WQ0004268_Technical Memorandum_20160516

P.O. Box 129
Morrisville, NC 275
919-467-1239
SEALy. .;
11069
MAcCONNELL
& ASSOCIATES, P.C.
Technical Memorandum
1903 North Harrison Avenue
Suite 102
Cary, NC 27513
Fax [phone]
To: Distribution (Confidential) Date: May 16, 2016
Client: Sager Creek Vegetable Co. From: Gary S. MacConnell, P.E.
Subject: Lagoon Cleaning — Biosolids Project: No. A56201.10
Quality
Introduction
This Technical Memorandum addresses the biosolids/sludge quality in both the upper and lower
lagoons. Biosolids or sludge with domestic wastes are regulated on the Federal level by the
Environmental Protection Agency (EPA) under the: 40 CFR Part 503 - STANDARDS FOR
THE USE OR DISPOSAL OF SEWAGE SLUDGE. At the State level regulation is by the
North Carolina Department of Environmental Quality (NCDEQ). Regulations which relate to
biosolids and the closure of lagoons may be found in Title 15A NCAC 2L — CLASSIFICATION
AND WATER QUALITY STANDARDS APPLICABLE TO THE GROUNDWATERS OF
NORTH CAROLINA and Title 15A NCAC 2T — WASTE NOT DISCHARGED TO SURFACE
WATERS. In addition to these rules and regulations, the NCDEQ (formerly the North Carolina
Department of Environment and Natural Resources (NCDENR)) issued Guidelines for the
closure of Permitted Wastewater Ponds and Lagoons (see attached). The purpose of this
memorandum is not to rehash these documents but to concisely present the quality of the upper
and lower lagoon biosolids and how they relate to these documents.
Laboratory Analysis
Composite samples were collected from both the upper (small) lagoon and lower (large) lagoon
on March 29, 2016 and resampled for the Nitrogen series on May 5, 2016 (see attached). The
samples were collected from the upper lagoon using a pole with a cup around the edge of the
lagoon. Due to the gas bubbles in the lagoon, it was determined that entering the lagoon on a
john boat could be dangerous. Samples collected from the lower lagoon were taken from a john
boat using a sludge judge. In both cases multiple samples were mixed to form a composite
sample. The samples were tested for Toxicity Characteristic Leaching Procedure (TCLP), metals
and nutrients. No biological tests were taken as it was determined that some form of treatment
for pathogens and vector attraction reduction would possibly be needed at a later date.
1

Laboratory Results and Discussion
The TCLP test came back negative (passed) in all aspects for the lower lagoon. This is an
expensive test and was only done on the lower lagoon. It was believed that concentrations of
metals and organics would most likely be higher in the lower lagoon due to retention time. This
is important as this test essentially measures for hazardous and toxic compounds.
The metal analysis for both lagoons with respect to the regulations is presented on the following
page in Table 1. The good news is that the concentrations of metals are below the ceiling
concentrations (40 CFR 503) for all metals. The maximum cumulative loading as specified in
the 40 CFR 503 regulations for each metal is also shown, as well as the calculated mass of
biosolids which can be land applied based on the metal concentrations. Based on the biosolids
metal concentrations, metals will not be the limiting factor with respect to land application.
The "soils analysis" results from an agricultural soils laboratory are presented in Tables 2 and 3.
The results from the March 29, 2016 samples are presented in Table 2 and the results from the
May 5, 2016 sample are shown in Table 3. These analyses include nutrient concentrations. The
calculated plant available nitrogen values for the samples from the two lagoons are presented in
Table 4. Table 5 shows theoretical biosolids loadings based on various plant available nitrogen
(PAN) concentrations and PAN loadings. The shadowed area represents the range of PAN
concentrations based on this preliminary testing.
Summary
The following discussion points summarize this technical memorandum:
1. Based on initial laboratory testing the biosolids are not hazardous or toxic as they pass
the TCLP.
2. The biosolids metals concentrations are below the 40 CFR 503 ceiling concentrations for
metals.
3. Additional testing will need to be done for pathogens.
4. Land application or dedicated site disposal site will most likely be determined by PAN
concentration.
5. Additional laboratory testing will be required in conjunction with the closure plan and
closeout of the lagoon
2

5. Additional laboratory testing will be required in conjunction with the closure plan and
closeout of the lagoon
cc: Allen Mize
Tim Ruby
Andy Steffes
3

1UUIC 1• 1.31luaunua 1y1GIaa
Sample or Composite
Date
A11Q1JJs..
3/29/2016
Lw1u
Ceiling
Conc.
Max. Bulk
Application
Max. Land
Application
Max. Land
Application
Laboratory
Test
Pace
6010
Units
40CFR503
Units
40CFR503
Units
Sager Creek
Dry Wt.
Units
Sager Creek
Dry Wt.
Units
Lagoon
Large
Percent Solids
Parameters (mg/kg)
Arsenic
ND
75
mg/kg
41
kg/ha
N/A
N/A
Cadmium
ND
85
mg/kg
39
kg/ha
N/A
N/A
Copper
256
mg/kg
4,300
mg/kg
1,500
kg/ha
5,859
Mton/ha
2,613
ton/acre
Lead
44.4
mg/kg
840
mg/kg
300
kg/ha
6,757
Mton/ha
3,013
ton/acre
Mercury
0.11
mg/kg
57
mg/kg
17
kg/ha
154,545
Mton/ha
68,923
ton/acre
Molybdenum
34.5
mg/kg
75
mg/kg
N/A
kg/ha
N/A
N/A
Nickel
58.5
mg/kg
420
mg/kg
420
kg/ha
7,179
Mton/ha
3,202
ton/acre
Selenium
ND
100
mg/kg
100
kg/ha
N/A
N/A
Zinc
3,220
mg/kg
7,500
mg/kg
2,800
kg/ha
870
Mton/ha
388
ton/acre
Lagoon
Small
Percent Solids
Arsenic
ND
75
mg/kg
41
kg/ha
N/A
N/A
Cadmium
0.13
85
mg/kg
39
kg/ha
300,000
Mton/ha
133,792
ton/acre
Copper
17.5
mg/kg
4,300
mg/kg
1,500
kg/ha
85,714
Mton/ha
38,226
ton/acre
Lead
2.4
mg/kg
840
mg/kg
300
kg/ha
125,000
Mton/ha
55,747
ton/acre
Mercury
0.0033
mg/kg
57
mg/kg
17
kg/ha
5,151,515
Mton/ha
2,297,438
ton/acre
Molybdenum
2.5
mg/kg
75
mg/kg
N/A
kg/ha
N/A
N/A
Nickel
5.9
mg/kg
420
mg/kg
420
kg/ha
71,186
Mton/ha
31,747
ton/acre
Selenium
ND
100
mg/kg
100
kg/ha
N/A
N/A
Zinc
321
mg/kg
7,500
mg/kg
2,800
kg/ha
8,723
Mton/ha
3,890
ton/acre

