NC0024911_Groundwater Monitoring Report June 2022_20220725

SEWL840j
6�`�Metropolitan Sewera istrict
• • OF BUNCOMBE COUNTY, NORTH CAROLINA
F UNT y $ �
July 25, 2022
Division of Water Resources
Information Processing Unit
1617 Mail Service Center
Raleigh, NC 276994617
Information Processing Unit:
Please find attached Groundwater Quality monitoring reports for June 2022 from Metropolitan
Sewerage District of Buncombe County (MSD). These monitoring report forms have additional
identification on the well ID line, MW-05, MW-0611, MW-07 and MW-08R, for ease and reference.
Monitoring Well-05 exceeded allowable limits for pH, manganese, and iron. Monitoring WeIW611
exceeded allowable limits for pH, manganese, and iron. Monitoring Well-07 exceeded allowable limits
for pH and manganese. Monitoring Well-08R exceeded allowable limits for manganese and iron.
Please do hesitate to contact me at 828-225-8224 with questions regarding the attached reports.
Sincerely,
oger Edwards
Director of Operations &Pretreatment
MSD of Buncombe County
Protecting Our Natural Resources
2028 RIVERSIDE DRIVE, ASHEVILLE, NORTH CAROLINA28804 TELEPHONE: [phone] FAX: [phone] WEBSITE; www.msdbc.org

GW-59A COMPLIANCE REPORT FORM
Permit # NC002491I
(Submit one each monitoring period with GN-59 forms.)
1
Enter date monitoring results were due. L07/31/2022—) Will this monitoring report (GW-59 and GW-59A)
YES
NO
be submitted after the established due date?
2
Was any required information missing on the GW-59 report forms?
YES
O
IF the answer to question 1 or 2 is "YES', list in the space provided below the well identification number(s) and
explain the problems encountered in obtaining the required information.
3
Are any of the monitor wells in need of repair or maintenance (damaged casing, unlocked or missing cap, missing
YES
O
identification plate, area overgrown, etc.)9 lfthe answer is "les", contact the Regional Office for gttidance.
4
Are any monitored constituents equal to or above the established standards?
ES
NO
If the answer to question 4 is "NO", skip to section 8.
If the answer to question 4 is "YES" list the affected wells individually with constituent(s) and concentration(s)
exceeding standards in the space provided below:
MW-05 MW-06R MW-07 MW-08R
pH 5.52 pH 5.67 pH 5.89
Mn 76.2 ug/L Mn 14,100 ug/L Mn 191 ug/L Mn 17,000 ug/L
Fe 382 ug/L Fe 16,900 ug/L Fe 49,900 ug/L
5
For the constituents identified in question 4 above, have standards been exceeded previously for the
ES
NO
same constituent(s) in the same well(s) in the last two years?
If the answer to question 5 is 'A/0" skip to section 8.
If the answer to question 5 is "YES", list in the space provided below, each well with constituent(s) exceeding standards,
concentration(s) reported, and sample collection date for each occurrence (for the last two years).
MW-05 pH Mn Fe MW-06R pH Mn Fe MW-07 pH Mn Fe MW-08R pH Mn Fe
618120 5.6 6/8120 5.5 7,880 ug/L 1,820 ug/L 618/20 5.9 308 ug/L 447 ug/L 618120 19,700 ug/L 70,700 ug/L
10/23/20 5.4 10/23/20 5.2 9,330 ug/L 5,410 ug/L 10/23/20 5.9 831 ug/L 10/23/20 14,800 ug/L 61,600 ug/L
1115/21 5.6 1116/21 5.3 87510 ug/L 1,250 ug/L 1/15121 6.0 334 ug/L 1/15/21 20,100 ug/L 69,000 ug/L
6/24/21 5.4 6/24/21 5.4 9,980 ug/L 5,360 ug/1 6/24121 5.9 176 ug/L 6/24121 15,000 ug/L 50,700 ug/L
1011121 5.5 10/1121 5.2 6,690 ug/L 1,080 ug/L 1011/21 5.8 740ug/L 10/1/21 11,000 ug/L 37,600 ug/L
1/24122 5.7 1/24122 5.17 12,300 ug/L 9.200 ug/L 1/24/22 6.1 1/24/22 9,780 ug/L 32,300 ug/L
Are the monitoring wells listed in section 5 located at or beyond the review boundary?
YES
O
If the answer is "YES", a groundwater quality problem may be occurring. CONTACT THE REGIONAL
OFFICE IMMEDIATELY FOR GUIDANCE. If the answer is "NO", monitoring wells may be improperly
located; contact the Regional Office.
7
Is the permittee implementing previously approved actions required by the Division involving this
YE
NO
groundwater quality problem?
If the answer to question 7 is "YES", describe those actions in the space provided below.
If the answer to question 7 is "NO", contact the Regional Office within 90 days: an evaluation may be
to determine the impact the waste disposal system is having at the review and compliance
wired
boundaries surroundina
this
facility. Failure to do so may subiect
the
permittee
to a Notice of Violation.
fines. andp /orena'lties.
rA154P1114!: cf Nrw Nun/Ji �oarMg- Fjcc6rEe(oftitccs A A 4F Nk{zaadl��/ o��uRiiz
9
g
The person completing this portion (G W-59A) of the monitoring report should sign below and submit this
form with GW-59 forms for required wells to the address provided at the top of the current GW-59 form.
I hereby acknowledge that the above information was evaluated and the information submitted in this
report (Compliance Report GW-59A) is true and complete to the best of my knowledge.
ve�va ,a 2,E2 ac� J, D
ign ure of Perm ittee (or Authorized Agent) Date
GW-59A 12/8/2003

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Analytical
www.pacelabs.com
July 20, 2022
Mr. Roger Edwards
Metropolitan Sewerage District
2028 Riverside Drive
Asheville, NC 28804
RE: Project: MWs 6/27
Pace Project No.: 92611877
Dear Mr. Edwards:
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Enclosed are the analytical results for samples) received by the laboratory on June 27, 2022. The results relate only to the
samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services -Asheville
• Pace Analytical Services - Charlotte
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Lorri Patton
lorri. patton @pacelabs. com
1(828)254-7176
Project Manager
Enclosures
cc: Ms. Shannon Bergeron, Metropolitan Sewerage District
Mr. John Gosnell, Metropolitan Sewerage District
Ms. Sheila Kilby, MSD of Buncombe County
Mr, Chad Ledford, Metropolitan Sewerage District
Ms, Angel McCrain, MSD of Buncombe County
Patrick Smith, MSD of Buncombe County, NC
Mr. Alan Taylor, Metropolitan Sewerage District
Mr, Schuyler Taylor, Metropolitan Sewerage District
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
out the written consent of Pace Analytical Services, LLC.
Page 1 of 25

