WQ0004268_Groundwater Monitoring_20090423

PVC 'DWQ Laboratory Section Results
County:
River Basin
Report To
SAMPSON
FROAP
Collector: B TODD
Region: FRO
RECEIVED
APR22009
Sample Matrix: GROUNDWATER
Loc. Type:, MONITORING WELL p—FAYETIEl4lLEHEGIONAIOfFICE
Emergency Yes/No
COC Yes/No
Location ID:
. YES
6P082W00004268
VisitlD
Loc. Descr • ALLEN CANNING FACILITY INC
Collect Date:
03/16/2009
Collect Time:: 10:50
Sample ID:
PO Number#
Date Received:
Time Received:
Labworks LoginlD
Date Reported:
Report Generated:
Sample Depth
AB41905
9G0370
03/17/2009
08:15
SMATHIS
4/23/09
04/23/2009.
Sample Qualifiers and Comments
Routine Qualifiers
For a more detailed description of these qualifier codes
A -Value reported is the average of two or more determinations
B1-Countable membranes with <20 colonies; Estimated
B2- Counts from all filters were zero.
B3- Countable membranes with more than 60 or 80 colonies; Estimated
64-Filters, have counts of both >60 or 80 and < 20; Estimated
B5-Too many colonies were present; too numerous to count (TNTC)
J2- Reported value failed to meet QC criteria for either precision, or accuracy; Estimated
J3-The sample matrix interfered with the ability to make any accurate determination; .Estimated
J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated
N1-The component has been tentatively identified based on mass spectral library search and has an estimated value
refer to www.dwglab.org under Staff Access
N3-Estimated concentration is < PQL and >MDL
NE -No established POL•
P-Elevated PQL due to matrix interference and/or sample dilution
Q1-Holding time exceeded prior to receipt at lab.
Q2- Holding time exceeded following receipt by lab
PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity
U- Samples analyzed for this compound but not detected
X1- Sample not analyzed for this compound
LAB
Laboratory Section» 1623 Mall Service Center, Raleigh, NC 27699.1623 [phone]-
Page 1 of 2

Location ID: 6P082W00004268
Loc. Descr.: ALLEN CANNING FACILITY INC
Visit ID
9VC DWQ La6oratoiy Section Results
Sample ID. AB41905
, Collect Date: . 03/16/2009
Collect Time:: 10:50
CAS #
Analyte Name
PQL
Result Qualifier Units
Analyst/Date
Approved By /Date
Sample temperature at receipt by lab
Method Reference
1.6
°C
DSAUNDERS SMATHIS
3/17109 3/17/09
"MIC
TOC In liquid
Method Reference
• APHA5310B-20th
2.0 3.5
NDEO
4/3/09
CGREEN,.
4/20/09
WET
Chemical Oxygen Demand In liquid
Method Reference Hach 8000
20 20 U
mg/L
JSTALEY
3/18/09
CGREEN
3/19/09
Ion Chromatography
Method Reference EPA 300.0
TITLE_
mL
AWILLIAMS .CGREEN
-
3/25/09 4/1/09
Total Dissolved Solids In liquid 12 270 . mg/L AWILLIAMS . CGREEN
• Method Reference APHA2540C-18TH
3/17/09 3/19109
Chloride
Method Reference EPA 3000
1.0
61 mg/L
AWILLIAMS
3/25/09
CGREEN
4/1/09
Fluoride
Method Reference
EPA 300.0
0.4 2.0 U,P mg/L AWILLIAMS
3/25/09
CGREEN.
4/1/09
Sulfate
Method Reference EPA 300.0
2.0 10 U,P . mgll. AWILLIAMS CGREEN
3/25/09 4/1/09
NUT
NH3 as N In liquid
Method Reference
Lac10-107 06-1-J
0.02 0.02 mg/L as N
MAJAYI CGREEN
3/18/09 4/1/09
Total Kjeldahl N as N In liquid 0.2 0.23 mg/L as N MOVERMAN . ' CGREEN
Method Reference Lachat107-06-2-H 3/20/09 3/24/09
NO2+NO3 asN In liquid 0.02 0.02 U mg/L as N MAJAYI CGREEN
Method Reference Lac10-107-04-1-c 3/18/09 4/1/09
Phosphorus_ total as P In liquid 0.02 4.5 mg/L as P GBELK
Method Reference Lac10-115-01-1EF 3/20/09
CGREEN
4/1/09
Nitrate as N In liquid
Method Reference Lachat107-04-1-c
0.02 0.02 U mg/L as N MOVERMAN CGREEN
3/25/09 4/1/09
Nitrite as N In liquid
Method Reference
Lachat107-04-1-c
0.01 '0.01 J2 mg/L as N GBELK . CGREEN
3/18/09 4/1/09
Laboratory Section» 1623 Mall Service Center, Raleigh, NC 27699-1623 [phone]
Page 2 of 2

GROUNDWATER FIELD/LAB FORM
Location code_6P082WQ0004268
County_Sampson
Quad No Serial No.
Lat. Long.
Report To: ARO FRO )MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO Fed. Trust, Central Off., Other:
Shipped by: Bus, t ourie Hand Del., Other:
Collector(s):_BiIITo.
SAMPLE TYPE
® Water
El Soil
❑ 'Other
El Chain of Custody
Date 3/,
SAMPLE PRIORITY
Routine
El Emergency
North Carolina
Department of Environment and Natural Resources
DIVISION OF WATER QUALITY -GROUNDWATER SECTION
Lab Number G O33-O
Date Received c.3'I! -0'3 Time. dS-
Rec'd By: � From :Bu Courier, Hand Del.,
Other:
Data Entry By:
Date Reported:
Ck:'
LUST, Pesticide Study, Federal Trust, Other:'
(circle one)
FIELD ANALYSES Owner % f/eiit' C41i1'4- 4/ /4cZ /, ' - 1 .�i�f e.
pH 400 /7, Dip Spec. Cond.94 at 25°C Location or Site �'+`�o e t'�R�"c i �% uR / f _de. ad', �13
Temp.io /t. 1 ' °C Odor Description of sampling,Doint L,Jz-1( ( coo-
Appearance 442 d . Sampling Method si 1 /e.e..
tmo. bailer. etc.)
'
Remarks 7..1, .✓Im [-.,o.� y.sttnt.�
(Pumping time; air temp., etc.)
Field Analysis
By:_BillTodd
LABORATORY ANALYSES
BOD 310
mg/L
COD High 340
mg/L
X
COD Low 335
mg/L
Coliform: MF Fecal 31616
/100m1
Coliform: MF Total 31504
/10om1
X
TOC 680
mg/L
Turbidity 76
NTU .
Residue, Suspended 530
mg/L
pH 403
units
Alkalinity to pH 4.5 410
mglL
Alkalinity to pH 8.3 415
mg/L
Carbonate 445
mg/L
Bicarbonate 440
mg/L
Carbon dioxide 405
mg/L
X
Chloride 940
mg/L
Chromium: Hex 1032
ug/L
Color: True 80
CU
Cyanide 720
mg/L
PurposeA n
Time / '. �D Baseline, Complaint,
X
•Diss. Solids 70300
mg/L
Fluoride 951
mg/L
.Hardness: Total 900
mg/L
Hardness (non-carb) 902
mglL
Phenols 32730
ug/1
Specific Cond. 95
- uMhos/cm
X
Sulfate 945
mg/L
Sulfide 745
mg/L
1
Oil and Grease
. mg/L
X
NH3 as N 610
mg/L
X
TKN as N 625,
mglL
X
NO2 + NO3 as N 630
mg/L
X
P: Total as P 665
mg/L
X
Nitrate (NO3 as N) 620
mg/L
X
Nitrite (NO2 as N) 615
mg/L
(P c.) AG, -- ` 4 e
K cD
Ag-Silver 46566
ug/L
Al -Aluminum 46557
ug/L
As -Arsenic 46551
ug/L
Ba-Barium 46558
ug/L
Ca -Calcium 46552
mg/L
Cd-Cadmium 46559
ug/L
Cr-Chromium 46559
uglL
Cu-Copper 46562
.
'
ug/L
Fe -Iron 46563
ug/L
Hg-Mercury 71900
ug/L
K-Potassium 46555
mg/L
Mg -Magnesium 46554
•
mglL
Mn-Manganese 46565
ug/L
Na-Sodium 46556
mg/L
Ni-Nickel
ug/L
Pb-Lead 46564
ug/L
Se -Selenium ,
. ug/L
Zn-Zinc•46567
ug/L
Sample Interval
Organochlorine Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
PCBs
Semivolatile Organics
TPH-Diesel Range
Volatile Organics (VOA bottle)
TPH-Gasoline Range
TPH-BTEX Gasoline Range
LAB USE ONLY
Temperature on,arrival (°C):
Lab Comments
GW-54 REV. 7/03 For Dissolved Analysis -submit filtered sample and write "DIS" in block.

Report to: _FROAP
NC DENR/DWQ Laboratory
Sample Anomaly Report (SAR)
Lab Number:
Station Location: ALLEN
CANNING FAC.
oample Type: GROUND H2O
Date collected: 3/16/09
Affected Parameter(s): NO2
Analytical Area (check one):
❑WCH
®NUT
jqa�
County: SAMPSON
Sample ID:
Po221,0 pogo y21 8
Region: FRO
Priority: coo.
Date received: 3/17/09
DMETALS
❑MICRO
The following anomalies occurred (check all that apply):
['Samples
❑Improper container used
['VOA vials with headspace
['Sulfide samples with headspace
['Samples not received, but listed on fieldsheet
['Samples received, but not listed on fieldsheet
DMislabeled as to tests, preservatives, etc.
['Holding time expired
['Prior to receipt in lab
['After receipt in lab
❑Insufficientquantity for analysis
❑Sample exhibits gross non -homogeneity
['Sample not chemically preserved properly
❑pH out of range (record pH):7.0
['Improper chemical
❑Residual chlorine present in sample
['Color interference
❑Heavy emulsion formed during extraction -
❑Sample bottle broken in lab - no reportable results
['Other (specify):
Comments: LLS RECOVERY LESS THAN 75% .
Corrective Action:
Collector:
Date analyzed:
['VOA
❑PEST
BTODD.,
❑ WARO
❑SVGA
®Quality Control
❑Instrument failure — no reportable results
['Analyst error — no reportable results
['Surrogates
[None added
['Recovery outside acceptance limits
❑ Spike recovery
[None added
❑Recovery outside acceptance limits
❑Failed to meet criteria for precision •
❑Internal standards
❑Blank contamination
®QC data reported outside of controls (e.g., QCS, LCS)
❑ Incorrect procedure used
['SOP intentionally modified with QA and Branch Head
approval
❑ Invalid instrument calibration
DElevated detection limits due to:
❑Insufficient sample volume
(12,c „)t-r -n ., )
Al- D, c, l 4 t /L-
t,�S = I c u `€, 1•42-` s
Q-CP\ -tzk P
❑Samples were rejected by DWQ Lab. Authorized by: Date:
['Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured.
❑Sample(s) on hold until:
®Sample reported with qualification. Data qualification code used:J2
['Other (explain):
Notification Required? ❑ Yes ❑ No
Person Contacted: Date:
Form completed by:
Lead Chemist Review (initial):
I .BIOCHEM M°
DMETALS
Branch Head Review (initial):
•QA/QC Review (initial):
A\Forms\Laboratory\SAR
❑PEST
❑VOA
3, 2:71vf
3 LOA/
Date: 3/18/2009
❑SVOA
Logged into database by (initial): RV O .3/2i/01
10/23/Oldbs

