NC0024911_Groundwater Monitoring Report October 2020_20201104

r ;
o\,LPN SEWEggC�.
4 �J
�Q 9
'�eoyeF N 4PQo
'UUNiY, NOPS
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 27699-1617
Information Processing Unit:
M
litan Sewerage District
OF BUNCOMBE COUNTY, NORTH CAROLINA
November 4th, 2020
Please find attached the Groundwater Quality Monitoring Reports for the month of October 2020 from
Metropolitan Sewerage District of Buncombe County (MSD). These monitoring report forms have
additional identification on the well ID line, MW-05, MW-06R, MW-07, MW-08R, for ease of reference.
Monitoring Well-05 exceeded allowable limits for pH. Monitoring Well-0611 exceeded allowable limits for
pH, iron and manganese. Monitoring Well-07 exceeded allowable limits for pH and iron. Monitoring
Well-08R exceeded allowable limits for iron and manganese. A second report is also attached to include
the resampling of VOCs for the month of October. Due to a power outage at the lab the samples were
required to be retested.
Please do not hesitate to contact me at 828-225-8224 with questions regarding the attached reports.
Sincerely,
Roger C. Edwards
Director of Operations & Pretreatment
MSD of Buncombe County
-Protecting Our Natural Resources-
Water Quality Regional Operations
Asheville Regional Office
SCANNED
2028 RIVERSIDE DRIVE, ASHEVILLE, NORTH CAROLINA 28804 TELEPHONE: [phone] FAX: [phone] WEBSITE: www.msdbc.org

GW-59A COMPLIANCE REPORT FORM Permit # NCO024911
(Submit one each monitoring period with GRf--.59 for/ns.)
1
Enter date monitoring results were due. (_011/30I2020_) Will this monitoring report (GW-59 and GW-
YES
NO
59A) be submitted after the established due date?
2
Was any required information missing on the GW-59 report forms?
YES
NO
IF the answer to question 1 or 2 is "YES', list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked at, missing cap, missing
YES
NO
identification plate, area overgrown, etc.)? Ifthe anslver is "Yes", contact the Regional 0jrice forguidance.
4
Are any monitored constituents equal to or above the established standards?
YES
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
MW-05 MW-06R MW-07 MW-08R
pH 5.4 pH 5.2 pH 5.9
Mn 9,330 ug/L Mn 14,800 ug/L
Fe 5,410ug/L Fe 831 ug/L Fe 61,600 ug/L
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
YES
NO
same constituent(s) in the same wells) in the last two years?
If the answer to question 5 is WO° skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding
standards, concentration(s) reported, and sample collection date for each occurrence (for the last two years).
MW-05 pH Mn Fe MW-06R pH Mn Fe MW-07 pH Mn Fe MW-08R pH Mn Fe
6112/19 68 482 ugIL
IOID19 5.7 302 uglL 102119 6.1 12.700 uglL 50,800 uglL 10019 6.3 10,400 uglL 2,860 uglL
1/220 5.9 533 uglL 524 uglL lIV20 63 10,000 ugA 43,000 uglL 1020 6.2 125 uglL 627 ugIL lIV20 11,700 ug1L 18,800 uglL
618120 5.6 U8120 5.5 7,860 uglL 1,820 uglL 61820 5a 308 uglL 447 uglL 618120 19,700 e/L 70,700 uglL
6
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
If the answer is "YES", a groundwater quality problem maybe occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells maybe improperly
FNO
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YES
N
groundwater quality problem?
If the answer to question 7 is 'YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 day,s� an evaluation may be
reauired to determine the impact the waste disposal system is havina at the review compliance
boundaries surroundina this facility, Failure to do so may subiect the rmitt to a Notice of Violation
fines, and/or penalties.
8
The person completing this portion (G W-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current G W-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
-&44 — t , a 11/ yAu) av
S'gnat e of Permittee (or Authorized Agent) I Dat
GW-59A 12/8/2003

Arl
(_,A`ceAna1Xica10
www.pacelabs.cam
October 28, 2020
Mr. Roger Edwards
Metropolitan Sewerage District
2028 Riverside Drive
Asheville, NC 28804
RE: Project: MWS 101520
Pace Project No.: 92500507
Dear Mr. Edwards:
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Enclosed are the analytical results for sample(s) received by the laboratory on October 14, 2020, The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lord Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
cc: Ms. Shannon Bergeron, Metropolitan Sewerage District
Mr. Chad Ledford, Metropolitan Sewerage District
Mr. Dwayne Martin, Metropolitan Sewerage District
Ms. Cassandra McKnight, MSD of Buncombe County
Patrick Smith, MSD of Buncombe County, NO
Mr. Alan Taylor, Metropolitan Sewerage District
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Pagel of27

.r
aceAnalXical
www.Dacelabs.cam
Project: MWS 101520
Pace Project No.: 92500507
Pace Analytical Services Charlotte
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
9800 Kincey Ave, Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
VirginiaNELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 27

r
ArPace
aceAnalytical o
www.pacelabs.com
Project: MWS 101520
Pace Project No.: 92500507
SAMPLE ANALYTE COUNT
Analytical Services, LLC
2225 eNC Riverside28 04
Asheville, NC 28804
[phone]
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92500507001 MW-05
EPA 200.7 Rev 4.41994
SH1
10
PASI-A
EPA 245,1 Rev 3.01994
SOO
1
PASI-A
SM 2540C-2011
RED
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.01993
KDF1
i
PASI-A
EPA 353.2 Rev 2.0 1993
CJL
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92500507002 MW-06R
EPA 200.7 Rev 4.41994
SH1
10
PASI-A
EPA 245.1 Rev 3.0 1994
SOO
1
PASI-A
SM 2540C-2011
RED
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.01993
KDF1
1
PASI-A
EPA 353.2 Rev 2.0 1993
CJL
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
92500507003 MW-08R
EPA 200.7 Rev 4.41994
SHt
10
PASI-A
EPA 245.1 Rev 3,0 1994
SOO
1
PASI-A
SM 2540C-2011
RED
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.01993
KDF7
1
PASI-A
EPA 353.2 Rev 2.0 1993
CJL
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 5310B-2011
ECH
1
PASI-A
92600607004 MW-07
EPA 200.7 Rev 4.41994
SH1
10
PASI-A
EPA 245.1 Rev 3.0 1994
SOO
1
PASI-A
SM 2540C-2011
RED
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
1
PASI-A
EPA 350.1 Rev 2.01993
KDF1
1
PASI-A
EPA 353.2 Rev 2.01993
CJL
1
PASI-A
SM 4500-CI-E-2011
CJL
1
PASI-A
SM 53108-2011
ECH
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
. This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 27

f ,
aceAnalXical
www.pacelabs.cam
ANALYTICAL RESULTS
Project: MWS 101520
Pace Project No.: 92500507
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-05 Lab ID: 92500507001 Collected: 10114/20 16:45 Received: 10/14/20 17:25 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Performed by
Collected By
Collected Date
Collected Time
pH
Temperature
Static Water Level
Specific Conductance
Odor
Appearance
200.7 MET ICP
Arsenic
Barium
Cadmium
Chromium
Iron
Lead
Manganese
Selenium
Silver
Sodium
245.1 Mercury
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
300.0 IC Anions 28 Days
Sulfate
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
Date: 10/28/2020 02:45 PM
Analytical Method:
Pace Analytical Services - Charlotte
Pace
1
10/20/20 10:28
Mark
1
10/20/20 10:28
Swann
10/14/20
1
10/20/20 10:28
10:45
1
10/20/20 10:28
5.4 Std, Units
1
10/20/20 10:28
17.9 deg C
1
10/20/20 10:28
17.62 feet
1
10120/2010:28
32.1 umhos/cm
1
10/2012010:28
No odor
1
10/20/20 10:28
Clear
1
10/20/20 10:28
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
NO ug/L
10.0
1
10/21/20 14:12
10/22/20 04:39
7440-38-2
14.0 ug/L
5.0
1
10/21/20 14:12
10/22/20 04:39
7440-39-3
NO ug/L
1.0
1
1012112014:12
1012212004:39
7440-43-9
NO ug/L
5.0
1
10/21/20 14:12
10/22/20 04:39
7440-47-3
260 ug/L
50.0
1
10/21/20 14:12
10/22/20 04:39
7439-89-6
ND ug/L
5.0
1
10/21/20 14:12
10/22/20 04:39
7439-92-1
33.4 ug/L
5.0
1
10/21/20 14:12
10/22/20 04:39
7439-96-5
NO ug/L
10.0
1
1012112014:12
10/2212004:39
7782-49-2
NO ug/L
5.0
1
10/21/20 14:12
10/22/20 04:39
7440-22-4
NO ug/L
5000
1
10/21/20 14:12
10/22/20 04:39
7440-23-5
Analytical Method: EPA 245.1 Rev 3.0
1994 Preparation
Method: EPA 245.1 Rev 3.0 1994
Pace Analytical Services -Asheville
NO ug/L
0.20
1
10/20/2018:47
10/22/2021:21
7439-97-6
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
62.0 mg/L
25.0
1
10119/2018:32
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services -Asheville
4.0 mg/L
1.0
1
1Olt 5/2020:40
14808-79-8
Analytical Method: EPA 350.1 Rev 2.0
1993
Pace Analytical Services -Asheville
NO mg/L
0.10
1
10123/2011:27
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
0.042 mg/L
0.040
1
10/16/20 00:03
14797-55-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 4 of 27

Pace Analytical Services, LLC
1 aceAnalytical o 2225 Riverside
Asheville, NC 2880404
www.pacelabs.com [phone]
ANALYTICAL RESULTS
Project: MWS 101520
Pace Project No.: 92500507
Sample: MW-05 Lab ID: 92600507001 Collected: 10/14/20 16:45 Received: 10/14/20 17:25 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua)
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride 1.4 mg/L 1.0 1 10/21/2003:34 16887-00-6
53106 TOC Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon NO mg/L 1.0 1 10/2612017:46 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Dale: 10/28/2020 02:45 PM without the written consent of Pace Analytical Services, U.C. Page 5 of 27

Analytical
www.pacelaba.cam
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: MWS 101520
Pace Project No.: 92500507
Sample: MW-06R
Lab ID: 92500507002 Collected: 10/14/20 13:10
Parameters
Results
Received; 10/14/20 17:25 Matrix: Water
Monitoring Well Data
Units Report Limit
------
OF Prepared
P Analyzed CAS No. Qua)
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Collected By
Pace
1
Mark
10/20/20 10:29
Collected Date
Swann
1 10/20/20 10:29
Collected Time
10/14/20
1
pH
13:10
10/20/20 10:29
Temperature
5.2 Sid. Units
1 10/20/20 10:29
1
Water Level
22,2 deg C
10/20/20 10:29
1
Static
pecific Conductance
9.85 feet
10/20/20 10:29
1
Odor
220.4 umhos/cm
10/20/20 10:291
Appearance
No odor
10/20/20 10:29
1
Clear
10/20/20 10:29
200.7 MET ICP
Analytical Method: EPA 200.7 Rev
1 10120/2010:29
4.4 1994 Preparation
Pace Analytical Services - Asheville
Method: EPA 200.7 Rev 4.4 1994
Arsenic
Barium
Cadmium
NO ug/L 10.0
77.2 ug/L 5.0
1 10/21/20 14:12 10/22/20 04:48 7440-38-2
Chromium
NO ug/L 1.0
1 10/21/20 14:12 10/22/20 04:48 7440-39-3
1
Iron
NO ug/L 5.0
10/21/20 14:12 10/22/20 04:48 7440-43-9
Lead
5410 ug/L 50.0
1 10/21/20 14:12 10/22/2004:48 7440-47-3
1
Manganese
NO ug/L 5.0
10/21/20 14:12 10/22/20 04:48 7439-89-6
1
Selenium
9330 ug/L 5.0
10/21/20 14:12 10/22/20 04:48 7439-92-1
1
Silver
NO ug/L 10.0
10/21/20 14:12 10/22/20 04:48 7439-96-5
1
Sodium
NO ug/L 5.0
10/2112014:12 10122/2004:48 7782-49-2
1
17800 ug/L 5000
10/21/20 14:12 10/22/20 04:48 7440-224
1
245.1 Mercury
Analytical Method: EPA245.1 Rev
10/21/20 14:12 10/22/20 04:48 7440-23-5
3.0 1994 Preparation Method: EPA245A Rev 3.01994
Pace Analytical Services
Mercury
-Asheville
2540C Total Dissolved Solids
NO ug/L 0.20
Analytical Method: SM 254OC-2011
1 10/20/20 18:47 10/22/20 21:28 7439-97-6
Pace Analytical Services - Asheville
Total Dissolved Solids
195 mg/L 25.0
1
300.0 IC Anions 28 Days
Y
A
Analytical Method: EPA 300.0 Rev
10/19/20 18:33
2.1 1993
Pace Analytical Services -Asheville
Sulfate
83.4 mg/L 1.0 1
350.1 Ammonia
Analytical Method: EPA 350.1 Rev
10/15/20 20:52 14808-79-8
2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
0.24 mg/L 0.10 1
353.2 Nitrogen, N021NO3 unpres
Analytical Method: EPA 353.2 Rev
10/23/20 11:35 7664-41-7
2.0 1993
Pace Analytical Services - Asheville
Nitrogen, Nitrate
0.069 mg/L 0,040 1
10/16/20 00:07 14797-55-8
REPORT OF LABORATORY ANALYSIS
Date: 10/28/2020 02:45 PM This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 27

aceAnalyical2 Pace Analytical Services, LLC
www.Pacelaas.com 2225 Riverside D,
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: MWS 101520
Pace Project No.: 92500507
SamPle: MW-06R
Lab ID: 92500607002 Collected: 10/14/20 13:10
Received:
Parameters
Results
10/14/20 17:25
Matrix: Water
Units Report Limit DF
Pre ared
P Analyzed
CAS No.
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Qual
--
Pace Analytical Services -Asheville
Chloride
9.4 mg/L 1.0 1
5310B TOC
Analytical Method: SM 53108-2011
10/21/20 03:37
16887-00-6
Pace Analytical Services - Asheville
Total Organic Carbon
1.3 mg/L 1.0 1
10/28/20 01:50
7440-44-0
REPORT OF LABORATORY ANALYSIS
Date: 10/28/2020 02:45 PM This report shall not be reproduced, except in lull,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 27

ate,.
�PaceAnalXical
www.pacela6s.csm
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: MWS 101520
Pace Project No.: 92500507
Sample: MW-08R
Lab ID: 92600607003 Collected: 10/1412014:05 Received:
10/1412017:25 Matrix: Water
Parameters
Results Units Report Limit OF Prepared
Analyzed CAS No. Qua]
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace 1
Collected By
Mark
10/20/20 10:30
1
Swann
10/20/20 10:30
Collected Date
10/14/20 1
Collected Time
15:25
10/20/20 10:30
pH
1
10/20/20 10:30
Temperature
6.6 Sid. Units 1
10/20/20 10:30
Static Water Level
23.1 deg C 1
9.97 feet
10/20/20 10:30
Specific Conductance
1
686 umhos/cm 1
10/20/20 10:30
Odor
No odor
10/20/20 10:30
Appearance
1
Clear
10/20/20 10:30
1
10/20/20 10:30
200.7 MET ICP
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation Method: EPA
200.7
Pace Analytical Services -Asheville
Rev 4.4 1994
Arsenic
Barium
NO ug/L 10.0 1 10/21/20 14:12
10/22/20 04:51 7440-38-2
Cadmium
62.6 ug/L 5.0 1 10/21/20 14:12
10/22/20 04:51 7440-39-3
Chromium
ND ug/L 1.0 1 10/21/20 14:12
10/22/20 04:51 7440-43-9
Iron
NO ug/L 5.0 1 10/21/20 14:12
10/22/20 04:51 7440-47-3
Lead
61600 ug/L 50.0 1 10/21/20 14:12
10/22/20 04:51 7439-89-6
Manganese
NO ug/L 5.0 1 10/21/20 14:12
10/22/20 04:51 7439-92-1
Selenium
14800 ug/L 25.0 5 10121/2014:12
10/2212020:59 7439-96-5
Silver
NO ug/L 10.0 1 10/21/20 14:12
10/22/20 04:51 7782-49-2
Sodium
NO ug/L 5.0 1 10/21/20 14:12
10122/2004:51 7440-22-4
24800 ug/L 5000 1 10/21/20 14:12
10/22/20 04:51 7440-23-5
245.1 Mercury
Analytical Method: EPA 245,1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev
Pace Analytical Services -Asheville
3.0 1994
Mercury
NO ug/L 0.20 1 10/20/20 18:47
10/22/20 21:31 7439-97-6
2540C Total Dissolved Solids
Analytical Method: SM 2540C-2011
Pace Analytical Services -Asheville
Total Dissolved Solids
392 mg/L 25.0 1
10/19/20 18:33
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Sulfate
162 mg/L 3.0 3
10/1712004:20 14808-79-8 M1
350.1 Ammonia
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Ammonia
0.56 mg/L 0.10 1
10123/2011:36 7664-41-7
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
Nitrogen, Nitrate
NO mg/L 0.040 1
10/1612000:10 14797-55-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Dale: 10/28/2020 02:45 PM
without the written consent of Pace Analytical Services, LLC.
Page 8 of 27