Analytical
www.pacelabs.com
CERTIFICATIONS
Project: MWs 6/27
Pace Project No.: 92611877
Pace Analytical Services Charlotte
South
Carolina
Laboratory ID: 99006
South Carolina
Certification #:
99006001
9800
Kincey Ave. Ste 100, Huntersville, NC 28078
South Carolina
Drinking Water
Cert. #: 99006003
North
Carolina
Drinking Water Certification M 37706
Florida/NELAP
Certification M
E87627
North
Carolina
Field Services Certification #: 5342
Kentucky UST
Certification #: 84
North
Carolina
Wastewater Certification M 12
Louisiana DoH
Drinking Water
#: LA029
South
Carolina
Laboratory ID: 99006
VirginiaNELAP Certification M
460221
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804 South Carolina Laboratory ID: 99030
Florida/NELAP Certification M E87648 South Carolina Certification #: 99030001
North Carolina Drinking Water Certification M 37712 Virginia/VELAP Certification #: 460222
North Carolina Wastewater Certification M 40
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
out the written consent 01 Pace Analytical Services, LLC.
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Page 2 of 25

Analytical
www.pacalabs.com
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: MWs 6/27
Pace Project No.: 92611877
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92611877001 MW-05 EPA 200.7 Rev 4.4 1994 DEC, MJI 10 PASI-A
EPA 245.1 Rev 3.0 1994 NMP 1 PASI-A
SM 2540C-2015 MAB2 1 PASI-A
EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A
EPA 350.1 Rev 2.0 1993 NDS 1 PASI-A
EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A
SM 4500-CI-E-2011 ANM 1 PASI-A
SM 5310B-2014 MJP 1 PASI-A
92611877002 MW-061R EPA 200.7 Rev 4.4 1994 DEC, MJI 10 PASI-A
EPA 245.1 Rev 3.0 1994 NMP 1 PASI-A
SM 2540C-2015 MAB2 1 PASI-A
EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A
EPA 350.1 Rev 2.0 1993 NDS 1 PASI-A
EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A
SM 4500-CI-E-2011 ANM 1 PASI-A
SM 5310B-2014 MJP 1 PASI-A
92611877003 MW-08R EPA 200.7 Rev 4.4 1994 DEC, MJI 10 PASI-A
EPA 245.1 Rev 3.01994 NMP 1 PASI-A
SM 2540C-2015 MAB2 1 PASI-A
EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A
EPA 350.1 Rev 2.0 1993 NDS 1 PASI-A
EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A
SM 4500-CI-E-2011 ANM 1 PASI-A
SM 5310B-2014 MJP 1 PASI-A
92611877004 MW-07 EPA 2003 Rev 4A 1994 DEC 10 PASI-A
EPA 245.1 Rev 3.0 1994 NMP 1 PASI-A
SM 2540C-2015 MAB2 1 PASI-A
EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A
EPA 350A Rev 2.0 1993 NDS 1 PASI-A
EPA 353.2 Rev 2.0 1993 KDF1 1 PASI-A
SM 4500-CI-E-2011 ANM 1 PASI-A
SM 5310B-2014 MJP 1 PASI-A
PASI-A =Pace
Analytical
Services -Asheville
PASI-C
=Pace
Analytical
Services -Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
out the written consent of Pace Analytical Services, LLC, Page 3 of 25

Analytical
ww%pacelabs.com
Project: MWs 6/27
Pace Project No.: 92611877
Sample: MW-05
Parameters
ANALYTICAL RESULTS
Lab ID: 92611877001
Results Units
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
[phone]
Collected: 06/27/22 11:25 Received: 06/27/22 16:28 Matrix: Water
Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data Analytical Method:
Pace Analytical Services - Charlotte
Performed by Pace 1 07/06/22 13:06
Collected By M.Swann 1 07/06/22 13:06
Collected Date 6/27122 1 07/06/22 13:06
Collected Time 11:25 1 07/06/22 13:06
pH 5.52 Std, Units 1 07/06/22 13:06
Temperature 21.0 deg C 1 07/06/22 13:06
Static Water Level 17.63 feet 1 07/06/22 13:06
Specific Conductance 34.9 umhos/cm 1 07/06/22 13:06
Odor No Odor 1 07/06/22 13:06
Appearance Clear 1 07/06/22 13:06
2001 MET ICP Analytical Method: EPA 2003 Rev 4A 1994 Preparation Method: EPA 200.7 Rev 4A 1994
Pace Analytical Services -Asheville
Arsenic ND ug/L 10.0 1 07/14/22 00:36 07/15/22 13:57 7440-38-2
Barium 15.8 ug/L 5.0 1 07/14/22 00:36 07/15/22 13:57 7440-39-3
Cadmium ND ug/L 1.0 1 07/14/22 00:36 07/15/22 13:57 7440-43-9
Chromium ND ug/L 5.0 1 07/14/22 00:36 07/15/22 13:57 7440-47-3
Iron 382 ug/L 50.0 1 07/14/22 00:36 07/15/22 13:57 7439-89-6
Lead ND ug/L 5.0 1 07/14/22 00:36 07/15/22 13:57 7439-92-1
Manganese 76.2 ug/L 5.0 1 07/14/22 00:36 07/15/22 13:57 7439-96-5
Selenium ND ug/L 10.0 1 07/14/22 00:36 07/15/22 13:57 7782-49-2
Silver ND ug/L 5.0 1 07/14/22 00:36 07/18/22 14:46 7440-22-4
Sodium ND ug/L 5000 1 07/14/22 00:36 07/15/22 13:57 7440-23-5
246.1 Mercury Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994
Pace Analytical Services -Asheville
Mercury ND ug/L 0,20 1 07/02/2218:57 07/07/2213:11 7439-97-6
2540C Total Dissolved Solids Analytical Method: SM 2540C-2015
Pace Analytical Services - Asheville
Total Dissolved Solids ND mg/L 25.0 1 07/01/22 10:57
300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Sulfate
350.1 Ammonia
Nitrogen, Ammon
ia
353.2 Nitrogen, N021NO3 unpres
Nitrogen, Nitrate
Date: 07/20/2022 04:38 PM
3.9 mg/L
1.0 1
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L
0.10 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.041 mg/L
0.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
out the written consent of Pace Analytical Services, LLC.
06/28/22 20:32 14808-79-8
07/02/2210:15 7664-41-7
06/28/22 14:08 14797-55-8
Page 4 of 25