NC DWQ Laboratory Section Results
County:
River Basin
Report To FROAP
SAMPSON
Collector: -B TODD
Region: FRO
Sample Matrix: GROUNDWATER
Loc. Type: MONITORING WELL
Emergency Yes/No
COC Yes/No
YES
RECEIVED
!PRO 9 ; 1.
DENR—FAYEEtEVILLE REGIONALORaCE
VisitID
Loc. Descr.: ALLEN CANNING FACILITY INC
Sample ID:
PO Number #
Date Received:
Time Received:
Labworks LoginlD
Date Reported:
Report Generated:
Location ID: 6P082WQ0004268
Collect Date: 03/16/2009
Collect Time:: 10:13
Sample Depth
AB41904
9G0369
03/17/2009
08:15
SMATHIS
4/1 /09
04/01/2009
Sample Qualifiers and Comments
Routine Qualifiers
For a more detailed description of these qualifier codes refer to www.dwglab.org under Staff Access
A -Value reported is the average of two or more determinations
B1-Countable membranes with <20 colonies; Estimated
B2- Counts from all filters were zero. .
B3- Countable membranes with more than 60 or 80 colonies; Estimated
B4-Filters have counts of both >60 or 80 and < 20; Estimated
B5-Too many colonies were present; too numerous to count (TNTC) -
J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated
J3-The sample matrix interfered with the ability to make any accurate determination; Estimated
J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated
N3-Estimated concentration is < PQL and >MDL
NE -No established PQL
P-Elevated PQL due to matrix interference and/or sample dilution.
Q1-Holding time exceeded prior to receipt at lab.
Q2- Holding time exceeded following receipt by lab
PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity
U- Samples analyzed for this compound but not detected
X1- Sample not analyzed for this compound
N1 The component has been tentatively identified based on mass spectral library searchand has an estimated value
I AR
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
Page 1 of 2

Location ID:-
Loc. Descr,:
Visit ID
6P082WQ0004268 '
ALLEN CANNING FACILITY INC
NG DWQ Laboratory Section results
Sample ID
Collect Date:
Collect Time::
AB41904
03/16/2009
10:13
CAS #
Analyte Name
PQL
Result Qualifier Units Analyst/Date
Approved By /Date
LAB
Sample temperature at receipt by lab
Method Reference
1.6
`C
DSAUNDERS SMATHIS
3/17/09 3/17/09
_MIC
TOC in liquid
Method Reference APHA5310B-20th
2.0 - 2.9
mg/L
ADEXTER CGREEN
3/19/09 3/3.1/09
- WET
Chemical Oxygen Demand In. liquid - 20 20 U mg/L JSTALEY CGREEN
Method Reference Hach 8000 -
3/18/09 , 3/19/09
Ion Chromatography
Method Reference EPA 300.0
_TITLE_ mg/L AWILLIAMS CGREEN
3/25/09 4/1/09
Total Dissolved Solids In liquid 12 214 mg/L AWILLIAMS CGREEN
3/17/09 3/19/09
Method Reference APHA2540C-18TH
Chloride 1.0 120 • mg/L AWILLIAMS CGREEN
Method Reference EPA 300.0
3/25/09 4/1/09
Fluoride 0.4 2.0 U,P mg/L AWILLIAMS CGREEN
Method Reference EPA 300.0
3/25/09 4/1/09
Sulfate 2.0 10•. U,P mg/L AWILLIAMS CGREEN
3/25/09 4/1/09
Method Reference EPA 300.0
NUT
NH3 as N in liquid 0.02 0.12 mg/L as N MAJAYI CGREEN
Method Reference Lac10-107-06-1-J 3/18/09 4/1/09
Total Kjeldahl N as N in liquid 0.2 0.36 mg/L as N MOVERMAN CGREEN
Method Reference Lachat107-06-2-H ' . 3/20/09 3/24/09
NO2+NO3 as N in liquid
Method Reference Lac10-107-04-1-c
0.02 0.05 mg/L as N MAJAYI CGREEN
3/18/09 4/1/09
Phosphorus_ total as Pin liquid -, 0.02 0.03 . mg/L as GBELK CGREEN
Method Reference Lac10-115-01-1EF _ 3/20/09 4/1/09
Nitrate as N in liquid . 0.02 0.05 mg/L as N MOVERMAN CGREEN
Method Reference Lachat107-04-1-c 3/25/09 4/1/09
Nitrite as N in liquid
Method Reference Lachat107-04-1-c
0.01 0.01 U,J2 . mg/L as N- GBELK CGREEN
- 3/18/09 4/1/09
5
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone] Page 2 of 2

GROUNDWATER FIELD/LAB FORM
Location code_6P082WQ0004268
County_Sampson
Quad No Serial No.
Lat. Long.
Report To: ARO FRO,)MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO, Fed. Trust, Central Off., Other:
Shipped by: Bus, Qtouriee Hand Del., Other:
Collector(s):_BiIITo
FIELD ANAL.YSES
pH 400 3 i°'�
Temp.lo / i °C
Appearance C. E µ!L
Field Analysis .
By:_BillTodd
LABORATORY ANALYSES
BOD 310
mg/L
COD High 340
mg/L
X
COD Low 335-
mg/L
Coliform: MF Fecal 31616
/100m1
Coliform: MF Total 31504
/100m1
X
TOC 680
mg/L
Turbidity 76
NTU
Residue, Suspended 530
mg/L
pH 403
units ,
Alkalinity to pH 4.5 410
mg/L
Alkalinity to pH 8.3 415
mg/L
Carbonate 445
mg/L
Bicarbonate 440 -
mg/L
Carbon dioxide 405
mg/L
X
Chloride 940 '
mg/L
Chromium: Hex 1032
ug/L
Color: True 80
CU
Cyanide 720
mg/L
Purpose:
SAMPLE PRIORITY
Ei Routine
❑ Emergency
North Carolina
Department of Environment and Natural Resources
DIVISION OF WATER QUALITY -GROUNDWATER SECTION
Lab Number �t(rf�3t0q'
Date Received 3--/7.-t Time:
Rec'd By: / From:Bus, ourier, and Del.,
Other:
Data Entry By:
Date Reported:
Ck:
Time' /t► z 13t seline, Complaint, omplianc LUST, Pesticide Study, Federal Trust, Other:
(circle one)
Owner //��' C/a/v.-+//4'q //ICi f,4 . ; �.
Location or Site S `3DO �t2/.�,,Cc: ��s I 7 u.‹Xtei A%� - oicY',3 93
'Description of sam lin oint z ! (� r9-
SAMPLE TYPE
® Water
❑ Soil
❑ Other
Date '4WD/
Spec. Cond.94• at 25°C
Odor p p g,p, LrI
Sampling Method ,44 A 1 1 e.e-
(Y o. bailer. eic.i
Remarks ToMrn L�+.Jg, .6
01/ o) .616 - s •c t (Pumping time, air temp., etc.)
f( K eDr
X
Diss. Solids 70300
mg/L
Fluoride 951
mg/L
Hardness: Total 900
mg/L
Hardness (non-carb) 902
mg/L
Phenols 32730
ug/I
Specific Cond. 95
uMhos/cm
X
Sulfate 945
mg/L
Sulfide 745
mg/L
Oil and Grease
mg/L
X
NH3 as N 610
mg/L
X
TKN as N 625
mg/L
X
NO2 + NO3 as N 630
mg/L
X
P: Total as P 665
mg/L
X
Nitrate (NO3 as N) 620
mg/L
X
Nitrite (NO2 as N) 615
', mg/L
Ag-Silver 46566
ug/L
Al -Aluminum 46557
ug/L •
As -Arsenic 46551
ug/L
Ba-Barium 46558 -
ug/L-
Ca-Calcium 46552
mg/L
Cd-Cadmium 46559
ug/L
Cr-Chromium 46559
- ug/L
Cu-Copper 46562
ug/L
Fe -Iron 46563
ug/L
Hg-Mercury 71900
ug/L
K-Potassium 46555
mg/L
Mg -Magnesium 46554
• . mg/L
Mn-Manganese 46565
ug/L
Na-Sodium 46556 -
mg/L
Ni-Nickel
ug/L
Pb-Lead 46564
ug/L
Se -Selenium . -
ug/L
Zn-Zinc•46567
ug/L
Sample Interval -
Organochlorine Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides -
Acid Herbicides
PCBs
Semivolatile Organics
TPH-Diesel Range
Volatile Organics (VOA bottle)
TPH-Gasoline Range
TPH-BTEX Gasoline Range
LAB USE ONLY
Temperature on"arrival (°C):
Lab Comments -
GW-54 REV. 7/03 For. Dissolved Analysis -submit filtered sample and write "DIS" in block.