aceAnalXical
www.pacclabs.con1
Project: MWS 101520
Pace Project No.: 92500507
Sample: MW-08R
Parameters
4600 Chloride
Chloride
5310B TOC
Total Organic Carbon
Date: 10/28/2020 02:45 PM
Pace Analytical Services, LLC
2225 Riverside Or
Asheville, NC 28804
(828)254�7176
ANALYTICAL RESULTS
Lab ID: 92500507003 Collected. 10/14/20 14:05 Received: 10/1412017:25 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No.
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
14.6 mg/L 1.0 1
10/21/20 03:39 16887-00-6
Analytical Method: SM 53108-2011
Pace Analytical Services -Asheville
3.1 mg/L 1.0 1
10/28/20 02:43 7440-44-0
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Without the written consent of Pace Analytical Services, LLC,
Qual
Page 9 of 27

aceAnalytical
www.pacelabs.cart
ANALYTICAL RESULTS
Project: MWS 101520
Pace Project No.: 92500507
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-07 Lab ID: 92500507004 Collected: 10/14/2015:25 Received: 10/14/20 17:25 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Performed by
Collected By
Collected Date
Collected Time
pH
Temperature
Static Water Level
Specific Conductance
Odor
Appearance
200.7 MET ICP
Arsenic
Barium
Cadmium
Chromium
Iron
Lead
Manganese
Selenium
Silver
Sodium
245.1 Mercury
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
300.0 IC Anions 28 Days
Sulfate
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
Date: 10/28/2020 02:45 PM
Analytical Method:
Pace Analytical Services - Charlotte
Pace
1
10/20/20 10:31
Mark
1
10/20/20 10:31
Swann
10/14120
1
10/20/20 10:31
14:05
1
10/20/20 10:31
5.9 Sid. Units
1
10/20/20 10:31
22.8 deg C
1
10/20/20 10:31
10.68 feet
1
10/20/20 10:31
324.3 umhos/cm
1
10/20/20 10:31
No odor
1
10/20/20 10:31
Clear
1
10/20/20 10:31
Analytical Method: EPA 200.7 Rev 4.4 1994 Preparation
Method: EPA 200.7 Rev 4.4 1994
Pace Analytical Services -Asheville
ND ug/L
10.0
1
10/21/20 14:12
10/22/20 05:01
7440-38-2
41.9 ug/L
5.0
1
10/21/20 14:12
10/22/20 05:01
7440-39-3
ND ug/L
1.0
1
10/21/20 14:12
10/22/20 05:01
7440-43-9
NO ug/L
5.0
1
10/21/20 14:12
10/22/20 05:01
7440-47-3
831 ug/L
50.0
1
10/21/20 14:12
10/22/20 05:01
7439-89-6
NO ug/L
5.0
1
10/21/20 14:12
10/22/20 05:01
7439-92-1
46.8 ug/L
5.0
1
10121/2014:12
10/22/20 05:01
7439-96-5
NO ug/L
10.0
1
10/21/20 14:12
10/22/20 05:01
7782-49-2
NO ug/L
5.0
1
10/21/20 14:12
10/22/20 05:01
7440-22-4
11500 ug/L
5000
1
10/21/20 14:12
10/22/20 05:01
7440-23-5
Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994
Pace Analytical Services - Asheville
NO ug/L
0.20
1
1012012018:47
10122/2021:33
7439-97-6
Analytical Method: SM 2540C-2011
Pace Analytical Services - Asheville
275 mg/L
25.0
1
10/1912018:33
Analytical Method: EPA 300.0 Rev 2.1
1993
Pace Analytical Services - Asheville
86.9 mg/L
1.0
1
10/15/20 21:42
14808-79-8
Analytical Method: EPA 350.1 Rev 2.0
1993
Pace Analytical Services -Asheville
NO mg/L
0.10
1
10/23/2011:38
7664-41-7
Analytical Method: EPA 353.2 Rev 2.0
1993
Pace Analytical Services -Asheville
1.6 mg/L
0.040
1
10/16/20 00:11
14797-55-8
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, L-C.
Page 10 of 27

_,PaceAnalytical
vim.pacelabs.com
ANALYTICAL RESULTS
Project: MWS 101520
Pace Project No.: 92500507
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-07 Lab ID: 92500507004 Collected: 10/14/2015:25 Received: 10114/2017:25 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride 7.0 mg/L 1.0 1 10/21/20 03:40 16887-00-6
5310B TOC Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon 1.6 mg/L 1.0 1 10/28/20 03:00 7440-44-0
Date: 10/28/2020 02:45 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, L-C.
Pagel 1 of 27

aceAnalytical o
www.yacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: MWS 101520
Pace Project No.: 92500507
QC Batch: 574519
Analysis Method: EPA 245.1 Rev 3.0 1994
QC Balch Method: EPA 245.1 Rev 3.0 1994
Analysis Description: 245.1 Mercury
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92500507001, 92500507002,
92500507003, 92500507004
METHOD BLANK: 3041515
Matrix: Water
Associated Lab Samples: 92500507001, 92500507002,
92500507003, 92500507004
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Mercury ug/L
ND 0.20 10/22/20 21:17
LABORATORY CONTROL SAMPLE: 3041516
Spike LCS LCS % Rec
Parameter Units
Conc. Result e/ Rec Limits Qualifiers
Mercury ug/L
2.5 2.4 96 85-115
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3041517 3041518
MS MSD
92500507001
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Cone. Conc. Result Result %Rec %Rec
Limits RPD Qual
Mercury ug/L ND
2.5 2.5 2.5 2.4 100 96
70-130 4
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3041519 3041520
MS MSD
92500507002
Spike Spike MS MSD MS MSD
%Rec
Parameter Units Result
Conc. Conc. Result Result %Rec %Rec
Limits RPD Qual
Mercury ug/L ND
2.5 2.5 2.2 2.2 86 86
70-130 0
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit Is presented to the right aline result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
Date: 10/28/2020 02:45 PM without the written consent of Pace Analytical Services, LLC,
Page 12 of 27

Ar
aceAnalytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: MWS 101520
Pace Project No.: 92500507
uC Batch: 574746 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Balch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92500507001, 92500507002, 92500507003, 92500507004
METHOD BLANK: 3042565
Matrix:
Water
Associated Lab Samples:
92500507001, 92500507002, 92500507003, 92500507004
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed
Arsenic
ug/L
ND
10.0
10/22/20 04:32
Barium
ug/L
NO
5.0
10/22/20 04:32
Cadmium
ug/L
NO
1.0
10/22/20 04:32
Chromium
ug/L
NO
5.0
10/22/20 04:32
Iron
ug/L
ND
50.0
10/22/20 04:32
Lead
ug/L
NO
5.0
10/22/20 04:32
Manganese
ug/L
NO
5.0
10/22/20 20:56
Selenium
ug/L
ND
10.0
10/22/20 04:32
Silver
ug/L
ND
5.0
10/22/20 04:32
Sodium
ug/L
NO
5000
10/22/20 04:32
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3042566
Units
Spike
Conc.
LCS
Result
LCS
%Rec
%Rec
Limits
Arsenic
ug/L
500
512
102
85-115
Barium
ug/L
500
455
91
85-115
Cadmium
ug/L
500
484
97
85-115
Chromium
ug/L
500
455
91
85-115
Iron
ug/L
5000
4730
95
85-115
Lead
ug/L
500
499
100
85-115
Manganese
ug/L
500
468
94
85-115
Selenium
ug/L
500
502
100
85-115
Silver
ug/L
250
232
93
85-115
Sodium
ug/L
5000
4740J
95
85-115
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Qualifiers
MATRIX SPIKE R MATRIX SPIKE
DUPLICATE:
3042567
3042568
MS
MSD
92500507001
Spike
Spike
MS
MSD
MS
MSD
%Rec
Parameter
Units
Result
Conc.
Cone.
Result
Result
%Rec
%Rec
Limits
RPD Qual
Arsenic
ug/L
ND
500
500
527
546
105
109
70-130
4
Barium
ug/L
14.0
500
500
480
498
93
97
70-130
4
Cadmium
ug/L
NO
500
500
507
526
101
105
70-130
4
Chromium
ug/L
NO
500
500
473
492
95
98
70-130
4
Iron
ug/L
260
5000
5000
5100
5290
97
101
70-130
4
Lead
ug/L
ND
500
500
518
536
103
107
70-130
3
Manganese
ug/L
33.4
500
500
517
536
97
101
70-130
4
Selenium
ug/L
ND
500
500
540
566
108
113
70-130
5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right or the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/28/2020 02:45 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 27

jar
aceAnalXical
www.pacelabs.com
QUALITY CONTROL DATA
Project: MWS 101520
Pace Project No.: 92500507
Pace Ana lytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3042567 3042568
MS MSD
92500507001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Cone. Cone. Result Result %Rec %Rec Limits RPD Qua[
Silver ug/L ND 250 250 243 254 97 101 70-130 4
Sodium ug/L ND 5000 5000 6730 7000 95 100 70-130 4
MATRIX SPIKE & MATRIX
Parameter
SPIKE DUPLICATE: 3042569
MS
92500912002 Spike
Units Result Conc.
MSD
Spike
Cone.
3042570
MS
Result
MSD
Result
MS
%Rec
MSD
%Rec
%Rec
Limits
RPD Dual
Arsenic
ug/L
ND
500
500
545
542
109
108
70-130
0
Barium
ug/L
14.6
500
500
486
484
94
94
70-130
0
Cadmium
ug/L
ND
500
500
515
512
103
102
70-130
1
Chromium
ug/L
ND
500
500
472
466
94
93
70-130
1
Iron
ug/L
ND
5000
5000
4920
4840
98
97
70-130
2
Lead
ug/L
ND
500
500
524
519
105
104
70-130
1
Manganese
ug/L
NO
500
500
490
481
97
96
70-130
2
Selenium
ug/L
ND
500
500
559
554
112
111
70-130
1
Silver
ug/L
ND
250
250
246
242
98
97
70-130
2
Sodium
ug/L
12600
5000
5000
17400
17200
96
92
70-130
1
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Dale: 10/28/2020 02:45 PM without the written consent of Pace Analytical Services, L-C.
Page 14 of 27

aceAnalytical
www.pacolahs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: MWS 101520
Pace Project No.: 92500507
QC Batch: 574190
Analysis Method: SM 2540C-2011
QC Balch Method: SM 254OC-2011
Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92500507001, 92500507002, 92500507003, 92500507004
METHOD BLANK: 3040151
Matrix: Water
Associated Lab Samples: 92500507001, 92500507002, 92500507003, 92500507004
Blank Reporting
Parameter
Units
Result Limit Analyzed Qualifiers
Total Dissolved Solids
mg/L
NO 25.0 10/19/20 18:31
LABORATORY CONTROL SAMPLE:
3040152
Spike LCS LCS % Rec
Parameter
Units
Conc. Result %Rec Limits Qualifiers
Total Dissolved Solids
mg/L
250 266 106 90-110
SAMPLE DUPLICATE: 3040153
92500314013 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Dissolved Solids
mg/L
8750 8750 0
SAMPLE DUPLICATE: 3040154
92500507001 Dup
Parameter
Units
Result Result RPD Qualifiers
Total Dissolved Solids
mg/L
62.0 64.0 3
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/28/2020 02:45 PM without the written consent of Pace Analytical Services, LLC, Page 15 of 27

aceAnalXical
wwwpacelabs.corn
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NO 28804
[phone]
Project: MWS 101520
Pace Project No.: 92500507
QC Batch: 573438
Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993
Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92500507001, 92500507002, 92500507003, 92500507004
METHOD BLANK: 3036096
Matrix: Water
Associated Lab Samples: 92500507001, 92500507002, 92500507003, 92500507004
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Sulfate mg/L
NO 1.0
10/15/2017:31
LABORATORY CONTROL SAMPLE: 3036097
Spike LCS
LCS % Rec
Parameter Units
Cone. Result
%Rec Limits Qualifiers
Sulfate mg/L
50 51.0
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3036100 3036101
MS MSD
92500607003
Spike Spike MS
MSD MS MSD
%Rec
Parameter Units Result
Cone. Cone. Result
Result %Rec %Rec
Limits RPD Qual
Sulfate ril 162
50 50 208
202 93 81
90-110 3 Ml
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3036939 3036940
MS MSD
92500361005
Spike Spike MS
MSD MS MSD
%Rec
Parameter Units Result
Cone. Cone. Result
Result %Rec %Rec
Limits RPD Qual
Sulfate mg/L 50.7
50 50 95.4
97.1 89 93
90-110 2 M1
Results presented on this page are in the units indicated by the "Units" column except when an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 1012812020 02:45 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 27

Pace Analytical services, LLC
aceAnalytical0
2226 Riverside
Asheville, NC 2880404
www.pacelabs.com
[phone]
QUALITY CONTROL DATA
Project: MWS 101520
Pace Project No.: 92500507
QC Batch: 574949
Analysis Method: EPA 350.1 Rev 2.0 1993
QC Batch Method: EPA 350.1 Rev 2.0 1993
Analysis Description: 350.1 Ammonia
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92500507001, 92500507002,
92500507003, 92500507004
METHOD BLANK: 3043500
Matrix: Water
Associated Lab Samples: 92500507001, 92500507002,
92500507003, 92500507004
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L
NO 0.10 10/23/20 11:20
LABORATORY CONTROL SAMPLE: 3043501
Spike LCS LCS % Rec
Parameter Units
Cone. Result %Rec Limits Qualifiers
Nitrogen, Ammonia mg/L
5 5.0 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3043502 3043503
MS MSD
92500505001
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Cone. Cone. Result Result %Rec %Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L 15.7
5 5 20.6 20.3 99 92
90-110 2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3043504 3043505
MS MSD
92500507001
Spike Spike MS MSD MS MSD
% Rec
Parameter Units Result
Cone. Cone. Result Result %Rec %Rec
Limits RPD Qual
Nitrogen, Ammonia mg/L ND
5 5 4.8 4.8 97 97
90-110 0
Results presented on this page are in the units indicated by the "Units' column except where an alternate unit is presented to the right orthe result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/28/2020 02:45 PM without the written consent of Pace Analytical Services, L-C.
Page 17 of 27

aceAnalytical
www.pacelabsxorn
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: MWS 101520
Pace Project No.: 92500507
QC Batch: 573633
Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993
Analysis Description: 353.2 Nitrate + Nitrite, Unpres.
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92500507001, 92500507002, 92500507003, 92500507004
METHOD BLANK: 3037270
Matrix: Water
Associated Lab Samples: 92500507001, 92500507002,
92500507003, 92500507004
Blank Reporting
Parameter Units
Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L
NO 0.040 10/16/20 00:01
LABORATORY CONTROL SAMPLE: 3037271
Spike LCS LCS % Rec
Parameter Units
Cone. Result %Rec Limits Qualifiers
Nitrogen, Nitrate mg/L
1.5 1.5 100 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3037272 3037273
MS MSD
92500507001
Spike Spike MS MSD MS MSD
%Rec
Parameter Units Result
Cone. Cone. Result Result e/ Rec % Rec
Limits RPD Qual
Nitrogen, Nitrate mg/L 0.042
1.5 1.5 1.5 1.5 98 97
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3037274 3037275
MS MSD
92500507002
Spike Spike MS MSD MS MSD
%Rec
Parameter Units Result
Cone. Cone. Result Result %Rec %Rec
Limits RPD Qua[
Nitrogen, Nitrate mg/L 0.069
1.5 1.5 1.4 1.4 91 91
90-110 0
Results presented on this page are in the units Indicated bythe "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/28/2020 02:45 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 27

aceAnalytical
www.pacelabs.catn
QUALITY CONTROL DATA
Project: MWS 101520
Pace Project No.: 92500507
QC Batch: 574280
QC Batch Method: SM 4500-CI-E-2011 Analysis Method:
SM 4500-CI-E-2011
Analysis Description:
4500 Chloride
Associated Lab Samples: 92500507001, 92500507002, 9250
Pace Analytical Services -Asheville
507003,92500507004
METHOD BLANK: 3040376
Matr: Water
Associated Lab Samples: 92500507001, 92500507002, 92500507003 x92500507004
Parameter Blank Reporting
Units
Result Limit
Chloride
Analyzed Qualifiers
mg/L NO 1.0 10/21/20 03:22
LABORATORY CONTROL 'SAMPLE:
Pace Analytical Services, LLC
2225 Riverside D,
Asheville, NC 28804
[phone]
Parameter Units
Spike
LCS
LCS
Rec
Chloride
Cone.
Result
�^ Roc
Limits Qualifiers
mg/L
20
19.9
99
90-110
MATRIX SPIKE &MATRIX SPIKE DUPLICATE:
3040382
3040383
MS
MSD
92500507001
Parameter Units Result
Spike
Cone.
Spike
MS
MSD
MS MSD
%Rec
Chloride
mg/L 1
Cone.
Result
Result
%Rec %Rec
Limits RPD Qual
.4
10
10
11.3
11.4
99 99
9 0-110 __
1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3040384
3040385
MS
MSD
92500507002
Parameter Units Result
Spike
Cone.
Spike
MS
MSD
MS MSD
%Rec
Chloride
mg/L 9.4
Cons.
Result
Result
% Rec % Rec
Limits RPD Qual
10
10
19.6
19.6
102 102
90-110 p
Results presented oa this page are In the units indicated by the "Units" column except where an alternate unit is Presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 10/28/2020 02:45 PM This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC,
Page 19 of 27

y T
acekialytical
WWW,pacalabsaam
I
Project: MWS 101520
Pace Project No.: 92500507
QC Batch: 575657
QC Batch Method: SM 531OB-2011
Associated Lab Samples: 92500507001
METHOD BLANK: 3047249
Associated Lab Samples: 92500507001
Parameter Units
Total Organic Carbon mg/L
LABORATORY CONTROL SAMPLE: 3047250
Parameter Units
Total Organic Carbon mg/L
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Analysis Method:
SM 53108-2011
Analysis Description:
5310B TOC
Laboratory:
Pace Analytical Services -Asheville
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
NO 1.0 10/26 01013:05
Spike LCS LCS % Rec
Cone. Result %Rec Limits Qualifiers
25 26.3 105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3047251 3047252
MS MSD
92500271001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD
Total Organic Carbon Qual
mg/L ND 25 25 26.0 26.3 104 105 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3047253 3047254
MS MSD
92500507001 Spike Spike MS MSD MS MSD %Rec
Parameter Units Result Conc. Conc. Result Result %Rec %Rec Limits RPD
Total Organic Carbon m /L ND Qual
9 25 25 25.7 26.0 102 104 90-110 1
Results Presented on this page are in the units ideated by the "Units" column except where an alternate unit Is presentetl to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/28/2020 02:45 PM without the written consent or Pace Analytical Services, LLC.
Page 20 of 27