Analytical
www.pacelabs.com
ANALYTICAL RESULTS
Project: MWs 6/27
Pace Project No.: 92611877
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-05 Lab ID: 92611877001 Collected: 06/27/22 11:25 Received: 06/27/22 16:28 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
4500 Chloride Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride 1.3 mg/L 1.0 1 07/0512214:08 16887-00-6
5310E TOC Analytical Method: SM 531 OB-2014
Pace Analytical Services - Asheville
Total Organic Carbon ND mg/L 1.0 1 06/29/22 19:42 7440-44-0
Date: 07/20/2022 04:38 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 25

Analytical
www.pacelabs.com
Project: MWs 6/27
Pace Project No.: 92611877
Samp
le: MW-06R
Parameters
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Lab ID: 92611877002 Collected: O6/27/22 14:45 Received: 06/27/22 16:28 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical
Services - Charlotte
Performed by
Pace
1
07/06/22 13:08
Collected By
M.Swann
1
07/06/22 13:08
Collected Date
6127122
1
07/06/22 13:08
Collected Time
14:45
1
07/06/22 13:08
pH
5.67
Std. Units
1
07/06/22 13:08
Temperature
23.2
deg C
1
07/06/22 13:08
Static Water Level
10.40
feet
1
07/06/22 13:08
Specific Conductance
349.0
umhos/cm
1
07/06/22 13:08
Odor
No odor
1
07/06/22 13:08
Appearance
Clear
1
07/06/22 13:08
2003 MET ICP
Analytical Method:
EPA 200.7 Rev 4.4
1994
Preparation
Method:
EPA 200.7 Rev 4A
1994
Pace Analytical
Services - Asheville
Arsenic
ND
ug/L
10.0
1
07/14/22
00:36
07/15/22 14:14
7440-38-2
Barium
67.9
ug/L
5.0
1
07/14/22
00:36
07/15/22 14:14
7440-39-3
Cadmium
ND
ug/L
1.0
1
07/14/22
00:36
07/15/22 14:14
7440-43-9
Chromium
ND
ug/L
5.0
1
07/14/22
00:36
07/15/22 14:14
7440-47-3
Iron
16900
ug/L
50.0
1
07/14/22
00:36
07/15/22 14:14
7439-89-6
Lead
ND
ug/L
5.0
1
07/14/22
00:36
07/15/22 14:14
7439-92-1
Manganese
14100
ug/L
125
25
07/14/22
00:36
07/18/22 14:53
7439-96-5
Selenium
ND
ug/L
10.0
1
07/14/22
00:36
07/15/22 14:14
7782-49-2
Silver
ND
ug/L
5.0
1
07/14/22
00:36
07/19/22 14:06
7440-22-4
Sodium
17900
ug/L
5000
1
07/14/22
00:36
07/15/22 14:14
7440-23-5
245.1 Mercury
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
.0
300IC Anions 28 Days
Sulfate
350.1
Ammonia
Nitrogen
, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
Date: 07/20/2022 04:38 PM
Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994
Pace Analytical Services -Asheville
ND ug/L 0.20 1
Analytical
Method: SM 2540C-2015
Pace Analytical Services -Asheville
225 mg/L 25.0 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
90.4 mg/L
2.0 2
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
0.21 mg/L
0.10 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L
0.040 1
07/02/2218:57 07/07/2213:13 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
out the written consent 01 Pace Analytical Services, LLC.
07/01 /22 10:57
06/29/22 03:10 14808-79-8
07/02/2210:19 7664-41-7
06/28/22 14:28 14797-55-8
Page 6 of 25

Analytical
www.pacelabs.com
ANALYTICAL RESULTS
Project: MWs 6/27
Pace Project No.: 92611877
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-O6R
Parameters
Lab ID: 92611877002 Collected:
Results Units Report
06/27/22
Limit
14:45
DF
Received: 06/27/22 16:28
Prepared Analyzed
Matrix: Water
CAS No.
Date: 07/20/2022 04:38 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Qual
Page 7 of 25

Analytical o
www.pacelabs.com
ANALYTICAL RESULTS
Project: MWs 6/27
Pace Project No.: 92611877
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
[phone]
Sample: MW-08R
Lab ID:
92611877003
Collected:
06/27/22
15:05
Received:
06/27/22 16:28
Matrix: Water
Parameters
Results
Units
Report
Limit
DF
Prepared
Analyzed
CAS No,
Monitoring Well Data
Analytical Method:
Pace Analytical
Services - Charlotte
Performed by
Pace
1
07/06/22 13:10
Collected By
M.Swann
1
07/06/22 13:10
Collected Date
6/27/22
1
07/06/22 13:10
Collected Time
15:05
1
07/06/22 13:10
pH
6.87
Std. Units
1
07/06/22 13:10
Temperature
22.8
deg C
1
07/06/22 13:10
Static Water Level
10A9
feet
1
07/06/22 13:10
Specific Conductance
602
umhos/cm
1
07/06/22 13:10
Odor
No odor
1
07/06/22 13:10
Appearance
Clear
1
07/06/22 13:10
2001 MET ICP
Analytical Method: EPA 2003 Rev 4.4
1994
Preparation
Method:
EPA 200.7 Rev 4A 1994
Pace Analytical
Services - Asheville
Arsenic
ND
ug/L
10.0
1
07/14/22
00:36
07/15/22 14:18
7440-38-2
Barium
51.9
ug/L
5.0
1
07/14/22
00:36
07/15/22 14:18
7440-39-3
Cadmium
ND
ug/L
1.0
1
07/14/22
00:36
07/15/22 14:18
7440-43-9
Chromium
ND
ug/L
5.0
1
07/14/22
00:36
07/15/22 14:18
7440-47-3
Iron
49900
ug/L
50.0
1
07/14/22
00:36
07/15/22 14:18
7439-89-6
Lead
ND
ug/L
5.0
1
07/14/22
00:36
07/15/22 14:18
7439-92-1
Manganese
17000
ug/L
125
25
07/14/22
00:36
07/18/22 14:56
7439-96-5
Selenium
ND
ug/L
10.0
1
07/14/22
00:36
07/15/22 14:18
7782-49-2
Silver
ND
ug/L
5.0
1
07/14/22
00:36
07/19/22 14:09
7440-22-4
Sodium
21600
ug/L
5000
1
07/14/22
00:36
07/15/22 14:18
7440-23-5
245.1 Mercury
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
300.0 IC Anions 28 Days
Sulfate
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
Date: 07/20/2022 04:38 PM
Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994
Pace Analytical Services -Asheville
ND ug/L 0.20 1
Analytical Method: SM 2540C-2015
Pace Analytical Services -Asheville
305 mg/L 25.0 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
88.5 mg/L
2.0 2
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
0.46 mg/L
0.10 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L
0.040 1
07/02/2218:57 07/07/2213:19 7439-97-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent 01 Pace Analytical Services, LLC.
07/01 /22 10:57
06/29/22 03:26 14808-79-8
07/02/2210:20 7664-41-7
06/28/22 14:29 14797-55-8
Qual
Page 8 of 25