Table 2: Residual Analysis Data Soils Test 3/29/2016
Sample or
Composite Date
3/29/2016
3/29/2016
Laboratory
Test
Waypoint
Soil Anal.
Waypoint
Soil Anal.
Units
Lagoon
Large
Small
Organic Matter
20.5
24.7
%
Magnesium
316
3
ppm
Calcium
1124
110
ppm
s
B
CD
m
V>
Sodium
519
6
ppm
pH
6.6
6.9
Acidity
0.9
0.0
meq/100g
C.E.C.
14.6
0.6
meq/100g
% Base Saturation
Potassium
22.1
5.1
Magnesium
18.0
4.2
%
Calcium
38.5
15.5
%
Sodium
15.5
4.3
%
Hydrogen
6.2
0.0
%
Sulfur
85
1
ppm
Zinc
29.6
0.7
ppm
Manganese
10
1
ppm
Iron
206
5.0
ppm
Copper
0.2
0.1
ppm
Boron
1.1
0.1
ppm
Potassium
1257
12
ppm
Total Phosphorus
218
2
ppm
TKN
N/A
N/A
Ammonia-
Nitrogen
N/A
N/A
Nitrate and Nitrite
N/A
N/A
5

Table 3: Residual Analysis Data Soils Test 5/5/2016
Parameters
Sample or
Composite Date
5/5/2016
5/5/2016
Laboratory
Test
Waypoint
Soil
Anal.
Waypoint
Soil
Anal.
Units
Lagoon
Large
Small
Organic Matter
46.9
29.3
Magnesium
666
463
ppm
Calcium
1657
1229
ppm
Sodium
751
722
ppm
pH
8.1
7.2
Acidity
0
0.0
meq/100g
C.E.C.
24.5
18.3
meq/100g
% Base Saturation
Potassum
30
28.3
Magnesium
22.7
21.1
Calcium
33.8
33.6
Sodium
13.3
17.2
%
Hydrogen
0.0
0.0
%
Sulfur
N/A
N/A
ppm •
Zinc
N/A
N/A
ppm
Manganese
N/A
N/A
ppm
Iron
N/A
N/A
ppm
Copper
N/A
N/A
ppm
Boron
N/A
N/A
ppm
Potassium
2870
2022
ppm
Total Phosphorus
557
386
ppm
TKN
29100
16800
ppm
Ammonia-
Nitrogen
57
91
ppm
Nitrate and Nitrite
2
N/R
ppm
6

Table 4: Calculation of Plant Available Nitrogen
Year 2016
Date Sampled 5/9/2016
Upper Lagoon
Mineralization Rate (%) 30%
Nitrate/Nitrite (mg/kg) 0.00
Ammonia (mg/kg) 91.00
TKN (mg/kg) 16,800.00
Plant Available Nitrogen
Lbs PAN/Dry Ton
Lower Lagoon
5,058.20 mg/kg
10.12
Mineralization Rate (%) 30%
Nitrate/Nitrite (mg/kg) 2.00
Ammonia (mg/kg) 57.00
TKN (mg/kg) 29,100.00
Plant Available Nitrogen
Lbs PAN/Dry Ton
8,743.40 mg/kg
17.49
Notes:
1. Equation used: PAN=((MR) x (TKN-Ammonia)) + (0.5 x Ammonia) + Nitrate +
Nitrite
7

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(*.2_eAnalytical
www pacelabs corn.
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
May 12, 2016
McConnell and Associates
1903 N. Harrison Avenue
Cary, NC 27513
RE: Project: McConnell and Associates
Pace Project No.: 92291795
Dear McConnell Associates:
Enclosed are the analytical results for sample(s) received by the laboratory on March 29, 2016. The
results relate only to the samples included in this report.
Analyses were performed at the Pace Analytical Services location indicated on the sample analyte
page for analysis unless otherwise footnoted.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
°_10,A• Ng --
Terri Page
[e-mail]
Project Manager
Enclosures
cc: McConnell and Associates
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical
www.pace/abs.com:
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
CERTIFICATIONS
Project: McConnell and Associates
Pace Project No.: 92291795
Ormond Beach Certification IDs
8 East Tower Circle, Ormond Beach, FL 32174
Alabama Certification #: 41320
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Missouri Certification #: 236
Montana Certification #: Cert 0074
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Nebraska Certification: NE-OS-28-14
Nevada Certification: FL NELAC Reciprocity
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FL01264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
TexasCertification: FL NELAC Reciprocity
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Virginia Environmental Certification #: 460165
Wyoming Certification: FL NELAC Reciprocity
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
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VirginiaNELAP Certification #: 460221
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
VirginiaNELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