WC J WQ Laboratory Section 12esu(ts
County: SAMPSON
River Basin
Deport To FROAP
Collector:. B TODD
Region: - FRO
Sample Matrix: GROUNDWATER
Loc. Type: MONITORING WELL
Emergency Yes/No
COC Yes/No
YES
VisitID
Loc. Descr.: ALLEN CANNING FACILITY INC
Sample ID:
PO Number #
Date Received:
Time Received:
Labworks LoginID
Date Reported:
Report Generated:
AB41906
9G0371
03/17/2009
08:15
SMATHIS
4/1 /09,
04/01/2009
9/c H 0
Location ID: 6P082WQ0004268
Collect Date: 03/16/2009
Collect Time:: 11:20
Sample Depth
Sample Qualifiers and Comments
Routine Qualifiers
For a more detailed description of these qualifier codes'refer to www:dwglab.org under Staff Access
A -Value reported is. the average of two or more determinations
B1-Countable membranes with <20 colonies; Estimated
B2- Counts from all filters were zero.
B3- Countable membranes with more than 60 or 80 colonies; Estimated
B4-Filters have counts of both >60 or 80 and < 20; Estimated
B5-Too many colonies were present; too numerous to count (TNTC)
J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated
J3-The sample matrix interfered with the ability to make any accurate determination; Estimated
J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated
N1-The component has been tentatively identified based on mass spectral library search and has an estimated value
N3-Estimated concentration is < PQL and >MDL
NE -No established PQL
P-Elevated PQL due to matrix interference and/or -sample dilution
Q1-Holding time exceeded prior to receipt at lab.
Q2- Holding time exceeded following receipt by lab
PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity
U- Samples analyzed for this -compound but not detected
X1- Sample not analyzed for this compound
I AR
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
Page 1 of 2

WC CDWQ Laboratory Section Results
Location ID: 6P082WQ0004268
Loc. Descr.: ALLEN CANNING FACILITY INC
Visit ID
Sample ID AB41906
Collect Date: 03116/2009
Collect Time:: 11:20
CAS # Analyte Name
PQL
Result Qualifier Units Analyst/Date
Approved By !Date
,LAB
. •
Sample temperature at receipt by lab
Method Reference -
1.6
°C
DSAUNDERS SMATHIS
3/17/09 3/17/09
MIC
TOC in liquid
Method Reference APHA5310B-20th
2.0 2 U mg/L ADEXTER CGREEN
3/19/09 • 3/31/09
WET .
Chemical Oxygen Demand In liquid
Method Reference Hach 8000
20' 20 U
mg/L JSTALEY CGREEN
3/18/09 3/19/09
Ion Chromatography
Method Reference EPA 300.0
_TITLE_ • mg/L AWILLIAMS CGREEN
3/23/09 4/1/09
Total Dissolved Solids in liquid - 12 65 mg/L AWILLIAMS CGREEN
• Method Reference APHA2540C-18TH 3/17/09 - 3/19/09
Chloride
Method Reference EPA 300.0
1.0 17 mg/L AWILLIAMS CGREEN
3/23/09 4/1/09
Fluoride 0.4 0.4 1.1 mg/L AWILLIAMS CGREEN
Method Reference EPA 300.0 3/23/09 4/1/09
Sulfate
Method Reference EPA 300.0
2.0 3.5 mg/L AWILLIAMS CGREEN
3/23/09.. 4/1/09
NUT
NH3 as N In liquid - 0.02 0.02 U mg/L as N MAJAYI CGREEN
Method Reference 1:ac10-107-06-1-J 3/18/09 4/1/09
Total Kjeldahl N as N in liquid, 0.2 - " 0.2 U mg/L as N' MOVERMAN CGREEN
Method Reference Lachat107-06-2-H 3/20/09 3/24/09
NO2+NO3 as N In liquid 0.02 - 6.5 mg/L as N MAJAYI. CGREEN
Method Reference Lac10-107-04-1-c 3/18/09 4/1/09
Phosphorus- total as P : 0.02 - -0.17 mg/L as P GBELK- CGREEN
Method Reference Lac10-115;01-1EF 3/20/09 4/1/09
Nitrate as N In liquid 0.02 6.5
Method Reference Lachat107-04-1-c
mg/L as N MOVERMAN , CGREEN
3/25/09 4/1/09
Nitrite as N in liquid
Method Reference- Lachat107-04-1-c
0.01
0.01 U,J2 mg/L as N GBELK CGREEN
3/18/09 4/1/09
' • .
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone] - Page 2 of 2

GROUNDWATER FIELD/LAB FORM
Location•code 6P082WQ0004268
County_Sampson
Quad No Serial No.
Lat. Long.
Report To: ARO FRO,MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO Fed. Trust, Cehtral.Off., Other:
Shipped by: Bus, ourie Hand Del., Other:
Collector(s):_BilITod� -
FIELD ANALYSES
pH 400 d_ /(% Spec. Cond.s4
Temp.lo / _ °C Odor
Appearance
Field Analysis
By:_BillTodd
LABORATORY ANALYSES.
North Carolina
Department of Environment and Natural Resources
DIVISION OF WATER QUALITY -GROUNDWATER SECTION
SAMPLE TYPE
® Water
Soil
❑ Other
Ig Chain of Custody
SAMPLE.PRIORITY
E( Routine
❑ Emergency
DateS/l?/D Q
Purpose:
Time/% % 74.4" aseline Complaint,
at 25°C
BOD 310
mg/L
COD High 340
mg/L
X
COD Low 335
mg/L
Coliform: MF Fecal 31616
/100m1
Coliform: MF Total 31504
/100m1
X
TOC 680
mg/L
Turbidity 76
NTU
Residue, Suspended 530
mg/L,
pH 403
units
Alkalinity to pH 4.5 410
.' ' mg/L
Alkalinity to pH 8.3 415
mg/L
Carbonate 445
mg/L
Bicarbonate 440
• mg/L
Carbon dioxide 405
• mglL
X
Chloride 940
mg/L
Chromium: Hex 1032
ug/L
Color: True 80
CU_
Cyanide 720'
mg/L
Lab Comments
Lab Number l& DPI
Date Received 3- 11- 0 1 Tim
Rec'd By: , • , From:Bu
Other:
Data Entry By:
Date Reported:
190b
Ck:
LUST, Pesticide Study, Federal Trust, Other:
• r (circle one)
Owner >q //e r>(' Cit n�f y' i'�Ci r c� Z.
Location or Site t Re�"� f� r � 7u,Q K,` y AL . o2c?,E 93
Description of sam lin oilit z 1(� + ev¢ �h (
p P g,P, i
Sampling Method hi A i .1 e:z
Remarks j 5 /tam L p,4, xi -Ai Yym°. °ailer. etc.t
0Pic) 4'16 e »'ta (Pumping time, air temp., etc.)
K [D r
X
Diss. Solids 70300
mg/L
Fluoride 951
mg/L
Hardness: Total 900
mg/L
Hardness (non-carb) 902
mglL
Phenols 32730
ug/I
Specific Cond. 95
uMhos/cm
X
Sulfate 945
mg/L
Sulfide 745
_.mg/L
Oil and Grease '.
mg/L'
X
NH3 as N 610
mglL
X
TKN as N 625
mglL
X
NO2 + NO3 as N 630
mg/L
X
P: Total as P 665
mg/L
X
Nitrate (NO3as N) 620
mg/L
X
Nitrite (NO2 as N) 615
• mg/L
Ag-Silver 46566
ug/L
AI -Aluminum 46557
ug/L
As -Arsenic 46551
ug/L
Ba-Barium 46558
ug/L
Ca -Calcium 46552
mglL
Cd-Cadmium 46559
ug/L
Cr-Chromium 46559,
ug/L
Cu-Copper 46562
ug/L
Fe' -Iron 46563
ug/L
Hg-Mercury 71900
ug/L
K-Potassium 46555
mg/L
Mg -Magnesium 46554
mg/L
Mn-Manganese 46565
ug/L
Na-Sodium 46556
mg/L
'Ni-Nickel
ug/L
Pb-Lead 46564
ug/L
Se -Selenium;.
ug/L
Zn-Zinc'46567
' ug/L•
Sample Interval
O'ganochlorine Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides '
PCBs
Semivolatile Organics
TPH-Diesel Range -
Volatile Organics (VOA bottle)
TPH-Gasoline Range
TPH-BTEX Gasoline Range
LAB USE ONLY -
, 1
Temperature on -arrival (°C): .,
GW-54 REV. 7/03
For Dissolved Analysis -submit filtered sample and write"DIS" in block.

Report to: FRO
GROUNDWATER SECTION
CHAIN OF CUSTODY (COC) RECORD
NC DENR/DWQ LABORATORY (check one): [®) CENTRAL [❑) ARO [❑ [ WaRO
Page 1 of 1
DENR—FRO
For Investigation of: Allen Canning Facility Inc. WQ0004268
Incident No.
•
MAR 1 7 Mg
collector (print name)
and GW-54 forms completed by: Bill Todd Sample collector's signature:
dSample
.LGC
rye {t /Q
i W 1!
Field storage conditions and location (when applicable):
_ 'Lab Use, Only . -
.-_::,
LAB NO. "
SAMPLE ID
QUAD. NO.
LOCATION •
DATE
SAMPLED -
TIME
SAMPLED
NUMBER
OF
CONTAINERS
' '=
P'.�, "! �i.�
MW- 1
5900 Turkey Hwy
Turkey, NC 28393
din,*
CAM
9 '
6
MW 2
Same as above
©: a prn,
6
PO L'q o;
MW - 3
Same as above
/itywi
Obi Soeifr
6
A 1 5o /
MW 4
Same as above
g
AG/oet
P.'zbr�
6
•
Relin uished y (sign lure)•
4 di
atlo;
4/1
Timej
ec e b s'
a r
Date
Time
Relinquished by (signature):
Date
Time
Received by (signature):
Date •
Time
Relinquished by (signature):
Date
Time
Received by (signature):
Date
Time
Method of Shipment (check one): State
-delivered
Express■
UPS
Courier Hand
■ Federal
■ Other:
Security Type and Conditions:
Sealed by: MM-
isiajtret4t c yajo 9 1,6
Bro e by
`;
INTRALABORATORY CHAIN
LAB NUMBERS
FROM THROUGH
k1��1g03
Poi 'A3
ks II9o7:
woo
L(!9'°4.
OF CUSTODY - Lab Use Onl
NUMBER
BOTTLES.
y
ANALYSES
REQUESTED
C,oD.
-rD.
RELINQUISHED •
BY: -
3;
i

County:
River Basin
Report To
Collector.'
Region: •
Sample Matrix:
Loc. Type:
Emergency Yes/No
COC Yes/No
SAMPSON
FROAP
KGB/ED
APR 13 200
B TODD
FRO DDBBR—FAYEITEVILLEREGIONALOFRCE
GROUNDWATER
MONITORING WELL
YES
DWQ La6oratory,Section lWe:sults
VdATc
VisitlD
Loc. Descr:: ALLEN CANNING FACILITY INC
Sample ID:
PO Number#
Date Received:
Time Received:
Labworks LoginlD
Date Reported:
Report Generated:
Location ID:
6P082W00004268.
Collect Date: 03/16/2009
Collect Time::
09:55
Sample Depth
AB41903
9G0368
03/17/2009
08:15
SMATHIS
4R/09
04/07/2009
z1/8109
Sample Qualifiers and Comments
Routine Qualifiers •
For a more detailed description of these qualifier codes refer to www.dwglab.org under Staff Access
A -Value reported is the average of two or more determinations
B1-Countable membranes with <20 colonies; Estimated
B2- Counts from all filters were zero. -
B3- Countable membranes with more than 60 or 80 colonies; Estimated
B4-Filters have counts of both >60 or 80 and < 20; Estimated
B5-Too many colonies were present; too numerous to count (TNTC)
J2- Reported value failed to meet QC criteria for either precision or accuracy;'Estimated
J3-The sample matrix interfered with the ability to make any accurate determination; Estimated
J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated
N1-The component has been tentatively identified based on mass spectral library search and has an estimated value
N3-Estimated concentration is < PQL and >MDL
NE -No established PQL
P-Elevated PQL due to matrix interference and/or sample dilution
Q1-Holding time exceeded prior to receipt at lab.
Q2- Holding time exceeded following receipt by lab
PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity
U- Samples analyzed for this compound but not detected
X1- Sample not analyzed for this compound •
LAB,
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
Page 1 of 2