Aar
aceAnalytical
wam.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: MWS 101520
Pace Project No.: 92500507
QC Batch: 576014
Analysis Method:
SM 531 OB-2011
QC Batch Method: SM 531 OB-2011
Analysis Description:
5310B TOC
Laboratory:
Pace Analytical Services - Asheville
Associated Lab Samples: 92500507002, 92500507003, 92600507004
METHOD BLANK: 3048566
Matrix: Water
Associated Lab Samples: 92500507002, 92500507003, 92500507004
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Total Organic Carbon mg/L
ND 1.0
10/28/20 01:16
LABORATORY CONTROL SAMPLE: 3048567
Spike LCS
LCS % Rec
Parameter Units
Cone. Result
% Rec Limits Qualifiers
Total Organic Carbon mg/1-
25 26.3
105 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3048568 3048569
MS MSD
92500507002
Spike Spike MS
MSD MS MSD
% Rec
Parameter Units Result
Cone. Cone. Result
Result % Rec % Rec
Limits RPD Qual
Total Organic Carbon mg/L 1.3
25 25 27.9 28.3 106 108
90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3048570 3048571
MS MSD
92501837001
Spike Spike MS
MSD MS MSD
e/ Rec
Parameter Units Result
Cone. Cone. Result
Result % Rec a/ Rec
Limits RPD Qual
Total Organic Carbon mg/L 72.8
25 25 101
99.1 114 105
90-110 2 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/28/2020 02:45 PM without the written consent of Pace Analytical Services, LLC.
Page 21 of 27

aceAnalytical
www.pacelabs.com
QUALIFIERS
Project: MWS 101520
Pace Project No.: 92500507
DEFINITIONS
OF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit,
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
PQL- Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroelhylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis ofAcrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/28/2020 02:45 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 27

aceAna1j&a1
www.pacelabs.com
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Pace Analyti cal Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project:
Pace Project No.:
MWS 101520
92500507
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92500507001
MW-05
92500507002
MW-06R
92600507003
MW-08R
92500507004
MW-07
92500507001
MW-05
EPA 200.7 Rev 4.4 1994
574746
EPA 200.7 Rev 4.4 1994
574810
92600607002
MW-06R
EPA 200.7 Rev 4.4 1994
574746
EPA 200.7 Rev 4.4 1994
574810
92600507003
MW-08R
EPA 200.7 Rev 4.4 1994
574746
EPA 200.7 Rev 4.4 1994
574810
92500507004
MW-07
EPA 200.7 Rev 4.4 1994
574746
EPA 200.7 Rev 4.4 1994
574810
92500507001
MW-05
EPA 245.1 Rev 3.01994
574519
EPA 245.1 Rev 3.01994
574547
92500507002
MW-06R
EPA 245.1 Rev 3.01994
574519
EPA 245.1 Rev 3.01994
574547
92500607003
MW-08R
EPA 245.1 Rev 3.0 1994
574519
EPA 245.1 Rev 3.0 1994
574547
92500507004
MW-07
EPA 245.1 Rev 3.0 1994
574519
EPA 245.1 Rev 3.0 1994
574547
92500507001
MW-05
SM 2540C-2011
574190
92500607002
MW-06R
SM 2540C-2011
574190
92500507003
MW-08R
SM 2540C-2011
574190
92500507004
MW-07
SM 2540C-2011
574190
92500507001
MW-05
EPA 300.0 Rev 2.1 1993
573438
92500507002
MW-06R
EPA 300.0 Rev 2.1 1993
573438
92500507003
MW-08R
EPA 300.0 Rev 2.11993
573438
92500507004
MW-07
EPA 300.0 Rev 2.11993
573438
92600507001
MW-05
EPA 350.1 Rev 2.01993
574949
92500507002
MW-06R
EPA 350.1 Rev 2.01993
574949
92500507003
MW-08R
EPA 350.1 Rev 2.01993
574949
92500507004
MW-07
EPA 350.1 Rev 2.01993
574949
92600507001
MW-06
EPA 353.2 Rev 2.0 1993
573633
92500607002
MW-06R
EPA 353.2 Rev 2.01993
573633
92500507003
MW-08R
EPA 353.2 Rev 2.0 1993
573633
92500507004
MW-07
EPA 353.2 Rev 2.0 1993
573633
92500507001
MW-05
SM 4500-CI-E-2011
574280
92500507002
MW-06R
SM 4500-CI-E-2011
574280
92500607003
MW-08R
SM 4500-CI-E-2011
574280
92500507004
MW-07
SM 4500-CI-E-2011
574280
92500507001
MW-05
SM 5310B-2011
575657
92500507002
MW-06R
SM 5310B-2011
576014
92600507003
MW-08R
SM 5310B-2011
576014
92500507004
MW-07
SM 5310B-2011
576014
Date: 10/28/2020 02:45 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 23 of 27

`✓`
Document Name:
Document Revised: February 7, 2018
aceAnalytical'
Sample Condition Upon Recolpt(SCUR)
Page 1 of 2
Document No.;
Issuing Authority;
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving Sal pies:
Ashevile / Eden[] Greenwood❑ Huntersville❑ Raleigh[] Mechanicsville[]
Client Name: A
sProjectq: n�92D0050i
S
Courier: ❑Fed Ex ❑UPS ❑USPS ❑Client
❑Commercial Pace ,,,,,,______,,,,,,(((( ❑Other:_
Custody Seal Present? ❑Yes LINO Seals Intact? []Yes PNo
Packing Material; I JlOubble Wrap
Thermomet r. nT'
PIR Gun ID: r'7 6)M/ 6i-QA
El Bubble Bags ❑None ❑ Other
Type of ice; I let ❑Blue ❑None
Cooler Temp ('C): Z _ Correction Factor: Add/Subtract (°C)
Cooler Temp Corrected (°C);
d
USDA Regulated Soil (I /I N/A, water sample)
Did samples originate In a quarantine zone within the United States: CA, NY, or SC (check maps)?
❑Yes ❑No
IIIN I IIII IIII III II III
t32500507
Date/Initials Person Examining Contents:
JO - /v,GU
Biological Tissue Frozen?
❑Yes ❑No ❑N/A
Temp should be above freezing to 6°C
❑Samples out of temp criteria. Samples an ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
Including Havaii and Puerto Rico)? ❑Yes ONO
Comments/Discrepancy:
Chain Of Custody Present?
Yes
ONO
❑N/A
1.
Samples Arrived within Hold Time?
J Yes
❑Na
❑N/A
2.
Short Hold Time Analysis(<72 hr.)?
PIYes
❑No
EINIA
3.
Rush Turn Around Time Requested?
[]Yes
DN.
❑N/A
4.
Sufficient Volume?
Yes
❑No
[]N/A
5.
Correct Containers Used?
-Pace Containers Used?
Oiyos
'yes
❑No
[]No
❑N/A
❑N/A
6.
Containers Intact?
)]Yes
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered? ❑Yes
ON.
❑N/A
8.
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis
/OYes
Matrix: ' l
❑No
❑N/A
9.
Headspace in VOA Vials(>5-6mm)?
❑Yes
❑i No
❑N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
❑Yes
,ONo
❑No
❑N/A
❑NrA
11.
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Date/Time:
Field Data Required? ❑Yes JI_INo
Project Manager SCURF Review: Da
Project Manager SRF Review: % Date:
Page 24 of 27

�'
t =
rnucnuaryut.af
i
Document Name:
Sample Condition Upon fteceipt(5[UR)
Document Revised: February 7, 2018
Page 1 of 2
I DocumentNo.;
F-CAR-CS-033-Rev.06
Issuing Authority:
Pace Carolinas (ualityoffice
*Check marls top half of box if pH and/or dechlorination is Project N
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHS
**Bottom half of box is to list number of bottle
CIO# a 921" 00507
Pik LJP Due Date: 10/28/20
CLIENT: 93-MV)
Y
aV
_
E
E
rEV
•i
>
6
m
n
x
E
N
>
M
6
m
a
n
x
m
E
N
J
N
6
v
j
q
v
;
"J'
o.
m
O
M
x
m.H.�,
E
Nj
�%1
V
G
„
M
z
y
E
N
Z
M
0.
m
m
¢
m
E
,Nj
N
V
4
m
x
O
tlEf
,N{
V
6
so
a
z
m
o
v
3
O
3
a
u
a
a
E
N
U'
¢
V
n
E
`v
ri
U'
a
N
n
E
¢
E
N
M
U'
a
�'
a
a
a
E
M
N
G
a
v
O
¢
E
u,
M1I
V'
a
$
Z
E
o
rh
m
0
M
V'
a
z
q
O
E
`f
O
c
¢
z
¢O
v
O1
U'
>
z
¢
O
E
P
0
>
\
v
d
¢
O
E
U'
a
Z
s
«
o
1p
a
O
>
n
>
m
li
\
>
q
z
-
a
5
E
N
6
w.
Z
-
vE1
N
6
M
O
z
m
a
E
¢
M
6
m
z
W
w
c
x
E
a
of
�
a
Z
.>
o
c
-
E
M
>
z
Z
a
n
j
as
E
E
m
M
o
/M
1
1
3
fvi
LI
1
l
✓ i
s
6
7
8
9
10
11
12
pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot N
Note: Whenever there Is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, Incorrect containers.
Page 25 of 27

3
A
D
3 D
A
-
U
I-
W
J
Or
N
A
W
N
ITEM III01'
g 0
3 a
3
N
O
_
to
A
A
C O
d
O2
3 u
D
o
s
3
P'T
a@y
n
O
3'
O
:r
`9
E
m_
ps
so
m
3
a`SE5to
f<
n
4£Foe vFF_
to 3 k
s £
A A
a
a n
..
�
O
e o m
9
��
9
i
i
MATRIXCODE(seev ild codes la 10)
t\
z
g
of
SAMPLE TYPE (G•GRAe UGOLIP)
1
c
v
m
~
o
P-se
J
'z
m
2
y
i
c°
77
_
m
m
n
m
S-
�`
.
m
m
o
d
D
z
z
o
i
m
A
Le
SAMPLE TEMP AT COLLECTION
\r
V
Lz
T
A
R
v Is
g
Is n C'
g g
➢ n
3 a
r
OOF CONTAINERS
�
W
J'
.✓
Unpreservetl
��
\
m
v
cd N
iso
a
a O
_.
H2SO4
m
g
m z
O
HNO3
R_
MCI
m
N0O14
v
Na25203
m
-
Methanol
_
(
Other
_Analyses Test
YIN
1
\_
v
x
x
x
x
ammonia
8
x
x
X
x
Metals
°y
n
z
A
3
X
x
x
x
Chlorltla, SLIMS
m
m
rA,
\:
G
i
X
x
x
x
Nilrale
n
Cx
n
Ix
x
x
IDS
x
x
x
x
TOC
-
it
V0C 6200
_
>
S
g
3
K
`
to
z
m
m
TEMP inC
Resitleal Chlmine(YIN)
-
m
c
Receivae on
e
(YIN)
a
(D-
1.
Os10 Y
Sealed
1
�T
0
Cooler
YIN
N
K1
K
Samples
Intad
(YIN)
j ci
m =
°n
s
m z
o O
N 0n
vi C,^
N V/
d 0
�v
Ed
O ti
3 d
mK
D n
= y
< to
m (D
0
li 0
m 0
° c
3 ID
0
m ro
n
m
Z
Page 26 of 27

0
gggg
F
�
i
i
i
r
O•
n
Y
9
11
w
»
>
J
?
9
n
3
:A1
cU
V
w
Y
C 4
J
�G
l
_
J
1"
J
v
i
j
'\
V
y
o'
3
I` U
O
N
t+
Ltj Page 27 of 27

m
0
O r
D d D
N
d
<z�:
o
O:E* N
O
m
-0
m
m
n 0
a
vm W
3
c
m
a m rm' 3
�.
3
o
n
O r'11
o
O
o
m O
m
m$
p r v
o
n
F
,�
[-{
go
3 1
L)
m
o
mD
to
Z
m
a
d
d
K
r' Z
m
o
w
3
~ v y
�°
o
m
°�' c 41
m
z
D O
N
c 3
A A
o
_o
co
T
A A
mm
m
J
n
d
e
-1
O
i-
d
O
T
m
0
()
m
c
D
z
d
m
J
0
J
n
0
d
O
0
0 A
m
o f
m
m
o
0
0
a'
W
3
m
�'
o
o
p
Z
O
Z
m
°
.'9 D
a
3
C
a
3
3
z
Z
o
p
o
�
»
�
o.
0
3
3
3
3
3
3°
3
�+
3
N
d
N
co
ro
Km
m
o
m
m,
?
o
0
�o
o
m
iv
m
-•
Wo
!=
a
�
'
2
m
m
p
a
m
o
Z
O
n
E
Q
J
Z
»
Z
v
d
o
t
D
IO
D
O
d__.
m
!n
w
O..
m
J S
j
N
O
N
s
N
O
z
m m
Z
'
m
m
o
a
3
�-
O
3
o
m
m
m
o
0
0 m
o
3,
FT
nWi
J.
9 J
3
Z
v
m
m
3
•2
m
3
3
3
3 m
m
Z
0 302
n
m
0
0
0o
0
0
0
0
0
o
o
N d
y
m
n O O
d
N
Cm
J
Vi J
J
N
A
N
m
O
N
N
O"
d—
N
ON
N 3 N
Q
N
O
W
n
N
n
A
N
O
O
O
O
A
�
❑
�—�
�-
d
N
o-
d
O
N
p01
.•Y' J O
A
z❑
x
8
Ip
3
Ip �O
3
1�
1p
10
3
<O
(O
10
3
tO
�
3 3
m 10
3
�O
3
�O
3
tp
"
r
A
IN
z
z
°-�' m
❑0❑❑
m
O
o
?
m
m
<9
'm m
m
m
0
g
n zA
m
A
9
n
a= m
d
o v
s
p
a
;u
in
N
Q
,voD
m m
C)
m
m
N
N
N
`D
m
?
m
Q
o r
n
m
•c
o
v
d
C
m y
p F
.v
D
n
<
r
d
p
.z
m
o
J
m
A
Q
y o
D
N
O
O my
m
m
m �" m
m<
x
O
o A<
m
e
m
p
N 0
m
Q
o
O
o
O
d
A m
0
0
p
N
-mZi
A m Z
O
O.
O
^
n
z
O
S
0
Q
O
N
N '
-0
m
m
t0
A m
Ytril
y
y W
0
3
3 3
3®
N
3
O
0.
m
❑®�0co
Z
O
n 3 A
Dm
n
d
m
m $5
y
i
n
>
>
m
o
m im
n
n
n
Z
0
"
v
m
z
m
a 3
3
N
s
c_
w
v 0
o
W
m
3
mt
c
0
a
O
z
o m
d
0
Z
O
mm
9 N d
N
m
A
O
m'
O
O
J
z
^O
A
m
2
10 N d
m
m 3 ':
❑
0o
m p r
o r
{

m
<
0
n
v O
G
y
o
cn
o
Dm
m
o
mm
n
o
oO9zm
'0
,
�n
�yy
O
m
o
m 3
m
ar
O
m
z
r z
ory
y
m
o
�
c
y
zo
D
c
A°zd
y
y,
m
m
m
<
3
m
m
�
m
mA
z
=d
o°
�'
°
Q
d
sd
d
o
o° �°�
N ^n
3
o
N
i
N o
0
o
u
a w
m D
3 0
'='
z
A
m
0y
m
o
o
o>
m
A
a
00
W
coo.
o
m z
A r
0
m
o
f
m
w
a
Z
»
¢
O
3
?
N
J
p
n
o
0
a
NIW
a
o
3
°
d
3p
g
-
v.
m
m
m
o
Z
0
3
<
J
o
-1
]
10
Q
A
_
N
Z
»
6
©
c
m
p
O
3
3
F
3
3
c
3
3
c
3
3
.G.)
�m
m
Km
m
3
3
<
r
r
a
v
-
a
>
>'
°
m
n'
o
—
❑
0
o
W
a
z
o
o
m
0
O
ow
z
m
a
D s
o
»
I
o
c
3
a
m
m
o
y
`°
o
m
o
m
D s
-i
z
Z
m of
o.
m
m
m
3
a
m
w»
o
m
<
fn m
i z
w c'p
o
3 y
o
0
x'
m c•
MO
C
U
O
3
C
32
d
3
3
3
3 m
m
Z
Z
o m
n
n
m
a O n
N
m
J
N J
J
O
N
N
A
V
N
O
°"
<
— o
3 1
Q
W
N
0
N°
N
3
y
O
j
UI
V
O
W
ElN
°
N ry
N
W
Q
�
N
N
I� J O
ya
x
S
H
O
m
m
m
m m
m
mm
ro
io
is
�o
�o
co
�o
z
z
V
E o a
x'
o
m
y< 9
❑❑❑
Elro
v m
m
0
9
ym
o
A
m
a
a `
O
0
OO
Q
Z
m om
°0
ONm
m
m �C ~
D
cn
O T
J
A m
3P
n y o
°
0
3
c'
n D
J
°
a
J
N
j .. Z
c
3
�^ n
o
m
o- a D
=. o.
D
o
N
y o
W
J
•<
o
o
'r O
,$ N$
O N
m Z
°
o
Z
A c N
m
O p
c
-'� A 3
a
m
n
?
t°
o
0
oni
N 3
A
m Z
0
N
m
A
0.
N
o.
m
z
3
m
3 3
m m
3®
m❑®OBm
3
a
a¢
n
y
n
>
>
r
m
m
x
o
A
z M
n
$
z O
1O
3
3
G) 3
c
d
m' v 0
lOOZ
D a
a
3-
6
o
O n
DW
a M N
O
A
rr
O
O
ZW
z
m
J
°
0
0
1
••
ri
N
O
a
o 3
�
o
�
m
m
m
m D
"xa3Nm
❑
m p r
Boa{r