7_,AelaceAnalylicar®
www.pace/abs.crorp
Pace Analytical Services, Inc.
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[phone]
SAMPLE ANALYTE COUNT
Project: McConnell and Associates
Pace Project No:: 92291795
Analytes
Lab ID Sample ID Method Analysts Reported .Laboratory
92291795001 SAGER CREEK LARGE LAGOON
92291795004 SAGER CREEK SMALL LAGOON
EPA 8081 SWB 8 PASI-C
EPA 8151 LJM 3 PASI-O
EPA 6010 CDF 8 PASI-A
EPA 6010 CDF 7 PASI-A
EPA 7470 HVK 1 PASI-A
EPA 7471 HVK 1 PASI-A
EPA 8260 GAW 14 PASI-C
ASTM D2974-87 KDF 1 PASI-C
EPA 1010 MLS 1 PASI-A
EPA 9034 AGS 1 PASI-O
EPA 9045 TEP 1 PASI-A
EPA 9012 BIP 1 PASI-O
EPA 6010 CDF 8 PASI-A
EPA 7471 HVK 1 PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceArelytical®
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
ANALYTICAL RESULTS
Project: McConnell and Associates
Pace Project No.: 92291795
Sample: SAGER CREEK LARGE
LAGOON
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters Results Units Report Limit DF Prepared Analyzed
Lab ID: 92291795001 Collected: 02/29/16 13:20 'Received: 03/29/16 17:00 Matrix: Solid
CAS No. Qual
8081 GCS Pesticides, TCLP
gamma-BHC (Lindane)
Chlordane (Technical)
Endrin
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Decachlorobiphenyl (S)
Tetrachloro-m-xylene (S)
8151 Chlorinate Herbicide TCLP
2,4-D
2,4,5-TP (Silvex)
Surrogates
2,4-DCAA (S)
6010 MET ICP
Arsenic
Cadmium
Copper
Lead
Molybdenum
Nickel
Selenium
Zinc
6010 MET ICP, TCLP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
7470 Mercury, TCLP
Mercury
7471 Mercury
Mercury
Date: 05/12/2016 03:20 PM
Analytical Method: EPA 8081 Preparation Method: EPA 3510
Leachate Method/Date: EPA 1311; 04/08/16 14:00
ND
ND
ND
ND
ND
ND
44
87
ug/L
ug/L
ug/L
ug/L
uglL
ug/L
0.50
3.0
0.50
0.50
1000
3.0
1
1
1
1
04/12/16 10:16 04/12/16 12:17 58-89-9
04/12/16 10:16 04/12/16 12:17 57-74-9
04/12/16 10:16 04/12/16 12:17 72-20-8
04/12/16 10:16 04/12/16 12:17 1024-57-3
04/12/16 10:16 04/12/16 12:17 72-43-5
04/12/16 10:16 04/12/16 12:17 8001-35-2
10-138 1 04/12/16 10:16 04/12/16 12:17 2051-24-3
10-110 1 04/12/16 10:16 04/12/16 12:17 877-09-8
Analytical Method: EPA 8151 Preparation Method: EPA 3510
ND
ND
76
mg/L
mg/L
Analytical Method: EPA 6010
ND mg/kg
ND mg/kg
256 mg/kg
44.4 mg/kg
34.5 mg/kg
58.5 mg/kg
ND mg/kg
3220 mg/kg
0.40 1 04/12/16 08:50 04/13/16 04:30 94-75-7
0.40 1 04/12/16 08:50 04/13/16 04:30 93-72-1
39-139 1 04/12/16 08:50 04/13/16 04:30 19719-28-9
Preparation Method: EPA 3050
30.6
3.1
15.3
15.3
15.3
15.3
30.6
30.6
04/01/16 20:00 04/04/16 17:02 7440-38-2
04/01/16 20:00 04/04/16 17:02 7440-43-9
04/01/16 20:00 04/04/16 17:02 7440-50-8
04/01/16 20:00 04/04/16 17:02 7439-92-1
04/01/16 20:00 04/04/16 17:02 7439-98-7
04/01/16 20:00 04/04/16 17:02 7440-02-0
04/01/16 20:00 04/04/16 17:02 7782-49-2
04/01/16 20:00 04/04/16 17:02 7440-66-6
Analytical Method: EPA 6010 Preparation Method: EPA 3010A
Leachate Method/Date: EPA 1311; 04/02/16 05:30 Initial pH: 7.8; Final pH: 5.1
ND
ND
ND
ND
ND
ND
ND
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Analytical Method: EPA 7470
0.050
0.25
0.0050
0.025
0.025
0.10
0.025
04/05/16 02:20
04/05/16 02:20
04/05/16 02:20
04/05/16 02:20
04/05/16 02:20
04/05/16 02:20
04/05/16 02:20
Preparation Method: EPA 7470
04/05/16 13:09
04/05/16 13:09
04/05/16 13:09
04/05/16 13:09
04/05/16 13:09
04/05/16 13:09
04/05/16 13:09
Leachate Method/Date: EPA 1311; 04/02/16 05:30 Initial pH: 7.8; Final pH: 5.1
ND mg/L
Analytical Method: EPA 7471
0.11 mg/kg
H3
H2,H3
H2,H3
7440-38-2 H2
7440-39-3 H2
7440-43-9 H2
7440-47-3 H2
7439-92-1 H2
7782-49-2 H2
7440-22-4 . H2
0.00020 1 04/05/16 13:30 04/05/16 16:45 7439-97-6
Preparation Method: EPA 7471
0.087 1 04/05/16 15:20 04/05/16 17:21 7439-97-6
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..
H2
H3,M1,
R1