Location I,4:
cLoc. Descr.:
Visit ID
6P082WQ0004268
ALLEN CANNING FACILITY INC
NC DWQ Laboratory Section Results
Sample ID AB41903
Collect Date: 03/16/2009
Collect Time:: 09:55
CAS #
Analyte Name
PQL
Result Qualifier Units • Analyst/Date
Approved By /Date
Sample temperature at receipt by lab
Method Reference
1.6
DSAUNDERS - SMATHIS
3/17/09 3/17/09
MIC
TOC In liquid
Method Reference
APHA5310B-20th ,
2.0 52
mg/L
NDEO
CGREEN
• 4/1/09 ' 4/7/09 •
WET
Chemical Oxygen Demand in liquid
Method Reference Hach 8000
20 20 U
JSTALEY
3/18/09
CGREEN
3/19/09
Ion Chromatography
- Method Reference EPA 300.0 - •
_TITLE_
mg/L
AWILLIAMS
3/25/09
CGREEN
4/1/09
Total Dissolved Solids in liquid ' -
Method Reference APHA2540C-18TH
12
470 mg/L
AWILLIAMS
• 3/17/09
CGREEN
3/19/09
Chloride
Method Reference EPA 300.0
1.0 100
g/L AWILLIAMS CGREEN
3/25/09 4/1/09
Fluoride -
Method Reference . EPA 300.0
0-4 2.0 U,P . mg/L AWILLIAMS CGREEN
3/25/09 4/1/09
Sulfate 2.0 91 mg/L AWILLIAMS CGREEN
Method Reference EPA 300.0
3/25/09
4/1/09
NUT
NH3 as N In liquid
Method Reference
Lac10-107-06-1-J •
0.02 0.02 U mg/L as N MAJAYI CGREEN
3/18/09 4/1/09
Total Igeidahi N as N In liquid 0.2 02 • U mg/L as N MOVERMAN CGREEN.
- Method Reference Lachat107-06-2-H - - 3/20/09 - 3/24/09
NO2+NO3 as N In liquid 0.02 17 mg/L as N MAJAYI , - CGREEN
Method Reference Lac10-107-04-1-c 3/18/09 - 4/1/09 -
Phosphorus_ total as P in liquid 0.02 0.02 mg/L as P GBELK CGREEN
Method Reference Lac10-115-01-1EF - - 3/20/09 4/1/09
Nitrate as N In liquid 0.02 17 mg/L as N , MOVERMAN CGREEN
Method Reference Lachat107-04-1-c 3/25/09 4/1/09
Nitrite as N In liquid 0.01 0.01 U,J2 mg/L as N• GBELK CGREEN
Method Reference Lachat107-04-1-c 3/18/09 _ 4/1/09
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
Page 2 of 2

GROUNDWATER FIELD/LAB FORM
Location code_6P082WQ0004268
County_Sampson
-Quad No Serial No.
Lat. Long.
Report To: ARO FRO MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO Fed. Trust, Central Off., Other:
Shipped by: Bus, ourie Hand Del., Other:
Collector (s) :_B i I I To . .
FIELD ANALYSES
pH 400 S, 1015 Spec. Cond.94 at 25°C
Temp.lo - ;IA j °C Odor
Appearance
�LG,4L
Field Analysis
By:_BillTodd
LABORATORY ANALYSES
North Carolina
Department of Environment and Natural Resources
DIVISION OF WATER QUALITY -GROUNDWATER SECTION
SAMPLE TYPE
® Water
❑ Soil
❑ Other
E Chain of Custody
SAMPLE PRIORITY
)�( Routine
❑ Emergency
-Date[6101
BOD 310
mg/L
COD High 340
mg/L
X
COD Low 335
mg/L
- '-
Coliform: MF Fecal 31616
/100mI
Coliform: MF Total 31504
/100m1
X
TOC 680 '
mg/L
Turbidity 76
NTU
Residue, Suspended 530
mg/L
pH 403
units
Alkalinity to pH 4.5 410
mg/L
Alkalinity to pH 8.3 415
mg/L
Carbonate 445
mglL
Bicarbonate 440
mg/L
Carbon dioxide 405
mg1L
X
Chloride 940
mg/L
Chromium: Hex 1032
ug/L
Color: True 80
CU
Cyanide 720
mg/L
Lab Comments
Pur osefXa
Time C3'- Baseline, Complaint, omplian , LUST, Pesticide Study, Federal Trust, Other:
Jrr / (circle one)
Owner f! /k d aArii�1 1q / f Ci f r �i1ie.
Location or Site `90o Lu/,IC y IusLir 1 7RXCcy Jiff - a�c?393
Description of sampling,point /v z 1( ( c - 4
Sampling Method AP6 /3 f' I e:e-. Sample Interval
Remarks to„im Lp„/g.stir, o.bailer.etc.)
(1/ o) .AC, — Q v t e ,. (Pumping time, air temp., etc.)
, K cD r
M
Lab Number 16-05tOS /66
T)3
Date Received 3-1�-0 R Time: rat 1
Rec'd By: 1 From:Bus,
Other:
Data Entry By:
Ck:
X
Diss. Solids 70300
mg/L
Fluoride 951
mg/L
Hardness: Total 900
mg/L
Hardness (non-carb) 902
mg/L
Phenols 32730
ug/l
Specific Cond. 95
uMhos/cm
X
Sulfate 945
mg/L
Sulfide 745
mg/L
Oil and Grease
mg/L
X
NH3 as N 610
mg/L
X
TKN as N 625.
mg/L
X
NO2 + NO3 as N 630 •
mg/L
X
P: Total as P•665
mg/L
X
Nitrate (NO3 as N) 620
mg/L
X
Nitrite (NO2 as N) 615
mg/L
Date Reported:
Ag-Silver 46566
ug/L
Al -Aluminum 46557
ug/L
As -Arsenic 46551
ug/L
Ba-Barium 46558
ug/L
Ca -Calcium 46552
mg/L
Cd-Cadmium 46559
ug/L
Cr-Chromium 46559
ug/L
Cu-Copper46562
ug/L
Fe -Iron 46563 •
ug/L
Hg-Mercury 71900
ug/L
K-Potassium 46555
mg/L
Mg -Magnesium 46554
mg/L
Mn-Manganese 46565
ug/L
Na-Sodium 46556
mg/L
Ni-Nickel
ug/L
Pb-Lead 46564
ug/L
Se -Selenium
ug/L
Zn-Zinc 46567
ug/L
Organochlorine Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
PCBs
Semivolatile Organics
TPH-Diesel Range
Volatile Organics (VOA bottle)
TPH-Gasoline Range
TPH-BTEX Gasoline Range
LAB USE ONLY
Temperature on -arrival (°C):
GW-54 REV. 7/03
For Dissolved Analysis -submit filtered sample and write "DIS" in block.

NC CDWQ Laboratory Section Results
County:
,River Basin
Report To
Collector:
Region:
Sample Matrix:
Loc. Type:
Emergency Yes/No
COC Yes/No
SAMPSON
FROAP
B TODD
FRO
GROUNDWATER
MONITORING WELL
• YES
VisitID
Loc. Descr : ALLEN CANNING FACILITY INC
Sample ID:
PO Number#
Date Received:
Time Received:
Labworks LoginlD
Date Reported:
Report Generated:
Location ID:
6P082WQ0004268
Collect Date:
03/16/2009
Collect Time:: 09:55
Sample Depth
AB41903
9G0368
03/17/2009
08:15
SMATHIS
4/7/09
04/07/2009
-z-//8109
Sample Qualifiers and Comments
RECEIVED
APR 202
bENR-FAYE TENILLEREGIONALOFFICE
DATE:
REVISED
EPORT
ll BTlALS:.
Routine Qualifiers •
For a more detailed description of these qualifier codes refer to www.dwglab.org under Staff Access
A -Value reported is the average of two or more determinations
B1-Countable membranes with <20 colonies; Estimated
B2- Counts from all filters were zero.
B3-,Countable membranes with more than 60 or 80 colonies; Estimated
B4-Filters have counts of both >60 or 80 and < 20; Estimated
B5-Too many colonies were present; too numerous to count (TNTC)
J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated
J3-The sample matrix interfered with the ability to make any accurate determination; Estimated
J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated
N1-The component has been tentatively identified based on mass spectral library search and has an estimated value
N3-Estimated concentration is < PQL and >MDL
NE -No established PQL
P-Elevated PQL due to matrix interference and/or sample dilution
Q1-Holding time exceeded prior to receipt at lab.
Q2- Holding time exceeded following receipt by lab
PQL- Practical Quantitation Limit -subject to change due'to instrument sensitivity
U- Samples analyzed for this compound but not detected
X1- Sample not analyzed for this compound
LAB
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
Page 1 of 2