A
0
w
DA
y
o
w
or
m
y
n O
N
p
M D
m
o
m
Dm
3
OC
O
o
O
3 N A
y
m
o mO r
z
r
3
O
�iJ
N
-- _•
O
i
S Z
pl
d
d
d
r Z
i
3 0
ry
¢
,°-p o
•mi "30
Q
(O
m C O
o
y
o-
3
3
D
'
0
m
o
3
m m 0,
'a A
3
d
v
o.
m z
_
o
m
tD
z
m
Z �2
d
_
z
a 3
tci
N
.0
D
x
y
a T
T
z
Era
y
0 m o
m
¢
A
m -i
A
omzi
m
vOZ
o
D
om
zd
°
a3a
o
UN
Mm?
vpAc
3
z
O
N
QD,o
mo•
oo
Z
AD
o
u T 0
0
N
O
F
N
v
r
3 o
m
"oV
m
v
c Z
a
¢
d
m
m
m
O
a
3
0
0m
m
.*
-
m
of
O
-
c
-
m
a
N
x
-'-
nn
J
O
z
-1
u
d
v
➢
¢
Elc
m
o
O
O
G7
N
N
3
3
F
3
c
3
c
3
3
c
3
3
3
3
{
0
0
c
m
a
(O
u
@
u
F?
n
n
J.
u
0
N
m
O
m
f�
O
r
r
r
O
O
<
N
r
r
o
v
d
o
00
❑
a
0
0
o
0
o
z
m
o
O
O
0
v
>•
z
4
Z
a
d
O
o
t
a
J t0
J'
a
ci
D
O
d
m
-,
O r
W
m
O
3
0m
o
y
�°
J�
0
J
m
O
m
z
w d
c
d
y s
z
Z
0
n
m
m
z
m
t°m 'm
m
3¢
0
m
o
0
z
J m
m
o
°'
v
3.
d
Q
ELC
m
� '"
d
O
J
C
N C
C
C
Q
C
C
C
C d
N
Z
d
N
z
m 3
3
J
3
3
3
3 m
m
z
O
0
0
o
0
0
0 of
o
J
m
_;
m
o. p m
ut
N
m
J
N J
W
O
Wo
J
OJ
o
fli
m
m
O'
m o_
S
m
N
N
O
tAl1
W
N
P
N
i
W
d
ry 3 m
Z m_
Q
m
(Nn
O
3
W
N
O
O
f0
rn
(]
ElJ
O
d m¢
N
N
m
3
NN
7
A N
d
m
N
O
A
m
¢
�i
•.Z' � O
A
?.
z
x
g
o
c
c 3
3
c
c
3
c
c
3
c
3 3
3
3
3
f-
f-
r
f-
r
r
f-
?
•
z
z
00
FP
❑
❑❑
El0
O
J
m
m
<
y9
m
m
m
o
3
y oA
o
<
r
O
z
N
D 0
D
O
N 'o •n
m
A N
r
p
y
p
=m m
a¢
m
0
0G)
0
0
zA
m
0
Q
y o
rMdo
i
rooa
o
n
3
A
2
�P.
n
3�Q
m
3
'ma
Z
pFmzz
0m
<DrD
m
e
m
o
y a p
W
J
mNA
•<
o
o
n O
N
1
(n
a:m
0»
p
o
0 Z
0¢
N
o
o
n
n
z
A c 0
w
p
A A
m
a
n
'°
m
a
o
w
ni 3
m
m z
r
m
m
m
A
w
a
o
n
p
w
3
m N
¢
0
{
m z z
¢
3
m
m
N
2 D
O
m
m m
m❑>
n
N
¢
3
Li®❑
❑
n
x
m
W
m
N rD-
s{
D
o
o
O
r x
x
m
n p m
a
s o.
¢
y
0
0
J
m
z
p
z y
m
z
m
l
¢ 3
3
G)
s
o
l
J
O A
Dm
[o
3
�o
c
N
.p
9
H
a d
d
O
z
mon
m
w
m
0
m>?
0
m
3 z
z
m
m
0
�_
N
m
J
'-J"
-
m
N
O
V
J
m
u
m
m
m S d
IZ N m
❑

3
c
d
0
O
O
N
3
0
n
N
3
d
e
Tp O r
w
<g:
O:E :E w
�E
O
T
T
T
T
0O
O :0
y Wp
3
3
go
O
D
o 0
< ._.
0
m3 ��'
m
o
�.
o �_ o�
d
D
Z
z<
[ Z
n
O
n s o
m m O°
z
m O
v
nd
o-
3
0
O
m
f
v
C
o
N _
m
z
D
a
fn
�
..
0
D
0>
z
3
c
a
" °z T
< A
m
'°°'
O
m
J
s
o,
o
r
O m O
T
N
0
H r
Z N p
m
D
.�
z
d
N
d
9
D
m
;u
N
Z
Mi.o
i
J
0
J
6
O
0
N
O
O"
d
N
.0
"
M
-0 O
0
O
O 3
Q
O -1
N
Ut
O
v
O
o
A
o
o
_.
m- D
0
Q
o
m 3 0
A
v
Z
0 C
z o
T
-Ni
m
o
w
o
o
4'
='I
o
d
o
T Z
m
<
g
70 D
o
N
ar
W
Z
N
T
D N
N
O
N
N o
a
U)
O
o
m
N
C
O
a
v.
Z
<
v
O
3
O
c
_
ry
N
d
d
pQ
o
c _
N
0
m
Z
3
m
g
z
3
3
3
c
3
c
3
3
3
�O
t0
K:n
4R?
�
ro
E
-
�O o
o
i0
m
?
r=
o?
r=
El
O
0
0
_
o
z
O
o
s
a?
O oJ.
z
a
o
t
�o
0
o
T
C
3
d➢
0
Z
N d
o
3
J
c
N C
C
C
U
O
C
C
C
C d N
N
Z
d
C 3
F
�^
d 3
3
,2
O
J
',
d
3
3
3
3 m v
z
z
0
d<
o
o o
m
N
m
m
n p
N
m
VV
N
N
W
A
J
J
(T N
N
d
o
3 ry
N
nw
p
O-
A
O
N
N
O
d
Q
O
d ry^ N
y
W
0
o
a
o
➢
<
W N D
w
Jw
N
m
g
y
O
c
c 3
3
c
c
3
10
�L �O
f0
10
10
�O
t0
tc
�O
�O
�p 10 10
f0
(O
r
r
r r
r
r
r
r
r
r
r
r r?
r
n
Z
Z
m
00
❑
❑ ❑
❑
T
o
?
m
< v
m
m
O
3
D
<ra
0
z
D O
D
O
O
0Oz
O
v
?
vomS
m
,a
O
O
o
m
m
p r
d r
o
m
D
Z
D-Di
oT
u
J
o
O
m
3
o
m mz
o
n
n
o
'�''�
o-
A
3
P
O
O
o
m
m D
D
j
s
W
d
C
m
pxi
o
o
•nc O
m
O w
S-
❑
o
m O z
Ono
coo�3
n
Oz.1p".c(n
d
pp
Am
0
ry
3
0
t°
m
0
m 3
T
m'
D m y
n
o
o
ooi
m N
3
;u
m N N
a
®D
#
N
0
.-1
O
Z x C
mmm
130011
3
m
y �
O
O O
O
O
j
p
N
V
•'
n
n n
n
y
0
0
J
ry
ry
Z
O
Z frail
`�
m
z
m
l
n 3
3
O
s
m
c
m A o
D¢
n
9
l
O
o
O a
DW
N
`no
3
IC
O
u
a^^
Z
O
S !ran N
.0
ry
Z
m
9
c
J
A
N
m
O
J
A
d
i C
N
0
=
m
O
A
(1
�
�
m
Z
m
D
oOA
Elx.
d p r
� r
o �
<

O
O
I�
c1
�
ya
N
c•
r
<
r
Y
Y
�
J
�
J
n
C
0 3
U
� zaoZi
o
`
� D
0
a
w'
r.
�
n
ro L
o: 2
n
O
O
OV
0
0
U
m
�
r_
ry j
V ry
m b
r
Q \
P
o
o
➢
\
Q
c
o

ace Analytical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
October 30, 2020
Mr. Roger Edwards
Metropolitan Sewerage District
2028 Riverside Drive
Asheville, NC 28804
RE: Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
Dear Mr. Edwards:
Water Quality Regional. Operations
Asheville Regional Office
Enclosed are the analytical results for sample(s) received by the laboratory on October 23, 2020. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
11r�c��
orr Patton
[e-mail]
1(828)254-7176
Project Manager
Enclosures
cc: Ms. Shannon Bergeron, Metropolitan Sewerage District
Mr. Chad Ledford, Metropolitan Sewerage District
Mr. Dwayne Martin, Metropolitan Sewerage District
Ms. Cassandra McKnight, MSD of Buncombe County
Patrick Smith, MSD of Buncombe County, NC
Mr. Alan Taylor, Metropolitan Sewerage District
SCANNED
�p PC[REp.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical services, LLC. Page 1 of 23

aceAnalytical
www.pacelabsxom
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky LIST Certification #: 84
VirginiaNELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 23

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
MONITORING WELL RESAMPLE102320
92502026
Analytes
Lab ID
Sample 10
Method
Analysts
Reported
Laboratory
92502026001
MW-05
SM 6200B
SAS
63
PASI-C
92502026002
MW-06R
SM 6200B
SAS
63
PASI-C
92502026003
MW-07
SM 6200B
SAS
63
PASI-C
92502026004
MW-08R
SM 6200B
SAS
63
PASI-C
PASI-C = Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 23

aceAnalyiical
wwd.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
Sample: MW-05
Parameters
Lab ID: 92502026001 Collected: 10/21/20 16:30 Received: 10/23/20 16:45 Matrix: Water
Results Units Report Limit OF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
10/28/20 15:13
Collected By
Mark
1
10/28/20 15:13
Swann
Collected Date
10/21/20
1
10/28/20 15:13
Collected Time
16:30
1
10/28/20 15:13
pH
5.4
Std. Units
1
10/28/20 15:13
Temperature
18.5
deg C
1
10/28/20 15:13
Static Water Level
17.76
feet
1
10/28/20 15:13
Specific Conductance
34
umhos/cm
1
10/28/20 15:13
Odor
No odor
1
10/28/20 15:13
Appearance
Clear
1
10/28/20 15:13
6200E MSV
Analytical Method:
SM 6200B
PaceAnalytical Services - Charlotte
Benzene
ND
ug/L
0.50
1
10/29/20 15:23 71-43-2
Bromobenzene
ND
ug/L
0.50
1
10/29/20 15:23 108-86-1
Bromochloromethane
NO
ug/L
0.50
1
10129/2015:23 74-97-5
Bromodichloromelhane
NO
ug/L
0.50
1
10/29/20 15:23 75-27-4
Bromoform
ND
ug/L
0.50
1
10/2912015:23 75-25-2
Bromomethane
ND
ug/L
5.0
1
10/29/20 15:23 74-83-9
n-Butylbenzene
NO
ug/L
0.50
1
10/29/20 15:23 104-51-8
sec-Butylbenzene
NO
ug/L
0.50
1
10/29/20 15:23 135-98-8
tert-Butylbenzene
NO
ug/L
0.50
1
10/29/20 15:23 98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
10/29/20 15:23 56-23-5
Chlorobenzene
NO
ug/L
0.50
1
10/29/20 15:23 108-90-7
Chloroethane
NO
ug/L
1.0
1
10/29/20 15:23 75-00-3
Chloroform
NO
ug/L
0.50
1
10129/2015:23 67-66-3
Chloromethane
ND
ug/L
1.0
1
10/29/20 15:23 74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
10/29/20 15:23 95-49-8
4-Chlorotoluene
NO
ug/L
0.50
1
10/29/20 15:23 106-43-4
1,2-Dibromo-3-chloropropane
NO
ug/L
1.0
1
10/29/20 15:23 96-12-8
Dibromochloromethane
NO
ug/L
0.50
1
10/29/2016:23 124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
10/29/20 15:23 106-93-4
Dibromomethane
NO
ug/L
0.50
1
10/29/20 15:23 74-95-3
1,2-Dichlorobenzene
NO
ug/L
0.50
1
10/29/20 15:23 95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
10/29/20 15:23 541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
10/29/20 15:23 106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
10/29/20 15:23 75-71-8
1,1-Dichloroelhane
NO
ug/L
0.50
1
10/29/20 15:23 75-34-3
1,2-Dichloroethane
NO
ug/L
0.50
1
10/2912015:23 107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
10/29/20 15:23 75-35-4
cis-1,2-Dichloroethene
NO
ug/L
0.50
1
10129/2015:23 156-59-2
trans-1,2-Dichloroethene
NO
ug/L
0.50
1
10/29/20 15:23 156-60-5
1,2-Dichloropropane
NO
ug/L
0.50
1
10/2912015:23 78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
10/2912015:23 142-28-9
2,2-Dichloropropane
NO
ug/L
0.50
1
10/29/20 15:23 594-20-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC, Page 4 of 23

aceAnalytical
www.pacelatn.cam
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
Sample: MW-05 Lab ID: 92602026001 Collected: 10/21/20 16:30 Received: 10123/2016:45 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
1,1-Dichloropropene
NO
ug/L
0.50
1
10/29/20 15:23 563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
10/29/20 15:23 10061-01-5
trans-1,3-Dichloropropene
ND
ug/L
0.50
1
10/29/20 15:23 10061-02-6
Ditsopropyl ether
NO
ug/L
0.50
1
10/29/20 15:23 108-20-3
Ethylbenzene
NO
ug/L
0.50
1
10/29/20 15:23 100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
10/29/20 15:23 87-68-3
Isopropylbenzene (Cumene)
NO
ug/L
0.50
1
10/29/20 15:23 98-82-8
Methylene Chloride
NO
ug/L
2.0
1
10/29/20 15:23 75-09-2
Methyl-tert-butyl ether
NO
ug/L
0.50
1
10/29/20 15:23 1634-04-4
Naphthalene
NO
ug/L
2.0
1
10129/2015:23 91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
10/29/20 15:23 103-65-1
Styrene
NO
ug/L
0.50
1
10/29/20 15:23 100-42-5
1,1,1,2-Tetrachloroethane
NO
ug/L
0.50
1
10/29/20 15:23 630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
10/2912015:23 79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
10/29/20 15:23 127-18-4
Toluene
NO
ug/L
0.50
1
10/29/20 15:23 108-88-3
1,2,3-Trichlorobenzene
NO
ug/L
2.0
1
10/29/20 15:23 87-61-6
1,2,4-Trichlorobenzene
NO
ug/L
2.0
1
10/29/20 15:23 120-82-1
1,1,1-Trichloroethane
NO
ug/L
0.50
1
10/2912015:23 71-55-6
1,1,2-Trichloroethane
ND
ug/L
0.50
1
1012912015:23 79-00-5
Trichloroethene
NO
ug/L
0.50
1
10/29/20 15:23 79-01-6
Trichlorofluoromethane
NO
ug/L
1.0
1
10/29/20 15:23 75-69-4
1,2,3-Trichloropropane
NO
ug/L
0.50
1
10/29/20 15:23 96-18-4
1,2,4-Trimethylbenzene
NO
ug/L
0.50
1
10/29/20 15:23 95-63-6
1,3,5-Trimethylbenzene
NO
ug/L
0.50
1
10/29/20 15:23 108-67-8
Vinyl chloride
ND
ug/L
1.0
1
10/29/20 15:23 75-01-4
m&p-Xylene
NO
ug/L
1.0
1
10/29/20 15:23 179601-23-1
o-Xylene
NO
ug/L
0.50
1
10/29/20 15:23 95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
101
%
70-130
1
10/29/20 15:23 17060-07-0
4-Bromofluorobenzene (S)
97
%
70-130
1
10/29/20 15:23 460-00-4
Toluene-d8 (S)
100
%
70-130
1
10/29/20 15:23 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 23