aceAnalytical
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Pace Analytical Services, Inc.
6701 Conference Drive
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[phone]
ANALYTICAL RESULTS
Project: McConnell and Associates
Pace Project No.: 92291795
Sample: SAGER CREEK LARGE
LAGOON
Results reported on a "dry weight" basis and are adjusted for percent moisture, sample size and any dilutions.
Parameters
Results Units Report Limit DF Prepared Analyzed
Lab ID: 92291795001 Collected: 02/29/16 13:20 Received: 03/29/16 17:00 Matrix: Solid
CAS No. Qual
8260 MSV TCLP
Benzene
2-Butanone (MEK)
Carbon tetrachloride
Chlorobenzene
Chloroform
1,4-Dichlorobenzene
1,2-Dichloroethane
1,1-Dichloroethene
Tetrachloroethene
Trichloroethene
Vinyl chloride
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4-Bromofluorobenzene (S)
Percent Moisture
Percent Moisture
1010 Flashpoint,Closed Cup
Flashpoint
9034 Sulfide
Sulfide
9045 pH Soil
pH at 25 Degrees C
9012 Cyanide, Total
Cyanide
Analytical Method: EPA 8260
Leachate Method/Date: EPA 1311; 04/04/16 11:52
ND ug/L 100 20
ND ug/L 200 20
ND ug/L 100 20
ND ug/L 100 20
ND ug/L 100 20
ND ug/L 100 20
ND ug/L 100 20
ND ug/L 100 20
ND ug/L 100 20
ND ug/L 100 20
ND ug/L 100 20
96 % 70-130 20
100 % 67-135 20
99 % 70-130 20
Analytical Method: ASTM D2974-87
97.5 % 0.10 1
Analytical Method: EPA 1010
>200 deg F 70.0 1
Analytical Method: EPA 9034 Preparation Method: EPA 9030A
ND mg/kg
Analytical Method: EPA 9045
7.1 Std. Units
04/06/16 21:11 71-43-2
04/06/16 21:11 78-93-3
04/06/16 21:11 56-23-5
04/06/16 21:11 108-90-7
04/06/16 21:11 67-66-3
04/06/16 21:11 106-46-7
04/06/16 21:11 107-06-2
04/06/16 21:11 75-35-4
04/06/16 21:11 127-18-4
04/06/16 21:11 79-01-6
04/06/16 21:11 75-01-4
04/06/16 21:11 17060-07-0
04/06/16 21:11 2037-26-5
04/06/16 21:11 460-00-4
04/01/16 06:46
04/03/16 12:20
1190 1 04/04/16 14:00 04/04/16 14:10 18496-25-8
0.10 1
Analytical Method: EPA 9012 Preparation Method: EPA 9012
ND mg/kg
04/01/16 15:00
9.2 1 04/13/16 11:55 04/13/16 15:25 57-12-5
H3
H3
H6
H3
Sample: SAGER CREEK SMALL
LAGOON
Results reported on a "wet -weight" basis
Parameters Results
Lab ID: 92291795004 Collected: 03/29/16 13:20 Received: 03/29/16 17:00 Matrix: Solid
Units
Report Limit DF Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Arsenic
Cadmium
Copper
Lead
Molybdenum
Nickel
Date: 05/12/2016 03:20 PM
Analytical Method: EPA 6010 Preparation Method: EPA 3050
ND mg/kg
0.13 mg/kg
17.5 mg/kg
2.4 mg/kg
2.5 mg/kg
5.9 mg/kg
0.83 1
0.083 1
0.42 1
0.42 1
0.42 1
0.42 1
04/04/16 21:00
04/04/16 21:00
04/04/16 21:00
04/04/16 21:00
04/04/16 21:00
04/04/16 21:00
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
04/05/16 19:13 7440-38-2
04/05/16 19:13 7440-43=9
04/05/16 19:13 7440-50-8
04/05/16 19:13 7439-92-1
04/05/16 19:13 7439-98-7
04/05/16 19:13 7440-02-0