Analytical
www.pacelabs.com
ANALYTICAL RESULTS
Project: MWs 6/27
Pace Project No.: 92611877
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-08R
Parameters
Lab ID: 92611877003 Collected:
Results Units Report
06/27/22
Limit
15:05
DF
Received: 06/27/22 16:28 Matrix: Water
Prepared Analyzed CAS No. Qual
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride
13.0 mg/L
1.0
1
07/05/2214:10 16887-00-6
5310E TOC
Analytical Method: SM 531OB-2014
Pace Analytical Services - Asheville
Total Organic Carbon
2.3 mg/L
1.0
1
06/29/22 20:48 7440-44-0
Date: 07/20/2022 04:38 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 25

Analytical
www.pacelabsxom
Project: MWs 6/27
Pace Project No.: 92611877
Sample: MW-07
Parameters
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
[phone]
ANALYTICAL RESULTS
Lab ID: 92611877004 Collected: 06/27/22 15:50 Received: 06/27/22 16:28 Matrix: Water
Results Units Report Limit DF Prepared Analyzed CAS No. Qual
Monitoring Well Data
Analytical Method:
Pace Analytical
Services - Charlotte
Performed by
Pace
1
07/06/22 13:12
Collected By
M.Swann
1
07/06/22 13:12
Collected Date
6/27/22
1
07/06/22 13:12
Collected Time
15:50
1
07/06/22 13:12
pH
5.89
Std, Units
1
07/06/22 13:12
Temperature
24.3
deg C
1
07/06/22 13:12
Static Water Level
11.27
feet
1
07/06/22 13:12
Specific Conductance
369
umhos/cm
1
07/06/22 13:12
Odor
No odor
1
07/06/22 13:12
Appearance
Clear
1
07/06/22 13:12
2003 MET ICP
Analytical Method: EPA 200.7 Rev 4.4
1994
Preparation
Method:
EPA 200.7 Rev 4.4 1994
Pace Analytical
Services - Asheville
Arsenic
ND
ug/L
10.0
1
07/14/22
00:36
07/15/22 14:21
7440-38-2
Barium
40.5
ug/L
5.0
1
07/14/22
00:36
07/15/22 14:21
7440-39-3
Cadmium
ND
ug/L
1.0
1
07/14/22
00:36
07/15/22 14:21
7440-43-9
Chromium
ND
ug/L
5.0
1
07/14/22
00:36
07/15/22 14:21
7440-47-3
Iron
63.7
ug/L
50.0
1
07/14/22
00:36
07/15/22 14:21
7439-89-6
Lead
ND
ug/L
5.0
1
07/14/22
00:36
07/15/22 14:21
7439-92-1
Manganese
191
ug/L
5.0
1
07/14/22
00:36
07/15/22 14:21
7439-96-5
Selenium
ND
ug/L
10.0
1
07/14/22
00:36
07/15/22 14:21
7782-49-2
Silver
ND
ug/L
5.0
1
07/14/22
00:36
07/19/22 14:13
7440-22-4
Sodium
11800
ug/L
5000
1
07/14/22
00:36
07/15/22 14:21
7440-23-5
245.1 Mercu
Mercury
2540C Total Dissolved Solids
Total Dissolved Solids
300.0 IC Anions 28 Days
6M
IFiia
350.1 Ammonia
Nitrogen, Ammonia
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
Date: 07/20/2022 04:38 PM
Analytical Method: EPA 245.1 Rev 3.0 1994 Preparation Method: EPA 245.1 Rev 3.0 1994
Pace Analytical Services -Asheville
ND ug/L
Analytical SM 2540C-2015
Pace Analytical Services -Asheville
Method:
228 mg/L
0.20 1 07/02/2218:57 07/07/2213:21 7439-9
7-6
25.0 1
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
88.3 mg/L
2.0 2
Analytical Method: EPA 350.1 Rev 2.0 1993
Pace Analytical Services -Asheville
ND mg/L
0.10 1
Analytical Method: EPA 353.2 Rev 2.0 1993
Pace Analytical Services -Asheville
0.28 mg/L
0.040 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
out the written consent 01 Pace Analytical Services, LLC.
07/01 /22 10:59
06/29/22 03:42 14808-79-8
07/02/2210:22 7664-41-7
06/28/22 14:31 14797-55-8
Page 10 of 25

Analytical
www.pacelabs.com
ANALYTICAL RESULTS
Project: MWs 6/27
Pace Project No.: 92611877
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Sample: MW-07
Parameters
Lab ID: 92611877004 Collected:
Results Units Report
06/27/22
Limit
15:50
DF
Received: 06/27/22 16:28 Matrix: Water
Prepared Analyzed CAS No. Qual
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services - Asheville
Chloride
6.8 mg/L
1.0
1
07/05/2214:11 16887-00-6
5310B TOC
Analytical Method: SM 531 OB-2014
Pace Analytical Services - Asheville
Total Organic Carbon
ND mg/L
1.0
1
06/29/22 21:08 7440-44-0
Date: 07/20/2022 04:38 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent 01 Pace Analytical Services, LLC.
Page 11 of 25

Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: MWs 6/27
Pace Project No.: 92611877
QC Batch: 708500
Analysis
Method:
EPA 245.1 Rev 3.0 1994
QC Batch Method: EPA 245.1 Rev
3.0 1994
Analysis
Description:
245.1 Mercury
Laboratory:
Pace Analytical Services -
Asheville
Associated Lab Samples: 92611877001,
92611877002,
92611877003, 92611877004
METHOD BLANK: 3695156
Matrix: Water
Associated Lab Samples: 92611877001,
92611877002,
92611877003, 92611877004
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Mercury
ug/L
ND 0.20 07/0612212:50
LABORATORY CONTROL SAMPLE: 3695157
Spike
LCS
LCS % Rec
Parameter
Units
Conc.
Result
% Rec Limits
Qualifiers
Mercury
ug/L
2.5
2.6
104 85-115
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3695158
3695159
MS
MSD
92611220001
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result
Conc.
Conc, Result
Result % Rec
% Rec
Limits RPD Qual
Mercury
ug/L ND
2.5
2.5 2.7
2.6 106
103
70-130 2
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3695160
3695161
MS
MSD
92611877002
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result
Conc.
Conc, Result
Result % Rec
% Rec
Limits RPD Qual
Mercury
ug/L ND
2.5
2.5 2.2
2.3 84
89
70-130 6
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 04:38 PM without the written consent of Pace Analytical Services, LLC, Page 12 of 25

Analytical
www.pacelatis.com
QUALITY CONTROL DATA
Project: MWs 6/27
Pace Project No.: 92611877
QC Batch: 710453 Analysis Method: EPA 200.7 Rev 4.4 1994
QC Batch Method: EPA 200.7 Rev 4.4 1994 Analysis Description: 200.7 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92611877001, 92611877002, 92611877003, 92611877004
METHOD BLANK: 3704700
Associated Lab Samples: 92611877001,
Parameter
92611877002,
Units
Matrix: Water
92611877003, 92611877004
Blank Reporting
Result Limit
Analyzed
Qualifiers
Arsenic
ug/L
ND
10.0
07/15/2213:50
Barium
ug/L
ND
5.0
07/15/2213:50
Cadmium
ug/L
ND
1.0
07/15/2213:50
Chromium
ug/L
ND
5.0
07/1512213:50
Iron
ug/L
ND
50.0
07/15/2213:50
Lead
ug/L
ND
5.0
07/15/2213:50
Manganese
ug/L
ND
5.0
07/15/2213:50
Selenium
ug/L
ND
10.0
07/15/2213:50
Silver
ug/L
ND
5.0
07/18/2214:39
Sodium
ug/L
ND
5000
07/15/2213:50
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL
SAMPLE: 3704701
Spike
LCS
LCS
To Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Arsenic
ug/L
500
458
92
85-115
Barium
ug/L
500
475
95
85-115
Cadmium
ug/L
500
480
96
85-115
Chromium
ug/L
500
473
95
85-115
Iron
ug/L
5000
4910
98
85-115
Lead
ug/L
500
482
96
85-115
Manganese
ug/L
500
491
98
85-115
Selenium
ug/L
500
476
95
85-115
Silver
ug/L
250
222
89
85-115
Sodium
ug/L
5000
ND
100
85-115
MATRIX SPIKE & MATRIX
SPIKE DUPLICATE:
3704702
3704703
MS
MSD
92611877001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units
Result
Conc.
Conc,
Result
Result
% Rec
% Rec
Limits
RPD
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
Date: 07/20/2022 04:38 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent 01 Pace Analytical Services, LLC.
Qual
Page 13 of 25

Analytical
www,pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
[phone]
Project: MWs 6/27
Pace Project No.: 92611877
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
3704702
3704703
MS
MSD
92611877001
Spike
Spike
MS
MSD MS
MSD % Rec
Parameter
Units
Result
Conc,
Conc,
Result
Result % Rec
% Rec Limits RPD Qual
Silver
ug/L
ND
250
250
228
231 91
92 70-130 1
Sodium
ug/L
ND
5000
5000
6690
6800 95
97 70-130 2
Results presented on this page are In the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 04:38 PM without the written consent of Pace Analytical Services, I.I.C. Page 14 of 25

Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: MWs 6/27
Pace Project No.: 92611877
QC Batch: 708225 Analysis Method: SM 2540C-2015
QC Batch Method: SM 2540C-2015 Analysis Description: 2540C Total Dissolved Solids
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92611877001, 92611877002, 92611877003, 92611877004
METHOD BLANK: 3693533 Matrix: Water
Associated Lab Samples: 92611877001, 92611877002, 92611877003, 92611877004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Total Dissolved Solids mg/L ND 25.0 07/01/22 10:57
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 3693534
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Total Dissolved Solids mg/L 250 238 95 90-110
SAMPLE DUPLICATE: 3693535
92611877001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L ND ND
SAMPLE DUPLICATE: 3693536
92612334001 Dup
Parameter Units Result Result RPD Qualifiers
Total Dissolved Solids mg/L 76.0 80.0 5
Results presented on this page are In the units Indicated by the "Units" column except where an alternate un(t Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 04:38 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 25

Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: MWs 6/27
Pace Project No.: 92611877
QC Batch: 707478 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92611877001, 92611877002, 92611877003, 92611877004
METHOD BLANK: 3690128 Matrix: Water
Associated Lab Samples: 92611877001, 92611877002, 92611877003, 92611877004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Sulfate mg/L ND 1.0 06/28/2219:12
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
LABORATORY CONTROL SAMPLE: 3690129
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Sulfate mg/L 50 50.6 101 90-110
MATRIX SPIKE &MATRIX SPIKE DUPLICATE: 3690130 3690131
MS MSD
92611876001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfate mg/L 9.3 61.5 61.5 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 04:38 PM without the written consent of Pace Analytical Services, LLC, Page 16 of 25

Analyfical
www.pacelabs.com
QUALITY CONTROL DATA
Project: MWs 6/27
Pace Project No.: 92611877
QC
Batch:
708348
Analysis
Method:
EPA
350.1 Rev 2.0 1993
QC
Batch Method:
EPA 350A Rev 2.0 1993
Analysis
Description:
350.1
Ammonia
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92611877001, 92611877002, 92611877003, 92611877004
METHOD BLANK: 3694232 Matrix: Waler
Associated Lab Samples: 92611877001, 92611877002, 92611877003, 92611877004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Ammonia mg/L ND 0.10 07/02/22 08:54
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
[phone]
LABORATORY CONTROL
SAMPLE: 3694233
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Nitrogen, Ammonia
mg/L
5
5.0
100
90-110
MATRIX SPIKE & MATRIX
SPIKE DUPLICATE: 3694234
3694235
MS
MSD
92612637001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Nitrogen, Ammonia
mg/L 26A
5
5
30.8
30.5
88
82
90110 1 M1
MATRIX SPIKE & MATRIX
SPIKE DUPLICATE: 3694236
3694237
MS
MSD
92612637002
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter
Units Result
Conc.
Conc,
Result
Result
% Rec
% Rec
Limits RPD Qual
Nitrogen, Ammonia
mg/L 26.2
5
5
30.3
29.8
81
71
90-110 2 M1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 04:38 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 25