aceAnalXical
www.pacelabs.eom
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
Sample: MW-06R Lab ID: 92502026002 Collected: 10/23/20 15:20 Received: 10/23/20 16:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
10/28/20 15:17
Collected By
Mark
1
10/28/20 15:17
Swann
Collected Date
10/23/20
1
10/28/20 15:17
Collected Time
15:20
1
10/28/20 15:17
pH
5.0
Sid. Units
1
10/28/20 15:17
Temperature
21.4
deg C
1
10/28/20 15:17
Static Water Level
9.89
feet
1
10/28/20 15:17
Specific Conductance
234
umhos/cm
1
10/28/20 15:17
Odor
No odor
1
10/28/20 15:17
Appearance
Clear
1
10/28/20 15:17
6200E MSV
Analytical Method:
SM 6200B
Pace Analytical Services - Charlotte
Benzene
ND
ug/L
0.50
1
10/29/20 00:50 71-43-2
Bromobenzene
ND
ug/L
0,50
1
10/29/20 00:50 108-86-1
Bromochloromethane
ND
ug/L
0.50
1
10/29/20 00:50 74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
10/2912000:50 75-27-4
Bromoform
ND
ug/L
0.50
1
10/29/20 00:50 75-25-2
Bromomethane
ND
ug/L
5.0
1
10/29/20 00:50 74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
10/29/20 00:50 104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
10/29/20 00:50 135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
10/29/20 00:50 98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
10/29/20 00:50 56-23-5
Chlorobenzene
ND
ug/L
0.50
1
10/29/20 00:50 108-90-7
Chloroethane
ND
ug/L
1.0
1
10/29/20 00:50 75-00-3
Chloroform
ND
ug/L
0.50
1
10/29/20 00:50 67-66-3
Chloromethane
ND
ug/L
1.0
1
10129/2000:50 74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
10/29/20 00:50 95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
10/29/20 00:50 106-43-4
1,2-Dibromo-3-chloropropane
ND
ug/L
1.0
1
10/29/20 00:50 96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
10/29/20 00:50 124-48-1
1,2-Dibromoethane(EDB)
ND
ug/L
0.50
1
10/29/20 00:50 106-93-4
Dibromomethane
ND
ug/L
0.50
1
10/29/20 00:50 74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
10/29/20 00:50 95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
10/29/20 00:50 541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
10/29/20 00:50 106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
10129/2000:50 75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
10129/2000:50 75-34-3
1,2-Dichloroethane
ND
ug/L
0.50
1
10/29/20 00:50 107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
10/29/20 00:50 75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
10129/2000:50 156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
10/29/20 00:50 156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
10/29/20 00:50 78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
10/2912000:50 142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
10/29/20 00:50 594-20-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 23

(�';a?eAnalyticalo
www.pacalabsxom
ANALYTICAL RESULTS
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
Sample: MW-06R
Lab ID: 92502026002 Collected:
10/23/20 15:20
Received: 10/23/20 16:45 Matrix: Water
Parameters
Results
Units
Report Limit
OF
Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method:
SM 6200B
Pace Analytical
Services - Charlotte
1,1-Dichloropropene
ND
ug/L
0.50
1
10/29/20 00:50 563-58-6
cis-1,3-Dichloropropene
NO
ug/L
0.50
1
10/29/20 00:50 10061-01-5
trans-1,3-Dichloropropene
NO
ug/L
0.50
1
10/29/20 00:50 10061-02-6
Diisopropyl ether
NO
ug/L
0.50
1
10/29/20 00:50 108-20-3
Ethylbenzene
ND
ug/L
0.50
1
10/29/20 00:50 100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
10/29/20 00:50 87-68-3
Isopropylbenzene (Cumene)
NO
ug/L
0.50
1
10/29/20 00:50 98-82-8
Methylene Chloride
NO
ug/L
2.0
1
10/29/20 00:50 75-09-2
Methyl-tert-butyl ether
NO
ug/L
0.50
1
10/29/20 00:50 1634-04-4
Naphthalene
ND
ug/L
2.0
1
10129/2000:50 91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
10/29/20 00:50 103-65-1
Styrene
NO
ug/L
0.50
1
10/29/20 00:50 100-42-5
1,1,1,2-Tetrachloroethane
NO
ug/L
0.50
1
10/29/20 00:50 630-20-6
1,1,2,2-Tetrachloroethane
NO
ug/L
0.50
1
10/29/20 00:50 79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
10/29/20 00:50 127-18-4
Toluene
ND
ug/L
0.50
1
10/29/20 00:50 108-88-3
1,2,3-Trichlorobenzene
NO
ug/L
2.0
1
10/29/20 00:50 87-61-6
1,2,4-Trichlorobenzene
NO
ug/L
2.0
1
10/29/20 00:50 120-82-1
1,1,1-Trichloroethane
NO
ug/L
0.50
1
10/29/20 00:50 71-55-6
1,1,2-Trichloroethane
ND
ug/L
0.50
1
10/29/20 00:50 79-00-5
Trichloroethene
NO
ug/L
0.50
1
10/29/20 00:50 79-01-6
Trichlorofluoromethane
NO
ug/L
1.0
1
10/29/20 00:50 75-69-4
1,2,3-Trichloropropane
NO
ug/L
0.50
1
10/29/20 00:50 96-18-4
1,2,4-Trimethylbenzene
NO
ug/L
0.50
1
10/29/20 00:50 95-63-6
1,3,5-Trimethylbenzene
NO
ug/L
0.50
1
10/29/20 00:50 108-67-8
Vinyl chloride
ND
ug/L
1.0
1
10/29/20 00:50 75-01-4
m&p-Xylene
NO
ug/L
1.0
1
10/29/20 00:50 179601-23-1
o-Xylene
NO
ug/L
0.50
1
10/29/20 00:50 95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
101
%
70-130
1
10/29/20 00:50 17060-07-0
4-Bromofluorobenzene (S)
97
%
70-130
1
10/29/20 00:50 460-00-4
Toluene-d8 (S)
99
%
70-130
1
10/29/20 00:50 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 23

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
Sample: MW-07 Lab ID: 92602026003 Collected: 10/23/20 16:00 Received: 10123/2016:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
10/28/20 15:18
Collected By
Mark
1
10/28/20 15:18
Swann
Collected Date
10/23/20
1
10/28/20 15:18
Collected Time
16:05
1
10/28/20 15:18
pH
5.6
Sid. Units
1
10/28/20 15:18
Temperature
21.6
deg C
1
10/28/20 15:18
Static Water Level
10.83
feel
1
10/28/20 15:18
Specific Conductance
337
umhos/cm
1
10/28/20 15:18
Odor
No odor
1
10/28/20 15:18
Appearance
Clear
1
10/28/20 15:18
62008 MSV
Analytical Method:
SM 6200B
Pace Analytical Services - Charlotte
Benzene
NO
ug/L
0.50
1
10/29/20 01:08 71-43-2
Bromobenzene
ND
ug/L
0.50
1
10/29/2001:08 108-86-1
Bromochloromethane
ND
ug/L
0.50
1
10/29/20 01:08 74-97-5
Bromodichloromethane
NO
ug/L
0.50
1
10/29/20 01:08 75-27-4
Bromoform
ND
ug/L
0.50
1
10/29/20 01:08 75-25-2
Bromomethane
NO
ug/L
5.0
1
10/29/2001:08 74-83-9
n-Butylbenzene
NO
ug/L
0.50
1
10/29/20 01:08 104-51-8
sec-Butylbenzene
NO
ug/L
0.50
1
10/29/20 01:08 135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
10/29/20 01:08 98-06-6
Carbon tetrachloride
ND
ug/L
0.50
1
10/29/20 01:08 56-23-5
Chlorobenzene
ND
ug/L
0.50
1
10/29/20 01:08 108-90-7
Chloroethane
NO
ug/L
1.0
1
10/29/20 01:08 75-00-3
Chloroform
ND
ug/L
0.50
1
10/29/20 01:08 67-66-3
Chloromethane
NO
ug/L
1.0
1
10/29/20 01:08 74-87-3
2-Chlorotoluene
ND
ug/L
0.50
1
10/29/20 01:08 95-49-8
4-Chlorotoluene
NO
ug/L
0.50
1
10/29/20 01:08 106-43-4
1,2-Dibromo-3-chloropropane
NO
ug/L
1.0
1
10/29/20 01:08 96-12-8
Dibromochloromethane
ND
ug/L
0.50
1
10/29/20 01:08 124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
0.50
1
10/29/20 01:08 106-93-4
Dibromomethane
ND
ug/L
0.50
1
10/29/20 01:08 74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
10/29/20 01:08 95-50-1
1,3-Dichlorobenzene
NO
ug/L
0.50
1
10129/2001:08 541-73-1
1,4-Dichlorobenzene
ND
ug/L
0.50
1
10/29/20 01:08 106-46-7
Dichlorodifluoromethane
ND
ug/L
0.50
1
10/29/20 01:08 75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
10/29/20 01:08 75-34-3
1,2-Dichloroethane
NO
ug/L
0.50
1
10/29/20 01:08 107-06-2
1,1-Dichloroethene
NO
ug/L
0.50
1
10/29/20 01:08 75-35-4
cis-1,2-Dichloroethene
ND
ug/L
0.50
1
10/29/20 01:08 156-59-2
trans- l,2-Dichloroethene
ND
ug/L
0.50
1
10/29/20 01:08 156-60-5
1,2-Dichloropropane
NO
ug/L
0.50
1
10/29/20 01:08 78-87-5
1,3-Dichloropropane
NO
ug/L
0.50
1
10129/2001:08 142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
10/29/20 01:08 594-20-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, L-C. Page 8 of 23

aceAnalytical
Ww .pacelabsxcrn
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
Sample: MW-07 Lab ID: 92502026003 Collected: 10/23/20 16:00 Received: 10/23/20 16:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
1,1-Dichloropropene
ND
ug/L
0.50
1
10/29/20 01:08 563-58-6
cis- 1,3-Dichloropropene
NO
ug/L
0.50
1
10/29/20 01:08 10061-01-5
trans-1,3-Dichloropropene
NO
ug/L
0.50
1
10/29/20 01:08 10061-02-6
Diisopropyl ether
NO
ug/L
0.50
1
10/29/20 01:08 108-20-3
Ethylbenzene
ND
ug/L
0.50
1
10/29/20 01:08 100-41-4
Hexachloro-1,3-butadiene
ND
ug/L
2.0
1
10/29/20 01:08 87-68-3
Isopropylbenzene (Cumene)
NO
ug/L
0.50
1
10/29/20 01:08 98-82-8
Methylene Chloride
NO
ug/L
2.0
1
10/29/20 01:08 75-09-2
Methyl-tert-butyl ether
ND
ug/L
0.50
1
10/29/20 01:08 1634-04-4
Naphthalene
NO
ug/L
2.0
1
10/29/20 01:08 91-20-3
n-Propylbenzene
ND
ug/L
0.50
1
10/29/20 01:08 103-65-1
Styrene
ND
ug/L
0.50
1
10/29/20 01:08 100-42-5
1,1,1,2-Tetrachloroethane
NO
ug/L
0.50
1
10/29/20 01:08 630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
10/29/20 01:08 79-34-5
Tetrachloroethene
ND
ug/L
0.50
1
10/29/20 01:08 127-18-4
Toluene
NO
ug/L
0.50
1
10/29/20 01:08 108-88-3
1,2,3-Trichlorobenzene
NO
ug/L
2.0
1
10/29/20 01:08 87-61-6
1,2,4-Trichlorobenzene
ND
ug/L
2.0
1
10/29/20 01:08 120-82-1
1,1,1-Trichloroethane
NO
ug/L
0.50
1
10129/2001:08 71-55-6
1,1,2-Trichloroethane
NO
ug/L
0.50
1
10/29/20 01:08 79-00-5
Trichloroethene
ND
ug/L
0.50
1
10/29/20 01:08 79-01-6
Trichlorofluoromelhane
NO
ug/L
1.0
1
10/29/20 01:08 75-69-4
1,2,3-Trichloropropane
NO
ug/L
0.50
1
10/29/20 01:08 96-18-4
1,2,4-Trimethylbenzene
ND
ug/L
0.50
1
10/29/20 01:08 95-63-6
1,3,5-Trimethylbenzene
ND
ug/L
0.50
1
10/29/20 01:08 108-67-8
Vinyl chloride
NO
ug/L
1.0
1
10/29/20 01:08 75-01-4
m&p-Xylene
ND
ug/L
1.0
1
10/29/20 01:08 179601-23-1
o-Xylene
ND
ug/L
0.50
1
10/29/20 01:08 95-47-6
Surrogates
1,2-Dichloroethane-d4 (S)
99
%
70-130
1
10/29/20 01:08 17060-07-0
4-Bromofluorobenzene (S)
95
%
70-130
1
10/29/20 01:08 460-00-4
Toluene-d8 (S)
101
%
70-130
1
10/29/20 01:08 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC, Page 9 of 23

(�5?ceAnaljdicala
www.pacelabsxom
ANALYTICAL RESULTS
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
Sample: MW-U6R
Parameters
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Lab ID: 92602026004 Collected: 10/23/20 16:40 Received: 10/23/20 16:45 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical Services - Charlotte
Performed by
Pace
1
10/28/20 15:19
Collected By
Mark
1
10/28/20 15:19
Swann
Collected Date
10/23/20
1
10/28/20 15:19
Collected Time
16:40
1
10/28/20 15:19
pH
6.4
Sid. Units
1
10/28/20 15:19
Temperature
20.6
deg C
1
10/28/20 15:19
Static Water Level
10.21
feet
1
10/28/20 15:19
Specific Conductance
634
umhos/cm
1
10/28/20 15:19
Odor
No odor
1
10/28/20 15:19
Appearance
Clear
1
10/28/20 15:19
6200B MSV
Analytical Method:
SM 6200B
Pace Analytical Services - Charlotte
Benzene
NO
ug/L
0.50
1
10/29/20 01:26 71-43-2
Bromobenzene
ND
ug/L
0.50
1
10/29/20 01:26 108-86-1
Bromochloromethane
ND
ug/L
0.50
1
10/29/20 01:26 74-97-5
Bromodichloromethane
ND
ug/L
0.50
1
10/29/20 01:26 75-27-4
Bromoform
ND
ug/L
0.50
1
10/29/20 01:26 75-25-2
Bromomethane
ND
ug/L
5.0
1
10/29/20 01:26 74-83-9
n-Butylbenzene
ND
ug/L
0.50
1
10/29/20 01:26 104-51-8
sec-Butylbenzene
ND
ug/L
0.50
1
10/29/20 01:26 135-98-8
tert-Butylbenzene
ND
ug/L
0.50
1
10/29/20 01:26 98-06-6
Carbon tetrachloride
NO
ug/L
0.50
1
10/29/20 01:26 56-23-5
Chlorobenzene
ND
ug/L
0.50
1
10/29/20 01:26 108-90-7
Chloroethane
NO
ug/L
1.0
1
10/29/20 01:26 75-00-3
Chloroform
ND
ug/L
0.50
1
10/29/20 01:26 67-66-3
Chloromethane
NO
ug/L
1.0
1
10/29/20 01:26 74-87-3
2-Chlorotoluene
NO
ug/L
0.50
1
10/29/20 0126 95-49-8
4-Chlorotoluene
ND
ug/L
0.50
1
10/29/20 01:26 106-43-4
1,2-Dibromo-3-chloropropane
NO
ug/L
1.0
1
10/29/20 01:26 96-12-8
Dibromochloromethane
NO
ug/L
0.50
1
10/29/20 01:26 124-48-1
1,2-Dibromoethane(EDB)
ND
ug/L
0.50
1
10/2912001:26 106-93-4
Dibromomethane
ND
ug/L
0.50
1
10/29/20 01:26 74-95-3
1,2-Dichlorobenzene
ND
ug/L
0.50
1
10/29/20 01:26 95-50-1
1,3-Dichlorobenzene
ND
ug/L
0.50
1
10/29/20 01:26 541-73-1
1,4-Dichlorobenzene
NO
ug/L
0.50
1
10/29/20 01:26 106-46-7
DichlorodiFluoromethane
ND
ug/L
0.50
1
10/29/20 01:26 75-71-8
1,1-Dichloroethane
ND
ug/L
0.50
1
10/29/20 01:26 75-34-3
1,2-Dichloroethane
NO
ug/L
0.50
1
10/29/20 01:26 107-06-2
1,1-Dichloroethene
ND
ug/L
0.50
1
10/2912001:26 75-35-4
cis-1,2-Dichloroethene
NO
ug/L
0.50
1
10/29/20 01:26 156-59-2
trans-1,2-Dichloroethene
ND
ug/L
0.50
1
10/29/20 01:26 156-60-5
1,2-Dichloropropane
ND
ug/L
0.50
1
10/29/20 01:26 78-87-5
1,3-Dichloropropane
ND
ug/L
0.50
1
10/29/20 01:26 142-28-9
2,2-Dichloropropane
ND
ug/L
0.50
1
10/29/20 01:26 594-20-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 23