1 GaceAnalytical
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Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
ANALYTICAL RESULTS
Project: McConnell and Associates
Pace Project No.: 92291795
Sample: SAGER CREEK SMALL Lab ID: 92291795004 Collected: 03/29/16 13:20 Received: 03/29/16 17:00 Matrix: Solid
LAGOON
Results reported on a "wet -weight" basis
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010 Preparation Method: EPA 3050
Selenium ND mg/kg 0.83 1 04/04/16 21:00 04/05/16 19:13 7782-49-2
Zinc 321 mg/kg 0.83 1 04/04/16 21:00 04/05/16 19:13 7440-66-6
7471 Mercury Analytical Method: EPA 7471 Preparation Method: EPA 7471
Mercury 0.0033 mg/kg 0.0028 1 04/06/16 15:10 04/06/16 19:05 7439-97-6
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical®
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Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
QC Batch: MERP/9203
QC Batch Method: EPA 7470
Associated Lab Samples: 92291795001
Analysis Method:
Analysis Description:
EPA 7470
7470 Mercury TCLP
METHOD BLANK: 1701931 Matrix: Water
Associated Lab Samples: 92291795001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury mg/L ND 0.00020 04/05/16 16:02
LABORATORY CONTROL. SAMPLE: 1701932
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury mg/L .0025 0.0025 99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1701933 1701934
MS MSD
92291659001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury
mg/L ND .0025 .0025 0.0027 0.0027 106 107 75-125 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical
www.pacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
QC Batch: MERP/9185 Analysis Method: EPA 7471
QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury
Associated Lab Samples: 92291795001
METHOD BLANK: 1699992 Matrix: Solid
Associated Lab Samples: 92291795001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury mg/kg ND 0.0040 04/05/16 17:16
LABORATORY CONTROL SAMPLE: 1699993
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Mercury mg/kg .067 0.068 102 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1699994 1699995
MS MSD
92291795001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result 'AD Rec % Rec Limits RPD Qual
Mercury
mg/kg 0.11 1.4 1.1 1.2 0.80 79 65 75-125 41 H3,M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical
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Pace Analytical Services, Inc.
6701 Conference.Drive
Raleigh,NC 27607
[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
QC Batch: MERP/9201 Analysis Method: EPA 7471
QC Batch Method: EPA 7471 Analysis Description: 7471 Mercury
Associated Lab Samples: 92291795004
METHOD BLANK: 1701831 Matrix: Solid
Associated Lab Samples: 92291795004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Mercury mg/kg ND 0.0040 04/06/16 18:29
LABORATORY CONTROL SAMPLE: 1701832
Parameter
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
Mercury mg/kg .067 0.066 99 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1701836 1701837
MS MSD
92292048001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Mercury
mg/kg ND .069 .07 0.068 0.070 97 99 75-125 3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical ®.
www.pacelabs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
QC Batch: MPRP/21206 Analysis Method: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET
Associated Lab Samples: 92291795001
METHOD BLANK: 1700397 Matrix: Solid
Associated Lab Samples: 92291795001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Arsenic mg/kg ND 1.0 04/04/16 16:06
Cadmium mg/kg ND 0.10 04/04/16 16:06
Copper mg/kg ND 0.50 04/04/16 16:06
Lead mg/kg ND 0.50 04/04/16 16:06
Molybdenum mg/kg ND 0.50 04/04/16 16:06
Nickel mg/kg ND 0.50 04/04/16 16:06
Selenium mg/kg ND 1.0 04/04/16 16:06
Zinc mg/kg ND 1.0 04/04/16 16:06
LABORATORY CONTROL SAMPLE: 1700398
Parameter
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
Arsenic mg/kg 50 47.0 94 80-120
Cadmium mg/kg 50 51.8 104 80-120
Copper mg/kg 50 52.9 106 80-120
Lead mg/kg 50 50.3 101 80-120
Molybdenum mg/kg 50 49.7 99 80-120
Nickel mg/kg 50 51.8 104 80-120
Selenium mg/kg 50 50.6 101 80-120
Zinc mg/kg 50 50.6 101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1700399 1700400
MS MSD
92291687001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Arsenic mg/kg ND 53 74.2 52.4 72.4 98 97 75-125 32 R1
Cadmium mg/kg ND 53 74.2 55.5 77.2 105 104 75-125 33 R1
Copper mg/kg 1.4 53 74.2 58.3 80.1 107 106 75-125 32 R1
Lead mg/kg ND 53 74.2 52.9 73.4 99 99 75-125 32 R1
Molybdenum mg/kg ND 53 74.2 50.1 72.6 94 98 75-125 37 R1
Nickel mg/kg ND 53 74.2 55.9 76.7 105 103 75-125 31 R1
Selenium mg/kg ND 53 74.2 60.9 82.4 114 110 75-125 30 R1
Zinc mg/kg 8.4 53 74.2 60.2 81.5 98 99 75-125 30 R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical
www.pacelabs com.
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
QC Batch: MPRP/21238 Analysis Method:: EPA 6010
QC Batch Method: EPA 3050 Analysis Description: 6010 MET
Associated Lab Samples: 92291795004
METHOD BLANK: 1701361 Matrix: Solid
Associated Lab Samples: 92291795004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Arsenic mg/kg ND 1.0 04/05/16 18:46
Cadmium mg/kg ND 0.10 04/05/16 18:46
Copper mg/kg ND . 0.50 04/05/16 18:46
Lead mg/kg ND 0.50 04/05/16 18:46
Molybdenum mg/kg ND 0.50 04/05/16 18:46
Nickel mg/kg ND 0.50 04/05/16 18:46
Selenium mg/kg ND 1.0 04/05/16 18:46
Zinc mg/kg ND 1.0 04/05/16 18:46
LABORATORY CONTROL SAMPLE: 1701362
Parameter
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
Arsenic mg/kg 50 50.5 101 80-120
Cadmium mg/kg 50 52.2 104 80-120
Copper mg/kg 50 52.1 104 80-120
Lead mg/kg 50 52.0 104 80-120
Molybdenum mg/kg 50 50.5 101 80-120
Nickel mg/kg 50 52.5 105 80-120
Selenium mg/kg 50 50.9 102 80-120
Zinc mg/kg 50 53.2 106 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1701363 1701364
MS MSD
92292023001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual.
Arsenic mg/kg ND 50.6 70.5 52.3 73.0 103 104 75-125 33 R1
Cadmium mg/kg ND 50.6 70.5 52.9 73.9 105 105 75-125 33 R1
Copper mg/kg 1.9 50.6 70.5 54.6 76.4 104 106 75-125 - 33 R1
Lead mg/kg ND 50.6 70.5 52.6 72.6 103 102 75-125 32 R1
Molybdenum mg/kg ND 50.6 70.5 50.3 69.7 99 99 75-125 32 R1
Nickel mg/kg ND 50.6 70.5 53.4 74.0 105 105 75-125 32 R1
Selenium mg/kg ND 50.6 70.5 55.6 78.2 109 110 75-125 34 R1
Zinc mg/kg 9.6 50.6 70.5 63.7 83.9 107 105 75-125 27 R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical
www.pacelabs.corn.
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
QC Batch: MPRP/21241 Analysis Method: EPA 6010
QC Batch Method: EPA 3010A Analysis Description: 6010 MET TCLP
Associated Lab Samples: 92291795001
METHOD BLANK: 1701563 Matrix: Water
Associated Lab Samples: 92291795001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Arsenic mg/L ND 0.050 04/05/16 12:05
Barium mg/L ND 0.25 04/05/16 12:05
Cadmium mg/L ND 0.0050 04/05/16 12:05
Chromium mg/L ND 0.025 04/05/16 12:05
Lead mg/L ND 0.025 04/05/16 12:05
Selenium mg/L ND 0.10 04/05/16 12:05
Silver mg/L ND 0.025 04/05/16 12:05
LABORATORY CONTROL SAMPLE: 1701564
Parameter
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
Arsenic mg/L 2.5 2.7 109 80-120
Barium mg/L 2.5 2.6 104 80-120
Cadmium mg/L 2.5 2.7 107 80-120
Chromium mg/L 2.5 2.7 107 80-120
Lead mg/L 2.5 2.5 101 80-120
Selenium mg/L 2.5 2.8 110 80-120
Silver mg/L 1.2 1.2 98 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1701565 1701566
MS MSD
92291659001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Arsenic mg/L ND 2.5 2.5 2.9 2.8 116 113 75-125 2
Barium mg/L ND 2.5 2.5 2.9 2.8 111 107 75-125 4
Cadmium mg/L ND 2.5 2.5 2.9 2.8 115 112 75-125 2
Chromium mg/L ND 2.5 2.5 2.9 2.8 114 111 75-125 3
Lead mg/L ND 2.5 2.5 2.7 2.7 109 106 75-125 3
Selenium mg/L ND 2.5 2.5 3.0 -2.9 119 116 75-125 3
Silver mg/L ND 1.2 1.2 1:3 1.3 106 103 75-125 4
Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..