Location ID:
Loc. Descr.:
Visit ID
6P082WQ0004268 •
ALLEN CANNING FACILITY INC
NC 'WQ Laboratory Section R
Sample ID AB41903
Collect Date:
Collect Time::
03/16/2009
09:55
CAS #
Analyte Name
PQL
Result "Qualifier Units Analyst/Date
Approved By/Date
Sample temperature at receipt by lab
Method Reference
1.6
°C
DSAUNDERS
3/17/09
SMATHIS
3/17/09
MIC
WET
TOC In Iiquld
Method Reference
APHA5310B-201h
2.0 52
mg/L
NDEO CGREEN
4/1/09 4/7/09
Chemical Oxygen Demand In liquid 20 20 U mg/L JSTALEY - .CGREEN
Method Reference Hach 8000_
3/18/09 - • '3/19/09
Ion Chromatography _TITLE_ mg/L AWILLIAMS CGREEN
Method Reference EPA300.0 . 3/25/09 4/1/09
Total. Dissolved Solids In Ilquid 12 470 mg/L AWILLIAMS
Method Reference APHA2540C-18TH 3/17/09 .
CGREEN
3/19/09
Chloride 1.0 100 - mg/L AWILLIAMS CGREEN
Method Reference EPA 300.0 3/25/09 4/1/09 .
Fluoride 0.4 2.0 U,P mg/L AWILLIAMS CGREEN
Method Reference EPA 300.0 3/25/09 4/1/09
Sulfate
Method Reference EPA 300.0
2.0 91 mg/L AWILLIAMS - _ CGREEN
3/25/09 4/1/09
NUT
NH3 as N In Ilquid
Method Reference
Lad 0-107-06-1-J
0.02 0.02 U mg/L es N MAJAYI CGREEN
3/18/09 4/1/09
Total Kjeldahi N as N In Ilquid 0.2 0.2 U mg/L as N MOVERMAN
Method Reference Lachat107-06-2-1-1 3/20/09 •
CGREEN
3/24/09
NO2+NO3 as N In liquid 0.02 17 mg/L as N - MAJAYI CGREEN
Method Reference Lac10-107-04-1-c 3/18/09 4/1/09
Phosphorus total as P In liquid 0.02 0.02 mg/L as P
GBELK• CGREEN
Method Reference Lac10-115-01-1EF 3/20/09 4/1/09
•Nkrate aslN InJiquldll" 0.02
Method Reference Lachat107-04-•1-c
,17
mg/L as N
MOVERMAN • CGREEN '
3/25/09 4/1/09
Nitta as N In Iiquld 0.01 0.01 U,J2 mg/L as N GBELK CGREEN
Method Reference Lachat107-04-1-c 3/18/09 4/1/09
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone] Page 2 of 2

GROUNDWATER FIELD/LAB FORM
Location code_6P082WQ0004268
County_Sampson
Quad No
Serial No.
Lat. Long.
Report To: ARO FRO MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO Fed. Trust, Central Off., Other:
Shipped by: Bus, t ourie Hand Del., Other:
Collector(s):=BiliTo• •
FIELD ANALYSES
pH 400 S. % V
Temp.to 4 °C
Appearance �t&t --
Field Analysis
By:_BillTodd
LABORATORY ANALYSES
BOD 310
mg/L
COD High 340
mg/L
X
COD Low 335
mg/L
-
Coliform: MF Fecal 31616
/100m1
Coliform: MF Total 31504
/100m1
X
TOC 680
mg/L
Turbidity 76
NTU
Residue, Suspended 530
mg/L
pH 403
units
Alkalinity to pH 4.5 410
mg/L
Alkalinity to pH 8.3 415
mg/L
Carbonate 445
mg/L
Bicarbonate 440
mg/L
Carbon dioxide 405
mg/L
X
Chloride 940
mg/L
Chromium: Hex 1032
ug/L
Color: True 80
CU
Cyanide 720
r
mg/L
SAMPLE TYPE
® Water
❑ Soil
❑ Other
El Chain of Custody
SAMPLE PRIORITY
Routine
El Emergency
Date3/ 6101
Pur os fr/6.
Time ��' -3 Baseline, Complaint,
Spec. Cond.94 at 25°C
North Carolina
Department of Environment and Natural Resources
DIVISION OF WATER QUALITY -GROUNDWATER SECTION
Lab Number t7G-0 Jto0 A51-11 ( 7-03
Date Received 3-I -Q9 Time:
Rec'd By: From:Bus, ' ourier, and Del.,
Other:
Data Entry By ' Ck:
Date Reported:
LUST, Pesticide Study, Federal Trust, Other:
(circle one)
Owner it %%,i ar11,11!A'y / ✓iCi l r �-,, L1i&.
Location or Site .d 9Do '6a/tCc y7t I �¢Ky
Description of sam lilt oint t! ( e;.4 th
Odor p g_ p 1J
Sampling Method AO sq r" I e.e-
Remarks to °. palter. etc.t
TDMm L..Anitjs'tte/�'
(9/ c) .S..6. — v .' 2-8 : . (Pumping time, air temp., etc.)
K cDr
X
Diss. Solids 70300
mg/L
Fluoride 951
mg/L
Hardness: Total 900
mg/L
Hardness (non-carb) 902
. mg/L
Phenols 32730
ug/I
Specific Cond. 95
uMhos/cm
X
Sulfate 945
mg/L
Sulfide 745
mg/L
Oil and Grease
mg/L
X
NH3 as N 610
mg/L
X
TKN as N 625
mg/L
X
NO2 + NO3 as N 630
mg/L
X
P: Total as P 66g
mg/L
X
Nitrate (NO3as N) 620
mg/L
X
Nitrite (NO2 as N) 615
mg/L_
Ag-Silver 46566
ug/L
Al -Aluminum 46557
ug/L
As -Arsenic 46551
ug/L
Ba-Barium 46558
ug/L
Ca -Calcium 46552 -
mg/L
Cd-Cadmium 46559
ug/L
Cr-Chromium 46559
ug/L
Cu-Copper 46562
•
ug/L
Fe -Iron 46563
ug/L
Hg-Mercury 71900
ug/L
K-Potassium 46555
mg/L
Mg -Magnesium 46554
m./L
Mn-Manganese 46565
ug/L
Na-Sodium 46556
mg/L
Ni-Nickel
ug/L
Pb-Lead 46564
ug/L
Se -Selenium
ug/L
Zn-Zinc'46567
ug/L
Are - aay' 93
Sample Interval
Organochlorine Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
PCBs
Semivolatile Organics
TPH-Diesel Range
Volatile Organics (VOA bottle)
TPH-Gasoline Range
TPH-BTEX Gasoline Range
LAB USE ONLY
?
p
1 II0
Temperature on arrival (°C):
Lab Comments
GW-54 REV. 7/03
For Dissolved Analysis -submit filtered sample and write "DIS° in block.

Report to: _FROAP
NC DENR/DWQ Laboratory
Sample Anomaly Report (SAR)
Lab Number:
AB41903-
Station Location: ALLEN
CANNING FAC.
Sample Type: GROUND H2O
Date collected:
Affected Parameter(s): NO2
Sample ID:
County: SAMPSON
6Pog2wLct o6 2C
Priority: [ 4G
3/16/09 Date received: 3/17/09
Analytical Area (check one):
❑WCH
®NUT
DMETALS
❑MICRO
The following anomalies occurred (check all that apply):
❑Samples
❑Improper container used
❑VOA vials with headspace
❑Sulfide samples with headspace
['Samples not received, but listed on fieldsheet
['Samples received, but not listed on fieldsheet
DMislabeled as to tests, preservatives, etc.
['Holding time expired
['Prior to receipt in lab
['After receipt in lab
❑Insufficient quantity for analysis
['Sample exhibits gross non -homogeneity
•❑Sample not chemically preserved properly
- ❑pH out of range (record pH):7.0
❑Improper chemical
['Residual chlorine present in sample
DColor interference
['Heavy emulsion formed during extraction
['Sample bottle broken in lab - no reportable results
❑Other (specify):
Comments: LLS RECOVERY LESS THAN 75% . ( cw-6.1 „ems iz /).
1-J. ©, a r M9 J /L.
Corrective Action:
DVOA
❑PEST
Region: FRO
Collector: B TODD
Date analyzed: II S /09
❑ WARO
❑SVGA
®Quality Control
❑ Instrument failure — no reportable results
DAnalyst error — no reportable results
['Surrogates
DNone added
DRecovery outside acceptance limits
['Spike recovery
❑None added
❑Recovery outside acceptance limits
DFailed to meet criteria for precision
❑ Internal standards
['Blank contamination
®QC data reported outside of controls (e.g., QCS, LCS)
❑Incorrect procedure used
['SOP intentionally modified with QA and Branch Head
approval
❑ Invalid instrument calibration
DElevated detection limits due to:
❑Insufficient sample volume
oW .
Vev p a
['Samples were rejected by DWQ Lab. Authorized by: Date:
❑Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured.
❑Sample(s), on hold until:
®Sample reported with qualification. Data qualification code used:J2
❑Other (explain):
Notification Required? ❑ Yes ❑ No
Person Contacted:
Form completed by:
', Lead Chemist Review (initial):
[c�BIOCHEM
DMETALS
Branch Head Review (initial):
QA/QC Review (initial):
\A\Formsll.aboratory\S AR
[WEST
❑VOA
3/ :7/0 f
3 LthAi
Date: 3/18/2009
❑SVOA
Logged into database. by (initial): 1/24,42 3/2 )/0 j
10/23/0ldbs

County:
,River Basin
Report To
Collector:
Region:
Sample Matrix:
Loc. Type:
SAMPSON
FROAP
B TODD
FRO
GROUNDWATER
MONITORING WELL
Emergency Yes/No
COC Yes/No
Location ID:
YES
6P082WQ0004268
NC ��llp La6orato
VisitlD
ection 1�Zesufts
Loc. Descr.: ALLEN CANNING FACILITY INC
Collect Date: 03/16/2009
Collect Time:: 10:13
Sample Qualifiers and Comments
Sample ID:
PO Number #
Date Received:
Time Received:
Labworks LoginlD
Date Reported:
Report Generated:
Sample Depth
AB41904
9G0369
03/17/2009
08:15
SMATHIS
4/1/09
04/01 /2009
)4 0
Routine Qualifiers
For a more detailed description of these qualifier codes refer to www.dwglab.org.under Staff Access
A -Value reported is the average of two or more determinations
B1-Countable membranes with <20 colonies; Estimated
B2- Counts from all filters were zero.
B3- Countable membranes with more than 60 or 80 colonies; Estimated
B4-Filters have counts of both >60 or 80 and < 20; Estimated
B5-Too many colonies were present; too numerous to count (TNTC)
J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated
J3-The sample matrix interfered with the ability to make any accurate determination; Estimated
J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated
N1-The component has been tentatively identified based on mass spectral library search and has an estimated value
N3-Estimated concentration is < PQL and >MDL
NE -No established PQL
P-Elevated PQL due to matrix interference and/or sample dilution
Q1-Holding time exceeded prior to receipt at lab..
Q2- Holding time exceeded following receipt by lab
PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity
U- Samples analyzed for this compound but not detected
X1- Sample not analyzed for this compound
I AR
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
Page 1 of.2'