aceAnalytical s
Ww .pacelabsx m
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
-111V,V. ,.,..-wort Lab iD: 92502026004 Collected: 10/23/20 16:40 Received: 10/23/26 16:45 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua]
6200B MSV
Analytical Method: SM 6200B
Pace Analytical Services - Charlotte
1,1-Dichloropropene
NO
ug/L
0.50
1
10/29/20 01:26 563-58-6
cis-1,3-Dichloropropene
ND
ug/L
0.50
1
10129/2001:26 10061-01-5
trans- 1,3-Dichloropropene
NO
ug/L
0.50
1
10/29/20 01:26 10061-02-6
Diisopropyl ether
ND
ug /L
0.50
1
10/29/20 01:26 10
Ethylbenzene
Hexachloro-1,3-butadiene
NO
u/L
9
0.50
1
10/29/20 01:26 100--41-3
41-4
Isopropylbenzene (Cumene)
ND
NO
ug/L
ug/L
2.0
0.50
1
10/29/20 01:26 87-68-3
Methylene Chloride
NO
ug/L
2.0
1
10/29/20 01:26 98-82-8
Methyl-tert-butyl ether
ND
ug/L
1
10/29/20 01:26 75-09-2
Naphthalene
NO
ug/L
0.50
2.0
1
10/29/20 01:26 1634-04-4
n-Propylbenzene
ND
ug/L
0.50
1
10/29/20 01:26 91-20-3
Styrene
1
10/29/20 01:26 103-65-1
1,1,1,2-Tetrachloroethane
ND
NO
ug/L
ug/L
0.50
0.50
1
10/29/20 01:26 100-42-5
1,1,2,2-Tetrachloroethane
ND
ug/L
0.50
1
10/29/20 01:26 630-20-6
Tetrachloroethene
NO
1
10/29/20 01:26 79-34-5
Toluene
ug/L
0.50
1
10/29/20 01:26 127-18-4
1,2,3-Trichlorobenzene
ND
ND
ug/L
ug/L
0.50
1
10/29/20 01:26 108-88-3
1,2,4-Trichlorobenzene
ND
ug/L
2.0
1
10/29/20 01:26 87-61-6
1,1,1-Trichloroethane
ND
ug/L
2.0
0.50
1
10/29/20 01:26 120-82-1
1,1,2-Trichloroethane
ND
ug/L
1
10/29/20 01:26 71-55-6
Trichloroethene
NO
ug/L
0.50
0.50
1
10/29/20 01:26 79-00-5
Trichlorofluoromethane
ND
ug/L
1
10/29/20 01:26 79-01-6
1,2,3-Trichloropropane
ND
ug/L
1.0
0.50
1
1
10/29/20 01:26 75-69-4
1,2,4-Trimethylbenzene
NO
ug/L
0.50
1
10/29/20 01:26 96-18-4
1,3,5-Trimethylbenzene
ND
ug/L
10/29/20 01:26 95-63-6
Vinyl chloride
NO
ug/L
0.50
1
10/29/20 01:26 108-67-8
m&p-Xylene
ND
ug/L
1.0
1
10/29/20 01:26 75-01-4
o-Xylene
NO
ug/L
1.0
1
10/29/20 01:26 179601-23-1
Surrogates
0.50
1
10/29/20 01:26 95-47-6
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
10/29/20 01:26 17060-07-0
4-Bromofluorobenzene (S)
98
%
70-130
1
10/29/20 01:26 460-00-4
Toluene-d8 (S)
100
%
70-130
1
10/29/20 01:26 2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 23

�-aceAnalj4icalo
www.pacelabs.com
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
QC Batch: 576403 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200B MSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92502026002, 92502026003, 92502026004
METHOD BLANK: 3050399 Matrix: Water
Associated Lab Samples: 92502026002, 92502026003, 92502026004
Blank Reporting
Parameter Units Result Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
NO
0.50
10/29/20 00:33
1,1,1-Trichloroethane
ug/L
NO
0.50
10/29/20 00:33
1,1,2,2-Tetrachloroethane
ug/L
NO
0.50
10/29/20 00:33
1,1,2-Trichloroethane
ug/L
ND
0.50
10129/2000:33
1,1-Dichloroelhane
ug/L
NO
0.50
10/29/2000:33
1,1-Dichloroethene
ug/L
ND
0.50
10/29/20 00:33
1,1-Dichloropropene
ug/L
NO
0.50
10/29/20 00:33
1,2,3-Trichlorobenzene
ug/L
ND
2.0
10/29/20 00:33
1,2,3-Trichloropropane
ug/L
NO
0.50
10/29/20 00:33
1,2,4-Trichlorobenzene
ug/L
NO
2.0
10/29/20 00:33
1,2,4-Trimethylbenzene
ug/L
NO
0.50
10/29/20 00:33
1,2-Dibromo-3-chloropropane
ug/L
NO
1.0
1012912000:33
1,2-Dibromoethane(EDB)
ug/L
ND
0.50
10/29/20 00:33
1,2-Dichlorobenzene
ug/L
NO
0.50
10/29/20 00:33
1,2-Dichloroethane
ug/L
NO
0.50
10/29/20 00:33
1,2-Dichloropropane
ug/L
NO
0.50
10/29/20 00:33
1,3,5-Trimethylbenzene
ug/L
NO
0.50
10/29/20 00:33
1,3-Dichlorobenzene
ug/L
NO
0.50
10129/2000:33
1,3-Dichloropropane
ug/L
NO
0.50
10/29/20 00:33
1,4-Dichlorobenzene
ug/L
ND
0.50
10/29/20 00:33
2,2-Dichloropropane
ug/L
NO
0.50
10/29/20 00:33
2-Chlorotoluene
ug/L
NO
0.50
10/29/20 00:33
4-Chlorotoluene
ug/L
NO
0.50
1012912000:33
Benzene
ug/L
NO
0.50
10/29/20 00:33
Bromobenzene
ug/L
ND
0.50
10/29/20 00:33
Bromochloromethane
ug/L
ND
0.50
10/29/20 00:33
Bromodichloromethane
ug/L
NO
0.50
10/29/20 00:33
Bromoform
ug/L
NO
0.50
10/29/20 00:33
Bromomethane
ug/L
NO
5.0
10/29/20 00:33
Carbon tetrachloride
ug/L
ND
0.50
10/29/20 00:33
Chlorobenzene
ug/L
NO
0.50
10/29/20 00:33
Chloroethane
ug/L
NO
1.0
10/29/20 00:33
Chloroform
ug/L
NO
0.50
10/29/20 00:33
Chloromethane
ug/L
NO
1.0
10/29/20 00:33
cis-1,2-Dichloroethene
ug/L
ND
0.50
10/29/20 00:33
cis-1,3-Dichloropropene
ug/L
NO
0.50
10/29/20 00:33
Dibromochloromethane
ug/L
NO
0.50
10/29/20 00:33
Dibromomethane
ug/L
NO
0.50
10/29/20 00:33
Dichlorodifluoromethane
ug/L
NO
0.50
10/29/20 00:33
Diisopropyl ether
ug/L
ND
0.50
10/29/20 00:33
Qualifiers
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the resu It.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, U.C. Page 12 of 23

aceAnalytical w
www.pacelabs.com
Pace Analytical services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
METHOD BLANK: 3050399 Matrix:
Associated Lab Samples: 92502026002, 92502026003, 92502026004
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
Ethylbenzene
ug/L
NO
0.50
10/29/20 00:33
Hexachloro-1,3-butadiene
ug/L
ND
2.0
10/29/20 00:33
Isopropyibenzene (Cumene)
ug/L
ND
0.50
10/29/20 00:33
m&p-Xylene
ug/L
NO
1.0
10/29/20 00:33
Methyl-tert-butyl ether
ug/L
ND
0.50
10/29/20 00:33
Methylene Chloride
ug/L
ND
2.0
10/29/20 00:33
n-Butylbenzene
ug/L
ND
0.50
10/29/20 00:33
n-Propylbenzene
ug/L
ND
0.50
10/29/20 00:33
Naphthalene
ug/L
NO
2.0
10/29/20 00:33
o-Xylene
ug/L
ND
0.50
10/29/20 00:33
sec-Butylbenzene
ug/L
ND
0.50
10/29/20 00:33
Styrene
ug/L
NO
0.50
10/29/20 00:33
tert-Butylbenzene
ug/L
ND
0.50
10/29/20 00:33
Tetrachloroethene
ug/L
NO
0.50
10/29/20 00:33
Toluene
ug/L
NO
0.50
10/29/20 00:33
trans-1,2-Dich loroethene
ug/L
ND
0.50
10/29/20 00:33
trans-1,3-Dichloropropene
ug/L
NO
0.50
10/29/20 00:33
Trichloroethene
ug/L
ND
0.50
10/29/20 00:33
Trichlorofluoromethane
ug/L
ND
1.0
10129/2000:33
Vinyl chloride
ug/L
NO
1.0
10/29/20 00:33
1,2-Dichloroethane-d4 (S)
%
98
70-130
10/29/20 00:33
4-Bromofluorobenzene (S)
%
95
70-130
10/29/20 00:33
Toluene-d8 (S)
%
100
70-130
10/29/20 00:33
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3050400
Units
Spike
Conic.
LCS
Result
LCS
%Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
50
54.9
110
60-140
1,1,1-Trichloroethane
ug/L
50
52.2
104
60-140
1,1,2,2-Tetrachloroethane
ug/L
50
54.7
109
60-140
1,1,2-Trichloroethane
ug/L
50
53.3
107
60-140
1,1-Dichloroethane
ug/L
50
52.5
105
60-140
1,1-Dichloroethene
ug/L
50
53.9
108
60-140
1,1-Dichloropropene
ug/L
50
53.2
106
60-140
1,2,3-Trichlorobenzene
ug/L
50
57.2
114
60-140
1,2,3-Trichloropropane
ug/L
50
53.2
106
60-140
1,2,4-Trichlorobenzene
ug/L
50
58.1
116
60-140
1,2,4-Trimethylbenzene
ug/L
50
51.9
104
60-140
1,2-Dibromo-3-chloropropane
ug/L
50
61.4
123
60-140
1,2-Dibromoethane (EDB)
ug/L
50
56.2
112
60-140
1,2-Dichlorobenzene
ug/L
50
53.6
107
60-140
1,2-Dichloroethane
ug/L
50
48.0
96
60-140
1,2-Dichloropropane
ug/L
50
54.3
109
60-140
1,3,5-Trimethylbenzene
ug/L
50
53.1
106
60-140
Qualifiers
Results presented on this page are in the units indicated by tlse "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical services, L-C. Page 13 of 23

aceAnalytical
www.pacalabs,°°m
QUALITY
CONTROL
DATA
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
LABORATORY CONTROL SAMPLE:
3050400
Parameter
Units
Spike
Conc.
LCS
LCS
% Rec
1,3-Dichlorobenzene
Result
%Rec
Limits
1,3-Dichloropropane
ug/L
ug/L
50
.
539
10g
60-140
1,4-Dichlorobenzene
ug/L
50
55.7
- 111
60-140
2,2-Dichloropropane
ug/L
50
54.2
108
60-140
2-Chlorotoluene
ug/L
50
52.4
105
60-140
4-Chlorotoluene
ug/L
50
53.0
106
60-140
Benzene
ug/L
50
50
52.6
105
60-140
Bromobenzene
ug/L
52.9
106
60-140
Bromochloromethane
ug/L
50
52.2
104
60-140
Bromodichloromethane
ug/L
50
52.9
106
60-140
Bromoform
ug/L
50
53.2
106
60-140
Bromomethane
ug/L
50
53.1
106
60-140
Carbon tetrachloride
ug/L
50
55.5
111
60-140
Chlorobenzene
ug/L
50
51.5
103
60-140
Chloroethane
ug/L
50
53.4
107
60-140
Chloroform
ug/L
50
40.3
81
60-140
Chloromethane
ug/L
50
51.6
103
60-140
cis-1,2-Dichloroethene
ug/L
50
48.1
96
60-140
cis- 1,3-Dich loropropene
ug/L
50
51.4
103
60-140
Dibromochloromethane
ug/L
50
55.7
111
60-140
Dibromomethane
ug/L
50
57.4
115
60-140
Dichlorodifluoromethane
ug/L
50
56.4
113
60-140
Diisopropyl ether
ug/L
5 0
47.7
95
60-140
Ethylbenzene
ug/L
50
51.4
103
60-140
Hexachloro-1,3-buladiene
ug/L
50
51.9
104
60-140
Isopropylbenzene (Cumene)
50
53.5
107
60-140
m&p-Xylene
ug/L
ug/L -
50
54.6
109
60-140
Methyl-tert-butyl ether
ug/L
100
106
106
60-140
Methylene Chloride
ug/L
50
53.5
107
60-140
n-Butylbenzene
ug/L
50
50.8
102
60-140
n-Propylbenzene
ug/L
50
55.0
110
60-140
Naphthalene
ug/L
5 0
53.2
106
60-140
o-Xylene
ug/L
50
61.7
123
60-140
sec-Butylbenzene
ug/L
50
53.8
108
60-140
Styrene
ug/L
50
53.2
106
60-140
tert-Butylbenzene
50
54.8
110
60-140
Tetrachloroethene
ug L
50
45.7
91
60-140
Toluene
ug/L
50
50
53.6
107
60-140
trans-1,2-Dichloroethene
ug/L
52.5
105
60-140
transloroet ichloropropene
ug/L
50
53.6
107
60-140
Trichloroethene
ug/L
50
55.0
110
60-140
Trichlorofluoromethane
ug/L
80
54.1
108
60-140
Vinyl chloride
ug°/L
50
42.7
85
60-140
1,2-Dichloroethane-d4 (S)
50
46.5
93
60-140
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
102
70-130
99
70-130
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Qualifiers
Results presented on this page are in the units Indicated by the "Unit,' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
Date: 10/30/2020 03:42 PM This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 23

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3050401
MS
92502026004 Spike
Parameter Units Result Cone.
MSD
Spike
Cone.
3050402
MS
Result
MSD
Result
MS
% Rae
MSD
% Rae
% Rae
Limits
RPD Qua]
1,1,1,2-Tetrachloroethane
ug/L
NO
20
20
22.6
22.9
113
115
60-140
1
1,1,1-Trichloroethane
ug/L
ND
20
20
23.5
23.0
117
115
60-140
2
1,1,2,2-Tetrachloroethane
ug/L
NO
20
20
22.7
22.4
113
112
60-140
1
1,1,2-Trichloroethane
ug/L
NO
20
20
22.2
22.3
111
111
60-140
1
1,1-Dichloroethane
ug/L
ND
20
20
22.3
22.4
112
112
60-140
0
1,1-Dichloroethene
ug/L
NO
20
20
25.7
24.7
128
124
60-140
4
1,1-Dichloropropene
ug/L
NO
20
20
23.2
23.1
116
116
60-140
0
1,2,3-Trichlorobenzene
ug/L
ND
20
20
26.2
24.5
131
122
60-140
7
1,2,3-Trichloropropane
ug/L
ND
20
20
23.0
22.4
115
112
60-140
3
1,2,4-Trichlorobenzene
ug/L
ND
20
20
26.3
24.3
132
122
60-140
8
1,2,4-Trimethylbenzene
ug/L
ND
20
20
22.5
22.6
112
113
60-140
1
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20
25.4
25.7
127
128
60-140
1
1,2-Dibromoethane (EDB)
ug/L
NO
20
20
22.9
23.3
115
117
60-140
2
1,2-Dichlorobenzene
ug/L
ND
20
20
22.6
22.3
113
111
60-140
2
1,2-Dichloroethane
ug/L
ND
20
20
19.9
19.9
100
100
60-140
0
1,2-Dichloropropane
ug/L
ND
20
20
22.4
22.9
112
114
60-140
2
1,3,5-Trimethylbenzene
ug/L
NO
20
20
23.0
23.6
115
118
60-140
3
1,3-Dichlorobenzene
ug/L
NO
20
20
22.5
23.0
112
115
60-140
2
1,3-Dichloropropane
ug/L
ND
20
20
23.1
23.0
116
115
60-140
1
1,4-Dichlorobenzene
ug/L
NO
20
20
22.4
22.7
112
113
60-140
1
2,2-Dichloropropane
ug/L
NO
20
20
23.8
23.9
119
120
60-140
1
2-Chlorotoluene
ug/L
NO
20
20
23.0
23.7
115
118
60-140
3
4-Chlorotoluene
ug/L
ND
20
20
21.9
22.5
109
113
60-140
3
Benzene
ug/L
ND
20
20
22.7
22.6
113
113
60-140
0
Bromobenzene
ug/L
NO
20
20
22.2
22.8
111
114
60-140
3
Bromochloromethane
ug/L
ND
20
20
21.6
21.2
108
106
60-140
2
Bromodichloromethane
ug/L
ND
20
20
21.7
21.9
108
110
60-140
1
Bromoform
ug/L
NO
20
20
21.8
21.3
109
107
60-140
2
Bromomethane
ug/L
NO
20
20
25.9
26.6
130
133
60-140
2
Carbon tetrachloride
ug/L
ND
20
20
23.6
23.2
118
116
60-140
2
Chlorobenzene
ug/L
NO
20
20
22.6
22.8
113
114
60-140
1
Chloroethane
ug/L
NO
20
20
20.2
20.3
101
101
60-140
0
Chloroform
ug/L
NO
20
20
22.7
23.3
114
117
60-140
3
Chloromethane
ug/L
ND
20
20
21.2
21.0
106
105
60-140
1
cis-1,2-Dichloroethene
ug/L
ND
20
20
22.0
22.1
110
111
60-140
1
cis-1,3-Dichloropropene
ug/L
NO
20
20
23A
23.0
116
115
60-140
0
Dibromochloromethane
ug/L
ND
20
20
23.6
23.4
118
117
60-140
1
Dibromomethane
ug/L
NO
20
20
23.4
23.1
117
115
60-140
1
Dichlorodifluoromethane
ug/L
NO
20
20
20.0
20.0
100
100
60-140
0
Diisopropyl ether
ug/L
NO
20
20
21.4
21.6
107
108
60-140
1
Ethylbenzene
ug/L
ND
20
20
22.5
22.4
112
112
60-140
0
Hexachloro-1,3-butadiene
ug/L
ND
20
20
27.5
25.6
138
128
60-140
7
Isopropylbenzene (Cumene)
ug/L
NO
20
20
23.7
23.4
118
117
60-140
1
m&p-Xylene
ug/L
NO
40
40
45.7
44.7
114
112
60-140
2
Methyl-tert-butyl ether
ug/L
NO
20
20
22.0
21.7
110
108
60-140
1
Methylene Chloride
ug/L
NO
20
20
21.6
21.5
108
107
60-140
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC, Page 15 of 23