aceAnalytical
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Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
QC Batch: MSV/36273
QC Batch Method: EPA 8260
Associated Lab Samples: 92291795001
Analysis Method:
Analysis Description:
EPA 8260
8260 MSV TCLP
METHOD BLANK: 1703373 Matrix: Water
Associated Lab Samples: 92291795001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
1,1-Dichloroethene ug/L ND 5.0 04/06/16 20:03
1,2-Dichloroethane ug/L ND 5.0 04/06/16 20:03
1,4-Dichlorobenzene ug/L ND 5.0 04/06/16 20:03
2-Butanone (MEK) ug/L ND 10.0 04/06/16 20:03
Benzene ug/L ND 5.0 04/06/16 20:03
Carbon tetrachloride ug/L ND 5.0 04/06/16 20:03
Chlorobenzene ug/L ND 5.0 04/06/16 20:03
Chloroform ug/L ND 5.0 04/06/16 20:03
Tetrachloroethene ug/L ND 5.0 04/06/16 20:03
Trichloroethene ug/L ND 5.0 04/06/16 20:03
Vinyl chloride ug/L ND 5.0 04/06/16 20:03
1,2-Dichloroethane-d4 (S) % 96 70-130 04/06/16 20:03
4-Bromofluorobenzene (S) % 102 70-130 04/06/16 20:03
Toluene-d8 (S) % 98 67-135 04/06/16 20:03
LABORATORY CONTROL SAMPLE: 1703374
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,1-Dichloroethene ug/L 50 46.1 92 66-135
1,2-Dichloroethane ug/L 50 44.1 88 67-128
1,4-Dichlorobenzene ug/L 50 46.4 93 78-130
2-Butanone (MEK) ug/L 100 94.4 94 61-144
Benzene ug/L 50 46.4 93 80-125
Carbon tetrachloride ug/L 50 47.9 96 69-131
Chlorobenzene ug/L 50 46.9 94 81-122
Chloroform ug/L 50 44.3 89 73-127
Tetrachloroethene ug/L 50 46.0 92 78-122
Trichloroethene ug/L 50 44.4 89 78-122
Vinyl chloride ug/L 50 46.1 92 58-137
1,2-Dichloroethane-d4(S) e/a 96 70-130
4-Bromofluorobenzene (S) % 98 70-130
Toluene-d8 (S) % 99 67-135
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1703377 1703378
MS MSD
92292213001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
1,1-Dichloroethene
ug/L ND 20 20 19.7 17.1 98 85 70-150 14
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalyfical
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Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1703377 1703378
MS MSD
92292213001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
1,2-Dichloroethane ug/L ND 20 20 20.8 18.6 104 93 70-150 11
1,4-Dichlorobenzene ug/L ND 20 20 12.9 12.8 64 64 70-150 1 M1
2-Butanone (MEK) ug/L ND 40 40 45.0 40.1 113 100 70-150 12
Benzene ug/L ND 20 20 17.9 15.9 90 80 70-150 12
Carbon. tetrachloride ug/L ND 20 20 19.2 17.5 96 87 70-150 10
Chlorobenzene ug/L ND 20 20 15.1 13.9 76 70 70-150 8
Chloroform ug/L ND 20 20 21.3 18.3 106 91 70-150 15
Tetrachloroethene ug/L ND 20 20 16.0 15.4 80 77 70-150 3
Trichloroethene ug/L ND 20 20 16.6 15.1 83 76 70-150 9
Vinyl chloride ug/L ND 20 20 20.9 18.4 105 92 70-150 13
1,2-Dichloroethane-d4 (S) % 98 96 70-130
4-Bromofluorobenzene (S) % 97 103 70-130
Toluene-d8 (S) % 100 97 67-135
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, Inc..