Sample ID AB41904
Location ID: 6P082WQ0004268
Loc. Descr.: ALLEN CANNING FACILITY INC
Visit ID
NC DWQ Laboratory Section I esuCts
Collect Date: 03/16/2009
Collect Time:: 10:13
CAS # Analyte Name
PQL
Result Qualifier Units Analyst/Date Approved By /Date
LAB
Sample temperature at receipt by lab
Method Reference -
1.6 'C DSAUNDERS SMATHIS
3/17/09 '3/17/09
MIC
TOC in liquid 2.0
Method Reference " APHA5310B-20th
2.9 mg/L ADEXTER CGREEN
3/19/09 3/31/09.
WET
Chemical Oxygen Demand in liquid - 20 20 U mg/L JSTALEY
Method Reference Hach 8000 - 3/18/09
CGREEN
3/19/09
Ion Chromatography
Method Reference EPA 300.0
TITLE_ mg/L AWILLIAMS CGREEN
3/25/09 4/1/09
Total Dissolved Solids In liquid 12 214 - mg/L AWILLIAMS CGREEN
Method Reference APHA2540C-18TH 3/17/09 3/19/09
Chloride 1.0 120 mg/L AWILLIAMS CGREEN
Method Reference EPA 300.0 3/25/09 4/1/09
Fluoride 0.4 2.0 U,P mg/L AWILLIAMS CGREEN
Method Reference EPA 300.0 - 3/25/09 4/1/09
Sulfate
Method Reference EPA 300.0
2.0 10 U,P mg/L AWILLIAMS CGREEN
3/25/09 4/1/09
NUT
NH3 as N in liquid 0.02 0.12 mg/L as N MAJAYI CGREEN
Method Reference Lac10-107-06-1-J - 3/18/09 4/1/09
Total KJeldahl N as N in liquid 0.2 0.36 mg/L as.N MOVERMAN CGREEN
Method Reference Lachat107-06-2-H 3/20/09 3/24/09
NO2+NO3 as N in liquid
Method Reference Lac10-107-04-1-c
0.02 0.05 mg/L as N MAJAYI CGREEN
3/18/09 4/1/09
Phosphorus total as P in liquid
Method Reference Lac10-115-01-1EF
0.02 0.03
mg/L as P GBELK CGREEN
3/20/09 4/1/09
.. Nitrate as AI inaiquii 0.02 05;, mg/L as N MOVERMAN CGREEN
Method Reference Lachat107-04-1-c 3/25/09 4/1/09
Nitrite as N in liquid
Method Reference Lachat107-04-1-c
0.01 0.01 U,J2 mg/L as N GBELK CGREEN
3/18/09 4/1/09
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone] Page 2 of 2

GROUNDWATER FIELD/LAB FORM
Location code_6P082WQ0004268
County_Sampson
Quad No Serial No.
Lat. Long.
Report To: ARO FRO,)MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO Fed. Trust, Central Off., Other:
Shipped by: Bus, ourie Hand Del., Other:
Collector(s):_BiIITo• •
FIELD ANALxSES
PH400 �• b�
SAMPLE TYPE
® Water
❑ Soil
LI Other
ig Chain of Custody
Dated /DI
Purpose:
SAMPLE PRIORITY
Er Routine
❑ Emergency
Time `b i 1'3'► ' seline, Complaint,
Spec. Cond.s4• at 25°C
Temp.10- 13:1 °C Odor
Appearance (E AO -
Field Analysis
By:_BillTodd
LABORATORY ANALYSES
BOD 310
mg/L
COD High 340
mg/L
X
COD Low 335
mg/L
Coliform: MF Fecal 31616
/100m1
Coliform: MF Total 31504
/100m1
X
TOC 680
mglL
Turbidity 76
NTU'
Residue, Suspended 530
mg/L
pH 403
units
Alkalinity to pH 4.5410
mg/L
Alkalinity to pH 8.3 415
mg/L
Carbonate 445
_ rng/L
Bicarbonate 440
mg/L
Carbon dioxide 405 •
mglL
X
Chloride 940
mg/L
Chromium: Hex 1032
ug/L
Color: True 80
CU
Cyanide 720 •
mg/L
Lab Comments
North Carolina
Department of Environment and Natural Resources
DIVISION OF WATER QUALITY -GROUNDWATER SECTION
Lab Number 16'1034pR
Date Received' 3--q-f Time:
Rec'd By: From:Bus, ourier, and Del.,
Other:
Data Entry By:
Date Reported:
Ck:
LUST, Pesticide Study, Federal Trust, Other:
(circle one)
_ f!! i
Owner //� reC � Z,1/2i1t /,4/1) / 4C i
Location or Site . `3 0 c i42AK : , ua I
Description of sampling,point /,I) z 1( %-F e;3at
-
Sampling Method I. A gym
Mn'7 LA.J ttAto1 o. bailer. etc.)
Remarks Tc
Sample. Interval
X
Diss. Solids 70300
mg/L
Fluoride 951
mg/L
Hardness: Total 900
mg/L
Hardness (non-carb) 902
- mglL
Phenols 32730
ug/I
Specific Cond. 95
uMhos/cm
X
Sulfate 945
mg/L
Sulfide 745
mglL
Oil and Grease
mg/L
X
NH3 as N 610
mg/L
X
TKN as N 625
mg/L
X
NO2 + NO3 as N 630
mg/L
X
P: Total as P 665
mg/L
X
Nitrate (NO3 as N) 620
mg/L
X
Nitrite (NO2 as N) 615
• mg/L .
(Pumping time, air temp., etc.)
pc cDr
Ag-Silver 46566
ug/L
AI -Aluminum 46557
ug/L
As -Arsenic 46551
ug/L
Ba-Barium 46558
ug/L
Ca -Calcium 46552
mg/L
Cd-Cadmium 46559
ug/L
Cr-Chromium 46559
ug/L
Cu-Copper 46562
ug/L
Fe -Iron 46563
ug/L
Hg-Mercury 71900
- ug/L
K-Potassium 46555
mg/L
Mg -Magnesium 46554
•
mg/L
Mn-Manganese 46565 •
ug/L
Na-Sodium 46556
mg/L
Ni-Nickel
ug/L
Pb-Lead 46564
ug/L
Se -Selenium
ug/L
Zn-Zinc'.46567
ug/L
Organochlorine Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
'
.
PCBs
Semivolatile Organics
TPH-Diesel Range
r
Volatile Organics (VOA bottle)
TPH-Gasoline Range
TPH-BTEX Gasoline Range
LAB USE ONLY
Temperature on,arrival (°C):
GW-54 REV. 7/03
For Dissolved Analysis -submit filtered sample and write in block.

Report to: _FROAP
NC DENR/DWQ Laboratory
Sample Anomaly Report (SAR)
Lab Number:
Station Location: ALLEN
CANNING FAC.
Sample ID:
County: SAMPSON •
(0Pogzwa2 00 vLJ g
.ample Type: GROUND H2O Priority: COG
Date collected: 3/16/09• Date received: 3/17/09
Affected Parameter(s): NO2
Region: FRO
Collector:
Date analyzed:
B TODD
Analytical Area (check one):
❑WCH
®NUT
['METALS
❑MICRO
The following anomalies occurred (check all that apply):
['Samples
❑Improper container used
❑VOA vials with headspace
['Sulfide samples with, headspace
['Samples not received, but listed on fieldsheet
['Samples received, but not listed on fieldsheet
❑Mislabeled as to tests, preservatives, etc.
['Holding time expired
['Prior to receipt in lab -
['After receipt in lab
❑Insufficient quantity for analysis
['Sample exhibits gross non -homogeneity
DSample not chemically preserved properly
['pH out of range (record pH).:7.0
['Improper chemical
['Residual chlorine present in sample
❑Color interference
['Heavy emulsion formed during extraction
❑Sample bottle broken in lab - no reportable results
❑Other (specify):
Comments: LLS RECOVERY LESS THAN 75% . (12.0c j 1Z /) ..
A 0,v I ,r,y 1J/t.
Corrective Action:
['VOA
['PEST
❑ WARO
❑SVGA
®Quality Control
❑Instrument failure — no reportable results
['Analyst error — no reportable results
❑ Surrogates
['None added
DRecovery outside acceptance. limits
DSpike recovery
['None added
DRecovery outside acceptance limits
DFailed to meet criteria for precision
❑Internal standards
DBlank contamination
®QC data reported outside of controls (e.g., QCS, LCS)
❑Incorrect procedure used
['SOP intentionally modified withQA and Branch Head
approval
❑Invalid instrument calibration
DElevated detection limits due to:
['Insufficient sample volume
LLS = 1 ova \ e P•
❑Samples were rejected by DWQ Lab.. -Authorized by:
❑Accepted and analyzed after notifying the collector or
❑Sample(s) on hold until: -
®Sample reported with qualification. Data qualification
❑Other (explain):
Notification Required? ❑ Yes
Person Contacted: Date:
Form completed by:
Lead Chemist Review (initial):
•. [BIOCHEM M-0
\ ❑METALS
Branch Head Review (initial):
QA/QC Review (initial):
)A\Forms\Laboratory\S AR
❑ No
❑PEST
['VOA
3/ 2:71O f
Date:
contact person and determining that another sample could not be secured.
code used:J2
Date: 3/18/2009
❑SVGA
Logged into database by (initial): t -12 3/27/0`
10/23/Oldbs

AB41906
9G0371
03/17/2009
08:15
SMATHIS
4/1/09
04/01/2009
) o
County: SAMPSON
River Basin
,; Fte}'drt To FROAP
Collector: B TODD
Region: FRO
Sample Matrix: GROUNDWATER
Loc. Type: MONITORING WELL
Emergency Yes/No
COC Yes/No
YES
WCDIN Q Laboratory Section
4F ER
VisitlD
Loc. Descr.: ALLEN CANNING FACILITY INC
esu(ts
Sample ID:
PO Number#
Date Received:
Time Received:
Labworks LoginlD
Date Reported:
Report Generated:
9/c
Location ID:
6P082WQ0004268
=
Collect Date:
03/16/2009
Collect Time::
11:20
Sample Depth
Routine Qualifiers,
For a more detailed description of these qualifier codes refer to www.dwglab.org under Staff Access
A -Value reported is the average of two or more determinations
B1-Countable membranes with <20 colonies; Estimated
B2- Counts from all filters were zero.
B3- Countable membranes with more than 60 or 80 colonies; Estimated
B4-Filters have counts of both >60 or 80 and < 20; Estimated
B5-Too many colonies were present; too numerous to count (TNTC)
J2- Reported value failed to meet QC criteria for either precision or accuracy; Estimated
J3-The sample. matrix interfered with the ability to make any accurate determination; Estimated
J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated
N1 The component has been tentatively identified based on mass spectral library search and has an estimated value
N3-Estimated concentration is < PQL and >MDL
NE -No established PQL
P-Elevated PQL due to matrix interference and/or sample dilution
Q1-Holding time exceeded prior to receipt at lab.
'Q2- Holding time exceeded following receipt by lab
PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity
U- Samples analyzed for this compound but not detected
X1- Sample not analyzed for this compound
I,AR
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
Page 1 of 2

