/L? —
0 YES 0 NO IN. Were. SUU'kie/Cyanicie received at a chlorine residual of<0,5 rri/L?0 YES jNO 118. Were orthophosphate samples filtered in the field within 15 minutes?
* TOC/Voiati'ies are pH checked a:trne Cr 2171v3Is and recorded on the benchsheet„
j
** Bacteria samples are checked for Chiorine at time of analysis and recorded on the benchsheat
Sample Preservation: (Must be completed for any sample(s) incorrectly preserved or with headspace)
Sample(s) were received incorrectly preserved and were adjusted accordingly
by adding (circle one): H2504 HNO3 H'CI NaOH
Time of preservation: If more than one preservative is needed, notate in comments below
-------
:,,te:Notify cui`xener se. /ce [----'—e-i-v:E!,!y fp'°-:o-rect'y pree-ved sip'es Ob::an a new sampe o-
lo:A'y ne state ,,IL Ili.d re'rej.t.-: a-a yzej by the fh.,50"72- Who vies noff ed da!:e and tThe:
Volatiles Sample(s)
were received with headspace
COMr,I El „ITS:
DOC CIA CO2 'e i 1

-i.7..,_.-_. . ...„.___ ENVIRONMENTAI_ CHEMISTS, INC 6602 Windmill Way Wilmington,NC 28405
- OFFICE:910-392-0223 FAX [phone]
- --. `
Analytical Consulting Chemists
NCDENR:DWQ CERTIFICATION#94 NCDHHS:DLS CERTIFICATION#37729 [e-mail]
&
COLLECTION AND CHAIN OF CUSTODY
Client: Quible and Associates PROJECT NAME:Stevens Towing-Edenton,NC REPORT NO: 2:2-rn 142C)
ADDRESS:Post Office Drawer 870 Permit:WQ0040672 PO NO: \67,FiRr-
,,
Kitty Hawk, NC 27966 REPORT TO: Brian Rubino, P.G. PHONE/FAX:
COPY TO: Simon Rich/Stevens Towing email: [e-mail]
Sampled By: 'rill IkAvrtn , SAMPLE TYPE:I=influent,E=Effluent,W=Well,ST=Stream,SO=Soil,SL=Sludge,Other:
ollection re
1 • i . 1 E. E.., (a 81 PRESERVATION
Sample Identification Eg: .atimE 1 '6 It DI 11 , 38g2 g ANALYSIS REQUESTED
4 a - ' 6 Jg 1 g
Date Time Temp 0 8 Z 2
— ,
C lel frit, 10:S)^40-mw: 1 li V.3 0 S ii„iily
, .,- x Chloride,NO2, TDS
z_ ,„),2
Depth to water: IS,IV G G LI 0<;27\ _ X ‘c' , NH3, NO3, TP
C P L—, -,;--\
Gallons Bailed: .5" G , G X Ba, Cr, Pb, Mn, Ni
C P
.
pH(field): 5.t.,1? G G 1W1-1 X Fecal Coliform
C P
Color deAir/4"‘ G G X TOG
_
C P
Odor Nett/ G G X VOC's(November)
_
C P
G G
C P
G G
Total of 3 wells(1,3,4)due in March,July and November.
Transfer Relinquished By: pate/Time Received By: Date/Time
it/fa- kuptvvk . 11:--Ic --1-ticiladi
2.
Temperature when Received° : , I Accepted: a 7-691;#1: Resampie equested:
Delivered By: i ',,'(----1 Received By: '--„, ---_, -r3'nA - Date: -7 2 L7-1--Time: : 21C DIO
Comments: i TURNAROUND:

ENVIRONMENTAL CHEMISTS INC 6602 Windmill Way Wilmington,NC 28405
9 OFFICE:910-392-0223 FAX [phone]
NCDENR:DWQ CERTIFICATION 9 94 NCDHHS:DLS CERTIFICATION II 37729 Infoglenvironmentalchemists.com
Analytical&Consulting Chemists
COLLECTION AND CHAIN OF CUSTODY
Client: Quible and Associates PROJECT NAME: Stevens Towing-Edenton, NC REPORT NO:Et,tY1140
ADDRESS: Post Office Drawer 870 Permit:WQ0040672 PO NO: ;'''-.2 - 1
Kitty Hawk, NC 27966 REPORT TO: Brian Rubino,P.G. PHONE/FAX:
____ _ .... ... ....______COPY TO: Simon Rich/Stevens Towing email: [e-mail]
Sampled By*. cett Lt .)2 SAMPLE TYPE:I=Influent,E=Effluent,W=Well,ST=Stream,SO=Soil,SL=Sludge,Other:
oil ction a PRESERVATION
0
-r, __
a
Sample Identification E ›., a a m m 2 gu , 3 8 g 0 iiii ANALYSIS REQUESTED i- § 0 c a. ze (inF- u
Date Time Temp 0 gR i m1 g
8
Intrt.- 10:3Qu.k z. d 0 c
mw:-3 0 n't.21$x Chloride, NO2, TDS
C P ,
Depth to water: 1.6.(SZ G G ,-v.___, 4---Aq \ /- -X ii-i-
--"-"---5 NH3, NO3, TP
C P
,
Gallons Bailed: G G X 4--fil' Ba,Cr, Pb, Mn, Ni
C P
pH(field): (0.6(45 G G X Fecal Coliform
C P
Color: 1-4.1\ G G X TOC
-
C P
Odor: 51; 1 cAl ,ei'f' G G X VOC's (November)
- _
C P
G G _C P
G G
Total of 3 wells(1,3,4)due in March,July and November.
Transfer Relinquished By: Date/Time Received By: Date!Time
11 I'1,2- 130
2.
„..--1-, .Lt3e f
Temperature when Received °I: 6.-.4. i Accepted: ; 1 ejected: Resample Requested:
Delivered By: Received By -J) - ' .-c,_ __---- Date:________Time: 17C
Comments: TURNAROUND:

(4,3-Ns,„: ENVIRONMENTAL CHEMISTS, INC 6602 Wndmill Way Wilmington,NC 28405
' - ' OFFICE:910-392-0223 FAX [phone]
Analytical&Consulting Chemists NCDENR:DWQ CERTIFICATION#94 PiCDHFIS:DLS CERTIFICATION#37729 [e-mail]
COLLECTION AND CHAIN OF CUSTODY
Client:Quible and Associates PROJECT NAME:Stevens Towing-Edenton,NC REPORT NO: ,P, 11-1 I L413
ADDRESS: Post Office Drawer 870 Permit:WQ0040672 PO NO: ffD,-- 1-731,t4S-
Kitty Hawk, NC 27966 REPORT TO: Brian Rubino,P.G. PHONE/FAX:
COPY TO:Simon Rich/Stevens Towing email:[e-mail]
Sampled By: ----Ec_ litber_ SAMPLE TYPE:I=Influent, E=Effluent W=Well,ST=Stream,SO=Soil,SL=Sludge,Other:
ollection e a ._
.- a x PRESERVATION . I
— 1A5-Sample Identification
o
P
ANALYSIS REQUESTED
of l i
Date Time Temp SI
7Actrz. Moo- c
mvv: Li' SI 1 A 6 t in.2.-Lq X . Chloride, NO2,TDS
-1 C P
I,
Depth to water. 11.914' G G .---. X -- ir'1 NH3, NO3,TP
axteutJ ol'vett Air C P
Gallons Bailed: IF G G X ---/-- Be,Cr, Pb,Mn,Ni
C P
,pH(field): S-1S(c, G G X Fecal Coliform
C P
Color: labsiefoviv" G G X TOC
C P
Odor _
MAL, G G X ,,. VOC's1November)
C P
G G
. ,
C P
G G
Total of 3 wells(1,3,4)due in March,July and November.
Transfer Relinquished By: DatefTime _,..gived By: Date/Time
1.
fr_----T- 471341 1/I 1St I:3 e /1 ler", 4----
12.
Temperature when Received °t: ( ) LAI Accepted: \---/V17-42-4Wejecti(d: Resample Requested:
Delivered By: Received 19: - ' L----K— —Date: I 17)---D1-22-Time:
Comments: I TURNAROUND: -I