aceAnalytical
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Pace Analytical Services, Inc.
6701 Conference Drive
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[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
QC Batch: OEXT/41893 Analysis Method: EPA 8081
QC Batch Method: EPA 3510 Analysis Description: 8081 GCS TCLP Pesticides
Associated Lab Samples: 92291795001
METHOD BLANK: 1707402 . Matrix: Water
Associated Lab Samples: 92291795001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Chlordane (Technical) ug/L ND 3.0 04/12/16 12:35
Endrin ug/L ND 0.50 04/12/16 12:35
gamma-BHC (Lindane) ug/L ND 0.50 04/12/16 12:35
Heptachlor epoxide ug/L ND 0.50 04/12/16 12:35
Methoxychlor ug/L ND 1000 04/12/16 12:35
Toxaphene ug/L ND 3.0 04/12/16 12:35
Decachlorobiphenyl (S) % 35 10-138 04/12/16 12:35
Tetrachloro-m-xylene (S) % 100 10-110 04/12/16 12:35
LABORATORY CONTROL SAMPLE & LCSD: 1707403 1707404
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Endrin ug/L 1.2 1.2 1.2 95 94 20-134 1 30
gamma-BHC (Lindane) ug/L 1.2 1.3 1.2 105 101 20-118 4 30
Heptachlor epoxide ug/L 1.2 1.2 1.2 99 95 22-133 4 30
Methoxychlor ug/L 3.7 ND ND 114 114 44-150 30
Decachlorobiphenyl (S) % 73 58 10-138
Tetrachloro-m-xylene (S) % 104 103 10-110
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical .
www.pacelabscom
rttGe AIICIy nGOI JCI vn.00, un..
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
QC Batch: OEXT/27410 Analysis Method: EPA 8151
QC Batch Method: EPA 3510 Analysis Description: 8151 GCS Herbicides TCLP
Associated Lab Samples: 92291795001
METHOD BLANK: 1530173 Matrix: Water
Associated Lab Samples: 92291795001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
2,4,5-TP (Silvex) mg/L ND 0.00019 04/13/16 03:30
2,4-D mg/L ND 0.00094 04/13/16 03:30
2,4-DCAA (S) % 87 39-139 04/13/16 03:30
METHOD BLANK: 1536514 Matrix: Water
Associated Lab Samples: 9229'1795001
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
2,4,5-TP (Silvex) mg/L ND 0.00019 04/13/16 06:01
2,4-D mg/L ND 0.00094 04/13/16 06:01
2,4-DCAA (S) % 81 39-139 04/13/16 06:01
LABORATORY CONTROL SAMPLE: 1530174
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
2,4,5-TP (Silvex) mg/L .012 0.010 86 53-134
2,4-D mg/L .06 0.045 75 35-124
2,4-DCAA (S) % 76 39-139
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1536512 1536513
MS MSD
92291795001 Spike Spike MS MSD MS. MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
2,4,5-TP (Silvex) mg/L ND .478 .478 0.43 0.41 90 86 53-134 5 H3
2,4-D mg/L ND 2.39 2.39 1.9 1.8 79 76 35-124 4 H3
2,4-DCAA (S) % 80 76 39-139
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

mvwpacelabs cor . •
race Anatyncar our vwaa, ,,,,..
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
QC Batch: PMST/8930 Analysis Method: ASTM D2974-87
QC Batch Method: ASTM D2974-87 Analysis Description: Dry Weight/Percent Moisture
Associated Lab Samples: 92291795001
SAMPLE DUPLICATE: 1699321
Parameter
92291915001 Dup
Units Result Result RPD Qualifiers
Percent Moisture
22.6 22.6 0
SAMPLE DUPLICATE: 1699322
92291821002 Dup
Parameter - Units Result Result RPD Qualifiers
Percent Moisture % 92.4 92.3 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAna►ytical
www.pacelabscom
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
QC Batch: WET/43988 Analysis Method: EPA 1010
QC Batch Method: EPA 1010 Analysis Description: 1010 Flash Point, Closed Cup
Associated Lab Samples: 92291795001
SAMPLE DUPLICATE: 1700787
92291185001 Dup
Parameter Units Result Result RPD Qualifiers
Flashpoint deg F >200 >200
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAhalytical
wwwpace!abs.com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
QC Batch: WET/36889 Analysis Method: EPA 9034
QC Batch Method: EPA 9030A Analysis Description: 9034 Sulfide Solid
Associated Lab Samples: 92291795001
METHOD BLANK: 1526952 Matrix: Solid
Associated Lab Samples: 92291795001
Blank Reporting.
Parameter Units Result Limit Analyzed Qualifiers
Sulfide mg/kg ND 149 04/04/16 14:10
LABORATORY CONTROL SAMPLE & LCSD: 1526953 1527129
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers
Sulfide mg/kg 300 284 284 95 96 80-120 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aeAnalytical®
/ ww..pace/abs.com.
I
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
�a..C,-,..a,r.. �,'- ,., ..,.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QC Batch: WET/43967 Analysis Method: EPA 9045
QC Batch Method: EPA 9045 Analysis Description: 9045 pH
Associated Lab Samples: 92291795001
SAMPLE DUPLICATE: 1700232
92291795001 Dup
Parameter Units Result Result RPD Qualifiers
pH at 25 Degrees C
Std. Units 7.1
7.1 0 H6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalyticol®
www.pacetabs;corn
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA
Project: McConnell and Associates
Pace Project No.: 92291795
QC Batch: WETA/56754 Analysis Method: EPA 9012
QC Batch Method: EPA 9012 Analysis Description: 9012 Cyanide
Associated Lab Samples: 92291795001
METHOD BLANK: 1536936
Associated Lab Samples: 92291795001
Parameter
Units
Matrix: Solid
Blank Reporting
Result Limit Analyzed Qualifiers
Cyanide mg/kg ND 0.26 04/13/16 15:23
LABORATORY CONTROL SAMPLE: 1536937
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Cyanide mg/kg .58 0.53 91 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 1536938 1536939
MS MSD
92291795001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Cyanide
mg/kg ND 23.9 23.9 27.7 28.4 81 85 80-120 3 H3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnalytical
wwwpacolabs.com.
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALIFIERS
Project: McConnell and Associates
Pace Project No.: 92291795
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL - Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD —Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether, Styrene, and Vinyl chloride.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
LABORATORIES
PASI-A
PASI-C
PASI-O
Pace Analytical Services - Asheville
Pace Analytical Services - Charlotte
Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
H2 Extraction or preparation conducted outside EPA method holding time.
H3 Sample was received or analysis requested beyond the recognized method holding time.
H6 Analysis initiated outside of the 15 minute EPA required holding time.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
Date: 05/12/2016 03:20 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..