Analytical o
www.pacelabs.com
QUALITY CONTROL DATA
Project: MWs 6/27
Pace Project No.: 92611877
QC Batch: 707349 Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres,
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92611877001, 92611877002, 92611877003, 92611877004
METHOD BLANK: 3689465 Matrix: Water
Associated Lab Samples: 92611877001, 92611877002, 92611877003, 92611877004
Blank Reporting
Parameter Units Result Limit Analyzed Qualifiers
Nitrogen, Nitrate mg/L ND 0,040 06/28/22 14:05
LABORATORY CONTROL SAMPLE: 3689466
Parameter
Nitrogen, Nitrate
Spike LCS
Units Cone. Result
mg/L 1.5
LCS %Rec
Rec Limits
1.5
99 90-110
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
[phone]
Qualif
iers
MATRIX SPIKE &MATRIX SPIKE DUPLICATE: 3689467 3689468
MS MSD
92611877001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc, Conc, Result Result % Rec % Rec Limits RPD Qual
Nitrogen, Nitrate mg/L 0,041 1.5 1.5 1.5 1.5 98 98 90-110 0
Results presented on thls page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 04:38 PM without the written consent 01 Pace Analytical Services, LLC.
Page 18 of 25

Analytical
www.pacelabs.com
QUALITY CONTROL DATA
Project: MWs 6/27
Pace Project No.: 92611877
QC Batch: 708577 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services - Asheville
Associated Lab Samples: 92611877001, 92611877002, 92611877003, 92611877004
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
[phone]
METHOD BLANK: 3695347
Matrix: Water
Associated Lab Samples:
92611877001,
92611877002,
92611877003, 92611877004
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Chloride
mg/L
ND 1.0
07/05/2213:55
LABORATORY CONTROL
SAMPLE: 3695348
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits
Qualifiers
Chloride
mg/L
20
20.6
103
90-110
MATRIX
SPIKE & MATRIX
SPIKE
DUPLICATE: 3695349
3695350
MS
MSD
92612051002
Spike
Spike MS
MSD
MS
MSD
% Rec
Parameter
Units Result
Cone.
Cone. Result
Result
% Rec
% Rec
Limits RPD Qual
Chloride
mg/L 99.2
10
10 111
109
114
93
90-110 2 M1
MATRIX
SPIKE & MATRIX
SPIKE
DUPLICATE: 3695351
3695352
MS
MSD
92612054001
Spike
Spike MS
MSD
MS
MSD
% Rec
Parameter
Units Result
Cone.
Cone. Result
Result
% Rec
% Rec
Limits RPD Qual
Chloride
mg/L 56.0
10
10 67.5
66.2
115
102
90-110 2 M1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 04:38 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 25

Analytical q)
www.pacelabs.com
QUALITY CONTROL DATA
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
Project: MWs 6/27
Pace Project No.: 92611877
QC Batch: 707676
Analysis
Method:
SM 531OB-2014
QC Batch Method: SM 531 OB-2014
Analysis
Description:
5310B TOC
Laboratory:
Pace Analytical Services -Asheville
Associated Lab Samples: 92611877001,
92611877002,
92611877003, 92611877004
METHOD BLANK: 3690862
Matrix: Water
Associated Lab Samples: 92611877001,
92611877002,
92611877003, 92611877004
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Total Organic Carbon
mg/L
ND 1.0
06/29/22 14:14
LABORATORY CONTROL SAMPLE: 3690863
Spike
LCS
LCS % Rec
Parameter
Units
Cone.
Result
% Rec Limits
Qualifiers
Total Organic Carbon
mg/L
25
24A
98 90-110
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3690864
3690865
MS
MSD
92611967001
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result
Cone.
Cone. Result
Result % Rec
% Rec
Limits RPD Qual
Total Organic Carbon
mg/L ND
25
25 24.7
24.8 99
99
90-110 1
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 3690866
3690867
MS
MSD
92611877001
Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result
Cone,
Cone. Result
Result % Rec
% Rec
Limits RPD Qual
Total Organic Carbon
mg/L ND
25
25 23.7
23.9 95
95
90-110 1
Results presented on this page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 04:38 PM without the written consent of Pace Analytical Services, LLC,
Page 20 of 25

Anai(Xicai�
www.pacelabs.cam
QUALIFIERS
Project: MWs 6/27
Pace Project No.: 92611877
DEFINITIONS
DF -Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
Pace Analytical Services, LLC
2225 Riverside Dr,
Asheville, NC 28804
[phone]
J -Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL-Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC -Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Reported results are not rounded until the final step prior to reporting. Therefore, calculated parameters that are typically reported as
'Total" may vary slightly from the sum of the reported component parameters.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analyles.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
Date: 07/20/2022 04:38 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
out the written consent of Pace Analytical Services, LLC.
Page 21 of 25