Location ID: 6P082WQ0004268
Loc. Descr.: ALLEN CANNING FACILITY INC
Visit ID
NC cWQ Laboratory Section &ssuul k
Sample ID AB41906
Collect Date: 03/16/2009
Collect Time:: 11:20
CAS #
Analyte Name
PQL
Result QUal fier>-' Units
Analyst/Date
Approved By /Date
LAB
Sample temperature at receipt by Jab
Method Reference
1.6
°C-
DSAUNDERS SMATHIS
3/17/09 3/17/09
MIC
TOC In liquid
Method Reference APHA5310B-20th
2.0
u.
mg/L •
ADEXTER CGREEN
3/19/09 - 3/31/09
WET
Chemical Oxygen Demand in liquid.
:Method Reference Hach 8000
20
20
mg/L
JSTALEY CGREEN
3/18/09 - 3/19/09
Ion Chromatography
Method Reference . EPA 300.0
_TITLE_ mg/L
AWILLIAMS CGREEN
3/23/09 4/1/09
Total Dissolved Solids in liquid
Method Reference APHA2540C-18TH
12
65
mg/L
AWILLIAMS CGREEN
- :3/17/09 3/19/09
Chloride
Method Reference . EPA 300.0
1.0 17 mg/L ' AWILLIAMS . CGREEN
3/23/09 4/1/09
Fluoride 0.4 0.4 U mg/L AWILLIAMS CGREEN
Method Reference EPA 300.0.
3/23/09 ' 4/1/09
Sulfate
Method Reference EPA 300.0
. 2:0E 3.5 mg/L . - AWILLIAMS CGREEN
3/23/09 4/1/09
NUT
NH3 as N in liquid
Method Reference Lac10-107-06-1-J
0.02 0.02 U mg/L.as 'N ' MAJAYI CGREEN
3/18/09 4/1/09
Total Kjeldahl N as N in liquid 0.2
Method Reference Lachat107-06-2-H
0.2 U , _ mg/L as N MOVERMAN CGREEN
3/20/09 3/24/09.
NO2+NO3 as N in liquid
Method Reference Lac10-107-04-1-c
0.02 6.5 mg/L as N MAJAYI CGREEN
3/18/09 4/1/09
Phosphorus_totai as.P in liquid ' 0.02 . 0.17 - mg/L as P GBELK CGREEN
Method Reference Lad 0-115-01-1EF 3/20/09 . 4/1/09
it ateeas N in liquid
ri. 3 ,
Meth eerence Lachat107-04-1-c
0.02
mg/L as N
MOVERMAN •CGREEN
3/25/09 - 4/1/09
Nitrite as N in liquid . . - ' 0.01
Method Reference Lachat107-04-1-c
0.01 U,J2 mg/L as N GBELK CGREEN
3/18/09 4/1/09
Laboratory Section» 1623 Mall Service Center, Raleigh, NC 27699-1623 [phone] Page 2 of 2

GROUNDWATER FIELD/LAB FORM
North Carolina
Department of Environment and Natural Resources
DIVISION OF WATER QUALITY -GROUNDWATER SECTION
Location dode_6P082WQ0004268
0
County_Sampson
Quad No Serial No.
Lat. Long.
Report To: ARO FRO)MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO Fed. Trust, Central Off., Other:
Shipped by: Bus, t ourie Hand Del., Other:
Collector(s):_BillTo• •
FIELD ANALYSES
pH 400 - /6,
Temp.io WJx:.3 °C
Appearance (,
SAMPLE TYPE
® Water
❑ Soil
❑ Other
® Chain of Custody
SAMPLE PRIORITY
Routine
El Emergency
DatJ/ko/©9
Purpose:
Timej% % Mail'rgaseline, Complaint, , LUST, Pesticide Study, Federal Trust, Other:
(circle one)
! / f
Owner /le At C.'l "Ii11,1.1f !" Cc� [ r ; e.
Date Received 3 - VI' 0 1 .Tim
Rec'd By: „ From:Bu:, Courier 'and Del.,
Other:
Data Entry By:
Date Reported:
Ck:
Spec. Cond.94 at 25°C
Description of sampling oint if} t J ( ( co4-
Sampling MethodSample Interval
Remarks 7DMrr7 LFy„r9.1.77, tybailer.etc.l
�{ t4 r.
Field Analysis
By:_BillTodd
LABORATORY ANALYSES
BOD 310
mglL
COD High 340
mg/L
X _
COD Low 335
mglL
Coliform: MF Fecal 31616
/100m1
Coliform: MF Total 31504
/100m1
X
TOC 680
mglL
Turbidity 76
NTU
Residue, Suspended 530
mglL
pH 403
units
Alkalinity to pH 4.5 410
mg/L
Alkalinity to pH 8.3 415
mglL
Carbonate 445
mglL
Bicarbonate 440
mglL
Carbon dioxide 405
mglL
X
Chloride 940
mglL
Chromium: Hex 1032
ug/L
Color: True 80
CU
Cyanide 720
mglL
Lab Comments
Odor Location or Site ..DO `ea/q/Ce q vs 1 �,Q14t ..A/(- acKE 93
X
Diss. Solids 70300
mglL
Fluoride 951
mg/L
Hardness: Total 900
' mglL
Hardness (non-carb) 902
mg/L
Phenols 32730.
ug/I
Specific Cond. 95
uMhos/cm
X
Sulfate 945
mg/L
Sulfide 745
mglL
Oil and Grease
mglc
X
NH3 as N 610
mglL
X
TKN as N 625
mg/L
X
NO2 + NO3 as N 630
mg/L
X
P: Total as P 665
mg/L
X
Nitrate (NO3 as N) 620
mglL
X
Nitrite (NO2 as N) 615
• mg/L
(Pumping time, air temp., etc.)
Ag-Silver 46566
ug/L
Al -Aluminum 46557
ug/L
As -Arsenic 46551
ug/L
Ba-Barium 46558
ug/L
Ca -Calcium 46552
mglL
Cd-Cadmium 46559
ug/L
Cr-Chromium 46559
ug/L
Cu-Copper 46562
•
ug/L
Fe -Iron 46563
ug/L
Hg-Mercury 71900
ug/L
K-Potassium 46555
mglL
Mg -Magnesium 46554
•
mg/L
Mn-Manganese 46565
ug/L
Na-Sodium 46556
mg/L
Ni-Nickel
ug/L
Pb-Lead 46564
ug/L
Se -Selenium
ug/L
Zn-Zinc•46567
ug1L
Organochlorine Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
PCBs
Semivolatile Organics
TPH-Diesel Range
Volatile Organics (VOA bottle)
TPH-Gasoline Range
TPH-BTEX Gasoline Range
LAB USE ONLY
Temperature an,arrival (°C):
GW-54 REV. 7/03 For Dissolved Analysis -submit filtered sample and write "DIS° in block.

Report to: _FROAP
Lab Number:
NC DENR/DWQ Laboratory
Sample Anomaly Report (SAR)
Sample ID: (opoR2Wdt 0002(4,8
AB41906
Station Location: ALLEN County: SAMPSON •
CANNING FAC.
.ample Type: GROUND H2O Priority: L0C
Date collected: 3/16/09 Date received: 3/17/09
Affected Parameter(s): NO2
Analytical Area (check one):.
❑WCH
®NUT
Region: FRO
Collector:
Date analyzed:
B TODD
DMETALS
❑MICRO
The following anomalies occurred (check all that apply):
['Samples
❑Improper container used
❑ VOA vials with headspace
❑Sulfide samples with headspace
❑ Samples not received, but listed on fieldsheet
['Samples received, but not listed on fieldsheet
❑Mislabeled as to tests, preservatives, etc.
[Holding time expired
[Prior to receipt in lab
❑After receipt in lab
❑Insufficient quantity for analysis
[Sample exhibits gross non -homogeneity
[Sample not chemically preserved properly
❑pH out of range (record pH):7.0
['Improper chemical
[Residual chlorine present in sample
[Color interference
['Heavy emulsion formed during extraction
['Sample bottle broken in lab - no reportable results
❑Other (specify):
Comments: LLS RECOVERY LESS THAN 75% .
Corrective Action:
['VOA
['PEST
❑ WARO
❑SVGA
®Quality Control
❑Instrument failure — no reportable results
DAnalyst error — no reportable results
❑Surrogates
[None added
DRecovery outside acceptance limits
❑Spike recovery
['None added
DRecovery outside acceptance limits
❑Failed to meet criteria for precision
❑Internal standards
❑Blank contamination
®QC data reported outside of controls (e.g., QCS, LCS)
❑Incorrect procedure used
OSOP intentionally modified with QA and Branch Head
approval
❑Invalid instrument calibration
['Elevated detection limits due to:
❑Insufficient sample volume
y,)
AA- O, C' I my
LLS = I o� Vey p a
['Samples were rejected by DWQ Lab. Authorized by: Date:
['Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured.
❑Sample(s) on hold until:
®Sample reported with qualification. Data qualification code used:J2
❑Other (explain):
Notification Required? ❑ No
Person Contacted:
Form completed by:
Lead Chemist Review (initial):
[1BIOCHEM i^-'°
❑METALS
Branch Head Review (initial):
QAIQC Review (initial):
)Worms\laboratory\SAR
❑ Yes
Date:
3/ 2=7/0r
❑PEST
❑VOA
Date: 3/18/2009
❑SVGA
Logged into database by (initial): at.° 3//)/01
10/23/01dbs

NC DWQ Laboratory Section Results
County: SAMPSON
River Basin
Ftep'ort To FROAP
Collector: B TODD
.Region: FRO
Sample Matrix: GROUNDWATER
Loc. Type: MONITORING WELL
Emergency Yes/No
COC Yes/No
YES
VisitlD
Loc. Descr.: ALLEN CANNING FACILITY INC
Sample ID:
PO Number#
Date Received:
Time Received:
Labworks LoginlD
Date Reported:
Report Generated:
Location ID: 6P082WQ0004268
Collect Date: 03/16/2009-
Collect Time:: 11:20
Sample Depth
AB41906
9G0371
03/17/2009
08:15
SMATHIS
4/1/09
04/01 /2009
1 o
Routine Qualifiers.
For a more detailed description of these qualifier codes refer to www.dwglab.org under Staff Access
A -Value reported is the average of two or more determinations
B1-Countable membranes with <20 colonies; Estimated
B2- Counts from all filters were zero.
B3- Countable membranes with more than 60 or 80 colonies; Estimated
B4-Filters have counts of both >60 or 80 and < 20; Estimated
B5-Too many colonies were present; too numerous to count (TNTC)
J2- Reported value failed to meet QC criteria for either precision_ or accuracy; Estimated
J3-The sample matrix interfered with the ability to make any accurate determination; Estimated
J6-The lab analysis was from an unpreserved or improperly chemically preserved sample; Estimated
N1-The component has been tentatively identified based on mass`spectral library search and has an estimated value
N3-Estimated concentration is < PQL and >MDL
NE -No established PQL
P-Elevated PQL due to matrix interference and/or sample dilution
Q1-Holding time exceeded prior to receipt at lab.
Q2- Holding time exceeded following receipt by lab
PQL- Practical Quantitation Limit -subject to change due to instrument sensitivity
U- Samples analyzed for this compound but not detected
X1- Sample not analyzed for this compound
I,AR
Laboratory Section» 1623 Mail Service Center, Raleigh, NC 27699-1623 [phone]
Page 1 of 2