ace Analytical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3050401
MS MSD
92502026004 Spike Spike
Parameter Units Result Cone. Cone.
3050402
MS MSD MS MSD % Rae
Result Result % Rec % Red Limits RPD Qual
n-Butylbenzene
ug/L
ND
20
20
25.2
24.4
126
122
60-140 3
n-Propylbenzene
ug/L
ND
20
20
23.3
23.7
116
119
60-140 2
Naphthalene
ug/L
ND
20
20
26.5
25.1
132
125
60-140 5
o-Xylene
ug/L
ND
20
20
22.7
22.7
114
113
60-140 0
sec-Butylbenzene
ug/L
ND
20
20
23.9
24.1
119
121
60-140 1
Styrene
ug/L
NO
20
20
22.3
21.9
112
109
60-140 2
lert-Butylbenzene
ug/L
ND
20
20
20.1
20.6
101
103
60-140 2
Tetrachloroethene
ug/L
ND
20
20
23A
23.1
117
116
60-140 1
Toluene
ug/L
ND
20
20
22.3
22.3
111
111
60-140 0
trans-1,2-Dichloroethe ne
ug/L
NO
20
20
23.3
23.4
116
117
60-140 1
trans- 1,3-Dichloropropene
ug/L
ND
20
20
22.6
22.3
113
112
60-140 1
Trichloroethene
ug/L
ND
20
20
23.2
23.5
116
117
60-140 1
Trichlorofluoromethane
ug/L
ND
20
20
21.0
21.4
105
107
60-140 2
Vinyl chloride
ug/L
ND
20
20
20.8
21.0
104
105
60-140 1
1,2-Dichloroethane-d4 (S)
%
101
102
70-130
4-Bromofluorobenzene (S)
%
99
98
70-130
Toluene-d8(S)
%
99
100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, -I-C. Page 16 of 23

aceAnalytical
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
(828)254-717e
QUALITY CONTROL DATA
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
QC Batch: 576667 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Description: 6200E MSV
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92502026001
METHOD BLANK: 3051751
Associated Lab Samples: 92502026001
Parameter
Units
Matrix: Water
Blank Reporting
Result Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
0.50
10/29/20 11:48
1,1,1-Trichloroethane
ug/L
ND
0.50
10/29/20 11:48
1,1,2,2-Tetrachloroethane
ug/L
ND
0.50
10/29/20 11:48
1,1,2-Trichloroethane
ug/L
ND
0.50
10/2912011:48
1,1-Dichloroethane
ug/L
ND
0.50
10/2912011:48
1,1-Dichloroethene
ug/L
ND
0.50
10/29/20 11:48
1,1-Dichloropropene
ug/L
ND
0.50
10/2912011:48
1,2,3-Trichlorobenzene
ug/L
ND
2.0
10/29/20 11:48
1,2,3-Trichloropropane
ug/L
ND
0.50
10/29/20 11:48
1,2,4-Trichlorobenzene
ug/L
ND
2.0
10/29/20 11:48
1,2,4-Trimethylbenzene
ug/L
ND
0.50
10/29/20 11:48
1,2-Dibromo-3-chloropropane
ug/L
ND
1.0
10/29/20 11:48
1,2-Dibromoethane(EDB)
ug/L
ND
0.50
10/29/20 11:48
1,2-Dichlorobenzene
ug/L
NO
0.50
10/29/20 11:48
1,2-Dichloroethane
ug/L
ND
0.50
10/29/20 11:48
1,2-Dichloropropane
ug/L
ND
0.50
10/29/20 11:48
1,3,5-Trimethylbenzene
ug/L
ND
0.50
10/29/20 11:48
1,3-Dichlorobenzene
ug/L
ND
0.50
10/29/20 11:48
1,3-Dichloropropane
ug/L
ND
0.50
10/29/20 11:48
1,4-Dichlorobenzene
ug/L
ND
0.50
10/29/20 11:48
2,2-Dichloropropane
ug/L
ND
0.50
10/29/20 11:48
2-Chlorotoluene
ug/L
ND
0.50
10/29/20 11:48
4-Chlorotoluene
ug/L
ND
0.50
10/29/20 11:48
Benzene
ug/L
ND
0.50
10/29/20 11:48
Bromobenzene
ug/L
ND
0.50
10/29/20 11:48
Bromochloromethane
ug/L
ND
0.50
10/29/20 11:48
Bromodichloromethane
ug/L
ND
0.50
10/29/20 11:48
Bromoform
ug/L
ND
0.50
10/29/20 11:48
Bromomethane
ug/L
ND
5.0
10/29/20 11:48
Carbon tetrachloride
ug/L
ND
0.50
10/29/20 11:48
Chlorobenzene
ug/L
ND
0.50
10/29/20 11:48
Chloroethane
ug/L
ND
1.0
10/2912011:48
Chloroform
ug/L
ND
0.50
10/29/20 11:48
Chloromethane
ug/L
ND
1.0
10/29/20 11:48
cis- 1,2-Dichloroethene
ug/L
ND
0.50
10/2912011:48
cis- 1,3-Dichloropropene
ug/L
ND
0.50
10/29/20 11:48
Dibromochloromethane
ug/L
ND
0.50
10/29/20 11:48
Dibromomethane
ug/L
ND
0.50
10/2912011:48
Dich lorodifluoromelha ne
ug/L
ND
0.50
10/29/20 11:48
Diisopropyl ether
ug/L
ND
0.50
10/29/20 11:48
Qualifiers
Results presented on this page are In the units indicated by the "Units' column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Dale: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 23

aceAnalytical�
www.pacelabs.cem
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
METHOD BLANK: 3051751
Associated Lab Samples: 92502026001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
Ethylbenzene
ug/L
NO
0.50
10/29/20 11:48
Hexachloro-1,3-butadiene
ug/L
NO
2.0
10129/2011:48
Isopropylbenzene (Cumene)
ug/L
ND
0.50
10/29/20 11:48
m&p-Xylene
ug/L
ND
1.0
10/29/2011:48
Methyl-tert-butyl ether
ug/L
ND
0.50
10/29/20 11:48
Methylene Chloride
ug/L
NO
2.0
10/29/20 11:48
n-Butylbenzene
ug/L
NO
0.50
10129/2011:48
n-Propylbenzene
ug/L
NO
0.50
10129/2011:48
Naphthalene
ug/L
ND
2.0
10/29/20 11:48
o-Xylene
ug/L
ND
0.50
10/29/20 11:48
sec-Butylbenzene
ug/L
ND
0.50
10129/2011:48
Styrene
ug/L
NO
0.50
10/29/20 11:48
tert-Butylbenzene
ug/L
ND
0.50
10129/2011:48
Tetrachloroethene
ug/L
ND
0.50
10/29/20 11:48
Toluene
ug/L
ND
0.50
10/29/20 11:48
trans-1,2-Dich loroelhene
ug/L
ND
0.50
10/29/20 11:48
trans-1,3-Dichloropropene
ug/L
ND
0.50
10/29/20 11:48
Trichloroethene
ug/L
NO
0.50
10/29/20 11:48
Trichlorofluoromethane
ug/L
NO
1.0
10129/2011:48
Vinyl chloride
ug/L
ND
1.0
10/29/20 11:48
1,2-Dichloroethane-d4 (S)
%
101
70-130
10/29/20 11:48
4-Bromofluorobenzene (S)
%
95
70-130
10/29/20 11:48
Toluene-d8 (S)
%
101
70-130
10/29/20 11:48
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
3051752
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
50
51.9
104
60-140
1,1,1-Trichloroethane
ug/L
50
51.3
103
60-140
1,1,2,2-Tetrachloroethane
ug/L
50
50.1
100
60-140
1,1,2-Trichloroethane
ug/L
50
50.7
101
60-140
1,1-Dichloroethane
ug/L
50
50.7
101
60-140
1,1-Dichloroethene
ug/L
50
53.6
107
60-140
i,t-Dichloropropene
ug/L
50
50.4
101
60-140
1,2,3-Trichlorobenzene
ug/L
50
54.5
109
60-140
1,2,3-Trichloropropane
ug/L
50
50.7
101
60-140
1,2,4-Trichlorobenzene
ug/L
50
56.1
112
60-140
1,2,4-Trimethylbenzene
ug/L
50
51.4
103
60-140
1,2-Dibromo-3-chloropropane
ug/L
50
55.8
112
60-140
1,2-Dibromoethane (EDB)
ug/L
50
52.8
106
60-140
1,2-Dichlorobenzene
ug/L
50
51.9
104
60-140
1,2-Dichloroethane
ug/L
50
44.9
90
60-140
1,2-Dichloropropane
ug/L
50
50.9
102
60-140
1,3,5-Trimethylbenzene
ug/L
50
51.4
103
60-140
Qualifiers
Results presented on this page are in the units indicated by the "Units' column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 23

Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
(�';a'ce Analytical
wwer.pacelahs.com
QUALITY CONTROL DATA
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
LABORATORY CONTROL SAMPLE:
Parameter
3051752
Units
Spike
Conc.
LCS
Result
LCS
%Rec
% Rec
Limits
1,3-Dichlorobenzene
ug/L
50
52.3
105
60-140
1,3-Dichloropropane
ug/L
50
52.6
105
60-140
1,4-Dichlorobenzene
ug/L
50
52.1
104
60-140
2,2-Dichloropropane
ug/L
50
51.4
103
60-140
2-Chlorotoluene
ug/L
50
52.8
106
60-140
4-Chlorotoluene
ug/L
50
51.1
102
60-140
Benzene
ug/L
50
50.5
101
60-140
Bromobenzene
ug/L
50
50.3
101
60-140
Bromochloromethane
ug/L
50
49.4
99
60-140
Bromodichloromethane
ug/L
50
50.0
100
60-140
Bromoform
ug/L
50
50.8
102
60-140
Bromomethane
ug/L
50
60.8
122
60-140
Carbon tetrachloride
ug/L
50
49.2
98
60-140
Chlorobenzene
ug/L
50
51.2
102
60-140
Chloroethane
ug/L
50
39.9
80
60-140
Chloroform
ug/L
50
51.0
102
60-140
Chloromethane
ug/L
50
45.4
91
60-140
cis-1,2-Dichloroethene
ug/L
50
49.0
98
60-140
cis-1,3-Dichloropropene
ug/L
50
52.3
105
60-140
Dibromochloromelhane
ug/L
50
54.2
108
60-140
Dibromomethane
ug/L
50
52.0
104
60-140
Dichlorodifluoromethane
ug/L
50
44.6
89
60-140
Diisopropyl ether
ug/L
50
48.9
98
60-140
Ethylbenzene
ug/L
50
50.3
101
60-140
Hexachloro-1,3-butadiene
ug/L
50
52.6
105
60-140
Isopropylbenzene (Cumene)
ug/L
50
52.3
105
60-140
m&p-Xylene
ug/L
100
102
102
60-140
Methyl-tert-butyl ether
ug/L
50
50.4
101
60-140
Methylene Chloride
ug/L
50
49.1
98
60-140
n-Bulylbenzene
ug/L
50
54.5
109
60-140
n-Propylbenzene
ug/L
50
51.4
103
60-140
Naphthalene
ug/L
50
56.0
112
60-140
o-Xylene
ug/L
50
51.5
103
60-140
sec-Bulylbenzene
ug/L
50
52.1
104
60-140
Styrene
ug/L
50
52.3
105
60-140
tert-Butylbenzene
ug/L
50
44.2
88
60-140
Tetrachloroethene
ug/L
50
51.6
103
60-140
Toluene
ug/L
50
49.5
99
60-140
trans- 1,2-Dichloroethene
ug/L
50
51.6
103
60-140
trans-1,3-Dichloropropene
ug/L
50
51.6
103
60-140
Trichloroethene
ug/L
50
51.3
103
60-140
Trichlorofluoromethane
ug/L
50
43.6
87
60-140
Vinyl chloride
ug/L
50
45.7
91
60-140
1,2-Dichloroethane-d4 (S)
%
95
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
99
70-130
Qualifiers
Results presented on this page are In the units Ind tested by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 23

ace Analytical a
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3051753
MS
92501901001 Spike
Parameter Units Result Cone.
MSD
Spike
Cone.
3051754
MS
Result
MSD
Result
MS
%Rec
MSD
%Rec
%Rec
Limits
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
NO
2000
2000
2210
2250
110
112
60-140
2
1,1,1-Trichloroethane
ug/L
NO
2000
2000
2270
2330
114
117
60-140
2
1,1,2,2-Tetrachloroethane
ug/L
ND
2000
2000
2120
2110
106
106
60-140
0
1,1,2-Trichloroethane
ug/L
ND
2000
2000
2170
2220
109
111
60-140
2
1,1-Dichloroethane
ug/L
NO
2000
2000
2260
2290
113
115
60-140
2
1,1-Dichloroethene
ug/L
NO
2000
2000
2410
2450
121
122
60-140
2
1,1-Dichloropropene
ug/L
ND
2000
2000
2280
2340
114
117
60-140
3
1,2,3-Trichlorobenzene
ug/L
ND
2000
2000
1990
2250
100
112
60-140
12
1,2,3-Trichloropropane
ug/L
ND
2000
2000
2090
2110
105
106
60-140
1
1,2,4-Trichlorobenzene
ug/L
NO
2000
2000
2010
2220
100
111
60-140
10
1,2,4-Trimethylbenzene
ug/L
1050
2000
2000
3100
3480
102
122
60-140
12
1,2-Dibromo-3-chloropropane
ug/L
ND
2000
2000
2190
2210
109
111
60-140
1
1,2-Dibromoethane (EDB)
ug/L
ND
2000
2000
2250
2330
110
114
60-140
3
1,2-Dichlorobenzene
ug/L
ND
2000
2000
2080
2170
104
109
60-140
4
1,2-Dichloroethane
ug/L
NO
2000
2000
2030
2010
100
99
60-140
1
1,2-Dichloropropane
ug/L
NO
2000
2000
2250
2260
112
113
60-140
0
1,3,5-Trimethylbenzene
ug/L
ND
2000
2000
2430
2620
122
131
60-140
8
1,3-Dichlorobenzene
ug/L
ND
2000
2000
2060
2190
103
109
60-140
6
1,3-Dichloropropane
ug/L
ND
2000
2000
2260
2250
113
112
60-140
1
1,4-Dichlorobenzene
ug/L
ND
2000
2000
2060
2180
103
109
60-140
6
2,2-Dichloropropane
ug/L
ND
2000
2000
2060
2090
103
104
60-140
1
2-Chlorotoluene
ug/L
NO
2000
2000
2120
2290
106
114
60-140
7
4-Chlorotoluene
ug/L
NO
2000
2000
2080
2160
104
108
60-140
4
Benzene
ug/L
4380
2000
2000
6630
7840
113
173
60-140
17 M1
Bromobenzene
ug/L
ND
2000
2000
2120
2220
106
111
60-140
4
Bromochloromethane
ug/L
ND
2000
2000
2160
2180
108
109
60-140
1
Bromodichloromethane
ug/L
ND
2000
2000
2180
2140
109
107
60-140
2
Bromoform
ug/L
NO
2000
2000
1990
2030
99
101
60-140
2
Bromomethane
ug/L
NO
2000
2000
2240
2720
112
136
60-140
19
Carbon tetrachloride
ug/L
ND
2000
2000
2250
2300
112
115
60-140
2
Chlorobenzene
ug/L
ND
2000
2000
2210
2250
111
112
60-140
2
Chloroethane
ug/L
ND
2000
2000
1990
2060
99
103
60A40
3
Chloroform
ug/L
ND
2000
2000
2160
2250
107
111
60-140
4
Chloromethane
ug/L
NO
2000
2000
1860
1950
93
97
60-140
4
cis-1,2-Dichloroethene
ug/L
NO
2000
2000
2200
2170
110
108
60-140
2
cis-1,3-Dichloropropene
ug/L
NO
2000
2000
2200
2230
110
111
60-140
1
Dibromochloromethane
ug/L
ND
2000
2000
2160
2310
108
115
60-140
7
Dibromomelhane
ug/L
ND
2000
2000
2300
2270
115
114
60-140
1
Dichlorodifluoromethane
ug/L
ND
2000
2000
1900
1970
95
99
60-140
4
Diisopropyl ether
ug/L
NO
2000
2000
2180
2170
109
108
60-140
1
Ethylbenzene
ug/L
830
2000
2000
2970
3280
107
122
60-140
10
Hexachloro-1,3-butadiene
ug/L
ND
2000
2000
2030
2290
101
115
60-140
12
Isopropylbenzene (Cumene)
ug/L
ND
2000
2000
2270
2360
111
116
60-140
4
m&p-Xylene
ug/L
2960
4000
4000
7200
8110
106
129
60-140
12
Methyl-tert-butyl ether
ug/L
182
2000
2000
2340
2430
108
112
60-140
4
Methylene Chloride
ug/L
ND
2000
2000
2250
2280
107
109
60-140
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Dale: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 23