aceAnalytical
www.pacelabs.cam
r
Project: MWs 6/27
Pace Project No.: 92611877
Lab ID Sample ID
92611877001 MW-05
92611877002 MW-06R
92611877003 MW-08R
92611877004 MW-07
Pace Analytical Services, LLC
2225 Riverside Dr.
Asheville, NC 28804
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Analytical
QC Batch Method QC Batch Analytical Method Batch
92611877001
MW-05
EPA
200.7
Rev
4.4
1994
710453
EPA
200.7
Rev
4.4
1994
710465
92611877002
MW-06R
EPA
200.7
Rev
4.4
1994
710453
EPA
200.7
Rev
4.4
1994
710465
92611877003
MW-08R
EPA
200.7
Rev
4.4
1994
710453
EPA
200.7
Rev
4.4
1994
710465
92611877004
MW-07
EPA
200.7
Rev
4.4
1994
710453
EPA
200.7
Rev
4.4
1994
710465
92611877001
MW-05
EPA
245.1
Rev
3.0
1994
708500
EPA
245.1
Rev
3.0
1994
708518
92611877002
MW-06R
EPA
245.1
Rev
3.0
1994
708500
EPA
245.1
Rev
3.0
1994
708518
92611877003
MW-081R
EPA
245.1
Rev
3.0
1994
708500
EPA
245.1
Rev
3.0
1994
708518
92611877004
MW-07
EPA
245.1
Rev
3.0
1994
708500
EPA
245A
Rev
3.0
1994
708518
92611877001
MW-05
SM 2540C-2015
708225
92611877002
MW-06R
SM 2540C-2015
708225
92611877003
MW-08R
SM 2540C-2015
708225
92611877004
MW-07
SM 2540C-2015
708225
92611877001
MW-05
EPA 300.0
Rev 2.1
1993
707478
92611877002
MWm06R
EPA 300.0
Rev 2.1
1993
707478
92611877003
MW-08R
EPA 300.0
Rev 2.1
1993
707478
92611877004
MW-07
EPA 300.0
Rev 2.1
1993
707478
92611877001
MW-05
EPA 350.1
Rev 2.0
1993
708348
92611877002
MW-061R
EPA 350.1
Rev 2.0
1993
708348
92611877003
MW-08R
EPA 350.1
Rev 2.0
1993
708348
92611877004
MW-07
EPA 350.1
Rev 2.0
1993
708348
92611877001
MW-05
EPA 353.2
Rev 2.0
1993
707349
92611877002
MW-06R
EPA 353.2
Rev 2.0
1993
707349
92611
877003
MW-08R
EPA 353.2
Rev 2.0
1993
707349
92611877004
MW-07
EPA 353.2
Rev 2.0
1993
707349
92611877001
MW-05
SM 4500-CI-E-2011
708577
92611877002
MW-06R
SM 4500-CI-E-2011
708577
92611877003
MW-08R
SM 4500-CI-E-2011
708577
92611877004
MW-07
SM 4500-CI-E-2011
708577
92611877001
MW-05
SM 5310B-2014
707676
92611877002
MW-06R
SM 5310B-2014
707676
92611877003
MW-081R
SM 5310B-2014
707676
92611877004
MW-07
SM 5310B-2014
707676
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 07/20/2022 04:38 PM out the written consent of Pace Analytical Services, LLC. Page 22 of 25

DC#_Title: ENV-FRM•HUN1-0083 v01_Sampie Condition Upon Receipt
AW
fu:ruacrrxss
Effective Date; 05/12/2022
Laboratory receiving samples:
Asheville Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsvill
Sa
. Client Name:
Upon Receipt
tZn
Cau vier;
Commercial
Custody Seal Present?
Packing Material
(_IFed Ex LjUPS t_J
❑Pace ❑
❑Yes �No Seals Intact?
[:Jot
Bubble Wrap
USPS
❑Yes IXNo
Atlanta❑ Kernersville❑
Project #: I WW : 92611877
lent 11111111 11111111111111
92611877
❑eubble Bags ❑None ❑ Other
Thermometer:
LJ IRGun ID: C� i 07l Type of Ice:
Correction Factor:
Cooler Temp: �' Add/Subtract (°C) d
Cooler Temp Corrected (°C): _ LI
USDA Regulated Soil( (A N/A, water sample)
Wet ❑Blue
Date/Initials Person Examining Contents: !�
Biological Tissue Frozen?
❑Yes ❑No ®N/A
❑None
Ternp should be above freezing to 6'C
]Samples out of temp criteria. Samples on ice, cooling process
has begun
r1
COMMEN75/SAMPLE
CLIENT
Person contacted:
ESOLUTION
Project Manager SCURF Review:
Project Manager SRF Review:
Lot ID of split cantairiers:
Uate/Time:
Oate:
Date:
Page 23 of 25
(lnaltrax In1;9R14 Paae 1 of 2

Document Name:
Document Revised: November 15, 2021
;aCleAnal
Sample Condition Upon Receipt (SCUR)
Page 2 of 2
real
Document No.:
f-CAR-0•033-Rev.08
Issuing Authority:
Pace Carolinas Quality Office
*Check mark top half of box if pH and/ dechlorination is
verified and within the acceptance range for preservation
samples,
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottles
Project # rWO9 92611877
PM: LJP Due Date: 07/12/22
CLIENT: 93-MSD
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Adjustment Log for Preserved Samples
Sample tD
Type to e I$ e
pH upon receipt
Oate preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lol I!
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, Incorrect preservative, out of temp, incorrect containers.
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Name and Affiliation (Sampler(s): M C )
Name and Affiliation (Inspector):__
Y Le11 Information
Nell ID: (�% �' _
Well Diameter: �r
Total Well Depth: �-� fE
Static Water Level: ./ ? R
Height of Water Column:ft
Field Data Slieet
Well Locked:
Construction:
Data Sheet Review:
Date:
NO)
'V Steel/StainlessSteel)
Multi Factor";' b.2 (`(Radius/12)2x3.14x7.481
Casing Volume: � gallons
Cal. 3 Volumes: gallons
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Pur„e Ir>forn�ati�n
Date Purged �� z7 J L Start : C1, Finish:.( i. J Purge Rate: t 0 0 MG/r'" `1
Purging Method:'- •ti 3-4 ZD C "Total Volume Purged: C ° (gallons/l
Sampling Information
Date Collected;_ (%/� �/ �- Time Collected: �/ /% I� (a pm)
Sampling Equipment Used: t�14 / 41 Intl ument ID:
Bottle Type
Preser<ration Analysis Required
J,
;"field i0�feasarenrents Observations /
Sample Temp (°C): �� r l7 Time: ` r �4 'Turbidity (ntu): �, ��~ Time: i .
I)iss bxy (mg/L): 3 ,_I_d Time: _ �/ s Fe 2+ mg/l.:--
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eneral/Y1'eaElter
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Document Name:
FieldDatasheet _
Document Number:
P-CAMLD-OOf.rev.02
Client: ,L_sij �^
Location;
Project:
Well ID; W . D „�
Reviewed Date and [3y;
Stabilization Test.
Document fsved: November 27, 2018
Pagd�ofl--
fssueing:#udiority:
Pace Htmtersville Quality Office
Well Maul AR-x .._4. fL1lt tC3 }kfl 5actar"
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(ntu)
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Document Name: Field data Sheet Date Issued: November 27, 2018
P3Ceslrralytic3(
Page: 1 ofZ -
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Document Number. F-CAR-F1.I)•001-rev.02
Issuing Authority; Face Huntersville Quality
--- --
Office
Client: ,_C. s�i ...Location:
4_ �L Project #:
Name and Affiliation (Sampler(s):_.J.11 S _ Field Data Sheet Review:
Name and Affiliation (Inspector):_
Well Information Date: By:
Well ID: _ : /t'�!v (7� Well Locked:
Well Diameter:
Construction: 'VC/Steel/Stainless Steel)
Total Well Depth: �/� ft Multi Factor*: r( �.� ('+(Radius/12)2x314x7.98J
Static Water Level; 1 f / . 7 ft. Casing Volume: gallons
Height of Water Column: u_`� Q ft Cal. 3 Volumes:_ gallons
Pump Intake:
) 4'
Pur eInformation
Date Purged_� �_ 7 / } Start: // Finish: � �/ � Purge Ra te:---�0 � 1H � %ia too/
Purging Method: t 2 i d �s I Total Volume Purged: ;L i%p r_- _ (gallons
Sampling Information
Date Collected: (' / 7/_ �`� Time Collected: t ��
—_ (am/pi-ft)
Sampling Equipment Used:_ ( . %1t+ t ._.__ _ I1lsfrument ID: y S "� 4:w i4:e 6
Bottle Type Preservation analysis Required
Field Measurements/Observations p
Sample Temp (°C): 1..'31L_Time:. t 1 4tZ 1 co
��,._Turbidity (ntu): � Time:
Diss Clxy (mg/L)� 1 Time: 14 11_ Fe 2-r mg/L. Tirrte:
Specific Cbnd. (US):!�'5 Z) Time: Res. Cl (mg/L)/(µg/i ): T e:
Sample pH (s.u.): S '? Time: ___% `P t Odor: N a - L Time: I IF&'e f'
ReDox (mV).fg o Time: `+ t I� Appearance: Ti
ReDox 6 (EH value):YSIProPlus+200mV_ Other; r----- Time:
GeneraVWeather Observations; L ✓Z ✓p -h �i /1/tV
(sunny/ •loudy/rain Temp. -20CF) Windv. (mp11)
Sampler Signature: Date: 7��1
Stabilization Test
Time
Temp,
piss Oxy.
Spec.
C011d•
pH (s.u.)
ReDox
Turbidity
Volume
Water
Purged,
uC)
(
m L )
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( mV )
ntu
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,
level (ft)
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40.