/
Location ID: 6P082WQ0004268
Loc. Descr.: ALLEN CANNING FACILITY INC
Visit ID
DWQ Laboratory Section csu
rAw"z
•
Sample ID AB41 906
Collect Date: 03/16/2009
Collect Time:: 11:20
CAS*
Analyte Name
PQL Result Q0alifier,--' Units Analyst/Date
Approved By /Date
' LAB
Sample temperature at receipt by lab'
Method Reference'
1.6 °C DSAUNDERS SMATHIS.
3/17/09 3/17/09
M IC
TOC In liquid
Method Reference APHA5310B-20th
2.0 2 U
mg/L
ADEXTER CGREEN
3/19/09 3/31/09.
WET
Chemical Oxygen Demand in liquid 20 20 U .mg/L JSTALEY CGREEN
. Method Reference Hach 8000
3/18/09 3/19/09
Ion Chromatography _TITLE_ mg/L AWILLIAMS CGREEN
Method Reference EPA 300.0
3/23/09 . 4/1/09
Total Dissolved Solids in liquid 12 65 - mg/L AWILLIAMS CGREEN
Method Reference APHA2540C-18TH
3/17/09 - 3/19/09
Chloride 1.0 17 mg/L AWILLIAMS
Method_Reference . EPA 300.0
3/23/09
CGREEN
4/1/09
Fluoride ,
Method Reference
EPA 300.0 .
0.4 0.4 U mg/L AWILLIAMS CGREEN
3/23/09 4/1/09
Sulfate
Method Reference EPA 300.0
2.0 3.5 mg/L AWILLIAMS CGREEN
3/23/09 4/1/09
NUT
NH3 as N in liquid •
Method Reference Lac10-107-06-1-J
0.02 0.02 • U mg/L as N MAJAYI CGREEN
3/18/09 4/1/09
Total Kjeldahl N as N in liquid 0.2
Method Reference Lachat107-06-2-H
0.2 U •• • trig/L.as'N MOVERMAN CGREEN •
- 3 /20/09 3/24/09
NO2+NO3 as N In liquid
Method Reference Lad 0-107-04-1-c
.0.02 6.5 mg/L as N MAJAYI CGREEN
3/18/09 4/1/09
phosphorus_total as.P in liquid
Method Reference Lad 0-115-01-1EF
O.02. 0.17 - mg/L as P , GBELK CGREEN
3/20109 ,..4/1/09
V.Nitratems N in liquid
Meth.. Reference
•
' Lachat107-04-11c
0.02 mg/L as N MOVERMAN CGREEN
3/25/09 4/1/09 • °
Nitrite as N In liquid
Method Reference • Lachat107-04-1-c
0.01
0.01 U,J2 mg/L as N GBELK CGREEN
3/18/09 4/1/09
Laboratory Section» 1623 Mall Service Center, Raleigh, NC 27699-1623 [phone]
Page 2 of 2

GROUNDWATER FIELD/LAB FORM
Location dode_6P082WQ0004268
fr
County_Sampson
Quad No Serial No.
Lat. . Long.
Report To:•ARO FRO)MRO, RRO, WaRO, WiRO,
WSRO, Kinston FO Fed. Trust, Central Off., Other:
Shipped by: Bus,Couri0 Hand Del., Other:
Collector(s):_BillTod
SAMPLE TYPE
® Water
O Soil
• Other
g Chain of Custody
SAMPLE PRIORITY
Z Routine
Emergency
FIELD ANALYSES
pH 400 LI - /le Spec. Cond.94
Temp.io . 'J �: -3 °C
Appearance
Field Analysis
By:_BillTodd
LABORATORY ANALYSES
North Carolina
Department of Environment and Natural Resources
DIVISION OF WATER QUALITY -GROUNDWATER SECTION
Lab Number 63 j I
Date Received 3 - l i - 0 J Tim
Rec'd By: From:Bu•, Courier and Del.,
Other: -
Data Entry By: Ck:
Date Reported:
(lob
Purpose:
g Timej? ? +b aseline, Complaint, omplianc:, LUST, Pesticide Study, Federal Trust, Other:
Date �lo�D (circle one)
frr r
Owner -X //� rif C4l+irrti/A4J '//i✓keir[ j 4. t
at 25°C Location or Site ,'Do t.SAK : y c e 1
Odor Description of sampling,,ppo,int /d e_ I ( ( 61
Sampling Method Ala 7 /e.-e_
BOD 310
mglL
COD High 340
mg/L
X .
COD Low 335
mg/L
Coliform: MF Fecal 31616
/100m1
Coliform: MF Total 31504
/10om1
X
TOC 680
mglL
Turbidity 76
NTU
Residue, Suspended 530
mglL
pH 403
units
Alkalinity to pH 4.5 410
mglL
Alkalinity to pH 8.3 415
mglL
Carbonate 445
mglL
Bicarbonate 440
mg/L
Carbon dioxide 405
mg/L
X
Chloride 940
mg/L
Chromium: Hex 1032
ug/L
Color: True 80
CU
Cyanide 720
mg/L
Lab Comments
Remarks j p runin `L�q�y^ Atj�mo. bailer. etc.)
cp.)�16 -- v
jt iDr
X
Diss. Solids 70300
mg/L
Fluoride 951
mg/L
Hardness: Total 900
mglL
Hardness (non-carb) 902
mg/L
Phenols 32730.
ug/I
Specific Cond. 95
uMhoslcm
X
Sulfate 945
mg/L
Sulfide 745
mg/L
Oil and Grease
mg/L
X
NH3 as N 610
mg/L
X
TKN as N 625
mglL
X
NO2 + NO3 as N 630
mg/L
X
P: Total as P 665
mg/L
X
Nitrate (NO3 as N) 620
mglL
X
Nitrite (NO2 as N) 615
' mglL
xytfe.
—7u,Qk�y de . ac%93
Sample Interval
(Pumping time, air temp., etc.)
Ag-Silver 46566
ug/L
Al -Aluminum 46557
ug/L
As -Arsenic 46551
ug/L
Ba-Barium 46558
ug/L
Ca -Calcium 46552
mg/L
Cd-Cadmium 46559
ug/L
Cr-Chromium 46559
ug/L
Cu-Copper 46562
ug/L
Fe -Iron 46563
ug/L
Hg-Mercury 71900
ug/L
K-Potassium 46555
mg/L
Mg -Magnesium 46554
mg/L
Mn-Manganese 46565
ug/L
Na-Sodium•46556
. mglL
Ni-Nickel
ug/L
Pb-Lead 46564
ug1L
Se -Selenium
ug/L
Zn-Zinc'46567
ug/L
Organochlorine Pesticides
Organophosphorus Pesticides
Nitrogen Pesticides
Acid Herbicides
PCBs
Semivolatile Organics
TPH-Diesel Range
Volatile Organics (VOA bottle).
TPH-Gasoline Range
TPH-BTEX Gasoline Range
LAB USE ONLY
Temperature on,arrival (°C): 1 IY/
GW-54 REV. 7/03 For Dissolved Analysis -submit filtered sample and write "DIS" in block.

Report to: _FROAP NC DENR/DWQ Laboratory
Sample Anomaly Report (SAR)
Lab Number:
AB41906
Station Location: ALLEN
CANNING FAC.
.ample Type: GROUND H2O
Date collected: 3/16/09
Affected Parameter(s): NO2
Analytical Area (check one):
❑WCH
®NUT
Sample ID:
County: SAMPSON •
PontA) 000,1.2.
Priority: c 0C
Date received: 3/17/09
Region: FRO
Collector:
Date.analyzed:
B TODD
*log
['METALS
❑MICRO
The following anomalies occurred (check all that apply):
['Samples
❑Improper. container used
['VOA vials with headspace
❑Sulfide samples with headspace
❑Samples not received, but listed on fieldsheet
❑Samples received, but not listed on fieldsheet
❑Mislabeled as to tests, preservatives, etc.
❑Holding time expired •
['Prior to receipt in lab
DAfter receipt in lab
❑Insufficient quantity for analysis
['Sample exhibits gross non -homogeneity
['Sample not chemically preserved properly
❑pH out of range (record pH):7.0
❑improper chemical
DResidual chlorine present in sample
❑Color interference -
['Heavy emulsion formed during extraction
['Sample bottle broken in lab - no reportable results
❑Other (specify):
Comments: LLS RECOVERY LESS THAN 75%
Corrective Action:
['VOA
[WEST
DWARO
DSVOA
®Quality Control
['Instrument failure — no reportable results
['Analyst error — no reportable results
❑Surrogates
['None added
['Recovery outside acceptance limits
❑Spike recovery
['None added
❑Recovery outside acceptance limits
DFailed to meet criteria for precision
❑Internal standards
['Blank contamination
®QC data reported outside of controls (e.g., QCS, LCS)
❑Incorrect procedure used
❑SOP intentionally modified with QA and Branch Head
approval
❑Invalid instrument calibration
DElevated detection limits due to:
❑Insufficient sample volume
62011 iz'/)
A o, c' I ,,. ti'L
(711/6
= l oW \ Q p .
❑Samples were rejected by DWQ Lab. Authorized by: Date:
❑Accepted and analyzed after notifying the collector or contact person and determining that another sample could not be secured.
❑Sample(s) on hold until:
®Sample reported with qualification. Data qualification code used:J2
['Other (explain):
Notification Required? ❑ Yes 0 No
Person Contacted: Date:
Form completed by: GWENDOLYN BELK
‘ Lead Chemist Review (initial):
D.BIOCHEM PM-0
['METALS.
Branch Head Review (initial):
QA/QC Review (initial): \
‘pFormsU.aEo atory\SAR
❑PEST
❑VOA
1;7/or
LtigAi
Date: 3/18/2009
❑SVOA
Logged into database by (initial): t .3/2i/01
10/23/Oldbs