aceAnalytical
www.pacelabsxom
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
3051753
3051754
MS
MSD
92501901001
Spike
Spike
MS
MSD
MS
MSD
%Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
%Rec
%Rec
Limits
RPD Qual
n-Butylbenzene
ug/L
NO
2000
2000
2170
2360
108
118
60-140
8
n-Propylbenzene
ug/L
ND
2000
2000
2300
2460
115
123
60-140
7
Naphthalene
ug/L
371
2000
2000
2410
2660
102
114
60-140
10
o-Xylene
ug/L
1390
2000
2000
3570
3880
109
125
60-140
8
sec-Butylbenzene
ug/L
NO
2000
2000
2190
2330
109
116
60-140
6
Styrene
ug/L
NO
2000
2000
2140
2220
107
111
60-140
3
tert-Butylbenzene
ug/L
ND
2000
2000
1880
1990
94
99
60-140
6
Tetrachloroethene
ug/L
NO
2000
2000
2230
2270
112
113
60-140
2
Toluene
ug/L
8610
2000
2000
10800
13100
109
224
60-140
19 M7
trans-1,2-Dichloroethene
ug/L
ND
2000
2000
2270
2300
114
115
60-140
1
trans-1,3-Dichloropropene
ug/L
ND
2000
2000
2090
2140
105
107
60-140
2
Trichloroethene
ug/L
NO
2000
2000
2250
2340
112
117
60-140
4
Trichlorofluoromethane
ug/L
ND
2000
2000
2060
2140
103
107
60-140
4
Vinyl chloride
ug/L
NO
2000
2000
1990
2040
99
102
60-140
3
1,2-Dichloroethane-d4 (S)
%
106
103
70-130
4-Bromofluorobenzene (S)
%
99
98
70-130
Toluene-d8 (S)
%
98
98
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 23

aceAnalytical e
www.pacelabs.com
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALIFIERS
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
NO - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyle in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyle is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
INC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI - The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 10/30/2020 03:42 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 23

aceAnalytical
www.pacelabsxom
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: MONITORING WELL RESAMPLE102320
Pace Project No.: 92502026
Lab ID Sample ID QC Batch Method QC Batch Analytical Method
92502026001
MW-05
92602026002
MW-06R
92602026003
MW-07
92502026004
MW-08R
92502026001
MW-05
SM
6200B
576667
92502026002
MW-06R
SM
6200B
576403
92502026003
MW-07
SM
6200B
576403
92502026004
MW-08R
SM
6200B
576403
Date: 10/30/2020 03:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except In full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 23 of 23

{k\-
!m-
�
� �
e6
=
`\
(
/
CID
E
` tie
_
_
y-
00'Y
>*xz
Oil
!-,ll-=-
S`§!,,
d
!.
}\W3-
�§`
Tl
as
-
.

P
N
b
\Y
'�
(V/IJ)slr.In PzN '��duMa9wtl 1u 04-(I6'AI
U
elu mnnlPUPS IT'0:� P95fi
�V—I
lw onrnow_
No
Iv/Nj sle!^P;.NTs+.l��n,a9wV
51a5eI.I lw 04 C-VEa41
3
IC'fi'E'6i1.0521241N1
P P
4 �91
v
all+'L• N, c'o-C_ s
l
tneV-a/N-al:°ela
m
..4e1-'E/^d) olsicid alua,0l•.•.et-uds
j
lti/NI b�tl 5=9: 11aIKU:'V..n =L i^
W
.
a u
�_'--iv/nn cGdztl von v„��.�c�n
lw pt-JI9A
1'd/Tli £G%SienlVOCs
O
� (V/D11 L'H tlt7T l�u OYt1690
R
_
(:IJIIV/Pli OV41N sa4"ry'II°GSL�Itlf9Gltl£9V
(q %. Hdl y(,5%tl,aQwylw pSZSF'Jtl
'L 'p'
12%Hdl tlnStll,agm;,a;Ili5i9tl
''ry' �
o
I-IJI (tl/N)PTNa ix,dun ,g9wy'IwllSi-nf9V
C N
v+
A
_
12 % Hd11J !+%'IwN�a,ll i'IIL9V
O_
� O
o �
1-I]Iltl/IYI P2Na5Tldun Ja9•Ly sash t'n(9V
p �
Pan azasdull ss szelO Pa4.tn m-eplM-naUM
�
�'
si �
(�%J)IZt <iltl) HO^-N anSCld i��a21-GP.10
H]apzela lm 52i-ZVdB
O
w
p p
IZa HdI£ON41 alAsnll lu165%-NfdO
O
'K
(.(P)1'(, r H II LGSt'H �!Asnld lw Slt-£Pd9
-
Itl/I•IIP'n:a.:aldun Jllsald salll i-nid0
i
(d/III PT, --dun J{]Sald'Iw 091IS11e
Iwl.�l ca a,aain anixlalw os-n£da
`�' y F_

N
D
0
p
D m W
3
0,
m
m
3
`=
o
n
O
ow
c
N,
s
g
3_
90
'n
m
n
N
o_
o
O
0
N O
3 m A
m
N
3
m
c
o r m
o m r
O
r
o
�.
'�
z
z<[
i=
y
-0 C
0
O
<
o -'
fa 3 D
o
n Z
�
v
`D
a
m
z
0
O
m
Z
° o
m m 0
f
v
m Z O
a
¢
3
3
O
z
3
o
`"
m
c
N<
A
1D
9
;1 m
c
s'
i
m
i� T
N
A
m
M,
p
o:
O
d
o
A0
O
zZOf
v
.-,3
xr
({��j
3
-Di
mA
O _I
mN>-d
'moo°'
N
m
N
o
S
m
vz
a
<
AD
Z?
3
Ti -I
3
N
6
N
JIA J
6
N
N
z
N
C
O
_SS
p
ry
x
N'w
O
O
'11
N
N
O
=
Z
o
a
3
y
p
Z
n
©
c
m
0
-
O
.G.)
3
3
F
3
c
3
3
3
c
3
3
N
<
o
n
m
v
io
m
ro
m
c
io
m
m
f/1
N
A
N
r
r
o
v
>
m
o
-
a
�
a
o
o
z
m
v
z
z
a
0
o
t
O
00,
O
D
m
m
m
c
3¢'
m
m
o
o
m
O
Z
N w
o
c
0
01
0
p
z
a
m
F
m C
3
m 3
3
,2
`,
d
3
3
3
3
m
z
z
0 °'
o:
.v
m¢
m
o P
y
m
N
m
C
J
VNi J
J
O
(AID
N
A
J
T
J
N
O
C'
d
E 3 ry
N
p
Q
�
N
D
[
O N
W
ro
N
N
s
a
FP
EF
O
c
3
3
c
c
3<<
3
c
3
3 3
3
3
"
o
tv
U]
to
10
m
4] t0
l0
r
l
r
❑❑❑0m
m
p
m
=
o
�
9
V,>
y oA
<
N
O
n
a 2 T
<
<
0
O
�i
r
O
P
y
N
N
b
N
m
"O
O
0
013n
N
47
0
A
N
=
ry
o
f01 o r
N
N `mG
O
W
C
A :E -i
m
O
A
w
o
z
c
mm
A z
D
m
yz
m
m 0
z
O0
A
xm m
m
a
n
a
d°
p '-
m
$
N -zi
J
m w
o
O
o.
n
o
v
z z
?
®#
d
N
d
N
.Z
R
...{
O
0 ->I
Z p C
m
m m
m
D.�
¢
¢
❑®❑❑l9
>y�
S
poi
0
0
0
m
D
>
>
o
d m
m
Z
'�O z N
Z
(r1
0
m
ik
at at
x
�_
_
m
z
m¢
3
3
O
EF
c_
m a c
v
P
l
D Z
Z
l
0m
N
a
IC
N
m
9.
m
0
Z
o
O
00
4mi N
W
f�
r
H
O
O
W®
A
r
W
O
.N. >>
O
N
q z
C
3
NP
N
O
m
N
u
0
0
N
0
p
ui
z
o
C)
m
o
�
�
W
�
m
�
�03�.D�
ym
Elxg3
= m p r
m
0
0
Z
m
n
m
0

m
0
•O p f
w<
K
O*� N
g
O
m
m
m D
n G)
O�
o3
mm
C4
m
"
r
G)
n
Z.
m
N3
3
O
c G)m
z
D
N<z
m'm
z
3
m
D
T
2
y
a T
m
°' Z
u
v
m m 0
m
a
7J
m -I
5
cn
m
m
r
m
< A A
m
m
O
m
of
fl»
t1Di
O
z a O
F
-30
3
A
N
m
I�il ''O
O
o
n Z
d
Q
O W
ry
Q
N O -)
3
N
v
o
V A
o
w
o
0
0
0o
m- D
o
Q
o
3 0
A
v° Z.
O C
uo
z
0
u&
o
N
o
m 8
u<
,�,
o
w
o
z
o
a
o
;a D
3
=
a ao
c �z^.
m
n
g
n
-n
o
a
m
d
a
ro
Z
m
3
3
o
x
o
m
ET
m
n
n
❑
c
o
"F
C
m
C
C
m
m°
ro
�0
3-
m�'
?.
o
o
0
?
N=
33�a
r
r
a
w
o
-
3
�
a
3
_
o
ol
�
w
0
o
Z
m
3 3
O
O
O fO
2
O
'O
n
O
D
y
O
m
o m
N
y
.ZI
1
3�
m
m
c
c.
°'
m
m
O
D�
Z
Z
n°
n
m
O
m
3.
y
o
0
x
y
N-
N
y C
wo 3
C
3
C
Q
0
5
U°
d
C
3
C
3
C
3
C w
3 m
y
m
Z
Z
z
m
0
... o
o
0
0 0
o
y
=i
m
o. O
m 2
m
N
3
n
❑�
°j
N N O.
_
N
N
m
o
�i
•Y' 7 O
p
c
c 3
3
c
c
3
c
c
3
c
3 3
3
3
3
W
0
1
n
m
n
t0
.
n
r
I m
r'
r•
`r
f
!'
f
r'
f
r
n
-I
Z
Z
"Fo'm
•
❑❑❑©
m
m
m
31
w
zm
a
x
mN
r
3"m
v
.9
mO
zm
mz
G)
om
o r
y
o
0
v
p°
C1w y
A0
m0
yoF
O
nrN
p
c
zm
p
o
O°
n
m
Oo
d
m
n y
c
wm
o
0
O
a
A
z Z
❑�
n
u
N
m
m
z'
m
m
Z
x nD
O
A
3
3 3
3
a
❑❑❑
9
0g
o
Cp
m
y
n
n o.
¢
n
o
m
m
Z
0
it
# Yk
ik
y
_
Q
ry
Z
o
s
m
n 3
3
G)
s
C_
O
O
..
D
N
Gp
�O
N
3 p
m
0
Z
°
O
m m
T y y
w
®m
m
z
9
?
A
c
Z
°
A
=
Q
ry
G
w
m
�
S 0 y N
"
D°
».D
m
0 3 m
F-y
❑
or
� 0 r
�

DmD
mo
mmm
y
n O
N
o
myo
,
v
y
A m^ W
DNO
3
c
3
c
v
m
»°-
90
N
°
O
O
o
o
r
A
o
9. A
y
g r
D
z
z
V C
>
N
O
<
e�.
°
m3 D_
o
z
o„
v
Q
m
[z
3 o
O
C3
n
n o
m m O-
`<
v
d z W
o
Q
3
3
z
D
m
o
3
m
g z
o =
m
m
z
z n
Q
m
a
N
�.
W T
vf°i
o
0>
z
2
W
m
D
a
m 0
m
Q
A
m -I
m
>>
m
0
a
n
O
d
3 0
m
my
znO
F
AA
3
N
l
9
m
A0
m4
O3
m nmi
m
z
Ni
o
oo
m
p1 o
A
a
O
z
V A
O c
"D'
O
A
N
-lo
d
o
y z
n
<'
°
AD
VNi
o
O
N
m
T
N u O
N
I-
oz'
c z
o
°.
o A 3
F
v
o
J
-� -j
N
Q
w
p
m
A E
90
si
n
N
3
z
z
=
m
3(0
m
m
m
J
m
o
o
m
N
{
O
d
N
W
U
CQ
J
a
ti
o
m
�
-
o
N
O
3
0
O
oJ'
v
E;
J
N
a
o
0
Q
m
D
o
m°
m
n
m
Z
N
m
io
O
W
s
m
O
m
p1
D
c
1
9.
O
J o
m
<
°
0
O
u
,
m
m ,m„
o
°
`2
OL
CC N
o°
H C
3
C
32
C
0
m
0
0
0
0
0
0
0
!^ m
a
RI
Q O
J
J
p0
N
p
N
J
O
O
Q
m
J N O
O^
W
=
2
3
O
J
d N Q
N
N
➢
{
A N O
W
N
�
(m
N
W
N
Q
ry
FP 5 O
A
x
o
O
c
c 3
3
c
c
3
c
c
3
c
3 3
3
3
3
H
A
'
IC
IC 1°
�D
1°
10
(➢
10
lC
(➢
IC
t0 t0
f0
(O
(O
I
�
�
z
z
T
m
FP
❑OO©
m
o
o A"
O
zN➢O
➢ONOm
AmrO
W.
nz<
V
N
in
in
=
Q
v
o
m x m
°
m
mS
z
N
$ iO
O
m
G7
m
m
p o r
m
o
d
o
m y
J
z
a
2
m y
l
N
m
m
o
0 o D
o
N
D T
A
�p
v
N
N
O
n
3
c
'O
n
6
°
No
N
z
C
N N_
N
T p m
M
w
3
t�i
o
o
m
°• to D
�j
4 Q
-1
Z
° p ,z�
y
O
{
m
N
O
N
m
ry
C
O
O
p
N
A 0 2
°
6
O
n
Z
a O W
d
O
P
p m
m
3
0
v
w 3
y m=
c
o
V y
c
3
m N W
n
J
Q
O
a0
sk
N
N
a,
R
O
° c
3
3 3
3
Q
n
3
❑mom
z
N
m m
m
y
x
m
W
m
D>
n
°
r
m
Q
Q Q
Q
N
fn]
I7
J
J
S
J N
N
z
O
u
at x
at
x
m
o
m
Q 3
3
W
`m
d
n
l
J
o
F
n
O
m m
°o
o
z
o
a m N
o®
A
J
r
r
ut
o
m D>
-I
m
q i
m
v
C
N
O
M
z
7
N
J
i C
o
A0
H
o
p
mxv3ym
❑

o
w
(�
O
➢ m
n.
NO
O
N
n
<
'z 0.
=
m 3
0 o
O
m
n
m°^ o
g
m m
a
ZZ
o 3
Sc
T
D
_
,0
T
N
Z
_
N
S
3
0
o
a
N
10
n
Kl0
A
P
N
r
r
v
of
—
0
0
0
3
n
O
a
o
?
v
z
m
0
2
D
0
o
o
ry
O
2
'O
c
3
n
m
v
y
Q
Z
-°
0
c
°1
z
n°
o
�0
'*�
m
c
0°
N
N
O
C
C
C
C
N
N
N
N
Z
z
z°
0j
o
o
N 3
J 1Nn
J
J
O
p'3
p
N
y
A
N
T
OJ
U
J
N
O
N
m
v
N
W
s
W_
N
N
2
0
c c
3
3
c
c
3
c
c
3
c
3
3
3
3
3
-"
<
y
O
O
y
°
N
G7
m
m 0
D
w
°
Z
v
o
n
D
m
6
m
n
a
J
C
O
a
�
B
U
D
N N
N N
0 0
0 0
{
v
m
a
® m
o
A
n
m
O
C
,
�o
r
70
❑❑❑ El
m
m
N
o
3
3 o p
D z y
r
O
w
0.
z
0
o
9
m
w
e
m y
0
�
o c
a
y
T
o
n
2
N
02 0
0
m
m
c
m
3
m y w
a
_ z
>
O
Z O c
❑®❑QO1
p
m
-i y>
Or
m
x
A
2
N
m n
m
3
m
3
Z
G)
O
z
c
w
fO N
m o
D
f
o x
v
d
6
o
Z
c
9 m m
0
0
_
O
N N
N
M
~
0
O
m
0
z
co
N_
C
O
0
m
m
N

1
Y
N
to
U
—
ry.
N y
t
0
2�
I G'
6D yj
6
m
o
0
T
6
O
r O
T-�
0
P
N
U D
�
N
o
,
m
„ v
o m
---
9 !n
0
0 7
n
O
to
3
m
C.
rt
A
9
mb�m
N
r
A
/
N
\/