pate %55"'" oo oe: 'L
ceAMtyficaf.:
�e1d data Sheet
Document Nam
CAR- gip-001.tev.02
Docua`�tNun`ber.F-�.
TieldData Sheet
�lient: SamPleTts)•-� ' ._- f f
d Af�ation t
Name an lnspectot):r
r A Aviation (YF51 teel)
Name a
1Ve11Gecked' StainlessS
W
ormatl� �steel/
eU�� 122x3.
,/° r Consttuciton: ,a_x'�.48
Welllp r! 1J
etet: - — MultiFactoz*'-�`� gallons
WellD%ja it
1 __ V olva71e:
Toth WellDe?&v -_", Casing r gallons
c W ate, Level:
eviev+'•
pata SheetR
OfFic?
pate:
Cal 3 V olam�: mottoft
f lnjateT Calumn�--'.""_`� pumF lnt�e•-
te' -
Height op�$elta •—
`r-�$�onsl
pur elnfoYniata10 7 J St volumePuc�ed
hate pnt oed:�1.� Total-' ot
puxg"'g CollecteL
�ed:
�o�tati0n �
Sam lin � }� �"1=-- 1ns�UmentlD�__--�AnalysisRe�1"ned
Date Collected: e$e
tUsed:_ r,. s 1'r ration
Saml'li'ngRquipmen
13Ott1eTyt2e
✓----"-"' -.�---_--fir (�. � a
�%
ents�Obse—�
FieldNleas Cxm ` � ime: S a Fe2a mgt Jl).� e: j
em )o c Time ---"` Cl �mglL)J�t g Time: �� s
Sample T f (, 1 �' � 1 Res ,✓ c% a f14
pis C�xy �m&J1,): S Tame: Cdoxa a
ax �e: time: --
Cond ime' i Appe an'
T
J,C
J Saample pl� Hsu)• " r l�` 'Time: G OtbeT:
Repo% r- �-'`vainy)
ue);YSIPz t$13 )cloudy)
RepOX x Observations b io I1 . ✓ --�
eathe� r �-
Generaliy`I
On'Test gpec.
5tabilizati
ss Oxy• Cool•
Tie Temp `mgJi l os)
purged � bet'
f.,44
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pa
l� Volume Water
ReDox Turbidity cecxtoved level
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DocumentName: Field data Sheet
Document Number: F•CAR-FLU-001-r�
,lieut:- - --- M P i --
Name and Affiliation --
Name and Affiliation (InapeCtor):.-.-.---•-----
Well lnformat_� Well Locked -
.A)
NTT 27,2018
)ate Issued: e 1 of t
Pa g =
An�jf,ale
,co ty. Pace Hoffice
�a a Sheet 1wview:
Date:
_
well ID-- _/-'Z I ;� -- Construction: (PVC/Steed/StainiessSteel)
Well Diameter: _ -----" 12 2 x 3,14 x 7.aa�
// 7_ ft
Total WellDep y�
Static Water Level; G- `—
�i
Height of Water Column: ft
Multi Factor ._f glons
Casing V olume: - --
Cal. 3 Volumes:
1'ulnp Intake:_----'----
Par_ cre bf anal °n •� a `� ' Pur e Rate:
1 S � � Finish..----- g mmmlll/
Date Purged: ��_/ _/
J.� Start:__ _--
,� ow s
' Total Volume Purged: 3 (f
Purging M
Sam 1in61�o_ '---ti°r-'
7>
Date Collected: (J -
/
SamplingEq ipMentUsed:_j�•�--'-•'
Bottle Type
Time Collected:_.___-. � j I,
Preservation
pttalysis Required
Field M_eaasurew.99 Ob"l-1 S I Turbidity (ntu): _--- - - T -
1. a.. Time:_ - Time: -
Sample Twip. (°t-) - Time: s 1,,, Fe 2-f-
Diss bxy (mg/(r; Iles. Cl (mg
0 1Time: :mac. -
Odor:__
Specific Cond. (uS); ----7 7 Time:----
H (s.u.}: _�. -- —� f^�- � Appearance: —� -- SampleY Tune: _L---- Time:---
.. - �J 7 Other:----
ReDox (mv),#
ReDox (EH value):YSI ProPlus
GeneralfWeathexObservations; ( unn
loudy/rY) Temp• v_(°F) Windi_—(mph)
ler Si ature:�=—�-y--
Samp � Volume
Water pt_her
Stabilization Test spec ReDox Turbidity raxioved level (ft)
rem Diss Oxy Cond. PH (s.u') (MV) (ntu) (gallons] mis)
Time o p (1ng/li (uS) 00 i0C/O
purged (� �, .(