aceAnaIytical
www.paxlabs:com
Pace Analytical Services, Inc.
6701 Conference Drive
Raleigh, NC 27607
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: McConnell and Associates
Pace Project No.: 92291795
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical
Analytical Method Batch
92291795001
92291795001
92291795001
92291795004
92291795001
92291795001
92291795001
92291795004
92291795001
92291795001
92291795001
92291795001
92291795001
92291795001
SAGER CREEK LARGE LAGOON
SAGER CREEK LARGE LAGOON
SAGER CREEK LARGE LAGOON
SAGER CREEK SMALL LAGOON
SAGER CREEK LARGE LAGOON
SAGER CREEK LARGE LAGOON
SAGER CREEK LARGE LAGOON
SAGER CREEK SMALL LAGOON
SAGER CREEK LARGE LAGOON
SAGER CREEK LARGE LAGOON
SAGER CREEK LARGE LAGOON
SAGER CREEK LARGE LAGOON
SAGER CREEK LARGE LAGOON
SAGER CREEK LARGE LAGOON
Date: 05/12/2016 03:20 PM
EPA 3510
EPA 3510
EPA 3050
EPA 3050
EPA 3010A
EPA 7470
EPA 7471
EPA 7471
EPA 8260
ASTM D2974-87
EPA 1010
EPA 9030A
EPA 9045
EPA 9012
OEXT/41893 EPA 8081
OEXT/27410 EPA 8151
MPRP/21206 EPA 6010
MPRP/21238 EPA 6010
MPRP/21241 EPA 6010
MERP/9203 EPA 7470
MERP/9185 EPA 7471
MERP/9201 EPA 7471
MSV/36273
PMST/8930
WET/43988
WET/36889 EPA 9034
WET/43967
WETA/56754 EPA 9012
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, Inc..
GCSV/24649
GCSV/17883
ICP/19066
ICP/19082
ICP/19087
MERC/8835
MERC/8837
MERC/8845
WET/36893
W ETA/56805

Page 1 of 2
Report Number: 16-127-0595
Account Number: 46926
Send To: PACE ANALYTICAL EDEN- (for Terri Fag(
TERRI PAGE
205 EAST MEADOW RD
SUITE A
EDEN NC 27288
•
ANALYTICAL
"Every acre...Every year. "nw
Submitted By: TERRI PAGE
SOIL ANALYSIS REPORT
: 05/12/2016
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Grower: WORKORDER NAME: MCCONN
Analytical Method(s): Lime Index Mehlich 3 Loss On Ignition Water pH
uase rceueiveui VJNW
.
CM 1 V
OM
✓o . ^
;.'r
J .
ENR ..,
- - ---
hosphorus
,
' `
Potassium
• Magnesium
Calcluln '
Sodium
_ pH:
a Adlty.
C E.0 "•..
Sample ID
FieId:ID
,
."Lab
...number
,. "
%
:.;
,;Rate
;W/V:
Soll `.
• .::::....
;Class,
'
IbslA
;: ....
M3`,
: , .
ppm ;.Rate
y ;ppm, , .Rate
' ppm .Rate
K
PPm Rate..
Mg
PPm.. Rate
Ca
ppm .:Rate
Na
ppm .;Rate.
Boll
H; ..
.p . ..+
n dex
H
;'me g710o
.-
,me L100 .
•
2870 VH
NC = 1468
666 H
1657 L
751 VH
8.1
0.0
24.5
SAGER CREEK LA
18072
46.9
150
557 VH
VH
ORG
NC = 464
SAGER CREEK SA
18073
29.3
150
386 VH
2022 VH
NC = 1034
463 H
1229 L
722 VH
7.2
0.0
18.3
VH
ORG
NC = 322
,,• _•u -,.,
s Percent!Base Saturation
_it,
Nitrate
,,
,�". Sulfur
,y,.. `...
; Zmc,- , -.
,.. .
Manganese':
Iron .
Coppe r"',...
Boron
,:Soluble Salts
ti;NH4N ,
TotalKjeldatif.
trogen '
Nippur
Sample ID'
FieId.ID, , . ;..
_ K
Mg
z},° .
/°
Ca
%�
Nay
._° .,
%�
H
j , o
% �.
NO3N
_.. ' , ., �
ppm Rater
S
.-.,
i;. .: _
..ppm Rate
Zn
'ppm Rate
Mn
pm�� Rate
Fe
p m`= Rate
Cu
in ,Rate
B'
tm �'�Rate
PpT
SS
ms/cm r Ftate
c ppm
�;;
SAGER CREEK LA
30.0
22.7
33.8
13.3
0.0
2 VL
57.0
29100
SAGER CREEK SIv
28.3
21.1
33.6
17.2
0.0
91.0
16800
Values on this report represent the plant available nut Tents in the
soil. Rating after each value: VL (Very Low), L (Low), M (Medium),
H (High), VH (Very High). ENR - Estimated Nitrogen Release.
C.E.C. - Cation Exchange Capacity.
Explanation of symbols: % (percent), ppm (parts per million), Ibs/A
(pounds per acre), ms/cm.(milli-mhos per centimeter), meq/100g
(milli -equivalent per 100 grams). Conversions: ppm x 2 = lbs/A, Soluble
Salts ms/cm x 640 = ppm.
l
is report applies to samples) tested. Sampe
maximum of thirty days after testing.
Analysis prepared by: WaypolntAnalytical Virginia, Inc.
w by:
P m` Oory
Pauric McGroary

Page 2 of 2
Report Number: 16-127-0595
Account Number: 46926
Send To: PACE ANALYTICAL EDEN- (for Terri Pagc
TERRI PAGE
205 EAST MEADOW RD
SUITE A
EDEN NC 27288
Comments:
poi d't..
ANALYTICAL
"Every acre...Every year."m.,
Submitted By: TERRI PAGE
7621 Whitepine Road, Richmond, VA 23237
Main 804-743-9401 ° Fax [phone]
www.waypointanalytical.com
Grower: WORKORDER NAME: MCCONN
"The recommendations are based on research data and experience, but NO GUARANTEE or WARRANTY expressed or implied, concerning crop performance is made."
Our reports and letters are for the exclusive and confidential use of our clients„ and may not be reproduced in whole or part, nor may any reference be made to the
work,the results, or the company in any advertising, news release, or other public anouncements without obtaining our prior written authorization. Copy right 1977.
Fib«
Pauric McGroary